Loading...
HomeMy WebLinkAboutNC0089915_Chemours Comments of Preliminary Draft Permit_20200501STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES DRAFT NPDES PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM hi compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, The Chemours Company FC, LLC is hereby authorized to discharge treated surface water and stormwater from a facility located at Chemours Company- Fayetteville Works 22828 NC Highway 87 W Fayetteville Bladen County to receiving waters designated as the Cape Fear River in the Cape Fear River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. The permit shall become effective Month DD, 20YY. This permit and the authorization to discharge shall expire at midnight on Month DD, 20YY. Signed this day Month DD, 20YY. DRAFT S. Daniel Smith, Director Division of Water Resources By Authority of the Environmental Management Commission Permit NCO089915 SUPPLEMENT TO PERMIT COVER SHEET The exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. The Chemours Company FC, LLC is hereby authorized to: Operate wastewater treatment facilities consisting of: • influent oxidation, coagulation, and pH adjustment tank; • dual booster pumps; • dual_ultrafiltration units; • three granular activated carbon (GAC)#asorqpt%,oW; • sludge pump; 1\ • polymer make down/injection system; • in -line mixer and thickener unit; • rotary fan press skid; • return filtrate pump'd6' NO Discharge treated surface ter groundwaW through Outfall 003 at the location specified on the attached map the Cape ear River, class C, WS-IV water in the Cape Page 2 of 12 Permit NCO089915 Part I A. (L) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS— OUTFALL 003 [15A NCAC 02B .0400 et seq., 02B .0500 et seq.] Facility Physical -Chemical Grade H Beginning on the effective date of this permit and lasting through the expiration date, the Permittee is authorized to discharge from OutfaH 003 (treated groundwater and surface water) Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS PARAMETER CHARACTERISTICS MonthlyAverage [DailyMai.. Measurement Sample Sample' quency Type Location Flow 50050 1.58 MGD F Continuous Recording Effluent 40, Recording Total Monthly Flow 82220 Monitor and Report (M o) Monthly or Effluent Calculation Effluent, Temperature (°C) 00010 See Note 2 Weekly Grab Upstream, Downstream ` BOD,5-day, 20°C C0310 30.0,mg/L 45.0 mg/L eekl Co site ------ Effluent --------- TSS C0530 30.0 mg/L 45.0 mg/L Weekly Composite Effluent Dissolved Oxygen, mg/L 00300 Weekly Grab Upstream, Adnhb Downstream ,MIN= HFPO-DA (GenX)4 52612 NEW 0.06 Ng/L�_ - - 0.06 Ng /L Weekli _Grab Influent, Effluent HFPO-DA (GenX)4 ??77 Monitor and Report (Ib/mo) Monthly Calculation Effluent HFPO-DA4GenX}4 2722 Mon for and Report (Ib/yr) Annually Calculation Effluent PFMOAA4 52613 0.85 Ng/L 0.85 Ng/L Weekly Grab Influent, Effluent PFMOAA4 ???? Monitor and Report (lb/mo) Monthly Calculation Effluent PFMOAA4 ???? Monitor and Report(lb/yr) Annually Calculation Effluent PFAS compounds, ng/LNI See A. (5.) Grab See A. (5.) Total Phosphorus, mg/L C0665 Monthly Composite Effluent Total Nitrogen, mg/L C0600 Monthly Composite Effluent (NO2+NO3+TKN) Conductivity 00094 Monthly Grab Upstream, Downstream Chronic Toxicity TGP3B See Note 5 Quarterly} Composite Effluent pH 00400 Between 6.0 and 9.0 Standard Units 3/Week Grab Effluent Mercury (Method 1631 E), COMER ng/L 47.0 ng/L 6 Quarterly Grab Effluent Page 3 of 12 Commented [RJB1 ]: Temperature will not change significantly on a daily basis in the river or outfa11003. Also this water will not be used for cooling. Chemours request weekly sampling Commented [CH2R1I: Commented [RJB3]: The influent characterization indicates that the BOD5 concentration is < 2mg/L which is significantly below the monthly average and daily max permit limitations. Commented [RJB4]: Chemours requests only a monthly limit for BFPO-DA and PFMOAA. The avg and max limits are the same. This could lead to two � permit exceedances instead of one since the limitations are the same. In addition, the calculations presented below for percent removal are only for monthly average. Commented [RJB5]: Chemours request that the sampling frequency be once per month for HFPO-DA and