HomeMy WebLinkAboutNC0089915_Material Safety Data Sheet_20190430BRENNTAGM MATERIAL SAFETY DATA Page 1/ 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Chemical description
Sodium hypochlorite , Chlorine bleache lye , Javel water, solution (5<20% Cl active
Type of product
Pure product in solution .
Reach registration number :
01-2119488154-34
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified use(s)
See table on the front page of the annex.
Use(s) advised against
This product is not recommended for any industrial, professional or consumer use
other than identified in table on the front page of the annex.
Not for use in ornamental articles, in tricks and jokes and in games (in accordance
with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or
mixtures, which are fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes
2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2,
2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7
adverse effects on sexual function and fertility or on development, 3.8 effects other
than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1).
1.3. Details of the supplier of the safety data sheet
Company identification
BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK
TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11
E-MAIL: info@brenntag.be - Website: www.brenntag.be
BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT
TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919
E-MAIL: info@brenntag.nl - Website: www.brenntag.nl
1.4. Emergency telephone number
Emergency phone number
Belgium : Antipoison Center - Brussels
TEL: +32(0)70/245.245
The Netherlands : National Poisoning Information Center - Bilthoven
TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in
cases of acute intoxications)
SECTION 2. Hazards identification
2.1. Classification of the substance or mixture
Classification accordina to Reaulation IECI No 1272/2008
Corrosive to metals - Category 1 - Warning (Met. Corr. 1; H290)
Skin corrosion - Category 1 B - Danger (Skin Corr. 1 B; H314)
Serious eye damage - Category 1 - Danger (Eye Dam. 1; H318)
Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (Aquatic Acute 1; H400)
Hazardous to the aquatic environment - Chronic hazard - Category 2 (Aquatic Chronic 2; H411)
2.2. Label elements
Label in accordance with Reaulation (EC) No 1272/2008
• Dangerous ingredient(s) Sodium hypochlorite, solution ...% Cl active
• Hazard pictogram(s)
<C>
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page : 2 / 10
Revision : 30/1/2019
Revision nr: 11
SODIUM HYPOCHLORITE 5<20%
Supersedes : 16/11/2015
Code : 16188
SECTION 2. Hazards identification (continued)
• Signal word Danger
• Hazard statements H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye
damage. H410 - Very toxic to aquatic life with long lasting effects. EUH031 -
Contact with acids liberates toxic gas.
• Precautionary statements
- Prevention P260 - Do not breathe fume/gas/mist/vapours/spray. P273 - Avoid release to the
environment. P280 - Wear protective gloves/protective clothing/eye protection/face
protection.
* - Response P303+P361+P353+P310 - IF ON SKIN (or hair): Remove immediately all
contaminated clothing. Rinse skin with water/shower. Immediately call a POISON
CENTER/doctor/... P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or doctor. P390 - Absorb
spillage to prevent material damage.
2.3. Other hazards
Physical/chemical hazards
The substance decomposes by heating and under influence of sunlight in formation
of toxic and corrosive vapours and in formation of oxygen that promotes fire.
Hazards for the health
A health dangerous concentration in the air will rahter slowly be reached by
evaporation of this substance at app. 20°C; by spraying much faster.
Hazards for the environment
Product causes a strong rise of the pH -value of water and soil. This product is no
substance or contains no PBT or vPvB (in accordance with Annex XIII).
Hazards for the safety
Incombustible product, but stimulates fire of other materials.
SECTION 3. Composition/information on ingredients
3.1. Substances
Name component(s)
Weight %
CAS nr
EINECS nr
Index nr
Reach nr
CLASSIFICATION
Sodium hypochlorite, solution
: 5 < 20 % Cl act.
7681-52-9
231-668-3
017-011-00-1
01-2119488154-34
Met. Corr. 1; H290
% Cl active
Skin Corr. 1 B; H314
STOT SE 3; H335
Aquatic Acute 1; H400
Aquatic Chronic 1; H410
EUH031
Sodium carbonate anhydrous
1 < 3 %
497-19-8
207-838-8
011-005-00-2
01-2119485498-19
Eye Irrit. 2; H319
Sodium hydroxide
0.5 < 1 %
1310-73-2
215-185-5
011-002-00-6
01-2119457892-27
Met. Corr. 1; H290
Skin Corr. 1A; H314
Sodium hypochlorite :
Note B (Regulation (EC) No 1272/2008) applies to the product or one or more of its components.
Note: M-factor=10 ( Acute ); Note: M-factor=1 ( Chronic )
Note: SCL applicable
Sodium hydroxide :
Note: SCL applicable
The full text of the (EU)H-statements is in section 16.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 3/ 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 4. First aid measures
4.1. Descriation of first aid measures
General CALL A PHYSICIAN IN ALL CIRCUMSTANCES.
Never give anything by mouth to an unconscious person.
First Aid Measures
- Inhalation Remove victim into fresh air.
Allow the affected person to rest in semi -sitting position.
If not breathing, give artificial respiration.
Seek medical attention IMMEDIATELY.
- Skin Contact Remove contaminated clothing and shoes while rinsing.
Rinse skin immediately with plenty of water. (shower if necessary).
Immediately call a POISON CENTER or doctor/physician.
- Eye Contact Rinse immediately thoroughly and long (at least 15 min.) with plenty of water.
Remove contact lenses.
Keep rinsing or dripping the eye during transport.
Immediately call a POISON CENTER or doctor/physician.
- Ingestion DO NOT INDUCE VOMITING. Rinse mouth with water.
Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
See section 11.
4.3. Indication of anv immediate medical attention and saecial treatment needed
For specialist advice doctors should contact the NVIC or the Belgian Poison center
SECTION 5. Firefighting measures
5.1. Extinauishina media
Extinguishing Media
Suitable In case of nearby fire, use preferably water spray.
Insuitable Not known .
5.2. Special hazards arising from the substance or mixture
Special Exposure Hazards Contact with acids liberates toxic gas. ( E.g. Chlorine gas )
5.3. Advice for firefighters
Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close
Firefighters proximity to fire.
Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter
environment.
SECTION 6. Accidental release measures
6.1. Personal Drecautions. Drotective eauioment and emeraencv Drocedures
Personal Precautions Evacuate all personnel immediately and ventilate area.
Avoid breathing vapour and contact with skin, eyes and clothing. Wear
recommended personal protective equipment. (See section 8)
6.2. Environmental precautions
Environmental Precautions Shut off leaks if without risks.
Dike in the spilled product as much as possible with inert material.
Prevent entry of product in public water, sewers or soil.
Notify authorities if product enters sewers or public waters.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page: 4 / 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 6. Accidental release measures (continued)
6.3. Methods and material for containment and cleaning up
Methods for Cleaning Up Collect the spillage in closable, corrosion resistant, suitable disposal containers.
Clean up any spills as soon as possible, using an inert absorbent material.
Residue is to be washed down with plenty of water.
6.4. Reference to other sections
For personal protection, see section 8.
For the removal of the waste product, see section 13.
SECTION 7. Handling and storage
7.1. Precautions for safe handlin
Handling AVOID FOG TRANSFORMATION! STRONG HYGIENE!
Avoid breathing vapour and contact with skin, eyes and clothing. Wear
recommended personal protective equipment. (See section 8)
Avoid splashing and formation of vapour when emptying or diluting the product.
When diluting: add the basic solution in water, never the other way around.
When using, do not eat, drink or smoke.
Emergency eye wash fountains and showers should be available in the immediate
vicinity of any potential exposure.
7.2. Conditions for safe storaae. includina anv incomaatibilities
Storage Keep only in the original, safely locked container in a well ventilated, cool and dark
place.
All dangerous products should be placed on a drip tray or should be barreled.
Keep away from : Combustibles , Reducing materials , Acids .
Packaging Material PVC , Polyethylene , Polyester, Steel covered with Ebonite .
Insuitable Packaging Material Metals .
7.3. Specific end use(s)
For identified uses, see subsection 1.2 and/or exposure scenarios.
SECTION 8. Exposure controls/personal protection
8.1. Control aarameters
Occupational Exposure Limits Sodium hypochlorite, solution ...% Cl active: Short time value (BE) : 0,5 ppm (1,5
mg/m') (2014) (Chlorine)
Sodium hydroxide: Limit value (BE) : 2 mg/m3 (2014) (M)
(M) The mention "M" means that the exposition above the limit value causes
irritation or that there is a danger for acute poisoning. The work procedure has to
be designed somehow or other that the exposition doesn't exceed the limit value.
During a control, the sample period should be so short as possible to carry out a
reliable measurement. The mesure result is then related to the considered period.
Biological limit values
DNELs
BRENNTAG
They will be included when available.
• Sodium hypochlorite, solution
inhalation : 3,1 mg/m3
• Sodium hypochlorite, solution
inhalation : 3,1 mg/m3
• Sodium hypochlorite, solution
inhalation : 1,55 mg/m3
• Sodium hypochlorite, solution
inhalation : 1,55 mg/m3
• Sodium hypochlorite, solution
inhalation : 1,55 mg/m3
• Sodium hypochlorite, solution
Cl• active
: Worker, acute - local effects,
Cl• active
: Worker, acute - systemic effects,
Cl• active
: Worker, long-term - local effects,
Cl• active
: Worker, long-term - systemic effects,
Cl• active
: Consumer, long-term - local effects,
Cl• active
: Consumer, long-term - systemic
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page :5/10
Revision : 30/1/2019
Revision nr : 11
SODIUM HYPOCHLORITE 5<20%
SECTION 8. Exposure controls/personal protection (continued)
Supersedes : 16/11/2015
Code : 16188
effects, inhalation : 1,55 mg/m3
• Sodium hypochlorite, solution
...% Cl active : Consumer, long-term - systemic
effects, oral : 0,26 mg/kg
• Sodium carbonate anhydrous
: Worker, long-term - local effects, inhalation : 10
mg/m'
• Sodium carbonate anhydrous
: Consumer, acute - local effects, inhalation : 10
mg/m'
• Sodium hydroxide : Worker, long-term
- local effects, inhalation : 1,0 mg/m2
• Sodium hydroxide : Consumer,
long-term - local effects, inhalation : 1,0 mg/m3
PNECs • Sodium hypochlorite, solution
...% Cl active: Fresh water: 0,21 mg/I
• Sodium hypochlorite, solution
...% Cl active: Marine water: 0,042 mg/I
• Sodium hypochlorite, solution
...% Cl active: Fresh water sediment : Not expected
• Sodium hypochlorite, solution
...% Cl active : Marine water sediment: Not
expected .
• Sodium hypochlorite, solution
...% Cl active : Soil : Not expected .
• Sodium hypochlorite, solution
...% Cl active : Sewage treatment plant : 0,03 mg/I
• Sodium carbonate anhydrous
: Not applicable
• Sodium hydroxide : Not applicable
8.2. Exposure controls
Engineering Measures Ventilation , Local exhaust ( If possible through the floor ).
Personal Protection Equipment
Respiratory protection CE-approved mask for inorganic vapours (type B, grey).
* Skin protection Chemical resistant clothing and boots (EN 14605) .
Hand protection Suitable material for safety gloves (EN 374):
The suitability of the gloves and the breakthrough time for a specific workplace
should be discussed with the producers of the protective gloves.
- material : Nitril rubber
- thickness : 0,5 mm
- penetration time : > 8 h
Eye/Face protection Closed safety glasses or face shield.
Environmental exposure controls See sections 6, 7, 12 and 13.
SECTION 9. Physical and chemical properties
9.1. Information on basic ohvsical and chemical orooerties
See technical data sheet for detailed information
Physical State (20°C)
Liquid .
Form/Colour
Clear, Yellow -green.
Odour
Weak chlorine odour. .
Odour threshold
No data available.
pH value
: > 12,5 .
* Melting/Freezing point
-20 °C ( solution 12% Cl active )
Boiling Point/Range (1013 hPa)
Not applicable. ( Decomposes )
Flash point
Not applicable.
Fire hazard
Not applicable.
Evaporation rate
No data available.
Explosion limits in air
Not applicable.
Vapour pressure (20°C)
: 2,5 kPa
Relative vapour density (air=1)
No data available.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 6/ 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 9. Physical and chemical properties (continued)
Relative density of saturated vapour/air
mixture (air=1)
Density (20oC)
Solubility in water
Log P Octanol/Water (20°C)
Auto -ignition temperature
Minimum ignition energy
Decomposition temperature
Viscosity (20°C)
Explosive properties
Oxidizing properties
No data available.
1,22 kg/I
Complete solubility .
-3,42
Not applicable.
Not applicable.
20 °C ( Decomposition in function of temperature and incidence of light )
2,6 mPa.s ( Dynamic)
No chemical groups associated with explosive properties .
No chemical groups associated with oxidizing properties .
SECTION 10. Stability and reactivity
10.1. Reactivit
Reactivity The product is a strong oxidizer and reacts violently with combustibles and
reducing agents. Reacts violently with acids . Corrosive to all metals.
10.2. Chemical stability
Stability Stable at normal circumstances .
10.3. Possibility of hazardous reactions
Hazardous reactions The substance decomposes by heating and under influence of sunlight in formation
of toxic and corrosive vapours and in formation of oxygen that promotes fire.
Contact with acids liberates toxic gas.
10.4. Conditions to avoid
Conditions to avoid High temperatures , Light .
10.5. Incompatible materials
Materials to avoid Combustibles , Reducing materials , Acids , Metals .
10.6. Hazardous decomposition products
Hazardous Decomposition Products : Chlorine , Hydrogen chloride ( Gas ).
SECTION 11.
Toxicological information
11.1. Information on toxicological effects
Acute toxicity
- Inhalation
Symptoms include: Sore throat , Cough , Difficulty in breathing .
• Sodium hypochlorite, solution ...% Cl active : LC50 (Rat, inhalation, 1 h) : >10,5
mg/I ( Air; OECD Guideline 403)
• Sodium carbonate anhydrous : LC50 (Rat, inhalation, 2 h) : 2,3 mg/I ( Aerosol;
OECD Guideline 403)
• Sodium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available.
- Skin contact
Symptoms include: Redness, Pain .
• Sodium hypochlorite, solution ...% Cl active: LD50 (Rabbit, dermal) : >20000 mg/
kg ( OECD Guideline 402)
• Sodium carbonate anhydrous : LD50 (Rabbit, dermal) : >2000 mg/kg
• Sodium hydroxide : LD50 (Rabbit, dermal) : No data available.
- Ingestion
Symptoms include: Sore throat , Abdominal pain , Vomiting .
• Sodium hypochlorite, solution ...% Cl active: LD50 (Rat, oral) : 8910 mg/kg
OECD Guideline 401)
• Sodium carbonate anhydrous : LD50 (Rat, oral) : 2800 mg/kg
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page :7/10
Revision : 30/1/2019
Revision nr : 11
SODIUM HYPOCHLORITE 5<20%
SECTION 11. Toxicological information (continued)
Skin corrosion/irritation
Serious eye damage/irritation
Aspiration hazard
Respiratory or skin sensitisation
Carcinogenicity
Mutagenicity
Reproductive toxicity
Specific target organ toxicity - single
exposure
Specific target organ toxicity - repeated
exposure
Supersedes : 16/11/2015
Code : 16188
• Sodium hydroxide : LD50 (Rat, oral) : No data available.
