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HomeMy WebLinkAboutNC0003298_PERMIT ISSUANCE_20130607NPDES DOCUMENT SCANNINS COVER SHEET NPDES Permit: NC0003298 Riegelwood Paper Mill Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Speculative Limits Monitoring Report Instream Assessment (67B) Environmental Assessment (EA) Permit History Document Date: June 7, 2013 This document is prated an r+01Mse paper - ignore any C axitent axk the reuersfa side NCD North Carolina Department of Environment and Natural Resources Division of Water Quality Pat McCrory Charles Wakild, P. E. John E. Governor Director June 7, 2013 Mr. Floyd Whitmire, Mill Manager International Paper Company Riegelwood Mill 865 John L. Riegel Road Riegelwood, North Carolina 28456 Dear Mr. Whitmire: Skvarla, Ill Secretary Subject: Issuance of NPDES Permit NCO003298 Riegelwood Mill Columbus County Facility Class IV Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007 (or as subsequently amended). The following changes have been incorporated into this permit renewal: 0 Lim_its for Chloroform were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 004 and Outfall 005. • Limits for AOX were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 001. 0 Li-mits for Pentachlotophenol and Trichloroplicnol were calculated in accordance with 40 CFR 430.100 and 40 CFR 430.20 and added to Outfall 001. • Limits for TSS were calculated in accordance with 40 CFR 430.22 and added to Outfalll 001. • Outfall 002 was eliminated from the permit due to the elimination of the discharge. • The influent monitoring requirements for BOD and TSS were eliminated (Outfall 001). • Monitoring for Total Chromium, Total Mercury, Total Nickel and Total Zinc was removed from the permit based on the results of the Reasonable Potential Analysis. 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury 61, Raleigh, North Carolina 27604 Phone: 91 M07-63001 FAX: 919.807-6492 Internet; www.rmat_ _erpuality,om NonrthCarolina Naturally ff An Equal Opportunity 1 Affirmative Action Employer Monitoring for the internal outfalls parameters (except for flow) were reduced to Quarterly in ' accordance with the 40 CFR 430.02. w Please note that the receiving waterbody has been designated as Primary Nursery Area (PNA) waters by the NC Marine Fisheries Commission. Such a designation may trigger a supplemental stream classification of High Quality Waters (HQW) with additional NPDES requirements for new and expanding wastewater discharges (per 15A NCAC 2B.0224), upon formal adoption of HQW class by the NC Environmental Management Commission, If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and fled with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Management Act or any other Federal. or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Sergei Cherniltov at telephone number (919) 807-6393. Sincerely, harles Wakild P.E. cc: OPDES Files Central Iles Wilmington Regional Office / Surface Water Protection Ms. Karrie-Jo Shell, EPA Region IV (e-copy) Environmental Sciences Section, Ecosystems Unit (e-copy: Steve Kroeger and Carrie Kuhlman) Aquatic Toxicology Unit (e-copy) r Permit No. NC0003298 ..�--� DEPARTMEN ENVIRONMENT. HEALTH_ AND NATURAL RESOURCES ATER QU. PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, International Paper Company, Inc. is hereby authorized to discharge wastewater from a facility located at NC Highway 87 in Riegelwood Columbus County to receiving waters designated as the Cape Fear River in the Cape Fear River Basin in accordance with effluent limitations, monitoring requirements, and other applicable conditions set forth in Parts I, II, and III hereof. This permit shall become effective July 1, 2013 This permit and authorization to discharge shall expire at midnight on November 30, 2016 Signed this day June 7, 2013 iarles Wakild P.E., Director i Division of Water Quality By Authority of the Environmental Management Commission Page 1 of 13 Permit No. NC0003298 • SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. International. Paper Company, Inc. Riegelwood Facility is hereby authorized to: Continue to operate existing treatment facilities (out£all 001) consisting of dual bar screens and primary clarifiers, nutrient addition facilities,173 acres of aerated lagoons with re -circulation, sludge holding Iagoons, sludge dewatering presses, oxygen injection facilities, flow measurement and recording equipment located at NC Highway 87, in Riegelwood, Columbus County, and 2. Discharge from said treatment works at the locations specified on the attached map into the Cape Fear River which is classified C-Swamp waters in the Cape Fear River Basin. Page 2 of 13 1� �.a a\� n hwr>Iod A D sT coRNrY,rrE 'Mitchell'. LaAinq, \' l� c� O ' ' Pridgeons _� S� r ✓1 �1�` "" 'y�/wy-r/ is r Na is r9 \ _, ` f NC0003298 - International Paper Company Latitude (Outfall 001): 34' 21' 10" Latitude (Outfall 002): 34' 21' 51" Longitude (Outfall O011: 78' 12' 10" Longitude (Outfall002): 78' 12' 70" USGS Quad: Acme, N.C. Stream Class: C-Swamp, PNA-HQW Receiving Stream: Cape Fear River Sub -Basin: 03-06.17 Facility Location ,fir Riegelwood Mill ✓Y Columbus County Permit NCO003298 A. (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS [001] During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge combined wastewaters from outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: -PARAMETER 4? y y "LIMITS ,'MONITORING REQUIREMENTS Monthly Average w t k Daily 1Vlaximum Measurement Frequency" Sample ' E 'TyP e Sample I:ocatibni Flow (MGD) 50.0 Continuous Recording Effluent BOD, 5-day, 200C une 1 — October 31 5,000 pounds/day 10,000 pounds/day Daily Composite Effluent BOD, 5-day, 200C (November 1 -- May 31 10,000 pounds/day 20,000 pounds/day Daily Composite Effluent Total Suspended Solids 55,371 ounds/dapounds/day 103,063 Daily Composite Effluent NH3-N Weekly Composite Effluent Temperature oC Daily Grab Effluent Dissolved Ongen Doly averse > 5.0 m /L Daily Grab Effluent Dissolved Oxygen I Daily Grab U & D H > 6.0 and c 9.0 standard units Daily Grab Effluent Total Phosphorus m /L Monthly Composite Effluent Total Nitrogen (mg/L) (NO2+NO3+TKN) Monthly Composite Effluent Chronic Toxici 2__Quarterly Comj2osite Effluent Dioxin3 0.9 /L Annually Composite Effluent AOX4 2,899 pounds/day 4,425 pounds/day Daily Composite Effluent Trichloro henol5 40.9pounds/day Weekly Composite Effluent Pentachloto henol' 6.51 ounds/da Weekly Composite Effluent Salim See Note 1 Grab, U & D Notes: 1. U: upstream at the International Paper water intake. D: downstream at the DuPont water intake. Instream samples shall be collected three times per week during June, July, August, and September and once per week during the remaining months of the year. NOTE: As a participant in the loaner Cape Fear River Monitoring Coalition, instream monitoring is not required Should the membershp in the Coalition be terminated, the Permittee shall not the Division immediately and be instream monitoring as specified in this permit. 2. Chronic Toxicity (Ceriodaphnia) P/F at 8.0% with testing in January, April, July, and October [see A. (4)]. 3. See A. (7) for derails. 4. AOX data shall, be submitted on a quarterly basis along with other Cluster Rule chemical data [see A. (9)]. 5. Monitoring is suspended for these compounds as long as chlorophenolic-containing biocides are not used at the facility. There shall be no discharge of floating solids or visible foam in other than trace amounts. Page 3 of 13 Permit NCO003298 A. (2) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS [004] During the period beginning upon the effective date of the permit and lasting until expiration, the discharge of wastewater from bleach plant 1 and bleach plant 2 to the wastewater treatment plant through internal outfall 004, shall be limited and monitored by the Permittee as specified below and detailed in partA. (9) of this permit: PARAMETER .Limits Monitaring Re'qui'rementsz Monthly Average.,, } 'Daily t Average'` Daily Minimum, Measurement Ftequeney, ' ' Sam' plc Type3` ' . ,Sample Location' Flown Weekly Calculated Effluent Chloroforms 10.4 pounds/day 17.4 pounds/day Quarterly Grab Effluent 2,3,7,8 Tetrachloro- dibenzo-p-dioxin CDD < 10 pg/L Quarterly Composite Effluent 2,3,7,8 Tetrachloro- dibenzo- -furan CD 31.9 pg/L Quarterly Composite Effluent Trichlorosyringol < 2.5 µg/L4 Quarterly Composite Effluent 3,4,5-Trichlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent 3,4,6-Trichlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent 3,4,5-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 3,4,6-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 4,5,6-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 2,4,5-Trichlorophenol < 2.5 µg/L4 Quarterly Composite Effluent 2,4,6-Trichlorophenol < 2.5 µg/L4 Quarterly . Composite Effluent Tetrachlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent Tetrachloroguaiacol < 5.0 µg/L4 Quarterly Composite Effluent 2 3,4,6- T� trachlorophenol < 2.5 µg/L4 Quarterly Composite Effluent Pentachlorophenol < 5.0 µg/L4 Quarterly Composite Effluent Footnotes: 1. Sample Location: Effluent is composed of bleach plants 1 and 2 effluent -acid (collected from acid sewer) and bleach plants 1 and 2 effluent -alkaline (collected from alkaline sewer) [see A. (9)]. 2. Monitoring and flow calculations shall be in accordance with A. (9). Chemical results for Effluent Guideline parameters as prepared by the perrnittee (Internal Outfall 004 parameters -+• AOX from Outfall 001) shall be reported on a quarterly basis or more frequently. 3. Sample Type: Calculated- calculate separate flows for alkaline and acid sewers by water balance or flow meters, and report total bleach plant 1 and 2 flow (acid + alkaline wastestreams) in DMRs. Grab- collect separate grab samples every 4-hours for 24-hour period from both the acid and alkaline streams, which will then be composited separately by the lab, and analyzed as separate 24-hr composite acid and alkaline samples. Composite- collect separate grab samples every 4 hours for 24-hour period from both the acid and alkaline streams, then prepare and analyze a single flow -proportioned composite of the acid and alkaline wastestrearn. 4. Limits are based on Minimum Levels (ML,) specified in 40 CFR 430.01. 5. For compliance purposes, the permittee must report total chloroform mass loading. Definitions: µg/L — Micrograms per liter pg/L — Picograms per liter ADT — air dried ton of pulp product Page 4of13 0i Pcrnut NCO003298 A• (3) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS 1005] During the period beginning upon the effective date of the permit and lasting until expiration, the discharge of wastewater from bleach plant 3 to the wastewater treatment plant through internal outfall 005, shall be limited and monitored by the Pennittee as specifier] below and detailed in part A. (9) of this permit: TARAM'ETER1., ,: •,• ' ';' :y. :.t• � �, ,,� €j { , ,,�,; ,, :Limit's• , , , , ; + "'• 't" •"' • •' r .t' _ _ ;; ,, ; ! Monitoring, Requirementss< . � i.'tY*�..4_' ri ..a: '�1 _�s .Monthly-, , Average- �� Daily' Average' Daily, Maximum 1' , : ;'Wa'suremeiiit•• ,;Frequency;; I`• 'Sample r�;' T,ype 'Sample Location'`" Flow2 Weekly Calculated Effluent Chloroforms 8.8 pounds/day 14.8 pounds/day Quarterly Grab Effluent 2,3,7,8 Tetrachloro-dibenzo-p- dioxin CDD < 10 pg/L Quarterly Composite Effluent 2,3,7,8 Tetmchloro-dibenzo-p- furan CD 31.9 pg/L Quarterly Composite Effluent Trichlorosyringol < 2.5 µg/L4 Quarterly Composite Effluent 3,4,5-Trichlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent 3,4,6-Trichlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent 3,4,5-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 3,4,6-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 4,5,6-Trichloroguaiacol < 2.5 µg/L4 Quarterly Composite Effluent 2,4,5-Trichlorophenol < 2,5 µg/L4 Quarterly Composite Effluent 2,4,6-Trichlorophenol < 2.5 µg/L4 Quarterly Composite Effluent Tetrachlorocatechol < 5.0 µg/L4 Quarterly Composite Effluent Tetrachloroguaiacol < 5.0 µg/U Quarterly Composite Effluent 2,3,4,G-Tetrachlorophenol < 2.5 µg/L4 Quarterly Composite Effluent Pentachlorophenol < 5.0 µg/L4 Quarterly Composite Effluent Footnotes: 1. Effluent is composed of bleach plant effluent -acid (collected from acid sewer) and bleach plant effluent - alkaline (collected from alkaline sewer) [see A. (9)]. 