WQ0003226_NOV-2020-PC-0211 Response_20200515

?"a qse&A &0
Public works and Utilities
May 15, 2020
ATTN: Scott Vinson, Regional Supervisor
Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: NOTICE OF VIOLATION
Tracking Number: NOV-2020-PC-0211
Permit No. WQ0003226
Town of Siler City RLAP
Chatham County
Dear Mr. Vinson,
This letter is in response to the Notice of Violation for quarterly sampling done at the WWTP and annual sample
for the WTP under our land application permit. There were four samples represented for the WWTP reported.
However, the 41" quarter sample is dated 1/16/20. This is due to the original 4th quarter samples being lost in
shipment to the lab. When the mistake was realized a new sample was pulled and sent in for analysis. Due to the
wet weather, we were unable to land apply. Even though the new sample was pulled on 1/16/20 it is my belief
that the sample still was a strong representation of the material produced in the 411 quarter of 2019.
The NOV was also for the WTP annual samples not being reported. I have attached a copy of their samples to this
letter showing sample data and results as shown in the annual report.
1f you have any questions please do not hesitate to contact me.
Sincerely, -
Town of er City
Britta y York
Wastewater Plant Superintendent
Cc: Roy Lynch Town Manager, Chris McCorquodale Public Works & Utility Director
Brittany York
WWTP Superintendent [e-mail]
PO Box 769.311 N Second Avenue Phone: [phone]
Siler City, NC 27344-0769 www.sliercity.org

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Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name Sample Date Report Range Ratio
2032-01-LIO-NC SILER CITY, NC WWTP LIQUID 1/16/2020 1 1 - 1 1 1.4199
Na mgli = (Na mglkg x % Solids) + 100 = (3890 x 3.7500) + 100 = 145.875
Ca mgll = (Ca mg/kg x % Solids) + 100 = (18300 x 3.7500) + 100 = 686.25
Mg mgll = (mg mgikg x % Solids) + 100 = (1790 x 3.7500) + 100 = 67.125
Na meq = Na mgll * Molec.Wgl.Na = 145.875 + 23 = 6.34239
Ca meq = Ca mgli + Molec.Wgt.Ca = 686.25 + 20 = 34,3125
Mg meq = Mg mg/1 + Molec_Wgt.Mg = 67.125 + 12 = 5.59375
SAR = Na meq + SgrRoot[0,5 x (Ca meq + Mg meq)] = 6.34239 + SgrRoot[0.5(34.3125+5.59375)] = 1.41987
Printed: 2/W020
Page 1 13:20

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Waypoint
ANALYTICAL
Synagro Central LLC/ Siler City
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 19-067-0201
Project Description: Siler City WTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
14CDept Of Environmental Quality
AUG 19 2020
Raleigh Regional Office
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received sample(s) on 3/8/2019 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZO629 Pennsylvania 68-03109 Virginia 460014
South Carolina 93007
New Jersey VA011
Rorlda E871087
North Carolina 257

Waypoint(D
ANALYTICAL
Client: Synagro Central LLC/ Siler City
Project: Siler City WTP
Lab Report Number: 19-067-0201
Date' 3/15/2019
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 65191 (Siler City WTP)
QC Batch No: L4260921L426648
This analyte was analyzed at a dilution due to IEC interferencelmatrix interference.
nr, -I-fT

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WaYPOint.
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 19-O67-0201
Client Project Description: Slier City V4TP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
65191
Slier city WTP
Solids
03/06/2019
03/00/2019
65191
Slier City WTP
Solids
03/06/2019
03/08/2019
5M-4500-NH3C
WtN
65191
Slier City WTP
Solids
03/06/2019
03/08/2019
9045D
WTN
65191
Slier City WTP
Solids
03/06/2019
03/08/2019
4500NO3F-2011
WTN
65191
Slier City WTP
Solids
93/06/2019
03/08/2019
6010D
WTN
65191
Sller City WTP
Solids
03/06/2019
03/08/2019
SW-7471B
WTN
65191
Slier City WTP
Solids
03/06/2019
03/08/2019
SM-4500-NH3C-TKN
WTN
65191
Slier City WTP
Solids
03/06/2019
03/08/2019
SM-2540G
WTN
WIN: Waypoint Analytical - TN, Memphis, TN, Certilicatlon: # 1354

