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HomeMy WebLinkAboutNC0024405_Errata_20200505synTerra CORRECTIVE ACTION PLAN UPDATE REVISION 1: APRIL 23, 2020 Site Name and Location: Belews Creek Steam Station 3195 Pine Hall Road Belews Creek, NC 27009 Groundwater Incident No.: 88227 NPDES Permit No.: NCO024406 NCDEQ CCR Impoundment Ranking Low -Risk Date of Report: December 31, 2019 Permittee and Current Duke Energy Carolinas, LLC Property Owner: 526 South Church Street Charlotte, NC 28202-1803 (855)355-7042 Consultant Information: SynTerra Corporation 148 River Street, Suite 220 Greenville, South Carolina 29601-2567 (864) 421-9999 Latitude and Longitude of Facility: N 36.2819444/W-80.0597222 � i4�rirfrnrei r.yrr A R '• z. SE s3� III.'21, ...' Ashley' A4of - ,C'2615 't ��''istlFanager James E` 1 f86f5 St Enthinger E. o V l6 FIGURES 900 800 700 00 00 600 Q Z V Z 500 _O H Q W 400 J W 300 200 100 A --a (SOUTH) f STRUCTURAL FILL COMPLIANCE BOUNDARY m m ■ ■ 0 N az a FILL >In —Al LEGEND AB 9S WELL IN SHALLOW ZONE AB 9D WELL IN DEEP ZONE AB 9BR WELL IN COMPETENT BEDROCK AB 4S WELL IN ASH PORE WATER — GENERALIZED WATER TABLE BEDROCK FRACTURE ORIENTATION �� GENERALIZED GROUNDWATER FLOW DIRECTION �� GENERALIZED ASH PORE WATER FLOW DIRECTION 0 ASH 0 ASH PORE WATER FILL 0 SAPROLITE ® WEATHERED ROCK BEDROCK ASH PORE WATER FLOW LAYER WATER LEVEL ELEVATION ALLUVIUM OR SAPROLITE FLOW LAYER GROUNDWATER LEVEL ELEVATION TRANSITION ZONE FLOW LAYER GROUNDWATER LEVEL ELEVATION BEDROCK FLOW LAYER GROUNDWATER LEVEL ELEVATION R9-UPID MEAN ARSENIC (As) CONCENTRATION (pg/L) Rg MEAN BERYLLIUM (Be) CONCENTRATION (pg/L) ,1 MEAN STRONTIUM (Sr) CONCENTRATION (pg/L) �r MEAN THALLIUM (TI) CONCENTRATION (pg/L) WELL SCREEN — — — COMPLIANCE BOUNDARY NOTES: 1- ALL CON C EN7RA7I ON5 SHOWN ARE STATISTICAL MEAN OR GEOMEAN CALC UALTED BASED ON C ENTRAL TEND ANCY OF ❑ATASET USING DATA RANGING FROM ]ANUARY 2018 TO APRIL 2019. 2. ALL CONCENTRATIONS ARE IN MICROGRAMS PER LITER (N gI L) 3. NO WAN ANALYSIS FOR WELLS AS-2B RD AND GWA-24S FOR CONSTITUENTS; Arsenic (As), Beryllium (Be), strontium (5r) AND Thallium (TI) 4. SFMW-2D IS PART OF THE 50 LID WASTE STIR LICTII MAIL FILL MONITORING NETWORK. THIS UNIT IS NOT CO NTI G UO US WITH THE ASH BAS] N HYDRAULIC SYSTEM AND 15 PARY 09 A 5EP AR ATE ONGOING SITES 0.55E 5SMENT. - NO DATA AVAI LAS LE ANALYTICAL PARAMETER As Be Sr TI REPORTING UNITS PWL 1,9/L pg/L pg/L SSA NCAC 02L STANDARD 10 9' NE 02' BACKGROUND THRESHOLD VALUE 1 0.3 46 0.2 (SHALLOW ROW ZONE)i BACKGROUND THRESHOLD VALUE (DEEP FLOW ZONE)' 1 0.1 73 0-1 BACKGROUND THRESHOLD VALUE 2 0.2 99 0.1 (BEDROCK ROW ZONE)' - INTERIM MAII IMUM ALLOWABLE CONCENTRATIONS ([MACS) OF THE 15A NCAC 021- STANDARD APPENDIX 1, APRIL 1, 2013. IBAC KG ROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED MAY 2015 TO DECEMBER 2018 AS $VBMI TTEO IN ]LINE 2019. - A' (NORTH) DAN RIVER 900 800 700 600 `0 Q Z V 500 Z _O H Q 400 W J W 300 200 100 CROSS SECTION LOCATION Rev. 1 pn 6-0 610 ryp G 6g0 600 8�O �90 O y40 6a° 610 690 6^O 0'0 590 820 01i0 a° 61° °40 TZ8 �80 710 1y0 - V V 830 V • 660 / 110790 Sg 6a0 W 7 - 2O 690 iN�1 // >>O 190 780 �; eo >> O 8i �, 0 Q0 740 0 690 ` A 640 6?0 ,y0 20 f 780 • >° 6 690 f 81° p 1 p 660 °So �MIODLET 11 .. �� p0 yp SON LOOP 820 1 730 ilk 820 S 1100 ~� >° l• � y0 LEGEND / 7� 5v E7 ■ 780 ° 40 I 760 � 77 •' Q • 80 1 /a■ /7l 1 ,I 660 "60 1p0 720 790 z) \680 ^ , � A. O � �• _ 5 ,� 16 � co ,J 1 ° Oq + �l 1,/ 0 OUkF ° a° __•`Ji± .;'` p.. y�.L°, � a■ 1yo 19 pOwFReTF 1g 600 � . Opp• � 11 � i:.-.�TMs'�� '�' l.. 770 r J-- : r■ �M p� ?� N Ito JJ�'' T r' �n rRo f ! .�`Arc,� A 8O NOTES: 11,90 80 / 780 850 840 �4 r1F1.f !, l rl� rf 0 900 h Hoo .O T90 840790 p �. °�,I �� l �4�/f _ \, __ ..� - 00° � �Jf �iY' /r�r. {I ... .� 111 � ► 1a ��. 7,10 870 II 870 . +83p' 83 pQ'.. - �'"' \ r/ L800 s0 • 820` 1� 800 190 Yy� � � � . � ■ r - r r / • O r1 �� � 8� >0 g2° 0 ° 11 r rr 740730 770 O •, I \\NEN 7q0 880 >JO 8g0rr 8J0 A ■ v / I a0 Owl 1 >>O '•i ` - 1a0 Sao 081 ♦ 680 gj0 B60 820 830 6 ` L S .I 1p0 740 T'0 Y GRAPHIC SCALE epO + '80 �4 DUKE ENERGY 500 0 500 1,000 FIGURE 6-11a ISOCONCENTRATION MAP 870ago 8S0 >80 78p ff 770 CAROLINAS (IN FEET) ARSENIC IN DEEP FLOW ZONE DRAWN BY:C.WYATT DATE:11/12/2019 REVISED BY: C. WYATT DATE: 02/26/2020 790 -- - >6p y •_.6O r�-+� -_ re� 8o0 r . f CORRECTIVE ACTION PLAN UPDATE R g1° g20 B00 ,770 `�2,0 r 7.80.....'d°ram --_. -- Teo =~ CHECKED BY: A.ALBERT DATE:02/26/2020 APPROVED BY: A. ALBERT DATE: 02/26/2020 BELEWS CREEK STEAM STATION BELEWS CREEK, NORTH CAROLINA � SO/ 790 `, - L PROJECT MANAGER: A.ALBERT 780 lap ° �ry 160 r�� a. < i s)mTerra www.synterracorp.com Rev. 1 23 April 2020 720 , , ' 790 �•• O,6p 640 610 /+ r600� r8 �530 r 660 I s '90 i`� � % `/ . , 780 00 810 3° 580 58o rrr 7p 690 + 710♦• 0°0 600 0 o R`l` A 040 °?0 0 : J 5g0 ° c1' 1 69 • 78o 10 - I 1I I I I I Q\ >>° sao yqo 0 1111R o 650 700 66 f AMID ET 0 R DL .820, � S � o p5#1 00041P► 8t0 • 0 ■ 004 + 610 590 02o R yap ��_ �wA/ ���,5 �� •_._�+ I+��. ! LEGEND IL p - 60 1 U 710 I _ O 1 O 1 ■ 750 770t / ® I r 73 0 780 • • Q I 720 so _ >g0 \ ��`JlN�— `^ Opp■ r I I I I I �1�� �, "t Z sao 6° Foy.. Ir i 10 50 QOvkFp 6`90 ,.y--'f • j' f Opo . 110 `J �.I`77 11:1 ' : ►,1 Igo STFgM p`4N ! r t 71040 �•.. . 'Arc, �r'� NOTES: > - �I 1A0 80 >80 -780-- I 1 � 850 .:� , ♦ op -�780 f °'0 sao 820 900"j i r 800 fj 0 f r' AO 8O >90 790 .� 870 % '' f f � t������-� �-- � � -. 7 � f�� � I I I I I I � ' �,' :i- ,'.-�� .. f ► 1"^� �`. f � 740 °''Y ? [r �\ r+�.: apt �► s8o - 800■szo850 �fli + • A / p 1g0 PIN • y2� Y ► '�' r+� , I 81 g2° ROAD ■ 6 O 0 S ® >y p O (CLOSED) 900 78 730 g10 �r + l ® 740 �770 0 _ - � � _ �p\NERD O5o .i. �/7�,% Igo I +■ .+ Vf I I >>0 g80 1^p 8a Oo f �� .- �6p ❑ 1 11° �I�p ,• ~ - >Q0 0 880 °00 880 15 ` 820 830 R So 0 \\�Q' • �{� I* 1g OOp I 1A0• 740 GRAPHIC SCALE ME 740 >60 740 DUKE 500 0 500 1,000 FIGURE 6-12a ISOCONCENTRATION MAP ENERGY °70 g3o °S >8p 790 �� CAROLINAS (IN FEET) BERYLLIUM IN SHALLOW FLOW ZONE DRAWN BY: C. WYATT DATE: 11/12/2019 77o 790 0 • ` _ ,6p y .I CORRECTIVE ACTION PLAN UPDATE ' g00 0 o ►-` ° p 82 Boo ,770 7„7` 780 80. --_. - _- -- g1 ° ---�� �•` `;; ` REVISED BY: C. WYATT CHECKED BY: A.ALBERT DATE: 02/25/2020 DATE:02/25/2020 BELEWS CREEK STEAM STATION \p Igo , . O SO �� r' -. APPROVED BY: A.ALBERT DATE:02/25/2020 BELEWS CREEK, NORTH CAROLINA 780 Igo / 790 1po s` Terra PROJECT MANAGER: A. ALBERT n— www.s nterracor .com Rev. 1 23 April 2020 �r ■ °ryp 640 610 y600� y �650 y 660 I �2 710 l0 f '�,1 7 58 690 _frf.1 \'>O �: + {` `10p� 1 780 600 g30 580 A 640 — `\ �] i^. d 4 5g0 61° 69 p • 780 0 I ' • • I Q� r1j0 s) O O 0 0 g° , p 660 690-MI°DLET i Og °O 6So°Op,_ y82o I _ 640 ` ■ > 3 820, g5° 80 810 _ .' - 5 •`.�'� .,'`. LEGEND 590 620 Ob0 >00 f 1 1g0 � 720 I� • �1 � / 76p0 _ 710 77 1 � 110 � O 730 750 ''0 l I , { • O, 40 760 : • ZP I T 720 �~ 66 g 1 ` ► l ■i 711 \\ sao a0 °���, � ..i4•- r r�� -' f � - -' _ 177o y .. r�i_' `�?� �� F � 090 O° �1° L77710 OTM �_ frI • ►, qNr NOTES. 40 s0. l 690 1 0110 10 >9p 61a � >r� � p >60 >ao .._4.. 