Causes severe burns.
Causes serious eye damage.
Inhalation can cause pneumonia and/or pulmonary oedema, but only after signs of
corrosive effects on the mucous membranes of the eyes and/or the upper
respiratory tract.
Not sensitive .
Not listed as carcinogenic .
Not listed as mutagenic .
Not listed for reproductive toxicity .
To human : May cause respiratory irritation.
To human : Listed not for organ toxicity .
For animals : No effects known.
SECTION 12. Ecological information
12.1. Toxicit
Ecotoxicity • Sodium hypochlorite, solution ...% Cl active: LC50 (Fish, 96 h) : 0,062-0,095 mg/I
(Oncorhynchus mykiss)
• Sodium hypochlorite, solution ...% Cl active: EC50 (Daphnia magna, 48 h) : 0,
0141 mg/I ( OECD Guideline 202)
• Sodium hypochlorite, solution ...% Cl active: NOEC (Algae, 7 d) : 0,0021 mg/I
Fresh water)
• Sodium carbonate anhydrous : LC50 (Fish, 96 h) : 300 mg/I (Lepomis
macrochirus)
• Sodium carbonate anhydrous : EC50 (Algae, 72 h) : No data available.
• Sodium carbonate anhydrous : EC50 (Daphnia magna, 48 h) : 200-227 mg/I
Ceriodaphnia dubia)
• Sodium hydroxide: LC50 (Fish, 96 h) : 35-189 mg/I
• Sodium hydroxide : EC50 (Algae, 72 h) : No data available.
• Sodium hydroxide: EC50 (Daphnia magna, 48 h) : 40,4 mg/I (Ceriodaphnia sp.)
12.2. Persistence and degradability
Persistence and degradability
• Sodium hypochlorite, solution ...%
Cl active : Persistence and degradability
Inorganic .
• Sodium carbonate anhydrous :
Persistence and degradability : Inorganic .
• Sodium hydroxide : Persistence
and degradability : Inorganic .
12.3. Bioaccumulative potential
Bioaccumulation
• Sodium hypochlorite, solution ...%
Cl active: Bioaccumulation : No
bioaccumulation .
• Sodium carbonate anhydrous :
Bioaccumulation : No bioaccumulation .
• Sodium hydroxide : Bioaccumulation : Bioaccumulation not expected .
12.4. Mobility in soil
Mobility
• Sodium hypochlorite, solution ...%
Cl active : Mobility : Completely soluble in
water .
• Sodium carbonate anhydrous :
Mobility : No absorption expected to the ground.
• Sodium hydroxide : Mobility : High potential for mobility in soil.
12.5. Results of PBT and vPvB assessment
Evaluation
• Sodium hypochlorite, solution ...%
Cl active: PBT/vPvB : No
• Sodium carbonate anhydrous :
PBT/vPvB : No
• Sodium hydroxide: PBT/vPvB
: No
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page :8/10
Revision : 30/1/2019
Revision nr : 11
SODIUM HYPOCHLORITE 5<20%
SECTION 12. Ecological information (continued)
12.6. Other adverse effects
Photochemical ozone creation potential
No data available.
Ozone depletion potential
No data available.
Endocrine disrupting potential
No data available.
Global warming potential
No data available.
SECTION 13. Disposal considerations
Supersedes : 16/11/2015
Code : 16188
13.1. Waste treatment methods
Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a
company specialised in handling hazardous waste products.
European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the
most current applications and can not be representative for pollutions which are
arisen at the effective use of the product. The producer of the waste has to
evaluate its process himself and has to grant the appropriate waste coding. See
Decision 2001/118/EC.
Removal contaminated packaging Packing is to be used exclusively for the packing of this product.
After use, empty and close the packing very carefully.
In case of returned packing, the empty packing can be offered back to the supplier.
SECTION 14. Transport information
14.1. UN number
UN Number
14.2. UN nroaer shiaaina name
1791
ADR/RID Name
UN 1791 Hypochlorite solution, 8, II, (E)
ADN Name
UN 1791 Hypochlorite solution , 8, II
IMDG Name
UN 1791 Hypochlorite solution , 8, II, MARINE POLLUTANT
IATA Name
UN 1791 Hypochlorite solution, 8, II
14.3. Transport hazard classe(s)
Class
14.4. Packing group
Packaging Group
14.5. Environmental hazards
Environmentally hazard
Marine pollutant
14.6. Special precautions for user
Danger number
Hazard Label(s)
EmS-N°
14.7. Transaort in bulk accordina
Type ship
Pollution category
BRENNTAG
8
Yes
Yes
80
8
F-A , S-B
to Annex II of MARPOL and the IBC Code
Not applicable.
Not applicable.
BRENNTAGM MATERIAL SAFETY DATA Page 9/ 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Inventories Australian inventory (AICS): Listed in inventory.
Canadian inventory (DSL): Listed in inventory.
European inventory (EINECS): Listed in inventory.
Japanese inventory (ENCS): Listed in inventory.
Korean inventory (KECI): Listed in inventory.
Chinese inventory (IECS): Listed in inventory.
Philippine inventory (PICCS): Listed in inventory.
Inventory of the United States (TSCA): Listed in inventory.
NFPA no : 2-0-2-OXY
Relevant EU Rule(s)
Directive 96/82/EC of the Council of 9 December 1996 on the control of major -
accident hazards involving dangerous substances
Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision
2000/532/EC as regards the list of wastes
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/
2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (Reach)
The restrictions in Annex
XVII to Regulation (EC) No 1907/2006 must be observed.
National regulations
- Germany
WGK : 2
- Netherlands
Water damaging : 5
Decontamination exertion : B
15.2. Chemical Safety
Assessment
A chemical safety assessment has been carried out for the material.
SECTION 16. Other information
This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006.
This safety data sheet is exclusively made for industrial/professional use.
* Has changed compared to previous revision.
* Changes Section 2 , Section 8 , Section 9 .
Sources of used key data The information contained herein is based on the present state of our knowledge
Producer(s) , Chemical cards , ...)
See also on the webaddress:
http://apps.echa.europa.eu/registered/registered-sub.aspx#search
(EU)H-statement(s) H290 - May be corrosive to metals.
H314 - Causes severe skin burns and eye damage.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H400 - Very toxic to aquatic life.
H410 - Very toxic to aquatic life with long lasting effects.
EUH031 - Contact with acids liberates toxic gas.
Classification procedure Met. Corr. 1; H290 - Based on test data (producer of component)
Skin Corr. 1 B; H314 - Additivity method
Aquatic Acute 1; H400 - Calculation method
Aquatic Chronic 2; H411 - Calculation method
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page: 10 / 10
SHEET Revision : 30/1 /2019
Revision nr : 11
Supersedes : 16/11/2015
SODIUM HYPOCHLORITE 5<20%
Code: 16188
SECTION 16. Other information (continued)
List of abbrevations and acronyms ADN (Accord europeen relatif au transport international des marchandises
Dangereuses par voie de Navigation interieur) : European agreement concerning
the international carriage of dangerous goods by inland waterways
Aquatic Acute 1 : Hazardous to the aquatic environment - Acute hazard - Category
1
ADR (Accord europeen relatif au transport international des marchandises
Dangereuses par Route) : European agreement concerning the international
carriage of dangerous goods by road
Aquatic Chronic 1 : Hazardous to the aquatic environment - Chronic hazard -
Category 1
Aquatic Chronic 2 : Hazardous to the aquatic environment - Chronic hazard -
Category 2
CO: Carbon monoxide
DNEL (Derived No Effect Level) : an estimated safe exposure level
EC50 : median Effective Concentration
EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and
the second code refers to the relevant spillage schedule
IATA (International Air Transport Association) : provisions concerning the
international carriage of dangerous goods by air
IMDG (International Maritime Dangerous Goods code)
LC50 : median Lethal Concentration
LD50 : median Lethal Dose
Met. Corr. 1 : Corrosive to metals - Category 1
M-Factor : a multiplying factor that is applied to the concentration of a substance
classified as hazardous to the aquatic environment (Aquatic Acute 1; H400 or
Aquatic Chronic 1; H410) and is used to derive by the summation method the
classification of a mixture in which the substance is present
NFPA (National Fire Protection Association) or fire diamant
NOEC (No Observed Effect Concentration)
NVIC : National Poisoning Information Center
OECD : Organisation for Economic Cooperation and Development
PVC : Polyvinyl chloride
PBT : persistent, bioaccumulative and toxic
PNEC (Predicted No Effect Concentration) : concentration below which exposure to
a substance is not expected to cause adverse effects
REACH : Registration, Evaluation, Authorisation and restriction of Chemicals
RID (Reglement concernant le transport International ferroviaire des marchandises
Dangereuses) : Regulation concerning the International carriage of Dangerous
goods by rail
SCL (Specific Concentration Limits)
Skin Corr. 1 B : Skin corrosion - Category 1 B
TWA (Time -Weighted Average) : the average exposure over a specified period
WGK (Wassergefahrdungsklasse) : a German classification of substances that
indicate the environmental hazard for surface water
vPvB : very persistent and very bioaccumulative
This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only
concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in
case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is
suitable and complete concerning the special use he makes of the product.
BRENNTAG denies all responsibility for loss or damage resulting from the use of these data.
End of document
BRENNTAG
&AD s u e2
SAFETY DATA SHEET
KLARAID* CDP1336
1. Identification
Product identifier KLARAID CDP1336
Other means of identification None.
Recommended use Coagulant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Version: 4.0
Effective Date: Jul-16-2019
Previous Date: Dec-17-2017
Physical hazards Not classified.
Health hazards Serious eye damage/eye irritation Category 2
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
OSHA defined hazards Not classified.
Label elements
< >
1
•
Signal word Warning
Hazard statement Causes serious eye irritation. May cause respiratory irritation.
Precautionary statement
Prevention Wear eye/face protection. Avoid breathing mist or vapor. Wash thoroughly after handling. Use
only outdoors or in a well -ventilated area.
Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation
persists: Get medical advice/attention.
Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
3. Composition/information on ingredients
Mixtures
Page: 1 / 8
Components
CAS # Percent
Aluminium chlorhydroxide
12042-91-0 20 - 40
N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer 26062-79-3 1 - 2.5
Composition comments
Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses.
Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur.
Most important
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause
symptoms/effects, acute and
respiratory irritation.
delayed
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation
emergency procedures of vapors or mists. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained.
Methods and materials for Prevent entry into waterways, sewer, basements or confined areas.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. Ventilate area, use specified protective
equipment.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Water contaminated with this
product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility,
in accordance with any local agreements.
7. Handling and storage
Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Provide
adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices. Use care in handling/storage.
Material name: KLARAID* CDP1336 Page: 2 / 8
Version number: 4.0
Conditions for safe storage,
Store locked up. Store in original tightly closed container. Store in accordance with
including any incompatibilities
local/regional/national/international regulation.
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit
Values
Components
Type Value Form
Aluminium chlorhydroxide
TWA 1 mg/m3 Respirable fraction.
(CAS 12042-91-0)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type Value
Aluminium chlorhydroxide
TWA 2 mg/m3
(CAS 12042-91-0)
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Provide eyewash station. Good general ventilation should be used. Ventilation rates should be
controls
matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Glove selection must take into account any solvents and other hazards present.
Other Wear suitable protective clothing. Use of an impervious apron is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH (concentrated product)
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Colorless to yellow
Liquid
Mild
Not available.
3.6
4.6 (0.5% SOL.)
29 °F (-2 °C)
212 °F (100 °C)
> 200 °F (> 93 °C) P-M(CC)
< 1 (Ether = 1)
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure 18 mm Hg
Material name: KLARAID* CDP1336 Page: 3 / 8
Version number: 4.0
Vapor pressure temp.
Vapor density
Relative density
Relative density temperature
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
Viscosity temperature
Other information
Pour point
Specific gravity
VOC
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
70 °F (21 °C)
< 1 (Air = 1)
1.3
70 °F (21 °C)
100 %
Not available.
Not available.
Not available.
73 cps
70 °F (21 °C)
34 °F (1 °C)
1.305
0 % (Estimated)
The product is stable and non -reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
Hydrogen chloride gas (HCI). Oxides of carbon and nitrogen evolved in fire.
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Prolonged or repeated contact may cause irritation.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause
physical, chemical and respiratory irritation. Skin irritation.
toxicological characteristics
Information on toxicological effects
Acute toxicity May cause respiratory irritation.
Product Species Test Results
KLARAID CDP1336 (CAS Mixture)
Acute
Dermal
LD50
Rabbit
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Oral
LD50
Rat
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Components
Species
Test Results
Aluminium chlorhydroxide (CAS 12042-91-0)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg
Material name: KLARAID* CDP1336 Page: 4 / 8
Version number: 4.0
Components Species Test Results
Oral
LD50
Rat
> 2000 mg/kg
N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer (CAS 26062-79-3)
Acute
Oral
LD50 Rat 3000 mg/kg
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
Aluminium chlorhydroxide (CAS 12042-91-0) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
May cause respiratory irritation.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
Based on available data, the classification criteria
are not met.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product
Species
Test Results
KLARAID CDP1336 (CAS Mixture)
Aquatic
Crustacea
LC50 Daphnia magna
8 mg/L, Static Renewal Bioassay, 48
hour
NOEL Daphnia magna
3.2 mg/L, Static Renewal Bioassay, 48
hour
Fish
LC50 Fathead Minnow
16 mg/L, Static Renewal Bioassay, 96
hour
Rainbow Trout
4.2 mg/L, Static Renewal Bioassay, 96
hour
NOEL Fathead Minnow
6.2 mg/L, Static Renewal Bioassay, 96
hour
Rainbow Trout
1.9 mg/L, Static Renewal Bioassay, 96
hour
Bioaccumulative potential
No data available.
Mobility in soil
No data available.
Other adverse effects
Not available.
Material name: KLARAID* CDP1336 Page: 5 / 8
Version number: 4.0
Persistence and degradability
1-5%
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
UN number
UN3082
UN proper shipping name
Environmentally hazardous substance, liquid, n.o.s. (CATIONIC POLYAMINE)
Transport hazard class(es)
Class
9M1
Subsidiary risk
-
Packing group
III
Environmental hazards
Yes
ERG Code
171
Special precautions for user Not available.
IMDG
UN number UN3082
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CATIONIC POLYAMINE),
MARINE POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS F-A, S-F
Special precautions for user Not available.
