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HomeMy WebLinkAboutNC0089915_Material Safety Data Sheet_20190430BRENNTAGM MATERIAL SAFETY DATA Page 1/ 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical description Sodium hypochlorite , Chlorine bleache lye , Javel water, solution (5<20% Cl active Type of product Pure product in solution . Reach registration number : 01-2119488154-34 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified use(s) See table on the front page of the annex. Use(s) advised against This product is not recommended for any industrial, professional or consumer use other than identified in table on the front page of the annex. Not for use in ornamental articles, in tricks and jokes and in games (in accordance with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or mixtures, which are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1). 1.3. Details of the supplier of the safety data sheet Company identification BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11 E-MAIL: info@brenntag.be - Website: www.brenntag.be BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919 E-MAIL: info@brenntag.nl - Website: www.brenntag.nl 1.4. Emergency telephone number Emergency phone number Belgium : Antipoison Center - Brussels TEL: +32(0)70/245.245 The Netherlands : National Poisoning Information Center - Bilthoven TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in cases of acute intoxications) SECTION 2. Hazards identification 2.1. Classification of the substance or mixture Classification accordina to Reaulation IECI No 1272/2008 Corrosive to metals - Category 1 - Warning (Met. Corr. 1; H290) Skin corrosion - Category 1 B - Danger (Skin Corr. 1 B; H314) Serious eye damage - Category 1 - Danger (Eye Dam. 1; H318) Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (Aquatic Acute 1; H400) Hazardous to the aquatic environment - Chronic hazard - Category 2 (Aquatic Chronic 2; H411) 2.2. Label elements Label in accordance with Reaulation (EC) No 1272/2008 • Dangerous ingredient(s) Sodium hypochlorite, solution ...% Cl active • Hazard pictogram(s) <C> BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page : 2 / 10 Revision : 30/1/2019 Revision nr: 11 SODIUM HYPOCHLORITE 5<20% Supersedes : 16/11/2015 Code : 16188 SECTION 2. Hazards identification (continued) • Signal word Danger • Hazard statements H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage. H410 - Very toxic to aquatic life with long lasting effects. EUH031 - Contact with acids liberates toxic gas. • Precautionary statements - Prevention P260 - Do not breathe fume/gas/mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. * - Response P303+P361+P353+P310 - IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor/... P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. P390 - Absorb spillage to prevent material damage. 2.3. Other hazards Physical/chemical hazards The substance decomposes by heating and under influence of sunlight in formation of toxic and corrosive vapours and in formation of oxygen that promotes fire. Hazards for the health A health dangerous concentration in the air will rahter slowly be reached by evaporation of this substance at app. 20°C; by spraying much faster. Hazards for the environment Product causes a strong rise of the pH -value of water and soil. This product is no substance or contains no PBT or vPvB (in accordance with Annex XIII). Hazards for the safety Incombustible product, but stimulates fire of other materials. SECTION 3. Composition/information on ingredients 3.1. Substances Name component(s) Weight % CAS nr EINECS nr Index nr Reach nr CLASSIFICATION Sodium hypochlorite, solution : 5 < 20 % Cl act. 7681-52-9 231-668-3 017-011-00-1 01-2119488154-34 Met. Corr. 1; H290 % Cl active Skin Corr. 1 B; H314 STOT SE 3; H335 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 EUH031 Sodium carbonate anhydrous 1 < 3 % 497-19-8 207-838-8 011-005-00-2 01-2119485498-19 Eye Irrit. 2; H319 Sodium hydroxide 0.5 < 1 % 1310-73-2 215-185-5 011-002-00-6 01-2119457892-27 Met. Corr. 1; H290 Skin Corr. 1A; H314 Sodium hypochlorite : Note B (Regulation (EC) No 1272/2008) applies to the product or one or more of its components. Note: M-factor=10 ( Acute ); Note: M-factor=1 ( Chronic ) Note: SCL applicable Sodium hydroxide : Note: SCL applicable The full text of the (EU)H-statements is in section 16. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 3/ 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 4. First aid measures 4.1. Descriation of first aid measures General CALL A PHYSICIAN IN ALL CIRCUMSTANCES. Never give anything by mouth to an unconscious person. First Aid Measures - Inhalation Remove victim into fresh air. Allow the affected person to rest in semi -sitting position. If not breathing, give artificial respiration. Seek medical attention IMMEDIATELY. - Skin Contact Remove contaminated clothing and shoes while rinsing. Rinse skin immediately with plenty of water. (shower if necessary). Immediately call a POISON CENTER or doctor/physician. - Eye Contact Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses. Keep rinsing or dripping the eye during transport. Immediately call a POISON CENTER or doctor/physician. - Ingestion DO NOT INDUCE VOMITING. Rinse mouth with water. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed See section 11. 4.3. Indication of anv immediate medical attention and saecial treatment needed For specialist advice doctors should contact the NVIC or the Belgian Poison center SECTION 5. Firefighting measures 5.1. Extinauishina media Extinguishing Media Suitable In case of nearby fire, use preferably water spray. Insuitable Not known . 5.2. Special hazards arising from the substance or mixture Special Exposure Hazards Contact with acids liberates toxic gas. ( E.g. Chlorine gas ) 5.3. Advice for firefighters Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close Firefighters proximity to fire. Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter environment. SECTION 6. Accidental release measures 6.1. Personal Drecautions. Drotective eauioment and emeraencv Drocedures Personal Precautions Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) 6.2. Environmental precautions Environmental Precautions Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil. Notify authorities if product enters sewers or public waters. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page: 4 / 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 6. Accidental release measures (continued) 6.3. Methods and material for containment and cleaning up Methods for Cleaning Up Collect the spillage in closable, corrosion resistant, suitable disposal containers. Clean up any spills as soon as possible, using an inert absorbent material. Residue is to be washed down with plenty of water. 6.4. Reference to other sections For personal protection, see section 8. For the removal of the waste product, see section 13. SECTION 7. Handling and storage 7.1. Precautions for safe handlin Handling AVOID FOG TRANSFORMATION! STRONG HYGIENE! Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) Avoid splashing and formation of vapour when emptying or diluting the product. When diluting: add the basic solution in water, never the other way around. When using, do not eat, drink or smoke. Emergency eye wash fountains and showers should be available in the immediate vicinity of any potential exposure. 7.2. Conditions for safe storaae. includina anv incomaatibilities Storage Keep only in the original, safely locked container in a well ventilated, cool and dark place. All dangerous products should be placed on a drip tray or should be barreled. Keep away from : Combustibles , Reducing materials , Acids . Packaging Material PVC , Polyethylene , Polyester, Steel covered with Ebonite . Insuitable Packaging Material Metals . 7.3. Specific end use(s) For identified uses, see subsection 1.2 and/or exposure scenarios. SECTION 8. Exposure controls/personal protection 8.1. Control aarameters Occupational Exposure Limits Sodium hypochlorite, solution ...% Cl active: Short time value (BE) : 0,5 ppm (1,5 mg/m') (2014) (Chlorine) Sodium hydroxide: Limit value (BE) : 2 mg/m3 (2014) (M) (M) The mention "M" means that the exposition above the limit value causes irritation or that there is a danger for acute poisoning. The work procedure has to be designed somehow or other that the exposition doesn't exceed the limit value. During a control, the sample period should be so short as possible to carry out a reliable measurement. The mesure result is then related to the considered period. Biological limit values DNELs BRENNTAG They will be included when available. • Sodium hypochlorite, solution inhalation : 3,1 mg/m3 • Sodium hypochlorite, solution inhalation : 3,1 mg/m3 • Sodium hypochlorite, solution inhalation : 1,55 mg/m3 • Sodium hypochlorite, solution inhalation : 1,55 mg/m3 • Sodium hypochlorite, solution inhalation : 1,55 mg/m3 • Sodium hypochlorite, solution Cl• active : Worker, acute - local effects, Cl• active : Worker, acute - systemic effects, Cl• active : Worker, long-term - local effects, Cl• active : Worker, long-term - systemic effects, Cl• active : Consumer, long-term - local effects, Cl• active : Consumer, long-term - systemic BRENNTAGM MATERIAL SAFETY DATA SHEET Page :5/10 Revision : 30/1/2019 Revision nr : 11 SODIUM HYPOCHLORITE 5<20% SECTION 8. Exposure controls/personal protection (continued) Supersedes : 16/11/2015 Code : 16188 effects, inhalation : 1,55 mg/m3 • Sodium hypochlorite, solution ...% Cl active : Consumer, long-term - systemic effects, oral : 0,26 mg/kg • Sodium carbonate anhydrous : Worker, long-term - local effects, inhalation : 10 mg/m' • Sodium carbonate anhydrous : Consumer, acute - local effects, inhalation : 10 mg/m' • Sodium hydroxide : Worker, long-term - local effects, inhalation : 1,0 mg/m2 • Sodium hydroxide : Consumer, long-term - local effects, inhalation : 1,0 mg/m3 PNECs • Sodium hypochlorite, solution ...% Cl active: Fresh water: 0,21 mg/I • Sodium hypochlorite, solution ...% Cl active: Marine water: 0,042 mg/I • Sodium hypochlorite, solution ...% Cl active: Fresh water sediment : Not expected • Sodium hypochlorite, solution ...% Cl active : Marine water sediment: Not expected . • Sodium hypochlorite, solution ...% Cl active : Soil : Not expected . • Sodium hypochlorite, solution ...% Cl active : Sewage treatment plant : 0,03 mg/I • Sodium carbonate anhydrous : Not applicable • Sodium hydroxide : Not applicable 8.2. Exposure controls Engineering Measures Ventilation , Local exhaust ( If possible through the floor ). Personal Protection Equipment Respiratory protection CE-approved mask for inorganic vapours (type B, grey). * Skin protection Chemical resistant clothing and boots (EN 14605) . Hand protection Suitable material for safety gloves (EN 374): The suitability of the gloves and the breakthrough time for a specific workplace should be discussed with the producers of the protective gloves. - material : Nitril rubber - thickness : 0,5 mm - penetration time : > 8 h Eye/Face protection Closed safety glasses or face shield. Environmental exposure controls See sections 6, 7, 12 and 13. SECTION 9. Physical and chemical properties 9.1. Information on basic ohvsical and chemical orooerties See technical data sheet for detailed information Physical State (20°C) Liquid . Form/Colour Clear, Yellow -green. Odour Weak chlorine odour. . Odour threshold No data available. pH value : > 12,5 . * Melting/Freezing point -20 °C ( solution 12% Cl active ) Boiling Point/Range (1013 hPa) Not applicable. ( Decomposes ) Flash point Not applicable. Fire hazard Not applicable. Evaporation rate No data available. Explosion limits in air Not applicable. Vapour pressure (20°C) : 2,5 kPa Relative vapour density (air=1) No data available. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 6/ 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 9. Physical and chemical properties (continued) Relative density of saturated vapour/air mixture (air=1) Density (20oC) Solubility in water Log P Octanol/Water (20°C) Auto -ignition temperature Minimum ignition energy Decomposition temperature Viscosity (20°C) Explosive properties Oxidizing properties No data available. 1,22 kg/I Complete solubility . -3,42 Not applicable. Not applicable. 20 °C ( Decomposition in function of temperature and incidence of light ) 2,6 mPa.s ( Dynamic) No chemical groups associated with explosive properties . No chemical groups associated with oxidizing properties . SECTION 10. Stability and reactivity 10.1. Reactivit Reactivity The product is a strong oxidizer and reacts violently with combustibles and reducing agents. Reacts violently with acids . Corrosive to all metals. 10.2. Chemical stability Stability Stable at normal circumstances . 10.3. Possibility of hazardous reactions Hazardous reactions The substance decomposes by heating and under influence of sunlight in formation of toxic and corrosive vapours and in formation of oxygen that promotes fire. Contact with acids liberates toxic gas. 10.4. Conditions to avoid Conditions to avoid High temperatures , Light . 10.5. Incompatible materials Materials to avoid Combustibles , Reducing materials , Acids , Metals . 10.6. Hazardous decomposition products Hazardous Decomposition Products : Chlorine , Hydrogen chloride ( Gas ). SECTION 11. Toxicological information 11.1. Information on toxicological effects Acute toxicity - Inhalation Symptoms include: Sore throat , Cough , Difficulty in breathing . • Sodium hypochlorite, solution ...% Cl active : LC50 (Rat, inhalation, 1 h) : >10,5 mg/I ( Air; OECD Guideline 403) • Sodium carbonate anhydrous : LC50 (Rat, inhalation, 2 h) : 2,3 mg/I ( Aerosol; OECD Guideline 403) • Sodium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available. - Skin contact Symptoms include: Redness, Pain . • Sodium hypochlorite, solution ...% Cl active: LD50 (Rabbit, dermal) : >20000 mg/ kg ( OECD Guideline 402) • Sodium carbonate anhydrous : LD50 (Rabbit, dermal) : >2000 mg/kg • Sodium hydroxide : LD50 (Rabbit, dermal) : No data available. - Ingestion Symptoms include: Sore throat , Abdominal pain , Vomiting . • Sodium hypochlorite, solution ...% Cl active: LD50 (Rat, oral) : 8910 mg/kg OECD Guideline 401) • Sodium carbonate anhydrous : LD50 (Rat, oral) : 2800 mg/kg BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page :7/10 Revision : 30/1/2019 Revision nr : 11 SODIUM HYPOCHLORITE 5<20% SECTION 11. Toxicological information (continued) Skin corrosion/irritation Serious eye damage/irritation Aspiration hazard Respiratory or skin sensitisation Carcinogenicity Mutagenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Supersedes : 16/11/2015 Code : 16188 • Sodium hydroxide : LD50 (Rat, oral) : No data available. Causes severe burns. Causes serious eye damage. Inhalation can cause pneumonia and/or pulmonary oedema, but only after signs of corrosive effects on the mucous membranes of the eyes and/or the upper respiratory tract. Not sensitive . Not listed as carcinogenic . Not listed as mutagenic . Not listed for reproductive toxicity . To human : May cause respiratory irritation. To human : Listed not for organ toxicity . For animals : No effects known. SECTION 12. Ecological information 12.1. Toxicit Ecotoxicity • Sodium hypochlorite, solution ...% Cl active: LC50 (Fish, 96 h) : 0,062-0,095 mg/I (Oncorhynchus mykiss) • Sodium hypochlorite, solution ...% Cl active: EC50 (Daphnia magna, 48 h) : 0, 0141 mg/I ( OECD Guideline 202) • Sodium hypochlorite, solution ...