NC0024911_Groundwater Monitoring Report January 2020_20200121

oQo \"pN SEW6194q %
ti 9
pie aCpP
f 00UNTY, 07
Metropolitan Sewerage District
OF BUNCOMBE COUNTY, NORTH CAROLINA
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Information Processing Unit:
Water Quality Regional Operations
Asheville Regional Office
Please find attached the Groundwater Quality Monitoring Reports for the month of January
2020 from the Metropolitan Sewerage District of Buncombe County (MSD). These monitoring
report forms have additional identification on the well ID line, MW-05, MW-06R, MW-07 and
MW-08R for ease of reference.
Monitoring Well-05, Monitoring Well-0611 and Monitoring Well-07 exceeded allowable
limits for pH, Manganese and Iron. Monitoring Well-0811 exceeded allowable limits for
Manganese and Iron.
If there are any questions or request for additional information, please contact Roger Edwards
at 828-225-8224.
Sincerely,
L
Mr. Thomas E. Hartye
General Manager, MSD
—Protecting Our Natural Resources—
nnno onmomnc novc Acuavu I P NnRTH CAROI INA 9RR04 TELEPHONE: [phone] FAX: [phone] WEBSITE: www.msdbc.org

GW-59A COMPLIANCE REPORT FORM Permit # NC0024911
(Submit are each monitoring period with G1K59 farms.)
Enter date monitoring results were due. (_2129/2020_) Will this monitoring report (GW-59 and GW-59A)
YES
NO
1
be submitted after the established due date?
2
�Yas any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES'; list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? if the answer is "Yes", contact the Regional Officefor guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO'; skip to section 8.
"YES" list the affected wells individually with constituent(s) and concentration(s)
If the answer to question 4 is
exceeding standards in the space provided below:
MW-05 MW-06R MW-07 MW-08R
pH 5.9 pH 6.3 pH 6.2
Mn Mn 533 ug/L Mn 10,000 ug/L Mn 125 ug/L 11,00 ug/L
Fe
Fe 524 ug/L Fe 43,000 ug/L Fe 627 ug/L Fe 18,800 ug/L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-05 pH Mn MW-O6R pH Mn Fe MW-08R pH Mn Fe
6/12119 5a 482 ug/L 10/2/19 6.1 12,700 q& 5g800 ug/L 10/2n 9 6.3 70,400 uglL 2,860 u IL
10M19 5.7 302 uga.
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
is "NO", monitoring wells maybe improperly
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
evaluation may be
If the answer to question 7 is "NO", contact the Reoion I Office ��ithin 90 days•
_ the impact the waste disposal system is having at the review and compliance
d to
Clete
this facilitL Failure to do so may subject the p rmi� ttee to a Notice of Violation.
bot_nd nes surrot_ndma
fines and/or penalties.
8
The person completing this portion (G W--59A) of the monitoring report should sign below and submit this
form.
form with GW-59 forms for required wells to the address provided at the top of the current GW-59
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Sitinalre of Permittee (or Authorized Agent) Date
GW-59A 12/8/2003

aceAnalytical
www.pacalabs.cam
January 13, 2020
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: MW's 1/2/20
Pace Project No.: 92459137
Pace Analytical Servlces, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Dear Mr. Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on January 02, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Since
rri atton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Ryan Dyson, MSD of Buncombe County, NC
Mr. Chad Ledford, Metropolitan Sewerage District
Mr. Dwayne Martin, Metropolitan Sewerage District
Ms. Cassandra McKnight, MSD of Buncombe County
Mr. Alan Taylor, Metropolitan Sewerage District
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, L-C.
Page 1 of 11

(�5?ceAnalyficalv`
Ww .pacelabs.com
Project: MW's 1/2120
Pace Project No.: 92459137
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: F87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full. Page 2 of 1 E
Without the written consent of Pace Analytical Services, LLC.

ace Analytical
www.pacalaba.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
MWs 112/20
Pace Project No.:
92459137
Analytes
Method
Analysts
Reported
Laboratory
Lab ID
Sample ID
EPA 200.7 Rev 4.4 1994
KQ
10
PASI-A
92459137001
MW05
EPA 245.1 Rev 3.0 1994
SOO
1
PASI-A
SM 2540C-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
EPA 200.7 Rev 4.4 1994
KQ
10
PASI-A
92459137002
MW06R
EPA 245.1 Rev 3.0 1994
SOO
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
EPA 200.7 Rev 4.4 1994
KQ
10
PASI-A
92459137003
MW-OSR
EPA 245.1 Rev 3.0 1994
SOO
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
EPA 200.7 Rev 4.4 1994
KQ
10
PASI-A
92459137004
MW07
EPA 245.1 Rev 3.01994
SOO
1
PASI-A
SM 254OC-2011 -
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 3 of 11
Without the written consent of Pace Analytical Services, LLC.

aceAnalytical
www.pacalahsxore
Project: MW's 1/2/20
Pace Project No.: 92459137
Sample: MW-05
Parameters
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310E TOC
Total Organic Carbon
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92459137001 Collected: 01/02/20 12:10
Received: 01/02/20 17:06 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
Analytical Method:
1
01/06/20 16:09
JDS
1
01/06/20 16:09
112120
1
01/06/20 16:09
12:10
1
01/0612016:09
5.9 Sid. Units
1
01/06/20 16:09
10.3 deg C
1
01/06/20 16:09
1feet
1
01/06/20 16:09
40.0 umhos/cm
0.0
1
01/06/20 16:09
None
Detected
1
01/0 = 16:09
Clear
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
ND ug/L 10.0
1
01/03/20 00:25 01/06/20 00:24 7440-38-2
ug/L 5.0
1
01/03/20 00:25 01/06/20 00:24 7440-39-3
18.7
1.0
1
01/03/20 00:25 01/06/20 00:24 7440-43-9
ND ug/L
5.0
1
01/03/20 00:25 01/06/20 00:24 7440-47-3
ND ug/L
50.0
1
01/03/20 00:25 01/06/20 00:24 7439-89-6
524 ug/L
5.0
1
01/03/20 00:25 01/06/20 00:24 7439-92-1
ND ug/L
5.0
1
01/03/20 00:25 Ot/06/20 00:24 7439-96-5
533 ug/L
10.0
1
O1/03/20 00:25 01/06/20 00:24 7782.49-2
NO ug/L
5.0
1
01103/2000:25 01/0612000:24 7440-22-4
ND ug/L
5000
1
01/03/20 00:25 01/06/20 00:24 7440-23-5
ND ug/L
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation
Method: EPA 245.1 Rev 3.0 1994
0.20
1
01103/2010:00 01/0312012:37 7439-97-6
ND ug/L
Analytical Method: SM 254OC-2011
47,0 mg/L 25.0
1
01/07/2017:08 D6
Analytical Method: EPA 300.0 Rev 2.1 1993
1.0
1
01/03/20 12:03 14808-79-8
3.8 mg/L
Analytical Method: EPA 350.1 Rev 2.0 1993
0.10
1
01/1012009:52 7664-41-7
ND mg/L
Analytical Method: EPA 353.2 Rev 2.0 1993
0.040
1
01/03/2023:07 14797-55-8
0.096 mg/L
Analytical Method: SM 4500-CI-E-2011
1.0
1
01/08/2011:36 16887-00-6
1.5 mg/L
Analytical Method: SM 5310B-2011
1.0
1
01/11/2006:49 7440-44-0
ND mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 4 of 1�
without the written consent of Pace Analytical Services, LLC.
Date: 01/13/2020 11:59 AM