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Waypoint,
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401"Fax [phone]
www,waypointa nalytica I.com
Cooler Receipt Form
Customer Number, 46490
Customer Name. Synagro Central LLCI Siler City
Report Number. 19-067-0201
Shipping Method
Fed Ex 0 US Postal 0 Lab
UPS Q Client 0 Courier
0 Other:
Thermometer ID:
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers received
F 1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
0 Not Required
Custody seals intact on sample bottles?
0 Yes
0 No
0 Not Required
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
0 Yes
0 No
Samples in proper containers?
0 Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
0 Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
0 Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 NIA
Water - VOA vials free of headspace
0 Yes
0 No
0 NIA
Trip Blanks received with VOAs
0 Yes
0 No
0 NIA
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 NIA
High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) F- Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes 0 No
Comments:
Signature: Drandi Watson
Date & Time: '03/08 019 11;36.59
Panes R of 7

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Pane 7 of 7

SUMM111
f��YIROPIIdEWI'AL TECIANOLOG =a, ':C
Arratyti'Cal r al:a.•atodes
February 27, 2018
Clay Fisackerly
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Siler City WTP
Dear Clay Fisackerly:
Stwratit Environmental Technologies, Inc,
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL, [phone] FAX. • [phone]
Websile: httxlAviviv,setlekconr
Order No.: 180I 1275
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/26/2018 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Forpof �. N
r
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, Colifomia 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho 01100923, Illinois
200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota
409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon
OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OFI009232011-1, Virginia VELAP 9456, Washington
C891
Page 1 of 29

Summit Environmental Terhnologies, Inc. Case Narrative
MI SUMMf1tv 3310 Win St.
f*NVIROM16ENIAL tcC14NOLOG I.c CuyahogaI-ails. Ohio44223 WOY: 190I1275
Anaryficaf LAhnrawrtr.; TEL: [phone] FAX- [phone]
Website:litlp:ll+�svav,..}rt{[{nr Dale: 2/27/2018
CLIENT: Synagro 11y
Project: Siler City WTP AUG 19 20
WorkOrder Narrative: Raleigh Regional OffiC*
18011275: This report in its entirety consists of the following documents: Cover Letter, Case larrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditationslcertifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Run Comments:
80349: CCV rerun exhibits high recovery for Vinyl Chloride. All samples are nondetect for Vinyl
Chloride.
Analytical Sequence Sample Notes:
18011275-001A SVOC-BNA_TCLP(8270): Possible low bias for Pyridine due to low recovery in the
LCS.
18011275-001a tclp-svoc-herb tclp(8151): Surrogate double spiked.
Analytical Sequence QC Notes:
Original
Page 2 of 29

Smnmit Environmental Technologies, lnc. Case Narrative
r. 3310 It?n St.
fINVIROMhtEMY'► L fcCHNOLOG:,S, :Nc- Cuyahoga Falls, Ohio 44223 WO#: 18011275
Arnaiyticat t ahoratarle; TEL; [phone] F.1,Y.• [phone]
Websile_ hila-Mvwtiv.seltek.com Date: 2/27/2018
CLIENT: Synagro
Project: Siler City WTP
LCS-30751. SVOC-BNA_TCLP(8270): LCS-30751(R80452) exhibited no recovery for Pyridine;
Pyridine is a known poor performer; Possible low bias in associated samples.
Original
Page 3 of 29