810 ..11 ty 840900 _ J v''/r 1y�111`. f •'��., r �,_y :..� 800 Z-1 '80 '90 790 840 III 0-0 r/f ►-• • I I 74o • -' �! 870 C�c�Jl� J.-. +83p 1 ' 830 8 O`70 + • ° gb - - ` ■ 6p O . -9 r� 800 O / 830 �, 8j 7g0 ) 9y • (• . r F ' • - - . — ■ • 860 - f �w rr19 S0 5° .. 0 gry° 780 Z - • / / 9°° 810 RpEy r O 740 • 730 770 A •• I • wE` g5 790 r \ 88 0 8eo i 860 gj0 860 820 o 780 O P�� • � L S 740 GRAPHIC SCALE 740 DUKE 500 O 500 1,000 FIGURE 6-12b ENERGY ISOCONCENTRATION MAP 870 g30 "SO '8p 78=1►- CAROLINAS (IN FEET) BERYLLIUM IN DEEP FLOW ZONE DRAWN BY: C. WYATT DATE: 11/12/2019 770 - - 790 ` _ y ~ 760 -'so• CORRECTIVE ACTION PLAN UPDATE 6o0 1 • !� w r - - -.V 800 70 �u> ` �7'p�'a0r �r - } '60 REVISED BY: C. WYATT DATE: 02/18/2020 CHECKEDBY: A. ALBERT DATE:02/18/2020 BELEWS CREEK STEAM STATION g,Lg '- ,p 190 . ,o APPROVED BY: A. ALBERT DATE:02/18/2020 BELEWS CREEK, NORTH CAROLINA 780 g 780 790 1g0 I PROJECT MANAGER: A. ALBERT synTerra www.synterracorp.com ■ - . .. Rev. 1 23 April 2020 • ,gyp 840 610 %��600�� �030 • 660 y3o Sao 56o 600 I 590 6S° 620 °'L° 660 � 00 Al 64° Oy0 y°o y1p l 6�° O'O R y � • • r ,` 590 6 ! .` L bd° • , 77` ° 0 •10 0.. . V 710 ` It 760 '30 720 f l 1 ao ap9 790 w_ J o ' I7r bt •90 O 710 40 790 �O 690 �j 780A°, r 81o. r�?�... .. y 0 JrjJi�'-\ -•1'•� +� , '`•Ir.-. •I J.'� >,0 780 •:i :'mot1 i V.>'/5. .-. • 81° 700�MIDDLET 110.: d �. `oN LOOP 820 1 820 � S > • O 00 ~ 810 • O � ' ? 47 790 ■ . /8r0 ! 690 110 � ��_�! �_i . Tr r• LEGEND 1 ■ o yo 1 I\ r 10 770 ,: �} eon+ . - • I • . .. � .- ' _ V' 1� j70� Ovk � f e ■ k. Fp p JY g • 790 °tq.F 13° —770- � I f ' 7g0 RSTFgMp ♦�► A �i • - NOTES: 'oo i10 '90 'F1 `O ro y �, r•.. Ohl \kk- . v --- ''0.7°840 Aa10 • - - ■f •-• • _ ;. .; � , '-- s '� 74o 870 O� M` , ,1-.860 826 830 ► 830 41, • v fV190 830 %• 800. ig0 y2� J •`��N�' .r.. �, o�r/rrrB J' 8j0 9'6° •. 0 y° a 7g0 It. 730 i I • , • , • O 1� aT0 RO� µ ~yo 740 • 770 so 8 r= r 1 Ji g "o ai0 860 860 SO 860 • 'B ■ 836 � ROP 6zo >y 780 1 6y° 7 A0 740 >O 8p0 ,o GRAPHIC SCALE ° DUKE 500 0 500 1,000 FIGURE 6-16 ENERGY ISOCONCENTRATION MAP 790 °7O g0 BS° 40 7So 1r • 776 (INN Feed 3IRON IN DEEP FLOW ZONE DRAWN BY: WYATTC. DATE:02/25/2020 CORRECTIVE ACTION PLAN UPDATE 800 760 + - •-'�° � � ^ rw� + � REVISED BY: C. WYATT DATE: 02/25/2020 gzo $20 Soo70 _L7^� �i:p�d°. r' ~ 60 CHECKED BY: A.ALBERT DATE:02/25/2020 BELEWS CREEK STEAM STATION °1p j90 ,S ■ APPROVED BY: A.ALBERT DATE:02/25/2020 BELEWS CREEK, NORTH CAROLINA 78 0 ig0 7'0 °• 790 760 s)mTerra PROJECT MANAGER: A. ALBERT O www.sVnterracorD.com Rev. 1 23 April 2020 6-0 610 1p 630 600 duo �°O O g40 "o 610 690 6^° 0'0 590 626 �Ao 61° 6''0 710 1yp 'Qo 720 y - 650 + F,O 660 11.0 I , 790 > >60 V'�o� 67 p f 20 ,, 780 ; d0 g1 , , 40 6a0 690 1° l� • 6p0 740 g80 A s2� 1 3 ti-� 1� ,+ f r ESP 6 0 65 0 J 700 � wMIDDLET 11 • I a90 1h0 610 B20 730 R SON LOOp.� y ilk S 820 'j =110Oy� IE" E=le - - I 4 ` 790d70 + I �, ` LEGEND u now ■ t5p►. I ' 0 01 ■ I f ��' �40 �. r.. 760 ,3p � �. w . . /� � � f ■ yam, 1°0 680 y 1 ' C] ■ 790`� I"I 100 ,80 O � i � t� --- �� ^ y. — ��� � w w 680f�'.; f `. FT. I . 0 ► ------ 0 DGkF'- 0 _.`f�'a' ■I jg0 1g0 DkFRStFq 130 1�77 I1'{ r /- : ■■ — MP�N �� 710 � � �nf JJ�x... fr^ j A �-�• y � ���.� � p0 RO � NOTES: 0. 690 1'If�I 110 >0p •,� f g ��- ... ��L Y �� sio YIW; 00780840 C 0 900'� i . L r ):� 800 6g 90 7 1ti° spy r-�f��\" ���` '� i]jr {r � �' J�� �'� ,��� - ,, ►�� r . �\, �/ 61° a 00 El 1g0 y2� ll . r • + ► 9 f O 7g0 Z f I , I 8° �LRO�r $50\/j L.% 4 730 0 Igo 770 1p 80 °40 w � w w w 660 '� 880 ■B61 66 19p - 0 gj0 B60 ` 6 ,8O 820 30 S° 0 \\.Q' •'C]{� r* i 1° °°° I 1 1A0•. 740 GRAPHIC SCALE 110 1p0 790 670gg0 °So �80 79'0 760 ° 800 � ` _ . -'6 R o g20 Boo ,770 �y�w g1 \p 190 °ter++�;.-�t�.! 780 ° Igo SO f 790 770 � .. + � � w78p 'd°+� --_. 60 -- 160 DUKE ENERGY CAROLINAS 500 0 (IN FEET) 500 1,000 FIGURE 6-19a ISOCONCENTRATION MAP STRONTIUM IN SHALLOW FLOW ZONE CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION BELEWS CREEK, NORTH CAROLINA DRAWNBY:C.WYATT.WYA DATE:02/26/2020 REVISED BY: C. WYATT DATE: 02/26/2020 CHECKED BY: A.ALBERT DATE:02/26/2020 APPROVED BY: A.ALBERT DATE:02/26/2020 PROJECT MANAGER: A. ALBERT �� s` Terra www.synterracorp.com Rev. 1 23 April 2020 otO 640 610 r60 + �630 r • 660 ; )° 710 ) • 790 >60 - r r 7O RMMI��� .�0 17ao ..Oa1i,68p �S ♦ $600 646620 �'r >>0 740 5g0 bryo � � � 0 .. I ' • • I I Q • >p I °�° ygo o , 0 66 650 700 f AMIDOE7 8 110 J� R`ON LDDP,_ y820 810 I� ■ 820 � S0 l 590 620 4• ` _ 790870 0ti 6901-, tto.._:�,�� I LEGEND f 759 I I _ 1 60 �v I - >� n—• - .-�- I 70 ♦ ` f 750 730 l • O' 40 760 >40720 800 >90 >6'0 , - ' goo. p0 790 _ 680 80 O�lm .�T•' ! f��.'rf ` 6 ' {" /. L-,� I I ► r �. ffr j o° � �2 \� ' + - fie° ► � f J 110 P F 13 ° `J .tea' ■ W Rsr 1-770 ® NOTES: 710 � , NT O 600 110 780 �_ J ..1w f r 8 8 g0 900(Jj/ t 1 > )] 1 �` _ 8 1p` I .O -' 0 >90 790 1ti° 'f r ���\�\ \ 1 Z�� { i j 1 I .. / - : - :� I . ►� tij �• • NO 740 870 O ''�Y�� /� \ , ,�, ■=8 870 �r;i680 800 1g0 yy _ w►•rrr w► 6 6j0 gy0 a i )9O TA w � 860 60 $r;0 � 0 >4 o 0.0 > 150 730 y ' • . / / g° 1T\ g10 �\. ROE gb° E 4pERMEEME 770 AO f• / \ •\NEN ® 790 8g0 r ► �+ P �y 0rO° po gbt 880 d0 86o gj0 860 820 O 1p0 740 ° 6po GRAPHIC SCALE `� ENTRATION MAP �' D�jj(� 500 0 500 1,000 FIGURE 6-19c 670 830 >6p 780110° ENORGY (IN FEET) STRONTIUM INISOCONBEDROCKFLOW ZONE 790 6so - r-:->8 '� DRAWN BY: C. WYATT DATE:11/12/2019 CORRECTIVE ACTION PLAN UPDATE 800 760 ` * - + + - J �7,-F'••� REVISED BY: C. WYATT DATE: 02/18/2020 82o g20 800 no s�>' �Tp�'aor+r+:• CHECKED BY. A. ALBERT DATE:02/18/2020 BELEWS CREEK STEAM STATION 1p 7go � . APPROVED BY: A. ALBERT DATE:02/18/2020 BELEWS CREEK, NORTH CAROLINA 780 $ 180 6O 4 790 160 synTerrd PROJECT MANAGER: A. ALBERT $o ■ - . .. www.synterracorp.com Rev. 1 23 April 2020 6-0 610 �p b 580 b30 5g0 600 590 1P 810 y°O O 640 1.611 hb° 510 yq0 590 02p 08" bp0 °1 ° 8O JZ0 �00 710 750 730 110 `40 720 680 1p0 '80 680 760 150 0 Og 710 �3 ❑ ( 11 1b0 sgO 9°°'❑ 810 850 ?° 0 900 870 ❑❑- O o q ,so '90 yA r 0 O 78 730 1 770 p _ JT g80 - 0 1 820 110 880 1°° °b '>0 790 870 83° 0 r0 Boo 61 ° 820 800 780 78° - - 670 ' ,2O 690 y-,r>� N, 'Jo 90 780 j � HBO St o /0 690 0 p 88 690 650 700 f -MID E7 g1 _M1 110 '� 0 „ DL pb yp -oN IOOpi y820 � ■ \R` 1 820 � 3 ❑ r �`y ,° 9°0 8t 0 /i::1. �- LE y0 Q� lie 790 ♦ M 7 I 110 � I :1 [E] El 1 I F• �� . 770 � 75 \❑�' ' ❑ ► � 1bo l � - 1 77oIL ■ . . � e ► � a1 '4° i Qy r ♦ �� � � J Q[yI 1yp 5o° F ` A '9p y I [790T00�� O ✓/ 16 770No � r j" : �,1 1q0 FR STFgMpt N 1 ' 910 ;,go � Jg •�-- i o J80 e i 14° } NOTES: J8p 760 /J V rf °jo ❑� rj1 h )� 800 '>90 7901A0 °❑t 1 i f � 810 740 820 _ [ [ p� .[ 9 �L ROB r^ • by0 ■ -� p1NE lie 889 gj0 860 1 0 . 8`70 lie 780 1 800 T ° 80 780 77 760 -' �� 760 -770 - 7 7 o rr r7� : o ..-• f sO' 790 100 I bry0 ` DUKE 0 ENERGY CARCUNIA::. 