aceAnalytical e
wwa.pecslebs.cam
Project: MW's 1/2/20
Pace Project No.: 92459137
Sample: MW-06R
Parameters
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310B TOC
Total Organic Carbon
Date: 01/13/2020 11:59 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92459137002 Collected: 01/02/20 16:40 Received: 01/02/2017:05 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method
1
01/06/20 16:10
JDS
1
01/06/20 16:10
112120
1
01/06/20 16:10
16:40
1
01106/2016:10
6.3 Std. Units
1
01/06/20 16:10
15.2 deg C
1
01/06/20 16:10
10.31 feet
1
01/06/20 16:10
473.1 umhos/cm
1
01/06/20 16:10
None
Detected
1
01/06/20 16:10
Clear
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA
200.7 Rev 4.4 1994
ND ug/L 10.0
1
01/03/20 00:25
01/06/20 00:27
7440-38-2
ug/L 5.0
1
01/03/20 00:25
01/06/20 00:27
7440-39-3
148
ND ug/L 1.0
1
01/03/20 00:25
01/06/20 00:27
7440-43-9
ND ug/L 5.0
1
01/03/20 00:25
01/06/20 00:27
7440-47-3
ug/L 50.0
1
01/03/20 00:25
01/06/20 00:27
7439-89-6
43000
ug/L 5.0
1
01/03/20 00:25
01/06/20 00:27
7439-92-1
ND
ug/L 5.0
1
01/03/20 00:25
01/06/20 00:27
7439-96-5
10000
ND ug/L 10.0
1
01/03/20 00:25
01/06/20 00:27
7782-49-2
ND ug/L 5.0
1
01/03/20 00:25
01/06/20 00:27
7440-22-4
5000
1
01/03/20 00:25
01/06/20 00:27
7440-23-5
17500 ug/L
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
0.20
1
01/03/2010:00
01/03/2012:39
7439-97-6
ND ug/L
Analytical Method: SM 254OC-2011
259 mg/L 25.0
1
01/0712017:08
Analytical Method: EPA 300.0 Rev 2.1 1993
1.0
1
01103/2012:17
14808-79-8
92.9 mg/L
Analytical Method: EPA 350.1 Rev 2.0 1993
0.10
1
01/10/20 09:56
7664-41-7
1.3 mg/L
Analytical Method: EPA 353.2 Rev 2.0 1993
0.040
1
01/03/20 23:13
14797-55-8
ND mg/L
Analytical Method: SM 4500-CI-E-2011
1.0
1
01/08/20 11:46
16887-00-6
20.5 mg/L
Analytical Method: SM 531OB-2011
1.0
1
01/11/20 07:06
7440-44-0
2.6 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 5 of 18
without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC
2225 Riverside Dr.
8804
aceAnalytical o Asheville, NC (828)25471767176
www.pacelabsxam
ANALYTICAL RESULTS
Project: MW's 1/2/20
Pace Project No.: 92459137
Sample: MW-08R Lab ID: 92459137003 Collected: 01/02/2013:35 Received: 01/02/2017:05 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
1
01/06/20 16:12
Collected By
JOS
1
01/06/20 16:12
Collected Date
112/20
1
01/O6/20 16:12
Collected Time
13:35
1
01106/2016:12
PH
6.5 Std. Units
1
01/06/20 16:12
Temperature
13.9 deg C
1
01/06/20 16:12
Static Water Level
10.13 feet
1
01/06/20 16:12
Specific Conductance
412.3 umhos/cm
1
01/06/20 16:12
Odor
None
Detected
1
01/06/20 16:12
A
Appearance
Clear
EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA
200.7 Rev 4.4 1994
200.7 MET ICP
Analytical Method:
NO ug/L 10.0
1
01/03/20 00:25
01/06/20 00:31
7440-38-2
Arsenic
52.7 ug/L 5.0
1
01/03/20 00:25
01/06/20 00:31
7440-39-3
Barium
ND ug/L 1.0
1
01/03/20 00:25
01/06/20 00:31
7440-43-9
Cadmium
NO ug/L 5.0
1
01/03/20 00:25
01/06/20 00:31
7440-47-3
Chromium
18800 ug/L 50.0
1
01/03/20 00:25
01/06/20 00:31
7439-89-6
Iron
ND ug/L 5.0
1
01/03/20 00:25
01/06/20 00:31
7439-92-1
Lead
11700 ug/L 25.0
5
01/03/20 00:25
01/07/2019:04
7439-96-5
Manganese
NO ug/L 10.0
1
01103/2000:25
01/06/20 00:31
7782-49-2
Selenium
ND ug/L 5.0
1
01/03/20 00:25
01/06/20 00:31
7440-22-4
Silver
29700 ug/L 5000
1
01/03/20 00:25
01/06/20 00:31
7440-23-5
Sodium
Method: EPA 245.1 Rev 3.0 1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
245.1 Mercury
Analytical
NO ug/L 0.20
1
01103/2010:00
01/03/2012:42
7439-97-6
Mercury
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Total Dissolved Solids
222 mg/L 25.0
1
01/07/20 17:08
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
72.3 mg/L 1.0
1
01/03/2013:01
14808-79.8
Sulfate
Analytical Method: EPA 350.1 Rev 2.0 1993
350.1 Ammonia
0.19 mg/L 0.10
1
01/10/20 09:58
7664-41-7
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
0.053 mg/L 0.040
1
01/03/20 23:10
14797-55-8
Nitrogen, Nitrate
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
18.4 mg/L 1.0
1
01/08/2011:47
16887-00-6
Chloride
53108 TOG
Analytical Method: SM 531OB-2011
2.9 mg/L 1.0
1
01/11/20 07:23
7440-44-0
Total Organic Carbon
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full, Page 6 of 18
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, L-C.

