Appendix A - MSD Sheets

PIEDMONT
Appendices
Response to DEMLR Additional
Information Request (dated
October 29, 2021)
Gaston County, North Carolina
December 15, 2021

Piedmont Lithium Carolinas, Inc. I Response to DEMLR Additional Information Request
Appendices
PIEDMONT
LITHIUM
a i
Appendix A: MSD Sheets

LTS Research Laboratories, Inc.
Re arch
LT Safety Data Sheet
Iron Silicide
1. Product and Company Identification
Trade Name: Iron silicide
Chemical Formula: FeSi
Recommended Use: Scientific research and development
Manufacturer/Supplier:
LTS Research Laboratories, Inc.
Street:
37 Ramland Road
City:
Orangeburg
State:
New York
Zip Code:
10962
Country:
USA
Tel #:
855-587-2436 / 855-Its-chem
24-Hour Emergency Contact:
800-424-9300 (US & Canada)
[phone] (International)
2. Hazards Identification
Signal Word: Warning
parch
Is. irtic.
Hazard Statements: H315 Causes skin irritation
H319 Causes serious eye irritation
Precautionary Statements: P261 Avoid breathing dust/fume/vapor
P305+P351 If in eyes: Rinse cautiously with water for several minutes.
HMIS Health Ratings (0-4):
Health: 1
Flammability: 0
Physical: 0
3. Composition
Chemical Family: Ceramic
Additional Names: Iron monosilicide, Iron silicon alloy
Iron silicide (FeSi):
Percentage: 100 wt%
CAS #: 12022-95-6
EC #: 234-671-8
1 of 4

4. First Aid Procedures
General Treatment:
Seek medical attention if symptoms persist.
Special Treatment:
None
Important Symptoms:
None
Inhalation:
Remove victim to fresh air. Supply oxygen if breathing is difficult.
Ingestion:
Give one to two glasses of water and induce vomiting. Never induce
vomiting or give anything by mouth to an unconscious person.
Skin:
Wash affected area with mild soap and water. Remove any
contaminated clothing.
Eyes:
Flush eyes with water, blinking often for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing
5. Firefighting Measures
Flammability:
Non-flammable
Extinguishing Media:
Do not use water — use CO2, sand, extinguishing powder.
Spec. Fire Fighting Procedure:
Use full -face, self-contained breathing apparatus with full protective
clothing to prevent contact with skin and eyes. See section 10 for
decomposition products.
6. Accidental Release Measures
If Material Is Released/Spilled:
Wear appropriate respiratory and protective equipment specified in
special protection information. Isolate spill area and provide
ventilation. Vacuum up spill using a high efficiency particulate
absolute (HEPA) air filter and (place in a closed container for disposal.
Take care not to raise dust.
Environmental Precautions:
Isolate runoff to prevent environmental pollution.
7. Handling and Storage
Handling Conditions:
Wash thoroughly after handling.
Storage Conditions:
Store in a cool dry place in a tightly sealed container. Store apart from
materials and conditions listed in section 10.
Work/Hygienic Maintenance:
Do not use tobacco or food in work area. Wash thoroughly before
eating and smoking. Do not blow dust off clothing or skin with
compressed air.
Ventilation:
Provide sufficient ventilation to maintain concentration at or below
threshold limit.
8. Exposure Controls and Personal Protection
Permissible Exposure Limits:
None
Threshold Limit Value:
None
Special Equipment:
Respiratory Protection:
Protective Gloves:
Eye Protection:
Body Protection:
None
Dust Respirator
Rubber gloves
Safety glasses or goggles
Protective work clothing.
sleeves/pants.
Wear close -toed shoes and long
2 of 4

Color
Form:
Odor:
Water Solubility:
Boiling Point:
Melting Point:
Flash Point:
Autoignition Temperature:
Density:
Molecular weight:
Stability:
Reacts With:
Incompatible Conditions:
Hazardous Decomposition Products:
Potential Health Effects:
Eyes:
Skin:
Ingestion:
Inhalation:
Chronic:
Signs & Symptoms:
Aggravated Medical Conditions:
Median Lethal Dose:
Carcinogen:
9. Physical and Chemical Characteristics
Grey
Powder, Granules, Pellets, Sputtering target, Custom parts
Odorless
Insoluble
N/A
1410 °C
N/A
N/A
6.1 g/cc
83.93 g/mol
10. Reactivity
Stable under recommended storage conditions
Strong oxidizing agents
None
Metal oxide fume
11. Toxicological Information
May cause serious irritation
May cause irritation
May cause irritation
May cause irritation
N&; A
LX Re�arch
rstoriss, inc.
N/A
N/A
N/A
12. Ecological Information
Aquatic Toxicity: Low
Persistent Bioaccumulation Toxicity: No
Very Persistent, Very Bioaccumulative: No
Notes: N/A
13. Disposal Considerations
Dispose of in accordance with local, state, national, and international regulations.
14. Transportation Data
Hazardous:
Not hazardous for transportation.
Hazard Class:
N/A
Packing Group:
N/A
UN Number:
N/A
Proper Shipping Name:
N/A
3 of 4

15. Regulatory Information
Sec 302 Extremely Hazardous: No
Sec 304 Reportable Quantities: N/A
Sec 313 Toxic Chemicals: No
16. Other Information
This safety data sheet should be used in conjunction with technical sheets. It does not replace them. The information
given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of
the user is drawn to the possible risks incurred by using the product for any other purpose other than that for which it
was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his
activity. It is the sole responsibility of the user to take all precautions required in handling the product. The aim of the
mandatory regulations mentioned is to help the user to fulfill his obligations regarding the use of hazardous products.
Document Last Revised: 04/24/2015
NN
LT&-'Rexarch
rBWrieB. Inc.
4 of 4

Arizona
MATERIAL SAFETY DATA SHEET
- CHEMICAL
1. Product and Company Identification
Material name
SYLFATTm FA2
Version #
1.0
Revision date
05-07-2012
Product Code
2000075, 2000652, 2000727, 2000728, 2001600, 2001602, 2001611, 2001648
Manufacturer information
Arizona Chemical Company, LLC
Building 100
4600 Touchton Road East, Suite 1200
Jacksonville, FL 32246 United States
Fax [phone]
Phone [phone]
Phone [phone]
Emergency -US CHEMTREC 800-424-9300
2. Hazards Identification
Emergency overview After prolonged contact with highly porous materials, this product may spontaneously combust.
Health injuries are not known or expected under normal use.
OSHA regulatory status This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Not applicable.
Eyes Health injuries are not known or expected under normal use.
Skin Health injuries are not known or expected under normal use.
Inhalation Health injuries are not known or expected under normal use.
Ingestion Health injuries are not known or expected under normal use.
3. Composition / Information on Ingredients
Non -hazardous components CAS # Percent
Tall Oil Fatty Acids 61790-12-3 100
4. First Aid Measures
First aid procedures
Eye contact
Skin contact
Inhalation
Ingestion
General advice
S. Fire Fighting Measures
Flammable properties
Extinguishing media
Suitable extinguishing
media
Rinse with water. Get medical attention if irritation develops and persists.
Get medical attention if irritation develops and persists. Rinse skin with water/shower.
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
If you feel unwell, seek medical advice (show the label where possible).
Not flammable by OSHA criteria. Not combustible by OSHA criteria. Porous material such as rags,
paper, insulation, or organic clay may spontaneously combust when wetted with this material.
Water spray, dry chemical, carbon dioxide.
Material name: SYLFATTm FA2 MSDS/SDS # 1257/2061E MSDs us
Version #: 1.0 Revision date: 05-07-2012 Print date: 05-07-2012 1/6

Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Protection of firefighters
Specific hazards arising
Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular
from the chemical
weight hydrocarbons.
Fire fighting
Wear suitable protective equipment. Move containers from fire area if you can do so without risk.
equipment/ instructions
6. Accidental Release Measures
Personal precautions
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up.
Environmental precautions
Prevent further leakage or spillage if safe to do so.
Methods for containment
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop the
flow of material, if this is without risk. Dike the spilled material, where this is possible.
Methods for cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers.
Small Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re -use.
7. Handling and Storage
Handling
Contaminated rags and cloths must be put in fireproof containers for disposal. Observe good
industrial hygiene practices. Follow all MSDS/label precautions even after container is emptied
because they may retain product residues. Porous material such as rags, paper, insulation, or
organic clay may spontaneously combust when wetted with this material. May auto -oxidize with
sufficient heat generation to ignite if spread (as a thin film) or absorbed on porous or fibrous
material.
Storage
Keep away from heat, sparks and open flame. Keep containers closed when not in use. Do not
store in direct sunlight. Store at ambient temperature and atmospheric pressure. Use care in
handling/storage.
8. Exposure Controls / Personal Protection
Occupational exposure limits
ACGIH
Components Type Value Form
Tall Oil Fatty Acids
(61790-12-3)
U.S. - OSHA
TWA
5 mg/m3 Oil Mist; Respirable
Components Type Value Form
Tall Oil Fatty Acids
(61790-12-3)
IBYLO
Personal protective equipment
Eye / face protection Safety glasses.
5 mg/m3 Oil Mist; Respirable
Skin protection Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene Handle in accordance with good industrial hygiene and safety practice. Eye wash fountain and
considerations emergency showers are recommended. Launder contaminated clothing before reuse.
9. Physical & Chemical Properties
Appearance Liquid.
Physical state Liquid.
Form Liquid.
Color Yellow.
Material name: SYLFATTm FA2 MSDS/SDS # 1257/2061E MSDs us
Version #: 1.0 Revision date: 05-07-2012 Print date: 05-07-2012 2/6

Odor
Mild.
pH
Not available.
Vapor pressure
< 0.001 mm Hg at 200C
Boiling point
> 392 OF (> 200 °C)
Melting point/Freezing point
41 OF (5 °C)
Solubility (water)
12.6 mg/L at 20OC; Data is for similar product.
Relative density
0.9 at 250C/25OC; (water=1)
Flash point
399 OF (204 °C) Cleveland Open Cup
Auto -ignition temperature
494.6 OF (257 °C) Data is for similar product.
Evaporation rate
0 approx.; (n-BuAc=1)
Viscosity
20 cP at 250C
Percent volatile
0 % estimated
Partition coefficient
4.9 - 6 at 30OC; Data is for similar product.
(n-octanol/water)
Other data
Chemical family
Tall Oil Fatty Acids
Density
898 kg/m3 at 200C
Flammability
Non flammable.
Flammability class
Not classified.
10. Chemical Stability & Reactivity Information
Chemical stability
Material is stable under normal conditions.
Conditions to avoid
Strong oxidizing agents. Porous material such as rags, paper, insulation, or organic clay may
spontaneously combust when wetted with this material.
Incompatible materials
This product may react with strong oxidizing agents.
Hazardous decomposition
Upon decomposition this product emits acrid dense smoke with carbon dioxide, carbon monoxide,
products
water and other products of combustion.
11. Toxicological Information
Toxicological data
Components
Test Results
Tall Oil Fatty Acids (61790-12-3)
Acute Dermal LD50 Albino rabbit: > 2000 mg/kg 14 days At this
dose no death occurred.
Acute Oral LD50 Albino Sprague-Dawley rat: > 10000 mg/kg 14
days At this dose no death occurred.
Sensitization
Not classified.
Product
Test Results
SYLFATTm FA2
Buehler Test
Result: Negative
Species: Guinea pig
Organ: Skin
Comments: Not a skin sensitizer
Notes: OECD 406
SYLFATTm FA2
Maximisation Assay (Magnusson and Kligman)
Result: Negative
Species: Guinea pig
Organ: Skin
Comments: Not a skin sensitizer
Notes: OECD 406
Acute effects
Not classified.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Skin corrosion/irritation
Not classified.
Material name: SYLFATTm FA2
MSDS/SDS # 1257/2061E MSDs US
Version #: 1.0
Revision date: 05-07-2012 Print date: 05-07-2012 3/6

Mutagenicity
Not classified.
Product
Test Results
SYLFATTm FA2 Germ Cell Mutagenicity: Ames
Result: Negative
Species: Salmonella typhimurium
Comments: No data available to indicate product or any
components present at greater than 0.1% are mutagenic or
genotoxic.
Notes: OECD 471
SYLFATTm FA2 Germ Cell Mutagenicity: Chromosome Abberation
Result: Positive
Species: Hamster
Organ: lymphatic system
Comments: Clastogenic only at concentrations overtly toxic to
the cells.
Notes: OECD 473
Further information This product has no known adverse effect on human health.
Serious eye damage/eye irritation
Not classified.
Product Test Results
SYLFATTm FA2 Draize Test
Result: Negative
Species: Albino rabbit
Organ: Eye
Test Duration: 7 days
Observation Period: 7 days
Comments: No eye irritation.
12. Ecological Information
Ecotoxicological data
Product Test Results
SYLFATTm FA2 LL100 Zebra danio (Danio rerio): > 10000 mg/I 96 hr
Components Test Results
Tall Oil Fatty Acids (61790-12-3) EC50 Bacteria (Pseudomonas putida): > 10000 mg/I 16 hr
EL50 Green algae (Selenastrum capricornutum): > 1000 mg/I
72 hr Growth rate; OECD 201
EL50 Water flea (Daphnia magna): > 1000 mg/I 48 hr OECD
202
LL50 Zebra danio (Danio rerio): > 10000 mg/I 96 hr
* Estimates for product may be based on additional component data not shown.
Environmental effects Not classified as an environmental hazard.
Persistence and degradability
This material is readily biodegraded and is not likely to bioconcentrate
Product Test Results
SYLFATTm FA2 56 % - Closed Bottle Test (% Degradation in 28 days)
Test Duration: 28 d
SYLFATTm FA2 74 % Modified Sturm Test
Test Duration: 28 d
SYLFATTm FA2 88 - 100 % CO2 Evolution Test
Test Duration: 28 d
Partition coefficient 4.9 - 6 at 30OC; Data is for similar product.
Material name: SYLFATTm FA2 MSDS/SDS # 1257/2061E MSDs us
Version #: 1.0 Revision date: 05-07-2012 Print date: 05-07-2012 4/6

13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this
material to drain into sewers/water supplies. This product, in its present state, when discarded or
disposed of, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)).
Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal,
whether the product meets RCRA criteria for hazardous waste. Dispose in accordance with all
applicable regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport Information
DOT
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations
Use as animal feed is prohibited in the United States. Similar regulations may restrict such use in other locations.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFF
1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2)
Not regulated
DEA Essential Chemical Code Number
Not regulated
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Not regulated
DEA Exempt Chemical Mixtures Code Number
Not regulated
CERCLA (Superfund) reportable quantity
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
hazardous substance
Section 311 hazardous
chemical
Inventory status
Country(s) or region
Australia
Canada
Canada
China
Europe
Europe
Japan
Korea
New Zealand
Philippines
No
No
Inventory name
Australian Inventory of Chemical Substances (AICS)
Domestic Substances List (DSL)
Non -Domestic Substances List (NDSL)
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of Existing Commercial Chemical Substances
(EINECS)
European List of Notified Chemical Substances (ELINCS)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
New Zealand Inventory
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
On inventory (yes/no)*
Yes
Yes
No
Yes
Yes
No
Yes
Yes
Yes
Yes
Material name: SYLFATTm FA2 MSDS/SDS # 1257/2061E MSDs US
Version #: 1.0 Revision date: 05-07-2012 Print date: 05-07-2012 5/6

Country(s) or region
Inventory name On inventory (yes/no)*
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components
of this product comply with the inventory requirements administered by the governing country(s)
16. Other Information
Further information
HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings
Health: 1
Flammability: 1
Physical hazard: 0
NFPA ratings
Health: 1
Flammability: 1
Instability: 0
Disclaimer
The information contained herein is based on data believed to be reliable and the manufactures
disclaims any liability incurred from the use or reliance upon the same. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text. This safety information is
not a license to use this material as claimed by any patents of third parties. The user alone must
finally determine whether a contemplated use of this material will infringe any such patents, and
for obtaining any required licenses.
Issue date
05-07-2012
List of abbreviations
Not available.
Material name: SYLFATTm FA2 MSDS/SDS # 1257/2061E MSDs US
Version #: 1.0 Revision date: 05-07-2012 Print date: 05-07-2012 6/6

Nouryon Product Data Sheet
Armac T
Tallowalkylamine acetates
Primary tallowamine acetate salt
Specifications
Amine number
> 165 mg KOH/g
Color
0-10 Gardner
Iodine value
32-50 g I2/100 g
Moisture
< 2
Characteristics
Appearance
Solid at 25°C
Equivalent mass
324 g/eq
Flash point
150 C
HLB
6.8 Davies Scale 0-40
Initial boiling point
decomposes at 100 °C
Melting point
55 °C
pH
6-9
Pour point
65 °C
Solubility in water, 25°C
isopropanol, ethanol, hexane (35C)
Specific Gravity
0.845(80)
Vapor pressure
< 1 mm Hg @20 C
Notes:
Typical Data are based on our own measurements or derived from the literature. They do not constitute part of the delivery specification.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to
be reliable. Nouryon, however, makes no warranty as to accuracy and/or sufficiency of such information and/or suggestions, as to the product's
merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. Nouryon does not accept any liability
whatsoever arising out of the use of or reliance on this information, or out of the use or the performance of the product. Nothing contained herein
shall be construed as granting or extending any license under any patent. Customer must determine for himself, by preliminary tests or otherwise,
the suitability of this product for his purposes. The information contained herein supersedes all previously issued information on the subject
matter covered. The customer may forward, distribute, and/or photocopy this document only if unaltered and complete, including all of its
headers and footers, and should refrain from any unauthorized use. Don't copy this document to a website.
Contact Us
USA and Canada
Global Headquarters
Chicago
USA
[phone]
ansc-cs(anouryon.com
China
Regional Headquarters
Shanghai
China
[phone]
[e-mail]
Europe
Regional Headquarters
Stenungsund
Sweden
[phone]
su rfacta nts.eu rope(anou ryon.com
South East Asia
Regional Headquarters
Singapore
[phone]
su rfacta nts.asia (anouryon.com
South America
Regional Sales Office
Itupeva
Brazil
[phone]
ARMAC is a registered trademark in many countries.
Nouryon
2020-1-8 Armac T
© 2020 surfacechemistry.nouryon.com

SAFETY DATA SHEET: HYDROFLUORIC ACID, 48%
1. IDENTIFICATION
Product Name: HYDROFLUORIC ACID, 48%
Synonyms: Hydrogen fluoride EFluorhyd ric acid-Fluoric acid
Formula and Formula Weight: HF 20.01
Integra numbers beginning with: H747.10_H747.50
Recommended Use: Commercial/industrial use
Restrictions on Use: No information available
INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887)
1216 6th Ave N
Kent WA 98032
Phone: [phone]
12. HAZARDS IDENTIFICATION
OSHA Classification: Hazard Category: Hazard Statement:
Acute Toxicity - Oral 2 Fatal if swallowed.
Acute Toxicity - Dermal 1 Fatal in contact with sun.
Acute Toxicity - Inhalation 2 Fatal if inhaled.
Sdn Corrosion/Irritation 1A Causes severe sin burns and eye damage.
Eye Damage/Irritation
Signal Word: DANGER
E*M*
Precautionary Statements
Prevention:
Response
Storage
Disposal
Causes serious eye damage.
Do not breathe fume, gas, mist, vapors, spray.
Do not get in eyes, on snn, or on clothing.
Wash thoroughly after handling.
Do not eat, drin-or smo-e when using this product.
Use only outdoors or in a well -ventilated area.
Wear protective gloves, protective clothing, eye protection, face protection.
Wear respiratory protection.
If swallowed: Immediately call a poison center, doctor. Rinse mouth. Do NOT induce vomiting.
If on sin (or hair): Ta-e off immediately all contaminated clothing. Rinse sin with water, shower.
If inhaled: Remove person to fresh air and -eep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Immediately call a poison center, doctor.
Specific treatment is urgent (see first aid section on this label)
Ta-e off immediately all contaminated clothing and wash it before reuse.
Store in a well ventilated place. Keep container tightly closed.
Store loc-ed up.
Dispose of contents, container in accordance with all governmental regulations.
Hazards Not Otherwise Classified: No information available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component Synonyms CAS - % Weight
Water 07732-18-5 50 - 54
Hydrofluoric acid Hydrogen fluoride -Fluorhydric acid-Fluoric acid 07664-39-3 46 - 50
4. FIRST AID MEASURES
Persons using HF must have immediate access to an effective antidote so that first aid treatment can begin immediately.
Just washing the burn with water is not sufficient. A neutralizing agent which will also penetrate the sdn is required. The
onset of pain, particularly with dilute solutions, may not be felt for up to 24 hours.
Inhalation: Remove person to fresh air and eep comfortable for breathing. If not breathing, give artificial respiration. If breathing is
difficult administer oxygen. See- medical attention.
OSHA SDS -: 25746 rev 101 3/27/2015 HYDROFLUORIC ACID, 48% Page 1

Eye Contact:
Irrigate the eyes for at least 30 minutes with large quantities of water. Keep eyelids apart and away from eyeballs during
irrigation. Get immediate medical attention, preferably from an eye specialist. Do not use oily drops or HF sdn burn
ointment on the eyes. May apply one or two drops of a 0.5% Pontocaine hydrochloride solution. Place ice pacoon eyes
until reaching emergency room.
Sdn Contact:
Remove victim from contaminated area and immediately place under safety shower or wash with a water hose. Remove
all contaminated clothing. Keep washing for at least 15-20 minutes. While waiting for medical attention, flush the affected
area with water for one minute and then massage calcium gluconate gel into the wound until there is a cessation of pain.
Alternatively, after a thorough washing, the burned area should be immersed in a soluton of 0.2% iced aqueous Hyamine
1622 or 0.13% iced aqueous Zephiran Chloride. If immersion is not practical, towels should be soal:ed with one of the
above and used as a compress on the burn area. Ideally compresses should be changed every 2 minutes. Another
treatment is to have a physician intact sterile 10% aqueous calcium gluconate solution subcutaneously beneath, around
and in the burned area. Initially, use no more than 0.5cc per square centimeter and do not distort sdn appearance. If
pain is not completely relieved, additional treatment is indicated. Seeumedical attention as soon as possible for all burns
regardless of how minor they may appear. Hyamine 1622 is a trade name for tetracaine benzethonium chloride.
Zephiran Chloride is a trade name for benzalConium chloride.
Ingestion:
Do not induce vomiting. If victim is conscious, rinse mouth, give water. Never give anything by mouth to an unconscious
person. SeeLlimmediate medical attention. MilDof magnesia may provide a soothing effect.
Additional notes:
Hydrofluoric acid is highly corrosive and toxic, even in dilute form. It can severely damage the sdn and eyes causing
severe burns which are extremely painful. Vapor from strong solutions or anhydrous HF can damage sdn, eyes and the
respiratory system. HF differs from other strong acids in that it not only causes surface burns but also rapidly penetrates
the sdn and causes destruction of the underlying tissue and bone by the extraction of calcium. This is true even for dilute
HF solutions.Symptoms and effects include severe irritation and burning of eyes, sdn, and respiratory tractLpulmonary
edema LihinitisLbronchitisLbone changes CsCeletal fluorosis.
5. FIRE -FIGHTING MEASURES
Extinguishing Media:
Material is not flammable. Use extinguishing media suitable to surrounding materials.
Special Equipment and
Precautions: Use water to cool nearby containers and structures. Wear full protective equipment, including suitable
respiratory protection. Hydrofluoric acid can react violently with water, causing spattering and misting.
Highly corrosive. Combat fire from a sheltered position. Review this SDS in its entirety.
Specific Hazards:
Contact with reactive metals may liberate flammable hydrogen gas. Toxic and corrosive fumes may be
liberated under fire conditions.
Hazardous combustion products: Hydrogen and hydrogen fluoride
C:i!_CK61U7=12,111If-ITo 7=14 =F_F�=1',II�
Spill Procedures:
Wear full protective equipment, including a full face -piece respirator. Good ventilation is necessary. Discharge
will ordinarily be a vapor or a liquid that gives off HF fumes. Rapid dilution of the spill will reduce the amount of
fumes generated. Carefully neutralize the spill with a dilute solution of sodium hydroxide, or with lime or other
alllaline material. Absorb with a non -silica based absorbent material and place into a suitable disposal container.
Flush spill area with water. Do not contact the HF.
7. HANDLING AND STORAGE
Incompatible Materials:
Incompatible with strong bases. Glass, ceramics, concrete and other silica -containing materials. Organic
materials, rubber, leather, water, suflides, carbonates, cyanides, and most common metals. Reacts violently with
acetic anhydride, ammonium hydroxide, arsenic trioxide, calcium oxide, potassium permanganate, sodium,
sodium hydroxide, sulfuric acid.
Storage and Handling:
Store IocCed up in a cool, dry, well -ventilated corrosive materials storage area away from incompatible materials.
Keep containers tightly closed and protect them from physical damage. Minimize exposure to air and light.
Hydrofluoric acid is incompatible with glass, ceramics, and all silicon -containing materials such as concrete.
Polyethylene is the best material for hydrofluoric acid storage. Unlined steel containers are subloct to hydrogen
blistering. Contact with many common metals may yield hydrogen gas, which is a fire and explosion hazard.
Any and all personnel who may come into contact with this product must be thoroughly trained in hydrofluoric
acid safety procedures.
Do not breathe fume, gas, mist, vapors, spray.
Do not get in eyes, on sdn, or on clothing.
Wash thoroughly after handling.
Do not eat, drinuor smoD9 when using this product.
Use only outdoors or in a well -ventilated area.
Wear protective gloves, protective clothing, eye protection, face protection.
Wear respiratory protection.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
OSHA & ACGIH Exposure Limits
Water None identified
Hydrofluoric acid OSHA TWA: 3 ppm, 2 mg/m3 (as F) ACGIH TWA: 0.5 ppm, 0.41 mg/m3 (as F) ACGIH Ceiling: 2 ppm,
1.64 mg/m3 (as F)
Engineering Controls: Material must be handled in an approved fume hood or with equivalent local ventilation.
Maintain a first aid [It containing suitable antidote for HF burns at all possible exposure locations. Have running
water and materials for neutralization available.
Any and all personnel who may come into contact with this product must be thoroughly trained in hydrofluoric
acid safety procedures.
OSHA SDS : 25746 rev 101 3/27/2015 HYDROFLUORIC ACID, 48% Page 2

Respiratory Protection: Respiratory protection should be worn at all times. Use a NIOSH approved full facepiece chemical cartridge
respirator with a hydrogen fluoride cartridge.
Sdn/Eye Protective Equipment: Safety goggles with plastic lenses, gloves, protective clothing, face shield if pouring liquid. Emergency showers
and eye wash station must be present nearby. Neoprene or PVC are the preferred materials for safety
equipment.
Facilities storing or utilizing this material should have readily accessible eyewash stations and safety showers.
Select respirators and other safety equipment in accordance with regulations and based upon the particular
conditions of use and risCof exposure. Always use safe chemical -handling and good industrial hygiene practices.
9. PHYSICAL AND CHEMICAL PROPERTIES
Apearance:
Odor:
Odor Threshold:
pH:
Melting/Freezing Point:
Initial Boiling Point and Boiling Range:
Flash Point:
Evaporation Rate:
Flammability:
Flammable or Explosive
Limits (% by volume in air)
Vapor Pressure:
Vapor Density:
Relative Density:
Solubility:
Partition Coefficient: n-octanol/water
Auto -Ignition Temperature:
Clear, colorless or almost colorless liquid
Sharp penetrating odor
0.5to3ppm
Not available
-36 -C
108 C
Not available
Not available
Not flammable
Upper: Not available
Lower: Not available
14 mm Hg@20CC
1.97
1.19 Water=1
Miscible with water
Not available
Not available
Decomposition Temperature: Not available
Viscosity: Not available
10. STABILITY AND REACTIVITY
Reactivity: No information available
Stability: Stable
Possibility of Hazardous Reactions: Hazardous polymerization will not occur
Conditions to Avoid: Moisture.
Incompatibles: Incompatible with strong bases. Glass, ceramics, concrete and other silica -containing materials. Organic
materials, rubber, leather, water, suflides, carbonates, cyanides, and most common metals. Reacts violently
with acetic anhydride, ammonium hydroxide, arsenic trioxide, calcium oxide, potassium permanganate,
sodium, sodium hydroxide, sulfuric acid.
Decomposition Products: Hydrogen and hydrogen fluoride.
11. TOXICOLOGICAL INFORMATION
Effects of Over Exposure:
Inhalation: Harmful or fatal if inhaled Severely irritates or burns the respiratory system. Irregular pulse, cold limbs, bloody urine,
pulmonary edema, lung inflammation, bronchitis, rhinitis, bone changes, s eletal fluorosis.
Sdn Contact: Harmful or fatal in contact with sdn. Contact with liquid or high vapor concentration may be corrosive with severe burns
and localized destruction of tissue. This may result in deep tissue destruction and decalcification of bone. Effects are often
delayed by 2 to 24 hours. Initial signs may be a slight burning or steady throbbing pain. If nails are involved, the burn may
first appear as a blue-blacOdiscoloration of the nail bed with significant pain.
Eye Contact: Contact with eyes may cause severe irritaion and burns with possible permanent eye damage and impairment of vision.
Ingestion: Harmful or fatal if swallowed. Severe burns to the mouth, throat and stomach. Kidney disfunction, bone changes, sCeletal
fluorosis.
Chronic Effects: HypocalcemiaEfluorosisEbone and loint damage.
Target Organs: Eyes, s1n, respiratory system. Bones, teeth, liver, Jdney, lungs.
Additional Effects: May aggravate pre-existing pulmonary disease, ddney disorders
Reproductive Effects: This material may cause adverse reproductive effects.
Carcinogenicity: None identified
Toxicity Data:
Water No information available
Hydrofluoric acid Irritation (sdn, rat) Severe: 50% /3 min
TClo (inhalation, human) 25 mg/m3
LClo (inhalation, rabbit) 40 mg/m3/2hr
LC50 (inhalation, rat) 1276 ppm/1 hr
LC50 (inhalation, mouse) 342 ppm/1hr
12. ECOLOGICAL INFORMATION
Aquatic Toxicity Data: Terrestrial Toxicity Data:
OSHA SDS -: 25746 rev 101 3/27/2015 HYDROFLUORIC ACID, 48% Page 3

Water No information available No information available
Hydrofluoric acid EC50 Aquatic fish: 270 mg/L - 48h No information available
Persistence and degradability: No information available
Bioaccumulative potential: No information available
Mobility in soil: No information available
Other adverse effects: No information available
13. DISPOSAL CONSIDERATIONS
Disposal Procedures: Dispose of material and containers in accordance with all local, state and federal regulations.
14. TRANSPORTATION INFORMATION
This product is a regulated material for domestic ground transporation, per CFR Title 49.
UN Number:
UN1790
Proper Shipping Name:
Hydrofluoric acid
PacLJng Group:
II
Hazard Class:
8
Subsidiary RisC
6.1
Environmental hazards:
No information available
Special precautions:
No information available
Bul_transport:
No information available
15. REGULATORY INFORMATION
Hydrofluoric acid is listed in the TSCA inventory, in SARA 302, and in SARA 313 (as hydrogen fluoride).
16. OTHER INFORMATION
OSHA SIDS E2 25746 rev 101 3/27/2015
NE = Not established, NA = Not applicable or Not available
The information presented above is offered for informational purposes only. This SDS, and the associated product, is intended for use only by technically qualified
persons, and at their own discretion and ris . Since conditions and manner of use are outside the control of Integra Chemical Company, we mai a no warranties, either
expressed or implied, and assume no liability in connection with any use of this information.
—*— END OF SDS "'
OSHA SDS n: 25746 rev 101 3/27/2015 HYDROFLUORIC ACID, 48% Page 4

Nouryon Product Data Sheet
Armac C
Coco amines, acetates
Organic amine salt, acetate of coco amine.
Specifications
Amine number
Color
Neutralization
Water content
Characteristics
Appearance
Density
Flash point
H LB
Iodine value
Melting point
pH
Surface Tension according to Du No0y
Viscosity
Water content
202 - 225 mg KOH/g
< 7 Gardner
98-104%
< 1.5
Dark yellow paste at 20°C
880 kg/m3 at 602C
> 130°C
21(Davies scale 0-40)
5 g I2/100 g
45 - 60 °C
6 - 9 (10% in 50/50 IPA/Water)
(0.5% w/w in water: 28 mN/m) (1.0% w/w in water: 29
mN/m) (0.1% w/w in water: 32 mN/m)
125 mPa.s at 60°C
0.6%
Notes:
Typical Data are based on our own measurements or derived from the literature. They do not constitute part of the delivery specification.

