HomeMy WebLinkAboutNC0089915_Draft Permit_20200101 (4)STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
DRAFT NPDES PERMIT
TO DISCHARGE WASTEWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards
and regulations promulgated and adopted by the North Carolina Environmental Management
Commission, and the Federal Water Pollution Control Act, as amended,
The Chemours Company FC, LLC
is hereby authorized to discharge treated wastewater and stormwater from a facility located at
Chemours Company- Fayetteville Works
22828 NC Highway 87 W
Fayetteville
Bladen County
to receiving waters designated as the Cape Fear River in the Cape Fear River Basin in accordance with
effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV
hereof.
The permit shall become effective Month DD, 20YY.
This permit and the authorization to discharge shall expire at midnight on Month DD, 20YY.
Signed this day Month DD, 20YY.
DRAFT
S. Daniel Smith, Director
Division of Water Resources
By Authority of the Environmental Management Commission
Permit NCO089915
SUPPLEMENT TO PERMIT COVER SHEET
The exclusive authority to operate and discharge from this facility arises under the permit conditions,
requirements, terms, and provisions included herein.
is hereby authorized to:
1
2
The Chemours Company FC, LLC
Operate a 1.58 MGD wastewater treatment faciliti
• influent oxidation, coagulation, and pH adj
• dual booster pumps;
• dual ultrafiltration units;
• three granular activated carbon (GAC)+asorp
• sludge pump;
• polymer make down/injection system;
• in -line mixer and thickener unit;
• rotary fan press skid; '*4
• return filtrate pump;*4,
of
Discharge treated surface water, treated filter backwash, stormwater, and groundwater,
including groundwater fromlie existing Black Creek Aquifer monitoring wells, through
Outfall 003 at the location specified on the attached map into the Cape Fear River, a class
C, WS-IV water in the Cape Fear River Basin; 1%
/F
Page 2of12
Permit NCO089915
Part I
A. (I.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS — OUTFALL 003
[15A NCAC 02B .0400 et seq., 02B .0500 et seq.] Facility Physical -Chemical Grade II
Beginning on the effective date of this permit and lasting through the expiration date, the Permittee is authorized to
discharge from Outfall 003 (treated surface water, groundwater, and stormwater) Such discharges shall be
limited and monitored by the Permittee as specified below:
PARAMETER CHARACTERISTICS
EFFLUENT LIMITS
MONITORING REQUIREMENTS
Monthly Average
Daily Maximum
Measurement
Frequency
Sample
Type
Sample
Location'
Flow 50050
1.58 MGD
Continuous
Recording
Effluent
Total Monthly Flow 82220
Monitor and Report (MG/mo)
Monthly
Recording
or
Calculation
Effluent
Temperature (°C) 00010
See Note 2
Weekly
Grab
Effluent,
Upstream,
Downstream
BOD, 5-day, 20°C C0310
30.0 mg/L
45.0 mg/L
Monthly
Composite
Effluent
TSS C0530
30.0 mg/L
45.0 mg/L
Monthly
Composite
Effluent
Dissolved Oxygen, mg/L 00300
Weekly
Grab
Upstream,
Downstream
PMPA3,4
0.054 pg/L 0.054 pg /L
Monitor and Report (lb/mo)
Twice per month
Monthly
Grab
Calculation
Influent, Effluent
Effluent
PMPA3,4
PMPA3,4
Monitor and Report (Ib/yr)
Annually
Calculation
Effluent
HFPO-DA4 52612
0.06 pg/L
0.06 pg /L
Twice per month
Grab
Influent, Effluent
HFPO-DA4
Monitor and Report (Ib/mo)
Monthly
Calculation
Effluent
HFPO-DA4
Monitor and Report (lb/yr)
Annually
Calculation
Effluent
PFMOAA4 52613
0.85 pg/L
0.85 pg/L
Twice per month
Grab
Influent, Effluent
PFMOAA4
Monitor and Report (Ib/mo)
Monthly
Calculation
Effluent
PFMOAA4
Monitor and Report (Ib/yr)
Annually
Calculation
Effluent
PFAS compounds, ng/L
See A. (5.)