Pace Analytical Services, LLC
2225 Riverside Dr.
® Asheville, NC 28804
ace Analytical [phone]
'w .pacelabsxom
ANALYTICAL RESULTS
Project: MWs 1/2120
Pace Project No.: 92459137
92459137004 Collected: 01102/2015:25
Received: 01/0212017:05 Matrix: Water
Sample: MW-07
Lab ID:
Units Report Limit OF
Prepared
Analyzed
CAS No. Qual
Parameters
Results
Monitoring Well Data
Analytical Method:
1
0110612016:14
Collected By
JDS 1
Ot/06/2016:14
Collected Date
1/2120
1
01106/2016:14
Collected Time
15:25
1
01/06/20 16:14
1 .2 Std. Units
01/06/20 16:14
Temperature
Te
1deg C 1
01/06/20 16:14
Static Water Level
10.71 0.71 feet
1
01/06/20 16:14
Specific Conductance
368.7 umhos/cm
1
01/06/20 16:14
Odor
None
Detected 1
01/06/20 16:14
Appearance
Clear
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA
200.7 Rev 4.4 1994
200.7 MET ICP
10.0 1
01/03/20 00:25
01/06/20 00:34
7440-38-2
Arsenic
NO ug/L
ug/L 5.0 1
01/03/20 00:25
01/06/20 00:34
7440-39-3
Barium
44.0
NO ug/L 1.0 1
01/0312000:25
01/06/20 00:34
7440-43-9
Cadmium
ND ug/L 5.0 1
01/03/20 00:25
01/06/20 00:34
7440-47-3
Chromium
627 ug/L 50.0 1
01/03/20 00:25
01/06/20 00:34
7439-89-6
Iron
ug/L 5.0 1
01/03/20 00:25
01/06/20 00:34
7439-92-1
Lead
ND
ug/L 5.0 1
01/03/20 00:25
01/06/20 00:34
7439-96-5
Manganese
125
NO ug/L 10.0 1
01/03/20 00:25
01/06/20 00:34
7782-49-2
Selenium
ug/L 5.0 1
01/03/20 00:25
01/06/20 00:34
7440-22-4
Silver
ND
ug/L 5000 1
01/03/20 00:25
01/06/20 00:34
7440-23-5
Sodium
11200
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
245.1 Mercury
0.20 1
01/03/20 10:00
01/03/20 12:44
7439-97-6
Mercury
ND ug/L
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
229 mg/L 25.0 1
01/07/2017:08
Total Dissolved Solids
Analytical Method: EPA 300.0 Rev 2.1 1993
300.0 IC Anions 28 Days
01/03/2013:16
14808-79-8
Sulfate
94.0 mg/L 1.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
350.1 Ammonia
1
01/10/20 09:59
7664-41-7
Nitrogen, Ammonia
ND mg/L 0.10
Analytical Method: EPA 353.2 Rev 2.0 1993
353.2 Nitrogen, N021NO3 unpres
01/03/2023:11
14797-55-8
Nitrogen, Nitrate
19 m9/L 0.040 1
Analytical Method: SM 4500-CI-E-2011
4500 Chloride
1
01/08/2011:38
16887-00-6
Chloride
8.9 mg/L 1.0
Analytical Method: SM 531OB-2011
5310B TOG
1.0 1
01/11/20 07:43
7440-44-0
Total Organic Carbon
1.4 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 7 of 18
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, L-C.

?ceAnalyficalo
www.pacelabs.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 517707 Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2771616 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifers
Mercury ug/L ND 0.20 01/03/2012:25
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE:
2771617
LCS
% Rae
Units
Spike
Cone.
LCS
Result
%Rec
Limits Qualifiers
Parameter
ug/L
2.5
2.5
99
85-115
Mercury
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2771618
2771619
92457045001
MS
Spike
MSD
Spike
MS
MSD
MS MSD % Rae
RPD Qual
Parameter
Units Result
Cone.
Cone.
Result
Result
% Rae % Rec Limits
ug/L ND
2.5
2.5
2.6
2.6
105 103 70-130 2
Mercury
Results presented on this page are in the units indicated by the"Units" column except where an alternate unit Is presented to the right of lha result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, L-C.
Page 8 of 18

(�ZeAnalXicalo
www.pacelabs.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 517676 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2771558 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Parameter
ug/L
ND
10.0
01/05/20 23:59
Arsenic
ug/L
ND
5.0
01/05/20 23:59
Barium
ug/L
ND
1.0
01105/2023:59
Cadmium
ug/L
ND
5.0
01/05/20 23:59
Chromium
ug/L
ND
50.o
01/05/20 23:59
Iron
ug/L
ND
5.0
01/05/20 23:59
Lead
ug/L
NO
5.0
01/05/2023:59
Manganese
ug/L
ND
10.0
01/05/20 23:59
Selenium
ug/L
ND
5.0
01/05/20 23:59
Silver
ug/L
ND
5000
01/05/20 23:59
Sodium
2771559
LCS %Rec
LABORATORY CONTROL SAMPLE:
Spike
LCS
Units
Conc.
Result % Rec Limits Qualifiers
Parameter
ug/L
500
471
94
85-115
Arsenic
ug/L
500
500
100
85-115
Barium
ug/L
500
481
96
85-115
Cadmium
ug/L
500
495
99
85-115
Chromium
ug/L
5000
4770
95
85-115
Iron
ug/L
500
482
96
85-115
Lead
ug/L
500
493
99
85-115
Manganese
ug/L
500
471
94
85-115
Selenium
ug/L
250
240
96
85-115
Silver
ug/L
5000
4960J
99
85-115
Sodium
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2771560
2771561
92459126001
MS
Spike
MSD
Spike MS
MSD MS
MSD
% Rec
RPD
Qual
Units
Result
Conic.
Conic.
Result
Result % Rec % Rec
Limits
Parameter
<10.0
500
500 515
496
103 99
70-130
4
Arsenic
ug/L
13.8
500
500 530
514
103 100
70-130
3
Barium
ug/L
ug/L
<1.0
500
500 515
501
103 100
70-130
3
3
Cadmium
ug/L
<5.0
500
500 519
504
1
104 01
70-130
3
Chromium
ug/L
206
5000
5000 5190
5040
100 97
70-130
3
Iron
ug/L
<5.0
500
500 500
484
100 97
70-130
3
Lead
ug/L
9.9
500
500 518
505
102 99
70-130
Manganese
ug/L
<10.0
500
500 518
505
104 101
70-130
2
Selenium
ug/L
<5.0
250
250 249
244
100 97
70-130
2
Silver
In the units indicated by the "units"
column except where an alternate unit
is presented to the right of the result.
Results presented on this
page
are
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 9 of 18
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical services, L-C.

