NC0024911_PPA Scan_20200608

Action History (UTC-05:00) Eastern Time (US & Canada)
Submit by Anonymous User 6/8/2020 2:31:16 PM (Supplemental Submittal)
Submit by Bennett, Bradley 8/17/2020 12:54:58 PM (Supplemental Info Submittal)
• Bennett, Bradley assigned the task to Bennett, Bradley 8/17/2020 12:54 PM
• The task was assigned to Thedford, Wren, Bennett, Bradley 6/8/2020 2:31 PM

Initial Review Information
Updated ID#:* IWORTANf:FEVIBAERSl-IOLLDVERFYand revise here ifnecessary.
NCOO24911
How should this project be handled?*
r File r Discard
Information Submitted on 6/8/2020
Submitter Information
Name: Roger Edwards
Vft is subrritting the inforrretion?
Email Address:* [e-mail]
Submittal Information
The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental
information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted
electronically through the eDMR system and should not be submitted here. Division staff will reviewall
uploaded documents and will only maintain required information. Documents such as laboratory reports are not required
to be submitted and will not be maintained in the system.
Project Information:
Rease SUDDly the Dernit nun ber for this
Existing ID#* PerrritNurrber
NCOO24911
Exarrples: NOKxxxxxx or NO&xxxxx
Facility Name:* Metropolitan Sewerage District of Buncombe County
County: Buncombe
Please upload all files that need to be
submited. *
dick the upload button or drag and drop files here to attach docurrent
MSD PPA Results 5-14-2O2O.pdf 1.29MB
Only pdf files are accepted.
Comments about the attachments:
* V By checking the box and signing box below, I certify that:
o I have given true, accurate, and complete information on this form;

• I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the
NC General Statutes (the "Uniform Electronic Transactions Act)
• I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
(the "Uniform Electronic Transactions Act');
• I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
signature; AND
• I intend to electronically sign and submit the Supplemental Information form."
Full Name: Roger Edwards
Signature: 11
Date Submitted: 06/08/2020

#=CL#
June 02, 2020
LIMS USE: FR - ROGER EDWARDS
LIMS OBJECT ID: 92477574
92477574
Project:
Pace Project No.:
RE:
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
PERMITTED PPA 5/14/20
Dear Mr. Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on May 14, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
cc:Ms. Shannon Bergeron, Metropolitan Sewerage District
Ryan Dyson, MSD of Buncombe County, NC
Mr. Chad Ledford, Metropolitan Sewerage District
Mr. Dwayne Martin, Metropolitan Sewerage District
Ms. Cassandra McKnight, MSD of Buncombe County
Mr. Alan Taylor, Metropolitan Sewerage District
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 32
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Lab ID Sample ID Matrix Date Collected Date Received
92477574001 PE Water 05/14/20 09:27 05/14/20 12:24
92477574002 FIELD BLANK Water 05/14/20 11:17 05/14/20 12:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92477574001 PE EPA 1664B 1 PASI-CWAM
EPA 200.7 Rev 4.4 1994 15 PASI-ARDT
EPA 1631E 1 PASI-ARDT
EPA 625.1 64 PASI-CPKS
EPA 624.1 37 PASI-CSAS
SM 2540C-2011 1 PASI-AJNS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 1 PASI-AKDF1
EPA 365.1 Rev 2.0 1993 1 PASI-AMDW
EPA 420.4 Rev 1.0 1993 1 PASI-AKDF1
SM 4500-CN-E-2011 1 PASI-ACJL
92477574002 FIELD BLANK EPA 1631E 1 PASI-ARDT
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Sample:PE Lab ID:92477574001 Collected:05/14/20 09:27 Received:05/14/20 12:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualLimitLimit
Report Reg.
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease ND mg/L 05/22/20 11:155.0 1
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Antimony ND ug/L 05/24/20 18:56 7440-36-005/22/20 01:595.0 1
Arsenic ND ug/L 05/27/20 12:53 7440-38-205/22/20 01:5910.0 1
Beryllium ND ug/L 05/24/20 18:56 7440-41-705/22/20 01:591.0 1
Cadmium ND ug/L 05/24/20 18:56 7440-43-905/22/20 01:591.0 1
Calcium 9490 ug/L 05/24/20 18:56 7440-70-205/22/20 01:591001
Chromium ND ug/L 05/24/20 18:56 7440-47-305/22/20 01:595.0 1
Copper 8.6 ug/L 05/24/20 18:56 7440-50-805/22/20 01:595.0 1
Lead ND ug/L 05/24/20 18:56 7439-92-105/22/20 01:595.0 1
Magnesium 3520 ug/L 05/24/20 18:56 7439-95-405/22/20 01:591001
Nickel ND ug/L 05/24/20 18:56 7440-02-005/22/20 01:595.0 1
Selenium ND ug/L 05/24/20 18:56 7782-49-205/22/20 01:5910.0 1
Silver ND ug/L 05/24/20 18:56 7440-22-405/22/20 01:595.0 1
Thallium ND ug/L 05/24/20 18:56 7440-28-005/22/20 01:5910.0 1
Hardness, Total(SM 2340B)38200 ug/L 05/24/20 18:5605/22/20 01:596621
Zinc 39.1 ug/L 05/24/20 18:56 7440-66-605/22/20 01:5910.0 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 10.2 ng/L 05/29/20 12:13 7439-97-605/28/20 21:040.50 1
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 05/23/20 02:20 83-32-905/18/20 14:115.0 1
Acenaphthylene ND ug/L 05/23/20 02:20 208-96-805/18/20 14:115.0 1
Anthracene ND ug/L 05/23/20 02:20 120-12-705/18/20 14:115.0 1
Benzidine ND ug/L 05/23/20 02:20 92-87-5 L205/18/20 14:1150.0 1
Benzo(a)anthracene ND ug/L 05/23/20 02:20 56-55-305/18/20 14:115.0 1
Benzo(a)pyrene ND ug/L 05/23/20 02:20 50-32-805/18/20 14:115.0 1
Benzo(b)fluoranthene ND ug/L 05/23/20 02:20 205-99-205/18/20 14:115.0 1
Benzo(g,h,i)perylene ND ug/L 05/23/20 02:20 191-24-205/18/20 14:115.0 1
Benzo(k)fluoranthene ND ug/L 05/23/20 02:20 207-08-905/18/20 14:115.0 1
4-Bromophenylphenyl ether ND ug/L 05/23/20 02:20 101-55-305/18/20 14:115.0 1
Butylbenzylphthalate ND ug/L 05/23/20 02:20 85-68-705/18/20 14:115.0 1
4-Chloro-3-methylphenol ND ug/L 05/23/20 02:20 59-50-705/18/20 14:115.0 1
bis(2-Chloroethoxy)methane ND ug/L 05/23/20 02:20 111-91-105/18/20 14:1110.0 1
bis(2-Chloroethyl) ether ND ug/L 05/23/20 02:20 111-44-405/18/20 14:115.0 1
2-Chloronaphthalene ND ug/L 05/23/20 02:20 91-58-705/18/20 14:115.0 1
2-Chlorophenol ND ug/L 05/23/20 02:20 95-57-805/18/20 14:115.0 1
4-Chlorophenylphenyl ether ND ug/L 05/23/20 02:20 7005-72-305/18/20 14:115.0 1
Chrysene ND ug/L 05/23/20 02:20 218-01-905/18/20 14:115.0 1
Dibenz(a,h)anthracene ND ug/L 05/23/20 02:20 53-70-305/18/20 14:115.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Sample:PE Lab ID:92477574001 Collected:05/14/20 09:27 Received:05/14/20 12:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualLimitLimit
Report Reg.