740 ® 0 1ao 'Qo 1p0 74( GRAPHIC SCALE 0 500 1,000 (IN FEET) DRAWN BY: C. WYATT DATE: 11/12/2019 REVISED BY: C. WYATT DATE: 02/26/2020 CHECKED BY: A. ALBERT DATE: 02/26/2020 APPROVED BY: A. ALBERT DATE: 02/26/2020 PROJECT MANAGER: A. ALBERT 790 78 0 7q0 740 730 FIGURE 6-20b ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN DEEP FLOW ZONE CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION BELEWS CREEK, NORTH CAROLINA Rev. 1 23 April 2020 6-0 6,o 1p G 580 050 5g0 600 590 0y0 el0 °°O O 640 660 560 510 500 6^0 610 590 s20 0p0 Sao 610 °40 7,0 1p0 >30 750 730 110 1p0 `Qo 720 68, 'oo >8 ° 680 r µ 630 r 660 I 710 ' 780 400 690 690♦�i/ J >>O 19p _y,11 , >> �O 8io � • 000 A 1111062 111 690 700 0 f 78 10 1 i I p 660 � -MIDDLET -� 1 '� ..I• � {{ °O 1yp 6S0 "`—oNLOOpi y820 ilk820 • 900~%;p 8,0`� ■ / ���_90 �870 °ry0 I 1°p 720 ■�`!780 • 7o it IL 0 ■ 7 + �. 71 I 770 / • � V—���1 "jf�f�� s 1g0 o tiC 820 900� 66 �f 870 O r g0 y2� 9 f 0 ' 1 78 730 0 770 860 10 880 000 C� 1 860 8G 810 1 820 100 >9O >>o 870 6g0 790 Soo g20 800 81 p 780 180 r :4 ■ a ao�1 ' I - I • I I � ��I e 10 go 770 7 �p 1q0 sTFgMptgN rRo >No rL >90 A60 7�� ■ "j 40 >8p � v 810 1 r'I 800 • r 'TO 840 I �00 >90 790 746 �p 830 i 63 d3 J// w r f! t`0 �• 930 •° "tin .p � � � .86� r.N� r8S0 9p0 81p �r r r ► �rrP`N�I� RO $50 660 ••�'� �r 0 r B60 0 830 i >8° I I � � L > ss '� ° 790 77 790 110 _ - - °§° O>O I 1a0 ,70NQ, 160 ' i� S0 {� 10 ,,.- ■4 DUKE 500 GRAPHIC SCALE500 1,000 ENERGY CAROLINAS (IN FEET) DRAWN BY: C. WYATT DATE: 11/12/2019 REVISED BY: C. WYATT DATE: 02/26/2020 CHECKED BY: A. ALBERT DATE: 02/26/2020 APPROVED BY: A. ALBERT DATE: 02/26/2020 PROJECT MANAGER: A. ALBERT �40 790 >80 >40 740 730 `` o LEGEND FIGURE 6-21b ISOCONCENTRATION MAP THALLIUM IN DEEP FLOW ZONE CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION BELEWS CREEK, NORTH CAROLINA Rev. 1 23 April 2020 TABLES TABLE 4-3 BACKGROUND VALUES FOR GROUNDWATER CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Constituent Reporting Unit 15A NCAC 02L Standard 2018 Background Threshold Values' 2019 Updated Background Threshold Values Piedmont Background Threshold Value Range3 Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone pH S.U. 6.5-8.5 5.1-6.0 5.2-7.0 6.3-6.5 5.2-6.0 5.6-7.0 6.2-8.4 3.6-9 Alkalinity mg-CaCO,/L NE 23 64 81 20 53 91 19 - 379 Aluminum I pg/L NE 860 140 100 805 204 120 100 - 1,238 Antimony pg/L 1* 1 1 1 1 1 1 1 0.5 - 2.9 Arsenic pg/L 10 1 1 1 1 1 2 0.2 - 6.35 Barium pg/L 700 58 13 6 123 16 11 10.52 - 840 Beryllium pg/L 4* 0.4 0.2 0.2 0.3 0.1 0.2 0.0625 - 1 Bicarbonate mg-CaCO,/L NE 22 63 78 24 54 91 19- 388 Boron pg/L 700 50 50 50 50 50 50 50 - 176.8 Cadmium pg/L 2 1 1 0.08 1 0.08 0.08 0.08- 1 Calcium mg/L NE 4 13 10 8 14 26 4 - 111 Carbonate mg-CaCO,/L NE 5 5 5 5 5 5 5- 10 Chloride mg/L 250 15 21 3 19 19 3 3.34 - 250 Chromium pg/L 10 5 3 5 11 3 11 1-26 Chromium (VI) pg/L 10 2 0.4 0.3 4 0.6 0.4 0.03 - 12 Cobalt pg/L 1* 0.5 2 0.8 0.6 2 0.8 0.088 - 88.85 Copper pg/L 1000 3 5 10 2 5 17 0.5 - 17.15 Fluoride mg/L 2 --- --- --- 0.1 0.1 0.6 0.1 - 1.8 Iron pg/L 300 750 240 228 1,600 226 341 56.3 - 37,500 Lead pg/L 15 1 1 0.1 1 0.6 0.2 0 - 2 Lithium pg/L NE --- --- --- 2 95 30 2 - 95.39 Magnesium mg/L NE 3 7 3 4 7 4 1- 45 Manganese pg/L 50 23 13 10 40 57 64 7-9,170 Mercury pg/L 1 0.2 0.2 0.2 0.2 0.2 0.2 0.05 - 0.5 Methane pg/L NE 3 3 10 3 10 10 1 - 2,505 Molybdenum pg/L NE 1 1 4 0.5 2 6 0.5- 26.2 Nickel pg/L 100 4 5 3 8 5 7 0.87 - 48 Nitrate + Nitrite mg-N/L NE 4 4 0.2 3 4 0.2 0.02 - 6.3 Potassium mg/L NE 5 5 5 5 19 5 1.609 - 18.8 Selenium pg/L 20 0.5 0.5 0.5 1 0.5 0.5 0.5 - 2.4 Sodium mg/L NE 6 11 12 7 11 15 6 - 190 Strontium pg/L NE 57 69 100 46 73 99 27 - 2,120 Sulfate mg/L 250 2 6 10 2 8 15 1.2 - 510 Sulfide mg/L NE 0.1 0.1 0.1 0.1 0.1 0.1 0.1 - 2 TDS mg/L 500 85 148 133 93 134 181 50 - 1,200 Thallium pg/L 0.2* 0.2 0.2 0.1 0.2 0.1 0.1 0.1 - 0.2 TOC mg/L NE 1 1 10 3 6 4 1- 12.3 Total Radium pCi/L 5^ 9 1 0.5 2 4 4 0.494 - 35 Total Uranium pg/mL 0.03^ 0.0005 0.0005 0.0005 0.0005 0.0005 0.002 0.0002 - 0.864 Vanadium pg/L 0.3* 1 1 1 3 2 2 0.33 - 25.8 Zinc I pg/L 1 1000 1 10 43 16 39 23 41 5 - 140 Prepared by: HES Checked by: JHG Revised by: DAA Notes: - Background threshold values were calculated using data from background groundwater samples collected June 2015 to April 2017 - Updated background threshold values were calculated using data from background groundwater samples collected October 2010 to December 2018 and submitted to NCDEQ June 2019 3 - Piedmont background threshold value ranges include the Duke Energy calculated 20174 and 2019' background threshold values from 10 Duke Energy facilities located in the Piedmont physiographic region (Allen Steam Station', Belews Creek Steam Stations, Buck Steam Station4, Cape Fear Steam Electric Plant4, Cliffside Steam Stations, Dan River Steam Station4, Marshall Steam Stations, Mayo Steam Electric Plants, Riverbend Steam Station4, and Roxboro Steam Electric Plants). 2018 background threshold values approved by North Carolina Department of Environmental Qualtity( NCDEQ) on May 14, 2018 Background threshold values have been rounded to similar levels of precision as 15A North Carolina Administrative Code (NCAC) 02L Standard or Interim Maximum Allowable Concentration (IMAC). --- - 2017 background threshold value was not calculated for constituent. * - IMAC of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. ^ - Federal Maximimum Contaminant Level pg/L - micrograms per liter pg/mL - micrograms per milliliter mg/L - milligrams per liter mg-CaCO3/1- - milligrams calcium carbonate per liter mg-N/L - milligrams nitrogen per liter NE - not established pCi/L - picocuries per liter S.U. - standard units TDS - total dissolved solids TOC - total organic carbon Rev. 1 Page 1 of 1 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. Ug/L ug/L pg/L pg/L ug/L ug/L mg/L pg/L ug/L ug/L ug/L Ng/L ug/L ug/L ug/L ug/L mg/L pg/L mg/L ug/L 15A NCAC 02L Standard 6.5-8.5 1* SO 700 4* 700 2 250 10 SO 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 0.4 50 1 15 2 5 0.5 750 NE 23 1 0.5 57 2 0.2 85 1 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2 0.2 93 3 2019 Background Dataset Range Shallow Flow Zone)2 5.3-5.9 0.1-1.1 1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 1 22-11,100 0.39-2 1 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 13 0.2 50 1 21 0.4 3 2 240 NE 13 1 0.5 69 6 0.2 148 1 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 1 226 95 57 2 0.5 73 8 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 1 1 6 0.2 50 0.08 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15 0.1 181 2 2019 Background Threshold Values Bedrock Flow Zone)21 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result; Background Locations° BG-01D Transition Zone 7.5 <0.5 0.52 13 0.10 51 0.096 12 0.29 0.74 0.49 135 52.4 64 <0.5 <0.5 89 6.7 <0.1 209 <0.3 BG-01S Shallow 5.5 <0.5 0.083 9.8 0.18 3.6 <0.08 7.6 - 50 1.1 - 4.4 - 1.3 <0.5 - 0.87 0.14 49 - BG-02BRA Bedrock 8.7 0.65 0.93 5.5 <0.1 <50 <0.08 3.1 0.12 1.5 0.19 103 35 39 8.4 <0.5 79 14 <0.1 154 0.69 BG-02D Transition Zone 6.6 <0.5 <0.1 5.8 <0.1 <50 <0.08 18 0.20 0.69 0.11 <50 15 <5 2.0 <0.5 38 2.6 <0.1 123 1.2 BG-02S Shallow 5.8 <0.5 0.11 77 0.10 <50 <0.08 13 2.2 2.3 0.11 357 2.5 12 