PFMOAA. In addition to these samples Chemours will be sampling the outfall for process control using our inhouse lab to assure compliance Permit NCO089915 PARAMETER CHARACTERISTICS EFFLUENT LIMITS MONITORING REQUIREMENTS Monthly Average [DailyMaximum Measurement Frequency Sample Type Sample' Location Total Selenium 01147 40.0 Ng/L 379.8 Ng/L _ _ _ Monthly Composite _ Effluent Total Silver 01077 0.48 Ng/U 2.01 Ng/Ls Monthly Composite Effluent Total Cobalt 01037 23.9 Ng/L 23.9 Ng/Ls Monthly Composite Effluent Total Cadmium, Ng/L 01027 Quarterly Composite Effluent Total Copper, Ng/L 01042 uarterly Composite Effluent Total Cyanide, Ng/L 00720 Quarterly Composite Effluent Total Lead, Ng/L 01051 Quarterly Composite Effluent Total Thallium, Ng/L 01059 Quarter) Composite Effluent Total Hardness [as CaCO3] 00900 (mg/L) Quarterly mposite Effluent - - Formatted: Superscript ..Notes: 1. Definitions a,. Upstream monitoring shall!bthe Chemo a e Fear rRiver Water Intake �Formatted station;bdDownstream shall be at tramp approximately 4500 downstream at Prospect Hall Landing. a-c. Influent— influent to the Oater treat ent system. ote the outfall 003 concentration limitations do not apply to the influent. Influent sampling is required to calculate the HFPO-DA and PFMOAA percent removal. b d. Effluent — Outfall 0 uent m the Old utfa11002 water treatment system). As a participant in the Middle Cape ver Basin sociation, the instream monitoring requirements for conventional parameters -(DO, Temperature, and conductivity) as stated above are waived. Should your membership in the agreement be terminated, you shall notify the Division immediately and the instream monitoring requirements specified in your permit shall be reinstated. 2. The temperature of the effluent shall be such as not to cause an increase in the temperature of the receiving stream of more than 2.8°C and in no case cause the ambient water temperature to exceed 32°C. 3. Daily shall be defined as every day except Saturdays, Sundays, and legal holidays. Instream temperature sampling shall be conducted weekly. 4. The Permittee shall remove indicator parameters HFPO-DA and PFMOAA at an efficiency of 99% as required by the Consent Order in order to maximally reduce PEAS loading to the Cape Fear River. The effluent limits listed above are Technology Based Effluent Limits ("TBELs") calculated to ensure a minimum of 99% removal efficiency. In addition to complying with these effluent limits the Permittee must demonstrate compliance with the 99% removal efficiency requirement by calculating monthly removal efficiency for HFPO-DA and PFMOAA pursuant to condition A.6 {I��-If the influent HFPO-DA or PFMOAA concentrations to the water treatment system are equal to or less than 200 ng/L and 500 ng/l, respectively then water treatment system effluent concentrations of less than the reporting limits (2 ng/L and 5 ng/L respectively) shall be considered as achieving 99% removal..Also the Permittee may request revision of the 99% removal efficiency requirement upon a demonstration that influent concentrations of-HFPO-DA and PFMOAA PEAS have been reduced to such a level that 99% removal is no longer Page 4 of 12 Permit NCO089915 technically feasible. 0--ever, notwithstanding any such revision, Chemours shall continue to operate the Treatment - - System at optimal efficiency. 5 Chronic Toxicity (Ceriodaphnia) P/F @ 9% %; semiannually-quatterly during January to June and July to December Fobfuary, May, August, Novef be ., see condition A. (2.) of this permit. 6For the compounds mercury, selenium, silver and cobalt Chemours shall: After 12 months of sampling the facility can apply for a reduction in sampling if all the sampling results demonstrate concentration below detections level. The facility shall be employing the sufficiently sensitive test method. 