% Cl active: NOEC (Algae, 7 d) : 0,0021 mg/I Fresh water) • Sodium carbonate anhydrous : LC50 (Fish, 96 h) : 300 mg/I (Lepomis macrochirus) • Sodium carbonate anhydrous : EC50 (Algae, 72 h) : No data available. • Sodium carbonate anhydrous : EC50 (Daphnia magna, 48 h) : 200-227 mg/I Ceriodaphnia dubia) • Sodium hydroxide: LC50 (Fish, 96 h) : 35-189 mg/I • Sodium hydroxide : EC50 (Algae, 72 h) : No data available. • Sodium hydroxide: EC50 (Daphnia magna, 48 h) : 40,4 mg/I (Ceriodaphnia sp.) 12.2. Persistence and degradability Persistence and degradability • Sodium hypochlorite, solution ...% Cl active : Persistence and degradability Inorganic . • Sodium carbonate anhydrous : Persistence and degradability : Inorganic . • Sodium hydroxide : Persistence and degradability : Inorganic . 12.3. Bioaccumulative potential Bioaccumulation • Sodium hypochlorite, solution ...% Cl active: Bioaccumulation : No bioaccumulation . • Sodium carbonate anhydrous : Bioaccumulation : No bioaccumulation . • Sodium hydroxide : Bioaccumulation : Bioaccumulation not expected . 12.4. Mobility in soil Mobility • Sodium hypochlorite, solution ...% Cl active : Mobility : Completely soluble in water . • Sodium carbonate anhydrous : Mobility : No absorption expected to the ground. • Sodium hydroxide : Mobility : High potential for mobility in soil. 12.5. Results of PBT and vPvB assessment Evaluation • Sodium hypochlorite, solution ...% Cl active: PBT/vPvB : No • Sodium carbonate anhydrous : PBT/vPvB : No • Sodium hydroxide: PBT/vPvB : No BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page :8/10 Revision : 30/1/2019 Revision nr : 11 SODIUM HYPOCHLORITE 5<20% SECTION 12. Ecological information (continued) 12.6. Other adverse effects Photochemical ozone creation potential No data available. Ozone depletion potential No data available. Endocrine disrupting potential No data available. Global warming potential No data available. SECTION 13. Disposal considerations Supersedes : 16/11/2015 Code : 16188 13.1. Waste treatment methods Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products. European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. See Decision 2001/118/EC. Removal contaminated packaging Packing is to be used exclusively for the packing of this product. After use, empty and close the packing very carefully. In case of returned packing, the empty packing can be offered back to the supplier. SECTION 14. Transport information 14.1. UN number UN Number 14.2. UN nroaer shiaaina name 1791 ADR/RID Name UN 1791 Hypochlorite solution, 8, II, (E) ADN Name UN 1791 Hypochlorite solution , 8, II IMDG Name UN 1791 Hypochlorite solution , 8, II, MARINE POLLUTANT IATA Name UN 1791 Hypochlorite solution, 8, II 14.3. Transport hazard classe(s) Class 14.4. Packing group Packaging Group 14.5. Environmental hazards Environmentally hazard Marine pollutant 14.6. Special precautions for user Danger number Hazard Label(s) EmS-N° 14.7. Transaort in bulk accordina Type ship Pollution category BRENNTAG 8 Yes Yes 80 8 F-A , S-B to Annex II of MARPOL and the IBC Code Not applicable. Not applicable. BRENNTAGM MATERIAL SAFETY DATA Page 9/ 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Inventories Australian inventory (AICS): Listed in inventory. Canadian inventory (DSL): Listed in inventory. European inventory (EINECS): Listed in inventory. Japanese inventory (ENCS): Listed in inventory. Korean inventory (KECI): Listed in inventory. Chinese inventory (IECS): Listed in inventory. Philippine inventory (PICCS): Listed in inventory. Inventory of the United States (TSCA): Listed in inventory. NFPA no : 2-0-2-OXY Relevant EU Rule(s) Directive 96/82/EC of the Council of 9 December 1996 on the control of major - accident hazards involving dangerous substances Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision 2000/532/EC as regards the list of wastes Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/ 2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (Reach) The restrictions in Annex XVII to Regulation (EC) No 1907/2006 must be observed. National regulations - Germany WGK : 2 - Netherlands Water damaging : 5 Decontamination exertion : B 15.2. Chemical Safety Assessment A chemical safety assessment has been carried out for the material. SECTION 16. Other information This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006. This safety data sheet is exclusively made for industrial/professional use. * Has changed compared to previous revision. * Changes Section 2 , Section 8 , Section 9 . Sources of used key data The information contained herein is based on the present state of our knowledge Producer(s) , Chemical cards , ...) See also on the webaddress: http://apps.echa.europa.eu/registered/registered-sub.aspx#search (EU)H-statement(s) H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H400 - Very toxic to aquatic life. H410 - Very toxic to aquatic life with long lasting effects. EUH031 - Contact with acids liberates toxic gas. Classification procedure Met. Corr. 1; H290 - Based on test data (producer of component) Skin Corr. 1 B; H314 - Additivity method Aquatic Acute 1; H400 - Calculation method Aquatic Chronic 2; H411 - Calculation method BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page: 10 / 10 SHEET Revision : 30/1 /2019 Revision nr : 11 Supersedes : 16/11/2015 SODIUM HYPOCHLORITE 5<20% Code: 16188 SECTION 16. Other information (continued) List of abbrevations and acronyms ADN (Accord europeen relatif au transport international des marchandises Dangereuses par voie de Navigation interieur) : European agreement concerning the international carriage of dangerous goods by inland waterways Aquatic Acute 1 : Hazardous to the aquatic environment - Acute hazard - Category 1 ADR (Accord europeen relatif au transport international des marchandises Dangereuses par Route) : European agreement concerning the international carriage of dangerous goods by road Aquatic Chronic 1 : Hazardous to the aquatic environment - Chronic hazard - Category 1 Aquatic Chronic 2 : Hazardous to the aquatic environment - Chronic hazard - Category 2 CO: Carbon monoxide DNEL (Derived No Effect Level) : an estimated safe exposure level EC50 : median Effective Concentration EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and the second code refers to the relevant spillage schedule IATA (International Air Transport Association) : provisions concerning the international carriage of dangerous goods by air IMDG (International Maritime Dangerous Goods code) LC50 : median Lethal Concentration LD50 : median Lethal Dose Met. Corr. 1 : Corrosive to metals - Category 1 M-Factor : a multiplying factor that is applied to the concentration of a substance classified as hazardous to the aquatic environment (Aquatic Acute 1; H400 or Aquatic Chronic 1; H410) and is used to derive by the summation method the classification of a mixture in which the substance is present NFPA (National Fire Protection Association) or fire diamant NOEC (No Observed Effect Concentration) NVIC : National Poisoning Information Center OECD : Organisation for Economic Cooperation and Development PVC : Polyvinyl chloride PBT : persistent, bioaccumulative and toxic PNEC (Predicted No Effect Concentration) : concentration below which exposure to a substance is not expected to cause adverse effects REACH : Registration, Evaluation, Authorisation and restriction of Chemicals RID (Reglement concernant le transport International ferroviaire des marchandises Dangereuses) : Regulation concerning the International carriage of Dangerous goods by rail SCL (Specific Concentration Limits) Skin Corr. 1 B : Skin corrosion - Category 1 B TWA (Time -Weighted Average) : the average exposure over a specified period WGK (Wassergefahrdungsklasse) : a German classification of substances that indicate the environmental hazard for surface water vPvB : very persistent and very bioaccumulative This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is suitable and complete concerning the special use he makes of the product. BRENNTAG denies all responsibility for loss or damage resulting from the use of these data. End of document BRENNTAG &AD s u e2 SAFETY DATA SHEET KLARAID* CDP1336 1. Identification Product identifier KLARAID CDP1336 Other means of identification None. Recommended use Coagulant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Version: 4.0 Effective Date: Jul-16-2019 Previous Date: Dec-17-2017 Physical hazards Not classified. Health hazards Serious eye damage/eye irritation Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation OSHA defined hazards Not classified. Label elements < > 1 • Signal word Warning Hazard statement Causes serious eye irritation. May cause respiratory irritation. Precautionary statement Prevention Wear eye/face protection. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well -ventilated area. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Page: 1 / 8 Components CAS # Percent Aluminium chlorhydroxide 12042-91-0 20 - 40 N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer 26062-79-3 1 - 2.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur. Most important Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause symptoms/effects, acute and respiratory irritation. delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation emergency procedures of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for Prevent entry into waterways, sewer, basements or confined areas. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. Ventilate area, use specified protective equipment. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in accordance with any local agreements. 7. Handling and storage Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Use care in handling/storage. Material name: KLARAID* CDP1336 Page: 2 / 8 Version number: 4.0 Conditions for safe storage, Store locked up. Store in original tightly closed container. Store in accordance with including any incompatibilities local/regional/national/international regulation. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Aluminium chlorhydroxide TWA 1 mg/m3 Respirable fraction. (CAS 12042-91-0) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Aluminium chlorhydroxide TWA 2 mg/m3 (CAS 12042-91-0) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Provide eyewash station. Good general ventilation should be used. Ventilation rates should be controls matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear suitable protective clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH (concentrated product) pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Colorless to yellow Liquid Mild Not available. 3.6 4.6 (0.5% SOL.) 29 °F (-2 °C) 212 °F (100 °C) > 200 °F (> 93 °C) P-M(CC) < 1 (Ether = 1) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Material name: KLARAID* CDP1336 Page: 3 / 8 Version number: 4.0 Vapor pressure temp. Vapor density Relative density Relative density temperature Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto -ignition temperature Decomposition temperature Viscosity Viscosity temperature Other information Pour point Specific gravity VOC 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 70 °F (21 °C) < 1 (Air = 1) 1.3 70 °F (21 °C) 100 % Not available. Not available. Not available. 73 cps 70 °F (21 °C) 34 °F (1 °C) 1.305 0 % (Estimated) The product is stable and non -reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. Hydrogen chloride gas (HCI). Oxides of carbon and nitrogen evolved in fire. 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Causes serious eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause physical, chemical and respiratory irritation. Skin irritation. toxicological characteristics Information on toxicological effects Acute toxicity May cause respiratory irritation. Product Species Test Results KLARAID CDP1336 (CAS Mixture) Acute Dermal LD50 Rabbit > 5000 mg/kg, (Calculated according to GHS additivity formula) Oral LD50 Rat > 5000 mg/kg, (Calculated according to GHS additivity formula) Components Species Test Results Aluminium chlorhydroxide (CAS 12042-91-0) Acute Dermal LD50 Rabbit > 2000 mg/kg Material name: KLARAID* CDP1336 Page: 4 / 8 Version number: 4.0 Components Species Test Results Oral LD50 Rat > 2000 mg/kg N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer (CAS 26062-79-3) Acute Oral LD50 Rat 3000 mg/kg Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH Carcinogens Aluminium chlorhydroxide (CAS 12042-91-0) A4 Not classifiable as a human carcinogen. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - May cause respiratory irritation. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product Species Test Results KLARAID CDP1336 (CAS Mixture) Aquatic Crustacea LC50 Daphnia magna 8 mg/L, Static Renewal Bioassay, 48 hour NOEL Daphnia magna 3.2 mg/L, Static Renewal Bioassay, 48 hour Fish LC50 Fathead Minnow 16 mg/L, Static Renewal Bioassay, 96 hour Rainbow Trout 4.2 mg/L, Static Renewal Bioassay, 96 hour NOEL Fathead Minnow 6.2 mg/L, Static Renewal Bioassay, 96 hour Rainbow Trout 1.9 mg/L, Static Renewal Bioassay, 96 hour Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects Not available. Material name: KLARAID* CDP1336 Page: 5 / 8 Version number: 4.0 Persistence and degradability 1-5% 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. IATA UN number UN3082 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (CATIONIC POLYAMINE) Transport hazard class(es) Class 9M1 Subsidiary risk - Packing group III Environmental hazards Yes ERG Code 171 Special precautions for user Not available. IMDG UN number UN3082 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CATIONIC POLYAMINE), MARINE POLLUTANT Transport hazard class(es) Class 9 Subsidiary risk - Packing group III Environmental hazards Marine pollutant Yes EmS F-A, S-F Special precautions for user Not available. IMDG Marine pollutant Material name: KLARAID* CDP1336 Page: 6 / 8 Version number: 4.0 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Classified hazard Serious eye damage or eye irritation categories Specific target organ toxicity (single or repeated exposure) SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) US state regulations US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. 16. Other information, including date of preparation or last revision Issue date Oct-31-2014 Revision date Jul-16-2019 Version # 4.0 NFPA ratings Health: 2 Flammability: 0 Instability: 0 Material name: KLARAID* CDP1336 Page: 7 / 8 Version number: 4.0 NFPA ratings i 0 List of abbreviations CAS: Chemical Abstract Service Registration Number ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. NFPA: National Fire Protection Association References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Composition/information on ingredients: Composition comments Handling and storage: Conditions for safe storage, including any incompatibilities Stability and reactivity: Hazardous decomposition products Transport Information: Material Transportation Information Regulatory information: California Prop 65 Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: KLARAID* CDP1336 Page: 8 / 8 Version number: 4.0 &AD s u e2 Version: 6.0 Effective Date: May-23-2019 Previous Date: Mar-05-2018 SAFETY DATA SHEET POLYFLOC* CE1154 1. Identification Product identifier POLYFLOC CE1154 Other means of identification None. Recommended use Flocculant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified. Serious eye damage/eye irritation Category 2 Not classified. 