0.72 <0.5 34 0.76 <0.1 71 0.98 BG-03D Transition Zone 6.0 <0.5 0.084 12 <0.1 <50 <0.08 4.9 0.045 <0.5 <0.1 75 2.5 5.8 <0.5 <0.5 46 <1 <0.1 70 0.51 BG-03S Shallow 1 5.4 <0.5 <0.1 40 1 0.25 <50 1 <0.08 2 0.42 1.1 1 0.12 1 261 1 1.5 1 14 <0.5 <0.5 1 27 1 <1 I <0.1 52 0.48 MW-202BR Bedrock 6.4 <0.5 0.17 <5 <0.1 <50 <0.08 2.7 0.21 1.4 <0.1 <50 4.2 <5 0.57 <0.5 34 3.7 <0.1 <250 0.48 MW-202D Transition Zone 6.0 <0.5 <0.1 <5 <0.1 <50 <0.08 2.5 0.25 0.60 <0.1 <50 3.3 <5 <0.5 <0.5 38 1.5 <0.1 <250 0.39 MW-202S Shallow 5.7 <0.5 <0.1 24 0.19 <50 <0.08 1.4 1.0 1.2 <0.1 <50 <0.5 <5 <0.5 <0.5 11 <1 <0.1 <250 0.30 At or Within the Waste Boundary Locations AB-01BR Bedrock 7.2 <0.5 1.0 129 0.11 5,630 <0.08 340 0.033 2.5 1.0 2,400 93 707 3.7 <0.5 824 7.6 <0.1 723 0.21 AB-01BRD Bedrock 12.3 - - - - 422 - - - - - - - - - - - - - - - AB-01D Transition Zone 5.6 <0.5 3.3 160 0.63 9,265 0.53 396 0.034 2.0 35 156 5.9 1,833 0.68 1.5 590 117 0.37 914 0.13 AB-01S Shallow 5.9 <0.5 3.9 86 0.094 10,240 0.25 392 0.032 1.3 29 231 0.9 1,865 0.31 1.0 680 141 0.32 962 0.21 AB-02BR Bedrock 8.0 - - 103 0.48 8,870 1.0 410 1.1 1.4 83 8.5 104 12,200 1.5 - 1,660 53 0.17 1,100 0.33 AB-02BRD Bedrock 12.2 - - - - 20.2 - - - - - - - - - - - - - - - AB-02D Transition Zone 5.8 1 1.1 2.2 1 92 0.57 9,552 1 0.49 408 1 <0.025 1.6 70 1,012 11.3 9,030 1 0.76 0.67 678 75 0.50 922 <0.3 AB-02S Shallow 6.6 <0.5 1.7 23 <0.1 50.7 <0.08 6.3 0.14 1.0 1.2 231 0.7 528 2.0 <0.5 34 6.9 0.15 95.4 10 AB-03BR Bedrock 11.1 - - - - 538 - - - - - - - - - - - - - - - AB-03D Transition Zone 7.2 <0.5 15.4 8.0 <0.1 2,836 <0.08 292 <0.025 1.9 2.8 445 198 91 5.3 <0.5 436 33 <0.1 721 0.24 AB-03S Shallow 6.3 <0.5 0.97 131 0.087 10,510 <0.08 378 <0.025 0.76 9.0 412 0.7 3,538 5.6 0.41 666 118 0.49 919 0.37 AB-04BR Bedrock 7.5 <0.5 0.48 6 <0.1 <50 <0.08 1.8 0.15 <0.5 <0.1 <50 11 17 3.9 <0.5 86 5.5 <0.1 <250 2.4 AB-04BRD Bedrock 8.9 <0.5 0.75 5.4 <0.1 1 <50 <0.08 1.1 0.035 <0.5 <0.1 <50 6.6 11 7.3 1 <0.5 64 14 <0.1 1 143 <0.3 AB-04D Transition Zone 6.2 1 0.21 3.4 23 <0.1 56 <0.08 3.3 1 0.69 0.72 0.094 1 71.4 12 162 4.3 0.64 159 3.0 <0.1 172 4.2 AB-04LOWERASH Ash Pore Water 9 7.1 409 47 <0.1 1,015 0.14 18 0.063 <0.5 0.10 176 26 22 963 2.7 498 77 <0.1 361 2.4 AB-04S Ash Pore Water 7.1 <0.5 101 135 <0.1 15,850 <0.08 544 0.025 0.57 0.071 10,564 76 819 16 <0.5 1476 214 <0.1 1,376 <0.3 AB-04SAP Shallow 5.7 0.37 2.6 99 0.17 91 <0.08 3.9 0.52 0.88 0.67 94 7.5 131 1.5 1.1 195 3.7 0.38 158 5.3 AB-04SL Ash Pore Water 10.8 - - - - 14,000 - - - - - - - - - - - - - - - AB-O5D Transition Zone 6.6 <0.5 0.90 10 <0.1 <50 <0.08 0.88 0.43 0.71 0.095 79 4.5 1 6.6L30 0.67 50 4.4 <0.1 <250 3.4 AB-05S Ash Pore Water 8.1 <0.5 100 224 0.11 7323 <0.08 327 <0.025 <0.5 0.11 1,002 75 1,098<0.5 1,260 186 <0.1 849 0.24 AB-05SL Ash Pore Water 10.1 6.6 57 197 <0.1 12,008 <0.08 330 <0.025 0.97 0.045 <50 217 <54.1 3475 206 0.038 1465 157 AB-06D Transition Zone 6.6 <0.5 0.088 19 <0.1 <50 <0.08 1.4 0.31 0.43 <0.1 50 3.5 <5<0.5 56 3.4 <0.1 <250 3.5 AB-06S Ash Pore Water 6.6 0.81 3.9 209 <0.1 115 <0.08 4.7 0.085 0.70 1.1 582 12 152.2 124 20 <0.1 <250 3.2 AB-06SL Ash Pore Water 6.9 <0.5 5.9 223 <0.1 507 <0.08 7.4 <0.025 0.57 <0.1 2,482 43 116<0.5 735 <1 <0.1 <250 0.67 AB-07D Transition Zone 6.7 <0.5 0.19 20 <0.1 <50 <0.08 4.8 0.069 0.25 0.09 153 1 9.3 25 <0.5 42 12.0 <0.1 <250 1.0 AB-07S Ash Pore Water 5.1 <0.5 30 30 1.2 2,315 0.68 108 0.030 1.2 34 53,040 56 2,768 1.9 1.7 1 494 320 1 3.1 765 0.61 AB-08D Transition Zone 6.1 <0.5 0.92 8.2 <0.1 <50 1 0.04 15.6 1 0.029 0.79 0.36 66 15 37 0.22 <U.5 <1 <0.1 <250 0.41 AB-08S Ash Pore Water 5.6 1 0.74 2.1 1 125 0.32 3,871 0.51 128 0.028 0.45 12 1,254 37 165 6.9 11 467 69 4.3 401 1.4 AB-08SL Ash Pore Water 6.8 0.22 259 335 0.11 6,733 <0.08 7.4 <0.025 1.8 0.52 56,475 45 1,030 80 0.56 1,187 6.8 0.064 376 23 AB-09BR Bedrock 7.7 <0.5 16 14 <0.1 <50 <0.08 4.4 0.029 0.54 0.071 1,024 12 585 1.9 <0.5 115 4.8 <0.1 179 <0.3 AB-09D Transition Zone 7.3 0.25 3.3 5.3 <0.1 72.3 <0.08 5 <0.025 0.45 0.18 289 6.6 95 8.2 <0.5 71.2 13 <0.1 205 0.22 AB-09S Shallow 5.2 <0.5 0.094 52 0.11 <50 <0.08 6.2 0.066 0.46 16 241 0.7 559 <0.5 <0.5 6.8 1 <1 0.12 34 <0.3 CCR-01D Transition Zone 6.9 <0.5 9.1 5.7 <0.1 11 <0.08 26 - 1.3 0.78 - 78 - 3.8 0.57 - 20.1 <0.1 155 - CCR-01S Shallow 4.8 <0.5 1 0.47 54 0.38 1 28 0.083 1 17 - 1.0 8.7 - 7.3 - <0.5 0.30 - <1 0.14 45 - CCR-02D Transition Zone 5.2 <0.5 1.4 16 1.2 3,862 0.97 237 0.060 <0.5 7.5 <50 72 2,605 <0.5 <0.5 621 3.0 <0.1 477 <0.3 CCR-02S Shallow 4.3 <0.5 15 411 2.7 6,266 0.36 292 0.028 4.3 256 109 9.1 6,350 <0.5 15 25 36 0.80 575 <0.3 CCR-04D Transition Zone 7.1 <0.5 1.8 49 <0.1 6,685 <0.08 386 - 1.8 JEW - 218 - 2.3 <0.5 - 27 <0.1 866 - CCR-04S Shallow 5.2 <0.5 1.3 275 2.4 7,793 0.65 291 - 1.5 9.0 - 12 - <0.5 1.8 - 46 0.65 1 563 - CCR-05D Transition Zone 12 - - - - 55 - - - - - - - - - - - - - - - CCR-05S Shallow 1 5.5 <0.5 2.3 164 1 0.28 10,630 1 0.1 398 1 <0.5 35 3.6 <0.5 2.5 125 0.36 941 CCR-06D Transition Zone 5.5 <0.5 0.80 195 0.88 10,825 0.51 404 - 0.54 15 - 10 - <0.5 1.4 - 110 0.52 892 - CCR-07D Transition Zone 6.5 <0.5 0.26 17 <0.1 5,148 <0.08 317 - <0.5 1.1 - 59 - <0.5 <0.5 - 32 <0.1 761 - CCR-07S Shallow 4.8 <0.5 0.13 1 162 3.9 84 0.26 82 <0.5 16 7.4 <0.5 <0.5 <1 0.26 183 Rev. 1 Page I of 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. Ug/L ug/L pg/L pg/L ug/L ug/L mg/L pg/L ug/L ug/L ug/L Ng/L ug/L ug/L ug/L ug/L mg/L pg/L mg/L ug/L 15A NCAC 02L Standard 6.5-8.5 1* SO 700 4* 700 2 250 10 SO 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 0.4 50 1 15 2 5 0.5 750 NE 23 1 0.5 57 2 0.2 85 1 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2 0.2 93 3 2019 Background Dataset Range Shallow Flow Zone)2 5.3-5.9 0.1-1.1 1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 1 22-11,100 0.39-2 1 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 13 0.2 50 1 21 0.4 3 2 240 NE 13 1 0.5 69 6 0.2 148 1 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 1 226 95 57 2 0.5 73 8 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 1 1 6 0.2 50 0.08 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15 0.1 181 2 2019 Background Threshold Values Bedrock Flow Zone)21 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result' At or Within the Waste Boundary Locations (Continued) CCR-08AD Transition Zone 5.6 <0.5 0.69 204 1.1 9,363 1.8 415 - 0.70 0.81 - 29 - <0.5 <0.5 - 84 0.17 788 - CCR-08D Transition Zone 5.8 <0.5 0.48 50 0.32 10,017 0.73 430 - <0.5 43 - 60 - <0.5 <0.5 - 80 0.13 773 - CCR-08S Shallow 5.5 <0.5 0.60 175 1.6 9,793 1.2 377 3.7 18 4.8 0.54 0.83 104 0.45 746 CCR-09D Transition Zone 6.2 <0.5 0.17 5.1 <0.1 42 <0.08 18 - 1.1 0.14 - 16 - 0.86 0.61 - 18 <0.1 150 - CCR-09S Shallow 6.0 <0.5 <0.1 21 <0.1 289 <0.08 25 1.8 <0.1 5.2 <0.5 0.51 8.7 <0.1 152 CCR-11S Shallow 6.3 <0.5 2.4 221 <0.1 6.9 <0.08 22 0.76 32 <2.5 0.66 <0.5 7.4 <0.1 377 CCR-11D Transition Zone 5.8 0.5 0.25 42 1 0.063 4.5 1 0.08 16 - 0.61 0.96 - 7.6 - 1.11 0.5 - 17 1 0.1 250 - CCR-12DA Transition Zone 9.0 0.95 1.4 11 <0.1 4.7 <0.08 2.3 - 1.1 1 0.11 - 27.7 - 6.0 <0.5 1- 21 <0.1 147 - CCR-12S Shallow 5.4 <0.5 <0.1 85 0.18 12 <0.08 2.8 - 0.68 <0.1 0.8 <0.5 <0.5 <1 <0.1 41 EXOB-01 Transition Zone 6.7 <0.5 25 24 <0.1 7,845 0.13 381 <0.025 4.3 192 12,772 70 3,180 2.4 <0.5 797 37 <0.1 864 <0.3 EXOB-02 Transition Zone 5.2 <0.5 4.9 218 1.6 8,083 0.69 423 0.043 1.0 139 99 11 4,600 <0.5 5.6 390 93 0.84 989 <0.3 At or Beyond the Compliance Boundary Locations Upgradient or the Ash Basin GWA-03D Transition Zone 6.1 <0.5 0.12 22.3 <0.1 <50 <0.08 9.7 1.0 3.0 0.095 201 2.4 10.3 0.54 <0.5 97.7 <1 <0.1 94 0.79 GWA-03S Shallow 5.8 <0.5 0.05 64.5 <0.1 <50 <0.08 9 0.23 1.2 0.15 104 <2.5 10.2 1.7 <0.5 109 <1 <0.1 101 0.44 GWA-06D Transition Zone 7.0 <0.5 2.0 19.5 <0.1 <50 <0.08 4.9 <0.025 0.69 1.2 1,570 7.6 514 5.1 <0.5 120 17.3 <0.1 <250 0.24 GWA-06S Shallow 5.1 <0.5 0.15 124 1.6 37.6 0.62 8.6 0.89 3.4 0.52 260 3.6 250 0.7 <0.5 34.3 14.1 0.26 <250 0.47 GWA-07D Transition Zone 7.5 0.78 1.1 14.5 <0.1 <50 <0.08 23.0 0.71 1.1 0.056 100 26.7 <5 8.6 <0.5 251 2.2 <0.1 <250 2.5 GWA-07SA Shallow 4.8 <0.5 <0.1 189 3.2 69.3 1 0.13 23.8 1 1.1 2.0 12.7 357 4.2 261 <0.5 <0.5 37.8 18.4 0.084 <250 0.68 GWA-08D Transition Zone 6.9 <0.5 0.29 6.5 <0.1 <50 <0.08 5.5 0.059 0.63 0.10 122 13.1 37.4 4.6 <0.5 1 59.1 11.9 1 <0.1 126 0.81 GWA-08S Shallow 5.4 <0.5 0.12 1 53.1 0.79 210 0.10 2.8 0.11 0.69 0.16 237 1.1 37.0 <0.5 11.2 230 55.9 <0.1 141 0.48 GWA-09BR Bedrock 6.6 <0.5 0.26 <5 <0.1 223 <0.08 57.0 0.22 1.8 0.26 128 18.3 135 1.7 <0.5 89.3 2.4 <0.1 <250 0.72 GWA-09D Transition Zone 6.2 0.30 0.25 9.8 <0.1 <50 <0.08 43.2 0.058 3.1 1.1 126 12.9 17.1 2.7 <0.5 106 4.8 <0.1 <250 0.43 GWA-09S Shallow 5.3 <0.5 0.47 83.5 0.45 <50 0.075 2.5 0.22 2.0 0.59 647 2.5 19.1 <0.5 <0.5 6.3 <1 0.14 49.5 0.74 GWA-22D Transition Zone 8.9 1 <0.5 0.91 16.1 <0.1 <50 <0.08 10.9 0.23 0.72 <0.1 56.6 33.6 13.5 5.1 0.51 86.7 7.7 <0.1 146 5.3 GWA-22S Shallow 5.9 <0.5 <0.1 <5 <0.1 <50 <0.08 2.2 0.31 1.1 0.15 <50 3.0 5.6 <0.5 <0.5 42.2 8.4 <0.1 64.4 1.2 GWA-25BR Bedrock 8.4 <0.5 0.67 7.3 <0.1 <50 <0.08 2.3 0.034 0.95 <0.1 54.7 4.8 9.7 12.8 <0.5 1 48.2 23.1 <0.1 134 <0.3 GWA-26BR Bedrock 7.7 <0.5 0.60 12.9 <0.1 <50 <0.08 10.0 0.026 1.0 2.9 228 2.2 104 11.3 <0.5 46.2 3.8 <0.1 <250 0.71 GWA-26D Transition Zone 5.6 <0.5 <0.1 41.9 0.17 <50 0.19 10.2 0.076 0.76 0.100 140 2.3 17.4 0.58 <0.5 30.3 0.77 <0.1 <250 0.17 GWA-26S Shallow 5.5 <0.5 <0.1 39.3 0.14 <50 <0.08 6.5 0.057 0.54 <0.1 101 2.6 13.0 <0.5 <0.5 16.2 0.54 <0.1 <250 0.19 LRB-01BR Bedrock 7.4 <0.5 0.34 5.5 1 <0.1 <50 <0.08 1.8 0.17 0.51 0.38 70.2 15.4 120 1.1 <0.5 46.1 1.4 <0.1 105 4.1 LRB-01D Transition Zone 6.4 1 <0.5 0.11 20.8 <0.1 <50 <0.08 2.4 22.3 15.0 <0.1 <50 3.0 1 <5 <0.5 0.61 67.3 21.6 <0.1 1 128 6 LRB-01S Shallow 6.3 <0.5 0.13 73.2 <0.1 <50 <0.08 1.1 8.0 7.9 0.44 196 1.0 23.3 0.29 <0.5 73.1 1 <1 <0.1 100 2.8 LRB-02BR Bedrock 7.0 <0.5 0.091 4.6 <0.1 <50 <0.08 4.2 0.083 <0.5 <0.1 1 <50 14.5 21.1 2 <0.5 106 2.2 <0.1 156 1.5 LRB-02D Transition Zone 6.2 <0.5 0.10 15.3 <0.1 <50 <0.08 6.2 0.14 0.73 1.4 59.4 6.8 10.1 0.88 <0.5 149 1.2 <0.1 135 1.1 LRB-02S Shallow 5.8 <0.5 0.053 82.1 0.083 <50 <0.08 13.8 0.15 0.90 0.27 116 <2.5 59.9 <0.5 <0.5 80.1 <1 <0.1 119 0.32 MW-01 Shallow 5.2 - - 20.5 0.11 <50 - 2.2 0.65 1.0 263 - 34.0 - - - 0.57 0.14 <25 - MW-01D Bedrock 6.5 - 3.5 0.028 <50 1 8.1 0.83 0.72 28.0 28.1 0.86 0.11 76.3 0.51 MW-02 Shallow 5.9 0.37 - 73.4 0.36 60.3 3.7 - 2.4 0.36 724 31.9 - - - 0.41 0.16 60.5 0.81 MW-03 Shallow 5.6 <0.5 0.22 54.4 0.17 <50 <0.08 7.5 1.5 4.2 0.19 127 1.8 8.0 <0.5 <0.5 34.3 1.0 1 <0.1 44.7 0.65 MW-04 Shallow 5.9 <0.5 0.10 3.9 <0.1 746 <0.08 2.7 10.7 13.3 0.23 432 <2.5 8.5 <0.5 15.5 76.1 80.7 0.10 183 2.6 MW-05 Shallow 5.6 - 0.59 32.3 0.22 <50 - 2.1 - 0.77 - 199 - 6.1 - - - 0.083 - 35.0 0.58 MW-06 Shallow 5.7 62.8 0.68 <50 7.8 0.28 54.7 2.4 - <0.1 54.7 0.35 MW-07 Shallow 5.5 - - 34.1 0.30 1,309 6.2 - 0.77 111 9.8 - 13.4 - 89.9 - 173 0.40 MW-104BRA Bedrock 7.9 0.27 1.4 22 <0.1 <50 <0.08 3.6 0.27 23.9 0.57 186 4.8 1 38.8 10.5 <0.5 291 9.5 <0.1 135 6.5 MW-104D Transition Zone 6.9 <0.5 0.12 5.6 <0.1 <50 <0.08 1.2 0.89 1.8 0.057 167 5.2 8.2 2.9 <0.5 73.8 1.0 <0.1 1 109 4.2 MW-104S Shallow 5.4 <0.5 <0.1 67.7 0.15 <50 <0.08 0.94 1.4 3.9 0.12 1 139 0.9 8.4 1.3 <0.5 1 28.4 <1 <0.1 42.3 0.32 MW-203BR Bedrock 6.7 <0.5 0.12 <5 <0.1 <50 <0.08 9.8 0.74 1.8 0.05 89.7 11.7 6.1 2.3 <0.5 48.6 2.1 <0.1 117 2.7 MW-203D Transition Zone 6.6 <0.5 0.11 8.7 <0.1 <50 <0.08 3.6 1.5 1.8 <0.1 89.4 9.6 6.8 1.4 <0.5 34.7 1.0 <0.1 94.8 3.4 MW-203S Shallow 5.6 <0.5 1 <0.1 1 48.8 1 0.17 <50 1 <0.08 1.4 0.30 1.1 <0.1 <50 0.8 <5 <0.5 <0.5 19.7 <1 <0.1 35.4 <0.3 MW2-07 Transition Zone 5.2 - 0.33 19.7 2.35 1 13,600 0.59 1 10.1 1 - 0.22 0.44 18.8 - 298 - 120 - 681 - 1,123 0.46 MW2-09 Transition Zone 6.1 0.35 59.4 0.023 292 3.5 1.6 1.0 564 288 0.60 32.1 0.10 141 0.80 OB-05 Shallow 5.3 0.51 113 0.52 <50 3.8 1.3 0.32 687 34.7 - 0.079 0.12 <25 1.3 OB-09 Transition Zone 5.1 0.71 13.6 2.0 26,233 1.7 9.9 - 1.1 0.36 26.8 1,079 - 277 - 955 1 493 0.54 Rev. 1 Page 2 of 4 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter PH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. Ug/L ug/L pg/L pg/L ug/L ug/L mg/L pg/L ug/L ug/L ug/L Ng/L ug/L ug/L ug/L ug/L mg/L pg/L mg/L ug/L 15A NCAC 02L Standard 6.5-8.5 1* 10 700 4* 700 2 250 10 10 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 0.4 50 1 15 2 5 0.5 750 NE 23 1 0.5 57 2 0.2 85 1 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2 0.2 93 3 2019 Background Dataset Range Shallow Flow Zone)2 5.3-5.9 0.1-1.1 1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 1 22-11,100 0.39-2 1 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 13 0.2 50 1 21 0.4 3 2 240 NE 13 1 0.5 69 6 0.2 148 1 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 1 226 95 57 2 0.5 73 8 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 1 1 6 0.2 50 0.08 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15 0.1 181 2 2019 Back round Threshold Values Bedrock Flow Zone Z 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result; Downgradient of the Ash CCR-13BR Bedrock 7.6 0.41 1.7 10 <0.1 <50 <0.08 22 0.21 2.5 0.18 107 30 31 9.4 <0.5 133 87 <0.1 300 1. CCR-13D Transition Zone 6.0 <0.5 0.72 13 0.13 <50 <0.08 14 <0.025 0.58 2.8 70 4.8 92 0.20 <0.5 52 13 0.077 73 <0.3 CCR-13S Shallow 5.6 <0.5 0.12 14 0.23 <50 <0.08 13 0.074 <0.5 0.78 134 4.2 34 <0.5 <0.5 44 0.78 0.076 54 0.33 GWA-01BR Bedrock 10.0 0.26 0.34 5.9 <0.1 <50 <0.08 2.4 <0.025 2.4 0.15 153 64 9.1 7.3 <0.5 75 6.4 <0.1 110 0.28 GWA-01D Transition Zone 6.1 0.70 0.99 9.7 <0.1 <50 <0.08 89 0.040 4.8 9.0 198 36 40 6.4 <0.5 120 4.2 0.053 233 0.63 GWA-01S Shallow 4.7 0.44 0.22 192 4.5 633 0.16 55 0.17 0.87 3.7 186 11 131 0.4 0.4 68 0.99 0.25 102 0.25 GWA-02D Transition Zone 6.2 <0.5 3.3 <5 0.072 <50 1 <0.08 1.8 0.16 2.4 0.31 1 73.5 29 1 12 0.62 <0.5 24 0.82 1 <0.1 55 0.30 GWA-02S Shallow 5.3 <0.5 0.69 17 0.21 <50 <0.08 1.5 0.078 0.63 0.33 553 4.7 16 <0.5 <0.5 3.2 <1 0.082 <25 0.29 GWA-10DA Transition Zone 7.7 <0.5 2.4 10 <0.1 <50 <0.08 8.4 0.22 1.1 0.24 243 45 12 0.33 <0.5 90 9.0 <0.1 128 0.63 