3This is an Annual Average limit, based on a calendar year. 3 4. Silver PQL = 1.0 ug/L THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS The facility shall develop a Dam (collection system maximum dry weather flow (up to 61C gpm) in the efforts should be applied at the sumps/dams or other seeps. OTHER THAN TRACE AMOUNTS. on and Maintenance Plan (Plan) to ensure is consistently captured and treated. Similar s that jy&be used to capture water from the The Plan should be provided to the DEQ within 30 days of the permit issuance for review and approval. Upon approval, the Plan becomes an integral part of the permit. The facility shall complete and submit EPA Form 2C for this Outfall within 180 days of commencement of the discharge. qF- -,4% %ff -qv A. (2.) CHRONIC TOXIC PE T LIMITNinhi UARTERLY) — OUTFALL 003 [15A NCAC 02B.0200] The effluent discharge shall at no time exhrt observabletionof reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 9123%. The permit holder shall perform at a minimum, erl monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," (Revised December 2010, or subsequent versions) or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised December 2010, or subsequent versions). The tests will be performed during the months of February, May, August, and November. These months signify the first month of each three-month toxicity testing quarter assigned to the facility. Effluent sampling for this testing must be obtained during representative effluent discharge and shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -December 2010, or subsequent versions). All toxicity testing results required as part of this permit condition will be entered electronically using the Division's eDMR system for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and TIIP3B for the Chronic Value. Additionally, DWR Form AT-3 (original) is to be sent to the following address: Page 5 of 12 Commented [RJB6]: Chemours has concerns that when the "influent concentration" of PFAS have been reduced to such a level that 99% removal cannot be accurately calculated leading to permit exceedances that would occur before the permit would be modified. Also, the potential exists for stormwater to dilute the influent concentrations to below 200 ng/L HFPO-DA and 500 ng/L PFMOAA such that 99% removal cannot be attained if the % reporting limit is used in the calculation to determine 99% removal. Chemours proposes additional language noted above Formatted: No bullets or numberina Formatted: Indent: Left: 0.56", No bullets or numbering Permit NCO089915 North Carolina Division of Water Resources Water Sciences Section/Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Or, results can be sent to the email, ATForms.ATBAncdenr.gov- Completed Aquatic Toxicity Test Forms shall be filed with the Water Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Idw Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Water S ences Section at the address cited above. Should the permittee fail to monitor during onth in which oxicity monitoring is requ onitoring will be required during the following month. Asse ent of toxicity compliance is based on the toxicity testing quarter, which is the three-month time interval that begins on the first day of the month in which toxicity testing is required by this permit and continues until the final day of the third month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Resources indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements limits. NOTE: Failure to achieve test conditions as specified in t Lecited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A. (3.) RE-OpA NER CONDITION [NCGS 143-215.3 (a) (2) and NCGS 143-215.66] This permit shall be modified, or revoked and reissued to incorporate additional limitations and monitoring requirements in the event toxicity testing or other studies indicate that detrimental effects may be expected as a result of this discharge. A. (4.) ELECTRONIC REPORTING OF MONITORING REPORTS [G.S. 143-2151(b)] Federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and program reports. The final NPDES Electronic Reporting Rule was adopted and became effective on December 21, 2015. NOTE: This special condition supplements or supersedes the following sections within Part H of this permit (Standard Conditions for NPDES Permits): Page 6 of 12 Permit NC0089915 • Section B. (11.) Signatory Requirements • Section D. (2.) Reporting • Section D. (6.) Records Retention • Section E. (5.) Monitoring Reports 1. Reporting Requirements [Supersedes Section D. (2.) and Section E. (5.) (a)1 The permittee shall report discharge monitoring data