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HomeMy WebLinkAboutWQ0000430_Application_202001150101 0 EEO Application For Renewal of Permit NO. WQ0000430 Land Application of Town of Cherryville, NC Residuals Prepared by: Alex Fox Synagro Central, LLC 284 Boger Road Mocksville, NC 27028 P 336-998-7150 F 336-998-8450 December 10, 2019 December 31, 2019 N.C. Department of Environment and Natural Resources Division of Water Resources Aquifer Protection Section — Land Application Unit 1636 Mail Service Center Raleigh, NC 27699-1636 ATTENTION: Mr. Nathaniel Thornburg REFERENCE: APPLICATION FOR RENEWAL OF PERMIT # WQ0000430 City of Cherryville Dear Mr. Thornburg: On behalf of the City of Cherryville, Synagro is submitting the additional information requested by your office. The LASC, RSC and the spill control have been updated. Attached is the records for the 30 Day Bench as well. The soil work has been fixed to include Hg in the Baseline test. This application package should contain all of the information necessary to complete the requested renewal of the City of Cherryville's permit. However, if you require additional information or have further questions, please contact me at 336-703-8681 or afox@synagro.com Thank you in advance for the timely and efficient review of this renewal application. Sincerely, Alex Fox o�0F w a rF,�QG State of North Carolina Department of Environment and Natural Resources j Division of Water Quality ft 'C RESIDUALS LAND APPLICATION PROGRAM INSTRUCTIONS FOR FORM: RLAP 08-11 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation For more information or for an electronic version of this form, visit the Land Application Unit (LAU) web site at: http: //portal. ncdenr. orgAveb/wg/aps/lau General — This application is for treatment, storage, transport, and/or land application of Class B residuals (may include residuals that are generated from a water treatment plant or other type facilities) on the proposed or currently approved land application site(s) under 15A NCAC 02T. 1100. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Residuals Land Application Program (FORM: RLAP 08-11) Application: (All Application Packages): Submit the completed and appropriately executed Residuals Land Application Program (FORM: RLAP 08-11) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. The Applicant's Certification on Page 5 of this form shall be signed in accordance with 15A NCAC 02T .0106(b). An alternate person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A NCAC 02T .0106(b). ® If this project is for a modification of an existing permit, submit one copy of the existing permit. ® Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units. B. Application Fee (New and Major Modification Application Packages) Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environment and Natural Resources (NCDENR). STANDARD REVIEW — Submit the appropriate fee for all new and major modification applications as listed in the table below. EXPRESS REVIEW — Visit the Express Review webpage for the Express Fee Schedule: STANDARD APPLICATION REVIEW FEES: Facility Classification I New Permit I Major Modification 1 Major (land are permitted for > 300 acres) 1 $1,310 1 $395 Minor (land are permitted for < 300 acres) 1 $810 1 $245 ' - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage; adds additional land application areas not previously approved; adds additional residuals sources; or includes the addition of new treatment or storage units/processes not previously permitted. There is no fee for minor permit modifications. C. Cover Letter (All Application Packages) List all items included in the application package, as well as a brief description of the requested permitting action. D. Environmental Assessments (May be Required — See 15A NCAC 1 C .0300) Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for the construction of the subject facilities. INSTRUCTIONS FOR FORM: RLAP 08-11 Page 1 of 3 E. Operation and Maintenance Plan (New and Renewal Application Packages) For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan. Submit the O&M Plan in accordance with 15A NCAC 02T . 1110 and include at a minimum: Operational functions; describe the operation of the program to show what operations are necessary for the program to function and by whom the functions are to be conducted. ® Maintenance schedules; may include equipments calibration, maintenance of signs, etc. ® Safety measures; may include safety training program, manuals, signs, etc. ® Spill response plan; including control, containment, remediation, emergency contact information, etc. ® Inspection plan including the following information; ® Names and titles of personnel responsible for conducting the inspections. Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the selected location(s) and inspection frequency are representative of the residuals management program. Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event that noncompliance is observed. ® Sampling and monitoring plan including the following information; ® Names and titles of personnel responsible for conducting the sampling and monitoring. ® Detailed description of monitoring procedures including parameters to be monitored. ® Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature, flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to meet pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected by cold temperatures. THE FOLLOWING ADDITIONAL ITEMS (G to M) ARE REQUIRED FOR DEDICATED PROGRAM ONLY. F. Program Determination Dedicated residuals land application programs are ones in which land application sites meet the criteria in 15A NCAC 02T .110202). Specifically, a residuals land application program is designated as dedicated if any of the following are applicable: Any land application site certified for the residuals land application program that receives residuals at rates or frequencies greater than agronomic rates. ❑ Any land application site certified for the residuals land application program that is used primarily for residuals disposal, and agricultural crop production is of secondary importance. Any land application site certified for the residuals land application program that receives residuals through fixed irrigation facilities or irrigation facilities fed through a feed supply system. ❑ Please contact the Aquifer Protection Section if you need any assistance in determining whether your residuals program falls under the dedicated program definitions. G. Program Information ❑ Provide an explanation of why a dedicated system is required instead of a conventional non -dedicated system. ❑ Provide an explanation of the dedicated system and its operation. H. Detailed Site Maps (All New or Modification Application Packages) Submit three (3) sets of standard size plans and two (2) sets of I I" by 17" plans (electronic format is acceptable - Adobe PDF only). For Modifications, submit plans specific to the modification(s) only. Plans must include the following minimum items: A general location map, a vicinity map and a topographic map with contours not exceeding 10 feet or 25% of the total site relief and showing all facility related structures and fences within the land application area. The location of all wells (including usage and construction details if available), streams (ephemeral, intermittent, and perennial), springs, lakes, ponds, and other surface drainage features within 500 feet of the land application site(s). Delineation of the review and compliance boundaries Setbacks as required by 15A NCAC 02T .1108 Site property boundaries within 500 feet of all waste treatment, storage, and disposal site(s). A map showing the entire irrigation area with an overlay of the suitable irrigation area depicted by the soil scientist's evaluation. The irrigation plans shall show each nozzle/emitter and wetted area (when applicable). Clearly label spray irrigation zones as they will be operated. Plans must depict a completed design and not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR CONSTRUCTION, etc.) that indicate that they are anything other than final plans. However, the plans may be labeled with the phrase: FINAL DESIGN - NOT RELEASED FOR CONSTRUCTION INSTRUCTIONS FOR FORM: RLAP 08-11 Page 2 of 3 L Project Evaluation and Receiver Site Management Plan (All New Application Packages or Modifications that include new sites) Submit a project evaluation and a receiver site management plan (if applicable) with recommendations concerning cover crops and their ability to accept the proposed application rates. J. Hydrogeologic Report (All New Application Packages or Modifications involving increasing the total design capacity) Submit a detailed hydrogeologic evaluation in accordance with 15A NCAC 02T .1104(d)(4) and current Division Policy available at: http://portal.ncdenr.org/web/wq/ans/lau/policies. The document shall be signed, sealed and dated by a qualified professional. K. Engineering Design Documents (All New or Modification Application Packages with fixed irrigation facilities or irrigation facilities fed through fixed supply system) Submit engineering design documents that have been signed, sealed, and dated by a NC licensed Professional Engineer and/or Professional Land Surveyor in accordance with 15A NCAC 02T . 1104(d)(2). For Modifications, submit an updated site map specific to the modification(s) only. ❑ The design documents must include the following minimum items: Engineering plans for the facility and equipment except those previously permitted unless they are directly tied into the new units or are critical to the understanding of the complete process; Specifications describing materials to be used, method of construction, and means for ensuring quality and integrity of the finished product including leaking testing; and Engineering calculations including hydraulic and pollutant loading, sizing criteria, hydraulic profile, total dynamic head curve analysis for each pump, and irrigation design. Soil mapping units shown on all disposal sites. L. Water Balance (All New Application Packages or Modifications that include new sites utilizing feed irrigation facilities or irrigation facilities fed through fixed supply systems) Submit a completed and accurate water balance in accordance with 15A NCAC 02T .1104(d)(5) and current Division Policy available at: http://portal.ncdenr.ora/web/wq/ans/lau/policies. M. Property Ownership Documentation (All New or Modification Application Packages involving new and/or relocated treatment or irrigation components) Property ownership documentation shall consist of one of the following: Legal documentation of ownership (i.e., GIS, deed or article of incorporation), or Written notarized intent to purchase agreement signed by both parties with a plat or survey map, or An easement running with the land specifically indicating the intended use of the property and meeting the requirements of 15A NCAC 02L .0107(fl, or A written notarized lease agreement signed by both parties, indicating the intended use of the property, as well as a plat or survey map. ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY AQUIFER PROTECTION SECTION LAND APPLICATION UNIT By U.S. Postal Service: 1636 MAIL SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1636 TELEPHONE NUMBER: (919) 733-3221 By Courier/Special Delivery: 2728 CAPITAL BOULEVARD RALEIGH, NORTH CAROLINA 27604 FAX NUMBER: (919) 715-6048 INSTRUCTIONS FOR FORM: RLAP 08-11 Page 3 of 3 o�0F w a rF,�QG State of North Carolina Department of Environment and Natural Resources j Division of Water Quality ft 'C RESIDUALS LAND APPLICATION PROGRAM FORM: RLAP 08-11 L APPLICANT INFORMATION: 1. Applicant's name: City of Cherryville Applicant type: Tn Individual 0 Corporation General Partnership 0 Privately -Owned Public Utility n Federal 0 State Municipal 0 County Signature authority's name per 15A NCAC 02T .0106: Larry Wright Title: Plant Supervisor/ORC Applicant's mailing address: 116 South Mountain Street City: Cherryville State: NC Zip: 28021 Telephone number: (704)-214-1162 Email Address: lwright@ciiyofcherryville.com 2. Consultant's name: Alex Fox License Number (for P.E.): _ Affiliation: 0 On Staff Retained (Firm: Svnagro Central, LLC) Consultant's mailing address: 284 Boger Rd City: Mocksville State: N.C. Zip: 27028 Telephone number: (336)-703-8681 Email Address: afox&synagro.com Agronomist's name: License Number: _ Affiliation: 0 On Staff 0 Retained (Firm: Svnagro Central, LLC) Agronomist's mailing address: City: State: Telephone number: 3. Soil Scientist's name: Zip: Email Address: License Number: Affiliation: 0 On Staff 0 Retained (Firm: Svnagro Central, LLC) Soil Scientist's mailing address: . City: State: Zip: Telephone number: Email IL PERMIT INFORMATION: 1. Application is for (check all that apply): JU new, 0 modified, 0 renewed permit 2. If this application is being submitted to renew or modify an existing permit, provide the following: Permit number: W00000430 Date of most -recently issued permit: 04/24/2015 Date of most -recently certified Attachment A (if different than the permit): Date of most -recently certified Attachment B (if different than the permit): FORM: RLAP 08-11 Page 1 of 5 III. RESIDUALS LAND APPLICATION PROGRAM INFORMATION: 1. Residuals Processing Facility's physical address: 736 Tot Dellinger Road City: Cherryville State: NC Zip: 28021 Coordinates: Latitude: 35' 24'51" Longitude: 81' 22' 08" Datum: NAD83 Level of accuracy: second Method of measurement: MAP 2. County where residuals land application program is headquartered: Gaston 3. List the Operator In Responsible Charge (ORC) and all Back -Up ORCs for the residuals land application program, their certification numbers, and their affiliations in the following table: Designation Name Affiliation Certification Number ORC Robert Michael Cox Synagro Central, LLC LA13191 Back -Up ORC Robert Roth Synagro Central, LLC LA1001672 Additional Back -Up ORCs (if applicable) If an ORC and at least one Back -Up ORC are not currently designated for this residuals land application program, provide the candidates' names, affiliations, and an estimated time schedule for each candidate's completion of the required training school and certification test: Alex Fox Snagxo Central LLC. Scheduled to take class and exam 04/02/2020 Complete the following tables regarding management of the residuals land application program: a. Plant Available Nitrogen Summary: Determine the maximum plant available nitrogen (PAN) generated by all residuals source -generating facilities as currently certified and proposed for certification with this application and list the results in the following table: Maximum amount of residuals to be certified: 273 dry tons per year. PAN Pounds of PAN per Dry Ton (Weighted Average) Pounds of PAN per Year Surface Incorporation or Injection Surface Incorporation or Injection First -Year 21.16 25.38 577 6928 Five -Year Maximum Adjusted 31.92 36.14 8714 9866 b. Land Application Site Use Summary: Summarize information regarding the land application sites as currently certified and proposed for certification with this application: Category Use Acres Comments Crops Forest or Plantation 0.0 _ Row Crops 93.8 _ Hay 0.0 Pasture 22.7 Total: 116.5 Methods Surface 116.5 Incorporation or Injection 0.0 _ Total: 116.5 _ FORM: RLAP 08-11 Page 2 of 5 c. Residuals Land Application Summary: Determine the minimum acreage required to land apply the residuals as currently certified and proposed for certification assuming the scenarios listed in the following table: Assumed Application Rate (lbs PAN/ac yr) Acres Required Using First -Year PAN Concentrations Acres Required Using Five -Year Maximum Adjusted PAN Concentrations Surface Incorporation or Injection Surface Incorporation or Injection 50 115.5 138.6 174.3 197.3 100 57.8 69.3 87.1 98.7 150 38.5 46.2 58.1 65.8 200 28.9 34.6 43.6 49.3 6. If applicable, provide a plan and a schedule to resolve any known issues that would prevent land application of the proposed residuals due to the violation of North Carolina Administrative Code (e.g. not enough storage, not enough land, vector reduction practices not in place, etc.):.56 7. Specify type of residuals program (See Instruction F): 0 Non -dedicated 0 Dedicated If Dedicated, specify the following (check all that apply): IR Residuals program contains any land application site(s) that receives residuals at rates or frequencies greater than agronomic rates, explain; = ❑ Residuals program contains any land application site(s) that is used primarily for residuals disposal, and agricultural crop production is of secondary importance, explain; _ Residuals program contains any land application site(s) that receives residuals through fixed irrigation facilities or irrigation facilities fed through a fixed supply system, explain; _ IV. RESIDUALS SOURCE INFORMATION: (Not required if no new, renewed, or modified residuals source) Complete and submit the following Residuals Source Certification and all associated documentation. R Residuals Source Certification V. LAND APPLICATION SITE INFORMATION: (Not required if no new, renewed, or modified land application site) Complete and submit the following Land Applications Site Certification and all associated documentation. IN Land Application Site Certification.doc FORM: RLAP 08-11 Page 3 of 5 Note: Item VI. Applicable to Dedicated Program with fixed irrigation system only. VI. DESIGN INFORMATION FOR FIXED IRRIGATION SYSTEM 1. The irrigation system is: 0 Spray 0 Drip 2. Disposal system is: 0 existing proposed. 