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HomeMy WebLinkAboutWI0400033_Underground Injection Summary Report_20100719Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility 515 West Balfour Avenue Asheboro, Randolph County, North Carolina Ground Water Incident No. 21340 Site Priority Ranking 60/1) June 22, 2010 Prepared For. Kayser -Roth Corporation Greensboro, North Carolina Submitted To: North Carolina Department of Environment and Natural Resources Division of Water Quality — Aquifer Protection Section Underground Injection Control Program Raleigh, North Carolina 27699 Prepared By: Duncklee & Dunham, P.C. Cary, North Carolina DUNCKLEE & DUNHAM, P.C. RECEIVED / DENR / DWQ Aquifer Protection Section ' JUL 19 2010 D UNCKLEE -. - & DUNHAM June 22, 2010 Mr. Thomas Slusser, L.G. North Carolina Department of Environment and Natural Resources Division of Water Quality Aquifer Protection Section — Underground Injection Control Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 ENVIRONMENTAL CONSULTANTS 511 KEISLER DRIVE - SUITE 102 CARY, NORTH CAROLINA 27518 OFFICE: (919) 858 - 9898 W W W. DUNCKLEEDUNHAM.COM Reference: Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina Ground Water Incident Number 21340 Site Priority Ranking 60/D Dear Mr. Slusser: On behalf of Kayser -Roth Corporation (Kayser -Roth), Duncklee & Dunham, P.C. has prepared this June 22, 2010, Underground Injection Summary Report for 2003 through 2009 for the above -referenced site. This report presents a summary of current injection activities conducted from 2003 through 2009. The injection of potassium permanganate is remediating the source area plume to the remediation goals specified in the Corrective Action Plan. Adjustments to the remedial approach will be needed to deliver the oxidant throughout the plume. If there are any questions, please do not hesitate to contact Mr. Dave Duncklee at dave(a)dunckleedunham.com or (919) 858-9898, or Mr. Laval Choiniere of Kayser -Roth at (336) 547-4766. Sincerely, DUNCKLEE & DUNHAM, P. C. -�, ; � B s n D. Trexler Jr. Ph.D.�P.G. R.S.M. I:Y � > Senior Hydrogeologist ,_ - ..-� Id L. Dunc ee, P. R.S.M. Senior Hydrogeologist RECEIVED / DENR / DWQ Aquifer Protection Section c: Mr. Laval Choiniere — Kayser -Roth Corporation, Greensboro (2) JUL 19 2010 Mr. Kim T. Caulk, P.G. — DENR Inactive Hazardous Sites Branch Ms. Doris H. Osborne — Adjacent Property Owner P:\Kayser-Roth\Asheboro-026W\DWQ Phase\UIC Tasks-Proposals\Injection Permit Dmuments\2010\UIC Summary Report-10053.doc MAILING ADDRESS — POST OFFICE BOX 33366 — RALEIGH, NORTH CAROLINA 27636 Table of Contents Letter of Transmittal Table of Contents I 1 Introduction 1 1.1 Site Background 1 1.2 Corrective Action Plan and Injection Permitting 1 2 Injection Activities and Results 1 2.1 Injection Pilot Tests 1 2.2 Phase III Injection 3 2.3 Water Injection 4 2.3.1 Water Injection Process 4 2.3.2 October 2007 Saprolite Results 4 2.3.3 October 2007 Bedrock Results 6 3 Conclusions and Recommendations 8 3.1 Conclusions 8 3.2 Recommendations 9 4 UIC Documents Produced 9 ID i i Figures Fi ure Title 1 USGS Topographic Map 2 Site Plan 3 2003 Direct -Push Injection Locations 4 Snapshots of Saprolite Plume from 2001 to 2005 5 Potassium Permanganate Slurry Injection Locations 6 PCE Plume in Bedrock Unit — Pre Injection March 3, 2005 7 PCE Plume in Bedrock Unit — Post Injection May 23, 2005 8 PCE Plume in Bedrock Unit — Post Injection August 9, 2005 9 PCE Plume in Bedrock Unit — Post Injection December 6, 2005 10 Site Plan with Water Injection Locations — September 24-27, 2007 11 Saprolite Unit Ground Water Contour Map — October 2007 12 Bedrock Unit Ground Water Contour Map — October 2007 13 PCE Plume in Saprolite Unit — October 2007 14 PCE Plume in Bedrock Unit — October 2007 15 PCE Plume in Cross Section B-B'- October 2007 Tables Table Title 1 Historical Analytical Data Appendices Appendix Title A Historical Water Levels B Historical Inorganic Parameters C Historical Field Parameters iii Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility 515 West Balfour Avenue Asheboro, North Carolina I1 Introduction 1.1 Site Background ` The Kayser -Roth Corporation (Kayser -Roth) Asheboro plant facility ("the site") is located at 515 West Balfour Avenue in Asheboro, North Carolina (see Figure 1). The plant currently manufactures socks and the property contains one main plant building and several smaller outbuildings located to the south and southeast of the main plant (see Figure 2). In 1999, environmental site assessment activities detected several chlorinated volatile organic compounds (VOCs) in ground water at concentrations exceeding North Carolina 2L ground water standards. The primary ground water constituent detected. is tetrachloroethene (PCE). 1.2 - Corrective Action Plan and Injection Permitting In 2001, Duncklee & Dunham, P.C. (Duncklee & Dunham) continued site assessment activities and _prepared a Corrective Action Plan (CAP) to address ground water remediation. The CAP, submitted to the North Carolina Department of Environment and Natural Resources (DENR) in 2002, outlined a plan to address the dissolved PCE plume through in -situ chemical oxidation (ISCO) via injection of potassium permanganate. An injection pilot test was proposed in the CAP to determine the most practical and cost-effective method of oxidant delivery and to estimate overall ground water treatment time. Duncklee & Dunham submitted an Application for Permit to Construct andlor Use a Class SI Injection Well to the DENR, Division of Water Quality (DWQ), Aquifer Protection Section (APS)-Underground Injection.Control (UIC) Program in late October 2002. An injection permit, WI0400033, was issued to Kayser -Roth by DWQ on January 7, 2003. Duncklee & Dunham requested an amendment to the injection permit in a correspondence" dated September 27, 2004, which included injection data results current through 2004. DWQ amended the permit in early 2005 to allow the injection of permanganate slurry in the suspected source area. The injection permit was renewed and approved without modification on August 1, 2007. 2 Injection Activities and Results 2.1 Injection Pilot Tests Phase I injection pilot test activities were performed on July 14-16, 2003. Approximately 2,600 gallons of 1 to 1.5 percent potassium permanganate solution (permanganate solution) was injected into saprolite well MW-IOc, bedrock well DW-1, and five direct -push injection points (IB-1 through IB-5) advanced to depths ranging from approximately 24 to 40 feet below land surface (ft bls) along the south fence line (see Figure 3). ]� DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22; 2010 Page 2 of 10 Phase II injection pilot test activities were performed from September 16-19 and 22-25, 2003. Approximately 20,000 gallons of 2.5 to 3 percent permanganate solution was again injected into wells MW-10c and DW-1 along with seven additional direct push injection points (IB-6 through IB-12) advanced to depths ranging from 28 to 38 ft bls along and south of the fence line in the vicinity of the lithologic contact zone identified during the CAP development activities (see Figure 3). Ground water levels were collected from the monitoring wells (see Appendix A Water Levels) and water samples collected and analyzed for VOCs according to SW-846 Method 826.0. As part of the post - injection monitoring, samples from saprolite wells MW-1, MW-3, MW-6b, MW-8, MW-10b, MW-12, MW-17, MW-21, and bedrock wells DW-2 and DW-3 were also analyzed in the laboratory for manganese and chromium according to Method 200.7 and for chloride according to Method 325.2 (see -- Appendix B). Field measurements included pH, specific conductance, oxidation reduction potential (ORP), dissolved oxygen (DO), and temperature (°C) were also collected (see Appendix Q. Pre and post -treatment monitoring was performed on wells MW-1, MW-3, MW-6b, MW-8, MW-10b, MW-12, MW-17, MW-21, DW-2 and DW-3 as outlined in the CAP and in the injection permit application. Significant reductions in PCE concentrations were noted immediately after the first injection event in MW-8 and MW-10b and immediately after the second event in MW-17 (see Figure 4). A semiannual ground water monitoring event was performed on May 24-28, 2004. Ground water levels and samples were collected from all monitoring wells except saprolite wells MW-2b, MW-9, MW-14 through MW-16, MW-18 and MW-19 (see Appendix A Water Levels). Well MW-2b remained inaccessible, and off -site wells MW 9, MW-14 through MW-16, MW-18 and MW-19 were dry. The 2004 shape and extent of the PCE plume in the saprolite unit wells is generally similar to that detected in late 2001 (see Figure 4). The May 2004 semiannual sampling results indicate that the PCE concentration in well MW-10b rebounded since the previous sampling event in November 2003 and was slightly above levels detected in early to mid-2001. The PCE concentration in well MW-3 had decreased since the previous sampling event in November 2003, but it remained above late 2001 levels. The PCE concentration in well MW-17 had decreased significantly since the November 2003 sampling event and showed a notable decrease compared to late 2001 levels. Well MW-8 also showed a decreased PCE concentration compared to both the previous sampling event and late 2001 levels. Bedrock wells DW-1 and DW-2 showed increased PCE concentrations compared to previous reductions caused by Phase I and II injections as evidenced in the November 2003 and late 2001 results (see Table 1). PCE levels in DW-3 remained stable and well DW-5 showed only trace levels of impact. Bedrock well DW-4 showed no PCE contamination. After a period of about six months subsequent to the Phase II injection, VOC concentrations in saprolite wells near the source area rebounded to pre -injection levels (see Figure 4 and Table 1). Aquifer recontamination in the shallow aquifer zone was attributed to dissolution of residual contaminants remaining in the source area. The 1 to 3 percent permanganate solutions, while highly effective in the dissolved VOC area of the ground water plume, was not able to overcome the residual VOC levels in the source area. DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22; 2010 Page 3 of 10 2.2 Phase III Injection Phase III injection was conducted on March 15-17, 2005, and involved injection of a more concentrated potassium permanganate slurry into the source area. The Phase III injection plan consisted of the placement of 30 to 35 percent potassium permanganate slurry in the vicinity of MW-1Ob using 11 direct - push injection points (see Figure 5). Approximately 330 pounds of potassium permanganate along with 100 gallons of water was injected in each point along and south of the fence line in the vicinity of g J P g tY MW-10b and along the lithologic contact zone previously identified in this area (i.e., the same area where the Phase I and II injection borings were completed). Pre injection ground water monitoring was performed on March 9-10, 2005, followed by post injection events on May 23-26, August 9-10, and December 6-7, 2005. Ten wells were sampled to evaluate the effectiveness of the injection activities. Ground water samples were collected from MW-1, MW-3, MW-8, MW-10b, MW-11, MW-17, MW-21, DW-1, DW-2 and DW-3. CAP semiannual sampling events were performed during May 23-26 and December 6-7, 2005. Samples were collected from all of the wells except for MW-2b, inaccessible, and off -site wells MW-14 through MW-16, and MW-18 which are dry. MW-9 and MW-19 were dry during the December sampling event. PCE was the primary plume constituent in both the saprolite (MW) and bedrock (DW)- wells (see Table 1). Prior