WQ0031314_Residual Annual Report 2014_20150227

Utilities Administration
Winston-Salem • Forsyth County
City of Winston-Salem • P.O. Box 2511 • Winston-Salem, NC 27102 • CiryLink 311 (336-727.8000) • Fax [phone] • rarmuriryofws org
Ut1�It1eS
Water • Sewer- Solid Waste Disposal February 25, 2015
To: NC DENR-Division of Water Quality
Aquifer Protection Section -Land Application Section
1636 Mail Service Center
Raleigh, NC 27699-1636
Subject: 2014 Residuals Application Annual Report T
Permit No. WQ0031314
Swann Water Treatment Plant RECEIVE®IDENR OWR i
Thomas Water Treatment Plant
Neilson Water Treatment F 2.7 WK
Dear Sirs,
Perm6Qt9 j Section
Enclosed are three copies of the Residuals Application Annual Report and supporting
documentation for the Swann, Thomas and Neilson Water Treatment Plants.
Swann Water Treatment Plant
The Swann Plant was in compliance with all parameters of its permit during the 2014 calendar year.
The Swann Water Treatment Plant operates one equalization basin and two residuals lagoons -and
produces a Class A Residual which is 503 exempt. Residuals are generated .by backwash produced
by' filter washes and automated sludge removal from the plant's sedimentation basins. The lagoons
are operated in a manner that allows one lagoon to accept residuals while the other lagoon is drying.
Attached with this correspondence are the following for the Swann WTP:
• Three copies of the followingreports:
DENR Form DMSDF=Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form.
✓ DENR Form RSSF-Annual Residual Sampling Summary Form
✓ DENR Form-RSSF-B Annual Residual Sampling Summary Form .
✓ Lab Data Sheets
✓ DENR Form-PVRF 02T Annual Pathogen and Vector Attraction Reduction Form (02T
Rules)
✓ Lab Data Sheets
✓ Maps of the residuals disposal sites
Thomas Water Treatment Plant
The Thomas Water,Treatment Plant operates one equalization basin, one residuals clarifier, and
two residuals lagoons. that produces a Class A Residual which is 503 exempt. _Residuals are
generated by backwash produced by filter washes, and automated sludge removal from the plant's
sedimentation basins. Backwash water is treated in equalization basin and clarifier where solids
are settled and then pumped to the residuals lagoon in service. Solids from the sedimentation
basins are pumped directly to the residuals lagoon in service. The lagoons are operated in a
manner that allows one lagoon to accept residuals while the other lagoon is drying. In a letter
dated September 15, 2014 (attached), Mr. Patrick Mitchell noted two items of concern as they
pertain to the Thomas WTP residuals as a result of his inspection that occurred on August 13, .
City Council: Mayor Allen Joiner; Vivian H. Burke, Mayor Pro Teinpore, Northeast Ward; Denise D. Adams, North Ward; Dan Besse, Southwest Ward; Robert C. Clark, West Wand;
Molly Leight, South Ward; Jeff Macintosh, Northwest \yard: Derwin L Montgomery, East Ward; JantesTaylor, Jr., Southeast Waal; City Manager. Lee D. Garrity
Forsyth County Caramis9iottts David R: Plyler, Chairman; Don Martin, Vice Chair; Ted Kaplan; Richard V. Linville Walter Marshall; Gloria D. Whisenhunn, Everette Witherspoon;
Call 311 or 336-7t2�$,or7-8000 County Manager. Dudley Watts, Jr.
CI link CI �I WCity/County Utility Commission- David Neill, Chairman; Randall S. Tattle. Vice -chair,' Wesley Curtis, Jr.; Harold F_ Day; Toni Griffin; Harold R. Holmes; Charles D. Jewel, 11;
`1 `r 9 Paul S. M,Gill: Chris Park,.. Al H. Scvmnnr. 1. Hill Srrckrnn .

2
2014. The residuals at the Thomas WTP were subsequently spread and over seeded as we agreed
during our compliance inspection. For future applications, the city will amend its practice in -this
area to incorporate the applied residuals when they are stockpiled in this area (within 24 hours) to
address Mr. Mitchell's item of concern #2. The residuals will also be over seeded and maintained
by mowing as requested, which has been our common practice. The residuals were -spread over
2.5 acres which resulted in a PAN application rate of 504 lbs/acre. It should be noted our TKN
value is higher this year at Thomas and Neilson than our previous sampling. The TKN value for
this site was derived from a single sample collected close to the surface ofthe residuals before
they were hauled. We believe this sample could have been influenced by vegetative matter that is
present in the lagoons.
Attached with this correspondence are the following for the Thomas WTP: -
• Three copies of the following reports:
✓ DENR Form DMSDF-Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form.
✓ DENR Form RSSF-Annual Residual Sampling Summary Form
✓ DENR Form-RSSF-B Annual Residual Sampling Summary Form
✓ Lab Data Sheets
✓ DENR Form-PVRF 02T Annual Pathogen and Vector Attraction Reduction Form (02T
Rules)
✓ Lab Data Sheets
✓ Maps of the residuals disposal sites
Neilson Water Treatment Plant _
The Neilson Water Treatment Plant operates three residuals lagoons that produces a Class A
Residual which is 503 exempt. Residuals are generated by the plant's sedimentation basins.
Solids from the sedimentation basins are pumped directly to the residual lagoon in service. The
lagoons are operated, in a manner that allows one lagoon to accept residuals, one lagoon to be
drying and one to be empty ready to be placed into, service. Mr. Mitchell also noted an area of
concern at the Neilson WTP. Item of concern.#1 was addressed by spreading -and over seeding
the stockpiled residuals subsequent to Mr. Mitchell's compliance visit as we discussed during our
compliance inspection. To address Mr. Mitchell's concern when residuals are stock piled at the
Cooper Road.site they will be spread immediately, over seeded and mowed to maintain a fescue
cover. The residuals were spread over approximately 5 acres which resulted in a PAN application
rate of 1,092 lbs/acre. It should be noted that our TKN value is higher,this year at Thomas and
Neilson than our previous sampling. The TKN.value for this site was derived from a single
sample collected close to the surface of the residuals before they were hauled. We believe this
sample could have been influenced by vegetative matter that is present "in the lagoons.
Attached with this correspondence are the following for.the Neilson WTP:
Three copies of the following reports:.
✓ DENR Form DMSDF-Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form.
✓ DENR Form RSSF-Annual Residual Sampling Summary Form
✓. DENR Form-RSSF-B Annual Residual Sampling Summary Form . .
✓ Lab Data Sheets
✓ DENR Form-PVRF.02T Annual'Pathogen.and Vector Attraction Reduction Form (02T.
Rules)
✓ .Lab Data Sheets

I.
3
✓ Maps of the residuals disposal sites
Preparer of Annual Report:
William C. Brewer
Water Treatment Superintendent
Swann Water Treatment Plant
2800 River Ridge Road
Pfafftown, NC 27040
Permittee•
Ron H. Hargrove
Director of Utilities
Utilities Administration
P.O. Box 2511
Winston-Salem, NC 27102
If you have any questions or require additional information regarding our 2014 Annual Report
please call Bill Brewer, Water Treatment Superintendent, at [phone].
Sincerely,
Ron H. Hargrove
Director of Utilities
City of Winston-Salem, NC

* 1
Al
A_DENR
North Carolina Department of Environiment and Natural Resources
Pat McCrory
Governor
September 15, 2014
Mr. David K. Saunders, Director of Utilities
City of Winston-Salem
101 North Main Street
Winston-Salem, NC 27101
John E. Skvarla, III
Secretary
Subject:. Compliance Evaluation Inspection
City of Winston-Salem — Distribution of Class A WTP Residuals Program
Permit No. WQ0031314
Forsyth County
Dear Mr. Saunders:
On August 13, 2014 staff of the North Carolina Division of Water Resources Winston-Salem
Regional Office (DWR) performed a compliance inspection of the City of Winston-Salem's
WTP residuals distribution program. This inspection was . conducted by DWR staff person
Patrick Mitchell. A separate in -office DWR file review of the 2013 annual report was also
conducted as part of this inspection. Onsite activities at all three permitted residuals
generating facilities were reviewed during this inspection. The activities associated with the
Swann WTP were found to be compliant with the permit. However, the following items of
concern were noted at the Neilson WTP and Thomas WTP:
1. Permit condition III. 7. requires that'a suitable vegetative cover shall be maintained on
land application sites onto which residuals are applied. As a reminder, Permit
condition.IU. 10. b. ii. requires that residuals distributed for land application shall not
be stockpiled in the receiving field for more than 14 days without being covered.
Residuals were found to be stockpiled on the receiving fields and the predominant
vegetative cover present was broadleaf weeds and sparse woody vegetation. The cover
crop reported. in the annual report was fescue grass. Please ensure that residuals are
spread in a timely manner and that a suitable vegetative cover is established and
maintained.
2. Permit condition M. 8. i. requires that if a receiving field is within a 100-year
floodplain, the residuals must be injected or incorporated within 24-hours following a
residuals land application event. According to Forsyth County GIS mapping the
receiving field located adjacent to the Thomas WTP is located within the 100-year
flood elevation; .the residuals land applied to this.Seld should be incorporated
Winston-Salem Regional Office
585 Waughtown Street, Winston-Salem, North Carolina 27107
Phone: [phone] FAX: [phone] Customer Service 1-877-623.6748
Intemet: www.rwdenr.gov
An Equal Opportunity IAffimiativeActlon Employer— Made In part by recycled paper

within 24-hour of application. Again, please ensure that residuals are spread and
that a suitable vegetative cover is established in a timely manner and maintained.
Our office appreciates your prompt attention to the above listed items of concern. If you or
your staff have any questions concerning this letter, please contact me or Patrick Mitchell at
[phone].
Sincerely,
.41
=`v`�y/•
Sherri V. Knight, PE - Assistant Regional Supervisor
Water Quality Regional Operations
Division of Water Resources, NC DENR
cc: Mr. William Brewer, Water Treatment Superintendent —Swann WT P, 2800 River Bridge Rd, Pfafftown, NC 27040
Forsyth County Environmental Health
DWR Central Office - Permit File WQ0031314
WSRO Files

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICA'IITUON AND SUMMARY FORM
WQ PERMIT #: WQ0031314 FACILITY NAME: City of Winston-Salem, Thomas Water Treatment Plant
PHONE: [phone] COUNTY: Forsyth OPERATOR: Kenneth C. Atkins
FACILITY TYPE (please check one): Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes , : No L —* If No skip parts A. B. C and certify form below
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
, (dry tons)
Recipient Information
AmAmendment/Volume
Bucking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
Thomas WTP NCO079821
454.82
454.82
On Site
454.92
Fescue
June
July
August
September
October
November
December
Total from FORM DMSDF (sup;
Totals: Annual (dry tons):,,`
0
454.92
454.82
454.82
Amendments) used: I
Bulking Agent(s) used:
* if more space is required, attach additional information sheets (FORM DMSDF (supp# Total Number of Forth DMSDF (Supp)l
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit 1 Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: � No --® If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
afore of ittee _.. _.
Date nature of Preparer**
(if different from Pernuttee)
**Preparer is defined in 40 CFR Part503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM DMSDF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSS)F - B
WQ Permit Number: WQ0031314
Facility Name- Thomas WTP
Residual Source WQ # or NCO079821
NPDES #a
WWTP Maine°
Residual Anaflvsis Data
Laboratory: 1) Pace Labs Inc.
2) Summit Environmental Technologies
3)
4)
5)
Parameter
(mg/kg)
Cone.
Limit
m /k )a
Sample or Composite Date
3/4/2014
Percent Solids (%)
NA
41.8
Arsenic
75
2.2
Cadmium
85
0.22
Copper
4,300
31.5
Chromium
NA
0.06
Lead
840
21
Mercury
57
0.2
Molybdenum
75
1.1
Nickel
420
11.6
Selenium
100
2.2
Zinc
7,500
113
Total Phosphorus
NA
1540
TICN
NA
3410
Ammonia -Nitrogen
NA
23.9
Nitrate and Nitrite
NA
4.6
a For surface disnosal facilities the ceiline concentration limits listed
in this form are not annlicable.
Reference the individual nermit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assume that qualified personnel properly gathered and evaluated the infformation submitted. I am aware that there are significant
Penalties f4r submittinglalse information, including the possibility of fines and imprisonment for knowing violations."
S' nature of Preparer * % ate
r *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for,over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0031314
Facility Name:
Thomas WTP
Residual Source NCO079821
NPDES # or WQ#:
WWTP Maine:
Recidnial Anglvsic Data
Laboratory: 1) Pace Labs Inc.
2) Summit EnvironmentalTechnologies
3)
4)
5)
Parameter
Sampleor • •• Date
Potassium
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
_ designed to assume that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant p naalties for su itting false information, including the possibility of finesand imprisonment for knowing violations."
/ rl'
i tore of Preparer bate
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
j DENR FORM RSSF - 8 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility'Name: 'Thomas WTP
WWTP Name:
WQ Permit Number:
NPDES Number:
WQ0031314
NCO079821
Monitoring Period: From 1/1/2014 To 12/1/2014
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) UYI
Alt B (Alk Treatment) [3
Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
......,...
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density ❑
Alt. (2) Process to Significantly Reduce Pathogens ❑
...........
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Di g estion
...........................................................................:..:.:..:....:..............::........:....................:::................ .
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in
in Sludge
Pathogen Density
Number of
Excee-
dences
Frequency
of Analysis
y
Sample
Type
Analytical
Tech -
ni ue
Minimum
Geo. Mean
aximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
5
6.43
8.6
MPN/g
0
yearly
grab
sm9221 ce
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. OZ uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable)
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
U "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fans and imprisonmen 99
Xal.,�1" ?' 4�.r/' �G�! �L ea%',— / ��?N7J�FzE2��fo� 0/=c
Preparer N e ano Title ype or print) ALandliame and itle (if applicable)(type or print)
�Applier
i ature of Preparer* ate nd (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DEfNR FORM PVRF 02T (12/2006)

'G►
Mineralization
as decimal
ITotal dry
tons/year
jAcres
Applied on
2.5
Rate
0.4
TKN
3410
NH3
23.9
NO3
4.6
NO2
2.3
% Solids
0.418 1
454.84
PAN Surface
1373.29 m /k 2.74658 lbs/dry ton
1249.254 Ibs total PAN
499.7018 Ibs PAN/acre
PAN Injection
1385.24 m /k 2.77048 lbs/dry ton
1260.125 Ibs total PAN
504.05 Ibs PAN/acre
Dry Tons/1000 gal.
1.74306
1st year PAN
Surface lbs.
1249.254447
1st year PAN
Injected lbs.
1260.125123
lbs./acre
Surface
499.7017789
lbs./acre
Injected
504.0500493
MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal."
2000

SAR & ESP
Sodium Absorption Ratio
Na: Sodium (Mg/L) Equivalent weight: 23
Ca: Calcium (Mg/L) Equivalent weight: 20
Mg : Magnesium (Mg/L) Equivalent weight: 12
Milli Equivalent = Mg/L / Equivalent weight
Na M /L Ca M /L M M /L
463.98 1 364.914 1 681.34
Na (ME)
Ca ME
Mg (ME)
20.17304
1 18.2457
166.77833
SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power
SAR = 3.293717 (From Mg/L entered above)
SAR= 3.293717 (From ME entered below)
Na (ME)
Ca (ME)
1 18.2457
Mq (ME)
20.173
1 56.778
The amount of exchangeable sodium ions versus the
amount of exchangeable calcium & magnesium ions in a given mate
Permitting guidance is if greater than 10 require ESP in permit.
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the cation exchange complex of soils
Na (ME) CEC
1 5.2
ESP = 119.23077 %
Na on NC soil test is expressed as meq.
Should be less than 15% (15-20%)

a,
` Summit Environmental Technologies, Inc.
t 3310 Win St
�tf4Tl i Al)41g109'J0.L'l� ".401140 03, 9ALQ CuyahogaFalLs, Ohio 44223
a�ahi1<ls�tP ptatpries. TEL: [phone] FiiY [phone]
Website: hggy6MMseackoom
April 23, 2014
Terri. Page
Pace Analytical Eden
205 East Meadow Rd.
Eden, NC 27288
TEL: [phone]
FAX:
RE: 92191605
Dear Terri Page:
Order No.: 14030178
Summit Environmental Technologies, Inc. received 1 sample(s) on 3/4/2014 for the analyses
presented in the following report..
There were no problems with the analytical events associated with this report unless noted in the
Case Narrative.
Quality control data is within laboratory defined' or method specified acceptance limits except
where noted.
If you have any questions regarding these tests results, please feel free to call the laboratory.
Sincerely,
. A_t�o
Dr. Mo Osman
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
A2LA 0724.01, Alabama 41600, Arkansas 88.0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC ES.7688,() eoigia
E87688 and 943, Idaho OH00923, Illinois 200061 and Reg.5, Indiaaa OOH-13, Kansas E-20347, Keatuoky'(undww mrd Storage Tank) 3, Kentucky
90146. Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New
Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio 4170, Olio VAP CL0052, Oklahoma 9940, Oregon
OW00001. Pennsylvania 6MI335, Rhode Island LA000317, South Carolina 920I6001; Tennessee TN04018, Texas T104704466-11-5, Region 8 STMS-
L, USDAIAPMS P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C
and E87688, Wisconsin 399013010
Page 1-of 8

1
SummitEmironmental Technologies, Inc. WorkArder
3310 Win Si.
t r,wa.►taye Cuyahoga Falls Ohio 44223 Sample Summary
1t�&fyrFl�a�1.'l �9�]rEltld�:. TEL: [phone] FAY [phone] WO#: 14030178
Wehsfte: tt -Aww.settekcom 23 Apr-14
I
CLIENT: Pace Analytical Eden
Project: 92191605
Lab SamplelD Client Sample ID Tag No Date Collected Date Received Matrix.
14030178-001 92191605007 3/3/2014 8:35:00 AM 3/4/2014 10:35:00 AM Solid
Page 2 of 8

Summit Envirommemal Technologies Inc.
V. 3310Win St. Case Narrative
1��UI:io�IME�1�lt!_TErCF99C.Ln�a �,at� Cuyahoga Falls, Ohio44223 Wo#: 14030178.
Jaat JyrllCa! l,abcta��i �ti TEL. [phone] FAX. [phone] paw. 4/23/2014 .
Webstte: http:l/www.settekcom
CLIENT* Pace Analytical Eden
Project: 92191605
This. report in its entirety consists of the documents listed .below. All documents contain the Summit
Environmental Technologies, Inc. Work Order Number assigned to this report.
Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality
Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample.
set.
Concentrations reported with a J flag in the Qual field are. values below the Limit of Quantitation
(LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty
associated with these results and data should be considered as estimated.
Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods.
Estimated uncertainty values are available upon request.
Any comments or problems with the analytical events associated with.th is report are noted below.
Revised Report: SAR resulti corrected (calculation error.). Result for Sodium added to report.
Revision vl
:Page 3 of 0

X
Summit Environmental Technologies, Inc,
WO#: 14030178
9NVI
i3N AE�1YaAI
T CldkiOl,(f
!:FTEL.-
3310 Win St.
uy gaFalls, Ohio 44223
Cuyahoga
Date Reported: 4/23/2014
[phone] FAX.- [phone]
Company: Pace Analytical Eden
I
4Yebstte: hup:/hvww.settek com
Address: 205 East Meadow Rd.
FdenNC 27288 °
Received: 3/4/2014
Project#: 92191605
Client ED#
Lab ID# Collected Analyse
Result Units
Matrix Method DF RL
Run
Analyst
92191605007
0.01
3/3/2014
Calclum(Ca)
620 mg/Kg
Solid E200.7 C 1 10
3/7/2014
WK
92191605007
001
3/3/2014
Magnesium(Mg)
730 mg/Kg
Solid E200.7 C 1 10
317/2014
WK
92191605007
001
3/3/2014
Sodium(Na)
210 mg/Kg
Solid E200.7 C 1 25
3/7/2014
WK
92191605007
001
3/3/2014
SAR
1.4 mg/L
Solid EPA 200.7 1
3/5/2014
WK
92191605007
001
3/3/2014
Cyanide, Reactive
ND ppm
Solid EPA 9014 1 0.50
3/512014
TIR
92191605007
001
3/3/2014
Ignitability
Non flammable mm/sec
Solid EPA 1030 1
3/7/2014
AYS
92191605007
001
3/3/2014
pH
5.6 a.u.
Solid EPA 9045 D 1
3/4/2014
AYS
j 92191605007
i
i
001
3/3/2014
Sulfide, Reactive
ND ppm
Solid EPA 9034 1 25
3/5/2014
TIR
I
Page 4 of 8

Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Win St.
erawlaciutla 1A1:Ct35VOlb�tr Cuyahoga Falls, Ohio 44223_
,+?l�tlr� iieiflritf TEL: Wes: 14030178
[phone] FAX.[phone]
Website: ham://www.settekcom 23-Apr-14
Client: Pace .Analytical Eden
Project: 92191605 TestCode: Cyanide,Reactive S(9014)'
Sample ID MB-R14361 SampType: MBLK TestCode: Cyanlde,Roa Units: ppm Prep Date: RunNo: 14351
Client ID: PBS Batch ID: R14361 TestNo: SW9014 Analysis Date: 3/5/2014 SegNo: 163352
Analyte Result PQL SPK value SPK Ref Val %REC Lowl imit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive ND 0.50
Sample ID LCS-R14361
SampType: LCS
TestCode: Cyanlde,Rea Units: ppm
Prep Date:
RunNo: 14351
Client 11): LCSS
Batch ID. R14351
TestNo: SW9014
Analysis Date: 315/2014
SegNo: 163363
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive . 1.0 0.50 1.000 0 102 70 130
Sample ID LCSD-R14351
SampType: LCSD
TestCode: Cyanide,Rea Units: ppm
Prep Date:
RunNo: 14351
Client ID: LCSS02
Batch ID. R14361
TestNo: SW9014'
Analysis Date: 3/5/2014
SegNo: 163354
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowtimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive 0.98 0.50 1.000 0 97.5 70 130 1.015 4.02 30
Qualifier's: ° Vetue exceeds Ma ' CootaminantLevel.
B
Andyte deeded in the assocbted Method Blank
C
Value is below Minimum Compound Limit
E Value above quantieuion range
H
Holding lanes for preparation or analysis exceeded
t
Anslyte detected below quantitatioo fmnB
M Meal integration used to determine area respamse
ND
Not Detected at the Reporting Limit
O
RSD is gredarthan RSDlimit
P Second column conf rmabon exoeeds
Pl.
Permit Limit
R.
RPD outside aeoepted recoveryliniu
RL Reporting Detection Limit
S
Splice Recovery outside acoepted recovery Emus
U
samples with CalcVal<MDL
Revision v1
r
Page 5 of 8

Summit Environmental Technologies, Inc. QC SUMMARY REPORT
- 3310 Win St.
0e;4t1i€Ofil}�1ted57iL iiCltt�lfLCbb(>3' 3hfG' Cuyahoga Falls, Ohio 44223
>�t P cal 1 bAfafarl - TEL_ [phone] FAX [phone] w 14030178
Websio. htW,1IWWW.settekM 23-Apr-14
Client: Pace Analytical Eden
Project: 92191605 TestCode: SuWde,Reactifve S("34)
Sample ID MB-RI4274
SampType: MBLK
TestCode: Sulflde,React Units: ppm
Prep Date:
RunNo: 14274
Client ID: PBS
Batch ID: R14274
TesWo: SW9034
Analysis Date: 3/5/2014
SegNo: 162269
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit Hight-imit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive ND 25
Sample ID LCS-R14274
SampType: LCS
TestCods: Sulfide,React Units: ppm
Prep Date:
RunNo: 14274
Crient 1D: LCSS
Batch ID: R14274
TesWo: SV49034
Analysis Date: 3/6/2014
SegNo: 162270
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowUmit HighLimit RPD Ref Val
%RPD RPDLImlt Qual
5uitide, Reactive 77 25 84.00 0 91.9 70 130
Sample ID LCSD-Ri4274
SampType: LCSD
TestCode: Sulfide,React Units: ppm
Prep Date:
RunNo: 14274
Client ID: LCSS02
Batch ID: R14274
TestNo: SW9034
Analysis Date: 3/5/2014
SegNo: 162271
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLImit HighLimit RPD Ref Val
%RPD RPDLimit Qual
moo, Reactive 76 25 84.00 0 90.5 70 130 77.20 1.67 30
Qualifiers: • value etmeeds Moe... comamimat Level.
H Value above quandtationrange
M Ma mal Integration used to determine area response
P Second column confirmation exceeds
RL ReportitgDetection U.it
B Amdyte detected m the assodeted Method Blank
H Holding fi=for ptepazatioaoranalysis ameeded
ND Not Detected at the Reporting Limit
PL Permit Lilt
S Spike Recoveryoutside accepted recovery limits
C vaweisbelow MidmumCompound Link
1 Andyte detected below quan"oo limits
O RSDisvenerthaaR9Dlimit
R RPD outside accepted recovery Emits
U Samples vAhCaleVal<MDL
Revision vl
.t
Page 6 of 8

a �
a
4-aceAnalyiical
www.pacelabs.com
i
March 27, 2014
Mr. Kenny Atkins
City of Winston Salem
1201 South MLK Jr. Dr.
Winston Salem, NC 27107
RE: Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Dear Mr. Atkins:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
S&tam " of. dcw-oyu
Brittany Gibson for
Terri Page
[e-mail]
Project Manager
Enclosures
cc: Mr. Bill Brewer, City of Winston Salem
Ms. Mattie Shamel, City of Winston Salem
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 38

3
11�7aceAnalytical
.pacelabs.com
t
t
i
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Raleigh Certification IDs
6701 Conference Drive Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
r
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 38

A
g
♦ 1 k
Pace Analytical Services, Inc.
aceAnalytical 9800 Kincey Ave. Suite100
Huntersville, NC 28078078
www.pacelabs.com [phone]
r
3
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Fecal Sludge Thomas WTP
92191736
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92191736001
Lagoon # F1
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191736002
Lagoon # F2
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191736003
Lagoon # F3
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191736004
Lagoon # F4
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191736005
Lagoon # F5
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191736006
Lagoon #2 F6
ASTM D2974-87
LLW
1
PASI-C
SM9221 C E (MPN) 503
LJI
1
PASI-R
92191736014
Lagoon #2
EPA8081
NU1
8
PASI-C
EPA6010
JMW
13
PASI-A
EPA6010
JMW
7
PASI-A
EPA 7470
MTS
1
PASI-A
EPA 7471
MTS
1
PASI-A
EPA 8270
RES
18
PASI-C
EPA 8260
DLK
14
PASI-C
EPA 8260
DLK
70
PASI-C
ASTM D2974-87
KDF
1
PASI-C
SM 254OG
LLW
1
PASI-A
EPA 9045
MDW
1
PASI-A
40CFR PART 432.2
EWS
1
PASI-A
EPA 350.1
AES2
1
PASI-A
EPA351.2
JDA
1
PASI-A
EPA353.2
DMN
3
PASI-A
EPA 365.1
JDA
1
PASI-A
92191736015
Fecal Sludge F7
ASTM D2974-87
KDF
1
PASI-C
SM9221 C E (MPN) 503
LJI
1
PASI-R
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 38