IMDG
Marine pollutant
Material name: KLARAID* CDP1336 Page: 6 / 8
Version number: 4.0
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Serious eye damage or eye irritation
categories Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
US state regulations
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
16. Other information, including date of preparation or last revision
Issue date Oct-31-2014
Revision date Jul-16-2019
Version # 4.0
NFPA ratings Health: 2
Flammability: 0
Instability: 0
Material name: KLARAID* CDP1336 Page: 7 / 8
Version number: 4.0
NFPA ratings
i
0
List of abbreviations
CAS: Chemical Abstract Service Registration Number
ACGIH: American Conference of Governmental Industrial Hygienists
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
NFPA: National Fire Protection Association
References:
No data available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information
Composition/information on ingredients: Composition comments
Handling and storage: Conditions for safe storage, including any incompatibilities
Stability and reactivity: Hazardous decomposition products
Transport Information: Material Transportation Information
Regulatory information: California Prop 65
Prepared by
This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: KLARAID* CDP1336 Page: 8 / 8
Version number: 4.0
&AD s u e2
Version: 6.0
Effective Date: May-23-2019
Previous Date: Mar-05-2018
SAFETY DATA SHEET
POLYFLOC* CE1154
1. Identification
Product identifier POLYFLOC CE1154
Other means of identification None.
Recommended use Flocculant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not classified.
Serious eye damage/eye irritation Category 2
Not classified.
1
•
Warning
Causes serious eye irritation.
Wash thoroughly after handling. Wear eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
3. Composition/information on ingredients
Mixtures
Components CAS # Percent
Distillates (petroleum), hydrotreated light 64742-47-8 20 - 40
Alcohols, C12-16 ethoxylated 68551-12-2 2.5 - 10
Alcohols, C10-16, ethoxylated
68002-97-1 1 - 2.5
Page: 1 / 8
Components
CAS # Percent
Citric acid
77-92-9 1 - 2.5
Composition comments
Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Skin contact
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs.
Most important
Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and
symptoms/effects, acute and
blurred vision.
delayed
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).
Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,
containment and cleaning up basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Avoid contact with eyes. Use only in well -ventilated areas. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Store in cool, well ventilated area. Store away from oxidizers. Keep away from heat and sources of
including any incompatibilities ignition. Store in original tightly closed container. Store in accordance with
local/regional/national/international regulation.
Material name: POLYFLOC* CE1154 Page: 2 / 8
Version number: 6.0
8. Exposure controls/personal protection
Occupational exposure limits
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Distillates (petroleum), TWA 100 mg/m3
hydrotreated light (CAS
64742-47-8)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Provide eyewash station. Good general ventilation should be used. Ventilation rates should be
controls matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Glove selection must take into account any solvents and other hazards present.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND
ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE. If engineering controls do not maintain airborne
concentrations below recommended exposure limits (where applicable) or to an acceptable level
(in countries where exposure limits have not been established), an approved respirator must be
worn.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
White to off-white
Emulsion
Slight hydrocarbon
Not available.
4.9 (0.5% SOL.)
< 23 °F (< -5 °C)
Not available.
> 212 °F (> 100 °C) P-M(CC)
< 1 (Ether = 1)
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure 18 mm Hg
Vapor pressure temp. 70 °F (21 °C)
Vapor density > 1 (Air = 1)
Relative density 1.04
Relative density temperature 70 °F (21 °C)
Material name: POLYFLOC* CE1154 Page: 3 / 8
Version number: 6.0
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
1440 cps
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
< 28 °F (< -2 °C)
Specific gravity
1.036
VOC
26 % (ASTM 3960-93)
10. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Ammonia, hydrogen chloride, oxides of carbon and nitrogen evolved in fire.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Causes serious
physical, chemical and eye irritation.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Product Species Test Results
POLYFLOC CE1154 (CAS Mixture)
Acute
Dermal
LD50
Rabbit
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Inhalation
LC50
Rat
> 20 mg/I, 4 Hours, (Calculated according
to GHS additivity formula)
Oral
LD50
Rat
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Components
Species
Test Results
Alcohols, C10-16, ethoxylated (CAS 68002-97-1)
Acute
Oral
LD50
Rat
384 mg/kg
Material name: POLYFLOC* CE1154 Page: 4 / 8
Version number: 6.0
Components Species Test Results
Alcohols, C12-16 ethoxylated (CAS 68551-12-2)
Acute
Oral
LD50 Rat
1600 mg/kg
Citric acid (CAS 77-92-9)
Acute
Dermal
LD50 Rabbit
> 2000 mg/kg
Oral
LD50 Rat
5400 mg/kg
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Acute
Dermal
LD50 Rabbit
> 2000 mg/kg
Inhalation
LC50 Rat > 5.2 mg/I, 4 Hour
Oral
LD50 Rat > 5000 mg/kg
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Not classified.
Serious eye damage/eye
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
This product is not expected to cause respiratory sensitization.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated
Substances (29 CFR 1910.1001-1052)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not met.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Species Test Results
POLYFLOC CE1154 (CAS Mixture)
Aquatic
Algae IC50 Selenastrum (algae) Algal inhibition tests are not appropriate.
Crustacea 10% Mortality Daphnia magna 0.78 mg/L, Static Renewal Bioassay, 48
hour
EC50 Daphnia magna 10 - 100 mg/I, 48 Hour, Fresh water.
Based on test data for structurally similar
materials.
Material name: POLYFLOC* CE1154 Page: 5 / 8
Version number: 6.0
Product Species Test Results
Fish LC50 Bluegill Sunfish
Fathead Minnow
Rainbow Trout
Zebra Fish
NOEL Fathead Minnow
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Citric acid
-1.64
Distillates (petroleum), hydrotreated light
3-6
Bioconcentration factor (BCF)
Citric acid
3
Distillates (petroleum), hydrotreated light
207.7
Mobility in soil No data available.
Other adverse effects Not available.
Persistence and degradability
2.4 mg/L, Static Renewal Bioassay, 48
hour
2.5 mg/L, Static Acute Bioassay, 96 hour
2.8 mg/L, Static Renewal Bioassay, 96
hour
0.94 mg/L, Static Acute Bioassay, 96
hour
1 - 10 mg/I, 96 Hour, Based on test data
for structurally similar materials.
0.7 mg/L, Static Renewal Bioassay, 96
hour
Testing has shown product not to be readily biodegradable. OECD (301 B)
CO2 Evolution (Modified Sturm Test) (OECD 301 B)
At natural pHs (>6) the product degrades due to hydrolysis to more than 70% in 28 days. The
hydrolysis products are not harmful to aquatic organisms.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container
classification.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
General information IMDG Regulated Marine Pollutant.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Material name: POLYFLOC* CE1154 Page: 6 / 8
Version number: 6.0
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Serious eye damage or eye irritation
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Acrylamide (CAS 79-06-1)
Formaldehyde (CAS 50-00-0)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Formaldehyde (CAS 50-00-0)
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
US state regulations
US. California Proposition 65
WARNING: This product can expose you to chemicals including Acrylamide, which is known to the State of California to
cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Acrylamide (CAS 79-06-1) Listed: January 1, 1990
Formaldehyde (CAS 50-00-0) Listed: January 1, 1988
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
16. Other information, including date of preparation or last revision
Issue date May-11-2015
Revision date May-23-2019
Version # 6.0
NFPA ratings Health: 2
Flammability: 0
Instability: 0
Material name: POLYFLOC* CE1154 Page: 7 / 8
Version number: 6.0
NFPA ratings
i
0
List of abbreviations CAS: Chemical Abstract Service Registration Number
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
ACGIH: American Conference of Governmental Industrial Hygienists
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
References: No data available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information Exposure controls/personal protection: Eye/face protection
Physical & Chemical Properties: Multiple Properties
Transport Information: Material Transportation Information
Regulatory Information: Risk Phrases - Classification
Regulatory information: California Prop 65
Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: POLYFLOC* CE1154 Page: 8 / 8
Version number: 6.0
&AD s u e2
Version: 3.1
Effective Date: Dec-17-2017
Previous Date: Jun-17-2016
SAFETY DATA SHEET
POLYFLOC* CE1161 P
1. Identification
Product identifier POLYFLOC CE1161 P
Other means of identification None.
Recommended use Potable water treatment chemical
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not classified.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority requirements.
Combustible.
None.
3. Composition/information on ingredients
Mixtures
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Remove contaminated clothing. Thoroughly wash clothing before reuse.
Page: 1 / 7
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire -fighting measures
Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
Do not feed anything by mouth to an unconscious or convulsive victim. Dilute contents of stomach
using 2-8 fluid ounces (60-240ml) of milk or water. If vomiting occurs, keep head low so that
stomach content doesn't get into the lungs.
Headache. Nausea, vomiting. Diarrhea.
Treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Combustible. No unusual fire or explosion hazards noted
6. Accidental release measures
Personal precautions,
Keep unnecessary personnel away. For personal protection, see section 8 of the SIDS. Spills are
protective equipment and
very slippery.
emergency procedures
Methods and materials for
Use water spray to reduce vapors or divert vapor cloud drift.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SIDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in
well -ventilated areas. Spills are very slippery.
Conditions for safe storage,
Keep away from heat and sources of ignition. Store in original tightly closed container. Store away
including any incompatibilities
from incompatible materials (see Section 10 of the SDS). Store in accordance with
local/regional/national/international regulation.
8. Exposure controls/personal protection
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Material name: POLYFLOC" CE1161P Page: 2 / 7
Version number: 3.1
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into
account any solvents and other hazards present.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
White to off-white
Emulsion
Slight hydrocarbon
Not available.
4.6 (1% SOL.)
< 23 °F (< -5 °C)
Not available.
> 200 °F (> 93 °C) P-M(CC)
Evaporation rate
< 1 (Ether = 1)
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
> 1 (Air = 1)
Relative density
1.04
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
1695 cps
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
< 28 °F (< -2 °C)
Specific gravity
1.038
Material name: POLYFLOC" CE1161P Page: 3 / 7
Version number: 3.1
VOC 25 % (SUPPLIER DATA)
10. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. None under
normal conditions.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Toxic gas. Ammonia, hydrogen chloride, oxides of carbon and nitrogen evolved in fire. Hydrogen
products cyanide evolved in fire.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Prolonged or repeated contact may cause irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Headache. Nausea, vomiting. Diarrhea.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Product Species
POLYFLOC CE1161 P (CAS Mixture)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Test Results
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
> 15.75 mg/I, 4 Hours, (Calculated
according to GHS additivity formula)
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Material name: POLYFLOC* CE1161 P Page: 4 / 7
Version number: 3.1
Not classified.
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Further information
12. Ecological information
Ecotoxicity
Product
Based on available data, the classification criteria are not met. Does not result in classification of
the mixture if the kinematic viscosity is greater than 20.5 mm2/sec measured at 40C.
Prolonged inhalation may be harmful.
This product has no known adverse effect on human health.
Species
POLYFLOC CE1161 P (CAS Mixture)
15% Mortality Fathead Minnow
Aquatic
Crustacea
Bioaccumulative potential
Mobility in soil
Other adverse effects
Persistence and degradability
- COD (mg02/g)
- BOD 5 (mg02/g)
- BOD 28 (mg02/g)
- Closed Bottle Test (%
Degradation in 28 days)
- Zahn-Wellens Test (%
Degradation in 28 days)
- TOC (mg C/g)
30% Mortality Ceriodaphnia
LC50 Ceriodaphnia
Fathead Minnow
Test Results
1.9 mg/L, Static Renewal Bioassay, 96
hour
0.24 mg/L, Static Acute Bioassay, 48
hour
0.34 mg/L, Static Acute Bioassay, 48
hour
5.5 mg/L, Static Renewal Bioassay, 96
hour
15% Mortality Daphnia magna 7.8 mg/L, Static Renewal Bioassay, 48
hour
LC50 Daphnia magna 29.1 mg/L, Static Renewal Bioassay, 48
hour
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Testing has shown product not to be readily biodegradable. At natural pHs (>6) the product
degrades due to hydrolysis to more than 70% in 28 days. The hydrolysis products are not harmful
to aquatic organisms.
1180
272
352
30
A
M
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
Material name: POLYFLOC" CE1161P Page: 5 / 7
Version number: 3.1
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
US state regulations
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Acrylamide (CAS 79-06-1) Listed: January 1, 1990
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
US - Massachusetts RTK - Substance List
Not regulated.
Material name: POLYFLOC" CE1161P Page: 6 / 7
Version number: 3.1
US - Pennsylvania RTK - Hazardous Substances
Not regulated.
US - Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
16. Other information, including date of preparation or last revision
Issue date Feb-18-2015
Revision date Dec-17-2017
Version # 3.1
List of abbreviations CAS: Chemical Abstract Service Registration Number
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
References: No data available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information Other information, including date of preparation or last revision: Prepared by
GHS: Classification
Trademark of SUEZ. May be registered in one or more countries.
Material name: POLYFLOC" CE1161P Page: 7 / 7
Version number: 3.1
&AD s u e2
Version: 3.2
Effective Date: Jan-22-2018
Previous Date: Dec-16-2017
SAFETY DATA SHEET
POLYFLOC* CE1167
1. Identification
Product identifier POLYFLOC CE1167
Other means of identification None.
Recommended use Flocculant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not classified.
Not classified.
Not classified.
None.
None.
The material is not hazardous under the criteria of the Federal OSHA Hazard Communication
Standard's (29CFR 1910.1200) implementation of the Globally Harmonized System (GHS), i.e.,
material is not a dangerous substance or mixture requiring GHS classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of contents/container to approved local facility..
Combustible.
None.
3. Composition/information on ingredients
Mixtures
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
Page: 1 / 7
4. First -aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire -fighting measures
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs.
Headache. Nausea, vomiting. Diarrhea.
Aspiration into the lungs will result in chemical pneumonia and may be fatal.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers exposed to heat with water spray and remove container, if no risk is
involved. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Combustible. No unusual fire or explosion hazards noted
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
protective equipment and
emergency procedures
Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Spills are very slippery. Avoid prolonged or repeated contact with skin. Use only in well -ventilated
areas.
Conditions for safe storage, Keep away from heat and sources of ignition. Store in original tightly closed container. Store away
including any incompatibilities from incompatible materials (see Section 10 of the SDS). Store in accordance with
local/regional/national/international regulation.
8. Exposure controls/personal protection
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Material name: POLYFLOC" CE1167 Page: 2 / 7
Version number: 3.2
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles. Chemical goggles are recommended.
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into
account any solvents and other hazards present.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment. A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT
A RESPIRATOR'S USE.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
White to off-white
Emulsion
Slight hydrocarbon
Not available.
4.2 (0.5% SOL.)
< 23 °F (< -5 °C)
210 °F (99 °C)
> 200 °F (> 93 °C) P-M(CC)
Evaporation rate
< 1 (Ether = 1)
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
> 1 (Air = 1)
Relative density
1.04
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
1500 cps
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
< 28 °F (< -2 °C)
Material name: POLYFLOC* CE1167 Page: 3 / 7
Version number: 3.2
Specific gravity
1.044
VOC
35 % (Calculated)
10. Stability and reactivity
Reactivity
The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
Hazardous polymerization does not occur.
reactions
Conditions to avoid
Avoid temperatures exceeding the flash point. Contact with incompatible materials. None under
normal conditions.
Incompatible materials
Strong oxidizing agents. Contact with oxidizers may cause fire.
