NCG030134_MONITORING INFO_20200102

STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
LGD3�) i3 I
DOC TYPE
❑ HISTORICAL FILE
[Y,MONITORING REPORTS
DOC DATE
❑ Q 0@ o o a
YYYYM M D D

Thermo Fisher
SCIENTIFIC
December 17, 2019
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: Stormwater Analytical Monitoring Results for Thermo Fisher Scientific, LLC
I have attached the analytical monitoring results from stormwater sampling that was collected on
November 23, 2019 at Thermo Fisher Scientific, LLC's four outfalls.
Per our General Storm Water Permit No. NCG03000 requirements of monthly monitoring for
applicable parameters during a storm event, I have sampled each outfall for copper, zinc, pH,
lead, TSS, and Non -Polar Oil/Grease/TPH. The result for zinc at one of the four outfalls was
above the benchmark value, as noted in Table 3 of the general storm water permit. All other
results were below the benchmark values. We have implemented a Tier Three response for the
site and Thermo Fisher Scientific, LLC has notified the Asheville Regional Office. Thermo
Fisher Scientific, LLC is currently working with an environmental consultant to help achieve
compliance with the benchmark values set forth in the facility's storm water permit. I have
attached the completed Monitoring Report containing the monitoring results from the four
outfalls.
If you have any questions, please feel free to contact me at 828-658-2845.
Jeremy Putnam
Sr. EFTS Manager
Attachments: 1
l
JAN 0 2 202�

Stormwater Discharge Monitoring Report
for North Carolina Division of Energy, Mineral and Land Resources General Permit No. NCG030000
Date submitted: 12/17/19
CERTIFICATE OF COVERAGE NO. N00030134
FACILITY NAME: Thermo Fisher Scientific (Asheville) LLC
COUNTY: Buncombe
PERSON COLLECTING SAMPLES: Jeremy Putnam, EHS
LABORATORY: Pace Analytical Lab Cert. p
Comments on sample collection or analysis:
Part A: Stormwater Benchmarks and Monitoring Results
SAMPLE COLLECTION YEAR
SAMPLEPERIOD —Jan-June_July-Dec
OrXMonthly: November
DISCHARGING TO CLASS ❑ ORW [IHQW nrrout []PNA
DZero-flow F—�NaterSupply []SA
nOther
PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 -
dVo discharge this period?'
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches'
Total Suspended Solids
p H,
Standard units
Total Copper
Total Lead
Total Zinc
Non -Polar O&G/
Total Petroleum
Hydrocarbons
Total Toxic
Organics
Benchmarks
-
-
100 mg/L or 50 mg/L4
6.0 — 9.0
0.010 mg/L
0.075mg/L
0.126 mg/L
15 mg/L
1 mg/L .
Parameter Code
-
46529
C0530
00400
01119
01051
01094
00552
78141
Outfall 1
11/23/19
10.15
2.5
6.3
<0.005
0.005
0.118
1<5
N/A
Outfall2
11/23/19
0.15
<2.5
6.3
<0.005
0.005
0.119
<5
N/A
Outfall3
11/23/19
0.15
<2.5
6.8
<0.005
0.005
0.0459
<5
N/A
Outfall4
11/23/19
0.15
2.5
6.9
0.005
0.005
0.195
<5
N/A
Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outran.
For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
See General Permit, Section B, Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies.
Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor
manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date: 11/1/2018-05/31/2021 SWU 245, last revised 11/1/2018
' Page 1 of 3

Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO
monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the
General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign, the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics (TTO),
I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent
management plan included in the Stormwater Pollution Pre tion Plan."
Name (Print name)
' le (Print title)
Signature
Date
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical
format. When results are below the applicable limits, they must be reported in the format "<XX mg/L" where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 1, or Tier 3 responses. See General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
o dischor e thi d 2z
Outfall No.
Date Sample Collected'
(mo/dd/yr)
24-hour rainfall amount,
Inches'
New Motor Oil or
Hydraulic Oil Usage
g
Non -Polar O&G Total
/
Petroleum Hydrocarbons
s peso .
Total Suspended
P
Solids
Benchmarks
-
-
-
15 mg/L
100 mg/L or 50 mg/O
Parameter Code
-
46529
NCOIL
00552
CO530
Footnotes from Part A also apply to Part B
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 1, or Tier 3 responses. See General Permit text.
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018
Page 2 of 3