to Phase III injection activities PCE was detected in saprolite wells MW-3, MW-8, MW-10b, MW-17, and MW-21. Monitoring wells MW-10b and MW-17 showed the greatest impact from the PCE. Sampling subsequent to the Phase III injection event showed a decrease in PCE concentration in MW-IOb and MW-17, while saprolite wells MW-6, MW-8, MW-13, and MW-21 remained relatively unchanged. Six months after injection the PCE concentration in MW-10b continued to be below laboratory detection limits (BDL) while MW-17 also showed.a significant drop in PCE concentration. Visual observations of the ground water during well purging activities indicated the presence of permanganate (purple color) in two wells. Well MW-IOb well water has exhibited a purple color during each post -Phase III injection event. Well MW-17 for the first time (post -Phase III injection) showed a slight purple tint during the December 2005 sampling event. Trichloroethene (TCE) was detected in saprolite wells MW-3, MW-10b, and MW-17 prior to Phase III injection. After Phase III injection, TCE in MW-10b and NW-17 was BDL while MW-3 showed a small increase. No other VOCs were detected in the saprolite unit wells. Chloroform, PCE, and TCE prior to Phase III injection and after injection remained relatively unchanged in the bedrock wells. PCE was detected at concentrations of 400 micrograms per liter (ug/L) in DW-I. TCE was detected at 27 ,ug/L in DW-3. Trace levels of chloroform were detected in all bedrock wells, with the exception of DW-1. The PCE data collected in the bedrock unit wells prior to Phase III injection activities and the follow up sampling have been contoured in plan view (see Figures 6, 7, 8, and 9). r__ DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 4 of 10 ORP readings, pH readings, and electrical conductivity continue to be stable with minor fluctuations, and no discernible trends (see Appendix Q. Well MW-10b was not measured for any field parameters because of the visible presence of permanganate in the well water. DO continue to be stable in the monitoring wells. Dissolved manganese prior to and post Phase III injection appears to be unchanged with the exception of MW-10b and possibly MW-17. Manganese in MW-10b since Phase III injection has increased significantly and remains higher than pre Phase III injection levels. The levels of chromium and chlorides have remained relatively unchanged in the monitoring wells (see Appendix B). Field. and analytical data obtained during ground water sampling subsequent to the Phase III injection event showed evidence that potassium permanganate had reached a,static state over time within the original injection zone. Therefore, a plan was developed to inject water into the shallow aquifer and suspected source area to better distribute the potassium permanganate slurry and improve oxidant contact with the contaminants. 2.3 Water Injection and Results 2.3.1 - Water Injection Process In February 2007, Duncklee & Dunham requested that the injection permit be renewed to facilitate water injection in to the aquifer. The purpose of the injection was to improve distribution and contact of residual potassium permanganate with the aquifer by moving the slurry farther away from the injection zone. The DENR approved the injection permit renewal as documented in a letter dated August 1, 2007. Subsequently, on September 24-28, 2007, water was injected into boreholes within the source area near the Phase III injection wells. The Phase IV water injection was performed by Geologic Exploration of Statesville, North Carolina at nine soil boring points (Pt-1 to Pt-3 and Pt-5 to Pt-10, see Figure 10). Each point was advanced with a direct push rig using two inch rods. Borings were advanced to approximately 30 ft bls (ft bls), with the exception of Pt-3 and Pt-8 which were advanced to refusal at 22 ft bls and 28 ft b1s, respectively. During the Phase IV injection event, water was injected into the potassium permanganate slurry in the shallow saprolite portion of the aquifer. City of Asheboro municipal water was injected into the injection points described above at pressures ranging from approximately 150 to 200 pounds per square inch (psi) at a rate of four to ten gallons per minute (gpm). Approximately 5,969 gallons of water was injected in to the shallow saprolite aquifer unit. 2.3.2 October 2007 Saprolite Results Following the water injection, the CAP semiannual ground water monitoring was performed on October 8 and 9, 2007. This was the sixth monitoring event performed following -the Phase III injection event. Physical and geochemical parameters were collected from saprolite monitoring wells MW-1, MW-3, MW-6b, MW-8, MW-13, MW-17, MW-20, MW-21, MW-22, and bedrock wells DW-1 through DW-5. Additionally, monitoring well MW-11 was sampled during this event. Monitoring wells MW-7, MW-1Ob MW-14, MW-15, MW-16 and MW-18 were dry. DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 5 of 10 Figure 11 shows the saprolite unit ground water contours and Figure 12 shows the bedrock unit ground water contours. The October 2007 flow directions are similar to past. events. During the ground water sampling process, field geochemical parameters were collected from select monitoring wells. Additionally, a field colorimeter instrument was used during the recent sampling event to evaluate potassium permanganate concentrations in select wells. This field data are summarized in Appendices B and C. PCE remains the primary ground water constituent present in saprolite and bedrock aquifer unit wells (see Table 1). Recent PCE results found in the saprolite and bedrock aquifer unit wells collected during the October 2007 semiannual sampling event have been contoured and shown in cross section and plan view on Figures 13, 14, and 15. During this event, VOCs were detected at various concentrations in MW-3, MW-6b, MW-8, MW-13, MW-17, and MW-21. A summary of historical and recent data results are shown in Table 1. Water levels, inorganic analysis, and field parameter data from this event are summarized on Appendices A, B, and C, respectively. Based on this data, the following observations are made: • Monitoring wells MW-1, MW-6b, MW-11, MW-20, and MW-22 continue to show PCE BDL. • The highest concentration of PCE occurred in MW-17 at 2,350 µg/L. The remaining saprolite wells showed detectable PCE concentrations above the 2L ground water standards at levels ranging from 14.7 µg/L in MW-13 to 456 µg/L in MW-3. • Additionally, analytical data showed degradation compound TCE present in select saprolite wells. TCE was detected above the 2L ground water standard in MW-3 at a concentration of 9.0 µg/L. Chloroform, which historically has been detected in several wells continues to be detected at low levels in several wells but not above the 2L standard. No other target VOCs were detected above the laboratory detection limit or 2L standards. • Among the saprolite wells, MW-10b,MW-8'and MW-17 are used in evaluating the effectiveness of injection activities. An analysis of historical data in these wells shows a good correlation between the byproducts of the oxidation process and PCE concentrations. Trends show that as manganese and chlorides increase in concentration, PCE decreases. October 2007 data collected in MW-8 shows an increase in chlorides and manganese while PCE decreased. Chloride, manganese, and chromium are byproducts of the oxidation process, and are used to evaluate PCE degradation and as a tracer to evaluate the distribution and impact of the oxidant to the aquifer. These results are summarized on Appendix B and the following observations can be made at this time: • Manganese levels remained elevated in saprolite wells closest to the injection zone. Data collected in wells MW-8 (0.905 mg/L) and MW-17 (0.818 mg/L) showed manganese at concentrations slightly higher than peripheral wells MW-6b (0.173 mg/L) and MW-13 (0.161 mg/L). Downgradient wells MW-21 (0.0549 mg/L) and MW-3 (<0.005 mg/L) contained manganese at levels much lower in comparison to wells adjacent to the injection zone. DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 6 of 10 Chloride concentrations continue to be elevated in source area well MW-8 at concentrations of 465 mg/L. Subsequently, chloride levels from the remaining saprolite wells ranged from 5 mg/L in MW-13 to 92.6 mg/L to in MW-6b. • Chromium levels showed a similar pattern to manganese levels. Data collected from saprolite wells closest to the injection zone showed chromium slightly higher than wells located on the periphery or hydraulically downgradient. MW-8 and MW-17 contained chromium at 0.0073 mg/L and 0.0162 mg/L, respectively. Peripheral wells MW-6b and NM-13, and downgradient wells MW-21 and MW-3, showed chromium level below laboratory detection limits. Field parameters collected during the October 2007 sampling event are presented in Appendix C. Additionally, a colorimeter was used to measure the concentration of potassium permanganate in impacted wells (see Appendix B). Based on the data collected, the following observations can be made. • Based on the colorimeter data, detectable levels of permanganate were present in monitoring wells MW-8, MW-3, MW-13, and MW-17. MW-8 exhibited the highest concentration with a colorimeter reading of 1.4 mg/L. Historically, MW-10b has showed the highest concentrations of permanganate. However, during the October 2007 sampling event, MW-10b was dry and could not be sampled or any other analysis performed. • ORP data collected indicate increasing trends in wells closest to the injection zone following the water injection event. Among the saprolite unit wells, MW-8 showed the highest ORP reading at 604 mV (millivolts) while elevated ORP results were also noted in MW-6b (327 mV) and j MW-17 (419 mV). Data collected in the remaining saprolite wells showed ORP readings ranging from 271 mV (MW-13) to 279 mV (MW-21). 2.3.3 October 2007 Bedrock Results During the October 2007 sampling event, PCE was the primary ground water constituent detected in the bedrock wells DW-1, DW-2, DW-3, DW-4 and DW-5 (see Table 1). Based on this most recent sampling event for the bedrock wells, the following observations were made: • Analytical results show PCE continues to be present above 2L ground water standards. DW-2 continues to show the greatest impact of PCE at a concentration of 883 µg/L. In the remaining bedrock wells, PCE ranged from 729 µg/L (DW-1) to 1.1 µg/L (DW-4). - Based on pre -injection and post injection PCE data trends, PCE appears to increase slightly in the bedrock wells following the injection work phases (see Table 1). The post water injection data results also show TCE and chloroform present in the bedrock wells at low to trace levels. TCE ranged from 39.3 µg/L (DW-4) to 4.0 µg/L (DW-5), while chloroform ranged from 33.3 µg/L (DW-4) to 9.0 µg/L (DW-1). No other target VOCs were detected above the laboratory detection limits in the bedrock wells. DUNCKLEE & DUNHAM, P.C. 1, Underground Injection Summary P g Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 7 of 10 • Among the bedrock wells, key wells (DW-1 and DW-2) are used in evaluating the effectiveness of injection activities. An analysis of historical data in these wells shows a good correlation between the byproducts of the oxidation process and PCE concentrations. As manganese and chlorides increase in concentrations, PCE decreases. Manganese concentrations remain relatively low. The chlorides and PCE concentrations appear to be in an increasing trend. As stated earlier, chloride, manganese, and chromium are typical byproducts of the oxidation process to evaluate PCE degradation and are used as a tracer to