electronically using the NC DWR's Electronic Discharge Monitoring Report (eDMR) internet application. Monitoring results obtained during the previous month(s) shall be summarized for each month and submitted electronically using eDMR. The eDMR system allows permitted facilities to enter monitoring data and submit DMRs electronically using the internet. Until such time that the state's eDMR application is compliant with EPA's Cross -Media Electronic Reporting Regulation (CROMERR), permittees will be required to submit all discharge monitoring data to the state electronically using eDMR and will be required to complete the eDMR submission by printing, signing, and submitting one ed original and a c of the computer printed eDMR to the following address: NC DEQ / Division of Water Resources / Water Quality Permitting Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 If a permittee is unable to use the eDMR system due to a demonstrated hardship or due to the facility being physically located in an area where less than 10 percent of the households have broadband access, then a temporary waiver from the NPDES electronic reporting requirements may be granted and discharge monitoring data may be submitted on paper DMR forms (MR 1, 1. 1, 2, 3) or alternative forms approved by the Director. Duplicate signed copies shall be submitted to the mailing address above. See "How to Request a Waiver from Electronic Reporting" section below. Regardless of the submission method, the first DMR is du n the last day of the month following the issuance of the permit or in the case of a new facility, on the last day of the month following the commencement of discharge. Starting on ber 21, 2020, the permittee must electronically report the following compliance monitoring data and reportk applicable: • Sewer Overflow/Bypass Event Reports; (This does not include the flow of waters over the dam of OOF2 drainage waters fi.... _sue to wet weather events causing OOF2 drainage flow rates to be above dry weather flows • Pretreatment Program Anal Reports; and • Clean Water Act (CWA) Section 316(b) Annual Reports. The permittee may seek an electronic reporting waiver from the Division (see "How to Request a Waiver from Electronic Reporting" section below). 2. Electronic Submissions Page 7 of 12 Permit NC0089915 In accordance with 40 CFR 122.41(1)(9), the permittee must identify the initial recipient at the time of each electronic submission. The permittee should use the EPA's website resources to identify the initial recipient for the electronic submission. Initial recipient of electronic NPDES information from NPDES-regulated facilities means the entity (EPA or the state authorized by EPA to implement the NPDES program) that is the designated entity for receiving electronic NPDES data [see 40 CFR 1272(b)]. EPA plans to establish a website that will also link to the appropriate electronic reporting tool for each type of electronic submission and for each state. Instructions on how to access and use the appropriate electronic reporting tool will be available as well. Information on EPA's NPDES Electronic Reporting Rule is found at: https://www.federalre ig ster.gov/documents/2015/10/22/2015-24954/national-pollutant-discharge-elimination- system-npdes-electronic-reporting-rule Electronic submissions must start by the dates listed in the "Reporting Re uirements" section above. 3. How to Request a Waiver from Electronic Reportlne The permittee may seek a temporary electronic rep ing waiver fr9p the Divi To obtain an electronic reporting waiver, a permittee must first submit an electronic reporting waiver reques a Division. Requests for temporary electronic reporting waiust be submitted in writing to the Divisio written approval at least sixty (60) days prior to the date -le facility would be required under this permit to begin submitting monitoring data and reports. The duration of a temporary waiver shall not exceed 5 years and shall thereupon expire. At such time, monitoring data and reports shall be submitted electronically to the Division unless the permittee re -applies for and is granted a new temporary electronic reporting waiver by the Division. Approved electronic reporting waivers are not transferrable. Only permittees with an approved reporting waiver request may submit monitoring data and reports on paper to the Division for the period that the approved reporting waiver request is effectivAndt Information on eDMR app Leation for a temporary electronic reporting waiver are found on the followine web Mae: 4. All eDMRs submitted to the permit issuing authority shall be signed by a person described in Part II, Section B. (I1.)