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HomeMy WebLinkAboutWI0400023_W/ Corrective Action_20011204IT Corporation of North Carolina, Inc. • the�i�-oup November 29, 2001 Ms. Sherri V. Knight North Carolina Department of Environment and Natural Resources Winston Salem Regional Office 585 Waughtown Street Winston-Salem, NC 27107-2241 Subject: Corrective Action Monitoring Report W. P. Ballard Property 2701 Branchwood Drive Greensboro, Guilford County, North Carolina Groundwater Incident No. # 6953 Site Priority Ranking: Low (E-070) IT Corporation of North Carolina Project # 107535 Dear Ms. Knight: 2200 Gateway Centre Boulevard. Suite 205 Morrisville, NC 27560-9129 Tel. 919467-2227 Fax. 919.467.1299 A Member of The IT Group - On behalf of Sears Logistics Services, Inc. (SLS), we are hereby forwarding for your review a Monitoring Report that presents the results of semiannual groundwater monitoring conducted at the subject site. in August 2001. This monitoring event was performed as a follow-up to Phase I full scale in situ chemical oxidation (ISCO) using sodium permanganate and the start-up of the High Vacuum Dual Phase (HVDP) remediation system. Phase I of the full scale ISCO was performed in June and July 2001 and the HVDP system was started up in March 2001. Analytical results summarized in this report will provide a baseline database for the evaluation of the effectiveness of Phase II full scale permanganate injection, which -was implemented at the site in October 2001. Follow up sampling of Phases I and 11 monitoring wells, is scheduled to be performed in December 2001 We would like to thank NCDENR for the issuance on November 21, 2001 of the UIC permit for the implementation of Phase III full scale ISCO. We would like to again respectfully request that NCDENR review and approve the Corrective Action Plan (CAP) submitted on May 20, 1999. As you know, Sears Logistics Services, Inc (SLS) is implementing a multi- technology approach to remediate contamination caused by a release (or releases) of tetrachloroethylene from the W. P. Ballard property. One aspect of the clean-up plan is to install and operate a HVDP extraction and soil vapor extraction (HVDPE/SVE) remediation system to reduce contaminant mass while awaiting approval of the UIC permit for ISCO with permanganate. A second aspect of the remedial action plan is to apply in situ oxidation with permanganate to further reduce contaminant concentrations in groundwater and soil to meet site clean-up goals. Operation of the HVDP/SVE system began on March 1, 2001 and was suspended on September 27, 2001. The system was shut down in preparation for implementation of the Phase II Full Scale injection in October to avoid pumping permanganate laden groundwater out of the subsurface where it is oxidizing contaminants in situ and into the on -site water treatment system where it could foul treatment system c ZE v d o� M� ;:Oa m cn= 0 z I i i IT CORPORATION aarend� or zhe rrc„oup CORRECTIVE ACTION/MONITORING REPORT March 2001 Through October 2001 W. P. Ballard Property 2701 Branchwood Drive Greensboro, Guilford County, North Carolina NCDENR Groundwater Incident # 6953 IT Corporation of North Carolina Project # 107535 November 29, 2001 Prepared by. IT Corporation of North Carolina, Inc. 2200 Gateway Center Drive, Suite 205 Morrisville, North Carolina 27560 (919) 467-2227 Volume I of II IT Corporation ofNorfh Carolina, Inc. A hfemher of The IT Croup Monitoring Report Page 2 of 2 W.P. Ballard Property November 29 2001 components. It is not expected that the HVDP/SVE system will be restarted since the entire area where the system was operating has now been injected with permanganate. The HVDP/SVE system will be disassembled and demobilized from the site in the first quarter of 2002. With the approval of the UIC permit for Phase III, IT Corporation is now proceeding with implementation of the Phase III ISCO using permanganate. The first step of the Phase III implementation will include excavation and removal of the source area "hot spot" soils from the site. The "hot spot' boundaries were identified via the collection and analysis of Geoprobe soil samples in October and November 2001. An infiltration gallery assembly, for the injection of sodium permanganate, will be installed at the base of the excavation cavity. Injection into the infiltration gallery will target residual vadose zone contamination not removed by excavation activities. Excavated soil materials will be treated on -site using a mobile thermal treatment unit and then disposed of off -site at a permitted disposal facility. The source soil excavation, treatment and off -site disposal is planned to be performed in December to 2001. The second step Hof the Phase III full-scale ISCO program will include subsurface injection of permanganate using the Geoprobe direct push method, which has been successfully implemented during the performance of Phases I & II. This step will be performed in January and February 2002. We look forward to working with the Department to proactively remediate this site. If you have any questions or concerns regarding the enclosed document, please contact Keith at 919-467-2227, extension 224 or Dale at extension 246. Sincerely, CORPORATION OF NORTH CAROLINA, INC. Dale E. Egner, L.G. Project Geologist Enclosure — Monitoring Report cc: Melanie Wells — Guilford County Health Department Mark Pritzl — UIC Permit Section Tom Grandys — SLS file 9�LG® R. Keith Og en�SM Senior Project Manager { IT Corporation ofNordi Carolina, Inc. f j A A/ember of The /7' Croup CORRECTIVE ACTION/MONITORING REPORT W. P. Ballard Property 2701 Branchwood Drive Greensboro, Guilford County, North Carolina NCDENR Groundwater Incident # 6953 IT Corporation of North Carolina Project # 107535 November 29, 2001 Prepared by. - IT Corporation of North Carolina, Inc. 2200 Gateway Center Drive, Suite 205 Morrisville, North Carolina 27560 (919) 467-2227 Release / Site Information: Land Use Category: To be assigned by Department Responsible Party: W.P Ballard and Company of Greensboro, Inc. Current Property Owner: 1775 The Exchange, Suite 320 Atlanta, Georgia 30339 Phone (770) 952-1661 'Contact: Mr. Wiley P. Ballard Date Release Discovered: September 3, 1991 Estimated Quantity of Release: Unknown Source of Release: 550-gallon gasoline UST and historic dry cleaning operations USTs at Time of Release: 1-550 gallon gasoline and 1-550 gallon heating oil Latitude and Longitude: 36.106 ° N and 79.82393° W Prepared by: f eviewed by: .�`0�'(1� �ARO4No � • 'lam Hass R. Hamm Dale Egner, LG = ° SEAL o 1708 ; Site Manager Project Geologist OLOG.-' F� ILIA RD R. Keith Ogde P.E., RSM Senior Project Manager i IT Corporation of North Carolina, Inc. A Alembcr of The IT Croup I Corrective Action/Monitoring Report Page ii W. P. Ballard and Downgradient Properties November 29, 2001 TABLE OF CONTENTS EXECUTIVE SUMMARY....................................................................................................................... 1 1.0 INTRODUCTION......................................................................................................................... 3 1.1 BACKGROUND........................................................................................................................................ 3 1.2 REPORT OBJECTIVES.............................................................................................................................. 6 2.0 FIELDACTIVITIES ...................................................................................................................... 7 2.1 REMEDIAL ACTIVITIES........................................................................................................................... 7 2.1.1 Fixed Treatment Activities............................................................................................................. 7 2.1.2 Phase I In Situ Chemical Oxidation Activities............................................................................... 9 2.2 SOURCE AREA GEOPROBE SOIL SAMPLING.......................................................................................... 10 2.3 SEMIANNUAL MONITORING ACTIVITIES............................................................................................... 11 2.3.1 Well Gauging............................................................................................................................... 11 2.3.2 Field Monitoring.......................................................................................................................... 11 2.3.3 Groundwater Sample Collection.................................................................................................. 11 2.3.4 Soil Vapor Sample Collection...................................................................................................... 12 3.0 RESULTS..................................................................................................................................13 3.1 GROUNDWATER GAUGING RESULTS.................................................................................................... 13 3.2 GROUNDWATER SAMPLING RESULTS................................................................................................... 13 3.2.1 Shallow Groundwater Sampling Results..................................................................................... 13 3.2.2 Deep Groundwater Sampling Results.......................................................................................... 14 3.3 DUPLICATE GROUNDWATER SAMPLE RESULTS.................................................................................... 15 3.4 SOIL SAMPLING RESULTS..................................................................................................................... 15 3.5 SOIL VAPOR SAMPLING RESULTS......................................................................................................... 16 3.6 PHASE I FULL SCALE ISCO RESULTS.................................................................................................... 16 4.0 RESULTS EVALUATION......................................................................................................... 18 4.1 GROUNDWATER MONITORING DATA................................................................................................... 18 4.1.1 Shallow Groundwater Data......................................................................................................... 18 .4.1.2 Deep Groundwater Data............................................................................................................. 20 4.2 SOURCE AREA SOIL DATA.................................................................................................................... 21 4.3 SOIL VAPOR DATA............................................................................................................................... 22 5.0 REMEDIATION EFFECTIVENESS EVALUATION.................................................................. 23 5.1 IN SITU CHEMICAL OXIDATION USING SODIUM PERMANGANATE........................................................ 23 5.1.1 Pilot Injection Test....................................................................................................................... 23 5.1.2 Preliminary Phase I Full Scale Application Results.................................................................... 24 5.2 TOTAL FLUID RECOVERY AND TREATMENT SYSTEMS......................................................................... 25 IT Corporation of North Carolina, Inc. A Member of The IT Croup I Corrective Action/Monitoring Report Page iii W. P. Ballard and Downgradient Properties November 29, 2001 5.2.1 Groundwater Recovery Data....................................................................................................... 25 5.2.2 Vapor Phase Recovery Data........................................................................................................ 26 6.0 CONCLUSIONS........................................................................................................................28 7.0 RECOMMENDATIONS.............................................................................................................30 FIGURES Figure 1 - Site Location Map Figure 2 - Monitoring Well Locations — W. P. Ballard and Downgradient Properties Figure 3 - W. P. Ballard and Axton -Cross Property Monitoring Well Locations Figure 4 - Remediation System Wells Figure 5 - ISCO Full Scale Application Phasing Plan Figure 6 - ISCO Phase I Area and Injection Point Layout Figure 7 - Geoprobe Soil Sample Location Map — July 10, 2001 Figure 8 - Groundwater Elevation Contours Shallow and Deep Monitoring Wells Figure 9 - Total VOCs - Shallow Monitoring Wells - August 2001 Figure 10 - Total VOCs - Deep Monitoring Wells - August 2001 Figure 11 - Total VOCs Isoconcentration Map for Shallow Wells- March & August 2001 Figure 12 - Total VOCs Isoconcentration Map for Deep Wells- March & August 2001 Figure 13 - Pilot Test: Pre- & Post -injection Total VOCs - Shallow Monitoring Wells Figure 14 - Pilot Test: Pre- & Post -injection Total VOCs - Deep Monitoring Wells Figure 15 - Phase I ISCO: Pre- & Post -injection Total VOCs - Shallow Monitoring Wells Figure 16 - Phase I ISCO: Pre- & Post -injection Total VOCs - Deep Monitoring Wells TABLES Table 1 - Well Construction Summary Table 2 - Summary of Groundwater Gauging and Field Monitoring Data Table 3 - August 2001 Groundwater Analytical Data Summary - Shallow Wells Table 4 - Historic Groundwater Analytical Data Summary - Shallow Wells -, Table 5 - August 2001 Groundwater Analytical Data Summary - Deep Wells Table 6 - Historic Groundwater Analytical Data Summary - Deep Wells Table 7 - Summary of Soil Analytical Results — July 10, 2001 Table 8 - Summary of Soil Vapor Monitoring Results — August 23, 2001 Table 9 - Summary of Historic Soil Vapor Monitoring Results Table 10 - Phase I Full Scale ISCO Application — Injection Data Summary IT Corporation of North Carolina, Inc. A Alember of The IT Croup Corrective Action/Monitoring Report Page iv W. P. Ballard and Downgradient Properties November 29, 2001 Table 11 - Phase I Full Scale ISCO Application — Field Monitoring Data Summary Table 12 - Pre- and Post -Injection Groundwater Data Summary- WP Ballard Property Table 13 - Phase I In Situ Chemical Oxidation - Shallow Groundwater Wells Preliminary Results Summary Table 14 - Phase I In Situ Chemical Oxidation - Deep Groundwater Wells Preliminary Results Summary Table 15 - Cumulative Mass Removal Via Groundwater Extraction Table 16 - NPDES Compliance Monitoring Summary Table 17 - Cumulative Mass Removal Via Vapor Extraction Table 18 - Off -Gas Effluent Air Permit Compliance Monitoring Summary APPENDICES Appendix A — Laboratory Analytical Data Reports — Groundwater Samples Appendix B — Laboratory Analytical Data Reports - Source Area Soil Samples Appendix C — Laboratory Analytical Data Reports - Soil Vapor Samples Appendix D — Field Data Sheets - Phase I Full Scale ISCO Injection Appendix E — Field Monitoring Data Sheets - Phase I Full Scale ISCO Injection Appendix F — Field Monitoring Results Graphs - Phase I Full Scale ISCO Injection Appendix G — Treatment System - Laboratory Analytical Data Reports IT Corporation of Nordl Cnrofinr+, Inc. A blember of The IT Group Corrective Action/Monitoring Report Page 1 W. P. Ballard and Downgradient Properties November 29, 2001 EXECUTIVE SUMMARY This monitoring report provides information on volatile organic compound levels in groundwater samples collected in August 2001 at the W. P. Ballard site in Greensboro, North Carolina. These samples were collected approximately six months after the startup of remedial activities using the high vacuum dual phase (HVDP) in conjunction with soil vapor extraction (SVE) system (HVDP/SVE) and six weeks after the completion of the full scale in situ chemical oxidation (ISCO) at the Phase I area, which was conducted in June and July 2001. The Phase I full scale injection was conducted under the conditions of North Carolina Department of Environment and Natural Resources (NCDENR) UIC Permit No. W10400023 issued by NCDENR on April 2, 2001. During the Phase I full scale application, Sodium Permanganate (NaMn04) was injected into the subsurface to oxidize chlorinated solvents, specifically tetrachloroethene (PCE). Approximately 21,450 pounds of NaMn04 were injected in the form of a 5% solution at 67 injection locations within the Phase I area. Over 2.2 million gallons of contaminated groundwater have been recovered and treated by the HVDP system. Approximately 50 pounds of dissolved phase PCE and 25 pounds of dissolved phase TCE have been recovered by this system. Additionally, over 313 pounds of vapor phase PCE and 64 pounds of total hydrocarbons (THC) have been removed by the vapor extraction system, which utilized a combination of HVDP and SVE treatment technologies. The August 2001 sampling results and other information discussed in this report provide information that will be used as an operational baseline for the future evaluation of the effectiveness of Phase II full scale ISCO, which was implemented at the site during October 2001. Based on the results of the August 2001 monitoring event and data acquired during the operation of the HVDP/SVE recovery and treatment system, the following conclusions are made: • The vertical and horizontal extent of the groundwater VOC contamination at the site, as defined in the December 1999 CSA, continues to be defined. Although the plume boundaries have not changed significantly, the intensity of the leading edge of the plume have been reduced. Total VOC concentrations in shallow and deep groundwater throughout the Phase I ISCO area have been reduced. Reduction in shallow wells ranged from 16% to 71 % and from 9% to 100% in deep wells. Since groundwater samples were taken soon after the Phase I injection, the results from the August 2001 sampling event are considered preliminary. More reduction is anticipated to occur in the Phase I area wells. The oxidation process, in previous events, by sodium permanganate has been seen to occur over an extended period after the actual injection of the oxidant. The decrease in total VOC concentration in deep groundwater wells was more pronounced than in shallow wells. The use of the bottom up injection method during the Phase I full scale application is thought to be the reason for this variation. The other reason is greater formation permeability at depth, which allowed better dispersion of the oxidizer and subsequently more oxidizer was available for reaction with VOCs in the deeper zone. • The HVDP/SVE system was started in March 2001 and operated intermittently throughout the current monitoring period. The system experienced several operational problems related to the thermal IT Corporation of North Carolina, Inc. A Afember of The IT Group Monitoring Report Page 2 W. P. Ballard and Downgradient Properties November 29, 2001 oxidizer. A total of 50 pounds of PCE and 25 pounds of TCE were removed from the site via groundwater extraction using the HVDP recovery wells. A total of 313 pounds of PCE, 2.7 pounds of TCE, and 64.4 pounds of THC were removed from the site by the vapor extraction system (i.e. HVDP/SVE). • Rebound in total VOC concentrations was observed in several shallow and deep wells located at the W. P. Ballard property (the primary source area). The observed rebound is suspected to be the result of continued dissolution of PCE from DNAPL entrapped in the source area vadose zone. • Total VOC concentrations continued to decrease in several shallow and deep wells located at the W. P. Ballard property (the primary source area). The observed decrease is most likely a result of operating source area SVE system wells. • Total VOC concentrations at locations immediately downgradient of the source area (i.e. Axton -Cross property) decreased at some locations (MW-27 for example) and increased at other locations (MW-10 for example). The observed change in the total VOC mass distribution can be attributed to the operation of the HVDP/SVE recovery- system during the current monitoring period. At several locations further downgradient of the Axton -Cross property (DW-5 and DMP-2), total VOC concentrations increased. The observed increases may be as a result of TCE migrating from the secondary source area previously identified on the Axton -Cross property. • Geoprobe soil sampling data obtained from the source area vadose zone in July 2001 indicate. that the bulk of the DNAPL contamination mass is still present in the source area soils. PCE contamination in excess of 2.5 million µg/kg was detected in the sample collected at the former location of the PCE AST. It is highly likely that the presence of the entrapped DNAPL in the source area vadose zone is the primary cause for the continuing contamination of groundwater at the site. • Soil vapor sampling data obtained in August 2001 from 12 soil vapor monitoring points located in the source area indicate that VOC vapor phase concentration has been significantly diminished. The observed decrease in vapor phase concentrations ranged from 84% to over 99%. Operation of the SVE system during the past six months and overall decrease in source area contamination mass following the implementation of the ISCO pilot test, are thought to be the primary reasons for the observed decreases. The following recommendations are made: • NCDENR should approve the CAP that was submitted in May 1999. • SLS should excavate and remove the source area "hot spot" from the site. The continued presence of high vadose zone VOC concentrations at and near the former location of the PCE AST appear to be impeding efforts to remediate source area and downgradient groundwater. • For the Phase III area, SLS should implement the full-scale permanganate injection to expedite reduction of VOC concentrations in source area groundwater and soils. The recommendations made after completion of the Phase II ISCO, should be followed. • SLS should suspend remedial efforts using the HVDP/SVE remediation system to allow for successful implementation of the ISCO technology. IT Corporation ofNorth Carolina, Inc - it Member of The IT Croup J Monitoring Report Page 3 W. P. Ballard and Downgradient Properties November 29, 2001 1.0 INTRODUCTION This Report presents and discusses the following: Groundwater analytical results for samples obtained from 38 site monitoring and treatment system wells. These samples were collected during the second 2001 semi annual groundwater monitoring event, which took place during the period from August 20 through August 23, 2001. • Soil vapor analytical results for samples obtained from 11 soil vapor monitoring points (SVMP) located at the source area of the site. These samples were collected on August 23, 2001. • Soil sampling analytical results for soil samples obtained from the site source area during July 2001 using standard Geoprobe direct push method. These samples were collected from three i locations on the W. P. Ballard Property at and near the former location of the PCE AST. i • Preliminary results of the Phase I full scale in situ chemical oxidation (ISCO) application performed at the W. P. Ballard property located in Greensboro, North Carolina. The Phase I full scale ISCO application was performed during the period from June 18 through July 11, 2001. • Results from the high vacuum dual phase (HVDP) and soil vapor extraction (SVE) and treatment systems for the operational period from March through September 2001. The HVDP/SVE system was installed as part of the remedial strategy for the site. 1.1 Background The subject site is a former dry cleaning supply facility, located at 2701 Branchwood Drive, approximately 400 feet east of Battleground Avenue in Greensboro, Guilford County, North Carolina. The site location is depicted on a portion of the United States Geological Survey (USGS) 7.5-minute topographic map of Greensboro, North Carolina Quadrangle, as shown in Figure 1. The subject site was developed in 1957 as a dry cleaning supply and distribution facility, operated by the W.P. Ballard and Company of Greensboro, Inc. (Ballard). From 1990 to July 1999, Phenix Supply Company leased the site from Ballard. A petroleum hydrocarbon release was discovered during the performance of underground storage tank (UST) removal activities in September 1991. At that time, two 550-gallon USTs used for the storage of heating oil and gasoline, were removed. The release was reported to have been associated with the gasoline UST. The estimated quantity and cause of the release are unknown. The NCDENR was notified of the release in September 1991. No other USTs are currently present at the site. In April 1992, Mortensen Engineering, Inc. (Mortensen) installed six monitoring wells (MW-1 through MW-6) at the site to assess the extent of the petroleum hydrocarbon contamination. Groundwater analytical results for samples obtained from these wells revealed the presence of high concentrations of dissolved phase IT Corporation of North Carolina, Inc. A Afemher of The IT Croup Monitoring Report Page 4 W. P. Ballard and Downgradient Properties November 29, 2001 chlorinated solvents. The chlorinated VOCs consisted mainly of tetrachloroethene (PCE) and its associated breakdown products. Detected PCE groundwater concentrations ranged from 11 µgh (MW-5) to 270,000 µg/I (MW-3). The chlorinated hydrocarbon release was attributed to PCE storage, handling, and distribution activities, historically performed at the site. The actual quantity of PCE released is unknown. The release - could have been caused by: • A leak or leaks in 55-gallon drums stored on site or from the 6000-gallon AST, or • Spillage during filling of the 6000-gallon AST from railcars or filing of distribution trucks from the 6000- gallon AST. In July 1999, the Phenix Supply Company vacated the property and ceased dry cleaning supply operations. In August 1999, the 6000-gallon AST used for the bulk storage of PCE was removed from the site. Subsequent to the discovery of the chlorinated solvent release, Mortenson performed several assessments between April 1992 and January 1997. A total of 38 monitoring wells were installed to determine the lateral and vertical extent of the dissolved phase plume. The wells included twenty six (26) Type II, shallow groundwater monitoring wells, installed to 35 feet bgs and twelve (12) Type III, deep monitoring wells; installed. to depths ranging from 47 feet to 63.5 feet bgs. In October 1998, IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI) was retained to prepare and implement a Corrective Action Plan (CAP) for the Ballard property and the adjacent property formerly owned by Sears Logistics Services. In January 1999, IT Corporation installed twelve soil vapor monitoring points (SVMP-1 through SVMP-12) to 12 feet bgs, two Type II (LMP-1 and LMP-2), and,four Type III monitoring wells (DMP-1 through DMP-4) to similar depths as those previously installed by Mortenson. A summary of well construction details is presented in Table 1. Site maps illustrating the locations of all monitoring wells on the W. P. Ballard and Downgradient Properties and W. P. Ballard and Axton -Cross properties are shown in Figures 2 and 3, respectively. In September and October 1999, IT Corporation conducted a comprehensive site assessment (CSA) investigation to delineate the extent of petroleum hydrocarbons in soil and groundwater at the site. As part of the soil CSA, four Geoprobe borings were advanced to 20 feet bgs at the W. P. Ballard and the former SLS properties. As part of the groundwater CSA, seven monitoring wells were installed to expand the groundwater monitoring network in the intermediate (60 to 80 feet below ground surface (bgs)) and deep/bedrock zones (100 to 150 feet bgs). Three of these wells are Type II monitoring wells (DW-13 through DW-15) were installed to a total depth of 65 feet bgs. The other four wells (BMW-1 through BMW- 4) are bedrock Type III monitoring wells were installed to delineate the vertical extent of the chlorinated solvent plume. The findings of the CSA investigation were presented in a report, which was submitted to the NCDENR on December 17, 1999. The CSA Report was approved by the NCDENR on April 9, 2001. IT Corporation of Norih Cam&n, Inc. A Afembet of The 17' Croup Monitoring Report W. P. Ballard and Downgradient Properties Page 5 November 29, 2001 In early 1999, IT Corporation performed an evaluation of remedial alternatives for this site. Based on this evaluation, a Corrective Action Plan (CAP) was prepared and submitted to the NCDENR in May 1999. The CAP proposed a conceptual remedial approach, which was based on evaluation of remedial alternatives and results of pilot and bench scale testing activities completed between 1997 and 1999. A. multi -phase approach was proposed. The initial phase proposed, the implementation of comprehensive in situ chemical oxidation via the application of sodium permanganate into the subsurface using direct push Geoprobe technology. Permanganate (a strong oxidizing agent) is expected to rapidly oxidize and transform chlorinated ethenes to innocuous breakdown products such as carbon dioxide, chloride ions, and manganese -dioxide. This process is anticipated to significantly reduce adsorbed phase and dissolved phase chlorinated ethylene concentrations in site's soil and groundwater. A pilot injection test was performed at the site during April and May 2000. The pilot test was conducted in two phases. The first phase,of the permanganate application was performed on the W. P. Ballard property in the area located in the immediate vicinity of the former location of the tetrachloroethene AST. The second phase of the pilot test was performed hydraulically downgradient of the source area, immediately south of Rollins Road, on the former SLS property. Subsequent to the pilot injection test, groundwater and soil vapor sampling were performed. Results from these events are presented in a report titled Final Project Evaluation Report of In Situ Chemical Oxidation Using Sodium permanganate, which was submitted to the NCDENR on December 11, 2000. The NCDENR approved the full scale UIC injection permit for Phases I and II on April 2, 2001. Following issuance of the UIC Permit, implementation of this remedial approach was carried out during June and July 2001 at the Phase I area. Preliminary results from the Phase I full scale application will be discussed in later sections of this report. On November 21, 2001, NCDENR approved the UIC permit for Phase III full scale injection. In addition to the in situ oxidation, a high -vacuum dual phase (HVDP) groundwater extraction and treatment system coupled with a low vacuum soil vapor extraction (SVE) and treatment system have been designed and installed at the site. The HVDP and low vacuum SVE systems have been designed to specifically address the source area and any adjacent areas where elevated adsorbed and dissolved phase concentrations continues to persist following the initial oxidation event. System installation activities started in January 2000 with the installation of the system recovery and injection wells, which included the construction of: • 29 HVDP recovery wells screened from 35 to 75 feet bgs; • 14 Soil Vapor Extraction (SVE) wells screened from 7 to 40 feet bgs; and • 9 Air Injection Wells (AIW) screened from 55 to 65 feet bgs. Remedial system piping installation was completed in April 2000 and component installation was completed in February 2001. The system was started up on March 1, 2001. H Corporation of North Cnm ina, Inc. A Member o! The IT Croup Monitoring Report W. P. Ballard and Downgradient Properties 1.2 Report Objectives Page 6 November 29, 2001 The objectives of this report are: • To provide current information regarding VOC groundwater concentrations across the site. After the startup of the treatment system in March 2001 and the completion of Phase I of the Full-scale ISCO at the area, VOC groundwater concentrations at the site are expected to drop. • To provide current information regarding soil vapor contaminant concentrations in the immediate vicinity of the source area of contamination at the site. • To provide preliminary information regarding the effectiveness of the Phase I Full-scale ISCO application completed at the site in July 2001. Residual permanganate, from the Phase I Full-scale application, is expected to continue to have a noticeable impact on total VOC concentrations within and outside the Phase I area. • To provide information regarding the effectiveness of the HVDP/SVE recovery and treatment system in lowering VOC concentrations in site's impacted media. The HVDP/SVE system has been operational since March 2001. • To establish a baseline of groundwater VOC concentrations in association with the Phase II Full-scale ISCO application, which has been performed during the period from October 1 through October 12, 2001. Groundwater analytical data from the August 2001 sampling event will be used to evaluate the effectiveness of the full scale injection of sodium permanganate at the Phase II area. IT Corporation ofNorth Carolina, Inc. A bfemher of The if croup Monitoring Report Page 7 W. P. Ballard and Downgradient Properties November 29, 2001 2.0 FIELD ACTIVITIES Several field activities have been performed at the site during the period covered by this remedial action monitoring report. Activities performed include the following: • HVDP/SVE system startup and operation, • Implementation of Phase I full scale ISCO, • Collection and analysis of soil samples from the source area, -- • Semi annual groundwater monitoring, and • Collection and analysis of soil vapor samples. Groundwater monitoring results obtained during March 2001 (i.e. prior to the startup of the HVDP/SVE system and implementation of the Phase I full scale ISCO) will be used as a baseline data for remedial activities that took place at the site. Groundwater monitoring results obtained during the current monitoring event (i.e. subsequent to the Phase I full scale ISCO and startup of the HVDP/SVE system) will be used to evaluate the effectiveness of remedial activities. Results from the August 2001 monitoring were also used as the basis for the design and implementation of the Phase II full scale ISCO application, which took place during October 2001. Additionally, these results will be used as a baseline to evaluate the effectiveness of the Phase II ISCO application. 2.1 Remedial Activities A multi -technology approach has been implemented to mitigate the subsurface contamination that -- impacts the site. High vacuum dual phase (HVDP) extraction and treatment in conjunction with low i vacuum soil vapor extraction (SVE), were selected to address dissolved phase chlorinated ethenes and residual soil concentrations in the vadose zone and the underlying water table aquifer. The l HVDP/SVE recovery and treatment system was specifically installed to address areas of the site impacted with relatively high adsorbed and dissolved phase chlorinated hydrocarbon concentrations. The second technology employs In Situ Chemical Oxidation (ISCO) using sodium permanganate. The f ISCO treatment technology was selected to address impacted media across the whole site including downgradient areas known to have relatively low levels of contamination. The following paragraphs provide a brief description of each of these technologies and the relating remedial activities performed during the current monitoring period. 