Appendix J - Abridged Safety Data Sheets_Hatch file H371132-0000-240-290-0001

. \ ALBEMARLE HUTCH
Permit Information - Table of Contents
H371132
September 15, 2023
Albemarle
Kings Mountain Mine Select Phase: Abridged Report from Hatch
(2O23a) only includes Safety Data Sheets; other deleted document
information available upon request.
Discipline Hatch ID Description
Deliverables Checklist
Project Description Sections 2.4-2.5
Mechanical M19 Dust Control Description
AP1/AP2 Site Layout— Emission Sources
W8 Conveyor Plan and Cross-Section
AP30/AP32 Firewater Pump Emergency Generator and Admin
Bldg Emergency Generator Description
Process M4/M7/NP5 Process Plant Design Summary (block flow
diagram —water circuit and material (ore))/
Process Plant Water and Mass Balance
M6/NP5 Process Plant— Block and Process Flow
AP5/AP8/AP14 Diagrams
M20 Safety Data Sheets (SDS)
AP3/AP5/AP7/AP9/AP10 Air Emission Template
AP 12/AP 15/AP 16/AP 17
AP 19/AP21/AP22/AP23/
AP24/AP25/AP26/AP27/
AP28/AP29/AP34
AP4/AP7/AP11/AP 13/AP18/AP20
Water M9/NP7 Water Treatment Plant Process Description
M10 Water Treatment Plant performance specs and
block flow
AP35 Water Treatment Plant and Other Chemical
Storage Tanks
H371132-4900-840-046-0001, Rev. A
Pagel
0 Hatch 2023 All rights reserved,including all rights relating to the use of this document or its contents.

HUTCH
NP1 Engineering Analysis— Flow Projections
(Chemical Consumption Rates)
Rail M24 Rail Design and cross section
M25 Rail Routing and Improvements
Construction M17 Construction Activities Sequencing
Civil M3 Acreage table
M8 NPI Water Services Description
M12/NP10 Stormwater Management Plan— Process Plant
M14/NP12 and NPI
M18 Erosion Control Measures Cross Section
M13/NP11 Stormwater Management Layout— Process Plant
and NPI
List of Chemical Safety Data Sheets:
• Sylfat FA2: Makes minerals hydrophobic.
• Washington Mills Duramet: Used in slurry density applications for heavy density separation.
• Magnafloc 10: Flocculant and coagulant to aid in mineral recovery.
• Flotigam EDAL A flotation collector to aid in mineral recovery.
• 4-Methyl-2-pentanol: Organic chemical compound used primarily as a frother in mineral flotation.
• Pionera- 100 powder: Used in blasting applications.
• Soda Ash: Leaching agent used in processing ore to help separate minerals; also neutralizes acidic water.
• Sodium Hydroxide: A common base that may be used for leaching ampheric hydroxides or oxides.
H371132-4900-840-046-0001, Rev. A
Page 2
©Hatch 2023 All rights reserved,including all rights relating to the use of this document or its contents.

SAFETY DATA SHEET
KRATON
1. Identification
Product identifier SYLFATTm FA2
Other means of identification
SDS number 8719
Product Code 200000000258
Recommended use Industrial uses: Uses of substances as such or in preparations at industrial sites. Formulation
[mixing]of preparations and/or re-packaging (excluding alloys).
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company Arizona Chemical Company LLC
Address Building 100
4600 Touchton Road East, Suite 1200
City/State Jacksonville, FL
Zip 32246
Country USA
Phone Number 904-928-8700
Alternate Phone Number 800-526-5294
Fax Number 904-928-8780
Emergency-US CHEMTREC 800-424-9300
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
OSHA defined hazards Not classified.
Label elements
Hazard symbol None.
Signal word None.
Hazard statement The substance does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise After prolonged contact with highly porous materials, this product may spontaneously combust.
classified (HNOC)
Supplemental information None.
3. Composition/information on ingredients
Substances
Chemical name Common name and synonyms CAS number %
Tall Oil Fatty Acids 61790-12-3 100
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 1 /8