ace Analytical
www.pacolain.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2771560
MS
92459126001 Spike
Parameter Units Result Cone.
Sodium ug/L 39000 5000
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
2771561
MSD
Spike MS MSD MS MSD %Rec
Cone. Result Result % Rec % Rae Limits RPD Qua[
5000 43800 43300 97 86 70-130 1
Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 18

aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 518157 Analysis Method: SM 254OC-2011
QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92459137001, 92459137002. 92459137003, 92459137004
METHOD BLANK: 2773983 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 01/07/20 17:08
LABORATORY CONTROL SAMPLE:
2773984
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 2773985
Parameter Units
Total Dissolved Solids mg/L
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Spike LCS 1-CS % Rec
Conc. Result % Rec Limits Qualifiers
250 260 104 90-110
92459137001 Dup
Result Result RPD Qualifiers
47.0 28.0 51 D6
Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical services, LLC.
Page 11 of 18

(aceAnalyficalo
Ww .pacelabsxom
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 517670 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2771530 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L NO 1.0 01/03/2010:05
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 2771531
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Sulfate mg/L 50 50.1 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2771532 2771533
MS MSD
92459106001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Sulfate mg/L 22.1 50 50 71.0 71.9 98 100 90-110 1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 01/13/2020 11:69 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

aceAnalytical e
www.pacelabs.com
QUALITY CONTROL DATA
Project: MW's 1/2120
Pace Project No.: 92459137
QC Batch: 518465 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350A Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2775365 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L NO 0.10 01/10/20 09:41
LABORATORY CONTROL SAMPLE:
2775366
Spike
1-CS
Parameter
Units
Conc.
Result
Nitrogen, Ammonia
mg/L
5
4.9
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2775367
2775368
MS
MSD
92459132005
Spike
Spike MS
Parameter
Units Result
Conc.
Conc. Result
Nitrogen, Ammonia
mg/L 93.1
5
5 97.0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2775369
MS MSD
92459137001 Spike Spike
Parameter Units Result Conc. Conc.
Nitrogen, Ammonia mg/1- ND 5 5
2775370
MS
Result
4.9
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
1-CS % Rec
% Rec Limits Qualifiers
98 90-110
MSD MS MSD % Rec
Result %Rec %Rec Limits RPD Qual
97.2 77 82 90-110 0 M6
MSD MS MSD % Rec
Result a/ Rec % Rec Limits RPD Qual
4.9 98 98 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 18

ZeAnalyficalo
,W.pacalaba.corn
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 517829 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2772270 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 01/03/2023:04
LABORATORY CONTROL SAMPLE: 2772271
Parameter
Nitrogen, Nitrate
Units
mg/L
Spike
Cone,
1.5
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2772272
MS
92459137001 Spike
Parameter Units Result Cone.
Nitrogen, Nitrate mg/L 0.096 1.5
LCS LCS
Result % Rec
1.5 102
2772273
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
a/ Rec
Limits Qualifiers
90-110
MSD
Spike MS MSD MS MSD %Rec
Cone. Result Result % Rec % Rec Limits RPD
1.5 1.7 1.7 105 104 90-110 1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical services, LLC.
Qual
Page 14 of I

aceAnalyticalo
www.pacelabs.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 518229 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2774214 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Chloride
mg/L
NO
1.0
01/08/2011:14
2774215
Units
Spike
Cone.
LCS
Result
LCS
% Rec
%Rec
Limits Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
Chloride
mg/L
20
20.3
102
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2774216 MS
92459122002 Spike
Parameter Units Result Cone.
Chloride mg/L 34.4 10
MSD
Spike
Cone.
10
2774217
MS
Result
46.3
MSD
Result
46.4
MS MSD % Rec
%Rec %Rec Limits RPD Qual
119 120 90-110 0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2774218 MS MSD
92459045001 Spike Spike
Parameter Units Result Cone. Cone.
Chloride mg/L 29.3 10 10
2774219
MS
Result
35.9
MSD MS MSD % Rec
Result % Rec % Rec Limits RPD Qual
35.7 66 64 90-110 0 M1
Results presented on this page are in the units Ind lcated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 18

aceAnalytical
www.pacelsbs.com
QUALITY CONTROL DATA
Project: MW's 1/2/20
Pace Project No.: 92459137
QC Batch: 518566 Analysis Method: SM 531OB-2011
QC Batch Method: SM 531OB-2011 Analysis Description: 5310E TOC
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
METHOD BLANK: 2775757 Matrix: Water
Associated Lab Samples: 92459137001, 92459137002, 92459137003, 92459137004
Blank Reporting
Parameter Units Result Limit Analyzed
Total Organic Carbon mg/L ND 1.0 01/10/20 23:39
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 2775758
Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Total Organic Carbon mg/L 25 23.9 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2775759 2775760
MS MSD
92459388020 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 22.7 22.6 90 90 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2775761
MS
92459388027 Spike
Parameter Units Result Cone.
Total Organic Carbon mg/L ND 25
MSD
Spike
Cone.
2775762
MS
Result
MSD MS MSD % Rec
Result % Rec % Rec Limits RPD Qual
25
23.7
23.5 94 93 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 16 of 18
Date: 01/13/2020 11:59 AM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
www.pacelahxom
QUALIFIERS
Project: MW's 1/2/20
Pace Project No.: 92459137
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NO - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
06 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date: 01/13/2020 11:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 18

aceAnalytical
www.pacelabs.com
Project: MW's 1/2120
Pace Project No.: 92459137
Lab ID
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
92459137003
92459137004
92459137001
92459137002
02459137003
92459137004
92459137001
92459137002
92459137003
92459137004
Sample ID
M W-05
MW-06R
MW-08R
M W-07
M W-05
MW-06R
M W-08R
M W-07
M W-05
MW-06R
MW-08R
MW-07
M W-05
MW-06R
MW-08R
M W-07
M W-05
MW-06R
MW-08R
MW-07
M W-05
M W-06R
MW-08R
M W-07
MW-05
MW-06R
MW-08R
M W-07
M W-05
MW-06R
M W-08R
M W-07
M W-05
MW-06R
MW-08R
MW-07
QUALITY CONTROL DATA CROSS REFERENCE TABLE
QC Batch Method
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
SM 254OC-2011
SM 254OC-2011
SM 254OC-2011
SM 2540C-2011
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
SM 4500-CI-E-2011
SM 4500-CI-E-2011
SM 4500-CI-E-2011
SM 4500-CI-E-2011
SM 531OB-2011
SM 531OB-2011
SM 531OB-2011
SM 531OB-2011
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch Analytical Method
517676
517676
517676
517676
517707
517707
517707
517707
518157
518157
518157
518157
517670
517670
517670
517670
518466
518465
518465
518465
517829
517829
517829
517829
518229
518229
518229
518229
518566
518566
518566
518566
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
EPA 245.1 Rev 3.0 1994
Analytical
Batch
517687
517687
517687
517687
517754
517754
517754
517754
Date: 01/13/2020 11:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 18