2.1.1 Fixed Treatment Activities Remedial activities using the HVDP/SVE recovery and treatment system were started during March 2001. The HVDP/SVE system was installed to address the highest adsorbed and dissolved phase concentrations in the source area and areas immediately downgradient from the source. This system IT Cagoradon ofNorib Carolina, Inc. A Alemher of The 17' Croup i -- Monitoring Report Page 8 W. P. Ballard and Downgradient Properties November 29, 2001 uses a two -level approach to address adsorbed and dissolved phase concentrations in subsurface zones of varying permeability. The SVE system addresses adsorbed phase contamination in shallow low permeability soils, which extend to approximately 35 to 40 feet bgs, and adsorbed phase contaminants in the deeper smear zone created by dewatering activities. The HVDP system mainly addresses the saturated zone and extracts adsorbed phase contaminants from the created deep vadose zone as well. Groundwater recovery from the HVDP wells is performed using downhole submersible pumps placed at depths ranging from 60 to 75 feet bgs. Soil vapor recovery is performed using high vacuum positive displacement blowers. The HVDP/SVE system employs a total of 14 SVE wells and 29 HVDP wells, which were installed to address shallow and deep adsorbed and dissolved phase soil and groundwater contamination, respectively. A map showing remediation system wells is shown in Figure 4. Shallow soil vapor extraction wells are used to reduce adsorbed phase contamination in the source area and in areas exhibiting the highest dissolved phase concentrations, concurrent with dewatering activities. The deep HVDP recovery wells were installed to depths ranging from 64 to 75 feet below ground surface (bgs) to reduce dissolved phase contamination throughout the impacted aquifer. Groundwater recovered by the HVDP system is transferred to the treatment system compound through 6-inch HDPE piping. Soil vapor recovery lines are constructed of 2-inch diameter schedule 40 PVC. Soil vapor extraction vapors are transferred from the HVDP and SVE points using six (6) trunk lines. Recovered groundwater undergoes extensive treatment prior to being discharged. Initially, recovered groundwater. is pumped into a shallow tray air stripper designed to handle a minimum influent flow rate of 50 gpm. Treated groundwater from the air stripper then passes through a series of bag pre -filters into two (2) granular activated carbon (GAC) vessels placed in series designed to handle influent at a flow rate of 50 gpm. Treated groundwater exiting the GAC vessels is finally discharged into the City of Greensboro sanitary sewer system under NPDES Permit No NC008686. Air emissions from the HVDP/SVE system coupled with the off gas from the air stripper are routed to a thermal catalytic oxidizer equipped with a scrubber unit for treatment prior to discharge into the atmosphere. The influent air stream enters into the catalytic oxidizers heat exchanger where it is preheated. The air passes through the tube side of the heat exchanger into the burner chamber, where the contaminated air stream temperature is raised to the catalyzing temperature. When the VOC laden air passes through the catalyst, an exothermic reaction takes place. The VOCs in the air stream are reduced to carbon dioxide, water vapor, and hydrochloric acid. The treated air stream then passes through the shell side of the heat exchanger to preheat the incoming air stream. The vapor stream then enters the scrubber unit, which transfers the hydrochloric acid from the vapor phase to the liquid phase. A caustic agent is used to equalize the pH in the scrubber unit, prior to . discharging the clean water. Carbon dioxide gas is discharged directly to the atmosphere from the scrubber unit. Removal efficiencies of up to 99% reduction are attainable with this technology. The treatment system components are housed inside the warehouse building at the W. P. Ballard IT Corporation of North Carolina, Inc. A Member of TI)e IT Croup I i I - Monitoring Report Page 9 W. P. Ballard and Downgradient Properties November 29, 2001 r-. Property. The exhaust gases from the catalytic oxidizer scrubbers are vented to the atmosphere. One main electric control panel controls the remediation system. A remote monitoring telemetry system complete with multiple input and output capabilities is included with the control panel. The system is capable of both voice and data communications. During the performance of remedial activities, both effluent vapor and groundwater samples were collected to monitor the performance of the treatment system components. Influent, post -stripper and effluent groundwater samples were collected per the general requirements of a NPDES permit and to monitor the total mass removal of the treatment system. Influent and effluent soil vapor samples were collected to monitor the removal efficiency of the off -gas treatment unit and to track the total mass removal of the system. Samples collected were submitted for analysis per the respective permit requirements. Monthly samples were collected during the duration of system operations to track system mass removal. Monthly sampling was performed on the groundwater treatment system process stream for the duration of system operations. Effluent sampling was performed per the requirements of the NPDES permit requirements. Influent, post -stripper and mid -carbon samples were collected to monitor the performance of the individual system components, determine the frequency of carbon change -out events, and to calculate period and cumulative mass removal rates. 2.1.2 Phase I In Situ Chemical Oxidation Activities Full-scale in -situ chemical oxidation (ISCO) using sodium permanganate was performed in the Phase I area (remedial Zone 3) located hydraulically downgradient from the chlorinated solvent release source, which was formerly located at the W. P. Ballard property. The Phase I injection area is a paved area with generally lower concentrations of chlorinated ethenes. A site map showing the location of the three designated remedial zones is included as Figure 5. The Phase I application area, which is located around the former SLS warehouse, covers approximately 84,500 square feet (2 acres) of paved land. A site map showing the Phase I application area is included as Figure 6. Sodium permanganate was delivered to the site in 55-gallon drums in the form of a 40% (w/v) solution. The drums were stored in containment inside the warehouse at the W. P. Ballard property to control spills that may occur as a result of an accidental release. The 40% sodium permanganate was diluted to the desired concentration of 5% (w/v) in two 1,000-gallon polyethylene tanks, mounted in containment areas in the back of two cargo trucks leased for this purpose. For each 1000-gallon batch, 2.5 drums of the 40% permanganate solution were transferred to the polyethylene tank using a Teflon -lined double diaphragm pump. Each tank was then topped off with municipal water to prepare 1,000-gallons of 5% solution for injection. The 5% permanganate solution was transported from the mixing area to the individual application points using the truck -mounted 1,000-gallon polyethylene tanks. Because NaMn04 is a strong oxidizer, special safety precautions were taken with regard to IT Corporation ofNorih Carolina, Inc. A Afember of 'f'be lf Croup I I ' -- Monitoring Report Page 10 W. P. Ballard and Downgradient Properties November 29, 2001 handling, dilution, and mixing. The solution was injected into the subsurface through temporary Geoprobe points using a 4-foot stainless steel injection tip designed for this application. Bottom up injection was employed to deliver l� the solution into the subsurface. In the bottom up method, the probe is pushed to the target depth and injection progresses as the probe is incrementally pulled to the surface. This method of application worked well with as many as three injection points being completed in one day. The top -down application method was attempted at one point but proved to be ineffective using the available injection equipment. The formation would not seal tightly enough around the rod and the injection tip to prevent the permanganate solution from short-circuiting and coming back up the borehole. This problem also occurred, to lesser extent, with the bottom up method near the surface. Pulling the Geoprobe rod up a foot or two and attempting to again inject the permanganate solved the short - circuiting problem. Geoprobe points were incrementally advanced to the maximum attainable depth (i.e. until refusal was encountered) in 4-foot intervals. The maximum attainable depth of the Geoprobe application points at the Phase I area ranged from 30 to 73 feet bgs. After reaching the attainable depth, the injection process began by raising the probe in 5-foot intervals. At each 5-foot interval, the Geoprobe rig was disconnected from the boring and the Geoprobe rods were manifolded to the permanganate delivery system, which consisted of a custom-made injection pump capable of injecting up to 10 gallons per minute at an injection pressure of up to 300 psi. The permanganate mixture was injected into the subsurface via a 4-foot. slotted stainless steel screen. Approximately 35 gallons of 5% sodium permanganate solution were injected into the bottom of each 5-foot interval with the pressure, flow, and total volume documented on field data sheets. Prior to injection of the permanganate solution, 10 gallons of water were injected to fracture the formation. Injection flows ranged from 5 to 8 gallons per minute. Injection pressures ranged from 100 to 300 psi. After the application of the solution, the manifold was gated off, the pressure was relieved and the application assembly point was disconnected to allow the probe rig to reconnect. The application point was pulled up through the next 5-foot interval, and the application process was repeated throughout the saturated zone. At the completion of each point, borings were back -filled with hydrated bentonite hole plug. 2.2 Source Area Geoprobe Soil Sampling As suggested by NCDENR during the June 7, 2001 meeting regarding the source area at the W. P. Ballard Property, IT Corporation advanced three Geoprobe soil borings in this area on July 10, 2001. The borings were advanced to obtain soil samples from the vadose zone to evaluate current contamination conditions in the source area at the site. One of the borings (Boring 1) was advanced to IT Corporation of North Carolina, Inc. A Member of The IT Group I j I Monitoring Report Page 11 W. P. Ballard and Downgradient Properties November 29, 2001 12 feet below ground surface (bgs) at the location of the former tetrachloroethene (PCE) above ground storage tank (AST). Another boring (Boring 2) was advanced to 16-feet bgs at a location where the chlorinated hydrocarbon and petroleum hydrocarbon plumes commingle to form the overall contamination plume. A third boring (Boring 3) was advanced to 16-feet bgs at the former location of the gasoline underground storage tank (UST). A map showing the approximate locations of the three soil borings is shown in Figure 7. At each location, the subsurface soil was continuously sampled and field screened, using a PID meter, during drilling activities. From each boring, the sample that gave the highest PID response was sent for laboratory analysis. The samples were submitted to Test America Inc. in Nashville, Tennessee for chemical analysis using USEPA Method 8260. -2.3 Semiannual Monitoring Activities 2.3.1 Well Gauging On August 20, 2001, thirty eight (38) monitoring wells were gauged to measure depth to water and thickness of Light Non -Aqueous Phase Liquid (LNAPL) and Dense Non -Aqueous Phase Liquid (DNAPL) prior to sampling. No LNAPL or DNAPL detectable thicknesses were observed in site wells included in this monitoring event. Gauging data collected during the August 2001 monitoring event in addition to historical gauging data are shown in Table 2. Groundwater surface elevation contours based on the August 2001 gauging data are illustrated on Figure 8. 2.3.2 Field Monitoring Prior to purging shallow and deep monitoring wells, the following groundwater field parameters were measured; color, temperature, dissolved oxygen (DO) concentration, oxidation reduction potential (ORP), pH and conductivity. Recorded groundwater field parameters are tabulated in Table 2. 2.3.3 Groundwater Sample Collectidn During the period from August 20 through 23, 2001, Groundwater samples were collected from twenty (20) shallow monitoring wells and eighteen (18) deep monitoring wells. Prior to purging, each well was gauged using an electronic interface probe. A low flow technique using a variable frequency pump was used to purge and sample the wells. At each well location, an optimum purge flow rate was established using the variable frequency adjustment on the pump to prevent wells from drying up during purging. Purged groundwater was directed through a flow -through cell where pH, conductivity, dissolved oxygen, temperature, and oxidation/reduction potential (ORP) were continuously measured. A water sample was taken when the measured parameters in each well reached a quasi -stable condition (i.e. the most recent measurement did not vary more than 10% from previous two readings). If the well purged dry, the well was allowed to recover to at least 80% of the pre -purging water level and a sample taken. Immediately after collection, each sample was properly preserved, labeled, and packed in an iced -cooler. The groundwater samples were shipped, on daily basis, via overnight courier to Test America, Inc., in Nashville, Tennessee for analytical testing. IT Corporation of Norib Carolina, Inc. A Alemher of The IT Croup Monitoring Report Page 12 W. P. Ballard and Downgradient Properties November 29, 2001 Two duplicate samples were collected from wells MW-3 and MW-17 during the August 2001 monitoring ' event. These samples were collected to test the precision of the analytical procedure employed by the laboratory contracted to complete the required analyses. Therefore, these samples were submitted under blind sample names to avoid intentional bias. 2.3.4 Soil Vapor Sample Collection _ On August 23, 2001 eleven (11) soil vapor extraction wells SVMP-1 through SVMP-10, and SVMP-12 were sampled. The wells were sampled by removing the well cap and installing a temporary (tri-seal) wellhead adapter. A Gast° vacuum pump was connected to the wellhead adapter using polyethylene tubing, with new tubing being used at each point. Using the Gast" vacuum pump, three boring volumes of soil vapors, or approximately 28.5 ft3, were evacuated from each well at a maximum flow rate of 1.5 cfm. Following purging, samples were collected using an airtight syringe from the vacuum pump outlet. Prior to sample collection, the syringe was flushed with 50 ml sample. The sample for laboratory analysis was collected by injecting 40 ml aliquots into 22-ml airtight vials. Two vials were collected from each SVMP well. Air samples were shipped via overnight courier to Micro -Seeps, Inc., in Pittsburgh, Pennsylvania for the analysis by Method AM 4.03 - for EPA Method 601/602 Compound List. SVMP-11 was inaccessible for sampling during the August 2001 event. ff Corporation ofNorfh Carolina, Inc. A b/ember of The 17' Croup Monitoring Report Page 13 W. P. Ballard and Downgradient Properties November 29, 2001 3.0 RESULTS During the August 2001 monitoring event, a total of thirty eight (38) wells were gauged and sampled. The results of this monitoring are discussed in the following sections. Analysis and evaluation of the laboratory analytical results will be presented in Section 4. 3.1 Groundwater Gauging Results Depth to water measurements were collected on August 20, 2001 using an electronic interface probe and were referenced to the top of casing elevation for each well. Depth to water in shallow wells ranged from j 10.9 feet below top of casing (btoc) in MW-12 to 24.54 feet btoc in MW-23. Depth to water in deep wells ranged from 9.68 feet btoc in DW-7 to 34.26 feet btoc in DW-1: A summary of well gauging data from this monitoring event, along with historic water level data, are presented in Table 2. The historic data presented in Table 2 show seasonal fluctuations in the water table across the site. The August. 2001 groundwater elevation data are also graphically shown in Figure 8. As shown on Figure 8, the general prevailing groundwater flow direction is predominantly toward the east with an average hydraulic gradient - of 0.019 ft/ft (feet per foot). 3.2 Groundwater Sampling Results All groundwater samples obtained during the August 2001 sampling event were analyzed for Purgeable Halocarbons using EPA Method 601. In addition, six groundwater samples collected from wells MW-3, MW-4, MW-5, MW-10, DW-3, and BMW-2 were analyzed by EPA Method 602 for the presence of volatile petroleum hydrocarbons (i.e. BTEX or benzene, toluene, ethylbenzene, and xylenes). Analytical data from the August 2001 sampling event provides updated information regarding the conditions of groundwater VOC contamination at the site. These data will be used to: • Evaluate the effectiveness of the full scale in situ chemical oxidation performed at the Phase I area during the period from June 18 through July 11, 2001, and • Establish the pre -injection VOC-concentration baseline for Phase II of the full-scale in situ oxidation performed during the period from October 1 through October 15, 2001. Additionally, the design of the Phase II full scale in situ oxidation, including required quantities of sodium permanganate and injection rates, was completed based on the August 2001 analytical results. 3.2.1 Shallow Groundwater Sampling Results During the August 2001 event, groundwater samples were obtained from twenty (20) shallow monitoring IT Corporation ol'1Vordi Carolina, Inc. A Hember of The IT Group i I — Monitoring Report Page 14 W. P. Ballard and Downgradient Properties November 29, 2001 wells across the site. A summary of groundwater analytical data for shallow wells is presented in Table 3. Historic shallow groundwater data are presented in Table 4. Analytical data reports area included in Appendix A. Additionally, total VOC concentrations in shallow monitoring wells for the March 2001 sampling event are graphically presented in Figure 9. Review of analytical data presented in Table 3 and illustrated on Figure 9 reveals the following: ➢ Total VOC concentrations in shallow monitoring wells ranged from non -detect in wells MW-9, MW- 13, and MW-23 to 126,116 µg/I at well MW-3. ➢ Tetrachloroethene, (PCE) is the primary VOC constituent in the shallow groundwater plume at the site. PCE degradation byproducts are the secondary components of the shallow groundwater contamination plume. ➢ PCE concentrations in shallow groundwater samples ranged from non -detect (i.e. less than 1 µg/1) in wells MW-9, MW-13, MW-23, MW-27, and MW-28 to 126,000 µg/I at the location of well MW-3. ➢ Shallow groundwater contamination was most pronounced in the source area, specifically in well MW-3, which was installed near the location of the former PCE AST. ➢ Shallow groundwater contamination, based on total VOC concentration, was less pronounced in monitoring wells downgradient from the source area. It ranged from non -detect at the location of wells MW-9, MW-13, and MW-23 to 16,882 µg/I at the location of MW-10. These results will be further discussed in Section 4.1 3.2:2 Deep Groundwater Sampling Results During the August 2001 event, groundwater samples were obtained from eighteen (18) deep monitoring wells located across the site. A summary of groundwater analytical data for deep wells is presented in Table 5. Historic deep groundwater data are presented in Table 6. Analytical Data Reports are included in Appendix A. Additionally; total VOC concentrations in deep monitoring wells for the August 2001 sampling event are graphically presented in Figure 10. A review of the analytical data presented in Table 5 and illustrated on Figure 10 reveals the following: ➢ Total VOC concentrations in deep monitoring wells ranged from non -detect in wells DW-4, DMP-1, DMP-4 to 76,940 ELg/I in well HVDP-15. ➢ Tetrachloroethene (PCE) is the primary VOC constituent in the deep groundwater plume at the site. Trichloroethylene (TCE) and PCE degradation byproducts are the secondary components of the deep groundwater contamination plume. ➢ PCE concentrations in deep monitoring wells ranged from non -detect in wells DW-4, DW-5, DMP- 1, and DMP-4 to 62,000 FLg/I in well DW-3. TCE concentrations in deep monitoring wells ranged from non -detect in wells DW-4, DW-7, DW-8, DMP-1, and DMP-4 to 72,700 FLg/I in well HVDP-15. ➢ Deep groundwater contamination was most pronounced in the source area, specifically in wells DW-3 (62,069 ELg/I) and BMW-2 (45,856 µg/1), which are installed near the location of the former IT Corporation of'North Carolina, Inc. A Alcmhcr of The IT Croup Monitoring Report Page 15 W. P. Ballard and Downgradient Properties November 29, 2001 PCE AST. Deep groundwater contamination was also significant in HVDP-15 located near the Axton -Cross Building. ➢ Deep groundwater contamination was less pronounced in monitoring wells downgradient from the source area. It ranged. from non -detect in wells DMP-1 and DMP-4 to 4,880 in well HVDP-27. These results will be further discussed in Section 4.2 3.3 Duplicate Groundwater Sample Results The results from the duplicate samples were compared with results from the regular samples to determine the precision of the analytical method used (EPA Methods 601 and 602 in this case). In each case, the relative percent difference (RPD) based on total VOC concentration was calculated as a measure of precision. The results of this analysis are: Sample ID Regular Duplicate Absolute Relative Percent Difference Sample Sample Difference, (RPD), % Result, µg/1 Result, µg/I µg/I MW-3 126,116 123,125 2,991 .2.4 MW-17 3,115 3,300 185 5.8 The results of the duplicate sample analysis indicate that the precision of the analytical method - increases as the detected concentration of the target analytes in the sample increases. It should -be noted that both the regular and duplicate sample result were reported in the summary tables included with this report. However, the regular sample result will be used in future design calculations. 3.4 Soil Sampling Results A summary of the soil analytical results is presented in Table 7. The laboratory analytical reports are included in Appendix B. Review of the data presented in Table 7 indicates that: ➢ Chlorinated hydrocarbon contamination was most pronounced in subsurface soil at the former location of the PCE AST (Boring 1). At this location (Sample ID GP-7-1 0-01 -1), PCE was detected at 2,537 mg/kg (milligrams per kilogram or ppm). Other chlorinated hydrocarbons were also detected at this location at concentrations that ranged from 0.169 ppm to 3.38 ppm. Naphthalene, a petroleum hydrocarbon constituent, was detected at a very low level (0.4412 mg/kg) at this location. IT Corporation of North Carolina, Inc. A Afember of The IT Group i I- Monitoring Report Page 16 W. P. Ballard and Downgradient Properties November 29, 2001 ➢ Only PCE was detected in the subsurface sample (Sample ID GP-07-10-01-2) collected at the location of the commingled plume (Boring 2). PCE was detected at 0.0028 ppm. i➢ No petroleum hydrocarbon constituents were detected in the subsurface sample (Sample ID GP-7-10-01-3) obtained from the former location of the gasoline UST (Boring 3). Only PCE and 1,2-DCE were detected at low concentration levels of 0.0051 and 0.0149 ppm, respectively. These results will be further discussed in Section 4. 3.5 Soil Vapor Sampling Results A summary of the August 2001 soil vapor laboratory analytical results is presented in Table 8. Historic Soil Vapor analytical data are presented in Table 9. Laboratory analytical reports are presented in Appendix C. Review of the data presented in Table 8 indicates that: ➢ PCE is the primary contaminant at the source area. Detected PCE concentrations ranged from 8.4 ppm-v (parts per million by volume) at SVMP-3 to 1,300 ppm-v at SVMP-7. ➢ Total VOC concentrations ranged from 8.5 ppm-v to 1,300 ppm-v. ➢ Several other chlorinated solvents, mainly PCE degradation byproducts, have been detected in soil vapor samples at relatively low concentrations. Compounds detected include: chloroform, carbon tetrachloride, TCE, 1,2-DCA, cis- and trans- 1,2-DCE, and 1,1-DCE. ➢ Chlorinated solvent contamination was most pronounced in soil vapor samples obtained from SVMP points located near the former location of the PCE AST. These results will be further discussed in Section 4 3.6 Phase I Full Scale ISCO Results Phase I of the full scale ISCO application was performed over an 18-day period from June 18 through July 11, 2001. A total of 15,600 gallons of 5% sodium permanganate solution was applied to the subsurface using two Geoprobe rigs via direct push and pressure injection. A total of 67 injection points were completed in the Phase I area located mainly around the SLS warehouse. Fifteen of these points were advanced near selected Phase I area monitoring wells. A site map depicting injection points locations is shown On Figure 6. Injection dates, total injection depth, volume injected, and injection method used for each point are summarized on Table 10. Field data sheets for each of the injection points are included in Appendix D. Throughout the application process, field data were collected to monitor the injection process and its effects in the subsurface. During the performance of Phase I application, groundwater gauging and IT Corporation ofNorth Carolina, Inc. A Member of The 17' Croup Monitoring Report Page 17 W. P. Ballard and Downgradient Properties November 29, 2001 field monitoring for depth to water, pH, temperature, conductivity, ORP, dissolved oxygen, and color were performed daily during the application using an Interface Probe and YSI water meter. The field data collected during this monitoring program are summarized in Table 11. The field data sheets from the injection byproduct monitoring are included in Appendix E. Additionally visual observation were made to evaluate the potential occurrence of adverse impacts as a result of injecting a strong oxidant into the subsurface. No pressure or temperature build-up was observed in any of the monitoring points near the injection area. No adverse impact was noted on the pavement as a result of the injection - process. At the completion of the Phase I application activities, temporary soil borings were performed to monitor for the subsurface transport of the injected .permanganate solution. The investigation consisted of advancing Geoprobe borings in the immediate vicinity of Injection Points IP-67 and IP-34. Continuous 1.5- inch diameter soil cores were collected using a standard Geoprobe Macro -core sampler. Soil cores were visually inspected for discoloration associated with the transport and reaction of the permanganate solution. The temporary soil borings were abandoned using the same technique employed on the application points. Based on visual inspection of the macro core samples, the estimated short-term injection radius of influence in the Phase I area ranged from 8 to 15 feet. A preliminary evaluation of the Phase I ISCO effectiveness based on analytical data from the August 2001 sampling event will be discussed in Section 5. IT Corporation of North Carolina, Inc. A Alembcr of The IT Croup Monitoring Report Page 18 W. P. Ballard and Downgradient Properties November 29, 2001 4.0 RESULTS EVALUATION 4.1 Groundwater Monitoring Data For a preliminary data evaluation, the groundwater analytical results presented in Section 3.0 were compared to the North Carolina Administrative Code 2L Standards (NCAC 2L). Table 3 (groundwater analytical results for shallow wells) and Table 5 (groundwater analytical results for deep wells) list the NCAC 2L standard for each VOC. Analytical concentrations above the NCAC 2L standard are bolded and exceedances are discussed in the following sections. 4.1.1 Shallow Groundwater Data Review of the VOC analytical data presented in Table 3 compared to the NCAC 2L standards reveals the following: ➢ PCE concentrations exceeded the NCAC 2L standard of 1 µg/I in all samples but those obtained from wells MW-9, MW-13, MW-23, MW-27, and MW-28 (i.e. PCE concentrations continue to exceed the NCAC 2L standard in 75% of the shallow wells sampled during August 2001). ➢ Tricholoroethene (TCE) concentrations exceeded the NCAC 2L standard of 2.8 µg/I in samples obtained from wells MW-2, MW-4, MW-10, MW-12, MW-15, MW-17, MW-22, MW- 27, MW-28, LMP-1, and LMP-2. That is, TCE concentrations continue to exceed the NCAC 2L standard in 55% of the shallow wells sampled during August 2001. ➢ Cis-1,2-Dichloroethene (cis-1,2-DCE) concentrations exceeded the NCAC 2L standard of 70 µg/I in samples obtained from MW-2, MW-4, MW-17, MW-27, and MW-28 (i.e. 25% of the shallow wells). - ➢ 1,2-Dichloroethene (1,2-DCA) concentrations exceeded the NCAC 2L standard of 0.38 µg/l in I� samples obtained from MW-6 and MW-10 (i.e. 10% of the shallow wells). ➢ 1,1-Dichloroethene (1,1-DCE) concentrations exceeded the NCAC 2L standard of 7 µg/1 in one sample obtained from MW-5 and MW-6 (i.e. 10% of the shallow wells). ➢ Carbon tetrachloride concentrations exceeded the NCAC 2L standard of 0.3 µg/I in samples _ obtained from MW-3 (i.e. 5% of the shallow wells). ➢ Chloroform concentrations exceeded the NCAC 2L standard of 0.19 µg/I in samples obtained from MW-1, MW-2, MW-3, MW-10, MW-15, MW-17, LMP-1 and LMP-2 (i.e. 40% of the - shallow wells). -- ➢ 1,2-Dichloropropane concentrations in wells MW-12, LMP-1, and LMP-2 exceeded it NCAC IT Corporation of North Caro&Ja Inc. rt Akinbcr of The 17' Croup - Monitoring Report Page 19 W. P. Ballard and Downgradient Properties November 29, 2001 2L standard of 0.56 µg/I (i.e. 15% of the shallow wells). None of these wells is located at the source area of the site. Analytical data from the August 2001 sampling event, for selected monitoring wells, was compared to analytical results from previous sampling events. Historic groundwater analytical data for shallow monitoring wells is presented in Table 4. Review of the data presented in Table 4 reveals the following: ➢ Total VOC concentration in wells MW-3, MW-4, and MW-6, located in the primary VOC contamination source area, dropped since the last sampling event conducted in March 2001. The observed decrease ranged from 6% at the location of MW-6 to 70% at the location of MW- 4. The observed decrease in these wells may be due in part to the continuing impact of sodium permanganate injected during the ISCO pilot test conducted in May 2000 and in part due to the ,operation of the SVE system. ➢ Total VOC concentration in wells MW-1, MW-2, and MW-5, also located in the primary source area, increased since the last sampling event conducted in March 2001. The observed increase ranged from 239% at the location of MW-1 to 377% at the location of MW-2. The observed increase in total VOC concentrations at these well locations is due mainly to an increase in PCE concentrations. Continuing dissolution of the DNAPL entrapped in the vadose zone is the primary source of PCE in these wells. ➢ Total VOC concentration in MW-7, located relatively upgradient from the source area decreased by 84%.since September 2000 (a sample was not collected from this well in March 2001). Since total VOC concentrations in this well have been fluctuating from non -detect to 184 µg/l, the observed decrease is most likely due to seasonal fluctuations. ➢ Total VOC concentration in MW-10, located immediately downgradient from the source area, increased by 714%. The observed increase at this location can be attributed to the short—term effect of pumping of the network of HVDP recovery wells (i.e. HVDP-21 through HVDP-29) located immediately downgradient from MW-10. Pumping of the HVDP wells may have caused the mobilization of source area contamination to downgradient locations, which in the process may have led to the observed increase in MW-10. ➢ Total VOC concentration in MW-28 located on the Axton -Cross property, increased by 199% since March 2001. The observed in total VOC concentration at this location is due mainly to increase in Cis-1,2-DCE and TCE concentrations. Both of these constituents have been historically detected in this well. ➢ Total VOC concentration in MW-27 also located on the Axton -Cross property, decreased by 90% since March 2001. The observed decrease at this location is due primarily to active remediation using the HVDP/SVE system wells near the location of MW-27. ➢ Total VOC concentration in wells MW-12, MW-13, MW-15, MW-17, MW-18, MW-22, all located in the Phase I ISCO area, decreased since the March 2001 sampling event. The observed decrease ranged from 16% at the location of MW-15 to 100% at the location of MW-13. The - IT Corporation ofNorth Carolina, Inc. A Member of The !T' Croup Monitoring Report Page 20 W. P. Ballard and Downgradient Properties November 29, 2001 decrease in total VOC concentrations in these wells is primarily as a result of the full scale ISCO application performed at the Phase I area during June and July 2001. Current (August 2001) and previous (March 2001) total VOC concentration isopleths for shallow wells are plotted together on the same isoconcentration contour map as shown in Figure 11. A comparison of current and previous isopleths shows the following: • Significant reduction in the extent of the distal (downgradient) portion of the plume manifested primarily as a narrowing of the contaminated area on the Axton -Cross and SLS properties. • A contraction of the 5,000 mg/I contour due to the implementation of the Phase I ISCO at the downgradient area. • A slight expansion of the 10,000 and 20,000 µg/I contours downgradient. This downgradient movement is likely due to the groundwater gradient being influenced by the pumping associated with operation of the remediation system. 4.1.2 Deep Groundwater Data Review of the VOC analytical data presented in Table 5 compared to the NCAC 2L standards reveals the following: ➢ PCE concentrations in deep monitoring wells exceeded the NCAC 2L standard of 1 µg/I in all but samples obtained from wells DW-4, DW-5, DMP-1, and DMP-4 (i.e. PCE concentrations continue to exceed the NCAC 2L standard in 78% of the deep wells sampled during August 2001). ➢ TCE concentrations in deep monitoring wells exceeded the NCAC 2L standard of 2.8 µg/I in all but samples obtained from wells DW-4, DW-5, DW-8, DMP-1, and DMP-4 (i.e. TCE concentrations continue to exceed the NCAC 2L standard in 78% of the deep wells sampled during August 2001). ➢ Cis-1,2-Dichloroethene concentrations exceeded the NCAC 2L standard of 70 µg/I in samples obtained from BMW-2, HVDP-15, HVDP-22, and HVDP-27 (i.e. 22% of the deep wells). ➢ Chloroform concentration exceeded the NCAC 2L standard of 0.19 µg/I in the sample obtained from DW-3 (i.e. 5.6% of the deep wells). ➢ 1,1-Dichloroethene concentrations exceeded the NCAC 2L standard of 7 µg/I only in the -- sample obtained from BMW-3 (i.e. 5.6% of the deep wells). ➢ Benzene concentration exceeded the NCAC 2L standard of 7 µg/I only in the sample obtained from DW-3 (i.e. 5.6% of the deep wells). Deep well analytical data from the August 2001 sampling event was compared to analytical results from previous sampling events. Historic groundwater analytical data for deep monitoring wells is presented in Table 6. Review of the data presented in Table 6 reveals the following: IT Corporation of North Carolina, Inc. A A1ember of The ITGroup Monitoring Report Page 21 W. P. Ballard and Downgradient Properties November 29, 2001 ➢ Total VOC concentrations in wells DW-3 and BMW-2, located in the primary VOC contamination source area, increased by 28% and 36%, respectively since the March 2001 sampling event. The increase can be attributed to the continuing dissolution of the entrapped DNAPL from the source area vadose zone. ➢ Total VOC concentration in well DW-5 and DMP-2, located in the middle parking lot downgradient from the primary and secondary source areas, increased by 169% and 39%, respectively since March 2001 sampling event. The observed increase at these well locations is due to an increase in TCE concentration. Increased TCE concentrations can be attributed to pumping of treatment recovery wells located in the middle parking lot (i.e. HVDP-21 through HVDP-29). Operation of these wells may have led to the transport of TCE contamination from upgradient source locations. ➢ Total VOC concentrations in wells DW-7, DW-8, DW-13, DMP-1, DMp-3, and DMP-4, all of which located in the Phase I ISCO area, decreased since the March 2001 sampling event. The observed decrease ranged from 9% at the location of DW-7 to 100% at the locations of DMP-1 and DMP-4. The decrease is primarily due to the full scale ISCO application at the Phase I area, which was performed during June and July 2001. ➢ Total VOC concentration in wells DW-14 and DW-15, located along the north side of the SLS warehouse and downgradient from the Phase I ISCO application area, experienced variable change. Total VOC concentration in DW-14 increased by 117% and in DW-15 decreased by 5%. Since, these, two wells have low concentrations (i.e., 571 and 561 µg/I, respectively), the observed changes may be as a result of experimental variability and seasonal fluctuations. Current (August 2001) and previous (March 2001) total VOC concentration isopleths for deep wells are plotted together on the same isoconcentration contour map as shown in Figure 12. A comparison of current and previous isopleths shows that current total VOC concentration isopleths indicate a significant reduction in the extent of groundwater contamination deeper aquifer zone compared to March 2001 levels. Total VOC concentrations appear to be concentrated in remedial zones #1 and #2 (i.e. W. P. Ballard and the Axton -Cross Properties). The distal portion of the plume is greatly reduced and appears to be isolated from the source area. 4.2 Source Area Soil Data Geoprobe soil sampling data for samples collected on July 10, 2001 are presented in Table 7. These data confirm that PCE is the primary contaminant at the source area. The highest PCE concentration of 2,537 ppm was detected in the sample collected at the location of the former PCE AST. It appears that the source area vadose zone soils continue to exhibit high levels of PCE. This PCE concentration indicates the likely presence of an entrapped DNAPL in the source area vadose zone. Continuing dissolution of PCE from this DNAPL is the primary source for groundwater contamination at the site. The exact limits of the source area "hot spot" are not well defined at the present. Therefore, additional IT Corporation of North Carolina, Inc. A dlemher of The IT Croup Monitoring Report Page 22 W. P. Ballard and Downgradient Properties November 29, 2001 soil samples need to be.collected from the source area vadose zone to better define the lateral and vertical extents of the heavy PCE contamination. The highest PCE concentration determined during this investigation will be used to calculate the quantity of permanganate required to treat the source area vadose zone during the Phase III application. The use of this concentration for this application will provide a conservative estimate regarding oxidant amounts to insure that PCE within the source area will be fully oxidized. 