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s)involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide(CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed. Upon decomposition,this product emits
the chemical carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Wear suitable protective equipment. Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Porous material such as rags, paper, insulation, or organic clay may spontaneously combust when
wetted with this material.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
protective equipment and
emergency procedures
Methods and materials for Absorb in vermiculite, dry sand or earth and place into containers.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material,where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery,
flush area with water.
Small Spills:Absorb in vermiculite, dry sand or earth and place into containers. Clean surface
thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains,water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Porous material such as rags, paper, insulation, or organic clay may spontaneously combust when
wetted with this material. May auto-oxidize with sufficient heat generation to ignite if spread (as a
thin film)or absorbed on porous or fibrous material. Contaminated rags and cloths must be put in
fireproof containers for disposal.Avoid prolonged exposure.Avoid release to the environment.
Observe good industrial hygiene practices. Follow all SDS/label precautions even after container is
emptied because they may retain product residues.
Conditions for safe storage, Do not store in direct sunlight. Store in original tightly closed container. Keep containers closed
including any incompatibilities when not in use. Store at ambient temperature and atmospheric pressure. Store away from
incompatible materials(see Section 10 of the SDS).
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus Us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 2/8

8. Exposure controls/personal protection
Occupational exposure limits
U.S.-OSHA
Components Type Value Form
Tall Oil Fatty Acids(CAS TWA 5 mg/m3 Oil Mist; Respirable
61790-12-3)
ACGIH
Components Type Value Form
Tall Oil Fatty Acids(CAS STEL 10 mg/m3 Oil Mist; Respirable
61790-12-3)
TWA 5 mg/m3 Oil Mist; Respirable
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour)should be used.Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures,such as personal protective equipment
Eye/face protection Wear safety glasses with side shields(or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Other Wear suitable protective clothing.
Respiratory protection In case of insufficient ventilation,wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
O D ;I
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Eye wash fountain and emergency showers are
recommended.
9. Physical and chemical properties
Appearance Liquid.
Physical state Liquid.
Form Liquid.
Color Yellow.
Odor Mild.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 41 °F (5 °C)
Initial boiling point and boiling >392 °F(>200 °C)
range
Flash point 399.2 °F(204.0 °C)Cleveland Open Cup
Evaporation rate 0 (n-BuAc=1)estimated
Flammability(solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit-lower Not available.
N
Flammability limit-upper Not available.
N
Explosive limit-lower(%) Not available.
Explosive limit-upper(%) Not available.
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 3/8

Vapor pressure <0.001 mm Hg at 20°C
Vapor density Not available.
Relative density 0.9 at 25°C/25°C; (water=1)
Solubility(ies)
Solubility(water) 12.6 mg/L at 20°C; Data is for similar product.
Partition coefficient 4.9-6 at 30°C; Data is for similar product.
(n-octanol/water)
Auto-ignition temperature 494.6 °F(257 °C) Data is for similar product.
Decomposition temperature Not available.
Viscosity 20 cP at 25°C
Other information
Chemical family Tall Oil Fatty Acids
Density 898.00 kg/m'at 20°C
Flammability class Combustible 111B estimated
Percent volatile 0 % estimated
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Strong oxidizing agents.Avoid temperatures exceeding the flash point. Contact with incompatible
materials. Porous material such as rags, paper, insulation, or organic clay may spontaneously
combust when wetted with this material.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Upon decomposition this product emits acrid dense smoke with carbon dioxide, carbon monoxide,
products water and other products of combustion.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Tall Oil Fatty Acids Draize Test, No eye irritation.
Result: Negative
Species:Albino rabbit
Organ: Eye
Test Duration: 7 days
Observation Period: 7 days
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Exposure may cause temporary irritation, redness, or discomfort.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Based on available data,the classification criteria are not met.
Components Species Test Results
Tall Oil Fatty Acids(CAS 61790-12-3)
Acute
Dermal
LD50 Albino rabbit >2000 mg/kg, 14 days At this dose no
death occurred.
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 4/8