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
1,2-Dichlorobenzene ND ug/L 05/23/20 02:20 95-50-105/18/20 14:115.0 1
1,3-Dichlorobenzene ND ug/L 05/23/20 02:20 541-73-105/18/20 14:115.0 1
1,4-Dichlorobenzene ND ug/L 05/23/20 02:20 106-46-705/18/20 14:115.0 1
3,3'-Dichlorobenzidine ND ug/L 05/23/20 02:20 91-94-105/18/20 14:1110.0 1
2,4-Dichlorophenol ND ug/L 05/23/20 02:20 120-83-205/18/20 14:115.0 1
Diethylphthalate ND ug/L 05/23/20 02:20 84-66-205/18/20 14:115.0 1
2,4-Dimethylphenol ND ug/L 05/23/20 02:20 105-67-905/18/20 14:1110.0 1
Dimethylphthalate ND ug/L 05/23/20 02:20 131-11-305/18/20 14:115.0 1
Di-n-butylphthalate ND ug/L 05/23/20 02:20 84-74-205/18/20 14:115.0 1
4,6-Dinitro-2-methylphenol ND ug/L 05/23/20 02:20 534-52-105/18/20 14:1110.0 1
2,4-Dinitrophenol ND ug/L 05/23/20 02:20 51-28-505/18/20 14:1150.0 1
2,4-Dinitrotoluene ND ug/L 05/23/20 02:20 121-14-205/18/20 14:115.0 1
2,6-Dinitrotoluene ND ug/L 05/23/20 02:20 606-20-205/18/20 14:115.0 1
Di-n-octylphthalate ND ug/L 05/23/20 02:20 117-84-005/18/20 14:115.0 1
1,2-Diphenylhydrazine ND ug/L 05/23/20 02:20 122-66-705/18/20 14:115.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 05/23/20 02:20 117-81-705/18/20 14:115.0 1
Fluoranthene ND ug/L 05/23/20 02:20 206-44-005/18/20 14:115.0 1
Fluorene ND ug/L 05/23/20 02:20 86-73-705/18/20 14:115.0 1
Hexachloro-1,3-butadiene ND ug/L 05/23/20 02:20 87-68-305/18/20 14:115.0 1
Hexachlorobenzene ND ug/L 05/23/20 02:20 118-74-105/18/20 14:115.0 1
Hexachlorocyclopentadiene ND ug/L 05/23/20 02:20 77-47-405/18/20 14:1110.0 1
Hexachloroethane ND ug/L 05/23/20 02:20 67-72-105/18/20 14:115.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 05/23/20 02:20 193-39-505/18/20 14:115.0 1
Isophorone ND ug/L 05/23/20 02:20 78-59-105/18/20 14:1110.0 1
3&4-Methylphenol(m&p Cresol)ND ug/L 05/23/20 02:20 15831-10-405/18/20 14:1110.0 1
Naphthalene ND ug/L 05/23/20 02:20 91-20-305/18/20 14:115.0 1
Nitrobenzene ND ug/L 05/23/20 02:20 98-95-305/18/20 14:115.0 1
2-Nitrophenol ND ug/L 05/23/20 02:20 88-75-505/18/20 14:115.0 1
4-Nitrophenol ND ug/L 05/23/20 02:20 100-02-705/18/20 14:1110.0 1
N-Nitrosodimethylamine ND ug/L 05/23/20 02:20 62-75-905/18/20 14:115.0 1
N-Nitroso-di-n-propylamine ND ug/L 05/23/20 02:20 621-64-705/18/20 14:115.0 1
N-Nitrosodiphenylamine ND ug/L 05/23/20 02:20 86-30-605/18/20 14:1110.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 05/23/20 02:20 108-60-105/18/20 14:115.0 1
Pentachlorophenol ND ug/L 05/23/20 02:20 87-86-505/18/20 14:1110.0 1
Phenanthrene ND ug/L 05/23/20 02:20 85-01-805/18/20 14:115.0 1
Phenol ND ug/L 05/23/20 02:20 108-95-205/18/20 14:115.0 1
Pyrene ND ug/L 05/23/20 02:20 129-00-0 L105/18/20 14:115.0 1
1,2,4-Trichlorobenzene ND ug/L 05/23/20 02:20 120-82-105/18/20 14:115.0 1
2,4,6-Trichlorophenol ND ug/L 05/23/20 02:20 88-06-205/18/20 14:1110.0 1
Surrogates
Nitrobenzene-d5 (S)23 %05/23/20 02:20 4165-60-005/18/20 14:1110-120 1
2-Fluorobiphenyl (S)19 %05/23/20 02:20 321-60-805/18/20 14:1115-120 1
Terphenyl-d14 (S)78 %05/23/20 02:20 1718-51-005/18/20 14:1111-131 1
Phenol-d6 (S)14 %05/23/20 02:20 13127-88-305/18/20 14:1110-120 1
2-Fluorophenol (S)20 %05/23/20 02:20 367-12-405/18/20 14:1110-120 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Sample:PE Lab ID:92477574001 Collected:05/14/20 09:27 Received:05/14/20 12:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualLimitLimit
Report Reg.