A
aceAnalytical
www.pdcolabs.com,
i
ANALYTICAL RESULTS
N
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Sample: Lagoon # F1 Lab ID: 92191736001 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 6&2 % 0.10 1 03/07/14 15:01
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 6.3 MPN/g 0.052 1 03/04/14 14:53
Sample: Lagoon # F2 Lab ID: 92191736002 Collected: 03/04/14 08:45 Received: 08/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 68A % 0.10 1 03/07/14 15:01
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 6.9 MPN/g 0.056 1 03/04/14 14:53 - 2g
Sample: Lagoon # F3 Lab ID: 92191736003 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 68.6 % 0.10 1 03/07/14 15:04
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 7.0 MPN/g 0.057 1 03/04/14 14:53 2g
Sample: Lagoon # F4 Lab ID: 92191736004 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 74.3 % 0.10 1 03/07/14 15:02
92210E Fecal Col[form, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 8.6 MPN/g 0.070 1 03/04/14 14:53
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
2g
Page 4 of 38

T
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
wAnalytical Huntersville, NC 28078 a
www.p&Wabs.cam [phone]
ANALYTICAL RESULTS
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Sample: Lagoon # F5 Lab ID: 92191736005 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 62.5 % 0.10 1 03/07/14 15:02
92210E Fecal Coliform, MPN RAIL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 5.9 MPN/g 0.048 1 03/04/14 14:53 2g
Sample: Lagoon #2 F6 Lab ID: 92191736006 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 58.5 % 0.10 1 03/07/14 15:02
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 5.3 MPN/g 0.043 1 03/04/14 14:53
Sample: Lagoon #2 Lab ID: 92191736014 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
8081 GCS Pesticides, TCLP
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/17/14 15:10
gamma-BHC (Lindane)
ND ug/L 0.50 1
03/18/14 08:00
03/18/14 12:59
58-89-9
Chlordane (Technical)
ND ug/L 3.0 1
03/18/14 08:00
03/18/14 12:59
57-74-9
Endrin
ND ug/L 0.50 1
03/18/14 08:00
03/18/14 12:59
72-20-8
Heptachlor epoxide
ND ug/L 0.50 JL
03/18/14 08:00
03/18/14 12:59
1024-57-3
Methoxychlor
ND ug/L 1000 1
03/18/1.4 08:00
03/18/14 12:59
72-43-5
Toxaphene
ND ug/L 3.0 1
03/18/14 08:00
03/18/14 12:59
8001-35-2
Surrogates
Decachlorobiphenyl' (S)
77 % 10-138 1
03/18/14 08:00
03/18/14 12:59
2051724-3
Tetrachloro-m-xylene (S)
66 % 10-110 1
03/18/14 08:00
03/18/14 12:59
877-09-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Aluminum
58300 mg/kg 222 10
03/07/14 10:00
03/10/14 14:00
7429-90-5
Arsenic
ND mg/kg 2.2 1
03/07/14 10:00
03/07/14 21:04
7440-38-2
Cadmium
ND mg/kg 0.22 1
03/07/14 10:00
03/07/14 21:04
7440-43-9
Calcium
873 mg/kg 22.2 1
03/07/14 10:00
03/07/14 21:04
7440-70-2
Copper
31Z mg/kg 1.1 1
03107/1410:00
03/07/14 21:04
7440-50-8
Lead
21.0 mg/kg 1.1 1
03/07/14 10:00
03/07/14 21:04
7439-92-1
Magnesium
1630 mg/kg 22.2 1
03/07/14 10:00
03/07/14 21:04
7439-95-4
Molybdenum
ND mg/kg 1.1 1
03/07/14 10:00
03/07/14 21:04
7439-98-7
Nickel
11.6 mg/kg 1.1 1
03/07/14 10:00
03/07/14 21:04
7440-02-0
REPORT OF LABORATORY ANALYSIS,
This report shall not be reproduced, except in
full,
Date: 03/27/2014 09:11 AM
without the written consent of Pace Analytical Services, Inc..
Page 5 of 38

aceAnalytical o
www.pecolabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Sample: Lagoon #2
Lab ID: 92191736014
Collected: 03/04/14 08:45
Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight"
basis
Parameters
Results Units
Report Limit
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Potassium
1370 mg/kg
1110
1
03/07/14 10:00
03/07/14 21:04
7440-09-7
Selenium
ND mg/kg
2.2
1
03/07/14 10:00
03/07/14 21:04
7782-49-2
Sodium
ND mg/kg
1110
1
03/07/14 10:00
03/07/14 21:04
7440-23-5
Zinc
113 mg/kg
2.2
1
03/07/14 10:00
03/07/14 21:04
7440-66-6
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Method:
EPA 3010
Leachate Method/Date: EPA 1311; 03/07/14 22:45
Arsenic
ND mg/L
0.050
1
03/10/1418:00
03/11/1418:26
7440-38-2
Barium
0.44 mg/L
0.25
1
03/10/1418:00
03/11/14 18:26
7440-39-3
Cadmium
ND mg/L
0.0050
1
03/10/1418:00
03/11/1418:26
7440-43-9
Chromium
ND mg/L
0.025
1
03/10/1418:00
03/11/1418:26
7440-47-3
Lead
0.029 mg/L
0.025
1
03/10/14 18:00
03/11/14 18:26
7439-92-1
Selenium
ND mg/L
0.10
1
03/10/1418:00
03/11/1418:26
7782-49-2
Silver
ND mg/L
0.025
1
03/10/1418:00
03/11/1418:26
7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA7470 Preparation Method: EPA7470
Leachate Method/Date: EPA 1311; 03/07/14 22:45
Mercury
ND ug/L
0.20
1
03110/1418:45
03/11/1418:59
7439-97-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
0.026 mg/kg
0.012
1
03/07/1413:50
03/11/1415:12
7439-97-6 M1,R1
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/17/14 15:10
1,4-Dichlorobenzene
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
106-46-7
2,4-Dinitrotoluene
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
121-14-2
Hexachloro-1,3-butadiene
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
87-68-3
Hexachlorobenzene
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
118-74-1
Hexachloroethane
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
67-72-1
2-Methylphenol(o-Cresol)
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
95-48-7
3&4-Methylphenol(m&p Cresol)
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
Nitrobenzene
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
98-95-3
Pentachlorophenol
ND ug/L
100
1
03/18/14 08:00
03/18/14 12:51
87-86-5
Pyridine
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
110-86-1
2,4,5-Trichlorophenol
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
95-95-4
2,4,6-Trichlorophenol
ND ug/L
50.0
1
03/18/14 08:00
03/18/14 12:51
88-06-2
Surrogates
Nitrobenzene-d5 (S)
76 %
12-102
1
03/18/14 08:00
03/18/14 12:51
4165-60-0
2-Fluorobiphenyl (S)
79 %
13-107
1
03/18/14 08:00
03/18/14 12:51
321-60-8
Terphenyl-d14 (S)
89 %
21-132
1
03/18/14 08:00
03/18/14 12:51
1718-51-0
Phenol-d6 (S)
37 %
10-110
1
03/18/14 08:00
03/18/14 12:51
13127-88-3
2-Fluorophenol (S)
53 %
10-110
1
03/18/14 08:00
03/18/14 12:51
367-12-4
2,4,6-Tribromophenol (S)
80 %
27-108
1
03/18/14 08:00
03/18/14 12:51
118-79-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 38

c
Y
aceAnNjdical
wmpacelabs:com.
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Sample: Lagoon #2 Lab ID:.92191736014 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
8260 MSV TCLP Analytical Method: EPA 8260
Benzene
ND ug/L
192
38'.5
03/12/1416:26
71-43-2
2-Butanone (MEK)
ND ug/L
385
38.5
03/12/14 16:26
78-93-3
Carbon tetrachloride
ND ug/L
192
38.5
03/12/14 16:26
56-23-5
Chlorobenzene
ND ug/L
192
38.5
03/12/14 16:26
108-90-7
Chloroform
ND ug/L
192
3&5
03/12/14 16:26
67-66-3
1,4-Dichlorobenzene
ND ug/L
192
38.5
03/12/14 16:26
106-46-7
1,2-Dichloroethane
ND ug/L
192
38.6
03/12/14 16:26
107-06-2
1,1-Dichloroethene
ND ug/L
192
3&.5
03/12/14 16:26
75-35-4
Tetrachloroethene
ND ug/L
192
38.5
03/12/14 16:26
127-18-4
Trichloroethene
ND ug/L
192
38.5
03/12/14 16:26
79-01-6
Vinyl chloride
ND ug/L
192
38.5
03/12/14 16:26
75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
98 %
70-130
38.5
03/12/14 16:26
17060-07-0 1g
Toluene-d8 (S)
98 %
67-135
38.5
03/12/14 16:26
2037-26-5
4-Bromofluorobenzene (S)
98 %
70-130
38.5
03/12/14 16:26
460-00-4
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone
1160 ug/kg
286
1
03/13/14 00:50
67-64-1 E
Benzene
ND ug/kg
14.3
1
03/13/14 00:50
71-43-2
Bromobenzene
ND ug/kg
14.3
1
03/13/14 00:50
108-86-1
Bromochloromethane-
ND ug/kg
14.3
1
03/13/14 00:50
74-97-5
Bromodichloromethane
ND- ug/kg
14.3
1
03/13/14 00:50
75-27-4
Bromoform
ND ug/kg
14.3
1
03/13/14 00:50
75-25-2
Bromomethane
ND ug/kg
28.6
1
03/13/14 00:50
74=83-9
2-Butanone (MEK)
ND ug/kg
286
1
03/13/14 00:50
78-93-3
n-Butylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
104-51-8
sec-Butylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
135-98-8
tert-Butylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
98-06-6
Carbon tetrachloride
ND ug/kg
14.3
1
03/13/14 00:50
56-23-5
Chlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
108-90-7
Chloroethane
ND ug/kg
28.6
1
03/13/14 00:50
75-00-3
Chloroform
ND ug/kg
14.3
1
03/13/14 00:50
67-66-3
Chloromethane
ND ug/kg
28.6
1
03/13/14 00:50
74-87-3
2-Chlorotoluene
ND ug/kg
14.3
1
03/13/14 00:50
95-49-8
4-Chlorotoluene
ND ug/kg
14.3
1
03/13/14 00:50
106-43-4
1,2-Dibromo-3-chloropropane
ND ug/kg
14.3
1
03/13/14 00:50
96-12-8
Dibromochloromethane
ND ug/kg
14.3
1
03/13/14 00:50
124-48-1
1,2-Dibromoethane (EDB)
ND ug/kg
14.3
1
03/13/14 00:50
106-93-4
Dibromomethane
ND ug/kg
14.3
1
03/13/14 00:50
74-95-3
1,2-Dichlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
95-50-1
1,3-Dichlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
541-73-1
1,4-Dichlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
106-46-7
Dichlorodifluoromethane
ND ug/kg
28.6
1
03/13/14 00:50
75-71-8 10
1,1-Dichloroethane
ND ug/kg
14.3
1
03/13/14 00:50
75-34-3
1,2-Dichloroethane
ND ug/kg
14.3
1
03/13/14 00:50
107-06-2
1,1-Dichloroethene
ND ug/kg
14.3
1
03/13/14 00:50
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 7 of 38

11-�acmnalXical
www.pawlabs.com
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's
ANALYTICAL RESULTS
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
xi Y
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Lagoon #2 Lab ID: 92191736014 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260/6035A Volatile Organics Analytical Method: EPA 8260
cis-1,2-Dichloroethene
ND ug/kg
14.3
1
03/13/14 00:50
156-59-2
trans- 1,2-Dichloroethene
ND ug/kg
14.3
1
03/13/14 00:50
156-60-5
1,2-Dichloropropane
ND ug/kg
14.3
1
03/13/14 00:50
78-87-5
1,3-Dichloropropane
ND ug/kg
14.3
1
03/13/14 00:50
142-28-9
2,2-Dichloropropane
ND ug/kg
14.3
1
03/13/14 00:50
594-20-7
1,1-Dichloropropene
ND ug/kg
14.3
1
03/13/14 00:50
563-58-6
cis-1,3-Dichloropropene
ND ug/kg
14.3
1
03/13/14 00:50
10061-01-5
trans- 1,3-Dichloropropene
ND ug/kg
14.3
1
03/13/14 00:50
10061-02-6
Diisopropyl ether
ND ug/kg
14.3
1
03/13/14 00:50
108-20-3
Ethylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
100-41-4
Hexachloro-1,3-butadiene
ND ug/kg
14.3
1
03/13/14 00:50
87-68-3
2-Hexanone
ND ug/kg
143
1
03/13/14 00:50
591-78-6
Isopropylbenzene (Cumene)
ND ug/kg
14.3
1
03/13/14 00:50
98-82-8
p4sopropyltoluene
ND ug/kg
14.3
1
03/13/14 00:50
99-87-6
Methylene Chloride
ND ug/kg
57.1
1
03/13/14 00:50
75-09-2
4-Methyl-2-pentanone (MIBK)
ND ug/kg
143
1
03/13/14 00:50
108-10-1
Methyl-tert-butyl ether
ND ug/kg
14.3
1
03/13/14 00:50
1634-04-4
Naphthalene
ND ug/kg
14.3
1
03/13/14 00:50
91-20-3
n-Propylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
103-65-1
Styrene
ND ug/kg
14.3
1
03/13/14 00:50
100-42-5
1,1,1,2-Tetrachloroethane
ND ug/kg
14.3
1
03/13/14 00:50
630-20-6
1,1,2,2-Tetrachloroethane
ND ug/kg
14.3
1
03/13/14 00:50
79-34-5
Tetrachloroethene
ND ug/kg
14.3
1
03/13/14 00:50
127-18-4
Toluene
ND ug/kg
14.3
1
03/13/14 00:50
108-88-3
1,2,3-Trichlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
87-61-6
1,2,4-Trichlorobenzene
ND ug/kg
14.3
1
03/13/14 00:50
120-82-1
1,1,1-Trichloroethane
ND ug/kg
14.3
1
03/13/14 00:50
71-55-6
1,1,2-Trichloroethane
ND ug/kg
14.3
1
03/13/14 00:50
79-00-5
Trichloroethene
ND ug/kg
14.3
1
03/13/14 00:50
79-01-6
Trichlorofluoromethane
ND ug/kg
14.3
1
03/13/14 00:50
75-69-4
1,2,3-Trichloropropane
ND ug/kg
14.3
1
03/13/14 00:50
96-18-4
1,2,4-Trimethylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
95-63-6
1,3,5-Trimethylbenzene
ND ug/kg
14.3
1
03/13/14 00:50
108-67-8
Vinyl acetate
ND ug/kg
143
1
03/13/14 00:50
108-05-4
Vinyl chloride
ND ug/kg
28.6
1
03/13/14 00:50
75-01-4
Xylene (Total)
ND ug/kg
28.6
1
03/13/14 00:50
1330-20-7
m&p-Xylene
ND ug/kg
28.6
1
03/13/14 00:50
179601-23-1
o-Xylene
ND ug/kg
14.3
1
03/13/14 00:50
95-47-6
Surrogates
Toluene-d8 (S)
126 %
70-130
1
03/13/14 00:50
2037-26-5
4-Bromofluorobenzene (S)
78 %
70-130
1
03/13/14 00:50
460-00-4
1,2-Dichloroethane-d4 (S)
75 %
70-132
1
03/13/14 00:50
17060-07-0
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
58.2 %
0.10
1
03/07/14 17:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM
without the written consent of Pace Analytical
Services, Inc..
Page 8 of 38

Y
aceAnalyfca!
WW..pgW18bs.com
ANALYTICAL RESULTS
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Lagoon #2
Lab ID: 92191736014 Collected: 03/04/14 08:45
Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
254OG Total- Percent Solids
Analytical Method: SM 2540G
Total Solids
41.8 %
0.000010
1
03/07/14 10:00
9045 pH Soil
Analytical Method: EPA 9045
pH at 25 Degrees C
5.7 Std. Units
0.10
1
03/10/14 16:03
D6,H1
Total Nitrogen Calculation
Analytical Method: 40CFR PART 432.2
Nitrogen
3410 mg/kg
40.0
1
03/25/1411:01
7727-37-9
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/kg
23.9
1
03/07/14 17:58
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
3410 mg/kg
332
5
03/14/14 11:42
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA353.2
Nitrogen,. Nitrate
ND mg/kg
4.6
1'
03/21/14 18:43
Nitrogen, Nitrite
ND mg/kg
2.3
1
03/21/14 18:43
Nitrogen, NO2 plus NO3
ND mg/kg
4.6
1
03/21/14 18:43
365.1 Phosphorus, Total
Analytical Method: EPA365.1
Phosphorus
1540 mg/kg
52.0
5
03/18/14 12:06
7723-14-0
Sample: Fecal Sludge F7 Lab ID: 92191736015 Collected: 03/04/14 08:45 Received: 03/04/14 12:55 Matrix: Solid
Results reported on a "dry-weight',basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 56.2 % 0.10 1 03/26/14 18:26
92210E Fecal Coliform, MPN,RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 5.0 MPN/g 0.041 1 03/04/14 14:53 2g
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 38

aceAnalytical
t www.pacelabs.com,
f
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MERP/6298 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 MercuryTCLP
Associated Lab Samples: 92191736014
METHOD BLANK: 1154050
Associated Lab Samples: 92191736014
Parameter Units
Mercury
ug/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.20 03111/1418:12
• q
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1154051
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.5 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154052 1154053
MS MSD
92191921001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Mercury ug/L 5.3 2.5 2.5 7.6 7.6 91 92 75-125 0
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 38

aceAnaiytical
tvwvw.pacelabs.c=
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MERP/6288
QC Batch Method: EPA7471
Associated Lab Samples: 92191736014
METHOD BLANK: 1152849
Associated Lab Samples: 92191736014
Parameter Units
mg/kg
Mercury
QUALITY CONTROL DATA
Analysis Method: EPA7471
Analysis Description: 7471 Mercury
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0050 03/11/1415:07
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1152850
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .067 0.068 102 80-120
MATRIX SPIKE & _MATRIX SPIKE DUPLICATE: 1152851 1152852
MS MSD
92191736014 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Mercury. mg/kg 0.026 .16 .12 0.13 0.082 65 46 75-125 42 M1,R1
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc:.
Page 11 of 38

aceAnalytical
..pacetabs.cwn
t
i
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MPRP/15396
Analysis Method: EPA6010
QC Batch Method: EPA3050
Analysis Description: 6010 MET
Associated Lab Samples: 92191736014
METHOD BLANK: 1152366
Matrix: Solid
Associated Lab Samples: 92191736014
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Aluminum
mg/kg
ND 10.0
03/07/14 20:28
Arsenic
mg/kg
ND 1.0
03/07/14 20:28
Cadmium
mg/kg
ND 0.10
03/07/14 20:28
Calcium
mg/kg
ND 10.0
03/07/14 20:28
Copper
mg/kg
ND 0.50
03/07/14 20:28
Lead
mg/kg
ND 0.50
03/07/14 20:28
Magnesium
mg/kg
ND 10.0
03/07/14 20:28
Molybdenum
mg/kg
ND 0.50
03/07/14 20:28
Nickel
mg/kg
ND 0.50
03/07/14 20:28
Potassium
mg/kg
ND 500
03/07/14 20:28
Selenium
mg/kg
ND 1.0
03/07/14 20:28
Sodium
mg/kg
ND 500
03/07/14 20:28
Zinc
mg/kg
ND 1.0
03/07/14 20:28
LABORATORY CONTROL SAMPLE: 1152367
Spike
LCS
LCS %
Rec
Parameter
Units
Conc.
Result
% Rec Limits
Qualifiers
Aluminum
mg/kg
500
524
105
80-120
Arsenic
mg/kg
50
51.4
103
80-120
Cadmium
mg/kg
50
52.2
104
80-120
Calcium
mg/kg
500
513
103
80-120
Copper
mg/kg
50
53.2
106
80-120
Lead
mg/kg
50
51.6
103
80-120
Magnesium
mg/kg
500
522
104
80-120
Molybdenum
mg/kg
50
53.7
107
80-120
Nickel
mg/kg
50
52.5
105
80-120
Potassium
mg/kg
500
554
111
80-120
Selenium
mg/kg
50
52.3
105
80-120
Sodium
mg/kg
500
547
109
80-120
Zinc
mg/kg
50
51.4
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1152368
1152369
MS
MSD
92192129001 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Aluminum
mg/kg
ND 368
347 372
357
100 101
75-125 4
Arsenic
mg/kg
ND 36.8
34.7 37.6
35.7
102 103
75-125 5
Cadmium
mg/kg
ND 36.8
34.7 37.4
35.2
102 101
75-125 6
Calcium
mg/kg
336 368
347 661
693
88 103
75-125 5
ug/g
REPORT OF LABORATORY ANALYSIS
This report shall
not be reproduced, except in full,
Date: 03/27/2014 09:11 AM
without the written consent of Pace Analytical Services, 1nc..
Page 12 of 38

k
P
aceAnalXical o
www.pamiabs.com
s
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Fecal Sludge Thomas WTP
Pace Project No.:
92191736
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1152368
1152369
MS
MSD
92192129001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Copper
mg/kg
4.87
36.8
34.7
42.1
40.8
101
103
75-125
3
ug/g
Lead
mg/kg
ND
36.8
34.7
36.3
34.3
98
99
75-125
6
Magnesium
mg/kg
ND
368
347
359
342
97
98
75-125
5
Molybdenum
mg/kg
ND
36.8
34.7
38.2
36.4
104
105
75-125
5
Nickel
mg/kg
ND
36.8
34.7
37.6
35.3
102
101
75-125
6
Potassium
mg/kg
ND
368
347
396
372
106
105
75-125
6
Selenium
mg/kg
ND
36.8
34.7
40.0
38.3
107
109
75-125
4
Sodium
mg/kg
ND
368
347
435
409
104
103
75-125
6
Zinc
mg/kg
28.9
36.8
34.7
54.5
62.8
70
98
75-125
14 M1
ug/g
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 38

1�;aceAnalXical"
lwww.pacelabs.com
}
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MPRP/15410 Analysis Method: EPA6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92191736014
METHOD BLANK: 1154055
Matrix:
Water
Associated Lab Samples: 92191736014
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
03/11/1417:28
Barium
mg/L
ND
0.25
03/11/1417:28
Cadmium
mg/L
ND
0.0050
03/11/1417:28
Chromium
mg/L
ND
0.025
03/11/1417:28
Lead
mg/L
ND
0.025
03/11/1417:28
Selenium
mg/L
ND
0.10
03/11/1417:28
Silver
mg/L
ND
0.025
03/11/1417:28
LABORATORY CONTROL SAMPLE:
1154056
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2.5
2.5
101
80-120
2.5
2.2
86
80-120
2.5
2.3
93
80-120
2.5
2.4
95
80-120
2.5
2.2
89
80-120
2.5
2.6
103
80-120
1.2
1.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1154057
MS
92191921001
Spike
Parameter
Units
Result
Conc.
Arsenic
mg/L
ND
2.5
Barium
mg/L
0.64
2.5
Cadmium
mg/L
0.011
2.5
Chromium
mg/L
ND
2.5
Lead
mg/L
0.12
2.5
Selenium
mg/L
ND
2.5
Silver
mg/L
ND
1.2
Date: 03/27/2014 09:11 AM
1154058
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
2.5
2.7
2.8
108
111
75-125
3
2.5
3.0
3.1
92
97
75-125
4
2.5
2.5
2.6
98
103
75-125
4
2.5
2.5
2.6
101
105
75-125
4
2.5
2.5
2.6
94
98
75-125
4
2.5
2.7
2.8
108
112
75-125
3
1.2
1.3
1.4
105
110
75-125
4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qua]
Page 14 of 38

r✓
aceAnalXical"
/ www.pacelabs.com
i
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MSV/26058
QC Batch Method: EPA 8260
Associated Lab Samples: 92191736014
Analysis Method:
Analysis Description:
EPA 8260
8260 MSV TCLP
METHOD BLANK: 1155334
Matrix: Water
Associated Lab Samples: 92191736014
Blank Reporting
Parameter
Units
Result Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
03/12/14 11:29
1,2-Dichloroethane
ug/L
ND
5.0
03/12/14 11:29
1,4-Dichlorobenzene
ug/L
ND
5.0
03/12/14 11:29
2-Butanone (MEK)
ug/L
ND
10.0
03/12/14 11:29
Benzene
ug/L
ND
5.0
03/12/14 11:29
Carbon tetrachloride
ug/L
ND
5.0
03/12/14 11:29
Chlorobenzene
ug/L
ND
5.0
03/12/14 11:29
Chloroform
ug/L
ND
5.0
03/12/14 11:29
Tetrachloroethene
ug/L
ND
5.0
03/12/14 11:29
Trichloroethene
ug/L
ND
5.0
03/1211411:29
Vinyl chloride
ug/L
ND
5.0
03/12/14 11:29
1,2-Dichloroethane-d4 (S)
%
113
70-130
03/12/14 11:29
4-Bromofluorobenzene (S)
%
98
70-130
03/12/14 11:29
Toluene-d8 (S)
%
98
67-135
03/12/14 11:29
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1155335
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
57.3
115
70-141
1,2-Dichloroethane
ug/L
50
62.5
125
70-139
1,4-Dichlorobenzene
ug/L
50
60.4
121
70-141
2-Butanone (MEK)
ug/L
100
138
138
63-150
Benzene
ug/L
50
55.8
112
70-132
Carbon tetrachloride
ug/L
50
52.8
106
70-150
Chlorobenzene
ug/L
50
58.4
117
70-134
Chloroform
ug/L
50
57.0
114
70-130
Tetrachloroethene
ug/L
50
58.8
118
70-137
Trichloroethene
ug/L
50
55.2
110
70-131
Vinyl chloride
ug/L
50
54.6
109
56-144
1,2-Dichloroethane-d4 (S)
%
122
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
99
67-135
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 15 of 38