Components Species Test Results
Oral
LD50 Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no
death occurred.
Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Eye Contact
Tall Oil Fatty Acids Draize Test, No eye irritation.
Result: Negative
Species:Albino rabbit
Organ: Eye
Test Duration: 7 days
Observation Period: 7 days
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Skin sensitization
Tall Oil Fatty Acids Buehler Test, Not a skin sensitizer.
Result: Negative
Species: Guinea pig
Organ: Skin
Notes: OECD 406
Maximisation Assay(Magnusson and Kligman), Not a skin
sensitizer.
Result: Negative
Species: Guinea pig
Organ: Skin
Notes: OECD 406
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%are
mutagenic or genotoxic.
Mutagenicity
Tall Oil Fatty Acids Germ Cell Mutagenicity:Ames, No data available to indicate
product or any components present at greater than 0.1%are
mutagenic or genotoxic.
Result: Negative
Species: Salmonella typhimurium
Notes: OECD 471
Carcinogenicity This product is not considered to be a carcinogen by IARC,ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity- Not classified.
single exposure
Specific target organ toxicity- Not classified.
repeated exposure
Aspiration hazard Not available.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 5/8

Components Species Test Results
Tall Oil Fatty Acids(CAS 61790-12-3)
EC50 Bacteria (Pseudomonas putida) > 10000 mg/I, 16 hr
Aquatic
Algae EL50 Green algae (Selenastrum > 1000 mg/I, 72 hr Growth rate; OECD
capricornutum) 201
Crustacea EL50 Water flea(Daphnia magna) > 1000 mg/I,48 hr OECD 202
Fish LL50 Zebra danio(Danio rerio) > 10000 mg/I, 96 hr
Estimates for product may be based on additional component data not shown.
Persistence and degradability The product is biodegradable.
Biodegradability
Percent degradation (Aerobic biodegradation)
Tall Oil Fatty Acids 88- 100 %CO2 Evolution Test
Species:Activated sewage sludge
Test Duration: 28 d
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential)are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues.This material and its container must be disposed of in a safe manner(see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not available.
Annex II of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is not known to be a"Hazardous Chemical'as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Use as animal feed is prohibited in the United States. Similar regulations may restrict such use in
other locations.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List(40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 6/8

Superfund Amendments and Reauthorization Act of 1986(SARA)
Hazard categories Immediate Hazard-No
Delayed Hazard- No
Fire Hazard- No
Pressure Hazard-No
Reactivity Hazard- No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313(TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs) List
Not regulated.
Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
NFPA ratings Health: 1
Flammability: 1
Instability: 0
NFPA ratings
41 0
16. Other information, including date of preparation or last revision
Issue date 02-23-2015
Revision date 12-13-2016
Version# 3.0
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 7/8

Disclaimer KRATON CORPORATION urges each customer or recipient of this SIDS to study it carefully and
consult appropriate expertise, as necessary or appropriate,to become aware of and understand
the data contained in this SIDS and any hazards associated with the product. The information set
forth in this document, as of the date of this document, is based on present knowledge, obtained
from reliable sources and made to our reasonable ability and in good faith. Such information is
made without any warranty or guarantee whatsoever, and shall establish no legal duty or
responsibility on the part of the author(s),their employer or its affiliates.The information given is
designed only as guidance and its completeness is not guaranteed.The information is not a
guarantee of any specific product properties,features, qualities or specifications.
The information relates only to the specific product designated as shipped, and may not be valid
for such product used in combination with any other materials or products, or in any process,
unless expressly specified in this document. Nothing set forth in this document shall be construed
as a recommendation or license to use any product in conflict with, or as claimed by, any existing
patents rights.The user alone must finally determine whether a contemplated use of a product will
infringe any such patents. Regulatory requirements are subject to change and may differ between
various locations. It is the buyer's/user's responsibility to ensure that his activities are in
compliance with all Local, Federal and International Legislation and Local Permits.
We,for ourselves and on behalf of our affiliates, expressly disclaim any and all liability for any
damages or injuries arising out of any activities relating in any way to the information set forth in
this document. Due to the proliferation of sources for information,we are not and cannot be
responsible for SDSs obtained from any other source other than ourselves. If you have obtained
an SIDS from another source or if you are not sure that the SIDS you have is current, please
contact us for the most current version.
*KRATON,the KRATON logo,ARIZONA CHEMICAL, the"Green Super Drop" logo, 1101,
ABIETA,AQUATAC, CARIFLEX, CENTURY, CENWAX, ELEXAR, E-LEXAR, , IPD, NEXAR,
SYLFAT, SYLVABLEND, SYLVACOTE, SYLVAFUEL, SYLVAGUM, SYLVALITE, SYLVAMIN,
SYLVAPINE, SYLVAPRINT, SYLVARES, SYLVAROAD, SYLVAROS, SYLVASOL, SYLVATAC,
SYLVATAL, SYLVATRAXX, UNICLEAR, UNIDYME, UNIFLEX, UNI-REZ, UNI-TAC, and
ZONATAC are either trademarks or registered trademarks of Kraton Corporation, or its
subsidiaries or affiliates, in one or more, but not all countries.
©2016 Kraton Corporation
Revision information Hazard(s)identification: National/local information
Ecological Information: Ecotox Property Data
Material name:SYLFATTm FA2 MSDS/SDS#8719 sus us
Version#:3.0 Revision date: 12-13-2016 Print date: 12-13-2016 8/8