4.3 Soil Vapor Data Comparison of the recent soil vapor sampling data presented in Table 8 with the historic soil vapor data presented in Table 9 indicate that VOC concentrations in the source area vadose zone vapor phase have been significantly diminished. The data indicate that over 99% reduction had been achieved at some locations. Except for the sample obtained from SVMP-8, the observed reduction was in excess of 90%. In SVMP-8, the observed reduction in vapor phase concentration was 84%. Operation of the soil vapor extraction system over the past six months was primarily responsible for the observed reductions. In addition, ISCO remedial activities performed during the May 2000 pilot test are partially responsible for the decrease in soil vapor concentrations. IT Corporation of North Carolina, Inc. A Alemher of The 17' Croup Monitoring Report Page 23 W. P. Ballard and Downgradient Properties November 29, 2001 5.0 REMEDIATION EFFECTIVENESS EVALUATION Remedial activities implemented at the site during the current monitoring period included the implementation of the full scale ISCO at the Phase I area (remedial zone 3) and startup and operation of the HVDP/SVE system. The following paragraphs provide a brief discussion regarding the effectiveness of site remediation efforts based on various remedial data acquired during this period. 5.1 In Situ Chemical oxidation Using Sodium Permanganate In situ chemical oxidation using sodium permanganate has been applied at the site during a pilot test performed in May 2000 and during a full scale ISCO application performed at the Phase I area (i.e. remedial zone #3) in June and July 2001. Approximately 34,100 pounds of sodium permanganate were injected in the form of 15% solution during the pilot test and 21,450 pounds where injected in the - form of 5% solution during the Phase I full scale application. The following sections discuss the observed change in total VOC groundwater concentrations as a result of sodium permanganate injection during these two events. 5.1.1 Pilot Injection Test The ISCO pilot test using sodium permanganate was conducted approximately 15 months prior to the August 2001 sampling event. Pre- and post- pilot injection groundwater analytical results for wells at the WP Ballard property are summarized in Table 12. As shown in Table 12, pre -injection baseline groundwater quality data were acquired on March 24, 2000. Several sampling events have been conducted since the completion of the pilot test in May 2000. Total VOC concentrations in wells MW-3, located near the former location of the PCE AST, and MW- 4, located in the area of the former petroleum UST, continue to decline. Both of these wells experienced significant rebound immediately after the performance of the pilot test. The primary reason for the observed reduction in total VOC concentration in these two wells can be attributed to the operation of the SVE system, which was installed to target shallow (i.e., <40 feet bgs) subsurface soil contamination. The August 2001 analytical results indicate that groundwater total VOC concentrations rebounded -in several wells around the pilot test injection area. The data presented in Table 12 reveal that - rebounding in total VOC concentration was observed in wells MW-1, MW-2, MW-5, DW-3, and BMW- 2. The reason for the observed rebound can be attributed to continuing dissolution of chlorinated solvents from the DNAPL entrapped in the source area vadose zone. Additionally, it appears that, as of the August 2001 sampling event, most residual sodium permanganate from the pilot injection test has been fully consumed by the oxidation processes. IT Corporation ofNorth Carohna,.be. A dlezuher of The lf Croup Monitoring Report Page 24 W. P. Ballard and Downgradient Properties November 29, 2001 The observed change in total VOC concentrations in shallow and deep groundwater wells since the pilot test in May 2000, is illustrated in Figures 13 and 14, respectively. The observed VOC concentration profile in shallow source area wells is more complex than that in deep wells. The complexity stems from the hydrogeologic nature of the surficial aquifer at the site, which is less permeable than the deep aquifer and more vulnerable to seasonal fluctuations in the water table. 5.1.2 Preliminary Phase i Full Scale Application Results Groundwater samples collected during the August 2001 sampling event from 13 wells (7 shallow and 6 deep wells) located in the Phase I application area, provided preliminary information regarding the effectiveness of this application. To quantify the effectiveness of the Phase I ISCO application, analytical results from the August 2001 sampling event were compared to the March 2001 analytical data (i.e. baseline data). Pre- and post- Phase I analytical results for shallow and deep monitoring wells are presented in Tables 13 and 14, respectively. The observed change in total VOC concentrations in Phase I shallow and deep groundwater wells is illustrated in Figures 15 and 16, respectively. Review of the data presented in Table 13 and illustrated in Figure 15 reveal that the observed reduction in total VOC concentrations in Phase I shallow wells ranged from 16% at the location of MW-15 to 71 % at the location of MW-18. Reduction in dissolved phase PCE ranged from 12 % at the location of MW-22 to 63% at the location of MW-15. Review of the data presented in Table 14 and illustrated in Figure 16 reveal that reduction in total VOC concentration in Phase I deep wells ranged from 9% at the location of DW-7 to 100% at the locations of DMP-1 and DMP-4. Reduction in dissolved PCE concentration in Phase I deep wells ranged from 6% at the location of DW-7 to 100% at the locations of DMP-1 and DMP-4. The reason for the variable reduction in total VOC concentration in wells located within the Phase I application area is primarily due to variability in the amounts injected at various Phase I areas. For example, areas known to have low VOC concentrations, such as the area around MW-12 and DW-7, received less oxidant than areas known to have high VOC concentrations, such as the area around MW-17, DW-8, and DMP-4. The observed reduction in total VOC concentrations was more pronounced in deep wells and relatively less pronounced in shallow wells. The reason for the observed higher reduction in deep wells is due in part to increased formation permeability with depth and in part due to the nature of the injection method. The Bottom -up injection method appears to create a preferential flow pathway at the bottom of the borehole. The presence of this pathway leads to the accumulation of the injected oxidant at the bottom of the borehole where hydraulic permeability is relatively higher. Injected permanganate solution would be expected to flow more readily through the least flow -resistant pathway within the IT Corporadon ofNorth Carolina, Inc. A dlember of The IT Croup Monitoring Report Page 25 W. P. Ballard and Downgradient Properties November 29, 2001 subsurface. During injection, daily field monitoring of indicator parameters including pH, DO, ORP and specific conductivity was conducted in area monitoring wells to monitor the distribution of the oxidizer and the reaction of the aquifer to treatment. A follow-up monitoring of field indicator parameters was conducted on August 3 and August 20, 2001. Field measurements collected to date were graphed for each monitoring well and are included in Appendix F. As was the case in the pilot test, for most wells, the graphs show a temporary increase in ORP as a primary indicator that oxidation is taking place. Expected temporary changes in the other parameters are also shown on the graphs. These data show that oxidation is occurring in groundwater. 5.2 Total Fluid Recovery and Treatment Systems As mentioned before, a multi -technology approach has been implemented to remediate the W. P. Ballard and downgradient properties. HVDP in conjunction with SVE (HVDP/SVE), were selected to mitigate -- dissolved -phase VOC concentrations and residual soil concentrations in the overburden aquifer. Although these two systems were simultaneously operated, dissolved phase and sorbed phase remedial data will be evaluated separately. The following paragraphs provide a brief description of the total fluid recovery results and briefly discuss the impact of problems encountered during the remedial period on the overall treatment system effectiveness. 5.2.9 Groundwater Recovery Data During the operational period from March 1, 2001 through September 6, 2001 the groundwater recovery and treatment system processed approximately 2,209,832 gallons of groundwater. The system was down for approximately 78 days during the first 4 months of the operational period due to problems associated with the catalytic oxidizer used to treat system off -gas. The catalytic oxidizer unit has been down several times due to design deficiencies related to the scrubber unit. The manufacturer replaced and rebuilt several parts to address deficiencies and render the unit operational. Except for maintenance shutdowns, the system was operated continuously after the catalytic oxidation unit was repaired. Monthly influent and pre -carbon (mid -influent) samples were collected to monitor the effectiveness of the groundwater treatment system. Based on system totalizer flow rate of treated water, and influent and effluent concentrations of VOC compounds, the groundwater treatment system removed a total of 24.6 pounds of TCE and 50.1 pounds of PCE during the operational period. Groundwater removal data are presented in Table 15. Copies of the laboratory analytical reports for the treatment system samples obtained during the current reporting period are included in Appendix G. Treated groundwater is discharged to the sanitary sewer system per NPDES Permit # NC008686. Per IT Corporation ofNorth Carolina, Inc. A Member of The IT Croup Monitoring Report Page 26 W. P. Ballard and Downgradient Properties November 29, 2001 NPDES permit requirements effluent samples were obtained from the treatment system on monthly basis throughout the period of system operation. Several exceedances to NPDES permit levels were reported during the monitoring period. NPDES permit analytical results (effluent sampling) are presented in Table 16. As shown in Table 16, NPDES permit exceedances were mainly associated with total suspended solids and chronic toxicity data. IT Corporation implemented several steps to identify and eliminate the chronic toxicity problem. After the effluent failed the chronic test in June, IT Corporation cleaned out sediment that had accumulated in the influent and effluent holding tanks and changed out the carbon in the two 1000-lb carbon vessels at the site. Since the effluent failed the second multiple concentration chronic toxicity test in July, it was concluded that the tanks sediment was not the cause of the problem. In August, an attempt was made to determine the cause for the chronic toxicity failures by collecting and analyzing water samples for a full range of water quality parameters. The samples were split between two labs for chronic toxicity testing, however, both tests failed, indicating that the problem was likely not due to lab error. Additionally, water quality analysis performed on two sets of system effluent samples in August, indicated that the effluent had levels of dissolved Aluminum, Iron, Magnesium and Zinc in the part per million range. These metals are naturally occurring in groundwater at this site and are not significantly removed by the current treatment system. It was hypothesized that one or more of these metals may be the cause of effluent toxicity. It was also concluded that the PCE and other VOC contamination from the site is not likely being the cause of the problem. The groundwater remediation system was designed to remove volatile organics such as PCE from the effluent and the laboratory analytical data confirmed that PCE and other VOCs were in fact being removed to levels below the laboratory detection limits. A cost -benefit analysis was performed to evaluate the installation of additional treatment to eliminate the naturally occurring inorganic constituents. It was concluded that the cost of modifying the system was not justified. Therefore the HVDP/SVE system was shutdown on September 27, 2001. The remainder of the site remediation will depend on the ISCO technology, which has shown to be effective. 5.2.2 Vapor Phase Recovery Data Throughout the treatment period, influent gas samples were collected on monthly basis to evaluate the effectiveness of VOC removal via volatilization by the HVDP/SVE system. A summary of the volatile organic compounds extracted via volatilization by the HVDP/SVE system is presented in Table 17. VOC concentrations in the influent air stream of the HVDP/SVE system have been measured in parts per million (ppm). Influent data for only cis-1,2-DCE , TCE , PCE, and total hydrocarbons (THC) are included in Table 17. During the operational period from March through September 2001, PCE influent i, concentrations ranged from non -detect (i.e. less than 0.23 ppm) on August 23, 2001, to 46 ppm on May 11, 2001. TCE influent concentrations ranged from non -detect to 0.68 ppm. During the operational period, i IT Corporation of North Carolina, Inc. A Afember of Vie 17' Croup I Monitoring Report Page 27 W. P. Ballard and Downgradient Properties November 29, 2001 approximately 313 pounds of PCE, 2.7 pounds of TCE, 2.6 pounds of cis-1,2-DCE, and 64.4 pounds of THC, were extracted by the HVDP/SVE system. Copies of the laboratory analytical reports for the HVDP/SVE system gas samples obtained during the current reporting period are included in Appendix H. Off -gas effluent air samples were also collected on monthly basis to evaluate compliance with the air permit requirements. A summary of the off -gas air permit compliance data is presented in Table 18. VOC concentrations in the off -gas effluent air stream have been measured in parts per billion on a volume basis (ppb-v). Approximately 0.63 pounds of PCE and 0.02 pounds of benzene were emitted to the atmosphere throughout the treatment period. These amounts are well below the compliance rates allowed by the air permit. It appears that the thermal oxidation unit effectively destroyed vapor phase contaminants prior to discharge to the ambient air: IT Corporation of North Carolina, Inc. A A/ember of The 17' Croup -- Monitoring Report Page 28 W. P. Ballard and Downgradient Properties November 29, 2001 6.0 CONCLUSIONS Based on the results of the August 2001 monitoring event and data acquired during the operation of the HVDP/SVE recovery and treatment system, the following conclusions are made: • The vertical and horizontal extent of the groundwater VOC contamination at the site, as defined in the December 1999 CSA, continues to be defined. Although the plume boundaries have not changed significantly, the intensity of the leading edge of the plume has been reduced. • Total VOC concentrations in shallow and deep groundwater throughout the Phase I ISCO area have been reduced. Reduction in shallow wells ranged from 16% to 71 % and from 9% to 100% in deep wells. Since groundwater samples were taken soon after the Phase I injection, the results from the August 2001 sampling event are considered preliminary. More reduction is anticipated to occur in the Phase I area wells. The oxidation process, in previous events, by sodium permanganate has been seen to occur over an extended period after the actual injection of the oxidant. • The decrease in total VOC concentration in deep groundwater wells was more pronounced than in shallow wells. The use of the bottom up injection method during the Phase I full scale application is thought to be the reason for this variation. The other reason is greater formation permeability at depth, which allowed better dispersion of the oxidizer and subsequently more oxidizer was available for reaction with VOCs in the deeper zone. • The HVDP/SVE system was started in March 2001 and operated intermittently throughout the current monitoring period. The system experienced several operational problems related to the thermal oxidizer. A total of 50 pounds of PCE and 25 pounds .of TCE were removed from the site via groundwater extraction using the HVDP recovery wells. A total of 313 pounds of PCE, 2.7 pounds of TCE, and 64.4 pounds of THC were removed from the site by the vapor extraction system (i.e. HVDP/SVE). • Rebound in total VOC concentrations was observed in several shallow and deep wells located at the W. P. Ballard property (the primary source area). The observed rebound is suspected to be the result of continued dissolution of PCE from the DNAPL entrapped in the source area vadose zone. • Total VOC concentrations continued to decrease in several shallow and deep wells located at the W. P. Ballard property (the primary source area). The observed decrease is most likely a result of operating source area SVE system wells. • Total VOC concentrations at locations immediately downgradient of the source area (i.e. Axton -Cross property) decreased at some locations (MW-27 for example) and increased at other locations (MW-10 for example). The observed change in the total VOC mass distribution can be attributed to the operation of the HVDP/SVE recovery system during the current monitoring period. At locations further downgradient of the Axton -Cross property (DW-5 and DMP-2), total VOC concentrations increased. The observed increases may be as a result of TCE migrating from the secondary source area previously identified on the Axton -Cross property. The migration of TCE was most likely induced by the operation of HVDP recovery wells located in the vicinity of DW-5 and DMP-2. IT Corporation ofNorth Carolina, Inc. A iticmbcr of The IT Croup Monitoring Report Page 29 W. P. Ballard and Downgradient Properties November 29, 2001 • Geoprobe soil sampling data obtained from the source area vadose zone in July 2001 indicate that the bulk of the DNAPL contamination mass is still present in the source area soils. PCE contamination in excess of 2.5 million µg/kg was detected in the sample collected at the former location of the PCE AST. It is highly likely that the presence of the entrapped DNAPL in the source area vadose zone is the primary cause for the continuing contamination of groundwater at the site. • Soil vapor sampling data obtained in August 2001 from 12 soil vapor monitoring points located in the source area indicate that VOC vapor phase concentration has been significantly diminished. The observed decrease in vapor phase concentrations ranged from 84% to over 99%. Operation of the SVE system during the past six months and overall decrease in source area contamination mass following the implementation of the ISCO pilot test, are thought to be the primary reasons for the observed decreases. 1T Corporation of Norih Carolina, Inc. A Member of 77)c IT Croup I Monitoring Report Page 30 W. P. Ballard and Downgradient Properties November 29, 2001 7.0 RECOMMENDATIONS The basis for selecting multiple treatment technologies to remediate the site were established in the corrective action plan (CAP) submitted for the NCDENR in May 1999. However, an approval for the CAP by the NCDENR has not been issued yet. NCDENR's formal approval of the CAP is essential at this point since the implementation of the selected technologies (HVDP/SVE and in situ chemical oxidation) has already been performed. These technologies have been tested and proved to be appropriate and effective to remediate the site. Therefore, we recommend that: • NCDENR should approve the CAP that was submitted in May 1999. • SLS should excavate and remove the source area "hot spot" from the site. The continued presence of high vadose zone VOC concentrations at and near the former location of the PCE AST appear to be impeding efforts to remediate source area and downgradient groundwater. • SLS should implement the full-scale permanganate injection to expedite reduction of VOC concentrations in source area groundwater and soils. The recommendations made after completion of the Phase II ISCO, should be followed. • SLS should suspend remedial efforts using the HVDP/SVE remediation system to allow for successful implementation of the ISCO technology. 8 IT Corporation ofNorth Carolina, Inc. A Alcmhcr of The IT Croup FIGURES '0 of '•X.", �� ,) h . •� C V. • :�/' / r Pisgah J; ♦ p a .. ✓8gp i� \ 1 '' m y NIIi I,�, �''� 1 ti 'v Mt Pisgah rowers MiEi►G1 ° r l�1 ' 7 / M. *, is 1 1 •78� ., a w& We 1s .. 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WILSON, INC. 60 0 30 60 0 120 ( IN FEET ) I' SEV" MANHOLE Ov CAS VALVE - T- TELEPHONE LINE TELEPHONE MANHOLE `QI UTILITY POLE LIGHT POLE NOTES: ❑ INLET HORIZONTAL DATUM IS NAD '83. ® DRAINAGE MANHOLE VERTICAL DATUM IS NGVD '29. THIS IS NOT A BOUNDARY SURVEY. NOT FOR RECORDATION. w0 SS CLEANOUT MAPPING SCALE : 1 INCH = 60 FEET, DG WATER VALVE MAPPING CONTOUR INTERVAL SHOWN HEREON = 2 FEET. -ALTA/AGSM FIRE HYDRANT PROPERTY LINE FROM PLAN ENTITLED LAND p ExISTINC IRON PIPE TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.", DATED 5/12/95 PREPARED BY ROBERT E. WILSON, INC. © SEWER MANHOLE GV X GAS VALVE GRAPHIC SCALE 40 0 20 4a 0 80 ( IN FEET ) 0, m ol —EL— ELECTRIC LINE --w- WATER LINE -c- GAS LI N E — T— TELEPHONE LINE WA S n NW-] ® M® 14 GnASS AND TREES 7. IN Ln* y� RETUNING rwL Aroma FIRE HYDRANT AND VµVf MW-73 OF CURB TYPICAL) REIWSG WALL ° I ® �yy��ll t �! 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Cd WATER VALVE —EL— ELECTRIC LINE DRAWING DATE: ACAO PILE I : MAPPNG SCALE 1 INCH = 60 FEET. —W— WATER LINE 11/23/99 7535BASE2 MAPPNG CONTOUR IN SHOWN HEREON = 2 FEET. FIRE HYDRANT PROPERTY LINE FROM PLAN ENTITLED 'ALTA/AGSM LAND GRAPHIC SCALE o EXISTING IRON PIPE —C— GAS LINE I I PROJECT 75 NOTES: TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.', \ 60 0 30 60 0 120 IS SEWER MANHOLE — T— TELEPHONE LINE 1035 DATED 5/12/95 PREPARED BY ROBERT E. WILSON,INC. cv \ ( ) CAS VALVE FIGURE d IN FEET NW-14 ASPHALT 7s PENCE ASPnALr { ASPHALT QJ WJS-E DW-1 i CUR TYPICAL v ' BUILDING q,T t BLOCK WALL ® CIO O 0 Ti STORAGE TANK BUILDING sA't� mp ® wW2w 4 _2 BUILDING � 'ti Q � O Dw-14 C' \7 W-4 T y Hw M e23 e Q ONP-4 O ww(�f m 0 e M-e.. ly �•'t� 9 �- ��:,i',: �::i .li.. 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IP-34 656315. 145 1756961. 857 862. 40 IP-77 856730. 649 1757116. 609 862, 11 34-1N 958317, 106 1756961. 372 862.39 IP-78 858770, 807 1757118. 184 862.12 34-5N 850322.626 1756961. 445 862. 40 IP-81 858729.853 1757157. 365 862. 03 34-1ON 558330. 925 1756961. 654 862. 38 IP-82 BSB765. 036 1757158, 756 861,66 IP-36 858357, 534 1756926. 924 B61. 54 IP-65 858730. 007 1757203, 561 862. 00 IP-44 858432. 568 1757004. 034 862. 40 IP-86 658768. 623 1757204, 175 861. 02 IP-45 8584761 121 1757005. 306 862.43 IP-88 858666, 059 1757242. 064 862. 58 IP-46 858396. 194 1756964, 398 862. 37 IP-89 858727, 085 1757242. 918 862. 07 IP-47 858478. 555 1756926, 281 861. 21 IP-92 856283. 266 17 . 252 671. 61 IP-49 8585171350 1756967.920 862.01 - 1756767. 38 873 IP-50 14 1757006. 856 862. 42 - IP-51 7.88 1757009. 496 862. 38 P-97 58312. 542 1756881 579 870. 57 IP-53 858549. BO 1756945. 732 861.69 IP-98 858338. 245 1756879. 082 870, 74 IP-54 858591, 868 1756931. 842 861.61 - IP-55 850591, 435 1756971. 605 861.91 - IP-56 85EI591I 187 1757011.680 862.32 - IP-57 858630. 352 1737011.979 862.24 - IP-58 858630. 466 1756972. 253 861.88 - IP-59 858633. 33EI 1756933.233 861.44 - IP-59.5 056650. 463 1756940. 553 661.36 TP-671E 958770, IP-60 858669, 130 1757013. U41 862.38 - IP-60. 5NV 856688. 434 1756991. 720 861.92 IP-DMP4E 85869 .4 5 1757094. 759 862, 56 IP-61 858670. 529 1756973, 256 861. 80 IP-DMP4N 856707�511 1757088. 585 862, 41 IP-62 858673. 186 1756933829 661.54 1P-➢MP4S IP-62.5 858695. 434 1756942. 766 861. 18 IP-DNP4V IP-63 858713. 694 1756947. 935 861, 74 IP-DM-BN 1P-DV-BS IP-64 858709.711 1756974.088 861.71 IP-65 858707. 290 1757013, 858 862. 36 IP-DW13E IP-67 858769. 603 17570001 995 862, 64 IP-➢W13V 1757155. 146 IP-68I 858747. 279 1756975. 726 862. 16 IP-RAMPN/68E 858745, 404 1756997. 761 862, 38 - - 44, 0 IP-69 85669L 166 1757034. 114 862. 44 IP-LMP-2N R5AP99,1159 1756819, 074 112-70 858732. 777 1757035. 219 862. 28 IP-MW-17N 858632, 904 1756961. 141 861 0 IP-72 838690, 3B2 1757073, 432 862. 57 IP-MV-17S 858620. 516 1756960. 467 861,70 IP-73 858730, 041 1757075. 437 862, 06 IP-MV22N B 0743.1331 1 9B4 862, 05 IP-74 858769. 063 1 1757077, 260 86L 85 IP-MV22S 85 733.235 1757136. 451 BfiR. 14 ASPHALT PAVEMENT Yw-11 0- SLS WAREHOUSE BUILDING NW-20 LEGEND . W { IP-BORING MONITORING WELL . HVOP ® SLE • NW aIW O ON • SYMP EW PT `1L UTILITY POLE LIGHT POLE ❑ INLET ® DRAINAGE MANHOLE 35 CLEANOUT WATER VALVE FIRE HYDRANT 0 EMSTING IRON RPE ® SEWER MANHOLE GAS VALVE []� WATER METER EDS END OF SGNAL CLF CHAIN LINK FENCE - ElECIWC LINE - - WATER LINE - - GAS 1111E - TELEPHONE UNE GRAPHIC SCALE w r r (mmrl I I-h - 40 K o po�E F�p,G BUILDING o X%RMER �1 CE AST LOCATION BUILDING BUILDING a GP-7-10-01-1(10-11') ` 72- 1t GP-7-10-01-2(8-1 J GP-7-10-01-3(10-12') BUILDING f F p P�E�1S .,SID 0 ROLLINGS RO AO \\ FORMER GASOLINE UST LOCATION , \ , \ - . \ , \ ya \ \ �IT. \ T , \ \ c \ o \ -7L \ \\\ E , 9n o,k on BUILDING \ PAVE \ \ \ A GRAPHIC SCALE 20 9 10 20 40 ( IN FEET ) Q ASPHALT PAVEMENT LEGEND Q GEOPROBE POINT II IT CORPORATIr OF NORTH CAROLINA, INC. lY��d 71rII'6to� 2200 GATEWAY CENTRE BLVD. SUITE 205 MORRIWLLE, NC 27560 _ (919) 467-2227 OEOPROBE SOIL SAMPLE LOCATION MAP JULY 10, 2001 W.P. BALLARD PROPERTY LOCATION: GREENSBORO. NC DESIGNED By. DETAILED Ely: CHECKED BY: DEE RHW - DRAWING DATE: ACAD ►ILE: 4/26/01 '7535GEOP PRDJM NO., NOTESt 107535 FIGURE 7 RATER MOMS MW-7 ® M -14 (867.12) S G AND TREES r,a.Vry LM1t (865.65 & R AND R HYORYHYDRANTT AND ND VALVE (854.22� MW o W—� BACK GC W BUILDING O Q, Q•/r 852.11) FACE OF (TTPIcu) GAINING YIAtl. (864.11) / BUILDING _ DW-13 LiF BUILD W-14� J fff r 3.77) c9 • N OR TAN W'Z iy Ab , DW_8 pMP_ BMW-4 B BUILDING O (8 .78) MCI 4 yC ASPHALT AVEMENT / BUILDINGj. (862.67 ' M� 1j aT AND -NCRETE O (864.96 v+ a $,� ASPHALT PAVOA (850.30) DW-15 E J HIGH VOLTAGE & PAVE DM - MIN GENERATOR INSIDE b (857.88� /- T (859 .9 D _5 7 (836.82) �Zg t4 fi P_z a1 �9 W,15 8 (849.59 r o -L !T oQ (851. 0) _ (85 .26) BUILDING N ❑ MW-21 (857.30) T DW-12 ' ASPHALT PAVEUENT LMP_1 (855.87) 851'225) BUILDING a ® LMP_ D �®` TELEPHONE LHONE MANHOLE \ (856.52) ? 7 A • \ BM ® MPlWO a� \ I _ I / I LINE I T 'CAL). OAS C If ffcmnmTlm ®A11f=bwaflLorrGm p If - _ - 22GO GATEWAY CENTRE BLVD.. MORRISVILLE, NO 27500 (BIG) 407-2227 I GROUNDWATER ELEVATION I LEGEND CONTOUR MAP AUGUST 20, 2001 MONITORING YELL (852.11) GROUNDWATER ELEVATION (FT) n `b p REINFORCED CONCRETE PIPE SITE: �,\ I (NG) NOT GAUGED ,� UTILITY POLE / W.P. 9ALLARED PROPERTY GROUNDWATER ELEVATION CONTOUR } LIGHT POLE I ❑ INLET LOCATION: GREENSBORQ NC NOTES: HORIZONTAL DATUM IS NAD '83. ® DRAINAGE MANHOLE DESIGNED GYE DETAILED BY: CHECKED BY: VERTICAL DATUM IS NGVD '29. THIS IS NOT A BOUNDARY SURVEY. wv I Ss cLEEwouT DEE RHW NOT FOR RECORDATION. I D4 WATER VALr DRAVANG 0%1TEE 0/Ot AGAD F73 5.3G801 MAPPING SCALE : 1 INCH = 80 FEET. 1 MAPPING CONTOUR INTERVAL SHOWN HEREON 2 FEET, I � FIRE HYDRANT GRAPHIC SCALE PROJECT 75 NOTES: PROPERTY LINE FROM PLAN ENTITLED "ALTA/AGSM LAND ( Q EXISTING IRON PIPE TITLE SURVEY FOR: GREENSBORO D.C.. PARTNERS, LTD.', \ 80 0 BO 120 107535 DATED 5/12/95 PREPARED BY ROBERT E. WILSON. INC. \ SEWER MANHOLE \ ( IN FEET) GAS VALVE FIGURE 8 WATER METERS (29) ® I\ �`\ (679 ,`\ GRASS AND TREES ltldr 111 I `\ \ \FEN RETAINING WALL ANDS (0�I.0) FIRE HYDRANT ANO VALVE (325) 1 1 `� ` `- - --- - 0--------- ----- - -- BUILDING `. O `\ q---- 50D------- -- --- -- _ ^—_ BACK DI' CURB (T»IDAL7 `.�, WALL ° ------ ---- i---------------1.000- ..1 ---------------------------- ` `. GATE Ile L;AC/ (126,116) 1 �`� O �W�13 p``� o `\ ° ❑ i Lai " / I -3 BUILDING . `\ \\ \\ ® i I Y/ M Aa • 1 — — — — — d &4W-22 � ``\ \� `. DW-14 j11SQiA( TAN 1` v pw,3 A 7`�57D rods` ��`. �_8 OMP_4 (1,970) \�` \`I MW,A Q�N' 1 :.a* BUILDING BUILDING ` —.` \ OF pA ASPHALT PAVEMENT IASRIALT PAVFl1EHT M1,1,`77 1 ° AND CONCRETE R J ♦♦ '1 \� �0 16,882I / 11J' (3,115) i 1 DW-15 HIGH fIN• PAYE / I i 1 I 111 / / 1 O GENERATOR TDR INSIDE 70,0 \ \\ �� `� .� DW-5 7 O t T. 000-- MW_15* - 6 -- MW-78 - o `---- - —---------- ' i 1 \4 (0.0) `� BUILDING (j03)� �� (940)e �,i 93)1 `.`. (971) 1 I ' ' 41 ®MW-27 it OUP----------------------- 0 DIN \ 0 P SLED a /\78) BUILDING \ ASPHALT PAVEIIA(T �/� MITI s ®(19 4p-1 _ �MP324) _ OW �`12 ---_- - \ LMP�1 `2 srAwy G 1� - - - ------ \ _ MW-20 IA R WALL \ bQ \ 6� PROPER_ E (TYPIC 1 TY ONE I AL)OAS PIPE ` RETAhpWC . GRAVID. / I — I o / LEGEND II (293) TOTAL VOC CONCENTRATION (ug/L) II ---500---- TOTAL VOC CONCENTRATION CONTOUR (ug/L) 1 / I MONITORING WELL / REINFORCED CONCRETE PIPE / UTILITY POLE I LIGHT POLE NOTES: ❑ INLET HORIZONTAL DATUM IS NAD '83. VERTICAL DATUM IS NGVD '29. I ® DRAINAGE MANHOLE THIS IS NOT A BOUNDARY SURVEY. GRAPHIC SCALE ss cEANDur NOT FOR RECORDATION. I MAPPING SCALE : 1 INCH = 60 FEET. / 60 0 30 60 0 120 pQ WATER VALVE MAPPING CONTOUR INTERVAL SHOWN HEREON = 2 FEET. PROPERTY LINE FROM PLAN ENTITLED "ALTA/ACSM LAND \4 FIRE HYDRANT I I TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.", \ ( IN FEET) 0 EIUSTING IRON PIPE DATED 5/12/95 PREPARED BY ROBERT E. WILSON, INC. \ ® SEWER MANHOLE \ cv NA CAS VALVE 12 TELEPHONE MANHOLE WATER METERS MW-7 ® N®A _ CRASS AND TREES — — 7 rMA1N �( IETAIMING WALL AND (62,069) -- FIRE HYDRANT AND VALVE l� \ - / / I -LANCE\ \ T% e ff i•URB (7WICALJ ryD WI'u (206) //� WA LL(45856\� I1 -------__ — �( 79)' RUI d MTH AGE N ` 11 ��0- ' 4�9 NP 0 0) _ `�\\`�\ DATEr c r / 0 — — - 22 • 1 11 1 I D) p00-- „� s) `.----------------- 0�(571) BUILDING -s \ � / •(0.0) �� \ \ `\ A FaPHALT PAV�INEMT �D „ .8 N0 MW 1 x 09PN r` (4,aeo) Yif i 1 i \\\ � op CONCRET� i (150)� 1` , • .l.7,/ ♦�,, ASALT PAVEMENT j / -26 P0,3,AGS p C �700p / I �10 , \\� 1 N� • �.��' �./ i \\�--_..— / WW-23 HIGH VOLTAGE k (1,935) .AE' ' ' PAVE I • ' �/ / om 10, GENERATOR IN90E \ ♦`1 `I I -.o l a 455). ice. rc id \a G 1 1 1 676,940) I 1 DYP,2 / mu A' MW-21 \ VNr® 1 1 1 1 1 1 1(1.530) 4` 1 1 � eJLo�Ic np•-+7 1 ; HN>rAa f � � �a O - 2,0° �_ ; /ll �`20,000 f BUILDING \ ASPHALT PAVELE7IT 0 NOTES: HORIZONTAL DATUM IS NA4 '83. VERTICAL DATUM IS NGVD 29. THIS IS NOT A BOUNDARY SURVEY. NOT FOR RECORDATION. MAPPING SCALE : 1 INCH = 60 FEET. MAPPING CONTOUR INTERVAL SHOWN HEREON = 2 FEET. PROPERTY LINE FROM PLAN ENTITLED -ALTA/ACSM LAND TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.", DATED 5/12/95 PREPARED BY ROBERT E. WILSON, INC 1 T 2 97Ap5 ,Y, (22 )70[W.I�� MW-20 m IE lo 12TELEPHONE MANHOLE I — (TYPICAL) / GAS; PIPE Rk7AWING OR It r / LEGEND (479.00) TOTAL VOC CONCENTRATION (ug/L) ® MONITORING WELL / / --- 500---- TOTAL VOC CONCENTRATION CONTOUR (ug/L) n REINFORCED CONCRETE PIPE / UTILITY POLE / (ND) NOT DETECTED LIGHT POLE / ❑ INLET \•�\ GRAPHIC SCALE 30 a0 120 240 ( IN FEET ) \ ® DRAINAGE MANHOLE SS CLEANOUT w Dd WATER VALVE FIRE HYDRANT 0 EXISTING IRON PIPE G SEWER MANHOLE DV I� W OAS VALVE WATER MEWS (29) MW-7®--------------- __ 4► 1 / A/ifi . (679 ` �I GRASS AND TREES �ATAINING WALL II�// ' 1 ��� ♦ _ ` I I �(�0.U) RRETRFRN/T AND VALVE (325) T j,%E /4 �`♦♦`♦♦ \ �w==/ ——0'-------- — — — — — — --f ----- 4----------- ----- BAaa nw ---BIALONG O ��. __aAu��u.T • 3 - - d \\ MW-22 \ �♦ `\ 'QW-14 `\ II I pW- ® 570) p�`. i �`. `� ow-8 DMP_ (1,9701\\ \ -'MW, euuDlNcT�` • �` i 4PHALT PAVEMENT IA�HALTPArnwrt M{►tl7 i 1 t ° 'PND CONCRETE I L i ♦` \ ♦ — �� I �0 16,882/`t t 11j 3y,115) �,� 11 , T DW-15� HIGHKxrncz r � \♦�\\ ��; '' �� ��1 PAVE / + 'may 1 / I I GENERATOR INSDE a 'K\ ' ♦ .' / / i DMP-3 1 / / 1 MW-23 • J. ��\� 4M`. ♦` p ---°-----------"'-- i .iM—21 a%Cs (40�(940) (0.0) � o (293) WW97•` VOMP_1 \`\ - ---- J. DW \ p' ' `ALT PAVEM4(T `� �_ �� �� MW _ �.� 14 • \ AETAp/p,G M ALL \ Yr d' \ \ M® If _ ` OPERTY E LIN � — _(T�'ICAQ 1 —OMN GRAVEL OAS G . $ 1 LEGEND (293) TOTAL VOC CONCENTRATION (ug/L) ---500---- TOTAL VOC CONCENTRATION CONTOUR (ug/L) / (AUGUST, 2001) / -500.00 OTAL VOC C NCENTRATION CONTOUR (ug/L) / 1 MARCH, 2001) / p i ® l �.\ I MONITORING WELL / REINFORCED CONCRETE PPE / r a, IITILTTY PCLE ' IGHT POLE NOTES: ❑ INLET HORIZONTAL DATUM IS NAD '83. VERTICAL DATUM IS NGVD '29. ® DRAINAGE MANHOLE THIS IS NOT A BOUNDARY SURVEY. NOT FOR RECORDATION. GRAPHIC SCALE ss aEANDur MAPPNG SCALE : 1 INCH = 60 FEET. I 60 0 30 60 a 120 pQ WATER VALVE MAPPING CONTOUR INTERVAL SHOWN HEREON 2 FEET. PROPERTY LINE FROM PLAN ENTITLED -ALTA/ACSM LAND \( FlRE HYDRANT I I TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.', \ ( IN FEET) 0 EXISTING IRON PIPE DATED 5/12/95 PREPARED BY ROBERT E. WILSON, INC. ® SEWER MANHOLE \ cV IA OAS VALVE 12 TELEPHONE MANHOLE ---- _MUCK METERS \ I I I I 7' � ROAD N®A 45 85s AGE T N 1 S I j1 4 i 0) ! BUILDING • C-- sf AVALT PAVEMENT {� \ \\0�00 //ri/wr-� (1,935) ��pr-� IA�c % NN \ \ I • \� \\ \ v 44 I 11 / 76,940 I 11 DEMLA\ ,1°. 1(4 5 \ -20,000',• I / \ Q`.♦,IALT+AVEl1ENT \ \ \ —W NOTES: HORIZONTAL DATUM IS NAD '83. VERTICAL DATUM IS NGVD '29, THIS IS NOT A BOUNDARY SURVEY. NOT FOR RECORDATION. MAPPING SCALE : 1 INCH = 60 FEET. MAPPNG CONTOUR INTERVAL SHOWN HEREON = 2 FEET. PROPERTY LINE FROM PLAN ENTITLED -ALTA/ACSM LAND TITLE SURVEY FOR: GREENSBORO D.C. PARTNERS, LTD.', DATED 5/12/95 PREPARED BY ROBERT E. WILSON, INC \/\ \ GRAPHIC SCALE 60 0 30 60 120 240 ( IN FEET ) \ / GRASS AND TREES \ WA 9RLL FIRE N1ANT WALL IRE HYDRANT — YM-" __ `_----- --- ---- 4AGIr OL• CURB (TYPICAL) — — \ ----------------- (l7s)y�lA n- ��---��- - Ak ASPHALT PA E'1OENT"\ ANQ, CONCRET \\ YM`7 — —-------- —// N YW-70 BUILDING GATE 161 ER WW-23 HIGH VOLTAGE h ® GENERATOR INSIDE ® 7' C •----7 W-12 • TELEPHONE MANHOLE r� 2 TAINING ALL PROPERTY _LINE (T�ICAL� e[T / GAS 'VNINC y. GRAVEL _ f I / f / I (479.00) TOTAL VOC CONCENTRATION (ug/L) LEGEND / f ---500.--. TOTAL VOC CONCENTRATION CONTOUR (ug/L) ® MONITORING WELL / I (AUGUST, 2001) n REINFORCED CONCRETE PIPE / --laoaoo--- TOTAL VOC CONCENTRATION CONTOUR (ug/L) `a, UTIUTY POLE T'�Y� (MARCH, 2001) Y LIGHT POLE / f ❑ INLET (ND) NOT DETECTED ® DRAINAGE MANHOLE 'I 0 SS CLEANOUT Dd WATER VALVE V FIRE HYDRANT Q EXISTING IRON PIPE IS SEWER MANHOLE ov W GAS VALVE 250,000 200,000 + z0 150,000 H Q Z W U Z v 100,000 O 80% 32% FIGURE 13 COMPARISON OF PRE- AND POST -INJECTION TOTAL VOCS IN GROUNDWATER INJECTION ZONE SHALLOW MONITORING WELLS WP BALLARD AND DOWNGRADIENT PROPERTIES, GREENSBORO, NORTH CAROLINA -40% -- -- ■ PRE-INJ Total VOCs 03/22/00 ■ POST-INJ Total VOCs 06/23/00 ❑ POST-INJ Total VOCs 09/06/00 ❑ POST-INJ Total VOCs 03/06/01 1 % ❑ POST-INJ Total VOCs 08/22/01 19% -602% 87% 77% 83% 50,000 - ---- 25% 38% 35% I N4 MW-1 MW-2 -207% 7% 244% 1 76% 1 % 28% _1% I -44% I_.-840k__- MW-3 MW-4 MW-5 MW-6 MW-10 PT-3S PT-4S WELL NUMBER 51% -21 % 1 OWN PT-5S SVE-8 88% SVE-9 120,000 100,000 80,000 Z O Z 60,000 w U Z 0 U p 40,000 20,000 0 FIGURE 14 COMPARISON OF PRE -AND POST INJECTION TOTAL VOCS IN GROUNDWATER INJECTION ZONE DEEP MONITORING WELLS W. P. BALLARD AND DOWNGRADIENT PROPERTIES, GREENSBORO, NORTH CAROLINA ■ PRE-INJ Total VOCs 03/22/00 18% 34% ■ POST-INJ Total VOCs 06/23/00 ❑ POST-INJ Total VOCs 09/06/00 58% ❑ POST-INJ Total VOCs 03/06/01 ■ POST- INJ Total VOCs 08/22/01 15% 58% 99% 100% 100% 69% 629/ 1 1 1 55% 20% 12% -66% 8% 47% 71% 92% -32% -22% 14% W "'y I I I I [ _r DW-1 DW-2 DW-3 DW-4 BMW-1 BMW-2 PT-1D PT-2D PT-3D PT-4D PT-5D HVDP-13 HVDP-14 WELL NUMBER 7,000 -1 . mv 5,000 z 0 4,000 Q z w U zz 3,000 U U O 1,000 C FIGURE 15 COMPARISON OF TOTAL VOCs IN SHALLOW GROUNDWATERMONITORING WELLS PRE- AND POST- PHASE I FULL SCALE ISCO USING NaMn04 WP BALLARD AND DOWNGRADIENT PROPERTIES, GREENSBORO, NORTH CAROLINA MW-12 MW-15 MW-17 MW-18 MW-22 LMP-1 LMP-2 WELL NUMBER FIGURE 16 COMPARISON OF TOTAL VOCs IN DEEP GROUNDWATER MONITORING WELLS PRE- AND POST- PHASE I FULL SCALE ISCO USING NaMn04 WP BALLARD AND DOWNGRADIENT PROPERTIES, GREENSBORO, NORTH CAROLINA 5,000 4,500 4,000 3,500 vs ZO 3,000 z 2,500 w U Z 0 2,000 U O > 1,500 1,000 500 51% DW-8 ■ PRE-INJ Total V ■ POST-INJ Total . 