1 • Warning Causes serious eye irritation. Wash thoroughly after handling. Wear eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. None. 3. Composition/information on ingredients Mixtures Components CAS # Percent Distillates (petroleum), hydrotreated light 64742-47-8 20 - 40 Alcohols, C12-16 ethoxylated 68551-12-2 2.5 - 10 Alcohols, C10-16, ethoxylated 68002-97-1 1 - 2.5 Page: 1 / 8 Components CAS # Percent Citric acid 77-92-9 1 - 2.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and symptoms/effects, acute and blurred vision. delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, containment and cleaning up basements or confined areas. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid contact with eyes. Use only in well -ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, Store in cool, well ventilated area. Store away from oxidizers. Keep away from heat and sources of including any incompatibilities ignition. Store in original tightly closed container. Store in accordance with local/regional/national/international regulation. Material name: POLYFLOC* CE1154 Page: 2 / 8 Version number: 6.0 8. Exposure controls/personal protection Occupational exposure limits US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Distillates (petroleum), TWA 100 mg/m3 hydrotreated light (CAS 64742-47-8) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Provide eyewash station. Good general ventilation should be used. Ventilation rates should be controls matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate White to off-white Emulsion Slight hydrocarbon Not available. 4.9 (0.5% SOL.) < 23 °F (< -5 °C) Not available. > 212 °F (> 100 °C) P-M(CC) < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density > 1 (Air = 1) Relative density 1.04 Relative density temperature 70 °F (21 °C) Material name: POLYFLOC* CE1154 Page: 3 / 8 Version number: 6.0 Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 1440 cps Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point < 28 °F (< -2 °C) Specific gravity 1.036 VOC 26 % (ASTM 3960-93) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Ammonia, hydrogen chloride, oxides of carbon and nitrogen evolved in fire. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Causes serious eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Causes serious physical, chemical and eye irritation. toxicological characteristics Information on toxicological effects Acute toxicity Product Species Test Results POLYFLOC CE1154 (CAS Mixture) Acute Dermal LD50 Rabbit > 5000 mg/kg, (Calculated according to GHS additivity formula) Inhalation LC50 Rat > 20 mg/I, 4 Hours, (Calculated according to GHS additivity formula) Oral LD50 Rat > 5000 mg/kg, (Calculated according to GHS additivity formula) Components Species Test Results Alcohols, C10-16, ethoxylated (CAS 68002-97-1) Acute Oral LD50 Rat 384 mg/kg Material name: POLYFLOC* CE1154 Page: 4 / 8 Version number: 6.0 Components Species Test Results Alcohols, C12-16 ethoxylated (CAS 68551-12-2) Acute Oral LD50 Rat 1600 mg/kg Citric acid (CAS 77-92-9) Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 5400 mg/kg Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Acute Dermal LD50 Rabbit > 2000 mg/kg Inhalation LC50 Rat > 5.2 mg/I, 4 Hour Oral LD50 Rat > 5000 mg/kg Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Not classified. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product Species Test Results POLYFLOC CE1154 (CAS Mixture) Aquatic Algae IC50 Selenastrum (algae) Algal inhibition tests are not appropriate. Crustacea 10% Mortality Daphnia magna 0.78 mg/L, Static Renewal Bioassay, 48 hour EC50 Daphnia magna 10 - 100 mg/I, 48 Hour, Fresh water. Based on test data for structurally similar materials. Material name: POLYFLOC* CE1154 Page: 5 / 8 Version number: 6.0 Product Species Test Results Fish LC50 Bluegill Sunfish Fathead Minnow Rainbow Trout Zebra Fish NOEL Fathead Minnow Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Citric acid -1.64 Distillates (petroleum), hydrotreated light 3-6 Bioconcentration factor (BCF) Citric acid 3 Distillates (petroleum), hydrotreated light 207.7 Mobility in soil No data available. Other adverse effects Not available. Persistence and degradability 2.4 mg/L, Static Renewal Bioassay, 48 hour 2.5 mg/L, Static Acute Bioassay, 96 hour 2.8 mg/L, Static Renewal Bioassay, 96 hour 0.94 mg/L, Static Acute Bioassay, 96 hour 1 - 10 mg/I, 96 Hour, Based on test data for structurally similar materials. 0.7 mg/L, Static Renewal Bioassay, 96 hour Testing has shown product not to be readily biodegradable. OECD (301 B) CO2 Evolution (Modified Sturm Test) (OECD 301 B) At natural pHs (>6) the product degrades due to hydrolysis to more than 70% in 28 days. The hydrolysis products are not harmful to aquatic organisms. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container classification. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. General information IMDG Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. Material name: POLYFLOC* CE1154 Page: 6 / 8 Version number: 6.0 CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Classified hazard Serious eye damage or eye irritation categories SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Acrylamide (CAS 79-06-1) Formaldehyde (CAS 50-00-0) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Formaldehyde (CAS 50-00-0) Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) US state regulations US. California Proposition 65 WARNING: This product can expose you to chemicals including Acrylamide, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Acrylamide (CAS 79-06-1) Listed: January 1, 1990 Formaldehyde (CAS 50-00-0) Listed: January 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 16. Other information, including date of preparation or last revision Issue date May-11-2015 Revision date May-23-2019 Version # 6.0 NFPA ratings Health: 2 Flammability: 0 Instability: 0 Material name: POLYFLOC* CE1154 Page: 7 / 8 Version number: 6.0 NFPA ratings i 0 List of abbreviations CAS: Chemical Abstract Service Registration Number TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code ACGIH: American Conference of Governmental Industrial Hygienists TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Exposure controls/personal protection: Eye/face protection Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Regulatory Information: Risk Phrases - Classification Regulatory information: California Prop 65 Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: POLYFLOC* CE1154 Page: 8 / 8 Version number: 6.0 &AD s u e2 Version: 3.1 Effective Date: Dec-17-2017 Previous Date: Jun-17-2016 SAFETY DATA SHEET POLYFLOC* CE1161 P 1. Identification Product identifier POLYFLOC CE1161 P Other means of identification None. Recommended use Potable water treatment chemical Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified. Not classified. Not classified. None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. Combustible. None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing. Thoroughly wash clothing before reuse. Page: 1 / 7 Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire -fighting measures Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do not feed anything by mouth to an unconscious or convulsive victim. Dilute contents of stomach using 2-8 fluid ounces (60-240ml) of milk or water. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Headache. Nausea, vomiting. Diarrhea. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Combustible. No unusual fire or explosion hazards noted 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SIDS. Spills are protective equipment and very slippery. emergency procedures Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SIDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in well -ventilated areas. Spills are very slippery. Conditions for safe storage, Keep away from heat and sources of ignition. Store in original tightly closed container. Store away including any incompatibilities from incompatible materials (see Section 10 of the SDS). Store in accordance with local/regional/national/international regulation. 8. Exposure controls/personal protection Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Material name: POLYFLOC" CE1161P Page: 2 / 7 Version number: 3.1 Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point White to off-white Emulsion Slight hydrocarbon Not available. 4.6 (1% SOL.) < 23 °F (< -5 °C) Not available. > 200 °F (> 93 °C) P-M(CC) Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density > 1 (Air = 1) Relative density 1.04 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 1695 cps Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point < 28 °F (< -2 °C) Specific gravity 1.038 Material name: POLYFLOC" CE1161P Page: 3 / 7 Version number: 3.1 VOC 25 % (SUPPLIER DATA) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. None under normal conditions. Incompatible materials Strong oxidizing agents. Hazardous decomposition Toxic gas. Ammonia, hydrogen chloride, oxides of carbon and nitrogen evolved in fire. Hydrogen products cyanide evolved in fire. 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Headache. Nausea, vomiting. Diarrhea. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Species POLYFLOC CE1161 P (CAS Mixture) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Oral LD50 Rat Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Test Results > 5000 mg/kg, (Calculated according to GHS additivity formula) > 15.75 mg/I, 4 Hours, (Calculated according to GHS additivity formula) > 5000 mg/kg, (Calculated according to GHS additivity formula) Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure Material name: POLYFLOC* CE1161 P Page: 4 / 7 Version number: 3.1 Not classified. Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity Product Based on available data, the classification criteria are not met. Does not result in classification of the mixture if the kinematic viscosity is greater than 20.5 mm2/sec measured at 40C. Prolonged inhalation may be harmful. This product has no known adverse effect on human health. Species POLYFLOC CE1161 P (CAS Mixture) 15% Mortality Fathead Minnow Aquatic Crustacea Bioaccumulative potential Mobility in soil Other adverse effects Persistence and degradability - COD (mg02/g) - BOD 5 (mg02/g) - BOD 28 (mg02/g) - Closed Bottle Test (% Degradation in 28 days) - Zahn-Wellens Test (% Degradation in 28 days) - TOC (mg C/g) 30% Mortality Ceriodaphnia LC50 Ceriodaphnia Fathead Minnow Test Results 1.9 mg/L, Static Renewal Bioassay, 96 hour 0.24 mg/L, Static Acute Bioassay, 48 hour 0.34 mg/L, Static Acute Bioassay, 48 hour 5.5 mg/L, Static Renewal Bioassay, 96 hour 15% Mortality Daphnia magna 7.8 mg/L, Static Renewal Bioassay, 48 hour LC50 Daphnia magna 29.1 mg/L, Static Renewal Bioassay, 48 hour No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Testing has shown product not to be readily biodegradable. At natural pHs (>6) the product degrades due to hydrolysis to more than 70% in 28 days. The hydrolysis products are not harmful to aquatic organisms. 1180 272 352 30 A M 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. Material name: POLYFLOC" CE1161P Page: 5 / 7 Version number: 3.1 IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) US state regulations US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Acrylamide (CAS 79-06-1) Listed: January 1, 1990 US - California Proposition 65 - CRT: Listed date/Developmental toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 US - Massachusetts RTK - Substance List Not regulated. Material name: POLYFLOC" CE1161P Page: 6 / 7 Version number: 3.1 US - Pennsylvania RTK - Hazardous Substances Not regulated. US - Rhode Island RTK Not regulated. US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. 16. Other information, including date of preparation or last revision Issue date Feb-18-2015 Revision date Dec-17-2017 Version # 3.1 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Other information, including date of preparation or last revision: Prepared by GHS: Classification Trademark of SUEZ. May be registered in one or more countries. Material name: POLYFLOC" CE1161P Page: 7 / 7 Version number: 3.1 &AD s u e2 Version: 3.2 Effective Date: Jan-22-2018 Previous Date: Dec-16-2017 SAFETY DATA SHEET POLYFLOC* CE1167 1. Identification Product identifier POLYFLOC CE1167 Other means of identification None. Recommended use Flocculant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified. Not classified. Not classified. None. None. The material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard's (29CFR 1910.1200) implementation of the Globally Harmonized System (GHS), i.e., material is not a dangerous substance or mixture requiring GHS classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of contents/container to approved local facility.. Combustible. None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. Page: 1 / 7 4. First -aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire -fighting measures If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Headache. Nausea, vomiting. Diarrhea. Aspiration into the lungs will result in chemical pneumonia and may be fatal. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Combustible. No unusual fire or explosion hazards noted 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. protective equipment and emergency procedures Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Spills are very slippery. Avoid prolonged or repeated contact with skin. Use only in well -ventilated areas. Conditions for safe storage, Keep away from heat and sources of ignition. Store in original tightly closed container. Store away including any incompatibilities from incompatible materials (see Section 10 of the SDS). Store in accordance with local/regional/national/international regulation. 8. Exposure controls/personal protection Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Material name: POLYFLOC" CE1167 Page: 2 / 7 Version number: 3.2 Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Chemical goggles are recommended. Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point White to off-white Emulsion Slight hydrocarbon Not available. 4.2 (0.5% SOL.) < 23 °F (< -5 °C) 210 °F (99 °C) > 200 °F (> 93 °C) P-M(CC) Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density > 1 (Air = 1) Relative density 1.04 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 1500 cps Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point < 28 °F (< -2 °C) Material name: POLYFLOC* CE1167 Page: 3 / 7 Version number: 3.2 Specific gravity 1.044 VOC 35 % (Calculated) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. None under normal conditions. Incompatible materials Strong oxidizing agents. Contact with oxidizers may cause fire. Hazardous decomposition Oxides of carbon and nitrogen, hydrogen chloride, ammonia and volatile amines. Toxic gas. products Hydrogen chloride. Oxides of carbon and nitrogen, ammonia and volatile amines. 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Mists/aerosols may cause irritation to upper respiratory tract. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Headache. Nausea, vomiting. Diarrhea. Exposure may cause temporary irritation, redness, or physical, chemical and discomfort. toxicological characteristics Information on toxicological effects Acute toxicity Product Species Test Results POLYFLOC CE1167 (CAS Mixture) Acute Dermal LD50 Rabbit > 5000 mg/kg, (Estimated value) Oral LD50 Rat > 5000 mg/kg, (Estimated value) Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Material name: POLYFLOC" CE1167 Page: 4 / 7 Version number: 3.2 Aspiration hazard Based on available data, the classification criteria are not met. Does not result in classification of the mixture if the kinematic viscosity is greater than 20.5 mm2/sec measured at 40C. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results POLYFLOC CE1167 (CAS Mixture) LC50 Fathead Minnow 2.2 mg/L, Static Renewal Bioassay, 96 hour NOEL Fathead Minnow 1.3 mg/L, Static Renewal Bioassay, 96 hour Aquatic Crustacea EC50 Daphnia magna > 50 mg/L, Acute Toxicity, 48 hour, (Natural Water) LC50 Daphnia magna 28 mg/L, Static Renewal Bioassay, 48 hour NOEL Daphnia magna 3 mg/L, Static Renewal Bioassay, 48 hour Fish LC50 Fish > 10 mg/L, Acute Toxicity, 96 hour, (Natural Water) Rainbow Trout 0.9 mg/L, Static Acute Bioassay, 96 hour NOEL Rainbow Trout 0.49 mg/L, Static Acute Bioassay, 96 hour Bioaccumulative potential Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Environmental fate The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. - COD (mg02/g) 1170 - BOD 5 (mg021g) 434 - BOD 28 (mg02/g) 434 - Closed Bottle Test (% 37 Degradation in 28 days) - TOC (mg C/g) 490 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOIL for exact container classification. Material name: POLYFLOC" CE1167 Page: 5 / 7 Version number: 3.2 IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations All components are on the U.S. EPA TSCA Inventory List. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 3111312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Clean Water Act (CWA) Hazardous substance Section 112(r) (40 CFR 68.130) Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) US state regulations US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. Material name: POLYFLOC" CE1167 Page: 6 / 7 Version number: 3.2 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. US - Massachusetts RTK - Substance List Not regulated. US - Pennsylvania RTK - Hazardous Substances Not regulated. US - Rhode Island RTK Not regulated. US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. 16. Other information, including date of preparation or last revision Issue date Jul-31-2015 Revision date Jan-22-2018 Version # 3.2 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LC50: Lethal Concentration, 50% LD50: Lethal Dose, 50% TWA: Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Hazard(s) identification: Hazard statement Other information, including date of preparation or last revision: Disclaimer GHS: Classification Prepared by This SDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: POLYFLOC" CE1167 Page: 7 / 7 Version number: 3.2 &AD s u e2 SAFETY DATA SHEET NOVUS* CE2667 1. Identification Product identifier NOVUS CE2667 Other means of identification None. Recommended use Flocculant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Version: 4.0 Effective Date: Oct-24-2019 Previous Date: Apr-17-2019 Physical hazards Not classified. Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects OSHA defined hazards Not classified. Label elements 1 • Signal word Warning Hazard statement Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well -ventilated area. Wear eye protection/face protection. Wear protective gloves. Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. Page: 1 / 9 3. Composition/information on ingredients Mixtures Components CAS # Percent Distillates (petroleum), hydrotreated light 64742-47-8 40 - 60 Ammonium chloride 12125-02-9 2.5 - 10 Poly(oxy-1,2-ethanediyl),alpha-tridecyl-omega-hydroxy- 24938-91-8 2.5 - 10 2-PROPENOIC ACID,2-ETHYLHEXYL ESTER, HOMOPOLYMER(PEHA) 9003-77-4 1 - 2.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention if symptoms occur. Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye symptoms/effects, acute and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May delayed cause respiratory irritation. Skin irritation. May cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Material name: NOVUS* CE2667 Page: 2 / 9 Version number: 4.0 7. Handling and storage Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in well -ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Clean spill immediately. Wash contaminated skin promptly. Conditions for safe storage, Store locked up. Keep away from heat and sources of ignition. Keep container tightly closed. Store including any incompatibilities away from oxidizers. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-3 (29 CFR 1910.1000) Components Type Value Form Ammonium chloride (CAS TWA 5 mg/m3 Respirable fraction. 12125-02-9) 15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction. US. ACGIH Threshold Limit Values Components Type Value Form Ammonium chloride (CAS STEL 20 mg/m3 Fume. 12125-02-9) TWA 10 mg/m3 Fume. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Ammonium chloride (CAS STEL 20 mg/m3 Fume. 12125-02-9) TWA 10 mg/m3 Fume. Distillates (petroleum), TWA 100 mg/m3 hydrotreated light (CAS 64742-47-8) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Eye wash facilities and emergency shower must be available when handling this product. Good controls general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color White to off-white Physical state Emulsion Odor Slight hydrocarbon Odor threshold Not available. Material name: NOVUS* CE2667 Page: 3 / 9 Version number: 4.0 pH (concentrated product) Not available. pH in aqueous solution 5 (0.5% SOL.) Melting point/freezing point < 23 °F (< -5 °C) Initial boiling point and boiling Not available. range Flash point > 200 °F (> 93 °C) P-M(CC) Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density > 1 (Air = 1) Relative density 1.03 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 1500 cps Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point < 28 °F (< -2 °C) Specific gravity 1.034 VOC 30 % (Estimated) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Oxides of carbon and nitrogen, ammonia and volatile amines. Oxides of sulfur. products 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea. Material name: NOVUS* CE2667 Page: 4 / 9 Version number: 4.0 Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye physical, chemical and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Narcotic effects. May cause respiratory irritation. Product Species Test Results NOVUS CE2667 (CAS Mixture) Acute Dermal LD50 Rabbit > 2000 mg/kg, (Calculated according to GHS additivity formula) Inhalation LC50 Rat > 20 mg/I, 4 Hours, (Calculated according to GHS additivity formula) Oral LD50 Rat > 5000 mg/kg, (Calculated according to GHS additivity formula) Components Species Test Results Ammonium chloride (CAS 12125-02-9) Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 1410 mg/kg Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Acute Dermal LD50 Rabbit > 2000 mg/kg Inhalation LC50 Rat > 5.2 mg/I, 4 Hour Oral LD50 Rat > 5000 mg/kg Poly(oxy-1,2-ethanediyl),alpha-tridecyl-omega-hydroxy- (CAS 24938-91-8) Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 2000 mg/kg Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Material name: NOVUS* CE2667 Page: 5 / 9 Version number: 4.0 US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - May cause respiratory irritation. May cause drowsiness and dizziness. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product Species NOVUS CE2667 (CAS Mixture) Aquatic Crustacea 35% Mortality Daphnia magna LC50 Daphnia magna Test Results 0.078 mg/L, Static Renewal Bioassay, 48 hour 0.14 mg/L, Static Renewal Bioassay, 48 hour Fish LC50 Fathead Minnow 2.5 mg/L, Static Renewal Bioassay, 96 hour NOEL Fathead Minnow 1.3 mg/L, Static Renewal Bioassay, 96 hour Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Distillates (petroleum), hydrotreated light Bioconcentration factor (BCF) Distillates (petroleum), hydrotreated light Mobility in soil No data available. Other adverse effects Not available. Persistence and degradability - COD (mg02/g) 1290 - BOD 5 (mg02/g) 29 - BOD 28 (mg02/g) 238 - Closed Bottle Test (% 18 Degradation in 28 days) - Zahn-Wellens Test (% 25 Degradation in 28 days) - TOC (mg C/g) 450 MOR 207.7 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. Material name: NOVUS* CE2667 Page: 6 / 9 Version number: 4.0 Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOIL for exact container classification. IATA UN number UN3082 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (PETROLEUM DISTILLATES) Transport hazard class(es) Class 9M1 Subsidiary risk - Packing group III Environmental hazards No. ERG Code 171 Special precautions for user Not available. IMDG UN number UN3082 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PETROLEUM DISTILLATES) Transport hazard class(es) Class 9 Subsidiary risk - Packing group III Environmental hazards Marine pollutant No. EmS F-A, S-F Special precautions for user Not available. IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Ammonium chloride (CAS 12125-02-9) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Classified hazard Skin corrosion or irritation categories Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) SARA 313 (TRI reporting) Chemical name CAS number % by wt. Ammonium chloride 12125-02-9 2.5 - 10 Material name: NOVUS* CE2667 Page: 7 / 9 Version number: 4.0 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Inventory status Country(s) or region Canada Not regulated. Inventory name Domestic Substances List (DSL) On inventory (yes/no)* Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). US state regulations California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. 16. Other information, including date of preparation or last revision Issue date Revision date Version # NFPA ratings NFPA ratings Dec-05-2014 Oct-24-2019 4.0 Health: 2 Flammability: 0 Instability: 0 r 0, O LAM List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LC50: Lethal Concentration, 50% LD50: Lethal Dose, 50% TWA: Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Material name: NOVUS* CE2667 Page: 8 / 9 Version number: 4.0 Revision information Product and Company Identification: Commercial Names Regulatory information: California Proposition 65 Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: NOVUS* CE2667 Page: 9 / 9 Version number: 4.0 &AD s u e2 SAFETY DATA SHEET NOVUS* CE2680 1. Identification Product identifier NOVUS CE2680 Other means of identification None. Recommended use Flocculant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Version: 4.0 Effective Date: Oct-11-2018 Previous Date: Mar-09-2018 Physical hazards Not classified. Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects OSHA defined hazards Not classified. Label elements 1 • Signal word Warning Hazard statement Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Wear eye/face protection. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well -ventilated area. Wear protective gloves. Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. Page: 1 / 9 3. Composition/information on ingredients Mixtures Components CAS # Percent Distillates (petroleum), hydrotreated light 64742-47-8 20 - 40 ALCOHOLS,C11-C14-ISO,C13-RICH,ETHOXYLATED 78330-21-9 1 - 2.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention if symptoms occur. Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye symptoms/effects, acute and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May delayed cause respiratory irritation. Skin irritation. May cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation emergency procedures of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, containment and cleaning up basements or confined areas. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. Ventilate area, use specified protective equipment. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Material name: NOVUS* CE2680 Page: 2 / 9 Version number: 4.0 7. Handling and storage Precautions for safe handling Avoid breathing mist or vapor. Avoid contact with eyes. Avoid contact with skin. Avoid prolonged or repeated contact with skin. Avoid contact with clothing. Avoid prolonged exposure. Use only in well -ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Use care in handling/storage. Conditions for safe storage, Store locked up. Keep away from heat and sources of ignition. Protect from freezing. Product including any incompatibilities forms unusable solids that can not be thawed, even at room temperature, if subjected to freezing conditions. Store in original tightly closed container. Store in accordance with local/regional/national/international regulation. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Distillates (petroleum), PEL 400 mg/m3 hydrotreated light (CAS 64742-47-8) 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Distillates (petroleum), TWA 100 mg/m3 hydrotreated light (CAS 64742-47-8) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color White to off-white Physical state Emulsion Odor Slight hydrocarbon Odor threshold Not available. pH in aqueous solution 4.8 (1% SOL.) 4.9 (0.5% SOL.) Melting point/freezing point < 23 °F (< -5 °C) Initial boiling point and boiling 210 °F (99 °C) range Flash point Evaporation rate > 200 °F (> 93 °C) P-M(CC) < 1 (Ether = 1) Material name: NOVUS* CE2680 Version number: 4.0 Page: 3 / 9 Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density > 1 (Air = 1) Relative density 1.03 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 1300 cps Viscosity temperature 70 °F (21 °C) Other information Pour point < 28 °F (< -2 °C) Specific gravity 1.034 VOC 25 % (Estimated) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Protect from freezing. Avoid contact with strong oxidizers. Incompatible materials Strong oxidizing agents. Hazardous decomposition Oxides of carbon evolved in fire. products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, mental confusion, dizziness and lethargy. Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Severe eye physical, chemical and irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May toxicological characteristics cause respiratory irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Narcotic effects. May cause respiratory irritation. Material name: NOVUS* CE2680 Page: 4 / 9 Version number: 4.0 Product Species Test Results NOWS CE2680 (CAS Mixture) Acute Dermal LD50 Rabbit > 5000 mg/kg, (Calculated according to GHS additivity formula) Inhalation LC50 Rat > 20 mg/I, 4 Hours, (Calculated according to GHS additivity formula) Oral LD50 Rat > 5000 mg/kg, (Calculated according to GHS additivity formula) Components Species Test Results Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Acute Dermal LD50 Rabbit > 2000 mg/kg Inhalation LC50 Rat > 5.2 mg/I, 4 Hour Oral LD50 Rat > 5000 mg/kg Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Narcotic effects. May cause respiratory irritation. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product Species NOWS CE2680 (CAS Mixture) LC50 Test Results Ceriodaphnia 0.09 mg/L, Static Renewal Bioassay, 48 hour Fathead Minnow 5.1 mg/L, Static Renewal Bioassay, 96 hour Material name: NOVUS* CE2680 Page: 5 / 9 Version number: 4.0 Product Species Test Results NOEL Ceriodaphnia 0.06 mg/L, Static Renewal Bioassay, 48 hour Fathead Minnow 0.8 mg/L, Static Renewal Bioassay, 96 hour Aquatic Crustacea LC50 Daphnia magna 2.4 mg/L, Static Renewal Bioassay, 48 hour NOEL Daphnia magna 0.39 mg/L, Static Renewal Bioassay, 48 hour Fish LC50 Rainbow Trout 1.1 mg/L, Static Renewal Bioassay, 96 hour NOEL Rainbow Trout 0.75 mg/L, Static Renewal Bioassay, 96 hour Persistence and degradability Not available. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Distillates (petroleum), hydrotreated light 3-6 Bioconcentration factor (BCF) Distillates (petroleum), hydrotreated light 207.7 Mobility in soil No data available. Other adverse effects Not available. Persistence and degradability - COD (mg02/g) 850 - BOD 5 (mg021g) 122 - BOD 28 (mg02/g) 132 - Closed Bottle Test (% 16 Degradation in 28 days) - Zahn-Wellens Test (% 44 Degradation in 28 days) - TOC (mg C/g) 320 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. IATA UN number UN3082 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (QUATERNARY AMMONIUM POLYACRYLAMIDE) Transport hazard class(es) Class 9 Material name: NOVUS* CE2680 Page: 6 / 9 Version number: 4.0 Subsidiary risk - Packing group III Environmental hazards Yes ERG Code 171 Special precautions for user Not available. IMDG UN number UN3082 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (QUATERNARY AMMONIUM POLYACRYLAMIDE), MARINE POLLUTANT Transport hazard class(es) Class 9 Subsidiary risk - Packing group III Environmental hazards Marine pollutant Yes EmS F-A, S-F Special precautions for user Not available. IATA; IMDG Marine pollutant General information 15. Regulatory information US federal regulations IMDG Regulated Marine Pollutant. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Material name: NOVUS* CE2680 Page: 7 / 9 Version number: 4.0 Classified hazard categories Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Inventory status Country(s) or region Canada Canada Not regulated. Inventory name Domestic Substances List (DSL) Non -Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)* Yes No Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration Generally recognized as safe (GRAS) for papermaking applications that may contact aqueous and fatty food per 21 CFR 170.30. US state regulations US. California Proposition 65 This product can expose you to chemicals including Acrylamide, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Acrylamide (CAS 79-06-1) Listed: January 1, 1990 US - California Proposition 65 - CRT: Listed date/Developmental toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Acrylamide (CAS 79-06-1) Listed: February 25, 2011 16. Other information, including date of preparation or last revision Issue date Nov-14-2014 Revision date Oct-11-2018 Version # 4.0 List of abbreviations CAS: Chemical Abstract Service Registration Number ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Material name: NOVUS* CE2680 Page: 8 / 9 Version number: 4.0 Revision information Product and Company Identification: Commercial Names Composition/information on ingredients: Composition comments Physical & Chemical Properties: Multiple Properties Toxicological Information: Toxicological Data Transport Information: Material Transportation Information Regulatory information: California Prop 65 Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). * Trademark of SUEZ. May be registered in one or more countries. Material name: NOVUS* CE2680 Page: 9 / 9 Version number: 4.0 BRENNTAGM MATERIAL SAFETY DATA Page 1/ 8 SHEET Revision : 10/4/2018 Revision nr : 6 Supersedes : 25/8/2014 CITRIC ACID >=20% Code: 11454 SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical description Citric acid anhydrous , solution (>=20%). Type of product Pure product in solution . Reach registration number : 01-2119457026-42 1.2. Relevant identified uses of the substance or mixture and uses advised aaainst Identified use(s) See table on the front page of the annex. Use(s) advised against This product is not recommended for any industrial, professional or consumer use other than identified in table on the front page of the annex. 1.3. Details of the supplier of the safety data sheet Company identification BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11 E-MAIL: info@brenntag.be - Website: www.brenntag.be BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919 E-MAIL: info@brenntag.nl - Website: www.brenntag.nl 1.4. Emergency telephone number Emergency phone number Belgium : Antipoison Center - Brussels TEL: +32(0)70/245.245 The Netherlands : National Poisoning Information Center - Bilthoven TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in cases of acute intoxications) SECTION 2. Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Eye irritation - Category 2 - Warning (Eye Irrit. 2; H319) 2.2. Label elements Label in accordance with Regulation (EC) No 1272/2008 • Dangerous ingredient(s) Citric acid anhydrous • Hazard pictogram(s) 1 • Signal word Warning • Hazard statements H319 - Causes serious eye irritation. • Precautionary statements - Prevention P264 - Wash skin thoroughly after handling. P280 - Wear protective gloves/ protective clothing/eye protection/face protection. - Response P305+P351+P338 - IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. 2.3. Other hazards Physical/chemical hazards The substance decomposes by heating above the melting point in information of methyl maleic anhydride. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page : 2 / 8 Revision : 10/4/2018 Revision nr: 6 CITRIC ACID >=20% Supersedes : 25/8/2014 Code: 11454 SECTION 2. Hazards identification (continued) Hazards for the health No significant danger. Hazards for the environment Product causes a strong drop of the pH -value of water and soil. This product is no substance or contains no PBT or vPvB (in accordance with Annex XIII). Hazards for the safety No significant danger. SECTION 3. Composition/information on ingredients 3.1. Substances Name component(s) Weight % CAS nr EINECS nr Index nr Reach nr CLASSIFICATION Citric acid anhydrous >= 20 % 77-92-9 201-069-1 ----- 01-2119457026-42 Eye Irrit. 2; H319 The full text of the (EU)H-statements is in section 16. SECTION 4. First aid measures 4.1. Descriation of first aid measures General In case of doubt or persistent symptoms, call a physician. Never give anything by mouth to an unconscious person. First Aid Measures - Inhalation Remove victim into fresh air. Allow the affected person to rest in semi -sitting position. If not breathing, give artificial respiration. Consult a doctor. - Skin Contact Remove contaminated clothing. Rinse skin immediately with plenty of water. (shower if necessary). Consult doctor if irritation develops. - Eye Contact Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses. Consult eye doctor. Do not use a neutralisation agent. - Ingestion DO NOT INDUCE VOMITING. Rinse mouth with water. Give victim plenty of water to drink. Consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed See section 11. 4.3. Indication of anv immediate medical attention and saecial treatment needed For specialist advice doctors should contact the NVIC or the Belgian Poison center SECTION 5. Firefighting measures 5.1. Extinguishing media Extinguishing Media - Suitable Extinguishing powder, Alcohol resistant foam , Carbon dioxide (CO2) , Water spray - Insuitable Heavy water stream . 5.2. Special hazards arising from the substance or mixture Special Exposure Hazards : Fire may liberate carbon oxides (CO) and smoke. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 3/ 8 SHEET Revision : 10/4/2018 Revision nr : 6 Supersedes : 25/8/2014 CITRIC ACID >=20% Code: 11454 SECTION 5. Firefighting measures (continued) 5.3. Advice for firefiahters Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close Firefighters proximity to fire. Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter environment. SECTION 6. Accidental release measures 6.1. Personal arecautions. protective eauiament and emeraencv procedures Personal Precautions Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin and eyes. Wear recommended personal protective equipment. (See section 8) 6.2. Environmental precautions Environmental Precautions Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for Cleaning Up Collect the spillage in closable, suitable disposal containers. Residue is to be washed down with plenty of water. Neutralise rinse liquid with base. 6.4. Reference to other sections For personal protection, see section 8. For the removal of the waste product, see section 13. SECTION 7. Handling and storage 7.1. Precautions for safe handlin Handling Avoid breathing vapour and contact with skin and eyes. Wear recommended personal protective equipment. (See section 8) When using, do not eat, drink or smoke. Wash hands before and after working with the product. Emergency eye wash fountains and showers should be available in the immediate vicinity of any potential exposure. 7.2. Conditions for safe storage, including any incompatibilities Storage Keep only in the original, safely locked container in a cool and well ventilated place. All dangerous products should be placed on a drip tray or should be barreled. Keep away from : Oxidizing agents , Bases , Metalnitrates . Packaging Material Polyethylene , Polypropylene . Insuitable Packaging Material Several metals . 7.3. Specific end use(s) For identified uses, see subsection 1.2 and/or exposure scenarios. SECTION 8. Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Not established. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page: 4/8 Revision : 10/4/2018 Revision nr : 6 CITRIC ACID >=20% SECTION 8. Exposure controls/personal protection (continued) Supersedes : 25/8/2014 Code: 11454 Biological limit values They will be included when available. DNELs • Citric acid anhydrous : Not applicable PNECs • Citric acid anhydrous : Fresh water: 0,44 mg/I • Citric acid anhydrous : Marine water: 0,044 mg/I • Citric acid anhydrous : Fresh water sediment : 3,46 mg/kg • Citric acid anhydrous : Marine water sediment : 34,6 mg/kg • Citric acid anhydrous : Soil : 33,1 mg/kg • Citric acid anhydrous : Sewage treatment plant : >1000 mg/I 8.2. Exaosure controls Engineering Measures Ventilation , Local exhaust . Personal Protection Equipment - Respiratory protection No special respiratory protection equipment is recommended under normal conditions of anticipated use with adequate ventilation. - Skin protection Suitable protective clothing . - Hand protection Suitable material for safety gloves (EN 374): The suitability of the gloves and the breakthrough time for a specific workplace should be discussed with the producers of the protective gloves. - material : Butyl rubber - thickness : 0, 11 mm - breakthrough time : > 8 h - Eye/Face protection Closed safety glasses or face shield. Environmental exposure controls See sections 6, 7, 12 and 13. SECTION 9. Physical and chemical properties 9.1. Information on basic ohvsical and chemical aroaerties See technical data sheet for detailed information Physical State (20°C) Liquid . Form/Colour Clear, Colourless . Odour : Odourless . Odour threshold Not applicable. pH value Strong acid . Melting/Freezing point No data available. Boiling Point/Range (1013 hPa) No data available. Flash point Not applicable. Fire hazard Not applicable. Evaporation rate No data available. Vapour pressure No data available. Relative vapour density (air=1) No data available. Density (20°C) 1,070 - 1,225 kg/I Solubility in water 163 g/100ml Soluble in Alcohol . Log P Octanol/Water (20°C) -1,7 Auto -ignition temperature No data available. Minimum ignition energy No data available. Decomposition temperature No data available. Viscosity No data available. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page : 5 / 8 Revision : 10/4/2018 Revision nr : 6 CITRIC ACID >=20% SECTION 9. Physical and chemical properties (continued) Explosive properties Oxidizing properties Supersedes : 25/8/2014 Code: 11454 No chemical groups associated with explosive properties . No chemical groups associated with oxidizing properties . SECTION 10. Stability and reactivity 10.1. Reactivit Reactivity Reacts violently with oxidizing agents and lyes. 10.2. Chemical stability Stability Stable at normal circumstances . 10.3. Possibilitv of hazardous reactions Hazardous reactions Reacts violently with: Metalnitrates => May cause fire and explosion! 10.4. Conditions to avoid Conditions to avoid High temperatures . 10.5. Incompatible materials Materials to avoid Oxidizing agents , Bases , Metalnitrates . 10.6. Hazardous decomposition products Hazardous Decomposition Products : Carbon oxides . SECTION 11. Toxicological information 11.1. Information on toxicological effects Acute toxicity * - Inhalation Symptoms include: Cough , Sore throat . - Skin contact - Ingestion Skin corrosion/irritation Serious eye damage/irritation Aspiration hazard Respiratory or skin sensitisation Carcinogenicity Mutagenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure • Citric acid anhydrous : LC50 (Rat, inhalation, 4 h) : No data available. Symptoms include: Redness, Pain . • Citric acid anhydrous : LD50 (Rat, dermal) : >2000 mg/kg ( OECD Guideline 402) Symptoms include: Sore throat , Abdominal pain , Vomiting . • Citric acid anhydrous : LD50 (Mouse, oral) : 5400 mg/kg • Citric acid anhydrous : LD50 (Rat, oral) : 5400 mg/kg ( OECD Guideline 401) Slightly irritating . Causes serious eye irritation. Not considered hazardous. Not sensitive . Not listed as carcinogenic. Not listed as mutagenic . Not listed for reproductive toxicity . To human : Listed not for organ toxicity . For animals : No effects known. To human : Listed not for organ toxicity . For animals : No effects known. SECTION 12. Ecological information 12.1. Toxicity Ecotoxicity • Citric acid anhydrous : LC50 (Fish, 96 h) : >400 mg/I (Leusiscus idus) • Citric acid anhydrous : LC50 (Daphnia magna, 24 h) : 1535 mg/I • Citric acid anhydrous : LOEC (Algae, 8 d) : 425 mg/I BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page : 6 / 8 Revision : 10/4/2018 Revision nr : 6 CITRIC ACID >=20% SECTION 12. Ecological information (continued) 12.2. Persistence and dearadabilit Supersedes : 25/8/2014 Code: 11454 Persistence and degradability • Citric acid anhydrous : Persistence and degradability : Readily biodegradable . 12.3. Bioaccumulative potential Bioaccumulation • Citric acid anhydrous : Bioaccumulation : Bioaccumulation not expected . 12.4. Mobility in soil Mobility • Citric acid anhydrous : Mobility : Highly soluble in water. 