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Surrogates
2,4,6-Tribromophenol (S)57 %05/23/20 02:20 118-79-605/18/20 14:1110-137 1
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
624 Volatile Organics Acrolein
Acrolein ND ug/L 05/15/20 12:53 107-02-8 L15.0 1
Acrylonitrile ND ug/L 05/15/20 12:53 107-13-15.0 1
Benzene ND ug/L 05/15/20 12:53 71-43-21.0 1
Bromodichloromethane ND ug/L 05/15/20 12:53 75-27-42.0 1
Bromoform ND ug/L 05/15/20 12:53 75-25-22.0 1
Bromomethane ND ug/L 05/15/20 12:53 74-83-92.0 1
Carbon tetrachloride ND ug/L 05/15/20 12:53 56-23-52.0 1
Chlorobenzene ND ug/L 05/15/20 12:53 108-90-72.0 1
Chloroethane ND ug/L 05/15/20 12:53 75-00-32.0 1
2-Chloroethylvinyl ether ND ug/L 05/15/20 12:53 110-75-85.0 1
Chloroform ND ug/L 05/15/20 12:53 67-66-32.0 1
Chloromethane ND ug/L 05/15/20 12:53 74-87-32.0 1
Dibromochloromethane ND ug/L 05/15/20 12:53 124-48-12.0 1
1,2-Dichlorobenzene ND ug/L 05/15/20 12:53 95-50-12.0 1
1,3-Dichlorobenzene ND ug/L 05/15/20 12:53 541-73-12.0 1
1,4-Dichlorobenzene ND ug/L 05/15/20 12:53 106-46-72.0 1
1,1-Dichloroethane ND ug/L 05/15/20 12:53 75-34-32.0 1
1,2-Dichloroethane ND ug/L 05/15/20 12:53 107-06-22.0 1
1,1-Dichloroethene ND ug/L 05/15/20 12:53 75-35-42.0 1
cis-1,2-Dichloroethene ND ug/L 05/15/20 12:53 156-59-22.0 1
trans-1,2-Dichloroethene ND ug/L 05/15/20 12:53 156-60-52.0 1
1,2-Dichloropropane ND ug/L 05/15/20 12:53 78-87-52.0 1
cis-1,3-Dichloropropene ND ug/L 05/15/20 12:53 10061-01-52.0 1
trans-1,3-Dichloropropene ND ug/L 05/15/20 12:53 10061-02-62.0 1
Ethylbenzene ND ug/L 05/15/20 12:53 100-41-41.0 1
Methylene Chloride ND ug/L 05/15/20 12:53 75-09-22.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/15/20 12:53 79-34-52.0 1
Tetrachloroethene ND ug/L 05/15/20 12:53 127-18-42.0 1
Toluene ND ug/L 05/15/20 12:53 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 05/15/20 12:53 71-55-62.0 1
1,1,2-Trichloroethane ND ug/L 05/15/20 12:53 79-00-52.0 1
Trichloroethene ND ug/L 05/15/20 12:53 79-01-62.0 1
Trichlorofluoromethane ND ug/L 05/15/20 12:53 75-69-42.0 1
Vinyl chloride ND ug/L 05/15/20 12:53 75-01-42.0 1
Surrogates
4-Bromofluorobenzene (S)99 %05/15/20 12:53 460-00-470-130 1
Toluene-d8 (S)99 %05/15/20 12:53 2037-26-570-130 1
1,2-Dichloroethane-d4 (S)94 %05/15/20 12:53 17060-07-070-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Sample:PE Lab ID:92477574001 Collected:05/14/20 09:27 Received:05/14/20 12:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualLimitLimit
Report Reg.
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 230 mg/L 05/19/20 13:5225.0 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 18.0 mg/L 05/27/20 01:02 7727-37-905/26/20 13:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3 3.8 mg/L 05/22/20 10:200.040 1
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
365.1 Phosphorus, Total
Phosphorus 3.0 mg/L 05/18/20 22:18 7723-14-005/18/20 18:480.050 1
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
420.4 Phenolics, Total
Phenol ND mg/L 05/18/20 14:55 108-95-205/18/20 10:300.020 1
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
Pace Analytical Services - Asheville
4500CNE Cyanide, Total
Cyanide ND mg/L 05/27/20 01:48 57-12-505/27/20 00:050.0080 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Sample:FIELD BLANK Lab ID:92477574002 Collected:05/14/20 11:17 Received:05/14/20 12:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualLimitLimit
Report Reg.