Hazardous decomposition
Oxides of carbon and nitrogen, hydrogen chloride, ammonia and volatile amines. Toxic gas.
products
Hydrogen chloride. Oxides of carbon and nitrogen, ammonia and volatile amines.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful. Mists/aerosols may cause irritation to upper respiratory
tract.
Skin contact Prolonged or repeated contact may cause irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Headache. Nausea, vomiting. Diarrhea. Exposure may cause temporary irritation, redness, or
physical, chemical and discomfort.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Product Species Test Results
POLYFLOC CE1167 (CAS Mixture)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg, (Estimated value)
Oral
LD50 Rat > 5000 mg/kg, (Estimated value)
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
Not available.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated
Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Material name: POLYFLOC" CE1167 Page: 4 / 7
Version number: 3.2
Aspiration hazard
Based on available data, the classification criteria are not met. Does not result in classification of
the mixture if the kinematic viscosity is greater than 20.5 mm2/sec measured at 40C.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product
Species Test Results
POLYFLOC CE1167 (CAS Mixture)
LC50 Fathead Minnow 2.2 mg/L, Static Renewal Bioassay, 96
hour
NOEL Fathead Minnow 1.3 mg/L, Static Renewal Bioassay, 96
hour
Aquatic
Crustacea
EC50 Daphnia magna > 50 mg/L, Acute Toxicity, 48 hour,
(Natural Water)
LC50 Daphnia magna 28 mg/L, Static Renewal Bioassay, 48
hour
NOEL Daphnia magna 3 mg/L, Static Renewal Bioassay, 48
hour
Fish
LC50 Fish > 10 mg/L, Acute Toxicity, 96 hour,
(Natural Water)
Rainbow Trout 0.9 mg/L, Static Acute Bioassay, 96 hour
NOEL Rainbow Trout 0.49 mg/L, Static Acute Bioassay, 96
hour
Bioaccumulative potential
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Environmental fate
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability
No data is available on the degradability of this product.
- COD (mg02/g)
1170
- BOD 5 (mg021g)
434
- BOD 28 (mg02/g)
434
- Closed Bottle Test (%
37
Degradation in 28 days)
- TOC (mg C/g)
490
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOIL for exact container
classification.
Material name: POLYFLOC" CE1167 Page: 5 / 7
Version number: 3.2
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations All components are on the U.S. EPA TSCA Inventory List.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 3111312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Clean Water Act (CWA) Hazardous substance
Section 112(r) (40 CFR
68.130)
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
US state regulations
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
Material name: POLYFLOC" CE1167 Page: 6 / 7
Version number: 3.2
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
US - Massachusetts RTK - Substance List
Not regulated.
US - Pennsylvania RTK - Hazardous Substances
Not regulated.
US - Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
16. Other information, including date of preparation or last revision
Issue date
Jul-31-2015
Revision date
Jan-22-2018
Version #
3.2
List of abbreviations
CAS: Chemical Abstract Service Registration Number
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists
NOEL: No Observed Effect Level
STEL: Short Term Exposure Limit
LC50: Lethal Concentration, 50%
LD50: Lethal Dose, 50%
TWA: Time Weighted Average
BOD: Biochemical Oxygen Demand
COD: Chemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
References:
No data available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information
Hazard(s) identification: Hazard statement
Other information, including date of preparation or last revision: Disclaimer
GHS: Classification
Prepared by
This SDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: POLYFLOC" CE1167 Page: 7 / 7
Version number: 3.2
&AD s u e2
SAFETY DATA SHEET
NOVUS* CE2667
1. Identification
Product identifier NOVUS CE2667
Other means of identification None.
Recommended use Flocculant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Version: 4.0
Effective Date: Oct-24-2019
Previous Date: Apr-17-2019
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
OSHA defined hazards Not classified.
Label elements
1
•
Signal word Warning
Hazard statement Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause
drowsiness or dizziness.
Precautionary statement
Prevention Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a
well -ventilated area. Wear eye protection/face protection. Wear protective gloves.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin
irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
Page: 1 / 9
3. Composition/information on ingredients
Mixtures
Components
CAS # Percent
Distillates (petroleum), hydrotreated
light 64742-47-8 40 - 60
Ammonium chloride
12125-02-9 2.5 - 10
Poly(oxy-1,2-ethanediyl),alpha-tridecyl-omega-hydroxy- 24938-91-8 2.5 - 10
2-PROPENOIC ACID,2-ETHYLHEXYL ESTER, HOMOPOLYMER(PEHA) 9003-77-4 1 - 2.5
Composition comments
Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact
Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Get medical attention if
symptoms occur.
Most important
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye
symptoms/effects, acute and
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
delayed
cause respiratory irritation. Skin irritation. May cause redness and pain.
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).
Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from
During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted
6. Accidental release measures
Personal precautions,
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and
appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do
emergency procedures
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained.
Methods and materials for
Use water spray to reduce vapors or divert vapor cloud drift.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
Material name: NOVUS* CE2667
Page: 2 / 9
Version number: 4.0
7. Handling and storage
Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or
repeated contact with skin. Avoid prolonged exposure. Use only in well -ventilated areas. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices. Clean spill
immediately. Wash contaminated skin promptly.
Conditions for safe storage,
Store locked up. Keep away from heat and sources of ignition. Keep container tightly closed. Store
including any incompatibilities
away from oxidizers.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
Type Value Form
Ammonium chloride (CAS
TWA 5 mg/m3 Respirable fraction.
12125-02-9)
15 mg/m3 Total dust.
50 mppcf Total dust.
15 mppcf Respirable fraction.
US. ACGIH Threshold Limit
Values
Components
Type Value Form
Ammonium chloride (CAS
STEL 20 mg/m3 Fume.
12125-02-9)
TWA 10 mg/m3 Fume.
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type Value Form
Ammonium chloride (CAS
STEL 20 mg/m3 Fume.
12125-02-9)
TWA 10 mg/m3 Fume.
Distillates (petroleum),
TWA 100 mg/m3
hydrotreated light (CAS
64742-47-8)
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Eye wash facilities and emergency shower must be available when handling this product. Good
controls
general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.
Individual protection measures,
such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Glove selection must take into account any solvents and other hazards present.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
Always observe good personal hygiene measures, such as washing after handling the material
considerations
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
White to off-white
Physical state
Emulsion
Odor
Slight hydrocarbon
Odor threshold
Not available.
Material name: NOVUS* CE2667 Page: 3 / 9
Version number: 4.0
pH (concentrated product)
Not available.
pH in aqueous solution
5 (0.5% SOL.)
Melting point/freezing point
< 23 °F (< -5 °C)
Initial boiling point and boiling
Not available.
range
Flash point
> 200 °F (> 93 °C) P-M(CC)
Evaporation rate
< 1 (Ether = 1)
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
> 1 (Air = 1)
Relative density
1.03
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
1500 cps
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
< 28 °F (< -2 °C)
Specific gravity
1.034
VOC
30 % (Estimated)
10. Stability and reactivity
Reactivity
The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
Hazardous polymerization does not occur.
reactions
Conditions to avoid
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition
Oxides of carbon and nitrogen, ammonia and volatile amines. Oxides of sulfur.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. May cause drowsiness and dizziness. Headache.
Nausea, vomiting. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and
diarrhea.
Material name: NOVUS* CE2667 Page: 4 / 9
Version number: 4.0
Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye
physical, chemical and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Narcotic effects. May cause respiratory irritation.
Product Species Test Results
NOVUS CE2667 (CAS Mixture)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg, (Calculated according to
GHS additivity formula)
Inhalation
LC50
Rat
> 20 mg/I, 4 Hours, (Calculated according
to GHS additivity formula)
Oral
LD50
Rat
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Components
Species
Test Results
Ammonium chloride (CAS 12125-02-9)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg
Oral
LD50
Rat
1410 mg/kg
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg
Inhalation
LC50 Rat > 5.2 mg/I, 4 Hour
Oral
LD50 Rat > 5000 mg/kg
Poly(oxy-1,2-ethanediyl),alpha-tridecyl-omega-hydroxy- (CAS 24938-91-8)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat > 2000 mg/kg
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Material name: NOVUS* CE2667 Page: 5 / 9
Version number: 4.0
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause respiratory irritation. May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Species
NOVUS CE2667 (CAS Mixture)
Aquatic
Crustacea 35% Mortality Daphnia magna
LC50 Daphnia magna
Test Results
0.078 mg/L, Static Renewal Bioassay,
48 hour
0.14 mg/L, Static Renewal Bioassay, 48
hour
Fish LC50 Fathead Minnow 2.5 mg/L, Static Renewal Bioassay, 96
hour
NOEL Fathead Minnow 1.3 mg/L, Static Renewal Bioassay, 96
hour
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Distillates (petroleum), hydrotreated light
Bioconcentration factor (BCF)
Distillates (petroleum), hydrotreated light
Mobility in soil No data available.
Other adverse effects Not available.
Persistence and degradability
- COD (mg02/g) 1290
- BOD 5 (mg02/g) 29
- BOD 28 (mg02/g) 238
- Closed Bottle Test (% 18
Degradation in 28 days)
- Zahn-Wellens Test (% 25
Degradation in 28 days)
- TOC (mg C/g) 450
MOR
207.7
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
Material name: NOVUS* CE2667 Page: 6 / 9
Version number: 4.0
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOIL for exact container
classification.
IATA
UN number
UN3082
UN proper shipping name
Environmentally hazardous substance, liquid, n.o.s. (PETROLEUM DISTILLATES)
Transport hazard class(es)
Class
9M1
Subsidiary risk
-
Packing group
III
Environmental hazards
No.
ERG Code
171
Special precautions for user Not available.
IMDG
UN number
UN3082
UN proper shipping name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PETROLEUM
DISTILLATES)
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant No.
EmS F-A, S-F
Special precautions for user Not available.
IMDG
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ammonium chloride (CAS 12125-02-9) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Skin corrosion or irritation
categories Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Ammonium chloride 12125-02-9 2.5 - 10
Material name: NOVUS* CE2667 Page: 7 / 9
Version number: 4.0
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Inventory status
Country(s) or region
Canada
Not regulated.
Inventory name
Domestic Substances List (DSL)
On inventory (yes/no)*
Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
US state regulations
California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
NFPA ratings
NFPA ratings
Dec-05-2014
Oct-24-2019
4.0
Health: 2
Flammability: 0
Instability: 0
r
0,
O
LAM
List of abbreviations CAS: Chemical Abstract Service Registration Number
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists
NOEL: No Observed Effect Level
STEL: Short Term Exposure Limit
LC50: Lethal Concentration, 50%
LD50: Lethal Dose, 50%
TWA: Time Weighted Average
BOD: Biochemical Oxygen Demand
COD: Chemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
References: No data available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Material name: NOVUS* CE2667 Page: 8 / 9
Version number: 4.0
Revision information Product and Company Identification: Commercial Names
Regulatory information: California Proposition 65
Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: NOVUS* CE2667 Page: 9 / 9
Version number: 4.0
&AD s u e2
SAFETY DATA SHEET
NOVUS* CE2680
1. Identification
Product identifier NOVUS CE2680
Other means of identification None.
Recommended use Flocculant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Version: 4.0
Effective Date: Oct-11-2018
Previous Date: Mar-09-2018
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
OSHA defined hazards Not classified.
Label elements
1
•
Signal word Warning
Hazard statement Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause
drowsiness or dizziness.
Precautionary statement
Prevention Wear eye/face protection. Avoid breathing mist or vapor. Wash thoroughly after handling. Use
only outdoors or in a well -ventilated area. Wear protective gloves.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin
irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash before reuse.
Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
Page: 1 / 9
3. Composition/information on ingredients
Mixtures
Components
CAS # Percent
Distillates (petroleum), hydrotreated light 64742-47-8 20 - 40
ALCOHOLS,C11-C14-ISO,C13-RICH,ETHOXYLATED 78330-21-9 1 - 2.5
Composition comments
Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact
Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash
contaminated clothing before reuse.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Get medical attention if
symptoms occur.
Most important
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye
symptoms/effects, acute and
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
delayed
cause respiratory irritation. Skin irritation. May cause redness and pain.
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation
emergency procedures of vapors or mists. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained.
Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,
containment and cleaning up basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. Ventilate area, use specified protective
equipment.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
Material name: NOVUS* CE2680 Page: 2 / 9
Version number: 4.0
7. Handling and storage
Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes. Avoid contact with skin. Avoid prolonged or
repeated contact with skin. Avoid contact with clothing. Avoid prolonged exposure. Use only in
well -ventilated areas. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices. Use care in handling/storage.
Conditions for safe storage,
Store locked up. Keep away from heat and sources of ignition. Protect from freezing. Product
including any incompatibilities
forms unusable solids that can not be thawed, even at room temperature, if subjected to freezing
conditions. Store in original tightly closed container. Store in accordance with
local/regional/national/international regulation.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type Value
Distillates (petroleum),
PEL 400 mg/m3
hydrotreated light (CAS
64742-47-8)
100 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type Value
Distillates (petroleum),
TWA 100 mg/m3
hydrotreated light (CAS
64742-47-8)
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures,
such as personal protective equipment
Eye/face protection
Splash proof chemical goggles.
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Glove selection must take into account any solvents and other hazards present.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
Always observe good personal hygiene measures, such as washing after handling the material
considerations
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
White to off-white
Physical state
Emulsion
Odor
Slight hydrocarbon
Odor threshold
Not available.
pH in aqueous solution
4.8 (1% SOL.)
4.9 (0.5% SOL.)
Melting point/freezing point
< 23 °F (< -5 °C)
Initial boiling point and boiling
210 °F (99 °C)
range
Flash point
Evaporation rate
> 200 °F (> 93 °C) P-M(CC)
< 1 (Ether = 1)
Material name: NOVUS* CE2680
Version number: 4.0
Page: 3 / 9
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
> 1 (Air = 1)
Relative density
1.03
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
1300 cps
Viscosity temperature
70 °F (21 °C)
Other information
Pour point
< 28 °F (< -2 °C)
Specific gravity
1.034
VOC
25 % (Estimated)
10. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Protect from freezing. Avoid contact with strong oxidizers.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Oxides of carbon evolved in fire.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the
respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, mental confusion,
dizziness and lethargy.
Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye
physical, chemical and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Narcotic effects. May cause respiratory irritation.