12.5. Results of PBT and vPvB assessment Evaluation : • Citric acid anhydrous : PBT/vPvB : No 12.6. Other adverse effects Photochemical ozone creation potential No data available. Ozone depletion potential No data available. Endocrine disrupting potential No data available. Global warming potential No data available. SECTION 13. Disposal considerations 13.1. Waste treatment methods Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products. European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. See Decision 2001/118/EC. Removal contaminated packaging Packing is to be used exclusively for the packing of this product. After use, empty and close the packing very carefully. In case of returned packing, the empty packing can be offered back to the supplier. SECTION 14. Transport information 14.1. UN number UN Number 14.2. UN proper shipping name ADR/RID Name ADN Name IMDG Name * IATA Name 14.3. Transport hazard classe(s) Class 14.4. Packing group Packaging Group 14.5. Environmental hazards Environmentally hazard Marine pollutant BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 7/ 8 SHEET Revision : 10/4/2018 Revision nr : 6 Supersedes : 25/8/2014 CITRIC ACID >=20% Code: 11454 SECTION 14. Transport information (continued) 14.6. Snecial arecautions for user Danger number Hazard Label(s) EmS-N° 14.7. Transaort in bulk accordina Type ship Pollution category to Annex II of MARPOL and the IBC Code SECTION 15. Regulatory information 15.1. Safetv. health and environmental reaulations/leaislation saecific for the substance or mixture Inventories European inventory (EINECS): Listed in inventory. Relevant EU Rule(s) Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision 2000/532/EC as regards the list of wastes Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/ 2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (Reach) * National regulations * - Germany WGK : 1 * - Netherlands Water damaging : B Decontamination exertion : 5 15.2. Chemical Safety Assessment A chemical safety assessment has been carried out for the material. SECTION 16. Other information * This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006 and the corresponding current changes. This safety data sheet is exclusively made for industrial/professional use. * Has changed compared to previous revision. * Changes Section 2 , Section 3 , Section 11 , Section 14 , Section 15 , Section 16 . Sources of used key data The information contained herein is based on the present state of our knowledge Producers of starting materials , Chemical cards , ...). See also on the webaddress: http://apps.echa.europa.eu/registered/registered-sub.aspx#search * (EU)H-statement(s) H319 - Causes serious eye irritation. * List of abbrevations and acronyms ADN (Accord europ6en relatif au transport international des marchandises Dangereuses par voie de Navigation interieur) : European agreement concerning the international carriage of dangerous goods by inland waterways ADR (Accord europ6en relatif au transport international des marchandises Dangereuses par Route) : European agreement concerning the international carriage of dangerous goods by road CO: Carbon monoxide DNEL (Derived No Effect Level) : an estimated safe exposure level EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and the second code refers to the relevant spillage schedule BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 8/ 8 SHEET Revision : 10/4/2018 Revision nr : 6 Supersedes : 25/8/2014 CITRIC ACID >=20% Code: 11454 SECTION 16. Other information (continued) Eye Irrit. 2 : Eye irritation - Category 2 IATA (International Air Transport Association) : provisions concerning the international carriage of dangerous goods by air IMDG (International Maritime Dangerous Goods code) LC50 : median Lethal Concentration LD50 : median Lethal Dose LOEC (Lowest Observed Effect Concentration) NVIC : National Poisoning Information Center OECD : Organisation for Economic Cooperation and Development PBT : persistent, bioaccumulative and toxic PNEC (Predicted No Effect Concentration) : concentration below which exposure to a substance is not expected to cause adverse effects REACH : Registration, Evaluation, Authorisation and restriction of Chemicals RID (Reglement concernant le transport International ferroviaire des marchandises Dangereuses) : Regulation concerning the International carriage of Dangerous goods by rail WGK (Wassergefahrdungsklasse) : a German classification of substances that indicate the environmental hazard for surface water vPvB : very persistent and very bioaccumulative This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is suitable and complete concerning the special use he makes of the product. BRENNTAG denies all responsibility for loss or damage resulting from the use of these data. End of document BRENNTAG Version: 1.0 Effective Date: Jan-26-2015 Previous Date: Jan-26-2015 GE Power & Water Water & Process Technologies SAFETY DATA SHEET KLARAID* IC1173 1. Identification Product identifier KLARAID IC1173 Other means of identification None. Recommended use Coagulant Recommended restrictions None known. Company/undertaking identification GE Betz, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Corrosive to metals Category 1 Health hazards Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation OSHA defined hazards Not classified. Label elements u , -g• Signal word Danger Hazard statement May be corrosive to metals. Causes serious eye damage. May cause respiratory irritation. Precautionary statement Prevention Keep only in original container. Avoid breathing mist or vapor. Use only outdoors or in a well -ventilated area. Wear eye/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor/. Absorb spillage to prevent material damage. Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant/ container with a resistant inner liner. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified None known. IHNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Page: 1 / 8 Chemical name Common name and synonyms CAS number % Aluminum chloride, basic 1327-41-9 20 - 40 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Dilute contents of stomach using 2-8 fluid ounces (60-240ml) of milk or water. Rinse mouth. Get medical attention if symptoms occur. Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. symptoms/effects, acute and Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation. delayed Indication of immediate medical Provide general supportive measures and treat symptomatically. Keep victim under observation. attention and special treatment Symptoms may be delayed. needed General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use waterjet as an extinguisher, as this will spread the fire. Specific hazards arising from the During fire, gases hazardous to health may be formed. chemical Special protective equipment and Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand precautions for firefighters breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider equipment/instructions the hazards of other involved materials. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. 6. Accidental release measures Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low equipment and emergency areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or procedures vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Absorb spillage to prevent material damage. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in accordance with any local agreements. 7. Handling and storage Precautions for safe handling Do not get this material in contact with eyes. Avoid breathing mist or vapor. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Material name: KLARAID* IC1173 Page: 2 / 8 Version number: 1.0 Conditions for safe storage, Store in corrosive resistant container with a resistant inner liner. Store away from incompatible materials including any incompatibilities (see Section 10 of the SDS). Store between 4 - 38 °C Store locked up. Store in a cool, dry place out of direct sunlight. Keep only in the original container. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Aluminum chloride, basic TWA 1 mg/m3 Respirable fraction. (CAS 1327-41-9) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Aluminum chloride, basic TWA 2 mg/m3 (CAS 1327-41-9) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear suitable protective clothing. Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Colorless to yellow Physical state Liquid Odor Slight Odor threshold Not available. pH (concentrated product) 1.3 pH in aqueous solution 4 (0.5% SOL.) Melting point/freezing point < -40 °F (< -40 °C) Initial boiling point and boiling 212 °F (100 °C) range Flash point > 200 °F (> 93 °C) P-M(CC) Evaporation rate < 1(Ether = 1) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper Not available. 1%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Material name: KLARAID* IC1173 Page: 3 / 8 Version number: 1.0 Vapor pressure temp. Vapor density Relative density Relative density temperature Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto -ignition temperature Decomposition temperature Viscosity Viscosity temperature Other information Percent volatile Pour point Specific gravity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 70 °F (21 °C) < 1 (Air = 1) 1.27 70 °F (21 °C) 100 % Not available. Not available. Not available. 20 cps 70 °F (21 °C) 0 (Calculated) < -40 °F (< -40 °C) 1.27 May be corrosive to metals. May react violently with alkaline materials. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. May react with bases or strong oxidizers. Hydrogen chloride. 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Causes serious eye damage. May cause gastrointestinal irritation. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation. May cause respiratory irritation. Species Test Results KLARAID IC1173 (CAS Mixture) Acute Dermal LD50 Rabbit > 5000 mg/kg, (Calculated according to GHS additivity formula) Inhalation LC50 Rat > 5 mg/I, 4 Hours, (Calculated according to GHS additivity formula) Oral LD50 Rat > 5000 mg/kg, (Calculated according to GHS additivity formula) Material name: KLARAID* IC1173 Page: 4 / 8 Version number: 1.0 Components Species Test Results Aluminum chloride, basic (CAS 1327-41-9) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Oral LD50 Rat * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitization > 2000 mg/kg > 5 mg/I, 4 Hour > 2000 mg/kg Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - May cause respiratory irritation. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. May be harmful if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species Test Results KLARAID IC1173 (CAS Mixture) 0% Mortality Fathead Minnow 1000 mg/L, Static Bioassay with 48-Hour Renewal, 96 hour, (pH adjusted) 100% Mortality Fathead Minnow 5000 mg/L, Static Bioassay with 48-Hour Renewal, 96 hour, (pH adjusted) Aquatic Crustacea 0% Mortality Daphnia magna 5000 mg/L, Static Acute Bioassay, 48 hour, (pH adjusted) * Estimates for product may be based on additional component data not shown. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Environmental fate The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Material name: KLARAID* IC1173 Page: 5 / 8 Version number: 1.0 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code D002: Waste Corrosive material [pH <=2 or=>12.5, or corrosive to steel] The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some product products residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE) Transport hazard class(es) Class 8 Subsidiary risk - Packing group III Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. ERG number 154 Some containers may be DOT exempt, please check BOL for exact container classification. IATA UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE) Transport hazard class(es) Class 8 Subsidiary risk - Packing group III Environmental hazards No. ERG Code 154 Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. IMDG UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS POLYALUMINUM CHLORIDE) Transport hazard class(es) Class 8 Subsidiary risk - Packing group III Environmental hazards Marine pollutant No. Ems Not available. Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. DOT Material name: KLARAID* IC1173 Page: 6 / 8 Version number: 1.0 IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 121b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List 140 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 ITRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants MAN List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing countrylsl. Food and drug administration Generally recognized as safe (GRAS) for papermaking applications that may contact aqueous and fatty food per 21 CFR 170.30. US state regulations US - Massachusetts RTK - Substance List Not regulated. US - Pennsylvania RTK - Hazardous Substances Aluminum chloride, basic (CAS 1327-41-9) Material name: KLARAID* IC1173 Page: 7 / 8 Version number: 1.0 US - Rhode Island RTK Not regulated. US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right -to -Know Act Not listed. US. Pennsylvania Worker and Community Right -to -Know Law Aluminum chloride, basic (CAS 1327-41-9) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. 16.Other information, including date of preparation or last revision Issue date Jan-26-2015 Revision date Jan-26-2015 Version # 1.0 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LC50: Lethal Concentration, 50% TWA: Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code TLV: Threshold Limit Value LD50: Lethal Dose, 50% NFPA: National Fire Protection Association References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Physical States Toxicological Information: Toxicological Data Transport Information: Experimental Data HazReg Data: North America GHS: Classification Prepared by This SIDS has been prepared by GE Water & Process Technologies Regulatory Department (1-215-355-3300). * Trademark of General Electric Company. May be registered in one or more countries. Material name: KLARAID* IC1173 Page: 8 / 8 Version number: 1.0 &AD s u e2 Version: 3.1 Effective Date: Dec-17-2017 Previous Date: Feb-13-2017 SAFETY DATA SHEET KLARAI D* I C 1183 1. Identification Product identifier KLARAID IC1183 Other means of identification None. Recommended use Coagulant Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified. Not classified. Not classified. None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. 4. First -aid measures Inhalation If nasal, throat or lung irritation develops - remove to fresh air and get medical attention. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Page: 1 / 7 Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth with water. Do not induce vomiting. Call a physician immediately. Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed Indication of immediate Treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Wear full protective clothing, including helmet, self-contained positive pressure or pressure and precautions for firefighters demand breathing apparatus, protective clothing and face mask. Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SIDS. protective equipment and emergency procedures Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS. Environmental precautions Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in accordance with any local agreements. 7. Handling and storage Precautions for safe handling Avoid prolonged exposure. Use care in handling/storage. Conditions for safe storage, Store in original tightly closed container. Keep containers closed when not in use. Store away from including any incompatibilities incompatible materials (see Section 10 of the SDS). Do not freeze. If frozen, thaw completely and mix thoroughly prior to use. Store away from oxidizers. Store in cool, well ventilated area. 8. Exposure controls/personal protection Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Material name: KLARAID* IC1183 Page: 2 / 7 Version number: 3.1 Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Suitable gloves can be recommended by the glove supplier. Glove selection must take into account any solvents and other hazards present. Other Wear suitable protective clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH (concentrated product) pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Colorless to yellow Liquid Mild Not available. 1.8 3.5 (5% SOL.) < -30 °F (< -34 °C) 212 °F (100 °C) > 200 °F (> 93 °C) P-M(CC) < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mm Hg Vapor pressure temp. 70 °F (21 °C) Vapor density < 1 (Air = 1) Relative density 1.32 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) 100 % Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 35 cps Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point < -30 °F (< -34 °C) Material name: KLARAID* IC1183 Page: 3 / 7 Version number: 3.1 Specific gravity 1.315 VOC 0 % (Calculated) 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Incompatible materials Avoid contact with strong oxidizers. Avoid contact with strong bases. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Species Test Results KLARAID IC1183 (CAS Mixture) Acute Dermal LD50 Rabbit > 2000 mg/kg, (Calculated according to GHS additivity formula) Inhalation LC50 Rat > 5 mg/I, 4 Hours, (Calculated according to GHS additivity formula) Oral LD50 Rat > 2000 mg/kg, (Calculated according to GHS additivity formula) Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Material name: KLARAID* IC1183 Page: 4 / 7 Version number: 3.1 Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Product Not classified. Not classified. Based on available data, the classification criteria are not met. Prolonged inhalation may be harmful. Species KLARAID IC1183 (CAS Mixture) 0% Mortality Fathead Minnow Aquatic Crustacea 0% Mortality Daphnia magna Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects Not available. Persistence and degradability 13. Disposal considerations Test Results 5000 mg/L, Static Acute Bioassay, 96 hour, (pH adjusted) 5000 mg/L, Static Acute Bioassay, 48 hour, (pH adjusted) Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container classification. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Material name: KLARAID* IC1183 Page: 5 / 7 Version number: 3.1 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Food and drug administration 21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) US state regulations US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. US - Massachusetts RTK - Substance List Not regulated. US - Pennsylvania RTK - Hazardous Substances Not regulated. US - Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. 16. Other information, including date of preparation or last revision Issue date Jan-27-2015 Revision date Dec-17-2017 Version # 3.1 Material name: KLARAID* IC1183 Page: 6 / 7 Version number: 3.1 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LC50: Lethal Concentration, 50% LD50: Lethal Dose, 50% TWA: Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Toxicological Information: Toxicological Data Transport Information: Experimental Data Other information, including date of preparation or last revision: Prepared by Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: KLARAID* IC1183 Page: 7 / 7 Version number: 3.1 &AD s u e2 Version: 5.0 Effective Date: Sep-10-2018 Previous Date: Apr-16-2018 SAFETY DATA SHEET KLARAI D* I C 1172 1. Identification Product identifier KLARAID IC1172 Other means of identification None. Recommended use Waste treatment additive. Recommended restrictions None known. Company/undertaking identification SUEZ WTS USA, Inc. 4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (800) 877 1940 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified. Not classified. Not classified. None. None. The mixture does not meet the criteria for classification. The material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard's (29CFR 1910.1200) implementation of the Globally Harmonized System (GHS), i.e., material is not a dangerous substance or mixture requiring GHS classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. None. 3. Composition/information on ingredients Mixtures Components CAS # Percent Aluminium chlorhydroxide 12042-91-0 40 - 60 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SIDS for our assessment of the potential hazards of this formulation. Page: 1 / 7 4. First -aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire -fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards Move to fresh air. Remove contaminated clothing immediately and wash skin with soap and water. Wash contaminated clothing before reuse. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Rinse mouth. Do not induce vomiting. Do not feed anything by mouth to an unconscious or convulsive victim. Direct contact with eyes may cause temporary irritation. Treat symptomatically. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, For personal protection, see section 8 of the SDS. protective equipment and emergency procedures Methods and materials for Large Spills: Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or containment and cleaning up earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS. Environmental precautions Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in accordance with any local agreements. 7. Handling and storage Precautions for safe handling Observe good industrial hygiene practices. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10 including any incompatibilities of the SDS). Do not freeze. If frozen, thaw completely and mix thoroughly prior to use. 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. ACGIH Threshold Limit Values Components Type Value Form Aluminium chlorhydroxide TWA 1 mg/m3 Respirable fraction. (CAS 12042-91-0) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Aluminium chlorhydroxide TWA 2 mg/m3 (CAS 12042-91-0) Biological limit values No biological exposure limits noted for the ingredient(s). Material name: KLARAID" IC1172 Page: 2 / 7 Version number: 5.0 Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Face shield is recommended. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Physical state Odor Odor threshold pH (concentrated product) pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range Flash point Colorless to light yellow Liquid Mild Not available. 3.7 Neat 4.5 (5% Solution) 19 °F (-7 °C) 219 °F (104 °C) Not applicable. Evaporation rate Slower than Ether Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 18 mmHg Vapor pressure temp. 70 °F (21 °C) Vapor density < 1 Relative density 1.34 Relative density temperature 70 °F (21 °C) Solubility(ies) Solubility (water) 100 % Partition coefficient Not available. (n-octanol/water) Auto -ignition temperature Not available. Decomposition temperature Not available. Viscosity 45 mPa.s Material name: KLARAID* IC1172 Page: 3 / 7 Version number: 5.0 Viscosity temperature 70 °F (21 °C) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Pour point 24 °F (4 °C) Specific gravity 1.339 VOC 0 % CALCULATED 10. Stability and reactivity Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Hydrogen chloride. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Prolonged or repeated contact may cause irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Species Test Results KLARAID IC1172 (CAS Mixture) Acute Dermal LD50 Rabbit Oral LD50 Rat Components Species > 5000 mg/kg, (Calculated according to GHS additivity formula) > 5000 mg/kg, (Calculated according to GHS additivity formula) Test Results Aluminium chlorhydroxide (CAS 12042-91-0) Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 2000 mg/kg Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Causes serious eye damage. irritation Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Material name: KLARAID* IC1172 Page: 4 / 7 Version number: 5.0 Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. 12. Ecological information Ecotoxicity Product Species Test Results KLARAID IC1172 (CAS Mixture) LC50 Ceriodaphnia 750 mg/L, Static Renewal Bioassay, 48 hour, (pH adjusted) Fathead Minnow 517 mg/L, Static Acute Bioassay, 96 hour LOEL Ceriodaphnia 3.1 mg/L, Chronic Bioassay, 7 day Fathead Minnow 10 mg/L, Chronic Bioassay, 7 day NOEL Ceriodaphnia 156 mg/L, Static Renewal Bioassay, 48 hour, (pH adjusted) 1.5 mg/L, Chronic Bioassay, 7 day Fathead Minnow 370 mg/L, Static Acute Bioassay, 96 hour 5 mg/L, Chronic Bioassay, 7 day Aquatic Crustacea 0% Mortality Daphnia magna 2500 mg/L, Static Screen, 48 hour, (pH adjusted) 20% Mortality Daphnia magna 5000 mg/L, Static Screen, 48 hour, (pH adjusted) Fish LC50 Rainbow Trout 390 mg/L, Static Acute Bioassay, 96 hour NOEL Rainbow Trout 210 mg/L, Static Acute Bioassay, 96 hour Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects Not available. Persistence and degradability 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Empty containers or liners may retain some product residues. This material and its container must products be disposed of in a safe manner. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Material name: KLARAID* IC1172 Page: 5 / 7 Version number: 5.0 14. Transport information DOT Not regulated as dangerous goods. Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container classification. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). US state regulations US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. Material name: KLARAID* IC1172 Page: 6 / 7 Version number: 5.0 US - Massachusetts RTK - Substance List Not regulated. US - Pennsylvania RTK - Hazardous Substances Aluminium chlorhydroxide (CAS 12042-91-0) Listed. US - Rhode Island RTK Not regulated. US. Pennsylvania Worker and Community Right -to -Know Law Aluminium chlorhydroxide (CAS 12042-91-0) Hazardous substance US. California Proposition 65 Not Listed. 16. Other information, including date of preparation or last revision Issue date Oct-29-2014 Revision date Sep-10-2018 Version # 5.0 List of abbreviations CAS: Chemical Abstract Service Registration Number TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code ACGIH: American Conference of Governmental Industrial Hygienists TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information Hazard(s) identification: Hazard statement Hazard(s) identification: Prevention Hazard(s) identification: Response Composition / Information on Ingredients: Disclosure Overrides Composition/information on ingredients: Composition comments First -aid measures: Indication of immediate medical attention and special treatment needed First -aid measures: Most important symptoms/effects, acute and delayed Exposure controls/personal protection: Occupational exposure limits Regulatory information: California Prop 65 Regulatory information: US federal regulations GHS: Classification Prepared by This SIDS has been prepared by SUEZ Regulatory Department (1-215-355-3300). Trademark of SUEZ. May be registered in one or more countries. Material name: KLARAID* IC1172 Page: 7 / 7 Version number: 5.0 BRENNTAGM MATERIAL SAFETY DATA Page 1/ 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical description Sodium hydroxide , Caustic soda , solution (5-51 Type of product Mixture. Reach registration number : 01-2119457892-27 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified use(s) See table on the front page of the annex. Use(s) advised against This product is not recommended for any industrial, professional or consumer use other than identified in table on the front page of the annex. Not for use in ornamental articles, in tricks and jokes and in games (in accordance with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or mixtures, which are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1). 1.3. Details of the supplier of the safety data sheet Company identification BRENNTAG N.V. - Nijverheidslaan 38 - BE-8540 DEERLIJK TEL: +32(0)56/77.69.44 - FAX: +32(0)56/77/57/11 E-MAIL: info@brenntag.be - Website: www.brenntag.be BRENNTAG Nederland B.V. - Donker Duyvisweg 44 - NL-3316 BM DORDRECHT TEL: +31(0)78/65.44.944 - FAX: +31(0)78/65.44.919 E-MAIL: info@brenntag.nl - Website: www.brenntag.nl 1.4. Emergency telephone number Emergency phone number Belgium : Antipoison Center - Brussels TEL: +32(0)70/245.245 The Netherlands : National Poisoning Information Center - Bilthoven TEL: +31(0)30/274.88.88 (Only for the purpose of informing medical personnel in cases of acute intoxications) SECTION 2. Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Corrosive to metals - Category 1 - Warning (Met. Corr. 1; H290) Skin corrosion - Category 1A - Danger (Skin Corr. 1A; H314) Serious eye damage - Category 1 - Danger (Eye Dam. 1; H318) 2.2. Label elements Label in accordance with Regulation (EC) No 1272/2008 • Dangerous ingredient(s) • Hazard pictogram(s) • Signal word • Hazard statements BRENNTAG Sodium hydroxide 4Q> Danger H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage. BRENNTAGM MATERIAL SAFETY DATA Page 2/ 10 SHEET Revision : 14/3/2019 Revision nr: 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 2. Hazards identification (continued) • Precautionary statements - Prevention P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. - Response P303+P361+P353+P310 - IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor/... P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. - Disposal considerations P501 - Dispose of this material and its container to hazardous or special waste collection point. 2.3. Other hazards Physical/chemical hazards Product reacts violently and explosive when contact with organic substances, reducing substances, metals and when contamination with dust (exotherm reaction). Hazards for the health A health dangerous concentration in the air will not or very slowly be reached by evaporation of this substance at app. 20°C; by spraying much faster. Hazards for the environment Product causes a strong rise of the pH -value of water and soil. This product is no substance or contains no PBT or vPvB (in accordance with Annex XIII). Hazards for the safety Risk of explosion by many reactions. SECTION 3. Composition/information on ingredients 3.2. Mixtures Name component(s) Weight % CAS nr EINECS nr Index nr Reach nr CLASSIFICATION Sodium hydroxide 5 -51 % 1310-73-2 215-185-5 011-002-00-6 01-2119457892-27 Met. Corr. 1; H290 Skin Corr. 1A; H314 Potassium hydroxide 0.5 < 1 % 1310-58-3 215-181-3 019-002-00-8 01-2119487136-33 Met. Corr. 1; H290 Acute Tox. 4 (oral); H302 Skin Corr. 1A; H314 The full text of the (EU)H-statements is in section 16. Note: SCL applicable SECTION 4. First aid measures 4.1. Description of first aid measures General In case of doubt or persistent symptoms, call a physician. Never give anything by mouth to an unconscious person. First Aid Measures - Inhalation Remove victim into fresh air. Allow the affected person to rest in semi -sitting position. If not breathing, give artificial respiration. Seek medical attention immediately. - Skin Contact Remove contaminated clothing and shoes while rinsing. Rinse skin immediately with mild soap and plenty of water. ( at least 20') (shower if necessary). Immediately call a POISON CENTER or doctor/physician. - Eye Contact Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses after a few minutes rinse. Immediately call a POISON CENTER or doctor/physician. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 3/ 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 4. First aid measures (continued) Keep rinsing or dripping the eye during transport. - Ingestion DO NOT INDUCE VOMITING. Rinse mouth. Give victim plenty of water to drink. Take the patient IMMEDIATELY to the hospital. 4.2. Most important symptoms and effects, both acute and delayed See section 11. 4.3. Indication of anv immediate medical attention and special treatment needed For specialist advice doctors should contact the NVIC or the Belgian Poison center SECTION 5. Firefighting measures 5.1. Extinguishing media Extinguishing Media * - Suitable Extinguishing powder, Foam , Carbon dioxide (CO2) , Water spray . - Insuitable Heavy water stream . 5.2. Special hazards arising from the substance or mixture Special Exposure Hazards : Fire may liberate toxic and stinging vapours. 