3. Minimum depth to mean seasonal high water table (SHWT) within irrigation sites(s) per Soil Scientist's Evaluation: feet below ground surface. Rules 15A NCAC 02T .0505(o requires at least one -foot vertical separation between SHWT and ground surface. 4. Are there any artificial drainage or water movement structures within 200 feet of any irrigation area? ❑ Yes or JU No If Yes, please explain if the soil scientist report addresses artificial structures and please indicate if structures are to be maintained or modified: _ 5. Loading rates recommended by the Soil Scientist Evaluation: Soil Series Fields within Soil Area Recommended Loading Rate in/hr Recommended Loading Rate in/ r 6. Design loading rates are equal or less than the loading rates recommended by Soil Scientist? JR Yes or JR No If No, explain why 15A NCAC 02T .0505(n) is not met: 7. Non -dedicated System Design (fill in the appropriate information for either a spray or drip irrigation system): Field / Zone Design Area (ft-) Number of Nozzles Maximum Application Rate ( allons/hr) Design Annual Loading Rate ( allons/yr) Total Spray Irrigation Design Element Plan Sheet Number Specification Page Number Wetted diameter of nozzles ft Wetted area of nozzles _ ftz Nozzle capacity _ gpm Nozzle manufacturer / model Elevation of highest nozzle _ ft FORM: RLAP 08-11 Page 4 of 5 Applicant's Certification (signing authority must be in compliance with 15A NCAC 02T .0106): The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105. Yes 0 No, Explain;_ I, Larry Wright Plant Supervisor/ORC (Signature Authority's Name — PLEASE PRINT) (Title) attest that this application for City of Cherryvilli (Facility Name) has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Quality may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action, which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water Quality should a condition of this permit be violated. I also understand that if all required parts of this application are not completed and that if all required supporting information and attachments are not included, this application package will be returned to me as incomplete. Note: In accordance with North Carolina General Statutes §143-215.6A and §143-215.6B, any person who knowingly makes any false statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to exceed $10,000 as well as civil penalties up to $25,000 per violation. Signature: Date: FORM: RLAP 08-11 Page 5 of 5 o�0F w a rF,�QG State of North Carolina Department of Environment and Natural Resources Division of Water Quality ft 'C RESIDUALS SOURCE CERTIFICATION INSTRUCTIONS FOR FORM: RSC 08-11 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and supporting documentation For more information or for an electronic version of this form, visit the Land Application Unit (LAU) web site at: http: //portal. ncdenr. org/webhvq/aps/lau General — This certification provides detailed information of residuals source generating facility and its residuals quality for land application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without a corresponding application form (FORM: RLAP 08-11, FORM: DCAR 08-11, or FORM: SDR 08-11). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Residuals Source Certification (FORM: RSC 08-11): ® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 08-11) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. ® For new or renewed permits, submit a separate certification for each source facility. ❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification. ® Complete the residuals source facility summary page. List all new, renewed, or modified facilities. B. Residuals Source -Generating Facility Information: ® For each source facility, attach the following: ® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for Residuals Land Application Permits". ® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals are to be generated, treated, processed, and stored at the facility. ® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8. Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed, and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during processing. ® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition, ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as they are to be land applied, distributed, and/or disposed. C. Residuals Quality Information: ® For each source facility, attach the following: ® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification. ® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector attraction reduction requirements. ❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please attach analytical results of residuals generated from a similar facility along with the description of similarities of the two facilities. INSTRUCTIONS FOR FORM: RSC 08-11 Page 1 of 1 RESIDUALS SOURCE FACILITY SUMMARY Applicant's name: City of Cherryville Status Code ° Facility Permit Holder Facility Name County Permit Number Maximum Dry Tons Per Year Current n Proposed R City of Cherryville City of Cherryville WWTP Gaston NCO044440 273 273 'Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted) b The amount of residuals currently permitted for distribution, land application, or disposal (i.e, not applicable to new facility). SUMMARY FOR FORM: RSC 08-11 Page 1 o�0F w a rF,�QG State of North Carolina Department of Environment and Natural Resources Division of Water Quality ft 'C RESIDUALS SOURCE CERTIFICATION FORM: RSC 08-11 I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.): 1. Facility Name: City of Cherrvville WWTP 2. Facility permit holder is: ❑ Federal, 0 State, Local Government, or 11 Private. Facility permit issued by: U Div. of Water Quality, Div. of Environmental Health, or W Other (explain: �). 3. Facility contact person and title: Larry Wright, Plant Supervisor, ORC Complete mailing address: 116 South Mountain Street City: Cherryville State: NC Zip: 28021 Telephone number: (704) 214-1162 E-mail address: lwrightkcityofcherryville.com 4. Facility physical address: 736 Tot Dellinger Road City: Cherryville State: NC Zip: 28021 Coordinates: Latitude: 35' 24' 51" Longitude: 81' 22' 08" Datum: NAD83 Level of accuracy: Second Method of measurement: MAP 5. Purpose of the facility: treatment of municipal wastewater, treatment of 100% domestic wastewater, treatment of potable water, treatment of 100% industrial wastewater, treatment of industrial wastewater mixed with domestic wastewater, (approximate percentages: _ % industrial and _ % domestic) other (explain: _ ). 6. Does the facility have an approved pretreatment program: Yes No 7. Facility permitted/design flow: 2.0 MGD and facility average daily flow: 350,000 MGD 8. Average amount of residuals being generated at this facility 108.0 dry tons per year. 9. Specify the following regarding treatment and storage volumes available at the facility: Type and volume of residuals treatment: sludge holding tank: 248,000 gallons Type and volume of residuals storage (i.e., outside of residuals treatment units): sludge lagoon: 250,000 gallons II. RESIDUALS QUALITY INFORMATION (See Instruction C.): 1. Specify if residuals are regulated under: 40 CFR Part 503 or 40 CFR Part 257. Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40 CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257. 2. Specify if residuals are defined under 15A NCAC 02T.1102(6) as: Biological 0 Non -Biological FORM: RSC 08-11 Page 1 of 5 Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems). 3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat 100% non -municipal, domestic wastewater only) a. Are the residuals listed in 40 CFR §261.31-§261.33: " yes no. If yes, list the number(s): _ b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21- 261.24: 0 yes 0 no. Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as well as those for corrosivity, ignitability, and reactivity: Laboratory: Summit Environmental Technologies, Inc. and Date(s) of analysis: 06/05/2019 Passed corrosivity test: 0 yes ❑ no. pH: 7_1 s.u. (2 < pH < 12.5) Passed ignitability test: 0 yes Ld no. Flashpoint: >140 OF (> 140°F) Passed reactivity test: W yes ❑Ino. HCN: nd mg/kg (<250) & H2S: nd mg/kg (<500) TCLP Parameter Limit (m917) Result (m917) TCLP Parameter Limit (m917) Result (m917) Arsenic 5.0 nd Hexachlorobenzene 0.13 nd Barium 100.0 nd Hexachloro-1,3-Butadiene 0.5 nd Benzene 0.5 nd Hexachloroethane 3.0 nd Cadmium 1.0 nd Lead 5.0 nd Carbon Tetrachloride 0.5 nd Lindane 0.4 nd Chlordane 0.03 nd Mercury 0.2 nd Chlorobenzene 100.0 nd Methoxychlor 10.0 nd Chloroform 6.0 nd Methyl Ethyl Ketone 200.0 nd Chromium 5.0 nd Nitrobenzene 2.0 nd m-Cresol 200.0 nd Pentachlorophenol 100.0 nd o-Cresol 200.0 nd Pyridine 5.0 nd p-Cresol 200.0 nd Selenium 1.0 nd Cresol 200.0 nd Silver 5.0 nd 2,4-D 10.0 nd Tetrachloroethylene 0.7 nd 1,4-Dichlorobenzene 7.5 nd Toxaphene 0.5 nd 1,2-Dichloroethane 0.5 nd Trichloroethylene 0.5 nd 1, 1 -Dichloroethylene 0.7 nd 2,4,5-Trichlorophenol 400.0 nd 2,4-Dinitrotoluene 0.13 nd 2,4,6-Trichlorophenol 2.0 nd Endrin 0.02 nd 2,4,5-TP (Silvex) 1.0 nd Heptachlor and its Hydroxide 0.008 nd Vinyl Chloride 0.2 nd FORM: RSC 08-11 Page 2 of 5 4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105. a. For Distribution/Land Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: WayPoint Analytical and Date of analysis: 05/24/2019 Parameter Ceiling Concentration Limits (ClassA & ClassB) (mglkg) Monthly Average Concentration Limits (Class A Only) (mglkg) Result (mglkg) Arsenic 75 41 <5.0 Cadmium 85 39 2.57 Copper 4,300 1,500 996 Lead 840 300 34.7 Mercury 57 17 2.15 Molybdenum 75 n/a 8.44 Nickel 420 420 70.8 Selenium 100 100 <5.0 Zinc 7,500 2,800 897 b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: _ and Date of analysis: _ Distance from Disposal Unit to Boundary to Closest Property Line (meters, check one) Arsenic (mg/kg) Chromium (mg/kg) Nickel (mg/kg) N > 0 but < 25 30 200 210 ❑ > 25 but < 50 34 220 240 ❑ > 50 but < 75 39 260 270 ❑ > 75 but < 100 46 300 320 ❑ > 100 but < 125 53 360 390 ❑ > 125 62 450 420 Result (mg/kg) FORM: RSC 08-11 Page 3 of 5 5. Nutrient/Micronutrient Determination: Complete the following: a. Total solids: 4.51 %. b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and micronutrient parameters: Laboratory: Waypoint Analytical and Date of analysis: 05/24/2019 Parameter Result (mglkg) Aluminum 16,500 Ammonia -Nitrogen 4,220 Calcium 7,590 Magnesium 2,230 Nitrate -Nitrite Nitrogen 195 pH (Standard Unit) 6.7 Phosphorus 12,900 Potassium 1,700 Sodium 833 Total Kjeldahl Nitrogen 31,800 c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 0.56 [Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity and conditions conducive to crop growth]. d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 30 %. This rate is a (check one): JJ default value, or ❑ actually established. If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical justification as to why the selected default value is appropriate to be applied to these residuals: This is a default value for water treatment plant alum residuals. e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table: Application Method First (15) Year PAN Five -Year Maximum Adjusted PAN (mglkg) (mg/kg) Surface 10,579 15,960 Inj ection/Incorporation 12,689 18,070 Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide the results of the latest analyses: No FORM: RSC 08-11 Page 4 of 5 7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements: a. For Distribution/Land Application of Class A or Equivalent: A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids, or A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids. AND one of the followings (except for non -biological residuals): q Alternative 1 [15A NCAC 02T.I 106(b)(3)(A)] - Time/Temperature Compliance. q Alternative 2 [15A NCAC 02T.I 106(b)(3)(13)] - Alkaline Treatment. Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova. q Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova. J Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP). Specify one: ❑ composting, 0 heat drying, heat treatment, ❑ thermophilic aerobic digestion, beta ray irradiation, ❑ gamma ray irradiation, or pasteurization. b. For Land Application of Class B. Alternative 1 [15A NCAC 02T.I 106(c)(1)] - Fecal Coliform Density Demonstration. Alternative 2 [15A NCAC 02T.I 106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP). Specify one: ® aerobic digestion, I air drying, EI anaerobic digestion, LJ composting, or lime stabilization. c. For Surface Disposal: Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above. Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above. Exempt -If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T.1106(a)(2)]. E] Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. 8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements: ❑ Alternative 1 [15A NCAC 02T.1107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion). Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion). Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion). Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion). E] Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes. E] Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization. Alternative 7 [15A NCAC 02T.I 107(a)(7)] - Drying of Stabilized Residuals. E] Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals. E] Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection. E] Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation. q Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.I 107(b)(2)]. n Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically occur when these residuals are applied and left on the land surface. FORM: RSC 08-11 Page 5 of 5 OPERATIONS AND MAINTENANCE PLAN RESIDUALS LAND APPLICATION FOR WQ0000430 (City of Cherryville) Inspection Plan Inspections will be conducted on a weekly basis at the land application site during activities of this project. Inspection frequency is based on the time frame to complete the project and the amount of dry tons to be land applied from the facility. The inspections will consist of inspecting a field that is currently being applied as well as inspecting random fields that have been completed. These inspections will consist of: 1. Verifying that the "Pre -Operations Check List" has been completed and signed by both operational and technical staff. 2. Checking the calculated loads to insure the correct amount of residuals are being land applied. 