100% DW-13 DMP-1 WELL NUMBER DMP-3 DMP-4 IT Corporation oPNorth Carolina, Inc. A b/cmhcr of The 17' Croup TABLES Table 1 Well Construction Summmary W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Casing Diameter Well Material Total Depth Cased Interval Screened Interval Top of Casing Elevation Notes MW-1 2" PVC 35' 0-25' 25-35' 881.03 MW-2 2" PVC 35' 0-25' 25-35' 882.43 MW-3 2" PVC 35' 0-25' 25-35' 883.10 MW-4 2" PVC 35' 0-25' 25-35' 882.33 MW-5 2" PVC 35' 0-25' 25-35' 883.47 MW-6 2" PVC 35' 0-25' 25-35' 884.33 MW-7 2" PVC 35' 0-25' 25-35' 882.59 MW-8 2" PVC 35' 0-25' 25-35' 883.03 MW-9 2" PVC 35' 0-25' 25-35' 880.43 MW-10 2" PVC 35' 0-25' 25-35' 882.42 MW-11 2" PVC 35' 0-25' 25-35' 874.71 MW-12 2" PVC 35' 0-25' 25-35' 862.15 MW-13 2" PVC 35' 0-25' 25-35' 863.77 MW-14 2" PVC 35' 0-25' 25-35' 884.36 MW-15 2" PVC 35' 0-25' 25-35' 872.10 MW-16 2" PVC 35' 0-25' 25-35' NS Destroyed during construction MW-17 2" PVC 35' 0-25' 25-35' 881.43 MW-18 2" PVC 35' 0-25' 25-35' 862.26 MW-19 2" PVC 35' 0-25' 25-35' NS Destroyed during construction MW-20 2" PVC 35' 0-25' 25-35' 866.15 MW-21 2" PVC 35' 0-25' 25-35' 866.12 MW-22 2" PVC 35' 0-25' 25-35' 861.83 MW-23 2" PVC 35' 0-25' 25-35' 861.15 MW-24 2" PVC 35' 0-25' 25-35' NS Destroyed during construction MW-25 2" PVC 35' 0-25' 25-35' NS Destroyed during construction MW-26 2" PVC 35' 0-25' 25-35' NS Destroyed during construction MW-27 2" PVC 35' 0-25' 25-35' 879.80 MW-28 1" PVC 35' 0-25' 25-35' 881.23 LMP-1 2" PVC 35' 0-25' 25-35' 873.50 LMP-2 2" PVC 35' 0-25' 25-35' 871.41 DW-1 1" PVC 65' 0-50' / 0-55' 55'-65' 882.31 DW-2 2" PVC 65' 0-50' / 0-55' 55'-65' 881.12 DW-3 2" PVC 65' 0-50' / 0-55' 55'-65' 882.59 DW-4 2" PVC 65' 0-50' / 0-55' 55'-65' 883.69 DW-5 2" PVC 63.5' 0-45' / 0-48.5' 48.5-63.5' 872.80 DW-6 2" PVC 63.5' 0-45' / 0-48.5' 48.5-63.5' NS Destroyed during construction DW-7 2" PVC 63.5' 0-45' / 0-48.5' 48.5-63.5' 862.17 DW-8 2" PVC 63.5' 0-45' / 0-48.5' 48.5-63.5' 861.44 DW-9 2" PVC 53' 0-40' / 0-43' 43-53' NS Destroyed during construction DW-10 2" PVC 58' 0-40' / 0-43' 43'-58' NS Destroyed during construction DW-11 2" PVC 53' 0-40' / 0-43' 43-53' NS Destroyed during construction DW-12 2" PVC 47' 0-4070-42' 42-47' 845.45 DW-13 2" PVC 76' 0-61' 61-76' 861.10?? DW-14 2" PVC 69' 0-54' 54-69' 860.06 DW-15 2" PVC 79' 0-64' 64-79' 861.20 DMP-1 2" PVC 65' 0-4570-50' 50-60' 870.83 DMP-2 2" PVC 60' 0-45'/0-50' 50-60' 872.13 DMP-3 2" PVC 57' 0-4070-47' 47-57' 862.18 DMP-4 2" PVC 64' 0-4170-49' 49-64' 862.25 BMW-1 6" / 2" G.S./PVC 150' 0-12370-130' 130-150' 882.45?? BMW-2 6" / 2" G.S./PVC 115' 0-90'/0-95' 95-115' 882.97?? BMW-3 6" / 2" G.S./PVC 143' 0-11070-123' 123-143' 862.12?? BMW-4 6" / 2" G.S./PVC 100' 0-7170-80' 80-100' 859.81?? Table 1.xls Page 1 of 3 Revised: 11/28/01 Table 1 Well Construction Summmary W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Casing Diameter Well Material Total Depth Cased Interval Screened Interval Top of Casing Elevation Notes SVMP-1 2" PVC 12' 0-2' 2-12' 883.63 Soil vapor monitoring point SVMP-2 2" PVC 12' 0-2' 2-12' 883.79 Soil vapor monitoring point SVMP-3 2" PVC 12' 0-2' 2-12' 883.83 Soil vapor monitoring point SVMP-4 2" PVC 12' 0-2' 2-12' 882.90 Soil vapor monitoring point SVMP-5 2" PVC 12' 0-2' 2-12' 883.37 Soil vapor monitoring point SVMP-6 2" PVC 12' 0-2' 2-12' 883.44 Soil vapor monitoring point SVMP-7 2" PVC 12' 0-2' 2-12' 883.04 Soil vapor monitoring point SVMP-8 2" PVC 12' 0-2' 2-12' 883.03 Soil vapor monitoring point SVMP-9 2" PVC 12' 0-2' 2-12' 882.75 Soil vapor monitoring point SVMP-10 2" PVC 12' 0-2' 2-12' 882.44 Soil vapor monitoring point SVMP-11 2" PVC 12' 0-2' 2-12' 882.44 Soil vapor monitoring point SVMP-12 2" PVC 12' 0-2' 2-12' 882.71 Soil vapor monitoring point PT-1S 1" PVC 25' 0-5' 5-25, 882.69 Wells installed for 9/97 pilot test PT-2S 1" PVC 22.2' 0-2.2' 2.2-22.2' 882.95 Wells installed for 9/97 pilot test PT-3S 1" PVC 25' 0-5' 5-25' 882.59 Wells installed for 9/97 pilot test PT-4S 1" PVC 25' 0-5' 5-25' 882.21 Wells installed for 9/97 pilot test PT-5S 1" PVC 25' 0-5' 5-25' 882.97 Wells installed for 9/97 pilot test PT-1 D 2" PVC 65' 0-50' 50-65' 882.70 Wells installed for 9/97 pilot test PT-21D 2" PVC 65' 0-50' 50-65' 882.95 Wells installed for 9/97 pilot test PT-31D 2" PVC 65' 0-50, 50-65' 882.66 Wells installed for 9/97 pilot test PT-41D 2" PVC 65' 0-50, 50-65' 882.41 Wells installed for 9/97 pilot test PT-51D 2" PVC 65' 0-50' 50-65' 882.96 Wells installed for 9/97 pilot test HVDP-1 4" PVC/S.S. 75' 0-35' 35-75' 881.84 Groundwater/soil vapor extraction well, Header 1 HVDP-2 4" PVC/S.S. 75' 0-35' 35-75' 882.04 Groundwater/soil vapor extraction well, Header 1 HVDP-3 4" PVC/S.S. 75' 0-35' 35-75' 881.13 Groundwater/soil vapor extraction well, Header 1 HVDP-4 4" PVC/S.S. 75' 0-35' 35-75' 881.37 Groundwater/soil vapor extraction well, Header 1 HVDP-5 4" PVC/S.S. 75' 0-35' 35-75' 880.85 Groundwater/soil vapor extraction well, Header 1 HVDP-6 4" PVC/S.S. 75' 0-35' 35-75' 881.92 Groundwater/soil vapor extraction well, Header 2 HVDP-7 4" PVC/S.S. 75' 0-35' 35-75' 882.21 Groundwater/soil vapor extraction well, Header 2 HVDP-8 4" PVC/S.S. 75' 0-35' 35-75' 882.40 Groundwater/soil vapor extraction well, Header 2 HVDP-9 4" PVC/S.S. 75' 0-35' 35-75' 882.63 Groundwater/soil vapor extraction well, Header 2 HVDP-10 4" PVC/S.S. 75' 0-35' 35-75' 881.65 Groundwater/soil vapor extraction well, Header 3 HVDP-11 4" PVC/S.S. 75' 0-35' 35-75' 881.41 Groundwater/soil vapor extraction well, Header 3 HVDP-12 4" PVC/S.S. 75' 0-35' 35-75' 881.98 Groundwater/soil vapor extraction well, Header 3 HVDP-13 (EW-3) 4" PVC 65, 0-50' 50-65' 882.81 Groundwater/soil vapor extraction well, Header 3 HVDP-14 (EW-1) 4" PVC 64' 0-49' 49-64' 882.57 Groundwater/soil vapor extraction well, Header 3 HVDP-15 4" PVC/S.S. 75' 0-35' 35-75' 881.24 Groundwater/soil vapor extraction well, Header 3 HVDP-16 4" PVC/S.S. 75' 0-35' 35-75' 879.73 Groundwater/soil vapor extraction well, Header 4 HVDP-17 4" PVC/S.S. 75' 0-35' 35-75' 878.89 Groundwater/soil vapor extraction well, Header 4 HVDP-18 4" PVC/S.S. 75' 0-35' 35-75' 873.99 Groundwater/soil vapor extraction well, Header 4 HVDP-19 4" PVC/S.S. 75' 0-35' 35-75' 875.83 Groundwater/soil vapor extraction well, Header 4 HVDP-20 4" PVC/S.S. 75' 0-35' 35-75' 872.84 Groundwater/soil vapor extraction well, Header 4 HVDP-21 4" PVC/S.S. 75' 0-35' 35-75' 871.23 Groundwater/soil vapor extraction well, Header 4 HVDP-22 4" PVC/S.S. 75' 0-35' 35-75' 870.56 Groundwater/soil vapor extraction well, Header 4 HVDP-23 4" PVC/S.S. 74' 0-34' 34-74' 871.70 Groundwater/soil vapor extraction well, Header 5 HVDP-24 4" PVC/S.S. 75' 0-35' 35-75' 872.56 Groundwater/soil vapor extraction well, Header 5 HVDP-25 4" PVC/S.S. 75' 0-35' 35-75' 872.37 Groundwater/soil vapor extraction well, Header 5 HVDP-26 4" PVC/S.S. 75' 0-35' 35-75' 873.48 Groundwater/soil vapor extraction well, Header 5 HVDP-27 4" PVC/S.S. 75' 0-35' 35-75' 875.39 Groundwater/soil vapor extraction well, Header 5 HVDP-28 4" PVC/S.S. 67' 0-27' 27-67' 876.17 Groundwater/soil vapor extraction well, Header 5 HVDP-29 4" PVC/S.S. 75' 0-35' 35-75' 878.38 Groundwater/soil vapor extraction well, Header 5 Table t.xls Page 2 of 3 Revised: 11/28/011 Table 1 Well Construction Summmary W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Casing I Diameter Well Material Total Depth Cased Interval Screened Interval Top of Casing Elevation Notes SVE-1 4" PVC 40' 0-7' 7-40' 881.40 Soil vapor extraction well, Header A SVE-2 4" PVC 40' 0-7' 7-40' 881.97 Soil vapor extraction well, Header A SVE-3 4" PVC 40' 0-7' 7-40' 881.96 Soil vapor extraction well, Header A SVE-4 4" PVC 40' 0-7' 7-40' 881.21 Soil vapor extraction well, Header A SVE-5 4" PVC 40' 0-7' 7-40' 881.98 Soil vapor extraction well, Header A SVE-6 4" PVC 40' 0-7' 7-40' 882.67 Soil vapor extraction well, Header A SVE-7 4" PVC 40' 0-7' 7-40' 883.39 Soil vapor extraction well, Header A SVE-8 (EW-4) 4" PVC 40' 0-7' 7-40' 881.94 Soil vapor extraction well, Header B SVE-9 (EW-2) 4" PVC 40' 0-7' 7-40' 881.54 Soil vapor extraction well, Header B SVE-10 4" PVC 40' 0-7' 7-40' 879.25 Soil vapor extraction well, Header B SVE-11 4" PVC 40' 0-7' 7-40' 875.99 Soil vapor extraction well, Header B SVE-12 4" PVC 40' 0-7' 7-40' 878.56 Soil vapor extraction well, Header B SVE-13 4" PVC 40' 0-7' 7-40' 876.26 Soil vapor extraction well, Header B SVE-14 4" PVC 40' 0-7' 7-40' 881.51 Soil vapor extraction well, Header B AIW-1 2" PVC 65' 0-55' 55-65' 881.51 Air injection wells, Common Header AIW-2 2" PVC 65' 0-55' 55-65' 881.65 Air injection wells, Common Header AIW-3 2" PVC 65' 0-55' 55-65' 882.47 Air injection wells, Common Header AIW-4 2" PVC 65' 0-55' 55-65' 881.30 Air injection wells, Common Header AIW-5 2" PVC 65' 0-55' 55-65' 881.64 Air injection wells, Common Header AIW-6 2" PVC 65' 0-55' 55-65' 877.81 Air injection wells, Common Header AIW-7 2" PVC 65' 0-55' 55-65' 871.55 Air injection wells, Common Header AIW-8 2" PVC 65' 0-55' 55-65' 873.20 Air injection wells, Common Header AIW-9 2" PVC 1 65' 0-55' 55-65' 875.32 Air injection wells, Common Header Notes: PVC denote poly vinyl chloride G.S. denotes galvanized steel S.S. denotes stainless steel Table 1.xls Page 3 of 3 Revised: 11 /28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH, (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color MW-1 11/30/98 881.03 16.05 864.98 5.01 51 2.00 19.0 117 10/22/99 881.03 9.50 871.53 5.40 68 3.92 22.0 308 03/22/00 ,881.03 10.51 870.52 4.90 5.00 1.10 17.9 354 Clear 06/22/00 881.03 12.33 868.70 5.30 6.00 2.60 19.6 233 Clear 09/06/00 881.03 8.97 872.06 4.80 63 0.91 21.6 268 NG 03/06/01 881.03 10.18 870.85 5.19 62 1.35 16.2 278 08/20/01 881.03 17.25 863.78, 4.99 52 1.35 22.9 326 MW-2 11/30/98 882.43 16.70 865.73 5.70 150 3.00 17.7 72 10/22/99 882.43 8.97 873.46 6.76 165 5.44 16.9 260 03/22/00 882.43 10.12 872.31 6.60 11.00 1.20 15.5 119 Clear 06/22/00 882.43 12.40 870.03 6.40 25.00 4.50 19.8 132 Cloudy 09/07/00 882.43 9.42 873.01 6.40 130 1.05 22.6 152 NG 03/06/01 882.43 10.50 871.93 6.61 95 0.48 16.8 62 08/20/01 882.43 18.21 864.22 6.94 122 0.66 23.5 318 MW-3 11/30/98 883.10 17.40 865.70 4.90 35 4.60 18.0 119 10/22/99 883.10 12.94 870.16 6.44 79 4.51 20.3 245 03/23/00 883.10 13.06 , 870.04 4.50 4.00 4.10 17.6 378 Clear 06/22/00 883.10 13.57 869.53 6.16 5.00 9.80 23.2 386 Cloudy 09/08/00 883.10 12.87 870.23 4.79 4.60 4.87 21.7 511 NG 09/14/00 883.10 12.93 870.17 4.79 4.6 4.87 21.7 511 Purple 03/06/01 883.10 14.02 869.08 5.32 57 5.63 20.2 249 08/20/01 883.10 18.99 864.11 6.20 188 6.48 25.8 316 MW-4 11/30/98 882.33 17.50 864.83 5.50 95 2.10 19.0 88 10/22/99 882.33 12.19 470.14 5.41 98 3.96 18.9 304 03/23/00 882.33 13.49 868.84 5.10 9.00 2.10 17.2 289 Clear 06/22/00 882.33 13.18 869.15 5.68 33.00 4.50 21.6 181 Cloudy 09/07/00 882.33 11.76 870.57 5.80 356 2.89 24.1 115 Brownish 03/06/01 882.33 13.05 869428 6.11 333 1.49 20.9 32 08/20/01 882.33 19.66 862.67 6.23 143 0.71 23.1 128 Table 2.xls 1 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific. Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mV) Color MW-5 11/30/98 883.47 18.70 864.77 5.40 19 5.90 19.0 88 10/22/99 883.47 15.64 867.83 5.73 29 4.67 15.7 292 03/22/00 883.47 16.10 867.37 5.00 2.00 6.40 19.5 358 Clear 06/22/00 883.47 15.75 867.72 5.18 3.00 6.20 24.6 246 Gray, Silty 09/07/00 883.47 16.08 867.39 4.98 2.5 6.04 22.5 258 NG 03/06/01 883.47 17.05 866.42 5.26 29 7.74 19.9 248 08/20/01 883.47 19.70 863.77 6.05 20 4.41 28.2 429 MW-6 11/30/98 884.33 18.75 865.58 5.50 31 4.90 18.0 85 10/22/99 884.33 14.65 869.68 5.70 39 4.95 13.6 305 03/20/00 884.33 15.33 869.00 5.30 3 5.40 18.2 306 06/22/00 884.33 NG NG NG NG NG NG NG NG 09/06/00 884.33 13.00 871.33 5.16 3.4 5.68 22.4 210 NG 08/20/01 884.33 18.68 865.65 5.19 32 3.70 24.7 368 Very Silty MW-7 11/30/98 882.59 16.90 865.69 5.60 56 2.00 19.1 81 10/22/99 882.59 7.65 874.94 5.63 84 4.25 20.3 270 03/20/00 882.59 8.05 874.54 4.50 4 5.40 16.2 326 06/22/00 882.59 NG NG NG NG NG NG NG NG 09/06/00 882.59 7.00 875.59 4.90 58 0.78 20.4 232 Brown -Orange 08/20/01 882.59 15.47 867.12 5.00 55 0.39 21.2 421 MW-8 11/30/98 883.03 17.66 865.37 4.80 37 1.82 19.8 126 10/22/99 883.03 12.85 870.18 4.99 46 3.32 19.9 328 03/20/00 883.03 12.90 870.13 4.60 4 0.70 18.4 377 06/22/00 883.03 NG NG NG NG NG NG NG NG 09/06/00 883.03 11.52 871.51 4.30 46 2.07 23.6 336 NG 08/20/01 883.03 18.07 864.96 NG NG NG NG NG MW-9 11/30/98 880.43 17.84 862.59 6.73 60 4.08 20.0 76 10/22/99 880.43 11.65 868.78 5.28 44 4.43 21.8 307 03/20/00 880.43 12.75 867.68 4.80 4 2.80 20.0 346 06/22/00 880.43 NG NG NG NG NG NG NG NG 09/06/00 880.43 11.75 868.68 4.77, 38 3.05 24.5 236 NG 08/20/01 880.43 20.17 860.26 4.99 40 2.95 25.6 404 Table 2.xls 2 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color MW-10 11/30/98 882.42 22.60 859.82 5.70 17- 5.50 19.0 66 10/22/99 882.42 18.73 863.69 5.52 20 5.38 18.8 314 03/20/00 882.42 19.03 863.39 4.90 2 7.50 20.8 264 06/22/00 882.42 NG NG NG NG NG NG NG NG 09/06/00 882.42 19.25 863.17 4.51 1.9 6.81 25.0 267 Orange -brown 03/06/01 882.42 19.31 863.11 5.11 22 9.63 16.5 227 08/20/01 882.42 24.54 857.88 4.89 17 6.53 23.2 377 Pinkish/orange, Silty MW-11 11/30/98 874.71 19.03 855.68 6.30 47 4.10 18.6 45 10/22/99 874.71 14.00 860.71 7.80 580 7.03 19.6 195 03/20/00 874.71 15.33 859.38 5.30 5 4.00 19.6 329 06/22/00 874.71 NG NG NG NG NG NG NG NG 09/06/00 874.71 13.45 861.26 5.14 53 4.38 24.0 284 NG MW-12 11/30/98 862.15 11.50 850.65 5.80 164 3.90 19.0 68 10/22/99 862.15 8.68 853.47 6.41 198 4.87 20.0 225 03/20/00 862.15 9.10 853.05 5.99 144 3.70 17.9 162 06/22/00 862.15 NG NG NG NG NG NG NG NG 09/06/00 862.15 8.70 853.45 5.40 17.4 3.81 25.1 178 Light brown 03/06/01 862.15 9.45 852.70 6.90 150 6.22 17.7 169 08/20/01 862.15 10.90 851.25 5.50 156 2.14 27.7 491 MW-13 11/30/98 863.77 7.31 856.46 7.10 420 'NS 15.4 83 10/22/99 863.77 7.06 856.71 7.00 80 6.40 15.0 279 03/20/00 863.77 6.68 857.09 6.41 168 6.40 15.9 132 06/22/00 863.77 NG NG NG NG NG NG NG NG 09/06/00 863.77 6.98 856.79 5.83 9.8 5.96 22.8 209 NG 08/20/01 863.77 .-- 11.66 852.11 6.04 34 5.23 26.9 417 MW-14 11/30/98 884.36 19.78 864.58 7.70 280 NS 15.2 70 10/22/99 884.36 NG - NS NS NS NS NS 03/20/00 884.36 18.95 865.41 6.60 67 4.50 16.6 NG O6/22/00 884.36 NG NG NG NG NG NG NG NG 09/06/00 884.36 20.16 864.20 4.38 4.5 4.15 21.2 333 NG Table 2.xls 3 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color MW-15 11/30/98 872.10 16.58 855.52 5.60 57 3.99 19.0 78 10/22/99 872.10 14.75 857.35 5.87 50 4.39 18.4 254 03/20/00 872.10 13.87 858.23 4.64 41 5.84 21.3 269 06/22/00 872.10 NG NG NG NG NG NG NG NG 09/06/00 872.10 14.62 857.48 5.32 65 6.39 26.9 177 Orange 03/06/01 872.10 13.86 858.24 5.42 50 7.71 19.5 208 08/20/01 872.10 20.90 851.20 6.20 24 2.66 40.7 628 Light Pinkish MW-17 11/30/98 861.43 6.45 854.98 6.10 79 5.80 19.0 26 10/22/99 861.43 5.26 856.17 7.00 90 5.80 16.7 303 •, 03/20/00 861.43 6.36 855.07 5.18 80 8.60 20.7 153 06/22/00 861.43 NG NG NG NG NG NG NG NG 09/06/00 861.43 5.40 856.03 6.52 8.6 4.90 20.1 218 NG 03/06/01 861.43 5.00 856.43 6.26 96 6.18 15.8 139 08/20/01 861.43 11.13 850.30 6.07 72 4.01 23.8 505 MW-18 11/30/98 862.26 12.15 850.11 6.01 82 3.60 18.3 60 10/22/99 862.26 10.35 851.91 6.21 100 6.03 15.5 251 03/20/00 862.26 10.14 852.12 5.87 85 2.90 18.3 169 06/22/00 862.26 NG NG NG NG NG NG NG NG 09/06/00 862.26 10.51 851.75 5.23 8.9 3.02 21.5 305 NG 03/06/01 862.26 9.82 852.44 5.81 106 2.87 16.3 231 08/20/01 862.26 12.67 849.59 5.67 75 1.58 31.1 922 Slightly Pinkish MW-20 11/30/98 866.15 22.65 843.60 6.30 154 NS 17.6 126 10/22/99 866.15 22.99 843.16 5.77 160 4.77 17.1 344 03/20/00 866.15 22.97 843.18 5.79 149 3.40 18.6 157 06/22/00 866.15 NG NG NG NG NG NG NG NG 09/06/00 866.15 22.91 843.24 5.20 15.4 2.67 23.2 241 NG MW-21 11/30/98 866.12 29.44 836.68 6.10 63 5.30 17.0 50 10/22/99 866.12 28.44 837.68 6.19 70 5.18 17.2 335 03/20/00 866.12 27.98 838.14 5.90, 560 5.00 19.5 150 06/22/00 866.12 NG NG NG NG NG NG NG NG 09/06/00 866.12 28.82 837.30 5.17 6.3 4.92 20.7 258 NG Table 2.xls 4 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color MW-22 11/30/98 861.83 10.80 851.03 6.66 100 5.50 16.1 18 10/22/99 861.83 9.57 852.26 7.00 110 5.90 16.8 236 03/20/00 861.83 9.58 852.25 6.40 10 5.30 16.8 218 06/22/00 861.83 NG NG NG NG NG NG NG NG 09/06/00 861.83 10.25 851.58 6.24 102 7.59 21.5 69 Silty 03/06/01 861.83 4.45 852.38 6.62- 122 7.39 13.2 106 08/20/01 861.83 12.18 849.65 • 6.07 93 3.39 27.2 288 MW-23 11/30/98 861.15 24.10 837.05 6.20 598 1.60 16.9 43 10/22/99 861.15 24.13 837.02 6.70 760 4.90 18.4 -87 03/20/00 861.15 24.22 836.93 6.20 60 0.80 18.4 -74 06/22/00 861.15 NG NG NG NG NG NG NG NG 09/06/00 861.15 24.29 836.86 6.08 605 6.51 23.1 -98 Brown, silty 03/06/01 861.15 24.28 836.87 6.50 687 6.06 15.5 -96 08/20/01 861.15 24.33 836.82 5.84 494 0.95 24.0 151 MW-27 11/30/98 879.80 19.85 859.95 4.70 235 2.60 20.0 130 10/22/99 879.80 15.34 864.46 5.05 232 3.54 20.5 299 03/20/00 879.80 NG -- NG NG NG NG NG O6/22/00 879.80 NG NG NG NG NG NG NG NG 09/06/00 879.80 15.26 864.54 4.92 212 12.54 24.4 294 NG 03/06/01 879.80 15.85 863.95 4.97 228 5.11 20.1 618 08/20/01 879.80 22.50 857.30 4.73 250 3.06 22.5 503 MW-28 11/30/98 881.23 19.40 861.83 4.80 25 2.10 20.0 125 10/22/99 881.23 13.42 867.81 5.22 37 3.44 20.9 291 03/20/00 881.23 14.92 866.31 5.10 3 6.30 18.4 311 O6/22/00 881.23 NG NG NG NG NG NG NG NG 09/06/00 881.23 11.68 869.55 4.76 39 6.45 24.0 215 NG 03/06/01 881.23 14.45 866.78 4.88 29 8.27 19.3 535 08/20/01 881.23 21.83 859.40 4.71 24 3.43 25.4 507 Table 2.xls 5 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color LMP-1 01/21/99 873.50 12.83 860.67 6.80 318 NS 19.3 129 10/22/99 873.50 11.39 862.11 6.60 330 5.28 20.4 223 03/20/00 873.50 13.35 860.15 5.22 310 1.34 21.2 174 06/22/00 873.50 NG NG NG NG NG NG NG NG 09/06/00 873.50 12.00 861.50 5.83 320 12.35 24.0 161 NG 03/06/01 873.50 13.10 860.40 6.19 356 1.71 20.4 148 08/20/01 873.60 16.98 856.52 6.82 263 0.38 26.8 142 LMP-2 01/21/99 871.41 11.52 859.89 6.70 79 NS 18.7 128 10/22/99 871.41 11.32 860.09 6.36 111 4.99 20.4 228 03/20/00 871.41 11.70 859.71 5.50 98 5.70 23.0 144 06/22/00 871.41 NG NG NG NG NG NG NG NG 09/06/00 871.41 12.33 859.08 5.53 101 2.58 23.6 207 NG 03/06/01 871.41 8.65 862.76 5.87 116 3.78 18.4 162 08/20/01 871.41 15.64 855.87 6.67 82 0.74 37.1 357 Light Pinkish DW-1 11/30/98 882.31 17.10 865.21 6.20 178 1.70 17.4 47 10/22/99 882.31 10.72 871.59 7.01 89 4.13 17.3 242 03/20/00 882.31 11.25 871.06 6.10 7 2.50 15.9 207 06/22/00 882.31 NG NG NG NG NG NG NG NG 09/06/00 882.31 9.66 872.65 5.70 70 2.57 19.0 159 NG 08/20/01 882.31 34.26 848.05 NG NG NG NG NG DW-2 11/30/98 881.12 16.35 864.77 5.50 83 4.60 19.0 88 10/22/99 881.12 14.45 866.67 6.71 1 4.89 22.0 226 03/22/00 881.12 11.38 869.74 6.10 9.00 1.90 17.8 176 NG 06/22/00 881.12 NG NG NG NG NG NG NG NG 09/07/00 881.12 9.66 871.46 5.90 97 2.56 18.4 134 NG 08/20/01 881.12 17.40 863.72 NG NG NG NG NG Table 2.xis 6 of 14 Revised 11/28/01 l Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color DW-3 11/30/98 882.59 18.30 864.29 5.50 61 ' 5.00 18.0 93 10/22/99 882.59 12.35 870.24 5.23 43 4.17 16.5 317 _ 03/23/00 882.59 13.90 868.69 5.80 6.00 4.40 17.1 224 Clear 06/22/00 882.59 14.11 868.48 5.58 34.00 7.20 23.0 693 Purple 09/07/00 882.59 14.00 868.59 4.92 22.9 4.95 20.9 663 NG 03/06/01 882.59 15.90 866.69 5.84 150 4.03 19.0 506 08/20/01 882.69 19.05 863.54 6.78 140 3.00 23.6 784 Slightly Pinkish DW-4 11/30/98 883.69 18.87 864.82 5.60 57 4.40 20.0 80 10/22/99 883.69 18.35 865.34 6.40 61 4.58 18.0 243 03/22/00 883.69 16.00 867.69 5.90 6.00 4.40 19.0 254 Clear 06/22/00 883.69 15.94 867.75 6.01 8.00 4.30 21.7 632 Purple 09/14/00 883.69 16.11 867.58 5.59 499 7.43 21.3 768 Deep Purple 03/06/01 883.69 16.80 866.89 6.62 5.13 4.27 16.9 710 08/20/01 883.69 20.47 863.22 NG NG NG NG NG DW-5 11/30/98 872.80 17.39 855.41 6.10 114 3.40 20.0 47 10/22/99 872.80 17.21 855.59 6.58 120 3.79 19.7 208 03/20/00 872.80 15.81 856.99 5.60 110 4.80 19.4 179 06/22/00 872.80 NG NG NG NG NG NG NG NG 09/06/00 872.80 16.42 856.38 5.89 10.6 3.94 23.8 142 NG 03/06/01 872.80 6.68 866.22 6.42 124 4.71 16.9 129 08/20/01 872.80 26.26 846.54 6.09 94 1.92 35.1 460 DW-7 11/30/98 862.17 9.91 852.26 6.60 172 3.30 21.0 27 10/22/99 862.17 7.91 854.26 7.52 187 6.02 20.3 176 03/20/00 862.17 9.00 853.17 6.79 164 5.30 17.3 126 06/22/00 862.17 NG NG NG NG. NG NG NG NG 09/06/00 862.17 7.40 854.77 6.33 18.6 3.48 18.6 34 Olive -brown 03/06/01 862.17 1.70 860.47 6.81 209 3.95 14.3 158 08/20/01 862.17 9.68 852.49 6.53 132 2.31 29.0 473 Table 2.xls 7 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties . Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color DW-8 11/30/98 861.44 5.77 855.67 6.50 84 4.60 18.6 29 10/22/99 861.44 4.02 857.42 6.81 98 8.62 17.3 258 03/20/00 861.44 4.02 857.42 6.19 210 5.10 16.5 NG 06/22/00 861.44 NG NG NG NG NG NG NG NG 09/06/00 861.44 4.35 857.09 4.62 8.4 5.72 20.2 215 NG 03/06/01 861.44 3.94 857.50 6.49 94 6.06 16.6 576 08/20/01 861.44 11.17 850.27 6.13 85 4.58 23.6 794 DW-9 11/30/98 NS 16.35 NS 7.00 170 0.94 17.9 21 10/22/99 Well destroyed during construction DW-11 11/30/98 NS I 22.23 I NS I 8.30 I 138 I 4.60 I 16.4 I -84 10/22/99 Well destroyed during construction DW-12 11/30/98 845.45 14.38 831.07 7.34 110 4.30 19.0 -41 10/22/99 845.45 12.82 832.63 6.58 100 4.60 16.3 189 03/20/00 845.45 12.56 832.89 5.30 10 4.00 17.9 290 06/22/00 845.45 NG NG NG NG NG NG NG NG 09/06/00 845.45 12.87 832.58 5.83 9.1 3.85 22.0 191 NG DW-13 10/22/99 861.10 11.91 849.19 7.17 150 4.60 17.8 165 03/20/00 861.10 10.56 850.54 5.80 12 4.40 16.4 232 O6/22/00 861.10 NG NG NG NG NG NG NG NG 09/06/00 861.10 10.56 850.54 6.21 108 6.14 19.6 102 Silty 03/06/01 861.10 6.33 854.77 6.55 129 6.13 14.6 160 08/20/01 861.10 13.25 847.85 6.43 121 3.82 20.2 362 DW-14 10/22/99 860.06 22.52 837.54 6.82 160 4.30 17.2 -258 03/20/00 860.06 21.31 838.75 5.90 15 3.40 18.0 59 O6/22/00 860.06 NG NG NG NG NG NG NG NG 09/06/00 860.06 22.46 837.60 9.23 184 1.90 21.9 -121 Brown, silty 03/06/01 860.06 21.55 838.51 7.00 170 4.87 17.8 44 08/20/01 860.06 23.52 836.54 6.71 161 1.19 27.9 196 Table 2.xis 8 of 14 Revised 11/28/01 - -- - - - -- -- -- -- -- - -- - - -- -- - - - - -- - - - - - - --- Table 2.xls Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mV) Color DW-15 10/22/99 861.20 24.91 836.29 7.30 180 4.24 19.5 -345 03/20/00 861.20 23.56 837.64 5.80 15 2.60 18.1 206 06/22/00 861.20 NG NG NG NG NG NG NG NG 09/06/00 861.20 24.86 836.34 6.25 140 3.69 21.9 109 Brown, silty 03/06/01 861.20 23.80 837.40 9.75 178 3.28 17.7 4 08/20/01 861.20 25.61 835.69 6.42 138 2.19 21.4 260 DMP-1 01/21/99 870:83 13.61 857.22 5.80 643 NS 18.0 127 10/22/99 870.83 13.82 857.01 6.36 569 4.18 19.3 252 03/20/00 870.83 13.44 857.39 5.29 460 1.82 19.7 197 06/22/00 870.83 NG NG NG NG NG NG NG NG 09/06/00 870.83 13.21 857.62 5.84 38.7 1.74 23.8 173 NG 03/06/01 870.83 13.62 857.21 6.23 446 3.52 16.2 159 08/20/01 870.83 17.54 853.29 NG NG NG NG NG Light Purple Color DMP-2 01/21/99 872.13 11.85 860.28 7.60 187 NS 17.8 107 10/22/99 872.13 11.71 860.42 7.02 163 4.51 20.3 207 03/20/00 872.13 11.45 860.68 6.32 140 3.60 19.5 170 06/22/00 872.13 NG NG NG . NG NG NG NG NG 09/06/00 872.13 11.86 860.27 6.15 123 5.01 21.1 154 Brown, silty 03/06/01 872.13 12.05 860.08 6.60 147 4.83 17.2 167 08/20/01 872.13 31.84 840.29 6.40 171 1.62 25.2 101 DMP-3 01/21/99 862.18 8.00 854.18 7.10 151 NS 16.3 86 10/22/99 862.18 7.64 854.54 6.98 100 5.73 17.1 188 03/20/00 862.18 7.70 854.48 6.54 95 4.80 20.9 72 06/22/00 862.18 NG NG NG NG NG NG NG NG 09/06/00 862.18 7.63 854.65 6.16 10.5 5.88 22.7 145 Brown, silty 03/06/01 862.18 7.56 854.62 6.94 137 8.54 12.3 157 08/20/01 862.18 11.98 850.20 6.41 71 3.94 27.5 416 Very Silty 9of14 Revised 11/28/01 I Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color DMP-4 01/21/99 862.25 7.11 855.14 7.10 152 NS 15.8 85 10/22/99 862.25 7.13 855.12 7.13 90 5.89 15.8 281 03/20/00 862.25 7.03 855.22 6.26 80 4.90 17.0 NG 06/22/00 862.25 NG NG NG NG NG NG NG NG 09/06/00 862.25 6.51 855.74 5.87 89 6.26 18.8 114 Silty 03/06/01 862.25 6.60 855.65 6.44 91 7.38 13.7 147 08/20/01 862.25 11.68 860.57 6.50 299 5.08 23.8 916 Purple Color BMW-1 10/22/99 882.45 DRY NG DRY DRY DRY DRY DRY 03/23/00 882.45 18.35 864.10 11.50 11.00 0.40 17.7 560 Clear O6/22/00 882.45 18.30 864.15 11.08 12.00 3.70 22.9 -246 Clear 09/08/00 882.45 32.23 850.22 11.02 83.1 2.13 18.9 A63 NG 03/06/01 882.45 18.55 863.90 12.01 1070 6.49 17.6 -555 08/20/01 882.45 21.48 860.97 NG NG NG NG NG BMW-2 10/22/99 882.97 13.10 869.87 6.80 119 5.08 20.7 199 03/23/00 882.97 ( 14.09 868.88 5.80 11.00 3.60 17.6 -40 Clear 06/22/00 882.97 14.19 868.78 6.34 11.00 6.70 19.9 158 Clear 09/07/00 882.97 13.33 869.64 6.16 11.8 4.30 18.7 -31 NG 03/06/01 882.97 14.45 868.52 6.49 118 2.72 17.7 -120 O8/20101 882.97 20.88 862.09 6.31 152 1.80 25.0 45 BMW-3 10/22/99 862.12 11.81 850.31 7.43 320 6.48 18.7 173 03/20/00 862.12 11.50 850.62 8.17 265 0.60 21.3 -232 06/22/00 862.12 NG NG NG NG NG NG NG NG 09/06/00 862.12 9.52 852.60 7.14 42.6 1.76 22.1 -203 Sulfur odor 08/20/01 862.12 10.92 851.20 NG NG NG NG NG BMW-4 10/22/99 860.08 22.45 837.63 6.80 530 5.04 17.7 220 03/20/00 860.08 21.22 838.86 5.50 11 4.90 17.0 234 06/22/00 860.08 NG NG NG NG NG NG NG NG 09/06/00 860.08 22.71 837.37 7.33 246 1.90 21.5 -192 Brown, silty 03/06/01 860.08 21.38 838.70 7.92 256 0.26 16.2 -114 08/20/01 860.08 23.47 836.61 NG NG NG NG NG Table 2.xls 10 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mv) Color PT-1 S 03/23/00 882.69 NG NG NG NG NG NG NG NG 06/22/00 882.69 17.60 865.09 5.19 3.00 8.80 29.4 226 Brownish, Silty 09/12/00 882.69 17.82 864.87 4.97 2.3 7.59 23.7 337 Brown, silty PT-2S 03/23/00 882.95 15.30 867.65 5.50 3.20 9.10 19.7 244 NG 06/22/00 882.95 16.55 866.40 NG NG NG NG NG Unable to Remove Water 09/06/00 882.95 16.87 866.08 NG NG NG NG NG Well Not Sampled PT-3S 03/23/00 882.59 18.24 864.35 5.20 2.00 6.80 19.7 280 NG 06/22/00 882.59 19.21 863.38 5.38 3.00 7.00 27.3 217 Brownish orange 09/12/00 882.59 18.05 864.54 5.13 2.8 7.24 23.2 325 Brown, silty PT4S 03/23/00 882.21 19.10 863.11 4.60 9.00 4.80 15.4 320 NG 06/22/00 882.21 19.17 863.04 4.94 9.00 5.50 26.3 285 Brownish orange 09/12/00 882.21 17.96 864.25 5.69 8.3 6.37 27.5 313 Brown, silty PT-5S 03/23/00 882.97 16.83 866.14 5.15 1.80 8.96 19.2 274 NG 06/22/00 882.97 16.87 866.10 5.39 4.00 6.60 28.9 236 Orange, Turbid 09/12/00 882.97 16.66 866.31 4.90 8.3 8.26 21.5 356 Brown, silty PT-1 D 03/23/00 882.70 17.78 864.92 5.28 7.00 5.70 21.3 221 NG 06/22/00 882.70 18.34 864.36 6.20 7.00 6.80 20.6 179 Clear 09/08/00 882.70 17.70 865.00 6.00 6.7 6.48 22.4 297 NG PT-2D 03/23/00 882.95 17.28 865.67 6.27 7.20 5.52 19.1 229 NG 06/22/00 882.95 17.41 865.54 6.28 8.00 5.60 22.1 126 Slightly Cloudy 09/08/00 882.95 16.77 866.18 6.00 78 4.46 23.3 159 NG PT-3D 03/23/00 882.66 18.24 864.42 6.90 6.10 5.10 20.5 185 NG 06/22/00 882.66 18.25 864.41 6.04 7.00 9.50 23.2 190 Brownish orange, Silty 09/09/00 882.66 17.71 864.95 5.88 5.7 9.26 23.9 227 NG PT4D 03/23/00 882.41 18.40 864.01 5.00 8.00 1.12 19.6 238 NG 06/22/00 882.41 18.15 864.26 5.70 9.00 3.00 23.5 217 Cloudy,Silty Brown 09/09/00 882.41 17.63 864.78 5.40 11.8 - - 5.02 22.7 204 NG Table 2.xis 11 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) -Temp. (°C) Oxidation Reduction Potential (mV) Color PT-5D 03/23/00 882.96 16.41 866.55 5.92 6.30 2.89 19.3 258 NG 6/22/00 882.96 16.56 866.40 5.89 7.00 1.30 21.5 146 Slightly Cloudy 9/8/00 882.96 16.40 866.56 5.75 6.9 2.29 22.7 204 NG HVDP-1 09/06/00 881.84 9.30 872.54 6.30 194 5.66 19.1 182 NG HVDP-2 09/06/00 882.04 9.65 872.39 5.40 66 3.66 19.3. 232 NG HVDP-3 09/06/00 881.13 9.91 871.22 5.47 6.3 2.55 21.2 682 Purple HVDP-4 09/06/00 881.37 13.35 868.02 5.90 126 1.23 21.8 121 NG HVDP-5 09/06/00 880.85 12.90 867.95 4.80 34 1.86 23.3 198 NG HVDP-6 09/06/00 881.92 12.36 869.56 4.20 116 3.85 20.5 321 NG HVDP-7 09/06/00 882.21 13.51 868.70 5.23 6 5.12 22.6 619 NG HVDP-8 09/06/00 882.40 13.72 868.68 6.42 26.9 2.84 21.3 243 NG HVDP-9 09/06/00 882.63 15.27 867.36 5.60 5.5 5.28 20.9 580 NG HVDP-10 09/06/00 881.65 14.78 866.87 5.30 44 3.33 21.7 195 NG HVDP-11 09/06/00 881.41 15.80 865.61 5.63 5.7 3.15 22.7 280 NG HVDP-12 09/06/00 881.98 14.47 867.51 5.81 6.5 1.89 22.7 166 NG HVDP13 03/23/00 882.84 17.16 865.68 6.10 7.10 2.80 18.9 270 NG 06/22/00 882.84 15.89 866.95 5.64 4.00 4.90 25.5 148 Light Orange 09/06/00 882.81 16.25 866.56 6.06 7.8 2.33 21.4 333 NG Table 2.xls 12 of 14 Revised 11/28/01 Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top -of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/CM) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mV) Color HVDP14 03/23/00 882.57 18.40 864.17 5.00 4.00 5.10 21.0 250 NG (EW-1) 06/22/00 882.57 19.50 863.07 5.97 6.00 6.30 21.8 193 Clear 09/09/00 882.57 16.92 865.65 6.29 5.30 3.76 22.9 578 NG HVDP-15 09/06/00 881.24 17.00 864.24 J 5.48 5.1 2.98 22.1 208 NG HVDP-16 09/06/00 879.73 15.19 864.64 5.80 123 0.63 23.5 -144 NG HVDP-17 09/06/00 878.89 15.65 863.24 5.90 32 1.47 24.8 81 NG HVDP-18 09/06/00 873.99 10.28 863.71 6.20 196 0.00 20.9 -3 NG HVDP-19 09/06/00 875.83 11.27 864.56 6.00 524 0.00 22.0 67 NG HVDP-20 09/06/00 872.84 9.70 863.14 6.00 187 0.00 19.3 41 NG HVDP-21 09/06/00 871.23 10.21 861.02 5.70 275 0.01 23.1 113 NG HVDP-22 09/06/00 870.56 10.65 859.91. 6.30 197 0.25 20.5 -86 Sulphur odor HVDP-23 09/06/00 871.70 11.81 859.89 6.00 146 1.27 20.6 39 NG HVDP-24 09/06/00 872.56 13.60 858.96 5.80 85 3.60 20.5 111 NG HVDP-25 09/06/00 872.37 15.43 856.94 5.82 83 5.57 22.9 123 NG HVDP-26 09/06/00 873.48 16.46 857.02 5.08 16 2.77 22.6 207 NG HVDP-27 09/06/00 875.39 16.96 858.43 5.29 42 2.67 21.1 14 Sulphur odor HVDP-28 09/06/00 876.17 18.29 857.88 5.17 20 5.15 22.8 174 NG HVDP-29 09/06/00 878.38 19.69 858.69 5.29 24 8.78 21.6 195 NG Table 2.xls 13 of 14 Revised 11/28/01 r Table 2 Summary of Groundwater Gauging and Field Monitoring Data W.P. Ballard and Downgradient Properties Greensboro, North Carolina Well Identification Date Top of Casing Elevation (ft) Depth to Water (ft) Water Table Elevation (ft) pH (S.U.) Specific Cond. (US/cm) Dissolved Oxygen (mg/L) Temp. (°C) Oxidation Reduction Potential (mV) Color SVE-1 09/06/00 881.40 10.19 871.21 4.80 55 3.72 21.2 314 NG SVE-2 09/06/00 881.97 11.60 870.37 4.80 109 3.64 23.6 219 NG SVE-3 09/06/00 881.96 13.02 868.94 5.40 6.4 2.92 21.6 400 NG SVE-4 09/06/00 881.21 9.40 871.81 4.60 54 4.40 21.5 304 NG SVE-5 09/06/00 881.98 10.16 871.82 4.90 73 5.87 19.9 278 NG SVE-6 09/06/00 882.67 11.05 871.62 5.58 56.3 7.00 18.4 273 Dark Brown SVE-7 09/06/00 883.39 12.93 870.46 5.66 7.3 5.36 21.1 462 NG SVE8 03/23/00 882.81 16.20 866.61 5.30 7.40 3.11 21.0 205 NG (EW-3) 06/22/00 882.81 16.47 866.34 6.20 7.00 4.00 21.9 158 Clear 09/08/00 882.81 16.22 866.59 5.30 3.80 5.24 28.2 198 NG SVE9 03/23/00 882.56 17.87 864.69 5.38 2.10 7.39 21.2 242 NG (EW-2) 06/22/00 882.56 17.18 865.38 6.67 3.00 7.80 25.1 190 Cloudy 09/09/00 882.56 16.90 865.66 6.77 2.50 10.32 25.8 249 NG SVE-10 09/06/00 879.25 14.96 864.29 4.94 104 7.22 25.4 190 NG SVE-11 09/06/00 875.99 12.00 863.99 6.14 1.04 1.96 22.5 -43 NG SVE-12 09/06/00 878.56 13.75 864.81 5.06 743 6.63 23.3 183 NG SVE-13 09/06/00 876.26 NG NS 5.08 222 7.30 23.8 173 NG SVE-14 09/06/00 881.51 11.40 870.11 4.77 38 3.05 24.5 236 NG rvores: rv%.:, aenorea parameter not gauges or measurea. NS denotes TOC elevation not surveyed. Bold-faced indicate most recent measurements. Table 2.xis 14 of 14 Revised 11/28/01 TABLE 3 August 2001 Groundwater Analysis Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-1 MW-2 MW-3 MW-3 (Dup) MW-4 MW-5 MW-6 MW-7 MW-9 MW-10 MW-12 MW-13 MW-15 MW-17 MW-17(Dup MW-18 MW-22 MW-23 MW-27 MW-28 LMP-1 LMP-2 Sample Date: 8/22/01 B 8122101 B 8/22/01 B 8/22/01 B 8/23/01 B 8/22/01 B 8/22/01 B 8/22/01 B 8122101 B 8/22/01 B 8121/01 B 8/21/01 B 8/21/01 B 8/21/01 B 8/21/01 B 8/21/O1 B 8/20/01 B 8/20/01 B 8/22/01 B 8122/01 B 8/21/01 B 8/21/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1 <1 2.3 <1 NA NA NA 1.7 NA NA NA NA NA NA NA NA NA NA NA NA Ethylbenzene (ug/L) 29 NA NA <1 <1 1.4 <1 NA NA NA <1 NA NA NA NA NA NA NA NA NA NA NA NA Methylene Chloride (ug/L) 5.0 <5.0 <1 <1 <1 <250 9.8 <5 <5 <5 <5.0 <5 <5 <50 <50 <50 <50 <250 <1.0 <5 <5 <50 <1.0 Chloroform (ug/L) 0.19 1.5 5.2 43.7 45.9 <50 <5 <1 <1 <1 5.5 <1 <1 25 55 55 <50 <50 <1.0 <1 <1 11 1.7 Chloromethane (ug/L) none <1.0 <1 <1 <1 <50 <1 <1 <1 <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1 4.6 5.1 <50 <1 <1 <t <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 1, 1 -Dichloroethane (ug/L) 700 <1.0 <1 <1 <1 <50 <1 9.4 1.2 <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 1,2-Dichloroethane (ug/L) 0.38 <1.0 <1 <1 <1 <50 <1 4.4 <1 <1 8 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 1,1-Dichloroethene (ug/L) 7.0 <1.0 5.9 2.9 4.2 <50 34.9 450 2.0 <1 <1 <t <1 <10 <50 <50 <50 <50 <1.0 1.7 <1 <10 <1.0 cis-1,2-Dichloroethene (ug/L) 70 <1.0 88 <1 <1 90 3.1 6.5 <1 <1 11.6 5.2 <1 22 165 155 <50 <50 <1.0 527 583 65 13.8 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <1 2.2 3.8 <50 <1 3.7 <1 <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1 <1 <1 <50 <1 <1 <1 <1 <1 60 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 595 250 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA <1 <1 <1 <50 <1 <1 <1 <1 <1 <1 <1 <10 <50 <50 <50 <50 NA <1 <1 <1 <1.0 Trichloroethene (ug/L) 2.8 1.2 39.8 <1 <1 370 1.4 <1 <1 <1 30.6 5.2 <1 345 556 610 <50 180 <1.0 442 134 67 6.9 Tetrachloroethene (ug/L) 1 2,310 184 126,000 123,000 12,800 7,520 166 25.8 <1 16,800 7.7 <1 11 2,340 2,480 940 1 790 <1.0 <1 <1 81 51.8 1,1,2,2-Tetrachloroethane (ug/L) none <1.0 <1 <1 <1 <50 <1 <1 <1 <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 Toluene (ug/L) 1,000 NA NA 15.5 15.4 2.4 <1 <1 NA NA <1 NA NA NA NA NA NA NA <1.0 NA NA NA NA 1,1,1-Trich loroethane (ug/L) 200 <1.0 1.7 3 3.6 <50 <1 30.3 <1 <1 <1 <1 <1 <10 <50 <50 <50 <50 <1.0 <1 <1 <10 <1.0 1,1,2-Tdchloroethane (ug/L) none <1.0 <1 40.2 43 <50 1 9 <1 <1 24.4 <1 <1 <10 <50 <50 <50 =50 <1.0 <1 <1 <10 <1.0 Xylenes, Total (ug/L) 530 NA NA 3.5 1 3.5 1 16.4 1 <1 NA NA NA <1 NA NA NA NA NA NA NA NA NA NA NA NA Total VOCs Detected (ug/L) MM 2,313 325 126,116 1 123,125 1 13,283 1 7,570 1 679 29 0 16,882 78 0 403 3,115 3,300 F 940 1,970 0 971 717 819 324 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. B - indicates samples collected by IT Corporation o/North Carolina, Inc. (fomredy Fluor Daniel GTI, Inc.) NA denotes compound not analyzed Table 3.xls Page 1 of 1 Revised: 11/28/01 TABLE 4 Historical Groundwater Analytical Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-1 MW-2 Sample Date: 5129/92 A 7/22/94 A 07/11/96 A 12/02/98 B 10/28/99 B 3/22/00 B 9/6/00 B 3r7/Ot B 8/22101 B 5/29/92 A 7/22/94 A 07/12/96 A 12/02/98 B 10/27/99 B 3/22/00 B 917/00 B 10/19/00 B 3/8101 B 8/22/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA <100 <50 <1.0 NA NA NA NA NA NA <100 <1.0 <1.0 NA <1 NA NA Ethylbenzene (ug/L) 29 NA NA NA <100 <50 <1.0 NA NA NA NA NA NA <100 <1.0 <1.0 NA <1 NA NA Methylene Chloride (ug/L) 5.0 <1,000 <100 <1,200 <500 <250 <5.0 <5.0 <5.0 <5.0 640 <100 <250 <500 <5.0 <5.0 <50 <5 <5.0 <1 Chloroform (ug/L) 0.19 <1,000 <100 <250 <100 <50 <1.0 <1.0 1 1.5 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 6.2 Chloromethane (ug/L) none <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 <1 Carbon Tetrachloride (ug/L) 0.3 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1,0 <1 1,1-Dichloroethane (ug/L) 700 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 <1 1,2-Dichloroethane (ug/L) 0.38 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 <1 1,1-Dichloroethene (ug/L) 7.0 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 5.9 cis-1,2-Dichloroethene (ug/L) 70 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 1,070 95.7 <10.0 <1 <1.0 88 trans-1,2-Dichloroethene (ug/L) 70 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 14.4 <1.0 <10.0 <1 <1.0 <1 1,2-Dichloropropane (ug/L) 0.56 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 <1 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA <50 NA NA NA NA NA NA NA NA 19.3 NA NA <1 NA <1 Trichloroethene (ug/L) 2.8 <1,000 <100 <250 <100 <50 6.5 3.1 2 1.2 <200 <100 <50 <100 156 66.7 <10.0 2.0 <1.0 39.8 Tetrachloroethene (ug/L) 1 33,000 8,000 18,000 12,600 3,880 3,420 2,240 680 2310 11,000 6,500 4,100 5,080 56 358 72 46 68 184 1,1,2,2-Tetrachloroethane (ug/L) none <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <520 <100 <1.0 <1.0 <10.0 <1.0 <1 Toluene (ug/L) 1,000 NA NA NA <100 <50 <1.0 NA NA NA NA NA NA <100 <1.0 <1.0 NA NA NA 1,1,1-Trichloroethane (ug/L) 200 <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <1 <1.0 1.7 1,1,2-Trichloroethane (ug/L) none <1,000 <100 <250 <100 <50 <1.0 <1.0 <1.0 <1.0 <200 <100 <50 <100 <1.0 <1.0 <10.0 <t <1.0 <1 Xylenes, Total (ug/L) NA NA NA <200 <100 <2.0 NA NA NA NA NA NA <200 <2.0 <2.0 NA NA NA Total VOCs Detected (ug/L) RM 33,000 8,000 1 18,000 12,600 3,880 1 3.427 2,243 683 2,313 11,540 6,500 4,100 1 5,080 1,316 520 72 48 68 325 Sample Location: MW-3 MW-4 Sample Date: 5/29/92 A 1 6/25/93 A 7/22/94 A 7l10/96 A 07/10/96 B 12/ 22198 B 1/21/99 B 10/28/99 B 3/22/00 8 9/8100 B 10/18/00 B 3/8/01 B 8/22/01 B 5/29/92 A 07/10/96 A 7/10/96 B 12/2/98 B 10/28/99 B 3/22/00 B 9/7/00 B 10/19/00 B 3/8/01 B 8/23/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA NA NA <100 NA <5,000 <1.0 <5,000 <1.000 NA <1 NA NA NA <100 <500 <1.0 <1,000 <1,000 NA 2.3 Ethylbenzene (ug/L) 29 NA NA NA NA NA <100 NA <5,000 <1.0 <5,000 <1,000 NA <1 NA NA NA <100 <500 <1.0 <1,000 <1,000 NA 1.4 Methylene Chloride (ug/L) 5.0 <10.000 <5,000 <1000 <25.000 <1000 <500 <2,500 <25,000 <5.0 <25.000 <5,000 <100 <5 <2,000 <12,000 <2,500 <500 <2,500 <5.0 <5,000 <5,000 <5.0 <250 Chloroform (ug/L) 0.19 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 9.7 <5,000 <7,000 18 43.7 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 8 <50 Chloromethane (ug/L) none <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 <1.0 <5,000 <1,000 <1.0 <1 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 Carbon Tetrachloride (ug/L) 0.3 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 3.7 <5,000 <1,000 3 4.6 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 1,1-Dichloroethane (ug/L) 700 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 <1.0 <5,000 <1,000 <1.0 <1 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 1,2-Dichloroethane (ug/L) 0.38 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 <1.0 <5,000 <1,000 <1.0 <1 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <7,000 <1.0 <50 1,1-Dichloroethene (ug/L) 7.0 <10,000 <5,000 2,100 <5,000 <1000 <100 <500 <5,000 3.4 <5,000 <1,000 3 2.9 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 cis-1,2-Dichloroethene (ug/L) 70 <10,000 <5,000 <1000 <5,000 NA 310 <500 <5,000 210 <5,000 <1,000 166 <1 <2,000 <2,500 NA <100 <500 2.7 <1,000 <1,000 415 90 trans-1,2-Dichloroethene (ug/L) 70 <10,000 <5,000 <1000 <5,000 NA <100 <500 <5,000 3.2 <5,000 <1,000 4 2.2 <2,000 <2,500 NA <100 <500 <7.0 <1,000 <1,000 5 <50 1,2-Dichloropropane (ug/L) 0.56 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 <1.0 <5,000 <1,000 <1.0 <t <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 Methyl tert-butyl ether (MTBE) (ugA) 200 NA NA NA NA NA NA NA <5,000 NA <5,000 <1,000 <1.0 <1 NA NA NA NA <500 NA NA <1,000 NA <50 Trichloroethene (ug/L) 2.8 <10,000 <5,000 <1000 <5,000 <1000 210 <500 <5,000 <1000 <5,000 <1.000 90 <1 <2,000 <2,500 <2,500 <100 <500 7.6 <1,000 <1,000 880 370 Tetrachloroethene (ug/L) 0.7 270,000 250,000 110,000 200,000 200,000 162,000 94,000 60,500 156,000 154,000 148,000 138,000 126,000 55,000 39,000 38,000 17,000 22,200 13,400 41,200 64,800 44,800 12,800 1,1,2,2-Tetrachloroethane (ug/L) none <10.000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 5 <5,000 <1.0 <1 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1.0 <50 Toluene (ug/L) 1,000 NA NA NA NA NA <100 NA <5,000 <1.0 <5,000 NA 15.5 NA NA NA <100 <500 <1.0 <1,000 <1.0 2.4 1,1,1-Trichloroethane (ug/L) 200 <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 2 <5,000 <1,000 2 3 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 1,1,2-Trichloroethane (ug/L) none <10,000 <5,000 <1000 <5,000 <1000 <100 <500 <5,000 52.5 <5,000 <1,000 42 40.2 <2,000 <2,500 <2,500 <100 <500 <1.0 <1,000 <1,000 <1.0 <50 Xylenes, Total (ug/L) 530 NA NA NA NA NA <200 NA <10,000 <2.0 <10,000 NA 3.5 NA NA NA <200 <1,000 <2.0 <2,000 NA 16.4 Total VOCs Detected (ug/L)an= 270,000 250.000 112,100 200,000 200,000 152,520 94,000 60,500 156,290 154,000 148,000 138,328 126,116 55,000 39,000 38,000 17,000 22,200 13,410 41.200 54,800 46,108 13,283 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed NS denotes well not sampled Monitoring wells MW-16, MW-19, MW-24, MW-25 and MW-26 were destroyed during site construction activities. Shallow gw Hist summary.As Page 1 of 6 Revised 11/18/01 TABLE 4 Historical Groundwater Analytical Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-5 MW-6 Sample Date: 5/29/92 A 7/22/94 A 7/22/96 A 12/02/98 B 10/28/99 B 3/22/00 B 917/00 B 10/19/00 B 3/8/01 B 8/22/01 B 5/29/92 A 7/11/96A 12/02/98 B 10/28/99 B 3/22100 B 9/7/00 B 10/19/00 B 8/22/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA <1.0 <100 <1.0 NA <100 NA <1 NA NA <1.0 <10.0 <10.0 NA <50 NA Ethylbenzene (ug/L) 29 NA NA NA <1.0 <700 <1.0 NA <100 NA <1 NA NA <1.0 <10.0 <10.0 NA <50 NA Methylene Chloride (ug/L) 5.0 <200 <100 <500 <5.0 <500 <5.0 <500 <500 10 9.8 <10 <5.0 <5.0 <50.0 <50.0 <250.0 <250 <5 Chloroform (ug/L) 0.19 <200 <100 <100 <1.0 <100 <1.0 <100 <100 1 <5 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 <1 Chloromethane (ug/L) none <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 <1 Carbon Tetrachloride (ug/L) 0.3 <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 <1 1. 