Grab
See A. (5.)
Total Phosphorus, mg/L C0665
Monthly
Composite
Effluent
Total Nitrogen, mg/L C0600
(NO2+NO3+TKN)
Monthly
Composite
Effluent
Conductivity 00094
Monthly
Grab
Upstream,
Downstream
Page 3 of 12
Permit NCO089915
PARAMETER CHARACTERISTICS
EFFLUENT LIMITS
MONITORING REQUIREMENTS
Monthly Average
Daily Maximum
Measurement
Frequency
Sample
Type
Sample
Location,
Chronic Toxicity TGP3B
See Note 5
Quarterly
Composite
Effluent
pH 00400
Between 6.0 and 9.0 Standard Units
Weekly
Grab
Effluent
Mercury (Method 1631E), COMER
ng/L
Quarterly
Grab
Effluent
Total Selenium 01147
Quarterly
Composite
Effluent
Total Silver? 01077
0.48 Hg/1-6
2.01 Hg/L
Monthly
Composite
Effluent
Total Cobalfl 01037
23.9 Hg/L
23.9 Hg/L
Monthly
Composite
Effluent
Total Cadmium, Ng/L 01027
Quarterly
Composite
Effluent
Total Copper, Ng/L 01042
Quarterly
Composite
Effluent
Total Cyanide, Ng/L 00720
Quarterly
Composite
Effluent
Total Lead, Ng/L 01051
Quarterly
Composite
Effluent
Total Thallium, Ng/L 01059
Quarterly
Composite
Effluent
Total Hardness [as CaCO3] 00900
(mg/L)
Quarterly
Composite
Effluent
Notes:
1. Upstream monitoring shall be at the Permittee's Cape Fear River Wa r Intake; downstream shall be at the
boat ramp approximately 4500 feet downstream at Prospect Hall Landing.
As a participant in the Middle Cape Fear River Basin Association, the instream monitoring requirements for
conventional parameters (DO, temperature, and conductivity) as stated above are waived. Should your
membership in the agreement be terminated, you shall notify the Division immediately and the instream
monitoring requirements specified in your permit shall be reinstated.
Influent — influent to the Old Outfall 002 Wastewater Treatment System. Note the Outfall 003 concentration
limitations do not apply to the influent. Influent sampling is required to calculate the HFPO-DA and
PFMOAA percent removal.
Effluent — Outfall 003 (effluent from the Old Outfall 002 Wastewater Treatment System).
2. The temperature of the effluent shall be such as not to cause an increase in the temperature of the receiving
stream of more than 2.8°C and in no case cause the ambient water temperature to exceed 32°C.
3. The requirement for 99% removal at the treatment system for PMPA shall not become effective until Jan. 31,
2021. The monitoring and reporting requirements for PMPA are effective immediately.
4. The Permittee shall remove indicator parameters HFPO-DA, PFMOAA, and PMPA at an efficiency of 99% in
order to reduce PFAS loading to the Cape Fear River. The effluent limits listed above are Technology Based
Effluent Limits ("TBELs") calculated to ensure a minimum of 99% removal efficiency. In addition to
complying with these effluent limits the Permittee must demonstrate compliance with the 99% removal
efficiency requirement by calculating monthly removal efficiency for HFPO-DA, PFMOAA, and PMPA
pursuant to condition A. (6.). The Permittee may request revision of the 99% removal efficiency requirement
upon a demonstration that influent concentrations of PFAS have been reduced to such a level that 99% removal
is no longer technically feasible. However, notwithstanding any such revision, Chemours shall continue to
operate the Treatment System at optimal efficiency.
Page 4 of 12
Permit NCO089915
5. Chronic Toxicity (Ceriodaphnia) P/F @ 12.5%; quarterly during February, May, August, November; see
condition A. (2.) of this permit.
6. Sufficiently sensitive test methods shall be used to analyze for Silver. The Division shall consider all effluent
Silver values reported below the PQL to be in compliance with the Monthly Average Silver limit. As of the
effective date of this permit, DWR recommends a target PQL of 1.0 µg/L for Silver.