3. Insuring that all manned equipment has a copy of the spill control plan, the permit, and the operations and maintenance plan. 4. Insuring that the field has been flagged properly and that all buffers are being adhered to. 5. Insuring that the "Crop and Landowner Verification" form has been filled out. 6. Verifying that the residuals have been adequately sampled to confirm compliance. The records will be kept in the project files in the respective office for the project. The Permittee or Inspector shall report by telephone to the NCDENR/DWR Mooresville Regional Office at 704-663-1699, as soon as possible, but no later than 24 hours after, or the next working day, following the occurrence or first knowledge of the occurrence of the following. • Any occurrence with the distribution program resulting in the land application of significant amounts of material that is abnormal in quantity or characteristics. • Any failure of the program that results in a release of material to surface waters. • Any time that self -monitoring information indicates that the program has gone out of compliance with the permit. • Any process unit failure that results in the system not adequately treating the residuals. • Any spill or discharge from a vehicle or piping system during residuals transportation. Any release that requires immediate reporting outside of normal business hours shall be called in to DENR at 800-662- 7956, 800-858-0368, or 919-733-3300. These numbers are to be called in the event of a release to surface waters or the imminent failure of a storage system when the event occurs outside of normal business hours. Within 5 days of the first notice of on occurrence, a written response in the form of a letter shall be sent to DENR outlining the actions taken or proposed actions taken to ensure that the problem does not recur. Persons responsible for inspections on this project are as follows: Mike Cox or his designee is responsible for inspections on this project . OPERATIONS AND MAINTENANCE PLAN RESIDUALS LAND APPLICATION FOR WQ0000430 (City of Cherryville) Sampling Plan Sampling for this project consists of sampling the residuals just before land application is to occur. Based on the dry tonnage of this plant, there will be one sample for each parameter per year. The residuals shall be sampled annually for the following: (Regulatory level in milligrams per liter in parentheses.) Arsenic (5.0) 1, 4-Dichlorobenzene (7.5) Nitrobenzene (2.0) Barium (100.0) 1, 2-Dichloroethane (0.5) Pentachlorophenol (100.0) Benzene (0.5) 1, 1-Dichloroethylene (0.7) Pyridine (5.0) Cadmium (1.0) 2, 4-Dinitrotoluene (0.13) Selenium (1.0) Carbon tetrachloride (0.5) Endrin (0.02) Silver (5.0) Chlordane (0.03) Hexachlorobenzene (0.13 Tetrachloroethylene (0.7) Chlorobenzene (100.0) Heptachlor (and its hydroxide) (0.008) Toxaphene (0.5) Chloroform (6.0) Hexachloro-1,3-butadiene (0.5) Trichloroethylene (0.5) Chromium (5.0) Hexachlorethane (3.0) 2,4,5-Trichlorophenol (400.0) m-Cresol (200.0) Lead (5.0) 2,4,6-Trichlorophenol (2.0) o-Cresol (200.0) Lindane (0.4) 2,4,5 TP ( Silvex) (1.0) p-Cresol (200.0) Mercury (0.2) Vinyl Chloride (0.2) Cresol (200.0) Methoxychlor (10.0) 2,4-D (10.0) Methyl ethyl ketone (200.0) The residuals will also be sampled, based on the chart below, for the following constituents Dry Tons Generated (short tons per year) Monitoring Frequency (Established in 40 CFR 503 and 15A NCAC 02T.1111) <319 1 time per year =>319-<1,650 1 per Quarter (4 times per year) =>1,650-<16,500 1 every 60 days (6 times per year) =>16500 1 every month (12 times per year) Aluminum Ammonia -Nitrogen Arsenic Cadmium Calcium Copper Lead Sodium Adsorption Ratio (SAR) Magnesium Mercury Molybdenum Nickel Nitrate -Nitrite Nitrogen Phosphorous Potassium pH Plant Available Nitrogen (calculation) Selenium Sodium Total Solids Total Kjeldahl Nitrogen Zinc In order to meet pathogen and vector requirements, the material will be sampled for fecal coliform density and the 30- day bench test. The samples will be taken from the digester. Additional samples will be taken for TCLP/RCI and nutrients and metals analysis. Methods of sampling will follow the conditions of the permit and applicable regulations. The following people are responsible for sampling: Marshall Puryear, Technical Services Manager or his designee. SPILL RESPONSE PLAN PROJECT: City of Cherryville Permit W00000430 IN THE UNLIKELY EVENT OF A SPILL, THE FOLLOWING ACTIONS SHALL BE TAKEN IMMEDIATELY: 1. MANAGEMENT OF SPILL CLEAN-UP ACTIVITIES: The Operations Manager shall take immediate charge and initiate clean-up activities. Synagro labor and equipment is to be utilized. In the event additional labor and equipment is required, assistance may be requested from the City of Cherryville or the NC Department of Transportation, and other private contractors as necessary. 2. HALT THE SOURCE OF THE SPILL: Such as a ruptured container or damaged transport unit. 3. CONTAIN THE SPILL: Form a barrier. Sufficient quantities of straw shall be used for such purposes. Earthen barriers may be constructed to augment the straw bale containment area of the spill. The Operations Manager or the person in charge on the spill site will advise the clean-up personnel where to get the straw, lime, and other items necessary to complete the clean-up operation, i.e., local farmers, farm supply centers, nurseries, etc. 4. CLEAN-UP: Employ front-end loaders, vacuum equipment, sludge application vehicles, and/or local septic tank service to remove as much of the spilled material as possible. Straw and/or sand should be scattered in the spill area to soak up the remaining material. The straw- and sand -soaked material will be collected and removed to a disposal area approved by representatives of the state regulatory agency. 5. FINAL CLEAN-UP: Employ rotary brush sweeper if needed, and apply lime to the spill area upon the approval of the clean-up efforts by the state regulatory representative. If the event occurs on private property, the clean-up will be completed to the satisfaction of the property owner and state regulatory representatives. The ultimate goal will be to restore the spill area to its original condition if possible. 6. NOTIFICATION: As soon as possible after the spill occurs, the Synagro Operations Manager or assistant will notify the Synagro Central office, and they will then be responsible for notifying other key Synagro personnel. 7. REPORTING: Synagro Central personnel will notify the Mooresville Regional office for The City of Cherryville WWTP as soon as possible, but not more than 24 hours after, or on the next working day following the occurrence. The Operations Manager shall provide a written report within 48 hours of the spill to the Technical Services Manager. The report shall list all relative information and actions taken. Synagro Central personnel will file a written report to the Mooresville Regional office of the NCDENR within 5 days of the occurrence. For after hours reporting the Division's emergency number shall be called to report all incidences (800-662-7956 or 800-858-0368 or 919-733-3300) Contact Numbers: Mocksville Regional Office- 336-790-1610 Quantitative Justification for Residuals Production Rate Facility: City of Cherryville WWTP Maximum Permitted Rate: 273 dry tons/year Justification: The City of Cherryville's WWTP currently produces an average (for the past five years) of just over 108 dry tons of biosolids per year. The calculations below indicate that the average daily flow is less than one million gallons per day. The amount of production has been variable, but, for the past five years, no greater than 70 percent of the permitted tonnage (273 dry tons). Calculations: Based on rule -of -thumb that average daily flow is approximate to annual volume of residuals produced: (1,000,000 gal/yr) x (4 % solids) 8.5 lbs/gal) z 170 dt/yr (2,000 lbs/ton) Residuals Sampling Plan City of Cherryville Land Application Program Nutrient and Metal Analysis Sampling Point: Biosolids Storage Lagoon Sampling Frequency: Annual or event specific Sample Type: Composite Lab: Waypoint Analytical Pathogen Reduction Sampling Point: Biosolids Storage Lagoon Sampling Frequency: Annual or event specific Sample Type: Grab Lab: Cameron Testing Services, Inc. Vector Attraction Reduction Sampling Point: Biosolids Storage Lagoon Sampling Frequency: Annual or event specific Sample Type: Composite Lab: Cameron Testing Services, Inc. TCLP/RCI Sampling Point: Biosolids Storage Lagoon Sampling Frequency: Annual Sample Type: Composite Lab: Shealy Environmental OPERATIONS AND MAINTENANCE PLAN RESIDUALS LAND APPLICATION FOR WQ0000430 (City of Cherryville) Operational Functions The operational function of this project involves land application of residuals for the City of Cherryville's wastewater treatment plant. This material will be loaded onto tractor trailers or "spreader trucks" and hauled to land application sites. The residuals will be spread at agronomic rates, as determined by a recently analyzed nutrients and metals sample. The material will be land applied with a liquid applicator that will use pressure to achieve a consistent spread pattern. The fields applied will have a crop, either established or planted soon after application, which is to be utilized for animal consumption. Safety Measures Synagro believes in operating in a safety -conscious manner and has all employees participate in quarterly online safety courses. These courses are designed to help employees recognize safety issues and take steps to prevent accidents from occurring. In addition, all Synagro employees have the authority to stop operations if they think any aspect of the operation could cause environmental or personal harm. Maintenance Schedule Synagro will follow the maintenance schedule specified by their fleet management section for the equipment necessary to complete the job. VICINITY MAP SYNAGRO i5 a�''rM1 h i T taus •, r7V+ .e. } l"y i, e t i9i0 k� a 1736 Tot Dellinger Road 16 0 Fi636 16 77 b ��P Yi4 6421 aValmart Supercenter i Sa White Pines $y. Dellview ,,� -�,-� s• � p96V4wrRd tL� Cheryville rp x °c i431 a � s F i4i6 Google laze Hr COUNTY: Gaston OWNER(S): Cherryville WWTP t¢. F D ¢ uj N c W CA w• (j w uj \ x o Lu cr V z \ A w cs z \y�, Z z ea � a A r O z _ U A O_ -•r - m ti z Z o a w J d X A O � A � �t Lu LLJ a W ¢ 7 -+ Z cr FF6 W C= A W. W F-, q LLI a o Lid V1N� �P osil . FIGURE 1-1 PLANT LAYOUT Analytical Results Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 05/14/2019 Reported: 05/15/2019 For: Cherryville WWTP Comments: Geometric Mean: <1775 MPNIg STATESVILLE ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 190514-37-01 Fecal Coliforms 1 <2381 MPNIg SM92210E-2oo6 05/14/2019 CL 190514-37-01 Percent Solids 1 0.84 % SM2540B-2011 05/14/2019 CL 190514-37-02 Fecal Coliforms 2 <1515 MPNIg SM92210E-2oo6 05/14/2019 CL 190514-37-02 Percent Solids 2 1.32 ova SM25400-2011 05/14/2019 CL 190514-37-03 Fecal Coliforms 3 <1961 MPNIg SM92210E-2006 05/14/2019 CL 190514-37-03 Percent Solids 3 1.02 % SM2540B-2011 05/14/2019 CL 190514-37-04 Fecal Coliforms 4 <1156 MPNIg SM92210E-2006 05/14/2019 CL 190514-37-04 Percent Solids 4 1.73 % SM25408-2011 05/14/2019 CL 190514-37-05 Fecal Coliforms 5 <1905 MPN/g SM92210E-2006 05/14/2019 CL 190514-37-05 Percent Solids 5 1.05 % SM2540a-2011 05/14/2019 CL 190514-37-06 Fecal Coliforms 6 <2105 MPNIg SM92210E-2006 05/14/2019 CL 190514-37-06 Percent Solids 6 0.95 1110 SM25408-2011 05/14/2019 CL 190514-37-07 Fecal Coliforms 7 <1695 MPNIg SM92210E-2006 05/14/2019 CL 190514-37-07 Percent Solids 7 1.18 % SM2540B-2011 05/14/2019 CL Respectfully submitted, �0� ,411ft-." , Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 190514-37-01 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-02 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on lee Sample Number 190514-37-03 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-04 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-05 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-06 Temp on Arrival: 2.3 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-07 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 O ao a x N ry 00 rn m ro rD z n N 00 M Do V m 00 V o � Cn lD v Client: rt STA'[>?5VI4.LEANALYnCAL ] 22 Court sued PA Box 228 Address: Statesville, NC 28687 (704)872.4697 i Chlain of Contact Person: Phone #FAX# �3fo (� G U Custody Record PO # Requisitioned by: (Time Date) Customer Sample ICW ta6dp # Time sampled (Grab Onl/) pate Sampled (Grab On9y) Matrix seudx w ww p requested for analysis ti.L4o , raS vto1 i3�i .4"' 4)S Relinquished by: Time am<mDate SJ•,_TJj Sampled by: Received by: Time am, pm Date- ! Transported by: w-- Relinquished by: Time am, pm Date / �/ Holding times met: Received by: Time am, pm Date �i _ J Compliance work: OMPOite SO[i1RJhg #1: Time begin am, pm Date _I_f Non-compliance work: Time and am, pm Date —J_! Lab Comments: Samples Transported On ice: Time begin am, pm Date f Time end am, pm Date TI I Initials: SUMM111 ENVIRONMENTAL TECHNOLOMZ3. INC ArrzrJy0ca1 Laboralorhn June 05, 2019 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Cherryville WWTP Dear Erik Bruce: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com Order No.: 19051264 Summit Environmental Technologies, Inc. received 1 sample(s) on 5/16/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAT CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH00923201 1 -1, Virginia VELAP 9456, Washington C891 Page 1 of 35 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL rEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 19051264 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 6/5/2019 CLIENT: Synagro Project: Cherryville WWTP WorkOrder Narrative: 19051264: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 19051264-OOIA TCLP-SVOC_8270E: The CCV (Batch R98606) exhibited high recovery of 2,4- Dinitrotoluene. The associated samples are ND for 2,4-Dinitrotoluene. 19051264-OOIA TCLP-SVOC-CPest(8081B): CCV exhibited high recoveries for Endrin. Associated samples were ND Revision v 1 Page 2 of 35 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S Ekiwlt OMM@N-rALTECHN❑LOG{r,S,INC Cuyahoga Falls, Ohio442� WO#: 19051264 ArralyUcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-446 Wehsite: httn:11www.settek.co, Date: 6/5/2019 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low () or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low () or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low () or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low () or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Revision v 1 Page 3 of 35 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIROMMEWAL YECHNO ijULES. INC. Cuyahoga Falls, Ohio 44223 Analytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Cherryville WWTP Lab SampleID Client Sample ID 19051264-001 Chenyville WWI'P Tag No Date Collected 5/14/2019 11:00:00 AM Workorder Sample Summary WO#: 19051264 05 Jun-l9 Date Received Matrix 5/16/2019 10:20:00 AM Sludge Page 4 of 35 mm'y Summit Environmental Technologies, Inc. DATES REPORT su3310 Win St. ENVIROIJMENTALTECHNOLOG 4r;S.INC Cuyahoga Falls, Ohio44223 WO#: 19051264 Arrzrjo�cal Laboralorhm TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19051264-OOIA Chenyville WWTP 5/14/2019 11:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 6/3/2019 5:55:23 PM pH (SW9045D) 5/31/2019 3:40:31 PM Reactive Cyanide (9014/7.3.3.2)-Solid 5/17/2019 8:10:00 PM Reactive Sulfide (9034)/7.3.4.2 5/17/2019 8:10:00 PM SVOC SW-846: 8151 Herbicides-TCL 5/18/2019 6:00:00 PM 5/24/2019 2:15:00 PM 6/1/2019 8:31:00 AM TCLP Mercury Analysis (SW1311/74 i 5/18/2019 6:00:00 PM 5/20/2019 2:35:00 PM 5/20/2019 6:58:00 PM TCLP Metals Analysis (SW 1311/6010 5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 8:27:03 PM TCLP Metals Analysis (SW 1311/6010 5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 4:04:46 PM TCLP Pesticides Analysis (SW 1311/8(5/18/2019 6:00:00 PM 5/24/2019 1:00:06 PM 5/31/2019 11:17:00 PM TCLP Semi-Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 1:00:00 PM 5/21/2019 3:47:00 PM (SW1311/8270) TCLP Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 5:32:00 PM Revision vl Page 5 of 35 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arralyi9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19051264 Date Reported: 6/5/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -LIQUID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00500 mg/L SW7470A SW7470A Analyst: DNS 1 5/20/2019 6:58:00 PM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW6010D SW301OA Analyst: KMO TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM TCLP Barium(Ba) ND 12.5 mg/L 1 5/22/2019 4:04:46 PM TCLP Cadmium(Ccl) ND 0.250 mg/L 1 5/22/2019 4:04:46 PM TCLP Chromium(Cr) ND 0.500 mg/L 1 5/22/2019 4:04:46 PM TCLP Lead(Pb) ND 1.25 mg/L 1 5/22/2019 8:27:03 PM TCLP Selenium(Se) ND 0.125 mg/L 1 5/22/2019 4:04:46 PM TCLP Silver(Ag) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8270 SW351OC Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM 2,4-Dinitrotoluene ND 0.0400 QC+ mg/L 2 5/21/2019 3:47:00 PM Cresols, Total ND 4.00 mg/L 2 5/21/2019 3:47:00 PM Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 5/21/2019 3:47:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 5/21/2019 3:47:00 PM Hexachloroethane ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM Nitrobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM Pentachlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM Pyridine ND 0.200 mg/L 2 5/21/2019 3:47:00 PM Surr: 2-Fluorophenol 53.3 10 - 109 %Rec 2 5/21/2019 3:47:00 PM Surr: Phenol-d6 64.7 10 - 109 %Rec 2 5/21/2019 3:47:00 PM Surr: Nitrobenzene-d5 49.6 19 - 120 %Rec 2 5/21/2019 3:47:00 PM Surr: 2,4,6-Tribromophenol 96.5 10 - 120 %Rec 2 5/21/2019 3:47:00 PM Surr: 2-Fluorobiphenyl 49.4 22 - 117 %Rec 2 5/21/2019 3:47:00 PM Surr: p-Terphenyl-d14 85.9 34 - 116 %Rec 2 5/21/2019 3:47:00 PM Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision v 1 RL Reporting Detection Limit U Samples with CalcVal <MDL Page 6 of 35 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arrafyi9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19051264 Date Reported: 6/5/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8081 SW351OC Analyst: SFG TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.0250 mg/L 10 5/31/2019 11:17:00 PM Toxaphene ND 0.0500 mg/L 10 5/31/2019 11:17:00 PM Endrin ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM gamma-BHC ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM Heptachlor ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM Heptachlor epoxide ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM Methoxychlor ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM Surr: TCMX 61.