Material name: NOVUS* CE2680 Page: 4 / 9
Version number: 4.0
Product
Species Test Results
NOWS CE2680 (CAS Mixture)
Acute
Dermal
LD50
Rabbit > 5000 mg/kg, (Calculated according to
GHS additivity formula)
Inhalation
LC50
Rat > 20 mg/I, 4 Hours, (Calculated according
to GHS additivity formula)
Oral
LD50
Rat > 5000 mg/kg, (Calculated according to
GHS additivity formula)
Components
Species Test Results
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Acute
Dermal
LD50
Rabbit > 2000 mg/kg
Inhalation
LC50
Rat > 5.2 mg/I, 4 Hour
Oral
LD50
Rat > 5000 mg/kg
Estimates for product may be
based on additional component data not shown.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
This product is not expected to cause respiratory sensitization.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated
Substances (29 CFR 1910.1001-1052)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
Narcotic effects. May cause respiratory irritation.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not met.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Species
NOWS CE2680 (CAS Mixture)
LC50
Test Results
Ceriodaphnia 0.09 mg/L, Static Renewal Bioassay, 48
hour
Fathead Minnow 5.1 mg/L, Static Renewal Bioassay, 96
hour
Material name: NOVUS* CE2680 Page: 5 / 9
Version number: 4.0
Product
Species
Test Results
NOEL
Ceriodaphnia
0.06 mg/L, Static Renewal Bioassay, 48
hour
Fathead Minnow
0.8 mg/L, Static Renewal Bioassay, 96
hour
Aquatic
Crustacea
LC50
Daphnia magna
2.4 mg/L, Static Renewal Bioassay, 48
hour
NOEL
Daphnia magna
0.39 mg/L, Static Renewal Bioassay, 48
hour
Fish
LC50
Rainbow Trout
1.1 mg/L, Static Renewal Bioassay, 96
hour
NOEL
Rainbow Trout
0.75 mg/L, Static Renewal Bioassay, 96
hour
Persistence and degradability Not available.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Distillates (petroleum), hydrotreated light 3-6
Bioconcentration factor (BCF)
Distillates (petroleum), hydrotreated light 207.7
Mobility in soil No data available.
Other adverse effects Not available.
Persistence and degradability
- COD (mg02/g) 850
- BOD 5 (mg021g) 122
- BOD 28 (mg02/g) 132
- Closed Bottle Test (% 16
Degradation in 28 days)
- Zahn-Wellens Test (% 44
Degradation in 28 days)
- TOC (mg C/g) 320
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions). Empty containers or liners may retain some product residues. This material
and its container must be disposed of in a safe manner.
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
UN number UN3082
UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (QUATERNARY AMMONIUM
POLYACRYLAMIDE)
Transport hazard class(es)
Class 9
Material name: NOVUS* CE2680 Page: 6 / 9
Version number: 4.0
Subsidiary risk -
Packing group III
Environmental hazards Yes
ERG Code 171
Special precautions for user Not available.
IMDG
UN number UN3082
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (QUATERNARY
AMMONIUM POLYACRYLAMIDE), MARINE POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS F-A, S-F
Special precautions for user Not available.
IATA; IMDG
Marine pollutant
General information
15. Regulatory information
US federal regulations
IMDG Regulated Marine Pollutant.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Material name: NOVUS* CE2680 Page: 7 / 9
Version number: 4.0
Classified hazard
categories
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Inventory status
Country(s) or region
Canada
Canada
Not regulated.
Inventory name
Domestic Substances List (DSL)
Non -Domestic Substances List (NDSL)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
Yes
No
Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration Generally recognized as safe (GRAS) for papermaking applications that may contact aqueous and
fatty food per 21 CFR 170.30.
US state regulations
US. California Proposition 65
This product can expose you to chemicals including Acrylamide, which is known to the State of California to cause cancer
and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Acrylamide (CAS 79-06-1) Listed: January 1, 1990
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Acrylamide (CAS 79-06-1) Listed: February 25, 2011
16. Other information, including date of preparation or last revision
Issue date
Nov-14-2014
Revision date
Oct-11-2018
Version #
4.0
List of abbreviations
CAS: Chemical Abstract Service Registration Number
ACGIH: American Conference of Governmental Industrial Hygienists
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
References:
No data available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Material name: NOVUS* CE2680 Page: 8 / 9
Version number: 4.0
Revision information Product and Company Identification: Commercial Names
Composition/information on ingredients: Composition comments
Physical & Chemical Properties: Multiple Properties
Toxicological Information: Toxicological Data
Transport Information: Material Transportation Information
Regulatory information: California Prop 65
Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
* Trademark of SUEZ. May be registered in one or more countries.
Material name: NOVUS* CE2680 Page: 9 / 9
Version number: 4.0
BRENNTAGM MATERIAL SAFETY DATA Page 1/ 8
SHEET Revision : 10/4/2018
Revision nr : 6
Supersedes : 25/8/2014
CITRIC ACID >=20% Code: 11454
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Chemical description Citric acid anhydrous , solution (>=20%).
Type of product Pure product in solution .
Reach registration number : 01-2119457026-42
1.2. Relevant identified uses of the substance or mixture and uses advised aaainst
Identified use(s) See table on the front page of the annex.
Use(s) advised against This product is not recommended for any industrial, professional or consumer use
other than identified in table on the front page of the annex.
1.3. Details of the supplier of the safety data sheet
Company identification BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK
TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11
E-MAIL: info@brenntag.be - Website: www.brenntag.be
BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT
TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919
E-MAIL: info@brenntag.nl - Website: www.brenntag.nl
1.4. Emergency telephone number
Emergency phone number Belgium : Antipoison Center - Brussels
TEL: +32(0)70/245.245
The Netherlands : National Poisoning Information Center - Bilthoven
TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in
cases of acute intoxications)
SECTION 2. Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye irritation - Category 2 - Warning (Eye Irrit. 2; H319)
2.2. Label elements
Label in accordance with Regulation (EC) No 1272/2008
• Dangerous ingredient(s) Citric acid anhydrous
• Hazard pictogram(s)
1
• Signal word Warning
• Hazard statements H319 - Causes serious eye irritation.
• Precautionary statements
- Prevention P264 - Wash skin thoroughly after handling. P280 - Wear protective gloves/
protective clothing/eye protection/face protection.
- Response P305+P351+P338 - IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 -
If eye irritation persists: Get medical advice/attention.
2.3. Other hazards
Physical/chemical hazards The substance decomposes by heating above the melting point in information of
methyl maleic anhydride.
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page : 2 / 8
Revision : 10/4/2018
Revision nr: 6
CITRIC ACID >=20%
Supersedes : 25/8/2014
Code: 11454
SECTION 2. Hazards identification (continued)
Hazards for the health No significant danger.
Hazards for the environment Product causes a strong drop of the pH -value of water and soil.
This product is no substance or contains no PBT or vPvB (in accordance with
Annex XIII).
Hazards for the safety No significant danger.
SECTION 3. Composition/information on ingredients
3.1. Substances
Name component(s) Weight % CAS nr EINECS nr Index nr Reach nr CLASSIFICATION
Citric acid anhydrous >= 20 % 77-92-9 201-069-1 ----- 01-2119457026-42 Eye Irrit. 2; H319
The full text of the (EU)H-statements is in section 16.
SECTION 4. First aid measures
4.1. Descriation of first aid measures
General
In case of doubt or persistent symptoms, call a physician.
Never give anything by mouth to an unconscious person.
First Aid Measures
- Inhalation
Remove victim into fresh air.
Allow the affected person to rest in semi -sitting position.
If not breathing, give artificial respiration.
Consult a doctor.
- Skin Contact
Remove contaminated clothing.
Rinse skin immediately with plenty of water. (shower if necessary).
Consult doctor if irritation develops.
- Eye Contact
Rinse immediately thoroughly and long (at least 15 min.) with plenty of water.
Remove contact lenses.
Consult eye doctor.
Do not use a neutralisation agent.
- Ingestion
DO NOT INDUCE VOMITING. Rinse mouth with water.
Give victim plenty of water to drink.
Consult a doctor.
4.2. Most important symptoms
and effects, both acute and delayed
See section 11.
4.3. Indication of anv
immediate medical attention and saecial treatment needed
For specialist advice doctors should contact the NVIC or the Belgian Poison center
SECTION 5. Firefighting measures
5.1. Extinguishing media
Extinguishing Media
- Suitable Extinguishing powder, Alcohol resistant foam , Carbon dioxide (CO2) , Water spray
- Insuitable Heavy water stream .
5.2. Special hazards arising from the substance or mixture
Special Exposure Hazards : Fire may liberate carbon oxides (CO) and smoke.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 3/ 8
SHEET Revision : 10/4/2018
Revision nr : 6
Supersedes : 25/8/2014
CITRIC ACID >=20% Code: 11454
SECTION 5. Firefighting measures (continued)
5.3. Advice for firefiahters
Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close
Firefighters proximity to fire.
Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter
environment.
SECTION 6. Accidental release measures
6.1. Personal arecautions. protective eauiament and emeraencv procedures
Personal Precautions
Evacuate all personnel immediately and ventilate area.
Avoid breathing vapour and contact with skin and eyes.
Wear recommended personal protective equipment. (See section 8)
6.2. Environmental precautions
Environmental Precautions
Shut off leaks if without risks.
Dike in the spilled product as much as possible with inert material.
Prevent entry of product in public water, sewers or soil.
Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for Cleaning Up
Collect the spillage in closable, suitable disposal containers.
Residue is to be washed down with plenty of water.
Neutralise rinse liquid with base.
6.4. Reference to other sections
For personal protection, see section 8.
For the removal of the waste product, see
section 13.
SECTION 7. Handling and storage
7.1. Precautions for safe handlin
Handling Avoid breathing vapour and contact with skin and eyes.
Wear recommended personal protective equipment. (See section 8)
When using, do not eat, drink or smoke.
Wash hands before and after working with the product.
Emergency eye wash fountains and showers should be available in the immediate
vicinity of any potential exposure.
7.2. Conditions for safe storage, including any incompatibilities
Storage Keep only in the original, safely locked container in a cool and well ventilated place.
All dangerous products should be placed on a drip tray or should be barreled.
Keep away from : Oxidizing agents , Bases , Metalnitrates .
Packaging Material Polyethylene , Polypropylene .
Insuitable Packaging Material Several metals .
7.3. Specific end use(s)
For identified uses, see subsection 1.2 and/or exposure scenarios.
SECTION 8. Exposure controls/personal protection
8.1. Control parameters
Occupational Exposure Limits Not established.
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page: 4/8
Revision : 10/4/2018
Revision nr : 6
CITRIC ACID >=20%
SECTION 8. Exposure controls/personal protection (continued)
Supersedes : 25/8/2014
Code: 11454
Biological limit values They will be included when available.
DNELs • Citric acid anhydrous
: Not applicable
PNECs • Citric acid anhydrous
: Fresh water: 0,44 mg/I
• Citric acid anhydrous
: Marine water: 0,044 mg/I
• Citric acid anhydrous
: Fresh water sediment : 3,46 mg/kg
• Citric acid anhydrous
: Marine water sediment : 34,6 mg/kg
• Citric acid anhydrous
: Soil : 33,1 mg/kg
• Citric acid anhydrous
: Sewage treatment plant : >1000 mg/I
8.2. Exaosure controls
Engineering Measures Ventilation , Local exhaust .
Personal Protection Equipment
- Respiratory protection No special respiratory protection equipment is recommended under normal
conditions of anticipated use with adequate ventilation.
- Skin protection Suitable protective clothing .
- Hand protection Suitable material for safety gloves (EN 374):
The suitability of the gloves and the breakthrough time for a specific workplace
should be discussed with the producers of the protective gloves.
- material : Butyl rubber
- thickness : 0, 11 mm
- breakthrough time : > 8 h
- Eye/Face protection Closed safety glasses or face shield.
Environmental exposure controls See sections 6, 7, 12 and 13.
SECTION 9. Physical and chemical properties
9.1. Information on basic ohvsical and chemical aroaerties
See technical data sheet for detailed information
Physical State (20°C)
Liquid .
Form/Colour
Clear, Colourless .
Odour
: Odourless .
Odour threshold
Not applicable.
pH value
Strong acid .
Melting/Freezing point
No data available.
Boiling Point/Range (1013 hPa)
No data available.
Flash point
Not applicable.
Fire hazard
Not applicable.
Evaporation rate
No data available.
Vapour pressure
No data available.
Relative vapour density (air=1)
No data available.
Density (20°C)
1,070 - 1,225 kg/I
Solubility in water
163 g/100ml
Soluble in
Alcohol .
Log P Octanol/Water (20°C)
-1,7
Auto -ignition temperature
No data available.
Minimum ignition energy
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page : 5 / 8
Revision : 10/4/2018
Revision nr : 6
CITRIC ACID >=20%
SECTION 9. Physical and chemical properties (continued)
Explosive properties
Oxidizing properties
Supersedes : 25/8/2014
Code: 11454
No chemical groups associated with explosive properties .
No chemical groups associated with oxidizing properties .
SECTION 10. Stability and reactivity
10.1. Reactivit
Reactivity Reacts violently with oxidizing agents and lyes.
10.2. Chemical stability
Stability Stable at normal circumstances .
10.3. Possibilitv of hazardous reactions
Hazardous reactions Reacts violently with: Metalnitrates => May cause fire and explosion!
10.4. Conditions to avoid
Conditions to avoid High temperatures .
10.5. Incompatible materials
Materials to avoid Oxidizing agents , Bases , Metalnitrates .
10.6. Hazardous decomposition products
Hazardous Decomposition Products : Carbon oxides .
SECTION 11. Toxicological information
11.1. Information on toxicological effects
Acute toxicity
* - Inhalation Symptoms include: Cough , Sore throat .
- Skin contact
- Ingestion
Skin corrosion/irritation
Serious eye damage/irritation
Aspiration hazard
Respiratory or skin sensitisation
Carcinogenicity
Mutagenicity
Reproductive toxicity
Specific target organ toxicity - single
exposure
Specific target organ toxicity - repeated
exposure
• Citric acid anhydrous : LC50 (Rat, inhalation, 4 h) : No data available.
Symptoms include: Redness, Pain .
• Citric acid anhydrous : LD50 (Rat, dermal) : >2000 mg/kg ( OECD Guideline 402)
Symptoms include: Sore throat , Abdominal pain , Vomiting .
• Citric acid anhydrous : LD50 (Mouse, oral) : 5400 mg/kg
• Citric acid anhydrous : LD50 (Rat, oral) : 5400 mg/kg ( OECD Guideline 401)
Slightly irritating .
Causes serious eye irritation.
Not considered hazardous.
Not sensitive .
Not listed as carcinogenic.
Not listed as mutagenic .
Not listed for reproductive toxicity .
To human : Listed not for organ toxicity .
For animals : No effects known.
To human : Listed not for organ toxicity .
For animals : No effects known.
SECTION 12. Ecological information
12.1. Toxicity
Ecotoxicity • Citric acid anhydrous : LC50 (Fish, 96 h) : >400 mg/I (Leusiscus idus)
• Citric acid anhydrous : LC50 (Daphnia magna, 24 h) : 1535 mg/I
• Citric acid anhydrous : LOEC (Algae, 8 d) : 425 mg/I
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page : 6 / 8
Revision : 10/4/2018
Revision nr : 6
CITRIC ACID >=20%
SECTION 12. Ecological information (continued)
12.2. Persistence and dearadabilit
Supersedes : 25/8/2014
Code: 11454
Persistence and degradability • Citric acid anhydrous : Persistence and degradability : Readily biodegradable .
12.3. Bioaccumulative potential
Bioaccumulation • Citric acid anhydrous : Bioaccumulation : Bioaccumulation not expected .