evaluate the distribution and impact of the oxidant to the aquifer. These data results for the bedrock wells are also summarized on Table 4 and the following observations can be made at this time: • Manganese levels remained elevated in DW-1 (0.379 mg/L) and DW-4 (0.436 mg/L) at concentrations at or just below data results obtained during the pre -water injection monitoring event that occurred in April 2007. The remaining wells revealed no substantive increase or decrease in data trends when compared to the pre -water injection and the October results. • Among the bedrock wells, chloride concentrations are higher in downgradient wells compared to wells closer to the source area. DW-I and DW-4 contain chlorides at concentrations 23.2 mg/L and 27.6 mg/L. However, downgradient wells DW-2, DW-3, and DW-5 contain chlorides at concentrations 120 mg/L, 70.6 mg/L and 42.3 mg/L, respectively. • Analytical data collected in the bedrock wells showed chromium levels decreased slightly in comparison to the April 2007 sampling event. The highest chromium levels were detected in wells closest to the injection zone. DW-1 and DW-4 contained chromium at concentrations 0.0094 mg/L and 0.0072 mg/L while downgradient bedrock well DW-2 contained chromium at 0.0063 mg/L. Data collected in peripheral bedrock wells DW-3 and DW-5 showed chromium below the laboratory detection limit of 0.005 mg/L. Field parameters collected in the bedrock wells during the October 2007 sampling event are presented in Appendix C. Additionally, a colorimeter was used to evaluate during the recent sampling period to ascertain the relative concentration of potassium permanganate in impacted wells. Based on the data collected, the following observations can be made. • Based on the colorimeter data, detectable levels of potassium permanganate were present in three of the five bedrock wells. Upgradient well DW-4 (0.98 mg/L) showed the highest concentration of permanganate while downgradient well DW-3 (0.20 mg/L) showed the lowest concentration of permanganate. • Data collected in the bedrock wells continue to show aerobic conditions. DO levels ranged from 5.75 mg/L in DW-5 to 6.77 mg/L in DW-1. • Based on previous ORP and conductivity readings, no discernable trends can be seen at this time. DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue -_J Asheboro, Randolph County, North Carolina June 22, 2010 Page 8 of 10 Conclusions and Recommendations 3.1 Conclusions Based on the 2003 to 2007 injection events and the ground water monitoring results, the following conclusions are presented. • Injection of 1 to 2.5 percent permanganate solution occurred in July and September 2003, a 30 to 35 percent permanganate slurry was injected in March 2005, and water to stir and reactivate the permanganate slurry was injected in September 2007. • The permanganate solution and slurry is effective in treating the PCE and TCE and reduced a large mass of PCE. • Analytical data showed one biodegradation compound, TCE, present in the saprolite wells. The highest concentration of PCE based on the last sampling event (October 2007) occurred in saprolite well MW-17 at 2,350 µg/L. The water injection event appears to have had a short-term impact in this well and additional activation of the permanganate slurry is needed. The October 2007 128 µg/L for PCE in saprolite well MW-8 is the lowest concentration detected in this well in two and a half years. Ground water in this well exhibited the highest colorimeter reading of dissolved permanganate of the wells sampled. Chlorides and manganese have increased as PCE has decreased. This shallow well is adjacent to and hydraulically downgradient of the slurry injection and water injection area. The water injection event appears to have had a short term impact in this well and additional data is needed to evaluate the long term effects. Field indicator parameters measured in key shallow saprolite wells suggest VOCs may be degrading aerobically (cometabolism) due to the high DO and via enhanced degradation resulting from the potassium permanganate injections as noted by the high ORP values. Based on the historical data collected at the site, Duncklee & Dunham does not believe this ground water system is capable of shifting to an anaerobic state. In the bedrock wells, based on pre -injection and post- injection PCE data trends, PCE has increased slightly following the injection work phases. This can possibly be explained by the formation of PCE concentration gradients in the aquifer as a result of the permanganate injection. The water injection is believed to mobilize the PCE to a certain extent at depth as it comes in contact with the permanganate slurry. However, future monitoring events should reveal if PCE degradation is occurring or additional source is impacting ground water. The post injection data results indicated TCE and chloroform were present in the bedrock wells at low to trace levels. TCE ranged from 39.3 µg/L (DW-4) to 4.0 µg/L (DW-5), while chloroform ranged from 33.3 µg/L (DW-4) to 9.0 µg/L (DW-1). No other target VOCs were detected above the laboratory detection limits in the bedrock wells. Bedrock wells DW-1 and DW-4, used to evaluate the injection process in and adjacent to the source area, indicate PCE levels are slow to degrade. However, residual impacts of the potassium permanganate oxidation process .are present in the deep wells as evidenced by increased magnesium concentrations. DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 9 of 10 • It is believed that the chloride concentrations measured in the monitoring wells are a direct result of the dechlorination of both PCE and TCE. In wells closest to the source area, TCE and chlorides were detected at similar concentrations. However, the downgradient wells show a proportionately higher concentration of chloride than TCE. It is believed this phenomenon. is possible due to the distance and time traveled thereby allowing enough time to for the breakdown of TCE to add to the amount of chlorides produced by the PCE oxidation processes. 3.2 Recommendations Based on the 2003 to 2007 injection events and the ground water monitoring results, the following recommendations are made. • It is recommended that the potassium permanganate continue to be used as the injectate for the remediation of the PCE and TCE compounds in the saprolite and bedrock plumes. • A sampling event of the saprolite and bedrock wells should be conducted to continue the evaluation of the effectiveness of the remediation since the October 2007 sampling event. • Another water injection, or similar type event, should be considered in the area where the permanganate slurry was injected and possibly southward along the fenceline. Consideration for injection again in DW-I should also be reviewed.. • A sampling event of the select saprolite and bedrock wells should be conducted several months after any additional injection event to continue the evaluation of the effectiveness of the remediation. • In the future, the bedrock unit needs permanganate injected directly into the plume and a sampling event conducted several months later to evaluate the effective of the injection event. 4 UIC Documents Produced The following list of documents has been provided to the Underground Injection Control Program in the past and these documents were used to prepare this summary document. Duncklee & Dunham, P.C., 2002, Application for Permit to Construct andlor Use a Well(s) for Injection, Class 51 Wells, 515 W Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Water Quality, Underground Injection Control Program, Raleigh, August 26. Duncklee & Dunham, P.C., 2004, Semiannual Ground Water Monitoring Report, Asheboro Sock Facility, SI S W Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Water Quality, P Q tY Groundwater Section, Winston-Salem, March 9. i DUNCKLEE & DUNHAM, P.C. Underground Injection Summary Report for 2003 through 2009 Asheboro Sock Facility, 515 West Balfour Avenue Asheboro, Randolph County, North Carolina June 22, 2010 Page 10 of 10 Duncklee & Dunham, P.C., 2004, Injection Pilot Study Status Report and Permit Amendment Request, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina: Prepared for Kayser -Roth Corporation and Submitted to Department of Environment and Natural Resources, Division of Water Quality, Aquifer Protection Section, Raleigh, September 27. Duncklee & Dunham, P.C., 2004, Semiannual Ground Water Monitoring Report, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources,, Division of Water Quality, Groundwater Section, Winston-Salem, October 15. Duncklee & Dunham, P.C., 2004, Semiannual Ground Water Monitoring Report, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Water Quality, Groundwater Section, Winston-Salem, November 10. Duncklee & Dunham, P.C., 2006, Semiannual Ground Water Monitoring Report, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Water Quality, Aquifer Protection Section, Winston-Salem, February 24. Duncklee & Dunham, P.C., 2007, Semiannual Monitoring and Injection Report, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site.Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Waste Management, Superfund Section, Winston-Salem, May 31. Duncklee & Dunham, P.C., 2007, Application for Permit to Construct and/or Use a Well(s) for Injection, Class 51 Wells, 515 W. Balfour Avenue, Asheboro, Randolph County, North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to NC Department of Environment and Natural Resources, Division of Water Quality, Underground Injection Control Program, Raleigh, February 6. Duncklee & Dunham, P.C., 2008, October 2007 Semiannual Ground Water Monitoring and Injection Evaluation Report, Asheboro Sock Facility, 515 W. Balfour Avenue, Asheboro, Randolph County, _ North Carolina, Groundwater Incident Number 21340, Site Priority Ranking 60ID: Prepared for Kayser -Roth Corporation and Submitted to Department of Environment and Natural Resources, Division of Waste , Mana ementSu erfund Section, Inactive Hazardous Sites Branch, Winston- Salem, March 14. pj DUNCKLEE & DUNHAM, P.C. !r �+ r -��• 1. \�\ ,l�.�•'-/•` \ lot(/ 7 :X' 16 ry till 69 jit SITE ?P j r 1�� � h `il�.-,%� • _ - �.. ! f ���+ At .� fps � � t { >✓�� .� � � �,,�./'r�"./IrJ �,� � 1 � t i to a: f _ t , " ,�A• 1 if �.{ ors• .i I �, �"- Source Map: U.S. G.S. Asheboro 7.5-Minute Quadrangle. DUNCKLEE & DUNHAM, P.C. Approximate Scale: Title: ENVIRONMENTAL CONSULTANTS I" = 2000' USGS Topographic Map 511 KEISLER DRIVE - SUITE 102 Figure: Project: CARY, NORTH CAROLINA 27518 Asheboro Sock Facility 1 Asheboro, North Carolina Wooded .Area M\\'-22 & 9 DUNCKLEE °"I��o ,1 F`°" N; o? \ -5 fi• / & DUN f LAM CARP, NORTHCAROLGJA 27511 � OFFICE. li1})45i-9898 WED WNCKUMUMAIVICOM Job No. Layers Date 02600 0' l' 1 /28/2008 ® b1W-12 Drawing Figure Scale 02600-1 2 As Shown Water 1V1Vc�-11 Towers it e Estimated Impacted "0 Site Plan Source Area MW-4 O ' ASTs Project Kayser Roth Facility Asheboro, North Carolina Brick DW -4 Residential �''-13 �: ' �'-106 Home Q Legend MW-17 0 Property Line X Fence Line Main Pump Plant /House Building MW-16 Saprolite Unit Well Brick MW-14 Garage MVO' 18 -19 N V-3 NnV-2b DW-3 Bedrock Unit Well Electrical Substation B B' Cross Section Line DW-1 Mobile Boiler Homes ®DW-2 House b1\k'-20 NI\ '-1 S DW-3 M\V-1 DW-5 Trailer Park ip M\1'-19 16 Parking " �'-� ---- Fence Lot Bun-"" Road (SR 1500 Scale 90 45 0 90 180 1 "=90' MW-P Duncklee & Dunham, P.C. Environmental Consultants ® MW 12 Author Drawing Layers Date DIVIR 02600-1a 0,19 10-30-01 Wooded Job No. Revision Figure Scale MlX/-1102600 9-24-04 3 1 "=50' 0 ® Title 2003 Direct -Push Injection Point Locations IB-3 1IIW-411 O • Q Project D�yi'-F O Asheboro Sock facility MW-13 ® I:-11 Asheboro, North Carolina �U-10b -10C O -9 1vIVG'-17® _ p �-4 0 Legend: IB-7 IB-8 ® NiW-6b '- ®IVIW-1 5aprolite Unit Monitoring Well ❑ B_ Main Plant 1HDW-1 Bedrock Unit Monitoring Well MW-22a) MW-21$ Building bIW-14 B Property Line lvfw 18® ® 1v1W- MTV-21e • 1B-2 Direct -Push Injection Point R ® ❑ w� DW-1 C 14 R ®DW-2 El -?