/5a'ceAnalXical"
t www.pacelabs.com
1
4
i
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: MSV/26068 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV 5035A Volatile Organics
Associated Lab Samples: 92191736014
METHOD BLANK: 1155688
Associated Lab Samples: 92191736014
Parameter Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/kg
ND
6.2
03/12/14 16:34
1,1,1-Trichloroethane
ug/kg
ND
6.2
03/12/14 16:34
1,1,2,2-Tetrachloroethane
ug/kg
ND
6.2
03/1211416:34
1,1,2-Trichloroethane
ug/kg
ND
6.2
03/12/14 16:34
1,1-Dichloroethane
ug/kg
ND
6.2
03/12/14 16:34
1,1-Dichloroethene
ug/kg
ND
6.2
03/12/14 16:34
1,1-Dichloropropene
ug/kg
ND
6.2
03/12/14 16:34
1,2,3-Trichlorobenzene
ug/kg
ND
6.2
03/12/14 16:34
1,2,3-Trichloropropane
ug/kg
ND
6.2
03/12/14 16:34
1,2,4-Trichlorobenzene
ug/kg
ND
6.2
03/12/14 16:34
1,2,4-Trimethylbenzene
ug/kg
ND
6.2
03/12/1416:34
1,2-Dibromo-3-chloropropane
ug/kg
ND
6.2
03/12/14 16:34
1,2-Dibromoethane (EDB)
ug/kg
ND
6.2
03/12/14 16:34
1,2-Dichlorobenzene
ug/kg
ND
6.2
03/12/14 16:34
1,2-Dichloroethane
ug/kg
ND
6.2
03/12/14 16:34
1,2-Dichloropropane
ug/kg
ND
6.2
03/12/14 16:34
1,3,5-Trimethylbenzene
ug/kg
ND
6.2
03/12/14 16:34
1,3-Dichlorobenzene
ug/kg
ND
6.2
03/12/14 16:34
1,3-Dichloropropane
ug/kg
ND
6.2
03/12/14 16:34
1,4-Dichlorobenzene
ug/kg
ND
6.2
03/12/14 16:34
2,2-Dichloropropane
ug/kg
ND
6.2
03/12/14 16:34
2-Butanone (MEK)
ug/kg
ND
124
03/12/14 16:34
2-Chlorotoluene
ug/kg
ND
6.2
03/12/14 16:34
2-Hexanone
ug/kg
ND
61.9
03/12/14 16:34
4-Chlorotoluene
ug/kg
ND
6.2
03/12/14 16:34
4-Methyl-2-pentanone (MIBK)
ug/kg
ND
61.9
03/12/14 16:34
Acetone
ug/kg
ND
124
03/12/14 16:34
Benzene
ug/kg
ND
6.2
03/12/14 16:34
Bromobenzene
ug/kg
ND
6.2
03/12/14 16:34
Bromochloromethane
ug/kg
ND
6.2
03/12/14 16:34
Bromodichloromethane
ug/kg
ND
6.2
03/12/14 16:34
Bromoform
ug/kg
ND
6.2
03/12/14 16:34
Bromomethane
ug/kg
ND
12.4
03/12/14 16:34
Carbon tetrachloride
ug/kg
ND
6.2
03/12/14 16:34
Chlorobenzene
ug/kg
ND
6.2
03/1211416:34
Chloroethane
ug/kg
ND
12.4
03/12/14 16:34
Chloroform
ug/kg
ND
6.2
03/12/14 16:34
Chloromethane
ug/kg
ND
12.4
03/1211416:34
cis- 1,2-Dichloroethene
ug/kg
ND
6.2
03/12/14 16:34
cis-1,3-Dichloropropene
ug/kg
ND
6.2
03/12/14 16:34
Dibromochloromethane
ug/kg
ND
6.2
03/12/14 16:34
Dibromomethane
ug/kg
ND
6.2
03/12/14 16:34
Dichlorodifluoromethane
ug/kg
ND
12.4
03/12/14 16:34
REPORT OF LABORATORY ANALYSIS
Qualifiers
;.
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 38

aceAnalytical
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QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
METHOD BLANK: 1155688
Associated Lab Samples: 92191736014
Parameter Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Diisopropyl ether
ug/kg
ND
6.2
03/12/14 16:34
Ethylbenzene
ug/kg
ND
6.2
03/12/14 16:34
Hexachloro-1,3-butadiene
ug/kg
ND
6.2
03/12/14 16:34
Isopropylbenzene (Cumene)
ug/kg
ND
6.2
03/12/14 16:34
m&p-Xylene
ug/kg
ND
12.4
03/12/14 16:34
Methyl-tert-butyl ether
ug/kg
ND
6.2
03/12/14 16:34
Methylene Chloride
ug/kg
ND
24.8
03/12/14 16:34
n-Butylbenzene
ug/kg
ND
6.2
03/12/14 16:34
n-Propylbenzene
ug/kg
ND
6.2
03/12/14 16:34
Naphthalene
ug/kg
ND
6.2
03/12/14 16:34
o-Xylene
ug/kg
ND
6.2
03/12/14 16:34
p-Isopropyltoluene
ug/kg
ND
6.2
03/12/14 16:34
sec-Butylbenzene
ug/kg
ND
6.2
03/12/14 16:34
Styrene
ug/kg
ND
6.2
03/12/14 16:34
tert-Butyl benzene
ug/kg
ND
6.2
0311211416:34
Tetrachloroethene
ug/kg
ND
6.2
03/12/14 16:34
Toluene
ug/kg
ND
6.2
03/12/14 16:34
trans-1,2-Dichloroethene
ug/kg
ND
6.2
03/12/14 16:34
trans-1,3-Dichloropropene
ug/kg
ND
6.2
03/12/14 16:34
Trichloroethene
ug/kg
ND
6.2
03/12/14 16:34
Trichlorofluoromethane
ug/kg
ND
6.2
03/12/14 16:34
Vinyl acetate
ug/kg
ND
61.9
03/12/14 16:34
Vinyl chloride
ug/kg
ND
12.4
03/12/14 16:34
Xylene (Total)
ug/kg
ND
12.4
03/12/14 16:34
1,2-Dichloroethane-d4 (S)
%
97
70-132
03/12/14 16:34
4-Bromofluorobenzene (S)
%
94
70-130
03/12/14 16:34
Toluene-d8 (S)
%
109
70-130
03/12/14 16:34
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1155689
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/kg
61.4
80.0
130
70-131
1, 1, 1 -Trichloroethane
ug/kg
61.4
74.5
121
70-141
1,1,2,2-Tetrachloroethane
ug/kg
61.4
77.1
126
70-130
1,1,2-Trichloroethane
ug/kg
61.4
78.0
127
70-132
1,1-Dichloroethane
ug/kg
61.4
70.4
115
70-143
1,1-Dichloroethene
ug/kg
61.4
67.4
110
70-137
1,1-Dichloropropene
ug/kg
61.4
68.5
112
70-135
1,2,3-Trichlorobenzene
ug/kg
61.4
69.3
113
69-153
1,2,3-Trichloropropane
ug/kg
61.4
75.2
122
70-130
1,2,4-Trichlorobenzene
ug/kg
61.4
67.0
109
55-171
1,2,4-Trimethylbenzene
ug/kg
61.4
74.8
122
70-149
1,2-Dibromo-3-chloropropane
ug/kg
61.4
72.8
119
68-141
1,2-Dibromoethane (EDB)
ug/kg
61.4
70.2
114
70-130
1,2-Dichlorobenzene
ug/kg
61.4
71.7
117
70-140
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 38

acmnalytical
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i
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
LABORATORY CONTROL SAMPLE:
Parameter
1155689
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloroethane
ug/kg
61.4
72.5
118
70-137
1,2-Dichloropropane
ug/kg
61.4
76.3
124
70-133
1,3,5-Trimethylbenzene
ug/kg
61.4
76.1
124
70-143
1,3-Dichlorobenzene
ug/kg
61.4
70.0
114
70-144
1,3-Dichloropropane
ug/kg
61.4
78.8
128
70-132
1,4-Dichlorobenzene
ug/kg
61.4
71.9
117
70-142
2,2-Dichloropropane
ug/kg
61.4
74.8
122
68-152
2-Butanone (MEK)
ug/kg
123
138
112
70-149
2-Chlorotoluene
ug/kg
61.4
72.3
118
70-141
2-Hexanone
ug/kg
123
150
122
70-149
4-Chlorotoluene
ug/kg
61.4
72.7
118
70-149
4-Methyl-2-pentanone (MIBK)
ug/kg
123
151
123
70-153
Acetone
ug/kg
123
127
103
70-157
Benzene
ug/kg
61.4
78.3
127
70-130
Bromobenzene
ug/kg
61.4
75.1
122
70-141
Bromochloromethane
ug/kg
61.4
70.9
115
70-149
Bromodichloromethane
ug/kg
61.4
75.0
122
70-130
Bromoform
ug/kg
61.4
70.2
114
70-131
Bromomethane
ug/kg
61.4
74.0
120
64-136
Carbon tetrachloride
ug/kg
61.4
71.4
116
70-154
Chlorobenzene
ug/kg
61.4
73.7
120
70-135
Chloroethane
ug/kg
61.4
70.9
115
68-151
Chloroform
ug/kg
61.4
72.0
117
70-130
Chloromethane
ug/kg
61.4
66.4
108
70-132
cis- 1,2-Dichloroethene
ug/kg
61.4
69.2
113
70-140
cis-1,3-Dichloropropene
ug/kg
61.4
77.9
127
70-137
Dibromochloromethane
ug/kg
61.4
71.8
117
70-130
Dibromomethane
ug/kg
61.4
70.4
115
70-136
Dichlorod ifluoromethane
ug/kg
61.4
66.1
108
36-148
Diisopropyl ether
ug/kg
61.4
67.8
110
70-139
Ethylbenzene
ug/kg
61.4
72.5
118
70-137
Hexachloro-1,3-butadiene
ug/kg
61.4
70.4
115
70-145
Isopropylbenzene (Cumene)
ug/kg
61.4
75.2
122
70-141
m&p-Xylene
ug/kg
123
147
120
70-140
Methyl-tert-butyl ether
ug/kg
61.4
83.7
136
45-150
Methylene Chloride
ug/kg
61.4
64.3
105
70-133
n-Butylbenzene
ug/kg
61.4
73.8
120
65-155
n-Propylbenzene
ug/kg
61.4
76.2
124
70-148
Naphthalene
ug/kg
61.4
73.4
120
70-148
o-Xylene
ug/kg
61.4
75.0
122
70-141
p-Isopropyltoluene
ug/kg
61.4
72.3
118
70-148
sec-Butylbenzene
ug/kg
61.4
75.7
123
70-145
Styrene
ug/kg
61.4
78.1
127
70-138
tert-Butylbenzene
ug/kg
61.4
77.7
126
70-143
Tetrachloroethene
ug/kg
61.4
76.2
124
70-140
Toluene
ug/kg
61.4
72.3
118
70-130
trans- 1,2-Dichloroethene
ug/kg
61.4
68.7
112
70-136
trans-1,3-Dichloropropene
ug/kg
61.4
80.3
131
70-138
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc..
Page 18 of 38

• o
w
aceAnalytical"
tt www.pacelabs.com
f
s
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
LABORATORY CONTROL SAMPLE: 1155689
Parameter Units
Trichloroethene
ug/kg
Trichlorofluoromethane
ug/kg
Vinyl acetate
ug/kg
Vinyl chloride
ug/kg
Xylene (Total)
ug/kg
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
61.4
73.5
120
70-132
61.4
70.3
114
69-134
123
631
514
24-161 F3,1-0
61.4
74.8
122
55-140
184
222
121
70-141
108
70-132
100
70-130
96
70-130
MATRIX SPIKE SAMPLE:
Parameter
1156372
Units
92192113003
Result
Spike
Cone.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1-Dichloroethene
ug/kg
ND
45.3
47.2
104
49-180
Benzene
ug/kg
ND
45.3
45.6
101
50-166
Chlorobenzene
ug/kg
ND
45.3
51.4
113
43-169
Toluene
ug/kg
ND
45.3
44.7
99
52-163
Trichloroethene
ug/kg
ND
45.3
46.8
103
49-167
1,2-Dichloroethane-d4 (S)
%
106
70-132
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
101
70-130
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 38

aceAnalytical o
tiwrw.pacetatrs.com
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: OEXT/26541
QC Batch Method: EPA 3510
Associated Lab Samples: 92191736014
METHOD BLANK: 1159043
Associated Lab Samples: 92191736014
Parameter
Units
Chlordane (Technical)
ug/L
Endrin
ug/L
gamma-BHC (Lindane)
ug/L
Heptachlor epoxide
ug/L
Methoxychlor
ug/L
Toxaphene
ug/L
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
LABORATORY CONTROL SAMPLE: 1159044
Parameter Units
Endrin
ug/L
gamma-BHC (Lindane)
ug/L
Heptachlor epoxide
ug/L
Methoxychlor
ug/L
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
QUALITY CONTROL DATA
a
Pace Analytical Services, Inc.
9800 Kincey Ave: Suite 100
Huntersville, NC 28078
[phone]
Analysis Method: EPA 8081
Analysis Description: 8081 GCS TCLP Pesticides
Matrix: Water
Blank
Result
Spike
Cone.
1.2
1.2
1.2
3.7
ND
ND
ND
ND
ND
ND
77
68
Reporting
Limit Analyzed
3.0
03/18/1412:24
0.50
03/18/1412:24
0.50
03/18/1412:24
0.50
03/18/1412:24
1000
03/18/1412:24
3.0
03/18/1412:24
10-138
03/18/1412:24
10-110
03/18/1412:24
LCS LCS
Result % Rec
1.2 94
0.96 78
0.94 76
ND 86
79
67
Qualifiers
% Rec
Limits Qualifiers
20-134
20-118
22-133
44-150
10-138
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1159045
1159046
MS
MSD
92191736014
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qua]
Endrin
ug/L
ND
1.2
1.2
1.2
1.2
96
100
21-133
3
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
0.97
1.0
79
81
24-119
3
Heptachlor epoxide
ug/L
ND
1.2
1.2
0.95
0.96
77
78
50-150
1
Methoxychlor
ug/L
ND
3.7
3.7
ND
ND
87
88
50-150
Decachlorobiphenyl (S)
%
82
91
10-138
Tetrachloro-m-xylene (S)
%
69
75
10-110
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 38

,alMnalytical"
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QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: OEXT/26540 Analysis Method: EPA 8270
QC Batch Method: EPA 3510 Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92191736014
METHOD BLANK: 1159039
Associated Lab Samples: 92191736014
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
03/18/14 10:05
2,4,5-Trichlorophenol
ug/L
ND
50.0
03/18/14 10:05
2,4,6-Trichlorophenol
ug/L
ND
50.0
03/18/14 10:05
2,4-Dinitrotoluene
ug/L
ND
50.0
03/18/14 10:05
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
03/18/14 10:05
3&4-Methylphenol(m&p Cresol)
ug/L
ND
50.0
03/18/14 10:05
Hexachloro-1,3-butadiene
ug/L
ND
50.0
03/18/14 10:05
Hexachlorobenzene
ug/L
ND
50.0
03/18/14 10:05
Hexachloroethane
ug/L
ND
50.0
03/18/14 10:05
Nitrobenzene
ug/L
ND
50,0
03/18/14 10:05
Pentachlorophenol
ug/L
ND
100
03/18/14 10:05
Pyridine
ug/L
ND
50.0
03/18/14 10:05
2,4,6-Tribromophenol (S)
%
75
27-108
03/18/14 10:05
2-Fluor6biphenyl (S)
%
73
13-107
03/18/14 10:05
2-Fluorophenol (S)
%
42
10-110
03/18/14 10:05
Nitrobenzene-d5 (S)
%
74
12-102
03/18/14 10:05
Phenol-d6 (S)
%
29
10-110
03/18/14 10:05
Terphenyl-d14 (S)
%
86
21-132
03/18/14 10:05
LABORATORY CONTROL SAMPLE: 1159040
Parameter
1,4-Dichlorobenzene
ug/L
2,4,5-Trichlorophenol
ug/L
2,4,6-Trichlorophenol
ug/L
2,4-Dinitrotoluene
ug/L
2-Methylphenol(o-Cresol)
ug/L
3&4-Methylphenol(m&p Cresol)
ug/L
Hexachloro-1,3-butadiene
ug/L
Hexachlorobenzene
ug/L
Hexachloroethane
ug/L
Nitrobenzene
ug/L
Pentachlorophenol
ug/L
Pyridine
ug/L
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
Date: 03/27/2014 09:11 AM
Spike
Units Conc.
LCS
Result
500
363
500
402
500
360
500
468
500
395
500
369
500
321
500
394
500
357
500
398
1000
520
500
185
LCS
% Rec
Qualifiers
% Rec
Limits
73 10-110
80 39-108
72 40-104
94 42-109
79 31-110
74 30-110
64 10-110
79 39-121
71 10-110
80 32-101
52 18-108
37 10-110
78 27-108
80 13-107
45 10-110
76 12-102
38 10-110
80 21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 21 of 38

aceAnalytical
1 www.pecolobs.com
1
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
1,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
2-Methyl pheno I (o-Cresol)
3&4-Methylphenol(m&p
Cresol)
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachloro phenol
Pyridine
2,4,6-Tribromophenol (S)
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
Date: 03/27/2014 09:11 AM
QUALITY CONTROL DATA
1159048
MS
92193031001
Spike
Units
Result
Conc.
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
1000
ug/L
ND
500
MSD
Spike
Conc.
500
500
500
500
500
500
500
500
500
500
1000
500
1159049
MS
Result
370
426
381
489
378
361
334
407
353
399
798
242
MSD
Result
249
295
261
438
223
211
222
357
233
261
737
149
MS
% Rec
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
74
85
76
98
76
72
67
81
71
80
80
48
85
77
53
75
43
89
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MSD
% Rec
% Rec
Limits
RPD Qual
50
30-150
39 R1
59
30-150
36 R1
52
30-150
37 R1
88
30-150
11
45
30-150
52 R1
42
30-150
52 R1
44
30-150
40 R1
71
30-150
13
47
30-150
41 R1
52
30-150
42 R1
74
30-150
8
30
30-150
48 R1
74
27-108
51
13-107
35
10-110
50
12-102
27
10-110
77
21-132
Page 22 of 38

aceAnaljdical
www.pacetabs.com
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: PMST/6324 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191736014
SAMPLE DUPLICATE: 1152372
Parameter
Percent Moisture
SAMPLE DUPLICATE: 1152373
Parameter
Percent Moisture
Date: 03/27/2014 09:11 AM
92192237001 Dup
Units Result Result
20.2 18.4
92192252015 Dup
Units Result Result
22.0 21.3
RPD Qualifiers
10
RPD Qualifiers
3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 38

aceAnalytical
www.pacclabs.com
i
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: PMST/6325 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191736001, 92191736002, 92191736003, 92191736004, 92191736005, 92191736006
SAMPLE DUPLICATE: 1152377
92191704005 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 70.0 71.2 2
SAMPLE DUPLICATE: 1152378
92192299004 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 12.7 10.6 18
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 38

;acieAnalyfical
www.pacetatrs.cam
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: PMST/6403 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191736015
SAMPLE DUPLICATE: 1165215
Parameter
Percent Moisture
Date: 03/27/2014 09:11 AM
92191736015 Dup
Units Result Result
56.2 57.2
RPD Qualifiers
2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 38

aceAnalytical
www.pawlabs.com
4
i
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: RBIO/3734 Analysis Method: SM9221C E (MPN) 503
QC Batch Method: SM9221C E (MPN) 503 Analysis Description: 92210E Fecal Coliform, MPN Solid
Associated Lab Samples: 92191736001, 92191736002, 92191736003, 92191736004, 92191736005, 92191736006, 92191736015
METHOD BLANK: 1151531 Matrix: Solid
Associated Lab Samples: 92191736001, 92191736002, 92191736003, 92191736004, 92191736005, 92191736006, 92191736015
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms, MPN MPN/g ND 0.018 03/04/14 14:53
LFi=2 00)Wilker,Eto ]IIIVlul
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 26 of 38

k I 1
1
Pace Analytical Services, Inc.
g �+ I® 9800 Kincey Ave. Suite 100
J aCV AnalXica Huntersville, NC 28078
www.pacelabs.com. [phone]
}
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: WET/29893 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92191736014
SAMPLE DUPLICATE: 1153848
92191736014 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 5.7 5.9 3 D6,H1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 38

aceAnalytical
www.pacelabs.com
I
s
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: WETAN 8277
QC Batch Method: EPA 350.1
Associated Lab Samples: 92191736014
METHOD BLANK: 1152945
Associated Lab Samples: 92191736014
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 1152946
Parameter Units
Nitrogen, Ammonia mg/kg
1 q
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 03/07/1417:53
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
500 527 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152947 1152948
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg ND 1500 1500 1450 1470 94 96 90-110 1
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 28 of 38

Q
aceAnalytical
www.pacelabs.com
I
QUALITY CONTROL DATA
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: WETA/18343 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92191736014
METHOD BLANK: 1156852
Associated Lab Samples: 92191736014
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 1156853
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 03/14/1411:13
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 1050 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1156854 1156855
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 6490 2070 1000 9030 9020 123 252 90-110 0 M1
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 29 of 38

QD
a(eAnalytical
www.pacelabs.com
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: WETA/18438
QC Batch Method: EPA 353.2
Associated Lab Samples: 92191736014
METHOD BLANK: 1162435
Associated Lab Samples: 92191736014
Parameter Units
Nitrogen, Nitrate mg/kg
Nitrogen, Nitrite mg/kg
Nitrogen, NO2 plus NO3 mg/kg
QUALITY CONTROL DATA
Analysis Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite
Matrix: Solid
Blank Reporting
Result Limit Analyzed
ND 2.0 03/21/1418:39
ND 1.0 03/21/1418:39
ND 2.0 03/21/1418:39
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1162436
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 25 24.9 100 90-110
Nitrogen, Nitrite mg/kg 10 9.9 99 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 24.9 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1162437
MS
92192828001
Spike
Parameter
Units
Result
Conc.
Nitrogen, Nitrate
mg/kg
ND
50.8
Nitrogen, Nitrite
mg/kg
ND
21.4
Nitrogen, NO2 plus NO3
mg/kg
ND
50.8
Date: 03/27/2014 09:11 AM
1162438
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits RPD
50.8
51.5
52.2
101
103
90-110 1
21.4
22.0
22.0
103
103
90-110 0
50.8
51.5
52.2
101
103
90-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 30 of 38

;�;aneAnalyticalo
www.pacelabs.com
i
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
QC Batch: WETA/18394
QC Batch Method: EPA 365.1
Associated Lab Samples: 92191736014
METHOD BLANK: 1158573
Associated Lab Samples: 92191736014
Parameter Units
Phosphorus mg/kg
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
Matrix: Solid
EPA 365.1
365.1 Phosphorus, Total
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.0 03/18/1411:08
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1158574
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Phosphorus mg/kg 50 50.8 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158575 1158576
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 1790 301 301 2270 1940 160 49 90-110 16 M1
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 31 of 38

Pace Analytical Services, Inc.
aceAnalX cal " 9800 Kincey Ave. Suite 100
Huntersville, NC 28078078
www.pecelabs.com [phone]
f
QUALIFIERS
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL- Pace Reporting Limit.
RL- Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated, from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-R Pace Analytical Services - Raleigh
ANALYTE QUALIFIERS
1g 8260 results are from a total analysis which show that analytes are not present or that they are present but at such low
levels that the appropriate regulatory levels could not possibly be exceeded, per Section 1.2 of Method 1311.
2g This is a less than value.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
F3 The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.
H1 Analysis conducted outside the EPA method holding time.
10 The internal standard response was outside the laboratory acceptance limits confirmed by reanalysis. The results
reported are from the most QC compliant analysis.
LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2014 09:11 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 38

c q y
aceAnalytical
1 www.pacetabs.wm.
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Fecal Sludge Thomas WTP
Pace Project No.: 92191736
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92191736014
Lagoon #2
EPA 3510
0EXT/26541
EPA 8081
GCSV/16988
92191736014
Lagoon #2
EPA 3050
MPRP/15396
EPA 6010
ICP/13959
92191736014
Lagoon#2
EPA3010
MPRP/15410
EPA6010
ICP/13974
92191736014
Lagoon#2
EPA7470
MERP/6298
EPA7470
MERC/6073
92191736014
Lagoon#2
EPA7471
MERP/6288
EPA7471
MERC/6068
92191736014
Lagoon #2
EPA 3510
OEXT/26540
EPA 8270
MSSV/8883
92191736014
Lagoon #2
EPA 8260
MSV/26058
92191736014
Lagoon #2
EPA 8260
MSV/26068
92191736001
Lagoon # F1
ASTM D2974-87
PMST/6325
92191736002
Lagoon # F2
ASTM D2974-87
PMST/6325
92191736003
Lagoon # F3
ASTM D2974-87
PMST/6325
92191736004
Lagoon # F4
ASTM D2974-87
PMST/6325
92191736005
Lagoon # F5
ASTM D2974-87
PMST/6325
92191736006
Lagoon #2 F6
ASTM D2974-87
PMST/6325
92191736014
Lagoon #2
ASTM D2974-87
PMST/6324
92191736015
Fecal Sludge F7
ASTM D2974-87
PMST/6403
92191736001
Lagoon # F1
SM9221C E (MPN) 503
RBI0/3734
92191736002
Lagoon # F2
SM9221C E (MPN) 503
RBI0/3734
92191736003
Lagoon # F3
SM9221C E (MPN) 503
RBI0/3734
92191736004
Lagoon # F4
SM9221C E (MPN) 503
RBI0/3734
92191736006
Lagoon # F5
SM9221C E (MPN) 503
R13I0/3734
92191736006
Lagoon #2 F6
SM9221C E (MPN) 503
RBI0/3734
92191736015
Fecal Sludge F7
SM9221C E (MPN) 503
RBI0/3734
92191736014
Lagoon #2
SM 254OG
WET/29869
92191736014
Lagoon #2
EPA 9045
WET/29893
92191736014
Lagoon #2
40CFR PART 432.2
WET/30157
92191736014
Lagoon #2
EPA 350.1
WETA/18277
92191736014
Lagoon #2
EPA 351.2
WETA/18343
92191736014
Lagoon #2
EPA 353:2
WETA/18438
92191736014
Lagoon #2
EPA 365.1
WETA/18394
Date: 03/27/2014 09:11 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 33 of 38

;RCA8_ ,6�11
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL. DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C
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'Imoortan[ Note: By 5iun4w this corm you are acceouno Pace's NET 90 day c rvrnerl terms and aoreeina to late charges d 1.5A Der mordy(or any invorces nat oaid- wnF n 90 days.
! / F-ALL-Q-020rev.07, 15-May-2007