SL++rmit Environmental Technologies, In
3310 IVin
NVIROHNIENIAL 1-=CHc4()LOG'_5, ivc Cuyahoga Falls, Ohio 4424
nj Arratyt;cal Lahorar,')WS TEL: [phone] FAX. [phone]
IVebsile: btrn;1Aviv%v,seuek.ca
Qualifiers and Acronyms
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
WON: 180111275
Date: 2/27/2018
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GC/MS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The 1CB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
1CB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
RLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
CU
ea
d
R
4,
o
_
N
q
°
euQ
Q.
U
�
z
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
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wM
5unindt Enviromnentaf T€vhnologies. Inc-
Workorder
S 14 M fl U
r WIROMhMENTAL 1ECtiWiLOGies, inC
3310 Win St.
Cuyahoga Falls, Ohio 44223
Sample Summary
Analytical Labaraforles
TEL: [phone] FAX. [phone]
WO#: 18011275
Website= 11 -1Avww. tt nr
27-Feb-18
CLIENT:
Synagro
Project:
Siler City WTP
Lab Sample[D Client Sample [D Tag No Date Collected
Date Received Matrix
18011275-001
Siler City WTP TCLP
V24i2018 9:00,00 AM
112&2018 9:30,00 AM Sludge
Page 5 of 29

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CNWROMPAEN1'AL T5CHUOLOG155, -'tC
Analyt,cal Laboraforms
Summit Environmental Technologies, Inc.
3310 IVin St.
Cuyahoga Falls, 01da 44223
TEL, [phone] FAX: [phone]
Website: hya.-Ilxpww.setteLEM
Analytical Report
(base report}
W�#: 18011275
Date Reported: 2/27/2018
CLIENT: Synagro
Tag Number:
Matrix: SLUDGE
Collection Date:
1/24/2018 9:00:00 AM
Lab ID: 18011275-001A
Project: Siler City WTP
Client Samplc ID Siler City WTP TCLP
Analyses Result
RL
Qual Units
DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW7470A
SW7470A Analyst: EAM
TCLP MERCURY ANALYSIS (SW131117470)
TCLP Mercury
ND
0.0100
mg/L
1 2/8/2018 10:24:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010D
Analyst: KMS
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
ND
0.500
mg/L
1 2/7/2018 2:19:30 AM
TCLP Barium(Ba)
ND
5.00
mg/L
1 2/7/2018 2:19:30 AM
TCLP Cadmium(Cd)
ND
0.100
mg/L
1 2/7/2018 2:19:30 AM
TCLP Chromium(Cr)
ND
0.200
mg/L
1 2/7/2018 2:19:30 AM
TCLP Lead(Pb)
ND
0.500
mg/L
1 217/2018 2:19:30 AM
TCLP Selenium(Se)
ND
0.0500
mg/L
1 2/7/2018 ZM30 AM
TCLP Silver(Ag)
ND
0.500
mg/L
1 2/7/2018 2:19:30 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270D
SW3510C Analyst: BJH
TCLP SEMI-VOLATILES ANALYSIS (SW131118270)
1,4-Dichlorobenzene
ND
0.0800
mg/L
2 2/9/2018 6:24:00 PM
2,4,5-Tdchlorophenol
ND
0.200
mg/L
2 2/9/2018 6:24:00 PM
2,4,6-Tdchlorophenol
ND
0.200
mg1L
2 2/9/2018 6:24:00 PM
2,4-Dinitrotoluene
ND
0.0400
mg/L
2 2/9/2018 6:24.00 PM
o-Cresol
ND
0,200
mg/L
2 2/9/2018 6:24:00 PM
m/p-Cresol(s)
0.648
0.200
mg/L
2 2/9/2018 6:24:00 PM
Cresols, Total
ND
4.00
mg/L
2 2/9/2018 6:24:00 PM
Hexachioro-1,3-butadiene
ND
0.0160
mg/L
2 2/9/2018 6:24:00 PM
Hexachforobenzene
ND
0.0400
mg/L
2 2/9/2018 6,24:00 PM
Hexachloroethane
ND
0,0800
mg/L
2 2/9/2018 6:24:00 PM
Nitrobenzene
ND
0.0800
mg/L
2 2/9/2018 6:24:00 PM
Pentachlorophenol
ND
0.200
mg1L
2 2/9/2018 6:24:00 PM
Pyridine
ND
0.200
QL- mg/L
2 2/9/2018 6:24:00 PM
Surr. 2-Fluorophenol
44.6
10 - 109
%Rec
2 2/9/2018 6:24:00 PM
Surr: Phenol-d6
22.3
10 - 109
%Rec
2 2/9/2018 6:24:00 PM
Surr: Nitrobenzene-d5
77.6
19 - 120
%Rec
2 2/9/2018 6:24:00 PM
Surr: 2,4,6-Tribromophenol
52.8
10 - 120
%Rec
2 2/9/2018 6:24:00 PM
Surr: 2-Fluombiphenyl
70.1
22 - 117
%Rec
2 2/9/2018 6:24:00 PM
Qualifiers: * Value exceeds Maximum Contaminant Level.
E Value above quantitation range
H Holding times For preparation or
analysis exceeded
M Manual Integration
used to determine area response
MC Value is below Minimum Compound Limit,
N Tentatively identified compounds
ND Not Detected
O RSD is greater than RSDlimit
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 7 of 29