� ® DW-3 Trailer Park MW-1 DW-5 MW-1� MW-16 Parking Lot MW- 6) fence Burmii Road (SR 1500) Wooded N1W_11ia ❑ MW-18 VIW-20 jD (BDL) DLL'-5 November 2001 Pre Phase I Injection 40 June 2004 Pre Phase III Injection of 0 MW-200 (BDI,) DW-5 Tip--'-11 ;BDI; MAX'-4 L)i " igkb Da-4 NIW-6b MiX'-1 \J b'IW-4 0 (<1) B B DW-4 NRt'-1 N -10b (-1) MW-6b (5.41 9 (NS) N & S( S MW-18 Y. 0 x x DW-2 X?y(NS+ M)XI-20Q) NIX 1- MVP 1 << a (\. DW-5 October 2006 Legend Mi7L'-] 1 OTAW-11 ti ®MW-1 Saprolite Unit Well N]W-4 QO (BDL Nam'-4 DW_4 � (� O � E NIW-13Q' ] DW-4 DW-1 Bedrock Unit Well 0(5,800) MW- h° '-10b (BD ) Nltx;_17 (6,100) Tetrachloroethene Concentration in ppb (BQ L) NIW-6b 17 (2) NIX'-6b PCE Concentration 1,000-10,000 ppb ✓-2] MW !D PCE Concentration 100-1,000 ppb ! (24 N1W-14 •� � 3 ElN, g ❑ PCE Concentration 10-100 ppb 1 ( 0 ] PCE Concentration BDL-10 ppb DNX-2 DW-2 NU 20 ^ August 2005 September 2003 MW i Mt�i_20 MW-1 M P 'BO LI Two Weeks Post hzW_1 Post Phase II Injection D\X'-5 cBDLI Phase III Injection DW.-5ENTAL t�nl,l 0 0. Layers ate Title DUNCKLEE avv.ROLES LR VECONSSUITE UI EN02 02600 1 12-15-2005 Snapshots of Saprolite Plume from 2001 to 2005 CARY. NORTH CAROLINA 27511 & DUNHAM OFFICE 919)85B-9898 cawing lgure Scale Project WEB DUNCKLEEDUMAMCOM 4 Not to Scale Asheboro Sock Facility, Asheboro North Carolina Wooded Area MW-22 DUNCKLEE ENvtiLONMENrAL CONSULTANTS s11 KELA.ER GRrvE - SUITE 102 CART, r+oRni caea.Bm Mn& DUNFiAM OFFICE rq19)esa-9e9a WEB SWCK WUNIAM COM Job No. Layers Date 02600 0, 1,20 1/28/2008 � M\x'-12 Drawing Figure Scale 02600-1 5 As Shown ® Water MW-11 Towers Title Estimated Impacted Potassium Permanganate Slimy Injection Locations O Source Area M\V-4 ASTs Project Kayser Roth Facility B- N Asheboro, North Carolina Brick SIB-23 DW-4 Residential NRV-13 fir IVG'_10b Home �� B- 3 SIB-22 IB-21 O Legend iB-i iB-zo MW7_17 ,%: 1B-1 _» Q Property Line iB MW-6b 1 -19 �( Fence Line Main PumpL-1 Plant OMW-16 A1W-21� /House Building Saprolite Unit Well Brick Garage MW-14 - MW-18 9 Bedrock Unit Well ® Electrical Substation • 113-2; Injection Points for March 2005 D\W-1 Permanganate Slurry Injection l3 R Cross Section Line Mobile Boiler Homes ®DW-2 House MNV-20 _ - 6 DW-3 M\V_1 D\w'-5 Trailer Park ik &RV-19 MW-16 Parking —Fence Lot Bumvl Road (SR 1500) Scale 90 45 0 90 180 1 "=90' Wooded Area M\V-22 & Estimated Impacted Source Area Brick Residential ��\ -7 3 S Home IviW-17 i MW TiW-21 Brick T `-14 Garage &� it :�l rD MW-18 rz r v, rD rD Mobile Homes TIW-20 0 DW- Trailer Park (N'S) al' TI\V-19 T '-9 BUrrnil Road (SR 1500 J Wooded Water Towers TIW-4 DW-4 10br w, (NS)O MW-6b Pump /House 91 DW-2 W MW-1 1 �H �a --- ' 0 G APT-5 S 00 Y C U r` U b W 3 3 Z O Rt' r4 « N i-r R Ln .S �L STs N o � �v 'n Plain Plant ,n Building o TIW-2b Electrical Substation Boiler Legend U House M\' a� o °r l� — — — Property Line ., solo,DW-3 (S>) X Fence Line Q� lv1W-16 Saprolite Unit Well Z Z 7---J y o� N N DW-3 Bedrock Unit Well o y o o �--� Cross Section Line p � U w p cs a a� Q (390) PCE Concentration in ppb- (BDL) Below Labratory Detection Limit - (NS) Not Sampled `- swwdw by D.I. In}2mxi l PCE Concentration 1,000-10,000 ppb U Fence Parking ® PCE Concentration 100-1,000 ppb c Lot 0 0 PCE Concentration 10-100 ppbCd 3 3 p ■ ® PCE Concentration BDL-10 ppb p V)) Fi aure 0 100' 200' 6 MEMi Graphic Scale: V = 100' � o a Q O ^y U W � 3 MW-12 a 1z Wooded Area ® Water „ N 1\fW"-11 Towers rA 5 Estimated Impacted !1 B Q w U Source Area b1\Y'-4 1 ASTs N •y z Brick DW-4 � Residential MW-13 9 M W- I ObI. U Home O h1W-17 O MW-R MW-6b Main Pump Plant o N1\V-22 & IVIW-21 /House Building Brick X -14 Ll Garage_3 1\,IW-2b N y MW-1 SfD A Electrical Substation �• A O r Boiler Legend y Mobile House DW Homes -2 o w 72 _ _ _ Property Line = � / 1,1\lr' 20 DW-3 0 U w `;t MW-1 (92ff x------ n Fence Line aFi o DW B 0 bi\V-16 Saprolite Unit Well � 0 z � c Trailer Park (4) � Z � Cq ® DW-3 Bedrock Unit Well 0 0 o CU Cross Section Line b1W-19 pa d MW-16 (190) PCE Concentration in ppb 0- O3n1- Below Labratory Detection Limit (\i) Not Sampled iu 1 a U in Da by sa W by llata Inferred 0 ❑ PCE Concentration 1,000-10,000 ppb a N -9 �.J 1 Fence i Parking (3 Ej PCE Concentration 100-1,000 ppb Lot 0 a 3 II i PCE Concentration 10-100 ppb � ■ ® PCE Concentration BUL-10 ppb Bur�;1 Road (SR lsao� Figure 0 100' 200' Wooded Graphic Scale: 1 " = 100' Table 1. Historical Ground Water VOC Analytical Data MW-1" Sample Date PCE in µg/L TCE in µglL Chloroform in 0811, cis 1,2-DCE in µg/L tran 1 2-DCE inµ L Manganese in m Chromium in mglL Chlorides in m L A nl9 1999 <5 <5 5 5 NA NA NA Judy 9 1999 <5 <5 <5 <5 <5 NA NA NA September 21999 <S <5 <5 <5 5 NA NA NA September 14 2000 <1 <1 2.7 <1 <1 NA NA NA Feliniary 15 2001 <0.3 <0.5 2.4 <D.5 <0.5 NA NA NA 8.2001 <1 <1 2.1 <0.5 <0.5 NA I NA NA ovember 27 2001 <1 <1 3.3 <] I <1 0.12 NA 9.7 xil 9,2003 <1 <1 <1 <1 <1 0.14 <0.002 96 IIIIILIRRvnh a 1 Pilot T >il 30 2003 <1 <t <1 i <1 0.14 002 42 q4 13 2003 <1 I <1 I 0.13 o2 U ase II Pilot Test Se tember 29 2003 <1 <l <i <I <l 0.13 . <0.002 90 " October 27 2003 <1 <I L2 <I <1 0.13 <0.002 100 November 24, 2003 <1 <I -1 <l <1 014 <0.002 120 Fe 16 2004 <1 <1 <1 <1 <1 0.15 <0.002 69 M 27 2004 <1 <1 <I <1 <1 0.14 <0.002 130 March 3 2005 <1 <1 <5 1 0 I2 <0.002 5�) May 23, 2005 <1 <1 `, Slurry InjeCti " <5 <1 <I NA NA NA August 9 2005 <I <1 <5 <1 <I 0.084 <0.010 35 December 5 2005 , I 7 <1 <5 <I <1 NA NA NA April 10 2006 <1 <1 <1 <1 <1 NA NA NA October 11 2006 <1 <1 <1 <1 <1 NA NA NA April ]7, 2007 <1 <1 <1 <1 <1 NA NA NA October 23, 2007 <I _ Water In'ectioo„ <I 3.5 <I U NA SA N:A L Standard 0.7 2.8 70 1 70 100 NIW-2b Sample Date PCEin µg/L TCEin µg/L Ch loroform in ugiL cis 1,2-D(C1,in Iran l_-DCE gitin pg/L Manganese in Chromiinu in mr'1, Chlorides in m„L September 8, 1999 3 <1 41 <I - I NA NA NA September IS 2000 9 1 <l 24 <1 <1 NA NA NA November 6 2000 6 <1 24 <1 <] NA NA NA Feliniaty 15 2001 T8 <0.5 23 <0.5 <0.5 NA NA NA Well Not Accessible After Febru 2001 21, Standard 0.7 2.8 70 10 100 MW-3 A nl9, 1999 180 TCE in Chloroform in µ2/L cis 1,24DCE in µg/1. trap 12-IICE in µyJL. Manganese in mg/L Chromium in Chlorides in m;Jl. 5 5 <5 --5 NA NA NA Jul 9 1999 250 6 <5 <5 <5 NA NA NA September2 1999 160 10 10 <10 <10 NA NA NA September 15 2000 440 6.3 4.6 <1 <1 NA NA NA ovemb 8 2000 270 5.4 3.9 <1 <1 NA NA NA j Fe 15 2001 1 100 <5 11 <5 <5 NA NA NA May 8, 2001 800 <10 - Io <10 <10 NA NA NA November 28, 2001 160 T2 43 <.I <1 NA NA N:\ „ Phase I Pilot Test ase 11 Pilot Test August 13 2003 600 <1 <1 <t <170!021 2 <0.002 7.1 Sear ber 29 2003 420 <1 <1 <1 <15 <0.002 8A October 27 2003 670 <l <1 <1 <13 <0.002 11 November 24 2003 540 <1 <t <t <18 <0.002 19 Fe 16 2004 1100 <10 <10 <10 <104 <0.002 14 M 28,2004 460 <5 <5 <5 <5 <0.002 29 March 3, 2005 760 1.8 May23 2005 690 4.1 <5 <I <13 ,. Shtrry Injection <5 <1 <I 0.047 <0.002 <0.010 12 IIIIIIIIIIIIIIIIEL- 13 August 9 2005 410 6.4 <5 <1 <1 0.019 <0.010 13 December 5 2005 320 7.1 <5 <1 <1 NA <0.010 14 April 11 2006 660 5.2 2 <1 <1 0.0086 <0.002 14 October 11 2006 230 6.9 2.6 <1 <1 0.0088 0.011 19.9 April 17, 2007 390 <2 <2 <2 <2 0 078 <0.005 1 13.8 Water Injection October 10._007 456.0 9.0 5.1 <5 - 0.005_u 005 22.9 Standard 0.7 2.8 70 1 70 100 RgIL = Parrs per billion or ppb BDL - Below detection limit (laboratory reporting limit unknown) NA - Not Analyzed (compound not on target list) All samples through May 2001 collected by GalaTech, Inc. * Samples Currently Collected in Passtve Diffusion Bag Samplers mg/L=Para per million -pp. PAKayser-Roth\Ashebomo 02600\DWQ Phase\Excel\Table 1 iEstorical Analytical 1 of 8 Table 1. liistorical Ground NNatei M(C Xllalctical Data Sample Date PCE in µg/L ICE in py,/I. Chloroform in 11901, cis l,2-DCE in µ tran 12-DCE i 1, Manganese in mg/L Chromium in mg/l, Chlorides in Se tember9 1999 <1.., I <1 <1 <1 September 15 2000 <1 <1 <1 <1 <1 \A \ \ Webruary 13 2001 <0.5 <0.5 <0.5 <0.5 <0.5 %A NA 1M.v 8 2001 <0.5 <0.5 <0.5 <0.5 <0.5 NA \A \ \ ovember262001 <1 <1 <1 <t <l NA NA \\ Phase I Pilot Test Phase II Pilot Test Nov ember 21, 2003 <1 <I <1 <1 <I NA Mav 26.2004 <1 <1 <I <1 <I AA NA A,A Aw Slurry Injection May 23 2005 <1 <1 <5 1 <1 <1 NA NA \:\ Decembers 2005 <I <1 <5 <1 <1 NA NA \ \ April 12 2006 <1 <1 1.7 <1 <1 NA NA \:\ Ocotber 12 2006 <1 <1 <1 <I <1 NA NA \ \ A ril 17, 2007 1 <1 <l 1-I <1 <1 NA NA S1 Water Injection October 10. 2007 NS NS \S SS \S \S \ \� LStandard 0.7 2.8 70 70 loo ►\ \\M Sample Date PCE in µg/L TCE in µg/L Chloroform in µg/L cis 1,2-DCE in µg/L tran 1,2-DCE in pg/L Manganese in mg/L Chromium in mg& Chlorides in in April 91999 15 <5 <5 <5 <5 NA NA NA July 9 1999 <5 <5 <5 <5 <5 NA NA NA September 2 1999 <5 <5 <5 <5 <5 NA NA NA September 14 2000 <1 <1 <1 <1 <1 NA NA NA February 12 2001 <t <1 <1 <1 <1 NA NA NA May 8 2001 <0.5 <0.5 <0.5 <0.5 <0.5 1 NA NA NA November 26 2001 <1 <I <1 <1 <1 NA NA NA November 21 2003 <1 <1 <1 <1 <1 NA NA NA May 26 2004 <1 <1 <1 <1 <1 NA NA NA 21, Standard 0.7 2.8 70 70 100 \t\4'-&h Sample Date PCE in µg/L. ICE in µg/1. Chloroform in L p cis 1,2-DCE in p tran ] 2-DCE is Manganese in - m L Chromium in m L Chlorides in m L September 8, 1999 <1 <1 <1 I <1 NA NA NA Se tember 15 2000 <1 <1 <1 <1 NA NA NA February 13 2001 <0.5 <0.5 <0.5 <0.5 NA NA 1 NA May 8 2001 <0.5 <0.5 <0.5 <0.5 <0.5 NA NA NA ovember 27 2001 <1 <1 <I <1 <1 0.98 <0.002 48 My 9, 2003 1.2 <1 <1 <1 <1 0.52 <0.002 220 Phase I Pilot Test July 30 2003 1.3 <I <i I <1 <1 0.45 <0.002 200 August 13, 2003 <1 <1 <1 <1 <1 0.44 <0.002 210 _ Phase <1 it Pilot Test <1 <1 " 0.41 <0 002 180 September 12 2003 2 <1 October 27 2003 <1 <1 <1 <1 <1 0.51 <0.002 220 ovember24 2003 2.8 <1 <1 <1 <1 0.48 <0.002 220 Fe 16 2004 2.2 <1 <1 <1 <1 0.58 <0.002 220 May 27, 2004 2.9 <1 <1 <1 <1 0.47 <0.002 390 Slurry Injection May 23 2005 1.4 <1 <I <1 <1 0.370 <0.010 MEME 170 December 5 2005 3.8 <1 <1 <I <1 NA <0.010 82 April 11 2006 10 <1 7 <1 <1 0.130 <0.002 121 October 11 2006 5.4 <1 <1 <1 <1 0.210 0.0061 138 April 17 2007 2.3 <1 <1 <1 <1 0.170 <0.005 128 Water Injection Octoberl0 2007 <t - l - 1 U - <t - 0_173 <0.005 92 o M&btanclard 0.7 2.8 70 70 100 µg/L = Parts per billion or ppb BDL = Below detection limit (laboratory, reporting limit unlawwn) NA - Not Analyzed (ro end not on target lisp .-111 samples through:Nay 2001 collected by Uaial ech, Inc Samples Currently Collected in Passive Dion Bag Samplers mg/L=Pats per million or ppm P:\Kayser-Roth\Asheboro-02600\DWQPhase\Excel\Table 1 Historical Analytical 2 of 8 Table 1. Historical Ground Water I'OC Analvtical Data M W-7" Sample Date PCE in µg/L TCE in µg/L Chloroform in cis 1,2-DCE in /L tran 1,2-DCE 11anganese in in /L m •/L. Chromium in mg/1, Chlorides in m •/t. July 12, 1999 5 7 5 <5 1 5 NA VA SA September 2 1999 <1 10 7 <l <1 NA NA NA September 15 2000 <1 4.4 7 <1 <1 NA NA NA February IS 2001 <0.5 6.4 3 8 <0.5 <0.5 NA NA NA 8 2001 ovember 24, 2003 <0.5 <1 1.7 <1 8 5 2 Phase Phase <0 5 I Pilot Test 11 Pilot Test <0.5 NA NA NA NA NA A' A May 25, 2004 <t <1 3.3 NA NA NA z Slurry Injection May 23 2005 <1 <1 <5 - I - I NA NA December 5 2005 <I <1 <5 I NA NA April 12 2006 <1 <1 1.7 11 <1 NA NA October 12 2006 <1 <1 1 <1 <t U NA NA April 17, 2007 <_ 1 <1 Q <1 - 1 NA N.AWater Injection (Otober10,2007 Dig Dn Dry Dnii„ Dn 1)" 2L Standard 0.7 2.8 70 70 100 Table 1. Historical Ground Water VOC Anal tical Data .