GWA-10S Shallow 4.0 <0.5 5.5 583 0.91 327 0.45 116 0.026 1.2 14 153 5.0 2,753 <0.5 3.3 46 <1 0.24 200 0.32 GWA-11D Transition Zone 6.0 <0.5 3.0 17 0.56 419 <0.08 251 <0.025 4.6 3.4 3,743 117 153 0.56 <0.5 538 4.2 <0.1 553 0.38 GWA-11S Shallow 4.6 <0.5 1.9 547 11 1,338 0.81 203 0.032 2.4 10 377 33 162 <0.5 1.4 432 <1 0.38 415 0.44 GWA-16BR Bedrock 9.6 0.91 1.7 8.1 <0.1 <50 <0.08 0.95 0.079 0.64 <0.1 50 17 <5 1.6 <0.5 1 136 14 <0.1 130 0.54 GWA-16DA Transition Zone 6.5 <0.5 0.11 5.7 <0.1 1 <50 <0.08 0.99 0.051 0.80 0.92 1 1,972 4.3 1 19 0.63 <0.5 42 8.5 <0.1 <250 <0.3 GWA-16S Shallow 5.0 <0.5 <0.1 38 0.10 <50 <0.08 0.78 0.25 0.58 1.2 65 2.0 50 <0.5 <0.5 7.1 <1 <0.1 34 <0.3 GWA-17D Transition Zone 6.9 <0.5 0.11 8.1 <0.1 51 <0.08 1.1 <0.025 1.3 0.31 2,090 1.0 43 0.47 <0.5 41 12 <0.1 100 0.34 GWA-17S Shallow 5.3 <0.5 0.12 52 <0.1 55 0.079 1.1 0.037 0.66 11 237 2.4 167 <0.5 <0.5 10 19 <0.1 52 0.33 GWA-18D Transition Zone 6.4 1 <0.5 0.56 <5 <0.1 <50 <0.08 21 1 1.4 1.7 0.12 <50 12 30 0.86 <0.5 62 6.4 <0.1 <250 0.49 GWA-18SA Shallow 4.4 <0.5 2.6 644 5.9 693 0.94 145 0.026 1.1 89 188 36 1,937 <0.5 1.3 138 <1 1.2 <250 <0.3 GWA-19BR Bedrock 10.4 0.77 0.32 1 7.9 <0.1 <50 1 <0.08 1.3 0.10 1.1 <0.1 53 57 <5 2.3 1 <0.5 51 14 <0.1 136 0.19 GWA-19D Transition Zone 7.2 <0.5 15 6.3 <0.1 <50 <0.08 3.6 0.043 <0.5 0.33 1 2,449 60 87 1.2 <0.5 80 13 <0.1 <250 0.20 GWA-19SA Shallow 4.7 <0.5 6.1 686 9.5 2,225 0.82 191 0.030 1.2 48 137 20 2,033 <0.5 5.9 153 <1 0.48 331 <0.3 GWA-20BR Bedrock 9.6 0.67 30 <5 <0.1 63 <0.08 27 0.047 1.7 <0.1 92 93 6.6 50 <0.5 55 15 <0.1 <250 0.43 GWA-20D Transition Zone 5.2 <0.5 4.1 42 1.5 9,690 1.9 425 0.030 1.1 2.9 54 63 1,987 <0.5 <0.5 863 68 0.2 885 <0.3 GWA-20SA Shallow 5.1 <0.5 3.0 198 5.8 11,176 1.1 415 1 0.050 0.92 17 148 18 5,000 <0.5 0.70 494 87 0.44 919 <0.3 GWA-21D Transition Zone 5.1 0.5 1 0.23 220 5.0 507 0.96 238 0.03 0.68 0.9 47 17 48 0.5 0.45 643 1 0.29 468 0.23 GWA-21S Shallow 4.7 <0.5 1.8 400 1 9.9 364 1 0.7 137 0.036 1.1 20 101 15 208 <0.5 1.3 194 1.9 0.27 247 <0.3 GWA-24BR Bedrock 7.7 <0.5 2.3 <5 <0.1 <50 <0.08 2.0 0.034 2.1 0.17 227 29 15 3.7 <0.5 108 5.3 <0.1 144 0.35 GWA-24D Transition Zone 5.4 0.58 <0.1 9.5 0.16 <50 0.089 56 0.16 4.0 0.22 105 1.8 13 0.59 <0.5 110 1.6 <0.1 157 <0.3 GWA-24S Shallow 5.8 - - - - <50 - - - - - - - - - - - 1.1 - 105 - GWA-27BR Bedrock 11.5 - - - - <50 - - - - - - - - - - - - - - - GWA-27D Transition Zone 5.1 <0.5 2.5 91 3.2 7,663 1.9 1 431 0.079 0.72 9.6 <50 58 2,810 0.4 0.42 833 23 0.37 834 <0.3 GWA-27S Shallow 4.6 <0.5 2.4 111 1.6 533 0.25 47 0.035 1.3 1 41 228 13 884 <0.5 1.3 38 4.1 0.25 154 <0.3 GWA-30D Transition Zone 7.4 <0.5 1.3 31 <0.1 <50 <0.08 4.3 0.14 <0.5 0.087 <50 25 70 3.2 <0.5 70 1 1.0 <0.1 116 0.58 GWA-30S Shallow 5.1 <0.5 0.34 18 0.54 <50 <0.08 5.2 0.042 <0.5 1.4 58 7.9 1 19 <0.5 <0.5 35 <1 <0.1 46 <0.3 GWA-31D Transition Zone 7.4 <0.5 0.28 4.2 0.16 <50 <0.08 2.3 <0.025 0.73 <0.1 819 26.2 33 0.34 <0.5 54 5.5 <0.1 104 <0.3 GWA-31S Shallow 5.5 <0.5 0.23 17 0.37 <50 <0.08 2.7 0.057 1.1 0.19 304 2.3 9.7 <0.5 <0.5 13 <1 <0.1 31 0.40 GWA-32D Transition Zone 8.0 0.56 0.49 9.7 <0.1 42 <0.08 71 0.073 0.80 0.050 1,004 64 213 1 1.4 <0.5 145 48 1 <0.1 356 <0.3 GWA-32S Shallow 6.3 <0.5 1 53 27 0.24 1 87 <0.08 1 50 0.034 1.2 58 34,820 1 9,180 0.67 <0.5 6.4 <1 0.70 128 <0.3 MW-200BR Bedrock 7.3 <0.5 1.3 <5 0.21 156 <0.08 62 <0.025 <0.5 0.08 1 237 42 132 0.43 <0.5 191 6.5 <0.1 273 <0.3 MW-200D Transition Zone 6.1 <0.5 0.79 <5 0.077 159 <0.08 39 0.10 0.54 0.064 56 13 13 0.29 <0.5 1 113 3.2 <0.1 156 <0.3 MW-200S Shallow 5.6 <0.5 1.6 48 0.32 62 <0.08 26 0.063 1.3 4.0 953 1.7 123 <0.5 <0.5 L 55 6.4 <0.1 107 0.67 MW-201BR Bedrock 7.6 0.54 0.46 <5 <0.1 <50 <0.08 5.0 0.080 0.85 0.054 63 14 44 11 <0.5 40 8.1 <0.1 127 0.32 MW-201D Transition Zone 6.1 <0.5 0.064 <5 <0.1 <50 <0.08 4.9 3.1 4.0 0.043 64 4.5 6.4 0.47 <0.5 62 1.1 <0.1 99 1.3 MW-204D Transition Zone 5.6 <0.5 <0.1 45 <0.1 <50 <0.08 1.9 0.098 <0.5 26 104 1.8 38 <0.5 <0.5 15 4.9 0.068 <250 0.39 MW-204S Shallow 5.6 <0.5 0.17 253 0.069 <50 0.15 2.9 <O.025 0.68 14 4,621 2.6 503 <0.5 <0.5 21 1 2.4 1 0.12 1 <250 0.43 Rev. 1 Page 3of4 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. Ug/L pg/L pg/L Ug/L pg/L pg/L mg/L Ug/L pg/L pg/L pg/L pg/L ug/L pg/L ug/L pg/L mg/L Ug/L mg/L pg/L 15A NCAC 02L Standard 6.5-8.5 1* SO 700 4* 700 2 250 10 SO 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 0.4 50 1 15 2 5 0.5 750 NE 23 1 0.5 57 2 0.2 85 1 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2 0.2 93 3 2019 Background Dataset Range Shallow Flow Zone)2 5.3-5.9 0.1-1.1 1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 1 22-11,100 0.39-2 1 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 13 0.2 50 1 21 0.4 3 2 240 NE 13 1 0.5 69 6 0.2 148 1 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 1 226 95 57 2 0.5 73 8 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 1 1 6 0.2 50 0.08 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15 0.1 181 2 2019 Back round Threshold Values Bedrock Flow Zone Z 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result; IMP Extraction System EX-01 Transition Zone 5.3 1.1 2.8 102 4.3 9,877 1.6 412 0.071 1.9 10 121 38 3,940 0.30 <0.5 853 69 0.37 893 <0.3 EX-02 Transition Zone 5.0 <0.5 3.0 146 7.1 10,157 1.5 538 0.18 4.5 17 <50 24 3,843 0.30 0.71 592 116 0.37 922 <0.3 EX-03 Transition Zone 5.2 <0.5 3.2 210 2.7 9,663 0.48 540 0.078 0.55 43 28 12 4,523 0.22 1.3 507 112 0.63 958 <0.3 EX-04 Transition Zone 5.2 <0.5 2.5 259 1.9 9,897 0.47 461 0.13 0.69 81 26 13 6,073 0.22 1.3 475 76 0.60 998 <0.3 EX-05 Transition Zone 5.3 <0.5 3.0 229 0.86 10,083 0.37 450 0.069 0.82 100 36 10 5,060 0.14 1.9 492 118 0.74 980 <0.3 EX-06 Transition Zone 5.5 <0.5 1.1 278 1.2 9,983 0.84 463 0.078 0.97 124 <50 16 7,313 <0.5 0.73 709 74 0.86 984 <0.3 EX-07 Transition Zone 5.3 <0.5 1.7 192 1.5 6,140 0.86 329 0.069 1.0 57 86 32 3,510 0.12 0.36 711 24 0.59 705 <0.3 EX-08 Transition Zone 5.2 <0.5 0.63 371 1.8 2,790 0.80 235 0.100 <0.5 9.7 <50 24 1,570 <0.5 <0.5 534 1.9 0.76 464 <0.3 EX-09 Transition Zone 5.1 - 0.97 471 2.4 2,600 1.1 285 0.073 - 7.0 153 43 1,365 - - 795 0.97 0.56 595 <0.3 EX-10 Transition Zone 5.6 <0.5 1.0 7.5 1.3 3,970 0.38 264 0.038 4.3 7.3 31 125 1,450 0.29 <0.5 553 3.3 1 0.095 569 <0.3 Prepared by: ALA/LWD Checked by: DAA/MCR Notes: Revised by: DAA 3/2/2020 Checked by: ALA 3/2/2020 ' - Background threshold values were calculated using data from background groundwater samples collected June 2015 to April 2017 2 - Background threshold values were calculated using data from background groundwater samples collected October 2010 to December 2018 and sumbmitted to NCDEQ June 2019 3 - Statistical mean, geomean, or median calculated from data ranging from January 2018 to April 2019. Ash pore water results are not compared to groundwater standards or criteria. 