J
_N
N
O
OI
J 0 O W
J N _ o
`�i6woE wcv
❑
w
O
V
o
pn;
0
=
O
0
N
49
°
a
z
O
M
=
13
O
ZO
gm0
0
G
u u ;:
m m
a
3
E
5
t 0E
E
c
r
o
z
u
U
w####
Wi g. Ar
,.
.a
U W
w aw'
O
m
0
aI--
Y
:a
a I
r
L c
o
c
13
w
Q
E
E E
E
o
Z
O
Fa
m
m
y
C6 y
Q
_
d
m
,� ..w�
�
E
O
�
(9 t
�•
E
U E
'O
t
0
m
W v
z U
v
o
o
U v
u
zo w,
o p=
y
0
U
m
o
o
a m
le
E
Q vi
�
am
'oy
Cy
. wtrWN
wZw
auJ
iwLL�n0
O
Q
m
E
2
.
aaLL•
N
Co)
OJ
o
J
N
v
UmA
Z
gc
Nm
wo
a m
d
a
d
N
t
�0
!
m
y
Umn
0
.wFu0
O
J m
O
K
n
w¢ 1
n
O Q
O
m
Q
m
Z
O
m
J>
o
❑c
❑
❑' ❑
❑
❑
)a
v
rn
rn
rn
E rn
rn
m
rn
m
NI
-
E
E
E
E
E E
E E
E�
E
E>>
2
E>>
E
E>>
E
lamO
�_
O
�.
Z
2
d
C
,0
i
N
d
m
m
.. ..
'�
E
Elm
m
I�
m
O
O
V
N
o
OV
N
E
3
m
a
'N'
u d
m
'00
a
O
V
c
N
m
m
m
m
m
o
0 0
0
z
0
m 0>>>>
>
n>
d
c
a#i
3
E 3 m
m
'.o-.
y
o
n _-
u
0
0
m
u
01
v
r`
'd
.�
m
E
E
m
m
a
F
o
U
i
o
vmi to
« c
U
uni
o o
m
U
m
E
z
m
z
a
z
❑
K
'°
e
O
'N °
m
E
U
a
F
m O
'�
o
U
v
S
m
J
Z
m
0
U
0
O
9
Z
a
o
rn
z
a
❑
U
�
9
C
d
d
J
E
m
N
<
C
m
In
m
o
J
0
0
J
J
J
t
v
w
E
o
o
E
m
pl
rn
g
a
ci
>
N
��
E
�
E
E
E
o
E
E o
E
s
E
E
E
E
ry
m
t
z
E
W
C
O
o
t
t
a
E
y
v
s
z
rn
¢
¢
o
44
a m
E
05
w
yj
'c
C O
N
�°
'm
E
O .0
O
N
'�
N
O1
€. N en-
'O
Uj
�•
V
V
V
m
Hl
E E
=
9
O'>
m
o
0
0
o
n m
m
o
I
Q 2'o
O
Z o
;=, y
`w
O E N
o a
M'
o
.'a
n a
i-
o
0
0
0'
0
0
0"
o
a W
°1
`�
o
y
f
~~„°`., m
a
m
kw-
KvO
❑�
�r
m
a
U
.mO
V�N
m
o
m�
�§
Z
W
m N
K
z
W >
N
OLL Z
O
Li
~ z
~
`•
O
CO
N
'� L
5
E 9
O 1
m
w
W
¢
m
Z
LL
v=
r
a
f0
.R¢
z
F- W
K
v
Q
LLm
uyy
LL
u
n
U
Q�
m
?
E
3 Z
ti
•d v
o m
E
c
K id K
E'
a
W
m
m
a
0
Q n
FY-
❑ Q
E
y
c
.gym-
3
a
€
m
Z J
m
} Z
a
m v
QN�
m
a
m
Z w
Z O ¢
rn
c o
.0
m
I
Q E w
9'-
2
V
>
0
o
N
N
m
O
O
U
O
U
02
J :e
.m.
J
6 J O c
m E
O 0 a
U
K Oami
3
3❑�>
o
m
g m Q
rq
(90
LL LL
a LL
c�
Ni
rn
❑a
1

-:�
r
U'
rn
3Qa Ewv
oJ❑v_y
Ve
o
d
z
N '
d
O
Ory
N
L
V
N
1 O
N N
❑
Z
O O
A
U
d
N
m2
O
m m
O
m
N
Q
0'd
@DLO
O Z
E E
m o
c
c
U
O
v a
a a
a
m
o
..°a
�:z u.
Z
a❑❑❑
a
E E
E
-
z
'E'
`m
o
p
N
Z
(i
V
E?
V
E
Z
o
o❑
�O
d
2
W00'
N
°
U w
o
o
,Tip
S
I
o
Z
v
E
>;
m
O
n
0
o a-'>'.:
o
dJ
cc
o U
o
m e
N
d
h>
v
'v
z=
d m
m
w-'
E rn
o a.
2•
❑
o
`p
m
W
Y
r
w p lNt:
z u O N
6
O m
m n
Y
O
.O.
ry
J o 0
W a
a
m
C
N
L N
N
w
fn
N
C7
K
d
a U
E Z: J.'.
♦' N
LL
U p
J (7
> 3
S
IL 6 wp
Od,
Q
a
w
p Q
wZ
O
N
J%
K.O . �•.
'L Q
w W
[0 El
El
Ela+>"
o4dzz�
w o
a
Er
,o
I
E E
E E
rn
E
rn rn
E
rn
a E
E m
m
E E
E
E E
o
E
o
o
>>
E
E>>
z
'Z
N
E
y
ON
N
p"
C
O
O
O
O
O
N
O
E
L6
v
u N 2
a
ov
.�-
v
vp
aye
v
0
O
O
N
O
N_
O
ry
O
S
m0
O
O
O
m
m0 0
f°
iO
y
m d
w
a
E c
o0 .
o
n o
0
0
0
0
0
o
0
'o
y
o
m°
z z
°'
E
E
E
E
-a
`m
c
2• E
E
`u
m
Z w
0 N
m
r _�
0
'=
=
t
a£
u>>
m
u f
0
0
°
of N
>
v
U
w
O A
c rn
Z f
U
Q
O
Z
N
4=
r
m N
O Q
p
O O
Q
U
m
E
LL
m C
Z"
m
d
Z
F�
U
a
0
U
=
f
$
o
m
z "'
L U
U
g
a
o
Z
w
w z
°u
0
L
z
❑
a
�
a
c
a
d
a
E
N
v
w
e
W
p
Orn o
o
2
S.
w
ar
p�
E
m
or
a
Y
E
E
E
E
o
E
E
E i
E
E i
E
N
c
E
y
z
Z
V
N
3
J
0 O
N
N
O
L
C
`0K
O
N
0
'O
C
N
21 N
m
i
Q
N
O
m
C
E
r
N
fV
N
v
ONl
`-
Z�
0` j
�n N
mm
N
o
0
o
m
a
h
N
0
o
C
O
Z
.�'-
w
`w
O F o
n $F.�
o M
6
M a
n
a
'N°
o
o
o
o
m
0 0
0„
r
E
Oa
E
O y
.'-: N
c N
S'
y
E
a o
a m`
¢ vd,
Fw-
p❑
«`
m
,o
U
m
u
N
o
o
m o
0'
mi
Z
p
p
W LL
2
'Ya_
Z
N
!�
N
TZ
LL
116
N
v
O
y
D
LL
7
E e
m °
F- W
w
O w J
m
6 1p
_Z
m
c
a. U
-el
Z
O
LL y
'v m
-
y
Z
LL
z i
C
'o
N°
E
C (lf
t0 K
N
m
o
n
`
F
O a
?
E
„m`,
c�
m
a
nIw-
E'
U°
gym, E
9
DEL
m
a
m°
o
z r 3
�°ms
m
w
v_�E�
o
�'
�
v
'°
~
a
Z'
d
N
o
O
-_�
U '�
E :�
m
.
J
a J❑ c
W n
N
E
E
O
m m
U
N
m
n
K O
v
a
m
N
N
K