'�� r.., r Summitrlvrro�rrnerrtal 7eclrnologies, Inc. 331 R Jvin St.Analytical Report
'NV1R0D1h1eN'1ALTECHNOLOG'W5,-�,G Cuyahoga Falls, Ohdo44223 (base report)
Anaiyf;cal Laborafoyfr 5 TEL.- [phone] FAX [phone] WD#: 18011275
Websife: hgp.1Avwiv sellekcom Date Reported: 2/27/2018
CLIENT: Synagro Arc Depr Of Tag Number: - -
Matrix: SLUDGE Fn�'ronmenr$1 Collection Date: 1/24/2018 9:00:00 AM
Lab ID: 18011275-00I A �U(j ' Qu$lity
Project: Siler City WTI?
Client Sample ID Siler City WT1y:lO!$h
_ & 12a
Analyses Result oflficflual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
Surr. p-Terphenyl-d14 55.9 34 - 116
NOTES:
Possible low bias for Pyridine due to low recovery in the LCS.
SW8270D SW3510C Analyst: BJH
%Rec 2 2/9/2018 6:24:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW3510C Analyst JBN
TCLP PESTICIDES ANALYSIS (SW131118081)
Chlordane, total ND
00200
mg1L
2 2/7/2018 10:02:00 PM
Toxaphene ND
00400
mg/L
2 2/7/201810:02:00 PM
Endrin NO
0.00200
d
mg/L
2 217/2018 10:02:00 PM
gamma-BHC ND
0.00200
rnglL
2 217/2018 10:02:00 PM
Heptachlor ND
0.00200
d
mg/L
2 2/7/2018 10:02:00 PM
Heptachlor epoxide ND
0.00200
mglL
2 2/7/2018 10:02:00 PM
Methoxychlor ND
0.00200
rn
mglL
2 2/7/2018 10:02.00 PM
Surr: TCMX 63.7
10-119
m
%Rec
2 2/7/2018 10-02:00 PM
Sum DCB 43.5
10-119
%Rec
2 217/201B 10.02:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8151A
SW8151A Analyst: JBN
TCLP HERBICIDES ANALYSIS (SW131118151)
2,4-D ND
1.00
d
mg/L
1 2/20/2018 3:49:00 PM
2,4,5-TP ND
0.500
d
mg/L
1 2/20/2018 3:49:00 PM
Surr. DCAA 178
20 -140
S
%Rec
1 2/20/2018 3:49:00 PM
NOTES:
Surrogate double spiked.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260B
SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND
0.250
mglL
50 2/7/2018 7:09-00 PM
1,2-Dichloroethane ND
0.250
mg/L
50 2/7/2018 7:09 00 PM
MEK ND
1.25
mg/L
50 2/7/2018 7:09.00 PM
Benzene ND
0.250
mg/L
50 2/7/2018 7:09-00 PM
Carbon tetrachloride ND
0.250
mg/L
50 2/7/2018 7:09:00 PM
Chlorobenzene ND
0.250
mg/L
50 2/7/2018 7:09:00 PM
Qualifiers•. ` Value exceeds Maximum Contaminant Level.
E Value above quantitation
range
H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified
compounds
ND Not Detected
O RSD is greater than RSDlimit
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Paae 8 of 29