OP6
Washington Mills Duramet
Not Available Chemwatch Hazard Alert Code:2
Chemwatch:9258123 Issue Date:11/01/2019
Version No:4.1 Print Date:02/01/2023
Safety Data Sheet according to OSHA HazCom Standard(2012)requirements S.GHS.USA.EN
SECTION 1 Identification
Product Identifier
Product name Washington Mills Duramet
Chemical Name Not Applicable
Synonyms Ferrosilicon
Chemical formula Not Applicable
Other means of identification Not Available
Recommended use of the chemical and restrictions on use
Relevant identified uses Use according to manufacturers directions.
Name,address,and telephone number of the chemical manufacturer,importer,or other responsible party
Registered company name Not Available
Address Not Available
Telephone Not Available
Fax Not Available
Website Not Available
Email Not Available
Emergency phone number
Association/Organisation CHEMWATCH EMERGENCY RESPONSE
Emergency telephone [phone]
numbers
Other emergency telephone [phone]
numbers
Once connected and if the message is not in your preferred language then please dial 01
Una vez conectado y si el mensaje no esta en su idioma preferido,por favor marque 02
SECTION 2 Hazard(s)identification
Classification of the substance or mixture
Chemwatch Hazard Ratings
Min Max NFPA 704 diamond
Flammability 0
Toxicity 2 0=Minimum
Body Contact 1 1=Low
2=Moderate 0 Note:The hazard category numbers found in GHS classification in section 2
Reactivity 2 3=High of this SDSs are NOT to be used to fill in the NFPA 704 diamond.Blue=
Chronic 0 4=Extreme Health Red=Fire Yellow=Reactivity White=Special(Oxidizer or water
reactive substances)
Classification Serious Eye Damage/Eye Irritation Category 2B,Acute Toxicity(Oral)Category 4
Label elements
Hazard pictogram(s) 1
•
Page 1 continued...