2. Monitoring and flow calculations shall be in accordance with A. (9). Chemical results for Effluent Guideline parameters as prepared by the pexmittee (Internal Outfall 005 parameters + AOX from Outfall 001) shall be reported on a quarterly basis or more frequently. 3. Sample Type: Calculated- calculate separate flows for alkaline and acid sewers by water balance or flow meters, and report total bleach plant flow (acid + alkaline wastestrenins) in DMRs.' Grab- collect separate grab samples evei-T 4- hours for 24-hour period from both the acid and alkaline streams, which will then be composited separately by the lab, and analyzed as separate 24-hr composite acid and alkaline samples. Composite- collect separate grab samples every 4 hours for 24-hour period from both the acid and alkaline streams, then prepare and analyze a single flow - proportioned composite of the acid and alkaline wastestream. 4. Limits are based on Minimum Levels (ML) specified in 40 CFR 430.01. 5. For compliance purposes, the pexmittee must report total chloroform mass loading, Definitions: µg/L -- Micrograms per liter pg/L — Picograms per liter Page 6 of 13 ADT —air dried ton of pulp product Permit NCO003298 A. (4) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 8.0%. The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of January, April, July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first rest of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: Attention: NC DENR / DWQ / Environmental Sciences Section 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section no later titan 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow' in the comment area of the form. The report shall be submitted to the Environmental Sciences Section at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. Page 6 of 13 Permit NCO003298 A: (5) 'BIOCIDE CONDITION The Permittee shall obtain authorization from the Division prior to utilizing any biocide in the cooling water. The Permittee shall notify the Director in writing not later than ninety (90) days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life or other than those previously reported to the Division. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Concentrations of chromium, copper or zinc added to biocides shall not exceed applicable water quality standards or action levels in the receiving stream, as determined by calculations from the Biocide Worksheet Form 101 with Supplemental Metals Analysis worksheet. A. (6) PERMIT RE -OPENER: NUTRIENT CONTROLS Pursuant to N.C. Gen. Stat. Section 143-215.1 and the implementing rules found in Title 15A of the North Carolina Administrative Code, Subchapter 2H, specifically, 15A NCAC 2H.0112(b)(1) and 2H.0114(a), and Part II sections B-12 and B-13 of this Permit, the Director of DWQ may reopen this permit to require supplemental nutrient monitoring of the discharge. The additional monitoring will be to support water quality modeling efforts within the Cape Fear River Basin, and shall be consistent with a monitoring plan developed jointly by the Division and affected stakeholders. A. (7) DIOXIN MONITORING For compliance purposes, the point of compliance shall be defined as the final effluent before discharge. Compliance with the daily maximum permit limit shall be demonstrated by determining the TCDD concentration at the final discharge point. Adequate sample volume shall be collected to perform the analysis. The total sample volume shall be collected and preserved in accordance with Part II, Section C Monitoring and Records. The sample shall be analyzed in accordance with the appropriate method of analysis specified in Analytical Procedures and Quality Assurance for Multimedia Analysis of Polychlorinated Dibenzo-para-dioxins and Polychlorinated Dibenzofurans by High Resolution Gas Chromatography/1-Iigh Resolution Mass Spectrometry, EPA, 1987 (EPA Method 1613), or another equivalent analytical protocol approved by DWQ. A single sample may be analyzed to determine compliance with the daily maximum effluent limitation. Alternatively, a sample volume may be collected to enable the sample to be split (duplicate analysis). If the analysis of either split sample is below the detection limit, the quantity, for the purposes of compliance evaluation, is considered to be zero. If both splits are positive, the results of the two analyses shall be averaged to determine compliance with the daily maximum effluent limitation. If the measurement is below detection limits, the quantity for the purposes of compliance evaluation is considered to be zero. The detection limit using these methods for the purpose of compliance evaluation is considered to be 10 picograms per liter. The dioxin isomer to be monitored and limited by this permit is 2, 3, 7, 8, TCDD. The Permittee shall perform the following analysis for dioxin: 1. Effluent 2. Fish tissue Annual Composite DWQ approved monitoring plan Fish tissue analysis will be performed in accordance with the Division of Water Quality approved monitoring plan. The monitoring plan is an enforceable part of this permit. All dioxin data collected as part of this monitoring requirement will be reported within two months of receiving the finalized analyses from the data collection. Page 7 of 13 Permit NC0003298 The chlorodibenzo dioxins and furans to be monitored are (this requirement applies for fish tissue monitoring I only): DIOXIN Isomer 2,3,7,8 TCDD 1,2,3,7,8 PeCDD 1,2,3,4,7,8 HxCDD 1,2,3,7,8,9 HxCDD 1,2,3,6,7,8 HxCDD 1,2,3,4,6,7,8 HpCDD DIBENZOFURAN Isomer 2,3,7,8 TCDF 1,2,3,7,8 PeCDF 2,3,4,7,8 PeCDF 1,2,3,4,7,8 HxCDF 1,2,3,7,8,9 HxCDF 1,2,3,6,7,8 HxCDF 2,3,4,6,7,8 HxCDF 1,2,3,4,6,7,8 HpCDF 1,2,3,4,7,8,9 HpCDF A. (8) CLUSTER RULE BMPs The permittee must implement the BMPs specified in Section A below. The primary BMP objective is to prevent leaks and spills of spent pulping liquors, soap, and turpentine. A secondary objective is to contain, collect, and recover at the immediate process area, or otherwise control, those leaks, spills, and intentional diversions of spent pulping liquor, soap, and turpentine that do occur. BMPs must be developed according to best engineering practices and must be implemented in a manner that takes into account the specific circumstances at the mill. Section A. Bh2 Implementation Requirements I. The permittee must return spilled or diverted spent pulping liquors, soap, and turpentine to the process to the maximum extent practicable as determined by the mill, recover such materials outside the process, or discharge spilled or diverted material at a rate that does not disrupt the receiving wastewater treatment system. 2. The permittee gust maintain a program to identify and repair leaking equipment items. This program must include: (i) Regular visual inspections (e.g., once per day) of process area with equipment items in spent pulping liquor, soap, and turpentine service; (ii) Immediate repair of leaking equipment items, when possible. Leaking equipment items that cannot be repaired during normal operations must be identified, temporary means for Snit. ting the leaks must be provided, and the leaking equipment items repaired during the next maintenance outage; (iii) Identification of conditions under which production will be curtailed or halted to repair leaking equipment items or to prevent pulping liquor, soap, and turpentine leaks and spills; and (iv) A means for tracking repairs over time to identify those equipment items where upgrade or replacement may be warranted based on frequency and severity of leaks, spills, or failures. 3. The permittee must operate continuous, automatic monitoring systems that the mill determines are necessary to detect and control leaks, spills, and intentional diversions of spent pulping liquor, soap, and turpentine. These monitoring systems should be integrated with the mill process control system and may include, e.g., high level monitors and alarms on storage tanks; process area conductivity (or pH) monitors and alarms; and process area sewer, process wastewater, and wastewater treatment plant conductivity (or pH) monitors and alarms. 4. The permittee must maintain a program of initial and refresher training of operators, maintenance personnel, and other technical and supervisory personnel who have responsibility for operating, maintaining, or supervising the operation and maintenance of equipment items in spent pulping liquor, soap, and turpentine service. The refresher training must be conducted at least annually and the training program must be documented. S. The permittee must prepare a brief report that evaluates each spill of spent pulping liquor, soap, or turpentine that is not contained at the immediate process area and any intentional diversion of spent pulping liquor, soap, or turpentine that is not contained at the immediate process area. The report must describe the equipment Page 8 of 13 Permit NC0003298 items involved, the circumstances leading to the incident, the effectiveness of the corrective actions taken to contA and recover the spill or intentional diversion, and plans to develop changes to equipment and operating and maintenance practices as necessary to prevent recurrence. Discussion of the reports must be included as part of the annual refresher training. 6. The permittee must maintain a program to review any planned modifications to the pulping and chemical recovery facilities and any construction activities in the pulping and chemical recovery areas before these activities commence. The purpose of such review is to prevent leaks and spills of spent pulping liquor, soap, and turpentine during the planned modifications, and to ensure that construction and supervisory personnel are aware of possible liquor diversions and of the requirement to prevent leaks and spills of spent pulping liquors, soap, and turpentine during construction. 7. The permittee must install and maintain secondary containment (i.e., containment constructed of materials impervious to pulping liquors) for spent pulping liquor bulk storage tanks equivalent to the volume of the largest tank plus sufficient freeboard for precipitation. An annual tank integrity testing program, if coupled with other containment or diversion structures, may be substituted for secondary containment for spent pulping liquor bulk storage tanks. 8. The permittee must install and maintain secondary containment for turpentine bulk storage tanks. 