-.1 tat. Sample Date PCE in µg/L "CCE in µg/L Chloroform in cis 12-DCE in tran 1.2-DCE -Nt:mganese in Chromium in Chlorides in September 281999 4300 <50 <50 <50 <50 NA NA October6 1999 4000 1 <1 <1 <1 NA NA NA September 15 2000 8,900 2.5 <1 <1 <1 NA NA NA November 8 2000 6,300 <100 <100 <100 <100 NA NA NA February 12 2001 9,000 14 <l <1 <1 NA NA NA May 8 2001 1 7 000 <10 <10 <10 <10 NA NA NA Jul 9 2003 9 700 1.2 <1 <1 <1 0.084 0.0059 3 Jul, 30, 2003 6,900 <1 Phase I To Test < Q <1 0.053 0.0043 24 August 13, 2003 9,300 <I <I <l <1 0.046 0.0028 Phase II Pilot Test <1 <t •-' <1 1.1 -.- 0.01 7.2 September 29, 2003 5,800 <1 October 27 2003 4,400 <I <I <1 <I 0.24 0.0042 4.9 November 26 2003 6,400 <1 <1 <1 <I 0.22 0.0054 4.6 February 16 2004 8,200 Q00 <200 Q00 <200 0.41 0.0043 3.8 May 28 2004 10 000 <100 I <100 <100 <100 0.26 0.0033 0 March 3, 2005 6,100 1.4 <5 <I <1 0.33 1 <0.010 1.5 Slurry InjidW May 23 2005 <100 <100 <500 <100 <100 730 <0.010 <50 Au 9 2005 <1 <1 <5 <1 <1 23 0.012 <10 December 5 2005 2.6 <1 <5 <1 <1 NA <0.010 <10 April 12 2006 <1 <1 <1 <1 <1 12 0.045 7.78 October 12 2006 <1 <1 <1 <1 <1 NS NS 12.9 A ril 17 2007 <1 <1 <1 <1 <I 270 0.011 42,900 Water Iti eeliod _�.__.. . October 1 Q 2007 Di Dr, Dn- Dn- Drv- Dry Dry Dn L Standard 0.7 1 2.8 70 70 100 NIX ADc Chloroform in cis 1.2-DCE: in tran 1 2-DCE j Manganese in Chromium in Chlorides in Sample Date PCL in pg/l. TCE in pg/L µ /l, µ inµ L m L m m L \ht\ _'8.2004 42 - I 26 <I 'I NA NA NA 21. Standard 0.7 '_.8 70 70 100 %1" -41 Sample Date PCE in µg/L TCE in pg/L Chloroform in µg/L cis 1,2-DCE in µg/L tran 1,2-DC'E in 1g/1. Manganese in mg/L Chromium in mg/L Chlorides in mg/L Octobers, 1999 Q I i I N� September 14 2000 <1 <1 -1 \,\ N February 13 2001 <05 <0.5 <OS \A NA Nd May 8,2001 062 <0,5 <0.5 -05 <U.5 NA NA A:> Phase 1 Pilot Test Phase 11 Pilot Test ovember2l 2003 Q <t <7 <=7 4 NA NA May 26 2004 <i 1 I <7 <l NA NA March 3 2005 <1 �1-5 <1 <1 0.02 <0.010 '- Slur Injection M 23 2005 <t <1 <5 <1 <1 0.019 <0.010 8 9 2005 <1 <1 <5 <1 <1 0.022 <0.010 2.7 December 5 2005 <1 <1 <5 <1 <1 NA <0.010 2.5 April 12 2006 NS NS NS NS NS NS NS NS October 12 2006 <I <1 <1 <1 <1 0,046 <0.005 4.15 ril 17, 2007 NS NS NS NS NS NS NS NS - Water Injection October 23, 2007 <1 °I -I <1 <1 NA NA NA L Standard 0.7 2.8 70 70 100 ag L - Parrs per b,lh, or ppb .,.a = Xot Analr d (compound not on target list) BDL = Below detection limit (laboratory reporting limit unknown) NS-Not Smnpled '.Samples ['urrentlr Collected in Pass- D ff slon Bag Samplers All samples through May 2001 collected by GaiaTech, Inc. mg/L=Parts per million or ppm P:\Kayser-Roth\Asheboro-02600\DWQ Phase\Excel\Table I Historical Analytical 4 of 8 Table 1. Historical Ground Water VOC Analytical Data MW-12 Sample Date PCE in µg/L TCE in µg/L Chloroform in PKIL_ cis 1,2-DCE in PWL tran 1,2-DCE is L Manganese in L Chromium in in L Chlorides in in0, October 6 1999 1 <I <1 <1 <I September 14, 2000 <1 <1 <1 <1 <I February 13, 2001 <0.5 <0.5 <0.5 <0.5 <0.5 May 8 2001 <0.5 <0.5 <0.5 <0.5 <0.5 NA NA NA Jul 9 2003 <1 <1 <I <1 <1 0.066 0.0048 3.7 July 30, 2003 I Pilot d!t' <1 1 <l <I - •_ .. - , <l 0.0'_ 0.0027 2 Q August 13,2003 <1 ....I -:1 <-I <1 0.01 0.0021 I Aff Phase 11 Pilot Test September 29 2003 1 <I <I <1 <1 0.012 <0.002 15 October27 2003 <I <1 <1 <l <1 0.0054 <0.002 2.5 ovember 21 2003 < 1 <1 <1 <t <1 0.012 0.0026 2.9 February 16 2004 <1 <1 <1 <1 <1 0.016 0.0021 2.6 May 26 2004 <1 <1 <1 <1 0.03 0.03 0 21, Standard 0.7 IN 70 70 100 ,\I\\-13 Sample Date PC}: in I. µg/ TCE in pglL Chloroform in cis I,'_-D('E in tran 1,2-DCE L Manganese in tit gll. Chromiwn in Chlorides in February 15, 2001 - <0,5 NA NA March 1, 2001 - - _ <0.5 NA NA May 9, 2001 I.:+ - OS <0.5 NA NA NA November 28, 2001 9.2 i- I <1 NA NA NA Phase I Pilot Test Phase 11 Pilot Test November 25, 2003 3.8 - 1 -I I - 1 S4 NA NA May 28, 2004 J 3 I - I - 1 NA N A A Slurn Injection May 23, 2005 <1 - I _-1 1 1 1 0.57 <0 01 Decembers 2005 14 "1 1 - 1 NA 0.011 24 April 10 2006 4 <1 4 1 <1 1 0.15 100026 �30 October 1 2006 5.2 <1 - <1 - 1 1 '_ 0", 4 69 April 13, 2007 6.2 -1 b.4 -1 - 1 0.11) 49 Water Injection October 10, 2007 14.7 1 ; 1 0.161 <0.005 " 0 21, Standard 0.7 2.8 70 70 lu0 Nl\\-17 Sample Date PCE in µg/L TCE in µg/L Chloroform in cis 1,2-DCE in µ /L tran 1,2-DCE in pg/L Manganese in mg/L Chromium in mg/L Cli lorides in m February 15 2001 2,500 4.6 1.2 <0.5 <0.5 \A NA NA March 1 2001 2,200 6.2 1.4 <0.5 <0.5 NA NA NA May 9, 2001 9600 <100 <100 <I 000 <1 000 NA NA NA ovember 28, 2001 1,200 6.9 1.9 <1 1.5 NA NA NA Augwt 13, 2003 13,000 <1 ase i Pil; "t ' <1 <1 <1 O.G'_6 <0.002 10 'Phase I Pilot Test Se [ember 29 2003 <1 <1 <1 <l <I 12 0.020 14 October27 2003 900 <1 2.1 <1 <1 9.6 0.016 16 ovembes 25 2003 5 00 <1 1.9 <1 <1 2.4 0.019 17 Feb 16 2004 1 00 <50 G50 <50 <50 11 0.021 11 Ma 28 2004 760 <10 <10 <10 <10 35 0.024 20 March 3, 2005 May 23,2005 6 500 6300 8.8 <5 Slur jB' ' QO <100 <20 <1 <20 0.14 0.53 0.020 0.023 5.4 5.2 ` August 9 2005 5 800 <20 <100 <20 <20 0.43 0.015 4.9 December 5 2005 720 <20 <100 <20 QA NA <0.010 5.7 April2 2006 6800 <50 <50 <50 <50 0.35 0,019 7.49 October 12 2006 1,800 <0 QO <20 <20 1.5 0 01 a 8.36 A ril 17, 2007 7,200 <10 <10 <10 <10 0.044 0.0I S 5.91 Water Injection October 10 2007 2,350.0 <50 10 10 Its �1818 0 0102 7.8 L S 0.7 2.8 70 70 1 oo ug,L = Paru per billion or ppb NA = NmAnalysed (compound not on target list) • Samples Currently Collected in Passive Dion Bag Samplers BDL - Below detection limit (laboratory reporting limit unknown) All samples through May 2001 collected by GmaTech, Inc. mglL-Paru per million or ppm P:\Kayser-Roth\Asheboro-02600\DWQ Phase\Excel\Table 1 Rstoncal Analytical 5 of 8 Table 1. Historical Ground Water VOC Analytical Data t'iw_10 Sample Date PC F, in µg/1. TCE in µy/L Chloroform in µg/I, cis l,'_-DCE in µglL I tran 1,2-DCE in µg/L Manganese in mg/L Chromium in mglL Chlorides in mg/L Phase I Pilot Test Phase Il Pilot Test ovember 20, 2003 <1 <1 - I <l <I NA NA Slurry Injection May 23, 2005 <l <15 <1 <1 0.65 <0.0103 December 5, 2005 Dry Dry Dn Dry Dry Dry D Dry 21, Standard 0,7 2.8 70 70 100 xlx%-Mn Sample Date PCE in µg/L TCE in µg/I, Chloroloi-n in /1, cis 1; -DCE in 1L tran 1,2-1)CE in L Manganese in ra I, Chrominm in m L Chlorides in no L November 27, 2001 <7 <1 <I II NA NA NA Phase 1 Pilot Test Phase II Pilot Test November25, 2003 32 A SA N:A May 26 2004 <l A NA AA Slurry Injection May 23 2005 <1 <1-1 <1 NA NA NA Decembers 2005 <1 <1 5 <1 <1 NA NA NA April 12 2006 <1 <1 ,.I <t <I NA NA NA October 10, 2006 April 17, 2007 <1 <I I <1 <1 NA NA NA WE Water Injection _ October 23, 2007 <1 <1 3 9 <7 <t NA NA NA L Standard 0.7 2.8 70 70 100 Sample Date PCE in µg/L TCE in µg/L Chloroform in µ /L cis 1,2-DCE in µ tran 1,2-DCE inµ L Manganese in m Chromium in m Chlorides in m L ovember 27, 2001 22 <1 2 <1 <1 0.068 0.002 17 July 9, 2003 <1 <I I <1 <1 0.03 1 <0.002 12 Phase I Pilot Test July 30, 2003 1 18 4 - I <t <7 0.01 <0.002 16 August 13, 2003 5.1 <1 I <1 <1 0.04 <0A02 8.4 Phase If Pilot Test _ September 29 2003 21 <1 <1 <1 <1 0,014 <OM2 19 October 27 2003 30 <1 L5 <1 <1 0.016 <0.002 19 November 20 2003 35 <1 1.9 <1 <1 0.0004 <0.002 26 February 16 2004 30 <1 <l <l <1 0.02 <0.002 22 May 25, 2004 26 <1 1.9 <1 <1 0.024 0.024 23 March 3. 2005 23 <1 <5 <1 <1 0.013 <0.010 16 Slurry injection May 23 2005 24 <1 <5 <1 <1 0.023 <0.010 16 August 9 2005 24 <1 <5 <1 <1 0.028 <0.010 17 Decembers 2005 35 <1 <5 <1 <1 NA <0.010 19 April 10 2006 45 <1 2.6 <1 <1 0.0098 <0.002 22.7 October 10 2006 28 <1 1.5 <1 <1 0.034 <0.005 18.3 April 17, 2007 39 <t L8 <1 <1 0.014 <0.005 19.2 Water Injection October 10. 1 9.7 <1 I I 1 � I I 0.0549 <0.005 11.4 2L Standard 1 0.7 2.8 70 1 70 100 ug "L = Paru per billion or ppb • Samples Currently Collected in Passive Diffusion Bog Samplers BDL - Below defection limit (laboratory reporting limit -k—n.) mg/L=Parts per million or ppm NA = NotAnalyred (,compound not oa target list) P:AKayser-Roth\Asheboro-02600VDWQPhaaeAExcel\Table 1 IEistorical Analytical 6 0` 8 Table 1. Historical Ground Water VOC Analytical Data MW-22• DN-1 Sample Date PCE in µg/L TCE in µg/L Chloro grit in µ L us In µ L file - •2- inµ L anganese in to L Chromium in mg/L COnMes in mg/L July 12 1999 120 10 11 <5 <5 NA NA NA September 8 1999 210 12 8 <1 <1 NA NA NA September 15 2000 190 11 9.3 <1 <1 NA NA NA November 8 2000 240 9.4 8.9 <1 <1 NA NA NA February 15 2001 310 14 12 <2.5 <2.5 NA NA NA May 8, 2001 240 12 14 <10 <10 NA NA NA November 28, 2001 11 8.6 4.2-I <.I NA I NA NA November 24, 2003 <1 <1 Phase l Pilot Test JOEL Phase II Pilot Test 6.6 1 <1 NA NA NA May27 2004 540 11 3 1 <1 NA NA NA March 3, 2005 270 <25 <25 <25 0.012 0,017 15 .. Slurry Injection May 23 2005 400 16 <5 <10 <10 <0.010 0.014 14 August 9 2005 400 15 <5 <1 <1 0.19 0.013 14 December 5 2005 420 16 <5 <1 <1 NA 0.014 15 April 112006 590 16 4.1 <1 <1 3.6 0.012 20.7 October 11, 2006 440 15 3.8 <1 <1 1.2 0.012 22.3 A riI 17, 2007 480 16 <5 <5 <5 0.01 0.01 23.9 `_�" October 10. 2007 729 0 24.6 'W'ater ln' 6.1 1 <5.0 <5.0 0.379 0 0094 23.2 L Standard 0.7 1 2.8 70 1 70 100 Doi'-2 Sample Date PCE in µg/L TCE'ie µg/I, "Toro form" µg/L ,2-DCE in µg/L trap 1,2-DCE in µg/L .0 Chromium in mg/L Chlorides in mg/L July 12 1999 140 <25 <25 <25 - NA NA NA September 8 1999 190 3 14 <1 <l NA NA NA September 15 2000 320 3.3 18 <1 <1 NA NA NA November 8 2000 410 <10 19 <10 <10 NA NA NA February 15 2001 420 <2.5 14 <2.5 <2.5 NA NA NA May 8 2001 420 <10 18 110 <10 NA NA NA November 28, 2001 340 4.5 15 <1 <l 0 NA 85 July 9,2003 350 <1 <1 <1 <1 0 <0.002 130 ` Phase I Pilot Test " July 30 2003 250 <1 15 <1 <1 0 <0.002 1'n t13 2003 370 <1 I <1 0 <0.002 1 September 29 2003 <1 Phase If Pilot Test <1 I <1 <1 29 0.044 89 October27 2003 290 1.5 15 <1 <1 0.079 0.11 100 November 24 2003 21 <1 16 <1 <1 9.3 0.12 130 February 16 2004 81 <1 <1 <1 <1 1 0.18 80 May 27 2004 550 1.4 10 <1 <1 0.016 0.075 160 March 3 2005 May 23 2005 340 390 3.7 15 <1 <1 <0.010 Slurry Injection 3.4 14 <10 <-10 <0.010 0.031 0.022 90 98 August 9 2005 330 3.7 11 <1 1 <0.010 0.021 88 Decembers 2005 390 4.3 11 <1 <I <0.010 0.021 83 April 11 2006 710 5.5 12 <1 1 0.0083 0.017 80.1 October 11, 2006 430 4.6 15 <1 ;-1 <0.005 0.013 9Z0 A nl 17, 2007 610 <5 15 <5 =5 0.037 0.0089 98.7 " Water In' October 10, 2007 1 883.0 1 5.6 252 <5 <5 1 0.0344 0.0063 1200.11 2L Standard 1 0.7 1 2.8 1 70 70 1 100 ug L - Parts per billion or ppb-Samples Currently Colle-din Passive Div,,- Rag .Sample,, BDL - Below demcnon limit (laboratory reporting limit unimown) mg L -Parts per million or ppm NA - Not Anal ned (compound not on target list) P:\Kayser-Roth\Asheboro-02600\DWQ Phase\Excel\Table 1 Historical Analytical 7 of 8 Table 1. Historical Ground Water VOC Analytical Data "W-'2 Date 1'CE in µg/L TCE in µg/L - (chloroform in g/L cis L2-D('F. in µi"A' tran 1,2-DCE in no. Manganese in m Chromium in m Chlorides in m 38 15 - NA NA NA 999 F15,2001 37 31 34 <1 NA NA NA 2000 54 37 41 1 <1 NA NA NA 000 47 18 59 <7 <1 NA NA NA 001 70 22 86 05 <0.5 NA NA NA May 8 2001 78 18 78 <1 <1 NA NA NA November 27 2001 51 28 43 <l <1 NA NA NA " -- August 13, 2003 99 <l Phase I Pilot Test 39 �- l <1 0 <0.002 61 Phase II Pilot Test 26 30 <1 <1 0 <0.002 60 September 29 2003 90 October27 2003 230 57 55 <1 <14NA<0.010 0.002 65 ovemher24 2003 110 26 36 <1 <10.002 77 Fe 16 2004 100 32 33 QO QO0.002 64 May 25, 2004 97 29 32 <1 <10.002 140 March 3,2005 85 38 'I <10.010 64 May 23 2005 98 25L29 SlurryInjectioa <10 <100.010 65 Au t 9 2005 76 26 <1 <10.010 64 December 5 2005 80 23 <1 <1 65 April 10 2006 110 26 <1 <1 <0.005 <0.002 71.4 October 10 2006 97 23 <1 <1 <0.005 <0.005 70.5 A ril 17, 2007 120 24 <1 <1 <0.005 <0.005 71 6ter October 10, 2007 126.0 28 9 33.3 In' n <1 <1 <0.005 1 <0.005 70.6 2L Standard 0.7 2.8 70 70 1 