CHAIN -OF -CUSTODY I Analytical Request Document
laceAnalyfical w The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
1
- rv+w.paeareos.rnro -
Section A Section B section C
Required Client lnformallon: Required Project Information: Invoice Information:
COPy_ - "d A Report To: A
r Y "f+'fS
- -
Paga of
i Z
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dress:
JZ@i .fo H? w
Copy To:
mpany Name:
C WS 1tiovkAS uJTI°
REGULATORY AGENCY '
-S NC Z7Jd
J�41L
I- NPDES r- GROUND WATER 'f • DRINKING WATER
F' UST RCRA iW OTFIER
$Ile Locat(oa
STATE:
Emil To: j!
tt.►9
Phone: Fax —f
1y7-927
Requested Du■ DateFTAT:
Purchase Order
Project Name:
Project Number.-
Paw Quote
Reference: QL7e�la
Paw Project
Manarfar.
Pace Prome p:
Requested
Analysis
Filtered
(YIN)
'
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Section D Matrix Codes
"tf-dClient InfoRnWon UMBIX r CODE
Drinking Water DW
Water VVT Waste Water 'NW
Product P
So USoIId SL
SAMPLE'ID ,°Nrl� °`VJP
(&Z.0-9!.) Air TS
Sample IDS MUST BE UNIQUE Tissue TS
Other OT
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ADDITIONAL COMMENTS
R UISHED UY r AF•FIIJATION
DATE
TIME
ACCS<iIED BY! FILIATION
DATE
TIME
SAMPLE CONDITIONS
ORIGINAL
SAMPLER NAME AND SIGNATURE
U
6
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a
PRINT Name of SAMPLER:
SIGNATURE WSAMPLE
DATE Signed
(MMJDD1Y1f): 40
Ninnn.rnM +J.Ju• A� .] — lhle.nnn v.vr arw --file. PAWS NET W day oavmer�t lP end Aareainp to late [harCee ai 7S10 per maldi fw Ay UNaoes rJ paid wit n W days• J / 1--ALL-Wirturev.ur, -I o-may-cuu+
II i

f Document Name: Sample Condition Upon Document Revised: April 04, 2013
/ r,F�aceArzalyiical d Receipt (SCUR) Pa e 2 of 2
tIM1YLY.pF1COALfRCCA1 Document No: issuing Authorities:
F-RAL-CS-001-rev.02 Pace Asheville Qual'�t Office
. •
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OR
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125 mi Plastic Unp: BP4U
250 MI Plastic Unp: BP3U
500 ml Plastic Unp: BP2U
1 Liter Plastic Unp: 5P1U
250 ml Plastic H2304: BP3S
250 ml Plastic HNO3: BP3N
250 ml Plastic ZN Acetate: BP37-
250 mi Plastic NaOH: SP30
Wide mouthed glass jar urip: WGFU
1 Liter Amber Unp: AG1U
40 ml VOA H2SO4; OG9S
1 Liter Amber HCI: AG1H
5035 Kit: VOAK
500 ml Amber Unp: AG21.1
VPH 1 Gas Kit: V1GK
1 Liter Amber H2SO4: AGI S
125 ml Sterile Plastic: SP5T
250 ml Amber H2SO4: AM
250 mi Sterile Plastic: SP2T
250 ml Amber NH4CL: AGM
40 ml VOA H01: 009H
40 ml VOA N62S203: VG9T
40 mi VOA Unp: VG9U
Page 36 of 38

gE }o LE a6ed
Document Name: Sample Condition Upon
Document Revised: April 04, 2013
2!'FaaZeAnaocal
Recei t SCUR
Pa e 1 of 2
www.nnca�tsa eo",
Document No.: •
issuing Authorities:
+
F-RAL-CS-001-rev.02
Pace Asheville QualU Office
Client Name:N_ &=
Where Received: Huritersville [] Asheville' Eden Raleigh• _
Courier (Circle): Fed Ex ZIPS USPS Client Commercial Pace Other
Custody Seal on Cooler/Box Present: C] yes V no Seals Intact: A yes 0 no
Packing Material: Bubble Wrap gs 4 None Other
Circle Thermometer Used: IR Gun S 122065387T a of Ice: Wet Blue None Samples on fee, cooling process has begun
Temp Correction Factor:, Add 1r ubtract . _ C
Corrected Cooler Temp.: C Biological Tissue is Frozen: Yes No WA
Temp should be above freezing to 6°C Comments:
Rate and Initials of pe�rsoh examining
ca 1 Pre
check
Chain of Custody Present:
es [IN,
ONrA
1,
Chain of Custody Filled Out:
Yes DNo
❑N1A
2. '
Chain of Custod Relinquished:
Yes ON,
❑rirA
3.
Sampler Name & Signature on COC:
Yes ON.
❑wA
4.
Samples Arrived within Hold Time:
Yas ❑No
❑wA
5.
Short Hold Time Artalysls <72hr :
Yes No
❑wA
B.
Rush Tuni Around Time. Requested:
Yes ❑No
DwA
7.
Suffid€ent Volume:
Yes Ow
❑wA
8•
Correct Containers Used:
-Pace Containers Used:
Ayes ❑No
Yes ❑No
❑N/A
❑wA
9.
Containers intact:
Yes ©No
ONiA
10,
Filtered volume -received for Dissolved tests
❑Yes 13No
wA
11.
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
All containers needing preservatlon have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA, colifonn, Too, 00. Wl IDR0 (water)
�Yes DNo
r
[]No
/Y"
es ❑No
Yes ❑No
ON/A
❑NIA
ON/A
12.
13.
Samples checked for dechlorination:
Yes DNo
❑NIA
14.
Heads ace In VOA Vials >6mm
❑Yes ON*
ANIA
15.
Trip Blank Present:
Trip Blank Custody Seals Present
Race Trip Blank Lot # (ifpurchased):
❑Yea ❑No
Oyes ❑No
�WA
VIN/A
16.
Client Notification/ Resolution:
Field Data Required? Y J N
Person Contacte& ----
Commenis/ Resolution:
SCURF w,: f Date:
Review:: J
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina REHNR
Certification Office ( i-e out of hold, Incorrect preservative, out of temp,
incorrect containers)
Place label here
Handwrite project number
(If no label available)
0 `, L I w

Document Name: Sample Condition Upon
Document Revised: April 04; 2013
Receipt SCUR
Pa e 2 of 2
aCBfifkilj�ICatr;
•p�u
Document No.:
[ssOng Authorities:
F-RAL-CS-001-rev.02
Pace Asheville Qua& Office
as
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Client Sample ID(sJ
Sample Discre anc
pH Adjustment Lag for Preserved Samples
Sample ID
Type of
Preservative
pH upon
receipt
Date preservation
Adjusted
Time Preservation
Adjusted
Amount of
Preservative edded
Lot# of
PreservatIVO
Bottle Code Key
125 mi Plastic Unp: BP4U
250 ml Plastic Unp: BP3U
500 ml Plastic Unp; SP2U
1 Liter Plastic Unp: 13131 U
250 ml Plastic H2SO4: BP3S
250 ml Plastic HNO3: BP3N
250 ml Plastic ZN Acetate: BP3Z
250 ml Plastic NaOH: BP3C
Wide mouthed glass jar unp: WGFU
1 Liter Amber Unp: AG1 U
1 Liter Amber HCI: AG H
500 ml Amber Unp: AG2U
1 LiterAmber H2SC)4: AG1S
250 ml Amber H2SO4: AG3S
250 mi Amber NH4CL: AGM
40 mi VOA HCI: DG9H
40 ml VOA Na2S2O3: VG9T
40 ml VOA Unp: VG9U
40 mi VOA H2SO4: EMS
5035 Kit: VOAK
VPH / Gas Kit: V/GK
125 ml Sterile Plastic: SPST
250 ml Sterile Plastic: SP2T
Page 38 of 38

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CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQD031314 FACILITY NAME: _ City of Winston-Salem - Neilson Water Treatment Plant
PHONE: [phone] COUNTY: Forsyth OPERATOR: Rodney C. Darr
FACILITY TYPE (please check one): Z Surface Disposal (complete Part A (Source(s) and "Residual in" Volume only) and Part C)
Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes u No Lj --op- If No skin parts A. B. C and certify form below
Part A*•
Part B*: — -
Month
Sources(s) (include NPDES # if
applicable)
(drytons
Recipient Information
����vVolume
Amendment/
Agent
BuIldngJanuary
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
February
March
April
May
June
R.W Neilson WTP 4 NCO086011
0
1044
1044
4561 Cooper Rd
1044
Fescue
July
August
September
October
November
December
Total from FORM DMSDF (sn )
Totals: Annual d tons :
0
1044
1044
1044
Amendment(s) used:
Bulking A s used:
- it more space is required, attach addition information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit E Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No —o If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
111 certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
of P ittee � #
1'�e Signature of Preparer* Date
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM DMSDF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional_ parameters to be analyzed. T-he:parameters can be -reported in.FORM RSSF.- B
WQ Permit Number: WQ0031314 Laboratory:
Facility Name: Neilson Water Treatment Plant.
Residual Source WQ # or NCO086011
NPDES #:
MAWAV 100
Recirinnl Annlvcia lnntn
1) Pace Analytical ID # 12
2)
3)
4)
5)
Parameter
(mg/kg)
Ceiling
Conc.
Limit
Sample or Composite Date
3/4/14
Percent Solids (%)
NA
34
Arsenic
75
<2.8
Cadmium
85
<0.28
Copper
4,300
36.4
Chromium
NA
<.025
Lead
840
21.3
Mercury
57
0.021
Molybdenum
75
<1.4
Nickel
420
11.5
Selenium
100
<2.8
Zinc
7,500
100
Total Phosphorus
NA
1790
TKN
NA
6490
Ammonia -Nitrogen
NA
<30.1
Nitrate and Nitrite
NA
<6.0
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to. 'assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submittin se information, including the possibility of fines and imprisonment for knowing violations."
a
Signature of Preparer * Date
J *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENRFORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B "
Report all sampling analysis results for parameters not listed in FORM RSSF,that are _part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WO0031314
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Recirinal Analvaic data
Neilson Water Treatmetri Plant
NC0086011
Laboratory: 1) Pace Analytical ID#12
2)
3)
4)
5)
Parameter
Sampleor • •• Date
• 11
-------�---
Potassium1
--5--------
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information -submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
47 *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .l 102 (26)
Date
DENR FORM RSSF - B (12/2006)

4NNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: tNeilson Water Treatment Plant WQ Permit Number: WQ0031314
WWTP Name:
N/A
NPDES Number:
NCO086011
Monitoring Period: From 7/1/2012 To 6/30/2013
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 El...........
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic
Beta Ray ❑
Gamma Ray ElPasteurization
Y
❑
Class B:
Alternative 1 ❑
Alternative 2' ❑
If applicable to alternative performed (Class B only) indicate "Pro_ cess to Significantly Reduce Pathogens":
Lime Stabilization ❑ Air Drying❑
Composting ❑ Aerobic Digestion ❑
Anaerobic Digestion
n El
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
Sludge
g
Pathogen Density
Number ot
Excee-
Frequency
of Analysis
Y
Sample
Type
Trialytical
Tech-
Minimum
Geo. Mean
Maximum
Unitsences
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
6.1
6.34
7.1
MPN/g
0
yearly
grab
M9221 C
Salmonella bacteria
(in lieu of fecal
coliform)
3' MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.l (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. 02 uptake) ❑
Alt. 5 (14-Day Aerobic) El
Alt. 6 (Alk. Stabilization Q
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying' - Unstable) ElAlt.
9 (Injection) ❑
Alt. 10 (Incorporation) 0
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector .
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Preparer Name and T' e (type or print)
C
Signature of Preparer*
Land Applier Name and Title (if applicable)(type or print)
'io 1S
Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

PAN
Mineralization
as decimal
ITotal dry
tons/year
jAcres
Applied on
1 5
Rate
0.4
TKN
6490
NH3
30.1
NO3
0
NO2
0
% Solids
0.125
1 1044
PAN Surface
2599.01 mg/kg 5.19802 Ibs/dry ton
5426.7331 Ibs total PAN
1085.347 Ibs PAN/acre
PAN Injection
2614.06 rng/kg 5.22812 Ibs/dry ton
5458.157 Ibs total PAN
1091.631 Ibs PAN/acre
Dry Tons/1000 gal.
0.52125
1st year PAN
Surface lbs.
5426.73288
1st year PAN
Injected Ibs.
5458.15728
Ibs./acre
Surface
1085.346576
Ibs./acre
Injected
1091.631456
MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal."
2000

SAR & ESP
Sodium Absorption Ratio
Na(Mg/L) Ca(Mq/L)
M9(M9/L)
Na : Sodium (Mg/L) ' Equivalent weight: 23
23. 20
12
Ca: Calcium (Mg/L) Equivalent weight: 20 .
Mg : Magnesium (Mg/L) Equivalent weight: 12
Na ME
Ca (ME)
Mg
Na (ME) Ca ME Mg
5 20' 3
(ME)

AnalyticalTM
)acelabs.com
Sold To:
Mr. Bill Brewer
City of Winston Salem
2800 River Ridge Rd.
Pfafftow5l NC 27040
INVOICE Pace Analytical Services, Inc.
9800 Kincey Ave., Suite 100
Huntersville, NC 28078
Phone:[phone]
Invoice Number: 149375316
Date: 03/1812014
Total Amount Due: $525.00
Please Remit To:
Pace Analytical Services, Inc.
P.O. Box 684056
Chicago, IL 60695-4056
Client Numtiei/Client=lU
=Furchase_Orde,f.No`�
''Pace.Pro ect'M"r:'r••.., _':_'»{ "
;,Temrs `
92-617227 / 92-WINSTON-S
Terri Page
Net 30 Days**
1
Client Project: Fecal'Sludge 03/04/2014 Client Name: City of Winston Salem
Pace Project No: 92191704 Sample Received: 3/4/2014
Report Sent To: Mr. Kenny Atkins, City of Winston Salem
Comments:
ANALYTICAL CHARGES
Quantity Unit Description Method Matrix Price Total
7 Ea 92210E Fecal Coliform, MPN SM9221C E (MPN) 503 Solid $75.00 $525.00
Analytical Subtotal $525.00
Total Number of Charges 7 Total Invoice Amount $525.00
Samples Received for analysis:
Lab lD
Client Sample ID Received
92191704001
Fecal.1
3/41201411:10:00
92191704002
Fecal2
3/4/201411:10:00
92191704003
Fecal3
3/4/201411:10:00
92191704004
Feca14
3/4/201411:10:00
92191704005
Fecal5
3/4/201411:10:00
92191704006
Fecal6
3/4/201411:10:00
92191704007
Fecal8
3/4/201411:10:00
de
/f you have any questions or to pay by credit card, please contact Terri Page at Pace.
Phone: [phone] Email: [e-mail]
Page 1 of 1
**1.6% MONTHLY FINANCE CHARGE ASSESSED AFTER 30 DAYS OR TERMS OF CONTRACT.
PLEASE REFERENCE THE INVOICE NUMBER ON ALL.REMITTANCE ADVICE.
AN EQUAL OPPORTUNITY EMPLOYER
Please complete and return copy of invoice with your payment.
'INVOICE TOTAL $525.00
Amount Paid: $
Check No:
Customer No: 92-617227 Invoice No: 149375316

c
acmnalytical
www.pacelabs.com
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Raleigh Certification IDs
6701 Conference Drive Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
CERTIFICATIONS
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 14

aceAnalytical
www.pecelabs.com
March 10, 2014
Mr. Kenny Atkins
City of Winston Salem
1201 South MLK Jr. Dr.
Winston Salem, NC 27107
RE: Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Dear Mr. Atkins:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
S'tdkan�- 9. d
Brittany Gibson for
Terri Page
[e-mail]
Project Manager
Enclosures
cc: Mr. Bill Brewer, City of Winston Salem
Ms. Mattie Shamel, City of Winston Salem
AURFO�
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 14

�.
Pace Analytical Services, Inc.
aceAnalytical ®
9800 KinceyAve. Suite 100
Huntersville, NC 28078
www.paWabs.com
[phone]
ANALYTICAL RESULTS
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Sample: Fecal 1
Lab ID: 92191704001 Collected: 03/04/14 07:30
Received:
03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qua]
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
64.8 % 0.10 1
03/07/14 15:37
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
6.3 MPN/g 0.051 1
03/04/14 14:53 1g
Sample: Fecal 2
Lab ID: 92191704002 Collected: 03/04/14 07:30
Received:
03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
64.4 % 0.10 1
03/07/14 15:37
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
6.2 MPN/g 0.051 1
03/04/14 14:53 1g
Sample: !Fecal 3
Lab ID: 92191704003 Collected: 03/04/14 07:30
Received:
03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
64.0 % 0.10 1
03/07/14 15:37
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
6.1 MPN/g 0.050 1
03/04/14 14:53 1g
Sample: Fecal 4 Lab ID: 92191704004 Collected: 03/04/14 07:30 Received: 03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 69.0 % 0.10 1 03/07/14 15:37
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 7.1 MPN/g 0.058 1 03/04/14 14:53 1g
Date: 03/10/2014 09:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 14

PaceAnalytic9l Services,)lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
acmnalytical
w w.pecelabs.=n
SAMPLE ANALYTE COUNT
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92191704001
Fecal 1
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704002
Fecal 2
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704003
Fecal 3
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704004
Fecal 4
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704005
Fecal 5
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704006
Fecal 6
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
92191704007
Fecal 8
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
LJI
1
PASI-R
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 14

aceAnalytical
www.pacelabs.c=
QUALITY CONTROL DATA
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
QC Batch: PMST/6325 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191704005
SAMPLE DUPLICATE: 1152377
Parameter
Percent Moisture
SAMPLE DUPLICATE: 1152378
Parameter
Percent Moisture
Date: 03/10/2014 09:37 AM
92191704005 Dup
Units Result Result
% 70.0 71.2
92192299004 Dup
Units Result Result
% 12.7 10.6
RPD Qualifiers
2
RPD Qualifiers
18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 14

acmnalytical
www.pacalabscom
ANALYTICAL RESULTS
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Pace 4nalytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: Fecal 5
Lab ID: 92191704005 Collected: 03/04/14 07:30
Received:
03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units Report Limit
DF
Prepared
Analyzed CAS No. Qua]
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
70.0 % 0.10
1
03/07/14 15:00
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
7.4 MPN/g 0.060
1
03/04/14 14:53 1g
Sample: Fecal 6
Lab ID: 92191704006 Collected: 03/04/14 07:30
Received:
03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units Report Limit
DF
Prepared
Analyzed CAS No. Qua[
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
63.5 % 0.10
1
03/07/14 15:37
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
6.0 MPN/g 0.049
1
03/04/14 14:53 1g
Sample: Fecal 8 Lab ID: 92191704007 Collected: 03/04/14 07:30 Received: 03/04/14 11:10 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 67.2 % 0.10 1 03/07/14 15:38
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 6.7 MPN/g 0.055 1 03/04/14 14:53 1g
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/10/2014 09:37 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 14

lacieAnalytical"
www.paWabs.com
QUALITY CONTROL DATA
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: RBIO/3734 Analysis Method: SM9221C E (MPN) 503
QC Batch Method: SM9221C E (MPN) 503 Analysis Description: 92210E Fecal Coliform, MPN Solid
Associated Lab Samples: 92191704001, 92191704002, 92191704003, 92191704004, 92191704005, 92191704006, 92191704007
METHOD BLANK: 1151531 Matrix: Solid
Associated Lab Samples: 92191704001, 92191704002, 92191704003, 92191704004, 92191704005, 92191704006, 92191704007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms, MPN MPN/g ND 0.018 03/04/14 14:53
Date: 03/10/2014 09:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 14

aceAnalytical
www.pacalabs.com
QUALITY CONTROL DATA
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
QC Batch: PMST/6326 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191704001, 92191704002, 92191704003, 92191704004, 92191704006, 92191704007
SAMPLE DUPLICATE: 1152402
92191700001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 65.7 71.3 8
SAMPLE DUPLICATE: 1152403
Parameter
Percent Moisture
Date: 03/10/2014 09:37 AM
92192267002 Dup
Units Result Result
% 92.4 89.9
RPD Qualifiers
3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1 ,
Pace Analytical Syervices, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 14

aceMalXical
www.pacalabs.c=
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92191704001
Fecal 1
ASTM D2974-87
PMST/6326
92191704002
Fecal 2
ASTM D2974-87
PMST/6326
92191704003
Fecal 3
ASTM D2974-87
PMST/6326
92191704004
Fecal 4
ASTM D2974-87
PMST/6326
92191704005
Fecal 5
ASTM D2974-87
PMST/6325
92191704006
Feca16
ASTM,D2974-87
PMST/6326
92191704007
Fecal 8
ASTM D2974-87
PMST/6326
92191704001
Fecal 1
SM9221C E (MPN) 503
RBIO/3734
92191704002
Fecal 2
SM9221C E (MPN) 503
R13I0/3734
92191704003
Fecal 3
SM9221C E (MPN) 503
R13I0/3734
92191704004
Feca14
SM9221C E (MPN) 503
RBIO/3734
92191704006
Fecal 5
SM9221C E (MPN) 503
R13I0/3734
92191704006
Fecal 6
SM9221C E,(MPN) 503
RBIO/3734
92191704007
Fecal 8
SM9221 C E (MPN) 503
R1310/3734
Date: 03/10/2014 09:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
Page 10 of 14

acemalXical
www.pacWabs.com
QUALIFIERS
Project: Fecal Sludge 03/04/2014
Pace Project No.: 92191704
L7�1�1.1��[�lib9
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
PASI-R Pace Analytical Services - Raleigh
ANALYTE QUALIFIERS
1g This is a less than value.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/10/2014 09:37 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 14

0
i+
aceAaalytrcal `
ww►.pwAtnnn
CHAIN -OF CUSTODY /Analytical Request Document
7N Chahof C study is a LEGAL DOCUMENT. All wtevwd 10a must be convicted xwroEety.
'L. IL 1IN
Matrix Cod"
D"In2wator ON
Wader wr
Product P—
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■■■■■!■■■
■■.M■M■■M.M■K
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FlInal"M
F ALL-0A20rev.07,154Aay-2W7

,�� ac�Atral�ical`
Document Name: Sample Co
Receipt SCUR)
'Document No.:
i=-RAL-CS-001-rev.
IMOMMME
WGUMMEME
IONEMMMIM
"DMEMEMIMINUMEMEMEN
©OMMMM■ IMMUMMMMEN
Revised: April 04, 20
Page 2 of 2
,ping Authorities:
:havilie Qualllty Office
t�ODaa
C�>>�cn
a
rn
Ca
•}
L
m
a
ro
tM
Y
F-
F-
Client Sample 10 s
Sample DiscrePancY
pH Adjustment Log for Preserved Samples
Sample ID Type of pH upon Date preservation Time Preservation Amount of Lot# of
Preservative reoeipt Adjusted Adjusted preservative added Preservative
Bottle Code Key
125 ml Plastic Unp: BP4U
250 ml Plastic Unp: BP3U
500 mi Plastic Unp: BP2U
1 Liter Plastic drip: BP1U
250 ml Plastic H2SO4: BP38
250 ml Plastic HNO3: BP3N
250 ml Plastic ZN Acetate: 5P3Z
250 ml Plastic NaOH: BP3C
Wide mouttied glass Jar unp: ►/VGFU
1 Liter Amber Unp: AG1U
40 mi VOA H2SO4: DG9S
1 Liter Amber HCI: AG1H
6035 Kit: VOAK
600 ml Amber Unp: AG2U
VPH / Gas Kit: VIGK
1 Liter Amber H2SO4: AG1 S
126 ml Sterile Plastic: SP5T
250 ml Amber H2SO4: AM.
250 mi Sterile Plastic: SP2T
250 ml Amber NH4CLL AG3A
40 mt VOA HCI: DG9H
40 ml VOA Na28203: VG9T
40 mi VOA Unp: VG9U
Page 14 of 14

,
�
Document Name: Sample Condition Upon
Document Revised: April 04, 2013
aceA/ra!}r�i 81l
Receipt (SCUM
Page 1 of 2
Document No.:
Issuing Authorities:
F-RAL-CS-001-rev.02
Pace Asheville Quality Of ice
Client Name: C:+4 rot v+: i5 ,ff
Where Received: Huntersville 0 Asheville Eden Q^^J�� Raleigh
Courier (Circle): Fed Ex UPS USPS Client Commercial Rae<3 Other
Custody Seal on Cooler/Box Present: [] yes 1 no Seals Intact z yes [] no
Packing Material; ❑ Bubble Wrap 0 Bub"gs .0 NonI Other
Circle Thermometer Used: iR Gun SN;1220 ype of Ice: W Blue None Samples on Ice, coolft process has b%w
1n %aw41 woun �,..,...,,,,,,....
Temp Correction Factor. Add / t
Corrected Cooler Temp.: C
TWp shkwid be above fn3exing to MIC
�O C
Biological Tissue la Frozen: Yes No
9 �
Comments:
Date and Initials of person examining
conten P ae n/L
. cheetc
Chain of Custody Present:
Yes ONo
OWA
1.
Chain of Custody Filled Out
46yes 17No
DNA
2.
Chain of Custody Relin hed:
eYea ONo
ON A
3.
sampler Name & Signature on COO:
-Aly-s Ow
OWA
4.
Samples Arrived within Hold Time:
filyes ONo
❑wA
5..
Short Hold Time Analysis <72hr :
Yea ONo
❑WA
6. G•
Rush Turn Around Time Requested:
Oyes J2Mo.
OwA
7.
Sufficient Volume:
Yes ONO
OWA
8.
Correct Containers Used:
-Pace Containers Used:
OYes ONo
, Yes ONO
OWA
OMA
9.
Containers Intact
Yea ONO
OWA
10.
Filtered volume received for Dissolved tests
Oyes ONo aWA
11.
Sample Labels match COC:
-Includes dateltimeAD/Mal 's Matrix
J6. ON.
ONIA
12,
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
e=ptiorm Y0A, coiirorm, TM 0&G, WI-DRO •)
yYy� ONo
" es ONO
J; Yea ONo
010A
OWA
13.
Sam les checked for dechlorinatlon:
Oyes ONo
ffNIA
14.
Pleads ace In VOA Vials >6mrn.
Oyes ONo
WA
15.
Trip Blank Present
Trip Blank Custody Seals Present
Pace Tri,Blank Lot # (if purchased),
Oyes ONO AWA
Oyes ONo .0NIA
16.
.
Client NoWcat)on/ Resolution: Add Data Regored9 Y / N
Person Contacted DateMme:
Comments! Resolution:
SCURF /SRF Y11`1 Date; nZ
Review:: �
Note: Whenever there is a discrepancy affecting North Carolina CompBance
sampie9, a copy of this form will be sent to the North Caroline DEHNR
Certification Office t Le out of hold, in=wct preservative, out Of tamp,
incorrect containers)
Place label here
OR
Handwrite project number
(if no label available)
Page 13 of 14