4 - Background groundwater results are not compared to compartive criteria. Background concentrations greater than background threshold values are within background dataset ranges or piedmont setting background ranges. Groundwater Flow directions across the Site indicate all approved background locations are representative of naturally occuring conditions. Mean or geomean results were used based on the central tendency of the data set. Median results were used for total radium only. For wells with datasets containing fewer than four valid results, the most recent valid sample data was used. Means were calculated for wells with four or more valid sample results. Sample results were excluded from calculations: 1) if turbidity >10 NTU (for COIs other than boron) 2) for unusable data (RO qualified) 3) if a result was non -detect at a reporting limit (RL) greater than the normal laboratory RL Bold text - greatest comparative value bold highlighted concentration indicates value is greater than applicable regulatory standarad (02L or IMAC) bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard 0 - highlighted concentration indicates value is within range of background threshold values for constituents where there is no regulatory standard, or background threshold values are greater than regulatory standard * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. < - concentration not detected at or above the adjusted reporting limit. -' - no available data to conduct mean analysis NE - not established mg/L- Milligrams per liter pg/L - Micrograms per liter S.U. Standard unit Rev. 1 Page aof4 23 April 2020 TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Lines of Evidence (LOE) - 02L Criterion Constituent Standards and Values - 02L Criterion Rationale - 02L Criterion Single location with mean greater than 02L at or beyond the compliance boundary. Does not exhibit a discernable plume and is not Shallow 1 1 52.5 5.25 1 GWA-32S 9 9 1 y within the 02L boron plume footprint. Location is adjacent to a wetland; reducing conditions may enhance constituent solubility. No means of constituent greater than 02L in deep flow zone at this location. Transition Zone 1 1 14.6 1.46 1 GWA-19D 7 6 1 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Arsenic µg/L 10 0.04-1.5 0.04 - 1.5 0.1 - 6.35 y Non -Conservative Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable Bedrock 1 2 30.4 3.04 1 GWA-20BR* 3 3 1 y plume but is within the 02L boron plume. Bedrock location exhibits slightly alkaline pH conditions which may enhance constituent solubility. Shallow 58 123 686 0.98 0 6 6 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 13 16 221 0.32 0 15 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Barium µg/L 700 0.004-124 0.004 - 124 11 - 840 N Non -Conservative Bedrock 6 11 10 0.01 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 50 50 11176 15.97 4 GWS-1S, GWA-11S, GWA-19SA, GWA-20SA 9 9 7 y Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Transition Zone 50 50 9690 13.64 2 GWA-20D, GWA-27D 4 4 3 y Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Boron µg/L 700 2.5-58.8 2.5 - 58.8 49.09 - 176.8 y Conservative Bedrock Zone 50 50 156 0.22 0 2 2 0 N No means greater than 02L at or beyond the compliance boundary, however, flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Shallow Zone 1 1 1.1 0.55 0 1 1 1 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 1 0.08 1.9 0.96 0 2 2 2 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Cadmium µg/L 2 0.03-1.0 0.03 - 1.0 0.08- 1 N Non -Conservative Bedrock Zone 0.8 0.08 <0.08 NA 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone is 19 415 1.66 1 GWA-20SA 9 9 1 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Transition Zone 21 19 431 1.72 3 GWA-IID, GWA-20D, GWA-27D 8 8 3 y Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Chloride mg/L 250 1.2-20.3 1.2 - 20.3 3- 250 y Conservative Bedrock Zone 3 3 62 0.25 a 4 3 0 N No means greater than 02L at or beyond the compliance boundary, however, flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Shallow Zone 5 11 2.4 0.22 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 3 3 4.8 0.48 0 0 0 0 N Non -Conservative Chromium (Total) µg/L 30 0.1-34.7 0.1 - 34.7 1 - 26 No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 5 11 2.5 0.22 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 2 4 0.17 0.02 0 5 5 0 No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 0.4 0.6 3.1 0.31 0 2 2 0 Variable No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Chromium (Hexaval mt) µg/L 10 0.03-2.7 0.03 - 2.7 0.03 - 12 Betlrock Zone 0.3 0.4 0.21 0.02 0 2 0 o N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable Shallow Zone 750 1600 34820 21.76 1 GWA-325 1 1 0 V plume and is not within the 02L boron plume footprint. Location is adjacent to a wetland; reducing conditions may enhance constituent solubility. 300 Iron µg/L (Deep Flow Transition Zone 24 226 13-11,100 13 - 11,100 56.3 - 37,500 3743 12.48 4 GWA-11D, GWA-19D, GWA-31D, GWA-32D y 3 0 0 y Variable Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Zone only) Bedrock Zone 228 341 237 0.70 0 1 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 23 40 9180 183.60 12 GWA-01S, GWA-10S, GWA-IIS, GWA-16S, GWAI7S, GWA-19SA, GWA-20SA, GWA-215, GWA-27S, GWA-325, MW-200S, MW-2045 7 7 1 y Mulit ple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Manganese µg/L S0 (Shallow Flow Zone only) 2.5-189 2.5 - 189 7 - 9,170 y Variable Transition Zone 13 57 2810 49.30 ] CCR-13D, GWA-11D, GWA-19D, GWA-20D, GWA-27D, GWA-30D, GWA-32D 4 3 0 V Mulit le locations with means P greater than background value at or beyond the Compliance boundary and which exhibit a discernable plume. Bedrock Zone 10 64 132 2,16 1 MW-200BR 1 0 D y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the predicted 02L boron plume footprint. Rev. 1 23 April 2020 TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Gr ... dw.t.r B Maximum Number of Wells F`6 d" Rationale for Selection of COIs for Corrective Action Evaluation Mean G ,K c' Steam Station s Station Background C=ter Than Constituents of Interest Reporting 02L or IMAC Bn'kt.u.d Th-hold �O . 01 'e, ..Hvedo Concentration p, Id, I& (constituents where no means are greater than comparative criteria low Zone E,,e,d,nce Groundwater Monitoring Well, With COX Concentration Greater . I " 0� 10 .101 hmtive (2017 CSA Upd,t,) unit Criterion alue" Backgro Background Value Range at or pleyond R,tio4 Cril Co At Th.. Comparative Criteria '.G o in all flow zones and/or multiple lines of evidence support that constituent occurrences Rumi D t-et nge C.m iance Beyond - Hance am not related to the source area, no corrective action is warranted) et -et ng Boundary Bou=py' Shallow zone 0.5 1 5.9 0.30 0 3 1 2 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Selenium µg/L 20 Transition Zone 0.1 0.5 0.1-3.] 