1 -Dichloroethane (ug/L) 700 <200 <100 <100 <1.0 <100 <1.0 <100 <100 12 <1 <10 <1.0 1 <10.0 <10.0 <50.0 <50 9.4 1,2-Dichloroethane (ug/L) 0.38 <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 4.4 1,1-Dichloroethene (ug/L) 7.0 <200 <100 <100 6.9 <100 6 <100 <100 <1.0 34.9 54 89 203 199 296 445 470 450 cis-1,2-Dichloroethene (ug/L) 70 <200 <100 <100 1.5 <100 <1.0 <100 <100 2 3.1 <10 NA 1.9 <10.0 <10.0 <50.0 <50 6.5 trans-1,2-Dichbroethene (ug/L) 70 <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 <10 NA 1.6 <10.0 <10.0 <50.0 <50 3.7 1,2-Dichloropropane (ug/L) 0.56 <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 <1 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA <100 NA NA <100 NA <t NA NA NA <10.0 NA NA <50 <1 Trichloroethene (ug/L) 2.8 <200 <too <100 1.2 <100 4.2 <100 <100 5 1.4 <10 <1.0 <1.0 <10.0 <10.0 <50.0 <50 <1 Tetrachloroethene (ug/L) 1 9,500 5,100 6,300 3,200 7,590 8,120 5,880 5,060 1,940 7,520 11 28 66 37 101 125 255 166 1, 1,2,2-Tetrach loroethane (ug/L) none <200 <100 <100 <1.0 <100 <1.0 <100 <1.0 <1 �:Jo <1.0 <1.0 <10.0 <10.0 <50.0 <1 Toluene (ug/L) 1,000 NA NA NA <1.0 <100 <1.0 NA NA <1 NA NA <1.0 <10.0 <10.0 NA NA <1 1,1,1-Trichloroethane (ug/L) 200 <200 <100 <100 <1.0 <100 <1.0 <100 <100 <1.0 <1 18 16 19 18 <10.0 <50.0 <50 30.3 1,1,2-Trichloroethane (ug/L) none <200 <100 <100 <1.0 <100 3.3 <100 <100 3 1 ._10 2.8 2.8 <10.0 <10.0 <50.0 <50 9 Xylenes, Total (ug/L) NA NA NA <2.0 <200 <2.0 NA NA <1 NA NA <2.0 <20.0 <20.0 NA NA NA Total VOCs Detected (ug/L) 9,500 1 5.100 6,300 1 3,210 7,590 8.134 5,880 5.060 1 1,973 7,570 83 136 295 254 1 397 1 570 725 1 679 Sample Location: MW-8 MW-9 Sample Date: 1/9/93 A 7/21/94 A 7111/96 A 12/02/98 B 10/28/99 B 3/22/00 B 9!7/00 B 1/9/93 A 7/21/94 A 7/9/96 A 7/9!96 B 12/02/98 B 10/27/99 B 3/22/00 B 9/12/00 B 8/21/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA Ethylbenzene (ug/L) 29 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA Methylene Chloride (ug/L) 5.0 7.8 <1.0 <5.0 <5.0 <5.0 <5.0 <5.0 9.5 <1.0 <5.0 <1.0 <5.0 <5.0 <5.0 <5.0 <5 Chloroform (ug/L) 0.19 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Chloromethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 1,1-Dichioroethane (ug/L) 700 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 1,2-Dichloroethane (ug/L) 0.38 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 1,1-Dichlorcethene (ug/L) 7.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 cis-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA <1.0 NA NA NA NA NA NA NA <1.0 NA NA <1 Trichloroethene (ug/L) 2.8 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Tetrachloroethene (ug/L) 0.7 4.5 3.9 2.6 4.2 <1.0 <1.0 <1.0 14 7.7 4.3 3.8 9.1 <1.0 <1.0 <1.0 <1 1,1,2,2-Tetrachloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Toluene (ug/L) 1,000 NA NA NA <1.0 <1.0 <1.0 NA NA <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 NA 1,1,1-Trichloroethane (ug/L) 200 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 1,1,2-Trichloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 Xylenes, Total (ug/L) 530 NA NA NA <2.0 <2.0 <2.0 NA NA NA NA NA 1 <2.0 1 <2.0 1 <2.0 NA NA Total VOCs Detected (ug/L) ow 12 4 3 4 0 0 0 24 8 4 4 9 0 0 0 0 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed NS denotes well not sampled Monitoring wells MW-16, MW-19, MW-24, MW-25 and MW-26 were destroyed during site construction activities. Shallow gw Hist summary.xls Page 2 of 6 Revised 11/18/01 TABLE 4 Historical Groundwater Analytical Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-7 MW-11 MW-12 Sample Date: 1/9/93 A 7122/94 A 7/12/96 A 12/02/98 B 10/27/99 B 3/22/00 B 9/8/00 B 8/22/01 8 6/25/93 A 7/9/96 A 7/9/96 B 12/02/98 B 10/26/99 B 3/22100 B 9/14/00 B 6/25/93 A 7/9/96 A 7/9/96 B 12/02/98 B 10/26/99 B 3/22/00 8 9/12/00 B 3/7/01 8 8121/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA NA <1.0 <10.0 <1.0 NA NA NA Ethylbenzene (ug/L) 29 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA NA <1.0 <10.0 <1.0 NA NA NA Methylene Chloride (ug/L) 5.0 6.8 <1.0 <5.0 <5.0 <5.0 <5.0 <25.0 <5 <1.0 <5.0 2.4 <5.0 <5.0 <5.0 <5.0 <1.0 <25 44 <5.0 <50.0 <5.0 <50.0 <5.0 <5 Chloroform (ug/L) 0.19 <1.0 1.4 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 Chloromethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 Carbon Tetrachloride (ug/L) 0.3 <1.0 <7.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1,0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 1, 1 -Dichloroethane (ug/L) 700 12 38 16 2.3 1.2 <1.0 <5.0 1.2 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 1,2-Dichloroethane (ug/L) 0.38 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <t <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 1, 1 -Dichloroethene (ug/L) 7.0 <1.0 5.9 1.8 <1.0 <1.0 <1.0 166 2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 cis-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 NA <1.0 <10.0 <1.0 <10.0 1 5.2 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 NA <1.0 <10.0 <1.0 <10.0 <1.0 <1 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <t <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 54 209 240 117 277 94 60 Methyl tert-butyl ether (MTBE) (ug/l) 200 NA NA NA NA <1.0 NA NA <1 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA <1 Trichloroethene (ug/L) 2.8 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 1.2 2.4 <10.0 2 <10.0 9 5.2 Tetrachloroethene (ug/L) 1 1 2 1 <1.0 <1.0 <1.0 18 25.8 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 110 1 2 <10.0 <1.0 <10.0 <1.0 7.7 1,1,2,2-Tetrachloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 7 <1 Toluene (ug/L) 1,000 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA NA <1.0 <10.0 <1.0 NA NA NA 1,1,1-Trichloroethane(ug/L) 200 4.4 6 3.4 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <10.0 <1.0 <10.0 <1.0 <1 1,1,2-Trichloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1 <1.0 <1.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 -;1.0 <10.0 <1.0 <10.0 <1.0 <1 Xylenes, Total (ug/L) NA NA NA <2.0 <2.0 <2.0 NA NA NA NA NA <2.0 <2.0 <2.0 NA NA NA NA 1 <2.0 1 <20.0 1 <2.0 1 NA NA NA Total VOCs Detected (ug/L) 25 54 23 2 1 0 184 29 0 0 2 0 0 0 0 0 110 100 214 1 240 1 119 1 277 111 78 Sample Location: MW-110 MW-14 Sample Date: 1/9/93 A 6/25/93 A 7/21/94 A 07/10/96 A 7/10196 B 12/02/98 B 10/27/99 B 3/22/00 B 9/14/00 8 3/7/01 B 8122101 B 6/25/93 A 7/9/96 A 7/9/96 B 1/21/99 B 10/26/99 B 3/22/00 B 9/13/00 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA 1.7 NA NA NA <1.0 NS <1.0 NA Ethylbenzene (ug/L) 29 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA <1 NA NA NA <1.0 NS <1.0 NA Methylene Chloride (ug/L) 5.0 <250 <100 <100 <2,500 <250 <5.0 <5.0 <5.0 <2500 <5.0 <5.0 <1.0 <5.0 <1.0 <5.0 NS <5.0 <5.0 Chloroform (ug/L) 0.19 <250 <100 <100 <500 <250 <1.0 2.4 <1.0 <500 3 5.5 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 Chloromethane (ug/L) none <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 1,1-Dichloroethane (ug/L) 700 <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 1,2-Dichloroethane (ug/L) 0.38 <250 <100 <100 <500 <250 <1.0 1.7 1.9 <500 5 8 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 1,1-Dichloroethene (ug/L) 7.0 <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 cis-1,2-Dichloroethene (ug/L) 70 <250 <100 <100 <500 NA 5.8 3.5 7.2 <500 11 11.6 <1.0 <1.0 NA <1.0 NS <1.0 <1.0 trans-1,2-Dichloroethene (ug/L) 70 <250 <100 <100 <500 NA <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 NA <1.0 NS <1.0 <1.0 1,2-Dichloropropane (ug/L) 0.56 <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <7.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 Methyl tert-butyl ether (MTBE) (ug/I) 200 NA NA NA NA NA NA <1.0 NA NA NA .=1 NA NA NA NA NS NA NA Trichloroethene (ug/L) 2.8 <250 <100 <100 <500 <250 21 13 13.8 <500 21 30.6 <1.0 <1.0 <1.0 <1.0 NS 1.8 <1.0 Tetrachloroethene (ug/L) 0.7 13,000 7,200 12,000 12,000 11,000 12,000 8,090 8,800 6,900 2,020 16,800 <1.0 <1.0 <1.0 <1.0 NS 30.4 1.8 1,1,2,2-Tetrachloroethane (ug/L) none <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 Toluene (ug/L) 1,000 NA NA NA NA NA <1.0 <1.0 <1.0 NA <1.0 <1 NA NA NA NA NS <1.0 NA 1,1,1-Trichloroethane (ug/L) 200 <250 <100 <100 <500 <250 <1.0 <1.0 <1.0 <500 <1.0 <1 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 1,1,2-Tdchloroethane (ug/L) none <250 <100 <100 <500 <250 11 8.3 12 <500 13 24.4 <1.0 <1.0 <1.0 <1.0 NS <1.0 <1.0 Xylenes, Total (ug/L) 530 NA NA NA NA NA <2.0 <2.0 <2.0 NA NA <1 NA NA NA NA NS <2.0 NA Total VOCs Detected (ug/L) 13,000 7,200 12,000 12,000 11,000 1 12,038 1 8,119 1 8,835 6,900 2,073 16,882 0 0 0 0 0 32 2 Notes: Compounds detected above the North Carolina 2L S A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed NS denotes well not sampled Monitoring wells MW-16, MW-19, MW-24, MW-25 and MW-26 were destroyed during site construction activities. Shallow gw Hist summary.xls Page 3 of 6 Revised 11/18/01 TABLE 4 Historical Groundwater Analytical Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-13 MW-17 Sample Date: 6/25/93 A 7/9/96 A 7/9/96 B 1/21/99 B 10/25M B 3/22/00 B 9/13/00 B 8/21/01 B 7/10/96 A 7110/96 B 10/07/96 B 12/02/98 B 10/26/99 B 3/22100 B 9113/00 B 317/01 B 8121/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA Ethylbenzene (ug/L) 29 NA NA NA NA <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA Methylene Chloride (ug/L) 5.0 <1.0 <5.0 1.5 <5,0 <5.0 <5.0 <5.0 <5 <250 <50 <10 <5.0 <5.0 <5.0 <500 <5.0 <50 Chloroform (ug/L) 0.19 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 31 <1.0 1.6 1 <100 4 55 Chloromethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <1.0 <1.0 <1.0 <100 <1.0 <50 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 140 6.4 12.6 16.7 <100 17 <50 1,1-Dichloroethane (ug/L) 700 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 - 10 <1.0 <1.0 <1.0 <100 <1.0 <50 1,2-Dichloroethane (ug/L) 0.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <1.0 <1.0 <1.0 <100 <1.0 <50 1,1-Dichloroethene (ug/L) 7.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <1.0 <1.0 <1.0 <100 2 <50 cis-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1 NA NA NA 59 95 130 <100 160 165 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1 NA NA NA <1.0 <1.0 11.2 <100 2 <50 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <1.0 6.0 <1.0 <100 <1.0 <50 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA NA NA NA <1 NA NA NA NA NA NA NA NA <50 Trichloroethene (ug/L) 2.8 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 6.2 <1 780 620 120 490 960 1,060 1,150 1330 565 Tetrachloroethene (ug/L) 1 <1.0 1 <1.0 <1.0 <1.0 <1.0 36 <1 5,200 5,200 28 2,600 4,880 5,680 4,090 4,770 2,340 1,1,2,2-Tetrachloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <11.0 <1.0 <1.0 <1.0 <1.0 <50 Toluene (ug/L) 1,000 NA NA NA NA <1.0 <1.0 NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA 1,1,1-Trichloroethane(ug/L) 200 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <50 <50 <10 <1.0 <1.0 <1.0 <100 <1.0 <50 1,1,2-Trichloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <t 450 <50 <10 <1.0 <11.0 <11.0 <100 2 <50 Xylenes, Total (ug/L) NA NA NA NA <2.0 <2.0 NA NA NA NA NA <2.0 <2.0 <2.0 NA NA NA Total VOCs Detected (ug/L) 0 1 2 0 0 I 0 42 0 5,980 1 5,820 1 319 1 3,155 1 5,955 1 6,899 1 5,240 1 6,287 1 3,115 Sample Location: MW-15 MW-16 MW-20 MW-21 Sample Date: 7/10/96 A 7/10196 B 12/02/98 B 10/27/99 B 3/22/00 B 9/13/00 B 317/01 B 8/21/01 B 7/10196 A 7/10/96 B 10/7/96 A 10/7/96 B 01/21/99 B 10/26/99 B 3/22/00 B 9113/00 B 10/7196 A 1017/96 B 12/62/98 B 10/26/99 B 3/22/00 B 9/13100 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA <1.0 <1.0 NA NA NA <1.0 <1.0 <1.0 NA Ethylbenzene (ug/L) 29 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA <1.0 <1.0 NA NA NA =1.0 <1.0 <1.0 NA Methylene Chloride (ug/L) 5.0 <25 <1.0 <5.0 <5.0 <5.0 <50.0 <5.0 <50 <5.0 1.4 <2.5 <1.0 <5.0 <5.0 <5.0 <5.0 <2.5 <1.0 <5.0 <5.0 <5.0 <50.0 Chloroform (ug/L) 0.19 28 27 24 16.4 18.7 22 17 25 <1.0 <1.0 <0.50 <0.19 <1.0 <1.0 <1.0 <1.0 <0.50 <0.19 <1.0 <1.0 <1.0 <10.0 Chloromethane (ug/L) none <5.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <10 <1.0 <1.0 <0.50 <2.0 <1.0 <1.0 <1.0 <1.0 <0.50 <2.0 <1.0 <1.0 <1.0 <10.0 Carbon Tetrachloride (ug/L) 0.3 29 24 13 7.7 7.6 <10.0 7 <10 <1.0 <1.0 <0.50 <0.30 <1.0 <1.0 <1.0 <1.0 <0.50 <0.30 <1.0 <1.0 <1.0 <10.0 1,1-Dichloroethane (ug/L) 700 <5.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <10.0 1,2-Dichloroethane (ug/L) 0.38 <5.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <11.0 <1.0 <1.0 <10.0 1,1-Dichloroethene (ug/L) 7.0 <5.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <10.0 cis-1,2-Dichloroethene (ug/L) 70 7.7 NA 16 18.9 30.5 19 24 22 <1.0 NA NA NA <1.0 <1.0 <1.0 <1.0 NA NA 1.9 <1.0 1.1 <10.0 Vans-1,2-Dichloroethene (ug/L) 70 <5.0 NA <1.0 <1.0 <1.0 <10.0 <1.0 <10 <1.0 NA NA NA <1.0 <1.0 <1.0 <1.0 NA NA <1.0 <1.0 <1.0 <10.0 - i oropropane (ug/L) 0.56 < <1.0 <1.0 <7.0 <1.0 <10.0 <1.0 <10 <1.0 <1.0 <0.50 <0.20 <1.0 <1.0 <1.0 <1.0 <0.50 <0.20 <1.0 <1.0 <1.0 <10.0 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA NA NA NA <10 NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trichloroethene (ug/L) 2.8 130 95 221 280 468 538 404 345 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 11 <1.0 39 40.9 39 46 Tetrachloroethene (ug/L) 0.7 42 33 39 20.8 87 40 30 11 <1.0 <1.0 <0.50 <0.70 <1.0 <1.0 <1.0 9.0 98 7.7 310 252 333 289 1,1,2,2-Tetrachioroethane (ug/L) none <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <10.0 Toluene (ug/L) 1,000 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA <1.0 <1.0 NA NA NA <1.0 <1.0 <1.0 NA 1,1,1-Trichloroethane (ug/L) 200 <5.0 <11.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <10.0 1,1,2-Trchloroethane (ug/L) none <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <10.0 Xylenes, Total (ug/L) 530 NA NA 1 <2.0 <2.0 <2.0 NA NA NA NA NA NA NA NA <2.0 <2.0 NA NA NA <2.0 <2.0 1 <2.0 NA Total VOCs Detected (ug/L) 237 179 313 344 612 619 482 403 0 1 0 0 0 0 0 9 109 8 351 293 373 335 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed NS denotes well not sampled Monitoring wells MW-16, MW-19, MW-24, MW-25 and MW-26 were destroyed during site construction activities. Shallow gw Hist summary.xls Page 4 of 6 Revised 11/18/01 TABLE 4 Historical Groundwater Analytical Data Summary - Shallow Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: MW-18 MW-19 MW-23 MW-24 MW-25 Sample Date: 1017/96A 10/07/96 B 12/02/98 B 10/26/99 B 3/22100 B 9/13/00 B 317/01 B 8/21/01 B 10/7196 A 108196 B 1017/96 A 10/7/96 B 12/02/98 B 10/25/99 B 3/22/00 B 9/13/00 8 96-/01 B 8120/01 B 10/7/96 A 10I//96 B 10/7/96 A 1 1017/96 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA <1.0 1.1 <1.0 NA NA NA NA NA NA NA Ethylbenzene (ug/L) 29 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA <1.0 2.5 <1.0 NA NA NA NA NA NA NA Methylene Chloride (ug/L) 5.0 <250 <100 <5.0 <5.0 <5.0 <500 <5.0 <250 <2.5 <1.0 9.3 6.5 <5.0 <5.0 <5.0 <5.0 <5.0 <1.0 <0.05 <1.0 <2.5 <1.0 Chloroform (ug/L) 0.19 <50 <19 <1.0 <1.0 <1.0 <100 1 <50 <0.50 <0.19 4.7 3.8 <1.0 <1.0 <1.0 <1.0 <11.0 <1.0 <0.50 <0.19 <0.50 <0.19 Chloromethane (ug/L) none <50 <200 <1.0 <11.0 <1.0 <100 <1.0 <50 <0.50 <2.0 <0.50 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <2.0 <0.50 <2.0 Carbon Tetrachloride (ug/L) 0.3 <50 <30 <1.0 <1.0 <1.0 <100 <1.0 <50 <0.50 <0.30 <0.50 <0.30 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <0.30 <0.50 <0.30 1,1-Dichloroethane (ug/L) 700 <50 <100 <1.0 <1.0 <1.0 <100 2 <50 <0.50 <1.0 <0.50 <11.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 1,2-Dichloroethane (ug/L) 0.38 <50 <100 <1.0 <1.0 <1.0 <100 <1.0 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <11.0 <0.50 <1.0 1,1-Dichloroethene (ug/L) 7.0 <50 <100 <1.0 <1.0 <1.0 <100 <1.0 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 cis-1,2-Dichloroethene (ug/L) 70 NA NA 18 15.6 18.3 <100 27 <50 NA NA NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA Vans-1,2-Dichloroethene (ug/L) 70 NA NA <1.0 <1.0 <1.0 <100 <1.0 <50 NA NA NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA 1,2-Dichloropropane (ug/L) 0.56 <50 <20 <1.0 12.0 <1.0 <100 <1.0 <50 <0.50 <0.20 <0.50 <0.20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <0.20 <0.50 <0.20 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA NA NA NA <50 NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trichloroethene (ug/L) 2.8 440 380 680 730 740 830 1,060 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <11.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 Tetrachloroethene (ug/L) 1 2,100 1,600 2,100 2,100 2,450 1,940 2,200 940 <0.50 <0.70 <0.50 <0.70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <0.70 <0.50 <0.70 1,1,2,2-Tetrachloroethane (ug/L) none <50 <100 <1.0 <1.0 <1.0 <100 <1.0 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 Toluene (ug/L) 1,000 NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA <1.0 <1.0 <1.0 NA <1.0 <1.0 NA NA NA NA 1,1,1-Trichloroethane (ug/L) 200 <50 <100 <1.0 <1.0 <1.0 <100 <11.0 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 1,1,2-Trichloroethane (ug/L) none <50 <100 <1.0 <1.0 <1.0 <100 2 <50 <0.50 <1.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 Xylenes, Total (ug/L) NA NA <2.0 <2.0 <2.0 NA NA NA NA NA NA NA <2.0 <2.0 <2.0 NA NA NA NA NA NA NA Total VOCs Detected (ug/L) 2,540 1 1,980 1 2,798 1 2.858 1 3,208 2,770 1 3,292 940 0 0 14 10 0 4 0 0 0 0 L 0 0 o 0 Sample Location: MW-22 LMP-1 LMP-2 Sample Date: 10/7/96 A 10I7/96 B 12/02/98 B . 10/25/99 B : 3/22/00 B 9/13/00 B 3/7/01 B 8/20/01 B 01/21/99 B 10/26/99 B 3/22/00 B 9/14/00 B 3M-0 B 8/21/01 8 01/21/99 8 10/26/99 B 3/22100 B 9/14/00 B 3/7/01 B 8/21/01 B Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1.0 <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA Ethylbenzene (ug/L) 29 NA NA <1.0 <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA Methylene Chloride (ug/L) 5.0 <120 <10 <5.0 <5.0 <5.0 <250 <5.0 <250 <5.0 <5.0 <5.0 <100 <5.0 <50 <5.0 <5.0 <5.0 <25 <5.0 <1.0 Chloroform (ug/L) 0.19 <25 <11.9 <1.0 <1.0 <1.0 <50 2 <50 <1.0 <1.0 <1.0 <20 <1.0 11 <1.0 1.4 <1.0 <5.0 <1.0 1.7 Chloromethane (ug/L) none <25 <20 <1.0 <1.0 <1.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <25 <0.30 <1.0 2.5 3 <50 5 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 1,1-Dichloroethane (ug/L) 700 <25 <10 <1.0 <1.0 <1.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 1,2-Dichloroethane (ug/L) 0.38 <25 <10 <1.0 <1.0 <11.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 1 <10 <1.0 1.7 <1.0 <5.0 <1.0 <1.0 1,1-Dichloroethene (ug/L) 7.0 <25 <10 <1.0 <1.0 <1.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 cis-1,2-Dichloroethene (ug/L) 70 NA NA 31.4 50.3 48.6 <50 85 <50 47.8 21.2 12.6 <20 11 65 10 10.9 9.9 7 10 13.8 trans-1,2-Dichloroethene (ug/L) 70 NA NA <1.0 <1.0 <1.0 <50 4 <50 1.4 <1.0 1.6 <20 1 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 1,2-Dichloropropane (ug/L) 0.56 <25 2.8 <1.0 <1.0 <1.0 <50 <1.0 <50 1,370 1,560 <1.0 1,370 830 596 238 316 <1.0 292 382 260 Methyl tert-butyl ether (MTBE) (ug/1) 200 NA NA NA NA NA NA NA <50 <1.0 <1.0 NA NA NA <1 <1.0 NA NA NA NA <1.0 Trichloroethene(ug/L) 2.8 62 53 110 146 170 195 365 180 <1.0 <1.0 34.7 120 33 67 <1.0 <1.0 8.4 26.5 12 6.9 Tetrachloroethene (ug/L) 0.7 1500 910 1,240 1,680 1,640 1,720 2,040 1,790 192 145 913 586 215 81 25.4 45.5 80.6 65.5 86 51.8 1,1,2,2-Tetrachloroethane (ug/L) none <25 <10 <1.0 <1.0 <1.0 <50.0 <1.0 <50 <1.0 <1.0 <1.0 <20.0 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 Toluene (ug/L) 1,000 NA NA <1.0 <1.0 <1.0 NA 0.0 NA NA <1.0 <11.0 NA NA NA NA <1.0 <1.0 NA NA NA 1,1,1-Tdchloroethane (ug/L) 200 <25 <10 <1.0 <1.0 <1.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 <1.0 <1'o <5.0 <1.0 <1.0 1,1,2-Trichloroethane (ug/L) none <25 <10 <1.0 <1.0 <1.0 <50 <1.0 <50 <1.0 <1.0 <1.0 <20 <1.0 <10 <1.0 8.3 <1.0 <5.0 <1.0 <1.0 Xylenes, Total (ug/L) 530 NA NA <2.0 1 <2.0 <2.0 NA NA NA NA <2.0 <2.0 NA NA NA NA <2.0 <2.0 NA NA NA Total VOCs Detected (ug/L) 1,562 966 1,381 1,879 1 1,862 1 1.915 1 2,491 1 1,970 1 1,611 1 1,726 962 2,076 1 1,091 819 1 273 1 384 99 391 1 490 324 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed NS denotes well not sampled Monitoring wells MW-16, MW-19, MW-24, MW-25 and MW-26 were destroyed during site construction activities. Shallow gw Hist summary.xls Page 5 of 6 Revised 11/18/01 TABLE 5 August 2001 Groundwater Analysis Data Summary - Deep Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: DW-3 DW-4 DW-5 DW-7 DW-8 DW-13 DW-14 DW-15 DMP-1 DMP-2 DMP DMP-4 BMW-2 HVDP-10 HVDP-15 HVDP-22 HVDP-27 HVDP-29 Sample Date: 8/22/01 B 8/22101 B 8/21/01 B 8/21/01 B 8/21/01 B 8121101 B 8120/01 B 8/20/01 B 8/23/01 8/21/01 B 8/21/01 8121/01 B 8/22/01 8/23/01 8/23/01 8/23/01 8/23/01 8/23/01 Analysis Method: EPA601/6021 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 Analyte NCAC 2L Benzene (ug/L) 1.0 3.2 NA NA NA NA NA NA NA NA NA NA NA <1.0 NA NA NA NA NA Bromoform (ug/L) 0.19 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1,2-Dichlorobenzene (ug/L) none <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1.3-Dichlorobenzene (ug/L) none <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 Methylene Chloride (ug/L) 5.0 <1.0 <2500 <250 <25 <250 <10 <50 <10 <2500 <50 <25 <25000 <5.0 <250 <250 <250 <250 <250 Chloroform (ug/L) 0.19 4.5 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 Chloromethane (ug/L) none <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 Carbon Tetrachloride (ug/L) 0.3 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1, 1 -Dichloroethane (ug/L) 700 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1,2-Dichloroethane (ug/L) 0.38 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 Vinyl chloride (ug/L) 0.015 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1, 1 -Dichloroethene (ug/L) 7.0 1.7 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 45.2 <50 <50 <50 <50 <50 cis-1,2-Dichloroethene (ug/L) 70 6.4 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 13,100 <50 2,800 215 600 <50 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1,2-Dichloropropane (ug/L) 0.56 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 Ethylbenzene (ug/L) 29 <1.0 NA NA NA NA NA <10 <10 NA NA NA NA <1.0 NA NA NA NA NA Trichloroethene (ug/L) 2.8 19.5 <500 655 <5 <50 32 116 92 <500 1,480 21.5 <5000 2,300 1,180 72,700 2,030 1,350 75 Tetrachloroethene (ug/L) 0.7 62,000 <500 <50 226 1,100 447 455 469 <500 150 144 <5000 30,400 755 1,440 2,150 2,930 780 Toluene (ug/L) 1,000 11 NA NA NA NA NA NA NA NA NA NA NA 1.9 NA NA NA NA NA 1,1,1-Trichloroethane (ug/L) 200 <1.0 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 <1.0 <50 <50 <50 <50 <50 1,1,2-Trichloroethane (ug/L) none 22.3 <500 <50 <5 <50 <10 <10 <10 <500 <50 <5 <5000 8.9 <50 <50 <50 <50 <50 Xylenes, Total (ug/L) 530 <1.0 NA NA NA NA NA NA NA NA I NA NA NA <1.0 NA NA NA NA NA Total VOCs (ug/L) 62,069 0 655 226 1,100 479 571 561 0 1,630 166 0 45,856 1,935 76,940 4,395 4,880 855 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. B - indicates samples collected by IT Corporation of North Carolina, Inc. (formerly Fluor Daniel GTI, Inc.) NA denotes compound not analyzed Table 5.xls Page 1 of 1 Revised: 11/28/01 TABLE 6 Historical Groundwater Analysis Data Summary - Deep Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: DW-1 DW-2 DW-3 7/22/94 A 7/12/96 A 12/2/98 B 10/27/99 B 3/23/00 B 977/00 B 10/19/00 B 722/94 A 7/11/96 A 12/2/98 B 1028/99 B 3/22/00 B 9/7/00 B 7/22194 A 7/10/96 A 7/10196 B 12/2198 B 10/28/99 B 3/23/00 B W7/00 B 10/18/00 B 3/8/01 B 8/22/01 B Sample Date: Analysis Method: EPA 601 EPA601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601/60 EPA 601/60 EPA 601 EPA 601/60. Anatyte NCAC 2L Benzene (ug/L) 1.0 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA <1.0 <10.0 <1.0 NA NA NA NA <1.0 <5,000 <1.0 <1.0 <1,000 NA 3.2 Bromoform (ug/L) 0.19 <1.0 <1.0 <1.0 1.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 1,2-Dichlorobenzene (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 41.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 1.3-Dichlorobenzene (ug/L) none <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 0.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 Methylene Chloride (ug/L) 5.0 1.2 14 <5.0 <5.0 <5.0 <5.0 <50 <1.0 <12 <5.0 <50.0 <5.0 <5.0 <100 <12,000 <1,000 50 <25,000 <5.0 <5.0 <5000 <250 <1.0 Chloroform (ug/L) 0.19 6.1 <1.0 <1.0 1.2 <1.0 <1.0 <10 3.2 <2.5 <1.0 <10.0 <1.0 0.0 <100 <2,500 <1,000 4 <5,000 1.4 <1.0 0,000 3 4.5 Chloromethane (ug/L) none <1.0 0.0 0.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 0.0 0.0 <100 <2,500 <2,000 <1.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1.0 <1.0 0.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 <1.0 <1.0 <100 <2,500 0,000 <1.0 <5,000 <1.0 <1.0 <1,000 0.0 <1.0 1. 1 -Dichloroethane (ug/L) 700 <1.0 <1.0 0.0 <1.0 16.6 <1.0 <10 <1.0 <2.5 <1.0 <10.0 3.5 <1.0 <100 <2,500 <1,000 0.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 1,2-Dichlorcethane (ug/L) 0.38 <1.0 0.0 <1.0 <1.0 <1.0 <1.0 <10 0.0 <2.5 <1.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 0,000 <1.0 <1.0 Vinyl chloride (ug/L) 0.015 <1.0 <1.0 0.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 0.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 0.0 <1,000 <1.0 <1.0 1. 1 -Dichloroethene (ug/L) 7.0 1.6 4.6 <1.0 9.4 <1.0 26 <10 23 <2.5 <1.0 <10.0 <1.0 5.2 <100 <2,500 <1,000 3 <5,000 <1.0 <1.0 <1,000 <1.0 1.7 cis-1.2-Dichloroethene (ug/L) 70 NA NA 29.2 10.5 7.6 0.0 <10 NA NA 0.0 <10.0 <1.0 <1.0 NA NA NA 24.5 <5,000 7.9 <1.0 <1,000 4 6.4 trans-1,2-Dichloroethene (ug/L) 70 NA NA <1.0 <1.0 <1.0 <1.0 <10 NA NA <1.0 <10.0 <1.0 <1.0 NA NA NA 1.4 <5,000 <1.0 <1.0 <1,000 0.0 <1.0 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 0,000 <1.0 <1.0 Ethylbenzene (ug/L) 29 NA <1.0 <1.0 <1.0 0.0 NA NA NA NA <1.0 <10.0 0.0 NA NA NA NA <1.0 <5,000 <1.0 NA <1,000 NA <1.0 Trichloroethene (ug/L) 2.8 <1.0 3 52.1 8.6 11.2 <1.0 <10 0.0 <2.5 1 <10.0 <1.0 <1.0 <100 <2,500 <1,000 56.1 <5,000 32.5 <1.0 <1,000 25 19.5 Tetrachloroethene (ug/L) 0.7 31 59 182 170 358 464 298 55 110 126 150 107 43.8 19,000 82,000 60,000 66,000 174,000 73,200 27,600 48,800 48,200 62,000 Toluene (ug/L) 1,000 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA <1.0 <10.0 <1.0 NA NA NA NA <1.0 <5,000 10 NA 0,000 NA 11 1. 1. 1 -Trichloroethane (ug/L) 200 .1.4 4.8 3 4.8 8.8 <1.0 <10 4.4 5.6 0.0 <10.0 2.0 <1.0 <100 <2,500 <1,000 <1.0 <5,000 <1.0 <1.0 <1,000 <1.0 <1.0 1,1,2-Trichloroethane (ug/L) 1Xylenes, none <1.0 <1.0 0.0 <1.0 <1.0 <1.0 <10 <1.0 <2.5 <1.0 <10.0 <1.0 <1.0 <100 <2,500 <1,000 21.1 <5,000 <1.0 <1.0 <1,000 18 22.3 Total u 2 530 NA <2.0 <2.0 <2.0 <2.0 NA NA NA N <2.0 <20.0 NA N 2 1000 <2.0NA <2,000 NA <1.0 Total VOCs u 41 85 266 206 402 490 298 86 116 127 150 113 49 19,000 82,000 60,000 66 4,000 1 73.251 1 27,600 1 48,800 48,250 62,069 Sample Location: DW4 DWS DW-6 DW-10 DW-11 722/94 A 7/11/96 A 12/2/98 B 10/28/99 B 323/00 B 9/14/00 B 10/19/00 B 3/8/01 B 822/01 B 7/15196 A 7/15/96 B 12/2/98 B 1027/99 B 322/00 B 9/13/00 B 317/01 B 821/01 B 7/15/96 A 7/15/96 B 7/15/96 A 7/15/96 B 10/6/96 A 10/6/96 B 10/6196 A 10/6/96 B 122/98 B Sample Date: Analysis Method: EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1.0 <500 <1.0 NA NA NA NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA NA NA <1.0 Bromoform (ug/L) 0.19 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 1,2-Dichlorobenzene (ug/L) none <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 1.3-Dichlorobenzene (ug/L) none <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 151.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 Methylene Chloride (ug/L) 5.0 <100 <1,200 <5.0 <2500 <5.0 <5.0 <250 <5000 <2500 <5 <10 <5.0 <5.0 <5.0 <5.0 <5.0 <250 <5 111!- a <1.0 <5 <1.0 <2.5 <1.0 <2.5 <1.0 <5.0 Chloroform (ug/L) 0.19 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 20 31 20 23.1 25 23 28 <50 1.5 2.6 <1.0 3.1 <0.50 <0.19 7.1 5.4 <1.0 Chloromethane (ug/L) none <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <2.0 <1.0 <2.0 <0.50 <2.0 <0.50 <2.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 100 140 27 73.2 98.3 63 82 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <0.30 <0.50 <0.30 <1.0 1,1-Dichloroethane (ug/L) 700 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 1,2-Dichloroethane (ug/L) 0.38 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 2.7 <10 <1.0 <1.0 5 <1.0 12 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 Vinyl chloride (ug/L) 0.015 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 1,1-Dichloroethene (ug/L) 7.0 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 cis-1,2-Dichloroethene (ug/L) 70 NA NA 97.7 <500 8.7 <1.0 <50 <1000 <500 NA NA 14 22.1 21.8 20 32 <50 NA NA NA NA NA NA NA NA <1.0 trans-1,2-Dichloroethene (ug/L) 70 NA NA <1.0 <500 <1.0 <1.0 <50 <1000 <500 NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <50 NA NA NA NA NA NA NA NA <1.0 1,2-Dichloropropane (ug/L) 0.56 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <0.20 <0.50 <0.20 <1.0 Ethylbenzene (ug/L) 29 NA NA <1.0 <500 <1.0 NA NA <1000 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA NA NA <1.0 Trichloroethene (ug/L) 2.8 <100 <250 64.4 <500 20.4 <1.0 <50 <1000 <500 94 120 78 261 287 449 44 655 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 Tetrachloroethene (ug/L) 0.7 10,000 16,000 8,600 23,900 24,900 <1.0 <50 <1000 <500 19 28 54 52.3 90 70 45 <50 1.1 1.6 <1.0 1.9 <0.50 <0.70 <0.50 <0.70 <1.0 Toluene (ug/L) 1,000 NA NA <1.0 <500 <1.0 NA NA <1000 NA NA NA <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA NA NA <1.0 lAl-Trichloroethane (ug/L) 200 <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 1,1,2-Tdchloroethane(ug/L) none <100 <250 <1.0 <500 <1.0 <1.0 <50 <1000 <500 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <1.0 <1.0 <1.0 <0.50 <1.0 <0.50 <1.0 <1.0 X lenes, Total u /L 530 NA NA <2.0 <1,000 <2.0 NA NA <1000 NA NA NA 1 <2.0 <2.0 <2.0 NA NA NA NA NA NA NA NA NA NA NA <2.0 Total VOCs (ug/L) 10,000 16,000 1 8.762 1 23.900 1 24,929 0 0 0 0 236 1 319 1 193 432 527 625 243 1 655 3 4 0 5 0 0 7 5 0 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. formerly Fluor Daniel GTI, Inc. NA = denotes compound not analyzed NS = indicates location not sampled Deep monitoring wells DW-6, DW-9, DW-10 and DW-11 were destroyed during site construction activities. deep gw Hist summery-ds 1 of 3 Revised 11/1W1 TABLE 6 Historical Groundwater Analysis Data Summary - Deep Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: Sample Date: Analysis Method: DW-7 OW-8 DWG DW-14 7/15/96 A EPA 601 7/15/96 B EPA 601 122/98 B EPA 601 10/26/99 B EPA 601 3123/00 B EPA 601 9/12/00 B EPA 601 3/7101 B EPA 601 8/21101 B EPA 601 7/15/96 A EPA 601 7/15/96 B EPA 601 12/2/98 B EPA 601 10/26/99 B EPA 601 323/00 B EPA 601 9/13/00 B EPA 601 318/01 B EPA 601 8/21/01 B EPA 601 7/15/96 A EPA 601 7/15/96 B EPA 601 10/6/96 A EPA 601 10/6/96 B EPA 601 12/2/98 B EPA 601 10/25/99 B EPA 601 3/21/00 B EPA 601 9/13/00 B EPA 601 3/6/01 B EPA 601 820/01 B EPA 601 Analyte NCAC 2L Benzene (ug/L) Bromoform (ug/L) 1,2-Dichlorobenzene (ug/L) 1.3-Dichlorobenzene (ug/L) Methylene Chloride (ug/L) Chloroform (ug/L) Chloromethane (ug/L) Carbon Tetrachloride (ug/L) 1. 1 -Dichloroethane (ug/L) 1,2-Dichloroethane (ug/L) Vinyl chloride (ug/L) 1. 1 -Dichlorcethene (ug/L) cis-1,2-Dichloroethene (ug/L) trans-1.2-Dichloroethene (ug/L) 1,2-Dichloropropane (ug/L) Ethylbenzene (ug/L) Trichloroethene (ug/L) Tetrachloroethene (ug/L) Toluene (ug/L) 1. 1. 1 -Trichloroethane (ug/L) 1,1,2-Trichloroethane (ug/L) X lenes, Total u /L Total VOCs (ug/L) 1.0 0.19 none none 5.0 0.19 none 0.3 700 0.38 0.015 7.0 70 70 0.56 29 2.8 0.7 1,000 200 none 530 ::i;:w. NA <5 <5 <5 <25 <5 <5 <5 <5 <5 <5 <5 NA NA <5 NA <5 230 NA <5 <5 NA 230 NA <1.0 <1.0 <1.0 <1.0 2.9 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA 2.1 NA 1.0 180 NA <1.0 <1.0 NA 185 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 10 205 <1.0 <1.0 <1.0 <2.0 215 <10.0 <10.0 <10.0 <10.0 <50.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 15 <10.0 <10.0 221 <10.0 <10.0 <10.0 <20.0 236 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2 270 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA <1.0 295 NA <1.0 <1.0 NA NA <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 7 NA 2 240 NA <1.0 <1.0 NA NA <5 <5 <5 <25 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 NA <5 226 NA <5 <5 NA NA <100 <100 <100 <500 <100 <100 <100 <100 <100 <100 <100 NA NA <100 NA 630 3,700 NA <100 <100 NA NA <100 <100 <100 <100 <100 <200 <100 <100 <100 <100 <100 NA NA <100 NA 440 2,600 NA <100 <100 NA <50.0 <50.0 <50.0 <50.0 <250 <50.0 <50.0 <50.0 <50.0 <50.0 <50.0 <50.0 280 <50.0 <50.0 <50.0 - 380 1,620 <50.0 <50.0 <50.0 <100 <1,0 <1,0 <1.0 <1.0 <5.0 5.6 <1.0 19.7 <1,0 <1.0 <1.0 <1.0 530 2.1 1.1 <1.0 1,300 4,290 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5.0 3 <1.0 28.1 <1.0 <1.0 <1.0 <1.0 445 22.8 <1.0 <1.0 1,360 5,150 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 420 <1.0 <1.0 NA 1,380 4,020 NA <1.0 <1.0 NA NA <1.0 <1.0 <1.0 <5.0 12 <1.0 20 <1.0 3 <1.0 <1.0 320 1 <1.0 NA 545 1,340 NA <1.0 2 NA NA <50 <50 <50 <250 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 NA <50 1,100 NA <50 <50 NA NA <1.0 <1.0 <1.0 <5 3.4 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 <1.0 <1.0 <1.0 4.5 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA <1.0 NA <1.0 3.4 NA <1.0 <1.0 NA NA <0.50 <0.50 <0.50 5.3 1.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA <0.50 NA <0.50 <0.50 NA <0.50 <0.50 NA NA <1.0 <1.0 <1.0 6, 1.E <2.0 <0.30 <1.0 <1.0 <1,0 <1.0 NA NA <0.20 NA <1.0 <0.70 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5 <1.0 <1.0 <1.0 <1.0 <1.0 1.1 <1.0 3.1 <1.0 <1.0 <1.0 84.5 304 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 13.3 83.7 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA 93 252 NA <1.0 <1.0 NA NA <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2 <1.0 <1.0 NA 57 204 NA <1.0 <1.0 NA NA NA <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 .116 455 NA <10 <10 NA 272 295 249 226 4,330 3,040 2,280 6,149 7,009 5,820 2,243 1,100 3 8 7 7 , 0 393 971 345 1 263 571 Sample Location: DW-12 DW-13 DMP4 BMIN-1 Sample Date: 10/6/96 A 10/6/96 B 12/2/98 B 1025/99 B 321/00 B 9/13100 B 1025/99 B 321/00 B 9/13/00 B Y7/01 B 821/01 B 121/99 B 1025/99 B 321/00 B 9/13/00 B 316/01 B 821/01 B 1028/99 B 323100 B 9/8/00 B 10/18/00 B 3/8101 B Analysis Method: EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601/60 EPA 601/60 EPA 601 Analyte NCAC 2L Benzene (ug/L) 1.0 NA NA <1.0 <1.0 <1.0 NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NS-DRY <1.0 <20.0 <20.0 NA Bromoform (ug/L) 0.19 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1,2-Dichlorobenzene (ug/L) none <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1.3-Dichlorobenzene (ug/L) none <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 Methylene Chloride (ug/L) 5.0 <2.5 <1.