4 '
Summit Environmental Technologies, Inc.
3310 Win
>~,1,fOrJL1EfJT1itTE�t#SUQLOG�SpteO Cuyahoga Falls, Ohio 44223
l ' =` 4tr#r+ l lip glaivtres:; TEL: [phone] FAX. [phone]
Website: http://mvw.settekcom
March 17, 2014
Terri Page
Pace Analytical Eden
205 East Meadow Rd.
Eden, NC 27288
TEL: [phone]
FAX:
RE: 92191605
Dear Terri Page:
Order No.: 14030178
Summit Environmental Technologies, Inc. received 1 sample(s) on 3/4/2014 for the analyses
presented in the following report.
There were no problems with the analytical events associated with this report unless noted in the
Case Narrative.
Qualitycontrol data is within laboratory defined or method specified acceptance limits except
where noted.
If you have any questions regarding these tests results, please feel free to call the laboratory.
Sincerely,
0��
Dr. Mo Osman
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
A2LA 0724.01, Alabarna 41600, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia
E87688 and 943, Idaho OH00923, Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (underground Storage Tank) 3, Kentucky
90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New
Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon
OH2O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-11-5, Region 8 8TMS-
L, USDA/APHIS P330-11-00244, Utah 011009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C
and E87688, Wisconsin 399013010
Page 1 of 8

Summit Environmental Technologies, Inc. Workorder
sun
3310 Win St.
-i:
', V :•;����IY1��i:NiAfilTiL!i�Gl�lti`�,QL��IiS)��3 Cuyahoga Falls, Ohio44223 Sample Summary
TEL: [phone] FAX. [phone]
WO#: 14030178
Website: http://www.settek.com 17-Mar-14
CLIENT: Pace Analytical Eden
Project: 92191605
Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix
14030178-001 92191605007 3/3/2014 8:35:00 AM 3/4/2014 10:35:00 AM Solid
Page 2 of 8

Summit Environmental Technologies, Inc.
331 Wi Case Narrative
F:�31�J, i�; 11�ENTtiL' 1 F?tv1gLA leS s�FC Cuyahoga Falls, Ohio 44223 W09: 14030178
``5f .t%rTL,gt��tiejes'• TEL: [phone] FAX.- [phone]
Website: http://www.,settekcom Date: 3/17/2014
CLIENT: Pace Analytical Eden
Project: 92191605
This report in its entirety consists of the •documents listed below. All documents contain the Summit
Environmental Technologies, Inc. Work Order Number assigned to this report.
Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality
Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample
set.
Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation
(LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty
associated with these results and data should be considered as estimated.
Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods.
Estimated uncertainty values are available upon request.
Any comments or problems with the analytical events associated with this report are noted below.
Original
Page 3 of 8

Summit Environmental Technologies, Inc. WO#: 14030178
r' 3310 Win St.
" fDate Reported: 3/17/2014 ~��'JIROI�'1+1£�1Y�LT�I:FENQ•iZeGlc5� iC�G Cuyahoga Falls, Ohio 44223 p
racy tic 1� C ba�a�otie TEL: [phone] FAX: [phone] Company: Pace Analytical Eden
Website: htlp:/hvlvw.settelccom Address: 205 East Meadow Rd.
Eden NC 27288
Received: 3/4/2014
Project#: 92191605
Client ID#
Lab ION Collected Analyte
Result Units
Matrix
Method
DF
RL
Run
Analyst
92191605007
001
3/3/2014
Calcium(Ca)
620 mg/Kg
Solid
E200.7 C
1
10
3/7/2014
V1/K
92191605007
001
3/3/2014
Magnesium(Mg)
730 mg/Kg
Solid
E200.7 C
1
10
3/7/2014
WK
92191605007
001
3/3/2014
SAR
0.014 mg/L
Solid
EPA 200.7
1
3/5/2014
WK
92191605007
001
3/3/2014
Cyanide, Reactive
ND pom
Solid
EPA 9014
1
0.50
3/5/2014
TIR
92191605007
001
3/3/2014
Ignitability
Non flammable mm/sec
Solid
EPA 1030
1
3/7/2014
AYS
92191605007
001
3/3/2014
pH
5.6 s.u.
Solid
EPA 9045 D
1
3/4/2014
AYS
92191605007
001
3/3/2014
Sulfide, Reactive
ND ppm
Solid
EPA 9034
1
25
3/5/2014
TIR
11
Page 4 of 8

Swun:it Environmental Technologies, Inc.
i S QC SUMMARY REPORT
1 33/0 Win Sr. _
Cu alio a Falls, Ohio 44223
�lli3ra:rlrtt,.t�T11i rGaitiOLQ:Ct..s;s,';c Y g WO#: 14030178
naljt}lcri'I.1 � kF+ �art� K TEL: [phone] FAX.- [phone]
Website: httn://upivw.settek.con: 17-Mar-14
Client: Pace Analytical Eden
Project: 92191605 TestCode: Cyanide,Reactive_S(9014)
Sample ID MB-R14351
SampType: MBLK
TestCode: Cyanide,Rea Units: ppm
Prep Date:
RunNo: 14351
Client ID: PBS
Batch ID: R14351
TestNo: SW9014
Analysis Date: 315/2014
SegNo: 163352
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qua]
Cyanide, Reactive ND 0.50
Sample ID LCS-R14351
SampType: LCS
TestCode: Cyanide,Rea Units: ppm
Prep Date:
RunNo: 14351
Client ID: LCSS
Batch ID: R14351
TestNo: SW9014
Analysis Date: 3/5/2014
SegNo: 163353
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive 1.0 0.50 1.000 0 102 70 130
Sample ID LCSD-R14351
SampType: LCSD
TestCode: Cyanide,Rea Units: ppm
Prep Date:
RunNo: 14351
Client ID: LCSS02
Batch ID: R14351
TestNo: SW9014
Analysis Date: 3/5/2014
SegNo: 163354
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive 0.98 0.50 1.000 0 97.5 70 130 1.015 4.02 30
Qualifiers: '
Value exceeds Maximum Contaminant Level.
G
Value above quantilation range
M
Manual Integration used to determine area response
p
Second column confirmation exceeds
RL
Reporting Detection Limit
D Analyte detected in the associated Method Blank
lI Holding limes for preparation or analysis exceeded
ND Not Detected at the Reporting Limit
PL Permit Limit
S Spike Recovery outside accepted recovery limits
C Value is below Minimum Compound Limit.
i Malyto detected below quantitation limits
O RSD is greater than RSDlimit Original
R RPD outside accepted recovery limits
U Samples with CalcVal <MDL
Page 5of8

Sunmtit Envirorvnentaf Technologies, WinInc.tQ C SUMMARY REPORT
- `•' � ,. ' � � 3310 [Yin St.
CPaVIRJ1dt;1Etljkl_lfGGiti1OLQ'G1£5i74C C:ryallogaPalls, Ohio 44223
Ar, (yirGsl'd ljgiai(�rJr TEL: [phone] FAX.- [phone] WO#: 14030178
Website: htfR.//wipw.seltek com 17-Mar-14
Client: Pace Analytical Eden
Pt•oject: 92191605 TestCode: Sulfide,Reactive S(9034)
Sample ID MB-R14274 SampType: MBLK TestCode: Sulfide,React Units: ppm Prep Date: RunNo: 14274
;lient ID: PBS Batch ID: R14274 TestNo: SW9034 Analysis Date: 3/5/2014 SegNo: 162269
\nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
;rilnrla Qo ,.�;,
Sample ID LCS-R14274 SampType: LCS TestCode: Sulfide,React Units: ppm Prep Date: RunNo: 14274
Client ID: LCSS Batch ID: R14274 TestNo: SW9034 Analysis Date: 3/5/2014 SegNo: 162270
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sulfide, Reactive 77 25 84.00 0 91.9 70 130
Sample ID LCSD-R14274
SampType: LCSD
TestCode: Sulfide,React Units: ppm
Prep Date:
RunNo: 14274
Client ID: LCSS02
Batch ID: R14274
TestNo: SW9034
Analysis Date: 3/6/2014
SegNo: 162271
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qua]
Sulfide, Reactive
76
25 84.00 0
90.5 70 130 77.20
1.57 30
Qualttlen: ' Value exceeds Maximum Contaminant Level.
B Value above quanlitation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
B Analyte detected in the associated Method Blank
II Holding tunes for preparation or analysis exceeded
ND Not Detected at the Reporting Limit
PL Permit Limit
S Spike Recovery outside accepted recovery limits
C Value is below Minimum Compound Limit.
J Analyte detected below quantitation limits
O RSD is greater than RSDlimit
R RPD outside accepted recovery limits
U Samples with CaleVal <MDL
Original
Page 6 of 8

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Page 8 of 8

• •
aceAnalytical
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April 03, 2014
Mr. Kenny Atkins
City of Winston Salem
1201 South MLK Jr. Dr.
Winston Salem, NC 27107
RE: Project: Nelson WTP
Pace Project No.: 92191605
Dear Mr. Atkins:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 03, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
\—Axx�
Terri Page
[e-mail]
Project Manager
Enclosures
cc: Mr. Bill Brewer, City of Winston Salem
Ms. Mattie Shame[, City of Winston Salem
PQ pC��
�6pg�Y0:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 25

10 x
A41
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CERTIFICATIONS
Project: Nelson WTP
Pace Project No.: 92191605
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
Virginia/VELAP Certification #: 460221
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 25

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SAMPLE ANALYTE COUNT
Project: Nelson WTP
Pace Project No.: 92191605
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92191605007 Lagoon NWP01-P08 EPA8081
NU1
8
PASI-C
EPA 6010
JMW
13
PASI-A
EPA 6010
JMW
7
PASI-A
EPA 7470
MTS
1
PASI-A
EPA 7471
MTS
1
PASI-A
EPA 8270
RES
18
PASI-C
EPA 8260
DLK
14
PASI-C
ASTM D2974-87
LLW
1
PASI-C
SM 2540G
LLW
1
PASI-A
EPA9045
MDW
1
PASI-A
40CFR PART 432.2
EWS
1
PASI-A
EPA 350.1
AES2
1
PASI-A
EPA 351.2
JDA
1
PASI-A
EPA 353.2
DMN
3
PASI-A
EPA 365.1
JDA
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 25

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ANALYTICAL RESULTS
Project: Nelson WTP
Pace Project No.: 92191605
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
z)ample: Lagoon NWP01-P08 Lab ID: 92191605007 Collected: 03/03/14 08:35 Received: 03/03/14 13:06 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Pr d
8081 GCS Pesticides, TCLP
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
7471 Mercury
Mercury
Date: 04/03/2014 02:34 PM
epare
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/05/14 15:10
Analyzed CAS No. Qua]
ND ug/L
0.50 1
03/06/14 14:30
03/08/14 05:36
58-89-9
ND ug/L
3.0 1
03/06/14 14:30
03/08/14 05:36
57-74-9
ND ug/L
0.50 1
03/06/14 14:30
03/08/14 05:36
72-20-8
ND ug/L
0.50 1
03/06/14 14:30
03/08/14 05:36
1024-57-3
ND ug/L
1000 1
03/06/14 14:30
03/08/14 05:36
72-43-5
ND ug/L
3.0 1
03/06/14 14:30
03/08/14 05:36
8001-35-2
72 %
10-138 1
03/06/14 14:30
03/08/14 05:36
2051-24-3
77 %
10-110 1
03/06/14 14:30
03/08/14 05:36
877-09-8
Analytical Method: EPA6010 Preparation Method: EPA3050
72600 mg/kg
567 20
03/05/14 10:30
03/06/14 14:08
7429-90-5
ND mg/kg
2.8 1
03/05/14 10:30
03/05/14 17:32
7440-38-2
ND mg/kg
0.28 1
03/05/14 10:30
03/05/14 17:32
7440-43-9
646 mg/kg
28.4 1
03/05/14 10:30
03/05/14 17:32
7440-70-2
36.4 mg/kg
1.4 1
03/05/14 10:30
03/05/14 17:32
7440-50-8
21.3 mg/kg
1.4 1
03/05/14 10:30
03/05/14 17:32
7439-92-1
1480 mg/kg
28.4 1
03/05/14 10:30
03/05/14 17:32
7439-95-4
ND mg/kg
1.4 1
03/05/14 10:30
03/06/14 14:04
7439-98-7
11.5 mg/kg
1.4 1
03/05/14 10:30
03/05/14 17:32
7440-02-0
ND mg/kg
1420 1
0310511410:30
03/05/14 17:32
7440-09-7
ND mg/kg
2.8 1
03/05/14 10:30
03/05/14 17:32
7782-49-2
ND mg/kg
1420 1
03/05/14 10:30
03/0511417:32
7440-23-5
100 mg/kg
2.8 1
03/05/14 10:30
03/05/14 17:32
7440-66-6
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311;
03/05/14 22:30
ND mg/L
0.050 1
03/06/14 17:25
03/07/14 13:30
7440-38-2
0.37 mg/L
0.25 1
03/06/14 17:25
03/07/14 13:30
7440-39-3
ND mg/L
0.0050 1
03/06/14 17:25
03107/1413:30
7440-43-9
ND mg/L
0.025 1
03/06/14 17:25
03/07/14 13:30
7440-47-3
ND mg/L
0.025 1
03/06/14 17:25
03107/1413:30
7439-92-1
ND mg/L
0.10 1
03/06/14 17:25
03/07/14 13:30
7782-49-2
ND mg/L
0.025 1
03/06/14 17:25
03/07/14 13:30
7440-22-4
Analytical Method: EPA 7470 Preparation
Method: EPA 7470
Leachate Method/Date: EPA 1311;
03/05/14 22:30
ND ug/L
0.20 1
03/06/14 17:55
03/07/14 20:28
7439-97-6
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.021 mg/kg
0.0092 1
03/06/14 20:40
03/07/14 14:54
7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
M1,R1
Page 4 of 25

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ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Nelson WTP
Pace Project No.: 92191605
Sample: Lagoon NWP01-P08 Lab ID: 92191605007 Collected: 03/03/14 08:35 Received: 03/03/14 13:06 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/05/14 15:10
1,4-Dichlorobenzene
ND ug/L
50.0
1
2,4-Dinitrotoluene
ND ug/L
03/06/14 13:15 03/10/14 18:00
106-46-7
Hexachloro-1,3-butadiene
ND ug/L
50.0
1
03/06/14 13:15 03/10/14 18:00
121-14-2
Hexachlorobenzene
ND ug/L
50.0
1
03/0611413:15 03110/1418:00
87-68-3
Hexachloroethane
ND ug/L
50.0
1
03/0611413:15 03/10/14 18:00
118-74-1
2-Methylphenol(o-Cresol)
ND ug/L
50.0
1
03/06/14 13:15 03/10/14 18:00
67-72-1
3&4-Methyl phenol(m&p Cresol)
ND ug/L
50.0
1
03/06/14 13:15 03/10/14 18:00
95-48-7
Nitrobenzene
ND ug/L
50.0
1
03/06/14 13:15 03/10/14 18:00
Pentachlorophenol
ND ug/L
50.0
1
03/06/14 13:15 03/10/14 18:00
98-95
Pyridine
ND ug/L
100
1
03/06/14 13:15 03/10/14 18:00
87-95-3
-
87-865
2,4,5-Trichlorophenol
ND ug/L
50.0
1
03/0611413:15 03/10/1418:00
-1
2,4,6-Trichlorophenol
ND ug/L
50.0
1
03/06/14 13:15 03/1011418:00
95-95-4
Surrogates
50.0
1
03/06/14 13:15 03/10/14 18:00
88-06-2
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
43 %
12-102
1
03/06/14 13:15 03/10/14 18:00
4165-60-0
Terphenyl,dl4 (S)
43 %
13-107
1
03/06/14 13:15 03/10/14 18:00
321-60-8
Phenol-d6 (S)
88 %
17 %
21-132
1
03/06/14 13:15 03/10/14 18:00
1718-51-0
2-Fluorophenol (S)
25 %
10-110
1
03/06/14 13:15 03/10/14 18:00
13127-88-3
2,4,6-Tribromophenol (S)
50 %
10-110
1
03/06/14 13:15 03/10/14 18:00
367-12-4
27-108
1
03/06/14 13:15 03/10/14 18:00
118-79-6
8260 MSV TCLP
Analytical Method: EPA8260
Benzene
2-Butanone (MEK)
ND ug/L
192
38.5
03/12/14 16:06
71-43-2
Carbon tetrachloride
ND ug/L
ND ug/L
38.5
03/12/14 16:06
78-93-3
Chlorobenzene
ND9/L
u
192
192
38.5
03/1211416:06
56-23-5
Chloroform
ND ug/L
192
38.5
03/12/14 16:06
108-90-7
1,4-Dichlorobenzene
ND ug/L
192
38.5
03/12/14 16:06
67-66-3
1,2-Dichloroethane
ND ug/L
192
38.5
03112/1416:06
106-46-7
1,1-Dichloroethene
ND ug/L
192
38.5
03/12/14 16:06
107-06-2
Tetrachloroethene
ND ug/L
192
38.5
03/12/14 16:06
75-35-4
Trichloroethene
ND ug/L
192
38.5
03/12/14 16:06
127-18-4
Vinyl chloride
ND ug/L
192
38.5
03/12/1416:06
79-01-6
Surrogates
192
38.5
03/1211416:06
75-01-4
1,2-Dichloroethane-d4 (S)
111 %
Toluene-d8 (S)
°
/° 99
70-130
38.5
03/12/14 16:06
17060-07-0 ig
4-Bromofluorobenzene (S)
99 %
67-135
38.5
03/12/14 16:06 2037-26-5
70-130
38.5
03/1211416:06
460-00-4
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
66.7 %
0.10
1
03/06/14 19:00
2540G Total Percent Solids
Analytical Method: SM 2540G
Total Solids
33.3 %
0.000010
1
03/06/14 10:50
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 25

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r
ANALYTICAL RESULTS
Project: Nelson WTP
Pace Project No.: 92191605
Pace Analytical Services, Inc_
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: Lagoon NWP01-P08
Lab ID: 92191605007 Collected:
03/03/14 08:35
Received: 03/03/14 13:06 Matrix: Solid
Results reported on a "dry -weight'
basis
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
9045 pH Soil
Analytical Method: EPA 9045
pH at 25.Degrees C
2.9 Std. Units
0.10 1
03/10/14 16:03 H1
Total Nitrogen Calculation
Analytical Method: 40CFR PART 432.2
Nitrogen
6490 mg/kg
40.0 1
03/25/1411:00 7727-37-9
350.1 Ammonia
Analytical.Method: EPA350.1
Nitrogen, Ammonia
ND mg/kg
30.1 1
03/07/14 17:55 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen Kieldahl Total
1 6490 mg/kg 485 5 03/14/1411:32 7727-37-9 M1
353.2 Nitrogen, NO2/NO3 Analytical Method: EPA353.2
Nitrogen, Nitrate ND mg/kg 6.0 1 03/21/14 18:42
Nitrogen, Nitrite ND mg/kg 3.0 1 03/21/14 18:42
Nitrogen, NO2 plus NO3 ND mg/kg 6.0 1 03/21/14 18:42
365.1 Phosphorus, Total Analytical Method: EPA 365.1
Phosphorus 1790 mg/kg 55.7 5 03/18/1412:02 7723-14-0 M1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 25

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QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
cat; batch: MERP/6280 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92191605007
METHOD BLANK: 1152085 Matrix: Water
Associated Lab Samples: 92191605007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 03/07/14 20:18
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1152086
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.7 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152087 1152088
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury;ug/L ND 2.5 2.5 3.6 2.9 144 116 75-125 21 M1,R1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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i
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: MERP/6285
QC'Batch Method: EPA 7471
Associated Lab Samples: 92191605007
METHOD BLANK: 1152266
Associated Lab Samples: 92191605007
Parameter Units
mg/kg
Mercury
QUALITY CONTROL DATA
Analysis Method: EPA 7471
Analysis Description: 7471 Mercury
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0050 03/07/1414:18
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1152267
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .067 0.067 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152268 1152269
MS MSD
92188476010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury , mg/kg 0.0090 .055 .073 0.051 0.071 76 85 75-125 32 R1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 25

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1
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: MPRP/15373
Analysis Method: EPA 6010
QC Batch Method: EPA
3050
Analysis Description: 6010
MET
Associated Lab Samples:
92191605007
METHOD BLANK: 1150442
Matrix: Solid
Associated Lab Samples:
92191605007
Blank Reporting
Parameter
Units Result Limit
Analyzed Qualifiers
Aluminum
Arsenic
mg/kg
ND 10.0
03/05/1417:17
Cadmium
mg/kg
ND 1.0
03/05/1417:17
Calcium
mg/kg
ND 0.10
03/0511417:17
Copper
mg/kg
ND 10.0
03/05/1417:17
Lead
mg/kg
ND 0.50
03/05/1417:17
Magnesium
mg/kg
ND 0.50
03/05/1417:17
Molybdenum
mg/kg
ND 10.0
03/05/1417:17
Nickel
mg/kg
ND 0.50
03/05/1417:17
Potassium
mg/kg
ND 0.50
03/05/1417:17
Selenium
mg/kg
ND 500
03/0511417:17
Sodium
mg/kg
ND 1.0
03/05/1417:17
Zinc
mg/kg
ND 500
03/05/1417:17
mg/kg
ND 1.0
03/05/1417:17
LABORATORY CONTROL SAMPLE: 1150443
Parameter
Spike LCS LCS % Rec
Units Conc. Result
% Rec Limits Qualifiers
Aluminum
Arsenic
mg/kg
500 510
102 80-120
Cadmium
mg/kg
50 49.5
99 80-120
Calcium
mg/kg
mg/kg
50 51.4
103 80-120
Copper
mg/kg
500 510
102 80-120
Lead
50 51.9
104 80-120
Magnesium
mg/kg
mg/kg
50 50.5
101 80-120
Molybdenum
mg/kg
500 513
103 80-120
Nickel
mg/kg
50 52.2
50
104 80-120
Potassium
mg/kg
51.3
500
103 80-120
Selenium
mg/kg
512
50
102 80-120
Sodium
mg/kg
50.2
500
100 80-120
Zinc
mg/kg
520
50
104 80-120
50.1
100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1150444 1150445
MS MSD
Parameter
92187356014 Spike Spike MS
MSD MS MSD
% Rec
Units
Result Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qua[
Aluminum
Arsenic
mg/kg
17200 491 590 18900
23500 342 1060
75-125 22 M1,R1
Cadmium
mg/kg
mg/kg
ND 49.1 59 30.1
ND
38.8 62 66
75-125 25 M1,R1
Calcium
mg/kg
49.1 59 41.4
22.1
50.7 84 86
75-125 20
Copper
mg/kg
491 590 438
15.5 49.1
635 85 104
75-125 37 R1
59 58.6
72.5 88 97
75-125 21 R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2014 02:34 PM
without the written consent of Pace Analytical Services, Inc..
Page 9 of 25

It
Pace Analytical
Services, Inc.
®
aceAnalytical
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
wwwpacelabs.com
[phone]
QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
1150444
1150445
MS
MSD
92187356014
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Lead
mg/kg
8.1
49.1
59
44.6
55.7
74
81
75-125
22 M1,R1
Magnesium
mg/kg
6250
491
590
6830
6820
118
97
75-125
0
Molybdenum
mg/kg
ND
49.1
•59
29.2
37.1
60
63
75-125
24 M1,R1
Nickel
mg/kg
30.3
49.1
59
70.4
80.2
82
84
75-125
13
Potassium
mg/kg
85.1J
491
590
469J
702
78
105
75-125
Selenium
mg/kg
ND
49.1
59
23.8
32.8
48
56
75-125
32 M1,R1
Sodium
mg/kg
32.7J
491
590
458J
660
87
106
75-125
Zinc
mg/kg
76.6
49.1
59
117
127
82
85
75-125
8
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 25

aceAna1Xica1"
vlmpacefabs.com
r'
QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
u,- natcn: MI'KI-/1b389 Analysis Method: EPA6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92191605007
METHOD BLANK: 1152092
Matrix: Water
Associated Lab Samples: 92191605007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
03/07/1413:05
Barium
mg/L
ND
0.25
03/07/1413:05
Cadmium
mg/L
ND
0.0050
03107/1413:05
Chromium
mg/L
ND
0.025
03/07/1413:05
Lead
mg/L
ND
0.025
03/07/1413:05
Selenium
mg/L
ND
0.10
03/07/1413:05
Silver
mg/L
ND
0.025
03107/1413:05
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1152093
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Arsenic
mg/L
2.5
2.6
102
80-120
Barium
mg/L
2.5
2.5
99
80-120
Cadmium
mg/L
2.5
2.5
99
80-120
Chromium
mg/L
2.5
2.5
99
80-120
Lead
mg/L
2.5
2.4
94
80-120
Selenium
mg/L
2.5
2.5
100
80-120
Silver
mg/L
1.2
1.2
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1152094
1152095
MS
MSD
92191605007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
Arsenic
mg/L
ND
2.5
2.5
2.5
2.6
100
103
75-125
3
Barium
mg/L
0.37
2.5
2.5
2.8
2.9
97
100
75-125
3
Cadmium
mg/L
ND
2.5
2.5
2.4
2.5
98
100
75-125
2
Chromium
mg/L
ND
2.5
2.5
2.5
2.5
98
100
75-125
3
Lead
mg/L
ND
2.5
2.5
2.3
2.4
94
96
75-125
3
Selenium
mg/L
ND
2.5
2.5
2.5
2.6
100
102
75-125
2
Silver
mg/L
ND
1.2
1.2
1.2
1.3
98
100
75-125
2
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qua[
Page 11 of 25

r
aceAnalytical
/ wwrv.pacelabs.com
i
QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
cat; Batch: MSV/26058 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV TCLP
Associated Lab Samples: 92191605007
METHOD BLANK: 1155334
Associated Lab Samples: 92191605007
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
03/12/14 11:29
1,2-Dichloroethane
ug/L
ND
5.0
03/12/14 11:29
1,4-Dichlorobenzene
ug/L
ND
5.0
03/12/14 11:29
2-Butanone (MEK)
ug/L
ND
10.0
03/12/14 11:29
Benzene
ug/L
ND
5.0
03/12/14 11:29
Carbon tetrachloride
ug/L
ND
5.0
03/12/14 11:29
Chlorobenzene
ug/L
ND
5.0
03/12/14 11:29
Chloroform
ug/L
ND
5.0
03/12/14 11:29
Tetrachloroethene
ug/L
ND
5.0
03/12/14 11:29
Trichloroethene
ug/L
ND
5.0
03112/1411:29
Vinyl chloride
ug/L
ND
5.0
03/12/14 11:29
1,2-Dichloroethane-d4 (S)
%
113
70-130
03/12/14 11:29
4-Bromofluorobenzene (S)
%
98
70-130
03/12/14 11:29
Toluene -dB (S)
%
98
67-135
03/12/14 11:29
LABORATORY CONTROL SAMPLE:
Parameter
1155335
Units
Spike
Conc.
LCS LCS
Result % Rec
1,1-Dichloroethene
ug/L
50
57.3
1,2-Dichloroethane
ug/L
50
62.5
1,4-Dichlorobenzene
ug/L
50
60.4
2-Butanone (MEK)
ug/L
100
138
Benzene
ug/L
50
55.8
Carbon tetrachloride
ug/L
50
52.8
Chlorobenzene
ug/L
50
58.4
Chloroform
ug/L
50
57.0
Tetrachloroethene
ug/L
50
58.8
Trichloroethene
ug/L
50
55.2
Vinyl chloride
ug/L
50
54.6
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Date: 04/03/2014 02:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
% Rec
Limits Qualifiers
115
70-141
125
70-139
121
70-141
138
63-150
112
70-132
106
70-150
117
70-134
114
70-130
118
70-137
110
70-131
109
56-144
122
70-130
96
70-130
99
67-135
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 25

t ' �
a ce Analytical
vimpacelabs.com
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: OEXT/26328
QC Batch Method: EPA 3510
Associated Lab Samples: 92191605007
METHOD BLANK: 1151704
Associated Lab Samples: 92191605007
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
Matrix: Water
EPA 8081
8081 GCS TCLP Pesticides
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
Parameter
Units
Blank Reporting
Result Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
03/08/14 01:13
Endrin
ug/L
ND
0.50
03/08/14 01:13
gamma-BHC (Lindane)
ug/L
ND
0.50
03/08/14 01:13
Heptachlor epoxide
ug/L
ND
0.50
03/08/14 01:13
Methoxychlor
Toxaphene
ug/L
ND
1000
03/08/14 01:13
Decachlorobiphenyl (S)
ug/L
%
ND
3.0
03/08/14 01:13
Tetrachloro-m-xylene (S)
%
77
10-138
03/08/14 01:13
82
10-110
03/08/14 01:13
LABORATORY CONTROL SAMPLE:
1151705
Parameter
Units
Spike
Conc.
LCS
Result
LCS % Rec
% Rec Limits Qualifiers
Endrin
gamma-BHC (Lindane)
ug/L
ug/L
1.2
1.3
107 20-134
Heptachlor epoxide
ug/L
1.2
1.0
84 20-118
Methoxychlor
ug/L
1.2
3.7
1.1
90 22-133
Decachlorobiphenyl (S)
%
ND
98 44-150
Tetrachloro-m-xylene (S)
%
86 10-138
81 10-110
MATRIX SPIKE'& MATRIX SPIKE DUPLICATE: 1151706
1151707
MS
MSD
Parameter
92190616001
Spike
Spike
MS
MSD MS MSD
% Rec
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits RPD Qual
Endrin
gamma-BHC (Lindane)
ug/L
ug/L
ND
ND
1.2
1.2
ND
ND 105 97
21-133
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.2
1.2
ND
ND 76 74
24-119
Methoxychlor
ug/L
ND
3.7
3.7
ND
ND
ND 168 144
50-150 M3
Decachlorobiphenyl (S)
ND 90 90
50-150
Tetrachloro-m-xylene (S)
%
0 0
10-138 D3,S4
0 0
10-110
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 25