12.4. Mobility in soil
Mobility • Citric acid anhydrous : Mobility : Highly soluble in water.
12.5. Results of PBT and vPvB assessment
Evaluation : • Citric acid anhydrous : PBT/vPvB : No
12.6. Other adverse effects
Photochemical ozone creation potential
No data available.
Ozone depletion potential
No data available.
Endocrine disrupting potential
No data available.
Global warming potential
No data available.
SECTION 13. Disposal considerations
13.1. Waste treatment methods
Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a
company specialised in handling hazardous waste products.
European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the
most current applications and can not be representative for pollutions which are
arisen at the effective use of the product. The producer of the waste has to
evaluate its process himself and has to grant the appropriate waste coding. See
Decision 2001/118/EC.
Removal contaminated packaging Packing is to be used exclusively for the packing of this product.
After use, empty and close the packing very carefully.
In case of returned packing, the empty packing can be offered back to the supplier.
SECTION 14. Transport information
14.1. UN number
UN Number
14.2. UN proper shipping name
ADR/RID Name
ADN Name
IMDG Name
* IATA Name
14.3. Transport hazard classe(s)
Class
14.4. Packing group
Packaging Group
14.5. Environmental hazards
Environmentally hazard
Marine pollutant
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 7/ 8
SHEET Revision : 10/4/2018
Revision nr : 6
Supersedes : 25/8/2014
CITRIC ACID >=20% Code: 11454
SECTION 14. Transport information (continued)
14.6. Snecial arecautions for user
Danger number
Hazard Label(s)
EmS-N°
14.7. Transaort in bulk accordina
Type ship
Pollution category
to Annex II of MARPOL and the IBC Code
SECTION 15. Regulatory information
15.1. Safetv. health and environmental reaulations/leaislation saecific for the substance or mixture
Inventories European inventory (EINECS): Listed in inventory.
Relevant EU Rule(s) Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision
2000/532/EC as regards the list of wastes
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/
2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (Reach)
* National regulations
* - Germany WGK : 1
* - Netherlands Water damaging : B
Decontamination exertion : 5
15.2. Chemical Safety Assessment
A chemical safety assessment has been carried out for the material.
SECTION 16. Other information
* This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006 and the corresponding current
changes.
This safety data sheet is exclusively made for industrial/professional use.
* Has changed compared to previous revision.
* Changes Section 2 , Section 3 , Section 11 , Section 14 , Section 15 , Section 16 .
Sources of used key data The information contained herein is based on the present state of our knowledge
Producers of starting materials , Chemical cards , ...).
See also on the webaddress:
http://apps.echa.europa.eu/registered/registered-sub.aspx#search
* (EU)H-statement(s) H319 - Causes serious eye irritation.
* List of abbrevations and acronyms ADN (Accord europ6en relatif au transport international des marchandises
Dangereuses par voie de Navigation interieur) : European agreement concerning
the international carriage of dangerous goods by inland waterways
ADR (Accord europ6en relatif au transport international des marchandises
Dangereuses par Route) : European agreement concerning the international
carriage of dangerous goods by road
CO: Carbon monoxide
DNEL (Derived No Effect Level) : an estimated safe exposure level
EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and
the second code refers to the relevant spillage schedule
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 8/ 8
SHEET Revision : 10/4/2018
Revision nr : 6
Supersedes : 25/8/2014
CITRIC ACID >=20% Code: 11454
SECTION 16. Other information (continued)
Eye Irrit. 2 : Eye irritation - Category 2
IATA (International Air Transport Association) : provisions concerning the
international carriage of dangerous goods by air
IMDG (International Maritime Dangerous Goods code)
LC50 : median Lethal Concentration
LD50 : median Lethal Dose
LOEC (Lowest Observed Effect Concentration)
NVIC : National Poisoning Information Center
OECD : Organisation for Economic Cooperation and Development
PBT : persistent, bioaccumulative and toxic
PNEC (Predicted No Effect Concentration) : concentration below which exposure to
a substance is not expected to cause adverse effects
REACH : Registration, Evaluation, Authorisation and restriction of Chemicals
RID (Reglement concernant le transport International ferroviaire des marchandises
Dangereuses) : Regulation concerning the International carriage of Dangerous
goods by rail
WGK (Wassergefahrdungsklasse) : a German classification of substances that
indicate the environmental hazard for surface water
vPvB : very persistent and very bioaccumulative
This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only
concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in
case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is
suitable and complete concerning the special use he makes of the product.
BRENNTAG denies all responsibility for loss or damage resulting from the use of these data.
End of document
BRENNTAG
Version: 1.0
Effective Date: Jan-26-2015
Previous Date: Jan-26-2015
GE Power & Water
Water & Process Technologies
SAFETY DATA SHEET
KLARAID* IC1173
1. Identification
Product identifier KLARAID IC1173
Other means of identification None.
Recommended use Coagulant
Recommended restrictions None known.
Company/undertaking identification
GE Betz, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards Corrosive to metals Category 1
Health hazards Serious eye damage/eye irritation Category 1
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
OSHA defined hazards Not classified.
Label elements
u
, -g•
Signal word Danger
Hazard statement May be corrosive to metals. Causes serious eye damage. May cause respiratory irritation.
Precautionary statement
Prevention
Keep only in original container. Avoid breathing mist or vapor. Use only outdoors or in a well -ventilated
area. Wear eye/face protection.
Response
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor/. Absorb spillage to prevent material damage.
Storage
Store in a well -ventilated place. Keep container tightly closed. Store locked up. Store in corrosive
resistant/ container with a resistant inner liner.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise classified
None known.
IHNOC)
Supplemental information
None.
3. Composition/information on ingredients
Mixtures
Page: 1 / 8
Chemical name Common name and synonyms CAS number %
Aluminum chloride, basic 1327-41-9 20 - 40
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION
STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards
of this formulation.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Dilute
contents of stomach using 2-8 fluid ounces (60-240ml) of milk or water. Rinse mouth. Get medical
attention if symptoms occur.
Most important
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
symptoms/effects, acute and
Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation.
delayed
Indication of immediate medical
Provide general supportive measures and treat symptomatically. Keep victim under observation.
attention and special treatment
Symptoms may be delayed.
needed
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel
are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Do not use waterjet as an extinguisher, as this will spread the fire.
Specific hazards arising from the
During fire, gases hazardous to health may be formed.
chemical
Special protective equipment and
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand
precautions for firefighters
breathing apparatus, protective clothing and face mask.
Fire fighting
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider
equipment/instructions
the hazards of other involved materials. Cool containers / tanks with water spray.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
6. Accidental release measures
Personal precautions, protective
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low
equipment and emergency
areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
procedures
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot
be contained. For personal protection, see section 8 of the SDS.
Methods and materials for
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up
possible. Absorb spillage to prevent material damage. Use a non-combustible material like vermiculite,
sand or earth to soak up the product and place into a container for later disposal. Prevent entry into
waterways, sewer, basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove
residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Water contaminated with this product
may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in
accordance with any local agreements.
7. Handling and storage
Precautions for safe handling Do not get this material in contact with eyes. Avoid breathing mist or vapor. Avoid prolonged exposure.
Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices.
Material name: KLARAID* IC1173 Page: 2 / 8
Version number: 1.0
Conditions for safe storage, Store in corrosive resistant container with a resistant inner liner. Store away from incompatible materials
including any incompatibilities (see Section 10 of the SDS). Store between 4 - 38 °C Store locked up. Store in a cool, dry place out of
direct sunlight. Keep only in the original container.
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value Form
Aluminum chloride, basic TWA 1 mg/m3 Respirable fraction.
(CAS 1327-41-9)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Aluminum chloride, basic TWA 2 mg/m3
(CAS 1327-41-9)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be
matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits
have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend
on its material but also on other quality features and is different from one producer to the other. Glove
selection must take into account any solvents and other hazards present.
Other Wear suitable protective clothing.
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED
WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and
before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants.
9. Physical and chemical properties
Appearance
Color
Colorless to yellow
Physical state
Liquid
Odor
Slight
Odor threshold
Not available.
pH (concentrated product)
1.3
pH in aqueous solution
4 (0.5% SOL.)
Melting point/freezing point
< -40 °F (< -40 °C)
Initial boiling point and boiling
212 °F (100 °C)
range
Flash point
> 200 °F (> 93 °C) P-M(CC)
Evaporation rate
< 1(Ether = 1)
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive
limits
Flammability limit - lower (%)
Not available.
Flammability limit - upper
Not available.
1%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Material name: KLARAID* IC1173 Page: 3 / 8
Version number: 1.0
Vapor pressure temp.
Vapor density
Relative density
Relative density temperature
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
Viscosity temperature
Other information
Percent volatile
Pour point
Specific gravity
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
70 °F (21 °C)
< 1 (Air = 1)
1.27
70 °F (21 °C)
100 %
Not available.
Not available.
Not available.
20 cps
70 °F (21 °C)
0 (Calculated)
< -40 °F (< -40 °C)
1.27
May be corrosive to metals. May react violently with alkaline materials.
Material is stable under normal conditions.
Hazardous polymerization does not occur.
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
May react with bases or strong oxidizers.
Hydrogen chloride.
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Prolonged or repeated contact may cause irritation.
Eye contact
Ingestion
Symptoms related to the physical,
chemical and toxicological
characteristics
Information on toxicological effects
Acute toxicity
Product
Causes serious eye damage.
May cause gastrointestinal irritation.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation.
May cause respiratory irritation.
Species
Test Results
KLARAID IC1173 (CAS Mixture)
Acute
Dermal
LD50 Rabbit
> 5000 mg/kg, (Calculated according to GHS
additivity formula)
Inhalation
LC50 Rat
> 5 mg/I, 4 Hours, (Calculated according to
GHS additivity formula)
Oral
LD50 Rat
> 5000 mg/kg, (Calculated according to GHS
additivity formula)
Material name: KLARAID* IC1173 Page: 4 / 8
Version number: 1.0
Components Species Test Results
Aluminum chloride, basic (CAS 1327-41-9)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye irritation Causes serious eye damage.
Respiratory or skin sensitization
> 2000 mg/kg
> 5 mg/I, 4 Hour
> 2000 mg/kg
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or
genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause respiratory irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met. May be harmful if swallowed and enters
airways.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Species Test Results
KLARAID IC1173 (CAS Mixture)
0% Mortality Fathead Minnow 1000 mg/L, Static Bioassay with 48-Hour
Renewal, 96 hour, (pH adjusted)
100% Mortality Fathead Minnow 5000 mg/L, Static Bioassay with 48-Hour
Renewal, 96 hour, (pH adjusted)
Aquatic
Crustacea
0% Mortality Daphnia magna 5000 mg/L, Static Acute Bioassay, 48 hour,
(pH adjusted)
* Estimates for product may be based on additional component data not shown.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential,
endocrine disruption, global warming potential) are expected from this component.
Environmental fate The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability
No data is available on the degradability of this product.
Material name: KLARAID* IC1173 Page: 5 / 8
Version number: 1.0
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D002: Waste Corrosive material [pH <=2 or=>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste disposal
company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some product
products residues. This material and its container must be disposed of in a safe manner (see: Disposal
instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since
emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number UN3264
UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE)
Transport hazard class(es)
Class 8
Subsidiary risk -
Packing group III
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
ERG number 154
Some containers may be DOT exempt, please check BOL for exact container classification.
IATA
UN number
UN3264
UN proper shipping name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE)
Transport hazard class(es)
Class
8
Subsidiary risk
-
Packing group
III
Environmental hazards
No.
ERG Code
154
Special precautions for user
Read safety instructions, SIDS and emergency procedures before handling.
IMDG
UN number
UN3264
UN proper shipping name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE)
Transport hazard class(es)
Class
8
Subsidiary risk
-
Packing group
III
Environmental hazards
Marine pollutant
No.
Ems
Not available.
Special precautions for user
Read safety instructions, SIDS and emergency procedures before handling.
DOT
Material name: KLARAID* IC1173 Page: 6 / 8
Version number: 1.0
IATA; IMDG
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
TSCA Section 121b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List 140 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 ITRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants MAN List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
countrylsl.
Food and drug administration Generally recognized as safe (GRAS) for papermaking applications that may contact aqueous and fatty
food per 21 CFR 170.30.
US state regulations
US - Massachusetts RTK - Substance List
Not regulated.
US - Pennsylvania RTK - Hazardous Substances
Aluminum chloride, basic (CAS 1327-41-9)
Material name: KLARAID* IC1173 Page: 7 / 8
Version number: 1.0
US - Rhode Island RTK
Not regulated.
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right -to -Know Act
Not listed.
US. Pennsylvania Worker and Community Right -to -Know Law
Aluminum chloride, basic (CAS 1327-41-9)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
16.Other information, including date of preparation or last revision
Issue date
Jan-26-2015
Revision date
Jan-26-2015
Version #
1.0
List of abbreviations
CAS: Chemical Abstract Service Registration Number
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists
NOEL: No Observed Effect Level
STEL: Short Term Exposure Limit
LC50: Lethal Concentration, 50%
TWA: Time Weighted Average
BOD: Biochemical Oxygen Demand
COD: Chemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
TLV: Threshold Limit Value
LD50: Lethal Dose, 50%
NFPA: National Fire Protection Association
References:
No data available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.
Revision Information
Product and Company Identification: Physical States
Toxicological Information: Toxicological Data
Transport Information: Experimental Data
HazReg Data: North America
GHS: Classification
Prepared by
This SIDS has been prepared by GE Water & Process Technologies Regulatory Department
(1-215-355-3300).
* Trademark of General Electric Company. May be registered in one or more countries.
Material name: KLARAID* IC1173 Page: 8 / 8
Version number: 1.0
&AD s u e2
Version: 3.1
Effective Date: Dec-17-2017
Previous Date: Feb-13-2017
SAFETY DATA SHEET
KLARAI D* I C 1183
1. Identification
Product identifier KLARAID IC1183
Other means of identification None.
Recommended use Coagulant
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not classified.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority requirements.
None known.
None.
3. Composition/information on ingredients
Mixtures
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
4. First -aid measures
Inhalation If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Page: 1 / 7
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth with water. Do not induce vomiting. Call a physician immediately.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure
and precautions for firefighters demand breathing apparatus, protective clothing and face mask.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
Keep unnecessary personnel away. For personal protection, see section 8 of the SIDS.
protective equipment and
emergency procedures
Methods and materials for
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a
permitted waste treatment facility, in accordance with any local agreements.
7. Handling and storage
Precautions for safe handling
Avoid prolonged exposure. Use care in handling/storage.
Conditions for safe storage,
Store in original tightly closed container. Keep containers closed when not in use. Store away from
including any incompatibilities
incompatible materials (see Section 10 of the SDS). Do not freeze. If frozen, thaw completely and
mix thoroughly prior to use. Store away from oxidizers. Store in cool, well ventilated area.
8. Exposure controls/personal protection
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Good general ventilation (typically 10
air changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.