9. The permittee must install and maintain curbing, diking or other means of isolating soap and turpentine processing and loading areas from the wastewater treatment facilities. 10. The permittee must conduct wastewater monitoring to detect leaks and spills, to track the effectiveness of the BMPs, and to detect trends in spent pulping liquor Iosses. Such monitoring must be performed in accordance with Section E. Section B. BMP Plan Requirements 1. The permittee must prepare and maintain a BMW Plan. The BMP Plan must be based on a detailed engineering review as described in this section. The BMP Plan must specify the procedures and the practices required for the mill to meet the requirements of Section A, the construction the mill determines is necessary to meet those requirements including a schedule for such construction, and the monitoring program (including the statistically derived action levels) that will be used to meet the requirements of Section E. The BMP Plan also must specify the period of time that the mill determines the action levels established under Section D may be exceeded without triggering the responses specified in Section E. 2. The permittee must conduct a detailed engineering review of the pulping and chemical recovery operations -- including but not limited to process equipment, storage tanks, pipelines and pumping systems, loading and unloading facilities, and other appurtenant pulping and chemical recovery equipment items in spent pulping liquor, soap, and turpentine service --for the purpose of determining the magnitude and routing of potential leaks, spills, and intentional diversions of spent pulping liquors, soap, and turpentine during the following periods of operation: (i) Process start-ups and shut downs; (ii) Maintenance; (iii) Production grade changes; (iv) Storm or other weather events; (v) Power failures; and (vi) Normal operations. 3. As part of the engineering review, the permittee must determine whether existing spent pulping liquor containment facilities are of adequate capacity for collection and storage of anticipated intentional liquor diversions with sufficient contingency for collection and containment of spills. The engineering review must also consider: (i) The need for continuous, automatic monitoring systems to detect and control leaks and spills of spent pulping liquor, soap, and turpentine; (i.i) The need for process wastewater diversion facilities to protect end -of -pipe wastewater treatment facilities from adverse effects of spills and diversions of spent pulping liquors, soap, and turpentine; (iii) The potential for contamination of storm water from the immediate process areas; and (iv) The extent to which segregation and/or collection and treatment of contaminated storm water from the immediate process areas is appropriate. Page 9 of 13 Permit NC0003298 4. The permittee must amend its BMP Plan whenever there is a change in mill design, construction, operation, or, maintenance that materially affects the potential for leaks or spills of spent pulping liquor, turpentine, or soap,, from the immediate process areas. S. The permittee must complete a review and evaluation of the BMP Plan five years after the first BMP Plan is prepared and, except as provided in Section BA., once every five years thereafter. As a result of this review and evaluation, the permittee must amend the BMP Plan within three months of the review if, the mill determines that any new or modified management practices and engineered controls are necessary to reduce significantly the likelihood of spent pulping liquor; soap, and turpentine leaks, spills, or intentional diversions from the immediate process areas, including a schedule for implementation of such practices and controls. 6. The BMP Plan, and any amendments thereto, must be reviewed by the senior technical manager at the mill and approved and signed by the mill manager. Any person signing the BMP Plan or its amendments must certify to the Division tinder penalty of law that the BMP Plan (or its amendments) has been prepared in accordance with good engineering practices and in accordance with this regulation. The permittee is not required to obtain approval from the Division of the BMP Plan or any amendments thereto. Section C. BMP Recordkeeping Requirements I. The permittee must maintain on its premises a complete copy of the current BMP Plan and the records specified in Section C.2 and must make such BMP Plan and records available to the Division for review upon request. 2. The permittee must maintain the following records for three years from the date they are created: (i) Records tracking the repairs performed in accordance with the repair program described in Section A; (ii) Records of initial and refresher training conducted in accordance with Section A; (iii) Reports prepared in accordance with Section A; and (iv) Records of monitoring required by Sections A and E. Section D. Establishment of Wastewater Treatment System Influent Action Levels 1. The permittee must conduct a monitoring program per Section D.2, for the purpose of defining wastewater treatment system influent characteristics (or action levels), described in Section D.3, that will trigger requirements to initiate investigations on BMP effectiveness and to take corrective action. 2. The permittee must employ the following procedures in order to develop the action levels required by Section D: Monitoringparameters. The permittee must collect 24-hour composite samples and analyze the samples for a measure of organic content (e.g., Chemical Oxygen Demand (COD) or Total Organic Carbon (TOC)). Alternatively, the mill may use a measure related to spent pulping liquor lnsses measured continuously and averaged over 24 hours (e.g., specific conductivity or color). Monitoring locations. The permittee must conduct monitoring at the point influent enters the wastewater treatment system. For the purposes of this requirement, the permittee may select alternate monitoring point(s) in order to isolate possible sources of spent pulping liquor, soap, or turpentine from other possible sources of organic wastewaters that are tributary to the wastewater treatment facilities -(e.g., bleach plants, paper machines and secondary fiber operations). 3. The pertittee must maintain an influent action levels monitoring program using the procedures specified in Section D and must maintain initial action levels based on the results of that program. A wastewater treatment influent action level is a statistically determined pollutant loading determined by a statistical analysis of six months of daily measurements. The action levels must consist of a lower action level, which if exceeded will Page 10 of 13 Permit NCO003298 trigger the investigation requirements described in Section E, and an upper action level, which if exceeded will r trigger the corrective action requirements described in Section E. 4. The permittee must complete a second six-month monitoring program using the procedures specified in Section D and must establish revised action levels based on the results of that program based on Section D5 requirements. The initial action levels shall remain in effect until replaced by revised action levels. 5. Action levels developed under this Section must be revised using six months of monitoring data after any change in mill design, construction, operation, or maintenance that materially affects the potential for leaks or spills of spent pulping liquor, soap, or turpentine from the immediate process areas. Section E. BMP Monitoring, Corrective Action and Reporting Requirements 1. The permittee must conduct daily monitoring of the influent to the wastewater treatment system in accordance with the procedures described in Section D for the purpose of detecting leaks and spills, tracking the effectiveness of the BMPs, and detecting trends in spent pulping liquor losses. 2. Whenever monitoring results exceed the lower action level for the period of time specified in the BMP Plan, the permittee must conduct an investigation to determine the cause of such exceedance. Whenever monitoring results exceed the upper action level for the period of time specified in the BMP Plan, the permittee must complete corrective action to bring the wastewater treatment system influent mass loading below the lower action level as soon as practicable. 3. Although exceedances of the action levels will not constitute violations of an NPDES permit, failure to take the actions required by Section E.2 as soon as practicable will be a permit violation. 4. The permittee must report to the Division the results of the daily monitoring conducted pursuant to Section E. I. Such reports must include a summary of the monitoring results, the number and dates of exceedances of the applicable action levels, and brief descriptions of any corrective actions taken to respond to such exceedances. Submission of such reports shall be annually, by March 31" o£ the following year. Section F. BMP Definitions 1. Action Level: A daily pollutant loading that when exceeded triggers investigative or corrective action. Mills determine action levels by a statistical analysis of six months of daily measurements collected at the mill. For example, the lower action level may be the 75th percentile of the running seven-day averages (that value exceeded by 25 percent of the running seven-day averages) and the upper action level may be the 90th percentile of the running seven-day averages (that value exceeded by 10 percent of the running seven-day averages). 2. Division: North Carolina DENR, Division of Water Quality, 1617 Mail Service Center, Raleigh, North Carolina 27699--1617. 3. Equipment Items in Spent Pulping Liquor, Soap, and Turpentine Service: Any process vessel, storage tank, pumping system, evaporator, heat exchanger, recovery furnace or boiler, pipeline, valve, fitting, or other device that contains, processes, transports, or comes into contact with spent pulping liquor, soap, or turpentine. Sometimes referred to as "equipment items." 4. Immediate Process Area: The location at the mill where pulping, screening, knotting, pulp washing, pulping liquor concentration, pulping liquor processing, and chemical recovery facilities are located, generally the battery limits of the aforementioned processes. "Immediate process area" includes spent pulping liquor storage and spill control tanks located at the mill, whether or not they are located in the immediate process area. Page 11 of 13 Permit NCO003299 5. Intentional Diversion: The planned removal of spent pulping liquor, soap, or turpentine from equipment items in spent pulping liquor, soap, or turpentine service by the mill for any purpose including, but not limited to, maintenance, grade changes, or process shutdowns. 6. Mill: The owner or operator of a direct or indirect discharging pulp, paper, or paperboard manufacturing facility subject to this section. 7. Senior Technical Manager: The person designated by the mill manager to review the BMP Plan. The senior technical manager shall be the chief engineer at the mill, the manager of pulping and chemical recovery operations, or other such responsible person designated by the mill manager who has knowledge of and responsibility for pulping and chemical recovery operations. 