Y
- aceAna1Xical
1 wwwpacelabs.com
i
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: OEXT/26323
QC Batch Method: EPA 3510
Associated Lab Samples: 92191605007
METHOD BLANK: 1151550
Associated Lab Samples: 92191605007
QUALITY CONTROL DATA
Analysis Method: EPA 8270
Analysis Description: 8270 TCLP MSSV
Matrix: Water
Parameter
Units
Blank
Result
1,4-Dichlorobenzene
ug/L
ND
2,4,5-Trichlorophenol
ug/L
ND
2,4,6-Trichlorophenol
ug/L
ND
2,4-Dinitrotoluene
ug/L
ND
2-Methylphenol(o-Cresol)
ug/L
ND
3&4-Methyl,phenol(m&p Cresol)
ug/L
ND
Hexachloro-1,3-butadiene
ug/L
ND
Hexachlorobenzene
ug/L
ND
Hexachloroethane
ug/L
ND
Nitrobenzene
ug/L
ND
Pentachlorophenol
ug/L
ND
Pyridine
ug/L
ND
2,4,6-Tri6romophenol (S)
%
89
2-Fluor6biphenyl (S)
%
84
2-Fluorophenol (S)
%
45
Nitrobenzene-d5 (S)
%
79
Phenol-d6 (S)
%
31
Terphenyl-dl4 (S)
%
99
LABORATORY CONTROL SAMPLE:
Parameter
1151551
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
500
2,4,5-Trichlorophenol
ug/L
500
2,4,6-Trichlorophenol
ug/L
500
2,4-Dinitrotoluene
ug/L
500
2-Methyl phenol (o-Cresol)
ug/L
500
3&4-Methylphenol(m&p Cresol)
ug/L
500
Hexachloro-1,3-butadiene
ug/L
500
Hexachlorobenzene
ug/L
500
Hexachloroethane
ug/L
500
Nitrobenzene
ug/L
500
Pentachlorophenol
ug/L
1000
Pyridine
ug/L
500
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
Terphenyl-d14 (S)
%
Reporting
Limit
Analyzed
50.0
03/0711414:33
50.0
03/07/1414:33
50.0
03/07/1414:33
50.0
03/07/1414:33
50.0
03/07/1414:33
50.0
03/0711414:33
50.0
03/07/1414:33
50.0
03/07/1414:33
50.0
03/0711414:33
50.0
03107/1414:33
100
03/07/1414:33
50.0
03/07/1414:33
27-108
03/07/1414:33
13-107
03107/1414:33
10-110
03/07/1414:33
12-102
0310711414:33
10-110
03/0711414:33
21-132
03/07/1414:33
Qualifiers
LCS
Result
LCS
% Rec
% Rec
Limits
361
72
10-110
417
83
39-108
395
79
40-104
476
95
42-109
304
61
31-110
274
55
30-110
359
72
10-110
445
89
39-121
341
68
10-110
395
79
32-101
833
83
18-108
180
36
10-110
95
27-108
81
13-107
42
10-110
76
12-102
29
10-110
96
21-132
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
This report shall not be reproduced, except in full,
Date: 04/03/2014 02:34 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 25

o
;�'ceAnalyticai'
rmv.pacelabs.com
Project: Nelson WTP
Pace Project No.: 92191605
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151552
Parameter
1,4-Dichlorobenzene
2,4, 5-Trich]orophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
2-Methylph en of (o-Cresol)
3&4-Methylphenol(m&p
Cresol)
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,6-Tribromophenol (S)
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
Date: 04/03/2014 02:34 PM
QUALITY CONTROL DATA
MS
92191725001 Spike
Units Result Conc.
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
ug/L
ND
500
1151553
MSD
Spike
MS
MSD
Conc.
Result
Result
500
363
341
500
125
46.9J
500
17.5J
54.1
500
470
424
500
400
284
500
385
226
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qua]
73
68
30-150
6
25
9
30-150
M1
4
11
30-150
M1
94
85
30-150
10
80
57
30-150
34 R1
77
45
30-150
52 R1
ug/L
ND
500
500
356
340
71
68
30-150
5
ug/L
ND
500
500
414
386
83
77
30-150
7
ug/L
ND
500
500
340
324
68
65
30-150
5
ug/L
ND
500
500
383
369
77
74
30-150
4
ug/L
ND
1000
1000
892
34.5J
89
3
30-150
M1
ug/L
ND
500
500
80.6
185
16
37
30-150
79 M1,R1
93
20
27-108
SO
72
72
13-107
%
55
3
10-110
SO
73
69
12-102
47
11
10-110
85
82
21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 25

1aceAn4dical
wwww.pacelahs.com
QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: PMST/6320 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92191605007
SAMPLE DUPLICATE: 1151356
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 1151357
Parameter
Percent Moisture
Date: 04/03/2014 02:34 PM
92191490001 Dup
Result Result RPD Qualifiers
28.7 29.7 3
92191605007 Dup
Units Result Result
% 66.7 65.2
RPD Qualifiers
2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 25

_ I
r, •
aceAnalyticai
vnw✓,pacelabs.com
QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: WET/29893 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92191605007
SAMPLE DUPLICATE: 1153848
Parameter
pH at 25 Degrees C
Date: 04/03/2014 02:34 PM
92191736014 Dup
Units Result Result RPD Qualifiers
Std. Units 5.7 5.9 3 D6.1-11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 25

;a?eAnalytical
/ vwwpecelabs.com
Project: Nelson WTP
Pace Project No.: 92191605
uubaicn: wtIA/18277
QC Batch Method: EPA 350.1
Associated Lab Samples: 92191605007
QUALITY CONTROL DATA
Analysis Method: EPA 350.1
Analysis Description: 350.1 Ammonia
METHOD BLANK: 1152945 Matrix: Solid
Associated Lab Samples: 92191605007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/kg ND 10.0 03/07/14 17:53
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1152946
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg 500 527 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152947 1152948
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Nitrogen, Ammonia mg/kg ND 1500 1500 1450 1470 94 96 90-110 1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 25

t;
aceAnalytical
vrnvpacelab&cam
Project: Nelson WTP
Pace Project No.: 92191605
QC Batch: WETA/18343
QC Batch Method: EPA 351.2
Associated Lab Samples: 92191605007
QUALITY CONTROL DATA
Analysis Method: EPA 351.2
Analysis Description: 351.2 TKN
METHOD BLANK: 1156852 Matrix: Solid
Associated Lab Samples: 92191605007
Blank Reporting
Parameter Units Result Limit Analyzed y Qualifiers
Nitrogen, Kjeldahl, Total mg/kg ND
50.0 03/14/1411:13
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1156853
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/kg 1000 1050
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1156854
Parameter
Nitrogen, Kjeldahl, Total
Date: 04/03/2014 02:34 PM
MS
92191605007 Spike
Units Result Conc.
mg/kg 6490 2070
1156855
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qual
1000 9030 9020 123 252 90-110 0 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 25

;1 '(
aceAnalyfical
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QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
ut- tsaicn: Wt IAll 8438 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite
Associated Lab Samples: 92191605007
not I HUU BLANK: 1162435
Matrix: Solid
Associated Lab Samples:
92191605007
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 2.0
03/21/14 18:39
Nitrogen, Nitrite
mg/kg
ND 1.0
03/21/14 18:39
Nitrogen, NO2 plus NO3
mg/kg
ND 2.0
03/21/14 18:39
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1162436
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate mg/kg
25
24.9
100
90-110
Nitrogen, Nitrite mg/kg
10
9.9
99
90-110
Nitrogen, NO2 plus NO3 mg/kg
25
24.9
100
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162437
1162438
MS
MSD
92192828001
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter Units Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/kg ND
50.8
50.8
51.5
52.2
101 103
90-110 1
Nitrogen, Nitrite mg/kg ND
21.4
21.4
22.0
22.0
103 103
90-110 0
Nitrogen, NO2 plus NO3 mg/kg ND
50.8
50.8
51.5
52.2
101 103
90-110 1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 25

aceAnalylical
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QUALITY CONTROL DATA
Project: Nelson WTP
Pace Project No.: 92191605
cat; batcn: WETA/18394 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92191605007
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 1158573 Matrix: Solid
Associated Lab Samples: 92191605007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/kg ND 2.0 03/18/1411:08
LABORATORY CONTROL SAMPLE: 1158574
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/kg 50 50.8 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158575 1158576
MS MSD
92191605007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Phosphorus mg/kg 1790 301 301 2270 1940 160 49 90-110 16 M1
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 21 of 25

aceAnalytical
www.pacelabs.ccm
QUALIFIERS
Project: Nelson WTP
Pace Project No.: 92191605
DEFINITIONS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL- Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
10 8260 results are from a total analysis which show that analytes are not present or that they are present but at such low
levels that the appropriate regulatory levels could not possibly be exceeded, per Section 1.2 of Method 1311.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
S4 Surrogate, recovery not evaluated against control limits due to sample dilution.
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 22 of 25

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aceAnalytical
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r
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Nelson WTP
Pace Project No.: 92191605
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92191605007
Lagoon NWP01-P08
EPA3510
OEXT/26328
EPA8081
92191605007
Lagoon NWP01-P08
EPA3050
MPRP/15373
EPA6010
92191605007
Lagoon NWP01-P08
EPA 3010
MPRP/15389
EPA 6010
92191605007
Lagoon NWP01-P08
EPA 7470
MERP/6280
EPA 7470
92191605007
Lagoon NWP01-P08
EPA 7471
MERP/6285
EPA 7471
92191605007
Lagoon NWP01-P08
EPA 3510
0EXT/26323
EPA 8270
92191605007
Lagoon NWP01-P08
EPA8260
MSV/26058
92191605007
Lagoon NWP01-P08
ASTM D2974-87
PMST/6320
92191605007
Lagoon NWP01-P08
SM 2540G
WET/29869
92191605007
Lagoon NWP01-P08
EPA 9045
WET/29893
92191605007
Lagoon NWP01-P08
40CFR PART432.2
WET/30157
92191605007
Lagoon NWP01-P08
EPA 350.1
WETA/18277
92191605007
Lagoon NWP01-P08
EPA351.2
WETA/18343
92191605007
Lagoon NWP01-P08
EPA353.2
WETA/18438
92191605007
Lagoon NWP01-P08
EPA 365.1
WETA/18394
Date: 04/03/2014 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
GCSV/16862
ICP/13939
ICP/13956
MERC/6056
MERC/6057
MSSV/8830
Page 23 of 25

r SIR Sr'EEDT PRINRNG CENT
Efl MINNEAPDI.IS. MN SSa Iq .
. eAna4jicai. ..• 612-9)&>ryg .
>".v.walzrs.rnm CHAIN-0
F_
R<9elrort C The CNain,o/gyp,.
usr
uont,n-1°DyaaLF ODC /gna'lefe al'Re
- ` .. ROVv'rvE Pmba INom GAL DOCUMENT. All relevant fide rngt be ee, ro a ry. Document
D �9 ''kPW170
— Section C
.-....aemH ama4n
Matrix Cons
Ww
4r^9 alor
B{
Dw
wT
`'
= 8
COLLECTED
wa,m waror
Pmypn
wW
a
SAMPLE ID
al wore
P"
SL
� Jrwrnc
�'OMeosRc
('Z0.9/.)
Saaylo lDx MUST
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wP
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or
W
O w
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a
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U
nll.lnO�_
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ACCEPTED
ORIGINAL SAMPLER NAME AND SIGNATU�-
Sk'IPL
�mwlat n'uu0y'^9 Nk/vmiYwwacco PRINTName oI ER
pNy PamY NE73p�YpaymeN ems aMerreewp lode eN(ATUUMISshrymC.
- °'o'�'M`°Iros mlpea t �nmM JO nay,.
REGULATORYAGENCY - 1713164
f NPDES i— GROUND WATER
I— UST I— RCRA (' DRfNXING WATER
SIO Leta/Ion 1jC OTHER
=PLE CONDITIONS

,r
Scrtlnn R
SIR SPEED! PRIMING CENTER • MINNEAP . MN 5Safs - B12-B]tl•T1]B
CHAIN-OF-CUSTODY/Analytical Request Document
T^e CABIMof-C :" i, u LEGAL DOCUMENT. All relevant `10d: must be—pleled a Idy.
--PaceAnallXical
S—fion A
Required Cllenl In'or Llw
S'�.o..-y Z.10.
A

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0031314 FACILITY NAME: City of Winston Salem -Swann Water Treatment Plant
PHONE: [phone] COUNTY: Forsyth OPERATOR: Harry E Hull
FACILITY TYPE (please check one): Surface Disposal (complete Part A (Sounx(s) and "Residual In" Volume only) and Part C)
Z Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes :�- No 0 —► If No skip parts A. B. C and certify form below
Part A*:
Part B*:
Month
Sources(s) (Include NPDES # it
applicable)
(dry tons)
Recipient Information
AmendmendVoinme
Bulling Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
Swann WTP NC0086762
13.2
13.2
On -Site
13.2
Corn
February
March
April
may
June
AugustJuly
September
October
November
December
Total from FORM DMSDF (sup)
Totals: Annual tons):
0 1
13.2
13.2
13.2
Amendment(s) used
Bulking A s used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)):
Part C:
Total Number of Form DMSDF (Supp)I
FacWty was compliant daring the past calendar year with all conditions of the land application permit Yes
(including but not limited to items I-3 below) issued by the Division of Water Quality: No — 0 If No, Explain In Nar hive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my Imowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
S of Phzmttei D Signature of Preparer** Date
(if different from Pennittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM DMSDF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0031314 Laboratory: 1) Pace Labs Inc
Facility Name: Swann WTP 2) '5ummit Enviromental Technologies In
Residual Source WQ # or NCO086762 3)
NPDES #: 4)
WWTP Name: 5)
Residual Analysis Data
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
10/10/13
Percent Solids (%)
NA
8
Arsenic
75
ND
Cadmium
85
ND
Copper
4,300
56
Chromium
NA
ND
Lead
840
17.3
Mercury
57
0.053
Molybdenum
75
ND
Nickel
420
8
Selenium
100
ND
Zinc
7,500
172
Total Phosphorus
NA
2760
TKN
NA
9440
Ammonia -Nitrogen '
NA
407
Nitrate and Nitrite
NA
ND
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
,Y "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that.there are significant
penaltie for submitting false information, including the possibility of fines and imprisonment for knowing violations."
1 JA 5
Signature of Preparer bate
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: W00031314
Facility Name: Swann WTP
Residual Source NCO086762
NPDES # or WQ#:
WWTP Name:
Residual AnalvAs Data
Laboratory: 1) Pace Labs Inc
2) Summit Enviromental Technologies Inc
3)
4)
5)
Parameter
Sampleor • •• Date
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
1 z f 1�
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) .
Facility Name: Swann WTP
WWTP Name:
WQ Permit Number:
NPDES.Number:
WQ0031314
NCO086762
Monitoring Period: From 1/1/2014 To 12/31/2014
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
Alt. C (Prior Testing)0
A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thetmophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density ❑
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative. performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
-
Lime Stabilization [3Air
Drying ❑ .
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
Number ot
Excee-
dences
Frequency
of Analysis
Sample
Type
AnalyticaT
Tech -
ni ue
MinimumGeo.
Mean
aximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
2.2
22.2
111
MPN/g
0
Annualy
Grab
M9221 C l
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) . ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. OZ uptake) [3Alt.
5 (14-Day Aerobic) [I
Alt. 6 (Alk. Stabilization [3
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
d "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
P14A,—5V&0-af:r&r
Preparer Name sand Title (type or print) Land A ier Name and Title (if applicable)(type or print)/" r
L IT�'Wt / ///-, L'd'rV(/l l .2 � �.7
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

PAN
Mineralization
as decimal
ITotal dry
tons/year
JAcres
Applied on
1 10
Rate
0.4
TKN
9440
F NH3
1 407
NO3
25
NO2
12.5
% Solids
0.08
1 10
PAN Surface
3854.2 mg/kg 7.7084 lbs/dry ton
77.084 Ibs total PAN
7.7084 Ibs PAN/acre
PAN Injection
4057.7 1 mg/kg 8.1154 lbs/dry ton
81.154 Ibs total PAN
8.11541 lbs PAN/acre
Dry Tons/1000 gal.
0.3336
1st year PAN
Surface lbs.
77.084
1st year PAN
Injected lbs.
81.154
lbs./acre
Surface
7.7084
lbs./acre
Injected
8.1154
MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal."
2000

SAR & ESP
Sodium Absorption Ratio
Na: Sodium (Mg/L) Equivalent weight: 23
Ca: Calcium (Mg/L) Equivalent weight: 20
Mg : Magnesium (Mg/L) Equivalent weight: 12
Milli Equivalent = Mg/L / Equivalent weight
Na(Mg/L) Ca(Mg/L) M M /L
1 502.4 1152 79.92
Na (ME)
Ca ME
Mg (ME)
21.84348
7.6 1
6.66
SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power
SAR = 8.180447 (From Mg/L entered above)
SAR= #DIV/0! (From ME entered below)
Na (ME) Ca ME I Mg (ME)11
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the
Na (MEA CEC
0 0
ESP = #DIV/0! .
Na on NC soil test is expressed as meq

The amount of exchangeable. sodium ions versus the
amount of exchangeable calcium & magnesium ions in a given material.
Permitting guidance is if greater than 10 require ESP in permit.
cation exchange complex of soils
Should be less than 15% (15-20%)

aceAnalytical
—pacelabs.com
i
November Vim:, 2013
Mr. Kenny Atkins
City of Winston Salem
1201 South MLK Jr. Dr.
Winston Salem, NC 27107
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Atkins:
Enclosed are the analytical results for sample(s) received by the laboratory on October 10, 2013.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNl standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terri Page
[e-mail]
'r'ruj@Gt ivialiagei
Enclosures
cc: INV.
VOI'll UIGVGI, Vlly VIVYlInstV_ -
IIVQVII
Ms_ idlattie Shamel, City of Winston Salem
�e pCCg�p
RLPO RT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, Inc..
Page 1 of 30

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vnnvpacelabs.com
I
Project: SWANN LAGOON #1
Pace Project No.: 92/754496
Raleigh Certification ivs
6701 Conference Drive Raleigh, NC 27607
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #. M-NC030
North Carolina Drinking Water Certification #. 37712
[phone]
Pace Analytical Services, Inc.
2225 Riverside Or_
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Bioassay Certification #. 16
aroB ^.a ^ # 37-
,......, .. .�... ... .^.^y ....
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #. 99030001
West Virginia Certification #: 356
VirginiaNELAP Certification #: 460222
REPORT OF LABORA71 ORY MA NALYSiS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full.
withoui the wditen conseni of race Analylkai Services, inc..
Page 2 of 30

'aceAnalyt'
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1
Proiect: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANAL'TE COON i
4 . I F
Pace Analyticai Services, inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
al, sFs
Analytes
92176496001
LAGOON 1
EPA8081
RES
8
PASI-C
EPA6010
JMW
13
PASI-A
EPA6010
JMW
7
PASI-A
EPA 7470
MTS
1
PASI-A
EPA8270
RES
18
PASI-C
EPA 8260
DLK
14
PASI-C
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
NAW
1
PASI-R
EPA9045
AES2
1
PASI-A
40CFR PART 432.2
EWS
1
PASI-A
EPA350.1
JTM
1
PASI-A
EPA351.2
JDA
1
PASI-A
EPA353.2
DMN
3
PASI-A
EPA 365.1
JDA
1
PASI-A
92175496002
Lagoon 1
EPA7471
MTS
1
PASI-A
ASTM D2974-87
LLW
1
PASI-C
SM9221C E (MPN) 503
NAW
1
PASI-R
92175496003
Lagoon 1
SM9221C E (MPN) 503
NAW
1
PASI-R
92175496004
Lagoonl
SM9221C E (MPN) 503
NAW
1
PASi-R
92175496005
Lagoonl
SM9221C E (MPN) 503
NAW
1
PASI-R
92175496006
Lagoonl
SM9221C E (MPN) 503
NAW
1
PASI-R
92175496007
Lagoonl
SM9221C E (MPN) 503
NAW
1
PASI-R
REPORT OF LASORAiOnYANALrr"SPIS
This report shall not be reproduced, except in full,
without the written consent of Pace Anaiyiicai Services, inc.. Page 3 of 30

` A 1 • J
aaeAnaoical0
vmrl.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTIC -AL RESULTS
Pace Analytical Services, Inc.
9800 Nncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SWANN LAGOON #.f1
Pace Project No.: 92175496
Sample: LAGOON 1 Lab ID: 92175496001 Collected: 10/10/13 06:30 Received: 10/10/13 16:21 Matrix: Solid
rresuiis reporied on a -dry-weighC basis
Pararnetem Re -stilts Units Rannrt I imit nP Pre -pared Analyzed C:AS N0, ^••-'
8081 GCS Pesticides, TCLP Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 10/14/13 15.00
BHC
gamma- (Llndane)
ND ug/L
0.50 1
10/17/13 14:10
10/18/13 21:24 58-89-9
Chlordane (Technical)
ND ug/L
3.0 1
10/17/13 14:10
10/18/13 21:24 57-74-9
Endrin
ND ug/L
0.50 1
10/17/13 14:10
10/18/13 21:24 72-20-8
Heptachlor epoxide
ND ug1L
0.50 1
10/ 17113 14:10
10/18/13 21:24 1024-57-3
Methoxychlor
ND ug/L
1000 1
10/17/13 14:10
10/18/13 21:24 72-43-5
Toxaphene
ND ug/L
3.0 1
10/17/13 14.10
10/18/13 21:24 8001-35-2
Surrogates
Decachlorobiphenyl (S)
56 %
10-138 1
10/17/13 14:10
10/18/13 21:24 2051-24-3
Tetrachloro-m-xylene (S)
80 %
10-110 1
10/17/13 14:10
10/18/13 21:24 877-09-8
6010 MET ICP
Analytical Method: EPA 6010
Preparation Method: EPA 3050
Aluminum
128000 mg/kg
1260 10
10/31/13 12:15
11/01/13 12:39 7429-90-5 M6
Arsenic
ND mg/kg
12.6 1
10/31/13 12:15
10/31/13 23:48 7440-38-2
Cadmium
ND mg/kg
1.3 1
10/31/13 12:15
10/31/13 23:48 7440-43-9
Calcium
1900 mg/kg
126 1
10/31/13 12:15
10/31/13 23:48 7440-70-2
Copper
56.0 mg/kg
6.3 1
10/31/13 12:15
10/31113 23:48 7440-50-8
Lead
17.3 mg/kg
6.3 1
10/31/13 12:15
10/31/13 23:48 7439-92-1
Magnesium
999 mg/kg
126 1
10/31/13 12:15
10/31/13 23:48 7439-95-4
Molybdenum
ND mg/kg
6.3 1
10/31/13 12:15
10/31/13 23:48 7439-98-7
Nickel
8.0 mglkg
6.3 1
10/31/13 12:15
10/31/13 23:48 7440-02-0
Potassium
ND mg/kg
6280 1
10/31/13 12:15
10/31/13 23:48 7440-09-7
Selenium
ND mg/kg
12.6 1
10/31/13 12:15
10/31/13 23:48 7782-49-2
Sodium
ND mg/kg
6280 1
10/31/13 12:15
10/31/13 23:48 7440-23-5
Zinc
172 mg/kg
12.6 1
10/31/13 12:15
10/31/13 23:48 7440-66-6
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 10/17113 22:00
Arsenic
ND mg/L
0-050 1
10/18/13 22:30
10/20/13 13:49 7440-38-2
Barium
ND mg/L
0.25 1
10/18/13 22:30
10/20/13 13:49 7440-39-3
Cadmium
ND mg/L
0.0050 1
10/18/13 22:30
10/20/13 13:49 7440-43-9
Chromium
ND mg/L
0.025 1
10/18/13 22:30
10/20/13. 13:49 7440-47-3
Lead
ND mg/L
0.025 1
10/18/13 22:30
10/20/13 13:49 7439-92-1
Selenium
ND mg/L
0.10 1
10/18/13 22:30
10/20/13 13:49 7782-49-2
Silver
ND mg/L
0.025 1
10/18/13 22:30
10/20/13 13:49 7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 10/17/13 22:00
Mercury
ND ug/L
0.20 1
10/18/13 20:30
10/19/13 11:59 7439-97-6
8:2i0 i:15SV TCLP Sep Fu:tnet
Analytical Method: EPA8270 Preparation method: EPA 35i0
Leachate Method/Date: EPA
1311; 10/14/13 15:00
1,4-Dichiorobenzene
ND ug/L
50.0 i
10A5ii314:45
10i1&1319:56 106-46-7
2,4-Dinitrotoiuene
ND ug1L
50.0 1
10/i5i1314:45
i0ii6113 i9:56 121-14-2
REPORT OF LABORATORY ANALYSIS
This repor i shaft not ba reproduoad, exCept in soli,
t14C•.. I:rVti:GV iJ ii .Vi. itii YJiJi J�Jl tli: �ti 1?U.'.il i3Jiu:iii Vi i %Sx /-ii hiiyiii ii J:I Vi�X _, Hii;.. - - --
vag-e 4 01 .)l/