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury ND ng/L 06/02/20 09:57 7439-97-605/28/20 21:040.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
543092
EPA 1664B
EPA 1664B
1664 HEM, Oil and Grease
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2893064
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Oil and Grease mg/L ND 5.0 05/22/20 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2893073LABORATORY CONTROL SAMPLE:
LCSSpike
Oil and Grease mg/L 34.340 86 78-114
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2893494MATRIX SPIKE SAMPLE:
MSSpike
Result
2632045002
Oil and Grease mg/L 43.640 106 78-114ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
544019
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001, 92477574002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2897422
Associated Lab Samples:92477574001, 92477574002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 06/02/20 10:51
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2897423
Associated Lab Samples:92477574001, 92477574002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 05/29/20 11:35
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2897424
Associated Lab Samples:92477574001, 92477574002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 05/29/20 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2897425LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 5.385 108 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2897426MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
20153559001
2897427
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ng/L 25 96 71-125103 5 24255.73 29.8 31.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2897428MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35550137001
2897429
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ng/L 25 93 71-12588 5 24250.25U 23.2 22.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
543000
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2892675
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Antimony ug/L ND 5.0 05/24/20 18:26
Arsenic ug/L ND 10.0 05/27/20 12:21
Beryllium ug/L ND 1.0 05/24/20 18:26
Cadmium ug/L ND 1.0 05/24/20 18:26
Calcium ug/L ND 100 05/24/20 18:26
Chromium ug/L ND 5.0 05/24/20 18:26
Copper ug/L ND 5.0 05/24/20 18:26
Hardness, Total(SM 2340B)ug/L ND 662 05/24/20 18:26
Lead ug/L ND 5.0 05/24/20 18:26
Magnesium ug/L ND 100 05/24/20 18:26
Nickel ug/L ND 5.0 05/24/20 18:26
Selenium ug/L ND 10.0 05/24/20 18:26
Silver ug/L ND 5.0 05/24/20 18:26
Thallium ug/L ND 10.0 05/24/20 18:26
Zinc ug/L ND 10.0 05/24/20 18:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2892676LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 453500 91 85-115
Arsenic ug/L 492500 98 85-115
Beryllium ug/L 451500 90 85-115
Cadmium ug/L 457500 91 85-115
Calcium ug/L 46205000 92 85-115
Chromium ug/L 456500 91 85-115
Copper ug/L 466500 93 85-115
Hardness, Total(SM 2340B)ug/L 3000033100 91 85-115
Lead ug/L 450500 90 85-115
Magnesium ug/L 45005000 90 85-115
Nickel ug/L 455500 91 85-115
Selenium ug/L 437500 87 85-115
Silver ug/L 225250 90 85-115
Thallium ug/L 439500 88 85-115
Zinc ug/L 437500 87 85-115
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2892677MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477518001
2892678
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 94 70-13095 1 20500ND469473
Arsenic ug/L 500 105 70-130105 0 20500ND529528
Beryllium ug/L 500 94 70-13095 1 20500ND469474
Cadmium ug/L 500 92 70-13093 0 20500ND462464
Calcium ug/L 5000 96 70-13096 0 205000111001590015900
Chromium ug/L 500 92 70-13092 1 20500ND462466
Copper ug/L 500 94 70-13095 1 205006.0 477 481
Hardness, Total(SM 2340B)ug/L 33100 94 70-13095 0 2033100526008380083900
Lead ug/L 500 91 70-13091 0 20500ND453453
Magnesium ug/L 5000 94 70-13094 0 20500060301070010700
Nickel ug/L 500 91 70-13092 1 2050013.5 470 474
Selenium ug/L 500 95 70-13095 0 20500ND475477
Silver ug/L 250 92 70-13092 1 20250ND230232
Thallium ug/L 500 87 70-13087 0 20500ND443443
Zinc ug/L 500 89 70-13089 0 2050068.2 515 514
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2892679MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92478429001
2892680
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 109 70-130105 4 20500ND545525
Arsenic ug/L 500 108 70-130107 1 20500ND538533
Beryllium ug/L 500 104 70-130102 3 20500ND522508
Cadmium ug/L 500 97 70-13093 4 20500ND484467
Calcium ug/L E,M1500014670-130222 0 205000131000013200001320000
Chromium ug/L 500 97 70-13094 3 205000.081
mg/L
565 549
Copper ug/L 500 114 70-130110 3 2050084.0 652 636
Hardness, Total(SM 2340B)ug/L 33100 120 70-130147 0 2033100339000034300003440000
Lead ug/L 500 97 70-13095 2 20500ND487476
Magnesium ug/L 5000 104 70-130101 0 205000278003310032900
Nickel ug/L 500 97 70-13094 1 205000.63 mg/L 1110 1100
Selenium ug/L 500 106 70-130105 1 20500ND528524
Silver ug/L 250 108 70-130105 3 20250ND270262
Thallium ug/L 500 95 70-13092 3 20500ND476462
Zinc ug/L 500 93 70-13090 3 20500ND471456
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
541822
EPA 624.1
EPA 624.1
624 MSV with Acrolein
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2887079
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
1,1,1-Trichloroethane ug/L ND 2.0 05/15/20 12:35
1,1,2,2-Tetrachloroethane ug/L ND 2.0 05/15/20 12:35
1,1,2-Trichloroethane ug/L ND 2.0 05/15/20 12:35