8. Soap: The product of reaction between the alkali in kraft pulping liquor and fatty acid portions of the wood, which precipitate out when water is evaporated from the spent pulping liquor. 9. Spent Pulping Liquor: For kraft and soda mills "spent pulping liquor" means black liquor that is used, generated, stored, or processed at any point in the pulping and chemical recovery processes. 10. Turpentine: A mixture of terpenes, principally pinene, obtained by the steam distillation of pine gum recovered from the condensation of digester relief gases from the cooking of softwoods by the kraft pulping process. Sometimes referred to as sulfate turpentine. A. (9) EFFLUENT GUIDELINE SAMPLING PLAN SPECIAL CONDITION The bleach plant effluent sample shall be analyzed for 2,3,7,8-TCDD in accordance with EPA Method 1613. A single sample may be analyzed to determine compliance with the daily maximum effluent limitation. Alternatively, a sample volume may be collected to enable the sample to be split. (duplicate analysis). If the analysis of either split sample.is below the Minimum Level (ML), the quantity is considered to be zero for compliance evaluation. If both splits are positive, the results of two analyses shall be averaged to determine compliance. The Minimum Level for 2,3,7,8-TCDD by EPA Method 1613 is 10 pg/L. The bleach plants effluent sample shall be analyzed for the 12 chlorinated phenolic compounds in Part 1, A(2) in accordance with EPA Method 1653. A single sample may be analyzed to determine compliance with the daily maximum effluent limitation. Alternatively, a sample volume may be collected to enable the sample to be split (duplicate analysis). If the analysis of either split sample is below the Minimum Level (ML), the quantity is considered to be zero for compliance evaluation. If both splits are positive, the results of two analyses shall be averaged to determine compliance. The Minimum Levels for each of the 12 chlorinated compounds are the same as the Daily Maximum concentrations listed in Part I, A.(2.) and A. (3.). The final wastewater treatment plant effluent sample (Outfall 001) shall be analyzed .for AOX in accordance with EPA Method 1650, or subsequent test methods approved by the Division. The permittec may request future monitoring modifications to the Cluster Rule requirements, including; 1) use of ECF certification in lieu of monitoring for chloroform in the bleach plant effluent (Outfall 004 and Outfall 005) when this rule is promulgated by EPA; 2) demonstrating compliance using samples collected less frequently than every four hours; 3) using automated composite volatile samplers for chloroform sampling; and 4) using automated composite samplers for chlorophenolic and TCDD/DF sampling. Such future requests will be evaluated in accordance with 15A NCAC 2H.0114. The flow calculations for internal Outfalls 004, and 005 shall not be subject to accuracy requirements specified under Part H, Section D.3. This exclusion is similar to that provided for pump log flow calculations. Page 12 of 13 Permit NCO003298 Chemical data for Cluster- Rule parameters (all Outfall 004, and 005 parameters + AOX from Outfall 001) shall be submitted to the Division on a quarterly basis Qanuary- March, April- June, July- September, October - December). Quarterly submissions shall be due 60 days following the last day of each quarter (Due dates = May 31, August 31, November 30, February 28). Chemical data shall be submitted on Division -approved DMR fortes, with a separate form provided for each month. Page 13 of 13 DENR/ DWQ FACT SHEET FOR NPDES. PERMIT DEVELOPMENT NPDES No. NC0003298, International Paper Company (IP) Riegelwood Facility F aciliti Irifor atio>n A licant Facili , Name::. International Paper - Riegelwood Facility A° licant`Address: ;: tj 865 John L. Riegel Road, Riegelwood, NC 28456 Facili .. Address: 865 John L. Riegel Road, Riegelwood, NC 28456 "P6rmitted Flow..; 50 MGD 'e of Waste':: 99.8 % Industrial, 0.2% Domestic Facility/Permit Status:--'.;' " Major Indust • Renewal; First inclusion of the cluster rules Columbus Miscellaaeous'.; Receivmg;Stream ,r `i Cape Fear River Regional;' „ WiRO Stream Classification:; ;'' C-Sw ;:Quad° J26SW 303(dJ'LMisted? ` Yes- DO and biological Per mit;Writer~ t' Sergei Chernikov �Subbasin: 030617 18-63-a Date r'�;,1 ,. ��,; January 9, 2013 :IDrama`e'Area` mil 5,301 Siirhiner 7Q10'. cfs < ; 856 a Winter.7Q1.0!(6f§) ...` 01 Ave`ra "e Flow` cfs 5330 Prima y`SIC.Code ""` 2611 Pulp/Kraft Mill, 2621 Paper Mill SUMMARY The International Paper (IP) Company - Riegelwood Facility is located near Wilmington. iP takes the raw material (logs/chips) and produces paperboard (bleached product), and fluff pulp (bleached product). Facility operates three bleach plants, Bleach Plant 1 process softwood (pine primarily), Bleach Plant 3 process -hardwood, and Bleach Plant 2 switches between hardwood and softwood depending on the production needs. Facility operates one external outfall (Outfall 001),and two newly established internal outfalls (Outfall 004 and Outfall 005). The internal outfalls were established to implement Cluster Rules. The facility is required to monitor for dioxin in fish tissue. The ESS staff evaluated the latest report submitted by IP in 2010 and concluded that "over the past 16 years, 1996-2009, all dioxin concentrations have been below the state advisory criterion of 4 parts per trillion". Outfall 001 This outfall contains wastewater associated with the all industrial operations, landfill leachate, and sanitary sewer wastewater. Outfall 001 and the newly established Internal Outfall 004 (combines effluent from Bleach Plant 1 and Bleach Plant 2) and 005 (effluent from Bleach Plant 3) are subject to the Cluster Rules - the modifications expressed by 40 CFR 430, Subpart B (430.20) - Bleached Papergrade Kraft and Soda (promulgated April 15, 1998). In accordance with the Cluster Rules each Bleach Plant should be monitored for numerous parameters. However, due to the configuration of deep sewer lines the permittee was unable to access effluent from Bleach Plant I and Bleach Plant 2 separately. EPA has granted a request from the permittee to establish one sampling point for both plants. However, acid waste and alkaline waste will be sampled separately. Bleach Plant 3 has a separate sampling point. The current oxygen consuming waste limits (BOD5) are water quality limited. The dioxin limit (0.9 pg/L) is also a water quality based limit. These limits will remain in the permit. International Paper Riegelwood NC0003298 NPDES Renewal Page 1 In 1992, the facility has requested. to a variance from -the Environmental Management Commission to redefine the summer period. The Environmental Management Commission has granted a variance request, the summer for this facility is now defined as June 1 - October 31. International Paper has requested the continuation of the variance with this renewal, the request was granted. TOXICITY TESTING: Current Requirement: Chronic. P/ Fat 8.0%, January April, July, October. Proposed Requirement: Chronic P/F at 8.0%, January April, July, October. The facility has had a good toxicity monitoring record for the past 4.5 years, they passed all the tests. RPA: The Reasonable Potential Analysis (RPA) was conducted for Cr, Hg, Ni, and Zn (see attached). The results indicate that the limits for these parameters are not necessary. COMPLIANCE SUMMARY: The DMRs were reviewed for the period 12/01/2007 through .12/01/12. The facility had only one limit violation, BOD on 09/30/2010. MERCURY EVALUATION: The mercury evaluation was conducted in accordance with the Permitting Guidelines for Statewide Mercury TMDL. Year 2008 2009 2010 2011 2012 Annual average 3.9 6.2 3.2 2.3 2.1 concentration n L Maximum sampling 18.6 9.8 15.7 6.7 7.8 result n ' I; Allowable concentration for this facility is 144.6 ng/L. All Annual average mercury concentrations are below allowable and no single value exceeds TBEL of 47 ng/L. Based on the Permitting Guidelines for Statewide Mercury TMDL, the limit and monitoring for mercury is not required. INSTREAM MONITORING: IP is required to perform stream sampling for D.Q. and salinity with their current permit. Stream sampling is conducted 3/week during June - September and 1/week during the remainder of the year. As a participant in the lower Cape Fear Monitoring Coalition, the instream monitoring is not required. Should the membership in the Coalition be terminated, the facility must notify Division immediately and begin instream monitoring as specified in this permit. Due to the significant number of dischargers in that segment of Cape Fear River it is difficult to separate influence of IP discharge on water quality in the receiving stream. CHANGES IN THE 2007 PERMIT In 2007 there were a number of significant changes in the permit due to the application of the Cluster Rule requirements. The changes are described below: In accordance with the Cluster Rule (40 CFR 430 Subpart B) two new internal outfall have been established: Outfall 004 for combined effluent from bleach plants I and 2, and.Outfa1l 005 for effluent from Bleach Plant 3. Limits for Chloroform were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 004 and Outfall 005. Limits for AOX were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 001. International Paper Riegelwood NCO003298 NPDES Renewal Page 2 • Limits for Pentachlorophenol and Trichlorophenol were calculated in accordance with 40 CFR 430.100 and 40 CFR 430.20 and added to Outfall 001. • Special Condition A. (9.) was added to the permit in accordance with the provisions of the Cluster Rule (40 CFR 430,03), • Special condition A. (10.) was added to the permit in accordance with the provisions of the Cluster Rule (40 CFR 430). • In accordance with the Division's new Permitting Strategy for the Cape Fear River Basin, the Nutrient Controls Re -Opener condition was added to the permit (See A. (7.)). • Biocide special condition was added to the permit (See A. (6.)). • Special Condition A. (8.) ,Dioxin Monitoring was updated to reflect current DEH requirements. • Mercury limits were eliminated from the permit based on a statistical analysis of the effluent data. The monitoring frequency for Mercury was reduced to 2/Month. • The monitoring frequency for Chromium, Nickel, and Zinc were reduced to Quarterly based on a statistical analysis of the effluent data. • Outfall 002 was added to the permit to allow sand filter backwash discharge from the surface water treatment plant (WTP). The discharge also contains small amount of stormwater from the roof of the water treatment plant, and small leaks from the various seals in the WTP building • Mercury sample type was changed to Grab to be consistent with method EPA- 1631E requirements. • Summer period was changed to June 1 through October 31 to correct an error (this summer period was granted by North Carolina Division of Environmental Management as a variance in 1992). • Dioxin monitoring frequency in the effluent was changed to Annual and, dioxin monitoring of the sludge, wastewater treatment plant influent and landfill leachate was eliminated based on the long term monitoring without detection. PROPOSED SCHEDULE FOR PERMIT ISSUANCE: Draft Permit to Public Notice: January 29, 2013 (est.) Permit Scheduled to Issue: March 25, 2013 (est.) STATE CONTACT: If you have any questions on any of the above information or on the attached permit, please contact Sergei Chernikov at (919) 807-6393 or