FOR PART A AND PART B MONITORING RESULTS:
A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B.
TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL?
YES X NO
IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE? YES NO REGIONAL OFFICE CONTACT NAME: Ms. Laura Herbert
(Asheville Regional Office) .
Mail an original copy of this DMR, including all "No Discharge" reports within 30 days of receipt of the lab results (or at end of monitoring period in the
case of "No Discharge" reports) to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
1�0-sle persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I
am aNgre that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Permittee
Permit Date:11/1/2018-05/31/2021- ...
--- - --
Date
-. -----SWU-245, last revised- - - - --

5ceAna1j4Jca1
wrw.pacala0s.cam
Pace Analytical Services, LLL
2225 Riverside Dr.
Asheville, NC 28804
[phone]
December 11, 2019
Mr. Jeremy Putnam
Thermo Electron Corp.
275 Aiken Road
Asheville, NC 28804
RE: Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
Dear Mr. Putnam:
Enclosed are the analytical results for sample(s) received by the laboratory on November 25, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
14-- .�..n_
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 15

aceAnalXical e
www.pacelahs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, INC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC, Page 2 of 15

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[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
NOVEMBER 2019 SW
92455066
Analyses
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92455066001
1-1
EPA 200.7 Rev 4.41994
SH1
3
PASI-A
92455066002
1.2
SM 254OD-2011
CJL
1
PASI-A
92455066003
1-3
EPA 1664B
HH
1
PASI-C
li
EPA 1664E
HH
1
PASI-C
92455066004
2.1
EPA 200.7 Rev 4.41994
Sill
3
PASI-A
92455066005
2-2
SM 254OD-2011
CJL
1
PASI-A
92455066006
2.3
EPA 1664B
HH
1
PASI-C
'
EPA 1664B
HH
1
PASI-C
92455066007
3.1
EPA 200.7 Rev 4.41994
SH1
3
PASI-A
92455066008
3.2
SM 254OD-2011
CJL
1
PASI-A
92455066009
3-3
EPA 1664E
HH
1
PASI-C
EPA 1664B
HH
1
PASI-C
92455066010
4.1
EPA 200.7 Rev 4.41994
SH1
3
PASI-A
92455066011
4-2
SM 254OD-2011
CJL
1
PASI-A
92455066012
4-3
EPA 1664E
HH
1
PASI-C
"
EPA 1664B
HH
1
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 15

aceAnalytical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: NOVEMBER 2019 SW
Pace Project No.: 92455056
Sample: 1-1 Lab ID: 92455066001 Collected: 11/23/1912:00 Received: 11/25/19 12:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Copper
ND ug/L
5.0 1 12/05/19 00:55 12/06/19 21:03
7440-50-8
Lead
ND ug/L
5.0 1 12/05/19 00:55 12/06/19 21:03
7439-92-1
Zinc
118 ug/L
10.0 1 12/05/19 00:55 12/06/19 21:03
7440-66-6
Sample: 1-2
Lab ID: 92455066002 Collected: 11/2311912:00
Received: 11/25/19 12:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No.
Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Total Suspended Solids
ND mg/L 2.5 1
11/26/19 17:01
Sample: 1-3
Lab ID: 92455066003 Collected: 11/23/19 12:00
Received: 11/25/19 12:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No.
Qual
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
NO mg/L 4.8 1
12/10/19 10:09
1664 SGT-HEM, TPH
Analytical Method: EPA 1664E
Total Petroleum Hydrocarbons
NO mg/L 4.8 1
12/10/19 10:09
Sample: 2-1
Lab ID: 92455066004 Collected: 11/23/19 12:15
Received: 11/25/19 12:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No.
Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Copper
ND ug/L 5.0 1
12/05/19 00:55 12/06/19 21:24 7440-50-8
Lead
ND ug/L 5.0 1
12/05/19 00:55 12/06/19 21:24 7439-92-1
Zinc
119 ug/L 10.0 1
12/05/19 00:55 12/06/19 21:24 7440-66-6
Sample: 2-2
Lab ID: 92455066005 Collected: 11/23/19 12:15
Received: 11/25/19 12:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No.
Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
Total Suspended Solids
NO mg/L 2.5 1
11/26/19 17:01
Date: 12/11/2019 03:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 15