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <50 <50.0 <5.0 <5.0 <5.0 <5.0 <5000 NS-DRY <5.0 <100 <100 <5.0 Chloroform (ug/L) 0.19 4.1 4.2 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 5.7 3.0 <1.0 10 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 Chloromethane (ug/L) none <0.50 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <0.50 <0.030 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1 <10 <10.0 17.1 27.1 <1.0 18 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1,1-Dichloroethane (ug/L) 700 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1,2-Dichloroethane (ug/L) 0.38 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 Vinyl chloride (ug/L) 0.015 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1. 1 -Dichloroethene (ug/L) 7.0 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 1.2 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 cis-1,2-Dichlorcethene (ug/L) 70 NA NA <1.0 <1.0 <1.0 <1.0 5.0 5.6 <1.0 20 <10 259 275 280 460 350 <5000 NS-DRY <1.0 <20.0 <20.0 5 trans-1,2-Dichloroethene (ug/L) 70 NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 2.8 31.2 <1.0 30 <5000 NS-DRY 4.0 <20.0 <20.0 2 1,2-Dichloropropane (ug/L) 0.56 <0.50 <0.20 <1.0 <1.0, <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 Ethylbenzene (ug/L) 29 NA NA <1.0 <1.0 <1.0 NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NS-DRY <1.0 <20.0 <20.0 NA Trichloroethene (ug/L) 2.8 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 21.7 31.7 44 89 32 <10.0 1,180 1,080 1,340 1,250 <5000 NS-DRY 39.9 52 28 43 Tetrachlorcethene (ug/L) 0.7 <0.50 <0.70 <1.0 <1.0 <1.0 <1.0 421 720 680 850 447 3460 4,500 5,600 4,090 2,940 <5000 NS-DRY 1,670 802 380 728 Toluene (ug/L) 1.000 NA NA <1.0 <1.0 <1.0 NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NS-DRY <1.0 <20.0 <20.0 NA 1,1,1-Trichloroethane(ug/L) 200 <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 <1.0 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 1.1,2-Trchloroethane (ug/L) none <0.50 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10 <10.0 <1.0 <1.0 <1.0 2 <5000 NS-DRY <1.0 <20.0 <20.0 <1.0 X lenes, Total u /L 530 NA NA I <2.0 1 <2.0 <2.0 NA <2.0 <2.0 1 NA NA NA NA <2.0 <2.0 NA NA NA NS-DRY <2.0 <40.0 <40.0 NA Total VOCs u /L 4 4 0 0 0 0 448 757 724 960 479 3,719 5,983 7,021 5,890 4,600 0 0 1,714 854 408 778 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. formerly Fluor Daniel GTI, Inc. NA = denotes compound not analyzed NS = indicates location not sampled Deep monitoring wells DW-6, DW-9, DW-10 and DW-11 were destroyed during site construction activities. deep gw Hist summary.ads 2 of 3 Redsed 11/1 &Ot TABLE 6 Historical Groundwater Analysis Data Summary - Deep Wells W. P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Location: DW-15 DMP-1 DMP-2 DMP.3 PT -ID 10/25/99 B 3/21/00 B 9/13/00 B 3/6/01 B 8/20/01 B 1/21/99 B 10/27/99 B 3122/00 B 9/13/00 B 3/7/01 B 8/23/01 1/21199 B 10/27/99 B 3/22/00 B 9/13/00 B 317101 B 8/21/01 B 1/21/99 B 10/26/99 B 3/25/0o B 9/12/00 B 3/7/01 B 8/21/01 8/29/97 B 3/23/00 B 9/8/00 B Sample Date: Analysis Method: EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 001 EPA 601 EPA 601 EPA 601 EPA 8260A EPA 601/602 EPA 601 Analyte NCAC 2L Benzene (ug/L) 1.0 <1.0 <1.0 NA NA NA 1.6 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA <1,0 <1.0 NA NA NA 7.8 <1.0 NA Bromoform (ug/L) 0.19 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 1,2-Dichlorobenzene (ug/L) none <1.0 <1.0 <1.0 <1.0 <10 <1.0 4.0 7.5 <1.0 6 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <10 <1.0 <100 1.3-Dichlorobenzene (ug/L) none <1.0 <1.0 <1.0 <1.0 <10 <1.0 1.1 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <10 <1.0 <100 Methylene Chloride (ug/L) 5.0 <5 <5.0 <5.0 <5.0 <10 <5.0 8.0 12.1 <5.0 <1.0 <2500 <5.0 <5.0 <5.0 <5.0 <5.0 <50 <25.0 <5,0 <5.0 <5.0 <5.0 <25 <5 <5.0 <500 Chloroform (ug/L) 0.19 <1.0 <1.0 <1.0 <1.0 <10 6.0 <1.0 <1.0 <1.0 <1.0 <500 7.5 3.5 4.4 <1.0 4 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 7.6 1.7 <100 Chloromethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <10 <1.0 <100 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 8.2 12.4 <1.0 4 <50 <5.0 <1,0 <1.0 <1.0 <1.0 <5 <5.0 4.4 <100 1,1-Dichloroethane (ug/L) 700 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 1,2-Dichloroethane (ug/L) 0.38 <1.0 <1.0 <1.0 <1.0 <10 <1.0 8.4 14.6 <1.0 11 <500 <5.0 2.8 <1.0 <1.0 2 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 Vinyl chloride (ug/L) 0.015 1.3 <1.0 <1.0 <1.0 <10 <1.0 3.6 6.4 <1.0 2 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <10 <1.0 <100 1. 1 -Dichloroethene (ug/L) 7.0 <1.0 <1.0 <1.0 <1.0 <10 <1.0 3.5 4.8 <1.0 4 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 5.4 <1.0 <100 cis-1,2-Dichloroethene (ug/L) 70 2.7 3.9 <1.0 4 <10 1,520 3,440 4,390 2,200 2,280 <500 24.5 6.8 22.5 <1.0 13 <50 <5.0 10.4 9.6 <1.0 9 <5 3,900 1.4 <100 trans-1,2-Dichloroethene (ug/L) 70 <7.0 <1.0 <1.0 <1.0 <10 24.0 16.9 18.9 <1.0 10 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 1,2-Dichloropropane (ug/L) 0.56 <1.0 <1.0 <1.0 <1.0 <10 28.0 28.6 <1.0 <1.0 17 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 Ethylbenzene (ug/L) 29 <1.0 <1.0 NA NA <10 NA <1.0 <1.0 NA <1.0 NA NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA <5.0 <1.0 NA 3 Trichloroethene (ug/L) 2.8 71.7 110 164 112 92 <1.0 355 390 300 320 <500 <5.0 505 678 865 875 1,480 <5.0 90 85 68 55 21.5 36 1,950 210 Tetrachloroethene (ug/L) 0.7 398 995 688 476 469 60.7 60 395 270 190 <500 254 329 525 421 275 150 580 562 799 474 289 144 1,900 5,800 3,510 Toluene (ug/L) 1,000 <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA NA <1.0 <1.0 NA NA NA 5.8 <1.0 NA 1,1,1-Trichloroethane (ug/L) 200 <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 <1.0 <100 1,1,2-Trichloroethane (ug/L) none <1.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <1.0 <1.0 <500 <5.0 <1.0 <1.0 <1.0 <1.0 <50 <5.0 <1.0 <1.0 <1.0 <1.0 <5 <5.0 1.2 <100 X lenes, Total u /L 530 <2.0 <2.0 NA NA NA NA <2.0 <2.0 NA NA NA NA <2.0 <2.0 NA NA NA NA <2.0 <2.0 NA NA NA <5.0 <2.0 NA Total VOCs u /L 474 1,109 852 592 561 1,639 3.931 5,239 2,770 2,840 0 2B6 855 1,242 1,286 1.173 1,630 580 662 894 542 353 166 5,863 7,759 3,720 Sample Location: BMW-2 13MW-3 BMW-4 PT-2113 PT-3D -PT-4D PT-5D 10/28/99 B 3/23/00 B 9/7/00 B 10/18/00 B 3/8/01 B 8/22/01 10/26/99 B 321/00 B 9/12/00 B 10/25/99 B 3/21/00 B 9/13/00 B 3/6/01 B 8/29/97 B 1 3/23/00 B 9/8/00 B 8/29/97 B 3/23/00 B 9/9/00 B 8/29/97 B 3/23/00 B 9/9/00 B 8/29/97 B 3/23/00 B 9/8/00 B Sample Date: Analysis Method: EPA 601 EPA 601 EPA 601/60 EPA 601/60 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 601 EPA 8260A JEPA 601/60 EPA 601/60 EPA 8260A EPA 601/60 EPA 601 EPA 8260A EPA 601/60 EPA 601 EPA 8260A EPA 601/60 EPA 601/602 Analyte NCAC 2L Benzene (ug/L) 1.0 <500 <1.0 <1,000 <1,000 NA <1.0 <10.0 <1.0 NA <1.0 <1.0 NA NA <25 <1.0 <100 <25 <1.0 NA <500 <1.0 NA <500 150 800 Bromoform (ug/L) 0.19 <500 <1.0 <1,000 <1,000 <1.0 <1.0 <10.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <25 <1.0 <100 <25 <1.0 <100 <500 <1.0 <500 <500 <1.0 <500 1,2-Dichlorobenzene (ug/L) none <500 <1.0 <1,000 <1,000 <1.0 <1.0 <10.0 <1.0 <1.0 <1.0 0.0 <1.0 <1.0 <50 0.0 <100 <50 <1.0 <100 <1,000 <1.0 <500 <1,000 0.0 <500 1.3-Dichlorobenzene (ug/L) none <500 <1.0 <1,000 <1,000 0.0 0.0 <10.0 0.0 <1.0 <1.0 0.0 <1.0 <1.0 <50 0.0 <100 <50 <1.0 <100 <1,000 0.0 <500 <1,000 <1.0 <500 Methylene Chloride (ug/L) 5.0 <2500 <5.0 <5,000 <5,000 <5.0 <5.0 <50.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <25 <5.0 <500 <25 <5.0 <500 <500 <5.0 <500 <500 <5.0 <2,500 Chloroform (ug/L) 0.19 <500 <1.0 0,000 0,000 <1.0 <1.0 <10.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <25 <1.0 <100 26 26.5 <100 <500 11.1 <500 <500 2.3 <500 Chloromethane (ug/L) none <500 <1.0 <1,000 <1,000 0.0 0.0 <10.0 <1.0 0.0 <1.0 <1.0 <1.0 <1.0 <50 <1.0 <100 <25 <1.0 <100 0,000 <1.0 <500 <1,000 <1.0 <500 Carbon Tetrachloride (ug/L) 0.3 <500 <1.0 <1,000 <1,000 0.0 <1.0 <10.0 0.0 0.0 0.0 <1.0 <1.0 <1.0 <25 1.8 <100 82 149 <100 <500 15 <500 <500 <1.0 <500 1. 1 -Dichloroethane (ug/L) 700 <500 <1.0 0,000 0,000 1 <1.0 <10.0 <1.0 0.0 0.0 <1.0 <1.0 0.0 <25 <1.0 <100 <25 <1.0 <100 <500 <1.0 <500 <500 <1.0 <500 1,2-Dichloroethane (ug/L) 0.38 <500 <1.0 0,000 <1,000 <1.0 <1.0 <10.0 <1.0 <1.0 0.0 <1.0 <1.0 0.0 <25 <1.0 <100 <25 <1.0 <100 <500 0.0 <500 <500 27.5 <500 Vinyl chloride (ug/L) 0.015 <500 <1.0 <1,000 <1,000 0.0 <1.0 <10.0 0.0 <1.0 <1.0 0.0 0.0 <1.0 <50 <1.0 <100 <50 <1.0 <100 <1,000 0.0 <500 <1,000 <1.0 <500 1,1-Dichloroethene (ug/L) 7.0 <500 19.7 <1,000 0,000 21 45.2 <10.0 <1.0 <1.0 0.0 <1.0 <1.0 <1.0 <25 <1.0 <100 <25 <1.0 <100 <500 3.8 <500 <500 <1.0 <500 cis-1,2-Dichloroethene (ug/L) 70 <500 <1.0 <1,000 <1,000 0.0 13,100 <10.0 <1.0 0.0 <1.0 <1.0 0.0 11 <25 <1.0 <100 <25 21.6 <100 1,100 1,750 1,150 <500 25.2 <500 trans-1,2-Dichloroethene (ug/L) 70 <500 4.9 <1,000 <1,000 8 <1.0 <10.0 <1.0 <1.0 5.5 <1.0 0.0 <1.0 <25 <1.0 <100 <25 <1.0 <100 <500 11.4 <500 <500 0.0 <500 1,2-Dichloropropane (ug/L) 0.56 <500 <1.0 <1,000 <1,000 <1.0 <1.0 18 11.1 0.0 <1.0 <1.0 <1.0 <1.0 <25 <1.0 <100 <25 <1.0 <100 <500 <1.0 <500 <500 <1.0 <500 Ethylbenzene (ug/L) 29 <500 <1.0 <1,000 <1,000 NA <1.0 <10.0 0.0 NA 0.0 <1.0 NA NA <25 <1.0 <100 <25 <1.0 NA <500 <1.0 NA <500 7.6 <500 Trichloroethene (ug/L) 2.8 <500 70.1 0,000 0,000 440 2,300 <10.0 3.2 <1.0 118 8.1 84 79 <25 25 <100 4,800 5,200 6,390 9,200 16,400 15,400 <500 68 <500 Tetrachloroethene (ug/L) 0.7 48,800 110,000 45,700 53,500 33,200 30,400 260 448 278 607 98.4 244 234 440 5,510 2,440 230 500 140 930 2,150 1,350 17,000 37,000 18,300 Toluene (ug/L) 1,000 <500 3 <1,000 0,000 NA 1.9 <10.0 4 NA 0.0 <1.0 NA NA <25 <1.0 <100 <25 <1.0 NA <500 <1.0 NA <500 410 600 1.1,1-Trichloroethane (ug/L) 200 <500 4.1 0,000 <1,000 4 <1.0 <10.0 <1.0 <1.0 0.0 <1.0 <1.0 <1.0 <25 <1.0 <100 <25 <1.0 <100 <500 <1.0 <500 <500 <1.0 <500 1,1,2-Trichloroethane (ug/L) none <500 <1.0 <1,000 <1.000 0.0 8.9 <10.0 <1.0 0.0 <1.0 <1.0 <1.0 <1.0 <25 1.8 <100 <25 <1.0 <100 <500 2.2 <500 <500 16.6 <500 X lenes, Total (ug/L) 530 0,000 1.1 <2,000 <2,000 NA <1.0 <20.0 <2.0 NA <2.0 <2.0 NA NA <25 <2.0 <200 <25 1 <2.0 NA 1 <500 <2.0 NA <500 90.5 <1,000 Total VOCs (ug/L)48,800 110,103 45,700 53,500 33,674 45,856 278 1 466 278 731 1 107 328 324 440 5,539 2,440 5,138 5,897 6,530 11,230 20,344 17,900 17,000 37,798 1 19,700 Notes: Compounds detected above the North Carolina 2L Standard are shown in bold. A - indicates samples collected by Mortensen Engineering, Inc. B - indicates samples collected by IT Corporation of North Carolina, Inc. formerly Fluor Daniel GTI, Inc. NA = denotes compound not analyzed NS = indicates location not sampled Deep monitoring wells DW-6, DW-9, DW-10 and DW-11 were destroyed during site construction activities. deep gw Hist summery.bs 303 Revised 11/18/01 TABLE 7 Summary of Soil Analytical Results Source Area (Phase III) W.P. Ballard Property Greensboro, NC Sample ID Carbon Chloroform cis-1,2- Napthalene 1,1,1,2- 1,1,2,2- Tetrachloro- 1,1,2- Trichloro- tetrachloride Dichloro- Tetrachloro- Tetrachloro- ethene Trichloro- ethane (sample depth) (mg/kg) (mg/kg) ethene (mg/kg) (mg/kg) ethane (mg/kg) ethane (mg/kg) (mg/kg) ethane (mg/kg) (mg/kg) GP-7-10-01-1 (10-11 ft) 0.4044 3.382 <0.1471 0.4412 2.515 0.1691 2537.0 0.7794 0.8162 GP-7-10-01-2 ( 8-10 ft) <0.0020 <0.0020 <0.0020 <0.0049 <0.0020 <0.0020 0.0028 <0.0020 <0.0020 GP-7-10-01-3 ( 10-12 ft) <0.0024 <0.0024 0.0149 <0.0061 <0.0024 <0.0024 0.0051 <0.0024 <0.0024 NOTES: 1) Samples analyzed using USEPA SW846 Method 8260 2) GP-7-10-01-1 obtained at the location of the former PCE AST., 3) GP-7-10-01-2 obtained from the PCE/Petroleum hydrocarbon commingled plume. 4) GP-7-10-01-3 obtained from the location of the former gasoline UST. 5) Analysis performed by Test America. 6) Sampled collected on July 10, 2001 using Geoprobe direct push method. TABLE 8 Summary of Soil Vapor Monitoring Results August 23, 2001 W.P. Ballard and Downgradient Properties Greensboro, North Carolina Sample Identification Compound SVMP-1 SVMP-2 SVMP-3 SVMP-4 SVMP-5 SVMP-6 SVMP-7 SVMP-8 SVMP-9 SVMP-10 SVMP-11 SVMP-12 Bromodichloromethane <0.005 <0.005 <0.005 <0.005 <O.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 Bromoform <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 2-Chloroethylvinylether NA NA NA NA NA NA NA NA NA NA NS NA Dibromochloromelhane <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 Dichlorodifluoromelhane NA NA NA NA NA NA NA NA NA NA NS <0.005 Trichlorofluoromethane <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 Vinyl Chloride <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 NS <3 Chloromethane <1 <1 <1 <1 <1 <1 <1 <1 <1 <t NS <1 Bromomethane NA NA NA NA NA NA NA NA NA NA NS NA Chloroelhane NA NA NA NA NA NA NA NA NA NA NS NA 1,1-Dichloroethane <0.001 <0.001 <0.01 0.021 <0.001 <0.001 <0.001 0.077 0.083 0.074 NS <0.001 1-1,2-Dichloroethene <0.01 <0.01 <0.01 <0.01 0.016 <0.01 <0.01 0.034 0.03 0.041 NS 0.085 1,2-Dichloropropane <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 NS <0.01 1,1,2-Trichloroethene <.005 <.005 <.005 <.005 <.005 <.005 <.005 <,005 <,005 <,005 NS <.005 1,2-Dibromoethane NA NA NA NA NA NA NA NA NA NA NS NA Chlorobenzene <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 NS <0.07 c-1,3-Dichloropropene <0.01 <0.01 <0.01 <0.01 <0.01 0.013 <0.01 <0.01 <0.01 <0.01 NS <0.01 t-1,3-Dichloropropene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 NS <0.01 1.1,2,2-Telrachloroethane <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 1,2-Dichlorobenzene <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 NS <0.07 1,3-Dichlorobenzene <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 NS <0.07 1,4-Dichlorobenzene <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 NS <0.07 1,2,4-Trichlorobenzene NA NA NA NA NA NA NA NA NA NA NS NA Methylene Chloride <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 NS <2 Chloroform 0.021 0.013 0.009 0.03 0.23 0.26 0.081 0.23 0.008 <0.005 NS 0.009 Carbon tetrachloride 0.021 <0.005 <0.005 <0.005 0.006 0.006 0.007 O.OD7 <0.005 <0.005 NS <0.005 Tetrachloroelhene 280 24 8.4 25 800 710 1300 1100 14 20 NS 440 Trichloroethene 0.051 0.029 0.02 0.17 0.46 0.97 0.36 0.7 0.069 0.84 NS 3.5 1,1,1-Trichloroethane 0.034 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS <0.005 1,2-Dichloroethane <0.01 <0.01 <0.01 <0.01 <0.01 0.056 <0.01 <0.01 <0.01 <0.01 NS <0.01 c-1,2-Dichloroethene 0.02 0.031 0.018 0.35 0.18 1.5 0.058 0.8 0.05 4.1 NS 4.6 1,1-Dichloroelhene 2.7 <0.01 <0.01 <0.01 <0.01 I <0.01 I <0.01 1 0.02 0.022 1 <0.01 I NS <.01 Sum of Detected Compounds 282.85 24.07 8.45 25.57 800.89 1 712.81 1 1,300.51 1 1,101.87 14.26 1 25.06 1 0.00 t448.19 Notes: Concntrations are in ppm-v (parts per million by volume). Baseline Soil vapor analysis performed by EPA Method TO3 for the Method 601 compound list. Detected compounds shown in bold. NS Denotes well not sampled. NA: Denotes compound not analyzed for Tables 8 & 9.xls Page 1 of 1 Revised: 11/2et01 TABLE 9 Summary of Historic Soil Vapor Monitoring Results W.P. Ballard and Downgradient Properties Greensboro, North Carolina Location SVMP-1 SVMP-2 SVMP-3 Dale Sampled 1/20/99 1/27/99 11/19/99 8/23101 1/20/99 1/27/99 11/19/99 8/23/01 1120/99 1/27/99 11/19/99 8/23101 Compound ppm-v ppm-v ppm-v ppm-v ppm-v PP m-v PPm-v PPm-v PPm-v PPm-v PPm-v PPm-v Bromodichloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Bromofonn <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 2-Chloroethylvinylether <0.5 <250 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Dibromochloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 0.005 <0.005 Dichlorodifluoromethane <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA Trichlorofluoromethane <0.5 <250 0.006 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Vinyl Chloride <0.5 <250 <3 <3 <0.5 <250 <3 <3 <0.5 <250 <3 <3 Chloromethane <0.5 <250 <1 <1 <0.5 <250 1 <1 <0.5 <250 6.6 <1 Bromomethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA Chloroethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA 1,1-Dichloroethane <0.5 <250 <0.01 <0.001 <0.5 <250 <0.01 <0.001 <0.5 <250 <0.01 <0.01 t-1,2-Dichloroethene <0.5 <250 <0.1 <0.01 <0.5 <250 0.2 <0.01 <0.5 <250 <0.1 <0.01 1,2-Dichloropropane <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2-Trichloroethane <0.5 <250 0.281 <.005 <0.5 <250 1.14 <.005 2.2 <250 3.064 <.005 1,2-Dibromoethane <0.5 <260 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Chlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 c-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 t-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2,2-Tetrachloroethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 1,2-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,3-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,4-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,2,4-Trichlorobenzene <0.5 <250 <0.2 NA <0.5 <250 <0.2 NA <0.5 <250 <0.2 NA Methylene Chloride <0.5 <250 <2 <2 <0.5 <250 <2 <2 <0.5 <250 <2 <2 Chloroform <0.5 <250 0.141 0.021 <0.5 <250 0.291 0.013 1.9 <250 0.423 0.009 Carbon tetrachloride <0.5 <250 0.034 0.021 <0.5 <250 0.04 <0.005 <0.5 <250 0.054 <0.005 Tetrachloroethene 5,300 8,600 1530.03 280 7,500 57,000 2180.56 24 8,300 13,000 2105.56 8.4 Trichloroethene 5.2 <250 0.954 0.051 7.8 <250 1.376 0.029 20 <250 3.218 0.02 1,1,1-Trichloroethane <0.5 <250 0.005 0.034 <0.5 <250 0.006 <0.005 <0.5 <250 0.011 <0.005 1,2-Dichloroethane <0.5 <250 <0.01 <0.01 <0.5 <250 -<0.01 <0.01 <0.5 <250 <0.01 <0.01 c-1,2-Dichloroethene <0.5 <250 <0.1 0.02 1.7 <250 <0.1 0.031 4.1 <250 1.4 0.018 1,1-Dichloroethene <0.5 <250 <0.01 2.7 <0.5 <250 <0.01 <0.01 1 <250 <0.01 <0.01 Sum of Detected EPA 601 Compounds 5,305.20 8.600.00 1.531.45 282.85 7,509.50 57,000.00 2,184.61 24.07 8,329.20 13,000.00 2,120.34 8.45 Baseline Total VOC Concentration" 6,952.60 282.85 32 254.75 24.07 10 664.60 8.45 -1. I uu io 1 u0%u Notes: Soil vapor analysis performed by EPA Method TO3 for the Method 601 compound list. " Detected compounds shown in bold. "The Baseline Total VOC Concentration is the average of the two modified total VOC concentrallons NS Denotes well not sampled. NA: Denotes compound not analyzed for ppm-v Denotes parts per million by volume. Page 1 of 4 TABLE 9 Summary of Historic Soil Vapor Monitoring Results W.P. Ballard and Downgradient Properties r,roanchnrn Nnrfh Cnrnnnn Location SVMP-4 SVMP-5 SVMP-6 Date 1120/99 1/27/99 11/19/99 8/23101 1/20/99 2/2/99 11/19/99 8/23/01 1120/99 1/27/99 11/19/99 8123/01 Compound ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v PP PPm-v Bromodichloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 0.008 <0.005 <0.5 <250 <0.005 <0.005 Bromoform <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 2-Chloroethylvinylether <0.5 <250 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Dibromochloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Dichlorodifluoromethane <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA Trichiorofluoromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Vinyl Chloride <0.5 <250 <3 <3 <0.5 <250 <3 <3 <0.5 <250 <3 <3 Chloromethane <0.5 <250 7.3 <1 <0.5 <250 7.1 <1 <0.5 <250 <1 - <1 Bromomethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA Chloroethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA 1,1-Dichloroelhane <0.5 <250 0.08 0.021 <0.5 <250 <0.01 <0.001 <0.5 <250 <0.01 <0.001 t-1,2-Dichloroethene <0.5 <250 0.1 <0.01 <0.5 <250 0.1 0.016 <0.5 <250 0.2 <0.01 1,2-Dichloropropane <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2-Trichloroethane <0.5 <250 0.765 <.005 3.2 <250 3.687 <.005 <0.5 <260 1.545 <.005 1,2-Dibromoethane <0.5 <250 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Chlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 0-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 0.013 t-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2,2-Tetrachloroethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 1,2-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,3-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,4-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,2,4-Trichlorobenzene <0.5 <250 <0.2 NA <0.5 <250 <0.2 NA <0.5 <250 <0.2 NA Methylene Chloride <0.5 <250 <2 <2 <0.5 <250 <2 <2 <0.5 <250 <2 <2 Chloroform <0.5 <250 0.194 0.03 2.9 <250 0.635 0.23 2.1 <250 0.455 0.26 Carbon tetrachloride <0.5 <250 0.017 <0.005 <0.5 <250 0.06 0.006 0.5 <250 0.084 0.006 Tetrachloroethene 5,900 6,500 805.59 25 8,600 48,000 2,890.87 800 8,700.00 17,000 2,791.58 710 Trichloroelhene 24 <250 3.123 0.17 23 <250 3.534 0.46 22 <250 3.29 0.97 1,1,1-Trichloroethane <0.5 <250 <0.005 <0.005 <0.5 <250 0.017 <0.005 <0.5 <250 0.012 <0.005 1,2-Dichloroethene 1.5 <250 0.92 <0.01 <0.5 <250 0.26 <0.01 <0.5 <250 0.05 0.056 c-1,2-Dichloroethene 6.6 <250 1.6 0.35 6.6 <250 1.9 0.18 4.8 <250 1.4 1.5 1,1-Dichloroethene 0. 1 <250 0.05 <0.01 1.5 1 <250 0.08 <0.01 1.6 1 <260 1 <0.01 <0.01 Sum of Detected EPA 601 Compounds 5,931.68 6,500.00 819.74 25.57 8.636.20 1 48,000.00 1 2,908.25 800.89 8,731.00 1 17.000.00 1 2,798.62 712.81 Baseline Total VOC Concentration" 6 215.84 25.57 28 318.10 800.89 12 865.50 712.81 uvo "Ful anmrwo pcuvuncv uy crn mcuwu i va Mw um NICIlIVU vV l GVrrlpuVnu OSr. Detected compounds shown in bold. The Baseline Total VOC Concentration Is the average of the two modified total VOC concentrations detected during the Initial baseline sampling events. NS Denotes well not sampled. NA: Denotes compound not analyzed for ppm-v Denotes parts per million by volume. Page 2 of 4 -- ` -- j---J --' TABLE 9 Summary of Historic Soil Vapor Monitoring Results W.P. Ballard and Downgradient Properties Greensboro, North Carolina Location SVMP-7 SVMP-8 SVMP-9 Date 1/20/99 1/27/99 11/19/99 8/23/01 1/20199 1/27/99 11/19/99 8/23/01 1/20/99 1/27/99 11/19/99 8/23/01 Compound ppm-v ppm-v ppm-v ppm-v ppm-v PP m-v PPm-v PPm-v PPm-v PPm-v PPm-v PPm-v Bromodichloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Bromoform <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 2-Chloroethylvinylether <0.5 <250 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Dibromochloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Dichlorodi0uoromethane <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA <0.5 <250 <0.005 NA Trichlorofluoromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 Vinyl Chloride <0.5 <250 <3 <3 <0.5 <250 <3 <3 <0.5 <250 <3 <3 Chloromethane <0.5 <250 <1 <1 <0.5 <250 1.1 <1 <0.5 <250 1.2 <1 Bromomethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA Chloroethane <0.5 <250 <1 NA <0.5 <250 <1 NA <0.5 <250 <1 NA 1,1-Dichloroethane <0.5 <250 0.01 <0.001 <0.5 <250 0.14 0.077 <0.5 <250 0.04 0.083 t-1,2-Dichloroethene <0.5 <250 0.4 <0.01 <0.5 <250 0.4 0.034 <0.5 <250 0.1 0.03 1,2-Dichloropropane <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2-Trichloroethane 2 <250 2.766 <.005 <0.5 <250 1.369 <.005 <0.5 <250 0.123 <.005 1,2-Dibromoethane <0.5 <250 NA NA <0.5 <250 NA NA <0.5 <250 NA NA Chlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 0.2 <0.07 c-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 t-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 <0.01 1,1,2,2-Tetrachloroethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 <0.005 1.2-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,3-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,4-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 <0.07 1,2,4-Trichlorobenzene <0.5 <250 <0.2 NA <0.5 <250 <0.2 NA <0.1 <250 <0.2 NA Methylene Chloride <0.5 <250 <2 <2 <0,5 <250 <2 <2 <0.5 <250 <2 <2 Chloroform 3 <250 0.546 0.081 <0.5 <250 0.182 0.23 <0.5 <250 0.183 0.008 Carbon tetrachloride 0.77 <250 0.141 0.007 <0.5 <250 0.048 0.007 <0.5 <250 0.005 <0.005 Tetrachloroethene 12,000 35,000 3782.39 1300 6,600 5,600 1956.24 1100 6,400 5,500 819.35 14 Trichloroethene 37 <250 7.338 0.36 2 <250 1.663 0.7 61 <250 12.14 0.069 1,1,1-Trichloroethane <0.5 <250 0.066 <0.005 <0.5 <250 0.023 <0.005 <0.5 <250 <0.005 <0.005 1,2-Dichloroethane <0.5 <250 <0.01 <0.01 <0.5 <250 0.11 <0.01 1.2 <250 0.69 <0.01 0-1,2-Dichloroethene 14 <250 3.6 0.058 0.65 <250 1.3 0.8 100 <250 24.1 0.05 1,1-Dichloroethene 2.2 <250 0.25 <0.01 <0.5 <250 0.25 0.02 <0.5 <250 0.9 0.022 Sum of Detected EPA 601 Compounds 12.058.97 35,000.00 3,797.51 1,300.51 6.603.05 .9,600.00 1,962.83 1,101.87 6,562.20 5,500.00 859.03 14.26 Baseline Total VOC Concentr 23 529.49 1,300.51 6,101.53 1,101.87 6 031.10 14.26 nu�w. odsdnnd uun vdpur dndryws penurrneu ny Cr-H meuluu I Ud ror me memo0 Qu7 compound llsr. Detected compounds shown In bold. "The Baseline Total VOC Concentration is the average of the two modified total VOC concentrations detected during the initial baseline sampling events. NS Denotes well not sampled. NA: Denotes compound not analyzed for ppm-v Denotes parts per million by volume. Page 3 of 4 TABLE 9 Summary of Historic Soil Vapor Monitoring Results W.P. Ballard and Downgradient Properties r..o-t,- N-4h Location SVMP-10 SVMP-11 SVMP-12 Date 1/20/99 1127/99 11/19/99 8/23/01 1/20/99 1/27199 11/19/99 8/23/O1 1120199 1/27/99 11119/99 11/2-1/01 Compound ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v ppm-v PP m v ppm-v Bromodichloromethane <0.5 _ <250 <0.005 <0.005 <0.5 <250 <0.005 NS <0.5 <250 <0.005 <0.005 Bromofonn <0.5 ' <250 <0.005 <0.005 <0.5 <250 <0.005 NS <0.5 <250 <0.005 <0.005 2-Chloroethylvinylether <0.5 <250 NA NA <0.5 <250 NA NS <0.5 <250 NA NA Dibromochloromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 NS <0.5 <250 <0.005 <0.005 Dichlorodifluoromethane <0.5 <250 <0.005 NA <0.5 <250 <0.005 NS <0.5 <250 <0.005 NA Trichlorofluoromethane <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 NS <0.5 <250 <0.005 <0.005 Vinyl Chloride <0.5 <250 <3 <3 <0.5 <250 <3 NS <0.5 <250 <3 <3 Chloromethane <0.5 <250 <1 <1 <0.5 <250 <1 NS <0.5 <250 <1 <1 Bromomethane <0.5 <250 <1 NA <0.5 <250 <1 NS <0.5 <250 <t NA Chloroethane <0.5 <250 <1 NA <0.5 <250 <1 NS <0.5 <250 <1 NA 1,1-Dichloroethane <0.5 <250 0.05 0.074 <0.5 <250 0.06 NS <0.5 <250 0.01 <0.001 t-1,2-Dichloroethene <0.5 <250 5.7 0.041 <0.5 <250 2 NS <0.5 <250 0.9 0.086 1,2-Dichloropropane <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 NS <0.5 <250 <0.01 <0.01 1,1,2-Trichloroethane <0.5 <250 1.71 <,005 1.5 <250 8.363 NS 4 <250 6.074 <,005 1,2-Dibromoethane <0.5 <250 NA NA <0.5 <250 NA NS <0.5 <250 NA NA Chlorobenzene <0.5 <250 0.28 <0.07 <0.5 <250 <0.07 NS <0.5 <250 <0.07 <0.07 0-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 NS <0.5 <250 <0.01 <0.01 t-1,3-Dichloropropene <0.5 <250 <0.01 <0.01 <0.5 <250 <0.01 NS <0.5 <250 <0.01 <0.01 1,1,2,2-Tetrachloroethene <0.5 <250 <0.005 <0.005 <0.5 <250 <0.005 NS <0.5 <250 <0.005 <0.005 1,2-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 NS <0.5 <250 <0.07 <0.07 1,3-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 NS <0.5 <250 <0.07 <0.07 1,4-Dichlorobenzene <0.5 <250 <0.07 <0.07 <0.5 <250 <0.07 NS <0.5 <250 <0.07 <0.07 1,2,4-Trichlorobenzene <0.5 <250 <0.2 NA <0.5 <250 <0.2 NS <0.5 <250 <0.2 NA Methylene Chloride <0.5 <250 <2 <2 <0.5 <250 <2 NS <0.5 <250 <2 <2 Chloroform <0.5 <250 0.159 <0.005 <0.5 <250 0.128 NS 1.5 <250 0.32 0.009 Carbon tetrachloride <0.5 <250 0.015 <0.005 1.1 <250 0.284 NS 1.3 <250 0.33 <0.005 Tetrachloroethene 5,900 11,000 783.44 20 11,000 55,000 4040.74 NS 12,000 43,000 3371.61 440 Trichloroethene 200 <250 22.69 0.84 120 <250 14.47 NS 80 <250 9.569 3.5 1. 1. 1 -Trichloroethane <0.5 <250 <0.005 <0.005 2.6 <250 0.684 NS 1.1 <250 0.326 <0.005 1,2-Dichloroethane <0.5 <250 0.17 <0.01 <0.5 <250 0.12 NS <0.5 <250 <0.01 <0.01 c-1,2-Dichloroethene 620 <250 213.3 4.1 300 <250 57.96 NS 130 <250 27.09 4.6 1,1-Dichloroethene <0.5 <250 3.86 <0.01 <0.5 <250 1.59 NS 6.7 <250 1.17 <.01 bum of ee e Compounds 6,720.00 11,000.00 1,031.27 25.06 11.425.20 55,000.00 4,126.40 NS 43,000.00 3,417.40 Baseline Total VOC Concentr 8 860.00 25.06 33 212.60 NS +12,223.60 27 611.80 7448.19 448.19 pores: oasenne aon vapor anatysis perrormea oy tt-A mernoa i ua ror the memos tint compound test. Detected compounds shown in bold. The Baseline Total VOC Concentration /s the average of the two modified total VOC concentrations detected during the initial baseline sampling events. NS Denotes well not sampled. NA: Denotes compound not analyzed for ppm-v Denotes parts per million by volume. Page 4 of 4 TABLE 10 Phase I Full -Scale Application - Injection Data Summary In Situ Chemical Oxidation Using Sodim Permanganate W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project #107636 Injection Date Injection Point ID Maximum Attainable Depth Feet Volume of 5% Injected Gallons Comments O6/18/01 IP-34 48 278 Backflow during injection at 30 ft O6/19/01 IP-46 48 245 O6/20/01 IP-44 54 315 06/20/01 IP-36 50 280 06/21/01 IP-49 42 245 Backflow during 35-40 ft injection 06/21/01 IP-47 45 245 06/21/01 IP-50 40 175 Backflow during 30-35 ft injection 06/21/01 IP-45 48 210 Backflow at MW-8 O6/22/01 IP-51 "43 245 06/22/01 IP-58 37 205 Backflow at MW-17 O6/25/01 IP-54 32 120 Backflow at 20-30 ft intervals 06/25/01 IP-61 40 270 O6/25/01 IP-56 40 250 - 06/25/01 IP-60 34 190 06/26/01 IP-62 32 175 O6/26/01 IP-65 31 175 O6/26/01 IP-72 40 205 06/26/01 IP-63 35 175 O6/26/01 IP-67 30 140 Skipped 20ft interval due to backflow 06/26/01 IP-78 34 130 Skipped 15ft interval 06/27/01 IP-81 50 245 O6/27/01 IP-86 50 280 06/27/01 IP-73 34 175 Backflow during injection at 20ft interval 06/27/01 IP-88 46 240 06/28/01 IP-77 45 210 06/28/01 IP-70 45 210 Backflow during 40ft interval 06/28/01 IP-101 55 275 Backflow during 40-45 ft intervals 06/28/01 IP-104 62 350 06/29/01 IP-102 55 280 06/29/01 IP-96 62 350 07/02/01 IP-94 65 385 07/02/01 IP-105 58 315 07/02/01 IP-92 64 385 07/02/01 IP-98 64 350 07/02/01 LMP-1 W 54 200 07/02/01 LMP-2N 64 240 07/02/01 DW-8S 40 200 07/02/01 DW-8N 32 200 07/03/01 IP-64 32 175 07/03/01 IP-57 43 245 07/03/01 IP-55 37 210 07/03/01 IP-100 73 420 Backflow during 15ft interval 07/04/01 IP-97 57 315 07/04/01 IP-103 64 350 Backflow during 60ft interval 07/04/01 IP-85 40 245 07/04/01 IP-82 50 280 07/04/01 IP-69 35 210 07/05/01 IP-89 37 210 Backflow during 35ft interval 07/05/01 DW-13E 50 200 07/05/01 DW-13W 41 100 Backflow in asphalt cracks Tables 10 & 11.xis Page 1 of 2 Revised: 11/28/01 TABLE 10 Phase I Full -Scale Application - Injection Data Summary In Situ Chemical Oxidation Using Sodim Permanganate W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project #107535 Injection Injection Point Maximum Volume of 5% Date ID Attainable Depth Injected Comments Feet Gallons 07/05/01 DMP-4E 44 100 Backflow in DMP-4 07/05/01 DMP-4W 49 100 07/05/01 MW-17S 50 100 07/05/01 MW-17N 42 100 07/09/01 DMP-4S 48 100 Backflow thru cracks in asphalt 07/09/01 DMP-4N 44 100 Slight backflow in DMP-4 07/09/01 IP-74 40 210 07/09/01 MW-22N 41 100 07/09/01 MW-22S 47 100 07/09/01 DMP-1W 59 240 Backflow at DMP-1 07/09/01 IP-59 43 245 07/10/01 IP-58.5 38 200 07/10/01 IP-62.5 38 200 Backflow atIP-63 07/10/01 IP-68 33 200 07/11/01 IP-53 35 200 07/11/01 IP-60.5NW 32 200 07/11/01 IP-68E 37 240 Totals 14,858 Notes: Actual Volume of 5% NaMnO4 Injected During the Phase I Application is 15,600 Gallons. The observed variation between the actual and measured volumes was due to the method of measurement used, which relied on using the markings on the solution tank to approximate the volume injected at each point. Tables 10 & 11.xis Page 2 of 2 Revised: 11/28/01 TABLE 11 Phase i In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. ms/cm mg/l. °C mV BMW-3 - -- - . _... -_._ 06/18/01 -._..__-_._....._ 862.12 ...---.._.... 13.32 _..........._.._....._50.47- 848.80 -- . 10.84 _..._.._._... 0.824 1.69 18.97 -626 Clear O6/20/01 11.65 850.47 - - - 10.90 ._._._._.._.__._.... .... 0.824 0.81 ---. 18.92 __............ --- .._.._ �63 Clear 06/20/01 9.33 852.79 10.85 0.818 2.47 18.83 -636 Clear _........ -._...._....._..._.._.__._....._..._.... 06/21/Ot _._......._.....__.._.__..._.-..... 8.76 -.--- .._._. ._......-..._..._.....------.. 853.36 10.98 -0.810 1.57 18.84 -634 Clear -- - ........... 0621/01 -............_..._..------..._..._........_.__..._..-- 8.69 _....-... 853.43 --................._._..---._....._........._----_....__ .-- ._...-...-.._.._...-_._..._ 10.75 ---._.._........_....._..- 0.814 ---.-.. 2.24 18.69 -573 - Clear 06/22/01 9.42 852.70 10.91 ...__......_..._........_..._...._.__._._ 0.810 _.............----.._..._.._....._.._._._..---.......----...._......__._.....----.. 0.75 19.02 -633 Clear 06/22/01 9.81 852.31 - 10.81 -- _ 0.815 1.49 19.19 -720 -� Clear _....._....._.._..._......__ 06/25/01 ..............._.............. ............ -....... _._..............._....._..._.._..................9.._..............................- 9.20 852.92 - ------- 10.71 0.805 1.20 19.49 -791 Clear -.._......_.._.__.................. - 06/25/01 -- ._......._...._...- 9.39 ---.._._......._........... .._...._ .... _................_.._ 852.73 ....__..._........_...- ---.......... ........... _........_.__._....__...._.....__...._.._..__._._..._.....__..._._ 10.47 0.806 ...... _......... 0.78 ........... _..._._..... 20.22 -- -806 Clear O6/26/01 - 8.62 853.50 --- --............_...._.__....._..__............ 10.27 - 0.807 --...._.. -- 0.99 - ......__..__.... - 21.07 -......._..-----........ --- -814 Clear 06/27/01 8.79 853.33 10.27 0.807 0.81 20.43 -817 Clear - - 06/28/01 ---..-_.___ ...._.. - 8,71 _... _............ 853.41 -- - 10.55 0.822 0.55 18.94 -765 Clear __. ...................._...._......_..............._.........__.._... ............10.31 0.829 -.........._......._. 3.42 - -... -......__.-.._.._._................_-._..._.._...._._... 19.02 -813 Clear, Slightly fizzy 8.38 �9.31 853.74 10.66 0.890 1.23 18.83 --._._....__.._......_._.. 806 Clear, Slightly fizzy 07/02/01 07/02/01 852.81 _ �10.33 V 0.890 -- - 0.12 - 20.09 -- -837 - Clear ..._07/03/01_.__...-.--- ._... _....._ .................._9!)0__...................._....._........_853:12__..__._._............._1. ................._._._.__.76 U.896..............._....................:2....._.__.........-_....18.92 Clear, Slightly fizzy ...... - -------- -----...._.. 07/04/01 -- ..__._......._.. - -- ----------- 8.66 853.46 11.06 0.905 1.27 ......_.._...- 19.00 --�07._.... --- 762 Clear 07/05/01 - ...._.__. 8.52 ._-. ------..-..._...----.._..._.._............ 853.60 ------._........._....- 0.912 ------7......... - 1.33 ------- 19.18 - ---...._..- -760 Clear, Slightly fizzy 07/09/01 8.B4 853.28 _10.82 11.13 0.914 0.32 18.97 -711 Clear, Slightly fizzy __...._-.-._.........-_._.._.. 07/13/01 .._.._.. _._... _ _.. 8.29 __.....---.._-.. _..... _853.83 NG NG NG NG NG Clear _.__.___..._........_08103/01 .,.- _._........_. _. _. _......... ............_.._......__......__.......-...._..__.._.._.._ 10.35 ..................................._....._.........._....---....__._....._...................._..----- _.__...._._..._.--.-__.............__... 851.77 11.41 - -- ------ 0.762 .._..._...... - ------- -1.07 - - 19.06 - - 855-- -- Clear, Slightly fizzy 08/20/01 10.92 _ 851.20 NG NG ......._...._.._..._...__...._.._......-- NG NG ---.._.....-85-._..__........_.. NG Clear - BMW-4 O6/18/Ot .....860:08- ---- --..._.......?..:90.................._......__._._838.18 17.88._..._.. Clear .._.......-._.._.-__....__.. 07/13/01 __.........I._.- .............. _.__.............-------........_..-_.........._..._..__._.......... 22.59 _..._.__.........._.._10.13 837.49 _ ...- ...------_............ ...-...............__0.3511......._..__...-- NG NG -�,58...._.-._.. NG NG _._--.._...'118 ..._._.._ NG' Clear 08/03/01 _ 22.76 837.32 -----_...._.._............._..__...-----_....... 9.70 0.256 --..__.-..--- 0.44 ---...._.... ---- 17.62 --. ..... 338 Clear 08/20/01 23.47 836.61 NG NG NG NG NG i Clear J D. ...... ............. --....._..._..__......_.._..........__.._._........................_... -----.._.-...._.....__....__....._................._..._._......._._....._..---......................._....---._..............._............_..__..__..............._......._......_..................................._........_......_........._... 06/28/01 13.98 856.85--- 5.71 0.458 0.98 20.47 -._...__............._.._.._. 392 Clear - 06/29/01 _ 14.82 856.01 - _ 5.75 - 0.490 1.20 20.57 411 Clear ........... _..-_..-_.._.... 07/02/01 ..... _...............----.......... _..-.......-- --- -- 14.67 ..._._....._.....__.._................_...._..---.........._......_........._._...----................._........_.........__..................._---._...._._.............._.. 856.16 ___- 5.90 - 0.488 - 0.11 - _ 20.81 - - 303 - Clear 07/03/01 ._._._......04/0- ..._.._...- ._.._... -- 14.92 --....__...........- - - 855.91 -. --- 5.68 0.492 ...... __.._..._........_..... 1.41 ..... ........ _.._._..._.__. 20.49 .......... __ -...._.._.._._..._.._._.._. 342 Clear _ 07/04/Ot 7.58 863.25 --.�_._._............__..._-...._..._.... 6.20 0.501 _..------------_........ 1.39 20.60 335 Clear _ 07/05/01 14.51 856.32 i5.44 -0.514 1.50 20.53 362 Clear 07/09/01 15.40 855.43 5.77- 0.532 1.45 20.60 357 Clear /1/01 ..... 3................._ .