sergei.chernikov@ncdenr.gov. PROPOSED CHANGES: • Limits for Chloroform were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 004 and Outfall 005. • Limits for AOX were calculated in accordance with 40 CFR 430 Subpart B based on 3 years of production data and added to Outfall 001. • Limits for Pentachloro phenol and Trichlorophenol were calculated in accordance with 40 CFR 430.100 and 40 CFR 430.20 and added to Outfall 001. • Limits for TSS were calculated in accordance with 40 CFR 430.22 and added to Outfall 001. • Outfall 002 was eliminated from the permit due to the elimination of the discharge. • The influent monitoring requirements for BOD and TSS were eliminated (Outfall 001). • The classification of the receiving stream was updated to C-Swamp PNA-HQW based on the information from the Division of the Marine Fisheries. • Monitoring for Total Chromium, Total Mercury, Total Nickel and Total Zinc was removed from the permit based on the results of the reasonable Potential Analysis. • Monitoring for the internal outfalls parameters (except for flow) were reduced to Quarterly in accordance with the 40 CFR 430.02. International Paper Riegelwood NC0003298 NPDES Renewal Page 3 The Division is unable to grant the facility's request to eliminate monitoring for chloroform, chlorinated phenolics and dioxins in Outfalls 004 and 005, and AOX in Outfall 001. The , Cluster Rule 40 CFR 430.02 requires continuing monitoring of these parameters. ' CHANGES IN THE FINAL PERMIT: • The PNA classification was removed from the permit based on the legal advice. international Paper Riegelwood NC0003298 NPOES Renewal Page 4 International Paper Company - Riegelwood, Pulp and Paper Facility Bleach plant 1 and bleach plant 2 have a combined sewer system calculations are based on 355 days of operatrion per year Bleached Kraft Air Dried Tons (english) Average per year Average (tons/day) Average (pounds/day) Average (kg/day) Bleach Plants 2008 2009 2010 Bleach plant 1+ 2 Bleach plant 3 430,869 1 427,999 481,358 393,463 340,717 403,306 446,742 379,162 1,258.40 1,068.10 2,516,856.30 2,136,123.90 1,144,025.60 970,965.4 Total 824,332 1 768,716 1 884,664 1 825,904.00 1 2,326.51 4,652,980.3 2,114,991.01 Limits for chloroform for each bleach plant are calculated in accordance with Subpart B effluent guidelines (430.24) Bleach plant 9 + Bleach plant 2 Chloroform daily max = 6.92 glkkg * 1,144 kkg = 7.92 kglday =17.4 lb/day Chloroform monthly average = 4.14 glkkg * 1,144 kkg = 4.74 kglday =10.4 lb/day Bleach plant 3 Chloroform daily max = 6.92 9/kkg * 971 kkg = 6.72 kg/day =14.8 Iblday Chloroform monthly average = 4.14 glkkg * 971 kkg = 4.02 kg/day = 8.8 lb/day Effluent limits for external outfall are calculated in accordance with Subpart B effluent guidelines (430.24) AOX daily max = 0.961 kglkkg * 2,115 kkg = 2,011.4 kglday = 4,425 lb/day AOX monthly average = 0.623 kglkkg * 2,115 kkg=1,317.6 kglday = 2,899 lb/day Pentachlorophenol daily max = 0.0014 kglkkg * 2,115 kkg = 2.96 kg/day = 6.61 Iblday Trichlorophenol daily max = 0.0088 kglkkg * 2,115 kkg =18.6 kg/day = 40.9 lb/day TSS daily max = 22.15 kglkkg * 2,115 kkg = 46,847 kglday=103,063 Iblday TSS monthly average =11.9 kglkkg * 2,115 kkg = 25,168.5 kg/day = 55,371 lb/day As summaried 10/21/2005 3298-production data-2011.xls As summarized by Diane Hardison International paper REASONABLE POTENTIAL ANALYSIS NCO003298 Qw(&fGD)= 50.00 WWTPAVTPClass: IV 1Q10S (cfs)= 68&2$ 1WC @ IQIOS = 10.12!G 7QI0S(cfs)= 856.00 IWC ®7QIOS= 8.30% 7QIOW (cls)= 1101.60 IWC @ 7QIOW = 6.58% 30Q2(cfs)= NO 3OQ2 DATA IWC@ 30Q2= NIA Avg. Stream Flow, QA (cis) — 5330.00 IWC @ QA = 1.43;6 Receiving Stream: Cape Fear River Stream Class: C-SW Outfaw 001 Ow = 50 MGD CHRONIC TEST CONCENTRATION = 8.3%. PARAMETER STANDARDS S CRITERIA (2) REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE -A to (1) NC WQS / Applied 1/2FAV / a Z D n 4 Det. Max Fred Allowable Cw Chronic Standard Acute Cw Acute: 10,098.8 Chromium NC 50 FW(7QIOs) 1022 ug1L 12 10 25.8 _ 602 _'w- Chronic: 4 remove moiiltolia4 " No value > Allowable Cw s,.... Acute: NO WQS51 : T Mercury NC 12 FW(7QIOs) 0.5 nglL 117 92 30.7_- Chronic: 144.E rernave miingcrinQ " No value > Allowable Cw "' Acute_ 2,579.1 no Nickel NC 88 FW(7QIOs) 261 ug1L 12 lZ 43.7 _ _ _ _ _ _ - 1 Chronic: 11060-2::-- - _—_- No value > Allowable Cw==.--- Acute: 662.1M. Zinc (AL) NC 50 FW(7QIOs) 67 ugfL 12 12 296-4 _ _ Chronic: 6@.4 remove monWrrg - - = No value > Allowable Cw - - 320& RPA- 2011.xism, rpa Page 1 of 1 U712013 REASONABLE POTENTIAL ANALYSIS Date Data 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18 17 18 19 20 21 27 28 29 30 31 32 33 34 35 36 37 1 38 39 y 40 51 52 53 Chromium 8DI-012DL Results 2.5 Std Dev. 2.5 Mean 11 C.V. 10 n 10 5 Mult Factor 12 Max. Value 10 Max. Pred Cw 7 8 7 5 7.5000 0,4302 12 2,15 12.0 ug1L 25.8 uglL 1 2 3 4 5 8 7 8 9 10 1i 12 13 14 15 18 17 is 19 20 21 22 23 24 25 26 27 28 29 30 $1 32 33 34 3$ 38 37 38 39 40 41 42 43 44 45 45 47 48 49 5D 51 62 63 54 55 58 57 58 59 5o a1 62 63 64 65 66 67 88 89 70 Mercury Date Data 8DL■112DL Results 5.4 5.4 Sic! Dev. 9: cst 9.4 9.4 Mean �•„'' 18.5 18.5 C.V. 1.2 1.2 n •c= ..: �: �' i 8.4 8.4 : 4.1 4.1 Mult Factor 4.3 4.3 Max. Value : 9 9 Max. Pred Cw 10 18 10.8 10.8 1 1 �r1E a; 2.5 2.5 3.4 3.4 3.3 33 II't E;1riI;, 8.2 3.9 3.9 fln;ial re µjiis7i,:W =n 1.7 1.7 GiE'S 3.3 3.3 3 3 s ;1.1lki 1.8 1.6 2.3 2.3 €, tMa for 2.2 2.2 0.5 0.6 0.7 0.7 €j' 3i;t is 1.3 1.3 ..p k 3A 3.1 is 5 5 3.5 3.5 <, 2.54 2.54 I 2.52 2.52 3.9 2.5 3.9 2.5 5 5 2.5 2.5 2.5 2.5 2.5 2.5 6.0 3.2 3.2 d,' 5 t,4 >:; 5 5 3.8 3.6 41p=,`ylE,iw; 2.5 2.5 U01 �a,=, i1> 3.6 3A 2.5 2.5 2.5 2.5 2.5 2.5 itr ,y: 4; 2.5 2.5 2.5 2.5 2.5 2.5 l-t : 2.5 2.5 t tu- �:-'I- -u 15.7 15.7 AI . 4-., 2.5 2.5 *�'_i:' . T - r 4.79 4.79 5.7 5.7 1.35 1.35 2.5 2.5 3.3985 1,0890 117 1.65 18.6 ng/L 30.7 ng/L 4- 3298- RPA• 2011.Asm, data 117=13 REASONABLE POTENTIAL ANALYSIS 71;,;' 72 73,,'p �. 741 to 75SE,,11 141 4 764 1i 77 l,j78 4 79 80 IL 82 t I 8a'I 84'�1, til�Ij�j I' 85 8667 '88 89, ISE Iota; e 90r 91 :t rr,:1 92 jj`clibil 93 '.. 11 1 + ir), 94 �EiPPi 95 98 y li if lit' 97 98 -: • Ir' i� 3i 99 1011ilit 102104 105 1071.,: 108 109'33'�£Iel�' 110 it'4 I�. s"i'si 111 'jl` IA: i'. 112�ii�!,V' 113 !: iE € 1144'" 117 119 „i'l311 120 121 122 123 :jw 124 125 126 t;, !ilr Y A: 127gt"3=' IE'°il 3t4I,;Il.t 129 130 131 132C� r 133 �1 134 135.'i'?t { 136j ,38j';'=lA k 139 y :; 140.- 141 142t ,'s 143, jqi `i6f,yil; 144E -I_ I i:r"; 2A7 3.15 2.5 4.12 6.7 0.5 3.9 2.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2.29 1.14 0.5 0.5 2.52 0.5 0.5 1.08 1.88 0.5 0,5 0.5 0.5 0.5 0.5 0.5 7.96 6.15 0.5 0.5 6.8 5 0.5 5-04 0.5 2.5 3,17 2.47 3.15 2.5 4.12 6.7 0.25 3.9 2.5 0.25 0.25 0.25 0.25 0.25 0.26 0.25 0.25 0.25 0.25 0.25 0.25 2.29 1,14 0.25 0.25 2.52 0.25 0.25 1.08 1.88 0.25 0.25 0.25 0.25 0.25 0.25 0.25 7.96 6.15 0.5 0, 5 6.8 5 0.5 5.04 0.25 2.5 3.17 5- 3298- RPA- 2011.xtsm, data 11712013 REASONABLE POTENTIAL ANALYSIS Nickel BDL=1120L Results 16 Std Dev. 14 Mean 24 C.V. 25 n 26 26 Mull Factor = 16 Max, Value 27 Max, Pred Cw 24 16 14 16 20.3333 0.2622 12 1.82 27.0 uglL 43.7 uglL 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 64 65 66 67 68 Be 70 361 65' A ta I Zinc (AL) BDLOI12DL ReaultS 43 Std Dev. 41 Mean 56 C.V. 34 n 31 103 Mull Factor 123 Max. Value 44 Max, Pred Cw 46 55 38 55 56.0000 0.5008 12 2.41 123.0 ug1L 296.4 ug1L -7- 3298- RPA- 2011,x1sm, data 1/7/2013 INTERNATIONAL PAPER Riegelwood, NC Production Stats - Paper Machines 2008-2010 Bleached Board = Paper Machine 15 Bristols = Paper Machine 18 Pulp = Pulp Dryer 2008 2009 2010 Units Finished Tons Manufactured - Total Al Tons 7,,96,568;' 71C,06 .•" 829,585 Bleached Board Al Tons 209,724 190,285 223,684 Bristols Al Tons 180,894 141,794 202,721 Pulp Al Tons 405,890 382,731 403,180 Production Stats - Pulp (2008-2010) 2008 2009 2010 Tons Manufactured - Total Units F 824,332 768,716 884,664 Unbleached Pine ADT 399,798 426,301 477,456 kkvUnbleached Hardwood - Batch ADT 31,071 1,698 3,902 n leached ardwood-Kamyr ADT 393,463 340,717 403,306 Tons Manufactured - Total =,772,541 -.. 703J50 .812,563 Bleached Pine ADT 372,044 393,803 433,524 Bleached Hardwood ADT ' 400,497 309,347 379,039 S:\Groups\Environmental\Wastewater\NPDES Permit Info\2011 Application\2010-2011 Prod Stats.xlsx INTERNATIONAL(& PAPER Riegelwood, NC Production Stats - Paper Machines (2008-2010) Bleached Board = Paper Machine 15 Bristols = Paper Machine 18 Pulp = Pulp Dryer 2008 2009 2010 Units Finished Tons Manufactured - Total Al Tons 796,508 _Y714,810 7829;585 Bleached Board Al Tons 209,724 190,285 223,684 Bristols Al Tons 180,894 141,794 202,721 Pulp Al Tons 405,890 382,731 403,180 Production Stats - Pulp (2008-2010) 2008 2009 2010 Tons Manufactured - Total Units 824,332 768,715 884664 Unbleached Pine ADT 399,798 426,301 477,456 Unbleached Hardwood - Batch ADT 31,071 1,698 3,902 Unbleached Hardwood-Kamyr ADT 393,463 340,717 403,306 Tons Manufactured - Total 772,541. ; 703,15U ;: 812,563 Bleached Pine ADT 372,044 393,803 433,524 Bleached Hardwood ADT 400,497 309,347 379,039 S:\Groups\Environmental\Wastewater\NPDES Permit Info\2011 Application\2010-2011 Prod Stats.xlsx UNITED STATES ENVIRONMENTAL PROTECTION AGENCY �z REGION 4 ATLANTA FEDERAL CENTER 61 FORSYTH STREET yf�� FROS�C, ATLANTA, GEORGIA 30303-8960 M INR 4 2013 Mr. Jeff Poupart Supervisor, NPDES Unit Division of Water Quality North Carolina Department of Environment and Natural Resources 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: Draft Permit Review International Paper Company - Riegelwood Mill National Pollutant Discharge Elimination System Permit No. NC0003298 Dear Mr. Poupart: This letter is to notify you that the U.S. Environmental Protection Agency has completed its review of the draft National Pollutant Discharge Elimination System (NPDES) permit referenced above, which is an existing source discharger. The draft permit and application materials were transmitted by your office to the EPA on February 4, 2013. Pursuant to Section IV.B.7 of the North CarolinatEPA NPDES Program Memorandum of Agreement and 40 Code of Federal Regulations (C.F.R.) § 123.44(a) and (b), this letter will serve as the EPA's comments pertaining to the issuance of this permit. The EPA commends North Carolina for implementing our September 6, 2012, recommendations to address statewide mercury impairment and North Carolina's approved mercury Total Maximum Daily Load. The permit's fact sheet includes the results of a mercury evaluation conducted by North Carolina which shows that the allowable concentration for this facility is 144.6 nanograms per liter (ng/l) and that all the annual average mercury concentrations for 2008-2012 are below a technology based effluent limit of 47 ng/l. However, as we noted in that recommendation letter, North Carolina should still assess reasonable potential to cause or contribute to the state's existing total mercury water column standard of 12 ng/l. Your draft fact sheet showed that the facility's previous mercury monitoring only requirements for Outfall 001 were deleted based on results of the statistical analysis of the data. Your statistical analysis concluded that based on 117 samples, the maximum predicted effluent concentration of 30.7 ng/1 for total mercury has no reasonable potential to cause an exceedance of this standard. The background concentration was assumed to be zero, and the calculated instream waste stream at 7Q 10 conditions is 8.3 percent. As stated in our September 6, 2012, letter to you, because North Carolina's Clean Water Act Section 303(d) list identifies every water body in the State as impaired for mercury, the EPA Region 4 believes that it is inappropriate to assume background is zero for this pollutant. If there are no ' background data in the receiving water body for total mercury, we recommend that North Carolina use the authority under 40 C.F.R. § 122.21(e) and corresponding state NPDES regulations to request the permittee collect site specific upstream receiving water total mercury concentration data during the permit term and include this data as supplemental information to the subsequent permit application. Intamet Address (URL) • http://www.opa,gov R&gyvted/R"VdabW .PAnted with Vegetable 04 Sued tnks on Ft"ded Paper (Mk*num 3M Postearmmet) Alternatively, North Carolina could utilize instream mercury concentrations that have been documented in nearby waters. If you are unable to obtain site -specific instream mercury data as described above, the EPA recommends that you also include a 12 ng/l weekly average limit in the final permit (ref: 40 C.F.R_ I 22.44(d)(1)(i)). If you have any questions, please contact Ms. Karrie-Jo Shell of my staff at (404) 562-9308. Sincerel , Christopher B. Th as, Chief Pollution Control and Implementation Branch Water Protection Division cc: Mr. Floyd Whitmire Mill Manager International Paper Company - Riegelwood Mill INTERNATIONAL PAPER February 21, 2013 RIEGELWOOD MILL JOHN L. RIEGEL ROAD RIEGELWOOD, NC 28456 Certified Mail: 7011 2000 0001 63d0.