1,1-Dichloroethane ug/L ND 2.0 05/15/20 12:35
1,1-Dichloroethene ug/L ND 2.0 05/15/20 12:35
1,2-Dichlorobenzene ug/L ND 2.0 05/15/20 12:35
1,2-Dichloroethane ug/L ND 2.0 05/15/20 12:35
1,2-Dichloropropane ug/L ND 2.0 05/15/20 12:35
1,3-Dichlorobenzene ug/L ND 2.0 05/15/20 12:35
1,4-Dichlorobenzene ug/L ND 2.0 05/15/20 12:35
2-Chloroethylvinyl ether ug/L ND 5.0 05/15/20 12:35
Acrolein ug/L ND 5.0 05/15/20 12:35
Acrylonitrile ug/L ND 5.0 05/15/20 12:35
Benzene ug/L ND 1.0 05/15/20 12:35
Bromodichloromethane ug/L ND 2.0 05/15/20 12:35
Bromoform ug/L ND 2.0 05/15/20 12:35
Bromomethane ug/L ND 2.0 05/15/20 12:35
Carbon tetrachloride ug/L ND 2.0 05/15/20 12:35
Chlorobenzene ug/L ND 2.0 05/15/20 12:35
Chloroethane ug/L ND 2.0 05/15/20 12:35
Chloroform ug/L ND 2.0 05/15/20 12:35
Chloromethane ug/L ND 2.0 05/15/20 12:35
cis-1,2-Dichloroethene ug/L ND 2.0 05/15/20 12:35
cis-1,3-Dichloropropene ug/L ND 2.0 05/15/20 12:35
Dibromochloromethane ug/L ND 2.0 05/15/20 12:35
Ethylbenzene ug/L ND 1.0 05/15/20 12:35
Methylene Chloride ug/L ND 2.0 05/15/20 12:35
Tetrachloroethene ug/L ND 2.0 05/15/20 12:35
Toluene ug/L ND 1.0 05/15/20 12:35
trans-1,2-Dichloroethene ug/L ND 2.0 05/15/20 12:35
trans-1,3-Dichloropropene ug/L ND 2.0 05/15/20 12:35
Trichloroethene ug/L ND 2.0 05/15/20 12:35
Trichlorofluoromethane ug/L ND 2.0 05/15/20 12:35
Vinyl chloride ug/L ND 2.0 05/15/20 12:35
1,2-Dichloroethane-d4 (S)%94 70-130 05/15/20 12:35
4-Bromofluorobenzene (S)%98 70-130 05/15/20 12:35
Toluene-d8 (S)%101 70-130 05/15/20 12:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2887080LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1-Trichloroethane ug/L 19.120 96 70-130
1,1,2,2-Tetrachloroethane ug/L 21.820 109 60-140
1,1,2-Trichloroethane ug/L 20.320 101 70-130
1,1-Dichloroethane ug/L 19.020 95 70-130
1,1-Dichloroethene ug/L 18.120 90 50-150
1,2-Dichlorobenzene ug/L 23.720 119 65-135
1,2-Dichloroethane ug/L 18.120 91 49-155
1,2-Dichloropropane ug/L 20.420 102 35-165
1,3-Dichlorobenzene ug/L 22.220 111 70-130
1,4-Dichlorobenzene ug/L 21.220 106 65-135
2-Chloroethylvinyl ether ug/L 40.040 100 1-225
Acrolein ug/L 201 L110020160-140
Acrylonitrile ug/L 89.1100 89 60-140
Benzene ug/L 20.520 102 65-135
Bromodichloromethane ug/L 19.620 98 65-135
Bromoform ug/L 15.720 78 70-130
Bromomethane ug/L 22.420 112 15-185
Carbon tetrachloride ug/L 20.420 102 70-130
Chlorobenzene ug/L 18.920 95 65-135
Chloroethane ug/L 18.920 94 40-160
Chloroform ug/L 19.820 99 70-135
Chloromethane ug/L 14.120 70 1-205
cis-1,2-Dichloroethene ug/L 18.620 93 68-146
cis-1,3-Dichloropropene ug/L 19.520 97 25-175
Dibromochloromethane ug/L 16.020 80 70-135
Ethylbenzene ug/L 18.220 91 60-140
Methylene Chloride ug/L 17.820 89 60-140
Tetrachloroethene ug/L 17.420 87 70-130
Toluene ug/L 19.620 98 70-130
trans-1,2-Dichloroethene ug/L 18.120 91 70-130
trans-1,3-Dichloropropene ug/L 19.020 95 50-150
Trichloroethene ug/L 18.620 93 65-135
Trichlorofluoromethane ug/L 18.220 91 50-150
Vinyl chloride ug/L 20.620 103 5-195
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2887081MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477574001
2887082
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1-Trichloroethane ug/L 20 104 52-162107 2 3620ND20.8 21.3
1,1,2,2-Tetrachloroethane ug/L 20 100 46-157101 0 6120ND20.0 20.1
1,1,2-Trichloroethane ug/L 20 108 52-150111 2 4520ND21.6 22.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2887081MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477574001
2887082
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1-Dichloroethane ug/L 20 109 59-155103 6 4020ND21.8 20.6
1,1-Dichloroethene ug/L 20 106 1-234107 1 3220ND21.1 21.4
1,2-Dichlorobenzene ug/L 20 110 18-190110 0 5720ND22.1 22.1
1,2-Dichloroethane ug/L 20 97 49-15595 2 4920ND19.5 19.0
1,2-Dichloropropane ug/L 20 109 1-210111 3 5520ND21.7 22.3
1,3-Dichlorobenzene ug/L 20 107 59-156105 2 4320ND21.4 20.9
1,4-Dichlorobenzene ug/L 20 107 18-190107 1 5720ND21.5 21.3
2-Chloroethylvinyl ether ug/L 40 97 1-305103 6 7140ND38.9 41.4
Acrolein ug/L 100 119 40-160113 5 60100ND119113
Acrylonitrile ug/L 100 98 40-160100 2 60100ND97.7 99.5
Benzene ug/L 20 110 37-151114 3 6120ND22.1 22.8
Bromodichloromethane ug/L 20 108 35-155105 3 5620ND21.6 20.9
Bromoform ug/L 20 75 45-16971 6 4220ND15.0 14.1
Bromomethane ug/L 20 106 1-242112 5 6120ND21.1 22.3
Carbon tetrachloride ug/L 20 109 70-140116 6 4120ND21.7 23.2
Chlorobenzene ug/L 20 107 37-160107 1 5320ND21.3 21.5
Chloroethane ug/L 20 102 14-230106 3 7820ND20.5 21.1
Chloroform ug/L 20 105 51-138104 2 5420ND21.4 21.0
Chloromethane ug/L 20 77 1-27378 1 6020ND15.5 15.7
cis-1,2-Dichloroethene ug/L 20 106 45-174102 4 3020ND21.2 20.3
cis-1,3-Dichloropropene ug/L 20 101 1-227102 1 5820ND20.1 20.4
Dibromochloromethane ug/L 20 92 53-14986 6 5020ND18.3 17.3
Ethylbenzene ug/L 20 100 37-16297 2 6320ND20.0 19.5
Methylene Chloride ug/L 20 97 1-22196 1 2820ND19.5 19.3
Tetrachloroethene ug/L 20 102 64-14898 4 3920ND20.4 19.7
Toluene ug/L 20 106 47-150108 2 4120ND21.8 22.2
trans-1,2-Dichloroethene ug/L 20 105 54-156102 2 4520ND20.9 20.5
trans-1,3-Dichloropropene ug/L 20 100 17-183102 1 8620ND20.0 20.3
Trichloroethene ug/L 20 99 70-157106 7 4820ND19.7 21.1
Trichlorofluoromethane ug/L 20 96 17-181107 11 8420ND19.3 21.4
Vinyl chloride ug/L 20 116 1-251116 0 6620ND23.2 23.3
1,2-Dichloroethane-d4 (S)%88 70-13090
4-Bromofluorobenzene (S)%100 70-13098