5.3. Advice for firefiahters Special Protective Equipment for Use self-contained breathing apparatus and wear protective clothes when in close Firefighters proximity to fire. Special Procedures Apply water spray or fog to cool nearby equipment. Avoid fire -fighting water to enter environment. SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal Precautions Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) 6.2. Environmental precautions Environmental Precautions Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for Cleaning Up Collect the spillage in closable, corrosion resistant, suitable disposal containers. Dilute spilled liquid immediately with plenty of water - neutralise with acid. Rinse abundantly with water. 6.4. Reference to other sections For personal protection, see section 8. For the removal of the waste product, see section 13. SECTION 7. Handling and storage 7.1. Precautions for safe handling Handling AVOID FOG TRANSFORMATION! AVOID EVERY CONTACT!! Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page: 4 / 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 7. Handling and storage (continued) When diluting: add the basic solution in water, never the other way around. When dissolving or diluting the product in water, heat and mist may develop. When using, do not eat, drink or smoke. Emergency eye wash fountains and showers should be available in the immediate vicinity of any potential exposure. 7.2. Conditions for safe storaae. includina anv incompatibilities Storage Keep only in the original, safely locked container in a cool and well ventilated place. All dangerous products should be placed on a drip tray or should be barreled. Keep away from : Oxidizing agents , Acids . Packaging Material Stainless steel , Nickel , Polyethylene , Polypropylene , PVC. Insuitable Packaging Material Several metals ( Aluminium , Magnesium , Copper, Zinc (+ Alloys)), Polyester. 7.3. Specific end use(s) For identified uses, see subsection 1.2 and/or exposure scenarios. SECTION 8. Exposure controls/personal protection 8.1. Control aarameters Occupational Exposure Limits For harmful components : Sodium hydroxide: Limit value (BE) : 2 mg/m3 (2014) (M) Potassium hydroxide : Short time value (BE) : 2 mg/m' (2014) (M) Potassium hydroxide: ACGIH (TWA 8h) : 2 mg/m3 (M) The mention "M" means that the exposition above the limit value causes irritation or that there is a danger for acute poisoning. The work procedure has to be designed somehow or other that the exposition doesn't exceed the limit value. During a control, the sample period should be so short as possible to carry out a reliable measurement. The mesure result is then related to the considered period. Biological limit values They will be included when available. DNELs For harmful components : • Sodium hydroxide : Worker, long-term - local effects, inhalation : 1,0 mg/mz • Sodium hydroxide : Consumer, long-term - local effects, inhalation : 1,0 mg/m3 • Potassium hydroxide : Worker, long-term - local effects, inhalation : 1 mg/m3 PNECs For harmful components : • Sodium hydroxide : Not applicable • Potassium hydroxide : Not applicable 8.2. Exposure controls Engineering Measures Ventilation , Local exhaust . Personal Protection Equipment - Respiratory protection CE-approved gas respirator ( Filter type B/P2). - Skin protection Corrosion -proof protective clothing. - Hand protection Suitable material for safety gloves (EN 374): The suitability of the gloves and the breakthrough time for a specific workplace should be discussed with the producers of the protective gloves. - material : Nitril rubber - thickness : 0,35 mm - breakthrough time : > 480' - Eye/Face protection Closed safety glasses or face shield. Environmental exposure controls See sections 6, 7, 12 and 13. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page :5/10 Revision : 14/3/2019 Revision nr : 9 SODIUM HYDROXIDE 5-51% SECTION 9. Physical and chemical properties 9.1. Information on basic nhvsical and chemical orooerties See technical data sheet for detailed information Physical State (20°C) Liquid . Form/Colour Clear, Colourless . Odour Odourless . Odour threshold Not applicable. pH value : > 14 Melting/Freezing point -17 °C (10%) 12 °C (50%) Boiling Point/Range (1013 hPa) 111 - 145 °C (25-50%) Flash point Not applicable. Fire hazard Not applicable. Evaporation rate No data available. Explosion limits in air Not applicable. Vapour pressure (20°C) : 0,1 -1,4 kPa (10-50%) Relative vapour density (air=1) No data available. Relative density of saturated vapour/air No data available. mixture (air=1) Relative density (water=1) Density (20°C) Solubility in water Soluble in Log P Octanol/Water (20°C) Auto -ignition temperature Minimum ignition energy Decomposition temperature Viscosity (20°C) Explosive properties Oxidizing properties Supersedes : 16/1/2017 Code : 16124 1,3-1,5 (25-50%) 1,0538 - 1,525 kg/I (5-50%) Complete solubility . Ethanol , Methanol , Glycerol . Inorganic Not applicable. Not applicable. No data available. 12 - 120 mPa.s (29-51 %) No chemical groups associated with explosive properties . No chemical groups associated with oxidizing properties . SECTION 10. Stability and reactivity 10.1. Reactivit Reactivity Reacts violently with: Halogenated hydrocarbons , Ammonium salts , Acids , Water Corrosive to metals. 10.2. Chemical stability Stability Stable at normal circumstances . 10.3. Possibility of hazardous reactions Hazardous reactions Exothermic reaction with: Water, Acids . Contact with metallic substances may release inflammable hydrogen gas. Reacts with Ammonium salts -> Creation of: Ammonia. Can react with sugar residues to form Carbon monoxide. 10.4. Conditions to avoid Conditions to avoid : Contact with water. 10.5. Incompatible materials BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 6/ 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 10. Stability and reactivity (continued) Materials to avoid Halogenated hydrocarbons, Ammonium salts , Acids, Aluminium , Magnesium , Copper, Zinc, Wool , Lether, , Polyester. 10.6. Hazardous decomposition products Hazardous Decomposition Products : Ammonia , Hydrogen . SECTION 11. Toxicological information 11.1. Information on toxicoloaical effects Acute toxicity Inhalation Symptoms include: Sore throat , Cough , Shortness of breath . For harmful components : • Sodium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available. • Potassium hydroxide : LC50 (Rat, inhalation, 4 h) : No data available. Skin contact Symptoms include: Redness , Pain , Severe burns . For harmful components : • Sodium hydroxide : LD50 (Rabbit, dermal) : No data available. • Potassium hydroxide : LD50 (Rabbit, dermal) : No data available. Ingestion Symptoms include: Sore throat , Abdominal cramps , Vomiting , Diarrhea . For harmful components : • Sodium hydroxide : LD50 (Rat, oral) : No data available. • Potassium hydroxide : LD50 (Rat, oral) : 333 mg/kg ( OECD Guideline 425) Skin corrosion/irritation Causes severe burns. Skin contact can damage eczema. Serious eye damage/irritation Causes serious eye damage. May cause diminished visual capacity to complete blindness. Aspiration hazard Symptoms of lungoedema mostly reveal after a few hours, intensified by physical effort. The product may affect the upper and lower airways, causing infections and impaired lung function. Respiratory or skin sensitisation Not sensitive . Carcinogenicity Not listed as carcinogenic . Mutagenicity Not listed as mutagenic . Reproductive toxicity Not listed for reproductive toxicity . Specific target organ toxicity - single To human : Listed not for organ toxicity . exposure Specific target organ toxicity - repeated To human : Listed not for organ toxicity . exposure For animals : No effects known. SECTION 12. Ecological information 12.1. Toxicity Ecotoxicity For harmful components • Sodium hydroxide: LC50 (Fish, 96 h) : 35-189 mg/I • Sodium hydroxide : EC50 (Algae, 72 h) : No data available. • Sodium hydroxide: EC50 (Daphnia magna, 48 h) : 40,4 mg/I (Ceriodaphnia sp.) • Potassium hydroxide: LC50 (Fish, 96 h) : 80 mg/I (Gambusia affinis) (TLm (_ median tolerance limit) ) • Potassium hydroxide : EC50 (Algae, 72 h) : No data available. • Potassium hydroxide : EC50 (Daphnia magna, 48 h) : No data available. 12.2. Persistence and dearadability BRENNTAG BRENNTAGM MATERIAL SAFETY DATA SHEET Page :7/10 Revision : 14/3/2019 Revision nr : 9 SODIUM HYDROXIDE 5-51% SECTION 12. Ecological information (continued) Supersedes : 16/1/2017 Code : 16124 Persistence and degradability For harmful components : • Sodium hydroxide : Persistence and degradability : Inorganic . • Potassium hydroxide : Persistence and degradability : Inorganic. 12.3. Bioaccumulative potential Bioaccumulation For harmful components • Sodium hydroxide : Bioaccumulation : Bioaccumulation not expected . • Potassium hydroxide : Bioaccumulation : Not applicable. 12.4. Mobility in soil Mobility For harmful components • Sodium hydroxide : Mobility : High potential for mobility in soil. • Potassium hydroxide : Mobility: No data available. 12.5. Results of PBT and vPvB assessment Evaluation For harmful components • Sodium hydroxide: PBT/vPvB : No • Potassium hydroxide : PBT/vPvB : No 12.6. Other adverse effects Photochemical ozone creation potential No data available . Ozone depletion potential None . Endocrine disrupting potential No data available . Global warming potential No data available . SECTION 13. Disposal considerations 13.1. Waste treatment methods Waste from residues/Unused products The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products. European list of waste products XXXXXX - European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. See Decision 2001/118/EC. Removal contaminated packaging Packing is to be used exclusively for the packing of this product. After use, empty and close the packing very carefully. In case of returned packing, the empty packing can be offered back to the supplier. SECTION 14. Transport information 14.1. UN number UN Number 14.2. UN aroaer shiaaina name 1824 ADR/RID Name UN 1824 Sodium hydroxide solution, 8, II, (E) ADN Name UN 1824 Sodium hydroxide solution , 8, II IMDG Name UN 1824 Sodium hydroxide, solution , 8, II IATA Name UN 1824 Sodium hydroxide, solution , 8, II 14.3. Transport hazard classelsl Class : 8 14.4. Packing group BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 8/ 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 14. Transport information (continued) Packaging Group 14.5. Environmental hazards Environmentally hazard No Marine pollutant No 14.6. Special precautions for user Danger number 80 Hazard Label(s) 8 EmS-N° F-A S-B 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Type ship Pollution category No data available. No data available. SECTION 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Inventories Australian inventory (AICS): Listed in inventory. Canadian inventory (DSL): Listed in inventory. Chinese inventory (IECS): Listed in inventory. European inventory (EINECS): Listed in inventory. Korean inventory (KECI): Listed in inventory. Philippine inventory (PICCS): Listed in inventory. Inventory of the United States (TSCA): Listed in inventory. NFPA n° : 3-0-1 Relevant EU Rule(s) Directive 98/24/EC of the Council of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work Decision 2001/118/EC of the Commission of 16 January 2001 amending Decision 2000/532/EC as regards the list of wastes Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/ 2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (Reach) The restrictions in Annex XVII to Regulation (EC) No 1907/2006 must be observed. National regulations - Germany WGK : 1 - Netherlands Water damaging : C Decontamination exertion : 2 15.2. Chemical Safety Assessment A chemical safety assessment has been carried out for the material. SECTION 16. Other information This safety data sheet has been drawn up in accordance with Regulation (EC) No 1907/2006. This safety data sheet is exclusively made for industrial/professional use. * Has changed compared to previous revision. BRENNTAG BRENNTAGM MATERIAL SAFETY DATA Page 9/ 10 SHEET Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 SODIUM HYDROXIDE 5-51% Code : 16124 SECTION 16. Other information (continued) * Changes Section 5 . Sources of used key data The information contained herein is based on the present state of our knowledge Producer(s) ) Chemical cards , ...) See also on the webaddress: http://apps.echa.europa.eu/registered/registered-sub.aspx#search (EU)H-statement(s) H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage. Classification procedure Met. Corr. 1; H290 - Based on test data (producer of component) Skin Corr. 1A; H314 - Additivity method Eye Dam. 1; H318 - Additivity method List of abbrevations and acronyms ACGIH : American Conference of Governmental Industrial Hygienists Acute Tox. 4, oral : Acute toxicity, oral - Category 4 ADN (Accord europeen relatif au transport international des marchandises Dangereuses par voie de Navigation interieur) : European agreement concerning the international carriage of dangerous goods by inland waterways ADR (Accord europeen relatif au transport international des marchandises Dangereuses par Route) : European agreement concerning the international carriage of dangerous goods by road DNEL (Derived No Effect Level) : an estimated safe exposure level EC50 : median Effective Concentration EmS (Emergency Schedule) : the first code refers to the relevant fire schedule and the second code refers to the relevant spillage schedule Eye Dam. 1 : Serious eye damage - Category 1 IARC (International Agency for Research on Cancer) IATA (International Air Transport Association) : provisions concerning the international carriage of dangerous goods by air IMDG (International Maritime Dangerous Goods code) LC50 : median Lethal Concentration LD50 : median Lethal Dose MR (Molar Ratio) Met. Corr. 1 : Corrosive to metals - Category 1 NFPA (National Fire Protection Association) or fire diamant NOEC (No Observed Effect Concentration) NVIC : National Poisoning Information Center OECD : Organisation for Economic Cooperation and Development PBT : persistent, bioaccumulative and toxic PNEC (Predicted No Effect Concentration) : concentration below which exposure to a substance is not expected to cause adverse effects REACH : Registration, Evaluation, Authorisation and restriction of Chemicals RID (Reglement concernant le transport International ferroviaire des marchandises Dangereuses) : Regulation concerning the International carriage of Dangerous goods by rail SCL (Specific Concentration Limits) Skin Corr. 1A : Skin corrosion - Category 1A TLm : median tolerance limit TWA (Time -Weighted Average) : the average exposure over a specified period WGK (Wassergefahrdungsklasse) : a German classification of substances that indicate the environmental hazard for surface water vPvB : very persistent and very bioaccumulative This information is to our knowledge correct and complete on the date of issue of this safety data sheet. The information only concerns the product and does not give any guarantee for the quality and the completeness of the properties of the product, or in case of mixing or using in any other process. It remains the responsibility of the user to assure himself that the information is suitable and complete concerning the special use he makes of the product. BRENNTAG denies all responsibility for loss or damage resulting from the use of these data. BRENNTAG 8 R E N N TAG � MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 5-51% BRENNTAG Page: 10/10 Revision : 14/3/2019 Revision nr : 9 Supersedes : 16/1/2017 Code : 16124 End of document