-_......._.._......---...-..._..__._...._....................._......_......_. 13.12 857.71 ._.__._.._......._.._._.-............._....-..._ NG N-..._.._... Pink_........_.. 08/03/01 15.78 855.05 10.47 ..............._......._..._......._.........._ 1.003 0.89 .- 20.58 -_._........._._G._..... _.._......._............ Purple 0820/01 17.54 853.29 �NG NG-� _ NG _ NG _445 NG Purpla Tables 10 811.x1s Page 1 of 7 Revised: 1128101 TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. mS/Cm mg/L °C my DMP-2 ...._. ....... _-06/18101 .. _ 872.13 _ 14.21 .................__........_........._......._...... 857.92 _............_..._._......._.._........._............_....................._.... 6.08 0.145 5.57 19.80 300 Clear 06/29/01 14.20 857.93 6.05 _........._................................_._..._..........................._...._......................__......._._...._..................__...._....._.-...................._.-.. 0.170 4.76 19.86 385 Clear 07/03/01 14.82 857.31 5.74 0.167 3.33 19.73 373 Clear 07/04/01 14.79 857.34 6.41 _07/05/01. ..........................__............................. 14.79........................................_857.34..................................`:78................................_0;553..............................5.05 ... ......._...---..........__......._.__.-_. . 19.97 _. 355 Clear 07/09/01 15.55 _ ✓ 856.58 5.80 0.190 3.34..........................19.67..........................................379............................ Clear 07/13/01 15.50 - - 856.63 -- NG -- __-NG V4WV NG NG W- NG ` Clear 08/03/01 .. _ 84.51 -- 7.09 - - --__� _, _ 295 Clear 08/20101 31.84840. .. ... ..._..........-........._._._....- - 6.40..........................__--................._...__...._1 ........ 52..._.- -.._..25.1.� - _ _ .-_........ . 101 ...__._..... -Clear DMP-3 06/18/01 862.18 10.16 852.02 6.32 0.111 6.87 17.63 350 Clear 06/22/Ot _._..._....._.__-._..._..........__........._._._._.__..__....._-......._..-...---._... 8.60 ---._...._..._.._-._.-._.._-.._.-_._... 853.58 6-I. 0.108 7.10 17.68 550 Clear O6/22/Ot _..........................._.........._....._....................._...__....__.._...._...._.........._......._......................._.._.._............._..._._.._._._............._.......8.._.......-- 8.80 853.38 __.....__...-.._....__..._...._...._._.. 6.32 0.110 -.....- - 8.00 ._.._..........7.._ -- 17.74 - -----........-- - 571 Clear. 06/25/01 7.22 854.96 ........_............._09 8.62 --..............._._..-- 0.098 .....-....-....._........._._........_..._.........._....-------- 8.26 18.12 ..._.._.__._._._.. 387 Clear 06/25/01 8.28 853.90 8.57 - _ _ 0.100 _ - 8.39 _ -18.33 _ 377 Clear _........_....__.._._...... 66/26/01 - - - -- ..............._..- -- --._................._.......__..._....__._.._..__......._._.._. 8.72 853.46 _.._._........._....................._.........._..._..._..-....-............_................................-..-_. 8.22 _ 0.104 8.48 - 18.43 399 Clear 06127/Ot.......... ......... ...............811.................... ........................ 853.47...... ........... -..._................................ 9.03 _.............._........-...--...._....._......_....._...................._.._._......... 17.96 375 Clear 06/28/01 8.47 _ ................e:86................................_0:091............ 853.71 7.31 0.106 6.16 17.56 452 Clear 06/28/01 8.54 853.64 6.50 - _ 0.107 - -6.63 - 17.61 - - 434 - Clear 06/29/01 8.57 ........ --853.61 6.41 17.49 444 Clear ......--...._...._..-....._....._.-.._.._.__..- 07/02/01 ................_ .............._..---- -. 8.84 _ ..................................._....__..__._._........................_........_.._. - 853.34 ..T_6_27_...._ 6.40 ---0.110_......___ 0.118 1.64 17.82 373 Clear 07/03/01 - 8.68 853.50 6.10 . .............................. 0.120 ._....._..._...__._........_._ 5.56 ......................- -- 17.84 ......_...............__....__..._.._..._...._... 417 Clear 07/04/01 8.96 853.22 _ 6.15 _ 0.118 - _ 6.25 17.65 477 _ Clear _...._....-.._........ ..---07/05/01.......... _................._...................._.........8..........................................._. 8.71 ......853.47 0;049. 17.64 2t33_ Clear 07/09/Ot 9.59........------852.59....._...._.._.. .................................7:5?..-. ........ _...._. 7_B5 ..... ...................... _... ...... _....._8:42.... .... .... .... ........ ...... -.....--- _ 320 Clear 07/13/01 8.95 853.23 -....__ NG ............_..._0:071.............- NG .._...__6:91..._..._.. -.._._._17.81 -.._ NG ...._...__......._... __. NG Clear 08/03/01 12.96 849.22 10.22 0.173 _NG 5.52 18.73 88 Clear 01/08/00 11.98 -.. _........-850.20.. -..._......._........41 .6 . .._...-......_...-_..... _0.071 ..... .....--- --------- 3.94..._._..... - 27.47- ....-......--..__...41.6__... -Silty DMP 4 06/18/01 862.25 9.68 852.57 _ 6.02 0.080 7.00 15.80 361 7.51 854.74 -- 6.37 - 0.084 - 8.25 y 16.10 _Clear 380 Clear _.__._....-----......_.__..._.....-._....._...---._.._..... 06/27/01 - 7.82 ------..........._................. 854.43 I..._..._.__........._--- 6.22 0.084 7.57 16.63 511 Clear ---._.._.._._..........-._._ O6/28/01 6.21 -- ._..._.......- - 856.04 ._.....__...._--..__.........._.........._-..._....._.._........._....._..0.._ ---- - - 6.12 -................__..-_.._..._._. 0.086 _.__....._...._..- -- 6.00 ._..... -- ....._......_.... 15.31 - ----- ... - 411 Clear 81---..._..._...._.._.. 06/28/01 7.70 _ 854.55 6.18 ................_._.__.........._...- 0.086 -.-............. 7.04 -- --._................._....----......_..._.__...__. 15.56 384 Clear 06/29/01 8.23 854.02 5.94 0.090' _ 8.06 15.22 429 Clear 07/02/.. .................. --..__.....----... .............. ......__._....-- ._......_..__...._ ._.... _..-............._.........._.__.......__...- 07/03/01 0.10 854.15 6.68 ---.._... 6.68 - .._._ . - -- .._._..._ ..... -- _.._.... ._.-._.._. 07/04101 8.00 854.25 6.06 . .._..... 0.103 _.._._........---- -- 6.00 ----....__.._.. 15.68 _. . - .. 432 Clear 07/05/01 8.04 854.21 - 5.56 0.097 _ 5.51 15.86 _ - 435 Clear .......... -._.............._._............. 07/13/01 .... _._..._.._.. _. __.... 6.91 ......_..._.._... 855.34 ...................... _......................_............................_.._.... NG _ NG ... ......_........... _........_.... .........-. NG W ............ ....._._..._....... NG NG Purple 08/03/01 ................... . .....................13:06........................................_849.:1.9.....I......._.................. �: 36................................_4;632................................. .......-..._-......_._.-...-........._.._......_._._.._....._..........._-....._.. �:66........_...............16:56..._........... Purple 08/20/01 11.68 850.57 6.50 2.990 5.08 23.79 _ __735 ' 916 Purple Tables 10 & 11.x1s Page 2 of 7 Revised: 11/28/01 i TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Identification Date Top of Casinng Elevation Feet Depth to Water Feet Groundwater Elevation Feet pH S.U. Specific Conductance mS/Cm Dissolved Oxygen mg/L Temperature °C Oxidation/Reduction Potential (ORP) mV Color ..._......... DW-13._..._..__.. _...._O6/18/01...._................._86. 06/28/01 ......_.................._......._10 13:11................._..........._ 11.10 .._._..... ._...._.._. 850.00 _..._._.._6 23.._..-.._....-_ 6.00 0.099 .... 0.102 - 6:94-- 5.76 - -16.03...___........_-370._..........._..-...._... 15.89 417 Clear Clear 06/28/01 11.13 849.97 5.98 0.102 6.34 15.94 419 Clear 06/29/01 11.53 849.57 6.03 0.110 7.63 15.95 416 Clear ..... _...... _..._- ---- 07/02/01 -' -'- --..- _ 07/03/01 .-._.-__ _ ..._.....-- 11.79 --... ' - --'-- 11.81 849.31 _ ...-._..._._.._-_..-- 849.29 6.38 -._._._...._..__-......-- 6.23 0.109 -- -._... 0.111 1.79 --_..._...-- - - 5.48 16.28 ---._....._....._. 15.98 _ _ 374 --_.... 374 Clear Clear 07/04/01 12.38 848.72 5.91 0.113 4.82 16.33 384 Clear ......................................._.......... 07/05/01 07/09/01 __...._...................................................................._........._......._.........._.........................._.........................._.........._.._._.................................................._....._._._..............._.__............-._........_.........__._......_...-......_.....-.......................--- 07/13/01 11.71 11.54 11.58 849.39 849.56 849.52 5.81 6.23 NG 0.113 0.122 NG _ 5.91 5.50 NG 16.66 16.73 -...__...._..__._...._..._............._._..__.. NG 398 - _Clear 492 - NG Clear Purple 08/03/01 12.92 848.18 7.63 0.131 5.51 16.79 689 Purple 08/20/01 __... _..-...--_..._ _._ 13.25 847.85 6.43 0.121 3.82 20.18 362 Light Pink DW-14 -- - 06/18/01 - 860.06 22.41 037.65 10.60 0.466 3.11 17.99 133 Clear 07/02/01 22.50 837.56 10.01- _ 0.289 0.80 _ -18.01 _ 130 - Clear ..... 07/13/01 08/03/01 08/20/01 22.71 _.._._..._..-...----.._.. 22.81 23.52 837.35 ---- - 837.2. 836.54 ... NG __.._........._... 6.71 NG --'--._......_....._..._ 0.161 NG _...... -- - 1.19 NG -- '- '--. 27.91 NG -- -- --- - -- _...._......_..._...- -- ' -- -'- 196 Clear Clear DW-15 ...... ........... _... _...... _............ 06/18/01 07/02/01 _... _.............. _.................. 07/13/01 861.20 .................................................... 25.59 -� 24.58 ......................... _._....................... _...... ..._....._... 24.74 835.61 ..__----__-_ 836.62 __............ ........... .............. 836.46 9.84 ----------- 9.25 .............................. _.__..... NG 0.107 _-......._ ..._-- 0.135 ......... _....................... .............. _... 5.13 ----.. _.._.-___.____.-- 0.79 ......................... _._..__...... NG 18.47 18.11 ._..... _........................... NG_ 98 ------__..._...______. 155 ............ _.__... _......... -_........... _.... _-. NG Clear Clear Clear 08/03/01 25.08 836.12 -- - 10.03 _NG_ -0.122 1.78 18.56 289 Clear 08/20/01 25.51 835.69 6.42 0.138 2.19 21.36 260 Clear DW-5 _ 06/18/01 872.80 19.08 853.72 5.86 0.108 4.73 20.40 309 Clear 06/29/01 17.90 854.90 5.95 0.120 6.14 20.49 409 Clear 07/02/01 16.93 855.87 5.80 0.120 1.94 20.55 380 Clear 07/03/01 07/04/01 -07/05/01 17.55 -..._..__..........-...._.__..._...__...__-._.._........_.-...- 17.10 855.25 855.70 5.75 --' - . 6.33 0.122 _.............._.....-........_-- 0.120 6.02 -.._..-._.-...- 6.09 20.49 -- ._..._..- -'- 20.82 390 - -- - -........ '-- 378 Clear Clear 17.11 855.69 5.15 0.128 0.12 20.55 387 Clear ............. _..._._.._- 07/09/01 _ _............._._..-. 07/13/01 0...%03%01................................................_._._._.........._..................._....3..._-._.....................................................__.._..................._..............._._.........._....................................................................._...................................._......................... 8 -.-_.....-.....__.._.._..._..._..._._................_......---..._.........._._..................._..__...._..._......_......--.--._.---..._....._._..-....._............._................._............._............_.._..._........._....- 17.90 17.14 23.0 854.90 855.66 849.77 6.50 NG 6.93 0.124 NG 0.109 5.21 NG 3.86 20.48 -._._......._._......._........._..._..__...__._... NG 20.38 387 .._-..._ NG _........_......._.........._...........................__.. 342 Clear Clear Clear 0t3/20/01 26.26 846.54 -6.09 Y 0.094 -1.92 35.07 - 460 J-- Clear Tables 10 & 11.xis Page 3 of 7 Revised: 11/28/01 TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng. Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. mS/Cm mg/L °C mV ._DW_....................I......_06/18/01 ............... 06/20/01 _ 8.12 854.05 7.65 0.190 .................. 4.75 ........_....__..................................................................... 18.93 42 Clear 06/20/01 8.64 853.53 6.42 �0.191 4.42 19.18 257 Clear 0621l01_. _..._..._.._8:1.7.................._....................._854:00..._.._..._......_......._6:52........_......_.__.....__ O6/21l01 8.20 853. ....._......__.._ ..._.__4:63 .._..... -..._19:00---......_._._..-.._.__�84.._....... .Clear 06/22/01 8.90 ......... 853.27 7.71 0.194 4.73 18.99 30 Clear 06l22/01 8.85 853.32 7.48 0.195 5.07 19.01 137 Clear .._...................................................._.._........................................._..............................................._........_...........I.........._.....I................................._._...............................................-........_....._.........................................................._..._................._......._..... 06/25/01 8:49 853.68 6.40 0.193 5.23 19.86 494 Clear ..................................................................................................................................................................................................................................................................................................................................................................................... 06/25/01 8.49 853.68 7.33 0.192 4.74 _..................................._...._.._...__._...._......_......................__._.. 19.18 124 Clear 06/26/01 - _ 8.10 854.07 7.39 0.194 .. .................... 4.98 .............................................................................................................. 19.58 103 Clear 0627I01 8.11 854.06u� 7.69 0.194 4.82 _ 19.51 -- 82 - - Clear _..........................__............_.. 06/28/01 ............................................. ...... ......... 8.10 ......_..._.._................._......._._......................... 854.07 7.02 0.195-- 3.60 18.89' 197_ __- Clear ..........................................._................._............................................................................_ 06/28/01 8.41 ......._............................................................................................................................................................................................................................._...................................._.................................. _....__.._.............................._.........._.._....... 853.76 ............... 7.31 ....._..._............__............. 0.194 _........_...................._...................._......__._..._......_....._......_..._..._...__.............-- 5.02 19.01 '.. 193 Clear 06/29/01 8.29 853.88 7.34 0.210 5.28 18.89 . 232........................... Clear 07/02/01 8.81 853.36 7.48 0.211 1.17 19.75 121 Clear .................................................. 07/03/01 ..... ..................................................._...........__._..................................................................................................._............ 8.55 853.62 �5.76 T 0.209 3.87 18.91 438 Clear .................._..............._......................................................... 07/04/01 ............................................................. 8.27 ................................................................................._...................................................................................................................._............_.. .............. ........................................................................................................ 853.90 6.15 0.212 _........._...._._....._............_........8........ 4.90 19.07 403....................... Clear _ 07/05/01 7.90 854.27 6.71 0.214 ................................. 3.43 ..................... 19.38 237 Clear 07/09/01 8.71 853.46 - 7.22 0.212 _ _ 3.34 18.95 - 164-� Clear _..........._ ......... 07/13/01 _._...._...__..................._.........__.._._._...._...........__.._._.._................_.__..__..._...._...............__....._...._.._.......__..........._...._....................._............. 7.87 854.30 NG NG NG NG NG Clear ....................................................................-................................................_........_...................................................................................................................................................................................................._................................._............... 08/03/01 8.95 853:22 8.91 0.186 __...._.....__.._..._......._........._............__._._._.._.__ 4.17 .............. ...._..__..__......... ......_....... __ 251 Clear 08/20/01 9.68 852.49 6.53 0.132 . 2.31 .............1...9.85 29.03 _................................... 473 Clear DW-8 ..._..................-.................................................._....._........................_...._......................................_..._....._... 06/18/01 861.44 4.96 856.48 6.35 0.084 7.08 17.62 65 Clear ..._......................................._................................_................................_........................................_........................................................................__................................................._........................................................................... 06/22/01 _. 5.54 855.90 6.51 0.083 7.49 ..................................................3.... 17.24 530 Clear _ 06/22/01 5.26 856.18 6.33 0.084 .. 6.83 17.57 553 Clear 06/25/01 5.31 856.13 6.57 0.094 - _ 7.03 21.07 _ 544 Clear 06/25/01 4.15 857.29 6.02 0.087 6.47 19.04 400 Clear ..................................................................................................................................................................................................................................................................................................................................................................... 06/26/01 5.03 856.41 6.36 0.093 7.45 21.46 519 Clear 06/27/01 5.44 856.00 6.62 0.092 .............._.................................................................................................................... 7.66 21.31 495 Clear 06/28/01 - -- 4.18 857.26 6.84 0_.086 5.95 18.52 360_ Clear 06/28/01 5.25 856.19 5.91 0.086 6.43 _ 17.25 435 Clear ............ . .............................. _..... 06/29/01 ...... ...................._................................._..................................._..............._..............................................................._.........................................................._...................................................................................... 5.39 _856.05..._............................5.79................_.............._0.090........................._..._.7.26............................17.45..............._..._.._.._..__.....431................._..._._.. Clear 07102/01 5.68 855.76 6.21 0.091 1.86..........................17.32_......................................382 Clear 07/03/01 8.47 852.97 5.85 _ 0.093 5.43 - 17.58 460 Clear ....................... ....... _...................................._........................._._._..._ 07/03/01 . ................. NG NG 5.75 0.099 5.31 19.91 ! 390 Clear ........................................................................................................................................................................................... 07/03/01 ........_............_..._..._......._.......... NG ..................................................................................................................... ......_.._....... _._........_......... ..._............ NG ..... _.............._......_.. 5.66 .......... _.........._... ......... _... _...... _......_...._...... 0.096 ._........_....._. 5.31 -.......__........_._._..__.......__...................._...._._...................__...- 19.14 389 Clear 07/04/01 5.04 B56.40 5.93 .................................................................................................... D.094 5.80 . 17.67 356 Clear 07/05/01 - 15.31 846.13 6.08 0.094 5.71 17.46 380 Clear _......................._....................... 07/09/01� ............ _......... ............... _............._......._......... .................. 6.24 855.20 6.44� 0.094 _ 6.44� 17.64 368 �T Clear 07/13101 _......5......................................._.........................................................................._....................................._......................................._............. 5.72 855.72 NG NG ... . .. NG......................... ..NG...... _....... ... _............ .............NG_.__...... ......__._. Clear 08/03/01 _ 13.21 848.23 8.11.................................0.082 ................................5.44............................18.87........................................314............................ Clear 08/20/01 11.17 850.27 6.13 '0.085 4.58 23.58 794 Clear Tables 10 & 11.x1s Page 4 of 7 Revised: 1128101 TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification I Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. MS/Cm mg/L °C mV LMP-1 ...._._......._........_.__......................_......_......._....._....__......_..._....._.-_....................------._....__._....._.__.............................--------...................._.............._....- 06/18/01 873.50 14.41 859.09 6.19 0.318 2.43 20.52 120 Clear 06/29/01 14.62 -14.32 858.88 -............._..............................----._.._...._.._......_.._._........__.._._-..................._...--._..._.__.._.._........._ 5.60 0.310 1.92 20.43 390 Clear 07102/01 859.18 _ 6.16 0.334 - 0.62 20.43 309 Clear 07/03/01 ._._..._.._.._.._.........._..-...-_--....._..---._...._ 14.58 ............._._........................__...................._...................................._....._...._._._....._._.._....._...................__.........._..._......_...._.... 858.92 - 5.53 0.324 3.11 20.26 369 Clear ....................................... ........ ......._07/04101......... .... ............. ................ ................... ......................_14;97....................... .... ..............,858:53................... ............. __...._..........._......_..._._....._....._...._._.._.._..........._ 1.71 20.23 ......._.__.._..._ .._..._..........._... .. 309 Clear 07/05/01 12.94 860.56 .,5.93.............. 4.64 ......... ........_0,333.................. 0.023 ... ..............7.85_.........................20.44.........................................432........................... Clear 07/09/01 115.71 857.79 5.59 0.279 2.70 362 Clear _ 07/13/01 ..... - ----- 15.71 _.._.__.- .. - 857.79 - 6.36- _ 0.320- 1.29 _20.41 20.22 _ 231 Clear ...---.........._............_.........__...__._...._... 08/03/01 - ._..... -----.._........__....................._................._.__._.....__.._..............................................._....._....._.............---.._.._._._...._................._.... 16.45 . 857.05 ............ _......_...._...._.- 6.84 -- - ----.._.._........... 0.252 - ..... - - - 0.61 .._......_._...._... --.._.-...----.._......._....._._._.. 20.08 305 Clear -- 08/20/01 16.98 856.52 5.82 ..._.._._........- 0.263 ---...__..__............... 0.38 -.._..... -- 26.82- ---._......_........_...._..-- - ..... 142 Clear _ - - - LMP-2 ^ 06/18/01 - 871.41 12.B4 858.57 6.08 0.116 4.99 20.67 273 Clear .._........._...._....._........._...._ 06/28/01 ...............__......._._......---.-._........._..._....................._.................-- - .._..-._._. __...._....................�......__..__..._...._._._..._.._............_....__..........__......_...._......_....._.._.-----...................._......__._..._.._.._........._.._...._...._..__........ 13.31 858.10 5.36 0.115 3.82 20.45 -..-.__..._.__._....._..._..__.._.... 440 Clear 06/29/01 _ - .._........__......-...._._................._...._......._...._..._......._....__.........----..-......._............_.............._..._...._......_....._....-- 13.38 858.03 5.52 0.120 5.27 ---..__..._..................---...._.._.__..__....__....... 459 Clear 07/02/01 - NG V_.__- NG - - 6.99 T 0.063 --1.21 _20.43 - 30.76- _ 297 - Brown Silty ............... ................ 07/03/01 _._................. _...._.......... .._............................ ....... 12.18 859.23 5.54 0.099 2.89 20.04 358 Clear ................................... 07/04/01 _...................................... .................. .......... .................................. ............................................................ . 13.50 ... .................................. ............. 857.91 ................... 5.69 0.113 3.29 20.26 346 Clear 07/05/01 15.03 .............._.................................................... 856.38 5.21 .......... ............................................ 0.336 ................. _.._................... 1.79 .................... ..... 20.03 338 Clear 07/09/01 13.91 857.50 - 5.62 0.106 - 2.06- 20.29 - - 324 Clear - ---- 07/13/01 ---.._-._... _..._..___..-----.._._.....---- 14.39 - 857.02 NG NG NG NG NG Clear .........._ ............ ...................... ........... 08/03101 .......... .......--........... ....__..._._...-._ .... ................ ................. ..._._._..... 14.76 .................. . --_....._..._._..-- - 856.65 -- _ 8.51 ..... ..__....__.._.__._.-. 0.058 -.. _ ..._.................... 3.90 - --- 20.87 ---.... --- .........---- 522 Clear 08/20/01 15.54 856.87 5.67 0.082 0.74 37.05 357 Light Pink MW-12 ................_...._....-................_._.__..__.._....._........---..._....__..._.__..._..__........_........._..._........._..._.._............._ 06/18/01 862.15 9.90 852.25 6.22 0.194 5.02 19.05 238 Clear - . O6/20/01 -..........._............._.........._.._._........ -----.............. 9.4.. ._.....__......__._.._..................................._.............. ......_...._.........-_......_......._.........__........._.._._... 852.69 -- -. - - 6.52 -.......__..._._._..............._...._...__._._............_.._........- -........._..................__.............._.. __....._....._..._.__._.._..............................._._........__.......__._......._._..........__...._..-- 4.29 18.94 203 Clear 06/20/01 9.54 852.61 6.178 0.184 ._......_.-_.._...._.-.._.....----._........_.........._..........---- 3.62 19.33 ----- 253 Clear _ 06/21/01 9.62 852.53 _5.40 - 5.83 0.190 3.13 _ 19.27 178 Clear ......... 06/21/01 9.23 852.92 6.24 0.185 4.27 19.14 06/22/01 ................................................................................................................................................................ 9.32 ......... ......... 852 83 ........... ......... ..... 6:24 ............ ............... ..... .... 0.190 3.43 18.85 . ........ 186 Clear 06/22/01 9.34 ...... 852.81 . ............. 6.11 0.190 4.42 19.06 _.. 270 Clear 06/25/01 9.30 852.85 5.42 0.155 3.69 20.13 438 Clear ........ ----- --..._-..__.......__._.._......._............__._.-....._..... 06/25/01 - 9.65 -------_....-......_...._ 852.50 6.27 0.176 4.52 19.29 202 Clear _............ _.................. 06/26/01 _..............._.._....._ ............_._............_.......-. .......................... .._........... 9.47-_.......... ........... _....-.--_......... _....... 852.68 ._._....__ ....... _................. -- 6.32 -----......................... _........_.._._.._...------..... 0.180 4.72 ............................... _............_....-- 19.20 ._._...._._._._.. ---- 202 Clear 06/27/01 9.43 ......._ .......... 852.72 _. ..._ ....._...._..._ ..... 6.37_ ......... __.. _... ........................._ _....... 0.191 .... .. .....4......._.._.........................__.._....._............................................__.._........ 4.20 19.31 - ... 192 Clear 06/28/01 9.36- 852.79 - 5.94 -0.185 --2.83 18.85 - 310 Clear _..._......--- ---_ -- 06/28/01 -------...-_...........__._..._.........__..__....._._.__ 9.36 -_..._..._.._....._....._._...._..._.....__....._........__..__.-......_._..........._....._._.._..... 852.79 6.38 0.180 4.23 18.89 299 Clear . 06/29/01 ... ... ................. 9.41 852.74 . ..... 6.32 ---......................_.._...._..__._._.....-._._-._.._._........._...._.. 0.190 ---- ..._._.._......._. 07/02101 9.48 852.67 6.63 ......... 0.195 ........................................ 1.46 ._._.- ..... ... ---.................... 07/03/01 9.77 852.38 5.05 0.210 . 18.84 515 Clear ..............................__.... 07/04/01 .. .............. .............._......_ ................. _._..--..... ...................._..........._.........._ 10.21 . 851.94 _ - 5.48 0.215 - _2.76 - 3.12- -19.12- _ - 474 Clear ................. ... _............. _._..... _..._ 07/05/01 ................... ............. _ ....................... 9.91 ....................._..... .........................................._ 852.24 ... 5.53 0.222 ............ ..... 3.33 ............ ...........-._............ 19.04 .............. 362 Clear 07/09/01 ....._..._.._............. ..- ... _........... _..........11.1 9.89 852._26.._.............................6.05................................_0.21.6................................3.97..._.............._.._..19.OB...................._..........._....319._....................... Clear 07/13/01 9.45 -852.70 -NG -_-NG- NG - - NG NG Clear _._......__.._.... 08/03/01 -----------._-....-- -- -- 10.34 ------- 851.81 7.81 0.121 3.30 - 21.06 351 Clear OBI20/01................................_-............................... ......_10:90................_........................851.:25......_.........................`:50................................_0.156........_......... _- -- _----._.... -....... ....... ..... ...... ......... ...-.-- ------------- _..........._2:14....................._27.71... __---...--- -... ... -- -- -- -- 491 Clear Tables 10 & 11.xls . Page 5 of 7 Revised: 11/28/01 TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification I Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. ms/Cm mg/L °C mV MW-13 .......... _..................... _....... 06/18/01...................863.77........._............................._5:69.........................................._858.08................................_6.11................................._0;085........... .. ...... 7.03 16.57 350 Clear 0626/01 7.00 856.77 6.25 ................................._.............................-............................................-........._................................. 0.089 9.24 17.57 515 Clear 06/27/01 7.55 86'6 22 6.36 0.092 LL 9.29� -17.29 _ - 507 _ Clear .........._._............................_06/28/01..._............._..............................................................._8.42._....................... -. 855.35 ...........__....._..._ 6.15 0.099�.._ 8.74 16.73 564 Clear 06/2e/01 `:10.........................................._858 ....................... 67.................... ._.._._............ .................. 5.97 .......... _.._..... _......._..__..._....... 0.099 ...... ...._..._..... --.._... 8.50 -_...........-....._.._............. 15.40 ......._.._.._.-- ---_........_...._--------- 576 Clear 06/29/01 __- 8.31 - _ _._ _.._.._._� 855.46 6.10 0.110 8.85 15.73 .. _ 1.................. 532 Clear 07/02/01 8.49 855.28 _...._..,___ 6.45 _........_._._...:..._ 0.119 r_ _ 2.16 ._. ___._._ ..._._.... 17.05 ._._ ..._......_._._.............. _.... 405 Brownish Yellow . ...................................................................................................................................................................... 07/0 .3/01 8.81 . 854.96 6.13 0.119 7.42 15.90 594 Slightly pink 07/04/01 8.52 855.25 6.30 0.121 8.06 15.97 584 Pink 07/05/01 � 7.90 855.87 6.13 0.153 8.46 .................._ 16.04 ._..........................................................._... 547 Pink _ 07/09/01 _ 8.63 _ 658.14 -6.51 _ _ 0.144 - _ 8.54 16.77 _ 583 V Purple _............. ..... ..-.......... ........................_.. 07/13/01 ... ..... ........... .... _......... _........-..._-............. 9.18 ...._......_.-............_..............._....._...... 854.59 ..... _.._...... .......... _..................... NG ......................... _....... -_.........-........_....................... NG -........ NG ....... ...... NG NG Purple ...................................................................................................................................................I............... 08/03/01 12.11 851..6fi................._ 8.89 ....................._..............................................................................................._............................................................................._............--............................ 0.080 .._...._.........._....._.__..__._...._T___............_..._..........__........_..._.................. 6.48 16.61 457 Faint Pink -� 08/20/01 11.66 852.11 6.04 5.23 26.90 417 Clear �0.034 .............. MW-15............_06/18/01........................_872.10.._................................_15:79........................................._856.31. ...........-. 314 Clear ............................._..........................._06/29/01........... ... ...................... ................................................_75:68 ................ 856:42................................_5 ............._5.................................0:047.............................._6.70............ 06..............................._0.040 7.28 .20.54 ............__.............._.._.__......_........_....................__. 20.51 457 Clear 07/02/01 15.99 856.11 5.29 0.042 2.35 .... _.... _.... 20.60 .........................._....._......_......................- 417 Clear 07/03l01 16.01 856.09 4.90 0.045 6.25 20.54 432 Clear --.._..-_.-..._-...�....._................._........_.__..................--- 07/04/01 -...._..........-..........._...........-_........ 16.17 _._...._..__....._......._............-......._......_............_..........................._._..._..._..._.._....._..........-.._.........._ 855.93 6.13 0.077 2.27 20.22 388 Clear 07/05/01 ........................................................................................................................... 16.02 856..08..................................4.67...............................0.045 .__........_........__..__....._ 6.45 ...-....._...........-._...__........._........._......_-_-................____.. 20.67 410 Clear V 07/09/01 _ 16.37 855.73 5.19 ............................................................_................................................._.._..._...................I........... 0.037 7.06 20.70 411 Clear 07/13/01 16.36 855.74.__.. v VNG NG NG W v-NG NG --"- Clear 08/03/01 21.13 850.97 5.31 0.032 mm 6.16 20.5 024.............................__3 :� �...........................40 . ... 74..._.................... ............. ...... ..... .......... 528 Light Pink MW-17 06/18/01 861.43 6.53 854.90 5.96 0.080 5.72 17.86 362 Clear 0622/01 ..........-..-.-._._._._..._....._...._9:24.._ .............................._......_85219.._......._....._.........._6:36....-_..._................_0:081..._.........._......-.._..._6.39._........_..._......._17:87............_........_.. 7...................._._.. Clear 06l22/01 ....................................................................... ..............................._5.02.........................................._856.41.................................-6:��................................_0:082.............. 18.49 551 Clear 06/25/01 5.58 855.85 6.97 0.090 . .5.34 ....._............................................................................----..................................._........ 5.81 19.95 525 Clear 06/25/01 5.61 855.82 6.54 0.088 5.39 19.99 524 Clear ._............................................... ......_..............._......................._............--.......................................................... 0626/01 5.83...................._............._.....-855 60................................_6 62................................._0 088..............................._6.:03......._..............._20.33...................... 508 Clear ............................................................................._........................................_-. 06/27l01 6.23 855.20 ........... ................................................ 7.09 0.087 6.36 20.57 ......................_.................._.........._ 462 Clear 06/28/01 6.19 855.24 ...................................................................................................., 6.93 0.083 4.66 ........_..............................- 17.91 .._._............................................................. 480 Clear T 06/28/01 - 6.22 855.21 5.72 0.083 4.70 17.86 457 Clear 06/29/01 _0.....-._-_0.._........._ ........ _.._..._.............._..._...................-_.........................................., 6.16 855:27 6.01 0.090 6.70 17.86 _ 441 Clear ...........7102.... 7 6.19 ............................................................5.2 ..._..._......-_-................._.................._......................._..........................................................-........:................._..._._._._......._................................................._.........._............_.........._.._........ 855..24 375 Clear 07/03/01 6.81 ..................................6:25................................-0:089................................._...:84........................ 854.62 7.18 0.940 3.99 _18.14.... ............, 18.57 ..................................................................... 250 Clear 07/04/01 6.04 855.39 5.92 0.091 4.62 17.94 424 Clear ........................._..........._.........._.._......................