Toluene-d8 (S)%100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
542031
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2888216
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 05/21/20 00:45
1,2-Dichlorobenzene ug/L ND 5.0 05/21/20 00:45
1,2-Diphenylhydrazine ug/L ND 5.0 05/21/20 00:45
1,3-Dichlorobenzene ug/L ND 5.0 05/21/20 00:45
1,4-Dichlorobenzene ug/L ND 5.0 05/21/20 00:45
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 05/21/20 00:45
2,4,6-Trichlorophenol ug/L ND 10.0 05/21/20 00:45
2,4-Dichlorophenol ug/L ND 5.0 05/21/20 00:45
2,4-Dimethylphenol ug/L ND 10.0 05/21/20 00:45
2,4-Dinitrophenol ug/L ND 50.0 05/21/20 00:45
2,4-Dinitrotoluene ug/L ND 5.0 05/21/20 00:45
2,6-Dinitrotoluene ug/L ND 5.0 05/21/20 00:45
2-Chloronaphthalene ug/L ND 5.0 05/21/20 00:45
2-Chlorophenol ug/L ND 5.0 05/21/20 00:45
2-Nitrophenol ug/L ND 5.0 05/21/20 00:45
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 05/21/20 00:45
3,3'-Dichlorobenzidine ug/L ND 10.0 05/21/20 00:45
4,6-Dinitro-2-methylphenol ug/L ND 10.0 05/21/20 00:45
4-Bromophenylphenyl ether ug/L ND 5.0 05/21/20 00:45
4-Chloro-3-methylphenol ug/L ND 5.0 05/21/20 00:45
4-Chlorophenylphenyl ether ug/L ND 5.0 05/21/20 00:45
4-Nitrophenol ug/L ND 10.0 05/21/20 00:45
Acenaphthene ug/L ND 5.0 05/21/20 00:45
Acenaphthylene ug/L ND 5.0 05/21/20 00:45
Anthracene ug/L ND 5.0 05/21/20 00:45
Benzidine ug/L ND 50.0 05/21/20 00:45
Benzo(a)anthracene ug/L ND 5.0 05/21/20 00:45
Benzo(a)pyrene ug/L ND 5.0 05/21/20 00:45
Benzo(b)fluoranthene ug/L ND 5.0 05/21/20 00:45
Benzo(g,h,i)perylene ug/L ND 5.0 05/21/20 00:45
Benzo(k)fluoranthene ug/L ND 5.0 05/21/20 00:45
bis(2-Chloroethoxy)methane ug/L ND 10.0 05/21/20 00:45
bis(2-Chloroethyl) ether ug/L ND 5.0 05/21/20 00:45
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 05/21/20 00:45
Butylbenzylphthalate ug/L ND 5.0 05/21/20 00:45
Chrysene ug/L ND 5.0 05/21/20 00:45
Di-n-butylphthalate ug/L ND 5.0 05/21/20 00:45
Di-n-octylphthalate ug/L ND 5.0 05/21/20 00:45
Dibenz(a,h)anthracene ug/L ND 5.0 05/21/20 00:45
Diethylphthalate ug/L ND 5.0 05/21/20 00:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2888216
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Dimethylphthalate ug/L ND 5.0 05/21/20 00:45
Fluoranthene ug/L ND 5.0 05/21/20 00:45
Fluorene ug/L ND 5.0 05/21/20 00:45
Hexachloro-1,3-butadiene ug/L ND 5.0 05/21/20 00:45
Hexachlorobenzene ug/L ND 5.0 05/21/20 00:45
Hexachlorocyclopentadiene ug/L ND 10.0 05/21/20 00:45
Hexachloroethane ug/L ND 5.0 05/21/20 00:45
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 05/21/20 00:45
Isophorone ug/L ND 10.0 05/21/20 00:45
N-Nitroso-di-n-propylamine ug/L ND 5.0 05/21/20 00:45
N-Nitrosodimethylamine ug/L ND 5.0 05/21/20 00:45
N-Nitrosodiphenylamine ug/L ND 10.0 05/21/20 00:45
Naphthalene ug/L ND 5.0 05/21/20 00:45
Nitrobenzene ug/L ND 5.0 05/21/20 00:45
Pentachlorophenol ug/L ND 10.0 05/21/20 00:45
Phenanthrene ug/L ND 5.0 05/21/20 00:45
Phenol ug/L ND 5.0 05/21/20 00:45
Pyrene ug/L ND 5.0 05/21/20 00:45
2,4,6-Tribromophenol (S)%100 10-137 05/21/20 00:45
2-Fluorobiphenyl (S)%92 15-120 05/21/20 00:45
2-Fluorophenol (S)%97 10-120 05/21/20 00:45
Nitrobenzene-d5 (S)%112 10-120 05/21/20 00:45
Phenol-d6 (S)%74 10-120 05/21/20 00:45
Terphenyl-d14 (S)%133 11-131 S305/21/20 00:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2888217LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 42.750 85 44-142
1,2-Dichlorobenzene ug/L 43.850 88 32-129
1,2-Diphenylhydrazine ug/L 53.950 108 25-150
1,3-Dichlorobenzene ug/L 43.650 87 1-172
1,4-Dichlorobenzene ug/L 44.950 90 20-124
2,2'-Oxybis(1-chloropropane)ug/L 51.250 102 36-166
2,4,6-Trichlorophenol ug/L 55.750 111 37-144
2,4-Dichlorophenol ug/L 54.250 108 1-191
2,4-Dimethylphenol ug/L 51.250 102 32-119
2,4-Dinitrophenol ug/L 306250 122 1-181
2,4-Dinitrotoluene ug/L 52.250 104 39-139
2,6-Dinitrotoluene ug/L 58.450 117 50-158
2-Chloronaphthalene ug/L 52.750 105 60-118
2-Chlorophenol ug/L 53.250 106 23-134
2-Nitrophenol ug/L 52.650 105 29-182
3&4-Methylphenol(m&p Cresol)ug/L 55.550 111 25-150
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Page 18 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2888217LABORATORY CONTROL SAMPLE:
LCSSpike
3,3'-Dichlorobenzidine ug/L 111100 111 1-262
4,6-Dinitro-2-methylphenol ug/L 106100 106 1-181
4-Bromophenylphenyl ether ug/L 47.750 95 53-127
4-Chloro-3-methylphenol ug/L 104100 104 22-147
4-Chlorophenylphenyl ether ug/L 48.750 97 25-158
4-Nitrophenol ug/L 216250 86 1-132
Acenaphthene ug/L 49.050 98 47-145
Acenaphthylene ug/L 49.250 98 33-145
Anthracene ug/L 53.450 107 1-166
Benzidine ug/L 7.3J L2100710-130
Benzo(a)anthracene ug/L 57.350 115 33-143
Benzo(a)pyrene ug/L 55.550 111 17-163
Benzo(b)fluoranthene ug/L 58.350 117 24-159
Benzo(g,h,i)perylene ug/L 58.450 117 1-219
Benzo(k)fluoranthene ug/L 56.950 114 11-162
bis(2-Chloroethoxy)methane ug/L 49.350 99 33-184
bis(2-Chloroethyl) ether ug/L 49.650 99 12-158
bis(2-Ethylhexyl)phthalate ug/L 53.750 107 8-158
Butylbenzylphthalate ug/L 56.450 113 1-152
Chrysene ug/L 56.450 113 17-168
Di-n-butylphthalate ug/L 57.150 114 1-118
Di-n-octylphthalate ug/L 60.250 120 4-146
Dibenz(a,h)anthracene ug/L 58.150 116 1-227
Diethylphthalate ug/L 53.650 107 1-114
Dimethylphthalate ug/L 54.950 110 1-112
Fluoranthene ug/L 54.950 110 26-137
Fluorene ug/L 48.650 97 59-121
Hexachloro-1,3-butadiene ug/L 37.850 76 24-116