Pace Analytical Services, LLC
/ceAnalytical ` 2225 Riverside Dr.
� Asheville, NC 28604
wvrr,pecelebs.com [phone]
ANALYTICAL RESULTS
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
Sample: 2.3 Lab ID: 92455066006 Collected: 11/2311912:15 Received: 11/25/1912:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease Analytical Method: EPA 16648
Oil and Grease NO mg/L 4.8 1 12/10/19 10:09
1664 SGT-HEM, TPH Analytical Method: EPA 1664E
Total Petroleum Hydrocarbons ND mg/L 4.8 1 12/10/19 10:09
Sample: 3.1 Lab ID: 92455066007 Collected: 11/23/19 12:30 Received: 11/25/1912:50 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Copper
ND ug/L
5.0 1
12/05/19 00:55 12J06119 21:27 7440-50-8
Lead
ND ug/L
5.0 1
12/05/19 00:55 12/06/19 21:27 7439-92-1
Zinc
45.9 ug/L
10.0 . 1
12/05/19 00:55 12/06/19 21:27 7440-66-6
Sample: 3.2
Lab ID: 92455066008
Collected: 11/2311912:30
Received: 11/2511912:50 Matrix: Water
Parameters
Results Units
Report Limit OF
Prepared Analyzed CAS No. Qual
t
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
i
Total Suspended Solids
NO mg/L
2.5 1
11/26/19 17:16
11
Sample: 3.3
Lab ID: 92455066009
Collected: 11/23/1912:30
Received: 11/25/19 12:50 Matrix: Water
Parameters
Results Units
Report Limit OF
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease NO mg/L 4.8 1 12/10/19 10,10
1664 SGT-HEM, TPH Analytical Method: EPA 1664B
Total Petroleum Hydrocarbons NO mg/L 4.8 1 12/10/19 10:10
Sample: 4-1 Lab ID: 92455066010 Collected: 11/23/19 12:45 Received: 11/25/19 12:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP
Copper
Lead
Zinc
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
ND ug/L 5.0 1 12/05/19 00:55 12/06/19 21:30 7440-50-8
ND ug/L 5.0 1 12/05/19 00:55 12/06/19 21:30 7439-92-1
195 ug/L 10.0 1 12/05/19 00:55 12/06/19 21:30 7440-66-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 12/11/2019 03:53 PM without the wiitlen consent of Pace Analytical Services, L-C. Page 5 of 15

aceAnalytical e
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
Sample: 4-2 Lab ID: 92455066011 Collected: 11/23/1912:45 Received: 11/25/19 12:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 2540D-2011
Total Suspended Solids ND mg/L 2.5 1 11/26/19 17:17
Sample: 4-3 Lab ID: 92455066012 Collected: 11/23/19 12:45 Received: 11/25/19 12:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua(
HEM, Oil and Grease Analytical Method: EPA 1664E
Oil and Grease NO mg/1- 4.8 1 12/10/19 10:10
1664 SGT-HEM, TPH Analytical Method: EPA 1664E
Total Petroleum Hydrocarbons ND mg/L 4.8 1 12/10/19 10:10
REPORT OF LABORATORY ANALYSIS
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Date: 12/11/2019 03:53 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15

