WQ0000430_Residual Annual Report 2019_20200225

Initial Review
INITIAL REVIEW
Reviewer Williams, Kendall
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application r Annual Report
what is the submittal r Residual Annual Report
type?* r Additional Information
r Other
Annual Report 2019
Year*
Date Paper Copy 2/25/2020
Received:*
Project Number* WQ0000430
Email Notifications
Does this need review by the hydrogeologist?*
r Yes r No
Regional Office
CO Reviewer
Admin Reviewer [e-mail]

Submitted Form
Project Contact Information
Rease provide information on the person to be contacted by MB Staff regarding electronic subnittal, confirmation of receipt, and other issues.
..........................................................................................................................................................................................................................................................................................................................................................................
Name * Lysa Finnerty
Email Address*
[e-mail]
Project Information
Submittal Type* r New Permit Application
r Renewal
r Annual Report
r Other
Permit Type * r Wastewater Irrigation
r Other Wastewater
r Closed -Loop Recycle
r Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?
r Yes r Nor N/A
Permit Number* WQ0000430
Applicant\Permittee * Synagro
Facility Name * City of Cherryville
Phone Number*
4434899026
r Modification (Major or Minor)
r Additional Information
r Residual Annual Report
r High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Cherryville 2019 Annual Report
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Rans, Specifications, Calculations, Etc.)
CHERRYVILLE NC 2019 Annual FINAL.pdf 20.28MB
Upload only 1 R7F document. NL@iple documents must be combined into one R7F file.

For new and modification permit applications, a paper copy may be required. If you have any questions
about what is required, please contactthe reviewer or Tessa Monday. If a paper 2-pol cation is required,
be advised, applications accepted for pre -review until both the paper and elect-c-ii.- --ol:ies have been
received. The paper copy shall include the following:
o Application Form
o All relevant attachments {talcs, soils report, specs, etc.]
o One full-size engineering plan set
o One 11x17" engineering plan set
o One extra set of specifications
o Fee (if required)
Mailine address:
Division of Water Resources ! Division of Water Resources
Non -Discharge Branch I Non -Discharge Branch
1617 Mail Service Center I Att: Nathaniel Thornburg, P Floor, Office #942W
- =
Raleigh, NC 27699-1617 S12 N.5alisburySt.
For questions or problems contact Tessa Monday attessa.monday@)ncdenr.Qov or 919.707.3560.
* rJ By checking this box I acknowledge that I understand the application will not be accepted
for pre -review until the paper copy (if required) and fee (if required) have been received by
the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with
all parts of the application in correct order (as specified by the application).
Signature
Submission Date 2/21/2020

435 Williams Court, Suite 100
Baltimore, MD 21220
wwwsynagro.com
FEBRUARY 213 2020
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2019 Annual Report fot Permit No. WQ0000430
Dear NCDEQ:
Synagro is submitting one copy and one electronic copy of the above referenced report on
behalf of the City of Cherryville, NC.
If you have any questions of need additional
information,
please
do not hesitate to contact Larry
Wright at [phone] or
Alex Fox at (336)
703-8681.
Sincerely,
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Larry Wright, City of Cherryville
Alex Fox, Synagxo
YOUR PARTNER FORA CLEANER, GREENER WORLD

CITY OF CHERRYVILLE, NC
RESIDUALS LAN® APPLICATION PROGRAM
Permit N®e l/VQ0000430
2019 ANNUAL REPORT
4

City of Cherryville, NC
Residuals Land Application Program
2019 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms, Residuals
Analysis, & SAR Calculation Page
3. Annual Land Application Fieid Summary Forms
4. TCLP Analysis
5. Pathogen ReductionNectorRttraction Reduction
5. Soil pFi &Lime Application Records
7. Soil Analyses

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit #: WQ0000430 County Gaston Year 2019
Facility Name (as shown on permit) City of Cherrvville WWTP NPDES No. NC0044440
Land Application Operator Syna@ro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip Part A, and PartB and proceed to Part C. Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A —Residuals Application Summary:
Total number of application fields in the permit: 7
Total number of fields utilized for land application during the year: 1
Total amount of dry tons applied during the year for all application sites: 68.8
Total number of acres utilized for land application during the year: 17
Part B —Annual Compliance Statement:
Facility was compliant during calendar year 2019 with all conditions of the land application permit (including but not limited to items
143 below) issued by the Division of Water Quality X YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .I I I I were complied with (applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C —Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete.
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations."
Larry Wright, Plant ORC &Plant Supervisor
Permittee Name and Title +;.p �� print)
Z-l• 2v20 U ...�
,m�'fa ure of reparer* Date S
different om Permi cc) (if different
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

2019 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
CHERRYVILLE, NC
CHERRYVILLE, NC LIQUID
MONTH/YEAR AMOUNT UNIT DRY TONS UNIT
August 2019 3651800400 G 68,80 D
YEARLY TOTAL 365,800000 G 68,80 D
DRY METRIC
TONS
62,40
62,40
1 /30/2020

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Hlease note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0000430
Facility Name: CHERRYVILLE, NC
NPDES# : NCO044440
or WQ# (residual only)
WWTP Name: CHERRYVILLE
Residuals Analysis Data
Product Type LIQ
Date Sampled (grab) or 05/14/19
Date Composited
Percent Solids 4.51
PARAMETERS (mg/kg dry weight)
Arsenic <5
Cadmium 2.57
Mercury 2.15
Chromium 147
Copper 996
Lead 34.7
Molybdenum 8.44
Nickel 70. 8
Selenium <5
Zinc 897
Total Phosphorus 12900
TKN 31800
Ammonia -Nitrogen 4220
Nitrate and Nitrite 195
Laboratory
Waypoint Analytical Virginia Inc.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false i�aff5 ion, i ing the possibility of fines and imprisonment for knowing violations."
(SIG
DENR FORM RSSF (5/2003) Printed Wednesday - February 5 2020 at 12:55:08 for: 2008 01

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0000430
Facility Name: CHERRYVILLE, NC
NPDES# : NCO044440
or WQ# (residual only)
WWTP Name. CHERRYVILLE
Residuals Analysis Data
Product Type L1Q
Date Sampled (grab) or 05/14/19
Date Composited
Percent Solids 4 . 51
PARAMETERS Qmg/kg dry weight)
Aluminum 16500
Calcium 7590
Magnesium 2230
pH 6.70
Potassium 1700
Sodium 833
Laboratory
Waypoint Analytical Virginia Inc.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel r .I athered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false-trf of motion, inc ing the possibility of fines and imprisonment for knowing violations."
„ E OF PREP
NRAData'Not Reported or D
ER)
Not Requ
DENR FORM RSSF-B (7/2002) Printed: Wednesday - February 5, 2020 at 12:55:29 for: 2008 01

Waypaint.
ANALYTICAL
5/24/2019
Synagro Central LLC/ Cherryville
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 19-136-0211
Project Description: Cherryville WWTP
7621 Whitepine Road, Richmond, VA 23237
Main $04-743-9401 °Fax [phone]
www.waypointanalytical.com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 5/16/2019 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
P�� m` �"�
Pauric McGroary
Agronomist
Laboratory's liability
in
any claim relating to analyses performed
shall be limited to, at laboratory's option, repeafing the
analysis in question
of
laboratory's expense, or the refund of the
charges paid for performance of said analysis.
Virginia 460014
Page 1 of 6

Wa dint,.
vp
ANALYTICAL
7621 Whitepine Road, Richmand, VA 23237
Main $04-743-9401 °Fax $04-271-6446
www.waypaintanalyfical.com
Sample Summary Table
Report Number: 19-136-0211
Client Project Description: Cherryville WWTP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
SM-4500-NH3C
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
9045D
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
4500NO3F-2011
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
6010D
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
SW-7471B
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
SM-4500-NH3C-TKN
WTN
66425
Cherryville
WWTP
Solids
05/14/2019
11:00
05/16/2019
SM-2540G
WTN
WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354
Page 2 of 6

Report Number: 19-136-0211
Account Number: 46442
Send To: Synagro Central LLC/ Cherryville
Mary Brewer
284 Boger Road
Mocksville , NC 27028
�I��,..
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main $p4-743-9401 °Fax $04-271-6446
www.waypointanalytical.com
Project :Cherryville WWTP
REPORT OFANALYS/S Date Sampled: 5/14/2019 11:00:00
Lab Number : 66425 Date Received: 05/16/2019 00:00
Sample Id :Cherryville WWTP Date Reported: 05/24/2019
Total Solids * 4.51 ADM 05/21/2019 16:54
Moisture * 95.50 ADM 05/21/2019 16:54
Total Kjeldahl Nitrogen 3.18 31800 250 CLP 05/23/2019 13:30
Phosphorus 1.29 12900 50.0 KKM 05/21/2019 23:43
Potassium 0.17 1700 50.0 KKM 05/21/2019 23:43
Sulfur 0.79 7880 50.0 KKM 05/21/2019 23:43
Calcium 0.76 7590 250 KKM 05/21/2019 23:43
Magnesium 0.22 2230 50.0 KKM 05/21/2019 23:43
Sodium 0.08 833 250 KKM 05/21/2019 23:43
Iron 28300 50.0 KKM 05/21/2019 23:43
Aluminum 16500 50.0 KKM 05/21/2019 23:43
Manganese 443 5.00 KKM 05/21/2019 23:43
Copper 996 2.50 KKM 05/21/2019 23:43
Zinc 897 12.5 KKM 05/21/2019 23:43
Ammonia Nitrogen 0.42 4220 100 ZBD 05/23/2019 16:00
Organic N 2.76 27580 250 05/23/2019 13:30
Nitrate+Nitrite-N 195 4.71 ZBD 05/22/201913:46
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
B-Analyte detected in blank H -Beyond Holding Time ����
Our reports
and
letters
are for
the exclusive and confidential use
of our clients; and may
not be reproduced in whole or part,
nor may any reference be made
to the work,
the
results,
or fhe
company in any advertising, news
release. or other public
announcements without obtaining
our prior written authorization.
SM-2540G
SM-2540G
SM-4500-NH3C-TKN
6010D
6010D
6010D
6010D
6010D
6010D
6010D
6010D
6010D
6010D
SM-4500-NH3C
CALCULATION
4500NO3F-2011
m` G�"�'
Pauric McGroary
Agronomist
Page 3 of 6