Individual protection measures,
such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Material name: KLARAID* IC1183 Page: 2 / 7
Version number: 3.1
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into
account any solvents and other hazards present.
Other
Wear suitable protective clothing.
Respiratory protection
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH (concentrated product)
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Colorless to yellow
Liquid
Mild
Not available.
1.8
3.5 (5% SOL.)
< -30 °F (< -34 °C)
212 °F (100 °C)
> 200 °F (> 93 °C) P-M(CC)
< 1 (Ether = 1)
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mm Hg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
< 1 (Air = 1)
Relative density
1.32
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
100 %
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
35 cps
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
< -30 °F (< -34 °C)
Material name: KLARAID* IC1183 Page: 3 / 7
Version number: 3.1
Specific gravity 1.315
VOC 0 % (Calculated)
10. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
Incompatible materials Avoid contact with strong oxidizers. Avoid contact with strong bases.
Hazardous decomposition No hazardous decomposition products are known.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact
Prolonged or repeated contact may cause irritation.
Eye contact
Direct contact with eyes may cause temporary irritation.
Ingestion
Expected to be a low ingestion hazard.
Symptoms related to the
Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Product
Species
Test Results
KLARAID IC1183 (CAS Mixture)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg, (Calculated according to
GHS additivity formula)
Inhalation
LC50
Rat
> 5 mg/I, 4 Hours, (Calculated according to
GHS additivity formula)
Oral
LD50
Rat
> 2000 mg/kg, (Calculated according to
GHS additivity formula)
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Material name: KLARAID* IC1183 Page: 4 / 7
Version number: 3.1
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
12. Ecological information
Ecotoxicity
Product
Not classified.
Not classified.
Based on available data, the classification criteria are not met.
Prolonged inhalation may be harmful.
Species
KLARAID IC1183 (CAS Mixture)
0% Mortality Fathead Minnow
Aquatic
Crustacea 0% Mortality Daphnia magna
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects Not available.
Persistence and degradability
13. Disposal considerations
Test Results
5000 mg/L, Static Acute Bioassay, 96
hour, (pH adjusted)
5000 mg/L, Static Acute Bioassay, 48
hour, (pH adjusted)
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations. Empty containers or liners may retain some
products
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container
classification.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Material name: KLARAID* IC1183 Page: 5 / 7
Version number: 3.1
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
US state regulations
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
US - Massachusetts RTK - Substance List
Not regulated.
US - Pennsylvania RTK - Hazardous Substances
Not regulated.
US - Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
16. Other information, including date of preparation or last revision
Issue date Jan-27-2015
Revision date Dec-17-2017
Version # 3.1
Material name: KLARAID* IC1183 Page: 6 / 7
Version number: 3.1
List of abbreviations
CAS: Chemical Abstract Service Registration Number
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists
NOEL: No Observed Effect Level
STEL: Short Term Exposure Limit
LC50: Lethal Concentration, 50%
LD50: Lethal Dose, 50%
TWA: Time Weighted Average
BOD: Biochemical Oxygen Demand
COD: Chemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
References:
No data available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information
Toxicological Information: Toxicological Data
Transport Information: Experimental Data
Other information, including date of preparation or last revision: Prepared by
Prepared by
This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: KLARAID* IC1183 Page: 7 / 7
Version number: 3.1
&AD s u e2
Version: 5.0
Effective Date: Sep-10-2018
Previous Date: Apr-16-2018
SAFETY DATA SHEET
KLARAI D* I C 1172
1. Identification
Product identifier KLARAID IC1172
Other means of identification None.
Recommended use Waste treatment additive.
Recommended restrictions None known.
Company/undertaking identification
SUEZ WTS USA, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355 3300, F 215 953 5524
Emergency telephone
(800) 877 1940
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not classified.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification. The material is not hazardous under the
criteria of the Federal OSHA Hazard Communication Standard's (29CFR 1910.1200)
implementation of the Globally Harmonized System (GHS), i.e., material is not a dangerous
substance or mixture requiring GHS classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority requirements.
None known.
None.
3. Composition/information on ingredients
Mixtures
Components
CAS # Percent
Aluminium chlorhydroxide 12042-91-0 40 - 60
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD
COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our
assessment of the potential hazards of this formulation.
Page: 1 / 7
4. First -aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
5. Fire -fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Move to fresh air.
Remove contaminated clothing immediately and wash skin with soap and water. Wash
contaminated clothing before reuse.
Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention
immediately.
Rinse mouth. Do not induce vomiting. Do not feed anything by mouth to an unconscious or
convulsive victim.
Direct contact with eyes may cause temporary irritation.
Treat symptomatically.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Cool containers / tanks with water spray.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, For personal protection, see section 8 of the SDS.
protective equipment and
emergency procedures
Methods and materials for Large Spills: Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or
containment and cleaning up earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a
permitted waste treatment facility, in accordance with any local agreements.
7. Handling and storage
Precautions for safe handling Observe good industrial hygiene practices.
Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10
including any incompatibilities of the SDS). Do not freeze. If frozen, thaw completely and mix thoroughly prior to use.
8. Exposure controls/personal protection
Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. ACGIH Threshold Limit Values
Components Type Value Form
Aluminium chlorhydroxide TWA 1 mg/m3 Respirable fraction.
(CAS 12042-91-0)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Aluminium chlorhydroxide TWA 2 mg/m3
(CAS 12042-91-0)
Biological limit values No biological exposure limits noted for the ingredient(s).
Material name: KLARAID" IC1172 Page: 2 / 7
Version number: 5.0
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles. Face shield is recommended. Wear safety glasses with side
shields (or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only
depend on its material but also on other quality features and is different from one producer to the
other. Glove selection must take into account any solvents and other hazards present.
Other Wear appropriate chemical resistant clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. A RESPIRATORY PROTECTION
PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST
BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Physical state
Odor
Odor threshold
pH (concentrated product)
pH in aqueous solution
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Colorless to light yellow
Liquid
Mild
Not available.
3.7 Neat
4.5 (5% Solution)
19 °F (-7 °C)
219 °F (104 °C)
Not applicable.
Evaporation rate
Slower than Ether
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
18 mmHg
Vapor pressure temp.
70 °F (21 °C)
Vapor density
< 1
Relative density
1.34
Relative density temperature
70 °F (21 °C)
Solubility(ies)
Solubility (water)
100 %
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
45 mPa.s
Material name: KLARAID* IC1172 Page: 3 / 7
Version number: 5.0
Viscosity temperature
70 °F (21 °C)
Other information
Explosive properties
Not explosive.
Oxidizing properties
Not oxidizing.
Pour point
24 °F (4 °C)
Specific gravity
1.339
VOC
0 % CALCULATED
10. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Hydrogen chloride.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Prolonged or repeated contact may cause irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Product Species Test Results
KLARAID IC1172 (CAS Mixture)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Components Species
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
> 5000 mg/kg, (Calculated according to
GHS additivity formula)
Test Results
Aluminium chlorhydroxide (CAS 12042-91-0)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat > 2000 mg/kg
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Material name: KLARAID* IC1172 Page: 4 / 7
Version number: 5.0
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met.
12. Ecological information
Ecotoxicity
Product
Species
Test Results
KLARAID IC1172 (CAS Mixture)
LC50
Ceriodaphnia
750 mg/L, Static Renewal Bioassay, 48
hour, (pH adjusted)
Fathead Minnow
517 mg/L, Static Acute Bioassay, 96
hour
LOEL
Ceriodaphnia
3.1 mg/L, Chronic Bioassay, 7 day
Fathead Minnow
10 mg/L, Chronic Bioassay, 7 day
NOEL
Ceriodaphnia
156 mg/L, Static Renewal Bioassay, 48
hour, (pH adjusted)
1.5 mg/L, Chronic Bioassay, 7 day
Fathead Minnow
370 mg/L, Static Acute Bioassay, 96
hour
5 mg/L, Chronic Bioassay, 7 day
Aquatic
Crustacea
0% Mortality
Daphnia magna
2500 mg/L, Static Screen, 48 hour, (pH
adjusted)
20% Mortality
Daphnia magna
5000 mg/L, Static Screen, 48 hour, (pH
adjusted)
Fish
LC50
Rainbow Trout
390 mg/L, Static Acute Bioassay, 96
hour
NOEL
Rainbow Trout
210 mg/L, Static Acute Bioassay, 96
hour
Bioaccumulative potential
No data available.
Mobility in soil
No data available.
Other adverse effects
Not available.
Persistence and degradability
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Empty containers or liners may retain some product residues. This material and its container must
products be disposed of in a safe manner.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Material name: KLARAID* IC1172 Page: 5 / 7
Version number: 5.0
14. Transport information
DOT
Not regulated as dangerous goods.
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container
classification.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
US state regulations
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
No ingredient listed.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
No ingredient listed.
Material name: KLARAID* IC1172 Page: 6 / 7
Version number: 5.0
US - Massachusetts RTK - Substance List
Not regulated.
US - Pennsylvania RTK - Hazardous Substances
Aluminium chlorhydroxide (CAS 12042-91-0) Listed.
US - Rhode Island RTK
Not regulated.
US. Pennsylvania Worker and Community Right -to -Know Law
Aluminium chlorhydroxide (CAS 12042-91-0) Hazardous substance
US. California Proposition 65
Not Listed.
16. Other information, including date of preparation or last revision
Issue date Oct-29-2014
Revision date Sep-10-2018
Version # 5.0
List of abbreviations CAS: Chemical Abstract Service Registration Number
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
ACGIH: American Conference of Governmental Industrial Hygienists
TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
References: No data available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information Hazard(s) identification: Hazard statement
Hazard(s) identification: Prevention
Hazard(s) identification: Response
Composition / Information on Ingredients: Disclosure Overrides
Composition/information on ingredients: Composition comments
First -aid measures: Indication of immediate medical attention and special treatment needed
First -aid measures: Most important symptoms/effects, acute and delayed
Exposure controls/personal protection: Occupational exposure limits
Regulatory information: California Prop 65
Regulatory information: US federal regulations
GHS: Classification
Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300).
Trademark of SUEZ. May be registered in one or more countries.
Material name: KLARAID* IC1172 Page: 7 / 7
Version number: 5.0
BRENNTAGM MATERIAL SAFETY DATA Page 1/ 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Chemical description
Sodium hydroxide , Caustic soda , solution (5-51
Type of product
Mixture.
Reach registration number
: 01-2119457892-27
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified use(s)
See table on the front page of the annex.
Use(s) advised against
This product is not recommended for any industrial, professional or consumer use
other than identified in table on the front page of the annex.
Not for use in ornamental articles, in tricks and jokes and in games (in accordance
with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or
mixtures, which are fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes
2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2,
2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7
adverse effects on sexual function and fertility or on development, 3.8 effects other
than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1).
1.3. Details of the supplier
of the safety data sheet
Company identification
BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK
TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11
E-MAIL: info@brenntag.be - Website: www.brenntag.be
BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT
TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919
E-MAIL: info@brenntag.nl - Website: www.brenntag.nl
1.4. Emergency telephone number
Emergency phone number
Belgium : Antipoison Center - Brussels
TEL: +32(0)70/245.245
The Netherlands : National Poisoning Information Center - Bilthoven
TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in
cases of acute intoxications)
SECTION 2. Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Corrosive to metals - Category 1 - Warning (Met. Corr. 1; H290)
Skin corrosion - Category 1A - Danger (Skin Corr. 1A; H314)
Serious eye damage - Category 1 - Danger (Eye Dam. 1; H318)
2.2. Label elements
Label in accordance with Regulation (EC) No 1272/2008
• Dangerous ingredient(s)
• Hazard pictogram(s)
• Signal word
• Hazard statements
BRENNTAG
Sodium hydroxide
4Q>
Danger
H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye
damage.
BRENNTAGM MATERIAL SAFETY DATA Page 2/ 10
SHEET Revision : 14/3/2019
Revision nr: 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 2. Hazards identification (continued)
• Precautionary statements
- Prevention
P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective
gloves/protective clothing/eye protection/face protection.
- Response
P303+P361+P353+P310 - IF ON SKIN (or hair): Remove immediately all
contaminated clothing. Rinse skin with water/shower. Immediately call a POISON
CENTER/doctor/... P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or doctor.
- Disposal considerations
P501 - Dispose of this material and its container to hazardous or special waste
collection point.
2.3. Other hazards
Physical/chemical hazards
Product reacts violently and explosive when contact with organic substances,
reducing substances, metals and when contamination with dust (exotherm
reaction).
Hazards for the health
A health dangerous concentration in the air will not or very slowly be reached by
evaporation of this substance at app. 20°C; by spraying much faster.
Hazards for the environment
Product causes a strong rise of the pH -value of water and soil.
This product is no substance or contains no PBT or vPvB (in accordance with
Annex XIII).
Hazards for the safety
Risk of explosion by many reactions.
SECTION 3. Composition/information on ingredients
3.2. Mixtures
Name component(s) Weight % CAS nr EINECS nr Index nr Reach nr CLASSIFICATION
Sodium hydroxide 5 -51 % 1310-73-2 215-185-5 011-002-00-6 01-2119457892-27 Met. Corr. 1; H290
Skin Corr. 1A; H314
Potassium hydroxide 0.5 < 1 % 1310-58-3 215-181-3 019-002-00-8 01-2119487136-33 Met. Corr. 1; H290
Acute Tox. 4 (oral); H302
Skin Corr. 1A; H314
The full text of the (EU)H-statements is in section 16.
Note: SCL applicable
SECTION 4. First aid measures
4.1. Description of first aid measures
General In case of doubt or persistent symptoms, call a physician.
Never give anything by mouth to an unconscious person.
First Aid Measures
- Inhalation Remove victim into fresh air.
Allow the affected person to rest in semi -sitting position.
If not breathing, give artificial respiration.
Seek medical attention immediately.
- Skin Contact Remove contaminated clothing and shoes while rinsing.
Rinse skin immediately with mild soap and plenty of water. ( at least 20') (shower if
necessary).
Immediately call a POISON CENTER or doctor/physician.
- Eye Contact Rinse immediately thoroughly and long (at least 15 min.) with plenty of water.
Remove contact lenses after a few minutes rinse.
Immediately call a POISON CENTER or doctor/physician.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 3/ 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 4. First aid measures (continued)
Keep rinsing or dripping the eye during transport.
- Ingestion DO NOT INDUCE VOMITING. Rinse mouth.
Give victim plenty of water to drink.
Take the patient IMMEDIATELY to the hospital.
4.2. Most important symptoms and effects, both acute and delayed
See section 11.
4.3. Indication of anv immediate medical attention and special treatment needed
For specialist advice doctors should contact the NVIC or the Belgian Poison center
SECTION 5. Firefighting measures
5.1. Extinguishing media
Extinguishing Media
* - Suitable Extinguishing powder, Foam , Carbon dioxide (CO2) , Water spray .
- Insuitable Heavy water stream .
5.2. Special hazards arising from the substance or mixture
Special Exposure Hazards : Fire may liberate toxic and stinging vapours.