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM Surr: DCB 76.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SVOC SW-846: 8151 HERBICIDES-TCLP SW8151A SW8151A Analyst: MES 2,4-D ND 0.0100 mg/L 1 6/1/2019 8:31:00 AM 2,4,5-TP ND 0.00500 mg/L 1 6/1/2019 8:31:00 AM Surr: 2,4-Dichlorophenylacetic aci 70.8 20 - 140 %Rec 1 6/1/2019 8:31:00 AM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8260 Analyst: CTB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.500 mg/L 100 5/20/20195:32:00PM 1,2-Dichloroethane ND 0.500 mg/L 100 5/20/2019 5:32:00 PM MEK ND 10.0 mg/L 100 5/20/2019 5:32:00 PM Benzene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Carbon tetrachloride ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Chlorobenzene ND 5.00 mg/L 100 5/20/2019 5:32:00 PM Chloroform ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Tetrachloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Trichloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Vinyl chloride ND 0.200 mg/L 100 5/20/2019 5:32:00 PM Surr: 4-Bromofluorobenzene 102 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Surr: Dibromofluoromethane 96.7 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Surr: Toluene-d8 107 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision v 1 RL Reporting Detection Limit U Samples with CalcVal <MDL Page 7 of 35 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVITtONMENTAL TECHNQLOGlr,$.IRC Cuyahoga Falls, Ohio 44223 Arralyi9cal Laboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19051264 Date Reported: 6/5/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed RCISOLID-W/ IGNITABILITY1030 SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.476 mg/Kg 1 5/17/2019 8:10:00 PM RCISOLID-W/ IGNITABILITY1030 SW1030 Analyst: CXS IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability nonflammable 1 6/3/2019 5:55:23 PM RCISOLID-W/ IGNITABILITY1030 SW9045D Analyst: VVK PH (SW9045D) pH 7.1 s.u.@20.9C 1 5/31/2019 3:40:31 PM RCISOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 5/17/2019 8:10:00 PM Qualifiers: E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit RL Reporting Detection Limit H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits Revision vl U Samples with CalcVal <MDL Page 8 of 35 Summit Environmental Technologies, Inc. Accreditation Program fr 3310 Win St. summlmr Anal�7n tes Report ENOROMMEWAL IrECHHOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y Arralytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Wehsite: http://www.settek.com 05 Jun-l9 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 19051264-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.32)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.42 Sulfide, Reactive U Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4,5-TP A Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Version #3 Page 9 of 35 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report EMOROMMEWAL YECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Wehsite: http://www.settek.com 05 Jun-l9 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 19051264-OOIA Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Version #3 Page 10 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTAL I ECHMGLOC4r.S. WC Cuyahoga Falls, Ohio 44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37518 Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124011 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2309 105 70 130 TCLP Cadmium(Cd) 2.04 0.100 2.000 0 102 70 130 TCLP Chromium(Cr) 2.16 0.200 2.000 0 108 70 130 TCLP Selenium(Se) 2.32 0.0500 2.000 0 116 70 130 TCLP Silver(Ag) 2.43 0.500 2.000 0.0007661 122 70 130 Sample ID 19051239-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124012 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.19 0.500 2.000 0 109 70 130 2.267 3.48 20 TCLP Barium(Ba) ND 5.00 2.000 0.2309 101 70 130 0 0 20 TCLP Cadmium(Cd) 1.96 0.100 2.000 0 97.8 70 130 2.036 4.02 20 TCLP Chromium(Cr) 2.08 0.200 2.000 0 104 70 130 2.159 3.78 20 TCLP Selenium(Se) 2.24 0.0500 2.000 0 112 70 130 2.323 3.45 20 TCLP Silver(Ag) 2.34 0.500 2.000 0.0007661 117 70 130 2.432 3.95 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 11 of 35 MM Summit Environmental Technologies, Inc. QC SUMMARY REPORT SUEF 3310 Win St. ENVI;i014MENTAL I ECHROLOC4r.S. WC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37518 Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124063 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Lead(Pb) 2.16 0.500 2.000 0.01223 107 70 130 Sample ID 19051239-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124064 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Lead(Pb) 2.16 0.500 2.000 0.01223 108 70 130 2.157 0.351 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 O RSD is greater than RSDlimit P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Page 12 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTAL I ECHMGLOC4r.S. WC Cuyahoga Falls, Ohio 44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37518 Sample ID MB-37518 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499 Client ID: PBS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118254 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-37518 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499 Client ID: LCSS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118255 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.11 0.500 2.000 0 105 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 106 80 120 TCLP Cadmium(Cd) 1.95 0.100 2.000 0 97.3 80 120 TCLP Chromium(Cr) 2.19 0.200 2.000 0 110 80 120 TCLP Lead(Pb) 2.23 0.500 2.000 0 ill 80 120 TCLP Selenium(Se) 2.17 0.0500 2.000 0 108 80 120 TCLP Silver(Ag) 2.32 0.500 2.000 0 116 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 13 of 35 SUEF MM Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVI;i014MENTAL I ECHNOLOC4r.S. WC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37523 TCLP Mercury ND 0.00200 TCLP Mercury 0.00397 0.00200 0.00400 0 99.2 80 120 TCLP Mercury 0.00435 0.00200 0.00400 0.0000500 108 75 125 Sample ID 19051026-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/20/2019 RunNo: 98535 Client ID: BatchQC Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117849 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00439 0.00200 0.00400 0.0000500 108 75 125 0.00435 0.915 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 14 of 35 mm1 � Summit Environmental Technologies, Inc. 3310 Win St. ENVIIi014MENtAL I ECHNOLOG4EES, INC Cuyahoga Falls, Ohio 44223 Arra1yVca1 Laboralorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 37523 WO#: 19051264 05-Jun-19 Sample ID 19051026-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/20/2019 RunNo: 98535 Client ID: BatchQC Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117849 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVI$lori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 15 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 37528 WO#: 19051264 05-Jun-19 Sample ID 19051350-001AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120533 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.282 0.0800 0.8000 0 35.3 33.8 126 QMR 2,4,5-Trichlorophenol 0.432 0.200 0.8000 0 54.0 28.7 144 QMR 2,4,6-Trichlorophenol 0.451 0.200 0.8000 0 56.4 12.8 153 QMR 2,4-Dinitrotoluene 0.455 0.0400 0.8000 0 56.9 20.4 155 QC+QMR Cresols, Total ND 4.00 1.600 0 50.3 10 148 QMR Hexachloro-1,3-butadiene 0.281 0.0160 0.8000 0 35.1 29 126 QMR Hexachlorobenzene 0.352 0.0400 0.8000 0 44.0 33.7 134 QMR Hexachloroethane 0.267 0.0800 0.8000 0 33.4 32.8 132 QMR Nitrobenzene 0.358 0.0800 0.8000 0 44.8 20 158 QMR Pentachlorophenol 0.473 0.200 0.8000 0 59.1 10 176 Pyridine 0.254 0.200 0.8000 0 31.7 10 130 Surr:2-Fluorophenol 0.404 1.000 40.4 3.39 130 Surr: Phenol-d6 0.457 1.000 45.7 5 130 Surr: Nitrobenzene-d5 0.344 1.000 34.4 14.5 154 Surr: 2,4,6-Tribromophenol 0.524 1.000 52.4 19.5 130 Surr:2-Fluorobiphenyl 0.350 1.000 35.0 34.4 130 Surr: p-Terphenyl-d14 0.539 1.000 53.9 8.86 156 Sample ID 19051350-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 Client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120534 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVISlOri V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 37528 WO#: 19051264 05-Jun-19 Sample ID 19051350-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120534 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.402 0.0800 1.600 0 25.2 33.8 126 0.2824 35.0 30 RS 2,4,5-Trichlorophenol 0.625 0.200 1.600 0 39.1 28.7 144 0.4320 36.5 30 R 2,4,6-Trichlorophenol 0.634 0.200 1.600 0 39.6 12.8 153 0.4508 33.8 30 R 2,4-Dinitrotoluene 0.654 0.0400 1.600 0 40.9 20.4 155 0.4548 35.9 30 RQC+ Cresols, Total ND 4.00 3.200 0 34.9 10 148 0 0 30 R Hexachloro-1,3-butadiene 0.423 0.0160 1.600 0 26.4 29 126 0.2808 40.5 30 RS Hexachlorobenzene 0.498 0.0400 1.600 0 31.2 33.7 134 0.3520 34.4 30 RS Hexachloroethane 0.374 0.0800 1.600 0 23.4 32.8 132 0.2668 33.6 30 RS Nitrobenzene 0.513 0.0800 1.600 0 32.1 20 158 0.3580 35.6 30 R Pentachlorophenol 0.607 0.200 1.600 0 37.9 10 176 0.4728 24.8 30 Pyridine 0.312 0.200 1.600 0 19.5 10 130 0.2536 20.5 30 Surr:2-Fluorophenol 0.590 2.000 29.5 3.39 130 0 Surr: Phenol-d6 0.646 2.000 32.3 10 130 0 Surr: Nitrobenzene-d5 0.500 2.000 25.0 14.5 154 0 Surr: 2,4,6-Tribromophenol 0.776 2.000 38.8 19.5 130 0 Surr:2-Fluorobiphenyl 0.507 2.000 25.4 34.4 130 0 S Surr: p-Terphenyl-d14 0.754 2.000 37.7 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVISlOri V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 17 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37528 Sample ID MB-37528 SampType: MBLK TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98559 Client ID: PBS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2119054 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0.100 2,4,6-Trichlorophenol ND 0.100 2,4-Dinitrotoluene ND 0.0200 Cresols, Total ND 2.00 Hexachloro-1,3-butadiene ND 0.00800 Hexachlorobenzene ND 0.0200 Hexachloroethane ND 0.0400 Nitrobenzene ND 0.0400 Pentachlorophenol ND 0.100 Pyridine ND 0.100 Surr: 2-Fluorophenol 0.486 Surr: Phenol-d6 0.605 Surr: Nitrobenzene-d5 0.501 Surr: 2,4,6-Tribromophenol 0.585 Surr: 2-Fluorobiphenyl 0.566 Surr: p-Terphenyl-d14 0.676 1.000 48.6 10 109 1.000 60.5 10 109 1.000 50.1 19 120 1.000 58.5 10 120 1.000 56.6 22 117 1.000 67.6 34 116 Sample ID LCS-37528 SampType: LCS TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98559 Client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2119055 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVISlOri V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 37528 WO#: 19051264 05-Jun-19 Sample ID LCS-37528 SampType: LCS TestCode: SVOC-BNA T Units: mg/L Prep Date: 5/20/2019 RunNo: 98559 client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2119055 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.409 0.0400 0.8000 0 51.2 36.4 130 2,4,5-Trichlorophenol 0.571 0.100 0.8000 0 71.4 31.7 132 2,4,6-Trichlorophenol 0.570 0.100 0.8000 0 71.2 31.1 133 2,4-Dinitrotoluene 0.568 0.0200 0.8000 0 71.0 43.3 130 Cresols, Total ND 2.00 1.600 0 65.2 31.7 130 Hexachloro-1,3-butadiene 0.403 0.00800 0.8000 0 50.4 31.4 130 Hexachlorobenzene 0.528 0.0200 0.8000 0 66.0 43.1 130 Hexachloroethane 0.396 0.0400 0.8000 0 49.5 36.5 130 Nitrobenzene 0.499 0.0400 0.8000 0 62.4 39.5 130 Pentachlorophenol 0.518 0.100 0.8000 0 64.8 34 130 Pyridine 0.138 0.100 0.8000 0 17.3 10 130 Surr: 2-Fluorophenol 0.604 1.000 60.4 17.1 130 Surr: Phenol-d6 0.648 1.000 64.8 10 130 Surr: Nitrobenzene-d5 0.615 1.000 61.5 32.6 130 Surr:2,4,6-Tribromophenol 0.714 1.000 71.4 4.43 130 Surr: 2-Fluorobiphenyl 0.621 1.000 62.1 41.8 130 Surr: p-Terphenyl-d14 0.814 1.000 81.4 36.4 130 m Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVISlOri V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 35 MM Summit Environmental Technologies, Inc. QC SUMMARY REPORT SUEF 3310 Win St. ENVI;i014MENTALTECHROLOC4r.S.WC Cuyahoga Falls, Ohio44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37600 Sample ID MB-37600 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799 Client ID: PBS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142057 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 d Heptachlor ND 0.000500 d Heptachlor epoxide ND 0.000500 d Methoxychlor ND 0.000500 d Surr: TCMX 9.56 20.00 47.8 10 119 Surr: DCB 16.6 20.00 82.9 10 119 Sample ID LCS-37600 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799 Client ID: LCSS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142058 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.0101 0.000500 0.0100 0 101 20 216 gamma-BHC 0.00768 0.000500 0.0100 0 76.8 20 197 Heptachlor 0.00679 0.000500 0.0100 0 67.9 20 200 Heptachlor epoxide 0.00803 0.000500 0.0100 0 80.3 20 200 Methoxychlor 0.00978 0.000500 0.0100 0 97.8 20 227 Surr: TCMX 11.5 20.00 57.5 20 143 Surr: DCB 18.7 20.00 93.5 20 151 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Revision vl Page 20 of 35 SUEF MM Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVI;i014MENTALTECHROLOC4r.S.WC Cuyahoga Falls, Ohio44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37650 2,4-D ND 0.0100 0 0 d 2,4,5-TP ND 0.00500 0 0 d Surr: DCAA 253 500.0 50.6 20 140 2,4-D 0.406 0.0100 0.500 0 81.2 43.8 130 2,4,5-TP 0.413 0.00500 0.500 0 82.6 51.5 ill Surr: DCAA 597 500.0 119 34.2 150 Sample ID LCSD-37650 SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034 Client ID: LCSS02 Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141489 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.408 0.0100 0.500 0 81.6 43.8 130 0.406 0.589 30 2,4,5-TP 0.428 0.00500 0.500 0 85.5 51.5 130 0.413 3.54 30 Surr: DCAA 292 500.0 58.3 34.2 150 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 O RSD is greater than RSDlimit P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98525 Sample ID LCS-98525 SampType: LCS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: LCSW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117453 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 70 138 1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 70 130 MEK 0.0961 0.0250 0.100 0 96.1 70 130 Benzene 0.0192 0.00500 0.0200 0 96.0 10 199 Carbon tetrachloride 0.0195 0.00500 0.0200 0 97.4 21.3 240 Chlorobenzene 0.0190 0.00500 0.0200 0 94.8 70 132 Chloroform 0.0193 0.00500 0.0200 0 96.5 70 130 Tetrachloroethene 0.0184 0.00500 0.0200 0 92.2 10 130 Trichloroethene 0.0193 0.00500 0.0200 0 96.6 70 130 Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 70 130 Surr:4-Bromofluorobenzene 50.8 50.00 102 70 130 Surr: Dibromofluoromethane 47.6 50.00 95.2 70 130 Surr: Toluene-d8 54.2 50.00 108 70 130 Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: PBW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117457 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: R98525 WO#: 19051264 05-Jun-19 Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: PBW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117457 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Bromofluorobenzene 50.3 Surr: Dibromofluoromethane 47.4 Surr: Toluene-d8 54.0 50.00 101 70 130 50.00 94.9 70 130 50.00 108 70 130 Sample ID 19051144-00laMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.131 0.0500 0.200 0 65.3 63.8 148 1,2-Dichloroethane 0.170 0.0500 0.200 0 85.0 70 130 MEK 0.943 0.250 1.00 0 94.3 10 130 Benzene 0.727 0.0500 0.200 0.547 89.9 70 130 Carbon tetrachloride 0.142 0.0500 0.200 0 71.0 70 130 Chlorobenzene 0.173 0.0500 0.200 0 86.2 70 130 Chloroform 0.180 0.0500 0.200 0 90.2 70 130 Tetrachloroethene 0.142 0.0500 0.200 0 70.8 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 23 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTALTECHMGLOC4r.S.WC Cuyahoga Falls, Ohio44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: R98525 WO#: 19051264 05-Jun-19 Sample ID 19051144-00laMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Trichloroethene 0.167 0.0500 0.200 0 83.7 70 130 Vinyl chloride 0.138 0.0200 0.200 0 69.2 53.9 141 Surr: 4-Bromofluorobenzene 507 500.0 101 70 130 Surr: Dibromofluoromethane 471 500.0 94.2 70 130 Surr: Toluene-d8 544 500.0 109 70 130 Sample ID 19051144-00laMSD SampType: MSD TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119584 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.144 0.0500 0.200 0 72.0 63.8 148 0.131 9.83 30 1,2-Dichloroethane 0.174 0.0500 0.200 0 87.2 70 130 0.170 2.61 25 MEK 0.927 0.250 1.00 0 92.7 10 130 0.943 1.69 25 Benzene 0.716 0.0500 0.200 0.547 84.6 70 130 0.727 1.48 30 Carbon tetrachloride 0.157 0.0500 0.200 0 78.4 70 130 0.142 9.91 25 Chlorobenzene 0.176 0.0500 0.200 0 88.2 70 130 0.173 2.29 30 Chloroform 0.182 0.0500 0.200 0 91.1 70 130 0.180 0.883 25 Tetrachloroethene 0.154 0.0500 0.200 0 77.0 70 130 0.142 8.25 25 Trichloroethene 0.174 0.0500 0.200 0 87.2 70 130 0.167 4.10 30 Vinyl chloride 0.134 0.0200 0.200 0 66.8 53.9 141 0.138 3.60 25 Surr:4-Bromofluorobenzene 510 500.0 102 70 130 0 25 Surr: Dibromofluoromethane 468 500.0 93.7 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 35 mm1 � Summit Environmental Technologies, Inc. 3310 Win St. ENVIIi014MENtAL I ECHNOL0i,IEES, INC Cuyahoga Falls, Ohio 44223 Arra1yVca1 Laboralorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98525 Sample ID 19051144-00laMSD SampType: MSD TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119584 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: Toluene-d8 547 500.0 109 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVI$lori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 35 MMI� Summit Environmental Technologies, Inc. SU3310 Win St. ENVI;i014MENTAL I ECHNOLOC4r.S. WC Cuyahoga Falls, Ohio 44223 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: R98525 WO#: 19051264 05-Jun-19 Sample ID LCS-98525 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98525 client ID: LCSS Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2119592 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 79.4 131 1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 73.6 137 MEK ND 0.100 0.100 0 96.1 55.1 163 Benzene 0.0192 0.00500 0.0200 0 96.0 73.1 132 Carbon tetrachloride 0.0195 0.00500 0.0200 0 97.4 63.7 139 Chlorobenzene ND 0.0500 0.0200 0 94.8 72.3 139 Chloroform 0.0193 0.00500 0.0200 0 96.5 79.3 129 Tetrachloroethene 0.0184 0.00500 0.0200 0 92.2 56.2 187 Trichloroethene 0.0193 0.00500 0.0200 0 96.6 64.1 138 Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 22.1 147 Surr:4-Bromofluorobenzene 50.8 50.00 102 80.4 126 Surr: Dibromofluoromethane 47.6 50.00 95.2 70.3 125 Surr: Toluene-d8 54.2 50.00 108 82 117 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 35 SUEF MM Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVI;i014MENTALTECHROLOC4r.S.WC Cuyahoga Falls, Ohio44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98750 Cyanide, Reactive ND 0.485 Cyanide, Reactive 9.43 0.490 10.00 0 94.3 85 115 Cyanide, Reactive 0.524 0.490 0.5000 0 105 50 150 Sample ID 19051158-011AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129319 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 10.0 0.500 10.00 0.3081 97.3 81.3 118 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 35 MM Summit Environmental Technologies, Inc. QC SUMMARY REPORT SUEF 3310 Win St. ENVI;i014MENTAL I ECHNOLOC4r.S. WC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98750 Sample ID 19051158-011AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129319 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID 19051158-011AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129320 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 10.2 0.500 10.00 0.3081 98.7 81.3 118 10.04 1.39 5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 O RSD is greater than RSDlimit P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 35 SUEF MM Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVI;i014MENTAL I ECHROLOC4r.S. WC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98776 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4560 25.0 4800 0 95.0 85 115 Sulfide, Reactive 4720 25.0 4800 0 98.3 75 125 Sample ID 19051158-011AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: BatchQC Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130210 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4680 25.0 4800 0 97.5 75 125 4720 0.851 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 29 of 35 mm1 � Summit Environmental Technologies, Inc. 3310 Win St. ENVIIi014MENtAL I ECHNOLOG4EES, INC Cuyahoga Falls, Ohio 44223 Arra1yVca1 Laboralorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: R98776 WO#: 19051264 05-Jun-19 Sample ID 19051158-011AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: BatchQC Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130210 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVI$lori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 30 of 35 MM Summit Environmental Technologies, Inc. QC SUMMARY REPORT SUEF 3310 Win St. ENVI;i014MENTAL I ECHNOLOC4r.S. WC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Arrzr/yVcaf Laboralorfes TEL: (330) 253-8211 FAX- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98995 Sample ID LCS-R98995 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@22.00 Prep Date: RunNo: 98995 Client ID: LCSS Batch ID: R98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2139142 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Sample ID CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@22.3C Prep Date: RunNo: 98995 Client ID: LCSS Batch ID: R98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2140377 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlSlori V 1 O RSD is greater than RSDlimit P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Page 31 of 35 mm1 � Summit Environmental Technologies, Inc. 3310 Win St. ENVIIi014MENtAL I ECHNOLOG4EES, INC Cuyahoga Falls, Ohio 44223 Arra1yVca1 Laboralorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: R98995 WO#: 19051264 05-Jun-19 Sample ID 19052000-001BDUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@20.3C Prep Date: RunNo: 98995 �lient ID: Batch= Batch ID: R98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2140375 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH M 6.9 0.6 5 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVI$lori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 32 of 35 mm1 � Summit Environmental Technologies, Inc. 3310 Win St. ENVIIi014MENtAL I ECHNOL0i,IEES, INC Cuyahoga Falls, Ohio 44223 Arra1yVca1 Laboralorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com QC SUMMARY REPORT WO#: 19051264 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R99073 Sample ID LCS-R99073 SampType: LCS TestCode: Ignitability_S Units: Prep Date: RunNo: 99073 Client ID: LCSS Batch ID: R99073 TestNo: SW1030 Analysis Date: 6/3/2019 SegNo: 2142958 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 7.94 7.240 0 110 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVI$lori V 1 ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 33 of 35 Summit Environmental Technologies, Inc. 3310 will street Analysis Request/Chain of Custody Cuyahoga Falls, Ohio 44223 Tel: 330.253.8211 Fax: 330,253.4489 I or 5url]miL (;aviresnlllental Technologies, Inc- use o Company Name {I'lea4e PrinlS Projccs Nalkrc Pagrz�,r sl"T No S. Analytical hirameters and !4leihads Ceml ny A d •v� Prajocl Adel is Client Phone No- lL}x,n fa Cknl Fax No. Please FaxktDLults Clicnl Enlail Y e36sr Emai . xsuHs J Q wle No. � 11 GC Cl)1ft:1tl F'[: ntil F[r p m yy V S.mrpled by i heck if Ohio VAP +ampler J n w U ri r rL •� •f Oa0 r � � C J t # Sample lrlclslificaliern Ira le 15me { ulkertcd Colle7l¢d .7 V d'Ir..r i ,i:. L AII:Ji'I lril kM�n I% ON 5 - , Nutcsl['umment%; �ralc Of Sulbp c C np, ORCY]MPIJANCI, yE" NU FRTIACATON kFCMi1Rl 7;��j 1I7 N[7 [PORT 7 O SiATP. { p W ONLY) i'f-:S Rcrritrd i n lab, hv'- Ualc 'lime Mnsf he a i owed f if yek pleatir pm+Ide Pws. 5 ru. & r RkLSIF k44]UCSIC� �y; I �. ,ry�x�r arrry,lu4. 9r-:4.la. .sunr!s M— n rm�n Ia:iJµ, :inu Mle by Iah rnanager P 11` �3 W��r ni l rq . riw v m,1 fl- . Whim and ycllcvw pages should amurnpany mFnpl, i,, the Iahew Iury. "Ilk (;lie -?A ML"ac 11w P11A hype-, 121473 Page 34 of 35 �� � � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.com Client Name: SYN-NC-27028 Work Order Number: 19051264 RcptNo: 1 Logged by: Kayla L. Oulton 5/16/2019 10:20:00 AM Completed By: Jesseca E. Westfall 5/16/2019 5:34:18 PM Reviewed By: Jennifer Woolf 5/17/2019 3:21:16 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Log In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 1 1 . Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes V No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 14.6 Goodl Not Present Page 35 of 35 Waypointo ANALYTICAL 5/24/2019 Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 19-136-0211 Project Description: Cherryville WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 5/16/2019 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Virginia 460014 "1'4 Page 1 of 6 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 19-136-0211 Client Project Description: Cherryville WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 SM-4500-NH3C WTN 9045D WTN 4500NO3F-2011 WTN 6010D WTN SW-7471B WTN SM-4500-NH3C-TKN WTN SM-2540G WTN WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354 Page 2 of 6 Report Number: 19-136-0211 Account Number: 46442 Waypoint. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Lab Number: 66425 Sample Id : Cherryville WWTP Project: Cherryville WWTP REPORT OF ANALYSIS Date Sampled: 5/14/2019 11:00:00 Date Received: 05/16/2019 00:00 Date Reported: 05/24/2019 Total Solids 4.51 ADM 05/21/2019 16:54 SM-2540G Moisture' 95.50 ADM 05/21/201916:54 SM-2540G Total Kjeldahl Nitrogen 3.18 31800 250 CLP 05/23/2019 13:30 SM-4500-NH3C-TKN Phosphorus 1.29 12900 50.0 KKM 05/21/2019 23:43 601 OD Potassium 0.17 1700 50.0 KKM 05/21/2019 23:43 601 OD Sulfur 0.79 7880 50.0 KKM 05/21/2019 23:43 601 OD Calcium 0.76 7590 250 KKM 05/21/2019 23:43 601 OD Magnesium 0.22 2230 50.0 KKM 05/21/2019 23:43 601 OD Sodium 0.08 833 250 KKM 05/21/2019 23:43 601 OD Iron 28300 50.0 KKM 05/21/2019 23:43 601 OD Aluminum 16500 50.0 KKM 05/21/2019 23:43 601 OD Manganese 443 5.00 KKM 05/21/2019 23:43 6010D Copper 996 2.50 KKM 05/21/2019 23:43 6010D Zinc 897 12.5 KKM 05/21/2019 23:43 6010D Ammonia Nitrogen 0.42 4220 100 ZBD 05/23/2019 16:00 SM-4500-NH3C Organic N 2.76 27580 250 05/23/2019 13:30 CALCULATION Nitrate+Nitrite-N 195 4.71 ZBD 05/22/201913:46 4500NO3F-2011 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B-Analyte detected in blank H - Beyond Holding Time Powir, #1C 10" rf Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made Pauric McGroary to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Agronomist Page 3 of 6 Report Number: 19-136-0211 Account Number: 46442 Waypoint. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Lab Number: 66425 Sample Id : Cherryville WWTP Project: Cherryville WWTP REPORT OF ANALYSIS Date Sampled: 5/14/2019 11:00:00 Date Received: 05/16/2019 00:00 Date Reported: 05/24/2019 Cadmium 2.57 1.00 KKM 05/21/2019 23:43 601 OD Chromium 147 2.50 KKM 05/21/2019 23:43 601 OD Nickel 70.8 2.50 KKM 05/21/2019 23:43 601 OD Lead 34.7 3.00 KKM 05/21/2019 23:43 601 OD Arsenic <5.00 5.00 KKM 05/21/2019 23:43 601 OD Mercury 2.15 0.0143 TJS 05/22/2019 12:37 SW-7471 B Selenium <5.00 5.00 KKM 05/21/2019 23:43 601 OD pH' 6.7 JSL 05/21/2019 08:40 9045D Molybdenum 8.44 2.50 KKM 05/21/2019 23:43 601 OD Comments: All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B-Analyte detected in blank H - Beyond Holding Time I i�G�QQN Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made Pauric McGroary to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Agronomist Page 4 of 6 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Cooler Receipt Form Customer Number: 46442 Customer Name: Synagro Central LLC/ Cherryville Report Number: 19-136-0211 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Required Custody seals intact on sample bottles? 0 Yes 0 No ® Not Required Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 05/16/2019 13:46:49 Page 5 of 6 ro (4 m rn 0 rn rn SAMPLIIVGLoG# j�� 111�«�I�I�IINIII�i��ll��ll��l��ll�l��fllll�l���1�11��11f�1�1��o .AI�S,iNC. � ���� � �����DY Ch,,,,,jlr 5-75-20is S p 3 CUSTOMER: SYNAGRC Che1FVVFjle VVWTP 13:44:33 RECORD =st that the groper field sampling procedures PROJECT MANAGER: were used during the collection of these samples, Phone: SAMPtEPF— A&L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAD ## SAMPLE I.R. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED Ct�rr4�•��Q ikA,�r'� t r'Y4iA ��� S .SA Ir;Cc ICE (-1-tnI-PI~ Relinquished by Sampler: Date Time Recleved by: REMARKS: .5/o Z � GG Relinquished by- --C- ❑ate Time Vey{ by: _ J ft(D I I q -��s Relinquished by: Dat Time Racleved by: SPECIAL INSTRUCTIONS: WoFar srnrE> monitoring purposes. PO.