r ,1`
�ij�-��+�'
Summit Environmental Technologies, Inc.
3310 wnr St.
Analytical Report
i'•,LIROMIIEN'Ir+l T�Cr!r�4LaGt;S, :C
Cuyahoga Falls, Ohio 44223
(base report)
Analytical Lahoralorle's
TEL: [phone] FffX.' [phone]
WO#: 18011275
Website - h11o:1Avivw.setleA.cnm
Date Reported: 2/2712018
CLIENT:
Synagro
Tag Number:
Matrix:
SLUDGE
Collection Date:
1/24/2018 9:00:00 AM
Lab ID:
18011275-001 A
Project:
Siler City WTI?
Client Sample ID Siler City WTP TCLP
Analyses
Result RL Qual Units
DR Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260B SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
Chloroform ND
0.250
mg/L 50 2/7/2018 7.09:00 PM
Tetrachloroethene ND
0.250
mg/L 50 2/7/2018 7:09:00 PM
Trichloroethene ND
0,250
mg/L 50 217/2018 7:09:00 PM
Vinyl chloride ND
0.100
QC+ mg/L 50 2/7/2018 7:09:00 PM
Surr. 4-Bromofluorobenzene 102
70 -130
%Rec 50 2/7/2018 7:09:00 PM
Sure Dibromofluoromethane 93.7
70 - 130
%Rec 50 2/7/2018 7:09:00 PM
Surr. Toluene-d8 103
70 -130
%Rec 50 21`7/2018 7:09:00 PM
NOTES:
CCV exhibits high recovery for Vinyl Chloride. All samples are
non -detect for Vinyl Chloride,
Sample diluted due to matrix.
RCI-SOLID-WI IGNITABILITY1030
SW9014 Analyst: MS
REACTIVE CYANIDE (901417.3.3.2)-SOLID
Cyanide, Reactive ND
0.500
mg/Kg 1 2/2/2018 3:16.00 PM
RCI-SOLID-WI IGNITABILITY1030
SW1030 Analyst: AJT
IGNITABILITY OF SOLIDS (SW-846: 1030)
Ignitability non-flammable
1 1/29/2018 3:00.00 PM
RCI-SOLID-WI IGNITABILITY1030
SW9045D Analyst: DHC
PH (SW9045D)
pH 5.9
s,u.@19 5C 1 2/12/201811,55 00 AM
RCI-SOLID-W/IGNITABILITY1030
SW9034 Analyst: MS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive ND
25.0
mg/Kg 1 212/2018 3,16,00 PM
Qualifiers: Value exceeds Maximum Contaminant Level,
E Value above quantitation range
I3 Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
ND Not Detected
O RSD is greater than RSDlimit
P Second column confirmation exceeds
PL Permit Limit Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 9 of 29

C
Summit Environmental Technologies, Inc.
Accreditation
Program
R 10 33/0 Win St.
% I`
Anal`` hyes Report
4 p
f`jvlp0A1h1E4TAL IFCHNOLOGI=S,
1PtC Cuyahoga Falls, Ohio 44223
J
Analyf,'caf Ubarafor*
TEL [phone] FkY: [phone]
Wo#:
18011275
Dept a F Websfle: hllorl/wiviy.setlek. com
nviranmental Qnl
Z7-Feb-18
Client: Synagro
4Ifr i q
State: NW
Project: Siler City WTP
Aq
Program Name: NC_WW
SCM
Sample ID IVlatdx
Cglonal �T]a at
Analyte
Status
18011275-001A Sludge
IgnitabilityofSolids (SW-846:1030)
Ignitability
A
Sludge
pH(SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7-3-3.2)-Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SW 13 f I/8151)
2,4,5-TP
A
Sludge
TCLP I Icrbicides Analysis (SW1311/815I)
2,4-D
A
Sludge
TCLP Herbicides Analysis (SW1311/8151)
DCAA
A
Sludge
TCLP Mercury Analysis (SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
2,2',3,3',4,4',5,5',6,6-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis (SW 131 118081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW 1311/808I)
gamma-BHC
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SWI311/8081)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SWI311/8081)
Tetmchloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
Toxaphene
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311/8270)
1,4-Dichlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichierophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Tribromophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitmtoluene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2-Fluorobiphenyl
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2-Fluorophenol
A
ey Key
NC WW SCM A Accredited NC WW SCM U Unavailable
Original #1
Page 10 of 29