(a) or by a duly authorizedirepresentative of that person as described in Part II, Section B. (I1.)(b). A person, and not a position, must be delegated signatory authority for eMm reporting purposes. For eDMR submissions, the person signing and submitting the DMR must obtain an eMm user account and login credentials to access the eDMR system. For more information on North Carolina's eDMR system, registering for eDMR and obtaining an eDMR user account, please visit the following web page: http://deg.nc.gov/about/divisions/water-resources/edmr Certification. Any person submitting an electronic DMR using the state's eDMR system shall make the following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE ACCEPTED: V certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that quaked personnel properly gather and Page 8 of 12 Permit NCO089915 evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. " 5. Records Retention [Supplements Section D. (6.)] The permittee shall retain records of all Discharge Monitoring Reports, including eDMR submissions. These records or copies shall be maintained for a period of at least 3 years from the date of the report. This period may be extended by request of the Director at any time [40 CFR 122.41]. �A. (5.) PFAS MONITORING REQUREMENTS, ANALYTICAL METHODS AND ASSOCIATED REPORTING LIMITS [NCGS 143-215.3 (a) (2) and NCGS 143-215.661- - - - - - - - *N- - - - - - - - - - - - - - - - - - - - - - - Commented [CH7]: Please include analytical method reporting limits in tables below for each compound The permittee shall monitor for PEAS compounds at the monitoring equencies described below. The lists of compounds follow. Note that not all required compounds have eDMR parameter codes. Those with parameter codes should be reported using the applicable codes, and all other results for PEAS compounds should be reported in the comment section of the eDMR or added as supplemental information. In addition, a complete copy of all PEAS samplingdesults shall be submitted to NPDES Permitting via email at svc deq Lipdes-ec e,ncdenr.gov, with the Facility permit number and name in the Subject heading. Chemours shall use the following analytic'Uhmelk6with thel&kwing reporting limit for the PFAS compounds. OEQ Approved Table 3+ SOPS date SOPS were approved by DE EPA Method 537 Modified , - Commented [CH8]• Please specify analytical methods and include in the table below the associated reporting limits for each compound oc Monitoring ations and Fre encv LocatiMi Compounxslqw Frequency Upstrear fthe Chemour e Fear River Intake Table 3+ Lab SOP Monthly Full Suite (Table 3+ Lab SOP and EPA Method 537 Mod) Quarterly Influent to the Tr nt Syste Table 3+ Lab SOP Monthly ull suite (Table 3+ Lab SOP and EPA Method 537 Mod) Quarterly Outfall 003 (effluent fr Treatment System) Table 3+ Lab SOP Monthly Full suite (Table 3+ Lab SOP and EPA Method 537 Mod) Quarterly Downstream The boat ramp approximately 4500 feet downstream at Prospect Hall Landing. Table 3+ Lab SOP Monthly Full Suite (Table 3+ Lab SOP and EPA Method 537 Mod) Quarterly PFAS Compounds: Full Suite = Table 3+ Lab SOP + 1 Method 537 Modified Compounds: Page 9 of 12 Permit NCO089915 Analytical Method Common Name Chemical Name CASN Chemical Formula Parameter code HFPO-DA Hexafluoropropylene oxide dimer acid 13252-13-6 C611F1103 52612 PEPA Perlfuoroethoxypropyl carboxylic acid 26729-61-2 C51IF903 52618 PFECA-G Perfluoro-4-isopropoxybutanoic acid 801212-59-9 C12H9F903S 52619 PFMOAA Perfluoro-2-methoxyacetic acid 674-13-5 C31IF503 52613 PF02HxA Perfluoro(3,5-dioxahexanoic) acid 39492-88-1 C41IF704 52617 PF030A Perfluoro(3,5,7-trioxaoctanoic) acid 39492-89-2 C51IF905 52616 PF04DA Perfluoro(3,5,7,9- tetraoxadecanoic) acid 39492-90-5 C611F1106 52615 PUPA Perfluoromethoxypr carboxylic acid 13140-29-9 C41IF703 52620 