Hexachlorobenzene ug/L 46.650 93 1-152
Hexachlorocyclopentadiene ug/L 45.550 91 25-150
Hexachloroethane ug/L 44.950 90 40-113
Indeno(1,2,3-cd)pyrene ug/L 56.450 113 1-171
Isophorone ug/L 53.750 107 21-196
N-Nitroso-di-n-propylamine ug/L 56.350 113 1-230
N-Nitrosodimethylamine ug/L 51.250 102 25-150
N-Nitrosodiphenylamine ug/L 53.050 106 25-150
Naphthalene ug/L 46.350 93 21-133
Nitrobenzene ug/L 51.750 103 35-180
Pentachlorophenol ug/L 109100 109 14-176
Phenanthrene ug/L 53.350 107 54-120
Phenol ug/L 39.850 80 5-112
Pyrene ug/L 62.3 L15012552-115
2,4,6-Tribromophenol (S)%96 10-137
2-Fluorobiphenyl (S)%94 15-120
2-Fluorophenol (S)%85 10-120
Nitrobenzene-d5 (S)%100 10-120
Phenol-d6 (S)%75 10-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Page 19 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2888217LABORATORY CONTROL SAMPLE:
LCSSpike
Terphenyl-d14 (S)%125 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2888218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477517001
2888219
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 72 44-14261 16 3050ND35.8 30.4
1,2-Dichlorobenzene ug/L 50 66 32-12962 7 3050ND33.2 30.8
1,2-Diphenylhydrazine ug/L 50 78 25-15065 19 3050ND39.2 32.3
1,3-Dichlorobenzene ug/L 50 70 1-17261 13 3050ND34.8 30.7
1,4-Dichlorobenzene ug/L 50 75 20-12464 15 3050ND37.4 32.0
2,2'-Oxybis(1-
chloropropane)
ug/L 50 86 36-16669 22 3050ND42.8 34.5
2,4,6-Trichlorophenol ug/L 50 96 37-14473 27 3050ND47.8 36.6
2,4-Dichlorophenol ug/L 50 87 1-19172 19 3050ND43.6 36.0
2,4-Dimethylphenol ug/L 50 93 32-11976 20 3050ND46.3 37.8
2,4-Dinitrophenol ug/L R1250981-18124 121 30250ND24559.9
2,4-Dinitrotoluene ug/L 50 90 39-13974 20 3050ND45.0 36.8
2,6-Dinitrotoluene ug/L 50 98 50-15874 28 3050ND49.1 37.1
2-Chloronaphthalene ug/L R1509160-11866 31 3050ND45.3 33.0
2-Chlorophenol ug/L 50 73 23-13465 13 3050ND36.7 32.3
2-Nitrophenol ug/L 50 88 29-18273 19 3050ND44.0 36.4
3&4-Methylphenol(m&p
Cresol)
ug/L 50 67 25-15063 7 3050ND33.6 31.5
3,3'-Dichlorobenzidine ug/L 100 4 1-26274 30100ND3.9J 74.4
4,6-Dinitro-2-methylphenol ug/L R1100991-18170 35 30100ND98.9 69.6
4-Bromophenylphenyl ether ug/L 50 83 53-12768 20 3050ND41.7 34.1
4-Chloro-3-methylphenol ug/L R11008622-14763 31 30100ND85.6 62.6
4-Chlorophenylphenyl ether ug/L 50 82 25-15869 16 3050ND40.9 34.7
4-Nitrophenol ug/L 250 60 1-13245 29 30250ND151113
Acenaphthene ug/L 50 81 47-14568 17 3050ND40.6 34.2
Acenaphthylene ug/L 50 82 33-14568 19 3050ND41.0 34.0
Anthracene ug/L 50 88 1-16671 21 3050ND43.9 35.5
Benzidine ug/L M0100010-13040 30100NDND40.1J
Benzo(a)anthracene ug/L 50 100 33-14380 23 3050ND50.2 39.9
Benzo(a)pyrene ug/L 50 98 17-16379 21 3050ND49.0 39.7
Benzo(b)fluoranthene ug/L 50 103 24-15978 27 3050ND51.4 39.2
Benzo(g,h,i)perylene ug/L 50 100 1-21977 26 3050ND49.9 38.5
Benzo(k)fluoranthene ug/L 50 100 11-16280 21 3050ND49.8 40.2
bis(2-
Chloroethoxy)methane
ug/L 50 91 33-18473 22 3050ND45.7 36.6
bis(2-Chloroethyl) ether ug/L 50 78 12-15867 15 3050ND39.1 33.5
bis(2-Ethylhexyl)phthalate ug/L 50 93 8-15874 22 3050ND49.1 39.4
Butylbenzylphthalate ug/L 50 101 1-15274 30 3050ND50.4 37.2
Chrysene ug/L 50 101 17-16876 28 3050ND50.3 37.9
Di-n-butylphthalate ug/L 50 95 1-11876 22 3050ND47.4 37.9
REPORT OF LABORATORY ANALYSIS
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Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2888218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477517001
2888219
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Di-n-octylphthalate ug/L 50 102 4-14690 13 3050ND50.8 44.8
Dibenz(a,h)anthracene ug/L 50 104 1-22779 28 3050ND52.1 39.3
Diethylphthalate ug/L 50 84 1-11469 20 3050ND41.9 34.3
Dimethylphthalate ug/L R150971-11271 31 3050ND48.4 35.3
Fluoranthene ug/L 50 96 26-13776 23 3050ND47.9 38.0
Fluorene ug/L 50 82 59-12169 17 3050ND40.9 34.5
Hexachloro-1,3-butadiene ug/L 50 65 24-11655 17 3050ND32.3 27.3
Hexachlorobenzene ug/L 50 84 1-15269 20 3050ND42.2 34.5
Hexachlorocyclopentadiene ug/L 50 81 25-15063 25 3050ND40.4 31.4
Hexachloroethane ug/L 50 67 40-11362 8 3050ND33.6 31.2
Indeno(1,2,3-cd)pyrene ug/L 50 98 1-17175 27 3050ND49.2 37.6
Isophorone ug/L 50 93 21-19669 30 3050ND46.4 34.4
N-Nitroso-di-n-propylamine ug/L 50 82 1-23074 10 3050ND41.0 37.0
N-Nitrosodimethylamine ug/L 50 72 25-15062 15 3050ND36.2 31.1
N-Nitrosodiphenylamine ug/L 50 85 25-15069 21 3050ND42.7 34.5
Naphthalene ug/L 50 79 21-13361 24 3050ND39.3 30.7
Nitrobenzene ug/L 50 91 35-18069 27 3050ND45.3 34.5
Pentachlorophenol ug/L R110011214-17677 37 30100ND11277.3
Phenanthrene ug/L 50 88 54-12070 23 3050ND44.1 35.0
Phenol ug/L 50 49 5-11242 15 3050ND24.6 21.2
Pyrene ug/L 50 98 52-11574 27 3050ND49.0 37.2
2,4,6-Tribromophenol (S)%98 10-13779
2-Fluorobiphenyl (S)%96 15-12070
2-Fluorophenol (S)%65 10-12055
Nitrobenzene-d5 (S)%97 10-12076
Phenol-d6 (S)%51 10-12046
Terphenyl-d14 (S)%115 11-13188
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
542289
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2889356
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 05/19/20 13:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2889357LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 248250 99 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92477759001
2889358SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 161 1 25160
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92477574001