Storage
Homogenized before use, unless the entire quantity is used. The product is converted into substituted amides with low
water solubitlity on heating at temperatures above 55°C. In applications involving heat, the temperature and time of
exposure should be kept at a minimum. Product can be removed from hard surfaces with high pressure hot water.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to
be reliable. Nouryon, however, makes no warranty as to accuracy and/or sufficiency of such information and/or suggestions, as to the product's
merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. Nouryon does not accept any liability
whatsoever arising out of the use of or reliance on this information, or out of the use or the performance of the product. Nothing contained herein
shall be construed as granting or extending any license under any patent. Customer must determine for himself, by preliminary tests or otherwise,
the suitability of this product for his purposes. The information contained herein supersedes all previously issued information on the subject
matter covered. The customer may forward, distribute, and/or photocopy this document only if unaltered and complete, including all of its
headers and footers, and should refrain from any unauthorized use. Don't copy this document to a website.
Contact Us
USA and Canada
Global Headquarters
Chicago
USA
[phone]
ansc-cs(anouryon.com
China
Regional Headquarters
Shanghai
China
[phone]
[e-mail]
Europe
Regional Headquarters
Stenungsund
Sweden
[phone]
su rfacta nts.eu rope(anou ryon.com
South East Asia
Regional Headquarters
Singapore
[phone]
su rfacta nts.asia (anouryon.com
South America
Regional Sales Office
Itupeva
Brazil
[phone]
ARMAC is a registered trademark in many countries.
Nouryon
2020-1-9 Armac C
© 2020 surfacechemistry.nouryon.com

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 1 of 7
Kerosene
SECTION t : Identification of the substance/mixture and of the supplier
Product name: Kerosene
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: 525373
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331
Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053
SECTION 2 : Hazards identification
Classification of the substance or mixture:
Health hazard
Aspiration hazard, category 1
Asp. Tox. 1
Signal word :Danger
Hazard statements:
May be fatal if swallowed and enters airways
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Other Non-GHS Classification:
WHMIS
B3 06
NFPA/HMIS

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 2 of 7
Kerosene
NFPA SCALE (0-4)
SECTION 3 : Composition/information on ingredients
Personal X
Protection
HMIS RATINGS (0-4)
Ingredients:
CAS 8008-10-b Kerosene >99 %
Percentages are by weight
SECTION 4 : First aid measures
Description of first aid measures
After inhalation: Loosen clothing as necessary and position individual in a comfortable position.Move exposed
to fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen.Get medical assistance if
cough or other symptoms appear.
After skin contact: Rinse/flush exposed skin gently using soap and water for 15-20 minutes.Seek medical
advice if discomfort or irritation persists.
After eye contact: Protect unexposed eye.Rinse/flush exposed eye(s) gently using water for 15-20
minutes.Remove contact lens(es) if able to do so during rinsing.Seek medical attention if irritation persists or if
concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Seek medical attention if irritation,
discomfort, or vomiting persists.
Most important symptoms and effects, both acute and delayed:
Irritation. Headache. Nausea.Shortness of breath.;
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention provide SDS document to physician. Physician should treat symptomatically.
SECTION 5 : Firefighting measures
Extinguishing media
Suitable extinguishing agents: Use water, dry chemical, chemical foam, carbon dioxide, or alcohol -resistant
foam.
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Thermal decomposition can lead to release of irritating gases and vapors.
Advice for firefighters:
Protective equipment: Wear protective eyeware, gloves, and clothing. Refer to Section 8.Use NIOSH-
approved respiratory protection/breathing apparatus.
Additional information (precautions): Avoid inhaling gases, fumes, dust, mist, vapor, and aerosols. Avoid

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev
Effective date : 02.11.2015 Page 3 of 7
Kerosene
contact with skin, eyes, and clothing.
SECTION 8 : Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation. Ensure that air -handling systems are operational.
Environmental precautions:
Should not be released into environment. Prevent from reaching drains, sewer, or waterway.
Methods and material for containment and cleaning up:
Wear protective eyeware, gloves, and clothing. Refer to Section 8.Always obey local regulations.Containerize
for disposal. Refer to Section 13.If necessary use trained response staff or contractor. Evacuate personnel to
safe areas. Keep in suitable closed containers for disposal.
Reference to other sections:
SECTION 7 : Handling and storage
Precautions for safe handling:
Avoid contact with skin, eyes, and clothing.Follow good hygiene procedures when handling chemical materials.
Refer to Section 8.Follow proper disposal methods. Refer to Section 13.Do not eat, drink, smoke, or use
personal products when handling chemical substances.
Conditions for safe storage, including any incompatibilities:
Store in a cool location. Keep away from food and beverages. Protect from freezing and physical
damage.Provide ventilation for containers. Keep container tightly sealed.Store away from incompatible
materials.
SECTION 8 : Exposure controls/personal protection
X .
k�
Control Parameters:
8008-20-6, Kerosene, ACGIH TLV TWA 200 mg/m3
8008-20-6, Kerosene, NIOSH TWA 100 mg/m3
Appropriate Engineering controls:
Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use or handling. Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
and mists below the applicable workplace exposure limits (Occupational
Exposure Limits-OELs) indicated above.
Respiratory protection:
Not required under normal conditions of use. Where risk assessment
shows air -purifying respirators are appropriate use a full -face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.When necessary use NIOSH approved
breathing equipment.
Protection of skin:
Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation. Dispose of
contaminated gloves after use in accordance with applicable laws and
good laboratory practices.Use proper glove removal technique without
touching outer surface. Avoid skin contact with used gloves.Wear
protective clothing.

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 4 of 7
Kerosene
Eye protection: Wear equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN
166(EU).Safety glasses or goggles are appropriate eye protection.
General hygienic measures: Perform routine housekeeping. Wash hands before breaks and at the end
of work. Avoid contact with skin, eyes, and clothing.Before wearing wash
contaminated clothing.
SECTION 9 : Physical and chemical properties
Appearance (physical
Clear, colorless liquid.
Explosion limit lower:
Not Determined
state,color):
Explosion limit upper:
Not Determined
Odor:
Odorless
Vapor pressure:
5mmHg @ 38 C
Odor threshold:
Not Determined
Vapor density:
4.5 (Air=1.0)
pH -value:
Not Determined
Relative density:
0.8 (H2O=1)
Melting/Freezing point:
- 17.8 C
Solubilities:
Insoluble in water.
Boiling point/Boiling
151.1 - 301 C
Partition coefficient (n-
Not Determined
range:
octanol/water):
Flash point (closed
71.1 C
Auto/Self-ignition
Not Determined
cup):
temperature:
Evaporation rate:
2.4
Decomposition
Not Determined
temperature:
Flammability
Not Determined
Viscosity:
a. Kinematic:Not Determined
(solid,gaseous):
b. Dynamic: Not Determined
Density: Not Determined
SECTION 10 : Stability and reactivity
Reactivity: Non reactive under normal conditions.
Chemical stability: Stable under normal conditions.
Possible hazardous reactions:None under normal processing.
Conditions to avoid:Heat, flames and sparks.lncompatible materials.
Incompatible materials: Strong oxidizing agents, Strong bases, Strong acids, Amines.
Hazardous decomposition products:
SECTION 11 : Toxicological information
Acute Toxicity:
Oral:
2,835 mg/kg
LD50 Rabbit
Chronic Toxicity: No additional information.
Corrosion Irritation: No additional information.
Sensitization:
No additional information.
Single Target Organ (STOT)
Inhalation - Respiratory system

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 5 of 7
Kerosene
Numerical Measures:
No additional information.
Carcinogenicity:
No additional information.
Mutagenicity:
No additional information.
Reproductive Toxicity:
No additional information.
SECTION 12 : Ecological information
Ecotoxicity Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
SECTION 13 : Disposal considerations
Waste disposal recommendations:
Contact a licensed professional waste disposal service to dispose of this material. Dispose of empty containers
as unused product.Product or containers must not be disposed with household garbage. It is the responsibility
of the waste generator to properly characterize all waste materials according to applicable regulatory entities
(US 40CFR262.11). Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste
regulations. Ensure complete and accurate classification.
SECTION 14 : Transport information
UN -Number
1223
UN proper shipping name
Kerosene
Transport hazard class(es)
Class:
3 Flammable liquids
Packing group:lll
Environmental hazard:
Transport in bulk:
Special precautions for user:
SECTION 15 : Regulatory information
United States (USA)
SARA Section 311/312 (Specific toxic chemical listings)
Acute, Fire
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 6 of 7
Kerosene
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed
Proposition 65 (California):
Chemicals known to cause cancer:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed
Canada
Canadian Domestic Substances List (DSL):
All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed
SECTION 16 : Other Information
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SOS contains all the information required by the Controlled Products Regulations. Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.lt is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No -Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS; Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.11.2015 Page 7 of 7
Kerosene
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No -Effect Level (REACH)
Effective date: 02.11.2015
Last updated : 03.19.2015

Product Information
Methyl Isobutyl
Carbinol
4-Methyl-2-Pentanol
MIBC
Isobutyl Methyl Carbinol
(CH3)2CHCH2CH(OH)CH3
Description
Physical properties
Methyl isobutyl carbinol is a
colorless stable liquid with a mild
Molecular Weight
102.18
alcohol odor.
Relative Evaporation Rate nBuAc=1
0.44
Vapor Pressure at 20°C, mmHg
3.7
Density at 200C lb/gal
6.72
Specific Gravity at 20/20°C
0.807
Viscosity at 20°C cP
5.2
Surface Tension
(dynes/cm at 20°C)
23.0
(dynes/cm at 25°C)
-
Hansen Solubility Parameters, [cal/cm3]1/2
Total
11.3
Non -Polar
8
Polar
5.7
Hydrogen Bonding
5.6
Boiling Point, °C at 760mm Hg
131.7
Solubility at 20°C
%Wt In Water
1.7
%Wt Water in
6.2
Closed Cup Flash Point °F
102
SARA 313 (see note 1 t)
N
Hazardous Air Pollutant (see note 2 t t)
N
t Note 1: Superfund Amendments and Reauthorization
Act of 1986 (SARA) Title III
Section 313
t t Note 2: Hazardous Air Pollutants listed under Title III
of the Clean Air Act
Classification/Registry Numbers
CAS Number
108-11-2
EINECS
203-551-7
(Please see second page)
*Trademark of The Dow Chemical Company

Methyl Isobutyl Carbinol
4-Methyl-2-Pentanol
MIBC
Isobutyl Methyl Carbinol
Features
• Slightly soluble in water and miscible with most organic solvents
• Latent solvent for coatings to adjust cure rate
• Latent solvent for coatings to reduce viscosity and to improve flow and leveling
• Coupling solvent for waterborne coatings
• Non -HAP (Hazardous Air Pollutant) Solvent
Applications
• Solvent for dyes and stains
• Solvent for oils, ester gums, natural resins, phenolics, waxes
• Solvent for nitrocellulose and ethylcellulose lacquers
• Froth flotation for mining
• Extraction solvent for essential oils for flavors/fragrances
• Hydraulic fluid diluent
• Process solvent for soaps
• Chemical intermediate for higher alcohols, surfactants
How supplied
Region..
Europe
Bulk
..
Tank Truck
Latin America
Bulk or Drum
Tank Truck
North America
Bulk
Tank Truck/Railcar
Pacific
Bulk or Drum
Tank Truck
Note: Consult the appropriate Material
Safety Data Sheet for safety and
handling guidelines for this product.
The Dow Chemical Company
Danbury, Connecticut 06817 U.S.A.
In the United States and Canada, Product Information: 1-800-447-4369; Fax: [phone]; Technical Support: 1-800-SOLVENT
In Europe: [phone]; Toll Phone: [phone]: Toll Fax: [phone]
In the Pacific: [phone]; Fax: [phone]
In Other Global Areas: 1-989-832-1556; Fax: [phone]
NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location to
another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for
Customer's use and for ensuring that Customer's workplace and disposal practices are in compliance with applicable laws and other governmental enactments.
Seller assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
Published September 2002 *Trademark of The Dow Chemical Company Form No.: 327-00049-0405

Pioneering solutions in mineral processing
PIONERA F-220 powder
Product Description
PIONERA F-220 contains specifically modified anionic functional biopolymers. The content of
insolubles, carbohydrates and chloride is very low.
PIONERA F-220 BioPolymer is water-soluble and available as a spray -dried powder or as liquid.
PIONERA BioPolymers provide benefits compared with many other process chemicals concerning
Health, Safety and Environment:
- Minimum regulations for storage and handling
- Minimum harm to environment
- Minimum toxicity level
- Exempted from REACH registration
Typical application: Additive for the selective depression of gangue materials in a mineral flotation
process.
Typical Analyses*
Chemical Data
Physical Data
Calcium
5 % Colour
Brown
Sulphur
7 % Dry Matter %
min 93.0
pH (10% Solution)
4.3 ± 0.8 Insolubles %
max 0.8
Carbohydrates
7 % Bulk density, kg/m3
550-630
*The analyses are not formal specifications and values may change. All values calculated on solids where applicable.
Customers may agree on seperate sales specifications.
Storage Stability
Under dry conditions, powder products remain stable for several years.
Compatibility
PIONERA F-220 BioPolymer is compatible with anionic and non-ionic, dispersants, wetting agents and
most organic and inorganic reagents used in mineral processing.
Packaging
Powder is usually packed in 600 kg bulk bags.
A Material Safety Data Sheet is available upon request.
Page 1 of 1
Contact: www.r)ionera.com Product name: PIONERA F-220 Revision No.: 02
Revision Date: 17.04.2012
The information given here is based on our best knowledge and we believe it to be true and accurate. However, Pionera does
not warrant or guarantee in any manner whatsoever, including the warranty of merchantability or fitness for the end user the
accuracy of the information and procedures listed herein and will not be responsible for any damage resulting from their use.

Safety Data Sheet
PIONERA F-220 - POWDER
SECTION 1: Identification of the substance/preparation and of the company/undertaking
1.1. Product identifier
Trade name: PIONERA F-220 - POWDER
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended uses:
Flotation depressant with selectivity for Calcite, Barite, etc
1.3. Details of the supplier of the safety data sheet
Supplier
Company:
Borregaard North America, Inc.
Address:
100 Grand Avenue
Rothchild, WI 54474-1198
Zip code:
Country:
UNITED STATES
Phone:
715-355-3699
1.4. Emergency Telephone
Number
[phone] (Emergency phone)
[phone] (Chemtrec phone) (24h)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
HazCom-classification - other The product does not have to be classified.
information:
2.2. Label elements
Signal word: Warning
2.3. Other hazards
Nuisance dust.
OSHA Hazard Category: Combustible Dust. Warning. May form combustible dust concentrations in air.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Substance
CAS number
Concentration
Notes
Chemically modified natural
Trade Secret.
>_ 92%
polymer.
Water
7732-18-5
<_ 8%
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 1/7

Safety Data Sheet
PIONERA F-220 - POWDER
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation: Seek fresh air.
Ingestion: Wash out mouth thoroughly and drink 1-2 glasses of water in small sips.
Skin contact: Wash the skin with water. Remove contaminated clothing.
Eye contact: Flush with water (preferably using eyewash equipment) until irritation subsides. Seek
medical advice if symptoms persist.
4.2. Most important symptoms and effects, both acute and delayed
Nuisance dust.
4.3. Indication of anv immediate medical attention and special treatment needed
None.
SECTION 5: Fire -fighting measures
5.1. Extinguishing media
Suitable extinguishing media: Extinguish with powder, foam, carbon dioxide or water mist.
Unsuitable extinguishing Do not use a jet of water, as it may spread the fire.
media:
5.2. Special hazards arising from the substance or mixture
Note the risk of dust explosion.
5.3. Advice for fire-fighters
Wear Self -Contained Breathing Apparatus with a chemical protection suit.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non -emergency personnel: Avoid formation of dust. Provide good ventilation.
6.2. Environmental precautions
Avoid unnecessary release to the environment. Prevent spillage from entering drains and/or surface water.
6.3. Methods and material for containment and cleaninq up
Sweep up/collect spills for possible reuse or transfer to suitable waste containers.
6.4. Reference to other sections
See section 8 for type of protective equipment.
See section 13 for instructions on disposal.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 2/7

Safety Data Sheet
PIONERA F-220 - POWDER
Work under effective process ventilation (e.g. local exhaust ventilation).
7.2. Conditions for safe storage, including any incompatibilities
Store in a dry, cool, well -ventilated area. Avoid accumulation of dust.
7.3. Specific end use(s)
/personal protection
8.1. Control parameters
Occupational exposure limit
Substance name
Time period
ppm
mg/m3
Comment
Remarks
Nuisance dust
OSHA
15
(total) and 5 mg/m3
(OSHA PELV)
respirable
Biological threshold values: Avoid formation of dust.
8.2. Exposure controls
Appropriate engineering Provide good ventilation.
controls:
Personal protective equipment, Wear safety goggles if there is a risk of dust contact with eyes.
eye/face protection:
Personal protective equipment, In the event of direct skin contact, wear protective gloves:
skin protection:
Personal protective equipment, Wear respiratory protective equipment with P2 filter when performing dusty work. NIOSH
respiratory protection: approved dust mask recommended.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State
Value/unit
Powder
Colour
Brown
Odour
Mild
Solubility
Water soluble.
Explosive properties
Oxidising properties
Parameter
Value/unit
Remarks
pH (solution for use)
3.5 - 5.5
pH (concentrate)
Not applicable.
Melting point
°C
Not applicable.
Freezing point
°C
Not applicable.
Initial boiling point and boiling range
°C
Not applicable.
Flash Point
°C
Not applicable.
Evaporation rate
Not applicable.
Flammability (solid, gas)
Not applicable.
Flammability limits
Not applicable.
Explosion limits
Vol%
LEL: 0.2 oz./cu.ft. UEL: 3.5 oz./cu.ft.
Vapour pressure
kPa
Not applicable.
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 3/7

Safety Data Sheet
PIONERA F-220 - POWDER
Vapour density
Not applicable.
Relative density
Not applicable.
Partition coefficient n-octonol/water
100% Water.
Auto -ignition temperature
> 400 °C
Decomposition temperature
> 200 °C
Viscosity
cSt
Not applicable.
Odour threshold
ppm
Not applicable.
9.2 Other information
r
Value/unit
Remarks
Density
0.37 - 0.56 g/ml (bulk
density)
Combustible Dust Characteristics
MIE: 1130 mJoule; Kst: SO (0-200 bar*m/s); Part
size: 100% < 150 micron.
SECTION 10: Stability and reactivity
10.1. Reactivity
Not reactive.
10.2. Chemical stabili
Stable.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
Avoid formation of dust. Avoid spark due to static electricity.
10.5. Incompatible materials
Strong oxidisers.
10.6. Hazardous decomposition products
Typical combustion products.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity - oral
Chemically modified natural polymer.
Organism
Test Type
Exposure time
Value
Conclusion
Test method
Source
Rat
LD50
> 5000mg/kg
Based on available data, the classification criteria are not met.
Acute toxicity - inhalation: The product does not have to be classified.
Skin corrosion/irritation: The product does not have to be classified.
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 4/7

Safety Data Sheet
PIONERA F-220 - POWDER
Serious eye damage/eye The product does not have to be classified.
irritation:
Respiratory sensitisation or None known.
skin sensitisation:
Germ cell mutagenicity: None known.
Carcinogenic properties: The product does not have to be classified.
Other toxicological effects: Sensitization to Material: May cause allergic reaction in rare cases.
SECTION 12: Ecological information
12.1. Toxicity
No effect on the environment. Based on available data, the classification criteria are not met.
12.2. Persistence and degradability
Partially biodegradable COD: 3300 mg 02/1- (0.25% solution)
12.3. Bioaccumulative potential
No bioaccumulation expected.
12.4. Mobility in soil
Solubility in water: Completely miscible
12.5. Results of PBT and vPvB assessment
None known.
12.6. Other adverse effects
None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Dispose of in accordance with Local Authority requirements.
SECTION 14: Transport information
14.1. UN -No.: Not applicable. 14.4. Packing group: Not applicable.
14.2. UN proper shipping Not applicable. 14.5. Environmental Not applicable.
name: hazards:
14.3. Transport hazard Not applicable.
class(es):
14.6. Special precautions for user
None.
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 5/7

Safety Data Sheet
PIONERA F-220 - POWDER
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC code
Not applicable.
Other Information: DOT Class 55 - Harmonized Tariff Code for US:3804.00.1000-0
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Special Provisions:
ADR/RID (2007) ECHA FAQ 7.7. GHS / CLP (EC N01272/2008) GHS USA June, 2015.
Authorisations / limitations:
Global inventory status:
Australia: On AICS Australian Inventory of Chemical Substances, June 1996 Ed
Canada: On DSL Supplement to Canada Gazette, Part I, January 26, 1991
China: On IECSC Inventory of Existing Chemical Substances in China, 2013
Japan: On ENCS Unlisted chemical name. For ENCS chemical class or category name,
refer to ENCS No. 8-209.
Korea: On ECL Korean Existing Chemicals List, January 1997, ECL Serial No.: KE-04572
Mexico: On INSQ National Inventory of Chemical Substances in Mexico, 2012
New Zealand: On NZIoC New Zealand Inventory of Chemicals, 2006 May be used as a
single component chemical under an appropriate group standard.
Philippines: On PICCS Philippines Inventory of Chemicals and Chemical Substances, 2000
Switzerland: On SWISS Giftliste 1 (List of Toxic Substances 1), 31 May 1999, SWISS No.:
G-44534
USA: On TSCA Inventory January 2015 TSCA Inventory EPA Flags: XU Exempt from
Update Rule
TSCA:
All ingredients are on the inventory or exempt from listing.
CERCLA:
None of the ingredients are on the inventory.
NFPA ratings
Health hazard:
Flammability:
Instability:
15.2. Chemical Safety Assessment
Other Information: The product does not have to be classified.
SECTION 16: Other information
Vendor notes: Information given in this safety data sheet is in accordance with our information, and to the
best of our knowledge, was correct on the last revision date. Information given is intented to
present guidelines for safe handling, use, processing, storage, transport, disposal and
discharge; it is not intended to be a guarantee or quality specification. It is the responsibility
of the recipient of this safety data sheet to ensure that information given here is read and
understood by all who use, handle, dispose of or in any way come in contact with the
product.
Revision date: 12/5/2015
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 6/7

Safety Data Sheet
PIONERA F-220 - POWDER
Document language: US
Copyright © 1995 - 2016 DGOffice A/S, www.DGOffice.net 7/7

0■BASF
The Chemical Company
Safety Data Sheet
MAGNAFLOC® 10
Revision date : 2010/03/01 Page: 1/5
Version: 1.1 (30481447/SDS GEN CA/EN)
1. Product and Company Identification
Company 24 Hour Emergency Response Information
BASF Canada Inc. CANUTEC (reverse charges): [phone]
100 Milverton Drive BASF HOTLINE: (800) 454-COPE (2673)
Mississauga, ON L5R 41-11, CANADA
Chemical family: Flocculant agent, anionic, acrylamide copolymer
2. Hazards Identification
State of matter: solid
Colour: off-white
Odour: odourless
Potential health effects
3. Composition / Information on Ingredients
Not WHMIS controlled.
4. First -Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
If on skin:
Wash thoroughly with soap and water.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open
If swallowed:
Rinse mouth and then drink plenty of water.
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no known
specific antidote.

Safety Data Sheet
MAGNAFLOC® 10
Revision date : 2010/03/01 Page: 2/5
Version: 1.1 (30481447/SDS_GEN_MEN)
5. Fire -Fighting Measures
Flash point:
A flash point determination is unnecessary
due to the high water content.
Autoignition: 350 °C
Lower explosion limit: not applicable
Flammability: No data available.
Self -ignition temperature: No data available.
Suitable extinguishing media:
dry extinguishing media, foam
Unsuitable extinguishing media for safety reasons:
water jet
Additional information:
If water is used, restrict pedestrian and vehicular traffic in areas where slip hazard may exist
Hazards during fire -fighting:
harmful vapours, carbon oxides, nitrogen oxides
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire
Protective equipment for fire -fighting:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing
water must be disposed of in accordance with official regulations.
6. Accidental release measures
Personal precautions:
Avoid dust formation. Use personal protective clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Cleanup:
Avoid raising dust. Spilled product which becomes wet or spilled aqueous solution create a hazard because of
their slippery nature.
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Contain with dust binding material and dispose of.
7. Handling and Storage
Handling
General advice:
Breathing must be protected when large quantities are decanted without local exhaust ventilation.
Protection against fire and explosion:
Avoid dust formation. Take precautionary measures against static discharges.
Storage
General advice:
Keep container tightly closed and dry; store in a cool place.
Avoid all sources of ignition: heat, sparks, open flame.