�4-40 Mr. Sergei Chernikov, Ph.D. %� M Fnvirnnrrlental F,n�irlPPr TI �� � Complex NPDES Permitting Unit Division of Water Quality 1617 Mail Service Center, Raleigh, NC 27699-1617 Subject: Comments on Draft NPDES Permit NCO003298 International Paper Company - Riegelwood Mill, Columbus County Dear Mr. Chernikov: We have only one comment on the draft permit to offer at this time. As I believe you and my staff have already discussed, the permit cover letter, the Supplement to the Permit Cover Sheet, and the Fact Sheet indicate that the classification of the Cape Fear River at the point of discharge is Class C-Swamp PNA-HQW. However, according to the officially adopted classifications of the Cape Fear River by the Environmental Management Commission referenced in 15A NCAC 0213.0311, this portion of the Cape Fear River is classified as Class C-Swamp. If you have any questions or would like to discuss anything related to the draft permit, please do not hesitate to call Ed Kreul at (910) 362-4883. Sincerely, Floyd .Whitmire Mill Manager — Riegelwood Mill cc: Edward Kreul Emily Henderson AFFIDAVIT OF PUBLICATION NORTH�CAROLI NA Cumberland County � r Pu6lK NWi<c North Carolina knvinmmcnlnl Mutx*cinrta Cutimi.xlim1NP171i't l4,it 1617 hlail lkervlce Cenler Ralcigh, NC 27647 c 1617 Naliee ad Intent h, I— n NPI i8 1, MIewaler Permit The N�th Carolina Eevitonmenial Man- n�g%cmcl CZ,mmusi,n rrnr—. k, k sue a NIZZA7 wsmew:aer dtachargc p, m4 to the l+crxe,n(a) litkd hllow. Wtitten cmm- mt. n:batdinp, the ppro�re,,1 I+�rmit will be �rrptxsl tnttl 30 days tfter IIu puNixfi date of Ihix notice: The Direct- of the NS: Divixim f Water Qualily (DW9) may lu,ld a puhlie hra.ing xlmuN them l+e n xignifi- cant doggm, tf puhlir inks-sl. 11eose n,yl cnmmcnlr an&mn lnfnnmtlea regt to to VW(2 at the. A— nddtxac Intmemed per- b. may vigil the DNVQ to 512 N. SAix- butw z L, Raleigh. NC k, mirw infixnta- fiim nn rma file. Additional inf dcm NI'DU9 pcimil.x and shin wxicc ,noy be fnrntd im t,ur wcbaiw htpll nU.ncdrnr. n&CFJxglxurl� InpdvdLakndu. r by c rag ,(919) flit 7.6, 911. fntunati,mal Pnper C' my teyucakd- runeval ,f pprram, "I NO fix Riegelwn„d Mill in Cnlum- Aux (.'gun ly Ihia !acuity di,x-hmSe is Leal- ed industna] warkwat ,r In Cape fear Riv- Cupe 1 c- River liastn Before the undersigned, a Notary Public of said County and state, duly commissioned and authorized to administer oaths, affirmations, etc., personally appeared. CINDY L. OROZCO Who, being duly sworn or affirmed, according to law, doth depose and say that he/she is LEGAL SECRETARY of THE FAYETTEVILLE PUBLISHING COMPANY, a corporation organized and doing business under the Laws of the State of North Carolina, and publishing a newspaper known as the FAYETTEVILLE OBSERVER, in the City of Fayetteville, County and State aforesaid, and that as such he/she makes this affidavit; that he/she is familiar with the books, files and business of said Corporation and by reference to the files of said publication the attached advertisement of CL Legal Line NOTICE OF INTENT TO ISSUE A NPDES WASTEWATER PERMIT -INTERNATIONAL PAPER CO. of NC DIVISION OF WATER QUALITY was inserted in the aforesaid newspaper in space, and on dates as follows: 2/4/2013 and at the time of such publication The Fayetteville Observer was a newspaper meeting all the requirements and qualifications prescribed by Sec. No. 1-597 G.S. of N.C. The above is correctly copied from the books and files of the aforesaid corporation and publication. N LEGAL SECRETARY Title Cumberland County, North Carolina Sworn or affirmed to, and subscribed before me, this 5 day of February, A.D., 2013. In Testimony Whereof, I have hereunto set my hand and affixed my official seal, the day and year aforesaid. H. Walters, Notary Public IMy commission expires 5th day of December, 2015. MAIL TO: NC DIVISION OF WATER QUALITY 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-00001617 0003902238 To: NPDES Permitting Unit Surface Water Protection Section Attention: Sergei Chernikov Date: September 27, 2011 NPDES STAFF REPORT AND RECOMMENDATION County: Columbus Permit No. NCO003298 PART I - GENERAL INFORMATION: Facility: International Paper Riegelwood Mill 865 John L. Riegel Road Riegelwood, NC 28456 Mailing: Edward J. Kreul, Manager EHS&S See address above 1. Date of Investigation: Inspection date September 22, 2011 2. Report Prepared by: Linda Willis Facility Contact: Edward Kruel 910-362-4883 (o), 910-612-2504 (c) Wallace Coverdale B/U operator 910-362-4590 Kim Fail 910-362-4753 (o), 910-512-0608 (c) Pat Soles WW3 4. Directions to Site: From WiRO, travel west on Hwy 74/76 approximately 35 miles to Riegelwood. Turn right on Hwy 87, travel approximately 5 miles. Turn right at intersection of Hwy 87 and John L. Riegel Road to plant entrance. Discharge Point: The facility has one discharge point (34021' 10"N and 78012' 10"W) 6. Receiving stream or affected surface waters: Cape Fear River a. Classification: Class C Sw **PNAIHQW** Impaired for DO and Biological b. River Basin and Subbasin No.: 03-06-17 AU # 18-63-(a) Segment length: 3.8 miles c. Describe receiving stream features and pertinent downstream uses: -Secondary recreation. No rating for aquatic life. There are two ambient monitoring stations in this segment of the river. According to CFR Basinwide WQP October 2005, chlorophyll a is noted . as a stressor with 33.3 % of the samples exceeding standard. There are 41 permitted wastewater discharges in this subbasin, and seven registered swine operations. Impairments include low dissolved oxygen, turbidity and low pH. Since the TMDL model suggests wastewater inputs to the Cape Fear River contribute very little to the low DO condition overall, it might be instructive to consider what impacts to dissolved oxygen many large wastewater inputs in smaller segments impose, PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS: 1. 0 3. 4. 5. 6. 7. 8. 9. a. Volume of wastewater to be permitted: 50 MGD b. What is the current permitted flow limit? 50 MGD C. Actual treatment capacity of the current facility? Not specified. d. Date(s) and construction activities allowed by previous Authorizations to Construct issued in the previous two years: NIA Please provide a description of existing or substantially constructed wastewater treatment facilities: This facility is composed of dual mechanical bar screens, dual primary clarifiers, earthen sludge ponds and three sludge screw presses, a series of three aeration lagoons with a total of 87x75HP aerators and 9x50HP aerators (WiRO requested verification of number and sizes of aerators during site visit) with one settling pond, nutrient and defoamer addition facilities, oxygen injection facilities, flow measurement and recording equipment. Please provide a description of proposed wastewater treatment facilities: N/A Possible toxic impacts to surface waters: carcinogens, PCBs, pesticides, Pretreatment Program (POTWs only): N/A metals, dioxin, Beta emitters, various Residuals handling and utilization/disposal scheme: NIA Compliance History: quarterly monitoring violations exist Treatment plant classification: WW4 SIC Code(s): 2611, 2621, previous staff reports indicate 2631 as well. PART III - EVALUATION AND RECOMMENDATIONS: The permittee requests relief from daily influent BOD and TSS monitoring and states the percent reduction limits do not apply to their facility. W1RO is not in support of the removal of the influent monitoring for either parameter unless the permitting unit determines that the regulation requiring such has been misapplied. The permittee requested that the monitoring associated with the Cluster Rule for Chloroform, chlorinated phenolics and dioxins in the internal outfalls as well as adsorbable organic halides (AOX) in outfall 001, be removed from the permit. WiRO has no objections to this request should the Rule allow relief. Any of the parameters associated with the Cluster Rule that have water quality based limits, and are expected to be present, should remain in the permit. The permittee requests that the outfall 002 be removed from the permit since the outfall has been eliminated. WiRO concurs that this outfall is no longer in existence and that the discharge has been removed permanently. The discharge has been rerouted directly to IP's intake pump station for reuse in the water treatment plant. WiRO recommends this outfall be removed from the permit. The permittee has provided their written rationale for continuation of the summer period variance. WiRO would like the NPDES Permitting Unit to take into consideration the recent and historically unusual algal blooms that are taking place in the Cape Fear River when making their decision for this request since these algal blooms have an impact on the DO in the river. They are becoming more prevalent and are impacting longer distances in the river. Also, IP does have the ability to add more aerators to their wastewater treatment system. There are only 5 aerators in their north lagoon (the last lagoon prior to discharge to the river). Please be sure to correct the classification of the receiving stream to reflect PNA/HQW. WiRO supports the reissuance of the NPDES Permit in accordance with the Cape Fear River Basinwidc Plan, provided the concerns outlined herein are addressed and no adverse public comments are received on the draft permit. ignature of Report Preparer ter uality Regional upervisor Enclosure Date 0 kq_ Date cc: DWQ WiRO NPDES Permit File NC0003298 Columbus County (w/att) DWQ Central Files (wlatt) - �-'-- � — � - � - �-'--•�-.- - -- , --- � ..1 l � T r� Nook r �- o.-r ' � • �t f� •� `l Yynrf.nw y ra --- Sit, T1i".,I leaf o •+ 7y - _=.fir- ! � �\ \ , F� ,� \_I- _f r� , i Y� _ � ;•/Path f' Is io Is and slan �.-'�?