Report Number: 19-136-0211
Account Number: 46442
Send To: Synagro Central LLC/ Cherryville
Mary Brewer
284 Boger Road
Mocksville , NC 27028
•
'a oink.
��
ANALYTICAL
?621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax $04-271-6446
www.waypointanalytical.com
Project :Cherryville WWTP
REPORT OFANALYS/S Date Sampled: 5/14/2019 11:00:00
Lab Number : 66425 Date Received: 05/16/2019 00:00
Sample Id :Cherryville WWTP Date Reported: 05/24/2019
Chromium
Nickel
Lead
Arsenic
Mercury
Selenium
pH
Molybdenum
Comments:
2.57
1.00
KKM
05/21/2019
23:43
6010D
147
2.50
KKM
05/21/2019
23:43
6010D
70.8
2.50
KKM
05/21/2019
23:43
6010D
34.7
3.00
KKM
05/21/2019
23:43
6010D
<5.00
5.00
KKM
05/21/2019
23:43
6010D
2.15
0.0143
TJS
05/22/2019
12:37
SW-7471 B
<5.00
5.00
KKM
05/21/2019
23:43
6010D
6.7
JSL
05/21/2019
08:40
9045D
8.44
2.50
KKM
05/21/2019
23:43
6010D
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
B - Analyte detected in blank H -Beyond Holding Time
Our reports
and
letters are
for
the exclusive and confidential use
of our clients, and may
not be reproduced in whole or part,
ncr may any reference be made
to the work,
the
results, or
the
company in any advertising, news
release, or other public
announcements without obtaining
our prior written authorization.
1 f��G 1"� ��K�
Pauric McGroary
Agronomist
Page 4 of 6

�.
. : � '� _:
� i �
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypo i nta nalytica Isom
Cooler Receipt Form
Customer Number: 46442
Customer Name: Synagro Central LLC/ Cherryville
Report Number: 19-136-0211
Shipping Method
0 Fed Ex � US Postal � Lab � Other
UPS � Client 0 Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes 0 No
Number of coolers received 1
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes � No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes 0 No
Cooler temperature in compliance? � Yes 0 No
Gooier/Samples arrived at the laboratory on ice. ®Yes C No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes 0 No ®N/A
Water -VOA vials free of headspace � Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 —compliance criteria met � Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes ®No
Comments:
Signature: Brandi Watson Date &Time: 05/16/2019 13:46:49
Page 5 of 6

Cll
SAMPLING LOG # t j )
IIIII�'IIIIIIIIIIII IIINIIIIIIIII IIII�llllllllll�lllll l 4 6 Zo?1
Svnagro Central LLC; Cherrvvdla
CherMille WVVTP 13:44:33
PROJECT MANAGER: LJ''"' �
Phone: � ') (o10 C1oruC-+k a
, Xc.CN"
SV ct
A & L CUSTOMER SAMPLING SAMPLE
LAB ## SAMPLE I.A. LOCATION TYPE
ale
Haltnquisneq by Sampler:
# OF
CONTAINERS
rteclevea ny:
Relinquished by: , _^_ — �li7ate� Time moved 6y:
Relinquished by:
SPECIAL INSTRUCTIONS:
For AT 3TAT'ct monitoring purposes.
(
Time
Recieved by:
CHAIN duCUSTODY
RECORD rANALYSIS
RECORD
=st that the proper field sampling procedures
were used during the collection of these samples.
SAMPLING M1=TROD METHOD
DATE TIME PRESERVED SHIPPED
PO#:
REMARKS:
SAMP�.E
ANALYSIS REQUEST
SLI
SL2
NH,-N
NOa N
grgark
Cd
I Ct
Ni
Pb
As
Hg
Se
pH
CaCO3
equiv,
Volatile
Solids
Mo
Cl
NO -N
a
SLR: Total Solids (Moisture), Total Kjeldahi Nitrogen, Phosphorus, and Potassium .
Sit: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium Iran, Aluminum, Manganese, Copper and Zinc

Product
Code
Product Name
Sample
Date
Report Range
Ratio
2008=01=LIQ-NC
CHERRYVILLE, NC LIQUID
51141201
9
l/l/2019A2/31/2019
0.4575
Na mg/I = (Na mg/kg x %Solids) = 100 = (833 x 4.5100) _ 100 = 37.5683
Ca mg/I = (Ca mg/kg x %Solids) = 100 = (7590 x 4.5100) _ 100 = 342.309
Mg mg/I = (mg mg/kg x %Solids) _ 100 = (2230 x 4.5100) + 100 = 100.573
Na meq = Na mg/I + Molec.Wgt.Na = 37.5683 _ 23 = 1.6334
Ca meq = Ca mg/I _ Molec.Wgt.Ca = 342.309 = 20 = 17.1155
Mg meq = Mg mg/I _ Molec.Wgt.Mg = 100.573 _ 12 = 8.38108
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.6334 _ SgrRoot[0.5(17.1155+8.38108)] = 0.457476
Printed: 2/5/2020
Page 1 12:59

FACILITY NAME: CHERRYVILLE, NC
OWNER: CALVIN WEHUNT
SITE #: NC LT 00107 FIELD# : LT 00107 0003
RESIDUAL SOURCE(S): See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PREDOMINANT SOIL SERIES : CECIL
PERMIT #: W00000430
OPERATOR: CALVIN WEHUNT
ANNUAL DRY TONS APPLIED : 68.80
CATION EXCHANGE CAPACTTY (NON-503):
ACRES UTILIZED: 17.00 ACRES PERMITTED: 17.00
Page : 1
Lime Applied ***
Date
Lbs/Ac
DATE or
allons (G) or Cubic Yazds (CY)
or Wet Tons (WT) (specify)
%
Diy
Tons
Per
Residual
Site
Cond.
Dry, Wet,
Inches
Precip.
Past 24
Appli-
cation
Method
Vola-
tili-
zation
Miner -
ali-
zation
TKN
Ammonia
Nitrogen
Nitrate
and
pAN
(pptn)
Crop
MONTH
Total
I Per Acre
Solids
Acre
Source
Moist
Hours
*
Rate**
Rate
Nitrite
8/19/19
99,200.00 (G)
5835.294
4.51
1.097
CHL
DRY
0-<1/2"
SUR
0.5
0.30
31,800. p
4,220.00 p
195.00 p
10579
SORGHiJM/SUDAN HAY
8/21/19
204,600.00 (G)
12035.294
4.51
2.263
CHL
MOIST
0-<1/2"
SUR
0.5
0.30
31,800. p
4,220.00 p
195.00 p
10579
SORGHUM/SUDAN HAY
8/22/19
62,000.00 (G)
3647.059
4.51
0.686
CHL
DRY
0-<1/2"
SUR
0.5
0.30
31,800. p
4,220.00 p
195.00 p
10579
SORGFiUM/SUDAN HAY
Aug-19
365,800.00 (G)
21,517.647
Total Gallons/Ac: 21,517.65
Total Wet Tons/Ac:
Total Cubic Yds/Ac: 0.00
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn
P
PAN
TOTALS:
86
Annual Ibs/acre
0.040
0.021
1.190
8.061
0.281
0.017
0.068
0.573
0.040
7.260
104.41
Cumulative lbs/acre
0.040
0.021
1.190
8.061
0.281
0.017
0.068
0.573
0.040
7.260
Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop
221
FD Cumulative Pollutant Loading Rate Limit (lbs/acre)
36.6
34.8
1339.0
267.9
15.0
375.0
89.0
2500.0
CHL = CHERRYVILLE, NC LIQUID
/1
(SIGNATURE OF LAND APPLIER) DATE
"I certify, under penalty of law, that this document was prepazed under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and
evaluated the information submitted. I am awaze that there aze significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
N/A =Not Applicable NR =Not Reported or Not Required % =percent p = ppm or mg/kg ** Volatilization Rate : Surface 0.5, Injection/Incorporation 1.0
* Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020

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Efd�IPiONh11=MThL TfC!fNC]L�I�;iF$, iM{;
,drr��iytica�P L�llol'�ttrtd��
June O5, 2019
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Cherryville WWTP
Dear Erik Bruce:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
Website: http://ivwwsettelc.com
Order No.: 19051264
Summit Environmental Technologies, Inc. received 1 sample(s) on 5/16/2019 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH 0108, Delawaze, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois
200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota
409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Cazolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP
CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-1 I-5, Utah
OH009232011-1, Virginia VELAP 9456, Washington C891
Page 1 of 35