Safety Data Sheet
MAGNAFLOC® 10
Revision date : 2010/03/01 Page: 3/5
Version: 1.1 (30481447/SDS_GEN_MEN)
8. Exposure Controls and Personal Protection
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Safety glasses with side -shields.
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is
recommended. Wear protective clothing as necessary to minimize contact. Handle in accordance with good
industrial hygiene and safety practice.
9. Physical and Chemical Properties
Form:
powder
Odour:
odourless
Odour threshold:
No data available.
Colour:
off-white
pH value:
The product has not been tested.
Melting point:
not applicable
Boiling point:
not applicable
Vapour pressure:
The product has not been tested.
Bulk density:
approx. 750 kg/m3
Partitioning coefficient n-
not applicable
octanol/water (log Pow):
Solubility in water:
Forms a viscous solution.
10. Stability and Reactivity
Hazardous reactions:
The product may contain explosive fine dust or such dust may be produced by abrasion during transport or
product transfer.
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
Oxidizing properties:
not applicable
11. Toxicological information
Acute toxicity
Oral:
Type of value: LD50
Species: rat
Value: > 2,000 mg/kg

Safety Data Sheet
MAGNAFLOC® 10
Revision date : 2010/03/01 Page: 4/5
Version: 1.1 (30481447/SDS_GEN_CA/EN)
The product has not been tested. The statement has been derived from products of a similar structure and
composition.
Irritation / corrosion
Skin:
Result: non-irritant
Method: OPP 81-5 (EPA -Guideline)
Eye:
Result: non-irritant
Method: Draize test
12. Ecological Information
Fish
Acute:
OECD 203; ISO 7346; 84/449/EEC, C.1 Brachydanio rerio/LC50 (96 h): > 100 mg/I
From tests on a product range
Aquatic invertebrates
Acute:
OECD Guideline 202, part 1 Daphnia magna/EC50 (48 h): > 100 mg/I
From tests on a product range
Aquatic plants
Toxicity to aquatic plants:
OECD Guideline 201 green algae/EC50 (72 h): > 100 mg/I
From tests on a product range
Microorganisms
Toxicity to microorganisms:
bacterium/EC50 (24 h): > 100 mg/I
From tests on a product range
13. Disposal considerations
Waste disposal of substance:
Must be dumped or incinerated in accordance with local regulations.
Container disposal:
The packaging must not be re -used. Recommend crushing, puncturing or other means to prevent unauthorized
use of used containers.
14. Transport Information
Land transport
TDG
Not classified as a dangerous good under transport regulations

Safety Data Sheet
MAGNAFLOC® 10
Revision date : 2010/03/01 Page: 5/5
Version: 1.1 (30481447/SDS_GEN_CA/EN)
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
Federal Regulations
WHMIS does not apply to this product.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR
AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
16. Other Information
BASF supports worldwide Responsible CareO initiatives. We value the health and safety of our employees,
customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible
Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible
fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our
products, and minimizing the impact of our operations on society and the environment during production,
storage, transport, use and disposal of our products.
MAGNAFLOCO 10 is a registered trademark of BASF Canada or BASF SE
Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the
basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In
case you have questions concerning such changes please contact us at the address mentioned in Section I.
END OF DATA SHEET

LT Lnbchem
performance through
Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 10/16/2013 Revision date: 02/07/2017 Supersedes: 10/16/2013 Version: 1.1
SECTIONIdentification
1.1. Identification
Product form
Mixtures
Product name
Sodium Hydroxide, 50% w/w
CAS -No.
1310-73-2
Product code
LC24150
Formula
NaOH
Synonyms
caustic soda 50% WAN / soda lye, 50%, aqueous solution / white caustic, 50%, aqueous
solution
1.2. Recommended use and restrictions on use
Use of the substance/mixture
Industrial use
Recommended use
Laboratory chemicals
Restrictions on use
Not for food, drug or household use
1.3. Supplier
LabChem Inc
Jac-son's Pointe Commerce ParElBuilding
1000, 1010 JacLson'S Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
info(cDlabchem.com - www.labchem.com
1.4. Emergency telephone number
Emergency number
CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION•(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
SUn corrosion/irritation
H314
Category 1 B
Serious eye damage/eye
H318
irritation Category 1
Hazardous to the aquatic
H402
environment - Acute
Hazard Category 3
Full text of H statements :
see section 16
Causes severe sdn burns and eye damage
Causes serious eye damage
Harmful to aquatic life
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US)
<e>
GHS05
Signal word (GHS-US) Danger
Hazard statements (GHS-US) H314 - Causes severe sLin burns and eye damage
H402 - Harmful to aquatic life
Precautionary statements (GHS-US) P260 - Do not breathe mist, vapors, spray.
P264 - Wash exposed sdn thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Remove/TaCe off immediately all contaminated
clothing. Rinse sdn with water/shower.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a poison center or doctor/physician.
P363 - Wash contaminated clothing before reuse.
P405 - Store locLABd up.
01/29/2018 EN (English US) Page 1

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
P501 - Dispose of contents/container to comply with local, state and federal regulations
If inhaled: Remove person to fresh air and Seep comfortable for breathing
2.3. Other hazards which do not result in classification -
No additional information available
2.4. Unknown acute toxicity (GHS US) -
Not applicable
3.1. Substances
Not applicable
3.2. Mixtures
Name
Product identifier
%
GHS-US classification
Sodium Hydroxide
(CAS -No.) 1310-73-2
50
Acute Tox. 4 (Dermal), H312
Sdn Corr. 1A, H314
Eye Dam. 1, H318
Aquatic Acute 3, H402
Water
(CAS -No.) 7732-18-5
50
Not classified
Full text of hazard classes and H-statements : see section 16
4.1. Description of first aid measures
First -aid measures general
Checothe vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with labored breathing: half -seated. Victim in shocil on his bacilwith legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain. Depending on the victim's condition: doctor/hospital. Never give anything by
mouth to an unconscious person. If you feel unwell, seeomedical advice (show the label where
possible).
First -aid measures after inhalation
Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
Remove victim to fresh air and Jeep at rest in a position comfortable for breathing. Immediately
call a poison center or doctor/physician.
First -aid measures after s in contact
Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it stick to the sNn. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface ❑ 10%: tale
victim to hospital. Remove/Tale off immediately all contaminated clothing. Rinse sNn with
water/shower. Immediately call a poison center or doctor/physician.
First -aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a poison center or doctor/physician.
First -aid measures after ingestion
Rinse mouth with water. Immediately after ingestion: give lots of water to drina Do not induce
vomiting. Do not give activated charcoal. Do not give chemical antidote. Immediately consult a
doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Talb the
container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital.
Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects
Causes severe shin burns and eye damage.
Symptoms/effects after inhalation
EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the
respiratory tract. Irritation of the nasal mucous membranes. FOLLOWING SYMPTOMS MAY
APPEAR LATER: Possible laryngeal spasm/oedema. Risoof lung edema. Respiratory
difficulties.
Symptoms/effects after sdn contact
Caustic burns/corrosion of the sdn. Slow -healing wounds.
Symptoms/effects after eye contact
Corrosion of the eye tissue. Permanent eye damage. Causes serious eye damage.
Symptoms/effects after ingestion
Vomiting. Diarrhoea. Burns to the gastric/intestinal mucosa. Possible esophageal perforation.
Bleeding of the gastrointestinal tract. Shoc❑ AFTER ABSORPTION OF LARGE QUANTITIES:
Disturbances of consciousness.
Chronic symptoms
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry sNn. Sdn rash/inflammation.
Possible inflammation of the respiratory tract.
4.3. Immediate medical attention and special treatment, if necessary -
No additional information available
01/29/2018 EN (English US) 219

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media EXTINGUISHING MEDIA FOR SURROUNDING FIRES: Adapt extinguishing media to the
environment. Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Solid water et ineffective as extinguishing medium.
5.2. Specific hazards arising from the chemical
Fire hazard
DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Reactions involving a
fire hazard: see 'Reactivity Hazard".
Explosion hazard
INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".
Reactivity
Violent exothermic reaction with water (moisture): (increased) risoof fire. On heating: release of
corrosive gases/vapours. Absorbs the atmospheric CO2. Violent exothermic reaction with
(some) acids. May be corrosive to metals. Reacts with (some) metals: release of highly
flammable gases/vapours (hydrogen).
5.3. Special protective equipment and precautions for fire-fighters
Precautionary measures fire
Exposure to fire/heat: roep upwind. Exposure to fire/heat: consider evacuation. Exposure to
fire/heat: have neighbourhood close doors and windows.
Firefighting instructions
Cool tan_s/drums with water spray/remove them into safety. Dilute toxic gases with water
spray. Taue account of toxic fire -fighting water. Use water moderately and if possible collect or
contain it.
Protection during firefighting
Heat/fire exposure: compressed air/oxygen apparatus.
_ . i
r -
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non -emergency personnel
Protective equipment Gloves. Face -shield. Corrosion -proof suit. Large spills/in enclosed spaces: compressed air
apparatus. Large spills/in enclosed spaces: gas -tight suit. See "Material -Handling" to select
protective clothing.
Emergency procedures Maruthe danger area. No na ed flames. Wash contaminated clothes. Large spills/in confined
spaces: consider evacuation. In case of hazardous reactions: veep upwind. In case of reactivity
hazard: consider evacuation.
6.1.2. For emergency responders
Protective equipment
Equip cleanup crew with proper protection.
Emergency procedures
Ventilate area.
6.2. Environmental precautions
Prevent soil and water pollution. Prevent spreading
in sewers. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or
public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment
Contain released substance, pump into suitable containers. Consult "Material -handling" to
select material of containers. Plug the lea cut off the supply. Dam up the liquid spill.
Hazardous reaction: measure explosive gas -air mixture. Reaction: dilute combustible
gas/vapour with water curtain. Heat exposure: dilute toxic gas/vapour with water spray. Taue
account of toxic/corrosive precipitation water.
Methods for cleaning up
Taue up liquid spill into absorbent material, e.g.: sand, saw dust, Jeselguhr. Scoop absorbed
substance into closing containers. See "Material -handling" for suitable container materials.
Carefully collect the spill/leftovers. Small quantities of liquid spill: neutralize with acid solution.
Wash away neutralized product with plentiful water. Damaged/cooled tanus must be emptied.
Clean contaminated surfaces with an excess of water. Taue collected spill to
manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
01/29/2018 EN (English US) 3/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
7.1. Precautions for safe handling
Precautions for safe handling Comply with the legal requirements. Remove contaminated clothing immediately. Clean
contaminated clothing. Handle and open the container with care. Thoroughly clean/dry the
installation before use. Do not discharge the waste into the drain. Keep away from naC-lad
flames/heat. Observe very strict hygiene - avoid contact. Keep container tightly closed.
Measure the concentration in the air regularly. Carry operations in the open/under local
exhaust/ventilation or with respiratory protection.
Hygiene measures Wash exposed sin thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities -
Technical measures : Comply with applicable regulations.
Storage conditions Keep only in the original container in a cool, well ventilated place away from : incompatible
materials. Keep container closed when not in use.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage temperature 1115 :C
Heat -ignition KEEP SUBSTANCE AWAY FROM: heat sources.
Prohibitions on mixed storage KEEP SUBSTANCE AWAY FROM: combustible materials. strong acids. metals.
Storage area Store in a dry area. Keep container in a well -ventilated place. Keep Ioc-ed up. Protect against
frost. Provide for a tub to collect spills. Unauthorized persons are not admitted. Meet the legal
requirements.
Special rules on pacEaging SPECIAL REQUIREMENTS: hermetical. dry. clean. correctly labelled. meet the legal
requirements. Secure fragile pacEagings in solid containers.
PacEbging materials SUITABLE MATERIAL: stainless steel. nic-el. polyethylene. polypropylene. glass.
stoneware/porcelain. MATERIAL TO AVOID: lead. aluminium. copper. tin. zinc. bronze.
8.1. Control parameters
Sodium Hydroxide, 50%w/w (1310-73-2)
OSHA
OSHA PEL (TWA) (mg/m3)
2 mg/m3
IDLH
US IDLH (mg/m3)
10 mg/m3
NIOSH
NIOSH REL (ceiling) (mg/m3)
2 mg/m3
Sodium Hydroxide (1310-73-2)
ACGIH
ACGIH Ceiling (mg/m3)
2 mg/m3 (Sodium hydroxide EUSAEMomentary value❑
TLV - Adopted Value)
OSHA
OSHA PEL (TWA) (mg/m3)
2 mg/m3
IDLH
US IDLH (mg/m3)
10 mg/m3
NIOSH
NIOSH REL (ceiling) (mg/m3)
2 mg/m3
Water (7732-18-5)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Provide adequate general and local exhaust ventilation.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Protective goggles. Gloves. Protective clothing. Face shield.
01/29/2018 EN (English US) 4/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Materials for protective clothing:
GIVE EXCELLENT RESISTANCE: nitrile rubber. GIVE GOOD RESISTANCE: No data available. GIVE LESS RESISTANCE: chlorinated
polyethylene. styrene-butadiene rubber. nitrile rubber/PVC. GIVE POOR RESISTANCE: PVA. natural fibres
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or face shield. Face shield
Skin and body protection:
Corrosion -proof clothing
Respiratory protection:
Wear gas mas_with filter type B if conc. in air
exposure limit
Other information:
Do not eat, drin-lor smo e during use.
9.1. Information on basic physical and chemical properties
Physical state
Liquid
Appearance
Liquid.
Color
Colorless
Odor
Odorless
Odor threshold
pH
pH solution
Melting point
Freezing point
Boiling point
Flash point
Relative evaporation rate (butyl acetate=1)
Flammability (solid, gas)
Vapor pressure
Relative vapor density at 20 :C
Relative density
Specific gravity / density
Molecular mass
Solubility
Log Pow
Auto -ignition temperature
Decomposition temperature
Viscosity, Jnematic
Viscosity, dynamic
Explosion limits
Explosive properties
Oxidizing properties
9.2. Other information
Minimum ignition energy
VOC content
Other properties
No data available
14 (8 %)
8%
12:C
No data available
143 -C
Not applicable
No data available
Non flammable.
1.2 hPa (20 EC)
No data available
1.5
1525 g/m3
40 g/mol
Exothermically soluble in water. Soluble in ethanol. Soluble in methanol. Soluble in glycerol.
Water: Complete
No data available
Not applicable
No data available
No data available
79 mPa.s (20 EC)
No data available
Not applicable.
None.
Not applicable
Not applicable (inorganic)
Clear. Hygroscopic. Slightly volatile. Substance has basic reaction.
01/29/2018 EN (English US) 5/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10.1. Reactivity
Violent exothermic reaction with water (moisture): (increased) risuof fire. On heating: release of corrosive gases/vapours. Absorbs the atmospheric
CO2. Violent exothermic reaction with (some) acids. May be corrosive to metals. Reacts with (some) metals: release of highly flammable gases/vapours
(hydrogen).
10.2. Chemical stability
Stable under normal conditions. Absorbs atmospheric CO2. Hygroscopic. Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. metals.
10.6. Hazardous decomposition products
Sodium oxide. Thermal decomposition generates : Corrosive vapors.
11.1. Information on toxicological effects
Li-ely routes of exposure
Acute toxicity
SJn and eye contact
Not classified
Sodium Hydroxide (1310-73-2)
ATE US (dermal) 1350 mg/ug body weight
Water (7732-18-5)
LD50 oral rat
>_ 90000 mg/kg
ATE US (oral)
90000 mg/fig body weight
SJn corrosion/irritation Causes severe s-in burns and eye damage.
pH: 14 (8 %)
Serious eye damage/irritation Causes serious eye damage.
pH: 14 (8 %)
Respiratory or sJn sensitization Not classified
Germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
Carcinogenicity Not classified
Reproductive toxicity Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity a single exposure Not classified
Specific target organ toxicity u repeated Not classified
exposure
Aspiration hazard
Not classified
Potential Adverse human health effects and
Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects after inhalation
EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the
respiratory tract. Irritation of the nasal mucous membranes. FOLLOWING SYMPTOMS MAY
APPEAR LATER: Possible laryngeal spasm/oedema. Risuof lung edema. Respiratory
difficulties.
Symptoms/effects after sJn contact
Caustic burns/corrosion of the sJn. Slow -healing wounds.
Symptoms/effects after eye contact
Corrosion of the eye tissue. Permanent eye damage. Causes serious eye damage.
Symptoms/effects after ingestion
Vomiting. Diarrhoea. Burns to the gastric/intestinal mucosa. Possible esophageal perforation.
Bleeding of the gastrointestinal tract. Shod AFTER ABSORPTION OF LARGE QUANTITIES:
Disturbances of consciousness.
01/29/2018
EN (English US) 6/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Chronic symptoms ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry sNn. Sdn rash/inflammation.
Possible inflammation of the respiratory tract.
SECTION• •• • •
12.1. Toxicity
Ecology - general Not classified as dangerous for the environment according to the criteria of Regulation (EC) No
1272/2008.
Ecology - air Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). None of the
mown components is included in the list of fluorinated greenhouse gases (Regulation (EC) No
842/2006).
Ecology - water Ground water pollutant. Maximum concentration in drindng water: 200 mg/I (sodium) (Directive
98/83/EC). Harmful to fishes. Harmful to invertebrates (Daphnia). pH shift.
Sodium Hydroxide (1310-73-2)
LC50 fish 1 45.4 mg/I (LC50110therE96 hl]Salmo gairdneriLiStatic systemEFresh waterEExperi mental
value)
12.2. Persistence and degradability
Sodium Hydroxide, 50%w/w (1310-73-2)
Persistence and degradability Biodegradability: not applicable. No test data on mobility of the components available.
Sodium Hydroxide (1310-73-2)
Persistence and degradability
Biodegradability: not applicable. No test data on mobility of the substance available.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
Water (7732-18-5)
Persistence and degradability
Not established.
12.3. Bioaccumulative potential
Sodium Hydroxide, 50%w/w (1310-73-2)
Bioaccumulative potential I Does not contain bioaccumulative component(s).
Sodium Hydroxide (1310-73-2)
Bioaccumulative potential No bioaccumulation data available.
Water (7732-18-5)
Bioaccumulative potential Not established.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
Other information
13.1. Disposal methods
Avoid release to the environment.
Waste disposal recommendations Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a ris❑ of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall taCe the necessary measures to prevent risC-9 of pollution or
damage to people or animals. Recycle/reuse. Remove for physico-chemical/biological
treatment. Do not discharge into drains or the environment.
Additional information LWCA (the Netherlands): KGA category 05. Hazardous waste according to Directive
2008/98/EC.
Ecology - waste materials Avoid release to the environment.
01/29/2018 EN (English US) 7/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Department of Transportation (DOT)
In accordance with DOT
Transport document description
UN-No.(DOT)
Proper Shipping Name (DOT)
Transport hazard class(es) (DOT)
PacLing group (DOT)
Hazard labels (DOT)
DOT Pac-aging Non BUID(49 CFR 173.xxx)
DOT Pac-aging Bul-1(49 CFR 173.xxx)
DOT Special Provisions (49 CFR 172.102)
DOT Pac-aging Exceptions (49 CFR 173.xxx)
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
DOT Vessel Stowage Location
DOT Vessel Stowage Other
Other information
15.1. US Federal regulations
UN1824 Sodium hydroxide solution, 8, II
U N 1824
Sodium hydroxide solution
8 - Class 8 - Corrosive material 49 CFR 173.136
II - Medium Danger
8 - Corrosive
r�
IV"
202
242
B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanL8 are
not authorized.
1132 -Authorized IBCs: Metal (31A, 31B and 31N)-Rigid plastics (31H1 and 31H2)-Composite
(31 HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
EPa at 50 C (1.1 bar at 122 F), or 130 pa at 55 C (1.3 bar at 131 F) are authorized.
N34 - Aluminum construction materials are not authorized for any part of a pacCaging which is
normally in contact with the hazardous material.
T7 - 4 178.274(d)(2) Normal ............. 178.275(d)(3)
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bulutemperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of
cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and
the maximum mean bul-itemperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C
(59 F) and 50 C (122 F), respectively.
154
1L
30 L
A - The material may be stowed -on dec-nor -Lander dec-Lon a cargo vessel and on a
passenger vessel.
52 - Stow -separated from-Liacids
No supplementary information available.
Sodium Hydroxide, 50%w/w (1310-73-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not sub ect to reporting requirements of the United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes
Health hazard - SJn corrosion or Irritation
Health hazard - Serious eye damage or eye irritation
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Sodium Hydroxide (1310-73-2)
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 311/312 Hazard Classes
Immediate (acute) health hazard
01/29/2018 EN (English US) 8/9

Sodium Hydroxide, 50% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
15.2. International regulations
CANADA
Sodium Hydroxide (1310-73-2)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
No additional information available
15.3. US State regulations
California Proposition 65 - This product does not contain any substances Ehown to the state of California to cause cancer,
developmental and/or reproductive harm
Revision date
Other information
Full text of H-phrases: see section 16:
02/07/2017
None.
H312
Harmful in contact with sdn
H314
Causes severe sdn burns and eye damage
H318
Causes serious eye damage
H402
Harmful to aquatic life
NFPA health hazard 3 - Materials that, under emergency conditions, can cause
serious or permanent inory.
NFPA fire hazard 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity 1 - Materials that in themselves are normally stable but can
become unstable at elevated temperatures and pressures.
Hazard Rating
Health 3 Serious Hazard - Malor inory IiCely unless prompt action is to en and medical treatment is
given
Flammability 0 Minimal Hazard - Materials that will not burn
Physical 1 Slight Hazard - Materials that are normally stable but can become unstable (self -react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
01/29/2018 EN (English US) 9/9

V
univnR
Material Safety Data Sheet
LA1109
Soda Ash 58% Dense
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Id: LA1109
Product Name: Soda Ash 58% Dense
Synonyms: Carbonic acid, disodium salt; Disodium carbonate; Soda ash Sodium carbonate, anhydrous.
Chemical Family: Sodium and compounds / inorganic sodium compound / sodium salt / inorganic carbon compound /
inorganic carbonic acid salt / inorganic carbonate.
Application: Soda salts. Manufacture of glass. Soap. Cleaners and water softeners. Pulp and paper. Photographical
agent. Water treatment. pH adjustment.
Distributed By:
Univar Canada Ltd.
9800 Van Horne Way
Richmond, BC
V6X 1 W 5
Prepared By: The Safety, Health and Environment Department of Univar Canada Ltd.
Preparation date of MSDS: 02 July 2009
Telephone number of preparer: 1-866-686-4827
24-Hour Emergency Telephone Number (CANUTEC): [phone]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Percentage
LD50s and LC50s Route & Species:
(W/W)
Sodium Carbonate
99.8
Dermal LD50 (Mouse) = 2210 mg/kg
497-19-8
Oral LD50 (Rat) = 4090 mg/kg
Note: No additional remark.
3. HAZARDS IDENTIFICATION
Potential Acute Health Effects:
Eye Contact: May cause severe eye irritation. Effects may include pain, marked redness and swelling.
Skin Contact: Symptoms include redness, swelling, itching and pain.
Inhalation: Material is irritating to mucous membrane and upper respiratory tract. Exposure can cause coughing, chest
pains and difficulty in breathing
Ingestion: May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
LA1109
Soda Ash 58% Dense
Page 1 of 6

4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water and continue washing for at least 15 minutes. Seek immediate medical
attention.
Skin Contact: Immediately wash with plenty of soap and water for at least 5 minutes. Remove contaminated clothing and
launder before reuse. If irritation persists or signs of toxicity occur, seek medical attention.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If
the heart has stopped, trained personnel should begin cardiopulmonary resuscitation (CPR) immediately. Get medical
attention immediately.
Ingestion: Do not induce vomiting. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or
convulsing. Seek medical attention.
Notes to Physician: Treatment based on sound judgment of physician and individual reactions of patient.
5. FIRE FIGHTING MEASURES
Flash Point: None.
Flash Point Method: Not applicable.
Autoignition Temperature: Not available.
Flammable Limits in Air (%): Not Available.
Extinguishing Media: Does not burn. Use extinguishing media appropriate for surrounding fire.
Special Exposure Hazards: Not flammable.
Hazardous Decomposition/Combustion Materials (under fire conditions): Carbon dioxide.
Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing
equipment.
NFPA RATINGS FOR THIS PRODUCT ARE: HEALTH 2, FLAMMABILITY 0, INSTABILITY 0
HMIS RATINGS FOR THIS PRODUCT ARE: HEALTH 2, FLAMMABILITY 0, REACTIVITY 0
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures: Wear appropriate protective equipment.
Environmental Precautionary Measures: Prevent entry into sewers or streams, dike if needed. Spills or releases should
be reported, if required to the appropriate municipal, provincial and federal agencies.
Procedure for Clean Up: Scoop up or vacuum up and place in an appropriate closed container. Avoid raising dust.
Cautiously spray residue with plenty of water. Prevent spilled material from entering sewers, confined spaces, drains, or
waterways.
7. HANDLING AND STORAGE
Handling: Avoid breathing in dust. Avoid prolonged contact with eyes or prolonged skin contact. Use good personal
hygiene. When dissolving, add to water cautiously while stirring; solutions can get hot.
Storage: Store in a cool, dry, well ventilated area. Store away from acids. Prolonged storage may cause product to cake
and become damp from atmospheric moisture.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls:
Local exhaust ventilation as necessary to maintain exposures to within applicable limits.
Respiratory Protection: For dusty or misty conditions, wear NIOSH-approved dust or mist respirator.
Gloves:
Cotton gloves permitted for dry product, impervious gloves when handling solutions.
Skin Protection: As a minimum, wear long -sleeve shirts, trousers, and gloves for routine product use.
Eyes: Safety glasses with side shields or chemical goggles.
Other Personal Protection Data: Long sleeves. Wear saranex coveralls if contact may occur. Hard hat. Do not wear
contact lenses. Ensure that eyewash stations and safety showers are proximal to the work -station location.
Ingredients
Exposure Limit - ACGIH
Exposure Limit - OSHA
Immediately Dangerous
to Life or Health - IDLH
Sodium Carbonate
Not available.
Not available.
Not Available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
LA1109
Soda Ash 58% Dense
Page 2 of 6

9. PHYSICAL AND CHEMICAL PROPERTIES
Colour: White
Odour: Odourless
pH 11.3-11.4 (1 % solution), 11.6 (5% solution), 11.7 (10% solution) @ 20°C
Specific Gravity: 2.533 @ 20°C
Boiling Point: Not Available.
Freezing/Melting Point: 854°C / 1569.2°F
Vapour Pressure: Not Available.
Vapour Density: Not Available.
% Volatile by Volume: Not Available.
Evaporation Rate: Not Available.
Solubility: 17% by Wt @ 20°C
VOCs: Not Available.
Viscosity: Not Available.
Molecular Weight: 105.99
Other: Not Available.
10. STABILITY AND REACTIVITY
Chemical Stability: Stable.
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Hygroscopic (absorbs moisture from the air). Simultaneous exposure to soda ash and lime dusts
(CaO). In the presence of moisture (i.e. perspiration) the two materials combine to form corrosive caustic soda (NaOH)
which may cause burns.
Materials to Avoid: Acids. Soda Ash is corrosive to aluminum, lead, and zinc and zinc brasses when in solution and to
aluminum when high humidity is present.
Hazardous Decomposition Products: Carbon dioxide. Decomposition temperature: 400°C / 752 °F
Additional Information:
Contact with acids will release carbon dioxide gas. Can react violently with red hot aluminum metal; fluorine gas; lithium;
and 2,4,6-trinitrotoluene.
11. TOXICOLOGICAL INFORMATION
Principle Routes of Exposure
Ingestion: May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Skin Contact: Symptoms include redness, swelling, itching and pain.
Inhalation: Material is irritating to mucous membrane and upper respiratory tract. Exposure can cause coughing, chest
pains and difficulty in breathing
Eye Contact: May cause severe eye irritation. Effects may include pain, marked redness and swelling.
Additional Information: Excessive contact may produce "soda ulcers" on hands and perforation of the nasal septum.
Sensitivity reactions may occur from prolonged and repeated exposure.
Acute Test of Product:
Acute Oral LD50: Not Available.
Acute Dermal LD50: Not Available.
Acute Inhalation LC50: Not Available.
Carcinogenicity:
Ingredients
IARC - Carcinogens
ACGIH - Carcinogens
Sodium Carbonate
Not listed.
Not listed.
Carcinogenicity Comment: No additional information available.
Reproductive Toxicity/ Teratogenicity/ Embryotoxicity/ Mutagenicity: Not Available.
LA1109
Soda Ash 58% Dense
Page 3 of 6

12. ECOLOGICAL INFORMATION
Ecotoxicological Information:
Ingredients
Ecotoxicity - Fish Species
Data
Acute Crustaceans Toxicity:
Ecotoxicity - Freshwater
Algae Data
Sodium Carbonate
LC50 (Lepomis macrochirus)
Not Available.
EC50 (Nitzschia) 242 mg/L
300 mg/L
LC50 (Daphnia Magna) 347
mg/L (24hr)
LC50 (Daphnia Magna) 565
mg/L (96hr)
Other Information:
No additional remark.
13. DISPOSAL CONSIDERATIONS
Disposal of Waste Method: Disposal of all wastes must be done in accordance with municipal, provincial and federal
regulations.
Contaminated Packaging: Empty containers should be recycled or disposed of through an approved waste management
facility.
14. TRANSPORT INFORMATION
DOT (U.S.):
DOT Shipping Name: Not Regulated.
DOT Hazardous Class Not Applicable.
DOT UN Number: Not Applicable.
DOT Packing Group: Not Applicable.
DOT Reportable Quantity (lbs): Not Available
Note: No additional remark.
Marine Pollutant: No.
TDG (Canada):
TDG Shipping Name: Not Regulated.
Hazard Class: Not Applicable.
UN Number: Not Applicable.
Packing Group: Not Applicable.
Note: No additional remark.
Marine Pollutant: No.
LA1109
Soda Ash 58% Dense
Page 4 of 6

15. REGULATORY INFORMATION
U.S. TSCA Inventory Status: All components of this product are either on the Toxic Substances Control Act (TSCA)
Inventory List or exempt.
Canadian DSL Inventory Status: All components of this product are either on the Domestic Substances List (DSL), the
Non -Domestic Substances List (NDSL) or exempt.
Note: Not available.
U.S. Regulatory Rules
Ingredients
CERCLA/SARA - Section
302:
SARA (311, 312) Hazard
Class:
CERCLA/SARA - Section
313:
Sodium Carbonate
Not Listed.
Not Listed.
Not Listed.
California Proposition 65: Not Listed.
MA Right to Know List: Not Listed.
New Jersey Right -to -Know List: Not Listed.
Pennsylvania Right to Know List: Not Listed.
WHMIS Hazardous Class:
D213 TOXIC MATERIALS
E CORROSIVE MATERIAL
LA1109
Soda Ash 58% Dense
Page 5 of 6

16. OTHER INFORMATION
Additional Information: This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the MSDS contains all the
information required by the CPR.
Disclaimer: NOTICE TO READER:
Univar, expressly disclaims all express or implied warranties of merchantability and
fitness for a particular purpose, with respect to the product or information provided
herein, and shall under no circumstances be liable for incidental or consequential
damages.
Do not use ingredient information and/or ingredient percentages in this MSDS as a
product specification. For product specification information refer to a Product
Specification Sheet and/or a Certificate of Analysis. These can be obtained from your
local Univar Sales Office.
All information appearing herein is based upon data obtained from the manufacturer
and/or recognized technical sources. While the information is believed to be accurate,
Univar makes no representations as to its accuracy or sufficiency. Conditions of use
are beyond Univar's control and therefore users are responsible to verify this data
under their own operating conditions to determine whether the product is suitable for
their particular purposes and they assume all risks of their use, handling, and disposal
of the product, or from the publication or use of, or reliance upon, information
contained herein. This information relates only to the product designated herein, and
does not relate to its use in combination with any other material or in any other
process.
***END OF MSDS***
l_A1109
Soda Ash 58% Dense
Page 6 of 6