7. After 12 months of sampling the facility can apply for a reduction in sampling if all the sampling results
demonstrate concentrations below detection levels. The facility shall be employing the sufficiently sensitive
test methods.
THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS.
The facility shall develop a Dam (collection system) Operation and Maintenance Plan (Plan) to ensure
maximum dry weather flow (— 610 gpm) in the channel is consistently captured and treated. Similar efforts
shall be applied at the sumps/dams or other devices that will be used to capture water from the seeps.
The Plan shall be provided to the DEQ within 30 days of the permit issuance for review and approval.
Upon approval, the Plan becomes an integral part of the permit.
The facility shall complete and submit EPA Form 2C for this Outfall within 180 days of commencement of
the discharge.
From time -to -time the Middle Cape Fear River has experienced floodin conditions which documented to
cause a significant increase in water levels below Lock and Dam 43, consistent with the location of proposed
Outfall 003. During these events a backwater condition propagates upstream in the "Old Outfall 002
Stream". Historical observation indicates that the Old Outfall 002 Stream levels can rise significantly (consistent
with the flooded Cape Fear River levels) and would be expected, at times, to be equal to or significantly greater
than the invert elevation of the treatment system intake dam and associated pumping system. During these
flooded backwater conditions elevated sediment load and reduced flow velocity gradients are expected to cause
significant sediment deposition within the collection dam and pumping structure. The sediment load may cause
failure of the pumping and treatment system during the flooded backwater condition. Requirement for treatment
shall be suspended during these force majeure flooding events and be allowed 48 hours after the backwater stream
level falls below the invert of the intake collection dam to safely maintain the influent collection structure and re-
initiate collection and treatment. The triggering Cape Fear River flood elevations; event documentation and
notification requirements; and procedure fo eatment cessation and safe restart shall be included in the approved
Dam Operation and Maintenance Plan.Ak 1%
A. (2.) CHRO]
[I5ANCAC 02F
LIMIT P/F (QUARTERLY) — OUTFALL 003
The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to
Ceriodaphnia dubia at an effluent concentration of 12.5%.
The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North
Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," (Revised December 2010, or subsequent versions)
or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised December 2010, or
subsequent versions). The tests will be performed during the months of February, May, August, and
November. These months signify the first month of each three-month toxicity testing quarter assigned to the
facility. Effluent sampling for this testing must be obtained during representative effluent discharge and shall be
performed at the NPDES permitted final effluent discharge below all treatment processes.
Page 5 of 12
Permit NCO089915
If the test procedure performed as the first test of any single quarter results in a failure or ChV below the
permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two
following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test
Procedure" (Revised -December 2010, or subsequent versions).
All toxicity testing results required as part of this permit condition will be entered electronically using the
Division's eDMR system for the months in which tests were performed, using the parameter code TGP313 for the
pass/fail results and THP313 for the Chronic Value. Additionally, DWR Form AT-3 (original) is to be sent to the
following address:
North Carolina Division of Water Resources
Water Sciences Section/"ncdenrx
logy Branch
1621 Mail Service Cente
Raleigh, NC 27699-1621
Or, results can be sent to the email, ATForms.AT
Completed Aquatic Toxicity Test Forms shall be filed with the Water Sciences Section no later than 30 days after
the end of the reporting period for which the report is made.
Test data shall be complete, accurate, include all supporting chemical/physical measurements and all
concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature.
Total residual chlorine of the effluent toxic plc must be measured and reported if chlorine is employed for
disinfection of the waste stream.
Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required,
the permittee will complete the information located at the top of the aquatic to city (AT) test form indicating the
facility name, permit number, pipe number, county, and the month/year of the port with the notation of "No
Flow" in the comment are of the form. T report shall be submitted to the Water Sciences Section at the address
cited above.
Should the permittee fail to monitor during a month in whic toxicity monitoring is required, monitoring will be
required during the following month. Assessment of toxicity compliance is based on the toxicity testing quarter,
which is the three-month time interval that begins on the first day of the month in which toxicity testing is
required by this ermit and continues until the final day of the third month.
Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water
Resources indicate potential impacts to the receiving stream, this permit may be re -opened and modified to
include alternate monitoring requirements or limits.
NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism
survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an
invalid test and will require immediate follow-up testing to be completed no later than the last day of the month
following the month of the initial monitoring.
A. (3.) RE -OPENER CONDITION
[NCGS 143-215.3 (a) (2) and NCGS 143-215.66]
This permit shall be modified, or revoked and reissued to incorporate additional limitations and monitoring
requirements in the event toxicity testing or other studies indicate that detrimental effects may be expected as a
result of this discharge. Additionally, and if appropriate, after 3 years of treatment system operation the division
will evaluate effluent limits and adjust the limits if the analysis indicates an improved performance.
Page 6 of 12
Permit NCO089915
A. (4.) ELECTRONIC REPORTING OF MONITORING REPORTS
[G. S. 143-215.1(b)]
Federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and program reports.
The final NPDES Electronic Reporting Rule was adopted and became effective on December 21, 2015.
NOTE: This special condition supplements or supersedes the following sections within Part II of this permit
(Standard Conditions for NPDES Permits):
1.
• Section B. (11.) Signatory Requirements
• Section D. (2.) Reporting
• Section D. (6.) Records Retention
• Section E. (5.) Monitoring Reports
The permittee shall report discharge monitoring data elEciffonically using the NC DWR's Electronic
Discharge Monitoring Report (eDMR) internet application.
Monitoring results obtained during the previous month(s) shall be summarized for each month and submitted
electronically using eDMR. The eDMR system allows permitted facilities to enter monitoring data and
submit DMRs electronically using the internet. The eDMR system may be accessed at:
htti)s:Hdeq.nc.gov/about/divis ter-resour edmr j
If a permittee is unable to use the eDMR system due to a demonstratM hardship or due to the facility being
physically located in an area where less than 10 percent of the households have broadband access, then a
temporary waiver from the NPDES electronic reporting requirements may be granted and discharge
monitoring data may be submitted on paper DMR forms (MR 1, 1.1, 2, 3) or alternative forms approved by
the Dir r Duplicate si ed copies shall be submitted to the following address:
NC DEQ ivision of Water urces ter Quality Permitting Section
ATTENTION: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-16
See "How to Request a Waiver from Electronic Reporting" section below.
Regardless of the submission thod, the first DMR is due on the last day of the month following the
issuance of the permit or in the case of a new facility, on the last day of the month following the
commencement of discharge.
Starting on December 21, 2020, the permittee must electronically report the following compliance
monitoring data and reports, when applicable:
Sewer Overflow/Bypass Event Reports; (This does not include the flow of waters over the dam of OOF2
drainage waters from water treatment due to wet weather events causing OOF2 drainage flow rates to be
above dry weather flows.)
Pretreatment Program Annual Reports; and
Page 7 of 12
Permit NC0089915
• Clean Water Act (CWA) Section 316(b) Annual Reports.
The permittee may seek an electronic reporting waiver from the Division (see "How to Request a Waiver
from Electronic Reporting" section below).
2. Electronic Submissions
In accordance with 40 CFR 122.41(1)(9), the permittee must identify the initial recipient at the time of each
electronic submission. The permittee shall use the EPA's website resources to identify the initial recipient for
the electronic submission.
Initial recipient of electronic NPDES information from NPDES-regulated facilities means the entity (EPA or
the state authorized by EPA to implement the NPDES program) that is the designated entity for receiving
electronic NPDES data [see 40 CFR 127.2(b)].
EPA plans to establish a website that will also link to the ap^pDrniate ectronic reporting tool for each type of
electronic submission and for each state. Instructions on how to access and use the appropriate electronic
reporting tool will be available as well. Information on EPA's NPDES Electronic Reporting Rule is found at:
system-npdes-electronic-reporting-rule
Electronic submissions must start by th tes listed in the "Reporting Requirements' ion above.
3. How to Request a Waiver from Electronic Reporting 1%
The permittee may seek a temporary electronic reporting waiver from the Division. To obtain an electronic
reporting waiver, a permittee must first submit an electronic reporting waiver request to the Division.