SIT
�Ntr113CtiNiA�idTAL iE�liF�lCiLtXC��= �, ir+t�;
.� � �ilrt�t<af L��c�r�tsarles
CLIENT: Synagro
Project: Cherryville WWTP
WorkOrder Narrative:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL; [phone] FAX.• [phone]
Website: httn://www.settek.com
Case Narrative
WO#: 19051264
Date: 6/5/2019
19051264: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical .report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
19051264-OOlA TCLP-SVOC_8270E: The CCV (Batch R98606) exhibited high recovery of 2,4-
Dinitrotoluene. The associated samples are ND for 2,4-Dinitrotoluene.
19051264-OOlA TCLP-SVOC-CPest(8081B): CCV exhibited high recoveries for Endrin. Associated
samples were ND
Revision vl
Page 2 of 35

�1�
EN'JI3ttItdHIENTAL TEG3iNt}LCfC;`iF$, 9N�:
An�lytiGaP i�6�rr�tarl�s
Sumnsit Environmental Technologies, In
3310 Win S
Cuyahoga Falls, Ohio 442�
TEL: [phone] F�4X.� (330) 253-445
Website: http://www.settek.co
Qualifiers and Acronyms
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
WO#: 19051264
Date: 6/5/2019
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
r The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25%difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GC/MS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/L,CSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
ICB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
RLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Revision vl
Page 3 of 35

�'�
i �Nlrilt�NfA�tdTALi[C34N[}1_tlfl�fi,lF#r,
e]gt3{(/t,�G'aP L�bo�raiarr��
CLIENT: Synagro
Project: Cherryville WWTP
Lab SampleID
19051264-001
Client Sample ID
Cherryville WWTP
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
Website: http://www.settek.com
Tag No Date Collected
5/14/2019 11:00:00 AM
Workorder
Sample Summary
WO#: 19051264
OS-Jun-19
Date Received Matrix
5/16/2019 10:20:00 AM Sludge
Page 4 of 35

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
EC;ti+li'iOtaMENTALTECHNOLLIGaE�75,.JKe. Cuyahoga Falls, Ohio44223
A na?y0cal Laboratones TEL: [phone] FAX:• [phone]
Website: htW.-Ilwww.settek.com
DATES REPORT
WO#: 19051264
OS-Jun-19
Client: Synagro
Project: ChenTville WWTP
Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date
19051264-001A Chenyville WWTP 5/14/2019 11:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 6/3/2019 5:55:23 PM
pH (SW9045D) 5/31/2019 3:40:31 PM
Reactive Cyanide (9014/7.3.3.2)-Solid 5/17/2019 8:10:00 PM
Reactive Sulfide (9034)/7.3.4.2 5/17/2019 8:10:00 PM
SVOC SW446: 8151 Herbicides-TCL5/18/2019 6:00:00 PM 5/24/2019 2:15:00 PM 6/1/2019 8:31:00 AM
TCLP Mercury Analysis (SW1311/7475/18/2019 6:00:00 PM 5/20/2019 2:35:00 PM 5/20/2019 6:58:00 PM
TCLP Metals Analysis (SW1311/6010:5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 8:27:03 PM
TCLP Metals Analysis (SW1311/6010:5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 4:04:46 PM
TCLP Pesticides Analysis (SW1311/8(5/18/2019 6:00:00 PM 5/24/2019 1:00:06 PM 5/31/2019 11:17:00 PM
TCLP Semi-Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 1:00:00 PM 5/21/2019 3:47:00 PM
(SW1311/8270)
TCLP Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 5:32:00 PM
Revision vl
Page 5 of 35

Sunvnit Environnaentnl Technologies, Inc. Analytical Report
3310 Win St.
Ft;tali'iQtdh7i=tJl'AL T[C}iNt7L[FC,,iES, ?N� Cuynhoga Falls, Ohio 44223 (base report)
- An�dyfiPra�f >' a5c+r�ta�rl�� TEL: [phone] FAX. [phone] WO#: 19051264
Website: http://ivrviv.settelc.cona Date Reported: 6/5/2019
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM
Lab ID: 19051264-OOlA
Project: Cherryville WWTP
Client Sample ID Cherryville WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW7470A SW7470A Analyst: DNS
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury ND 0.00500 mg/L 1 5/20/2019 6:58:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW6010D SW3010A Analyst: KMO
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM
TCLP Barium(Ba) ND 12.5 mg/L 1 5/22/2019 4:04:46 PM
TCLP Cadmium(Cd) ND 0.250 mg/L 1 5/22/2019 4:04:46 PM
TCLP Chromium(Cr) ND 0.500 mg/L 1 5/22/2019 4:04:46 PM
TCLP Lead(Pb) ND 1.25 mg/L 1 5/22/2019 8:27:03 PM
TCLP Selenium(Se) ND 0.125 mg/L 1 5/22/2019 4:04:46 PM
TCLP Silver(Ag) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8270 SW3510C Analyst: BJH
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM
2,4,5-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM
2,4,6-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM
2,4-Dinitrotoluene ND 0.0400 QC+ mg/L 2 5/21/2019 3:47:00 PM
Cresols, Total ND 4.00 mg/L 2 5/21/2019 3:47:00 PM
Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 5/21/2019 3:47:00 PM
Hexachlorobenzene ND 0.0400 mg/L 2 5/21/2019 3:47:00 PM
Hexachloroethane ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM
Nitrobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM
Pentachlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM
Pyridine ND 0.200 mg/L 2 5/21/2019 3:47:00 PM
Surr: 2-Fluorophenol 53.3 10 - 109 %Rec 2 5/21/2019 3:47:00 PM
Surr: Phenol-d6 64.7 10 - 109 %Rec 2 5/21/2019 3:47:00 PM
Surr: Nitrobenzene-d5 49.6 19 - 120 %Rec 2 5/21/2019 3:47:00 PM
Surr: 2,4,6-Tribromophenol 96.5 10 - 120 %Rec 2 5/21/2019 3:47:00 PM
Surr: 2-Fluorobiphenyl 49.4 22 - 117 %Rec 2 5/21/2019 3:47:00 PM
Surr: p-Terphenyl-d14 85.9 34 - 116 %Rec 2 5/21/2019 3:47:00 PM
Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response MC Value is below Minimum Compound Limit.
N Tentatively identified compounds ND Not Detected
O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits IZeVlSloll V 1
RL Reporting Detection Limit U Samples with CalcVal < MDL
Page 6 of 35

Sunznzit Environmental Technologies, Inc. Analytical Report
3310 Win St.
1_I4SzIPt�N1�1>=NTAL T,L-C±t�tt7l[ie;1FS, �N� Czryahoga Falls, Ohio 44223 (base report)
�trrifilrt�'ca1 ia5c��arot�d�s TEL: [phone] FAX.• [phone] WO#: 19051264
Website: http://rvwiv.settek.co�n Date Reported: 6/5/2019
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM
Lab ID: 19051264-OOlA
Project: Cherryville WWTP
Client Sample ID Cherryville WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8081 SW3510C Analyst: SFG
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total ND 0.0250 mg/L 10 5/31/2019 11:17:00 PM
Toxaphene ND 0.0500 mg/L 10 5/31/2019 11:17:00 PM
Endrin ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM
gamma-BHC ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM
Heptachlor ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM
Heptachlor epoxide ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM
Methoxychlor ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM
Surr: TCMX 61.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM
Surr: DCB 76.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8151A SW8151A Analyst: MES
SVOC SW-846: 8151 HERBICIDES-TCLP
2,4-D ND 0.0100 mg/L 1 6/1/2019 8:31:00 AM
2,4,5-TP ND 0.00500 mg/L 1 6/1/2019 8:31:00 AM
Surr: 2,4-Dichlorophenylacetic aci 70.8 20 - 140 %Rec 1 6/1/2019 8:31:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8260 Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
1,2-Dichloroethane ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
MEK ND 10.0 mg/L 100 5/20/2019 5:32:00 PM
Benzene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
Carbon tetrachloride ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
Chlorobenzene ND 5.00 mg/L 100 5/20/2019 5:32:00 PM
Chloroform ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
Tetrachloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
Trichloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM
Vinyl chloride ND 0.200 mg/L 100 5/20/2019 5:32:00 PM
Surr: 4-Bromofluorobenzene 102 70 - 130 %Rec 100 5/20/2019 5:32:00 PM
Surr: Dibromofluoromethane 96.7 70 - 130 %Rec 100 5/20/2019 5:32:00 PM
Surr: Toluene-d8 107 70 - 130 %Rec 100 5/20/2019 5:32:00 PM
Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response MC Value is below Minimum Compound Limit.
N Tentatively identified compounds ND Not Detected
O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RevlSlOri V 1
RL Reporting Detection Limit U Samples with Ca1cVa1 < MDL
Page 7 of 35