Sulfuric Acid 98%
SimplotSafety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/22/2019 Revision date: 11/22/2019 Version: 1.0
T1. Identification
Product form
Mixture
Product name
Sulfuric Acid 98%
Product code
M16030
1.2. Recommended use and restrictions on use —
Use of the substance/mixture
Industrial
1.3. Supplier
JR Simplot Company
P.O. Box 70013
Boise, ID 83707
T 1-208-336-2110
1 ^ Emergency telephone number
Emergency number
CHEMTREC 1-800-424-9300
AN 1, Hazardtsl i[ientiticatic
2.1. Classification of the substance or mixture
GHS-US classification
Corrosive to metals, Category 1 H290 May be corrosive to metals.
Sdn corrosion/irritation, Category 1A H314 Causes severe sdn burns and eye damage.
Serious eye damage/eye irritation, Category 1 H318 Causes serious eye damage.
Carcinogenicity, Category 1A H350 May cause cancer (Inhalation).
Hazardous to the aquatic environment — Acute Hazard, Category 3 H402 Harmful to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US)
Signal word (GHS US) Danger
Hazard statements (GHS US) H290 - May be corrosive to metals.
H314 - Causes severe sdn burns and eye damage.
H318 - Causes serious eye damage.
H350 - May cause cancer (Inhalation).
H402 - Harmful to aquatic life
Precautionary statements (GHS US) P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P234 - Keep only in original container.
P260 - Do not breathe mist, spray, or vapours.
P264 - Wash hands, forearms and face thoroughly after handling.
P271 - Use only outdoors or in a well -ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective clothing, eye protection, face protection, and protective gloves.
P284 - [In case of inadequate ventilation] wear respiratory protection.
P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting
P303+P361+P353 - If on sHn (or hair): Ta1:0 off immediately all contaminated clothing. Rinse
sdn with water/shower
P304+P340 - If inhaled: Remove person to fresh air and Ceep comfortable for breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - If exposed or concerned: Get medical attention
P310 - Immediately call a doctor or a POISON CENTER
P320 - Specific treatment is urgent (see supplemental first aid instruction on this label).
P321 - Specific treatment (see supplemental first aid instruction on this label)
P363 - Wash contaminated clothing before reuse.
11/22/2019 EN (English) Page 1

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
P390 - Absorb spillage to prevent material damage.
P403+P233 - Store in a well -ventilated place. Keep container tightly closed.
P405 - Store locked up.
P406 - Store in corrosive resistant container with a resistant inner liner.
P501 - Dispose of contents/container to ...in accordance with local/regional/national regulations
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
3.1. Substances
Not applicable
3.2. Mixtures
Product identifier % GHS-US :Iassificati
sulfuric acid (CAS -No.) 7664-93-9 98 S—in Corr. 1A, H314
`Strong inorganic acid aerosols/mists containing this substance are carcinogenic to humans via inhalation. Under normal conditions of use this route of exposure is not expected.
Full text of hazard classes and H-statements : see section 16
4.1. Description of first aid measures
First -aid measures general
Never give anything by mouth to an unconscious person. If you feel unwell, see -]medical
advice (show the label where possible). Call a physician immediately.
First -aid measures after inhalation
Remove person to fresh air and Eeep comfortable for breathing. Remove person to fresh air
and Eeep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First -aid measures after sdn contact
Immediately call a POISON CENTER/doctor. Rinse sin with water/shower. TaEe off
immediately all contaminated clothing. Call a physician immediately.
First -aid measures after eye contact
Immediately call a POISON CENTER/doctor. Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician
immediately.
First -aid measures after ingestion
Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. Rinse mouth. Do not
induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects Causes severe sin burns and eye damage.
Symptoms/effects after inhalation May cause cancer by inhalation.
Symptoms/effects after sCln contact Burns.
Symptoms/effects after eye contact Serious damage to eyes.
Symptoms/effects after ingestion Burns.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
No additional information available
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to taEe action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
11/22/2019 EN (English) 2/9
a
9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
• •
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non -emergency personnel
Emergency procedures Ventilate spillage area. Evacuate unnecessary personnel. Only qualified personnel equipped
with suitable protective equipment may intervene. Do not breathe
dust/fume/gas/mist/vapours/spray.
6.1.2. For emergency responders
Protective equipment Do not attempt to taF0 action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Notify authorities
if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment Collect spillage.
Methods for cleaning up TaEe up liquid spill into absorbent material. SoaE up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Notify authorities if product enters sewers or public waters.
Other information Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
7.1. Precautions for safe handling
Precautions for safe handling Ensure good ventilation of the worostation. Wash hands and other exposed areas with mild
soap and water before eating, drinnng or smorng and when leaving worF1 Provide good
ventilation in process area to prevent formation of vapour. Avoid contact during
pregnancy/while nursing. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Tar-e all necessary technical measures to avoid
or minimize the release of the product on the worEplace. Limit quantities of product at the
minimum necessary for handling and limit the number of exposed wor-ers. Provide local
exhaust or general room ventilation. Wear personal protective equipment. Floors, walls and
other surfaces in the hazard area must be cleaned regularly. Avoid contact with sdn and eyes.
Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures Wash hands, forearms and face thoroughly after handling. Separate wor:jng clothes from town
clothes. Launder separately. Wash contaminated clothing before reuse. Do not eat, drinEor
smoEe when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures Comply with applicable regulations.
Storage conditions Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use. Store in corrosive resistant container with a resistant inner liner. Keep
only in original container. Store loud up. Store in a well -ventilated place. Keep cool.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight. Metals.
8.1. Control parameters
Sulfuric Acid 98%
ACGIH
ACGIH TWA (mg/m')
0.2
ACGIH
ACGIH TWA (ppm)
0.0498 ppm
OSHA
OSHA PEL (TWA) (mg/m')
1
OSHA
OSHA PEL (TWA) (ppm)
0.25
sulfuric acid (7664-93-9)
Not applicable
11/22/2019 EN (English) 3/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
8.2. Appropriate engineering controls _
Appropriate engineering controls Ensure good ventilation of the wori istation.
Environmental exposure controls Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure. Corrosionproof clothing. Face shield. Gas mas-at concentration in the air - - TLV. Gloves. Protective goggles.
Head/nec_ protection.
Materials for protective clothing:
Condition
Material
Excellent resistance:
Chlorosulfonated polyethylene, Polyvinylchloride (PVC), Viton
Good resistance:
neoprene/butyl rubber, Neoprene/vton❑
Poor resistance:
Butyl rubber, Neoprene, Nitrile rubber, Tyvem
Hand protection:
Protective gloves made of PVC. A face shield is required when cleaning equipment
Eye protection:
Chemical goggles or face shield. Safety glasses
Skin and body protection:
Wear suitable protective clothing. Corrosion -proof clothing
Type
apron, Chemically resistant protective gloves, Face shield, Goggles
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment. [In case of inadequate ventilation] wear respiratory protection.
Device
Filter type
Condition
Full face masq Powered Air -Purifying
Gas/vapour filter
Gas protection, If conc. in air ❑ exposure limit,
Respirator (PAPR)
Vapour protection
Self-contained breathing apparatus (SCBA),
Long term exposure
Supplied -Air Respirator (SAR)
Personal protective equipment symbol(s):
Other information:
Do not eat, drin-or smo-e during use.
9.1. Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colourless
Odour
There may be no odour warning properties, odour is sub�ective and inadequate to warn of
overexposure.
Mixture contains one or more component(s) which have the following odour:
Almost odourless
Odour threshold
No data available
pH
No data available
Melting point
Not applicable
Freezing point
No data available
11/22/2019
EN (English) 4/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Boiling point
No data available
Flash point
No data available
Relative evaporation rate (butylacetate=1)
No data available
Flammability (solid, gas)
Non flammable.
Vapour pressure
No data available
Relative vapour density at 20 C
No data available
Relative density
No data available
Solubility
Soluble.
Log Pow
No data available
Auto -ignition temperature
No data available
Decomposition temperature
No data available
Viscosity, inematic
No data available
Viscosity, dynamic
No data available
Explosive limits
No data available
Explosive properties
No data available
Oxidising properties
No data available
9.2. Other information
No additional information available
10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable. Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases. metals.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity (oral) Not classified
Acute toxicity (dermal) Not classified
Acute toxicity (inhalation) Not classified
Sulfuric Acid 98%
LD50 oral rat
115000 mg/Eg
LC50 inhalation rat (mg/1)
18 - 420 mg/m'
ATE US (vapours)
0.018 mg/I/4h
ATE US (dust,mist)
0.018 mg/I/4h
Sdn corrosion/irritation Causes severe sin burns and eye damage.
Serious eye damage/irritation Causes serious eye damage.
Respiratory or sdn sensitisation Not classified
Germ cell mutagenicity Not classified
Carcinogenicity May cause cancer (Inhalation).
sulfuric acid (7664-93-9)
IARC group
1 - Carcinogenic to humans
National Toxicology Program (NTP) Status
I Known Human Carcinogens
11/22/2019 EN (English) 5/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Reproductive toxicity
STOT-single exposure
STOT-repeated exposure
Aspiration hazard
Viscosity, dnematic
Potential adverse human health effects and
symptoms
Symptoms/effects
Symptoms/effects after inhalation
Symptoms/effects after sdn contact
Symptoms/effects after eye contact
Symptoms/effects after ingestion
12.1. Toxicity
Ecology - general
Sulfuric Acid 98%
LC50 fish 1
EC50 Daphnia 1
sulfuric acid (7664-93-9)
LC50 fish 1
EC50 Daphnia 1
LC50 fish 2
TLM fish 1
Threshold limit other aquatic organisms 1
12.2. Persistence and degradability
Not classified
Not classified
Not classified
Not classified
No data available
Based on available data, the classification criteria are not met.
Causes severe sdn burns and eye damage.
May cause cancer by inhalation.
Burns.
Serious damage to eyes.
Burns.
The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment. Harmful to aquatic life.
42 - 500 mg/I
28 - 88 mg/I
42 mg/I (96 hOGambusia affinis)
29 mg/I (24 hLDaphnia magna)
49 mg/I (48 hElLepomis macrochirus)
42 mg/I (96 hoGambusia affinis)
6900 mg/I (24 hLPseudomonas fluorescens)
Sulfuric Acid 98%
Persistence and degradability Not established.
sulfuric acid (7664-93-9)
Persistence and degradability
Biodegradability: not applicable. No (test)data on mobility of the components available. Not
established.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD)
Not applicable
12.3. Bioaccumulative potential
Sulfuric Acid 98%
Bioaccumulative potential Not established.
sulfuric acid (7664-93-9)
Log Pow
-2.2 (Estimated value)
Bioaccumulative potential
Bioaccumulation: not applicable. Not established.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
Other information Avoid release to the environment.
11/22/2019 EN (English) 6/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
13.1. Disposal methods
Waste treatment methods
Product/PacFaging disposal recommendations
Ecology - waste materials
Department of Transportation (DOT)
In accordance with DOT
Transport document description
UN-No.(DOT)
Proper Shipping Name (DOT)
Class (DOT)
Pacnng group (DOT)
Hazard labels (DOT)
DOT Pac:13ging Non BUID(49 CFR 173.xxx)
DOT Pac:13ging BUIE(49 CFR 173.xxx)
DOT Special Provisions (49 CFR 172.102)
DOT Pac:13ging Exceptions (49 CFR 173.xxx)
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
DOT Vessel Stowage Location
Transport/Additional information
Other information
Dispose of contents/container in accordance with licensed collector's sorting instructions.
Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Avoid release to the environment.
UN1830 Sulfuric acid, 8, II
U N 1830
Sulfuric acid
8 - Class 8 - Corrosive material 49 CFR 173.136
II - Medium Danger
8 - Corrosive
Y
202
242
A3 - For combination pac-agings, if glass inner pacFagings (including ampoules) are used, they
must be pacCed with absorbent material in tightly closed metal receptacles before pacdng in
outer pacragings.
A7 - Steel pac-agings must be corrosion -resistant or have protection against corrosion.
B3 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tangy and
DOT 57 portable tanCs are not authorized.
B83 - Bottom outlets are prohibited on tanlicar tan Cs transporting sulfuric acid in
concentrations over 65.25 percent.
B84 - Paciagings must be protected with non-metallic linings impervious to the lading or have a
suitable corrosion allowance for sulfuric acid or spent sulfuric acid in concentration up to 65.25
percent.
1132 -Authorized IBCs: Metal (31A, 31B and 31N)ERigid plastics (31H1 and 31H2)OComposite
(31 HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
EPa at 50 C (1.1 bar at 122 F), or 130 EPa at 55 C (1.3 bar at 131 F) are authorized.
N34 - Aluminum construction materials are not authorized for any part of a pacEaging which is
normally in contact with the hazardous material.
T8 - 4 178.274(d)(2) Normal ............. Prohibited
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bul0temperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of
cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and
the maximum mean bulgytemperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C
(59 F) and 50 C (122 F), respectively.
TP12 - This material is considered highly corrosive to steel.
154
1L
30 L
C - The material must be stowed "on deck only" on a cargo vessel and on a passenger vessel.
14 - For metal drums, stowage permitted under dec0on cargo vessels
No supplementary information available.
11/22/2019 EN (English) 7/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG)
UN -No. (IMDG)
Proper Shipping Name (IMDG)
Class (IMDG)
Pacring group (IMDG)
Limited quantities (IMDG)
Air transport
Transport document description (IATA)
UN -No. (IATA)
Proper Shipping Name (IATA)
Class (IATA)
Pacdng group (IATA)
15.1. US Federal regulations
UN 1830 SULPHURIC ACID, 8, II
1830
SULPHURIC ACID
8 - Corrosive substances
II - substances presenting medium danger
1L
UN 1830 Sulphuric acid, 8, II
1830
Sulphuric acid
8 - Corrosives
II - Medium Danger
Sulfuric Acid 98%
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of
1986 and 40 CFR Part 372.
sulfuric acid CAS -No. 7664-93-9 98%
sulfuric acid (7664-93-9)
CERCLA RQ
1000 lb
RQ (Reportable quantity, section 304 of EPA's
List of Lists)
1000 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
1000 lb
15.2. International regulations
CANADA
sulfuric acid (7664-93-9)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
sulfuric acid (7664-93-9)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
California Proposition 65 - This product does not contain any substances Ehown to the state of California to cause cancer, developmental and/or
reproductive harm
11/22/2019 EN (English) 8/9

Sulfuric Acid 98%
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Component
State or local regulations
sulfuric acid(7664-93-9)
U.S. - Massachusetts - Right To Know ListCU.S. - New Jersey - Right to Know
Hazardous Substance ListEU.S. - Pennsylvania - RTK (Right to Know) List
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date
Data sources
Other information
Full text of H-statements:
11 /22/2019
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and pac[laging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
None.
H290
May be corrosive to metals.
H314
Causes severe sLJn burns and eye damage.
H318
Causes serious eye damage.
H350
May cause cancer.
H402
Harmful to aquatic life
SIDS US (GHS HazCom 2012)
Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the
best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. NO
WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN
PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may
occur from the use of this information nor do we offer warranty against patent infringement.
11/22/2019 EN (English) 9/9

SAFETY DATA SHEET
COCONUT SHELL ACTIVATED CARBON
DATE OF ISSUE: 02/24/2015
SECTION 1 — PRODUCT AND COMPANY INFORMATION
Product Name: ACTIVATED CARBON — Coconut Shell Based
Product Use: According to Manufacturer's recommendation
Company Identification: CALIFORNIA CARBON CO., INC.
2825 E. GRANT ST.
WILMINGTON, CA 90744
Telephone Number: 1-800-663-5830
1-562-436-1962
Fax Number: 1-562-437-1217
Email: [e-mail]
SECTION II — HAZARDS IDENTIFICATION
Key to Ratings
OSHA Regulatory Status: Not regulated
4 = Extreme/Severe
HMIS Ratings: Health — 0
3 = High/Serious
(NFPA) Flammability — 1
2 = Moderate
Reactivity — 0
1 = Slight
Special — n/a
W = Water Reactive
OX = Oxidizer
Protective Equipment: Safety glasses with side shield or goggles, gloves, long sleeve shirt or lab coat, long
pants recommended.
Health Effects: See Section IV
Environmental Effects: See Section XII
•
Hazard Symbol:
Eye Irritation Category 2B Contact may cause eye irritation. Dust may be slightly irritating to eyes
Respiratory Irritation Category 3 and respiratory track.
Wet activated carbon removes oxygen from air causing a severe hazard
to workers in enclosed or confined space.
Precautionary Statements
Prevention: Avoid generation of dust during handling. Avoid breathing dust. Wash thoroughly after handling.
Use in a well -ventilated area.
Response: IF INHALED: Remove to fresh air.
IF IN EYES: Rinse with water for several minutes. Remove contact lenses if present.
Continue rinsing.
Storage: Store in a well -ventilated place. Keep container tightly closed.
Container Labeling: Not implemented at this time.
SECTION III — COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Identity (% by weight) Common Name CAS No. Impurities
100% Activated Carbon 68647-86-9 None
CALIFORNIA CARBON CO., INC., SIDS COCONUT SHELL ACTIVATED CARBON, PAGE 1 OF 4 (02/24/2015)

SECTION IV - FIRST AID MEASURES
Routes of Exposure
Inhalation:
Skin:
Eyes:
Ingestion:
Signs/Symptoms of Exposure
Emergency and First Aid
Procedures:
Medical Conditions Generally
Aggravated by Exposure:
Dust may cause mild irritation to the upper respiratory tract.
Dust may cause mild irritation, possible reddening.
Dust may cause mild irritation, possible reddening.
Dust may cause mild irritation to digestive track resulting in nausea or diarrhea.
Dust may cause irritation and redness of eyes, irritation of skin and respiratory system.
The effects of long-term, low-level exposures to this product have not been determined.
For Eye Contact: Immediately flush with copious amounts of water for at least 15
minutes, lifting both the upper and lower lids occasionally; seek medical attention.
For Skin Contact: Wash with soap and water; seek medical attention.
For Inhalation: Remove to fresh air and rest as needed; seek medical attention for any
breathing difficulty.
For Ingestion: Drink plenty of water; seek medical attention.
People with pre-existing skin conditions or eye problems or impaired respiratory function
may be more susceptible to the potential effects of the dust.
SECTION V - FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Use an extinguishing media suitable for the surrounding fire.
Specific Hazards: As with most organic solids, fire is possible at elevated temperatures or by contact with
an ignition source. Activated carbon is difficult to ignite and tends to burn slowly
(smolder) without producing smoke or flame.
Carbon monoxide and carbon dioxide gas may be emitted upon combustion of material.
Contact with strong oxidizers such as ozone or liquid oxygen may cause rapid
combustion.
Protective Equipment
and Procedures: Wear NIOSH approved self-contained breathing apparatus suitable for the surrounding
fire.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear protective equipment, keep unnecessary personnel away, and ventilate area of
spill.
Environmental Precautions: The material is not soluble, but can cause a particulate emission if discharged to
waterways; therefore, dike all entrances to sewers and drains to avoid introducing the
material into the waterways.
Containment and Clean-up: Dike all entrances to sewers and drains. Vacuum or shovel spilled material and place in
closed container for disposal.
Remove product to appropriate storage area until it can be properly disposed of in
accordance with local, state and federal regulations. Avoid dust formation.
SECTION VII - HANDLING AND STORAGE
Precautions for Safe Handling: Avoid prolonged contact with eyes and skin. Keep away from ignition
sources. Use in well ventilated areas. Protect containers from physical
damage. Wash hands after handling.
Conditions for Safe Storage: Store in cool, dry, ventilated area and in closed containers. Keep away
from oxidizers, heat or flames. Store away from ignition sources.
CALIFORNIA CARBON CO., INC., SIDS COCONUT SHELL ACTIVATED CARBON, PAGE 2 OF 4 (02/24/2015)

SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines: Wet activated carbon removes oxygen from air posing a hazard to workers in
enclosed or confined space. Before entering such an area, sample the air to
assure sufficient oxygen supply. Use work procedures for low oxygen levels,
observing all local, state and federal regulations.
Engineering Controls: Exhaust ventilation should be designed to prevent accumulation and recirculation
in the workplace and safely remove carbon black from the air.
If risk of overexposure exists, wear an approved respirator.
Provide adequate ventilation in warehouse or closed storage area.
Personal Protective
Equipment: Use of NIOSH approved particulate filter is recommended if dust is generated in
handling. The usual precautionary measures for handling chemicals should be followed,
i.e. gloves, safety glasses with side shields or goggles, long sleeve shirt or lab coat, dust
respiration if dusty and/or other protective clothing or equipment as determined
appropriate.
General Hygiene: The usual precautionary measures for handling chemicals should be followed:
i.e. keep away from food and beverage; remove contaminated clothing
immediately; wash hands before breaks or eating; avoid contact with eyes and
skin.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical State (Appearance): Black granular, pellet or flake
Color:
Black
Molecular Weight:
N/A
Odor:
None
Odor Threshold:
None
pH Value:
N/A
Vapor Pressure:
0
Melting Point:
N/A
Vapor Density:
Solid
Freezing Point:
N/A
Relative Density:
0.4 to 0.7 g/ml
Initial Boiling Point:
N/A
Partition Coefficient:
N/A
Flashpoint:
N/A
Solubility:
Not Soluble
Evaporation Rate:
N/A
Auto Ignition Temp.:
>220 Deg. C
Flammability:
>220 Deg. C
Decomp. Temp.:
N/A
UEL:
N/A
Viscosity:
N/A
LEL:
N/A
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable Conditions to avoid: None
Possibility of Hazardous Reaction: Will Not Occur Conditions to avoid: None
Caution: High concentrations of organics in air will cause temperature rise due to heat of adsorption. At very high
concentration levels this may result in an exothermic reaction, referred to as a bed fire. High
concentrations of Ketones and Aldehydes may cause a bed temperature rise due to adsorption and
oxidation.
Materials to Avoid: Alkali metals and strong oxidizers such as ozone, oxygen, permanganate, chlorine.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide gas may be generated during combustion
of this material.
CALIFORNIA CARBON CO., INC., SIDS COCONUT SHELL ACTIVATED CARBON, PAGE 3 OF 4 (02/24/2015)

SECTION XI - TOXICOLOGICAL INFORMATION
Acute Toxicity: Not Classified
Inhalation, Ingestion, Eye Irritation, Skin Irritation: See Section IV.
Sensitization: Not determined on the finished product.
Target Organ(s) or System: Eyes, skin and upper respiratory system.
Signs and Symptoms of Exposure: See Sections III and IV
Chronic Effects: Carcinogenicity, Mutagenicity, Reproductive Effects, Developmental Factors: Not determined on the
finished product.
SECTION XII - ECOLOGICAL INFORMATION
Ecotoxicity, Persistence/Degradability, Bioaccumulation/Accumulation, Mobility in Environmental Media, Other Adverse
Effects: Not determined on the finished product.
SECTION XIII - DISPOSAL CONSIDERATIONS
Vacuum or shovel material into a closed container. Storage and disposal should be in accordance with applicable local,
state and federal laws and regulations. Local regulations may be more stringent than state or federal requirements.
Activated Carbon is an adsorbent media; hazard classification is generally determined by the adsorbate that the carbon
has picked up. Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste
prior to disposal.
SECTION XIV - TRANSPORT INFORMATION
Ship in accordance with all local, state, and federal laws and regulations.
UN Number: Not regulated
UN Proper Shipping Name: N/A
Transport Hazard Classes: N/A
Packing Group: N/A
Sea Pollutants: N/A
Special Precautions for user related to transport: N/A
Note: Under the UN classification for activated carbon, all activated carbons have been identified as a class 4.2 product.
However this product has been tested according to the United Nations Transport of Dangerous Goods test protocol for a
"self -heating substance" and it has been determined that this product does not meet the definition of a self -heating
substance, or any other hazard class, and therefore should not be listed as a hazardous material. This information is
applicable only for the Activated Carbon product identified in this document.
SECTION XV - REGULATORY INFORMATION
Carbon (7440-44-0): Listed on the United States TSCA Inventory
SECTION XVI - OTHER INFORMATION
The information contained herein is based on data considered accurate in light of current formulation. However, no
warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
CALIFORNIA CARBON CO., INC., SIDS COCONUT SHELL ACTIVATED CARBON, PAGE 4 OF 4 (02/24/2015)

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 1 of 7
Calcium Hydroxide,
SECTION 1 : Identification of the substance/mixture and of the supplier
Product name: Calcium Hydroxide,
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25225
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331
Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053
SECTION 2 : Hazards identification
Classification of the substance or mixture:
Irritant
1 Skin irritation, category 2
Specific target organ toxicity following single exposure, category 3
Corrosive
Serious eye damage, category 1
Skin Irritation 2
Eye Damage 1
Specific Target Organ Toxicity, Single Exposure (respiratory) 3
Signal word :Danger
Hazard statements:
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Wash ... thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapours/spray
Use only outdoors or in a well -ventilated area
Do not eat, drink or smoke when using this product
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing
If eye irritation persists get medical advice/attention
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF ON SKIN: Wash with soap and water
If skin irritation occurs: Get medical advice/attention

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 2 of 7
Calcium Hydroxide,
Specific treatment (see ... on this label)
Store locked up
Store in a well ventilated place. Keep container tightly closed
Combustible Dust Hazard: :
May form combustible dust concentrations in air (during processing).
Other Non-GHS Classification:
WHMIS
NFPA/HMIS
NFPA SCALE (0-4)
SECTION 3 : Composition/information on ingredients
- 3
Personal X
Protection
HMIS RATINGS (0-4)
Ingredients:
CAS 1305-62-0 Calcium Hydroxide >95 %
Percentages are by weight
SECTION 4 : First aid measures
Description of first aid measures
After inhalation: Move exposed individual to fresh air. Loosen clothing as necessary and position individual in
a comfortable position.Seek medical advice if discomfort or irritation persists.lf breathing difficult, give oxygen.
After skin contact: Wash affected area with soap and water. Rinse thoroughly. Seek medical attention if
irritation, discomfort or vomiting persists.
After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing. Seek medical attention if irritation persists or if
concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of
water. Seek medical attention if irritation, discomfort or vomiting persists.
Most important symptoms and effects, both acute and delayed:
Skin, eye, and upper respiratory tract irritation. Irritation, Nausea, Headache, Shortness of breath.;
Indication of any immediate medical attention and special treatment needed:

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 3 of 7
Calcium Hydroxide,
If seeking medical attention, provide SDS document to physician.
SECTION 5 : Firefighting measures
Extinguishing media
Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures. Use
appropriate fire suppression agents for adjacent combustible materials or sources of ignition
For safety reasons unsuitable extinguishing agents: Carbon Dioxide
Special hazards arising from the substance or mixture:
Combustion products may include carbon oxides or other toxic vapors.Thermal decomposition can lead to
release of irritating gases and vapors.Avoid generating dust; fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source is a potential dust explosion hazard.Calcium Oxide.
Advice for firefighters:
Protective equipment: Use NIOSH-approved respiratory protection/breathing apparatus.
Additional information (precautions): Move product containers away from fire or keep cool with water
spray as a protective measure, where feasible.Use spark -proof tools and explosion -proof equipment.
SECTION 6 : Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Transfer to a disposal or recovery container.Use spark -proof tools and explosion -
proof equipment.Use respiratory protective device against the effects of fumes/dust/aerosol. Keep unprotected
persons away. Ensure adequate ventilation. Keep away from ignition sources. Protect from heat.Stop the spill, if
possible. Contain spilled material by diking or using inert absorbent.
Environmental precautions:
Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13
Methods and material for containment and cleaning up:
If in a laboratory setting, follow Chemical Hygiene Plan procedures.Collect liquids using vacuum or by use of
absorbents. Place into properly labeled containers for recovery or disposal. If necessary, use trained response
staff/contractor. Dust deposits should not be allowed to accumulate on surfaces, as these may form an
explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in
the air (i.e., clearing dust surfaces with compressed air).
Reference to other sections:
SECTION 7 : Handling and storage
Precautions for safe handling:
Minimize dust generation and accumulation. Wash hands after handling. Avoid dispersal of dust in the air (i.e.,
clearing dust surfaces with compressed air). Routine housekeeping should be instituted to ensure that dusts do
not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of
transfer and mixing operations. Follow good hygiene procedures when handling chemical materials. Do not eat,
drink, smoke, or use personal products when handling chemical substances. If in a laboratory setting, follow
Chemical Hygiene Plan.Use only in well ventilated areas.Avoid generation of dust or fine particulate.Avoid
contact with eyes, skin, and clothing.
Conditions for safe storage, including any incompatibilities:
Store in a cool location. Provide ventilation for containers. Avoid storage near extreme heat, ignition sources or
open flame. Store away from foodstuffs. Store away from oxidizing agents.Store in cool, dry conditions in well
sealed containers. Keep container tightly sealed.
SECTION 8 : Exposure controls/personal protection

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev
Effective date : 12.14.2014 Page 4 of 7
Calcium Hydroxide,
*I]
Control Parameters: 1305-62-0, Calcium hydroxide, NIOSH REL: TWA 5 mg/m3
1305-62-0, Calcium hydroxide, ACGIH TLV TWA 5 mg/m3
1305-62-0, Calcium hydroxide, OSHA PEL TWA: 15 mg/m3 (total dust)
1305-62-0, Calcium hydroxide, OSHA PEL TWA: 5 mg/m3 (respirable
fraction)
Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/handling. Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
or dusts (total/respirable) below the applicable workplace exposure limits
(Occupational Exposure Limits-OELs) indicated above.Use under a fume
hood. It is recommended that all dust control equipment such as local
exhaust ventilation and material transport systems involved in handling
of this product contain explosion relief vents or an explosion suppression
system or an oxygen deficient environment. Ensure that dust -handling
systems (such as exhaust ducts, dust collectors, vessels, and processing
equipment) are designed in a manner to prevent the escape of dust into
the work area (i.e., there is no leakage from the equipment).
Respiratory protection: Not required under normal conditions of use. Use suitable respiratory
protective device when high concentrations are present. Use suitable
respiratory protective device when aerosol or mist is formed. For spills,
respiratory protection may be advisable.
Protection of skin: The glove material has to be impermeable and resistant to the product/
the substance/ the preparation being used/handled.Selection of the glove
material on consideration of the penetration times, rates of diffusion and
the degradation.
Eye protection: Safety glasses with side shields or goggles.
General hygienic measures: The usual precautionary measures are to be adhered to when handling
chemicals. Keep away from food, beverages and feed sources.
Immediately remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work. Do not inhale
gases/fumes/dust/mist/vapor/aerosols. Avoid contact with the eyes and
skin.
SECTION 9 : Physical and chemical properties
Appearance (physical
Off -white solid
Explosion limit lower:
Not Determined
state color):
Explosion limit upper:
Not Determined
Odor:
Odorless
Vapor pressure:
Not Determined
Odor threshold:
Not Determined
Vapor density:
Not Determined
pH -value:
12.4 saturated
solution
Relative density:
2.24
ND = Not Determined. N/A =
Melting/Freezing point:
580 C
Solubilities:
Not Applicable. Slightlyt
soluble in water.