2889359SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 228 1 25230
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Asheville, NC 28804
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
543359
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2894089
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 05/27/20 00:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2894090LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 9.310 93 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2894091MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477401001
2894092
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 96 90-11094 2 10102.6 12.2 12.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2894093MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477429001
2894094
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 92 90-11097 5 10101.5 10.7 11.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Asheville, NC 28804
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
542884
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, preserved
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2892031
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Nitrogen, NO2 plus NO3 mg/L ND 0.040 05/22/20 09:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2892032LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, NO2 plus NO3 mg/L 2.62.5 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2892033MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477262001
2892034
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L M12.5 86 90-11087 1 102.50.20 2.4 2.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2892035MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477512001
2892036
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L 2.5 96 90-11096 0 102.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
542156
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
365.1 Phosphorus, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2888881
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Phosphorus mg/L ND 0.050 05/18/20 22:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2888882LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2888883MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477498002
2888884
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/L M1,
M6,R1
2.5 30 90-1101390 120 102.510.5 11.3 45.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2888885MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477770001
2888886
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/L 2.5 98 90-110101 2 102.50.12 2.6 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Asheville, NC 28804
[phone]
Page 25 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
542038
EPA 420.4 Rev 1.0 1993
EPA 420.4 Rev 1.0 1993
420.4 Phenolics
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2888239
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Phenol mg/L ND 0.020 05/18/20 14:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2888240LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol mg/L 0.0480.05 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2888241MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92477574001
2888242
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phenol mg/L 0.05 92 90-11090 3 100.05ND 0.049 0.047
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
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Asheville, NC 28804
[phone]
Page 26 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
543525
SM 4500-CN-E-2011
SM 4500-CN-E-2011
4500CNE Cyanide, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92477574001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2894968
Associated Lab Samples:92477574001
Matrix:Water
Analyzed
Cyanide mg/L ND 0.0080 05/27/20 01:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2894969LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.110.1 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2894970MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
2631916005
2894971
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 97 80-12090 7 100.1ND 0.10 0.096
REPORT OF LABORATORY ANALYSIS
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Page 27 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
RPD value was outside control limits.R1
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 28 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92477574
PERMITTED PPA 5/14/20
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92477574001 543092PEEPA 1664B
92477574001 543000 543019PEEPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92477574001 544019 544117PEEPA 1631E EPA 1631E
92477574002 544019 544117FIELD BLANK EPA 1631E EPA 1631E
92477574001 542031 542407PEEPA 625.1 EPA 625.1
92477574001 541822PEEPA 624.1
92477574001 542289PESM 2540C-2011
92477574001 543359 543544PEEPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92477574001 542884PEEPA 353.2 Rev 2.0 1993
92477574001 542156 542218PEEPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993
92477574001 542038 542066PEEPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993
92477574001 543525 543546PESM 4500-CN-E-2011 SM 4500-CN-E-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/02/2020 11:56 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 29 of 32
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