,�, t' Summit Environmental Technologies, Inc.
33'°"�'"sr_
Accreditation Program
Anal tes Report
Y
P
FP4VIROMMENIAL TcC14NOLOG 2-S. INC Criyahoga Falls, Olrio 44223
Arraiylicai laboratories
TEL: [phone] r4.V- [phone]
WO#:
18011275
If'ebsire - h(W,1Avwiv.sellelccom
27-Feb-18
Client: Synagro
State: NW
Project: Siler City WTP
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
1801 1275-001 A Sludge
TCLP Semi-Volatiles Analysis (SW131 I18270)
2-Methylphenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311 i8270)
3,4-Methylphenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131118270)
Cresols, Total
A
Sludge
TCLPSemi-Volatiles AnalyMs(SW1311/8270)
Hcxachlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SWI311/8270)
Ifexachlorobutadiene
A
Sludge
TCLP Semi-Volatiles Analysis (SW 13l 1/8270)
Flexachloroethane
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311)8270)
Nitrobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311 f8270)
Nitrobenzene-d5
A
Sludge
TCLP Semi-Volatiles Analysis (SWI31118270)
Pentachlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW 13114270)
Phenol-d6
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131118270)
p-Terphcnyl-dl,l
A
Sludge
TCLP Scmi-Volatiles Analysis (SW131118270)
Pyridine
A
Sludge
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Sludge
TCLP Volatiles Analysis
%2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
4-Bromofluorobenzene
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromofluoromethane
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Toluene-dS
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
Key I ey
NC WW SCM A Accredited NC WW SCM U Unavailable
Original 91
Page 11 of 29

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AMU 5ur►t►rrit Environmental Technologies, Inc.
Mj- 1 3310 lYin St.
VliiOrthlEN'k'AtT?CY.tdULOG�_5,%c. Cuyahoga Fulls, Ohio44223 Sample Log -In Check List
M9 Analyt;cal Lahoratarira TEL, [phone] FAX. [phone]
Websile: n :1Avivw. e1 e rn
Client Name, SYN-NC-27028 Work Order Number: 18011275 RcptNo. 1
{ Logged by: Lori Douglas 1126/2018 9:30:00 AM
Completed By, Christopher Livengood 1/2612018 2:33:08 PM
Reviewed By: Jennifer Woolf 1/2612018 5:53:04 PM
Chain of Custody
1. Is Chain of Custody complete? Yes Not ] Not Present _
2_ Mow was the sample delivered? FedEx
LogIn
3_ Coolers are present? Yes © No ❑ NA ❑
4. Shipping containerlcooler in good cond.tion? Yes No ❑
Custody seats intact on shipping container/cooler? Yes No ❑ Not Present R1
No. Seal Date: Signed By:
6, Was an attempt made to cool the samples? Yes © No ❑ NA ❑
6. Were all samples received at a temperature of >0' C to 6.0'C Yes © No ❑ NA ❑
7. Sample(s) in proper container(s)? Yes © No ❑
8. Sufficient sample volume for indicated test(s)? Yes No ❑
g, Are samples (except VOA and ONG) properly preserved? Yes © No ❑
10. Was preservative added to bottles? Yes ❑ No ❑ NA ❑�
NA
11. is the headspace in the VOA vials less than 114 inch or 6 mm? Yes No ❑ No VOA Vials 0
12. Were any sample containers received broken? Yes Ej No
13. Does paperwork match bottle labels? Yes © No ❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody? Yes © No ❑
15. Is it clear what analyses were requested? Yes © No ❑
16. Were all holding times able to be met? Yes © No ❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order? Yes No ❑ NA
Person Notified: Date
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
Cooler Information
Cooler No Temp °C
Condition
Seal Intact
I Seal No
Seal Date
Signed 13
1 14.0
Good
Not Present
Paae 29 of 29