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 5 of 7
Calcium Hydroxide,
Boiling point/Boiling
2850C
Partition coefficient (n-
Not Determined
range:
octanol/water):
Flash point (closed
Not Determined
Auto/Self-ignition
Not Determined
cup):
temperature:
Evaporation rate:
Not Determined
Decomposition
Not Determined
temperature:
Flammability
Not Determined
Viscosity:
a. Kinematic:Not Determined
(solid,gaseous):
b. Dynamic: Not Determined
Density: Not Determined
SECTION 10 : Stability and reactivity
Reactivity:Nonreactive under normal conditions.
Chemical stability:No decomposition if used and stored according to specifications.
Possible hazardous reactions:None under normal processing
Conditions to avoid:Store away from oxidizing agents, strong acids or bases. Incompatible Materials.Dust
generation.excess heat.
Incompatible materials: Metals, acids, bases, strong oxidizing and reducing agents.
Hazardous decomposition products:Carbon oxides (CO, CO2).Oxides of calcium.
SECTION 11 : Toxicological information
Acute Toxicity:
Oral:
7340 mg/kg
LD50 (rat)
Chronic Toxicity: No additional information.
Corrosion Irritation: No additional information.
Sensitization:
No additional information.
Single Target Organ (STOT):
May cause respiratory irritation.
Numerical Measures:
No additional information.
Carcinogenicity:
No additional information.
Mutagenicity:
No additional information.
Reproductive Toxicity:
No additional information.
SECTION 12 : Ecological information
Ecotoxicity Persistence and degradability: Readily degradable in the environment.
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
SECTION 13 : Disposal considerations
Waste disposal recommendations:

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 6 of 7
Calcium Hydroxide,
Product/containers must not be disposed together with household garbage. Do not allow product to reach
sewage system or open water.lt is the responsibility of the waste generator to properly characterize all waste
materials according to applicable regulatory entities (US 40CFR262.11). Consult federal state/ provincial and
local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.
SECTION 14 : Transport information
UN -Number
3262
UN proper shipping name
Corrosive solid, basic, inorganic, n.o.s.
Transport hazard class(es)
Class:
8 Corrosive substances
Packing group:lll
Environmental hazard:
Transport in bulk:
Special precautions for user:
SECTION 15 : Regulatory Information
United States (USA)
SARA Section 311/312 (Specific toxic chemical listings):
Acute
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed
Proposition 65 (California):
Chemicals known to cause cancer:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed
Canada

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.14.2014 Page 7 of 7
Calcium Hydroxide,
Canadian Domestic Substances List (DSL):
All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
1305-62-0 Calcium hydroxide
SECTION 16 : Other information
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations. Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.lt is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No -Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No -Effect Level (REACH)
Effective date: 12.14.2014
Last updated : 03.19.2015

Safety Data Sheet
Hydrated lime
1. Identification
Product Name: Hydrated Lime
Synonyms: Chemical Hydrate Hydrate Tailings,
Commercial Hydrate Hydrated Lime Kiln Dust,
Hyd Chem SS, Industrial Hydrate,
Hyd Lime Chem, Pink Hydrate,
Recommended Uses: Water treatment, steel flux, caustic agent, pH adjustment, acid gas absorption,
Emergency Contact:
2. Hazards Identification
GHS Physical Hazards
classification None
(24 hrs a day, 7 days a week)
Health Hazards
Skin Irritation
Eye Damage
Carcinogenicity
Specific Target Organ Toxicity — Single Exposure
GHS Label Signal Word: Danger
Elements: Hazard Causes skin irritation.
Statements: Causes serious eye damage.
May cause respiratory irritation.
May cause cancer through inhalation
Category 2
Category 1
Category 1A
Category 3
Page 1 of 8

Safety Data Sheet
Hydrated lime
Precautionary Obtain special instructions before use.
Statements: Do not handle until all safety precautions have been read and
understood.
Keep container tightly closed
Do not breathe dust.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in well -ventilated area
Wear protective gloves, clothing and eye protection
Pictograms:
> <
1
3. Composition
f hamirnl nama
Calcium hydroxide
Silica -crystalline quartz
4. First Aid Measures
by weight CAS#
> 85 1305-62-0
< 1 14808-60-7
Eyes: Immediately flush eyes with generous amounts of water for at least 15 minutes. Pull back
the eyelid to ensure that all lime dust has been washed out. Seek medical attention
immediately. Do not rub eyes.
Skin: Wash exposed area with large amounts of water. Seek medical attention immediately.
Ingestion: Do not induce vomiting. Seek medical attention immediately. Never give anything by
mouth unless instructed to do so by medical personnel.
Inhalation: Move victim to fresh air. Seek medical attention if necessary. If breathing has stopped,
give artificial respiration
Most Important Irritation of skin, eyes, gastrointestinal tract or respiratory tract.
Symptoms:
Immediate medical attention / special See first aid information above. Note to Physicians: Provide
treatment? general supportive measures and treat symptomatically.
5. Fire Fighting Measures
Suitable (and unsuitable) Use dry chemical fire extinguisher. Do not use water or halogenated
fire extinguishing media: compounds, except that large amounts of water may be used to deluge small
quantities of this product.
Specific hazards arising Inhalation, skin or eye contact, can result in serious injury. This product is
from the product not combustible or flammable. This product is not considered to be an
Page 2 of 8

Special protective
equipment and
precautions for fire
fighters
6. Accidental Release Measures
Safety Data Sheet
Hydrated lime
explosion hazard, although reaction with water or other incompatible
materials may rupture containers. When this product is wet, it can be very
slippery and can result in a slip hazard. Hazardous Combustion Products:
None.
Wear full fire -fighting turn -out gear (full Bunker gear), and respiratory
protection (SCBA) to prevent inhalation, skin or eye contact.
Personal precautions, protective equipment, emergency procedures:
Avoid inhalation, eye and skin contact. Avoid generating airborne dust. Wear appropriate
protective clothing as described in section 8.
Methods and materials for containment and clean up:
Utilize cleanup methods that minimize generating dust: vacuum. Avoid dry sweeping. Residue on
surfaces may be removed with copious amount of water or vinegar.
7. Handling & Storage
Safe Handling: Avoid inhalation, skin and eye contact. Avoid generating airborne dust. An eye wash
station should be readily available when this product is handled.
Safe Storage: Keep in tightly closed containers. Protect containers from physical damage. Store in a
cool, dry, and well -ventilated location. Do not store near incompatible materials (see
Section 10 below). Keep away from moisture. Long-term storage in aluminum
containers is not recommended, as calcium oxide may corrode aluminum over long
periods of time
8. Exposure Controls/Personal Protection
Occupational Exposure Limits
Calcium hydroxide
silica - crystalline quartz
OSHA PEL
ACGIH TLV
Ont. Reg. 833 TWAEV
(mg/m3)
(mg/M3)
(mg/m3)
15 (total)
5
5
5 (respirable)
30 / (% silica +2) (total)
0.025
0.1
10 / (% silica +2)
(respirable)
(respirable)
Engineering Controls: Use with adequate general or local exhaust ventilation and to maintain
exposure below occupational exposure limits.
Individual Protection Measures (Personal Protective Equipment):
Page 3 of 8

Safety Data Sheet
Hydrated lime
Specific Eye / Face Safety glasses with side shields. In windy conditions, or if work activity
Protection: generates elevated airborne dust levels, dust proof or chemical goggles
are recommended. Contact lenses should not be worn.
Specific Skin When there is a risk of skin contact, wear appropriate clothing and
Protection: gloves to prevent contact.
Page 4 of 8

Safety Data Sheet
Hydrated lime
Specific Respiratory If exposure limits are exceeded, an approved particulate respirator, or
Protection: supplied air respirator, appropriate for the airborne concentrations,
should be used. Selection and use of the respiratory protective
equipment must be in accordance with applicable regulations and
good industrial hygiene practices.
Other: An emergency eye wash fountain and shower are recommended.
9. Physical & Chemical Properties
Appearance:
White powder
Odor:
Odorless
Odor threshold:
Not Applicable
pH at 25 degrees C:
12.45
Melting Point:
1076 OF (580 °C)
Boiling Point and range:
5162 OF (2850°C)
Flash Point:
Not Applicable
Evaporation Rate:
Not Applicable
Flammability:
Not Applicable
Upper/lower flammability or explosive limits Not Applicable
Vapor pressure/density: Non Volatile
Relative density: 2.24
Solubility: Slightly soluble in water: 0.2% @ 0'C. Soluble in acids, glycerin,
and sugar solutions
Partition coefficient: n-octanol/water Not applicable
Auto -ignition temperature: Not Available
Decomposition temperature: Not available
Viscosity: Not Applicable
10. Stability & Reactivity
Reactivity: Reacts with acids to form calcium salts, releasing heat. Reacts with
carbon dioxide in air to form calcium carbonate. See also
Incompatibility below.
Chemical stability:
Stable under normal storage and handling conditions.
Possibility of Hazardous Reactions: See "reactivity" above.
Conditions to avoid: Vicinity of incompatible materials.
Page 5 of 8

Safety Data Sheet
Hydrated lime
Incompatibility: This product should not be mixed or stored with the following
materials, due to the potential for violent reaction and release of
heat:
• acids
• reactive fluoridated compounds
• reactive brominated compounds
• reactive powdered metals
• reactive phosphorous compounds
• aluminum powder
• organic acid anhydrides
• nitro -organic compounds
• interhalogenated compounds
Hazardous decomposition products: None
11. Toxicological Information
Likely routes of exposure & symptoms:
Eyes:
Contact can cause severe irritation or burning of eyes, including permanent damage.
Skin:
Contact can cause severe irritation or burning of skin, especially in the presence of
moisture.
Ingestion:
This product can cause severe irritation or burning of gastrointestinal tract if
swallowed.
Inhalation:
This product can cause severe irritation of the respiratory system.
Chronic health effects: This product contains trace amounts of crystalline silica. Prolonged or
repeated inhalation of respirable crystalline silica can cause silicosis, as
serious lung disease.
Respiratory or skin
This material is not known to cause sensitization
sensitization:
Germ cell mutagenicity:
No data available.
Carcinogenicity:
This product is not listed as carcinogenic by OSHA, IARC, NTP, ACGIH, or
the EU Directives. This product may contain trace amounts of crystalline
silica quartz which is listed by IARC as "Carcinogenic to Humans" (Group
1) and "Known to be a Human Carcinogen" by NTP (National Toxicology
Program).
Reproductive toxicity: No Data Available.
Numerical Measures
of Crystalline Silica: Oral Rat LD50 > 22,500 mg/kg
Toxicity
Calcium Hydroxide: Oral (rat) LD50: 7340 mg/kg
Page 6 of 8

Safety Data Sheet
Hydrated Lime
12. Ecological Information
Because of the elevated pH of this product, it might be expected to produce some ecotoxicity upon
exposure to certain aquatic organisms and aquatic systems in high concentrations
This material shows no bioaccumulation effect or food chain concentration toxicity.
13. Disposal Considerations
Dispose of contents in accordance with federal, state, provincial and local regulations.
14. Transport Information
Not regulated by Department of Transportation, Transport of Dangerous Goods
15. Regulatory Information
CERCLA Hazardous Substances
SARA Toxic Chemical (40 CFR 372.65)
Not listed
Not listed
SARA Section 302 Extremely Hazardous Substances (40 CFR 355) Not listed
SARA 311/312
Not listed
SARA Section 313 Toxic Chemicals reporting requirements None
Threshold planning quantity (TPQ) Not listed
RCRA Hazardous Waste Classification (40 CFR 261) Not Classified
EPA Toxic Substances Control Act All of the components of this product are listed on the TSCA
(TSCA) Status
California Proposition 65 Airborne crystalline silica particulates of respirable size are known
to the State of California to cause cancer.
NFPA ratings Health: 3 Fire: 0 Reactivity: 0
HMIS Ratings Health: 3 Fire: 0 Reactivity: 0 Personal protection: E
OSHA Specifically regulated substance (29 CFR 1910) Not listed
OSHA Air contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A) Listed
MSHA Not listed
Canada DSL Listed
Canadian WHMIS Classification D2A, Materials Causing other toxic
effects.
E, Corrosive Material
Canada CPR This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulation of a Canada and this SDS contains all the required information.
Page 7 of 8

Safety Data Sheet
Hydrated lime
16. Other Information
List of GHS H315: Causes skin irritation
Hazard H318: Causes serious eye damage
Statements: H335: May cause respiratory irritation.
H350: May cause cancer through inhalation
List of GHS P201: Obtain special instructions before use.
Precautionary P202: Do not handle until all safety precautions have been read and understood.
Statements: P233: Keep container tightly closed
P260: Do not breathe dust.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in well -ventilated area
P280: Wear protective gloves, clothing and eye protection
Abbreviations
CERCLA Comprehensive Environmental RCRA Resource Conservation and Recovery Act
Response, Compensation and Liability
Act
SARA Superfund Amendments and IARC International Agency for Research on Cancer
Reauthorization Act
NTP National Toxicology Program
The information contained herein is believed to be accurate and reliable as of the date hereof. However, Carmeuse makes no
representation, warranty or guarantee as to results or as to the information's accuracy, reliability or completeness. Carmeuse
has no liability for any loss or damage that may result from use of the information. Each user is responsible to review this
information, satisfy itself as to the information's suitability and completeness, and circulate the information to its employees,
customers and other appropriate third parties.
Page 8 of 8

SafetyData Sheet castl-e
CC
5oluzjw.; Chemistry, service'
Hazardous Chemical, Dangerous Goods
1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION
Product name: Hydrochloric Acid 33%
Synonyms
Hydrochloric Acid 200L
Hydrochloric Acid 25L
Product Code
20211-200
20211-25
Recommended use: Industrial Mineral Acid, pH Control, Descaling, water Treatment.
Supplier:
ABN:
Street Address
Telephone:
Facsimile:
Castle Chemical Pty Ltd
86 001 443 901
16 Rural Drive
Sandgate NSW 2304
Australia
[phone]
[phone]
Emergency Telephone number: [phone]
2. HAZARDS IDENTIFICATION
This material is hazardous according to health criteria of Safe Work Australia.
Signal Word
Danger
Hazard Classifications
Acute Toxicity - Oral - Category 4
Acute Toxicity - Inhalation - Category 2
Corrosive to Metals - Category 1
Skin Corrosion/Irritation - Category 1A
Serious Eye Damage/Irritation - Category 1
Hazard Statements
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.
Prevention Precautionary Statements
P102
Keep out of reach of children.
P103
Read label before use.
P234
Keep only in original container.
P260
Do not breathe fume, gas, mist, vapours or spray.
P264
Wash hands, face and all exposed skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well -ventilated area.
P280
Wear protective clothing, gloves, eye/face protection and suitable respirator.
Product Name: Hydrochloric Acid 33%
Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 1 of 8

Safety Data Sheet
P284 Wear respiratory protection.
Response Precautionary Statements
castl-e
CC
'Soludwn Chemistry, Service'
P101
If medical advice is needed, have product container or label at hand.
P301+P310
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER or doctor/physician.
P330
Rinse mouth.
P363
Wash contaminated clothing before reuse.
P390
Absorb spillage to prevent material damage.
Storage Precautionary Statements
P403+P233 Store in a well -ventilated place. Keep container tightly closed.
P405 Store locked up.
P406 Store in original container with a resistant inner liner.
Disposal Precautionary Statement
P501 Dispose of contents/container in accordance with local, regional, national and
international regulations.
Poison Schedule: Not Applicable
DANGEROUS GOOD CLASSIFICATION
Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".
Dangerous Goods Class: 8
3. COMPOSITION INFORMATION
CHEMICAL ENTITY
Hydrochloric acid
Ingredients determined to be Non -Hazardous
4. FIRST AID MEASURES
CAS NO PROPORTION
7647-01-0 30-60 %
Balance
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800
764 766).
Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and
loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until
fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and have a qualified
person give oxygen through a facemask. If breathing has stopped apply artificial respiration at once. In the event
of cardiac arrest, apply external cardiac massage. Seek immediate medical advice.
Skin Contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
water. If swelling, redness, blistering or irritation occurs seek medical assistance. For gross contamination,
immediately drench with water and remove clothing. Continue to flush skin and hair with plenty of water (and soap
if material is insoluble). For skin burns, cover with a clean, dry dressing until medical help is available. If
Product Name: Hydrochloric Acid 33% Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 2 of 8

Safety Data Sheet castle
—CC—
Solutions, Chemistry, Service'
blistering occurs, do NOT break blisters. If swelling, redness, blistering, or irritation occurs seek medical
assistance.
Eye contact: Immediately irrigate with copious quantities of water for 15 minutes. Eyelids to be held open.
Remove clothing if contaminated and wash skin. Urgently seek medical assistance. Transport to hospital or
medical centre.
Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink.
Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Immediately
call Poisons Centre or Doctor.
Notes to physician: Treat symptomatically. Can cause corneal burns.
5. FIRE FIGHTING MEASURES
Hazchem Code: 2R
Suitable extinguishing media: If material is involved in a fire use water fog (or if unavailable fine water spray),
alcohol resistant foam, standard foam, dry agent (carbon dioxide, dry chemical powder).
Specific hazards: Non-combustible material.
Fire fighting further advice: Not applicable.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up
with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal.
LARGE SPILLS
Clear area of all unprotected personnel. Slippery when spilt. Avoid accidents, clean up immediately. Wear
protective equipment to prevent skin and eye contamination and the inhalation of vapours. Work up wind or
increase ventilation. Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert
material). Collect and seal in properly labelled containers or drums for disposal. If contamination of crops,
sewers or waterways has occurred advise local emergency services.
Dangerous Goods - Initial Emergency Response Guide No: 40
7. HANDLING AND STORAGE
Handling: Avoid eye contact and skin contact. Avoid inhalation of vapour, mist or aerosols.
Storage: Store in a cool, dry, well -ventilated place and out of direct sunlight. Store away from foodstuffs. Store
away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition.
Store locked up. Store in corrosive resistant container with a resistant inner liner. Keep container standing
upright. Keep containers closed when not in use - check regularly for leaks.
This material is classified as a Class 8 Corrosive as per the criteria of the "Australian Code for the Transport of
Dangerous Goods by Road & Rail" and/or the "New Zealand NZS5433: Transport of Dangerous Goods on Land"
and must be stored in accordance with the relevant regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Product Name: Hydrochloric Acid 33% Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 3 of 8

Safety Data Sheet
National occupational exposure limits:
castl-e
CC
5oludons, Chemistry, Service'
TWA STEL NOTICES
ppm mg/m3 ppm mg/m3
Hydrogen chloride 5 Peak 7.5 Peak - - -
limitation limitation
As published by Safe Work Australia.
TWA - The time -weighted average airborne concentration over an eight -hour working day, for a five-day working
week over an entire working life.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not
be exceeded at any time during a normal eight -hour workday.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept too as low a level as is workable. These exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.
If the directions for use on the product label are followed, exposure of individuals using the product should not
exceed the above standard. The standard was created for workers who are routinely, potentially exposed during
product manufacture.
Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous
Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated.
Engineering Measures: Ensure ventilation is adequate to maintain air concentrations below Exposure
Standards. Use only in well ventilated areas. Use with local exhaust ventilation or while wearing appropriate
respirator.
Personal Protection Equipment: RUBBER BOOTS, GLOVES, APRON, CHEMICAL GOGGLES,
RESPIRATOR.
Personal protective equipment (PPE) must be suitable for the nature of the work and any hazard associated with
the work as identified by the risk assessment conducted.
Wear rubber boots, gloves, apron, chemical goggles, respirator. Use with adequate ventilation. If inhalation risk
exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Available information suggests that gloves made from natural rubber, nitrile rubber should be suitable for
intermittent contact. However, due to variations in glove construction and local conditions, the user should make
a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated
clothing and other protective equipment before storing or re -using.
Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or
smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and skin
contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations and safety showers are close
to the workstation location.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Clear Liquid
Colour: Clear / Light Tan
Odour: Acrid Acidic
Solubility: Soluble with water.
Specific Gravity (20 °C): 1.15 - 1.17
Flash Point (°C): Non Flammable
Boiling Point/Range (°C): 109
Product Name: Hydrochloric Acid 33% Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 4 of 8

SafetyData Sheet castl-e
CC
5oludons, Chemistry, Service'
(Typical values only - consult specification sheet)
N Av = Not available, N App = Not applicable
10. STABILITY AND REACTIVITY
Chemical stability: This material is thermally stable when stored and used as directed.
Conditions to avoid: Elevated temperatures and sources of ignition.
Incompatible materials: Oxidising agents.
Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes.
Hazardous reactions: No known hazardous reactions.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Acute Effects
Inhalation: Fatal if inhaled. Material may be an irritant to mucous membranes and respiratory tract.
Skin contact: Contact with skin will result in severe irritation. Corrosive to skin - may cause skin burns.
Ingestion: Harmful if swallowed. Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and
chemical burns to the gastrointestinal tract.
Eye contact: A severe eye irritant. Corrosive to eyes: contact can cause corneal burns. Contamination of eyes
can result in permanent injury.
Acute toxicity
Inhalation: This material has been classified as a Category 2 Hazard. Acute toxicity estimate (based on
ingredients): 0.5 - 2.0 mg/L
Skin contact: This material has been classified as non -hazardous. Acute toxicity estimate (based on
ingredients): >2,000 mg/Kg bw
Ingestion: This material has been classified as a Category 4 Hazard. Acute toxicity estimate (based on
ingredients): 300 - 2,000 mg/Kg bw
Corrosion/Irritancy: Eye: this material has been classified as a Category 1 Hazard (irreversible effects to eyes).
Skin: this material has been classified as a Category 1A Hazard (irreversible effects to skin).
Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has
been classified as not a skin sensitiser.
Aspiration hazard: This material has been classified as non -hazardous.
Specific target organ toxicity (single exposure): This material has been classified as non -hazardous.
Chronic Toxicity
Mutagenicity: This material has been classified as non -hazardous.
Product Name: Hydrochloric Acid 33%
Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 5 of 8

SafetyData Sheet castl-e
CC
5oluzjw.; Chemistry, service'
Carcinogenicity: This material has been classified as non -hazardous.
Reproductive toxicity (including via lactation): This material has been classified as non -hazardous.
Specific target organ toxicity (repeat exposure): This material has been classified as non -hazardous.
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways.
Acute aquatic hazard: This material has been classified as non -hazardous. Acute toxicity estimate (based on
ingredients): >100 mg/L
Long-term aquatic hazard: This material has been classified as non -hazardous. Non -rapidly or rapidly
degradable substance for which there are adequate chronic toxicity data available OR in the absence of chronic
toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the substance is not rapidly
degradable and/or BCF < 500 and/or log Kow < 4.
Ecotoxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility: No information available.
13. DISPOSAL CONSIDERATIONS
Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal
protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS.
If possible material and its container should be recycled. If material or container cannot be recycled, dispose in
accordance with local, regional, national and international Regulations.
14. TRANSPORT INFORMATION
ROAD AND RAIL TRANSPORT
Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".
UN No: 1789
Dangerous Goods Class: 8
Packing Group: II
Hazchem Code: 2R
Emergency Response Guide No: 40
Proper Shipping Name: HYDROCHLORIC ACID
Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), dangerous when wet substances
Product Name: Hydrochloric Acid 33%
Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 6 of 8

Safety Data Sheet
castle
cc
5olutlon; Chemfssry, SeMre'
(Class 4.3), oxidising agents (Class 5.1), organic peroxides (Class 5.2), radioactive substances (Class 7) or food
and food packaging in any quantity. Note 1: Concentrated strong alkalis are incompatible with concentrated
strong acids. Note 2: Concentrated strong acids are incompatible with concentrated strong alkalis. Note 3: Acids
are incompatible with Dangerous Goods of Class 6 which are cyanides. Exemptions may apply.
MARINE TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea.
UN No:
Dangerous Goods Class
Packing Group:
Proper Shipping Name:
1789
8
11
HYDROCHLORIC ACID
AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous
Goods Regulations for transport by air.
UN No:
Dangerous Goods Class:
Packing Group:
Proper Shipping Name:
15. REGULATORY INFORMATION
1789
8
11
HYDROCHLORIC ACID
This material is not subject to the following international agreements:
Montreal Protocol (Ozone depleting substances)
The Stockholm Convention (Persistent Organic Pollutants)
The Rotterdam Convention (Prior Informed Consent)
Basel Convention (Hazardous Waste)
International Convention for the Prevention of Pollution from Ships (MARPOL)
This material/constituent(s) is covered by the following requirements:
• All components of this product are listed on or exempt from the Australian Inventory of Chemical Substances
(AICS).
16. OTHER INFORMATION
Reason for issue: First issue
This information was prepared in good faith from the best information available at the time of issue. It is based on
the present level of research and to this extent we believe it is accurate. However, no guarantee of accuracy is
Product Name: Hydrochloric Acid 33%
Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 7 of 8

Safety Data Sheet
castle
cc
5olutlon; Chemistry, SeMre'
made or implied and since conditions of use are beyond our control, all information relevant to usage is offered
without warranty. The manufacturer will not be held responsible for any unauthorised use of this information or for
any modified or altered versions.
If you are an employer it is your duty to tell your employees, and any others that may be affected, of any hazards
described in this sheet and of any precautions that should be taken.
Safety Data Sheets are updated frequently. Please ensure you have a current copy.
Product Name: Hydrochloric Acid 33%
Reference No: 20211
Issued: 2017-05-24 Version: 1.0 Page 8 of 8

+ www.sigmaainriCh.com
Version 6.5
SAFETY DATA SHEET
Revision Date 28.10.2021
Print Date 06.11.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name Sodium hydroxide
Product Number
Brand
Index -No.
CAS -No.
S5881
SIGALD
011-002-00-6
1310-73-2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Synthesis of substances
1.3 Details of the supplier of the safety data sheet
Company MilliporeSigma Canada Ltd
2149 WINSTON PARK DRIVE
OAKVILLE ON L6H 6J8
CANADA
Telephone [phone]
Fax [phone]
1.4 Emergency telephone
Emergency Phone # [phone] CHEMTREC (USA)
[phone] CHEMTREC
(International)
24 Hours/day; 7 Days/week
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GHS Classification in accordance with Hazardous Products Regulations (HPR)
(SOR/2015-17)
Corrosive to Metals (Category 1), H290
Skin corrosion (Category 1A), H314
Serious eye damage (Category 1), H318
Short-term (acute) aquatic hazard (Category 3), H402
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram P�
SIGALD - S5881
Page 1 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

Signal word
Danger
Hazard statement(s)
H290
H314
H402
Precautionary statement(s)
P234
P260
P264
P273
P280
P301 + P330 + P331
P303 + P361 + P353
P304 + P340 + P310
P305 + P351 + P338 +
P310
P363
P390
P405
P501
May be corrosive to metals.
Causes severe skin burns and eye damage.
Harmful to aquatic life.
Keep only in original packaging.
Do not breathe dusts or mists.
Wash skin thoroughly after handling.
Avoid release to the environment.
Wear protective gloves/ protective clothing/ eye protection/ face
protection.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER/ doctor.
Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage.
Store locked up.
Dispose of contents/ container to an approved waste disposal
plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
- none
SECTION 3: Composition/information on ingredients
3.1 Substances
Synonyms
Formula
Molecular weight
CAS -No.
EC -No.
Index -No.
: Caustic soda
NaOH
40.00 g/mol
1310-73-2
215-185-5
011-002-00-6
Component
Classification
Concentration
sodium hydroxide
Met. Corr. 1; Skin Corr.
<= 100
1A; Eye Dam. 1; Aquatic
Acute 3; H290, H314,
H318, H402
Concentration limits:
>= 0.4 %: Met. Corr. 1,
H290; >= 5 %: Skin Corr.
1A, H314; 2 - < 5 %: Skin
Corr. 1B, H314; 0.5 - < 2
SIGALD - S5881
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 2 of 11
mittipQitla
SiGMla

%: Skin Irrit. 2, H315; 0.5
- < 2 %: Eye Irrit. 2,
H319•
* Weight
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first -aid measures
General advice
First aiders need to protect themselves. Show this material safety data sheet to the doctor
in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of
perforation). Call a physician immediately. Do not attempt to neutralise.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Sodium oxides
Not combustible.
Ambient fire may liberate hazardous vapours.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
SIGALD - S5881
Page 3 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non -emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
No metal containers.
Tightly closed. Dry.
Storage class
Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Components with workplace control parameters
Components
CAS -No.
Value
Control
parameters
Basis
sodium
1310-73-2
C
2 mg/m3
Quebec. Regulation respecting
hydroxide
occupational health and safety,
Schedule 1, Part 1: Permissible
exposure values for airborne
contaminants
SIGALD - S5881
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 4 of 11
mittipQitla
SiGMla