#: s SAMPLE ANALYSIS REQUEST SL1 SL2 NH4 N NO3 N ❑rganee Cd Cr � Ni I Pb As ' 49 se P11 CaCO3 Volatile Solids MO. Cl ND2�fll poor PO ;0001 SL1: Total Solids (Moisture), Total K;eldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SLI plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Waypointo ANALYTICAL 4/14/2020 Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-099-0001 Project Description: Calvin Wehunt Cherryville WWTP LT-107 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 4/8/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Pam« mar,-- Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 7 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-099-0001 Client Project Description: Calvin Wehunt Cherryville WWTP LT-107 Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70986 4 Solids 04/08/2020 SW-7471B WP MTN 70987 5 Solids 04/08/2020 SW-7471B WP MTN 70988 6 Solids 04/08/2020 SW-7471B WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 7 WayPANALYTICAL 46442 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Synagro Central LLC/ Cherryville Alex Fox Mary Brewer Project Calvin Wehunt Report Date : 04/14/2020 284 Boger Road Information : Cherryville WWTP Received : 04/08/2020 Mocksville , NC 27028 LT- 107 mL 60wr Submitted By : Alex Fox Pauric McGroary Report Number : 20-099-0001 REPORT OFANALYSIS Agronomist Lab No : 70986 Matrix: Solids Sample ID : 4 Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury 0.0256 mg/Kg 0.0148 1 04/13/2011:19 DDB SW-7471B Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 7 WayPANALYTICAL 46442 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Synagro Central LLC/ Cherryville Alex Fox Mary Brewer Project Calvin Wehunt Report Date : 04/14/2020 284 Boger Road Information : Cherryville WWTP Received : 04/08/2020 Mocksville , NC 27028 LT- 107 mL 60wr Submitted By : Alex Fox Pauric McGroary Report Number : 20-099-0001 REPORT OFANALYSIS Agronomist Lab No : 70987 Matrix: Solids Sample ID : 5 Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury 0.0225 mg/Kg 0.0152 1 04/13/2011:20 DDB SW-7471B Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 4 of 7 WayPANALYTICAL 46442 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Synagro Central LLC/ Cherryville Alex Fox Mary Brewer Project Calvin Wehunt Report Date : 04/14/2020 284 Boger Road Information : Cherryville WWTP Received : 04/08/2020 Mocksville , NC 27028 LT- 107 mL 60wr Submitted By : Alex Fox Pauric McGroary Report Number : 20-099-0001 REPORT OFANALYSIS Agronomist Lab No : 70988 Matrix: Solids Sample ID : 6 Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury 0.0540 mg/Kg 0.0146 1 04/13/2011:22 DDB SW-7471B Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 5 of 7 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46442 Customer Name: Synagro Central LLC/ Cherryville Report Number: 20-099-0001 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes ® No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes ® No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 04/08/2020 09:59:41 Page 6 of 7 Waypoint.0 ANALYTICAL 5 III ir���� 1111111111111111111 IN ti1i 46"2 ��, Svnawa Central LLC. w Cherrille fl4-08-2026 calvm 1Nehunl 09 58.07 Account # Grower/Project Information _ nformation t14k_11__ Submitted By Charge To L',/ V Farm ID Field ID Credit Card # CSV Exp. Date. Phone # 76 E-mail address S Crop Info For Recommendations Sample ID Lab Number (Lab Use Only) SIM S2M - Specify additional Tests S3M Soluble Sall's Texture NOa-N Additional Tests Intended Crop Yield Goal Alternative Crop Yield Goal previous Crop B Cu Fe Mn Na 5 Zn s u Mehlich III Test Mackages Special Instructions or Additional Tests S1M - Organic matter, Phosphorus, Potassium, Calcium, Magnesium, pH, Buffer pH Cation Exchange Capacity, and % Base Saturation. S2l'JI - Test S1 M plus any two of the following: Sodium, Sulfur, Boron, Zinc, Manganese, Iron, Copper. Each additional test (above two) cost 100. PM - Test S 1 M pi us Sodium, Sulfur, Boron, Zinc, Manganese, Capper, and iron. J4 fC u P � DWR State of North Carolina Department of Environmental Quality Division of Water Resources Division of Water Resources COUNTY BOARD NOTIFICATION INSTRUCTIONS FOR FORM: CBN 06-16 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and supporting documentation For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit General — This notification is intended to provide the county board in which the land application site is proposed to be located with general information on the size, location and type of residuals land application proposed to occur in their county, and to give them an opportunity to comment on the pending permitting request as stipulated in Session Law 2013-340. Notification is not required for fields deemed permitted to receive Class A residuals under 15A NCAC 02T .1100. Do not submit this document for review without a corresponding residuals program application form (FORM: RLAP 11-15). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. County Board Notification (FORM: CBN 11-15): ® Submit the completed and appropriately executed County Board Notification (FORM: CBN 11-15). Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the form may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. ® Prepare a separate County Board Notification (FORM: CBN 11-15) for each county in which the proposed land application sites are located. B. Critical Watershed Areas Information: ® Under 15A NCAC 02B .0212, no new permitted sites for land application of residuals are allowed within critical watershed areas. It is the Applicant's responsibility to ensure that the proposed land application sites are not located within these areas. ® For more information regarding Water Supply Watershed Protection Program, please visit the Division website at: httDs:Hdea.nc. gov/about/divisions/water-resources/water-resources-rules/water-supply-watershed-protection-pro exam ® If uncertain about whether the proposed sites are located within the critical areas, contact the Division or call (919) 807-6337. C. Notification Package Submission: ® Complete and mail the notification letter, source facility summary, land application site summary, and site location maps to the appropriate County Board by certified mail with a return receipt requested. It is recommended that a copy of the notification package also be sent to the County Manager. ® The most current publication of the Directory of State and County Officials may be downloaded at: hM?s://www.sosnc.goy/publications/direct.aspx ® A list of the Division's regional offices, their county coverage, and their contact information may be downloaded at: hM2:Hdeg.nc.gov/contact/regional-offices. ® The source facility summary shall include: facility name; county where it is located; and the proposed annual dry tonnage (i.e., a copy of "Residuals Source Facility Summary" is adequate but not required). ® The land application site summary shall include: field ID; acreage; county where it is located; latitude and longitude (i.e., a copy of "Land Application Site Certification" is adequate but not required). D. Proof of Submission: ® Attach an 8.5 by 11-inch copy of the return receipt to the back of this attachment prior to submission of the application to the Division for review. INSTRUCTIONS FOR FORM: CBN 06-16 Page 1 of 1 North Carolina Department of Environmental Quality Pat McCrory Donald R. van der Vaart Governor Secretary Date: 01/2/2020 To: Name of Chairman to the Board of County Commissioners: Carrol Mitchem Complete mailing address: 7868 Hallman Mill Road City: Vale State: NC Zip: 28168 County where land application sites are located: Lincoln From: Applicant's name: City of Cherr vy ille (on behalf of the Division of Water Resources in accordance with Session Law 2013-340) Contact person and title: Larry Wright Waste Water Superintendent Complete mailing address: 736 Tot Dellinger rd City: Cherr vy ille State: NC Zip: 28021 Telephone number: 704) 214-1162 E-mail address: lwrightkci . ofcherryville.com Subject: Notification of residual land application site proposal This is to notify you that the Applicant listed above will be submitting an application to the Division of Water Resources for the land application of residual solids to site(s) located in your county. During this review, the Division will ensure that all federal and state regulations are enforced. Attached to this form is information regarding residuals - generating sources and locations of the proposed land application sites. Please forward this letter and its associated attachments to the appropriate Department within your County (i.e., Health or Environmental Health Department and Planning Department) if applicable. More information of the land application sites included in this application will be available at the following Division of Water Resources Regional Office: Name of appropriate regional office: NC DEQ Mooresville Complete mailing address: 610 East Center Ave Suite 301 City: Mooresville State: NC Zip: 28115 Telephone number: (704) 663-1699 Expected date of application submission: 01/10/20 Should you desire to comment on this application, please do so no later than 30 calendar days following the expected application submission date. If you have any questions or comments about this notification, or if you would like more information, please contact the appropriate regional office at the telephone number provided above. Thank you in advance for your attention to this matter. Enclosures: Source Facility Summary Land Application Site Summary Maps Non -Discharge Permitting Unit 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Phone: 919-807-6464 \ Internet: httyflPortal.ncdenr.org/web/wg An Equal Opportunity \ Affirmative Action Employer- Made in part with recycled paper P URM: UBN 06-16 o�0F w a rF,�QG State of North Carolina Department of Environment and Natural Resources Division of Water Quality ft 'C LAND APPLICATION SITE CERTIFICATION INSTRUCTIONS FOR FORM: LASC 08-11 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation For more information or for an electronic version of this form, visit the Land Application Unit (LAU) web site at. http: //portal. ncdenr. org/webhvg/aps/lau General — This certification provides detailed information of receiving sites for land application of Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without a corresponding application form (FORM: RLAP 08-11 or FORM: SDR 08-11). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Land Application Site Certification (FORM: LASC 08-11): ® Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 08-11) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. ® For new or renewed permits, submit the requested information for all land application sites. ® For modified permits, submit the requested information for only those sites that are new, transferred or affected by the proposed modification. B. Land Application Site Information: ® The status of the land application site with respect to this residuals land application program must be provided in table L The status categories and their corresponding codes are as follows: ♦ New (N) ♦ Renewed (R) ♦ Modified (M) ♦ Transferred (T) ♦ Deleted (D) ® Attach the following in accordance with each status code: Status Code Required Item N R T M County Manager Notification W y Land Owner Agreement (If applicable) Setback Waiver Agreement An updated vicinity/setback map in accordance with the "Map Guidance for Residuals Land Application Permits" ✓ ✓ ✓ A soils and agronomic evaluation in accordance with the "Soil Scientist ✓ Evaluation Policy" An updated accounting of the land application site's cumulative ✓ ✓ pollutant loading rates (CPLRs) INSTRUCTIONS FOR FORM: LASC 08-11 Page 1 of 3 Required Item Status Code N R T M For previously permitted sites without a soil series name indicated in the Attachment B, submit County Soil Survey Map (or equivalent) clearly ✓ ✓ ✓ indicate the location of the land application site and in accordance with the soil map requirements in the "Soil Scientist Evaluation Policy" Acknowledgement of field transfer from Permittee relinquishing field ✓ Acknowledgement of field transfer from Land Owner (Fields may not ✓ be permitted to multiple Permittees over the same time period) * This item may be required for land application site with a status code "M", please contact the Division if you need assistant in determining attachment requirements. ® Crop Type should include the most likely crop types for the life of the permit (five years). ® Predominant Soils Series Name must be either the name of the soil indicated in Attachment `B" of the existing permit, or name of the soil series as provided by the licensed soil scientist. ® Predominant Soil Mapping Unit or Representative Slope: Either the Soil Mapping Unit or the representative slope of each site must be provided. The predominant soil -mapping unit must be consistent with the predominant soil series name. Please note that the soil mapping units are variable between Counties, so care should be taken in properly identifying the correct mapping unit. If a representative slope is provided, it must be determined accordingly: ® For sites previously permitted for use, but do not have an established soil mapping unit (the mapping unit provides information on both the soil series name and the slope of the soil), the Applicant may determine the representative slope by using the average slope provided in the County Soil Survey (or equivalent). A soil type with a slope range of 4 - 8% would have a representative slope of 6%. ❑ New Sites to be permitted must have slopes determined as part of the soils report prepared by a licensed soil scientist. ® Acceptable methods for determining location coordinates (i.e., latitude and longitude) and their corresponding codes are as follows: • Address Matching (ADD) • Digital or Raw Photo Extraction (EXT) • Aerial Photography with Ground Control (AER) • Geodetic Quality GPS Survey (GEO) • Cadastral Survey (SUR) • LORAN-C Navigation Device (LOR) • Conversion from Coordinate Plane (CP) • Navigation Quality GPS (GPS) • Conversion from Township -Section -Range (TSR) • Remote Sensing (RS) • Conversion from Universal Trans Mere (UTM) • Zip Code Centroid (ZIP) • Map Interpretation by Digital or Manual Extraction (MAP) C. Waterbody and Classifications Information: (new sites only) ® Use an 8.5 by 11-inch copy of the portion of a 7.5-minute USGS Topographic Map to identify the location where the residuals program activities are planned to occur as well as the closest downslope surface waters as clearly as possible. Each map portion must be labeled with the map name and number, the identified location, and be of clear and reproducible quality. ® Surface water body classifications information may be found at: http://portal.ncdenr.ora/web/wq/�s/csu ❑ Any questions concerning the waterbody and its classification, please contact the Division's regional offices. ❑ A list of the Division's regional offices, their county coverage, and their contact information may be downloaded at: http://portal.ncdenr.ora/web/wg/home/ro ❑ General Instructions: There are 17 river basins in North Carolina. Each basin has associated waterbodies with assigned subbasins, location descriptions, stream index numbers and established classifications. 1. Identify the project area on a 7.5 minute USGS topographical map (an 8.5 x 11-inch sheet showing the project area should be submitted with the permit application regardless of whether a Stream classification was completed). 2. Determine the names of all the closest down slope surface waters from the project site. For unnamed tributaries, see Table 1: Unnamed Tributaries Entering Other States or for Specific Basin Areas. Label any unnamed tributaries as "UT to stream name" as the waterbody name. 3. Open the link hU://h2o.enr.state.nc.us/bims/reports/reportsWB.htrnl. If this link does not work, open http://portal.ncdenr.org/web/wg//s/csu/classifications and download weekly -updated classification lists for named waterbodies. ❑ Stream Classification Process: One of the options below may be used depending on the known initial project information. ❑ KNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED 1. Select proper basin from the List all Waterbodies in Error! Objects cannot be created from editing field codes. Basin sorted Error! Objects cannot be created from editing field codes. report. Sort hydrologically as this will provide the proper location descriptions if multiple runs. INSTRUCTIONS FOR FORM: LASC 08-11 Page 2 of 3 2. Locate the name of the identified waterbody (from General Directions) on the list. 3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term "source" in the description means the beginning of the waterbody segment (most upstream point). 4. Record all Basins, Stream Index Numbers and Classifications applicable to the project. ❑ KNOWN COUNTY WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED 1. Select the proper county from the List all Waterbodies in Error! Objects cannot be created from editing field codes. county, hydrologically report. 2. Locate the name of the identified waterbody (from General Directions) on the list. 3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term "source" in the description means the beginning of the waterbody segment (most upstream point). 