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l
QUALITY CONTROL DATA
I
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
QC Batch: 513864 Analysis Method: EPA 1664B
OC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92455066003, 92455066006, 92455066009, 92455066012
ll
METHOD BLANK: 2754387 Matrix: Water
As Lab Samples: 92455066003, 92455066006, 92455066009, 92455066012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L NO 5.0 12/10/19 10:08
Pace Analytical Services, LLC
2225 Riverside Dr.
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[phone]
LABORATORY CONTROL SAMPLE: 2754388
Spike LCS LCS % Rec
. Parameter Units Conc. Result e% Rec Limits Qualifiers
Oil and Grease mg/L 40 37.3 93 78-114
MATRIX SPIKE SAMPLE: 2754389
Parameter
Oil and Grease
b
92455125001 Spike
Units Result Conc.
mg/L NO 38.5
MS MS % Rec
Result % Rec Limits Qualifiers
17.4 43 78-114 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
I�
Date:l12/11/2019 03:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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aff
aceAnalytical a
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Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
QC Batch: 513867 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH
Associated Lab Samples: 92455066003, 92455066006, 92455066009, 92455066012
LABORATORY CONTROL SAMPLE: 2754405
Parameter Units
Total Petroleum Hydrocarbons ri
MATRIX SPIKE SAMPLE: 2754406
Parameter Units
Total Petroleum Hydrocarbons mg/L
Spike LCS LCS % Rec
Conc. Result %Rec Limits Qualifiers
20 15.6 78 64-132
92455125001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 19.2 5A 22 64-132 M1
Results presented on this page are in the units indicated by the 'Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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I
QUALITY CONTROL DATA
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
QC Batch: 512979 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92455066001, 92455066004, 92455066007, 92455066010
METHOD BLANK: 2750154 Matrix: Water
Associated Lab Samples: 92455066001, 92455066004, 92455066007, 92455066010
Blank Reporting
ll Parameter Units Result Limit Analyzed Qualifiers
Copper ug/L NO 5.0 12/06/19 20:57
Lead ug/L NO 5.0 12/06/19 20:57
Zinc ug/L ND 10.0 12/06/19 20:57
LABORATORY CONTROL SAMPLE: 2750155
Spike
Parameter Units
Conc.
Copper ug/L
500
Lead - ug/L
500
Zinc ug/L
500
Pace Analytical Services, LLC
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LCS LCS % Rec
Result % Rec Limits Qualifiers
513 103 85-115
501 100 85-115
488 98 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2750156
2750157
MS
MSD
92455066001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Copper
ug/L
NO
500
500
509
495
101
98
70-130
3
Lead
ug/L
ND
500
500
501
487
100
97
70-130
3
Zinc
ug/L
118
500
500
616
598
100
96
70-130
3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2750158
2750159
MS
MSD
92455878001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
%Rec
%Rec
Limits
RPD Qual
Copper
ug/L
ND
500
500
498
503
99
100
70-130
1
Lead
ug/L
ND
500
500
492
498
98
100
70-130
1
Zinc
i,
ug/L
38.2
500
500
525
529
97
98
70-130
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
i
Dale:. 12/11/2019 03:53 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: NOVEMBER 2019 SW
Pace Project No.'. 92455066
QC Batch: 511918
Analysis
Method:
SM 2540D-2011
QC Batch Method: SM 2540D-2011
Analysis
Description:
2540D Total Suspended Solids
Associated Lab Samples: 92455066002, 92455066005
METHOD BLANK: 2745545
Matrix:
Water
Associated Lab Samples: 92455066002, 92455066005
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 11/26/19 16:45
LABORATORY CONTROL SAMPLE:
2745546
Spike
LCS LCS e/ Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Total Suspended Solids
mg/L
250
230 92 90-110
SAMPLE DUPLICATE: 2745547
92454957001 Cup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 82.0 65.7 22
SAMPLE DUPLICATE: 2745548
92455004001 Dup
Parameter Units Result Result RED Qualifiers
Total Suspended Solids mg/L 7.6 9.0 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2019 03:53 PM without the written consent of Pace Analytical Services. L-C. Page 10 of 15

aceAnalytical
www ilacelebs.carn
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
I
Project: NOVEMBER 2019 SW
Pace Project No,: 92455066
QC Batch: 511928
OC Batch Method: SM 254OD-2011
Associated Lab Samples: 92455066008, 92455066011
METHOD BLANK: 2745618
Associated Lab Samples: 92455066008, 92455066011
b
Parameter Units
Total Suspended Solids mg/L
LABORATORY CONTROL SAMPLE:
2745619
Parameter
Units
Total Suspended Solids
mg/L
SAMPLE DUPLICATE: 2745620
Parameter
Units
Total Suspended Solids
mg/L
SAMPLE DUPLICATE: 2745621
Parameter
Units
Total Suspended Solids
mg/L
QUALITY CONTROL DATA
Analysis Method: SM 254OD-2011
Analysis Description: 2540D Total Suspended Solids
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 2.5 11/2611917:14
Spike LCS LCS % Rec
Conic. Result % Rec Limits Qualifiers
250 244 97 90-110
92455115001 Cup
Result Result
29.3 34.7
92455086005 Dup
Result Result
NO ND
RPD Qualifiers
17
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 12/11/2019 03:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 15

aceAnalytical a
arww.pacelabs.com
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: NOVEMBER 2019 SW
Pace Project No.: 92455066
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit,
PQL- Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1.2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NO - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260,
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2019 03:53 PM without the written consent of Pace Analytical Services, LLQ Page 12 of 15