Table 3+ Lab SOP Hydro -EVE Acid Perfluoroethoxypropanoic acid 773804-62-9 lak C8112F1404 52621 EVE Acid Perfluoroethoxypropionic acid 69087-46-3 C811F1304 52622 PFECA-B Perfluo r-3,6-dioxahepanoic acid 151772-58-6 C51IF904 52626 R-EVE R-EVE N/A C8112F1205 52640 PF05DA Perfluoro-3,5,7,9,1 I - pentaoxadodecanoic acid 39492 91-6 C71IF1307 52627 Byproduct 4 Byproduct 4 N/A C7112F 1206S 52643 Byproduct 5 Byproduct 5 N/A C7113F1107S 52644 Byproduct 6 Byproduct 6 N/A C6112F 1204S 52645 NVHOS Perfluoroethoxysulfonic acid 1132933-86- 86-8 C4112F804S 52628 PES Perfluoroethoxyethanesulfonic acid 113507-82-7 C41IF904S 52629 PFESA-BPI Byproduct 1 29311-67-9 C71IF1305S 52630 PFESA-BP2 Byproduct 749836-20-2 C7112F1405S 52614 PFBA Perfluorobutan is acid 375-22-4 C41IF702 51522 PFDA Perfluorodecanoic acid 335-76-2 C10HF1902 51627 PFDoA Perfluorododecanoic acid 307-55-1 C121IF2302 51629 PFHpA Perfluoroheptanoic acid 375-85-9 C71IF1302 51625 PFNA Perfluor000nanoic acid 375-95-1 C91IF1702 51626 PFOA Perfluorooctanoic acid 335-67-1 C81IF150 51521 EPA PFHxA Perfluorohexanoic acid 307-24-4 C611F1102 51624 PFPeA Perfluoropentanoic acid 2706-90-3 C51IF902 51623 Method PFTeA Perfluorotetradecanoic acid 376-06-7 C141IF2702 51531 537 Mod PFTriA Perfluorotridecanoic acid 72629-94-8 C131IF2502 51630 PFUnA Perfluoroundecanoic acid 2058-94-8 C111IF2102 51628 PFBS Perfluorobutanesulfonic acid 375-73-5 C41IF9SO 52602 PFDS Perfluorodecanesulfonic acid 335-77-3 C101IF2103S 52603 PFHpS Perfluoroheptanesulfonic acid 375-92-8 C71IF1503S 52604 PFHxS Perfluorohexanesulfonic acid 355-46-4 C61IF13SO3 52605 PFNS Perfluorononanesulfonic acid 68259-12-1 C91IF1903S 52611 Page 10 of 12 Permit NCO089915 PFOS Perfluorooctanesulfonic acid 1763-23-1 C81IF17SO3 52606 PFPeS Perfluoropentanesulfonic acid 2706-91-4 C511F1103S 52610 10:2 FTS 10:2 fluorotelomersulfonic acid 120226-60-0 C12145F2103 52631 4:2 FTS 4:2 fluorotelomersulfonic acid 757124-72-4 C6145F903S 52607 6:2 FTS 6:2 fluorotelomersulfonic acid 27619-97-2 C8H5F13S03 52608 8:2 FTS 8:2 fluorotelomersulfonic acid 39108-34-4 C10145F1703S 52609 NEtFOSAA NEtFOSAA 2991-50-6 C12H8F17N04S 51643 NEtPFOSA NEtPFOSA 4151-50-2 CI0H6F17NO2S 52642 NEtPFOSAE NEtPFOSAE 1691-99-2 C121410F17NO3S 51641 NMeFOSAA NMeFOSAA 2355-31-9 C11146F17N04S 51644 NMePFOSA NMePFOSA 31506-32-8 C9144F17NO2S 52641 NMePFOSAE NMePFOSAE 24448-09-7 C11H8F17NO3S 51642 PFDOS Perfluorododecanesulfonic acid 79780-39-5 C121IF2503S 52632 PFHxDA Perfluorohexadecanoic acid 67905-19-5 C161IF3102 52633 PFODA Perfluorooctadecanoic acid 16517-11-6 754-91-6 C181IF3502 C8H2F17NO2S 52634 51525 PFOSA Perfluorooctanesulfon 0 F-53B Major F-53B Major 73606-19-6 C8HCIF1604S 52638 F-53B Minor F-53B Minor jjW 83329-89-9 CIOHCIF2004S 52639 ADONA 4,8-dioxa-3H- perfluorononanoate 958445-44-81N C7142F1204 52635 NaDONA Sodium 4,8-dioxa-3H- perfluornonanoate S1361 (NOCAS_8924 52) C7HF12Na04 52637 DONA 4,8-Dioxa-3H-perfluorononanoic acid 919005-14-4 C7112F1204 52636 A. (6.) CALCULATION OF HFPO-DA & P OAA REMOVAL/LOADS a. The Pennittee shall calculate monthly removal efficiency for HFPO-DA and PFMOAA as follows: %Removal = Influent —Effluent Influent Where: Influent = mon y average in uent concentration Effluent = monthly average effluent concentration b. The Permittee shall calculate onthly load for HFPO-DA and PFMOAA as follows: Monthly C Load = C x TMF x 8.34 Where: C = monthly average concentration for each compound (mg/L) TMF = Total Monthly Flow of wastewater discharged during the month (MG/month) 8.34 = conversion factor from (mg/L x MG) to pounds Annual C Load = Sum of the 12 Monthly Loads for each compound for the calendar year Page 11 of 12 Permit NC0089915 c. The Permittee shall report monthly HFPO-DA and PFMOAA results [% removal (ng/L), and Loading (pounds/month)] in the discharge monitoring report for each month and shall report each calendar year's Annual Load (pounds/year) with the December report for that year. Percent removal shall be listed in the comment section of the eDMM since it has no parameter code. In addition, calculations shall be submitted electronically with all PFAS data to NPDES Permitting via email at svc deq ppdes-ec@ncdenr.gov, with the Facility permit number and name in the Subject heading. Page 12 of 12