0.1 - 3.] ..5- 2 0.42 0.02 o N 0 0 0 N variable No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 1 0.5 1 0.5 1 1 1 1 0.5 NA I 0 1 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 2 2 87 0.35 0 3 1 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Sulfate mg/L 250 Transition Zone 6 8 0.1-22.5 0.1- 22.5 1.2 - 510 68 0.27 0 y 5 3 0 N Variable No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 10 15 67 0.35 0 1 1 0 N Shallow Zone 85 93 919 1.84 1 GWA-20SA 10 3 0 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Total Dissolved Solids mg/L 500 Transition Zone 148 134 20-250 20 - 250 50 - 1,200 885 1.77 3 GWA-11D, GWA-20D, GWA-27D y 10 4 0 y Conservative Bedrock Zone 133 181 300 0.60 0 2 2 0 N No means greater than 02L at or beyond the compliance boundary, however, Flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Constituent Standards and Values - IMAC Criterion Lines of Evidence (LOE) - IMAC Criterion Rationale - IMAC Criterion Shallow zone 1 1 <0.5 NA 0 0 0 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Antimony µg/L 1 Transition Zone 1 1 0.1-1.5 0.1- 1.5 0.5 - 4.247 0.70 0.70 0 v t o 0 N Conservative No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Mulitple locations with means greater IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Bedrock Zone 1 1 0.77 0.77 0 1 0 0 N Shallow Zone 0.4 0.3 11 2.74 5 GWA-01S, GWA-IIS, GWA-19SA, GWA-20SA, GWA-21S 0 0 0 y Beryllium µg/L 4 Transition Zone 0.2 0.1 0.01-0.6 0.01 - 0.6 0.053 - 1 5.0 1.24 1 GWA-21D N 0 0 0 v Non C.nva-nive Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Betlrock Zone 0.2 0.2 0.21 0.05 0 0 0 0 N Shallow Zone 0.5 0.6 58 58.00 13 GWA-01S, GWA-10S, GWA-IIS, GWA-16S, GWA-17S, GWA-19SA, GWA-20SA,GWA-21S,GWA-27S, GWA-30S, GWA-32S, MW-200S, MW-204S 18 6 0 v Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discernable plume. Cobalt µg/L 1 Transition Zone 2 2 0.02-1.8 0.02 - 1.8 0.2- 88.85 25 12.30 6 CCR-13D, GWA-01D, GWA-IID, GWA-20D, GWA-27D, MW-204D y 5 0 0 y ,i,. „ No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Bedrock zone 0.8 1 0.8 0.18 0.18 0 0 0 0 N Shallow Zone 0.2 0.2 0.70 3.48 8 GWA-01S, GWA-10S, GWA-11S, GWA-19SA, GWA-20SA, GWA-21S, GWA-27S, GWA-32S 0 0 0 y Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Thallium µg/L 0.2 Transition Zone 0.2 0.1 0.02-0.2 0.02 - 0.1 0.1-0.2 0.37 1.87 2 GWA-21D, GWA-27D y 0 0 0 v Vari;:, No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Betlrock Zone 0.1 0.1 <0.1 NA 0 0 0 0 N Shallow zone 1 3 0.67 0.22 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. vanadium ug/L 0.3 Transition Zone 1 2 0.1-6.4 0.1 - 6.4 0.38 - 26 1.3 0.63 0 y 0 0 0 N Non -Conservative No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Bedrock zone 1 2 1.5 1,71 0 0 0 o N Rev. 1 23 April 2020 TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION Gr ... ..Hvedo ,K dw.t.r c' v B Steam Station low Zone Maximum Concentration s Station Background Mean E,,e,d,nce Number of Well. G C=ter Than p, DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Groundwater Monitoring Well, With COX Concentration Greater 10 .41 . Id, I& I " Rationale for Selection of COIs for Corrective Action Evaluation 8, 10 .101 (constituents where no means are greater than comparative criteria (2017 CSA Upd,t,) unit Criterion alue" Backgro Background Value Range at or Rumi . D t.set nge C.m Flow Zone 20� Constituent Standards and Values - Background Criterion pleyond iance R,tio4 hmtive Cril Co At Beyond - Hance Th.. Comparative Criteria Lines of Evidence (LOE) - Background Criterion '.G a in all flow zones and/or multiple lines of evidence support that constituent occurrences am not related to the source area, no connective action is warranted) Rationale - Background Criterion CCR-9W, GN/A-IS, GWA-IOW, GWA- S, GWA-16W, GWA- Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discernable Shallow Zone NE 2 33 16.71 14 125, GWA-195A, -195A, GWA-205A, GWA-215, 6WA-225, GWA-305, 6WA- 11 0 0 Y plume. 31W, MW-2045 Transition Zone NE 95 117 1.23 1 GWA-11D Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable Lithium pg/L NE 2 - 95 2 -95 2- 95.39 1 1 0 V Conservative plume but is within the 02L boron plume footprint. Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discemable Bedrock Zone NE 30 93 3.09 5 CCR-13BR, GWA-01BR*, GWA-19BR-, GWA-20BR*, MW-200BR 5 0 0 y plume. Several bedrock locations exhibit slightly alkaline pH conditions which may enhance constituent solubility. Remaining bedrock wells are within the 02L boron plume footprint. Shallow Zone 1 0.5 0.67 0.62 1 GWA-32S 1 0 0 V Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume and is not within the 02L boron plume footprint. Transition Zone 1 2 6.4 3.21 2 GWA-01D, GWA-30D Isolated locations with means greater than background value at or beyond the compliance boundary. Do not exhibit a discernable Molybdenum pg/L NE 0.1-5.3 0.1 - 5.3 0.5 - 26 0 0 0 y y." plume and are not within the 02L boron plume footprint. Isolated locations with means greater than background value at or beyond the compliance boundary. Do not exhibit a discernable Bedrock Zone 4 6 50 8.32 4 CCR-13BR, GWA-01BR*, GWA-20BR*, MW-201BR 2 0 o r plume and are not within the 02L boron plume footprint. Several bedrock locations exhibit slightly alkaline pH conditions which may enhance constituent solubility. Shallow Zone 52 46 494 8.62 2 GWA-01W, GWA-10S, GWA-11S, GWA-195A, GWA-20SA, 2 2 1 y Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discernable GWA-21S, MW-2005 plume. Transition Zone 69 73 863 11.82 10 GWA-01D, GWA-10DA, GWA-11D, GWA-19D, GWA-20D, GWA-21D, Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discernable Strontium µg/L NE 7.9-100 2.9 - 100 2] - 2222 12 9 1 V Non -Conservative GWA-24D, GWA-22D, GWA-32D, MW-200D plume. Bedrock Zone 110 99 191 1.93 4 CCR-13BR, GWA-168R, GWA-24BR, MW-200BR 10 4 0 y Mulitple locations with means greater than background value at Or beyond the compliance boundary and which exhbit ia discernable plume. Prepared by: DM Checked by: AlA Revised by: DAA (02/28/2020) Checked by: ALA (02/28/2020) F-1 - ae b n. cr er n F-1 - ev ence supports Inclusmn - Ev ence suppoda exclusmn ns rtuenl 11. re In. I l en ie in c e2017 csA update (synTera, 2012), wtth me add- V lithium. June 2015 co April were a mun rezodvauez cabal usm eta om ack9-d groundw-samples mlleccetl ace ark9-dth-h.ld values are iI,Ih.1-column and were calculated using d- from backgroubd groundwater samples ro11l ORober 20100 December 2018and zumbmned [o NCDEQ 3une 20190 rt mecic mean M magni than was use r Wconcentration range less than or equal [o one order G of magnicutle. eo b, mean Mr was usetl WEwttM1 concenhabon range greater one order tude. 5 Assignment of mnservabvero1- non -conservative, or variable beM1 - Iz based on geocM1emical motleling rezutts. - greater 1M1an < less Ma tz wx zllghtly alkline pH (a10 S.N.) e ulsetlIn Nei elvaluabon, In-Ing: CM-131N, water quaey. slightly alkaline candid- appear Iomlhea and CCR-131, 001135, GwA-111, GwA-115, GwA-161N, GwA-1611, unc M1araRerkbc bedrock I. M bflow zone GwA-16s, GwA- 71, GwA-11G, and might be attributable M well Inrtallatbn aRNibes. GwA- 1, GwA-191, GwA-19GA, GwA-1BR, GwA-1D, Gw s' G pg/L-mlce-iogram�rlbwable cencentratbn mv, - mllllgrams per Itter knbk NE -No Establtshetl .. tend-untts Rev. 1 23 April 2020 Page 3 of