��
fN�llfrOtdr�li=NTAL PL�±-1�1CIlC}f;iF�, ihl�:
- t6rr�lyt/��! i�t+nrar��i�+fi
CLIENT: Synagro
Matrix: SLUDGE
Lab ID: 19051264-OOlA
Project: Cherryville WWTP
Client Sample ID Cherryville WWTP
Szmvnit Environmental Technologies, Lac.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
Analytical Deport
(base report)
WO#: 19051264
Yi%bsite: http:/hvivw.settek.cona Date Reported: 6/5/2019
Tag Number:
Collection Date: 5/14/2019 11:00:00 AM
Analyses Result RL Qual Units DF Date Analyzed
RCI-SOLID-W/ IGNITABILITY1030
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive
RCI-SOLID-W/ IGNITABILITY1030
IGNITABILITY OF SOLIDS (SW-846: 1030)
Ignitability
RCI-SOLID-W/ IGNITABILITY1030
PH (SW9045D)
pH
RCI-SOLID-W/ IGNITABILITY1030
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive
ND
nonflammable
7.1
ND
SW9014 Analyst: MS
0.476 mg/Kg 1 5/17/2019 8:10:00 PM
Qualifiers: E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit
RL Reporting Detection Limit
SW1030 Analyst: CXS
1 6/3/2019 5:55:23 PM
SW9045D Analyst: WK
s.u.@20.9C 1 5/31/2019 3:40:31 PM
SW9034 Analyst: MS
25.0 mg/Kg 1 5/17/2019 8:10:00 PM
H Holding times for preparation or analysis exceeded
MC Value is below Minimum Compound Limit.
ND Not Detected
P Second column confirmation exceeds
R RPD outside accepted recovery limits Revlsiori vl
U Samples with CalcVal < MDL
Page 8 of 35

Summit Environmental Technologies, Inc. Accreditation Program
3310 Win St. Analytes Report
ENVII10t4rolENTAL TE�CHN01 (IGIF ,, summint
Cuyahoga Falls, Ohio 44223
AnafyVcal taboratorlea TEL: [phone] FAX: [phone] WO#: 19051264
Website: http://Www.settek.com 054un49
Client: Synagro State: NW
Project: Cherryville WWTP Program Name: NC WW SCM
Sample ID Matrix Test Name Analyte Status
19051264-001A Sludge Ignitability of Solids (SW-846: 1030) Ignitability A
Sludge pH (SW9045D) Hydrogen Ion (pH) A
Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U
Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U
Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,435-TP A
Sludge SVOC SW-846: 8151 Herbicides-TCLP 254-D A
Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A
Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A
Sludge TCLP Metals Analysis (SW1311/6010) Barium A
Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A
Sludge TCLP Metals Analysis (SW1311/6010) Chromium A
Sludge TCLP Metals Analysis (SW1311/6010) Lead A
Sludge TCLP Metals Analysis (SW1311/6010) Selenium A
Sludge TCLP Metals Analysis (SW1311/6010) Silver A
Sludge TCLP Pesticides Analysis (SW13 11/808 1) Chlordane, total A
Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A
Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A
Sludge TCLP Pesticides Analysis (SW13 11/808 1) Methoxychlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A
Key Key
NC WW SCM A Accredited NC WW SCM U Unavailable
Version #3
Page 9 of 35

Summit Environmental Technologies, Inc. Accreditation ProgramSUMMIEF .
3310 Win St. Anal teS Report
hlriiiNfA�NTAL et tiri�e�tctrt=, tAtr Cuyahoga Falls, Ohio 44223 y p
Ajv�yVcar Laboratarla TEL: [phone] FAX.• [phone] WO#: 19051264
Website: hto2:llwww.settelc.coni 054"n49
Client: Synagro State: NW
Project: Cherryville WWTP Program Name: NC WW_SCM
Sample ID Matrix Test Name Analyte Status
19051264-001 A Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
Sludge
TCLP
Volatiles
Analysis
NC WW SCM A Accredited NC WW SCM U Unavailable
Page 10 of 35
1,1-Dichloroethene
Dichloroethane
2-Butanone
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Version #3

MM111 Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St,
ENVIRONMENTAL TECHC,YQLC9GIV%, INC Cuyahoga Falls, Ohio 44223 WO#: 19051264
Ana?y0c2l Laboratooe!5 TEL: [phone] FAX: [phone]
Website: http://www.settelc.com 05-Jun49
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051239-001AMS
SampType:
MS
Client ID:
BatchQC
Batch ID:
37518
Analyte
Result
TestCode:
MtI-TCLP-7(6
Units:
mg/L
TestNo:
SW6010D
SW3010A
PQL SPK value SPK Ref Val
BatchID: 37518
Prep Date: 5/20/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130
TCLP Barium(Ba) ND 5.00 2.000 0.2309 105 70 130
TCLP Cadmium(Cd) 2.04 0.100 2.000 0 102 70 130
TCLP Chromium(Cr) 2.16 0.200 2.000 0 108 70 130
TCLP Selenium(Se) 2.32 0.0500 2.000 0 116 70 130
TCLP Silver(Ag) 2.43 0.500 2.000 0.0007661 122 70 130
Sample ID 19051239-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L
Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A
Analyte
Result
PQL SPK value SPK Ref Val
RunNo: 98666
SegNo: 2124011
%RPD RPDLimit Qual
Prep Date: 5/20/2019 RunNo: 98666
Analysis Date: 5/22/2019 SegNo: 2124012
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)0.500 2.000 0 109 70 130 2.267 3.48 20
TCLP Barium(Ba) ND 5.00 2.000 0.2309 101 70 130 0 0 20
TCLP Cadmium(Ccl) 1.96 0.100 2.000 0 97.8 70 130 2.036 4.02 20
TCLP Chromium(Cr) 2.08 0.200 2.000 0 104 70 130 2.159 3.78 20
TCLP Selenium(Se) 2.24 0.0500 2.000 0 112 70 130 2.323 3.45 20
TCLP Silver(Ag) 2.34 0.500 2.000 0,0007661 117 70 130 2.432 3.95 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to detennine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 11 of 35

mmill Summit Environmental Technologies, Inc. QC SUMMARY REPORT
su3310 Win St.
ENIVI!IIONNIENTAL rECHNOLOGIFIfi, fd^ Cuyahoga Falls, Ohio44223
WO#: 19051264
Arra y0ical La-boralvrWs TEL: [phone] FAX.• [phone]
Website: http://www.settelc.com 054un49
Client: Synagro
Project: Cherryville WWTP
BatchID0 37518
Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666
Client ID: Batch= Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124063
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Lead(Pb)
2.16 0.500 2.000 0.01223 107 70 130
Sample ID
19051239-001AMSD
SampType:
MSD
Client ID:
Batch=
Batch ID:
37518
Analyte
TCLP Lead(Pb)
Result
TestCode:
Mtl-TCLP-7(6
Units:
mg/L
TestNo:
SW6010D
SW3010A
PQL SPK value SPK Ref Val
Prep Date: 5/20/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98666
SegNo: 2124064
%RPD RPDLimit Qual
2.16 0.500 2.000 0.01223 108 70 130 2.157 0.351 20
Qualifiers: B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 12 of 35

mmill Summit Environmental Technologies, Inc. QC SUMMARY REPORT
ffl su3310 Win St,
P NIVIRO.WMENTAL rECHNOLQGIrS,..W. Cuyahoga Falls, Ohio 44223
WO#: 19051264
ArijiyClcal Labcralories TEL: [phone] FAX.• [phone]
Website: http://www.settefc.com 054un49
Client: Synagro
Project: Cherryville WWTP
BatchID: 37518
Sample ID MB-37518 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499
Client ID: PBS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118254
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP
Arsenic(As)
ND
0.500
TCLP
Barium(Ba)
ND
5.00
TCLP
Cadmium(Cd)
ND
0.100
TCLP
Chromium(Cr)
ND
0.200
TCLP
Lead(Pb)
ND
0.500
TCLP
Selenium(Se)
ND
0.0500
TCLP
Silver(Ag)
ND
0.500
Sample ID LCS-37518 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499
Client ID: LCSS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118255
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) 2.11 0.500 2.000 0 105 80 120
TCLP Barium(Ba) ND 5.00 2.000 0 106 80 120
TCLP Cadmium(Cd) 1.95 0.100 2.000 0 97.3 80 120
TCLP Chromium(Cr) 2.19 0.200 2.000 0 110 80 120
TCLP Lead(Pb) 2.23 0.500 2.000 0 ill 80 120
TCLP Selenium(Se) 2.17 0.0500 2.000 0 108 80 120
TCLP Silver(Ag) 2.32 0.500 2.000 0 116 80 120
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 13 of 35

MMIT Summit Environmental Technologies, Inc. QC SUMMARY REPORT
'SU3310 Win St.
ENIVIPI 4filENTAL TECHNCLOG ls$„ IRC Cuyahoga Falls, Ohio 44223 WO#: 19051264
A.rrafyticaf tabaraltorles TEL: [phone] FAX.• [phone]
Website: htt42:llwww.settelc.com 05-Jun49
Client: Synagro
Project: Cherryville WWTP BatchID: 37523
TCLP Mercury ND 0.00200
TCLP Mercury 0.00397 0.00200 0.00400 0 99.2 80 120
TCLP Mercury 0.00435 0.00200 0.00400 0.0000500 108 75 125
TCLP Mercury 0.00439 0.00200 0.00400 0.0000500 108 75 125 0.00435 0.915 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal,
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision vl
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 14 of 35