Requests for temporary electronic reporting waivers must be submitAcquired
in writing to the Division for written
approval at least sixty (60) days prior to the date the facility would b under this permit to begin
submitting monitoring data and reports. The duration of a temporary waiver shall not exceed 5 years and
shall thereupon expire. At such time, monitoring data and reports shall be submitted electronically to the
Division unless the permittee re -applies for and is granted a new temporary electronic reporting waiver by the
Division. Approved electronic reporting waivers are not transferrable. Only permittees with an approved
reporting waiver request may submit monitoring data and reports on paper to the Division for the period that
the approved reporting waiver request is effective.
Information on eDMR and the application for a temporary electronic reporting waiver are found on the
following web page:
h ://de .nc. ov/about isions/water-resources/edmr
NV
4. Signatory Requirements [Supplements Section B. (11.) (b) and Supersedes Section B. (11.) (d)1
All eDMRs submitted to the permit issuing authority shall be signed by a person described in Part II, Section
B. (I I.)(a) or by a duly authorized representative of that person as described in Part II, Section B. (I I.)(b). A
person, and not a position, must be delegated signatory authority for eDMR reporting purposes.
For eDMR submissions, the person signing and submitting the DMR must obtain an eDMR user account and
login credentials to access the eDMR system. For more information on North Carolina's eDMR system,
registering for eDMR and obtaining an eDMR user account, please visit the following web page:
hLtp:Hdeq.nc.gov/about/divisions/water-resources/edmr
Page 8 of 12
Permit NCO089915
Certification. Any person submitting an electronic DMR using the state's eDMR system shall make the
following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE
ACCEPTED:
7 certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualifiedpersonnelproperly gather and
evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of
my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations. "
5. Records Retention [Supplements Section D. (6.)]
The permittee shall retain records of all Discharge Monitoring Aeports,ncluding eDMR submissions. These
records or copies shall be maintained for a period of at least 3 years from the date of the report. This period
may be extended by request of the Director at any time 0 CFR 122.
A. (5.) PFAS MONITORING REQUREMENTS D ANALYTICAL HODS
[NCGS 143-215.3 (a) (2) and NCGS 143-215.66]
The permittee shall monitor for PFAS compounds at the monitorOing frequencies scribed below. The
lists of compounds follow. Note that not all required compounds have eDMR parameter codes. Those with
parameter codes shall be reported using the applicable codes, and all other results for PFAS compounds
shall be reported in the comment section of the eDMR or added as supplemental information. In addition
to other data reporting requirements a complete copy of all PFAS sampling results shall be submitted to
NPDES Permitting via email at svc_deq_npdes-ec o ncdenr.gov, with the Facility permit number and
name in the Subject heading, at the same time eDMR data is due; and
N
The Permittee shall use the follow^ana1yticahhethVoswhentesting for the PFAS compounds.
Method description: Approved methods and SOPS referred to as "EPA 537 Modified" and "Table 3"
shall be used as described in supporting material and approved by DEQ Division of Waste Management
in a letter dated May 8th 2019. For this permit, Eurofins Lancaster and Eurofins Test America shall use
these same approved methods and update all method revisions with the referenced methods for
consistency across all work projects for Chemours Company Fayetteville Works.
Monitoring Locations and Frequency
Location
Compounds
Frequency
Upstream at the Permittee's Cape
Fear River Water Intake
Table 3+ Lab SOP
Monthly
Full Suite (Table 3+ Lab SOP
and EPA Method 537 Mod)
Quarterly
Influent to the Treatment System
Table 3+ Lab SOP
Monthly
Full suite (Table 3+ Lab SOP
and EPA Method 537 Mod)
Quarterly
Page 9 of 12
Permit NCO089915
Outfall 003 (effluent from the
Table 3+ Lab SOP
Monthly
Treatment System)
Full suite (Table 3+ Lab SOP
Quarterly
and EPA Method 537 Mod)
Downstream
Table 3+ Lab SOP
Monthly
The boat ramp approximately
Full Suite (Table 3+ Lab SOP
Quarterly
4500 feet downstream at Prospect
and EPA Method 537 Mod)
Hall Landing.