2
r
d
A
�
m
J O O
JO Eco
W y E
� a= E 0
m t d
'—�3mmdL
o
o
E
o
d
Z
o
_0
y
N
<
a
•m
m
' i
v
E
00
a
g^
O
Z
K O
o
0
0
Q
d
o
0 0
0
m
0-
O
G
}
m
w
W
Z a❑❑❑
w
=
a❑
E
w
E E
m
E
Fy
m
of
v
o<
v
O
O
E
d
u
0
m
W
Z
U
J
O
O
a
0 O F-
O
W
w
K
7
d
J
C
Vw
Q
Z
Z
k
(
:yi
a
Oy
'uy
U0:
o
L"
d
m
F4
a�J
iLL
o
m w
o 0
n
d
Um
N°
o
n
O¢w
Z
pZaU'
?
jaa
y
0
v
O
K
c
O
}}a
J
ktl
J
OI
OI
OI
O)
OI
Ol
I
CI
OI
OI CI
OI
O
E
E
E
E EW
o T
E'
>
T
E
Z
o
E
E>>
❑
Y
C �
_y
o
y
y
m N
-m
L'
C
❑
m
O
O
O
^
N
ti
w
w
a
v
v
mV�
vv
G
d C
d
N
o
m
oO
o
ti
m
rn
0
ps
O
d
o
O
o
m
Z
Z
n
°E
E
E
E
-Fa
En
«
N
m
m>
F
F
_LLw
w
o C
q
U
cmE
?00
rvo
E
Z
o
Z
Z
.2
aEA
mmC
z
onm
o
0`n
2Z
Y
uo
L
rn c
ti
o
v
Z
'oO
U
o
Z
0
o
Z
0
a
g
O
E
1
L
J
'C
w
m
O
O
O)
'C
Ol
OI
OI
m
02
Ol
OI
a
ry
y
m
ry Y
m
E
E
o
E
E
E
E
E
E
z
U
c
Op
m
d
C
o
8
y
Z
w
m
E
v
i
0
0
c
c
<
3
a
0>
d
r
E
i
i
d
a
m
C
0
O
E
2
CQC
O
D n
y
N
3
€
.`r-
a
Z d
2
N
M
V
Oai
OV E
Q
CY 0
2
o
n
N
O E
N
o
a
Q- lil
o
0O
0E
om
O
o
o
❑
nvo
U
Z
W
m
2o
E 3N
0 wZ
O
OF0'
m
ZW
C
7
LL
CJ
mw`
Com
Lm
Jo
m0
<„
W
O w
0
o
E
U
?rZVIQ-i
z
O
E y
wm
'
N
oc
pY
,
Ja
Z�
OO`
iL
Z
o
'
m
NJ
O
'u
'u
c
LL J
a
E
O
m :•'
G
wO
w
w
d
v
m
(7U
LL
LL
a
2
C.)3
ei3
9 0"
2>
W.
u
N
m
K

q
r
w
c� m
W
o
Z
c E
o or.
c
p
rc; o', �.
o
O
v i
b
O
E E D v
E2'm
' 'a
O Z
v v 0
w
W
K K J O
<rc-p N..
O
F 0 "pe
N O
m
JO:
O
O =
K
_La
u. w.
`w
h O
E
rn
K
o
c ii. � y
, 'n
2
o. O
u 0.
u
LL
O
O
L
O
w
,E
c
a❑' ❑ ❑❑
6
Z
K
Z
02
2w
O
�O
aW
O
z
K o m ❑
� v c
in C 4Y .
U
J
�j J` J
E E E
T
_ 0
c
c
U
w o
a Z
W
0
tl N
�
J
�
U
w
O O O
a k L
S 5£
Q
E
E E E
U 0
C9 N•
N D
U E a
Ut LNm
� F A
Q
U � o
N >
O J
` J cg J `
E > > E > >
Inl
I I
I'NI
I�I�I
MINI
I Inl
u.l
E
E
Z
J
n
0
y O
Z
C) o
Z
0
'
Q
ro
U
m
U
.�
U
LL
�'
a
m
a
E
m
m
'
U
an
d
A
Z
m 0.a;
2
c
a
U
a
U
o
=
Y
?
Z
r
0
tj
rn
c
D
2 n
o
p
L
a
lO
�
01
J J
O O
J
y J
J J
J
y
J J t
J
J
O O
E
E
E
0
E
E
E
i
E
E
s
E
n
$'
3
ryry
q
m
0
N
O!
p0
e
00
d
O „v, v
•0 m
Z
U
Fp E
F
N
FO
'c C
O
C C
w
s
a
2
L Q
m
LL N
Z
$
o
U
v
E?
E'
o
n
a
6 a
.E
F
w=
v
U
«
o
U U
v
0
to