�IF/ +1 L Cape dear River j , J� don Crnl, Land,n)r lea R (� r} ss I Mielul COO dtrnnfwcY - / ;� pia rlrxrrg Cape Fear River 5r - „ f '-ii4,` ' I �� ; � /.' f _ _ `•I, , { _ JET \ \ �4 41 .. .'tom 1 j M1 � • - `�_r � 1 -rl I I i C't 1 � � { This map was produced for illustrative purposes as a general guide to assist the public. Informational data used for this map were collected from federal, state, county, and private organizations. While every effort Is made to keep this map accurate and up to -date, it Is not r';` Intended to replace any official source. Under no circumstances shall the L (' ` �`• '�+ ` - `' State of North Carollne be Ilable for any actions taken or omissions made from reliance on any Information contained herein from whatever source nor J� pid4�^ "� '� It � 70w�r �, 1� � ' shall the State be liable for any other consequences from any such reliance. i I �a f 1 �•' lk f ��- Background Imagery are U.S. Geological Fishery Nursery Areas FisheryNurse Areas Survay 1: 1 00.000-scale planimetrk: maps. ® Primary Nursery Permanent Secondary Map Datum: NADa3 Special Secondary Map Proje0on: NC Stata Plane Map Data: July20013 MARINE ® Military Danger 1000 0 1000 2000 Yards HSHUM Zones and Restricted Areas locator map 0.7 0 0.7 1.4 Mlles = inland w6ters(WRCJurisdiction) Map 24 INTERNATIONALQ PAPER RIEGELWOOD MILL 865 JOHN L. RIEGEL ROAD RIEGELWOOD, NC 28456 PHONE 910-362-4900 May 31, 2011 Ms. Dina Sprinkle NC DENR / DWQ Point Source Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Re: NPDES Permit NCO003298 Reissuance Summer Season Variance Justification In the transmittal letter of International Paper's (IP's) NPDES permit issued in 2007, the Division of Water Quality (DWQ) asked that IP provide justification during its next permit renewal cycle for continuance of the 1992 variance allowing a summer period of June through October rather than April through October. I am writing in response to provide the requested support for the variance and ask that it be continued. Below you will find a summary of the basis for the 1992 variance and more recent information supporting the rationale upon which the variance was granted. Background EPA issued NPDES Permit NCO003298 to Federal Paper Board in 1973 with a compliance schedule to meet limits of 5,000 lb/day BOD5 in summer (defined as June through October) and 10,000 lb/day in winter (November through May). All permits issued after this permit were challenged by Federal Paper, effectively staying these limits or negotiating Special Orders by Consent. In 1991, Federal Paper completed a study evaluating different treatment and disposal alternatives. The study also included water quality monitoring and modeling as part of a Use Attainability Analysis. The study recommended the limits included in the original 1973 NPDES permit be maintained. In 1992, Federal Paper submitted a variance request from the State's definition of summer and winter contained in 15A NCAC 02B.0404(c); the variance was approved by the Environmental Management Commission (EMC) and incorporated within Federal Paper's NPDES permit in 1993. NPDES Permit NC0003298 Reissuance Summer Season Variance Justification The rationale supporting continuance of this winter season variance centers on these key points: Lower Cape Fear River Dissolved Oxygen (DO) - North Carolina's ongoing evaluation of impacts from point and nonpoint sources and natural background conditions indicates minimal effect from point sources. Historically, DO concentrations in the Lower Cape Fear in April and May have been consistently above current water quali ty standards. Treatment - IP's wastewater treatment system is and has been among the best in the industry for BOD removal efficiency. Any additional BOD removal would be minimal and come only through major changes to the treatment system. Variance - The granted variance is not a variance from water quality standards subject to EPA review and thus has no specific recurrence. Further information on each of these points is provided below. Dissolved Oxygen Issues in Cape Fear River DWQ currently considers the Lower Cape Fear River as impaired for dissolved oxygen. DWQ has been working with the Lower Cape Fear River Program (I P is a member of the Program) to evaluate water quality issues in the lower river. DWQ hired Dr. Jim Bowen to develop a water quality model of the river to identify pollutant reduction loads to achieve water quality standards. Dr. Bowen's report indicates that DO is lower than the standard approximately 32 percent of the time, and removing point sources would only reduce this frequency to 27 percent. The report also concluded that removing 100 percent of the point source loads would result in an approximate increase in DO of 0.3 mg/L in times of lower DO concentrations. The removal of all the WWTPs changed the median DO concentration by approximately 0.1 mg/L. Exhibit 1 (from Dr. Bowen's report) illustrates these conclusions. ]'age 2 of 5 N PDES Permit NCO003298 Reissuance Summer Season Variance justification 'EXHIBIT 1 Percentile Plot of Model Predicted Dissolved Oxygen Concentrations During the Summer 2004 for the Base Case and Three Wastewater Treatment Plant Load Reduction Scenarios. The y-axis indicates the fraction of values below the corresponding DO concentration (mgfL) indicated on the x-axis. Source: Bowen et al., 1 0.8 0.6 8A 0.2 0 April through October Simulated Dissolved OxyM Concentrations fw the Impaired Area, Loner Cape Fear River Estuary .,._. Base Case................ i................... a................... 4....,...._,..,.._..r,..,,.,,_,...,r. All WWTPs off Wdrn. WWTPs off �` fP WWTP oiI ..,.....,.r...... .....,r....... p....,,..r...........,,............ ...........,.. _.................F...................}....._ .. _.. ............. ......... r........... ...................................... ............... ...�..�_�....... ................ .................... ................ ...5................... 5................... .................... ...i,......_................ ..,.. i.............. ................. .................... L ......r...........................O.a...,....x.u....Y.r...r_...rY.r.....r..r..a...._i_r...r.n..r.....r.Y......... _.n...............n_....... .r......._,..,.� ...................6. ............., ..,...,.........., .o..............,..,_d. ,.............,,., .,,.....,.,...... i 3 3.9 4 4.5 S 6.5 .6 6.5 7 2009 Dissolved Oxygen (mg/L) Dr. Bowen's report, based on very detailed hydrodynamic and water duality modeling, draws conclusions very similar to those of the less complex modeling used to support Federal Paper Board's Use Attainability Analysis and variance request in the early 1990s. Based on Dr. Bowen's work, DWQ has determined that an alternative water quality standard may be appropriate for the Lower Cape Fear River and is evaluating options. Until this work is complete, IP should continue to maintain its variance from the definition of summer. Three stations monitored by the LCFRP were evaluated for actual DO performance in the months of April and May. Box plots along the Cape Fear River compiled by DWQ in its 2009 Cape Fear River Basin Assessment Report indicate the dissolved oxygen sag occurs near Navassa and Horseshoe Bend at Wilmington. Based on this finding, LCFRP data from the following stations downstream of IP were chosen for review: • B9030000c -Cape Fear River Indian Creek Phoenix • B9050025c - Cape Fear River Railroad Bridge Navassa • B9050100c -Cape Fear River Horseshoe Bend Wilmington Page 3 of 5 NPDES Permit NC0003298 Reissuance Summer Season Variance justification The April and May data for each station were evaluated for 1996-2010. Exhibit 2 below summarizes the data. EXHIBIT 2 Summary of April and May DO Data Collected (1996-2010) Number of Number of Samples < Samples < Minimum Standard Standard DO Station DO Standard Observed (2007- Present) 0 (1996 -Present) B9030000c 4.0 4.3 0 (5/29/2007) B9050025c 5.0 4.8 1 1 (5/29/2007) B9050100c 5.0 5.1 0 0 Over the 15 year period reviewed, one sampling date from two stations had DO less than 5 mg/L and no DO values were Iess than 4 mg/L. It should also be noted that the station furthest upstream (B9030000c) is classified as C Sw. There were no observations below the DO standard of 4.0 at that sampling location. Based on in -stream data that indicate that DO values are generally not below the standard in April and May and that DWQ is still evaluating DO issues in the Lower Cape Fear River, IP should continue to maintain its variance from the definition of summer until further research is completed. At that time, the variance can be re-evaluated if the site -specific data and resulting programs to protect the Lower Cape Fear River warrant it. Treatment System IP's treatment system consists of primary clarification followed by aerated stabilization basins (ASBs). The system is operated efficiently but its temperature is significantly affected by weather, due to the long residence time needed to achieve high removal efficiency. IP has complied with its monthly average effluent BOD limits, but if summer limits had been imposed in April and May, the limit would have been exceeded in May 2008, as well as four other occasions in April/May from 2003-2007. In 1991, Federal Paperboard submitted a report to DWQ in which it evaluated several treatment alternatives to meet lower BOD limits as well as effluent discharge alternatives. That analysis showed that this system performed extremely well when compared to other systems at pulp and paper facilities throughout the world. Activated sludge treatment was evaluated and was not projected to provide better treatment for summertime conditions. This analysis indicated that activated sludge may improve treatment in April and May but the high cost of conversion was determined to be unwarranted by the minimal potential water quality benefit. Page 4 of 5 NPDES Permit NCO003298 Reissuance Summer Season Variance Justification Variance The variance is not a variance from water quality standards but from the State's definition of "summer and winter". In November 1993, EPA submitted a letter to the Division of Environmental Management Director on the state's triennial review in which they established priority areas to review. in that letter, EPA acknowledged two actions taken by the EMC that had been included in the state's triennial review package. One of those actions was the variance for the definition of summer and winter for Federal Paperboard. EPA's letter acknowledged that the variance was a variance to permitting requirements set forth in DWQ's rules and not a variance to the state's water quality standards. Therefore, EPA did not consider the variance to be part of the state's triennial revisions. Summary The most important considerations are that the Lower Cape Fear [fiver TMDL for DO is still in development and work to date shows very limited impact from point source discharges, April and May DO concentrations are consistently higher than the DO standards and the existing variance is not a variance to water quality standards. Therefore, we strongly believe the variance from the definition of summer in IP's NPDES permit is well conceived, causes no detriment and we request that the variance continue. If you have any questions or would like to discuss this or any related matter, please don't hesitate to call Kim Fail at (910) 362-4753 or me directly at (910) 362-4883. Yours truly, Edward J. Kr Manager — Environment, Health, Safety and Sustainability cc: Kim Fail, P.E., International Paper Ruth C. Rouse, CH2M Hill Page 5 of 5 INTERNATIONALO PAPER May 31, 2011 Ms. Dina Sprinkle NC DENR Division of Water Quality — Point Source Branch North Carolina Department of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Dear Ms. Sprinkle: RIEGELWOOD MILL 865 JOHN L. RIEGEL ROAD RIEGELWOOD, NC 28456 PHONE 910-362-4900 1�0 .