PFAS Compounds: Full Suite = Table 3+ Lab SOP + Method 537 Modified Compounds:
Analytical
Method
Common
Name
Chemical Name
SN
Chemical
Formula
Parameter
code
HFPO-DA
Hexafluoropropylene de
dimer acid 4&
13 -6
C61V1103
C51IF903
52612
52618
PEPA
Perlfuoroethoxypropyl
carboxylic acid
26729-6N
PFECA-G
Perfluoro-4-isopropoxybutanoic
acid
801212-59-9
C12H9F903S
52619
PFMOAA
Perfluo --methoxyacetic acid
74-13-5
C3HF503
52613
PF02HxA
Perfluoro(5-diox exanoic)
acid
39492-88-1
IL
C41IF704
52617
PF030A
Perfluoro(3,5,7-trioxaoctanoic
acid
39492-89-2
C51IF905
52616
PF04DA
Perfluoro(3,5,7,
tetraoxadecanoic)
39492- 0-5
C61VII06
52615
PMPA
Perfluoromethoxypropyl
carboxylic acid
13140-29-9
C41IF703
52620
Table 3+
Lab SOP
Hydro -EVE
Acid
Perfluoroethoxypropanoic acid
773804-62-9
C8H2F1404
52621
EVE Acid
Perfluoroethoxypropionic acid
69087-46-3
C81V1304
52622
ECA-B
Perfluoror-3-dioxaheptanoic
acid
151772-58-6
C51IF904
52626
R-EVE
R-EVE
N/A
C8H2F1205
52640
PF05DA
Perfluoro-3,5,7,9,11-
pentaoxadodecanoic acid
39492-91-6
C71VI307
52627
Byproduct
Byproduct 4
N/A
C7H2F1206S
52643
Byproduct 5
Byproduct 5
N/A
C7H3F1107S
52644
Byproduct 6
,Byproduct 6
N/A
C6H2F1204S
52645
NVHOS
Perfluoroethoxysulfonic acid
1132933-86-
86-8
C4H2F804S
52628
PES
Perfluoroethoxyethanesulfonic
acid
113507-82-7
C41IF904S
52629
PFESA-BPI
Byproduct 1
29311-67-9
C71VI305S
52630
PFESA-BP2
Byproduct 2
749836-20-2
C7H2F1405S
52614
DFSA'
DFSA
422-67-3
C2H2F205S
Table 3+
MMF'
MMF
1514-85-8
C3H2F204
Lab SOP
MTP'
MTP
93449-21-9
C4H4F403
PPF Acid'
PPF Acid
422-64-0
C31IF502
Page 10 of 12
Permit NCO089915
PFBA
Perfluorobutanoic acid
375-22-4
C41V702
51522
PFDA
Perfluorodecanoic acid
335-76-2
C101V1902
51627
PFDoA
Perfluorododecanoic acid
307-55-1
C121V2302
51629
PFHpA
Perfluoroheptanoic acid
375-85-9
C71V1302
51625
PFNA
Perfluorononanoic acid
375-95-1
C91V1702
51626
PFOA
Perfluorooctanoic acid
335-67-1
C81V150
51521
PFHxA
Perfluorohexanoic acid
307-24-4
C61V1102
51624
PFPeA
Perfluoropentanoic acid
2706-90-3
C51V902
51623
PFTeA
Perfluorotetradecanoic acid
376-06-7
C141V2702
51531
PFTriA
Perfluorotridecanoic acid
72629-94-8
C131V2502
51630
PFUnA
Perfluoroundecanoic acid
2058-94-8
C11HF2102
51628
PFBS
Perfluorobutanesulfonic acid
375-73-5
C41V9SO
52602
PFDS
Perfluorodecanesulfonic acid
335-77-3
C10HF2103S
52603
PFHpS
Perfluoroheptanesulfonic acid
375-92-8
C71V1503S
52604
PFHxS
Perfluorohexanesulfonic acid
355-46-4
C61V13S03
52605
PFNS
Perfluorononanesulfonic acid
68259-12-1
C91V1903S
52611
EPA
PFOS
Perfluorooctanesulfonic acid
1763-23-1
C81V17S03
52606
PFPeS
Perfluoropentanesulfonic acid
2706-91-4
C51V1103S
52610
Method
10:2 FTS
10:2 fluorotelomersulfonic acid
120226-60-M
C12H5F2103
52631
537 Mod
4:2 FTS
4:2 fluorotelomersulfonic acid
757124-72-4
C6H5F903S
52607
6:2 FTS
6:2 fluorotelomersulfonic acid
27619-97-2
C8H5F13S03
52608
8:2 FTS
8:2 fluorotelomersulfonic acid