Dafe leeued: March 8, 2019
Document Name: Field date Sheet Pa e:1of �•
gCefiltal}rflG:37y Ies;ZS Authority: Pam Huntenville Quality.
. Document Numbtr: F-CAR-FLD-001-rev.03 Office .
Field Data Sheet
�60 Sn 20213
Name and Affiliation (Sampler($):. \O —Pace. Field Data Sheet Review:
Name and Affiliation(Inspector): NA- " Date: By: 6FZ-r
Well Information
Well tD: rA W Well Locked: LS NO / Flushmount )
Well Diameter: 2, Consttuction: Steel/StainlessSteel)
Total Well Depth: 2_ ' 12 ft Mu1HFactor*:(? _["(ftadus/12)2x3.74x7.48].
Static Water Level: I -4 —it Casing Volume: J 55g gallons.
Height of Water Column: `) e 5b ft Cal. 3 Volumes: ''(. b_y gallons...
Pump Intake:
Purge Irrforrnatfon5,1-02,2a1o.
DatePutged:�/ ate—/ X;ZO Start: to i 5 Finish 12_b5 gPu/r�geoR'ate: OmI M
Purging Method: Pe(, S W'S5, ey n P � __Total Volume Purged: � (gallons/dig:WL)
Sampling Information
-Date ColleAed:_W _/Qa_/ -VU Time Collected:- L J _i 6 {am/ my
Sampling 9lt pmentUsed:OPC`QiaS �f: Q� lnstrurttentID:��S �37 /��At219H
Bottle Type Presgrvati4n Analysis Required
jXGOD ML PI SUC NONE
fXa 0mL'`Plasi_.. NDN._
IXI Srn. Riost-,(, cN> fj"If.ie_
) a5o m� Rlas'�� �r� m2k�15
Kt t—� L`���,LI^- NPO.51-;c HZ Ammon?a
3 i'&edsiiretnente/Observations FhoSpw c
Sample Terirp.(°C): . I� , Time: 1216 Turbidity (ntu): ".6. Timer
'Dig sOxy(Mg/L) Time: "_Fe2+mg/L: `
'Specific Cond. (us): O Time: 11,E —Res. Cl-:(mg/L)/(µg/L): Time:
Sa:
ut le H s.u.—N 1) T me( 11 d
P P ( ): . Time: Odor:
ReDox(mV): Time: Appearance:6 _Time:,:-.1kiu
ReDox(value):YSIProPhis+200mV J Other: Time:
FS-I
General/Weather Observations: W` S. N� W o it
(sunny/. u i�n Temp.1 a (T' Wind 3 - S (mph)
Sampler Signature,
^
Time.
Temp.
Digs Oxy.
Spec.
Court,
pH (s.u.)
Purged
(°C)
(mg/L)
(A
10�5
ti
C 6
3q•b
6Leg, {
I , 6
39.6.
5.
•
p'}'
`3
I q0
10 '8
39.J.
6,1
ReDox
Turbidity removed
Water
Omer
(mV)
(niu) (gallons/ tom'
level (it)
.
2�.6 00
13,ti�T.
I'll, y i2bo
$.4�i
9DDO
5b,9 �464

Document Name: Field data Sheet Pa : 1 of2-
�.. aCeMalyKical' issuing Authorlty Pace Hunteraville Quality.
t Document Number.P•CAR-FLD-001-rev.03 Office.
Field Data Sheet ' 000. Za?13
Clienf: M S Location: FFSI,e J;'I1P t/l/C Project #: tYl S P" -Ask 1 al
Name and Affiliation (Sampler(s}: t S ' P2'G� - Field Data Sheet Review:
Name and Affiliation (Inspector): A) Date: (3•,- d D'20 By: S'('.G'
Well Information
WellW: MW bR Well Lacked; (YE51/NO us o
Well Diameter: a Construction: I'Vteel/Stainless Steel)
ToWWellDepth: 15,t� ft Multi Factor`:OJO "r(Radiva/12)293.140-481.
.
StaticWater Level- 0.�.2917-
.ft GasingVolume: gallons,
Height of Water COlunu1 01 it Cal. 3 Volumes:— gallons .
Pump Intake: bL So It
Purge Information
Date Purged..( I_/ da' /2blO Start: 15-Go Finish: 6�PurgeRate;_((K3(tSlcll✓`
PurghlgMethod: PLC' SOrn ',L t7n�, _Total Volume Purged: -(gallons/ n�/1 L)
Sam - ling Inf ormatiOu "
Date Collected: wal)Time Collected:
�,
Sampling Equipment Used: eC S Eo } . ( u .
N « ?�t�Z4�
Instrument ID:r �_L
alysis Required .
Bottle Type PreservatiIim Analysis
X5cvnn A51:C _ �oN
(x2S©mL Flo,5'�f• NeN(a
CI I ? SDI :-
1 K12Srnl- Q�aS�'i �- /✓Qn) G
�� %�U.-�
ASf:C—
JIkZSdInL
tions(boo
Field Measurement$` 2R11tM
S a
Turbidity (ntu): _.Time: .
Sample TeAtp cc): Time:�11
➢fps. Oxy:(mg/L)' _ Time: ` .
Fe 2+ m€/L:_. . Time "
�{
Specific Cond. (uS): �3 ° -Time: -- -- —
`0
Res. Cl (mg%L))(µg/L) Time;�16�{0
f�
Sample pH 0-11- : n � Time: ) 6
- Odor: �__/l )L� r'r.� Timer
Appearance: MINI%^. T e.
ReDox (mV};, Time:
ReDox (EH Value):YSI ProPlus +200mV
Other: Time:
Generaj/Weather Observations PAW, ' 6 Q f,C)
G L Ye
(sunny/ F) Wind 1.�:(mPh)
Sampler
Time Temp. Diss Oxy. Spec• ReDox Turbidity rea oved . Water Other
u Cond, pH(s.u.). aUons is level ft
Purged (C) (mg/L) (US) . (mV) ( )