MMIT Summit Environmental Technologies, Inc. QC SUMMARY REPORT
ffl SU3310 Win St.
EN,Vl' ONtilENJTALTcC9it' CLi. ,ir.',Non Cuyahoga Falls, Ohio44223
WO#: 19051264
A.r7j?y /ca.P LaboraltWes TEL: [phone] FAX: [phone]
Website: http:11www.settek.com 05 Jun-19
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051026-001AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
37523
Analyte
Result
TestCode: HG_TCLP(74 units: PPM
TestNo: SW7470A SW7470A
PQL SPK value SPK Ref Val
BatchID: 37523
Prep Date: 5/20/2019
Analysis Date: 5/20/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98535
SegNo: 2117849
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 15 of 35

11 MMI
Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SUn3310 Win St.
ENVITTOt,IMENTAL TECH OLOG-If:$,. MW'. Cuyahoga Falls, Ohio 44223
WO#: 19051264
ffl Anayyt/.cal La'bcraIDOes TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 054un-19
Client: Synagro
Project: Cherryville WWTP
BatchID0 37528
Sample ID 19051350-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606
Client ID: Batch= Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120533
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
QMR
1,4-DichlorobenL.. 0.282 0.0800 0.8000 0 35.3 33.8 126
2,4,5-Trichlorophenol 0.432 0.200 0.8000 0 54.0 28.7 144 QMR
2,4,6-Trichlorophenol 0.451 0.200 0.8000 0 56A 12.8 153 QMR
2,4-Dinitrotoluene 0.455 0.0400 0.8000 0 56.9 20A 155 QC+QMR
Cresols, Total ND 4.00 1.600 0 50.3 10 148 QMR
Hexachloro-1,3-butadiene 0.281 0.0160 0.8000 0 35.1 29 126 QMR
Hexachlorobenzene 0.352 0.0400 0.8000 0 44.0 33.7 134 QMR
Hexachloroethane 0.267 0.0800 0.8000 0 33.4 32.8 132 QMR
Nitrobenzene 0.358 0.0800 0.8000 0 44.8 20 158 QMR
Pentachlorophenol 0.473 0.200 0.8000 0 59.1 10 176
Pyridine 0.254 0.200 0.8000 0 31.7 10 130
Surr:2-Fluorophenol 0.404 1.000 40.4 3.39 130
Surr: Phenol-d6 0.457 1.000 45.7 5 130
Surr: Nitrobenzene-d5 0.344 1.000 34.4 14.5 154
Surr: 2,4,6-Tribromophenol 0.524 1.000 52.4 19.5 130
Sum 2-Fluorobiphenyl 0.350 1.000 35.0 34.4 130
Surr: p-Terphenykd14 0.539 1.000 53.9 8.86 156
Sample ID 19051350-001AMSD SampType: MSD
Client ID: Batch= Batch ID: 37528
Analyte
Result
TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606
TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120534
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 16 of 35

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
EN"Vi'iIOPJFi1ENTAL TcCHNOLOCilr:y, Wi Cuyahoga Falls, Ohio 44223
M1 Anatytleal Labaradtwr oq TEL: [phone] FAX: [phone]
Website: http://Www.settelc.com
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051350-001AMSD
SampType:
MSD
Client ID:
Batch=
Batch ID:
37528
Analyte
Result
TestCode: SVOC-BNA_T Units: mg/L
TestNo: SW8270 SW3510C
PQL SPK value SPK Ref Val
QC SUMMARY REPORT
WO#: 19051264
OS-Jun-19
BatchIDa 37528
Prep Date: 5/20/2019
Analysis Date: 5/21/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98606
SegNo: 2120534
%RPD RPDLimit Qual
1,4-Dichlorobenzene 0.402 0.0800 1.600 0 25.2 33.8 126 0.2824 35.0 30 RS
2,4,5-Trichlorophenol 0,625 0.200 1.600 0 39.1 28.7 144 0.4320 36.5 30 R
2,4,6-Trichlorophenol 0,634 0.200 1.600 0 39.6 12.8 153 0.4508 33.8 30 R
2,4-Dinitrotoluene 0,654 0.0400 1.600 0 40.9 20A 155 0.4548 35.9 30 RQC+
Cresols, Total ND 4,00 3.200 0 34.9 10 148 0 0 30 R
Hexachloro-1,3-butadiene 0.423 0,0160 1,600 0 26A 29 126 0,2808 40.5 30 RS
Hexachlorobenzene 0.498 0,0400 1.600 0 31.2 33.7 134 0.3520 34.4 30 RS
Hexachloroethane 0.374 0,0800 1,600 0 23.4 32.8 132 0,2668 33.6 30 RS
Nitrobenzene 0,513 0,0800 1.600 0 32.1 20 158 0.3580 35.6 30 R
Pentachlorophenol 0.607 0.200 1.600 0 37.9 10 176 0.4728 24.8 30
Pyridine 0,312 0,200 1.600 0 19.5 10 130 0,2536 20.5 30
Surr:2-Fluorophenol 0,590 2.000 29.5 3.39 130 0
Surr: Phenokc16 0.646 2.000 32.3 10 130 0
Surr: Nitrobenzene-d5 0.500 2,000 25.0 14.5 154 0
Surr: 2,4,6-Tribromophenol 0.776 2.000 38.8 19.5 130 0
Surr:2-Fluorobiphenyl 0.507 2.000 25.4 34.4 130 0 S
Surr: p-Terphenyl-d14 0.754 2,000 37.7 8.86 156 0
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
O RSD is greater than RSDlimit
R RPD outside accepted recovery limits
H Holding times for preparation or anal
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Revision vl
Page 17 of 35

SUMMIT Summit Environmental Technologies, Inc.
ffl 3310 Win St,
ENVI IONNIENTAL TECtu'L` QLOGItrSt INC Cuyahoga Falls, Ohio 44223
An ?ydicaf Laborefiones TEL: [phone] FAX: [phone]
Website: httr://www.settelc.com
Client: Synagro
Project: Cherryville WWTP
Sample ID
MB-37528
SampType:
MBLK
Client ID:
PBS
Batch ID:
37528
Analyte Result
TestCode: SVOC-BNA_T Units: mg/L
TestNo: SW8270 SW3510C
PQL SPK value SPK Ref Val
1,4-Dichlorobenzene ND 0.0400
2,4,5-Trichlorophenol ND 0.100
2,4,6-Trichlorophenol ND 0.100
2,4-Dinitrotoluene ND 0.0200
Cresols, Total ND 2.00
Hexachloro-1,3-butadiene ND 0,00800
Hexachlorobenzene ND 0.0200
Hexachloroethane ND 0.0400
Nitrobenzene ND 0.0400
Pentachloro phenol ND 0.100
Pyridine ND 0.100
Sum 2-Fluorophenol 0.486
Surr: Phenol-d6 0.605
Sum Nitrobenzene-d5 0.501
Sum 2,4,6-Tribromophenol 0.585
Surr: 2-Fluorobiphenyl 0.566
Sum p-Terphenykd14 0.676
QC SUMMARY REPORT
WO#: 19051264
OS-Jnn-l9
BatchID: 37528
Prep Date: 5/20/2019
Analysis Date: 5/21/2019
%REC LowLimit HighLimit RPD Ref Val
1.000
48.6
10
109
1.000
60.5
10
109
1.000
50.1
19
120
1.000
58.5
10
120
1.000
56.6
22
117
1.000
67.6
34
116
Sample ID LCS-37528 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019
Client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
RunNo: 98559
SegNo: 2119054
%RPD RPDLimit Qual
RunNo: 98559
SegNo: 2119055
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anab
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 18 of 35

Summit Environmental Technologies, Inc.
ffISUMMqEF 3310 Win St,
ENVI1tONMENTAL trltCMOLOGi-' Cuyahoga Falls, Ohio44223
Aryalytlt:al Laboral-ones TEL: [phone] FAX: [phone]
Website: httl2:llwww.settelc.com
Client: Synagro
Project: Cherryville WWTP
QC SUMMARY REPORT
WO#: 19051264
OS-Jun-19
BatchID: 37528
Sample ID LCS-37528 Samp I ype: LCS Testuode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019
Client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
1,4-Dichlorobenzene 0.409 0.0400 0.8000 0 51.2 36.4 130
2,4,5-Trichlorophenol 0.571 0.100 0.8000 0 71.4 31.7 132
2,4,6-Trichlorophenol 0.570 0.100 0.8000 0 71.2 31.1 133
2,4-Dinitrotoluene 0.568 0.0200 0.8000 0 71.0 43.3 130
Cresols, Total ND 2000 1.600 0 65.2 31.7 130
Hexachloro-1,3-butadiene 0.403 0.00800 0.8000 0 50A 31.4 130
Hexachlorobenzene 0.528 0.0200 0.8000 0 66.0 43.1 130
Hexachloroethane 0.396 0.0400 0.8000 0 49.5 36.5 130
Nitrobenzene 0.499 0.0400 0.8000 0 62A 39.5 130
Pentachlorophenol 0.518 0.100 0.8000 0 64.8 34 130
Pyridine 0.138 0.100 0.8000 0 17.3 10 130
Surr: 2-Fluorophenol 0.604 1.000 60.4 17.1 130
Sum. Phenokd6 0.648 1.000 64.8 10 130
Surr: Nitrobenzene-d5 0.615 1.000 61.5 32.6 130
Sum 2,4,6-Tribromophenol 0.714 1.000 71 A 4.43 130
Sum 2-Fluorobiphenyl 0.621 1.000 62A 41.8 130
Sum p-Terphenyl-d14 0.814 1.000 81.4 36A 130
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
0 RSD is greater than RSDlimit
R RPD outside accepted recovery limits
RunNo: 98559
SegNo: 2119055
%RPD RPDLimit Qual
H Holding times for preparation or anal
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
m
Revision vl
Page 19 of 35

Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SUMMIT 3310 Win St.
E@NVInONMENTAL rECHNOS OG .QS,;NC Cuyahoga Falls, Ohio 44223
+� n31'rr/Gc'Y.P i�rlNnradotl�+s WO#: 19051264
TEL: [phone] FAX.• (330) 2534489
Website: htW://www.settelc.com 054un49
Client: Synagro
Project: Cherryville WWTP
BatchID0 37600
Sample ID M13-37600 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799
Client ID: PBS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142057
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total ND 0.00250
Toxaphene ND 0,00500
Endrin ND 0,000500
gamma-BHC ND 0,000500 d
Heptachlor ND 0.000500 d
Heptachlor epoxide ND 0,000500 d
Methoxychlor ND 0,000500 d
Surr: TCMX 9.56 20.00 47.8 10 119
Surr: DCB 16.6 20.00 82.9 10 119
Sample ID LCS-37600 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799
Client ID: LCSS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142058
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Endrin 0.0101 0.000500 0.0100 0 101 20 216
gamma-BHC 0.00768 0.000500 0.0100 0 76.8 20 197
Heptachlor 0,00679 0,000500 0.0100 0 67.9 20 200
Heptachlor epoxide 0,00803 0.000500 0.0100 0 80.3 20 200
Methoxychlor 0,00978 0.000500 0.0100 0 97.8 20 227
Surr: TCMX 11.5 20.00 57.5 20 143
Surr: DCB 18.7 20.00 93.5 20 151
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision vl
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 20 of 35

fflmmill Summit Environmental Technologies, Inc. QC SUMMARY REPORT
su3310 Win St.
ENVIP ON MENTAL TEcHNCST_OG15_S 'IW%, Cuyahoga Falls, Ohio 44223
A rratyrical taborat000�- TEL: [phone] FAX: [phone] WO#: 19051264
Website: http://Www.settek.com 05-Jun-19
Client: Synagro
Project: Cherryville WWTP
BatchID4 37650
Sample ID MB-37650 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034
Client ID: PBS Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141487
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[
2,4-D ND 0.0100 0 0 d
27415-TP ND 0.00500 0 0 d
Surr: DCAA 253 500.0 50.6 20 140
Sample ID LCS-37650 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034
Client ID: LCSS Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141488
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
214-D 0.406 0.0100 0.500 0 81.2 43.8 130
21415-TP 0.413 0,00500 0.500 0 82.6 51.5 ill
Surr: DCAA 597 500.0 119 34.2 150
Sample ID LCSD-37650 SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034
Client ID: LCSS02 Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141489
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
214-D 0.408 0.0100 0.500 0 81.6 43.8 130 0.406 0.589 30
21415-TP 0.428 0.00500 0.500 0 85.5 51.5 130 0.413 3.54 30
Surr: DCAA 292 500.0 58.3 34.2 150 0
Qualifiers: B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 21 of 35

ffISUMM111
A r Myr.r`c.a1 LabcraIones
Summit Environmental Technologies, Inc.
3310 Win St,
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX: [phone]
Website: http://www.settelc.com
QC SUMMARY REPORT
WO#: 19051264
OS-Jun-19
Client: Synagro
Project: Chenyville WWTP BatchID: R98525
Sample ID LCS-98525 SampType: LCS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525
Client ID: LCSW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117453
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 70 138
1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 70 130
MEK 0.0961 0.0250 0.100 0 96.1 70 130
Benzene 0.0192 0,00500 0.0200 0 96.0 10 199
Carbon tetrachloride 0.0195 0.00500 0.0200 0 97A 21.3 240
Chlorobenzene 0.0190 0.00500 0.0200 0 94.8 70 132
Chloroform 0.0193 0,00500 0.0200 0 96.5 70 130
Tetrachloroethene 0.0184 0,00500 0.0200 0 92.2 10 130
Trichloroethene 0.0193 0,00500 0.0200 0 96.6 70 130
Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 70 130
Surr:4-Bromofluorobenzene 50.8 50.00 102 70 130
Surr: Di bromofl uorom ethane 47.6 50.00 95.2 70 130
Surr: Toluene-d8 54.2 50.00 108 70 130
Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525
Client ID: PBW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117457
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene ND 0.00500
I2-Dichloroethane ND 0.00500
MEK ND 0.0250
Benzene ND 0,00500
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
0 RSD is greater than RSDlimit
R RPD outside accepted recovery limits
H Holding times for preparation or anab
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Revision vl
Page 22 of 35

Lmmill
Summit Environmental Technologies, Inc. QC SUMMARY REPORT
su3310 Win St,
ENVIi OPAIENTAL TEChN0L0n1 ,. NC Cuyahoga Falls, Ohio 44223 ffld.njrydcaf Laborationes FAX. TEL: [phone] • [phone] WO#: 19051264
Website: http://Www.settek.com 054un.19
Client: Synagro
Project: Cherryville WWTP
Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L
Client ID: PBW Batch ID: R98525 TestNo: SW8260
Analyte Result PQL SPK value SPK Ref Val
Carbon tetrachloride ND 0.00500
Chlorobenzene ND 0.00500
Chloroform ND 0,00500
Tetrachloroethene ND 0.00500
Trichloroethene ND 0.00500
Vinyl chloride ND 0.00200
Surr: 4-Bromofluorobenzene 50.3
Surr: Dibromof[ uoromethane 47.4
Surr: Toluene-d8 54.0
BatchID0 R98525
Prep Date:
Analysis Date: 5/20/2019
%REC LowLimit HighLimit RPD Ref Val
50.00
101
70 130
50.00
94.9
70 130
50.00
108
70 130
RunNo: 98525
SegNo: 2117457
%RPD RPDLimit Qual
Sample ID 19051144-001aMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525
Client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 0.131 0.0500 0.200 0 65.3 63.8 148
1,2-Dichloroethane 0.170 0.0500 0.200 0 85.0 70 130
MEK 0.943 0.250 1.00 0 94.3 10 130
Benzene 0.727 0.0500 0.200 0.547 89.9 70 130
Carbon tetrachloride 0.142 0.0500 0.200 0 71.0 70 130
Chlorobenzene 0.173 0.0500 0.200 0 86.2 70 130
Chloroform 0.180 0.0500 0.200 0 90.2 70 130
Tetrachloroethene 0.142 0.0500 0.200 0 70.8 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal,
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision V 1
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 23 of 35

ffl11 Summit Environmental Technologies, Inc. QC SUMMARY REPORT
um"MRIL 3310 Win St,
E[NWiillOr ` �t o Cuyahoga Falls, Ohio 44223
ArPatyr;caf taboralorws TEL: [phone] FAX.- [phone] WO#: 19051264
Website: http://Www.settek.com 05~Jun49
Client: Synagro
Project: Cherryville WWTP
BatchID0 R98525
Sample ID 19051144-001aMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525
Client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Trichloroethene 0.167 0.0500 0.200 0 83.7 70 130
Vinyl chloride 0.138 0.0200 0.200 0 69.2 53.9 141
Surr: 4-Bromofluorobenzene 507 500.0 101 70 130
Surr: Dibromofluoromethane 471 500.0 94.2 70 130
Surr: Toluene-d8 544 500.0 109 70 130
Sample ID
19051144-001aMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98525
Analyte
Result
TestCode: voc-mstr_np Units: mg/L
TestNo: SW8260
PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 5/21/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98525
SegNo: 2119584
%RPD RPDLimit Qual
1,1-Dichloroethene 0.144 0.0500 0.200 0 72.0 63.8 148 0.131 9.83 30
1,2-Dichloroethane 0.174 0.0500 0.200 0 87.2 70 130 0.170 2.61 25
MEK 0.927 0.250 1.00 0 92.7 10 130 0.943 1.69 25
Benzene 0.716 0.0500 0.200 0.547 84.6 70 130 0.727 1.48 30
Carbon tetrachloride 0.157 0.0500 0.200 0 78.4 70 130 0.142 9.91 25
Chlorobenzene 0.176 0.0500 0.200 0 88.2 70 130 .0.173 2.29 30
Chloroform 0.182 0.0500 0.200 0 91 A 70 130 0.180 0.883 25
Tetrachloroethene 0.154 0.0500 0.200 0 77.0 70 130 0.142 8.25 25
Trichloroethene 0.174 0.0500 0.200 0 87.2 70 130 0.167 4.10 30
Vinyl chloride 0.134 0.0200 0.200 0 66.8 53.9 141 0.138 3.60 25
Surr:4-Bromofluorobenzene 510 500.0 102 70 130 0 25
Surr: Di bromofl uorom ethane 468 500.0 93.7 70 130 0 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision V 1
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 24 of 35

MM111 Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St,
ENVItIO-NNIENTAL TECHNOLOGosS, 4w Cuyahoga Falls, Ohio 44223
WO#: 19051264
Ar?Myticaf Laboratar)L+s TEL: [phone] FAX: [phone]
Website: htW:Ilwww.settek.com 05-Jun49
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051144-001aMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98525
Analyte
Surr: Toluene-d8
Result
547
Testuode: voc-mstr_np units. mg/L
TestNo: SW8260
PQL SPK value SPK Ref Val
500.0
BatchID0 R98525
Prep Date:
Analysis Date: 5/21/2019
%REC LowLimit HighLimit RPD Ref Val
109 70 130
RunNo: 98525
SegNo: 2119584
%RPD RPDLimit Qual
0 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 25 of 35