100 ill\ _A Sample Uate t hlorofnrm in P(E in µg/L TCE in µg/L ug/l. cis 1.2-DCin in µK/L Iran 1, -DCE L Manganese in -in it, Chromium in m;/1, Chlorides in m Se tember;,'rr�%�� -1 39 <1 S.4 'v,1 NA September 14 2000 <1 44 <1 <1 <1 NA NA NA February 15 2001 <0.5 32 1.2 <0.5 <0.5 NA NA NA May 8 2001 <1 40 1.5 <1 <1 NA NA NA November 28 2001 <1 29 1.7 <l <l NA NA NA Phase I Pilot Test Phase 11 Pilot Test November 21, 2003 4 24 2.6 --1 I NA NA NA May 26, 2004 4 25 3 4 1I NA NA NA Slurry Injection May 23 2005 1 2 24 5.3 <1 <1 0.14 <0.010 13 Decembers 2005 <1 31 <5 <1 <1 NA 0.037 14 April 10 2006 <1 35 7.4 <1 <1 0.67 0.021 NA October 10 2006 <1 37 6.6 <1 <1 0.21 0.0086 22.3 April 17, 2007 = 1 - 9.5 <1 <1 0.85 0.028 29.2 Water Injection _ October 10, 200- 1 1 0 I <1 0.436 0 Ot1-9 21 L Standard 1 0.7 2.8 1 70 I 70 1 100 DW-5 Sample Date PCE in µg/L TCE in µg/L Chloroform in µg/L cis l,2-DCE in µ /L tran 1,2-DCE in µg/L Manganese in mgll. Chromium in m';/1, Chlorides in mg/L November 27, 2001 <L 1.2 11 1 'I SA NA Phase I Pilot Test Phase Il Pilot Test November 25,_0-', 35 8.2 IS - I - I NA >A. NA Mav 25, 2004 4.5 6.7 1-7 I <1 NA NA NA May 23, 2005 4 Slur Injection 7.8 16 <1 <1 0.029 <0.010 52 December 5 2005 2.8 4.0 11 <1 <t NA <0.010 37 April 10 2006 2.4 2.5 15 <1 <1 0.013 <0.002 42.9 October 10, 2006 2.9 3.6 13 <1 <1 0.014 <0.005 40.4 A ril 17, 2007 3.0 3.8 13 <1 <1 0.0078 <0.005 47.5 October I Q 2007 28 4.0 15.0 <1 4 <0 005 <0.005 42.3 L Standard. J 0.7 1 2.8 70 70 100 ug/L = Party per billion or ppb • Samples Currenrlr ('o(lected in Passive Diffusion Bng sarnplrr. BDL = Below detection limit Qaborotory reporting limit unknown) mg L=/',- per mlllimr or pp. NA = Not Analyzed (compound not on target list) P:IKayser-RothlAsheboro-026001DWQ Phase\Exceffable 1 Ilistoncal Analytical 8 of 8 Table 1. Water Level Data, September 20, 2002. Well Top of Casing Elevation (ft) Well Depth Below Grade A Screen Interval Below Grade (ft) Depth to Water (ft) Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 22.98 172.71 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 21.35 166.15 MW-4 207.50 52 32 to 52 24.5 171.34 MW-5 200.53 51.5 31.5 to 51.5 15.84 184.69 MW-6b 205.35 46 26 to 46 24.90 169.03 MW-7 199.26 30 20 to 30 22.98 176.28 MW-8 204.65 50 30 to 50 24.15 180.50 MW-9 175.17 15.71 10.71 to 15.71 11.07 164.10 MW-10b 207.61 38.5 18.5 to 38.5 26.13 169.53 MW-11 205.50 42 32 to 42 21.96 183.54 MW-12 203.62 53 43 to 53 20.42 171.54 MW-13 201.51 40.41 20.41 to 40.41 22.59 168.68 MW-14 199.44 24.78 14.78 to 24.78 Dry Dry MW-15 195.34 24.5 14.5 to 24.5 Dry Dry MW-16 191.42 14.87 4.87 to 14.87 Dry Dry MW-17 200.99 40.9 21.37 to 40.90 27.39 173.60 MW-18 198.70 21 11 to 21 Dry Dry MW-19 191.07 25.78 15.78 to 25.78 21.68 169.39 MW-20 198.53 42 32 to 42 23.07 166.02 MW-21 189.09 40 30 to 40 21.45 162.01 MW-22 182.64 37 22 to 37 17.58 160.92 DW-1 200.54 70 60 to 70 29.83 170.71 DW-2 196.53 96 86 to 96 25.81 163.30 DW-3 199.23 87 77 to 87 22.12 166.61 DW-4 207.83 98 83 to 98 26.51 181.32 IL-= 197.98 99 89 to 99 25.89 163.97 NM = Well not measured Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet Duncklee Dunham Job No. 02600 Page 1 of 1 02600.xls Table 1. Water Level Data, September 20, 2003. Well Top of Casing Elevation (ft) Well Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to Water (ft) Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 24.36 171.33 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 23.5 175.61 MW-4 207.50 52 32 to 52 25.52 181.98 MW-5 200.53 51.5 31.5 to 51.5 16.91 183.62 MW-6b 205.35 46 26 to 46 25.99 179.83 MW-7 199.26 30 20 to 30 21.42 177.84 MW-8 204.65 50 30 to 50 25.71 178.94 MW-9 175.17 15.71 10.71 to 15.71 13.78 161.39 MW-10b 207.61 38.5 18.5 to 38.5 27.37 180.24 MW-11 205.50 42 32 to 42 23.09 182.41 MW-12 203.62 53 43 to 53 21.45 182.17 MW-13 201.51 40.41 20.41 to 40.41 22.7 178.81 MW-14 199.44 24.78 14.78 to 24.78 Dry Dry MW-15 195.34 24.5 14.5 to 24.5 Dry Dry MW-16 191.42 14.87 4.87 to 14.87 Dry Dry MW-17 200.99 40.9 21.37 to 40.90 28.39 172.60 MW-18 198.70 21 11 to 21 Dry Dry MW-19 191.07 25.78 15.78 to 25.78 23.78 167.29 MW-20 198.53 42 32 to 42 24.96 173.57 MW-21 189.09 40 30 to 40 22.7 166.39 MW-22 182.64 37 22 to 37 19.29 163.35 DW-I 200.54 70 60 to 70 30.95 169.59 DW-2 196.53 96 86 to 96 27.29 169.24 DW-3 199.23 87 77 to 87 23.29 175.94 DW-4 207.83 98 83 to 98 27.60 180.23 DW-5 197.98 99 89 to 99 27.93 170.05 NM = Well not measured Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet Duncklee Dunham Job No. 02600 Page 1 of 1 02600.xis Table 2. Water Level Data, November 20, 2003. Well Top of Casing. Elevation (ft) Well Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to Water (ft) 1 Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 24.36 171.33 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 23.5 175.61 MW-4 207.50 52 32 to 52 25.52 181.98 MW-5 200.53 51.5 31.5 to 51.5 16.91 183.62 MW-6b 205.35 46 26 to 46 25.99 179.83 MW-7 199.26 30 20 to 30 21.42 177.84 MW-8 204.65 50 30 to 50 25.71 178.94 MW-9 175.17 15.71 10.71 to 15.71 13.78 161.39 MW-10b 207.61 38.5 18.5 to 38.5 27.37 180.24 MW-11 205.50 42 32 to 42 23.09 182.41 MW-12 203.62 53 43 to 53 21.45 182.17 MW-13 201.51 40.41 20.41 to 40.41 22.7 178.81 MW-14 199.44 24.78 14.78 to 24.78 Dry Dry MW-15 195.34 24.5 14.5 to 24.5 Dry Dry MW-16 191,42 14.87 4.87 to 14.87 Dry Dry MW-17 200.99 40.9 21.37 to 40.90 28.39 172.60 MW-18 198.70 21 11 to 21 Dry Dry MW-19 191.07 25.78 15.78 to 25.78 23.78 167.29 MW-20 198.53 42 32 to 42 24.96 173.57 MW-21 189.09 40 30 to 40 22.7 166.39 MW-22 182.64 37 22 to 37 19.29 163.35 DW-1 200.54 70 60 to 70 30.95 169.59 DW-2 196.53 96 86 to 96 27.29 169.24 DW-3 199.23 87 77 to 87 23.29 175.94 DW-4 207.83 98 83 to 98 27.60 180.23 DW-5 197.98 99 89 to 99 27.93 170.05 NM = Well not measured, not accessible Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet DunclJee Dunham Job No. 02600 Page 1 of 1 02600. \l < Table 2. Water Level Data, May 24, 2004. Well Top of Casing Elevation (ft) Well Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to Water (ft) Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 25.4 170.29 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 24.6 174.51 MW-4 207.50 52 32 to 52 26.45 181.05 MW-5 200.53 51.5 31.5 to 51.5 17.69 182.84 MW-6b 205.35 46 26 to 46 26.97 178.38 MW-7 199.26 30 20 to 30 23.10 176.16 MW-8 204.65 50 30 to 50 26.77 177.88 MW-9 175.17 15.71 10.71 to 15.71 Dry Dry MW-10b 207.61 38.5 18.5 to 38.5 28.37 179.24 MW-11 205.50 42 32 to 42 24.18 181.32 MW-12 203.62 53 43 to 53 22.13 181.49 MW-13 201.51 40.41 20.41 to 40.41 23.99 177.52 MW-14 199.44 24.78 14.78 to 24.78 Dry Dry MW-15 195.34 24.5 14.5 to 24.5 Dry Dry MW-16 191.42 14.87 4.87 to 14.87 Dry Dry MW-17 200.99 40.9 21.37 to 40.90 29.65 171.34 MW-18 198.70 21 11 to 21 Dry Dry MW-19 191.07 25.78 15.78 to 25.78 Dry Dry MW-20 198.53 42 32 to 42 26.14 172.39 MW-21 189.09 40 30 to 40 23.13 165.96 MW-22 182.64 37 22 to 37 19.56 163.08 DW-1 200.54 70 60 to 70 31.77 168.77 DW-2 196.53 96 86 to 96 28.09 168.44 DW-3 199.23 87 77 to 87 24.53 174.70 DW-4 207.83 98 83 to 98 28.47 179.36 DW-5 197.98 99 89 to 99 28.93 169.05 NM = Well not measured, not accessible Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet Duncklee Dunham Job No. 02600 Page 1 of 1 Semiannual Tables Oct 04 Table 2a. Water Level Data, March 9, 2005. Well Top of Casing Elevation (ft) Well Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to Water (ft) Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 24.97 170.72 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 28.03 171.08 MW-4 207.50 52 32 to 52 NM NM MW-5 200.53 52 32 to 52 NM NM MW-6b 205.35 46 26 to 46 NM NM NM-7 199.26 30 20 to 30 NM NM MW-8 204.65 50 30 to 50 27.43 177.22 MW-9 175.17 15.71 10.71 to 15.71 NM NM MW-10b 207.61 38.5 18.5 to 38.5 29.21 178.40 NM-11 205.50 42 32 to 42 25.22 180.28 MW-12 203.65 42 32 to 42 NM NM MW-13 201.51 40.41 20.41 to 40.41 NM NM MW-14 199.44 24.78 14.78 to 24.78 NM NM MW-15 195.34 24.5 14.5 to 24.5 NM NM MW-16 191.42 14.87 4.87 to 14.87 NM NM MW-17 200.99 40.9 21.37 to 40.90 29.40 171.59 MW-18 198.70 21 11 to 21 NM NM MW-19 191.07 25.78 15.78 to 25.78 NM NM MW-20 198.53 42 32 to 42 NM NM MW-21 189.09 40 30 to 40 22.70 166.39 MW-22 182.64 37 22 to 37 NM NM DW-1 200.54 70 60 to 70 31.59 168.95 DW-2 196.53 96 86 to 96 27.76 168.77 DW-3 199.23 87 77 to 87 24.96 174.27 DW-4 207.83 98 83 to 98 NM NM DW-5 197.98 99 89 to 99 NM NM NM = Well not measured, not accessible Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet Duncklee Dunham Job No. 02600 Page 1 of 1 Water Levels -Field Data March-05 Table 2c. Water Level Data, August 9, 2005. Well Top of Casing Elevation (ft) Well Depth Below Grade (fQ . Screen Interval Below Grade (ft) Depth to Water (ft) Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 27.74 167.95 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 27.55 171.56 MW-4 207.50 52 32 to 52 NM NM MW-5 200.53 52 32 to 52 NM NM MW-6b 205.35 46 26 to 46 NM NM MW-7 199.26 30 20 to 30 NM NM MW-8 204.65 50 30 to 50 29.94 174.71 MW-9 175.17 15.71 10.71 to 15.71 NM NM MW-10b 207.61 38.5 18.5 to 38.5 31.68 175.93 MW-11 205.50 42 32 to 42 27.07 178.43 MW-12 203.65 42 32 to 42 NM NM MW-13 201.51 40.41 20.41 to 40.41 NM NM MW-14 199.44 24.78 14.78 to 24.78 NM NM MW-15 195.34 24.5 14.5 to 24.5 NM NM MW-16 191.42 14.87 4.87 to 14.87 NM NM MW-17 200.99 40.9 21.37 to 40.90 32.26 168.73 MW-18 198.70 21 11 to 21 NM NM MW-19 191.07 25.78 15.78 to 25.78 NM NM MW-20 198.53 42 32 to 42 NM NM MW-21 189.09 40 30 to 40 25.00 164.09 MW-22 182.64 37 22 to 37 NM NM DW-I 200.54 70 60 to 70 34.03 166.51 DW-2 196.53 96 86 to 96 30.16 166.37 DW-3 199.23 87 77 to 87 27.14 172.09 DW4 207.83 98 83 to 98 NM NM DW-5 197.98 99 89 to 99 NM NM NM = Well not measured, not accessible Top -of -casing elevations referenced to arbitrary site datum of 200.00 feet Duncklee Dunham Job No. 02600 Page 1 of 1 Water Levels -Field Data Aug-05 fable 2d. NN ater Level Data, December 5, 2005. Well Top of Casing Elevation (ft) "ell Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to NNater A Ground Water Elevation (ft) MW-1 195.69 45.5 25.5 to 45.5 29.66 166.03 MW-2b 198.78 44 24 to 44 NM NM NM-3 199.11 46.5 26.5 to 46.5 29.78 169.33 MW-4 207.50 52 32 to 52 32.07 175.43 MW-5 200.53 52 32 to 52 22.64 177.89 MW-6b 205.35 46 26 to 46 32.68 172.67 MW-7 lW26 30 20to30 28.39 170.87 NW-8 204.65 50 30 to 50 32.36 172.29 MW-9 175.17 15.71 10.71 to 15.71 DRY DRY MW-10b 207.61 38.5 18.5 to 38.5 34,10 173.51 MW-11 205.50 42 32 to 42 29.69 175.81 MW-12 203.65 42 32 to 42 27.76 175.89 NM-13 201.51 40.41 20.41 to 40.41 29.22 172.29 MW-14 199.44 24.78 14.78 to 24.78 DRY DRY MW-15 195.34 24.5 14.5 to 24.5 DRY I DRY MW-16 191,42 14.87 4.87to14.87 DRY I DRY MW-17 200.99 40.9 21.37 to 40.90 28.12 17287 MW-18 198.70 21 11 to 21 DRY DRY MW-19 191.07 25.78 15.78 to 25.78 DRY DRY MW-20 98.53 :89.09 42 32 to 42 30.29 168.24 MW-21 40 30 to 40 25.65 163.44 MW-22 182.64 37 22 to 37 21.09 161.55 DW-1 200.54 70 60 to 70 35.23 165.31 DW-2 196.53 96 86 to 96 31.33 165.20 DW-3 199.23 87 77 to 87 29.39 169.94 DW4 207.83 98 83 to 98 33.91 173.92 DW-5 197.98 99 89 to 99 32.47 165.51 NM = Well not measured, not accessible Topo casing elevations referenced to arbitrary site datum of200.00 feet MW-1. MW-4, MW-7, MW-20, MW-22 were measured on 4120105 Duncklee Dunham Job No. 02600 Page I of 1 Water Levels -Field Data 12-05 Table 2a. Water Level Data, April 11, 2006. Well Top of Casing Elevation (ft) Well Depth Below Grade (ft) Screen Interval Below Grade (ft) Depth to N'ater (ft) Ground Rater Hlevation (ft) MW-1 • 195.69 45.5 25.5 to 45.5 27.01 168.68 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 27.24 171.87 MW4 • 207.50 52 32 to 52 29.18 178.32 MW-5 200.53 52 32 to 52 2039 180.14 MW-6b 205.35 46 26 to 46 30.01 175.34 MW-7 * 199.26 30 20 to 30 25.72 173.54 MW-8 204.65 50 30 to 50 29.54 175.11 MW-9 175.17 15.71 10.71 to 15.71 DRY DRY MW-10b 207.61 38.5 18.5 to 38.5 31.04 176.57 MW-11 205.50 42 32 to 42 27.88 177.62 MW-12 203.65 42 32 to 42 25.21 178.44 MW-13 201.51 40.41 20.41 to 40.41 26.53 174.98 MW-14 199.44 24.78 14.78 to 24.78 DRY DRY MW-15 195.34 24.5 14.5 to 24.5 DRY DRY MW-16 191.42 14.87 4.87 to 14.87 DRY DRY MW-17 200.99 40.9 21,37to40.90 30.95 170.04 MW-18 198.70 21 11 to 21 DRY DRY MW-19 191.07 25.78 15.78to25.78 25.3 165.77 MW-20 * 198.53 42 32 to 42 27.78 170.75 NW-21 189.09 40 30 to 40 24.03 165.06 MW-22 * 182.64 37 22 to 37 19.3 163.34 DW-1 200.54 70 60to70 33.25 167.29 DW-2 196.53 96 86 to 96 29.47 16Z06 DW-3 199.23 87 77 to 87 27.08 172.15 DW-4 207.83 98 83 to 98 31.47 176.36 DW-5 197.98 99 89 to 99 30.16 167.82 *Water levels were measured on 3-22-2006 NM = Well not measured not accessible Topaf-casing elevations referenced to arbitrary site datum of 200. 