Date issued:
Document Name: Field data Sheet
lot
i
i
,. 9CBRn9IJMeBl"
Document Numb&: F•CAR•111,13 001•rev.03
APPIO
Nameand Affiliation
Name pnd Affiliation (Inspector):.
Well hdt rmatiiJ
Well ID; M. 0 - T E
Well Diameter: 9-
-
Total WellDepth: I .� d £t
Static Water Level: 10...1 � it
Height of Water Column:.L—'I'--Jt
- V^a IField Data Sheet Review:
Date; OL-03-DOZ By:
Welllocked; (�YES / NO us )
Constmction: PV Steel/Stainless&teel)
Multi Fartor":04 6:3 ["(Radius/12)2x3.14OAS).
Casing Volume: gallons,
Cal. 3 Volumes: 4 (� 5� -gallons,
Pump Intake:
Purge Inforntati'dn C
Date For gad; /vim'/.LVG� Start: �3�J_—.._Finish: �J .. Purge Rate, (OOML /+1
Purging Method: krs+"01�C V Total Volume'Purged: ( (gallonsQL)
Sampling Infoymatiort _ Time DatYColleced;D d i (am/p�m A , it.. n
Sampling Equipment Used:`1 ..�,
n resetvatl.n Analysis.Required
Bottle Type
Tb5
lx lZS tltL Q�ASi t Aq N (N E. .._ AArWc,
' fink-i..) J
FiAtd easu a ente' Obi-ery tions e
°271 1
Sample Temp (°C): . Time. Turbidity (ntu): T mer
3L
DissOxy(mg/L): Time: Fe2+mg/L:Tune: •
Specific Cond..(u5): �+�yy �_ Time: f 3 Res. Ci (mg/Ly(µg/L): � Time
— �r-
- l"`
Sample H s.u.: 5 Time: Udor: rl td er Tune: L--
ReDox (mV): Time: Appearance: Time:
ReDox (EH value):YSI ProPlus +200mV ' - Other: 1 T,i�me:f_`_�
e' VI
VIFI—
Sampler
Stabilization
Test
Turbidity,
(ntn)
renove
(gallo mis
Water
ledel (ft)
7Other
Time
Tem .
DissOX O.Y.
Spec.
Cond
H s.u.
P ( )
ReDox
Purged
(°C)
(mg/l)
(US)'
(mV)
114f
I
9 I . '
6.3
c�
foo D
r0.
.

/
E2
Document Name: Field data Sheet _ Pa e: 1 of Z.
AuthoH Pace Huntersviae Quality. '
. Document Number. P•CA12-PLDetll-xev.03 OfFiee .
�A Field Data Sheet '
dStlt-c'_-7ri1ilx con/t .J4n La go .
t Location: AS I MIL I&I Cproject #:
Clienf:
Name and Affiliation (Sampler(s): tDS
,
_.—a�� Field Data Sheet Review;
P,
Name and Affiliation (Inspector)' aim — Date:Ot-O3-.a0o By'M&
Well Infomtatidn
M �) '
-
Well Locked: (YBS / NO II }
Well1D:
Well Diameter:
I
Consttuction:((PVC feel/Staittle"5teel) '
G
7 / +� rpdius/12)2 x 3.14ic 7.491.
Total Well Depth: f . ft Multi Factor .
1
Static Water Level: , �' Et
Casing Volume: I_ gl a gallons.
Column:, Cal. 3 VoIuines:.gallons'
Height of Wafer
``
Pump Intake: �b JC d __ ft '
Puree I'nforinafi'on
DatePurged: d L/y '/tart: 0 Firlish: 15to PuxgeRate:lD�ri1L/
C
u TotalVohtmePuxged: `6 �l (gallons/ l&L)
PurgtngMethod:
.
;.. i
Sam lin infdtmation,�/�c� "�
Collected: 15_ZS — .. (am m
Collected:
Date /k
f
�t C U :trumeht ID: vetr�a339 /�w�uy� I
Sampling Equipment Used:
Preservatt6n Analysis Required
Bottle Type
-r-ns
�1C5tio rnl
9Gn,t1jr 'tt�gb,'t'__
-
NoN•r,
1 K,1 ZS mU ROSES
NON F -;
1;
IlC1'5ovnL . C
I Kk, t my U iG
°}•�Alda ..• ,gm�,o,,2�.:
-5o - .. .. ., ..
AL2d 7Z7e
'Tti mtei V` PidSp
ie easurements/ bservations
5 i 5 zi
°(•
Sample Teulp (C):_ .
Time: }% Turbidity (ntu}: — Time:'
Time: %Fe2+m9/L: Time:
Specific Cond. (uS): 6�:
Time: 15Z5 `Ri s, Cl (mg/L)/(Itg/L):
Sam le H s.u.: 7i
P P ( ) -
Time: ) 5 25 �Odbx: N i7 Time:
ReDox(mV):^
' Appearance: c�— T1me:�—
Time: - PP
-�' ' Time:
ReDox (EHvalue):YSI ProPlus +2DomV Other: ---- ,.
t r '� xJ�J l
Genera(lGVeatherObservatlansh
(aututy clou / ain Temp.(°F) Wind.6 (mph)
Date: 01 -09 -?AZU -
Sampler Signature:
<., .
r.
Time
'temp,
Dlas Oxy.
Spec.
Cond.
PH (a
Purged
'(°C
(mg/L)
(us)
h
0 -1
WaterOther
u.)(ntu)
(gallons
level (it)
dReDoxurbidity.
�5
0
�
�W, 3
IlaD3

3
p a
m D D
n
x
ITEM#
rd
° 01'�
3 0
a
3
`
n
z N�
z
n
R
1
b
p z
n
p
N O
m
i
oGG
opao
'A
Y
a
3 n W
m
m
°
o
g
�Dd
0
x
-
b
N
D
Z
?4rFogsnn
_2g
sna= x
3
is
.Osa0�9�$Reo
m o
u
z q
o
o$
o
o
MATRI%CODE (see valid wtlea Wait)
C,
�^¢
SAMPLETYPE (G=GRAB C=COMP)
,,C..
m
yT
N:
N
a-:
D-,
m
O
/�
a
+H+
,
°
"i
D
y
m
3
m
m
°
n
N
'av
M
m
rI
z
SAMPLE TEMP AT COLLECTION
p
A
.Dj
c
m.
}
CYy
pOF CONTNNERS
m
a .
D¢ O
q
O
uei ;
6
° O
R
U.)
V3
`'`.
yry
IJJ
Unpre SPNEd
39
O
°
,
H2SO4
z
0 °
—
HNO3
U
o
HCI
m
,
NaOH
Na2S203
:-rI
m
a
Methanol
9.
�
o
1%
Other
Analyses Test ;
YIN
Dx
v
k
x
x
ammonia
y
[. °z'.,
S
x
x
x
x
Metals
m
m
X
x
X
x
Chloride, Sulfate
y
-
U
a
x
x
x
x
Nitrate
"
x'
k
k
x
X
TDS
O
�
-
x
x
x
k
70C
0
1`-➢..
C
N.
T
a
4—
`'
ta
ta
"
TEMP in C
rP
y
`y
3,
Residual Chlorine (YIN)
O
o
�-
b
O
Received on
Ce
o
Q
Q
p
uslo y
Soaled�.
O
Cooler
d
4"
(YIN)�\
m.
/
Samples
Intact
-
(YIN)
N
0
s0