�� � � Summit Environmental Technologies, Inc.
ffl 3310 Win St,
EN4VI!tiOhJMEMTAL4cChj%40LGG173,'W7 Cuyahoga Falls, Ohio44223
.4w(yOcal Laboratorles TEL: [phone] FAX: [phone]
Website: http://www.settek.com
Client: Synagro
Project: Cherryville WWTP
QC SUMMARY REPORT
BatchIDa R98525
WO#: 19051264
OS-Jun-19
Sample ID LCS-98525 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98525
Client ID: LCSS Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2119592
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-Bromofluorobenzene
Surr: Dibromofluoromethane
Surr: Toluene-d8
0.0167
0.00500
0.0200
0
83.7
79.4
131
0.0178
0,00500
0.0200
0
89.2
73.6
137
ND
0.100
0.100
0
96.1
55.1
163
0.0192
0.00500
0.0200
0
96.0
73.1
132
0.0195
0.00500
0.0200
0
97.4
63.7
139
ND
0.0500
0.0200
0
94.8
72.3
139
%
0.0193
0.00500
0.0200
0
96.5
79.3
129
0.0184
0,00500
0.0200
0
92.2
56.2
187
0.0193
0.00500
0.0200
0
96.6
64.1
138
0.0189
0,00200
0.0200
0
94.3
22.1
147
50.8
50.00
102
80.4
126
47.6
50.00
95.2
70.3
125
54.2
50.00
108
82
117
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 26 of 35

I
Summit Environmental Technologies, Inc. QC SUMMARY REPORT
IS U MM3310 Win St.
ENNVIROtJNIENTALTTrcG9-iNOLOGtR ,.W.. Cuyahoga Falls, Ohio44223
WO#: 19051264
.4.nalyUCar' Labcralorde!g TEL: [phone] FAX.• [phone]
Website: http://www.settelc.com 054un49
Client: Synagro
Project: Cherryville WWTP BatchID: R98750
Cyanide, Reactive ND 0.485
Cyanide, Reactive 9.43 0.490 10.00 0 94.3 85 115
Cyanide, Reactive 0.524 0.490 0.5000 0 105 50 150
Cyanide, Reactive 10.0 0.500 10.00 0.3081 97.3 81.3 118
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision V 1
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 27 of 35

mmill Summit Environmental Technologies, Inc. QC SUMMARY REPORT
su3310 Win St.
tENVItCONNIENTA,L TECHNOLOQIE:5,. WF !, Cuyahoga Falls, Ohio 44223 fflt�,rrzFtyr; aI Laborat-ones TEL: [phone] FAX* [phone] WO#: 19051264
Website: http://Www.settelc.com 054un49
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051158-011AMS
SampType:
MS
Client ID:
Batch=
Batch ID:
R98750
Analyte
Result
Sample ID
19051158-011AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98750
Analyte
Cyanide, Reactive
Result
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
PQL SPK value SPK Ref Val
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
PQL SPK value SPK Ref Val
BatchID 6 R98750
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98750
SegNo: 2129319
%RPD RPDLimit Qual
RunNo: 98750
SegNo: 2129320
%RPD RPDLimit Qual
10.2 0.500 10.00 0.3081 98.7 81.3 118 10.04 1.39 5
Qualii►ers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 28 of 35

MMIT
Summit Environmental Technologies, Inc. QC SUMMARY REPORT
ffISU3310 Win St.
EN•4'Iti IAIENTAL TZChN0L17oG1zS,. JKC, Cuyahoga Falls, Ohio 44223 WO#: 19051264
Arm. yi9ca1 Lab ratortes TEL: [phone] FAX.• [phone]
Website: ham://Www.settek.com 05 Jun49
Client: Synagro
Project: Cherryville WWTP BatchID: R98776
Sulfide, Reactive ND 25.0
Sulfide, Reactive 4560 25.0 4800 0 95.0 85 115
Sulfide, Reactive 4720 25.0 4800 0 98.3 75 125
Sulfide, Reactive 4680 25.0 4800 0 97.5 75 125 4720 0.851 30
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal,
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision V 1
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 29 of 35

MM111 Summit Environmental Technologies, Inc. QC SUMMARY REPORT
ffl SU3310 Win St.
ENVIRONMENTAL T`rCHNQWGlr$,, IW" Cuyahoga Falls, Ohio 44223
WO#: 19051264
Arr&Pytical Labcraljooas TEL: [phone] FAX.- [phone]
Website: htt2://www.settelc.com 05-Jun49
Client: Synagro
Project: Cherryville WWTP
Sample ID
19051158-011AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98776
Analyte
Result
TestCode: Sulfide,React Units: mg/L
TestNo: SW9034
PQL SPK value SPK Ref Val
BatchID: R98776
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98776
SegNo: 2130210
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 30 of 35

111
Summit Environmental Technologies, Inc. QC SUMMARY REPORT
ffl SUMM3310 Win St,
EWI4' ONNIEWAL TTECHNOLOGIERI. NC, Cuyahoga Falls, Ohio 44223
WO#: 19051264
A r+atyt}cal Laboralt)rles TEL: [phone] FAX.• [phone]
Website: httn://Www.settek.com 05-Jun49
Client: Synagro
Project. Cherryville WWTP
Sample ID LCS-R98995
Client ID: LCSS
Analyte
pH
Sample ID CHECK 7
Client ID: LCSS
Analyte
pH
SampType: LCS
Batch ID: R98995
Result
7.0
SampType: LCS
Batch ID: R98995
Result
7.0
BatchIDa R98995
TestCode: pH_S(9045D) Units: s.u.@22.00 Prep Date: RunNo: 98995
TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2139142
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
7.0
0 100 90 110
TestCode: pH_S(9045D) Units: s.u.@22.3C
TestNo: SW9045D
Prep Date:
Analysis Date: 5/31/2019
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
7.0
0 101 90 110
%RPD RPDLimit Qual
RunNo: 98995
SegNo: 2140377
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 31 of 35

MMITSummit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
lEN 1110MAENTAL TECHNOLOM�rS, Ifir, Cuyahoga Falls, Ohio 44223
WO#: 19051264
krfa?y9ca� La-boralc nes TEL: [phone] FAX.- [phone]
Website: htW:Ilwww.settek.com 054un49
Client: Synagro
Project: Cherryville WWTP
Sample ID
19052000-0016DUP
SampType:
DUP
Client ID:
BatchQC
Batch ID:
R98995
Analyte
pH
Result
6.9
BatchID 0 R98995
TestCode: pH_NPW(450 Units: s.u.@20.3C Prep Date: RunNo: 98995
TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2140375
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 32 of 35

mmill Summit Environmental Technologies, Inc. QC SUMMARY REPORT
su3310 Win St,
EAVl'i OtAIENITAL TErCHdNOLOGIr$, ! 7 Cuyahoga Falls, Ohio 44223 WO#: 19051264
ffl r .raMyflt aP taboratorles TEL: [phone] FAX.- [phone]
Website: http://Www.settek.com 054un49
Client: Synagro
Project: Cherryville WWTP
Sample ID LCS-R99073
Client ID: LCSS
Analyte
Ignitability
SampType: LCS
Batch ID: R99073
Result
7.94
TestCode: Ignitability_S Units:
TestNo: SW1030
PQL SPK value SPK Ref Val
7.240
BatchID0 R99073
Prep Date:
Analysis Date: 6/3/2019
%REC LowLimit HighLimit RPD Ref Val
0 110 70 130
RunNo: 99073
SegNo: 2142958
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 33 of 35

Summit Environmental Technot 'es, Inc,
��
I I
14
Received 'M lab kyp
Date
_
rin
�{
Rush i ca sa+# d 11
Mot b 1p*pTLAVd
y
p y
�1n
(/�
b h1Pa tnana4 v,t'
4�+llmdws�aaadyc#p,;nta Styr°csb�rtrlaT;�rc�usapa�sy aas�rtlro�uc 64rLhrc; [wthllras�3rg. C°�a ,daagri ra,°pa�iti_,
ar4
IIr81Itlwb IIllA
Ott '1l 1A II IDk1 i) I h i I Nid�
t!
. i ci,lli
Page 34 of 35

' � Suaavnit Enviromaaental Technologies, b7c.
3310 i�Vin St.
t=NVllyd}Pub�NTaL irECHtv[�1.+]Gir=�, tFte Cuyahoga Falls, Ohio 44223
Anatyfic�i Cabc+.rstbrtr�s TEL: [phone] FAX.• [phone]
Website: Latin://www. settek. cons
Client Name: SYN-NC-27028
Logged by: Kayla L. Oulton
Completed By: Jesseca E. Westfall
Reviewed By: Jennifer Woolf
Work Order Number: 19051264
5/16/2019 10:20:00 AM
5/16/2019 5:34:18 PM
5/17/2019 3:21:16 PM
Sample Log -In Check List
RcptNo: 1
�4��
.� ��'
Chain of Custody
1, Is Chain of Custody complete? Yes �/❑ No ❑ Not Present ❑
2, How was the sample delivered? UPS
Loq In
3. Coolers are present? Yes ❑� No ❑ NA ❑
4. Shipping container/cooler in good condition? Yes � No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑�
No. Seal Date: Signed By:
5, Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C Yes � No ❑ NA ❑
7, Sample(s) in proper container(s)? Yes � No ❑
$. Sufficient sample volume for indicated test(s)? Yes � No ❑
g. Are samples (except VOA and ONG) properly preserved? Yes ❑� No ❑
10. Was preservative added to bottles? Yes ❑ No 0 NA ❑
11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑�
12. Were any sample containers received broken? Yes ❑ No❑
13. Does paperwork match bottle labels? Yes � No ❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody? Yes ❑� No ❑
15. Is it clear what analyses were requested? Yes 0 No ❑
16. Were all holding times able to be met? Yes 0 No ❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA ❑�
18, Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
Seal No
Seal Date Signed By
1
4.6
Good
Not Present
Page 35 of 35