_.................................................._......_......................_.........................................................................................................................................................................................................................._...._ 07/05/01 3.20 858.23 5.27 0.091 4.33 17.80 419 Clear ................................................................................................................................................................................................................................................................................................................................................................................................. 07/09/01 6.44 854.99 7.11 0.105 ....... 5.44 . 20.26 337 Clear 07/13/01 6.36 855.07 NG NG . NG NG NG Clear _ 08/03/01 _ -�_ 11.00 850.43 8.57 0.083 4.29 20.19 304 Clear 08/20/01 11.13 850.30 6.07 0.072 4.01 23.76 505 Clear Tables 10 & 11.x1s Page 6 of 7 Revised: 1128101 TABLE 11 Phase I In Situ Chemical Oxidation Using Sodium Permanganate Field Monitoring Data Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation Project # 107535 Well Date Top of Casinng Depth to Water Groundwater pH Specific Dissolved Temperature Oxidation/Reduction Identification Elevation Elevation Conductance Oxygen Potential (ORP) Color Feet Feet Feet S.U. ms/cm mg/L °C my _MW-18......................._06/18/01.._........_ .... 862.26 .................._.... 10.65 .................................._......_._.__................................................................_.........._...._...................._......... 851.61 6.24 0.089 4.42 18.16 331 Clear _ _06/21/01 10.72 851.54 7.60 0.090 __.............._.._.._............-......._..... 3.08 ._._..__..................__._..-..._............_......_.............._. 18.10 112 Clear 06/22/01 10.27 851.99 6.10 _ 0.485 3.10 18.22 746 Purple - - -- 0622/01 -0625/01- ! - - 10.31 -_ - 851.95 6.01 0.461 3.75 18.06 741 Purple ........ ._......_.._ - ------..._._ _._............_..-- _ - _._.... 10.43 ----.._..__.._....._.__............._...._....._........_ 851.83 ..--...__..._...... - -6.26- - --0.198 - .._.._..._.....----...__ ...... 2.70 '-18.62 - - 734 - Purple 06/25/01 10.56 851.70 6.10 0.189 3.97 18.76 703 Purple 06/26/01 10.63 851.63 -6.04 0.198 3.96 18.96 699 Purple 0627/01 10.63 851.63 6.11 0.159 4.15 19.33 690 Purple _.........._......___... 06/28/01. ....................__._._ _. 10.50 _................__.............._....... 851.76 _.._._._...__.._....................._ 6.74 ......_.__.._._.. 0.136 ------ 3.01 17.98 623 Purple 06/28/01 10.52 851.74 5.77 0.130 _._..._._-.._... 3.03 _.._- 18.11 _ --.-. --- 679 Purple 06/29/01 10.49 851.77 6.18 0.130 5.07 17.90 638 Purple 07/02101- 10.63 851.63 0.115 0.82 17.96 577 Pink .............._..__..........._..........._..............._....._..._....................._.._........................_..__._..._......_.._........................................... 07/03/01 10.67 851.59� _........_..._...._................_...._.._......_........._...... _5.78 - 5.61 -- _ - 0.116 . .......... -- 2.84 17.98 _Light 634 07/04/01 10.82 851.44 5.80 0.115 2.65 . ..... 18.11 . _Purple 646 Pink 07/05/01 10.68 851.68 5.58 0.117 4.44 18.31 592 Faint Pink 07/09/01 8.95 853.31 5.81 0.130 3.28 18.24 617 Pink 07/13/01 10.78 851.48 NG NG NG NG NG Light Pink 08/03/01 12.76 849.50 7.50 0.085 3.22 18.39 363 Clear 08/20/01 12.67 849.59 5.67 0.075 1.58 31.10 922 Light Pink _.........._MW-22..... ............... _06/18/01......... ................861.83 Clear i 06/27/01 ............... ........... --_10.29......... _....... 9.87 ................_851:`.............. ... _........._.......6.05 851.96 .............. 6.43 ....... _...._0;101..........._.... 0.102 ... _........._6:19.............. 7.95 .._........_16.37... ....... 16.57 ....._.............. __._378....... ._....__._... 477 Clear 06/28/01 8.48 853.35 6.18 0.105 6.01 15.99 388 - Clear 06/28/01 9.43 852.40 6.26 0.105 6.98 15.94 407 Clear -_._._.._..........-.__......._06/29101 ... - _. _._...._..........._._ 9.79 ...----- - -- - 852.04 - ---- 6.07 0.110 7.74 16.17 415 Clear 07/02/01 10.08 ...__.... - 851.75 - _ ......... 6.17 - - -- . 0.111 1.67 16.06 --- 385 Clear 07/03/01 10.08 851.75 6.28 0.113 5.48 16.31 371 Clear 07/04/01 10.19 851.64 6.13 0.119 5.69 16.27 353 Clear ---.--._............_...._._.... 0. _...._ ....... ---- 10:06--- ..........._851.:��..__... 5.89 0.114--._ _ 407 Clear 07/09/01 7.05 _ 854.78 _ 5.93 0.113 _�_�_.�- 5.50 ---1628- 16.59 -- -...._...... 427 Clear 07/13/01 10.31 851.52 NG NG NG NG NG Clear 08/03/01 12.04 849.79 7.91 0.097 5.22 16.42 564 Clear 08/20/01 12,18 849.65 6.07 0.093 3.39 27.18 288- Clear MW-23 06/18/01 B61.15 24.48 836.67 6.72 0.613 2.02 18.29 -82 Clear -- 07./02/01 _ 22.29 _1 838.86 -'837.09 7.65 0.039 1.28 1 18.31-- 210 Clear - - ---' 07/13/01 .._...._................._.._ ._..._....__...__......_........._._...._.. 24.06 - - -- -.. _....----.._...._......._..._....._._.... NG - NG - NG NG NG - Clear 08/03/01 23.45 837.70 ..........................._..._.._.__..._..... 7.32 - .......__...,. 0.816 ---.-.....-..._............_._ 1.19 18.26 _...._._._...__....-.........- ..__.....__....... 123 Silty Tan 08/20/01 24.33 836.82 5.84 0.494 _ 0.95 23.96 151 Silty Tan Notes: NG Denotes well was not gauged. Tables 10 6 11.x1s Page 7 of 7 Revised: 1128101 Table 12 Pre- and Post - Pilot Test Injection Groundwater Data Summary - Pilot Test Area W.P. Ballard and Downgradient Properties Greensboro, North Carolina WELL ID: MW-1 MW-2 6/22/00 9/7/00 10/19/00 3/8/01 8/22/01 SAMPLE DATE: EPA 601/602 Compounds: (ug/L) NCAC 2L Benzene 1 <1.0 <1.0 NA NA NA <1.0 <1.0 NA NA NA NA 1,2 Dichlorobenzene 620 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <5.0 1,3 Dichlorobenzene 620 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 enzene 29 <1.0 <1.0 <1.0 NA NA <1.0 <1.0 <1.0 NA NA NA Toluene Tolue 1,000 <1.0 <1.0 <1.0 NA NA <1.0 <1.0 <1.0 NA NA NA m,p-Xylenes 530 <1.0 <1.0 <1.0 NA NA <1.0 <1.0 <1.0 NA NA NA o-Xylenes 530 <1.0 <1.0 <1.0 NA NA <1.0 <1.0 <1.0 NA NA NA Bromoform 0.19 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 Bromomethane None <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Tetrachloride 0.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Chloroform 0.19 <1.0 <1.0 <1.0 1 2 <1.0 <1.0 <1.0 <1.0 <1.0 5.2 Chloromethane None <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Vinyl Chloride 0.015 < 1.0 < 1.0 < 1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dibromochloromethane 0.41 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Ethylene Dibromide 0.0004 < 1 .0 <1.0 < 1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 700 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 0.38 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethene 7 <1.0 1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 5.9 cis-1,2-Dichloroethene 70 <1.0 14.7 <1.0 <1.0 <1.0 95.7 9.1 <1.0 <1.0 <1.0 <1.0 trans-1,2-Dichloroethene 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropane 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0 1. 1. cis-1,3-Dichloropropene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 88 trans- 1,3-Dichloropropene 0.2 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <1.0 <1.0 <1.0 <1.0 <1.0.0 Methylene Chloride 5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <1.0 <1.0 Tetra chloroethene 0.7 3,420 2,540 2240 680 2,310 358 69 72 46 68 184 1,1,1-Trichloroethane 200 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1,2-Trichloroethane None <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1,2,2-Tetrachchloroethane 0.17 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Trichloroethene 2.8 6.5 <50 3.1 2 2 66.7 8.7 <1.0 2.0 <1.0 39.8 TOTAL VOCs 3,427 2,556 2,243 683 2,314 520 86.8 72.0 48.2 68.0 322.9 Metals: (mg/L) Iron 300 0.150 0.176 NA NA NA NA 70.400 NA NA NA NA Ferrous Iron None <0.100 <0.100 NA NA NA NA 0.190 NA NA NA NA Manganese 50 0.042 0.043 NA NA NA NA 2.710 NA NA NA NA Ferric Iron None 0.150 0.176 NA NA NA NA 70.200 NA NA NA NA Miscellaneous Chemistry: (mg/L) Chloride 250 NA NA NA NA NA NA NA NA <1.0 NA NA Chemical Oxygen Demand None NA NA NA NA NA NA NA NA NA NA NA Percent Reduction (VOCs) 25% 35% 80% 32% 83% 86% 91 % 87% 38% �49% Percent Reduction (PCE) 26% 35% 80% 32% 81 % 80% 87% 81 % Notes: Concentrations detected in excess of the NCAC 2L Standard are shown in bold. Italicized NCAC 2L criteria indicate interim standards imposed by NCDENR NA denotes compound not analyzed during sampling event Groundwater samples analyzed for metals prior to injection were collected on 4124100 Monitoring Report /Table 12.xls / Phase 1 Wells Page 1 of 5 Revised: 11/28/01 Table 12 Pre- and Post - Pilot Test Injection Groundwater Data Summary - Pilot Test Area W.P. Ballard and Downgradient Properties Greensboro, North Carolina WELL ID: MW-3 MW4 SAMPLE DATE: 3/22/00 6/23/00 1 9/8/00 1 9/14/00 10/18/00 3/8/01 8/22/01 1 3/22/00 6/22/00 9/7/00 10/19/00 3/8/01 8/23/01 EPA 601/602 Compounds: (ug/L) NCAC 2L Benzene 1 <1.0 <50.0 <1.0 <1.0 <1000 NA <1.0 <1.0 <10.0 <1.0 <1000 NA 2.4 1.2 Dichlorobenzene 620 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,3 Dichlorobenzene 620 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Ethylbenzene 29 <1.0 <50.0 <1.0 <1.0 <1000 NA <1.0 <1.0 <10.0 <1.0 <1000 NA 1.4 Toluene 1,000 13.0 75.0 <1.0 <1.0 <1000 NA 15.5 <1.0 26.0 <1.0 <1000 NA 2.4 m,p-Xylenes 530 <1.0 <50.0 <1.0 <1.0 <1000 NA 3.5 1.5 18.0 <1.0 <1000 NA 16.4 o-Xylenes 530 3.3 <50.0 <1.0 <1.0 <1000 NA <1.0 1.0 348.0 <1.0 <1000 NA NA Bromoform 0.19 <1.0 <50.0 <2.0 <1.0 <1000 18 18 <1.0 <10.0 <2.0 <1000 <1.0 <1.0 Bromomethane None <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Carbon Tetrachloride 0.3 3.7 <50.0 <1.0 <1.0 <1000 3 5 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Chloroform 0.19 9.7 <50.0 50 <1.0 <1.0 <1000 <1.0 43.7 <1.0 <10.0 <1.0 <1000 8 <50 Chloromethane None <1.0 <50.0 <.0 1 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Vinyl Chloride 0.015 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Dibromochloromethane 0.41 <1.0 <50.0 <1.0 <1.0 <1000 33 33 <1.0 <10.0 <1.0 <1000 1 <1.0 Ethylene Dibromide 0.0004 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,1-Dichloroethane 700 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,2-Dichloroethane 0.38 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,1-Dichloroethene 7 3.4 < 50.0 <1.0 <1.0 <1000 3 3 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 cis- 1,2-Dichloroethene 70 210.0 210.0 <1.0 <1.0 <1000 166 <1 2.7 2,650 <1.0 <1000 415 90 trans- 1,2-Dichloroethene 70 3.2 <50.0 <1.0 <1.0 <1000 4 2 <1.0 11.0 <1.0 <1000 5 <1 1,2-Dichloropropane 0.56 <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 cis- 1,3-Dichloropropene <1.0 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 3 3 trans-1,3-Dichloroprope ne 0.2 <1.0 <50.0 <1.0 <1.0 <1000 3 3 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Methylene Chloride 5 <5.0 <250 <5.0 <5.0 <5000 <5.0 <5.0 <5.0 <50.0 <5.0 <5000 <5.0 <5.0 Tetrachloroethene 0.7 156,000 218,000 154,000 130,000 148,000 138,000 126,000 13,400 90,500 41,200 54,800 44,800 12,800 1,1,1-Trichloroethane 200 2.0 <50.0 <1.0 <1.0 <1000 2 3 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,1,2-Trichloroethane None 52.5 <50.0 <1.0 <1.0 <1000 42 40 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 1,1,2,2-Tetrachchloroethane 0.17 5.4 <50.0 <1.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <1000 <1.0 <1.0 Trichloroethene 2.8 <1000 135.0 <1.0 <1.0 <1000 90 <1 7.6 627.0 <1.0 <1000 880 370 TOTALVOCs 156,306 218,420 154,000 130,000 148,000 138,364 126,170 13413 94,180 41,200 541800 46,112 13,286 Metals: (mg/L) Iron 300 0.200 <0.050 NA NA NA NA NA 0.230 2.600 NA NA NA NA Ferrous Iron None <0.100 <0.100 NA NA NA NA NA <0.100 <0.100 NA NA NA NA Manganese 50 0.098 0.150 NA NA NA NA NA 0.541 2.030 NA NA NA NA Ferric Iron None 0.200 <0.100 NA NA NA NA NA 0.230 2.600 NA NA NA NA Miscellaneous Chemistry: (mg/L) Chloride 250 NA NA NA NA 5.3 NA NA NA NA NA 1.6 NA NA Chemical Oxygen Demand None <3.00 3.4 NA NA NA NA NA NA NA NA NA NA NA Percent Reduction (VOCs) -40% 1 1 % 1 17% 1 5% 11 % 19% -602% -207% -309% -244% 1 Percent Reduction (PCE) -40% 1 % 17% 5% 12% 19% -575% -207% -309% -234% 4% Notes: Concentrations detected in excess of the NCAC 2L Standard are shown in bold. Italicized NCAC 2L criteria indicate interim standards imposed by NCDENR NA denotes compound not analyzed during sampling event Groundwater samples analyzed for metals prior to injection were collected on 4124100 Monitoring Report /Table 12.xls / Phase 1 Wells Page 2 of 5 Revised: 11/28/01 Table 12 Pre- and Post - Pilot Test Injection Groundwater Data Summary - Pilot Test Area W.P. Ballard and Downgradient Properties Greensboro, North Carolina MW-5 MW-6 DW-1 WELL ID: 3/22/00 6/23/00 9/7/00 10/19/00 3/8/01 8/22/01 3/22/00 9/7/00 10/19/00 1 8/22/01 3/22/00 9/7/00 10/19/00 SAMPLE DATE: EPA 601/602 Compounds: (ug/L) NCAC 2L Benzene 1 <1.0 <10.0 <1.0 NA NA NA <10.0 <50.0 <50.0 NA <1.0 <20.0 <50.0 1,2 Dichlorobenzene 620 <1.0 <10.0 <1.0 < 100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 1,3 Dichlorobenzene 620 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Ethylbenzene 29 <1.0 <10.0 <1.0 NA NA NA <10.0 <50.0 <50.0 NA <1.0 <20.0 <50.0 Toluene 1,000 <1.0 <10.0 <1.0 NA NA NA <10.0 <50.0 <50.0 NA <1.0 <20.0 <50.0 m,p-Xylenes 530 <1.0 <10.0 <1.0 NA NA NA <10.0 <50.0 <50.0 NA <1.0 <20.0 <50.0 o-Xylenes 530 <1.0 <10.0 <1 NA NA NA <.0 10.0 <50.0 <50.0 NA <1.0 <20.0 <50.0 Bromoform 0.19 <1.0 <10.0 <2.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 o a Brom< None <1.0 <10.0 <1.0 <100 1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Tetra Carbon Tetrachloride Carbon <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Chloroform .1 0.19 <1.0 <10.0 <1.0 <100 1 10 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Chloromethane None <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Vinyl Chloride 0.015 <1.0 <10.0 <1.0 <100 <1 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0.0 Dibromochloro methane 0.41 <1.0 <10.0 <1.0 <100 3 3 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Ethylene Dibromide 0.0004 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 1, 1 -Dichloroethane 700 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 9.4 16.6 <20.0 <50.0 1,2-Dichloroethane 0.38 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 4.4 <1.0 <20.0 <50.0 1,1-Dichloroethene 7 6.0 <10.0 <1.0 <100 12 35 296 445 470 450 <1.0 26.0 470<50.0 cis-1,2-Dichloroethene 70 <1.0 <10.0 <1.0 <100 2 3 <10.0 <50.0 6.5 7.6 <20.0 <50.0 trans-ichlor 70 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 3.7 <1.0 <20.0 <50.0 propoethene 1,2-Dichloropropane 0.56 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 cis <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 -1 3ic ichlorropene trans-1,3-Dichloropropene 05 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Methylene Chloride 5 <5.0 <50.0 <5.0 <500 10 1 <50.0 <250 <250 <5 <5.0 <100 <250 Tetra chloroethene 0.7 8,120 8,220 5,880 5,060 1,940 7,520 101 125 255 166 358 464 255 1,1,1-Trichloroethane 200 <1.0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 30.3 8.8 <20.0 <50.0 1,1,2-Trichloroethane None <10.0 <1.0 <100 3 1 <10.0 <50.0 <50.0 9.0 <1.0 <20.0 <50.0 1,1,2,2-Tetrachchloroethane 0.17 <11.. 0 <10.0 <1.0 <100 <1.0 <1.0 <10.0 <50.0 <50.0 <1.0 <1.0 <20.0 <50.0 Trichloroethene 2.8 4.2 <10.0 <1.0 <100 5 1 <10.0 <50.0 <50.0 <1 11.2 <20.0 <50.0 TOTAL VOCs 8,134 8,220 5,880 5,060 1,976 7,575 397 570 725 679 402 490 725 Metals: (mg/L) Iron 300 0.223 1.110 NA NA NA NA NA NA NA NA NA NA NA Ferrous Iron None <0.100 <0.1 NA NA NA NA NA NA NA NA NA NA NA Manganese 50 0.026 0.095 NA NA NA NA NA NA NA NA NA NA NA Ferric Iron None 0.223 1.110 NA NA NA NA NA NA NA NA NA NA NA Miscellaneous Chemistry: (mg/L) Chloride 250 NA NA NA 1.4 NA NA NA NA 1.6 1.6 NA NA 1.6 Chemical Oxygen Demand None NA NA NA NA NA NA NA NA NA NA NA NA Percent Reduction (VOCs) -1 % 28% 38% 76% 7% -44% -83% -71 % -22% 0 -8% Percent Reduction (PCE) -1 % 1 28% 38% 1 76% 7% -24% -152% -64% -30% 29% Notes: Concentrations detected in excess of the NCAC 2L Standard are shown in bold. Italicized NCAC 2L criteria indicate interim standards imposed by NCDENR NA denotes compound not analyzed during sampling event Groundwater samples analyzed for metals prior to injection were collected on 4124100 Monitoring Report /Table 12.xls / Phase 1 Welts Page 3 of 5 Revised: 11/28/01 Table 12 Pre- and Post - Pilot Test Injection Groundwater Data Summary - Pilot Test Area W.P. Ballard and Downgradient Properties Greensboro, North Carolina WELL ID: DW-3 DW-4 F- SAMPLE DATE: 3/23/00 6/23/00 9/7/00 10/18/00 1 3/8/01 8/22/01 3/23/00 6/22/00 1 9/14/00 10/19/00 1 3/8/01 1 8/22/01 3/23/00 6/23/00 EPA 601/602 Compounds: (ug/L) NCAC 2L Benzene 1 <1.0 <20.0 <1.0 <1000 NA 3.2 <1.0 <10.0 NA NA NA NA <1.0 <1.0 1,2 Dichlorobenzene 620 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,3 Dichlorobenzene 620 <1.0 < 20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Ethylbenzene 29 <1.0 <20.0 <1.0 <1000 NA <1.0 <1.0 <10.0 NA NA NA NA <1.0 <1.0 Toluene 1,000 9.6 <20.0 <1.0 <1000 NA 11.0 <1.0 <10.0 NA NA NA NA <1.0 <1.0 m,p-Xylenes 530 <1.0 <20.0 <1.0 <1000 NA <1.0 <1.0 <10.0 NA NA NA NA <1.0 <1.0 o-Xylenes 530 <1.0 < 20.0 <1.0 <1000 NA <1.0 <1.0 <10.0 NA NA NA NA <1.0 <1.0 Bromoform 0.19 <1.0 <20.0 <2.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Bromomethane None <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Carbon Tetrachloride 0.3 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Chloroform 0.19 1.4 <20.0 <1.0 <1000 3 5 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Chloromethane None <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Vinyl Chloride 0.015 <1.0 < 20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 2.1 Dibromochloromethane 0.41 <1.0 <20.0 <1.0 <1000 18 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Ethylene Dibromide 0.0004 <1.0 <20.0 <1.0 <1000 3 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,1-Dichloroethane 700 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,2-Dichloroethane 0.38 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,1-Dichloroethene 7 <1.0 <20.0 <1.0 <1000 <1.0 1.7 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 1.7 cis-1,2-Dichloroethene 70 7.9 <20.0 <1.0 <1000 4 6 8.7 <10.0 <1.0 <50.0 <1000 <500 <1.0 1.9 trans-1,2-Dichloroethene 70 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 4.0 5.6 1,2-Dichloropropane 0.56 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 cis- 1,3-Dichloropropene <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 trans- 1,3-Dichloropropene 0.2 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Methylene Chloride 5 <5.0 <100 <5.0 <5000 <5.0 <5.0 <5.0 <50.0 <5.0 <250 <5000 <2500 <5.0 <5.0 Tetra chloroethene 0.7 73,200 932 27,600 48,800 48,200 62,000 24,900 20,000 <1.0 <50.0 <1000 <500 1,670 1,380 1,1,1-Trichloroethane 200 <1.0 < 20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,1,2-Trichloroethane None <1.0 <20.0 <1.0 <1000 18 22 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 1,1,2,2-Tetrachchloroethane 0.17 <1.0 <20.0 <1.0 <1000 <1.0 <1.0 <1.0 <10.0 <1.0 <50.0 <1000 <500 <1.0 <1.0 Trichloroethene 2.8 32.5 <20.0 <1.0 <1000 25 20 20.4 <10.0 <1.0 <50.0 <1000 <500 39.9 81.9 TOTAL VOCs 73,251 932 27,600 48,800 48,271 62,069_ 24,929 20,000 0 0 0 0 1,714 1,473 Metals: (mg/L) Iron 300 0.140 <0.0500 NA NA NA NA 0.347 0.693 NA NA NA NA 0.680 10.800 Ferrous Iron None <0.100 <0.100 NA NA NA NA <0.100 <0.100 NA NA NA NA 0.170 0.490 Manganese 50 0.017 29.200 NA NA NA NA 0.017 4.940 NA NA NA NA <0.100 0.210 Ferric Iron None 0.140 <0.100 NA NA NA NA 0.347 0.693 NA NA NA NA 0.510 10.300 Miscellaneous Chemistry: (mg/L) Chloride 250 NA NA NA 37.0 NA NA NA NA NA <50.0 NA NA NA NA Chemical Oxygen Demand None 6.3 <30.0 NA NA NA NA NA NA NA NA NA NA <3.00 41.2 Percent Reduction (VOCs) 99% 62% 33% 34% 1 15% 20% 100% 100% 1 100% 100% 14% Percent Reduction (PCE) 99% 62% 33% 34% 15% 20% 100% 100% 1 100% 100% 17% Notes: Concentrations detected in excess of the NCAC 2L Standard are shown in bold. Italicized NCAC 2L criteria indicate interim standards imposed by NCDENR NA denotes compound not analyzed during sampling event Groundwater samples analyzed for metals prior to injection were collected on 4124100 -1 0/18/00 1 3/8/01 <1.0 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 5 <1.0 <1.0 2 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <5.0 <5.0 802 380 728 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 52.0 28.0 43 854 408 778 NA NA NA NA NA NA NA NA NA NA NA NA NA 1 2.8 1 NA NA NA NA Monitoring Report /Table 12.xls / Phase 1 Wells Page 4 of 5 Revised: 11/28/01 Table 12 Pre- and Post - Pilot Test Injection Groundwater Data Summary - Pilot Test Area W.P. Ballard and Downgradient Properties Greensboro, North Carolina WELL ID: BMW-2 SAMPLE DATE: 3/23/00 6/22/00 9/7/ 00 10/18/00 3/8/01 8/22/01 EPA 601/602 Compounds: (ug/L) NCAC 2L Benzene 1 <1.0 <1.0 <1.0 <1000 NA <1.0 1,2 Dichlorobenzene 620 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 1,3 Dichlorobenzene 620 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Ethylbenzene 29 <1.0 <1.0 <1.0 <1000 NA <1.0 Toluene 1,000 3.1 4.5 <1.0 <1000 NA 1.9 m,p-Xylenes 530 <1.0 <1.0 <1.0 <1000 NA <1.0 o-Xylenes 530 1.1 <1.0 <1.0 <1000 NA <1.0 Bromoform 0.19 <1.0 <1.0 <2.0 <1000 <1.0 <1.0 Bromomethane None <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Carbon Tetrachloride 0.3 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Chloroform 0.19 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Chloromethane None <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Vinyl Chloride 0.015 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Dibromochloromethane 0.41 <1.0 16.5 <1.0 <1000 8 8 Ethylene Dibromide 0.0004 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 1,1-Dichloroethane 700 <1.0 <1.0 <1.0 <1000 1 1 1,2-Dichloroethane 0.38 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 1,1-Dichloroethene 7 19.7 21.0 <1.0 <1000- 21 45 cis-1,2-Dichloroethene 70 <1.0 <1.0 <1.0 <1000 <50 13,100 trans-1,2-Dichloroethene 70 4.9 <1.0 <1.0 <1000 8 8 1,2-Dichloropropane 0.56 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 cis-1,3-Dichloropropene <1.0 <1.0 <1.0 <1000 <1.0 <1.0 trans-1,3-Dichloropropene 0.2 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Methylene Chloride 5 <1.0 <5.0 <5.0 <5000 <5.0 <5.0 Tetrachloroethene 0.7 110,000 90,500 45,700 53,500 33,200 30,400 1,1,1-Trichloroethane 200 4.1 <1.0 <1.0 <1000 4 4 1,1,2-Trichloroethane None <1.0 <1.0 <1.0 <1000 -<1.0 <1.0 1,1,2,2-Tetrachchloroethane 0.17 <1.0 <1.0 <1.0 <1000 <1.0 <1.0 Trichloroethene 2.8 70.1 38.3 <1.0 <1000 440 2,300 TOTAL°VOCs 110,103 90,580 45,700 53,500 33,682 -45 868 Metals: (mg/L) Iron 300 0.105 0.100 NA NA NA NA Ferrous Iron None <0.100 <0.100 NA NA NA NA Manganese 50 0.031 0.017 NA NA NA NA Ferric Iron None 0.105 0.100 NA NA NA NA Miscellaneous Chemistry: (mg/L) Chloride 250 NA NA NA 2.7 NA NA Chemical Oxygen Demand None NA NA NA NA NA NA Percent Reduction (VOCs) 18% 58% 51% 69% 58% Percent Reduction PCE) 18°/ 58°/ 51 °/ 70% 72°/ 0 0 0 0 o I Notes: Concentrations detected in excess of the NCAC 2L Standard are shown in bold. Italicized NCAC 2L criteria indicate interim standards imposed by NCDENR NA denotes compound not analyzed during sampling event Groundwater samples analyzed for metals prior to injection were collected on 4124100 Monitoring Report frable 12.)ds / Phase 1 Wells Page 5 of 5 Revised: 11/28/01 TABLE 13 Phase I - In Situ Chemical Oxidation Shallow Groundwater Wells Preliminary Results Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina Analyte NCAC 2L . MW-12 MW-15 MW-17 MW-18 MW-22 LMP-1 LMP-2 3/7/01 8/21 /01 3/7/01 8/21 /01 3/7/01 8/21 /01 3/7/01 8/21 /01 3/7/01 8/20/01 3/7/01 8/21 /01 3/7/01 8/21 /01 Methylene Chloride (ug/L) 5.0 <5.0 <5 <5.0 <50 <5.0 <50 <5.0 <50 <5.0 <250 <5.0 <50 <5.0 <1.0 Chloroform (ug/L) 0.19 <1.0 <1 17 25 4 55 1 <50 2 <50 <1.0 11 <1.0 1.7 Chloromethane (ug/L) none <1.0 <1 <1.0 <10 <1.0 <50 <1.0 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 Carbon Tetrachloride (ug/L) 0.3 <1.0 <1 7 <10 17 <50 <1.0 <50 5 <50 <1.0 <10 <1.0 <1.0 1,1-Dichloroethane (ug/L) 700 <1.0 <1 <1.0 <10 <1.0 <50 2 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 1,2-Dichloroethane (ug/L) 0.38 <1.0 <1 <1.0 <10 <1.0 <50 <1.0 <50 <1.0 <50 1 <10 <1.0 <1.0 1,1-Dichloroethene (ug/L) 7.0 <1.0 <1 <1.0 <10 2 <50 <1.0 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 cis-1,2-Dichloroethene (ug/L) 70 1 5.2 24 22 160 165 27 <50 85 <50 11 65 10 13.8 trans-1,2-Dichloroethene (ug/L) 70 <1.0 <1 <1.0 <10 2 <50 <1.0 <50 4 <50 1 <10 <1.0 <1.0 1,2-Dichloropropane (ug/L) 0.56 94 60 <1.0 <10 <1.0 <50 <1.0 <50 <1.0 <50 830 595 382 250 Trichloroethene (ug/L) 2.8 9 5.2 404 345 1330 555 1,060 <50 355 180 33 67 12 6.9 Tetrachloroethene (ug/L) 1 <1.0 7.7 30 11 4,770 2,340 2,200 940 2,040 1,790 215 81 86 51.8 1,1,2,2-Tetrachloroethane (ug/L) none 7 <1 <1.0 <10 <1.0 <50 <1.0 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 1,1,1-Trichloroethane (ug/L) 200 <1.0 <1 <1.0 <10 <1.0 <50 <1.0 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 1,1,2-Trichloroethane (ug/L) none <1.0 <1 <1.0 <10 1 2 <50 2 <50 <1.0 <50 <1.0 <10 <1.0 <1.0 Total VOCs Detected (ug/L) 1.11 78 482 403 6,287 3,115 3,292 940 2.491 1,970 1,091 819 490 324 Percent Reduction (VOCs) Percent Reduction (PCE) = 77 30% NA 16% 63% 50% 51% 71% 57% f_ 21% 12% 4 b 25% 62% 34% 40% Tables 13 & 14.xis Pagel of 1 Revised: 11/28/01 TABLE 14 Phase I - In situ Chemical Oxidation Deep Groundwater Wells Preliminary Results Summary W. P. Ballard and Downgradient Properties Greensboro, North Carolina DMP-1 DMP-3 DMP-4 Analyte NCAC 2L DW-7 DW-8 DW-13 3/7/01 8/21/01 3/8/01 8/21/01 3/7/01 8/21/01 3/7/01 8/23/01 3/7/01 8/21/01 3/6/01 8/21/01 Bromoform (ug/L) 0.19 4 <1 M <5 <1.0 <50 <1.0 <10 <1.0 <500 <1.0 <5 <1.0 <5000 1,2-Dichlorobenzene (ug/L) none <170 <5 <1.0 <50 <1.0 <10 6 <500 <1.0 <5 <1.0 <5000 1.3-Dichlorobenzene (ug/L) none <10 <5 <1.0 <50 <1.0 <10 <1.0 <500 <1.0 <5 <1.0 <5000 Methylene Chloride (ug/L) 5.0 <50 <25 <5.0 <250 <5.0 <10 <1.0 <2500 <5.0 <25 <5.0 <25000 Chloroform (Ug/L) 0.19 <l 0 <5 12 <50 <1.0 <10 <1.0 <500 <1.0 <5 10 <5000 Chloromethane (ug/L) none <10 <5 <1.0 <50 <1.0 <10 <1.0 <500 <1.0 <5 <1.0 <5000 Carbon Tetrachloride (ug/L) 0.3 <1'0 <5 20 <50 1 <10 <1.0 <500 <1.0 <5 18 <5000 1,1-Dichloroethane (ug/L) 700 <1F0 k <5 <1.0 <50 <1.0 <10 <1.0 <500 <1.0 <5 <1.0 <5000 1,2-Dichloroethane (ug/L) 0.38 <10 <5 3 <50 <1.0 <10 11 <500 <1.0 <5 <1.0 <5000 Vinyl chloride (ug/L) 0.015 <110 <5 <1.0 <50 <1.0 <10 2 <500 <1.0 <5 <1.0 <5000 i 1,1-Dichloroethene (ug/L) 7.0 <10 <5 <1.0 <50 <1.0 <10 4 <500 <1.0 <5 <1.0 <5000 r - cis- 1,2-Dichloroethene (ug/L) 70 <1+.0 <5 320 <50 20 <10 2280 <500 9 <5 350 <5000 trans- 1,2-Dichloroethene (ug/L) 70 <1}.0 <5 1 <50 <1.0 <10 10 <500 <1.0 <5 30 <5000 1,2-Dichloropropane (ug/L) 0.56 7 <5 <1.0 <50 <1.0 <10 17 <500 <1.0 <5 <1.0 <5000 Trichloroethene (ug/L) 2.8 2 <5 645 <50 89 32 320 <500 55 21.5 1250 <5000 Tetrachloroethene (ug/L) 0.7 240 226 1340 1,100 860 447 190 <500 289 144 2940 <5000 1,1,1-Trichloroethane (ug/L) 200 <1+.0 <5 <1.0 <50 <1.0 <10 <1.0 <500 <1.0 <5 <1.0 <5000 1,1,2-Trichloroethane ug/L) none <11.0 <5 2 <50 <1.0 <10 <1.0 <500 <1.0 <5 2 <5000 Total VOCs ug/L -: 249 226 2,243 1,100 960 479 2,840 0 353 166 4,600 0 Percent Reduction (VOCs) 9% 51% 50% ;' `° 100% 53% 100% Percent Reduction (PCE) 6% 18% 47% 100% 50% 100% Tables 13 & 14.xls Page 1 of 1 Revised: 11/28/01 TABLE 15 Cumulative Mass Removal Via Groundwater Extraction W.P. Ballard and Downgradient Properties Greensboro, North Carolina IT Corporation of North Carolina Project 107535 Date Cumulative Groundwater Recovered (gallons)u Influent Concentrations (WSP-1) Mass Removed / Period Cummulative Mass Removal Trichloroethene WI- Tetrachloroethene u /L Trichloroethene Ibs Tetrachloroethene Ibs Trichloroethene Ibs Total Tetrachloroethene Ibs 3/28/01 68,527 490 1200 0.280 0.280 0.280 0.280 4/26/01 154,178 <50 1600 0.000 1.144 0.280 1.424 5/11/01 230,456 540 1300 0.344 0.827 0.624 2.251 6/14/01 465,638 3300 5000 6.476 9.812 7.100 12.063 7/19/01 1,046,704 1400 1200 6.788 5.818 13.888 17.882 8/23/01 2,011,623 1100 2600 8.857 20.934 22.745 38.816 9/6/01 1 2,209,832 1100 6800 1.819 11.247 24.564 1 50.063 Note: The formula used to calculate mass removed per month is: (Gallons Removed During Period) x (Influent Concentration) x (1 Ib/ 453.6 g) x (1 g/ 10 a ug) x (3.785 U 1 gal) Tables 15 & 16.x1s TABLE 16 NPDES Permit Compliance Monitoring Summary W.P. Ballard and Downgradlent Properties Greensboro, North Carolina IT Corporation of North Carolina Project 107535 Effluent Constituent Units Daily Maximum Limit 2001 Monthly NPDES Sampling Results8LISP-4 March April May June July August September 3/28/01 4/26/01 5/11101 5/31/2001 R 6/14/01 6/25/01 7/19/01 7/23/01 8113/01 8/13101 8120/01 8/23/01 9/6/01 9/17/01 Total Suspended Solids mg/L 30.0 92 15. 180 20 41 16 26 Oil and Grease mg/L 14 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11 <5.0 Lead mg/L 0.049 0.0077 <0.005 0.017 0.067 0.0065 <0.0030 0.0035 Iron mg/L 12 1A 44 3A 6.3 0.96 4.1 0.69 Manganese mg/L 0.71 1.2 0.66 0.38 0.18 0.041 0.098 0.033 Benzene µg/L 71.4 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Toluene µg/L 11.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Carbon tetrachloride µg/L 4.4 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1,1-Dichlorcethene µg/L 3.2 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1,2-Dichloropropane µg/L 39.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Trichloroethene µg/L 81.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Tetrachloroethene µg/L 8.85 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1,1,2-Tdchloroethane µg/L 42.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Vinyl chloride µg/L - <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 M <5.0 <5.0 Ethylbenzene µg/L - <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 a <5.0 <5.0 m&p-Xylene µg/L <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 o-Xylene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 r <5.0 <5.0 1,2-Dichloroethane µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 <5.0 1,2-Dichlorobenzene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 t <5.0 <5.0 1,3-Dichlorobenzene µg/L <5.0 <5.0 <5.0 ' <5.0 <5.0 P <5.0 P P e P <5.0 <5.0 P Methylene chloride µg/L <5.0 <5.0 <5.0 <5.0 <5.0 a <5,0 a a c a <5.0 <5.0 a Chloroform µg/L 18 17 19 9.8 <5.0 c <5,0 c c h c <5.0 <5.0 c 1,2-Dibromoethane µg/L <5.0 <5.0 <5.0 <5.0 <5.0 a <5.0 e e a <5.0 <5.0 e 1,1-Dichioroethane µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 <5.0 cis-1,2-Dichlorcethene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 A <5.0 A A n A <5.0 <5.0 A trans-1,2-Dichloroethene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 n <5.0 n n c n <5.0 <5.0 Naphthalene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 a <5.0 a a <5.0 <5.0 n 1,1,2,2-Tetrachloroethane µg/L _ <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 I I a <5.0 <5.0 a 1,1,1-Tdchloroethane µg/L <5.0 <5.0 <5.0 <5.0 <5.0 <5,0 ( I <5.0 <5.0 1 1,3,5-Trimethylbenzene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 y <50 .<5.0 y y S y <5.0 <5.0 y 1,2,4-Tdmethylbenzene µg/L <5.0 <5.0 <5.0 <5.0 <5.0 t t t P t <5.0 <5.0 t Bromoform µglL <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 I I L I <5.0 <5.0 Methyl-tert-butyl ether µg/L <5.0 <5.0 <5.0 <5.0 <5.0 c <5.0 c c I c <5.0 <5.0 c Nitrogen, Kjeldahl, Total mg/L 0.15 0.16 5.2 <0.10 <0.10 a <0.10 a a T a <0.10 <0.10 a Nitrate -Nitrite (as N) mg/L <0.30 <0.30 <0.30 <0.30 0.59 1 <0.30 1 1 ) 1 <0.30 0.35 1 Chronic Toxicity - PASS/FAIL FAIL FAIL Chronic Toxicity - Chronic Value (P) c P...-I-1 I % 1 190 1 <45 76.5 61.2 1 <45 Tables 15 & 16.x1s TABLE 17 Cumulative Mass Removal Via Vapor Extraction W.P. Ballard and Downgradtont Properties Greensboro, North Carolina Influent Concentration (ASP-2) Mass Removal Rates Cummalitve Mass Removal Days of System System cis4,2- cis4.2- cis-1,2- Date Operallon Temperature Flow Rate Dlchloroethens Trichlorosthene Tetrachi thane THC-Gas Dlchloroethens Tdchlorosthens Tatrachloroetheno TRC-Gas Dichloroethens Trichloroethene Tetrachlorostitans THc-Gas (' Rankine) (cfm) (ppm-v) (ppm-v) (ppm-v) (ppmar) (ibs/day) (lbsrday) (lbs/dsy) (lbs/day) (lbs) (Ibs) (Ibs) (Ibs) 328/01 3 570 588 0.39 0.33 2.4 7.4 0.08 0.09 0.81 1.56 0.23 0.28 2.42 4.69 426/01 4.5 590 334 1.2 0.68 20 26 0.13 0.10 3.70 3.03 0.81 0.71 19.05 18.32 5/11/01 5 652 837 1.0 0.5 46 18 0.29 0.20 22.78 4.99 2.26 1.69 132.98 4325 8114101 18 SSD 883 <0.15 <0.15 0.88 2.3 0.00 0.00 0.35 0.59 2.28 1.69 136.21 52.07 726101 32 5e8 610 <0.28 <0.26 2.2 <2.6 0.00 0.00 0.78 0.00 2.26 1.89 163.02 52.07 8/23/01 21 1 588 B10 <023 <0.23 <0.23 <2.3 0.00 0.00 0.00 0.00 2.26 1.69 163.02 52.07 816101 10 556 1010 0.1 02 23 3.0 0.03 0.09 13.65 1.12 2.58 2.63 299.49 63.28 Note: Molecular Weight Values: Molecular Weight Analyte (IbObmole) cis-1,2-Dichloroethene 98.94 ' Trichloroethene 131.38 Tetrachloroethene 165.82 THC - Gas 104.40 The formula used to calculate emission rates is: Mass Removal Rate (N / day) - mw(P/RT)(q)(B)(C/D) where: mw - molecular weight of contaminant (ib/Ibmoie) P= atmospheric pressure (1 aim) R = universal gas constant (0.7310 ft''atmnbmole-R) T - temperature (degrees Rankine) q = system flow rate (cfm) B - conversion factor (1440 min/day) C = concentration of hydrocarbons (ppmv) D - total volume (1 E+06) Tables 17 6 18.rds Temperature Conversion (Fahrenheft to Rankine) Rankine- Degrees Fahrenheit + 460 Air Flow Rate Calculation q = M(A) q - Air Flow Rate (cfm) V = Air Velocity - measured (fpm) A o Cross Sectional Area of Pipe (n•r') r -Pipe Radius TABLE 18 OH -Gas Effluent Air Permit Compliance Monitoring W.P. Ballard and Downgradlent Properties Greensboro, North Carolina Effluent Concentration (ASP-3) Days of Effluent Effluent System Temperature Flow Rate Carbon Hydrogen Data Operation ASP-3 ASP-3 Ben- Tatrachlorlds Chloroform Chloride Methylene Chloride Tatrechloroethone Vinyl Chloride ° Rankine (clm) (p b-v b-v ") (P by) (ppb-v) (pp") ( b-v) 328/01 3 570 586 <0.13 -0.13 -0.13 - NA -0.13 0.17 -0.13 426/01 4.5 590 334 <0.58 <0,56 <0.64 NA 2.2 5.3 -0.67 5/11/01 5 1 552 837 0.59 <0.56 <0.64 NA <0.67 5.3 <0.67 0/14101 15 550 683 <0.14 <0.14 <0.14 NA <0.14 98 <0.14 726I01 32 5W 610 <0.14 -0.14 <0.14 NA <0.14 <0.14 -0.14 823101 21 566 610 <0.14 NA <0.14 NA <0.14 <0.14 <0.14 916I01 10 556 1010 7.30 <0.58 -0.66 NA -0.69 5 -0.69 Note: Analyte Molecular Weight (1bAb-mole) Benzene 78.12 Carbon Tetrachloride 153.81 Chloroform 119.37 Hydrogen Chloride 36,46 Methylene Chloride 84.93 Tetrachloroethene 185.82 Vinyl Chloride US The formulas used to calculate emission rates are: Mass Removal Rate is I day) = mw(P/RT)(OHB)(CID) where: race= molecular weight of contaminant(lbMmole) P = atmospheric pressure (1 atm) R = universal gas constant (0.7310 ils•abnAb-mole-R) T = temperature (degrees Rankine) O = system flow rate (cfm) B = conversion factor (1440 miNday) C = concentration of hydrocarbons (ppmv) D = total volume (1E+09) Mess Removal Rate (# I hour) = mw(PIRTXQXBHC/D) where: mw = molecular weight of contaminant (lb/Ibmole) P = atmospheric pressure (1 atm) R = universal gas constant (0.7310 as'atMlRrtale-R) T = temperature (degrees Rankine) O = system flow rate (chn) B = conversion factor (60 min/hour) C = concentration of hydrocarbons (ppmv) D = total volume (1 E•09) Temperature Conversion (Fahrenheit to Rankine) ° Rankine = ° Fahrenheit • 460 Air Flow Rate Calculation D = (VXA) O = Alf Flow Rate (chn) V = Air Velocity - measured (fpm) A = Cross Sectional Area of Pipe (x•�) r = Pipe Radius Tables 17 8 18.xis Page 1 of 2 Revised: Tables 17 a 18.xh TABLE 18 (Continueco Off -Gas Effluent Air Permit Compliance Monitoring W.P. Ballard and Dow ipadient Properties Greensboro. North Carolina Mass Remcnral Hato Cummalalrs Mass Emmlaslons for 2001 Carbon Carbon Dab Benzene TetrachlorideHChlomfbm Hydrogen Chloride Mothylme Chloride Tetrachlorodhens Vinyl Chloride Boman. Tetrachloride Chloroform Hydrogen Chloride Mothylons Chloride Tatrachtorcd bons Vinyl Chiodds Ibarhour Ibafda Ibslhou Ibafday) Ibafday)Ibafda Ibaido ibsiday Ib(Ib.) Ib.l IW Ib• (Ib32fl101 0.0000 0.0000HA NA 0.0000 0.0000 0.0001 0.0000 0.0ow 0.0000 0.0000 NA 0.0000 0.0002 0.0000 426io1 0.0000 0.099oNA NA 0.0002 0.0000 0.0010 O.00DO 0.000O 0.0000 0.0000 NA 0.0009- 0.0048 0.0000 5f11i01 O.0001 0.0000NA NA 0.0000 0.0000 0.0020 0.000D 0.0007 0.0000 0.0000 NA 0.0009 MOM 0.0000 6114101 0.0000 0.0000 . NA NA 0.0000 0.0000 0.0389 O.G000 0.0007 0.0000 0.0000 NA 0.0008 0.601a O.0000 728101 0.0000 0.0000 0.0000 NA NA 0.0000 0.0000 0.0000 0.0007 0.0000 0.0000 NA 0.0009 0.601a 0.0000 023lO7 0.0000 0.0000 NA NA 0.0000 0.0000 0.0000 0•�7 O.W00 0.0000 NA 0.0009 O.a0fa 0.0000 9=1 0.0020 0.0000 0.0000 NA NA 0.0000 0.0000 0.0030 �Ed 0.0211 0.0000 0.0000 NA 0.0009 0.a315 0.0000 Compound (CAS Number) Carcinogens I ear Accute Systemic Toxbant Ibfhour Accute Irritants Ib/hr Benzene 7743-2 8.1 Carbon Tetmchloride 56-235 460 Chloroform 67585 290 d n CAbride 7647-01-00 0.18 Mefh na Chloride 74-87-3 1,600 0.38 Tetrochloroethem, 127,184 13000 Vinyl Chloride 75-0144 26 Tablas 17 a 18.x1s Page 2 of 2 Revised: Tobias 17 a 18.xh