5.3. Advice for firefiahters
Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close
Firefighters proximity to fire.
Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter
environment.
SECTION 6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal Precautions Evacuate all personnel immediately and ventilate area.
Avoid breathing vapour and contact with skin, eyes and clothing. Wear
recommended personal protective equipment. (See section 8)
6.2. Environmental precautions
Environmental Precautions Shut off leaks if without risks.
Dike in the spilled product as much as possible with inert material.
Prevent entry of product in public water, sewers or soil.
Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for Cleaning Up Collect the spillage in closable, corrosion resistant, suitable disposal containers.
Dilute spilled liquid immediately with plenty of water - neutralise with acid.
Rinse abundantly with water.
6.4. Reference to other sections
For personal protection, see section 8.
For the removal of the waste product, see section 13.
SECTION 7. Handling and storage
7.1. Precautions for safe handling
Handling AVOID FOG TRANSFORMATION! AVOID EVERY CONTACT!!
Avoid breathing vapour and contact with skin, eyes and clothing. Wear
recommended personal protective equipment. (See section 8)
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page: 4 / 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 7. Handling and storage (continued)
When diluting: add the basic solution in water, never the other way around.
When dissolving or diluting the product in water, heat and mist may develop.
When using, do not eat, drink or smoke.
Emergency eye wash fountains and showers should be available in the immediate
vicinity of any potential exposure.
7.2. Conditions for safe storaae. includina anv incompatibilities
Storage Keep only in the original, safely locked container in a cool and well ventilated place.
All dangerous products should be placed on a drip tray or should be barreled.
Keep away from : Oxidizing agents , Acids .
Packaging Material Stainless steel , Nickel , Polyethylene , Polypropylene , PVC.
Insuitable Packaging Material Several metals ( Aluminium , Magnesium , Copper, Zinc (+ Alloys)), Polyester.
7.3. Specific end use(s)
For identified uses, see subsection 1.2 and/or exposure scenarios.
SECTION 8. Exposure controls/personal protection
8.1. Control aarameters
Occupational Exposure Limits
For harmful components :
Sodium hydroxide: Limit value (BE) : 2 mg/m3 (2014) (M)
Potassium hydroxide : Short time value (BE) : 2 mg/m' (2014) (M)
Potassium hydroxide: ACGIH (TWA 8h) : 2 mg/m3
(M) The mention "M" means that the exposition above the limit value causes
irritation or that there is a danger for acute poisoning. The work procedure has to
be designed somehow or other that the exposition doesn't exceed the limit value.
During a control, the sample period should be so short as possible to carry out a
reliable measurement. The mesure result is then related to the considered period.
Biological limit values
They will be included when available.
DNELs
For harmful components :
• Sodium hydroxide : Worker, long-term - local effects, inhalation : 1,0 mg/mz
• Sodium hydroxide : Consumer, long-term - local effects, inhalation : 1,0 mg/m3
• Potassium hydroxide : Worker, long-term - local effects, inhalation : 1 mg/m3
PNECs
For harmful components :
• Sodium hydroxide : Not applicable
• Potassium hydroxide : Not applicable
8.2. Exposure controls
Engineering Measures
Ventilation , Local exhaust .
Personal Protection Equipment
- Respiratory protection
CE-approved gas respirator ( Filter type B/P2).
- Skin protection
Corrosion -proof protective clothing.
- Hand protection
Suitable material for safety gloves (EN 374):
The suitability of the gloves and the breakthrough time for a specific workplace
should be discussed with the producers of the protective gloves.
- material : Nitril rubber
- thickness : 0,35 mm
- breakthrough time : > 480'
- Eye/Face protection
Closed safety glasses or face shield.
Environmental exposure controls
See sections 6, 7, 12 and 13.
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page :5/10
Revision : 14/3/2019
Revision nr : 9
SODIUM HYDROXIDE 5-51%
SECTION 9. Physical and chemical properties
9.1. Information on basic nhvsical and chemical orooerties
See technical data sheet for detailed information
Physical State (20°C)
Liquid .
Form/Colour
Clear, Colourless .
Odour
Odourless .
Odour threshold
Not applicable.
pH value
: > 14
Melting/Freezing point
-17 °C (10%)
12 °C (50%)
Boiling Point/Range (1013 hPa)
111 - 145 °C (25-50%)
Flash point
Not applicable.
Fire hazard
Not applicable.
Evaporation rate
No data available.
Explosion limits in air
Not applicable.
Vapour pressure (20°C)
: 0,1 -1,4 kPa (10-50%)
Relative vapour density (air=1)
No data available.
Relative density of saturated vapour/air
No data available.
mixture (air=1)
Relative density (water=1)
Density (20°C)
Solubility in water
Soluble in
Log P Octanol/Water (20°C)
Auto -ignition temperature
Minimum ignition energy
Decomposition temperature
Viscosity (20°C)
Explosive properties
Oxidizing properties
Supersedes : 16/1/2017
Code : 16124
1,3-1,5 (25-50%)
1,0538 - 1,525 kg/I (5-50%)
Complete solubility .
Ethanol , Methanol , Glycerol .
Inorganic
Not applicable.
Not applicable.
No data available.
12 - 120 mPa.s (29-51 %)
No chemical groups associated with explosive properties .
No chemical groups associated with oxidizing properties .
SECTION 10. Stability and reactivity
10.1. Reactivit
Reactivity Reacts violently with: Halogenated hydrocarbons , Ammonium salts , Acids , Water
Corrosive to metals.
10.2. Chemical stability
Stability Stable at normal circumstances .
10.3. Possibility of hazardous reactions
Hazardous reactions Exothermic reaction with: Water, Acids .
Contact with metallic substances may release inflammable hydrogen gas.
Reacts with Ammonium salts -> Creation of: Ammonia.
Can react with sugar residues to form Carbon monoxide.
10.4. Conditions to avoid
Conditions to avoid : Contact with water.
10.5. Incompatible materials
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 6/ 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 10. Stability and reactivity (continued)
Materials to avoid Halogenated hydrocarbons, Ammonium salts , Acids, Aluminium , Magnesium ,
Copper, Zinc, Wool , Lether, , Polyester.
10.6. Hazardous decomposition products
Hazardous Decomposition Products : Ammonia , Hydrogen .
SECTION 11. Toxicological information
11.1. Information on toxicoloaical effects
Acute toxicity
Inhalation
Symptoms include: Sore throat , Cough , Shortness of breath .
For harmful components :
• Sodium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available.
• Potassium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available.
Skin contact
Symptoms include: Redness , Pain , Severe burns .
For harmful components :
• Sodium hydroxide : LD50 (Rabbit, dermal) : No data available.
• Potassium hydroxide : LD50 (Rabbit, dermal) : No data available.
Ingestion
Symptoms include: Sore throat , Abdominal cramps , Vomiting , Diarrhea .
For harmful components :
• Sodium hydroxide : LD50 (Rat, oral) : No data available.
• Potassium hydroxide : LD50 (Rat, oral) : 333 mg/kg ( OECD Guideline 425)
Skin corrosion/irritation
Causes severe burns.
Skin contact can damage eczema.
Serious eye damage/irritation
Causes serious eye damage.
May cause diminished visual capacity to complete blindness.
Aspiration hazard
Symptoms of lungoedema mostly reveal after a few hours, intensified by physical
effort.
The product may affect the upper and lower airways, causing infections and
impaired lung function.
Respiratory or skin sensitisation
Not sensitive .
Carcinogenicity
Not listed as carcinogenic .
Mutagenicity
Not listed as mutagenic .
Reproductive toxicity
Not listed for reproductive toxicity .
Specific target organ toxicity - single
To human : Listed not for organ toxicity .
exposure
Specific target organ toxicity - repeated
To human : Listed not for organ toxicity .
exposure
For animals : No effects known.
SECTION 12. Ecological information
12.1. Toxicity
Ecotoxicity For harmful components
• Sodium hydroxide: LC50 (Fish, 96 h) : 35-189 mg/I
• Sodium hydroxide : EC50 (Algae, 72 h) : No data available.
• Sodium hydroxide: EC50 (Daphnia magna, 48 h) : 40,4 mg/I (Ceriodaphnia sp.)
• Potassium hydroxide: LC50 (Fish, 96 h) : 80 mg/I (Gambusia affinis) (TLm (_
median tolerance limit) )
• Potassium hydroxide : EC50 (Algae, 72 h) : No data available.
• Potassium hydroxide : EC50 (Daphnia magna, 48 h) : No data available.
12.2. Persistence and dearadability
BRENNTAG
BRENNTAGM
MATERIAL SAFETY DATA
SHEET
Page :7/10
Revision : 14/3/2019
Revision nr : 9
SODIUM HYDROXIDE 5-51%
SECTION 12. Ecological information (continued)
Supersedes : 16/1/2017
Code : 16124
Persistence and degradability For harmful components :
• Sodium hydroxide : Persistence and degradability : Inorganic .
• Potassium hydroxide : Persistence and degradability : Inorganic.
12.3. Bioaccumulative potential
Bioaccumulation For harmful components
• Sodium hydroxide : Bioaccumulation : Bioaccumulation not expected .
• Potassium hydroxide : Bioaccumulation : Not applicable.
12.4. Mobility in soil
Mobility For harmful components
• Sodium hydroxide : Mobility : High potential for mobility in soil.
• Potassium hydroxide : Mobility: No data available.
12.5. Results of PBT and vPvB assessment
Evaluation For harmful components
• Sodium hydroxide: PBT/vPvB : No
• Potassium hydroxide : PBT/vPvB : No
12.6. Other adverse effects
Photochemical ozone creation potential No data available .
Ozone depletion potential None .
Endocrine disrupting potential No data available .
Global warming potential No data available .
SECTION 13. Disposal considerations
13.1. Waste treatment methods
Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a
company specialised in handling hazardous waste products.
European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the
most current applications and can not be representative for pollutions which are
arisen at the effective use of the product. The producer of the waste has to
evaluate its process himself and has to grant the appropriate waste coding. See
Decision 2001/118/EC.
Removal contaminated packaging Packing is to be used exclusively for the packing of this product.
After use, empty and close the packing very carefully.
In case of returned packing, the empty packing can be offered back to the supplier.
SECTION 14. Transport information
14.1. UN number
UN Number
14.2. UN aroaer shiaaina name
1824
ADR/RID Name UN 1824 Sodium hydroxide solution, 8, II, (E)
ADN Name UN 1824 Sodium hydroxide solution , 8, II
IMDG Name UN 1824 Sodium hydroxide, solution , 8, II
IATA Name UN 1824 Sodium hydroxide, solution , 8, II
14.3. Transport hazard classelsl
Class : 8
14.4. Packing group
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 8/ 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 14. Transport information (continued)
Packaging Group
14.5. Environmental hazards
Environmentally hazard No
Marine pollutant No
14.6. Special precautions for user
Danger number 80
Hazard Label(s) 8
EmS-N° F-A S-B
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Type ship
Pollution category
No data available.
No data available.
SECTION 15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Inventories Australian inventory (AICS): Listed in inventory.
Canadian inventory (DSL): Listed in inventory.
Chinese inventory (IECS): Listed in inventory.
European inventory (EINECS): Listed in inventory.
Korean inventory (KECI): Listed in inventory.
Philippine inventory (PICCS): Listed in inventory.
Inventory of the United States (TSCA): Listed in inventory.
NFPA n° : 3-0-1
Relevant EU Rule(s)
Directive 98/24/EC of the Council of 7 April 1998 on the protection of the health and
safety of workers from the risks related to chemical agents at work
Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision
2000/532/EC as regards the list of wastes
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/
2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (Reach)
The restrictions in Annex
XVII to Regulation (EC) No 1907/2006 must be observed.
National regulations
- Germany
WGK : 1
- Netherlands
Water damaging : C
Decontamination exertion : 2
15.2. Chemical Safety
Assessment
A chemical safety assessment has been carried out for the material.
SECTION 16. Other information
This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006.
This safety data sheet is exclusively made for industrial/professional use.
* Has changed compared to previous revision.
BRENNTAG
BRENNTAGM MATERIAL SAFETY DATA Page 9/ 10
SHEET Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
SODIUM HYDROXIDE 5-51%
Code : 16124
SECTION 16. Other information
(continued)
* Changes
Section 5 .
Sources of used key data
The information contained herein is based on the present state of our knowledge
Producer(s) ) Chemical cards , ...)
See also on the webaddress:
http://apps.echa.europa.eu/registered/registered-sub.aspx#search
(EU)H-statement(s)
H290 - May be corrosive to metals.
H314 - Causes severe skin burns and eye damage.
Classification procedure
Met. Corr. 1; H290 - Based on test data (producer of component)
Skin Corr. 1A; H314 - Additivity method
Eye Dam. 1; H318 - Additivity method
List of abbrevations and acronyms
ACGIH : American Conference of Governmental Industrial Hygienists
Acute Tox. 4, oral : Acute toxicity, oral - Category 4
ADN (Accord europeen relatif au transport international des marchandises
Dangereuses par voie de Navigation interieur) : European agreement concerning
the international carriage of dangerous goods by inland waterways
ADR (Accord europeen relatif au transport international des marchandises
Dangereuses par Route) : European agreement concerning the international
carriage of dangerous goods by road
DNEL (Derived No Effect Level) : an estimated safe exposure level
EC50 : median Effective Concentration
EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and
the second code refers to the relevant spillage schedule
Eye Dam. 1 : Serious eye damage - Category 1
IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association) : provisions concerning the
international carriage of dangerous goods by air
IMDG (International Maritime Dangerous Goods code)
LC50 : median Lethal Concentration
LD50 : median Lethal Dose
MR (Molar Ratio)
Met. Corr. 1 : Corrosive to metals - Category 1
NFPA (National Fire Protection Association) or fire diamant
NOEC (No Observed Effect Concentration)
NVIC : National Poisoning Information Center
OECD : Organisation for Economic Cooperation and Development
PBT : persistent, bioaccumulative and toxic
PNEC (Predicted No Effect Concentration) : concentration below which exposure to
a substance is not expected to cause adverse effects
REACH : Registration, Evaluation, Authorisation and restriction of Chemicals
RID (Reglement concernant le transport International ferroviaire des marchandises
Dangereuses) : Regulation concerning the International carriage of Dangerous
goods by rail
SCL (Specific Concentration Limits)
Skin Corr. 1A : Skin corrosion - Category 1A
TLm : median tolerance limit
TWA (Time -Weighted Average) : the average exposure over a specified period
WGK (Wassergefahrdungsklasse) : a German classification of substances that
indicate the environmental hazard for surface water
vPvB : very persistent and very bioaccumulative
This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only
concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in
case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is
suitable and complete concerning the special use he makes of the product.
BRENNTAG denies all responsibility for loss or damage resulting from the use of these data.
BRENNTAG
8 R E N N TAG � MATERIAL SAFETY DATA
SHEET
SODIUM HYDROXIDE 5-51%
BRENNTAG
Page: 10/10
Revision : 14/3/2019
Revision nr : 9
Supersedes : 16/1/2017
Code : 16124
End of document