00 jeer Duacklee Dunham Job No. 02600 Page 1 of I Water Levels -Field Data April-06 Table 2b. Water Level Data, October 10, 2006. Well Top of Casing Elevation (ft) Well Depth Belot, Grade (ft) Screen Interval Below Grade (fo Depth to Water (ft) Ground Water Elevation (ft) M1;-I 195.69 1S5 25.5to45.5 29.22 16647 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46 5 26.5 to 46.5 29.96 169 15 MW-4 207.50 52 32 to 52 31.02 176.48 MW-5 200.53 52 32 to 52 22.21 178.32 MW-6b 205.35 46 26 to 46 32.71 172.64 MW-7 lW26 30 20to30 26.81 172.45 MW-8 204.65 50 30 to 50 31.24 173.41 MW-9 175.17 1571 10.71 to 15.71 DRY DRY MW-10b 207.61 38 5 18.5 to 38.5 34.61 173.00 MW-11 205.50 42 32 to 42 27.22 178.28 MW-12 203.65 42 32 to 42 28.07 175.58 MW-13 201.51 40 41 20.41 to 40.41 29.56 17195 MW-14 199.44 24.78 14.78 to 24.78 DRY DRY MW-15 195.34 24.5 14.5 to 24.5 DRY DRY MW-16 191.42 14.87 4.87 to 14.87 DRY DRY MW-17 200.99 40.9 21.37 to 40.90 34.52 166.47 MW-18 198.70 21 11to21 DRY DRY MW-19 191.07 25.79 15.78 to 25.78 25.39 165.68 MW-20 198.53 42 32 to 42 29.92 168.61 MW-21 199.09 40 30to40 26.19 162.90 MW-22 182.64 37 22 to 37 21.10 161.54 DW-I 200.54 70 60 to 70 36.17 164.37 DW-2 196.53 46 86 to 96 31.92 164.61 DW-3 199.23 87 77 to 87 29.61 169.62 DW-4 207.83 1)8 83 to 98 34.23 173.60 DW-5 197.98 9e 89 to 99 32.99 164.99 Water Levels -Field Data Oct-06 Table 2c. eater Level Data, April 17. 2007. Well Top of Casing Elevation ft Well Depth Below Grade ft Screen Interval Below Grade ft Depth to Water It Ground Water Elevation ft MW-1' 195.69 45.5 25.5 to 45.5 25.80 169.89 MW-2b 198.78 44 24 to 44 NM NM NW-3 199.11 46.5 26.5 to 46.5 25.12 173.99 MW4 * 207.50 52 32 to 52 27.48 180.02 MW-5 200.53 52 32 to 52 18.11 182.42 MW-6b 205.35 46 26 to 46 27.79 177.56 MW-7 ' 199.26 30 20 to 30 24.07 175.19 MW-8 204.65 50 30 to 50 27.86 176.79 MW-9 175.17 15.71 10.71 to 15.71 13.12 162.05 MW-10b 207.61 38.5 18.5 to 38.5 29.49 178.12 MW-11 205.50 42 32 to 42 21.82 183.68 MW-12 203.65 42 32 to 42 22.72 180.93 MW-13 201.51 40.41 20.41 to 40.41 24.57 176.94 MW-14 199.44 24.78 14.78 to 24.78 DRY DRY MW-15 195.34 24.5 14.5 to 24.5 DRY DRY MW-16 191.42 14.87 4.87 to 14.87 DRY DRY MW-17 200.99 40.9 21.37 to 40.90 25.34 175.65 MW-18 198.70 21 11 to 21 DRY DRY MW-19 191.07 25.78 15.78 to 25.78 24.37 166.70 MW-20 r 198.53 42 32 to 42 25.90 172.63 MW-21 189.09 40 30 to 40 22.22 166.87 MW-22 w 182.64 37 22to 37 18.54 164.10 DW-1 200.54 70 60 to 70 33.25 167.29 DW-2 196.53 96 86 to 96 29.47 167.06 DW-3 199.23 87 77 to 87 27.08 172.15 DW4 207.83 98 83 to 98 31.47 176.36 DW-5 197.98 99 89 to 99 30.16 167.82 DW-I 200.54 70 60 to 70 31.43 169.11 DW-2 196.53 96 86 to 96 27.69 168.84 DW-3 199.23 87 77 to 87 25.16 174.07 DW4 207.83 98 83 to 98 31.69 176.14 DW-5 197.98 99 89 to 99 28.01 169.97 *Water levels were collected on 4-3-2007 NM = Well not measured, not accessible Top flcasing elevations referenced to arbitrary site datum of 200. 00 feet P:\Kayser-Roth\Asheboro-02600\DWQ Phase\ExM\2007 Data\Water Levels -Field Data April-07 Page 1 of l Table 2. Water Level Data, October 8, 2007. Nell16 ' MW-1 Top of Casing Elevation 195.69 Well Depth Below Grade Screen Interval Below Grade Depth to Water Ground Water Elevation 45.5 25.5to45.5 32.34 MW-2b 198.78 44 24 to 44 NM NM MW-3 199.11 46.5 26.5 to 46.5 32.45 166.66 MW4 207.50 52 32 to 52 34.74 172.76 bfW-5 200.53 52 32 to 52 26.11 174.42 MW-6b 205.35 46 26 to 46 35.02 170.33 MW-7 199.26 30 20to30 DRY DRY MW-8 204.65 52 30to50 34.89 169.76 MW-9 175.17 15 71 10.71 to 15.71 DRY DRY MW-10b 207.61 38.5 18.5 to 38.5 DRY DRY n1W-11 205.50 42 32to42 31.78 173.72 MW-12 203.65 42 32to42 30.74 172.91 MW-13 201.51 40.41 20.41to40.41 31.95 169.56 MW-14 199.44 24.78 14.78to24.78 DRY DRY MW-15 195.34 24.5 14.5 to 24.5 DRY DRY MW-16 191.42 14.87 4.87 to 14.87 DRY DRY MW-17 200.99 40.9 21.37 to 40.90 36.71 164.28 MW-18 198.70 21 11 to 21 DRY DRY MW-19 191.07 25.78 15.78 to 25.78 DRY DRY \fW-20 198.53 42 32to42 33.23 165.30 MW-21 189.09 40 30 to 40 29.06 160.03 MW-22 182.64 37 22 to 37 25.23 157.41 DW-1 200.54 70 60 to 70 38.61 161.93 DW-2 196.53 U6 86 to 96 34.56 161.97 DW-3 199.23 87 77 to 87 31.81 167.42 DW 4 207.83>8 83 to 98 35.71 172.12 DW-5 197.98 99 89.99 35.28 162.70 NM - Well not measured, not accessible 7bp-oJ=casing ele-ti.-- referenced to.,ha p site datum of200.00feet PAKayam-RothWsheboro-02600\DWQ Phm\Exce1t2007 DatsMater Levels -Field Data Oct-07 Page 1 of 1 Table 3. Ground Water Inorganics Laboratory Analytical Data, November 20-26, 2003. Well Manganese (mg/L) Chromium (mg/L) Chloride (mg/L) MW-1 0.14 <0.002 120 MW-3 0.028 <0.002 19 MW-6b 0.48 <0.002 220 MW-8 0.91 <0.002 850 MW-10b 0.22 0.0054 4.6 MW-12 0.012 0.0026 2.9 NM-17 2.4 0.019 1- MW-21 0.0094 <0.002 26 DW-2 9.3 0.12 130 DW-3 <0.005 <0.002 77 21, Standard 0.05 0.05 250 m&L = Parts per million or ppm Duncklee Dunham Job No. 02600 Page 1 of 1 02600.x1s Table 3. Ground Water Inorganics Laboratory Analytical Data, May 24-28, 2004. Well Manganese (mg/1.) Chromium (mg/L) Chloride (m /1.) M W-1 0.14 <0.002 130 M W -3 0.021 <0.002 29 MW-6b 0.47 <0.002 390 MW-8 1.3 <0.002 1,300 MW-10b 0.26 0.0033 <5 MW-12 0.03 0.0044 < MW-17 35 0.024 20 MW-21 0.024 <0.002 23 DW-2 0.016 0.075 160 DW-3 <0.005 <0.002 100 mg/L = Parts per million or ppm Duncklee Dunham Job No. 02600 Page 1 of I Semiannual Tables Oct 04 Table 3. Ground Water Inorganics Laboratory Analytical Data, May 23-26, 2005. Well Manganese (mg/L) Chromium (mg/L) Chloride (mg/L) Chemical Oxygen Demand (mg/L) MW-3 0.047 <0.010 13 <20 MW-6b 0.37 <0.010 170 <20 MW-8 1.4 <0.010 580 30 MW-9 0.12 <0.010 27 <20 MW-10b 730 <0.010 <50 6100 MW-11 0.019 <0.010 2.8 <20 MW-13 0.57 <0.010 2.7 <20 MW-17 0.53 0.023 5.2 <20 MW-19 0.65 <0.010 2.4 <20 MW-21 0.023 <0.01 16 <20 DW-I <0.010 0.014 14 <20 DW-2 <0.010 0.022 98 <20 DW-3 0.03 <0.010 65 <20 DW-4 0.14 <0.010 13 <20 DW-5 0.029 <0.010 52 <20 mg/L = Parts per million or ppm Duncklee Dunham Job No. 02600 Page I of 1 Water Levels -Field Data May-05 Table 4. Field Measured Ground Water Data, November 20-26, 2003. Well Temperature (Deg. Celsius) p11 (Stan(ard ! nits) Conductivity (us) ORP (MV) Dissolved Oxygen (mg/L) MW-I 21.5 4.8 354 387 6.05 MW-3 18.3 3.6 71 674 6.59 MW-6b 18.3 2.5 741 455 7.32 MW-8 17.7 1800 565 7.73 MW-10b 17.3 ?- I 23 473 5.74 MW-12 17.1 44 35 440 6.11 MW-17 NM 4.o 56 492 NM MW-21 17.7 130 382 4.43 DW-2 NM 4.� 434 648 NM DW-3 19.7 285 331 6.59 mg/L = Parts per million or ppm NM = Not measured due to presence ojpoiassium permanganate ORP = Oxidation Reduction Potential Duncklee Dunham Job No. 02600 Page 1 of 1 02600.xis I able 4. Field Measured Ground Water Data, May 24-28, 2004. Well T emperature (Dcg. Celsius) pH (Standard t nits) ConductivitN (us) ORP (mV) Dissolved Oxygen (mg/L) MW-1 21.6 5.1 307 270 7.98 MW-3 19.1 5.5 89 700 7.24 MW-6b 20 5.1 864 360 7.45 MW-8 18.5 4.7 1926 720 8.33 MW-10b 18.3 5 20 675 6.43 MW-12 17.8 : 4 39 270 5.76 MW-17 18.3 5 4 155 752 NM MW-21 18.2 5.7 147 255 4.18 DW-2 20 6,6 429 238 8.23 DW-3 19.9 6-5 33? 232 6.01 mg/L = Parts per million or ppm NM = Not measured due to presence of potassimn permanganate ORP = Oxidation Reduction Potential Duncklee Dunham Job No. 02600 Page I of I Semiannual Tables Oct 04 Table 3a. Field Measured Ground Water Data, March 3, 2005. NN ell Temperature (De,. Celsius) p1l (Standard t nits) Coil ducticit'N (µS4ut) ORP (IIIN Dissolved Oxygen (mg/L) MW-3 17.8 5.1 75 321 6.9 MW-6B NS NS NS NS NS MW-8 17.8 4.5 206 407 8.2 MW-9 NS NS NS NS NS MW-10b 17.2 5.4 24 318 8.0 MW-11 16.0 5.9 86 234 6.0 MW-13 NS NS NS NS NS MW-17 16.6 5.4 46 498 8.1 MW-19 NS NS NS NS NS MW-21 16.6 5.7 128 273 4.5 DW-1 18.0 6.8 162 302 7.0 DW-2 19.1 6.1 371 227 8.3 DW-3 19.1 6 278 222 6.7 DW-4 NS NS NS NS NS DW-5 17.5 6.14 234 128 5.6 mg,L -Paris per million orppm NM = Not measured due to presence of potassium permanganate ORP = Oxidation Reduction Potential NS = Not sampled Duncklee Dunham Job No. 02600 Page 1 of 1 Water Levels -Field Data March-05 Table 3b. Field Measured Ground Water Data, May 23-26, 2005. A cll Temperature (Deg. Celsius) pH (Standard l nits) Conductivity (µSleet) ORP (III V) Dissolved Oxygen (mg/L) MW-3 18.3 5.23 75 302 6 6 MW-6B 18.4 4.85 667 362 0 v MW-8 17.9 4.57 2010 415 8 MW-9 18.1 4.49 135 300 MW-IOb NM NM NM NM NN1 MW-11 17.5 6.13 103 223 6 3 MW-13 16.9 5.8 44 236-� MW-17 16.9 5.49 54 421 7 S MW-19 19.8 5.63 32 268 S_8 MW-21 17.4 5.86 131 243 4.9 DW-I 18.4 7.31 162 169 7 2 DW-2 20 6.25 407 196 76 DW-3 19.4 6.37 291 211 6 7 DW-4 18.7 6.43 110 221 9 DW-5 17.5 6.14 234 128 5.6 mg = Parts per million or ppm NM = Not measured due to presence ofpotassium permanganate ORP = Oxidation Reduction Potential Duncklee Dunham Job No. 02600 Page 1 of I Water Levels -Field Data May-05 Table 3c. Field Measured Ground Water Data, August 9, 2005. �� 11 Temperature (Deg. Celsius) pH (Standard units) Conductivity (µs/em) ORP Dissolved Oxygen (ing/L) MW-3 19.6 5.37 140 280 6.44 MW-6B NS 4.85 667 362 6.90 MW-8 18.5 4.58 167 385 7.45 MW-9 NS NS NS NS NS MW-10b NM NM NM NM NM MW-11 17.7 5.58 94 270 5.13 MW-13 NS NS NS NS NS MW-17 17.5 5.34 77 558 7.24 MW-19 NS NS NS NS NS MW-21 18.1 5.33 134 182 4.75 DW-1 19.5 6.25 235 164 6.61 DW-2 21.8 5.73 379 182 6.90 DW-3 19.7 5.45 303 190 6.42 DW-4 NS NS NS NS NS DW-5 17.5 6.14 234 128 5.60 mg/L = Parts per million or ppm NM = Not measured due to presence ofpotassium permanganate ORP = Oxidation Reduction Potential Duncklee Dunham lob No. 02600 Page I of I Water Levels -Field Data Aug-05 "Fable 3d. Field Measured Ground Water Data, December 5, 2005. N� ell Temperature (Deg. Celsius) pH (Standard units) CondUctiN ity (us) ORP (no Dissolved Oxygen (mg/L) MW-3 17.5 5.72 472 242 4.61 MW-6B 17.8 5.06 305 271 4.47 MW-8 17.2 4.55 331 394 5.50 MW-9 18.1 4.49 135 300 5.50 MW-10b NM NM NM NM NM MW-11 15.9 5.93 535 186 3.94 MW-13 16.4 5.75 161 187 5.47 MW-17 NM NM NM NM NM MW-19 19.8 5.63 32 268 8.80 MW-21 16.7 5.84 8840 190 1.48 DW-1 18.0 6.76 580 160 4.66 DW-2 18.7 6.19 1080 207 5.28 DW-3 19.0 6.17 7440 173 4.65 DW-4 17.8 6.25 598 221 7.15 DW-5 16.7 5.82 600 146 3.83 mg/L = Parts per million or ppm NM = Not measured due to presence of potassium permanganate ORP = Oxidation Reduction Potential Duncklee Dunham Job No. 02600 Page I of 1 Water Levels -Field Data 12-05 Table 3a. Field Measured Ground Water Data, April 11, 2006. Well Temperature (Deg. Celsius) pH (Standard Units) Conductivity (PS/cm) ORP (mV) Dissolved Oxygen (mg/L) Colorimeter (mg/L) MW-3 18.5 5.56 118 243 6.50 MW-613 19.1 5.09 195 330 6.66 MW-8 17.7 4.64 221 492 8.76 MW-10b 18.2 4.62 >9999 737 3.21 145.0 MW-13 16.7 6.70 394 222 7.23 MW-17 17.2 4.53 274 514 8.13 0,0 MW-21 17.2 6.20 330 237 3.17 