(c) 2 mg/m3 Canada. Alberta, Occupational Health
and Safety Code (table 2: OEL)
Remarks Occupational exposure limit is based on irritation effects and its adjustment to
compensate for unusual work schedules is not required
Al
A
Derived No Effect Level (DNEL)
2 mg/m3 I Canada. British Columbia OEL
2 mg/m3 USA. ACGIH Threshold Limit Values
(TLV)
Application Area
utes of
tposure
Health effect
Value
Workers Inhalation Long-term local effects 1 m /m3
Consumers Inhalation Lonq-term local effects 1 mq/m3
8.2 Exposure controls
Appropriate engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash
hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety
goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
Body Protection
protective clothing
SIGALD - S5881
Page 5 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a)
Appearance
Form: pellets
Color: white
b)
Odor
odorless
c)
Odor Threshold
Not applicable
d)
pH
ca.> 14 at 100 g/I at 20 °C (68 IF)
e)
Melting
Melting point/range: 318 °C (604 OF)
point/freezing point
f)
Initial boiling point
1,390 °C 2,534 IF at 1,013 hPa
and boiling range
g) Flash point ()Not applicable
h) Evaporation rate No data available
i) Flammability (solid, The product is not flammable.
gas)
j) Upper/lower No data available
flammability or
explosive limits
k) Vapor pressure < 24 hPa at 20 °C (68 OF)
1) Vapor density 1.38 - (Air = 1.0)
m) Density 2.13 g/cm3 at 20 °C (68 OF)
Relative density No data available
n) Water solubility 1,090 g/I at 20 °C (68 IF)
o) Partition coefficient: Not applicable for inorganic substances
n-octanol/water
p)
Autoignition
No data available
temperature
q)
Decomposition
No data available
temperature
r)
Viscosity
No data available
s)
Explosive properties
No data available
t)
Oxidizing properties
none
9.2 Other safety information
Relative vapor
1.38 - (Air = 1.0)
SIGALD -
S5881
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 6 of 11
mittiploftla
SiGMla

density
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
Violent reactions possible with:
Acetone
Chlorine
Ethylene oxide
Fluorine
Hydrogen halides
Hydrazine hydrate
hydroxylamine
Acid anhydrides
Acrolein
Acid chlorides
Acids
sulfuric acid
Chloroform
Water
hydrogen peroxide
anhydrides
phosphides
halogen -halogen compounds
trichloroethene
can decompose violently in contact with:
Organic Substances
hydrogen sulphide
Risk of ignition or formation of inflammable gases or vapours with:
powdered aluminium
Ammonium salts
persulfates
Sodium borohydride
phosphorus
Oxides of phosphorus
Halogenated hydrocarbon
Light metals
Metals
Risk of explosion/exothermic reaction with:
Bromine
Calcium
in powder form
furfuryl alcohol
Nitromethane
Peroxides
organic nitro compounds
Nitriles
Acrylic monomers
SIGALD - S5881
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 7 of 11
mittipQitla
SiGMla

Chloroform
with
Acetone
Nitrobenzene
with
Methanol
Nitrobenzene
with
salts
magnesium
Zinc
and
Tin
(in the presence of atmospheric oxygen and/or moisture)
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
Aluminum, brass, Metals, metal alloys, Zinc, Tin
10.6 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Oral: No data available
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of
perforation of the esophagus and the stomach.
Inhalation: No data available
Inhalation: Corrosive to respiratory system.
Symptoms: burns of mucous membranes, Cough, Shortness of breath, Possible damages:,
damage of respiratory tract
Dermal: No data available
No data available
Skin corrosion/irritation
Skin - Rabbit
Result: Causes burns.
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye damage.
(OECD Test Guideline 405)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Causes serious eye damage.
Respiratory or skin sensitization
Patch test: - In vitro study
Result: negative
Remarks: (ECHA)
SIGALD - S5881
Page 8 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
RTECS: WB4900000
burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation
and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis,
pulmonary edema, Material is extremely destructive to tissue of the mucous membranes
and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to fish LC50 - Gambusia affinis (Mosquito fish) - 125 mg/I - 96 h
Remarks: (ECOTOX Database)
Toxicity to daphnia EC50 - Ceriodaphnia (water flea) - 40.4 mg/I - 48 h
and other aquatic Remarks: (ECHA)
invertebrates
Toxicity to bacteria EC50 - Photobacterium phosphoreum - 22 mg/I - 15 min
Remarks: (External MSDS)
12.2 Persistence and degradability
The methods for determining the biological degradability are not applicable to inorganic
substances.
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
SIGALD - S5881
Page 9 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
Harmful effect due to pH shift.
Forms corrosive mixtures with water even if diluted.
Neutralisation possible in waste water treatment plants.
Discharge into the environment must be avoided.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned
containers like the product itself. See www.retrologistik.com for processes regarding the
return of chemicals and containers, or contact us there if you have further questions.
SECTION 14: Transport information
TDG
UN number: 1823 Class: 8 Packing group: II
Proper shipping name: SODIUM HYDROXIDE, SOLID
Labels: 8
ERG Code: 154
Marine pollutant: no
IMDG
UN number: 1823 Class: 8 Packing group: II
Proper shipping name: SODIUM HYDROXIDE, SOLID
IATA
UN number: 1823 Class: 8 Packing group: II
Proper shipping name: Sodium hydroxide, solid
SECTION 15: Regulatory information
EMS -No: F-A, S-B
This product has been classified in accordance with the hazard criteria of the Hazardous
Products Regulations (HPR) and the SDS contains all the information required by the HPR.
SECTION 16: Other information
Further information
The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. The information in this document is based on the
present state of our knowledge and is applicable to the product with regard to
SIGALD - S5881
Page 10 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

appropriate safety precautions. It does not represent any guarantee of the properties of
the product. Sigma -Aldrich Corporation and its Affiliates shall not be held liable for any
damage resulting from handling or from contact with the above product. See
www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional
terms and conditions of sale.
Copyright 2020 Sigma -Aldrich Co. LLC. License granted to make unlimited paper copies
for internal use only.
The branding on the header and/or footer of this document may temporarily not visually
match the product purchased as we transition our branding. However, all of the
information in the document regarding the product remains unchanged and matches the
product ordered. For further information please contact [e-mail].
Version: 6.5
SIGALD - S5881
Revision Date: 28.10.2021
Print Date: 06.11.2021
Page 11 of 11
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 1 of 7
Trisodium Phosphate,
SECTION 1 : Identification of the substance/mixture and of the supplier
Product name: Trisodium Phosphate,
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25564
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331
Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053
SECTION 2 : Hazards identification
Classification of the substance or mixture
■ Irritant
Skin Corr. 1B
Eye Damage. 1
Signal word :Warning
Hazard statements:
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Wear protective gloves/protective clothing/eye protection/face protection
Wash ... thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapours/spray
Use only outdoors or in a well -ventilated area
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing
Specific treatment (see ... on this label)
IF ON SKIN: Wash with soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
If eye irritation persists get medical advice/attention
Take off contaminated clothing and wash before reuse

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 2 of 7
Trisodium Phosphate,
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Store locked up
Store in a well ventilated place. Keep container tightly closed
Dispose of contents/container to ...
Combustible Dust Hazard: :
May form combustible dust concentrations in air (during processing).
Other Non-GHS Classification:
WHMIS
0
E
NFPA/HMIS
NFPA SCALE (0-4)
SECTION 3 : Composition/Information on ingredients
ealth K
ammability �E
1
Personal X
Protection
HMIS RATINGS (0-4)
Ingredients:
CAS 10101-89-0 Trisodium Phosphate 100 %
Percentages are by weight
SECTION 4 : First aid measures
Description of first aid measures
After inhalation: Loosen clothing as necessary and position individual in a comfortable position.Remove to
fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen. Do not perform mouth-to-
mouth to resuscitate. Immediately get medical assistance.
After skin contact: Wash affected area with soap and water. Seek medical advice if discomfort or irritation
persists.
After eye contact: Protect unexposed eye. Rinse or flush exposed eye gently using water for 15-20 minutes.
Remove contact lenses while rinsing.Occasionally lift the upper and lower eyelids while rinsing.Go to the
hospital. Continue rinsing eyes during transport to hospital.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Get medical assistance.
Most important symptoms and effects, both acute and delayed:
Irritation. Nausea. Headache. Shortness of breath.;

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 3 of 7
Trisodium Phosphate,
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention provide SIDS document to physician.
SECTION 5 : Firefighting measures
Extinguishing media
Suitable extinguishing agents: Use water, dry chemical, chemical foam, or alcohol -resistant foam.
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Advice for firefighters:
Protective equipment: Wear protective eyeware, gloves, and clothing.
Additional information (precautions): Ensure adequate ventilation.Avoid contact with skin, eyes, and
clothing.
SECTION 6 : Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of use or
handling. Use spark -proof tools and explosion -proof equipment.
Environmental precautions:
Should not be released into environment.Collect contaminated soil for characterization per Section 13 .
Methods and material for containment and cleaning up:
Sweep up and containerize for disposal. Avoid generating dust. Always obey local regulations.Collect liquids
using vacuum or by use of absorbents. Place into properly labeled containers for recovery or disposal. Dust
deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are
released into the atmosphere in sufficient concentration. Prevent further leakage or spillage if safe to do so.lf
necessary use trained response staff or contractor.
Reference to other sections:
SECTION 7 : Handling and storage
Precautions for safe handling:
Wash hands before breaks and immediately after handling the product.Wash hands and exposed skin with soap
and plenty of water. Do not eat, drink, smoke, or use personal products when handling chemical substances.
Avoid contact with eyes, skin, and clothing.
Conditions for safe storage, including any incompatibilities:
Keep away from food, beverages, and feed sources. Protect from freezing and physical damage.Do not store
near strong acids.Keep product and empty container away from heat and sources of ignition.Store with like
hazards. Keep container tightly closed in a cool, dry, and well -ventilated area. Store in inert atmosphere. Store
away from acids.
SECTION 8 : Exposure controls/personal protection

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev
Effective date : 12.19.2014 Page 4 of 7
Trisodium Phosphate,
Control Parameters:
10101-89-0, Sodium phosphate tribasic dodecahydrate, USA Workplace
Environmental Exposure Levels (WEEL)
Appropriate Engineering controls:
It is recommended that all dust control equipment such as local exhaust
ventilation and material transport systems involved in handling of this
product contain explosion relief vents or an explosion suppression system
or an oxygen deficient environment. Provide exhaust ventilation or other
engineering controls to keep the airborne concentrations of vapor and
mists below the applicable workplace exposure limits (Occupational
Exposure Limits-OELs) indicated above.
Respiratory protection:
Not required under normal conditions of use. Where risk assessment
shows air -purifying respirators are appropriate use a full -face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.Use NIOSH-approved respiratory
protection or breathing apparatus.
Protection of skin:
Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation.
Eye protection:
Safety glasses or goggles.
General hygienic measures:
Avoid contact with skin, eyes, and clothing.Wash hands and exposed skin
with soap and plenty of water. Wash hands before breaks and
immediately after handling the product.Remove contaminated clothing
and shoes.8efore wearing wash contaminated clothing.
SECTION 9 : Physical and chemical properties
Appearance (physical
White solid
Explosion limit lower:
No Information
state,color):
Explosion limit upper:
No Information
Odor:
Odorless
Vapor pressure:
Not Applicable
Odor threshold:
Not Applicable
Vapor density:
Not Applicable
pH -value:
11.8-12 1% aqueous
solution
Relative density:
1.62 g/cm3 at 25 °C
Melting/Freezing point:
750C
Solubilities:
Soluble in water: 190.1 g/I at
°C
20
Boiling point/Boiling
Not Applicable
Partition coefficient (n-
Not Applicable
range:
octanol/water):
Flash point (closed
Not Applicable
Auto/Self-ignition
No Information
cup):
temperature:
Evaporation rate:
Not Applicable
Decomposition
750C
temperature:
Flammability
No Information
Viscosity:
a. Kinematic:Not Applicable
(solid,gaseous):
b. Dynamic: Not Applicable
Density: Not Applicable
SECTION 10 : Stability and reactivity
Reactivity:
Chemical stability: Stable under normal conditions.
Possible hazardous reactions:
Conditions to avoid:High temperatures. Dust generation.

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 5 of 7
[ Trisodium Phosphate,
Incompatible materials: Strong acids.
Hazardous decomposition products: Phosphorus oxides.Sodium oxides.
SECTION 11 : Toxicological information
Acute Toxicity:
Oral:
ECHA
LD50 Oral - rat - 7,400 mg/kg
Chronic Toxicity: No additional information.
Corrosion Irritation: No additional information.
Sensitization:
No additional information.
Single Target Organ (STOT):
No additional information.
Numerical Measures:
No additional information.
Carcinogenicity:
No additional information.
Mutagenicity:
No additional information.
Reproductive Toxicity:
No additional information.
SECTION 12 : Ecological information
Ecotoxicity
Toxicity to fish: LCO - Leuciscus idus (Golden orfe) - 2,400 mg/I - 48 h
Persistence and degradability: Readily degradable in the environment.
Bioaccumulative potential:
Mobility in soil:
Other adverse effects: Shortness of breath.Coughing. Headache. Nausea.Vomiting.
SECTION 13 : Disposal considerations
Waste disposal recommendations:
Offer surplus and non -recyclable solutions to a licensed disposal company.Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in
a chemical incinerator equipped with an afterburner and scrubber.Do not allow product to reach sewage system
or open water.lt is the responsibility of the waste generator to properly characterize all waste materials
according to applicable regulatory entities (US 40CFR262.11), Product or containers must not be disposed
together with household garbage. Consult federal, state, provincial, and local regulations regarding the proper
disposal of waste material that may incorporate some amount of this product.
SECTION 14 : Transport information
UN -Number
3262
UN proper shipping name
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.
Transport hazard class(es)

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 6 of 7
Trisodium Phosphate,
Class:
8 Corrosive substances
Packing group:ll
Environmental hazard:
Transport in bulk:
Special precautions for user:
SECTION 15 : Regulatory information
United States (USA)
SARA Section 311/312 (Specific toxic chemical listings):
Acute
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
10101-89-0 Not applicable
TSCA (Toxic Substances Control Act):
10101-89-0 Not applicable
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
10101-89-0 Trisodium Phosphate 5000 lb
Proposition 65 (California):
Chemicals known to cause cancer:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed
Canada
Canadian Domestic Substances List (DSL):
10101-89-0 Not applicable
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed
SECTION 16 : Other information 1
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations. Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.19.2014 Page 7 of 7
Trisodium Phosphate,
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.lt is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No -Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No -Effect Level (REACH)
Effective date : 12.19.2014
Last updated : 03.19.2015

�a�nounr
CHEMICALS S PLAST/CS, //VC.
Sulfuric Acid 93%
Safety Data Sheet (SDS)
Health
Reactivity
0
0
Personal Protection
Section 1: Chemical Product and Company Identification
Product Name: Sulfuric Acid 93%
CAS#: 7664-93-9
Synonym: Oil of Vitriol; Sulfuric Acid
Chemical Name: Hydrogen sulfate
Chemical Formula: H2-SO4
Contact Information:
Paramount Chemicals & Plastics, Inc. CCN 811901
Warehouse:
14470 S State Road 29
Felda, FL 33930
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
CHEMTREC - 24 Hour Emergency Telephone- call: 1-800-424-9300
CCN 811901
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Sulfuric Acid 7664-93-9 93%
Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR
(LC50): Acute: 510 mg/m
2 hours [Rat]. 320 mg/m 2 hours [Mouse].
Page 1 of 8

Page 2 of 8

Section 3: Hazards Identification
Potential Acute Health Effects:
Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive),
of ingestion, of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous
membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray
mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of
breath. Severe over -exposure can result in death. Inflammation of the eye is characterized by redness,
watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,
blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified
A2 (Suspected for human.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to
kidneys, lungs, heart, cardiovascular system, upper respiratory tract, eyes, teeth. Repeated or prolonged
exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray
mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to
spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.
Section 4: First Aid Measures
IN CASE OF EYE CONTACT:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Cold water may be used. Get medical attention immediately.
IN CASE OF SKIN CONTACT:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.
Seek medical attention immediately.
IN CASE OF SERIOUS SKIN CONTACT:
Wash with a disinfectant soap and cover the contaminated skin with an anti -bacterial cream. Seek
medical attention immediately.
IN CASE OF INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Seek medical attention immediately.
IN CASE OF SERIOUS INHALATION:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-
mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth
resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
IN CASE OF INGESTION:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention if symptoms appear.
IN CASE OF SERIOUS INGESTION:
Not available.
Page 3 of 8

Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto -Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion:
Products of combustion are not available since material is non-flammable. However, products of
decomposition include fumes of oxides of sulfur. Will react with water or steam to produce toxic and
corrosive fumes. Reacts with carbonates to generate
carbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen
sulfide respectively.
Fire Hazards in Presence of Various Substances: Combustible materials
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of
the product in presence of static discharge: Not available. Slightly explosive in presence of oxidizing
materials.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid.
White Phosphorous + boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible
materials. May cause fire when sulfuric acid is mixed with Cyclopentadiene, cyclopentanone oxime,
nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, and oxidizing agents such as chlorates,
halogens, permanganates.
Special Remarks on Explosion Hazards:
MixturesofsuIfuricacidand anyofthefollowingcanexplode:p-nitrotolu
e n e, p e n t a s it v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen
peroxide, ammonium tetraperoxychromate, mercuric nitrite, potassium chlorate, potassium permanganate
with potassium chloride, carbides, nitro compounds, nitrates, carbides, phosphorous, iodides, picratres,
fulminats, dienes, alcohols (when heated) Nitramide decomposes explosively on contact with
concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosive
decompositon.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and absorb with an inert dry material and place in an appropriate waste disposal
container. If necessary, neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak ONLY if without risk. Absorb with DRY earth, sand or other
non-combustible material. Do not get water inside container. Do not touch spilled material. Use water
spray curtain to divert vapor drift/ reduce vapors. Prevent entry into waterways/sources, basements or
confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute
solution of sodium carbonate. Be careful the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
Keep locked up. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add
water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested,
seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.
Keep away from incompatibles such as oxidizing agents, reducing agents, combustible materials, organic
materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated
fiberboard drum using a strong polyethylene inner package.
Page 4 of 8

Storage:
Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well -
ventilated area. Do not store above 23°C (73.4°F).
Storage: Keep container tightly closed. Keep container in a cool, well -ventilated area. Do not store above
23°C (73.4°F).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
below their respective threshold limit value. Ensure eyewash stations and safety showers are proximal to
the work -station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should
be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a
specialist BEFORE handling this product.
Exposure Limits:
TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States]
Inhalation TWA: 1 STEL: 3 (mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3)
from NIOSH [United States] Inhalation TWA: 1 (mg/m3) [United Kingdom (UK)]Consult local authorities
for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid. (Thick oily liquid.)
Odor: Odorless, but has a choking odor when hot.
Taste: Marked acid taste. (Strong.)
Molecular Weight: 98.08 g/mole
Color: Colorless.
pH (1%soln/water): Acidic.
Boiling Point:
270°C (518°F) - 340 deg. C Decomposes at 340 deg. C
Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)
Critical Temperature: Not available.
Specific Gravity: 1.84 (Water = 1)
Vapor Pressure: Not available.
Vapor Density: 3.4 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
lonicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in
ethyl alcohol.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability:
Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic
materials, exposure to moist
air or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.
Incompatibility with various substances:
Page 5 of 8

Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids,
alkalis, moisture.
Corrosivity:
Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in
presence of stainless
steel(304). Non -corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to
the product.
Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID,
AMMONIUM HYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE
CYANOHYDRIN, ETHYLENEIMINE, NITRIC ACID, 2-NITROPROPANE, PROPYLENE OXIDE,
SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOL MONOMETHYL ETHER, ETHYL
ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHER ACETATE,
GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic
anhydride, Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile,
Acrolein, Acrylonitrile, Acrylonitrile +water, Alcohols + hydrogen peroxide, ally compounds such as Allyl
alcohol, and Allyl Chloride, 2-Aminoethanol, Ammonium hydroxide, Ammonium triperchromate, Aniline,
Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesium acetylene carbide,
Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonic
acid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-
Dinitronaphthlene + sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene,
Dimethylbenzylcarbinol + hydrogen peroxide, Epichlorohydrin, Ethyl alcohol + hydrogen peroxide,
Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine, Fulminates, hydrogen peroxide,
Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene, Lithium
silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid +
glycerides, p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid,
Permanganates + benzene, 1-Ph enyl-2-methyl propyl alcohol + hydrogen peroxide, Phosphorus,
Phosphorus isocyanate, Picrates, Potassium tert-butoxide, Potassium chlorate, Potassium Permanganate
and other permanganates, halogens, amines, Potassium Permanganate + Potassium chloride, Potassium
Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silver
permanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric
acid, Vinyl acetate, Thalium (1) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates,
cyanides, sulfides, sulfites, alkali hydrides, carboxylic acid anhydrides, nitriles, olefinic organics, aqueous
acids, cyclopentadiene, cyano-alcohols, metal acetylides, Hydrogen gas is generated by the action of the
acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentrated sulfuric acid oxidizes,
dehydrates, or sulfonates most organic compounds.
Special Remarks on Corrosivity:
Non -corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing
hydrogen. Minor
corrosive effect on bronze. No corrosion data on brass or zinc.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR
EXPOSURE. Acute oral toxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3
2 hours [Mouse].
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified
A2 (Suspected for human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart,
cardiovascular system, upper respiratory tract, eyes, teeth.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact
Page 6 of 8

(corrosive, irritant, permeator), of eye contact (corrosive), of ingestion..
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse
reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a
dose of 20 mg/m3 for 7 hrs.(RTECS)
Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses
producing some maternal toxicity.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can
cause tissue necrosis.
Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if
swallowed. May cause permanent damage to the digestive tract. Causes gastrointestial tract burns. May
cause perforation of the stomach, GI bleeding, edema of the glottis, necrosis and scarring, and sudden
circulatory collapse(similar to acute inhalation). It may also cause systemic toxicity with acidosis.
Inhalation: May cause severe irritation of the respiratory tract and mucous membranes with sore throat,
coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratory
tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect
cardiovascular system (hypotension, depressed cardiac output, bradycardia). Circulatory collapse with
clammy skin, weak and rapid pulse, shallow respiration, and scanty urine may follow. Circulatory shock is
often the immediate cause of death. May also affect teeth(changes in teeth and supporting structures -
erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalation
may affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and
cardiovascular system, heart (ischemic heart leisons), and respiratory system/lungs(pulmonary edema,
lung damage), teeth (dental discoloration, erosion).
Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.
Section 12: Ecological Information
Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/I 48 hours [bluegill/sunfish].
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the
product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar
material. It may also be diluted and neutralized. Waste must be disposed of in accordance with federal,
state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Class 8: Corrosive material
Identification:: Sulfuric acid UNNA: 1830 PG: II
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:
Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric
acid Rhode Island RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota:
Page 7 of 8

Sulfuric acid Massachusetts RTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of
Hazardous Substances (8 CCR 339): Sulfuric acid Tennessee RTK: Sulfuric acid TSCA 8(b) inventory:
Sulfuric acid SARA 302/304/311/312 extremely hazardous substances: Sulfuric acid SARA 313 toxic
chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:
Sulfuric acid: 1000 lbs. (453.6 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
DSCL (EEC):R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact
with eyes, rinse immediately with plenty of water and seek medical advice. S30- Never add water to this
product. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
Personal Protection:
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 2
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Face shield.
Section 16: Other Information
References:
-Material safety data sheet emitted by: The Sigma -Aldrich Library of Chemical Safety Data, Edition II. -
Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold,
1987.
Created: 10/10/2005 12:15 PM
Last Updated: 12/2015
The information above is believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their
own investigations to determine the suitability of the information for their particular purposes. In no event
shall Paramount Chemicals & Plastics, Inc. be liable for any claims, losses, or damages of any third party
or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if Paramount Chemicals & Plastics, Inc. has been advised of the possibility of such
damages.
Page 8 of 8

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208 -Energizing chemistry
Version Revision Date: SDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
SECTION 1. IDENTIFICATION
Product name : LEWATIT MDS TP 208
Material number : 56814470
Recommended use : Ion exchange, resins and catalysts
Manufacturer or supplier's details
Supplier LANXESS Corporation
Product Safety & Regulatory Affairs
111 RIDC Park West Drive
PittsburghPA 15275-1112
USA
Telephone +1800LANXESS
[phone] (international)
Emergency telephone CHEMTREC [phone]
International [phone]
Lanxess Emergency Phone [phone]
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200).
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Hazard Not Otherwise Classified (HNOC)
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Chemical nature styrene-divinylbenzene-copolymer with iminodiacetic acid
groups in form of salt
Hazardous ingredients
No hazardous ingredients
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
1/10
Print Date: 12/14/2020

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208-Erergizing chemistry
Version Revision Date: SDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
Do not leave the victim unattended.
Show this safety data sheet to the doctor in attendance.
If inhaled Remove victim to fresh air and keep at rest in a position com-
fortable for breathing.
Keep respiratory tract clear.
If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained per-
sonnel.
Maintain open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention if symptoms occur.
In case of skin contact Wash off with soap and plenty of water.
Remove contaminated clothing and shoes.
Get medical attention if symptoms occur.
In case of eye contact Get medical attention if symptoms appear.
If swallowed Rinse mouth with water.
Give small amounts of water to drink.
Never give anything by mouth to an unconscious person.
Get medical attention if symptoms appear.
Most important symptoms and effects, both acute and delayed
Symptoms : No symptoms known or expected.
Protection of first-aiders No action shall be taken involving any personal risk or without
suitable training.
Notes to physician No special actions required.
SECTION 5. FIRE -FIGHTING MEASURES
Suitable extinguishing media Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
In case of fire, use water spray (fog), foam or dry chemical.
Unsuitable extinguishing None known.
media
Specific hazards during fire none
fighting
Hazardous combustion prod- : Carbon monoxide
ucts Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Metal oxides
2/10
Print Date: 12/14/2020

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208 -Energizing Chemistry
Version Revision Date: SIDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
Further information Promptly isolate the scene by removing all persons from the
vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without
suitable training.
Special protective equipment Fire-fighters should wear appropriate protective equipment
for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face -piece operated in positive pressure mode.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : No action shall be taken involving any personal risk or without
tive equipment and emer- suitable training.
gency procedures Do not touch or walk through spilled material.
Put on appropriate personal protection equipment.
Hazard of slipping on spilled product.
Environmental precautions Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for Move containers from spill area.
containment and cleaning up Vacuum or sweep up material and place in a designated, la-
beled waste container.
Do not allow into the sewerage system, surface waters or
groundwater or into the soil.
Dispose of wastes in an approved waste disposal facility.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling Remove contaminated clothing and protective equipment be-
fore entering eating areas.
Workers should wash hands and face before eating, drinking
and smoking.
Put on appropriate personal protection equipment.
Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed.
Conditions for safe storage Store in accordance with local regulations.
Store in original container protected from direct sunlight in a
dry, cool and well -ventilated area, away from incompatible
materials (see Section 10) and food and drink.
Keep containers sealed until ready for use.
Do not store in unlabeled containers.
Take action to prevent static discharges.
3/10
Print Date: 12/14/2020

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208 -Energizing Chemistry
Version Revision Date: SDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
Do not allow to dry.
Further information on stor- It is recommended to store ion exchange resins at tempera -
age stability tures above the freezing point of water. If the resin should
become frozen, the resin should not be mechanically handled
and should be left to thaw out gradually at ambient tempera-
ture. It must be completely thawed before handling or use. No
attempt should be made to accelarate the thawing process.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Engineering measures Good general ventilation should be sufficient to control work-
er exposure to airborne contaminants.
Personal protective equipment
Respiratory protection In the case of dust or aerosol formation use respirator with an
approved filter.
Filter type : P1 filter
Hand protection
Material Polyvinyl chloride - PVC
Wearing time < 60 min
Material Nitrile rubber - NBR
Wearing time < 60 min
Eye protection : Safety glasses with side -shields
Skin and body protection : Wear suitable protective clothing.
Hygiene measures Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period.
Wash contaminated clothing before reusing.
Ensure that eyewash stations and safety showers are close
to the workstation location.
Appropriate techniques should be used to remove potentially
contaminated clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
4/10
Print Date: 12/14/2020

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208 -Energizing Chemistry
Version Revision Date: SIDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
Physical state
solid
Appearance
beads
Color
beige, opaque
Odor
odorless
Odor Threshold
No data available
pH
No data available
Melting point/range
> 392 °F (> 200 °C)
Boiling point/boiling range
No data available
Flash point
No data available
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper explosion limit / Upper
No data available
flammability limit
Lower explosion limit
No data available
Vapor pressure
No data available
Relative vapor density
No data available
Relative density
1.17
Density
1.16 g/cm3 (68 °F (20 °C))
Bulk density
663 - 735 kg/m3
Solubility(ies)
Water solubility
insoluble
Partition coefficient: n-
No data available
octanol/water
Ignition temperature
> 572 °F (> 300 °C)
Decomposition temperature No data available
Viscosity No data available
5/10
Print Date: 12/14/2020