4. Record all Basins, Stream Index Numbers and Classifications applicable to the project. ❑ UNKNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED 1. Use the Clickable basin map to hydrologically sorted list report. 2. Click on the approximate project location to bring up the hydrologically sorted list. 3. Locate the name of the identified waterbody (from General Directions) on the list. 4. For multiple listings of the same waterbody name in the report, select and verify the location description. The term "source" in the description means the beginning of the waterbody segment (most upstream point). 5. Record all Basins, Stream Index Numbers and Classifications applicable to the project. ❑ Notes on index number and unnamed streams: Unnamed Streams 15A NCAC 02B .030l(i). ❑ Any stream which is not named in the schedule of stream classifications carries the same classification as that assigned to the stream segment to which it is tributary (at the point of entry) except: (A) unnamed streams specifically described in the schedule of classifications; (B) unnamed freshwaters tributary to tidal saltwaters will be classified "C"; or (C) after November 1, 1986, any newly created areas of tidal saltwater which are connected to Class SA waters by approved dredging projects will be classified "SC" unless case -by -case reclassification proceedings are conducted. ❑ The following river basins have different policies for unnamed streams entering other states or for specific areas of the basin: Unnamed Tributaries Entering Other States or for Specific Basin Areas Hiwassee River Basin Streams entering Georgia or Tennessee shall be classified "C Tr." Little Tennesse River Basin And Savannah River Drainage Area Streams entering Georgia or Tennessee shall be classified "C Tr." Such streams in the Savannah River drainage area entering South Carolina shall be classified 'B Tr." French Broad River Basin Streams entering Tennessee will be classified "B." Watauga River Basin Streams entering the State of Tennessee are classified "C." Broad River Basin Streams entering South Carolina are classified "C." New River Basin Streams entering the State of Tennessee are classified "C." Catawba River Basin Streams entering South Carolina are classified "C." Yadkin -Pee Dee River Basin Streams entering Virginia are classified "C," and such streams entering South Carolina are classified "C." Lumber River Basin Streams entering South Carolina are classified "C Sw." Roanoke River Basin Streams entering Virginia are classified "C." Except that all backwaters of John H. Kerr Reservoir and the North Carolina portion of streams tributary thereto not otherwise named or described shall carry the classification "B," and all backwaters of Lake Gaston and the North Carolina portion of streams tributary thereto not otherwise named or described shall carry the classification "C and B." Chowan River Basin Streams entering Virginia are classified "C." Tar -Pamlico River Basin All drainage canals not noted in the schedule are classified "C Sw." except the main drainage canals to Pamlico Sound and its bays which shall be classified "SC." Pasquotank River Basin All drainage canals not noted in the schedule are classified "C." INSTRUCTIONS FOR FORM: LASC 08-11 Page 3 of 3 Applicant's name: City of CheMnAlle Land application sites currently certified: 78.3 net acres and Total to be certified: 116.6 net acres. I. LAND APPLICATION SITE INFORMATION (See Instruction B): Predominant Soil Status Codes Site/Field ID Landowners O Lessees or Operator(s) O Net Acres Count y Crop(s) s pO Series Name Mapping Unit or Rep. Slope° R NC-LT-120-02 Wayne Gilbert 27.6 Lincoln Fescue (hay) Cecil CeB2 R NC-LT-120-03 Wayne Gilbert 11.0 Lincoln Row Crops Cecil CeB2 D NC-LT-124-01 Keith Beam Keith Beam 30.0 Lincoln Fescue (pasture) Cecil CeB2 D NC-LT-124-02 Keith Beam Keith Beam 10.1 Lincoln Fescue (pasture) Pacolet PeC2 R NC-LT-107-01 Jason Huitt 10.7 Lincoln Fescue (pasture) Cecil CeB2 R NC-LT-107-02 Jason Huitt 12.0 Lincoln Fescue (pasture) Cecil CeB2 R NC-LT-107-03 Calvin Wehunt 17.0 Lincoln Corn(silage), Sorghum, Cecil CeB2 Sudex N NC-LT-107-04 Calvin Wehunt 10.9 Lincoln escue (pasture) Corn(silage), Rion Somhum, Sudex N NC-LT-107-05 Calvin Wehunt 17.8 Lincoln Fescue (pasture) Corn(silage), Cecil CeB2 Sorghum, Sudex N NC-LT-107-06 Calvin Wehunt 9.5 Lincoln Fescue (pasture) Corn(silage), Cecil CeB2 Somhum, Sudex a Status Code for land application sites are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ T (Transferred) ♦ D (Deleted) b Soil Series Name (i.e. Appling, Cecil, etc.) Mapping Unit must be consistent with those used in the County Soil Survey (i.e. for a 2-8% slope Cecil in Anson County the mapping unit is CeB2) C. WATERBODY AND CLASSIFICATIONS INFORMATION (See Instruction C): Site/Field ID Latitude Longitude Location Datum Location Method Code Location Accuracy Waterbody Subbasin and Stream Index No. Current and Proposed Class NC-LT-107-04 35.4737 -81.4674 NAD 83 MAP Second Little Buffalo Creek WS-111 WS-111 NC-LT-107-05 35.4717 -81.4664 NAD 83 MAP Second Little Buffalo Creek WS-111 WS-111 NC-LT-107-06 35.4701 -81.4633 NAD 83 MAP Second Little Buffalo Creek WS-111 WS-111 State of North Carolina Department of Environment and Natural Resources DW Division. of Water Resources LAND OWNER AGREEMENT Division of Water Resources FORM: LOA 06-16 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted the Applicant shall submit one on final and two co ies of the a lication and supporting documentation For more information, visit the Water Quality Permitting Section's Nan-Dischar a Permitting Unit General — This document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this agreement for review without a corresponding application form (FORM: RLAP 06-16). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Land Owner Agreement (FORM: LOA 06-16): ® Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 06-16) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. 1q ® Prepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the Applicant. ® A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator. _ AGREEMENT FOR THE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND he undersigned landowner or his repregentative hereby dP ,' Applicants name: e0 hereinafter referred to as the Permittee, to land apply -,;,-.".i application site(s) (i.e., see attached setback maps) in Agreement: Special note Residuals Source Lease Land Use or Intended Use of Crops (no-till/over-seed/ Site/Field ID (yes/no) Cropping Patterns (optional) pasture) asture residuals from the following facility(ies) onto the following land accordance with the stipulations and restrictions as given in this The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals wnue Inc Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals. ivision's permit for the residuals land application program and This Agreement shall remain in effect for the length of the D ! iall be renewed each time this permit is renewed. The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement. FORM: LOA 06-16 Pagel of 3 I. STIPULATIONS: 1. The landowner or his representative shall not enter into any additional residuals application contracts or agreements with another permitted entity for the site(s) specified by this Agreement. 2. Should the landowner or his representative lease or otherwise permit the use of the land application site(s) to a third party, the landowner shall be responsible to ensure that the third party agrees and complies with the terms and conditions of this Agreement. 3. The landowner or his representative shall adhere to the provisions of this Agreement until all of the site restrictions (under Section 11) are met. 4. Notification of cancellation of this Agreement shall be immediately forwarded to NCDENR-DWR, Non -Discharge Permitting Unit, 1636 Mail Service Center, Raleigh, NC 27699-1636. 5. The Permittee must request and obtain'a permit modification from the Division prior to a transfer of the land application site(s) to a new landowner. In addition, the current landowner shall give a notice to the new landowner that gives full details of the residuals applied at the land application site(s). 6. The Permittee has provided the landowner or his representative with information and data concerning the residuals land application program, including an analysis of constituents of the residuals, residuals application methods, schedules for typical cropping patterns, a description of the equipment used by the Permittee. 7. The Permittee will provide the landowner or his representative with a copy of the residuals permit prior to commencement of any residuals land application event and a copy of the results of each soil analysis. 8. If -the soil pH of the land application site(s) is not maintained at 6.0 or greater, sufficient amounts of lime shall be applied to achieve a final soil pH of at least 6.0, unless an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop. 9. The landowner or his representative and the Permittee will agree on residuals application rates and schedules based on crop patterns, results of soil samples, and the permitted application limits. 10. The landowner or his representative will provide the Permittee with information regarding the amount and analysis of other sources of nutrients (e.g., fertilizer, unregulated animal waste, etc.) that have been applied to the land application site(s). 11, The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns for the land application sites) prior to each planting season to enable the Permittee to amend this Agreement and schedule residuals land application events at appropriate periods. 12, Specific residuals land application area boundaries shall be clearly marked on the land application site(s) by the Permittee, the landowner, or his representative prior to and during a residuals land application event. 13. The landowner or his representative hereby authorizes the Permittee, local officials, and State officials or their representatives to; enter and inspect any property, premises, or place on or related to the land application site(s) at any reasonable time for the purpose of determining compliance with the permit; establish monitoring facilities on or near the land application site(s) as required by the permit; copy any records that must be kept under the terms and conditions of the permit; take necessary leachate, surface water, groundwater, or soil samples during the ' term of, and 12 months after termination of, this Agreement. RESTRICTIONS: I. Appropriate measures must be taken by the Permittee and/or the landowner or his representative to control public access to the land application site(s) during active use and for the 12-month period following a residuals land application event, Such controls may include the posting of signs that indicate the activities being conducted at the land application site(s). t` 2. Animals shall not be graced on the land application site(s) for a 30-day period following a residuals land application event. Land application sites that are to be used for grazing shall have fencing that will be used to prevent access during these periods after such residuals land application events. 3. Food crops, feed crops, and fiber crops shall not be harvested for a 30-day period following a residuals land application event. 4. Food crops with harvested parts that touch the residuals/soil mixture and are totally above the land surface shall not be harvested for a 14- month period following a residuals land application event. 5. Food crops with harvested parts below the surface of the land shall not be harvested for a 20-month period following a residuals land application event when the residuals remain on the land surface for four months or longer prior to incorporation into the soil. 6. Food crops with harvested parts below the surface of the land shall not be harvested for a 38-month period following a residuals land application event when the residuals remain on the land surface for less than four months prior to incorporation into the soil. 7. Turf grown on land where residuals are applied shall not be harvested for a 12-month period following a residuals land application event. III. ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY: (please check one) 15A NCAC 02L .0107(d) prohibits water supply wells within the compliance boundary. However, 15A NCAC 02T .0I051h1 allows the compliance boundary to be placed closer to the waste disposal area, such that the water supply well is situated outside of the compliance boundary provided the groundwater standards can be met at the newly -established compliance boundary. Please mark one of the following; ❑ A re -defined compliance boundary is needed for field(s) ID: _ (Please include the rationale for the requested re -location of the compliance boundary and attach a map showing the newly proposed pliance boundary to the application package) j A re -defined compliance boundary is not needed for this site. IV. ACKNOWLEDGEMENT OF FIELD TRANSFER: (if needed) ❑ The land application field(s) ID: is currently permitted under another { residuals land application program; Permit Number WQ: The land owner hereby acknowledge that by signing this agreement, he/she is requesting that the field(s) be removed from the previously permitted residuals land application program and transferred into the new program; . (Name of the new program) FORM: LOA 06-16 Page 2 of 3 Landowner's Certification: I certify that I am a deeded landowner of the above -referenced land application site(s) and am authorized to make decisions regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of the deeded landowners. I certify that the above -referenced land application site(s) are not included in any waste disposal contract or agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement, understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of field transfer, and do hereby grant permission to the Permittee to land apply residuals to the laud application site(s) as specified herein. Landowner name: Address: 2 3 City: �` State: Zip: V Z Phone: J'�r` a 7k0 E-mail address:- _vL . t04 VaLe,y' Signature: Date: NORTH CAROLINA, A w �� COUNTY 1, the undersigned Notary Public do hereby certify that b E l/L LP_ kn personally appeared before me this day and acknowledged the due execution of the forgoing instrument. 'I h .���Nvi�ii WITNESS my hand and official seal this the day of , 20 2 C.> Signature and seal: i My commission expires: ; CO\3XA %� Lessee'slOperator's Certification: I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein. Lessee/operator name: Address: City: Phone: Signature: Permittee's Certification: State: E-mail address: I certify that I have read this. Agreement and do hereby agree to Signing official name: Signature: Why Zip: Date: by the stipulations and restrictions as specified herein. Date: t, 3 ^ ZV2_v FORM: LOA 06-16 Page 3 of 3 State of North Carolina Department of Environment and Natural Resources Division of Water Resources `�Dlvlslon of Water Resources LAND OWNER AGREEMENT FORM: LOA 06-16 f� Please use the following instructions as a checklist in order to ensure all required 'items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and supporting documentation For more information, visit the Water Quality Permitting Section's Non-Dischar a Permfttin Unit General -- This document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this agreement for review without a corresponding application form (NORM: RLAP 06-16). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. A. Land Owner Agreement (FORM: LOA 06-16): ® Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 06-16) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. ® Prepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the Applicant. ® A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator. AGREEMENT FOR TIDE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND ae undersigned landowner or his rep esentatiive hereby per}nits. Applicant's name: 1 O JA �/ - CO�11�' _r/ — hereinafter referred to as the Permittee, to land apply residuals from the following facility(ies) onto the following land application site(s) (i.e., see attached setback maps) in accordance with the stipulations and restrictions as given in this Agreement: Special note Lease Land Use or Residuals Source no-tilllover-seed) Sitel�'ield ID Intended Use of Crops a tional (yes/no) Cropping Patterns (optional) pasture) G- L - 10 "ir 7-Al K S The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals. 