�T JUN 2 2011 DENR-WATER QUALITY POINT SOURCE MANCH International Paper (IP) operates a wastewater treatment facility at its Riegelwood, North Carolina mill under NPDES Permit NC0003298. As part of this permit, we are required to submit a permit renewal application 180 days prior to the permit expiration date of November 30, 2011. (i.e., by June 3, 2011). This submittal constitutes our formal permit renewal application and consists of the following parts: • Attachment A: Application Forms 1 and 2C • Attachment B: Figures • Attachment C: Sludge Management Plan Narrative As part of the renewal process, International Paper also requests that several permit conditions be revised as follows: Please remove influent daily monitoring requirements for biological oxygen demand (BOD) and total suspended solids (TSS), as shown in Section A.1 of the permit. We do not have influent or percent reduction limits for either constituent, and we are not aware of any state or federal requirement that requires monitoring of these parameters in the influent. • It is our understanding that the provisions of bleach plant and effluent monitoring for Cluster Rule compliance were only required for one five-year permit term, per 40 CFR 430.02(b)(1). The five-year term for our NPDES permit will end in March 2012, and we ? } �, , iti�' �•l jl./ ;Z. �" cL� i � J I i� j 1n,1J, � �,ll kv ��. 1' ��.R,+, S:/Groups/EnviranmentallWastewater/NPDES Permit Info/NPDES Permit Renewal Cover tetterOS3111.do) J � request that the monitoring requirements for the following constituents be eliminated after this date: o Chloroform, chlorinated phenolics and dioxins in Outfalla 004 and 005 (Bleach Plants 1, 2, and 3); and o Adsorbable organic halides (AOX) in Outfall 001 (effluent). • We request that Outfall 002, which has been eliminated, be removed from our permit. As requested in the NC DENR cover letter for the March and October 2007 NPDES permits, IP- Riegelwood is also submitting its rationale for continuing the existing summer period variance under separate cover. We look forward to working with you during this permit renewal process. Should you have any questions on this submittal, please contact me at 910/362-4883, Sincerely, Edward J.ul EHS&5 anager cc: Ruth C. Rouse, CH2M Hill Kim Fail, P.E., International Paper S:/Groups/Environmental/Wastewater/NPOES Permit Info/NPOES Permit Renewal Cover Letter 053111. doc INTERNATIOfdAL® PAPER Riegelwood, NC Production 5tats - Paper Machines (April 2M 0 - March 2011) Bleached Board = Paper Machine 15 Bristols = Paper Machine 18 Pulp = Pulp Dryer 2010 Units ABE Finished Tons Manufactured - Total Al Tons 69,522 Bleached Board Al Tons 20,430 Bristols Al Tons 16,%4 Pulp Al Tans 32,148 2010 2010 2010 2010 2010 2010 2010 2010 2011 2011 2011 12-Month May L Lft Aug ft Qq N- Dec L Feb Mar Total 37,100 74,430 77,608 73,326 73,629 71,164 73,674 74,335 72,048 64,413 72,680 833,929 12,606 18,911 19,8Z7 19,293 18,"5 19,698 18,837 19-W 17,787 15,874 19,124 220,811 12,052 18,609 18,886 18,798 16,2% 16,894 17,679 17,154 17,593 16,182 17,845 204,894 12,442 36,910 38,895 35,246 38515 34,572 37,159 37,601 36,668 32,357 35,711 408,224 Production 5tats - Pulp (Atari] 2010 - March 20111 2010 2010 2010 W10 2010 2010 2010 2010 2010 2011 2011 2011 12-Month units APT May L L Au¢ s� IQq Nov Dec jan Feb mar Total Tons Manufactured - Total 74,065 41,283 78,531 83,182 77,500 78,100 77,163 78,3M 79,613 77,156 69,276 76,951 891,150 Unbleached Pine ADT 38,831 18,679 42,292 44,174 41,924 42,749 41,381 43,289 43,211 41,467 37,806 41,524 477,327 Unbleached Hardwood - Batch ADT 391 89 676 249 622 356 2,383 Unbleached Hardwood•Kamyr ADT 35,234 22,604 36,239 39,008 35,185 35,262 35,782 34,365 36,402 35,440 30,848 35,071 411,440 Tons Manufactured - Total 67,942 35,945 72,494 76,585 71,393 71,949 70,877 72,309 73,464 71,154 63,569 71,175 t3i6i Bleached Pine ADT 35,612 15,264 38,651 40,256 38.186 39,024 37,391 39,587 39,522 37,922 34,165 38,036 Bleached hardwood ADT 32,330 20,681 33,843 36,329 33,207 32,925 33,486 32,722 33,942 33,232 29,404 33,139 385,240 .a S:1Groupsj[r ironmentak\Wastewater\NMES Permit Info\2011 Application12010-2011 Prod Stats.xlsx URSFILE N0, INTERNATIONAL PAPER 11RSCorporation - North Carolina SITE LAYOUT AND 31827122 RIEGELWOOD, NORTH r600 P, rive SURROUNDING CAROLINA A'artrr Carob)Park Morrisville, A'rrr7h Cmnliuu 77560 Telephone (919)461-1100 Fax(919)461.1415 TOPOGRAPHY FIG. NO. SCALE: DRAWN BY: AMM DATE: 3,22/04 2 2 CHECKED BY: I DATE: \ POND — GATE 3 ! PLANT NORTH R �r ,r 32.5 ACRES 2.4 DAYS RET. O 42MCD,V ». ELL NO. zLANDFILL �j� CELL NO. 1JFILJLANDFILL OPERATION) (UNDER ff gi � CLA1tlFlER WEST LANDFILL-J DATE 12 LL ~ - - ," CKKASH a FK*0 O o 00 0 SPILLWAY ELECTRICAL CONTROL STATIONS 0 50HP AERATORS x 9 = 450 TOTAL. HP ® 75HP AERATORS x 87 = 6525 6975 SUBTOTAL HP RECIRCULATION PUMPS 60.5 MGD x 4 = 242 MIGO •, ®,u ��_ - N W - 42 ACRES C ti - •s, _-_- --- - -=— _ .5 Ay RET. O 42MGD J e,40 bn� 0 14 / 1 , _ 1 _ - 45 ACRES ®a �i en BORROW PIT 11 2.3 DAYS RET. O 42MGD w GATE A d; SANITARY. LANDFILL _ ,x 1O "� it f t (IN' CLOSU0E PROCESS) _ F1 t ,fie a ®' SLUDGE PONDS I ; 35 ACRES LIME uUD�" ONO POND 1 • �,�, III TE 2 -SLIL►LMC ACID C 40UEDi15 AYMDNIA c20SL - aA10agy .� BORROW GATE 0 -------- - BORROW GATE C POND O/ GATE 1 INTERNATIONAL ®PAPER RIEGELWOOD MILL DRAWN CEW WASTE CHECKED WHIR TREATMENT APPROVED WHIR REV 12/20/00 REV 5/4/03 SYSTEM ,y 2/1/07 Ey 115EPT96 DAC. NO. REV REV 5/22/11 REV 13MAR97 A 12 00 0 3 ��, 7 INTAKE 34.6 MGD MGD BACKV1aSi-� APR 2010 / MAR 2011 YEARLY AVERAGE FLOWS 10 TREATMENT PLANT I sic 0.5 (E) MGD STORMWATER RUNOFF #5 RECOVERY 0.3 MGD #5 EVAPORATOR S (E) MGD Wi LIME KILNS 1.0 (E) MGD MOS. 2&5 1.3(E) MGD I POWER BOILER SCRU88ERS 1.0 MGO ASH POND TREATED WASTEWATER 0.8 (E) MGD EFFLUENT lip CAUSTICIZING SCREEN O.S MGD ROOM PAPER MACHINES 7.5 PULP DRYER 8 MGD NOS. i,2,3 14.7 E MGD BLEACH PLANTS 25.5 (E) MGD KNOT LINE 0.6 MGD 02 DELIG LANDFILL CELL 1 0.1 (E) MGD LEACHATE uouoR 3 8s NOS, 1.2,} g$1y PULP MILL 2€ MGD TOTAL JCLARWIE�R HATCH OICE51£RS #4 RECOVERY .6 E MGD 2.7 MGD NO. a RECOVERY LANDFILL CELL 2 LEACHATE (FUTURE) D.05 MGD iEAMYR DIGESTER TOTAL MILL WATER - 34.6 RAW WATER - 1.8 BASIN RETURN - 1.3 0.4 E MGD NO.4 BSW L—AREA 1.5 (E) MGD ► CHiLLER BLDG INOS. 2 & 3 SVP ROILS: 1. ALL FLOWS WERE AVERAGED FROM APR 2010 TO MAR 20111 HOLTRACHEM .04 MGD 2. TOTAL MILL EFFLUENT FLOW CAN BE DIRECTED TO EITHER CLARIFIER. THE BLEACH PLANT FLOW CAN BYPASS THE CLARIFIERS. O.2 E) MGD WFI CAR WASH , 19.3 (E) MGD N0.2 PRIMARY CLARIFIER INFLUENT UOUOR CYCLE POWER) 8.6 M00 HOLTRACHEM 0.04 MGD CAR WASH 1 7 (E) MGD INFLUENT (FIBER MILL) 1Q.7 MGD BAR SCREEN (IF NEEDH2504ED) BAR SCREEN 1.5 MGD (EST) 313 TPD SLUDGE PONDS 1-5X SOLIDS (EARTHEN) 3 0 J c.. w z Z ryR111R .2 GLARIFIEE (CONCRETE) SURFACE AREA: N0.1 IMARY CLA (EARTHEN) 0 J W s W 0 1.2E MG0 SLUDGE FILTRATE SCREW PRESSES SUPERNATANT 2a 5 MGD SUPERNATANT 0 u w _ N � J 4 J J J U 0 a 0 = 4 O = U z 6 a W z Q a W GROUP: Pulp and Paper r` DIVISION/SUBSIDIARY: Monufactoring - MILL/PLANT: Riegelwood Mill 1.5 MGD NO.1 ASS NO 2 ASS d[ SETTLING POND (EARTHEN) (EARTHEN) SURFACE AREA: .3 MGD C3333.3 MGD SURFA AREA: 34,8 w1GD RE 45 ACRES ^5O VOLUM VOLUM S13 MG 86.4 Mgal 1.670 LBS/DAT RESIDENCE TIME: RESIDENCE TIME: DAYS 2.5 DAYS NH3 � CTERIA NEEDED t RECIRCULATION (jjjD MGD POLISHING POND (EARTHEN) BACTERIA SURFACE AREA: (IF NEEDED) --32.5 TIMES) VOLUM 89.2 Mgol RES�1 CE ME: DAYS DEfOAMER 37E 7.0 MGD RIVER WATER NOTE: 430-4101XICSOUDS 1 TOTAL MILL EFFLUENT FLOW CAN BE DIRECTED TDEITHER CLARIFIER AND THE BLEACH PLANT MAY PARSHALL INDIVIDUALLY BYPASS THE CLARIFIER(S). 6 TPOXYGEN FLUME ip,000 LBS/DAYLERS IF OUTFACE 3.8 MGD CAPE FEAR RIVER TITLE DRAWN BY: CEW SCALE DRAWING NO, WASTEWATER FLOW INTERNATIONAL (?N PAPER V1 10012 DATE i 2-20-00 N/A RIEGELWOOD MILL F �Z UOUDR TANK CONTANMIENT ST°RMI►ATER r w HOTRACHEM FENCEUNE STORMWATER SUMP ROLLOVER QUMP/IIi CHIP DUMP STO 41TER NO.3 NO.• FRENCH NO.3 KILN ASH POND L } } 5 COOUHG TOWER CONTAINMENT $TORMWATER LK DRAIN SCAVOSER DUMP LK OVERFLOW z ' P ? C LhUSTIC TANK I oe 7AINF5 FILTERZFlL3rR:ATE 'I zr_NO.5 HOLTRACHEM EFFLUENT L-AREA RECOVERY WELL R.B. A C WER TANK OVUnOW GROUINCWATERSUMP PV11P � NO3 HQ NQiWELt TAWCS 5 R.B./ _ z5 EVAP. y . SW DEFOAMER TANKS WOODYARD _ m a h0 @DITCH Six 3EESS a<yz REV R�RECOVERY z L-AREA T— AT STE s in l� Wjnl WELL A cl N Z A[D ' NO _4 R, . x z NORTH O NO.2 CLARIFIER BASIN G SOUTH CAU D x m rt u z :owxzrAOR°H�°POWER Fc.- BOILER/m w z �... SOUTH SLUDGE PRESS z BASIN BY-PASS a POWER BOILER m m NO.1 CLARIFIER SLUDGE PRESS U-DRAMIS 0 A T SA! S BUILDING AREA a U-DRAINS m c S ? c 1 3 BL£ACH P ANT FF_ N0.5 2 k 3 BLACK } LANDFILL LIDQUORR PON W y x { zAND RUNOFF. LEACIIATE UNDERDRAINS STO'zN0.1 g N0.2 BRN. HD STORAGE x CAROLINA aCH HIGH DENSI TH NO." DECKER UDGE POND ;OVERFLOW x OVERFLOW uSAY TURP. UNDERF OW KAMYR W STRIPPED SCREEN ROOM REJECTS h LIME MUD POND SEAL PIT OVERFLOWS DECANT OVERFOLW TLIRP. UNDER OW BATCH IF STRIPPED B-75 OVERFLOWS AURACEL CHEST DWRFLOWS PAPER MILL EXCESS WW 49 STARCH R A TI R P INTERNATIONAL ®PAPER — RIECELWOOD MILL NOTES 1. SANITARY WASTE FROM SILL FACILITIES 'A y DRAWN KEFFER MILL -WIDE ARE DIRECTED TO PROCESS SEWERS AND RwErO -r:r4rFFN FIT CHECKED WBP/KJM ARE TREATED IN WASTEWATER TREATMENT SYSTEM.Z�n GUIDE 2. DRAWING SERVES A GENERAL SEWER SUBJECT Tb NC E_ APPROVED WHR _ REV 11/22/06 ,T,;v03/12/99 F L O W S H E E T REV 06/11/96 Rcv 12/20/00 DWG. NO. REv A 110 012 3 REW 02/12/9s REV ,�OFTI ATTACHMENT C SLUDGE MANAGEMENT PLAN NARRATIVE Sludge from the two primary clarifiers may be routed to either (1) sludge presses for mechanical dewatering or (2) one of three sludge dewatering ponds for settling (Ponds A, B, or C). Dewatered sludge from the sludge presses is routed to the power boilers for use as fuel. Primary sludge removed from the sludge ponds is typically landfilled in IP-Riegelwood's on - site landfill. The mill also has the option to land apply primary clarifier solids, per Land Application Permit WQ0015180 and its land management application plan (Wood Ash, Green Liquor Dregs, Slaker Grits, and Primary Clarifier Solids Soil Additive Program, International Paper, Riegelwood, NC, February 1998). However, IP-Riegelwood has not performed any land application during this permit term and has instead elected to manage the primary clarifier sludge in its on -site landfill or as boiler fuel. Effluent from the New Bay flows into a small settling pond of approximately 8 acres via a spillway, identified by the mill as the Theodorakis Settling Pond. Secondary sludge from this settling pond is dredged periodically and placed in any of the sludge dewatering ponds (Ponds A, B, C, 1, 2, or 3). After removal from the sludge dewatering pond(s), secondary sludge is placed in IP-Riegelwood's on -site landfill. The mill does not maintain a formal sludge management plan for its on -site sludge management activities. .5 /Jf ( iI Floyd Whitmire, Mill Manager Date S:/Groups/£nvironmentaVWostewoter/NPDES Permit )nfa/NPDF5 Permit Renewol Cover Letter 033111.doc