SAFETY DATA SHEET
LEWATIT MDS TP 208
Version Revision Date
2.0 12/05/2020
Explosive properties
Oxidizing properties
SDS Number:
103000009461
No data available
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Possibility of hazardous reac-
tions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
LANXESS
Energizing Chemistry
Date of previous issue: 11/26/2017
Country / Language: US / EN
No specific test data related to reactivity available for this
product or its ingredients.
The product is chemically stable.
No dangerous reaction known under conditions of normal use.
Auto -flammability
No specific data.
Strong oxidants, e.g. nitric acid, can cause violent reactions if
they come into contact with ion exchange resins.
No decomposition if stored normally.
SECTION 11. TOXICOLOGICAL INFORMATION
The most important known symptoms and effects are described in Section 2 and/or Section 4.
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity LD50 (Rat): > 5,000 mg/kg
Remarks: Test results on an analogous product
Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Remarks: Test results on an analogous product
Serious eye damage/eye irritation
Not classified based on available information.
Product:
Result: No eye irritation
Remarks: Test results on an analogous product
6/10
Print Date: 12/14/2020

SAFETY DATA SHEET
LEWATIT MDS TP 208
Version Revision Date: SDS Number:
2.0 12/05/2020 103000009461
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
LANXESS
Energizing Chemistry
Date of previous issue: 11/26/2017
Country / Language: US / EN
Carcinogenicity
Not classified based on available information.
IARC No ingredient of this product present at levels greater than or
equal to 0.1 % is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1 % is on OSHA's list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1 % is identified as a known or anticipated carcinogen
by NTP.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks: According to our experience and information the product has no harmful effects on
health if properly handled.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
7/10
Print Date: 12/14/2020

SAFETY DATA SHEET
LEWATIT MDS TP 208
Version Revision Date: SIDS Number:
2.0 12/05/2020 103000009461
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
LANXESS
Energizing Chemistry
Date of previous issue: 11/26/2017
Country / Language: US / EN
Product:
Adsorbed organic bound Remarks: The product does not contain organically bounded
halogens (AOX) halogens which could lead to an AOX value in waste water.
Additional ecological infor- No known significant effects or critical hazards.
mation
The product is insoluble in water. Therefore, ecological tests
have not been conducted.
SECTION 13. DISPOSAL CONSIDERATIONS
RCRA - Resource Conserva- : If discarded in its purchased form, this product would not be a
tion and Recovery Authoriza- hazardous waste either by listing or by characteristic. Howev-
tion Act er, under RCRA, it is the responsibility of the product user to
determine at the time of disposal, whether a material contain-
ing the product or derived from the product should be classi-
fied as a hazardous waste. (40 CFR 261.20-24)
Disposal methods The generation of waste should be avoided or minimized
wherever possible.
Dispose of wastes in an approved waste disposal facility.
This material and its container must be disposed of in a safe
way.
The product should not be allowed to enter drains, water
courses or the soil.
Waste disposal should be in accordance with existing federal,
state, provincial and/or local environmental controls.
SECTION 14. TRANSPORT INFORMATION
Domestic regulation
DOT
Not regulated as a dangerous good
Further information for If packagings larger than 3 m3: dangerous good of division
transport 4.2.
8/10
Print Date: 12/14/2020

SAFETY DATA SHEET LAN
XESS
LEWATIT MDS TP 208 -Energizing Chemistry
Version Revision Date: SIDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
International Regulations
IATA-DGR
Not regulated as a dangerous good
IATA (Cargo)
Further information for If packagings larger than 3 m3: dangerous good of division 4.2.
transport
IATA (Passenger)
Further information for If packagings larger than 3 m3: dangerous good of division 4.2.
transport
IMDG-Code
Not regulated as a dangerous good
Further information for If packagings larger than 3 m3: dangerous good of division
transport 4.2.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
CERCLA
None
Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : No SARA Hazards
SARA 313
This material does not contain any chemical components with known CAS numbers that exceed
the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
Massachusetts Right To Know
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know
Acetic acid, chloro-, reaction products with ami- 135620-93-8 50 - 60
nomethylated divinylbenzene-
ethenyl ethyl benzene -styrene polymer, sodium
salts
water 7732-18-5 40 - 50
9/10
Print Date: 12/14/2020

SAFETY DATA SHEET LANXESS
LEWATIT MDS TP 208 -Energizing chemistry
Version Revision Date: SIDS Number: Date of previous issue: 11/26/2017
2.0 12/05/2020 103000009461 Country / Language: US / EN
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth
defects, or any other reproductive defects.
TSCA inventory
TSCA
On TSCA Inventory
TSCA list
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
SECTION 16. OTHER INFORMATION
Further information
NFPA:
Flammability
L �
N O iS
HMIS® IV:
HMIS® ratings are based on a 0-4 rating
scale, with 0 representing minimal haz-
Special hazard ards or risks, and 4 representing signifi-
cant hazards or risks. The " " represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.
LANXESS' method of hazard communication is comprised of Product Labels and Safety Data
Sheets. HMIS and NFPA ratings are provided by LANXESS as a customer service.
Revision Date
12/05/2020
This information is furnished without warranty, express or implied. This information is believed to be
accurate to the best knowledge of our knowledge. The information provided in this Safety Data Sheet
(SDS) is correct to the best of our knowledge, information and belief at the date of its publication. We
assume no legal responsibility for use of or reliance upon the information in this SDS.
10 / 10
Print Date: 12/14/2020

V hemTreat,lnc.
SAFETY DA TA SHEET
Section 1. Chemical Product and Company Identification
Product Name:
Product Use:
Supplier's Name:
Emergency Telephone Number:
Address (Corporate Headquarters):
Telephone Number for Information:
Date of MSDS:
Section 2. Hazard(s) Identification
ChemTreat RL9004
Reverse Osmosis Treatment
ChemTreat, Inc.
[phone] (Toll Free)
[phone]
5640 COX ROAD
Glen Allen, VA 23060
[phone]
December 16, 2013
Signal Word: WARNING
Hazard Statement(s): Causes eye irritation.
May be harmful in contact with skin.
May be harmful if inhaled.
Harmful if swallowed.
Precautionary Statement(s): Wash hands thoroughly after handling.
Do not eat, drink, or smoke when using this product.
Section 3. Composition/Hazardous Ingredients
n
Component
I CAS Registry #
I wt.%
2 Phos hono-1,2,4—butane tricarbox lic acid
37971-36-1
13 — 7
Section 4. First Aid Measures
Inhalation: Remove to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or doctor/physician if you feel
unwell.
Eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation
persists, get medical advice/attention.
Skin: Wash with plenty of soap and water. Call a poison center or
doctor/physician if you feel unwell.
ChemTreat RL9004
Page 1

ChemTreat, Inc.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON
CENTER or doctor/physician.
Notes to Physician: N/A
Additional First Aid Remarks: N/A
Section 5. Fire Fighting Measures
Flammability of the Product: Not flammable.
Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.
Specific Hazards Arising from Use water spray to keep containers cool.
the Chemical:
Protective Equipment: If product is involved in a fire, wear full protective clothing
including a positive —pressure, NIOSH approved, self—contained
breathing apparatus.
Section 6. Accidental Release Measures
Personal Precautions: Use appropriate Personal Protective Equipment (PPE).
Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains, and sewers.
Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with water
spray.
Other Statements: If RQ (Reportable Quantity) is exceeded, report to National
Spill Response Office at 1-800-424-8802.
Section 7. Handling and Storage
Handling: Wear appropriate Personal Protective Equipment (PPE) when
handling this product. Do not get in eyes, or on skin and clothing.
Wash thoroughly after handling. Do not ingest. Avoid breathing
vapors, mist or dust.
Storage: Store away from incompatible materials (see Section 10). Store at
ambient temperatures. Keep container securely closed when not in use.
Label precautions also apply to empty container. Recondition or
dispose of empty containers in accordance with government regulations.
ChemTreat RL9004
Page 2

V hemTreat,lnc.
For Industrial use only.
Section 8. Exposure Controls/Personal Protection
Exposure Limits
Component Source Exposure Limits
2—Phosphono-1,2,4—butane tricarboxylic acid N/E
Carcinogenicity Category
Component rmf� L I Source I Code I Brief Description
2—Phosphono-1,2,4—butane tricarboxylic acid I I I NB
Engineering Controls: Use only with adequate ventilation. The use of local ventilation is
recommended to control emission near the source.
Personal Protection
Eyes: Wear chemical splash goggles or safety glasses with full —face
shield. Maintain eyewash fountain in work area.
Skin: Maintain quick —drench facilities in work area.
Wear butyl rubber or neoprene gloves. Wash them after each use and
replace as necessary. If conditions warrant, wear protective clothing
such as boots, aprons, and coveralls to prevent skin contact.
Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual
cartridge respirator with a dust/mist prefilter in accordance with 29
CFR 1910.134.
Section 9. Physical and Chemical Properties
Physical State and Appearance:
Specific Gravity:
pH:
Freezing Point:
Flash Point:
Odor:
Melting Point:
Boiling Point:
Solubility in Water:
Evaporation Rate:
Vapor Density:
Molecular Weight:
Viscosity:
Flammable Limits:
Autoignition Temperature:
Liquid, Dark Straw, Clear
1.233 @ 20°C
9.5 @ 20°C, 100.0%
30OF
N/A
Mild
N/A
N/D
Complete
N/D
N/D
N/D
<100 CPS @ 200C
N/A
N/A
ChemTreat RL9004
Page 3

V hemTreat,/nc_
Density:
Vapor Pressure:
% VOC:
Section 10. Stability and Reactivity
Chemical Stability:
Incompatibility with Various
Substances:
Hazardous Decomposition
Products:
Possibility of Hazardous
Reactions:
10.28 lb/ga
N/D
N/D
Stable at normal temperatures and pressures.
Strong oxidizers, Strong acids
Oxides of carbon, Oxides of nitrogen, Oxides of phosphorus
None known.
Section 11. Toxicological Information
n
Chemical Name
I Exposure
Type of Effect
Concentration
Species
2-Phos hono-1,2,4-butane tricarbox lic acid
I Oral
LD50
>6500 mg/kgmg/kg
Rat
Comments:
None.
Section 12. Ecological Information
Species
Duration
Type of Effect
Test Results
Ceriodaphnia dubia
48h
LC50
982 mg/1
7d
NOEC
375 mg/1
7d
LOEC
750 mg/1
7d
IC25
553 mg/1
Fathead Minnow
96h
LC50
1207 mg/1
7d
NOEC
375 mg/1
7d
LOEC
750 mg/1
7d
IC25
763 mg/1
Comments:
None.
ChemTreat RL9004
Page 4

ChemTreat, Inc.
Section 13. Disposal Considerations
Dispose of in accordance with local, state and federal regulations.
Section 14. Transport Information
DOT
IMDG
ICAO
TDG
Proper Shipping Name: COMPOUND, INDUSTRIAL
Technical Name:
N/A
Hazard Class:
Not D.O.T. Regulated
UN/NA#:
N/A
Packing Group:
N/A
Proper Shipping Name: COMPOUND, INDUSTRIAL
Technical Name:
N/A
Hazard Class:
Not D.O.T. Regulated
UN/NA#:
N/A
Packing Group:
N/A
Proper Shipping Name: COMPOUND, INDUSTRIAL
Technical Name:
N/A
Hazard Class:
Not D.O.T. Regulated
UN/NA#:
N/A
Packing Group:
N/A
Proper Shipping Name: COMPOUND, INDUSTRIAL
Technical Name:
N/A
Hazard Class:
Not D.O.T. Regulated
UN/NA#:
N/A
Packing Group:
N/A
ChemTreat RL9004
WATER TREATMENT, LIQUID
WATER TREATMENT, LIQUID
WATER TREATMENT, LIQUID
WATER TREATMENT, LIQUID
Page 5

V hemTreat,lnc.
Section 15. Regulatory Information
Inventory Status
United States (TSCA):
Canada (DSL/NDSL):
Federal Regulations
SARA Title III Rules
All ingredients listed.
All ingredients listed.
Sections 311/312 Hazard Classes
Fire Hazard:
Reactive Hazard:
Release of Pressure:
Acute Health Hazard:
Chronic Health Hazard:
Other Sections
No
No
No
Yes
No
n
Component
Section 313
Toxic Chemical
Section 302 EHS
TPQ
CERCLA RQ
2—Phosphono-1,2,4—butane tricarbox lic acid
N/A
N/A
N/A
Comments: None.
State Regulations
California Proposition 65:
Special Regulations
None known.
Component
2—Phosnhono-1.2.4—butane tricarboxvlic acid None
International Regulations
Canada
WHMIS Classification:
D2B (Toxic Material)
Controlled Product Regulations This product has been classified in accordance with
(CPR): the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all
the information required by the CPR.
ChemTreat RL9004
Page 6

ChemTreat, Inc.
Section 16. Other Information
HMIS Hazard Rating
Health: 1
Flammability: 0
Physical Hazard: 0
PPE: X
Notes: The PPE rating depends on circumstances of use. See
Section 8 for recommended PPE.
The Hazardous Material Information System (HMIS) is a
voluntary, subjective alpha —numeric symbolic system for
recommending hazard risk and personal protection equipment
information. It is a subjective rating system based on the
evaluator's understanding of the chemical associated risks.
The end —user must determine if the code is appropriate for
their use.
NSF: Certified to NSF/ANSI Standard 60
Maximum use rate for potable water — 15 mg/L
This product ships as NSF from:
Ashland, VA
Eldridge, IA
Nederland, TX
Vernon, CA
FDA/USDA/GRAS: N/A
KOSHER: This product has not been evaluated for Kosher approval.
FIFRA: N/A
Other: None
Abbreviations
Abbreviation
Definition
<
Less Than
>
Greater Than
ACGIH
American Conference of Governmental Industrial Hygienists
EHS
Environmental Health and Safety Dept
N/A
Not Applicable
N/D
Not Determined
N/E
Not Established
OSHA
Occupational Health and Safety Dept
PEL
Personal Exposure Limit
STEL
Short Term Exposure Limit
TLV
I Threshold Limit Value
TWA
I Time Weight Average
ChemTreat RL9004
Page 7

V hemTreat,lnc.
JUNK Unknown
Prepared by: Product Compliance Department;
[e-mail]
Disclaimer
n
Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof,
ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make
their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever
resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or
of any other nature are made hereunder with respect to information or the product to which information refers.
ChemTreat RL9004
Page 8

ChemTreatA
SAFETY DATA SHEET
Section 1. Chemical Product and Company Identification
Product Name:
Product Use:
Supplier's Name:
Emergency Telephone Number:
Address (Corporate Headquarters):
Telephone Number for Information:
Date of SDS:
Revision Date:
Revision Number:
Section 2. Hazard(s) Identification
Signal Word:
GHS Classification(s):
Hazard Statement(s):
Precautionary Statement(s):
DANGER
ChemTreat RL9013
Reverse Osmosis and Resin Cleaner
ChemTreat, Inc.
[phone] (Toll Free)
5640 Cox Road
Glen Allen, VA 23060
[phone]
March 25, 2019
March 25, 2019
19032501 AN
Corrosive to Metals - Category 1
Eye damage/irritation - Category 1
Skin corrosion/irritation - Category 1 b
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
Prevention: P234 Keep only in original container.
P264 Wash thoroughly after handling.
P273 Avoid release into the environment.
P280 Wear protective gloves/protective clothing/eye
protection/face protection.
19032501AN 03/25/19 Page 1 of 10 ChemTreat RL9013

v hemTreat°
Response: P301 + 330 + 331 IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair):
Remove/take off immediately all contaminated clothing.
Rinse skin with water/shower
P304 + P340 + P310 IF INHALED: Remove person
to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or
doctor/physician.
P305 + P351 + P338 IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment, see label.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
Storage: P405 Store locked up.
Disposal: P501 Dispose of contents and container in accordance
with applicable local, regional, national, and/or
international regulations.
System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Hazards Not Otherwise None.
Classified:
Section 3. Composition/Hazardous Ingredients
Component
AS Registry #
MA
Phosphoric acid
7664-38-2
0 - 1.5
Phosphorous acid, ortho
13598-36-2
0 - 4.0
Aminotri(methylenephosphonic acid)
6419-19-8
30 - 60
Comments
If chemical identity and/or exact percentage of composition has been
withheld, this information is considered to be a trade secret.
19032501AN 03/25/19 Page 2 of 10 ChemTreat RL9013

v hemTreat°
Section 4. First Aid Measures
Inhalation:
Eyes:
Skin:
Ingestion:
Most Important Symptoms:
Indication of Immediate
Medical Attention and
Special Treatment Needed, If
Necessary:
Remove to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or doctor/physician if you feel
unwell.
Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately
call a poison center or doctor/physician.
Immediately remove/take off all contaminated clothing. Rinse skin
with water/shower. Wash contaminated clothing before re -use.
Immediately call a poison center or doctor/physician.
DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON
CENTER or doctor/physician if you feel unwell.
NE
N/A
Section 5. Fire Fighting Measures
Flammability of the Product:
Suitable Extinguishing Media:
Specific Hazards Arising from
the Chemical:
Protective Equipment:
Not flammable.
Use extinguishing media suitable to surrounding fire.
Use water spray to keep containers cool.
If product is involved in a fire, wear full protective clothing
including a positive -pressure, NIOSH approved, self-contained
breathing apparatus.
19032501AN 03/25/19 Page 3 of 10 ChemTreat RL9013

v hemTreat°
Section 6. Accidental Release Measures
Personal Precautions: Use appropriate Personal Protective Equipment (PPE).
Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains, and sewers.
Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with
water spray.
Other Statements: If RQ (Reportable Quantity) is exceeded, report to National
Spill Response Office at 1-800-424-8802.
Section 7. Handling and Storage
Handling: Wear appropriate Personal Protective Equipment (PPE) when
handling this product. Do not get in eyes, or on skin and clothing.
Wash thoroughly after handling. Do not ingest. Avoid breathing
vapors, mist or dust.
Storage: Store away from incompatible materials (see Section 10). Store
at ambient temperatures. Keep container securely closed when not in
use. Label precautions also apply to empty container. Recondition
or dispose of empty containers in accordance with government
regulations. For Industrial use only.
Do not freeze. Store above Freeze Point. If freezes, then
mechanical mixing is required.
Section S. Exposure Controls/Personal Protection
Exposure Limits
Component
Source
Exposure Limits
Phosphoric acid
ACGIH TLV
3 mg/m3 STEL
OSHA PEL
1 mg/m3 TWA
Phosphorous acid, ortho
N/E
N/E
Aminotri(methylenephosphonic acid)
N/E
N/E
Engineering Controls:
Use only with adequate ventilation. The use of local ventilation is
recommended to control emission near the source.
19032501AN 03/25/19 Page 4 of 10 ChemTreat RL9013

v hemTreat° 46 ph
Personal Protection
Eyes: Wear chemical splash goggles or safety glasses with
full -face shield. Maintain eyewash fountain in work area.
Skin: Maintain quick -drench facilities in work area.
Wear butyl rubber or neoprene gloves. Wash them after
each use and replace as necessary. If conditions warrant,
wear protective clothing such as boots, aprons, and
coveralls to prevent skin contact.
Respiratory: If misting occurs, use NIOSH approved organic vapor/acid
gas dual cartridge respirator with a dust/mist prefilter in
accordance with 29 CFR 1910.134.
Section 9. Physical and Chemical Properties
Physical State and Appearance:
Liquid, Colorless, Clear
Specific Gravity:
1.076 @ 20°C
pH:
<2.0 @ 20°C, 100.0%
Freezing Point:
39.2°F
Flash Point:
N/A
Odor:
Odorless
Melting Point:
N/D
Initial Boiling Point and Boiling Range:
2260F
Solubility in Water:
Miscible
Evaporation Rate:
N/D
Vapor Density:
N/D
Molecular Weight:
N/D
Viscosity:
<100 CPS @ 200C
Flammability (solid, gas):
N/D
Flammable Limits:
N/A
Autoignition Temperature:
N/A
Density:
8.97 LB/GA
Vapor Pressure:
N/D
% VOC:
-50
Odor Threshold
N/D
n-octanol Partition Coefficient
N/D
Decomposition Temperature
N/D
19032501AN 03/25/19 Page 5 of 10 ChemTreat RL9013

v hemTreat°
Section 10. Stability and Reactivity
Chemical Stability:
Incompatibility with Various
Substances:
Hazardous Decomposition
Products:
Possibility of Hazardous
Reactions:
Reactivity:
Conditions To Avoid:
Stable at normal temperatures and pressures.
Strong oxidizers, Strong Alkalis, Strong bases, Metals or metal
oxides.
Oxides of carbon, Oxides of phosphorus, Acids of phosphorous.
None known.
N/D
N/D
Section 11. Toxicological Information
Acute Toxicity
Chemical Name
Exposure
Type of Effect
Concentration
Species
Phosphoric acid
Dermal
LD50
2740 MG/KG
Rabbit
Oral
LD50
1530 MG/KG
Rat
ChemTreat RL9013
N/D
N/D
N/D
N/D
Carcinogenicity Category
Component
Source
Code
Brief Description
Phosphoric acid
N/E
N/E
N/E
Phosphorous acid, ortho
N/E
N/E
N/E
Aminotri(methylenephosphonic acid)
N/E
N/E
N/E
Likely Routes of Exposure:
N/D
Symptoms
Inhalation:
N/D
Eye Contact:
N/D
Skin Contact:
N/D
Ingestion:
N/D
19032501AN 03/25/19 Page 6 of 10 ChemTreat RL9013

v hemTreat°
Skin Corrosion/Irritation:
N/D
Serious Eye Damage/Eye
N/D
Irritation:
Sensitization:
N/D
Germ Cell Mutagenicity:
N/D
Reproductive/Developmental
N/D
Toxicity:
Specific Target Organ Toxicity
Single Exposure:
Repeated Exposure:
Aspiration Hazard:
N/D
Comments:
None.
N/D
N/D
Section 12. Ecological Information
Ecotoxicity
Species
Duration
Type of Effect
Test Results
Fathead Minnow
96h
LC50
>10000 mg/1
Ceriodaphnia dubia
48h
LC50
2500 mg/1
Persistence and
N/D
Biodegradability:
Bioaccumulative Potential:
N/D
Mobility In Soil:
N/D
Other Adverse Effects:
N/D
Comments:
None.
19032501AN 03/25/19 Page 7 of 10 ChemTreat RL9013

ChemTreat° 46 ph
Section 13. Disposal Considerations
Dispose of in accordance with local, state and federal regulations.
EPA corrosivity characteristic hazardous waste D002 when disposed of in the original product form.
Section 14. Transport Information
Controlling
Packing
Regulation
UNMAM
Proper Shipping Name:
Technical Name:
Hazard Class:
Group:
DOT
UN3265
CORROSIVE LIQUID, ACIDIC,
(AMINO-
8
PGIII
ORGANIC, N.O.S.
TRI(METHYLENEPHOSPHONIC
ACID))
Note:
N/A
Section 15. Regulatory Information
Inventory Status
United States (TSCA):
Canada (DSL/NDSL):
Federal Regulations
SARA Title III Rules
Sections 311/312 Hazard
Classes
Fire Hazard:
Reactive Hazard:
Release of Pressure:
Acute Health Hazard:
Chronic Health Hazard:
Other Sections
All ingredients listed.
All ingredients listed.
No
No
No
Yes
No
Component
Section 313
Toxic Chemical
Section 302 EHS
TPQ
CERCLA RQ
Phosphoric acid
No
N/A
5000
Phosphorous acid, ortho
N/A
N/A
N/A
Aminotri(methylenephosphonic acid)
N/A
N/A
N/A
19032501AN 03/25/19 Page 8 of 10 ChemTreat RL9013

v hemTreat°
Comments:
State Regulations
California Proposition 65:
Special Regulations
None known.
None.
Component
States
Phosphoric acid
MA, MN, NY, WA
Phosphorous acid, ortho
None.
Aminotri(methylenephosphonic acid)
None.
Compliance Information
NSF:
Food Regulations:
KOSHER:
Halal:
FIFRA:
Other:
Comments:
None.
Section 16. Other Information
HMIS Hazard Rating
N/A
N/A
This product has not been evaluated for Kosher approval.
This product has not been evaluated for Halal approval.
N/A
None
Health: 3
Flammability: 0
Physical Hazard: 1
PPE: X
Notes: The PPE rating depends on circumstances of use. See
Section 8 for recommended PPE.
The Hazardous Material Information System (HMIS) is a
voluntary, subjective alpha -numeric symbolic system for
recommending hazard risk and personal protection equipment
information. It is a subjective rating system based on the
evaluator's understanding of the chemical associated risks.
The end -user must determine if the code is appropriate for
their use.
19032501AN 03/25/19 Page 9 of 10 ChemTreat RL9013

ChemTreat"
Abbreviations
Abbreviation
<
Definition
Less Than
>
Greater Than
ACGIH
American Conference of Governmental Industrial Hygienists
EHS
Environmental Health and Safety Dept
N/A
Not Applicable
N/D
Not Determined
N/E
Not Established
OSHA
Occupational Health and Safety Dept
PEL
Personal Exposure Limit
STEL
Short Term Exposure Limit
TLV
Threshold Limit Value
TWA
Time Weight Average
UNK
Unknown
Prepared by: Product Compliance Department; [e-mail]
Revision Date: March 25, 2019
Disclaimer
Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date
hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving
same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any
nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for
a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.
19032501AN 03/25/19 Page 10 of 10 ChemTreat RL9013

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.16.2014 Page 1 of 7
Sodium Bisulfate
SECTION 1 : Identification of the substance/mixture and of the supplier
Product name: Sodium Bisulfate
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25535A
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331
Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053
SECTION 2 : Hazards identification
Classification of the substance or mixture
0Corrosive
■ Irritant
Serious eye damage ( Category 1 )
Signal word :Danger
Hazard statements:
Causes serious eye damage
Causes severe skin burns and eye damage
May cause respiratory irritation
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Do not eat, drink or smoke when using this product
Combustible Dust Hazard: :
May form combustible dust concentrations in air (during processing).
Other Non-GHS Classification:
WHMIS

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.16.2014 Page 2 of 7
Sodium Bisulfate
NFPA/HMIS
NFPA SCALE (0-4) HMIS RATINGS (0-4)
SECTION 3 : Composition/Information on ingredients
Ingredients:
CAS 10034-88-5 Sodium bisulfate monohydrate 100 %
Percentages are by weight
SECTION 4 : First aid measures
Description of first aid measures
After inhalation: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give
oxygen.Move exposed individual to fresh air. Loosen clothing as necessary and position individual in a
comfortable position.Seek medical advice if discomfort or irritation persists.lf breathing difficult, give oxygen.
After skin contact: Flush with water for 15 minutes. Get medical assistance if irritation develops.Wash
affected area with soap and water. Rinse thoroughly. Seek medical attention if irritation, discomfort or vomiting
persists.
After eye contact: Immediately flush eyes with water for at least 15 minutes. Immediately get medical
assistance. Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes. Remove
contact lens(es) if able to do so during rinsing. Seek medical attention if irritation persists or if concerned.
After swallowing: Do NOT induce vomiting. Dilute with water. Get medical assistance. Rinse mouth
thoroughly. Do not induce vomiting. Have exposed individual drink sips of water. Seek medical attention if
irritation, discomfort or vomiting persists.
Most important symptoms and effects, both acute and delayed:
Irritation, Nausea, Headache, Shortness of breath.;
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention, provide SDS document to physician.
SECTION 5 : Firefighting measures
Extinguishing media
Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures. Use

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev
Effective date : 12.16.2014 Page 3 of 7
Sodium Bisulfate
appropriate fire suppression agents for adjacent combustible materials or sources of ignition
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Combustion products may include carbon oxides or other toxic vapors.Thermal decomposition can lead to
release of irritating gases and vapors.Avoid generating dust; fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Advice for firefighters:
Protective equipment: Use NIOSH-approved respiratory protection/breathing apparatus.
Additional information (precautions): Move product containers away from fire or keep cool with water
spray as a protective measure, where feasible.Use spark -proof tools and explosion -proof equipment.
SECTION 6 : Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Transfer to a disposal or recovery container.Use spark -proof tools and explosion -
proof equipment.Use respiratory protective device against the effects of fumes/dust/aerosol. Keep unprotected
persons away. Ensure adequate ventilation. Keep away from ignition sources. Protect from heat.Stop the spill, if
possible. Contain spilled material by diking or using inert absorbent.
Environmental precautions:
Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13
Methods and material for containment and cleaning up:
If in a laboratory setting, follow Chemical Hygiene Plan procedures.Collect liquids using vacuum or by use of
absorbents. Place into properly labeled containers for recovery or disposal. If necessary, use trained response
staff/contractor. Dust deposits should not be allowed to accumulate on surfaces, as these may form an
explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in
the air (i.e., clearing dust surfaces with compressed air).
Reference to other sections:
SECTION 7 : Handling and storage
Precautions for safe handling:
Minimize dust generation and accumulation. Wash hands after handling. Avoid dispersal of dust in the air (i.e.,
clearing dust surfaces with compressed air). Routine housekeeping should be instituted to ensure that dusts do
not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of
transfer and mixing operations. Follow good hygiene procedures when handling chemical materials. Do not eat,
drink, smoke, or use personal products when handling chemical substances. If in a laboratory setting, follow
Chemical Hygiene Plan.Use only in well ventilated areas.Avoid generation of dust or fine particulate.Avoid
contact with eyes, skin, and clothing.
Conditions for safe storage, including any incompatibilities:
Store in a cool location. Provide ventilation for containers. Avoid storage near extreme heat, ignition sources or
open flame. Store away from foodstuffs. Store away from oxidizing agents.Store in cool, dry conditions in well
sealed containers. Keep container tightly sealed.
SECTION 8 : Exposure controls/personal protection
:7� f