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Cherryville
WWTP Name: City of Cherryville WWTP
WQ Permit Number: W00000430
NI Number: NCO044440
Monitoring Period: From Jan 1, 2019 To Dec 31, 2019
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization
Anaerobic Digestion
Air Drying
Composting
Aerobic Digestion
Tf annlirahle to alternative nerfnrmed (('.lace A nr C'lacc Rl cmm�lete the fnllnwinu monitnrinu data:
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dances
Analysis
Fecal
2x10tothe 6`h
MPN
<1156
<1775
<2381
MPN/g
0
Annual
Grab
SM9221C
Coliform
power per gram
E-2006
of total solids
CFU/g
CFU
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
colifonn
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt. 1
(VS reduction)
Option/Alt. 5
(14-Day Aerobic)
Option/Alt. 9
(Infection)
(40-day bench)
Option/Alt. 2
Option/Alt. 6
(Alk Stabilization)
Option/Alt. 10
(Incorporation)
CERTIFICATION STATEMENT (please check the appropriate statement)
(30-day bench) X
Option/Alt. 3
Option/Alt, 7
(Drying — Stable)
(Spec.
Option/Alt. 4
02 uptake)
Option/Alt. 8
(Drying — Unstable)
were performed
No vector attraction reduction alternatives
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that Lite pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
expIanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the athogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification inc ding fine and0prisonment.55
�`
Larry WriL)ht, Plant ORC & Plant Superintendent �C /C`�X
Name and Titl e or rint) Land A 1' r Name and Title (if applicable) (Type or print)
z^ 7- zo 2a
of eparer* Date Signature of and Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Analytical Results
Synagro
284 Boger Rd.
Mocksville, NC 27028
Receive Date: 05/14/2019
Reported: 05/15/2019
For: Cherryville WWTP
Comments: Geometric Mean: <1775 MPN/g
TATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
190514-37-01 Fecal Coliforms 1 <2381 MPN/g SM92210E-20W 05114/2019 CL
190514-37-01 Percent Solids 1 0.84 % SM2540B-2011 05/14/2019 CL
190514-3M2 Fecal Coliforms 2 <1515 MPN/g SM92210E-2006 05/14/2019 CL
190514-37-02 Percent Solids 2 1.32 % SM2540B-2011 05/14/2019 CL
190514-37-03 Fecal Coliforms 3 <1961 MPN/g SM92210E-2WB 05/14/2019 CL
190514-37-03 Percent Solids 3 1402 % sM254OB-2011 05/14/2019 CL
190514-37-04 Fecal Coliforms 4 <1156 MPN/g SM92210E-2006 05/14/2019 CL
190514-37-04 Percent Solids 4 1,73 % SM25406-2011 05/14/2019 CL
190514-37-05 Fecal Coliforms 5 <1905 MPN/g SM92210E-2006 05/14/2019 CL
190514-37-05 Percent Solids 5 1.05 % SM2540B-2011 06/14/2019 CL
190514-37-06 Fecal Coliforms 6 <2105 MPN/g SM92210E-2006 05/14/2019 CL
190514-37-06 Percent Solids 6 0.95 % SM25409-2011 05/14/2019 CL
190514-37-07 Fecal Coliforms 7 <1695 MPN/g SM92210E-2006 05/14/2019 CL
190514-37-07 Percent Solids 7 1018 % SM2540B-2011 05/14/2019 CL
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 190514-37-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecai Conforms
Sodium Thiosulfate Received on Ice
Sample Number 190514-37-02 Temp on Arrival: 2.3
Parame#er Schedule: Percent Solids
Received on ice
Parameter Schedule: Fecal Conforms
Sodium Thiosulfate Received an ice
Sample Number 190514-37-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: FecaE Conforms
Sodium Thiosulfate Received on Ice
Sample Number 190514-37-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecai Conforms
Sodium Thiosulfate Received on Ice
Sample Number 190514-37-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecai Conforms
Sodium Thiosulfate Received on Ice
Sample Number 190514-37-06 Temp on Arrival: 2.3
PO Box 228 •5tatesvilie, NC 28687 • 704/872/4697
k'age 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Conforms
Sodium Thiosulfate Received on Ice
Sample Number 190514-37-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Colforms
Sodium Thiosulfate Received on Ice
PQ Box 228 •Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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284 Boger Rd.
Mocksville, NC 27028
Receive Date:
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Analytical Results
05/14/2019
06/12l2019
Cherryville WWTP
"TATESVILLE
ANALYTICAL
Sample Number parameter Sample ID Result Unit Method Analyzed Analyst
190514-3&01 30 Day Benchscale Cherryville
Respectfully submitted,
Dena Myers
NC Cert "401
NCDW Cert #37755,
EPA #NC00909
9.7
EPA625-R-92/0 05/14/2019 WC
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of 2

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Analytical Results
Synagro
Entered: 05-14-2019
Reported: 0644-2019
Sample ID: 190514-38-01
For: Cherryville
PARAMETER: Vector Attraction Reduction/Aerobically Digested Sludge (30day)
Total Solids Volatile Solids %Volatile Solids
Week 1 2.95
Week 2 2.79 1.37 0.4894
Week 3 2.96 .1.47 0.4924
Week 4 2.80 1.35 0.4814
Week 5 1.83 0.90 0.4916
Volatile Solids Reduction: 0.5172 - 0.4916 X 100 = 9.7%
0.5172 - (0.5172X 0.4916)
Respectfully submitted,
Dena Myers
Statesville Analytical, Inc.
NC WW Cert.# 440NC
DW Cert. #37755

Agricultural Lime Application Log
Year: 2019
Project: Cherayville
Field
(state -county -site -field)
Soil
pH
(from
Lime Requirement
soil analysis)
I ons/Acre
Applied(CCE Eq.)
Date Applied
LT-107-3
4.8
1.3 T/Ac.
1.3T/Ac
11/15/19

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY20-SL004614
Predictive
Soil Report Mehlich-3 Extraction
Helpful Information
Sampled: Received: 09/12/2019 Completed: 09/21/2019 Farm: NC-Lt-107
Client: Calvin (John) Wehunt
2385 Norman Parker
Cherryville, NC 28021
Sampled County : Lincoln
Client ID: 324632
Advisor: Alex Fox
Synagro
284 Boger Rd
Mocksville, NC 27028
Advisor ID: 501947
Sample ID: 03 Recommendations: Lime Nutrients (lb/acre) More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information
Lime History: 1 -Sudan/Sorghum past. 1.3 140-180 70 70 0 0 0 0 0 0 Note: 12
2 - 0.0
Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral
HM% W/V CEC BS% Ac pH P4 K-I Ca% Mg% S-I Mn-I Mn-A11 Mn-Al2 Zn4 Zn-AI Cu-1 Na ESP SS -I NO3-N
0.22 1.07 3.7 46 2.0 4.8 28 63 27 11 215 45 44 35 35 87 0.0
i+l1:i�:a � �''fr�ns4 I� iaiw.l � r�aFriuo�wic��ro
Reprogramming of the laboratory -information -management system that makes this report possible is"being funded
through a grant from the North Carolina Tobacco Trust Fund Commission..
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY20-SL004614
Calvin (John) Wehunt Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Lime
If testing finds that soil pH is too low for the crop(s) indicated, a time recommendation will be given in units of either
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 lb/1000 sq ft) at
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full r
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Fertilizer
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
for the crop being grown, not on soil test results. K4 and P-I values are based on test results and should be > 50. If they
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend witl usually satisfy crop needs, SS4 levels appear
only on reports for greenhouse soil or problem samples.
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
ncagr.gov/agronomi/pubs.ht
exact
Report Abbreviations
Ac exchangeable acidity
B boron
BS% % CEC occupied by basic cations
Ca% % CEC occupied by calcium
CEC cation exchange capacity
Cu-I copper index
ESP exchangeable sodium percent
HM% percent humic matter
K-I potassium index
Kz0 potash
Mg % CEC occupied by magnesium
MIN mineral soil class
Mn manganese
Mn-A11 Mn-availability index for crop 1
Mn-A
Mn-I
12 Mn-availability index for crop 2
manganese index
M-O , mineral -organic soil class
N nitrogen
Na sodium
NOs-N
nitrate nitrogen
ORG
organic soil class
pH
current soil pH
P-I
phosphorus index
PzOs
phosphate
S-1
sulfur index
Test Results SS -I soluble salt index
WN weight per volume
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-A1 zinc availability index
Zn-I zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-Al, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-1\1 (not routine)
available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncapr.aov/agronomi/uMt.htm