39108-34-4
C10H5F1703S
52609
NEtFOSAA
NEtFOSAA
2991-50-6
C12H8F17N04S
51643
NEtPFOSA
NEtPFOSA
4151-50-2
C10H6F17NO2S
52642
NEtPFOSAE
NEtPFOSAE
1691-99-2
C12H10F17NO3S
51641
NMeFOSAA
NMeFOSAA
2355-31-9
C11H6F17N04S
51644
NMePFOSA
NMePFOSA
31506-32-8
C9H4F17NO2S
52641
NMePFOSAE
NMePFOSAE
24448-09-7
C11H8F17NO3S
51642
PFDOS
Perfluorododecanesulfonic acid
79780-39-5
C121V2503S
52632
PFHxDA
Perfluorohexadecanoic acid
67905-19-5
C161V3102
52633
PFODA
Perfluorooctadecanoic acid
16517-11-6
C18IV3502
52634
PFDSA
Perfluorooctanesulfonamide
754-91-6
C8H2F17NO2S
51525
F-53B Major
F-53B Major
73606-19-6
C8HC1F1604S
52638
F-53B Minor
F-53B Minor
83329-89-9
C10HCIF2004S
52639
ADONA
4,8-Dioxa-3H-perfluorononanoic
acid
919005-14-4
C7H2F1204
52636
Notes:
1. Monitoring for the compound is suspended until an appropriate testing methodology is established.
The facility will be notified by DWR when monitoring shall begin.
A. (6.) CALCULATION OF HFPO-DA, PFMOAA, & PMPA REMOVAL/LOADS
a. The Permittee shall calculate monthly removal efficiency for HFPO-DA, PFMOAA and PMPA as
follows:
Removal = Influent -Effluent
Influent
Where:
Influent = monthly average influent concentration
Effluent = monthly average effluent concentration
b. The Permittee shall calculate monthly load for HFPO-DA, PFMOAA, and PMPA as follows:
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Permit NC0089915
Monthly C Load = C x TMF x 8.34
Where:
C = monthly average concentration for each compound (mg/L)
TMF = Total Monthly Flow of wastewater discharged during the month (MG/month)
8.34 = conversion factor from (mg/L x MG) to pounds
Annual C Load = Sum of the 12 Monthly Loads for each compound for the calendar year
c. The Permittee shall report monthly HFPO-DA, PFMOAA, and PMPA results [% removal (ng/L), and
Loading (pounds/month)] in the discharge monitoring report for each month and shall report each calendar
year's Annual Load (pounds/year) with the December report for that year. Percent removal shall be listed
in the comment section of the eDMR since it has no parameter code. The requirement for 99% removal at
the treatment system for PMPA shall not become effective until Jan. 31, 2021.
In addition, calculations shall be submitted electronically with all PFAS data to NPDES Permitting via
email at svc_decnpdes-ecgncdenr.gov, with the cility permit number and name in the Subject
heading.
This percent removal will be reported monthly with *Cemours electronic Discha onitoring Report
(eDMR) data. If the influent HFPO-DA or PFMOAA concentrations to the water treatment system are
equal to or less than 200 ng/L and 500 ng/L, respectively, then the water treatment system effluent
concentrations of less than the current reporting limits (2 ng/ and 5 ng/L, respectively) shall be
considered as achieving 99% oval.
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