Pace Analytical Services, LLC
ceAnalytical ® 2225 Riverside Dr.
Asheville, NC 28804
ww.Dacelabs.cam [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
NOVEMBER 2019 SW
92455066
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical
Method
Batch
92455066003
1-3
EPA 1664E
513864
92455066006
2.3
EPA 1664B
513864
92455066009
3-3
EPA 1664B
513864
92455066012
4.3
EPA 1664E
513864
92455066003
1-3
EPA 16646
513867
9Y455066006
23
EPA 1664E
513867
92455066009
3-3
EPA 1664B
513867
92455066012
4-3
EPA 1664B
513867
92455066001
1.1
EPA 200.7 Rev 4.4 1994
512979
EPA 200.7
Rev 4.4 1994
512998
92455066004
2-1
EPA 200.7 Rev 4.4 1994
512979
EPA 200.7
Rev 4.4 1994
512998
92455066007
3-1
EPA 200.7 Rev 4.4 1994
512979
EPA 200.7
Rev 4.4 1994
512998
92455066010
4-1
EPA 200.7 Rev 4.4 1994
512979
EPA 200.7
Rev 4.4 1994
512998
92455066002
1-2
SM 254OD-2011
511918
92455066005
2.2
SM 254OD-2011
511918
92455066008
3-2
SM 254OD-2011
511928
92455066011
d
4-2
SM 254OD-2011
511928
Date: 12/11/2019 03:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 15

I� eAnalytical CHAIN -OF -CUSTODY Analytical Request Document
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!Mto Billing Information:
emo FlSher AC.t oL�--tS Payable,
ass:
LABDStDNt WO# : 92455066
1111111111111111111111111
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To:
ite Collection Info/Address:
161 methanol, Pl sodium Bisulfate, (R)sodium thioml(ate, let he..ane,
IAl ascorbic acid, fBlammonium sulfate,
V]5 AiKc i R01A
(Cl a,nmonlum hydroxide, (DI T5P, NJ) Unpreserved, (0) Other
---lsnal
/mar Project Name Number
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State: County/City: Time Zone Collected:
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Turnaround Date Required:
Immedlatel'y Packed on Ice:
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Type of ice Used: VOIn( Blue Dry None
SHORT HOLDS PRESENT(<72 hours): Y V N/A
Lab Sample Temperature Into:
Packing Material Used:
l�
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Lab Tracking It:
Temp Blank Racal Y N NA
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Cooler 1 Tamp Upon Receipt: 22=-.00
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Samples receivevia'
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Cooler 1 Therm Corr. Factor: '�- oC
Imshed By/Company (Signature) Dale/Tim
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FEDEX _ UPS Clien Courier Pace Courier
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Comments -
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t rip manit Received: YP '-t1' NA
HCL MCOH TSP Other
Non Conform!e(s): I Page:

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CHAIN -OF -CUSTODY Analytical Request Document
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Billing Information:
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PM: CD1 Due Date: 12/11/19 e2
CLIENT: 93-Thermo d
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Container Preservative type ,ia r�..rc.............. -
Preservative Types: It) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate,
fd methanol, Ill sodium bisulfate, (R) sodium thiosulfate, (9) hexane, (A) ascorbic acid (R) ammoniurn sulfate.
ICI ammonlum hydroxide. I D) TSP. (U) Unpreserved. (0) Other
fie/Number:
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rchive: ( 12 Day 113 Day ( 14 Day 115 Day Analysis:
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nrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (W W),
(duct Rz, Soil/Solid ISE), Oil (OL), Wipe (WP), Air (AR), Tissue (T5), Bioassay (B), Vapor (V), Other (OT)
Comp/ Collected (or Composite End
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_ Date I Time Date I Time
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Res it
Cl I Cms
Type of Ice Used: Valet Blue 0ry None
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IRT HOLDS PRESENT (U2 hours): Y fN Nl
Tracking 7:
pies received via:
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'zfV Table N:
J!/ Acctnum:
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LaG :iiz=le Ricer pt Checkl:,t:'
custody Seals Present/intact 'i A NA
C"'trid, $Sg'ilro"s Pnnsnnr. Y 11 w,
Collector Signature. Pt'ep^nt Y N NA
Rottlrs Intact Y N NA
Corn_cc Bottles i- N NA
Sufficient vulum.+ i :I rip,
Safanles Received on Icr; Y y NA
VOA - ReadspaoO AOceptatilo Y tJ 0)
USDA Itcuuletr<t.$.its el%rri..
Saru]Cs in Folding Tiine Y 'l NA'
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tAS (12E? ONLY:
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Lan Sample Temperature Into:
Temp Blank Received: Y �1 NA
Therm IDN: - - C'9
Cooler i Temp Upon Receipt:
Cooler 1 Therm Corr..Factor.
Cooler 1 Corrected Temp:
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Blank Received:---Y,
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to/Time:
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