0
aceAnalytical
mmpacelabs.com
i
Project: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
1 • A
♦.3
Pace Analytical Services, Inc.
9800 IQnceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: LAGOON 1 Lab ID: 92175496001 Collected: 10/10113 06:30 Received: 10/10/13 1.6:21 Matrix: Solid
Results reporied on a -dry-avelghi" basis
Parameters Results Units Re -port Limit DF Prepared Analyzed CAS No. QUal
8270 MSSV TCLP Sep Funnel
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-Methyiphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichiorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichioroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
92210E Fecal Coliform, MPN RAL
Fecal Coiiforms, MPN
9045 pH Soil
pH at 25 Degrees C
Date: 1 1 /U4/20 13 0 r02 P i A
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 10/14/13 15:00
ND ug/L
50.0
1
10/15/13 14:45
10/16/13 19:56 87-68-3
ND ug/L
50.0
1
10/15/1314:45
10/16/1319.56 118-74-1
ND ug/L
50.0
1
10/15/13 14:45
10/16/13 19:56 67-72-1
ND ug/L
50.0
1
10/1511314:45
10116/1319:56 95-48-7
ND ug/L
50.0
1
10115/1314:45
10/16/13 19:56
ND ug/L
50.0
'1
10/15/1314:45
10/16/13 19:56 98-95-3
ND ug/L
100
1
10115/1314:45
10/16/13 19:56 87-86-5
ND ug/L
50.0
1
10/15/13 14:45
10/16/13 19:56 110-86-1
ND ug/L
50.0
1
10/15/13 14:45
10/16/13 19:56 95-95-4
ND ugiL
50.0
1
10/15/13 14:45
10116/1319:56 88-06-2
61 %
65 %
67 %'
32 %
39 %
83 %
Analytical Method: EPA 8260
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
109 %
101 %
103 %
Analytical Method: ASTM D2974-87
12-102
1
10/15/13 14:45
10/16/13 19:56 4165-60-0
13-107
1
10/1511314:45
10116/1319:56 321-60-8
21-132
1
10/15/13 14:45
10/16/13 19:56 1718-51-0
10-110
1
10/15/13 14:45
10/16/13 19:56 13127-88-3
10=110
1
1011511314:45
10/1611319:56 367-12-4
27-108
1
10/1511314:45
10/16/13 19:56 118-79-6
192 38.5
385 38.5
192 38.5
192 38.5
192 38.5
192 38.5
192 38.5
192 38.5
192 38.5
192 38.5
192 38.5
70-130 38.5
67-135 38.5
70-130 38.5
92.0 % 0.10 1
Analytical Method: SM9221 C E (MPN) 503
27.8 MPN/g O.i3 i
Analytical Method: EPA 9045
6.5 Std. Units 0.10 i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wli our Lne written comeni of Face Anaiyticaj Services, ino..
10/16/13 00:32 71-43-2
10/16/13 00:32
78-93-3
10/16/13 00:32
56-23-5
10/16/13 00:32
108-90-7
10/16/13 00:32
67-66-3
10/16/13 00:32
106-46-7
10/16/13 00:32
107-06-2
10/16/13 00:32
75-35-4
10/16/13 00:32
127-18-4
10/16/13 00:32
79-01-6
10/16/13 00:32
75-01-4
10/16/13 00:32 17060-07-0 1g
10/16/13 00:32 2037-26-5
10/16/13 00:32 460-00-4
10/21/13 15:09
i01i0A3 i3:16 29
10A6113 13:10
Page 5 of 30
3

aceAnalyticalB
vmvzpacelabs.com
Project: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: LAGOON 1
Lab ID: 92175496001 Collected: 10/10/13 06:30
Received: 10/10/13 1621 Matrix: Solid
Resuits reported on a 'dry -weight" basis
Parameters
Re-,Utg Unitg Report Unit DF
Prepared
Analyzed CAS No. Qual
Total Nitrogen Calculation
Analytical Method: 40CFR PART 432.2
Nitrogen
9440 mg/kg 40.0 1
10/25/13 10:40 7727-37-9
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
407 mglkg 126 1
10/15/13 14:32 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
9440 mg/kg 405 1
10/15/13 14:52 7727-37-9
353.2 Nitrogen, N021NO3
Analytical Method: EPA353.2
Nitrogen, Nitrate
ND mglkg 25.0 1
10/25/13 04:27
Nitrogen, Nitrite
ND mg/kg 12.5 1
10/25/13 04:27
Nitrogen, NO2 plus NO3
ND mg/kg 25.0 1
10/25/13 04:27
366.1 Phosphorus, Total
Analytical Method: EPA365.1
Phosphorus
2760 mg/kg 251 5
10/15/1311:45 7723-14-0
Sample: Lagoon 1
Lab ID: 92175496002 Collected: 10/10/13 06:30
Received:
10/10/13 11:14 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units Report Limit DF
'Prepared
Analyzed CAS No. Qual
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA
7471
Mercury
0.053 mglkg 0.039 1
10/17/13 15:45 10/18/13 22:10 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
91.6 % 0.10 1
10/21/13 15:09
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
111 MPN/g 0.12 1
10/10/13 13:16
Sample: Lagoon 1
Lab lD: 92175496003 Collected: 10/10/13 06:30
Received:
10/10/13 11:14 Matrix: Solid
Results reported on a "wet -weight"
basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qtlal
92210E Fecal Coliform, MPN RAIL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
2.2 MPN/q 0.010 1
10/10/13 13:16
Date: 11104/20 13 0 a:02 Plvl
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of FaceAnaiyucai Services, inc..
Page 6 of 30

aceAnalytical
vnmpacelabs.com
i
Project: SWANN LAGOON #1
Pace Project No.: 921754496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kncey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
Sample: Lagoonl
Lab ID: 92175496004
Collected: 10/10/13 06:30
Received:
10/10/13 11:14 Matrix. Solid
Results reporied on a "wet-weighi" basis
Parameters
RP_.StIIt$ Units
Report Limit IMF
Prenared
Analyzed GAS No. Qual
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C
E (MPN) 503
Fecal Coliforms, MPN
2.2 MPN/g
0.010 1
10/10/13 13:16 2g
Sample: Lagoonl
Lab ID: 92175496005
Collected: 10/10/13 06:30
Received:
10/10/13 11:14 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters
Results Units
Report Limit DF
Prepared
Analyzed CAS No. Qua[
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C
E (MPN) 503
Fecal Coliforms, MPN
2.2 MPN/g
0.010 1
10/10/13 13:16 2g
Sample: Lagoonl
Lab ID: 92175496006
Collected: 10/10/13 06:30
Received:
10/10/13 11:14 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters
Results Units
Report Limit DF
Prepared
Analyzed CAS No. Qua[
92210E Fecal Coliform, MPN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN
5.1 MPN/g
0.010 1
10/10/13 13:16
Sample: Lagoonl Lab ID: 92175496007 Collected: 10/10/13 06:30 Received: 10/10/13 11:14 Matrix: Solid
Results -reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.' Qual
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 5.1 MPN/g 0.010 1 10/10/13 13:16
Date: 11104120 13 0 1:02 RVI
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wiihoui the wriden conseni of Pace AnalyUcai Services, Inc..
Page 7 of 30

o Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
;��Ia�88Analytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 IGncey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
c.iUALi I Y CONTROL uA TA
Project: SWANN LAGOON #1
Pace Project No.: 92175496
QC Batch: MERP/5707 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Anaiysis Description: 7470 Mercury TUP
Associated Lab Samples: 92175496001
METHOD BLANK: 1069218 Matrix: Water
Associated Lab Samples: 92175496001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 10119/1311:24
LABORATORY CONTROL SAMPLE: 1069219
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.4 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1069220 1069221
MS MSD
92174669001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.4 2.3 94 91 75-125 3
Date: I1104120,3 01:02 PIVI
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Without the Written consent of Pace Anaiytioai Services, Inc..
Page 8 of 30

fir
aceAnalydical
pacefabsxom
I
Project: SWANN LAGOON #1
Pace Project No.: 92175496
QC Batch: MERP/5698
QCBaichivieihod: EPA747i
Associated Lab Samples: 92175496002
METHOD BLANK: 1067804
Associated Lab Samples: 92175496002
Parameter Units
mglkg
Mercury
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL ROL. DATA
Analysis Method: EPA 7471
Analysis Description: 747'i Mercury
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0050 10/18/13 21:13
Pace Analytical Services, Inc.
9800 16ncey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1067805
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Mercury mg/kg .067 0.068 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1067806 1067807
MS MSD
92175170011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.016 .056 .074 0.067 0.088 90 97 75-125 28 R1
Date: 1 1/04120 13 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
withoui the written Consent of Face AnaiyUcai Services, inc_.
Page 9 of 30

m
aceAnalytical
vaw.,.pacelabs.com
Project: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUAUt I Y CONTROL ROL DATA
QC Batch: MPRP/14552 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 60i0 MET
Associated Lab Samples: 92175496001
METHOD BLANK: 1076403 Matrix: Solid
Associated Lab Samples: 92175496001
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
1110111312:36
Arsenic
mg/kg
ND
1.0
11101/1312:36
Cadmium
mg/kg
ND
0.10
11101/1312:36
Calcium
mg/kg
ND
10.0
11101/1312:36
Copper
mg/kg
ND
0.50
11/01/1312:36
Lead
mg/kg
ND
0.50
11/01/1312:36
Magnesium
mg/kg
ND
10.0
11101/1312:36
Molybdenum
mg/kg
ND
0.50
11101/1312:36
Nickel
mg/kg
ND
0.50
11/01/1312:36
Potassium
mg/kg
ND
500
11/01/1312:36
Selenium
mg/kg
ND
1.0
11/01/1312:36
Sodium
mg/kg
ND
500
11101/1312:36
Zinc
mg/kg
ND
1.0
11101/1312:36
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1076404
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
500
507
101
80-120
Arsenic
mg/kg
50
49.9
100
80-120
Cadmium
mglkg
50
51.7
.103
80-120
Calcium
mg/kg
500
566
113
80-120
Copper
mg/kg
.50
47.3
95
80-120
Lead
mg/kg
50
51.4
103
80-120
Magnesium
mg/kg
500
505
101
80-120
Molybdenum
mg/kg
50
52.7
105
80-120
Nickel
mg/kg
50
53.2
106
80-120
Potassium
mg/kg
500
480J
96
80-120
Selenium
mg/kg
50
49.4
99
80-120
Sodium
mg/kg
500
501
100
80-120
Zinc
mg/kg
50
55.9
112
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1076405
MS
92175496001
Spike
Parameter
Units
Result
Conc.
Aluminum
mgikg
128000
6040
Arsenic
mg/kg
ND
604
Cadmium
mgikg
ND
604
Calcium
mgikg
1900
6040
Copper
mg/kg
56.0
604
Date: 11/04120 13 0 :02 PiAi
Pace Analytical Services, Inc.
9800 IGncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
1076406
MSD
Spike
MS
MSD
IVIS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Quai
6280
i37000
144000
151
254
75-i-75
5 MYI6
628
586
617
96
98
75-125
5
628
566
594
94
95
75-125
5
6280
7590
7950
94
96
75-125
5
628
633
667
96
97
75-125
' 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Fare Anaiytcal Services, inc..
Page 10 of 30

_ ;a'ceAnalydcal
mm.pacelabs.com
Project: SWANN LAGOON #1
Pace Project No.: 92/75496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUAL1 I Y CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1076405
1076406
MS
MSD
92175496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD ClUal
Lead
mg/kg
17.3
604
628
566
595
91
92
75-125
5
Magnesium
mg/kg
999
6040
6280
6490 '
6810
91
93
75-125
5
Molybdenum
mg/kg
ND
604
628
594
614
98
98
75-125
3
Nickel
mg/kg
8.0
604
628
595
626
97
98
75-125
5
Potassium
mg/kg
ND
6040
6280
7970
8360
117
119
75-125
5
Selenium
mg/kg
ND
604
628
547
605
91
96
75-125
10
Sodium
mg/kg
ND
6040
6280
7250
7580
118
119
75-125
5
Zinc
mg/kg
172
604
628
762
785
98
98
75-125
3
Date: 1 1104/20 , 3 0 1:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wiihoul the wriiien consent of face AnaiyUcai Services, inc_.
Page 11 of 3u

aceAnalytical
mm.pacelabs.com
i
Project: SWANN LAGOON #1
Pace Project No.: 92i75496
QC Batch: MPRP/14473
QG Batch Method: EPA 30i0
Associated Lab Samples: 92175496001
METHOD BLANK: 1069210
Associated Lab Samples: 92175496001
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Units
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL ROL DATA
Analysis Method: EPA 6010
Anaiysis Description: 60 i 0 ivic t TCLP
Matrix: Water
Blank
Reporting
Result
Limit
Analyzed
ND
0.050
10/20/1312:57
ND
0.25
10120/1312:57
ND
0.0050
10120/1312:57
ND
0.025
10/20/1312:57
ND
0.025
1012011312:57
ND
0.10
10/20/1312:57
ND
0.025
10/20/1312:57
Qualifiers
Pace Analytical Services, Inc"
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1069211
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Arsenic
mg/L
2.5
2.6
103
80-120
Barium
mg/L
2.5
2.5
98
80-120
Cadmium
mg/L
2.5
2.5
98
80-120
Chromium
mg/L
2.5
2.5
98
80-120
Lead
mg/L
2.5
2.3
94
80-120
Selenium
mg/L '
2.5
2.6
103
80-120
Silver
mg/L
1.2
1.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1069212
MS
92174669001
Spike
Parameter
Units
Result
Cone.
Arsenic
mg/L
ND
2.5
Barium
mg/L
ND
2.5
Cadmium
mg/L
ND
2.5
Chromium
mglL
ND
2.5
Lead
mg/L
ND
2.5
Selenium
mg/L
ND
2.5
Silver
mg/L
ND
1.2
Date: 11/04/20 I3 01:02 PM
1069213
MSD
Spike
MS
MSD
MS
MSD
% Rec
Cone.
Result
Result
% Rec
% Rec
Limits
RPD
2.5
2.8
2.8
113
113
75-125
0
2.5
2.7
2.7
106
106
75-125
0
2.5
2.7
2.7
107
108
75-125
1
2.5
2.6
2.6
104
105
75-125
0
2.5
2.5
2.5
100
100
75-125
0
2.5
2.7
2.8
110
110
75-125
0
1.2
1.3
1.3
105
105
75-125
0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
wiinoui the wnUen conseni of Pace Anaiyticai Services, inc..
i
Qua[
Page 12 of 30

aceAnalytical
vnwzpacelabs.com
Project: SWANN LAGOON #1
Pace Project No_: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUAD t Y CONTROL DATA
QC Batch: MSV/24551 Analysis Method: EPA 8260
QC Balch Method: EPA 8260 Analysis Description: 8�60 ibis V TCLP
Associated Lab Samples: 92175496001
METHOD BLANK: 1065798
Associated Lab Samples: 92175496001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
10115/1316:39
1,2-Dichloroethane
ug/L
ND
5.0
10/15/1316:39
1,4-Dichlorobenzene
ug/L
ND
5.0
10115/1316:39
2-Butanone (MEK)
ug/L
ND
10.0
10/15/13 16:39
Benzene
ug/L
ND
5.0
10115/1316:39
Carbon tetrachloride
ug/L
ND
5.0
10/15/13 16:39
Chlorobenzene
ug/L
ND
5.0
10/15/1316:39
Chloroform
ug/L
ND
5.0
10/1511316:39
Tetrachloroethene
ug/L
ND
5.0
10/1511316:39
Trichioroethene
ug/L
ND
5.0
10/1511316:39
Vinyl chloride
ug/L
ND
5.0
10/15/13 16:39
1,2-Dichloroethane-d4 (S)
%
104
70-130
10/15/13 16:39
4-Bromofluorobenzene (S)
%
102
70-130
10/15/13 16:39
Toluene-d8 (S)
%
100
67-135
10/15/13 16:39
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1065799
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
61.9
124
70-141
1,2-Dichloroethane
ug/L
50
60.4
121
70-139
1,4-Dichlorobenzene
ug/L
50
56.0
112
70-141
2-Butanone (MEK)
ug/L
100
123
123
63-150
Benzene
ug/L
50
56.7
113
70-132
Carbon tetrachloride
ug/L
50
46.2
92
70-150
Chlorobenzene
ug/L
50
55.8
112
70-134
Chloroform
ug/L
50
59.0
118
70-130
Tetrachloroethene
ug/L
50
52.0
104
70-137
Trichloroethene
ug/L
50
51.2
102
70-131
Vinyl chloride
ug/L
50
54.0
108
56-144
1,2-Dichloroethane-d4 (S)
%
109
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
101
67-135
Date: 1110412013 0I:02 Pfv1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
withoui the written conseni of Face Anaiyiicai Services, inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 13 of 30

aceAnalytical
mimpacela6scom
Project: SWANK LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: OEXT/24305
QC Batch ivieihod: CPA 35i 0
Associated Lab Samples: 92175496001
METHOD BLANK: 1067798
Associated Lab Samples: 92175496001
Parameter
Units
Chlordane (Technical)
ug/L
Endrin
ug/L
gamma-BHC (Lindane)
ug/L
Heptachlor epoxide
ug/L
Methoxychlor
ug/L
Toxaphene
ug/L
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 8081
Analysis Description: 808i GCS TCLP Pesticides
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed Qualifiers
ND
3.0
10/18/13 20:31
ND
0.50
10/18/13 20:31
ND
0.50
10/18/13 20:31
ND
0.50
10/18/13 20:31
ND
1000
10/18/13 20:31
ND
3.0
10/18/13 20:31
79
10-138
10/18/13 20:31
81
10-110
10/18/13 20:31
LABORATORY CONTROL SAMPLE:
1067799
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Endrin
ug/L
1.2
1.4
111
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.1
90
20-118
Heptachlor epoxide
ug/L
1.2
1.1
85
22-133
Methoxychlor
ug/L
3.7
ND
103
44-150
Decachlorobiphenyl (S)
%
76
10-138
Tetrachloro-m-xylene (S)
%
77
10-110
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 10o
Huntersville, NC 28078
[phone]
Qualifiers
IvlAI rclA srrltct & MAI RIX SPIKE DUPLICATE:
1067800
1067801
MS
MSD
92175496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.4
1.4
113
115
21-133
2
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.2
1.1
94
93
24-119
2
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.1
1.1
92
91
50-150
1
Methoxychlor
ug/L
ND
3.7
3.7
ND
ND
95
94
50-150
Decachlorobiphenyl (S)
%
56
56
10-138
Tetrachloro-m-xylene (S)
%
84
80
10-110
Date: 1 1104/20 13 0 I :02 MM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Fare Anaiytical Services, Inc..
Page 14 of 30

• D � D
aceAnalytical
vnw.pacelabs.com
Project: SWANN LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALI i Y CONTROL DATA
QU Batch: OEXT/24255 Analysis Method: EPA 8270
QC Batch Method: EPA35i0 Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92175496001
IVIL I HUD BLANK: 1065866
Associated Lab Samples: 92175496001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
10116/1310:03
2,4,5-Trichlorophenol
ug/L
ND
50.0
1011611310:03
2,4,6-Trichlorophenol
ug1L
ND
50.0
10/1611310:03
2,4-Dinitrotoluene
ug/L
ND
50.0
10/16/13 10:03
2-Methylphenol(o-Cresol)
ug/L
ND
50.0
10/16/13 10:03
3&4-Methylphenol(m&p Cresol)
ug/L
ND
50.0
10/16/13 10:03
Hexachloro-1,3-butadiene
ug/L
ND
50.0
10/16/1310:03
Hexachlorobenzene
ug/L
ND
50.0
10116/1310:03
Hexachloroethane
ug/L
ND
50.0
10/16/13 10:03
Nitrobenzene
ug/L
ND
50.0
1011611310:03
Pentachloro phenol
ug/L
ND
100
10/16/13 10:03
Pyridine
ug/L
ND
50.0
10/16/13 10:03
2,4,6-Tribromophenol (S)
%
60
27-108
10/16/13 10:03
2-Fluorobiphenyi (S)
%
54
13-107
10/16/13 10:03
2-Fluorophenol (S)
%
37
10-110
10/16/13 10:03
Nitrobenzene-d5 (S)
%
59
12-102
10/16/13 10:03
Phenol-d6 (S)
%
26
10-110
10/16/13 10:03
Terphenyl-d14 (S)
%
63
21-132
10/16/13 10:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1065867
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
282
56
10-110
2,4,5-Trichlorophenol
ug/L
500
457
91
39-108
2,4,6-Trichlorophenol
ug/L
500
384
77
40-104
2,4-Dinitrotoluene
ug/L
500
502
100
42-109
2-Methylphenol(o-Cresol)
ug/L
500
371
74
31-110
3&4-Methylphenol(m&p Cresol)
ug/L
500
327
65
30-110
Hexachloro-1,3-butadiene
ug/L
500
269
54
10-110
Hexachlorobenzene
ug/L
500
387
77
39-121
Hexachloroethane
ug/L
500
269
54
10-110
Nitrobenzene
ug/L
500
410
82
32-101
Pentachlorophenol
ug/L
1000
750
75
18-108
Pyridine
ug/L
500
193
39
10-110
2,4,6-Iribromophenol (S)
%
90
27-108
2-Fluorobiphenyi (S)
%
79
13-107
2-Fluorophenoi (8)
%
49
10-110
Nitrobenzene-d5 (S)
81
12-102
Phenoi-d6 (S)
%
34
i u-i i 0
Terphenyi-di4 (S)
%
78
21-132
REPORT OF LABORA71 ORY ANALYSIS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
This report shall not be reproduced, except in full,
Date: 1 1104120 13 0 1 :02 PIA without the wriiien consent of FaceAnaiyticai Services, inc.. Page 15 of 30

e
aceAnalytical
vnwi pacelabs.com
I
Project: SWANN LAGOON #1
Pace Project No.: 52175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALi i t l iUN i Kui- LiiAiH
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1065868
1065869
MS
MSD
92175496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
1,4-Dichlorobenzene
ug/L
ND
500
500
299
255
60
51
30-150
16
2,4,5-Trichlorophenol
ug/L
ND
500
500
486
470
97
94
30-150
3
2,4,6-Trichlorophenol
ug/L
ND
500
500
424
380
85
76
30-150
11
2,4-Dinitrotoluene
ug/L
ND
500
500
496
521
99
104
30-150
5
2-Methylphenol(o-Cresol)
uglL
ND
500
500
431
377
86
75
30-150
14
3&4-Methylphenol(m&p
ug/L
ND
500
500
385
329
77
66
30-150
16
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
271
238
54
48
30-150
13
Hexachlorobenzene
ug/L
ND
500
500
428
373
86
75
30-150
14
Hexachloroethane
ug/L
ND
500
500
287
231
57
46
30-150
22
Nitrobenzene
ug/L
ND
500
500
448
401
90
80
30-150
11
Pentachlorophenol
ug/L
ND
1000
1000
707
781
71
78
30-150
10
Pyridine
ug/L
ND
500
500
221
204
44
41
30-150
8
2,4,6-Tribromophenol (S)
%
91
90
27-108
2-Fluorobiphenyl (S)
%
92
78
13-107
2-Fluorophenol(S)
%
56
46
10-110
Nitrobenzene-d5 (S)
%
91
79
12-102
Phenol-d6 (S)
%
41
33
10-110
Terphenyl-d14 (S)
%
69
73
21-132
Date: 1/104120 13 0 i :02 P JI
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, excepi in full,
withou'a the written consent of race AnaiyUcal Services, inc..
Qua[
Page 16 of 30

aceAnaly,tical0
vm%,.pacelabs.com
i
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NO 27288
[phone]
Project: SWANK LAGOON #1
pace pcojeci iSu-: 9237549106
QC Batch: PMST/5912
QC Batch Meihod: AS i M D2974-87
Associated Lab Samples: 92175496001, 92175496002
SAMPLE DUPLICATE: 1068376
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 1068377
Parameter
Percent Moisture
Dote: 1 110412013 0 1:02 PM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QiiAUl Y is -ON i iGlli_ DA 1A
Analysis Method: ASTM D2974-87
Anaiysis Descrip-Li Dry`v42iyi+iirerCei+i Moisture
92175143001 Dup
Result Result RPD Qualifiers
35.5 33.4 6
92176034004
Units Result
26.2
Dup
Result RPD Qualifiers
27.9 6
REPOR Ti OF LAYOKAI ORY ANALYSIS
This report shall not be reproduced, except in iuli,
wiihoui the wriitan conseni of FaceAriaiyticai Servicez, inc..
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NO 28078
[phone]
Page 17 of 1,30