D W-1 18.0 6.93 219 171 6.57 DW-2 18.8 6.43 179 180 6.99 D W-3 19.1 7.17 464 170 5.66 D W-4 17.9 7.20 638 204 7.25 DW-5 16.9 6.70 440 162 5.27 Blank Cell=No Data mg/L = Parts per million or ppm ORP = Oxidation Reduction Potential µS/cm=microseimens per centimeter Duncklee Dunham Job No. 02600 Pagc I of I Water Levels -Field Data April-06 Table 3b. Field Measured Ground Water Data, October 10, 2006. Well Temperature (Deg. Celsius) pH (Standard Units) Conductivity (PS/CM) ORP (mV) Dissolved Oxygen (mg/L) Colorimeter (mg/I,) MW-3 18.3 6.27 17.6 41) 7.49 II.4 MW-613 18.2 5.62 90.0 79 6.84 MW-8 18.3 6.27 40.9 41 7.43 0.4 MW-10b 19.9 3,9.5 702 >19.99 134.5 MW-11 18.0 6.29 34.6 47 6.26 0.2 MW-13 16.5 3.53 82.0 177 9.77 0.8 MW-17 16.6 64.6 601 10.34 2.8 MW-21 18.3 6.31 31.3 49 2.49 0.4 DW-1 18.1 7.00 48.4 17 7.17 2.3 DW-2 18.8 6.16 65.2 54 8.32 0.2 DW-3 19.5 6.68 59.2 33 7.44 0.0 DW-4 18.0 6.39 16.9 47 11.30 0.4 DW-5 16.9 6.73 20.5 1 9 6.36 0.0 Blank Cell =No Data mg/L = Parts per million or ppm µS/cm=microseimem per centimeter OPP = Oxidation Reduction Potential measured in millivolts Duncklee Dunham Job No. 02600 Page I of 1 Water Levels -Field Data Oct-06 Table 3c. Field Measured Ground Water Data, April 17, 2007. NN ell Temperature (Deg. Celsius) pH (Standard Units) Conductivity (PS/CM) ORP (mV) Dissolved Oxygen (mg/L) Colorimeter (mg/L) MW-3 18.0 7.71 94 99 6.48 0.6 MW-613 18.2 6.27 655.0 276 6.29 ().1 MW-8 17.5 1.58 1,700 754 11.91 1.4 MW-10b 17.4 1.32 900 801 13.93 1 �OJ) MW-13 17.3 7.81 60.0 102 9.10 0.7 MW-17 16.9 5.16 48 412 7.87 0.0 MW-21 17.4 7.85 174 96 4.87 0.0 DW-I 18.1 7.86 239 88 7.01 0.4 DW-2 18.8 7.70 597 102 7.75 1.6 D W-3 19.2 7.79 410 97 7.09 ().2 D W-4 17.9 7.76 209 90 9.40 () IS DW-5 16.9 7.95 302 87 6.69 0.0 mg1L = Parts per million or ppm µNcm=microseimens per centimeter ORP = Oxidation Reduction Potential measured in millivolts Duncklee Dunham Job No. 02600 Page I of 1 Water Levels -Field Data April-07 Table 3. Field Measured Ground Water Data, October 2007. Well 'temperature (Deg. Celsius) pH (Standard Units) Conductivity (pS/cm) ORP (mv) Dissolved Oxygen (mg/L) Colorimeter (mg/L) MW-3 18.9 5.76 102 276 5.10 0.43 MW-613 19.1 5.01 327.0 327 5.39 0.00 MW-8 18.6 5.10 132 604 9.98 1.40 MW-10b DRY DRY DRY DRY DRY DRY MW-13 17.1 5.55 530.0 271 6.88 0.38 MW-17 19.1 5.57 46 419 7.58 0.22 MW-21 17.5 5.80 980 271) 3.84 0.01 DW-1 18.4 6.77 155 215 4.35 0.00 DW-2 19.3 6.16 436 236 5.31 0.00 DW-3 11).) 6.10 273 209 5.41 0.20 DW-4 18.4 6.14 117 239 6.21 0.98 DW-5 17.0 5.75 191 226 4.83 0.06 mg/L = Parts per million or ppm µNcm=microseimens per centimeter ORP = Oxidation Reduction Potential measured in millivolts Duncklee Dunham Job No. 02600 Page 1 of 1 Water Levels -Field Data Oct-07 Wooded Area NAV-22 R r Burmil Road (SR 1500 to Wooded T,TW-5" Boiler House — Fence 1\1W-2b y DW-3 (76J Main Plant Building Electrical Substation Parking T.ot — — — Property Line X Fence Line bfW-16 Saprolite Unit Well ® DW-3 Bedrock Unit Well ®--® Cross Section Line (390) PCE Concentration in ppb (BDL) Below Labratory Detection Limit (NS) Not Sampled Supported ny p„t. In f—d PCE Concentration 1,000-10,000 ppb ® ® PCE Concentration 100-1,000 ppb 0 0 PCE Concentration 10-100 ppb ■ ® PCE Concentration BDL-10 ppb 0 100' 200' Graphic Scale: 1" = 100' �n 0 o N U w � O � a~ ai •Y � U L; ti. Q O QI II Cz .� � rn Figure 0 • MW-5 & 1. S, MW-12 Wooded Area 1� ® Water MW-11 Towers Estimated Impacted Source Area MW-4 1 9 A! Brick DW-4 Residential h1W-13 0 ` T 'MW-10b (131JL) Home O MW-g hIVU-6b Pump Brick MW-22 ® MW-21 / House -T h W-14 Garage M W-3 rb f2 hIW-18� DW-I rb Boiler Mobile House Homes DW-2 h1W-20 MW-1 11 nn DW Trailer Park (,.h) 1 4P NIA'-19 4' hIW-16 1, 1 1 0 1 Tv Fence Burn,, Road (SR 1500 Wooded Maui Plant Building Electrical Substation ISA DW-3 — — — X x Property Line Fence Line ® bIW-16 Saprolite Unit Well ® DW-3 Bedrock Unit Well 3 —@ Cross Section Line (390) PCE Concentration in ppb BDL) Below Labratory Detection Limit (Ns) Not Sampled Supported by Data inferred 0 PCE Concentration 1,000-10,000 ppb ■ ® PCE Concentration 100-1,000 ppb Parking T,ot PCE Concentration 10-100 ppb ■ ® PCE Concentration BDL-10 ppb 0 100, 200' Graphic Scale: 1" = 100' O O N r� a� U N Q N o R p; �z o N V4 O d .� U ,,O �- 0 U u a U �� o Figure Z, Wooded Area MW-22 S ® Water MW_1O Towers Estimated Impacted Source Area MW'-4 S 19 Brick P• t DW-4 Residential LVRV-13 S Pr PJG'-10b Home • t_ Pt 6 MW'-17 N ,8•Pt8 MW-6b Pt 10 P1 ` Pump A1W-21 S House Brick Garage 1- SMW-14 D '-3 IvIW'-18 & ❑ DW'-1 Mobile Homes ® DW-2 MW-1 DW-5 Trailer Park IvAV-19 MW-16 n 0 B iel Road (SR 1500 MW'-O' ASTs C Boiler House S -is DW-3 DUNCKLEE r i�r C�. Dvly �M T,..- ff1�AL-s`rLr''"02 511 �[9.ESt LiUVE - SVIiE 10] UTICE 1019)35$-9598 cnar. I+M UMUNI nOM WEB Ewr+criEErvt+tuaca�t Job No. Layers Date 02600 0, 1, 34 1/28/2008 Drawing Figure Scale 02600-1 10 As Shown Title Site Plan with Water Injection Point Locations September 24-27, 2007 Project Kayser Roth Facility Asheboro, North Carolina Main Plant Building Electrical Substation 1 — Fence Parking Lot Legend Property Line X---X Fence Line &ff-16 Saprolite Unit Well 5%oDW-3 Bedrock Unit Well R g Cross Section Line Water Injection Point Scale 90 45 0 90 180 1 "=90' Wooded Area Icy MW-22 (157.41) MW-12 (172.Q1 Water 11 Towers Estimated ImpacteJ71 is Source Area (17 . 1)O M��'-4 — (172.76)S 16' ' Brick 10 DW-4 Residential MW-13 9 -10b Home (169.56) 1 DRY) 1633 MW-17� (164.28) 1-8 � Mom'-6b 161 � 61 (170.3� Pump MW-21 House i160.03) Garage I MW-14 (MW 18 (DRY) k 3 I r,1. CA w DW-1 cn n Mobile Homes + (D S ®DW-2 MW-20e-]- S(I3.35) 165.30) MW-1 DW-5 I , Trailer Park NRV-19 (DRY) e MW-16 n 0 0 8'In1v1 Road (sR 1500) Mtn-5& DUNCKLEE & DUNI IAM E 'T'ONNENTAL CONSUL7AMTS 51It�LSLERLRNE - SUITE 102 CARP, r+oRTM CAROLQJA 2751! ICE(174.42) WWED DUWKUlU)UN WC M Job No. Layers Date 02600 0, 1, 35 1/28/2008 Drawing Figure scale 02600-1 11 As Shown it e Saprolite Ground Water Contour Map October 8, 2007 ASTs —I Project Kayser Roth Facility Asheboro, North Carolina 165 I Boiler House � Fence Dom'-2bAV DW-3 Main Plant Building Electrical Substation Parking Lot Legend Property Line Xz----< Fence Line .NM-16 Saprolite Unit Well NDW-3 Bedrock Unit Well &� Cross Section Line (175.33) Ground Water Elevation in Feet Ground Water Contour Line in Feet Inferred Ground Water Contour Line Ground Water Flow Direction Not Measured Note: The average hydraulic gradient across the site is 0.03 ft/ft based on well pair distances between MW-11 to MW-13, MW-17 to MW-21, and MW-3 to MW-1 Scale 90 45 0 90 180 1 11=90' Wooded Area NINX'-22 (110 n w Brick Residential Home D NIW-21 1:1 Brick Garage Q5 Mobile Homes Estimated Impacted Source Area -,_ MW-12 ® Water MW-11 Towers SO MNV-4 (172.12)19 DW-4 M\TV -5 & DUNCKLEE ^ -I LA` - � UUN M & DU ENVM MENTAL CONSULTANTS :11 KEOMER DRIVE - SUITE 102 CARP, NOR1N CARO 9) 55 2751: �TIQ 19J9)!Si-9693 WEB r-utr UMUIVAM COM Job No. Layers Date 02600 0,36 1/28/2008 Drawing Figure Scale 02600-1 12 As Shown Title Bedrock Unit Ground Water Contour Map October 8, 2007 ,STs Project Kayser Roth Facility Asheboro, North Carolina MRY1-139 7 -10b 172 ' 17 171 Legend MW-17 & Property Line 169 - MWI-6b 1G7 169 �-�( Fence Line 166 Main mp Plant 165 e \ Building1vIW-16 Saprolite Unit Well �NiW 1464 �/- T\M�-2b6 19DW-3 Bedrock Unit Well NIVV'-18 � 63 — ® (161.93 Electrical Substation @—� Cross Section Line DW-1 175.33) Ground Water Elevation in Feet Ground Water Contour Line in Feet Boile DW-2 Hous$ N11G'-29 (167.42) \ Inferred Grotmd Water Contour Line & ��U,1.97j i ® �_ MVi'-20 -1- I DW-3 0 MAN'-1 16r, 167 Ground Water Flow Direction DW-5 O Trailer Park 1 1 6_ -, Not Measured Note: The average hydraulic gradient across the � g Y M\V-19 site is 0.04 ft/ft based on well pair distances between DW-2 to DW-3, and DW-I to DW-4 MON m Bun2v1 Road (SR 1500 01— MW-16 Fence Parking Lot Scale 90 45 0 90 180 1 11=901 Wooded Area Brick Residential Home (<1) (9.7) P— rb w n � IMobile Homes Iv V'-9 (NS) 9 MW-12 ®1) Water b1N`V-11O Towers Estimated Impacted Source Area 1ANV-4 (NS) +Sr DW-4 -10b (14.7) DRY) (23 50) MWI-lb -- (128) (<1) Pump House (DRY) MW-1 51 �(DR 3 MW-18 (456> DNV'-2 DINk'-20 -� (�I) (DRY) MW-1 DNN'-5 1 t I Trailer Park V (NS) MVV-19 (DRY) a MVi/-16 C:D a Bunilil Road (SR 1500) MW-5'9 ASTs Boiler House Fence 1 N"' (NS_ DN`G'-3 DUNCKLEE R DUNI iAM NTS envve0.Nm.x AVLc-',U, E102 ;11 l�tSl.FR DRIVE 9JfTE I0: ROLM 27,11 CAR OFFICE '939)!51-908 WEB NORiH C E[)UHH C0M WEB GVFICYtEmUNSAMCOM Job No. Layers Date 02600 0,37 1/28/2008 Drawing Figure Scale 02600-1 13 As Shown Title PCE Plume in Saprolite Unit, October 10, 2007 Project Kayser Roth Facility Asheboro, North Carolina Main Plant Building Electrical Substation Parking Lot Legend Property Line Xz--� Fence Line eNM-16 Saprolite Unit Well 19DW-3 Bedrock Unit Well g Cross Section Line (480) PCE Concentration in ppb (NS) Not Sampled PCE Concentration 1,000-10,000 pp PCE Concentration 100-1,000 ppb ❑ PCE Concentration 10-100 ppb PCE Concentration BDL-10 ppb Scale 90 45 0 90 180 1 t'=90' Wooded Area NIV'-22 Brick Residential Home Nf\V-21 ❑ 9 Brick Garage Mr,-9 Mobile Homes ,9 MW-12 ® Water bAV_10/1 Towers W-4 10 W-4 NnV-13 & '-10b (1.1) NM'-17 N MW-14 09 IVRV-18 MW-20 je Doti Trailer Park IhRxl-19 �.I Estimated Impacted Source Area --� MW-5 9 ASTs O O MW-6b Pump �--House ►'�'-3 I I MW-2b,� DLJNCKLEE R DUN LIAM ENYTYIONMENTAL CONSULTANTS 5I1 Fv:ISLER GRI'fE - SUITE 102 CAR CARO OFFR'E 1919)959-969! WEB GVIrF]iEDUli{AAICOM WEB tDUI Z.EEDUJA C0M Job No. Layers Date 02600 0,38 1/28/2008 Drawing Figure Scale 02600-1 14 As Shown it e PCE Plume in Bedrock Unit, October 10, 2007 Project Kayser Roth Facility Asheboro, North Carolina Main Plant Building Electrical Substation IC MW-16 c:: Fence Parking Lot Bu""'i' Road (SR 1500) Legend Property Line X4 ----- — X Fence Line AM-16 Saprolite Unit Well 0iDW-3 Bedrock Unit Well B B Cross Section Line (480) PCE Concentration in ppb (NS) Not Sampled PCE Concentration 1,000-10,000 ppb O PCE Concentration 100-1,000 ppb ❑ PCE Concentration 10-100 ppb PCE Concentration BDL-10 ppb Scale 90 45 0 90 180 111=90' U O U ® S ru O �z 210 MW-11 Pt-3 MW-10b MW-10c 210 U C C v — _ Pt-5 Yt-7 t_9 �.n7p_g Ground Surface DW-1 200-3 DW-2 MW_I 200 ;~ > .5 190 Clay and Silt Saprolite 190 W °o to Soft Weathered Rock y 180 — 180 w i - _.. 170 + + + (T�S) — O ON 160 (128) iG) 160 y r; + + + + + + + + + + _rq 150 + + + + + + + + + - — — 150 Q 140 + + + + + + + + + + \+ + + Hard W�eathercd + + + + + + + _ Iv + + + + + + + + + + + + + �t Rock to Fractures + + + + + + + — _ _ l30 + + + + + + + + + + + + + d rock + + + + + + + + + + J 130 C + + + + + + + + + + + + + + + + + + + + + + + + — �120 � 120 + + + + + + + + + + + +- + + + + + + + + + + + _ N + + + + + + + + + + + + + + +� + + + + + + + + + 7+ + + 110 C 110+ + + + + + + + + + + + + + + + +.+ + + + + + + + + + +r + + + + + + + + + + + + + + + + + + + + + + + + - + + `100 o c c 100 + + + + + + + + + + + + + + + + + + + + + + +� ` + + + + + +- '' q 90 + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - 90 — + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + --+ —� so ` 8U A legend: h ❑ Well Casing F+�' �i © Well Screen Approximate Horizontal Scalc V=30' Vertical Scale as Shuwn 9u } Approximate Location of Potassium Permanganate Slurry Injection (Phase 111) +� ❑ and Water Injection (Phase IV) F (3,111, PCE in ug/L (ppb) [251 TCR Concentration w Water Table (10-08-07) PCE Concentration 1,000-10,000 ppb r..r r..r ■ PCF. Concentration 100-1,000 ppb h.. ❑ PCF, Concentration 10-100 ppb Z J ■ PCE Concentration BDL-t0 ppb z ✓, Note: Isoconcentration are dashed where inferred ~ ~ r'1 Temporary Injection Point Advanced on September 28, 2007