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev
Effective date : 12.16.2014 Page 4 of 7
Sodium Bisulfate
Control Parameters:
10034-88-5, Sodium bisulfate monohydrate, Contains no substances with
occupational exposure limit values
Appropriate Engineering controls:
Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/hand ling. Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
or dusts (total/respirable) below the applicable workplace exposure limits
(Occupational Exposure Limits-OELs) indicated above.Use under a fume
hood. It is recommended that all dust control equipment such as local
exhaust ventilation and material transport systems involved in handling
of this product contain explosion relief vents or an explosion suppression
system or an oxygen deficient environment.Ensure that dust -handling
systems (such as exhaust ducts, dust collectors, vessels, and processing
equipment) are designed in a manner to prevent the escape of dust into
the work area (i.e., there is no leakage from the equipment).
Respiratory protection:
Not required under normal conditions of use. Use suitable respiratory
protective device when high concentrations are present. Use suitable
respiratory protective device when aerosol or mist is formed. For spills,
respiratory protection may be advisable.
Protection of skin:
The glove material has to be impermeable and resistant to the product/
the substance/ the preparation being used/handled.Selection of the glove
material on consideration of the penetration times, rates of diffusion and
the degradation.
Eye protection:
Safety glasses with side shields or goggles.
General hygienic measures:
The usual precautionary measures are to be adhered to when handling
chemicals. Keep away from food, beverages and feed sources.
Immediately remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work. Do not inhale
gases/fumes/dust/mist/vapor/aerosols. Avoid contact with the eyes and
skin.
SECTION 9 : Physical and chemical properties 1
Appearance (physical
Colorless Crystals.
Explosion limit lower:
Not Determined
state,color):
Explosion limit upper:
Not Determined
Odor:
Odorless
Vapor pressure:
Not Determined
Odor threshold:
Not Determined
Vapor density:
Not Determined
pH -value:
—1
Relative density:
Not Determined
Melting/Freezing point:
183C
Solubilities:
Soluble in Water
Boiling point/Boiling
Decomposes
Partition coefficient (n-
Not Determined
range:
octanol/water):
Flash point (closed
Not Determined
Auto/Self-ignition
Not Determined
cup):
temperature:
Evaporation rate:
Not Determined
Decomposition
430C
temperature:
Flammability
Not Determined
Viscosity:
a. Kinematic:Not Determined
(solid,gaseous):
b. Dynamic: Not Determined
Density: Not Determined

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.16.2014 Page 5 of 7
Sodium Bisulfate
SECTION 10 : Stability and reactivity
Reactivity:
Chemical stability:table under normal temperatures and pressures. Hygroscopic.No decomposition if used and
stored according to specifications.
Possible hazardous reactions:
Conditions to avoid:Store away from oxidizing agents, strong acids or bases.
Incompatible materials: Strong bases, Strong oxidizing agents. Strong acids.Strong bases.
Hazardous decomposition products:Sulphur oxides, Sodium oxides. Carbon oxides (CO, CO2).
SECTION it : Toxicological information
Acute Toxicity: No additional information.
Chronic Toxicity: No additional information.
Corrosion Irritation: No additional information.
Sensitization:
No additional information.
Single Target Organ (STOT):
No additional information.
Numerical Measures:
No additional information.
Carcinogenicity:
No additional information.
Mutagenicity:
No additional information.
Reproductive Toxicity:
No additional information.
SECTION 12 : Ecological information
Ecotoxicity Persistence and degradability: Readily degradable in the environment.
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
SECTION 13 : Disposal considerations
Waste disposal recommendations:
Product/containers must not be disposed together with household garbage. Do not allow product to reach
sewage system or open water.lt is the responsibility of the waste generator to properly characterize all waste
materials according to applicable regulatory entities (US 40CFR262.11). Consult federal state/ provincial and
local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.
SECTION 14 : Transport information
UN -Number
3260
UN proper shipping name
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Transport hazard class(es)

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.16.2014 Page 6 of 7
Sodium Bisulfate
Class:
8 Corrosive substances
Packing group:lll
Environmental hazard:
Transport in bulk:
Special precautions for user:
SECTION 15 : Regulatory information
United States (USA)
SARA Section 311/312 (Specific toxic chemical listings):
None of the ingredients is listed
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed
Proposition 65 (California):
Chemicals known to cause cancer:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed
Canada
Canadian Domestic Substances List (DSL):
All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed
SECTION 16 : Other information
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations. Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct

Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 12.16.2014 Page 7 of 7
Sodium Bisulfate
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.lt is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No -Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No -Effect Level (REACH)
Effective date: 12.16.2014
Last updated : 03.19.2015

SAFETY DATA SHEET LANXESS
Energizing Chemistry
Section 1. Identification
Product identifier
Antimicrobial N-20
Material Number
57075848
Chemical family
brominated amine
EPA Registration Number:
39967-103
Identified uses
Pesticide.
Supplier/Manufacturer
LANXESS Corporation
Product Safety & Regulatory Affairs
111 RIDC Park West Drive
Pittsburgh, PA 15275-1112
USA
For information: US/Canada (800) LANXESS
International [phone]
In case of emergency Chemtrec [phone]
International [phone]
Lanxess Emergency Phone [phone].
Section 2. Hazards identification
HAZCOM Standard Status This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Physical state Liquid.
Color Colorless. to Brown.
Classification of the ACUTE TOXICITY (oral) - Category 4
substance or mixture ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SKIN SENSITIZATION. - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
Hazard pictograms
ti7y U N '
•
Signal word
Hazard statements
Hazard Not Otherwise
Classified (HNOC)
Precautionary statements
Prevention
Danger
Harmful if swallowed or if inhaled. Causes serious eye damage. Causes skin irritation.
May cause an allergic skin reaction. May cause respiratory irritation. May cause
drowsiness and dizziness.
None known.
Wear protective gloves and eye/face protection. Use only in a well -ventilated area.
Avoid breathing vapor. Do not eat, drink or smoke when using this product. Wash hands
thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace.
Antimicrobial N-20 57075848 Version 3 1/10

Section 2. Hazards identification
Response
Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. IF SWALLOWED: Rinse mouth. IF
ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash
contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get
medical attention immediately.
Storage
Store locked up.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
Store in original container protected from direct sunlight in a dry, cool and well -ventilated
elements
area, away from incompatible materials and food and drink.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Ingredient name
%
CAS number
2,2-Dibromo-3-nitrilopropionamide - DBNPA
17 - 23%
10222-01-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of first aid measures
Eye contact Get medical attention immediately. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids. Check for and remove any contact
lenses. Continue to rinse for at least 10 minutes. In case of contact with eyes, flush eyes
with plenty of water for at least 30 minutes. Chemical burns must be treated promptly
by a physician.
Inhalation Get medical attention immediately. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours. If not breathing, if breathing is irregulor or respiratory arrest
occurs, provide artifical respiration, or oxygen by a trained professional, using a pocket
type respirator.
Skin contact In case of contact, flush skin with plenty of water for at least 30 minutes. Get medical
attention immediately. Immediately remove contaminated clothing and shoes. Wash
with plenty of soap and water. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. In the event of any complaints or symptoms, avoid further
exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion Get medical attention immediately. Wash out mouth with water. Remove victim to fresh
air and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Chemical
burns must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Potential acute health effects
Antimicrobial N-20 57075848 Version 3 2110

Section 4. First aid measures
Eye contact
Causes serious eye damage. No known significant effects or critical hazards.
Inhalation
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
respiratory irritation.
Skin contact
Causes skin irritation. May cause an allergic skin reaction.
Ingestion
Harmful if swallowed. May cause burns to mouth, throat and stomach.
Over -exposure signs/symptoms
Eye contact
Corrosive with symptoms of reddening, tearing, swelling, burning and possible
permanent damage.
Inhalation
May cause adverse respiratory effects including cough, tightness of chest and
shortness of breath.
May cause respiratory tract irritation with symptoms of coughing, sore throat and runny
nose.
May cause nervous system effects which can include symptoms of dizziness,
incoordination, headache, numbness, and/or confusion.
Skin contact
Corrosive with symptoms of reddening, itching, swelling, burning and possible
permanent damage.
Causes irritation with symptoms of reddening, itching, and swelling.
Once sensitized, an allergic skin reaction may occur with reddening, swelling, and rash
when subsequently exposed to very low levels.
Ingestion
Corrosive with symptoms of coughing, burning, ulceration, and pain.
Symptoms of ingestion may include abdominal pain, nausea, vomiting, and diarrhea.
May cause nervous system effects which can include symptoms of dizziness,
incoordination, headache, numbness, and/or confusion.
Potential chronic health effects
Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
Notes to physician Treat symptomatically. No specific treatment.
Protection of first-aiders If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire -fighting measures
Extinguishing media
Suitable extinguishing Use an extinguishing agent suitable for the surrounding fire. In case of fire, use water
media spray (fog), foam or dry chemical.
Unsuitable extinguishing None known.
media
Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst. Toxic
from the chemical and irritating gases/fumes may be given off during burning or thermal decomposition.
Water runoff from fire fighting may be corrosive.
Hazardous thermal Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode.
Antimicrobial N-20 57075848 Version 3 3110

Section 6. Accidental release measures
Personal precautions, No action shall be taken involving any personal risk or without suitable training.
protective equipment and Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
emergency procedures entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release from upwind.
containment and cleaning up Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see Section
1 for emergency contact information and Section 13 for waste disposal. Prevent entry
into sewers, water courses, basements or confined areas.
Section 7. Handling and storage
Precautions for safe handling
Protective measures Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container. Remove contaminated
clothing and protective equipment before entering eating areas. Workers should wash
hands and face before eating, drinking and smoking. Put on appropriate personal
protection equipment. Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Persons with a history of skin
sensitization to this product should not be employed in any process in which this product
is used.
Conditions for safe storage : Do not store above the following temperature: 35°C (95T). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well -ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Section 8. Exposure controls/personal protection
Occupational exposure limits
No exposure limit value known.
Appropriate engineering Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Personal protection
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Contaminated
work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to the
workstation location.
Respiratory protection A NIOSH approved air purifying respirator with organic vapor cartridges and particulate
prefilter must be used to minimize exposure.
Antimicrobial N-20 57075848 Version 3 4110

Section 8. Exposure controls/personal protection
Skin protection Use chemical -resistant, impervious gloves. Recommended: nitrile rubber, neoprene
rubber, Polyvinyl chloride - PVC
Eye/face protection Tight fitting chemical goggles (non -vented)
Medical Surveillance Not available.
Section 9. Physical and chemical properties
Physical state
Liquid.
Color
Colorless. to Brown.
Odor
Mild.
Odor threshold
Not available.
pH
1.5 to 5
Boiling point
>70 °C (1013 hPa)
Melting point
Not available.
Flash point
Closed cup: >100°C (>212°F)
Open cup: >=182°C (>=359.6°F) [Cleveland.]
Evaporation rate
Not available.
Explosion limits
Not available.
Vapor pressure
25.2 hPa (25°C)
Specific gravity (Relative
1.25 to 1.3
density)
Partition coefficient: n-
Not available.
octanol/water
Vapor density
Not available.
Viscosity
Not available.
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Section 10. Stability and reactivity
Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
The product is stable.
Possibility of hazardous
Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid
No specific data.
Incompatible materials
No specific data.
Hazardous decomposition
Under normal conditions of storage and use, hazardous decomposition products should
products
not be produced.
Section 11. Toxicological information
Information on the likely Dermal contact. Eye contact. Inhalation. Ingestion.
routes of exposure
Potential acute health effects
Eye contact Causes serious eye damage. No known significant effects or critical hazards.
Inhalation Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
respiratory irritation.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Ingestion Harmful if swallowed. May cause burns to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact Corrosive with symptoms of reddening, tearing, swelling, burning and possible
permanent damage.
Antimicrobial N-20 57075848 Version 3 5110

Section 11. Toxicological information
Inhalation
May cause adverse respiratory effects including cough, tightness of chest and shortness
of breath.
May cause respiratory tract irritation with symptoms of coughing, sore throat and runny
nose.
May cause nervous system effects which can include symptoms of dizziness,
incoordination, headache, numbness, and/or confusion.
Skin contact
Corrosive with symptoms of reddening, itching, swelling, burning and possible
permanent damage.
Causes irritation with symptoms of reddening, itching, and swelling.
Once sensitized, an allergic skin reaction may occur with reddening, swelling, and rash
when subsequently exposed to very low levels.
Ingestion
Corrosive with symptoms of coughing, burning, ulceration, and pain.
Symptoms of ingestion may include abdominal pain, nausea, vomiting, and diarrhea.
May cause nervous system effects which can include symptoms of dizziness,
incoordination, headache, numbness, and/or confusion.
Potential chronic health effects
Short term exposure
Potential immediate
Not available.
effects
Long term exposure
Potential delayed effects
Not available.
General
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Developmental effects
No known significant effects or critical hazards.
Fertility effects
No known significant effects or critical hazards.
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Test
Antimicrobial N20
LD50 Oral
Rat
500 mg/kg
-
-
Antimicrobial N20
LD50 Dermal
Rabbit
>2000 mg/kg
-
-
Antimicrobial N20
LC50
Rat
1.25 mg/I
4 hours
-
Inhalation
Dusts and
mists
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Sensitization
2,2-Dibromo-3-nitrilopropionamide - DBNPA:Moderate irritant
2,2-Dibromo-3-nitrilopropionamide - DBNPA:Risk of serious damage to eyes.
Product/ingredient name
Route of
Species
Result
exposure
2,2-Dibromo-
skin
Guinea pig
Sensitizing
3-nitrilopropionamide -
DBNPA
Skin
Sensitizing to the skin in an animal study. *Test results on an analogous product
Chronic toxicity
Antimicrobial N-20 57075848 Version 3 6110

Section 11. Toxicological information
Product/ingredient name
Result
Species
Dose
Exposure
2,2-Dibromo-
Sub -chronic NOEL Oral
Rat
5 mg/kg
90 days; 7 days
3-nitrilopropionamide -
per week
DBNPA
Carcinogenicity
Product/ingredient name
AS #
IARC
NTP
OSHA
2,2-Dibromo-3-nitrilopropionamide -
10222-01-2
Not classified.
Not classified.
Not classified.
DBNPA
Reproductive toxicity
Conclusion/Summary 2,2-Dibromo-3-nitrilopropionamide - DBNPA:Fetotoxicity has been observed in animal
studies
Specific target organ toxicity (single exposure)
Name
Category
Route of
Target organs
exposure
2,2-Dibromo-3-nitrilopropionamide - DBNPA
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name
Category
Route of
Target organs
exposure
2,2-Dibromo-3-nitrilopropionamide - DBNPA
Category 2
Not determined
kidneys
Acute toxicity estimates
Route ATE value (Acute Toxicity Estimates)
Not available.
Section 12. Ecological information
Toxicity
Product/ingredient name
Test
Result
Species
Exposure
Antimicrobial N20
-
Acute EC50 1.5 mg/I Growth
Algae -
96 hours
rate inhibition
Pseudokirchneriella
subcapitata
-
Acute EC50 2.5 mg/I
Daphnia
48 hours
immobilization
-
Acute LC50 3.6 mg/I
Fish -
96 hours
Oncorhynchus
mykiss
Conclusion/Summary
Persistence and degradability
Conclusion/Summary
Bioaccumulative potential
Not available
Mobility in soil
Soil/water partition
coefficient (Koc)
Other adverse effects
Not available.
Not available.
Not available.
No known significant effects or critical hazards.
Antimicrobial N-20 57075848 Version 3 7/10

Section 13. Disposal considerations
Disposal methods The generation of waste should be avoided or minimized wherever possible. This
material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers. Waste disposal
should be in accordance with existing federal state, provincial and or local
environmental controls laws.
RCRA classification : When discarded in its purchased form, this product meets the criteria of corrosivity,
and should be managed as a hazardous waste (EPA Hazardous Waste Number D002).
(40 CFR 261.20-24)
Section 14. Transport information
Regulatory
UN number
Proper shipping
Classes
PG*
Label
Additional
information
name
information
DOT Classification
UN3082
ENVIRONMENTALLY
9
III
8, 146, 173, 335, I133,
HAZARDOUS
T4, TP1, TP29The U.
SUBSTANCE,
S. Department of
LIQUID, N.O.S. (2,
Transportation
2-DIBROMO-
regulations in 49CFR
3-NITRILOPROPIONAMIDE)
172.102 permit this
material to ship as an
Environmentally
Hazardous Substance,
Class 9, using Special
Provision 146.
IMDG Class
UN3082
ENVIRONMENTALLY
9
III
Emergency
HAZARDOUS
schedules (EmS)
SUBSTANCE,
F-A, S-F
LIQUID, N.O.S. (2,
2-DIBROMO-
3-NITRILOPROPIONAMIDE)
IATA-DGR Class
UN3082
ENVIRONMENTALLY
9
III
Passenger aircraft
HAZARDOUS
964: 450 L
SUBSTANCE,
,
LIQUID, N.O.S. (2,
Cargo aircraft
2-DIBROMO-
964: 450 L
3-NITRILOPROPIONAMIDE)
PG* : Packing group
RQ 0 Ibs
Section 15. Regulatory information
SARA 311 /312
SARA Title III Section 302
Extremely Hazardous
Substances
SARA Title III Section 313
Toxic Chemicals
US EPA CERCLA
Hazardous Subtances (40
CFR 302)
Immediate (acute) health hazard
Delayed (chronic) health hazard
None
None
None
Antimicrobial N-20 57075848 Version 3 8110

Section 15. Regulatory information
State regulations
The following chemicals are specifically listed by individual states; other product specific health and safety data in other
sections on the SIDS may also be applicable for state requirements. For details on your regulatory requirements you
should contact the appropraite agency in your state.
Ingredient name CAS number State Code Concentration
2,2-Dibromo-3-nitrilopropionamide - 10222-01-2 NJ - HS 17 - 23%
DBNPA
Polyethylene Glycol 25322-68-3 49 - 55%
Water 7732-18-5 25 - 31 %
Massachusetts Substances: MA - S
Massachusetts Extraordinary Hazardous Substances: MA - Extra HS
New Jersey Hazardous Substances: NJ - HS
Pennsylvania RTK Hazardous Substances: PA - RTK HS
Pennsylvania Special Hazardous Substances: PA - Special HS
California Prop. 65
To the best of our knowledge, this product does not contain any of the listed chemicals, which the state of California has
found to cause cancer, birth defects or other reproductive harm.
U.S. Toxic Substances This product is excluded from TSCA Regulation under FIFRA Section 3 (2)(B)(ii) when
Control Act used as a pesticide.
FIFRA
EPA Registration Number 39967-103
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and
hazard information required for safety data sheets (SDS), and for workplace labels of non -pesticide chemicals. The hazard
information required on the pesticide label is reproduced below. The pesticide label also includes other important
information, including directions for use.
Signal word DANGER
Hazard statements Corrosive. Causes irreversible eye damage and skin burns. Fatal if absorbed through
skin. Harmful if swallowed or if inhaled.
Section 16. Other information
Hazardous Material
Information System
O=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
*=Chronic
The customer is responsible for determining the PPE code for this material. HMIS® ratings are to be used with a
fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association
(NPCA). HMIS® materials may be purchased exclusively from J. J. Keller [phone].
National Fire Protection
Association (U.S.A.)
Flammability
Health 3 1 Instability/Reactivity
Special
0= Minimal 1=Slight 2=Moderate 3=Serious 4=Severe
Antimicrobial N-20 57075848 Version 3 9110

Section 16. Other information
LANXESS' method of hazard communication is comprised of Product Labels and Safety Data Sheets. HMIS and
NFPA ratings are provided by LANXESS as a customer service.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Date of issue 05-19-2015
Date of previous issue 05-15-2015
Version 3
Product Safety and Regulatory Affairs
17 Indicates information that has changed from previously issued version.
Notice to reader
This information is furnished without warranty, express or implied. This information is believed to be accurate to
the best knowledge of LANXESS Corporation. The information in this SDS relates only to the specific material
designated herein. LANXESS Corporation assumes no legal responsibility for use of or reliance upon the
information in this SDS.

+ www.sigmaainriCh.com
Version 6.1
SAFETY DATA SHEET
Revision Date 27.10.2021
Print Date 05.11.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name Sodium molybdate
Product Number 243655
Brand SIGALD
CAS -No. 7631-95-0
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Synthesis of substances
1.3 Details of the supplier of the safety data sheet
Company MilliporeSigma Canada Ltd
2149 WINSTON PARK DRIVE
OAKVILLE ON L6H 6J8
CANADA
Telephone [phone]
Fax [phone]
1.4 Emergency telephone
Emergency Phone #
800-424-9300 CHEMTREC (USA)
[phone] CHEMTREC
(International)
24 Hours/day; 7 Days/week
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Not a hazardous substance or mixture.
2.2 GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
- none
SECTION 3: Composition/information on ingredients
3.1 Substances
Formula MoNa204
SIGALD - 243655
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 1 of 8
mittiploftla
SiGMla

Molecular weight 205.92 g/mol
CAS -No. 7631-95-0
EC -No. 231-551-7
No components need to be disclosed according to the applicable regulations.
SECTION 4: First aid measures
4.1 Description of first -aid measures
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Remove contact lenses.
If swallowed
After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling
unwell.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Sodium oxides
Molybdenum oxides
Not combustible.
Ambient fire may liberate hazardous vapours.
5.3 Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system.
SIGALD - 243655
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 2 of 8
mittiWORIB
SiGM4a

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non -emergency personnel: Avoid inhalation of dusts. Evacuate the danger
area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Storage class
Storage class (TRGS 510): 11: Combustible Solids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
8.2 Exposure controls
Appropriate engineering controls
Change contaminated clothing. Wash hands after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
SIGALD - 243655
Page 3 of 8
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: crystalline
Color: colorless
b)
Odor
c)
Odor Threshold
d)
pH
e)
Melting
point/freezing point
f)
Initial boiling point
and boiling range
g)
Flash point
h)
Evaporation rate
i)
Flammability (solid,
gas)
j)
Upper/lower
flammability or
explosive limits
k)
Vapor pressure
1)
Vapor density
No data available
No data available
No data available
Melting point/range: 687 °C (1269 OF) - lit.
No data available
()Not applicable
No data available
No data available
No data available
No data available
No data available
m) Density 3.78 g/cm3 at 25 °C (77 OF) - lit.
Relative density 2.59 at 23.3 °C (73.9 OF) - OECD Test Guideline 109
n) Water solubility 654.2 g/I at 20 °C (68 OF) - OECD Test Guideline 105 -
completely soluble
o) Partition coefficient: Not applicable for inorganic substances
n-octanol/water
p) Autoignition No data available
SIGALD - 243655
Page 4 of 8
The life science business of Merck KGaA, Darmstadt, Germany mittig)Qftlla
operates as MilliporeSigma in the US and Canada SiraMa

temperature
q)
Decomposition No data available
temperature
r)
Viscosity No data available
s)
Explosive properties No data available
t)
Oxidizing properties none
9.2 Other safety information
No
data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute toxicity estimate Oral - 2,500 mg/kg
(Calculation method)
LD50 Oral - Rat - male and female - > 2,000 mg/kg
(OECD Test Guideline 420)
Acute toxicity estimate Inhalation - 4 h - 5.25 mg/I - dust/mist(Calculation method)
LC50 Inhalation - Rat - male and female - 4 h - > 5.05 mg/I - dust/mist
(OECD Test Guideline 403)
Acute toxicity estimate Dermal - 2,500 mg/kg
(Calculation method)
LD50 Dermal - Rat - male and female - > 2,000 mg/kg
(OECD Test Guideline 402)
No data available
Skin corrosion/irritation
No data available
SIGALD - 243655
Page 5 of 8
The life science business of Merck KGaA, Darmstadt, Germany mittiWQRIB
operates as MilliporeSigma in the US and Canada SiGmia

Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
RTECS: QA5075000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 800 mg/I - 96 h
Remarks: (ECOTOX Database)
Toxicity to bacteria
12.2 Persistence and degradability
The methods for determining biodegradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
SIGALD - 243655
Page 6 of 8
The life science business of Merck KGaA, Darmstadt, Germany mittipQftla
operates as MilliporeSigma in the US and Canada SiGmia

12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
No data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned
containers like the product itself. See www.retrologistik.com for processes regarding the
return of chemicals and containers, or contact us there if you have further questions.
SECTION 14: Transport information
TDG
Not regulated as a dangerous good
IMDG
Not dangerous goods
IATA
Not dangerous goods
Further information
Not classified as dangerous in the meaning of transport regulations.
SECTION 15: Regulatory information
This product has been classified in accordance with the hazard criteria of the Hazardous
Products Regulations (HPR) and the SDS contains all the information required by the HPR.
SIGALD - 243655
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 7 of 8
SiGM4a

SECTION 16: Other information
Further information
The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. The information in this document is based on the
present state of our knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any guarantee of the properties of
the product. Sigma -Aldrich Corporation and its Affiliates shall not be held liable for any
damage resulting from handling or from contact with the above product. See
www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional
terms and conditions of sale.
Copyright 2020 Sigma -Aldrich Co. LLC. License granted to make unlimited paper copies
for internal use only.
The branding on the header and/or footer of this document may temporarily not visually
match the product purchased as we transition our branding. However, all of the
information in the document regarding the product remains unchanged and matches the
product ordered. For further information please contact [e-mail].
Version: 6.1 Revision Date: 27.10.2021 Print Date: 05.11.2021
SIGALD - 243655
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 8 of 8
mittiWORIB
SiGM4a

SAFETY DATA SHEET
Version 8.0
Revision Date 14.03.2021
Print Date 03.04.2021
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name Sodium polyphosphate EMPLURA® (Graham's
salt)
Product Number
1.06529
Catalogue No.
106529
Brand
Millipore
CAS -No.
10361-03-2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
: Materials for use in technical applications
1.3 Details of the supplier
of the safety data sheet
Company
Millipore (Canada) Ltd.
2149 Winston Park Dr. , Oakville
ONTARIO L6H 6J8
CANADA
Telephone
[phone]
Fax
[phone]
1.4 Emergency telephone
Emergency Phone #
800-424-9300 CHEMTREC (USA)
[phone] CHEMTREC
(International)
24 Hours/day; 7 Days/week
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Not a hazardous substance or mixture.
2.2 GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
- none
SECTION 3: Composition/information on ingredients
3.1 Substances
Millipore - 1.06529
Page 1 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittiWQR12
operates as MilliporeSigma in the US and Canada SiC7Niqa

Formula H03P.Na
CAS -No. 10361-03-2
EC -No. 233-782-9
No components need to be disclosed according to the applicable regulations.
SECTION 4: First aid measures
4.1 Description of first -aid measures
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Remove contact lenses.
If swallowed
After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling
unwell.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Oxides of phosphorus
Sodium oxides
Not combustible.
Fire may cause evolution of:
Oxides of phosphorus
Ambient fire may liberate hazardous vapours.
5.3 Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system.
Millipore - 1.06529
Page 2 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittiWQRIB
operates as MilliporeSigma in the US and Canada SiGNiqB

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non -emergency personnel: Avoid inhalation of dusts. Evacuate the danger
area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Recommended storage temperature see product label.
Storage class (TRGS 510): 11: Combustible Solids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
8.2 Exposure controls
Appropriate engineering controls
Change contaminated clothing. Wash hands after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Millipore - 1.06529
Page 3 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittiWQRIB
operates as MilliporeSigma in the US and Canada SiGNiqB

Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
Color: white
b)
Odor
c)
Odor Threshold
d)
pH
e)
Melting
point/freezing point
f)
Initial boiling point
and boiling range
g)
Flash point
h)
Evaporation rate
i) Flammability (solid,
gas)
j) Upper/lower
flammability or
explosive limits
k) Vapor pressure
1)
Vapor density
m)
Relative density
n)
Water solubility
o)
Partition coefficient
Millipore -
1.06529
No data available
No data available
5.7 at 10 g/I at 20 °C (68 OF)
628 °C (1162 OF)
No data available
()Not applicable
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
Page 4 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittipQRla
operates as MilliporeSigma in the US and Canada SiGNiqa

n-octanol/water
p)
Autoignition
No data available
temperature
q)
Decomposition
No data available
temperature
r)
Viscosity
No data available
s)
Explosive properties
No data available
t)
Oxidizing properties
No data available
9.2 Other safety information
Bulk density
ca.1,000 kg/m3
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
no information available
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation: No data available
Dermal: No data available
LD50 Intraperitoneal - Mouse - 830 mg/kg
Remarks:
Kidney, Ureter, Bladder:Changes in tubules (including acute renal failure, acute tubular
necrosis).
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Millipore - 1.06529
Page 5 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittiWQR12
operates as MilliporeSigma in the US and Canada SiGNiqa

Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
Not available
SECTION 12: Ecological information
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
12.6 Other adverse effects
No data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned
containers like the product itself. See www.retrologistik.com for processes regarding the
return of chemicals and containers, or contact us there if you have further questions.
Millipore - 1.06529
Page 6 of 7
The life science business of Merck KGaA, Darmstadt, Germany mittiWQRIB
operates as MilliporeSigma in the US and Canada SiGNiqB

SECTION 14: Transport information
TDG
Not regulated as a dangerous good
IMDG
Not dangerous goods
IATA
Not dangerous goods
Further information
Not classified as dangerous in the meaning of transport regulations.
SECTION 15: Regulatory information
This product has been classified in accordance with the hazard criteria of the Hazardous
Products Regulations (HPR) and the SDS contains all the information required by the HPR.
SECTION 16: Other information
Further information
The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. The information in this document is based on the
present state of our knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any guarantee of the properties of
the product. Sigma -Aldrich Corporation and its Affiliates shall not be held liable for any
damage resulting from handling or from contact with the above product. See
www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional
terms and conditions of sale.
Copyright 2020 Sigma -Aldrich Co. LLC. License granted to make unlimited paper copies
for internal use only.
The branding on the header and/or footer of this document may temporarily not visually
match the product purchased as we transition our branding. However, all of the
information in the document regarding the product remains unchanged and matches the
product ordered. For further information please contact [e-mail].
Version: 8.0 Revision Date: 14.03.2021 Print Date: 03.04.2021
Millipore - 1.06529
The life science business of Merck KGaA, Darmstadt, Germany
operates as MilliporeSigma in the US and Canada
Page 7 of 7
mittipQRIB
SIGh qB