AoMh
acmnalytical
vnwl.pacelabs.cora
i
Project: SWANK LAGOON #1
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QG batch: WET127624
QG Batch ivleihod: EPA 9045
Associated Lab Samples: 92175496001
SAMPLE DUPLICATE: 1066592
Parameter Units
PH at 25 Degrees C Std. Units
SAMPLE DUPLICATE: 1066593
Parameter Units
PH at 25 Degrees C Std. Units
Date: 1 1 /04120 1 3 0 I :02 PM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QU-1ALi i Y C U-bi T R 0 L DATA
Analysis Method: EPA 9045
Analysis Description: 9045 pH
92175170010 Dup
Result Result
7.1 7.3
92175334001 Dup
Result Result
9.2 8.7
RPD Qualifiers
4
RPD Qualifiers
6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wiihoui the written consent of race AnaiyUcal Services, inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
rage i9 ol;ju

�;a'ceAnalyfical0
myw.paceiabsxom
i
Project: SWANN LAGOON #1
Pace Proleci No.: y2 i75456
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
i ii iALi i t (:VN i KUL. LJAJIA
QC Batch: WETA/16751 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Anaiysis Description: 350.1 Ammonia
Associated Lab Samples: 92175496001
Mt I HUU t3lANK: 1065910
Associated Lab Samples: 92175496001
Parameter Units
Nitrogen, Ammonia mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 10/15/13 14:25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1065911
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg 500 480 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1065912 1065913
MS MSD
92175105001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Ammonia mg/kg 21.1 1050 1050 1040 1050 97 98 90-110 1
Dale-. 11i0412013 01:02 Pi•
1
REPORT OF LABORATORYANALYSIS
This report shall not be reproduced, except in full,
without the written conseni of Face Anaiyticai Services, inc..
Page 20 of 3u

aceAnalytical
v zpacelabs.com
I
Project: SWANN LAGOON -0i
Pace Project No.: 92175496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY.- i CON i RO-1- DATA
QC Batch: WETA/16736 Analysis Method: EPA 351.2
QC Batch Method: EPA 35i.2 Anaiysis Description: 351.2 TKN
Associated Lab Samples: 92175496001
METHOD BLANK: 1065113
Associated Lab Samples: 92175496001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 10/15/1314:45
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1065114
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mglkg 1000 915 91 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1065115 1065116
MS MSD
92175105001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 1540 1170 2010 2580 3620 89 104 90-110 33 M1,R1
Date: 11104,12013 0 1:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the w(Rien consent of 'race Anaiyucai Services, Inc;..
Page 21 of 30

( f
aceAni aalytical
vmvi pacelabs.c=
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Project: SWANN LAGOON #1
Pace Project No-: 92 17549-
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
C.Ni,-iAU i Y C ONV N ROL DA A
QC Batch: WETA/16845 Analysis Method: EPA 353.2
QC Batch Method: ERA 353.2 Analysis Description: 353.2 Marate + i nnie
Associated Lab Samples: 92175496001
METHOD BLANK: 1072506
Associated Lab Samples: 92175496001
Parameter Units
Nitrogen, Nitrate mg/kg
Nitrogen, Nitrite mg/kg
Nitrogen, NO2 plus NO3 mg/kg
Matrix: Solid
Blank Reporting
Result - Limit Analyzed
ND 2.0 10/25/13 04:20
ND 1.0 10/25/13 04:20
ND 2.0 10/25/13 04:20
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1072507
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 25 24.0 96 90-110
Nitrogen, Nitrite mg/kg 10 10.0 100 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 24.0 96 90-110
MATRIX SPIKE & MATRIX,SPIKE DUPLICATE:
1072508
1072509
MS
MSD
92175496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qua]
Nitrogen, Nitrate
mg/kg
ND
, 304
304
290
289
94
94
90-110
0
Nitrogen, Nitrite
mg/kg
ND
123
123
123
122
101
100
90-110
1
Nitrogen, NO2 plus NO3
mg/kg
ND
304
304
290
289
94
.94
90-110
0
D ate: ii/04120 13 "v 1:02 Pm
REPORT OF LABORAT ORY ANALYSIS
This report shall not be reproduced, except in iuii,
WirnOUt fhe wriRen consent of race Anaiyticai Services, inc..
Page 22 6i 30

m
acmnalytical
mm.pacelabs.com
Project: SWANN LAGOON #1
Pace Project No.: 921 15496
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QU-ALi T Y z:ONT�:uL DATA
QC Batch: WETA116741 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Anaiysis Description: 365.1 Phosphorus, Total'
Associated Lab Samples: 92175496001
METHOD BLANK: 1065166
Associated Lab Samples: 92175496001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 1065167
Parameter Units
Phosphorus mg/kg
1 • { p I' -
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28076
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.0 10/15/1311:14
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 52.3 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1065168 1065169
MS MSD
92175105001 Spike - Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 112 240 293 354 406 101 101 90-110 14
Date: 11/0412013 V 1:02' P.M.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in NO,
without the wriuen consent of FareAnaiyricai Services, inc..
Page 23 of 30

aceAnalytical
mwi.pacefabsxom
Project: SWANN LAGOON #1
Pace Project No.: 94t 0 tuti
IJE?ii 11 T IONS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Ltii�RUr ICK0
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PRL- Pace Reporting Limit.
RL- Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-R Pace Analytical Services - Raleigh
ANALYTE QUALIFIERS
1 g 8260 results are from a total analysis which show that analytes are not present or that they are present but at such low
levels that the appropriate regulatory levels could not possibly be exceeded, per Section 1.2 of Method 1311.
2g This is a less than value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
[phone]
This report shall not be reproduced, except in iuil,
✓�aE: i i 04i20 13 01:02 R., viiUioui the written consent of race Analyticai Services, inc.. Page 24 of 3ii

aceAnalyticalrD wml.pacelabs.com
i
I
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALI i i C."O i i R03L. DATA GROSS REF ERCE fC E
Project: SWANN LAGOON #1
Pace Project No.: 921754965
Pace Analytical Services, Inc.
9800 IGncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Lab ID
Samnle rn
QG Batch Method
C Batch
Anah,?leaf MethnV{
R2tch
92175496001
LAGOON 1
EPA 3510
OEXT/24305
EPA 8081
GCSV/15782
92175496001
LAGOON 1
EPA 3050
MPRP/14552
EPA 6010
1CP/13223
92176496001
LAGOON 1
EPA 3010
MPRP114473
EPA 6010
ICP/13158
92175496001
LAGOON 1
EPA7470
MERP/5707
EPA7470
MERC/5522
92175496002
Lagoon 1
EPA 7471
MERP15698
EPA 7471
MERC/5516
92175496001
LAGOON 1
EPA 3510
OEXT124255
EPA 8270
MSSV/8307
92175496001
LAGOON 1
EPA 8260
MSV/24551
92175496001
LAGOON 1
ASTM D2974-87
PMST/5912
92175496002
Lagoon 1
ASTM D2974-87
PMST/5912
92175496001
LAGOON 1
SM9221C E (MPN) 503
RBIO/3252
92175496002
Lagoon 1
SM9221C E (MPN) 503
RB10/3252
92175496003
Lagoonl
SM9221C E (MPN) 503
RB1013252
92175496004
Lagoonl
SM9221C E (MPN) 503
RBIO/3252
92175496005
Lagoonl
SM9221C E (MPN) 503
RBIO/3252
92175496006
Lagoonl
SM9221C E (MPN) 503
RB10/3252
92175496007
Lagoonl
SM9221C E (MPN) 503
RBIO/3252
92175496001
LAGOON 1
EPA 9045
WET/27624
92175496001
LAGOON 1
40CFR PART 432.2
WET/27792
92175496001
LAGOON 1
EPA 350.1
WETA/16751
92175496001
LAGOON 1
EPA 351.2
WETA/16736
92175496001
LAGOON 1
EPA 353.2
WETA/16845
92175496001
LAGOON 1
EPA 365.1
WETA/16741
Vale: 7 U04120 i3 01:02PIM
REPORT OF LABOR.a TORY ANALYSIS
This report shall not be reproduced, except in full,
wia out the written consent of PaceAnaiyticai Services, inc..
Page LJ ul JU

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Fleld-Data Required? - Y
Person Contacted:
COMMOMI Re§o,ldoin:'
scURF Review, Date: place. label heYe
SR;'Revlew-�
Note; Whenever thore, is a cilsorepancy affecting Noftb Caro.06 cOMO
semples,'ia copy of this form will be sent to the North W&O'Brz
Certification Office ( Lo out of.hold, incorrect preservative, -Out,6f fft-P,*,-`v",.!*-
incorrect containers)
Page 28 of-30

aceAnalytical
ww.pacdabs:com
Ship To:
Pace Analytical Ormond
Beach
8 East Tower Circle
Ormond Beach, FL 32174
Phone[phone]
INTER LABORATORY WORK ORDER # 92175496
(To be completed by sending lab)
Sending Project No
92175496
Receiving Project No
-
Check Box for Consolidated Invoice
FON
10/10/13
Date Prepared
REQUESTED COMPLETION DATE
10124/2013
Sending Region
IR92-Charlotte
Sending Project Mgr.
Terri Page •
Receiving Region
IR35-Ormond Beach
External Client
City of Winston Salem
State of Sample Origin
QC Deliverable
-STD REPORT
All questions should be addressed to sending project manager.
Requested Reportable Units Report Wet or Dry Weight? Dry Weight Cart. Needed
•`Y"- - - - — <.3: - _ .4.:a.�i'.=.}'r,..rs ::<>r, .q-_. _ ..r.ti�.�t %'.: �,n'r.� Tr.;Y.\�. � ,Y.+i.2ti _ _
.,4,a.C'- r�;li'NS���°,. Y;_'•�- '�?` - '.•,�,;...::V _o::WQfR - `TCc _ ..... �. y Y:' `s7 5
n
._.__,...._:_:��gr:.:�-.T,S•�,t4?;s::=�.'';; _" :,c;.>f,_' QU> prx..:��?�'T."`�.�.�>�''4^�- ` ���*,f''E'�=�i,'.ls�
-
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a"c:✓."` max -s�:.-'a'r . r i�:ti.t n_r,� _.,7.,�f`�r`� `. �
_ WGFU Unpreserved 1 $150.0 $150.0t
TOTA $150.0C
Special Requirements:
_ Yam..•• _ - - ;�-r . - -e,�.• • .i . rr•`� a.. -�' •'.Sri . ,�r�ec• r, c:
- 1�R�R fkNAt�YT Cm'L,INOR : -� •� •- � ,.x t _ ..�-
;`:��` - - - �'''= I.. A i{lC�t�:f�E7'�DxTIFS-acf.E/,�.�`.lil0
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Chain of Custody Included: M Yes P;�;J—No Return Samples to Sending Region: ❑ Yes No
Matrix: Soil PANater 'Air ❑ Other (Identify)
-s _ _�.;_ _z:���--� �- vE:6�:,.1.�IR14}�TIOp1.OF:WO' .6Gp :,_ �E �;�;'�=;'• �.
Date Completed:
Receiving Project Manager:
- _ _ _ .��=Y!l ..:.4•a-.Y%.L-).-.-1�1:3:T?t •a r.-lv1.F> .•vS�.ae-'z. v d ,.,!•y�u�^'� � -f.-. 2- ,{Tyh.., � - ]�.1�.:./:%='. ;:T t�.•5c-a�vr'".ls ;4...�'FI.•.tu.1a�_:i.i'1at 3 �'�Gi:... �i
Original sent to the receiving lab - Copy kept at the sending lab. m
When work completed: Original sent to the ABM at the receiving laboratory. Copies are made to corporate as needed.
Thursday, October 10, 2013 5:20:28 PM
FMT-ALL-C-001 rev.00 24March2009 Page 1 of 1
Page 29 of 30

(D
0
W
0
Chain of Custody -a.WeAnalytical
V1WW.p8Q01ab$xM
W—L,^rAnr- 0917-rUCIS Wnrknrtipr Nanne:SWANN LAGOON41 Owner Received Date: 10/10/2013 Results Requested By: 10/24/2013
MMII-i' M M � �Wlprffim MIEZ
Terri Page Pace Analytical Ormond Beach
Pace Analytical Services, Inc. 8 East Tower Circle
9800 KinceyAve., Suite 100 Ormond Beach, FL 32174
Huntersville, NC 28078 Phone [phone]
Phone [phone]
Fax [phone]
M 03W"'
LE
LAB USE ONLY
i.
1
ILAGOON1
Ps
10/10/2013 06:30
92175496001
Solid
1
2
3
4
5
IN M-10"Iffil 0101-00H 1 MVP j
Transfers Released By. Datefrime Received By DateMme
I -
2
3
Cooler Tem erature on Receipt Received on lee Y or N GustodySeal Y or N _Samples Intact Y or N
Thursday, October 10, 2013 5:20:28 PM
FMT-ALL-"02rev.00 24March2009 Page 1 of 1 -

a� a stir ra ti
Ssunnrlt F]svlrotw»eyal Teehrwlogles, lua.
3310 Net&
Er7Y1RON1A2N7ALT CHNOCpGf$Sy04 Cuyahoga Falls, Ohlo 44223
klr'alylicsL�3iti@rn¢BI$is 7E4' [phone] FAX. [phone]
lVebslte: M2YAmwellekeom-
October 30, 2013
Terri Page
Pace Analytical Eden
205 East Meadow Rd.
Eden, NC 27288
TEL: [phone]
FAX:
RE: •92446495­9a1'i5111 Ot Le
Dear Terri Page: Order No.: 13101143
Summit Environmental Technologies, Inc, received 1 sample(s) on 10/15/2013 for the analyses
presented in the following report.
There were no problems with the analytical events associated with this report unless noted in the
Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits except
where noted.
If you have any questions regarding these tests results, please feel free to call the laboratory.
Sincerely,
A-'--Lo C)
Dr. Mo Osman
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
A2LA0724.01,Alaba 41600,Arkansas88-0735,Califomia07256CA,CnIOmdo,CwnedicutPH-0105,Ddawuci Fbrida NELACE87688.GeorglaE87688
and 943,Idahe OH00923, lltimis 20MI and Rcg.5, Indiana C-0H-13, Kansas E-10347, Kentueky(undergroundSlorageTmk) 3, Kmtucky90146, I.ou slana
04061 and IAI2004, Maine 2012015, Marylanr1339, MaaSWIUrdts M-0PH923, Minnesota 40971 ],Mantua CERT0099, New Hampshire2996, New Imeey
OH006, New York 11777,North Carolina 39705 and 631, Ohio 4170, Ohio VAP CL0052, Okbboma9940, Oregon 0112O0001,1'masylvania68-01335, Rhode
Island LA000317,South Carolina92016001.T===TN04018, Tau T104704466.11.5,11gion8 BPMS-1, USDAMPHIS P330-11 M244,Utah
OH009232011-1, Vermont VT-87688, Vlr9or1a00440 and 1581, Wuhtugton C891, West Virginia 248 nd 9957C and E87688. Wisconsin 399013010
Pagel of3

y 441 0,1 "p
e
c , S-1,El vy wwlal Technologlu, lnc. Workorder
3310 0inS/
tH1�iA'OHM 37JrtLYF HNd Gt §;]k C*W)Qga Falls, Ohla 44223 Sample Summary
J1np�5rjjpgj:6:AppFa},pr &sC 7F1: [phone] FAX: [phone] WOE{: 13101143
iYebrile: (tf8t / •^• a 11 a om 30Oct13
CLIENT: Pace Analytical Eden
Project: 92175495
Lab SamplelDCllent Sample ID Tag No Date Collected Date Received Matrix
13101143.001 92175496001 10110/2013 6:30:00 AM 1011=013 10:00:00 AM Solid
Page 2 of

4 { i".' h v
Summit r4viramientat Tedmiugia, Inc. WOW.• 13101143
3310 I1rnSt.
•• i'?IfnHbia •NY11L7EC11Nb.[AGIBS,.R1G Cuyr lmga Fatly, Ohto 44123 Date Reported: 10/30/2013
fitr<)lyYtdaf fat prnMlte3 Mr [phone] FAX: [phone] CompanyTace Analytical Eden
Websire: hno:/Ae.: ysettekcom Address:205 East Meadow Rd.
Eden NC 27288
Received:10/15/2013
Project#:92175495
Client EM Lab ENCollected Analyte ResultUnits Matrix Method DF RL Run Analyst
92175496001
001
1011=013 Flashpoint(140°F)
921754MI
001
10/1012013 Cyanide, Reactive
92175496001
001
10/1012013 pH
921764MI
001
10/10=13 Suifide, Reactive
>140 T
Solid
EPA 1010 1
'10/28/201
TAH
3
ND mgtKg
Solid
EPA 9014 1
0.50 10/17/201
TIR
3
8.3 s.u.
Solid
EPA 9045 D 1
10/17/201
AYS
3
ND porn
Solid
EPA 9034 1
25 10tiW201
MR
3
Page 3 of 3

44--ce na i ica;
Pace Analytical Services, Inc.
205 East tvleadovl Road - SuiteA
Eden. NC 27286
[phone]
Pace Analytical Services, Inc.
- 2225 Riverside Dr.
Asheville, NO 2884S
[phone]
Pace Analytl al Servic,s, Inc.
9800 KinceyAve. Suite 100
i-iuntersvilie, NC 23078
[phone]
Project: Sl11ANN LAGOON 1
Pace Project No.: g2:75=:g
n non "4'" �:.L r� tin-LIc
AN L9 me �+NL fl. Q J
Sample: LAGOON 1 '_ab ll?: 921754N'0101 Collected: 10/ 10113 06:30 Received:/0110/13 16:21 Matrix: Solid
�rngiir r nni-inri �n a-rirv-uinini:' Das.s
P;wnrnatarc P''a.lIItg t1 nl "lanorl 1, imit D:= PrPn;;rPd Ann, :vzprl CAS Nn ^• ^l
8270 A9SSV TCLP Sep Funne!
Hexachl oro-1,3-butadiene'
Hexachiorobenzene
Hexachloroethane
2-fvlethy1phen oi(o-Cresol)
3&4-fV1ethylphenol(m&p Cresol)
iq!trobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
2 4,6- i richiorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyi-d'i4 (S)
Pheno)-16 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
i 4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetra chloroethene
Trichloroethene
Vinyl chloride
Surrogates .
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
52210E Feca; Cofi:orm, !M iti scAL
su-5 Ji' Soil
L,atY. i1;04;2013 01:U2 P',M
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate !vlethodiDate: EPA 1311: 10114ii3 15.J0
ND ug/L
50.0
1
10/15/13 14:45 10/1,6113 19:56 87-68-3
ND ugiL
50.0
1
10i15ii3 14:45 *1W16ii3 i9:55 118-74-1
ND ug/L
50.0
1
10115/ 13 14:45 10/16/13 19:56 67-72-1
ND ugiL
50.0
'1Oi15i'I3'14:45 10/'i6i'i3'i9:56 95-48-7
ND ug/L
50.0
1
10/ 15/ 13 14:45 10/16/13 19:56
ND ugiL
50.0
i
'i &i - 5113 -i 4:45 10i'i &N 3 19:56 98-95-3
ND ug/L
100
1
10/ 15113 14:45 10/ 16/13 19:56 87-86-5
ND ugiL
50.0
-1011511s 14:45 10/i61'13 19:56 i i0-86=i
ND ug/L
50.0
1
10115/ 13 14:45 10/16/13 19:56 95-95-4
ND ugiL
50.0
'101i 5/13 14:45 101i 6/13 19:56 88-06-2
6'i %
12-1 O2
!
-i Oi15i 13 i 4:45 1 Oi'i 6113 i 9:56 Ai 65-60-0
65 %
13-107
1
10/15/13 14:45 10/16/13 19:56 321-60-8
67 %
21=i32
i
10/15113 -i4:45 '101-i61-i3 19:56 1718-5'1-0
32 %
10-110
1
10/15/13 14:45 10/ 16/13 19:56 13127-88-3
39 %
"10- ! 10
1
101"i 51"I 3 -14:45 -i Oi'16/'13 19:56 36 7-12-4
83 %
27-103
1
10/1511314:45 10116/1319:56 118-79-6
Analytical Method: EPA 8260
ND ug/L
192
38.5
10/16/13 00:32 71-43-2
ND ug1L
385
38.5
10/16/ 13 00:32 78-93-3
ND ug/L
192
38.5
10/16/13 00:32 56-23-5
ND ug/L
192
38.5
10/16/13 00:32 .108-90-7
ND ug/L
192
38.5
10/16/13 00:32 67-66-3
ND ug/L
192
38.5
10/ 16/13 00:32 106-46-7
ND ug/L
192
38.5
10/16/13 00:32 107-06-2
ND ug/L
192
38.5
10/16/13 00:32 75-35-4
ND ug/L
192
38.5
10/16/13 00:32 127-18-4
ND ug/L
192
38.5
10/16/13 00:32 79-01-6
ND ug/L
192
38.5
10116113 00:32 75-01-4
109 %
70-130
38.5
10/16/13 00:32 17060-07-0 1g
101 %
67-135
38.5
10/16/13 00:32 2037-26-5
103 %
70-130
38.5
10/16/13 00:32 460-00-4
Analytical Method: ASTM D2974-87
92.0 %
0.10
1
10/21/13 15:09
AIiaiyticai i:'Ieihod: SM9LG 10 E (llPN)
5-03
1.7.8:apK'1^y
0.1.V
'
!i10i1"313:16 2L7
A�12iy1,icai i;lethod,: Ei A 90-5
i hiS rcj.wi ouou vvi w rc}riwo , cn:.ENi iu , ,
wiint.Lr ille :Y[iitl! rnii5cili :i i- rl f-,rhiytCssi

q�r r�zyl
t..,ace.Zcs.Co- r..
- -- '--'Y �...�„ oc,•aces. Inc.
205 East Mieadoel Road - Suite A
Eden, NO 27288
[phone]
MIV/'iLi i 1V�3.G�
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheviiie, NO 2880,
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
}•luniersvilie, NIC 28078
[phone]
Prn%ert- tlilagl ILAGOON
ace Y- jecl 114 -21 I..4.40
Sample: LAGOON ' L ab fD: 92175496001 Collected: 101i0/13 06:30 RF
ct it(?d10.1
10/ 13 1 ti 21
:�esuiis renr,.a��: ,,,; a , r_ty�r :�� - •
PF.P ;:?±?
Total Nitrogen Calculation
Nitrogen
350.5 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
Nitrogen, NO2 plus NO3
365.1 Phosphorus, Total
Phosphorus
Analytical Method: 40CFR PART 432.2
944o mg/kg
40.0
Analytical Method: EPA 350.1
407 mg/kg
126
Analytical Method: EPA 351.2
9440 mg/kg
405
Analytical Method: EPA 353.2
ND mg/kg
25.0
ND mg/kg
ND mg/kg
12.5
25.0
Analytical Method: EPA 365.1
2760 mg/kg
251
r'i- �ranara +Annlred nni Nn 0',in!
1 10125/ 13 10:40 7727-37-9
1 10/15/1314:32 7664-41-7
1 10/15/1314:52 7727-37-9
1 10/25/13 04:27
1 10/25/13 04:27
1 10/25/13 04:27
5 10/15/1311:45 7723-14-0
Sample: Lagoon 1 Lab ]D: 92175496002 Collected: 10/10/13 06:30
Results reported on "dry
Received:
10/1Oil 3 i1:14 Matrix: Solid
a -weight"
basis
Parameters
Results Units Report Limit DF
"Prepared
Analyzed CAS No
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
0.053 mg/kg 0.039 1
10/17/13 15:45 10/18/13 22:10 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
91.6 0-10 1
10121,113 15:09
92210E Fecal Colifonn, M3PN RAL
Analytical Method: SM9221C E (MPN) 503
Fecal Colijorms, MPN
111 MPN/g 0.12 1
10/10/13 13:16
Sample: Lagoon 1 Lab 1D: 92175496003 Collected: 10/10/13 06:30
Results reported on a "Wet
Received:
10/10/13 11:14 Matrix: Solid
-weight" basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No.
92210E Fecal Collrorm, iViPN RAL
Analytical Method: SM9221C E (PviPN) 503
i=•arai (Jniifnrmc r�rat�i
2,� I�r?rh� n Min -i
. -
10/10!13 i3:16
iJUt4, i iIV4/LV13 ill ,il% +iVi
i AIN!-'_l-.T+-,f;3
,2^YCn^ a nva vc r2ary :used, except In •"
4r. _Il �:i 11 _1} Wiit_Ctl (Y�[!SB!!i 0i :-BC�.C.n�lyiir-ai glvirov i11G..
Qual
Qual
:'age cf 3u

.......P0ce!abs.ccrr.
Pace Analytical Services, Inc.
205 East Meadow Road - Suite
Eden, NC 27288
[phone]
Pace Analyticai Services, Inc.
2225 Riverside Or.
Ashevilie, NC 28804
[phone]
Pace,Analyt .al �e tryic*, Inc.
9800 Kincey Ave. Suite 100
liuntersvilie. NC 28078
[phone]
Project: SV,4ANN LAGOON r1
ace ,-r 0le..t NO.: 92:: ;h' 9.�,
Sannple: Lagoon i Lab ID: 92175496004 Collected: 10110/ 13 06:30 Received:/0110113 i i:14 L;atrix: Solid
wes!u1s repo: tea or. 2 '!YeF-tvei�rz ` SiwslS
�ar6rn?ia:R RPCIIiiR !_I litg Rarinl l_irnl l pF Pre erred Ann!v:a CAS :v!o Oiler;
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221 C E (MPN) 503
Fecal Coliforms, MPN 2.2 MPNIg 0.010 1 10/ 10/ 13 13:16 2g
Sample: Lagoonl Lab ID: 92175496005 Collected: 10/10/13 06:30 Received: 10/10/13 11:14 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Umit DF Prepared Analyzed CAS No. Qual
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms, MPN 2.2 MPN/g 0.010 1 10/10/13 13:16 29
Sample: Lagoon-1 Lab ID: 92175496006 Collected: 10/10/13 06:30 Received: 10/10113 11:14 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
92210E Fecal Coliform, WN RAL Analytical Method: SM9221C E (MPN) 503
Fecal Coliforms. MPN 5.1 MPNIg 0.010 1 10/10/13 13:16
Sample: Lagoonl Lab ID: 92175496007 Collected: 10/10/13 06:30 Received: 10/10/13 11:14 Matrix: Solid
Resu/fs reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quaff
92210E Fecal Coliform, MPN RAL Analytical Method: SM9221C E (MPN) 503
Feral Coliforms, MPiv 5.1 m1pN/g 0.010 "1 1Oil Oil 3 "13:16
iJc+tc:, 1110412-013 ( :i12 f"iv,
F, VR: c.3F i._-tB(Drwiti.i,i
, n:This re}+�iii 3�iaii i Gi i? rc^t7rwuCd''u, axc2yt in iuii,
yffthrmJt Ulu vyl Mien of Pace ii,naiyilC2l1 Oel yl-Jw�, ifl,;..