'This Agreement shall remain in effect for the length of the Division's permit for the residuals land application program and 1�t iall be renewed each time this permit is renewed. The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement. FORM: LOA 06-16 Page I of 3 L STIPULATIONS: 1. The landowner or his representative shalt not enter into any additional residuals application contracts or agreements with another permitted entity for the site(s) specified by this Agreement. 2. Should the landowner or his representative lease or otherwise permit the use of the land application site(s) to a third party, the landowner shall be responsible to ensure that the third party agrees and complies with the terms and conditions of this Agreement. 3. The landowner or his representative shall adhere to the provisions of this Agreement until all of the site restrictions (under Section 11) are met. 4. Notification of cancellation of this Agreement shall be immediately forwarded to NCDENR-DWR, Non -Discharge Permitting Unit, 1636 Mail Service Center, Raleigh, NC 27699-1636. 5. The Permittee must request and obtain a permit modification from the Division prior to a transfer of the land application site(s) to a new landowner. In addition, the current landowner shall give a notice to the new landowner that gives full details of the residuals applied at the land application site(s). 6. The Permittee has provided the landowner or his representative with information and data concerning the residuals land application program, including an analysis of constituents of the residuals, residuals application methods, schedules for typical cropping patterns, a description of the equipment used by the Permittee. 7. The Permittee will provide the landowner or his representative with a copy of the residuals permit prior to commencement of any residuals land application event and a copy of the results of each soil analysis. 8. If -the soil pH of the land. application site(s) is not maintained at 6.0 or greater, sufficient amounts of time shall be applied to achieve a final soil pH of at least 6.0, unless an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop. 9. The landowner or his representative and the Permittee will agree on residuals application rates and schedules based on crop patterns, results of soil samples, and the permitted application limits. 10. The landowner or his representative will provide the Permittee with information regarding the amount and analysis of other sources of nutrients (e.g., fertilizer, unregulated animal waste, etc.) that have been applied to the land application site(s). 11. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns for the land application site(s) prior to each planting season to enable the Permittee to amend this Agreement and schedule residuals land application events at appropriate periods. 12. Specific residuals land application area boundaries shall be clearly marked on the land application site(s) by the Permittee, the landowner, or his representative prior to and during a residuals land application event. 13. The landowner or his representative hereby authorizes the Permittee, local officials, and State officials or their representatives to; enter and inspect any property, premises, or place on or related to the land application site(s) at any reasonable time for the purpose of determining compliance with the permit; establish monitoring facilities on or near the land application site(s) as required by the permit; copy any records that must be kept under the terms and conditions of the permit; take necessary leachate, surface water, groundwater, or soil samples during the term of, and 12 months after termination of, this Agreement. t RESTRICTIONS. 1. Appropriate measures roust be taken by the Permittee and/or the landowner or his representative to control public access to the land application sites) during active use and for the 12-month period following a residuals land application event, Such controls may include the posting of signs that indicate the activities being conducted at the land application site(s). 2. Animals shall not be grazed on the land application site(s) for a 30-day period following a residuals land application event, Land application sites that are to be used for grazing shall have fencing that will be used to prevent access during these periods after such residuals land application events. 3. Food crops, feed crops, and fiber crops shall not be harvested for a 30-day period following a residuals land application event. 4. Food crops with harvested parts that touch the residuals/soil mixture and are totally above the land surface shall not be harvested for a 14- month period following a residuals land application event. 5. Food crops with harvested parts below the surface of the land shall not be harvested for a 20-month period following a residuals land application event when the residuals remain on the land surface for four months or longer prior to incorporation into the soil. 6. Food crops with harvested parts below the surface of the land shall not be harvested for a 38-month period following a residuals land application event when the residuals remain on the land surface for less than four months prior to incorporation into the soil. 7. Turf grown on land where residuals are applied shall not be harvested for a 12-month period following a residuals land application event, M. ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY: (please check one) 15A NCAC 02L .0107(d) prohibits water supply wells within the compliance boundary. However, l3A NCAC 02T .OtO5(hl allows the compliance boundary to be placed closer to the waste disposal area, such that the water supply well is situated outside of the compliance boundary provided the groundwater standards can be met at the newly -established compliance boundary. Please mark one of the following; ❑ A re -defined compliance boundary is needed for field(s) ID: F'-C-P'liance include the rationale for the requested re -location of the compliance boundary and attach a map showing the newly proposed boundary to the application package) A -efined compliance boundary is not needed for this site. IV. ACKNOWLEDGEMENT OF FIELD TRANSFER: (if needed) ❑ The laird application field(s) ID: is currently permitted under another residuals land application program; Permit Number WQ: The land owner hereby acknowledge that by signing this agreement, he/she is requesting that the field(s) be removed from the previously permitted residuals land application program and transferred into the new Drop -ram: (Name of the new program) FORM: LOA 06-16 Page 2 of 3 Landown.er's Certification: I certify that f am a deeded landowner of the above -referenced land application sites) and am authorized to make decisions regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of the deeded landowners. I certify that the above -referenced land application site(s) are not included in any waste disposal contract or agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement, understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of field transfer, and do hereby grant permission to the Permittee td4and apply residuals to the land application sites) as specified herein. �Ae Landowner-name:l Address: TS La ` State: N % Zip: -P R V53 City: _?��� - Phone: 9 E-mail address:-'IDrJ+ Signature: Date: NORTH CAROLINA, &* COUNTY I, the undersigned Notary Public do hereby certify that r\ 4yi personally appeared before me this day and acknowledged the due execution of the forgoing instrument. %111i 10 .�� Ex WITNESS my hand and official seal this the day of r f Signature and seal: " m ► I ,ij� 11. y� ■ ' e My commission expires: 0V• ♦ '-�-;�,� f►�O U Lessee's/Operator's Certification: I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein. Lessee/operator name: Address: City: Phone. - Signature: Permittee's Certification: State: E-mail Date: Zip: I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein. Signing official name: Lc r V'� y i �' [ '�et�r�yllU P• w Signature: Date: 1- 1'3 2o20 FORM: LOA 06-16 ]gage 3 of 3 State of North Carolina I Department of Environment and Natural Resources RDivision of Water Resources ` Division of Water Resararces LAND OWNER AGREEMENT FORM: LOA 06-16 Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional information requested. Failure to submit all of the required items will lead to additional processing and review time for the permit application. Unless otherwise noted the Applicant shall submit one on inal and two copies of the application and sunnortina documentation For more information, visit the Water Quality Permitting Section's Mon -Discharge PermitUag Unit General —`Phis document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T 110 . Do not submit this agreement for review without a corresponding application form (FORM: RLAP 06-16). Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed below. f A. Lapd Owner Agreement (FORM: LOA 06-1.6): Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 06-16) form. Please do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer. dPrepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the Applicant. [U/A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator. AGREEMENT FOR THE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND .ie undersigned landowner or his re Applicant's name: 1,( + 0 hereby perm Ckr rry ✓Y hereinafter referred to as the Permittee, to land apply residuals from thh following facility(ies) onto the following land application site(s) (i.e., see attached setback maps) in accordance with the stipulations and restrictions as given in this Agreement: Site/Field ID Lease Lease band Use or Cropping Patterns Intended Use of Crops Residuals Source (optional) Special note - r-seedl (no-ti pasture) paasture} The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals. _This Agreement shall remain in effect for the length of the Division's permit for the residuals land application program and {( call be renewed each time this permit is renewed. j The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement. FORM: LOA 06-16 Page 1 of 3 Landowner's Certification: I certify that I am a deeded landowner of the above -referenced land application site(s) and aria authorized to make decisions regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of the deeded landowners. I certify that the above -referenced land application sites) are not included in any waste disposal contract or agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement, understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of field transfer, and do hereby grant permission to the Peimittee to Iand apply residuals to the land application site(s) as specified herein. _.e r Landowner name: Address: 'Sa Al CA � Sit," ! city: / 4 State: zip: Phone: O 2 7 --- % mail address: j f Signature: Date: --- NORTH CAROLINA, L."1101 COUNTY I, the undersigned Notary Public do hereby certify that t Ai e r 14 ge personally appeared before me this day and acknowledged the due execution of the forgoing instrument. WITNESS my hand and official seal this the day of 20 ` d;, Signature and seal: W z ►'� My commission expires: '4 _Z Lessee's/Operator's Certification: <<CO1%�`,`, I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein. Lessee/operator name: Address: City: Phone: Signature: Permittee's Certification: I certify that I have read this Agreement and do Signing official name: Signature: State: E-mail Zip: Date: to abide by the stipulations and restrictions as specified herein. Date: FORM: LOA 06-16 Page 3 of 3 SYNAGRO, CHERRYVILLE CLASS B PERMIT WQ 0000430 SOIL SCIENTIST CERTIFICATION This is to certify that soil profile evaluations were conducted on the proposed application sites for the Cherryville WWTP project by Piedmont Environmental Associates, P.A. on behalf of Synagro Central, LLC. The evaluations consisted of hand auger borings and descriptions of the soils on the application sites. All hand auger borings included in this package were either performed by me or under my direct supervision. All other work performed for this permit application was conducted by Synagro Central, LLC. G. Christopher Murray, L.S.S. No. 1284 Synagro, Cherryville WWTP Project, Various Fields Soil Profile Descriptions in Field Locations Project: Cherryville Permit (WQ 0000430) % Slope: 4% Site: Calvin Wehunt Crop: Forage/Pasture Field: Field 4 Conducted By: GC Murray Coordinates: 35.4737 N Date: 11/14/2019 -81.4674 W Soil Series: Rion 0 0 0 0 O x d N 5 z o 5 PIEDMONT ENVIRONMENTAL A S S O C I AT E:, P. A. w w -`a Q W N N c C9 cn d y N O Q co U L L L L O d d d x Z 0 N K 7 7 7 N 5 5 � 5 6. n n 1 5 o�� veep® • • � ®®� Legend. Texture s sand I loam si silt sil silt loam c clay cl clay loam scl sandy clay loam sl sandy loam sicl silty clay loam Structure Grade Structure Type wk weak gr granular m moderate pl platy str strong pr prismatic cpr columnar abk angular blocky sbk subangular blocky sg single grained ma massive Structure Size f fine med medium Moist Consistencv fr friable vfr very friable fi firm vfi very firm Seasonal High Water Table: Depth (") Type (apparent/perched) soli s Soil Profile Descriptions in Field Locations Project: Cherryville Permit (WQ 0000430) % Slope: 4% Site: Calvin Wehunt Crop: Forage/Pasture Field: Field 5 Conducted By: GC Murray Coordinates: 35.4717 N Date: 11/14/2019 -81.4664 W Soil Series: Cecil 0 0 0 0 O x d N 5 z o 5 PIEDMONT ENVIRONMENTAL A S S O C I AT E:, P. A. w w -`a Q W N N c C9 cn d y N O Q co U L L L L O d d d x Z 0 N K 7 7 7 N 5 5 � 5 6. n n 1 5 Ap 0-3 10YR 4/4 - - - - moist sl mod med gr fr ns np AB 3-11 5YR 4/4 - - - - moist scl mod med gr fr ns np Bt 11-41 2.5YR 4/6 - - - - moist cl mod med sbk fi s p BC 41-48 2.5YR 4/6 - - - - moist scl mod med sbk fi s p Legend. Texture s sand I loam si silt sil silt loam c clay cl clay loam scl sandy clay loam sl sandy loam sicl silty clay loam Structure Grade Structure Type wk weak gr granular m moderate pl platy str strong pr prismatic cpr columnar abk angular blocky sbk subangular blocky sg single grained ma massive Structure Size f fine med medium Moist Consistencv fr friable vfr very friable fi firm vfi very firm Seasonal High Water Table: Depth (") Type (apparent/perched) soli s Soil Profile Descriptions in Field Locations Project: Cherryville Permit (WQ 0000430) % Slope: 3% Site: Calvin Wehunt Crop: Forage/Pasture Field: Field 6 Conducted By: GC Murray Coordinates: 35.4701 N Date: 11/14/2019 -81.4633 W Soil Series: Cecil 0 0 0 0 O x d N 5 z o 5 PIEDMONT ENVIRONMENTAL A S S O C I AT E:, P. A. w w -`a Q W N N c C9 cn d y N O Q co U L L L L O d d d x Z 0 N K 7 7 7 N 5 5 � 5 6. n n 1 5 Legend. Texture s sand I loam si silt sil silt loam c clay cl clay loam scl sandy clay loam sl sandy loam sicl silty clay loam Structure Grade Structure Type wk weak gr granular m moderate pl platy str strong pr prismatic cpr columnar abk angular blocky sbk subangular blocky sg single grained ma massive Structure Size f fine med medium Moist Consistencv fr friable vfr very friable fi firm vfi very firm Seasonal High Water Table: Depth (") Type (apparent/perched) soli s % ' o -�i �, A�Qi APPLICATION MAP Q Cl� ■ " . qyv �f J ■ RO �� LEGEND APPLICATION AREA UNSUITABLE AREA — — — — — — PRIVATE ROAD =W WATER �� GRAPHIC SCALE — — — — STREAM ONSITE HOUSE V = 660 — DRAIN 660' 0 660' OFFSITE HOUSE FENCE OUTBUILDING PROPERTY LINE 0 WELL Q SOIL PROFILE The compliance boundary is established either 250 ft from the residuals application area or 50 feet within N C-LT-1 O7 in the property boundary, whichever is closest to the application area. The review boundary is established midway between the compliance boundary and the perimeter of the residuals application area. All locations are approximate. Field 3 a � � a � • 1' • 1 1• 1. 1 1' • • .11 • �