Chemwatch:9258123 Page 2 of 12 Issue Date:11/01/2019
Version No:4.1 Washington Mills Duramet Print Date:02/01/2023
Signal word I Warning
Hazard statement(s)
H320 �C. ye irritation.
H302 swallowed.
Hazard(s)not otherwise classified
Not Applicable
Precautionary statement(s)Prevention
P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat,drink or smoke when using this product.
Precautionary statement(s)Response
P305+P351+P338 IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing.
P337+P313 If eye irritation persists:Get medical advice/attention.
P301+P312 IF SWALLOWED:Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P330 Rinse mouth.
Precautionary statement(s)Storage
Not Applicable
Precautionary statement(s)Disposal
P501 1 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
SECTION 3 Composition/information on ingredients
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
7439-89-6 70-80 iron
7440-21-3 10-20 silicon
7440-32-6 5-10 titaplLm
7429-90-5 <5 aluminium
Not Available <1 other metallics,as impurities
The specific chemical identity and/or exact percentage(concentration)of composition has been withheld as a trade secret.
SECTION 4 First-aid measures
Description of first aid measures
If this product comes in contact with the eyes:
r Wash out immediately with fresh running water.
r Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Eye Contact r Seek medical attention without delay;if pain persists or recurs seek medical attention.
r Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
r DO NOT attempt to remove particles attached to or embedded in eye.
r Lay victim down,on stretcher if available and pad BOTH eyes,make sure dressing does not press on the injured eye by placing thick pads
under dressing,above and below the eye.
' Seek urgent medical assistance,or transport to hospital.
If skin contact occurs:
r Immediately remove all contaminated clothing,including footwear.
r Flush skin and hair with running water(and soap if available).
r Seek medical attention in event of irritation.
For thermal burns:
r Decontaminate area around burn.
' Consider the use of cold packs and topical antibiotics.
For first-degree burns(affecting top layer of skin)
' Hold burned skin under cool(not cold)running water or immerse in cool water until pain subsides.
' Use compresses if running water is not available.
Skin Contact Cover with sterile non-adhesive bandage or clean cloth.
Do NOT apply butter or ointments;this may cause infection.
Give over-the counter pain relievers if pain increases or swelling,redness,fever occur.
For second-degree burns(affecting top two layers of skin)
Cool the burn by immerse in cold running water for 10-15 minutes.
r Use compresses if running water is not available.
r Do NOT apply ice as this may lower body temperature and cause further damage.
r Do NOT break blisters or apply butter or ointments;this may cause infection.
r Protect burn by cover loosely with sterile,nonstick bandage and secure in place with gauze or tape.
To prevent shock:(unless the person has a head,neck,or leg injury,or it would cause discomfort):
Continued...

Chemwatch:9258123 Page 3 of 12 Issue Date:11/01/2019
Version No:4.1 Washington Mills Duramet Print Date:02/01/2023
r Lay the person flat.
r Elevate feet about 12 inches.
' Elevate burn area above heart level,if possible.
' Cover the person with coat or blanket.
' Seek medical assistance.
For third-degree burns
Seek immediate medical or emergency assistance.
In the mean time:
Protect burn area cover loosely with sterile,nonstick bandage or,for large areas,a sheet or other material that will not leave lint in wound.
Separate burned toes and fingers with dry,sterile dressings.
Do not soak burn in water or apply ointments or butter;this may cause infection.
r To prevent shock see above.
r For an airway burn,do not place pillow under the person's head when the person is lying down.This can close the airway.
r Have a person with a facial burn sit up.
r Check pulse and breathing to monitor for shock until emergency help arrives.
r If fumes or combustion products are inhaled remove from contaminated area.
r Lay patient down.Keep warm and rested.
Inhalation r Prostheses such as false teeth,which may block airway,should be removed,where possible,prior to initiating first aid procedures.
r Apply artificial respiration if not breathing,preferably with a demand valve resuscitator,bag-valve mask device,or pocket mask as trained.
Perform CPR if necessary.
' Transport to hospital,or doctor.
r IF SWALLOWED,REFER FOR MEDICAL ATTENTION,WHERE POSSIBLE,WITHOUT DELAY.
r For advice,contact a Poisons Information Centre or a doctor.
r Urgent hospital treatment is likely to be needed.
r In the mean time,qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated
by the patient's condition.
r If the services of a medical officer or medical doctor are readily available,the patient should be placed in his/her care and a copy of the SIDS
should be provided.Further action will be the responsibility of the medical specialist.
Ingestion ' If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the SIDS.
Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed
otherwise:
INDUCE vomiting with fingers down the back of the throat,ONLY IF CONSCIOUS.Lean patient forward or place on left side(head-down
position,if possible)to maintain open airway and prevent aspiration.
NOTE:Wear a protective glove when inducing vomiting by mechanical means.
Most important symptoms and effects,both acute and delayed
See Section 11
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Copper,magnesium,aluminium,antimony,iron,manganese,nickel,zinc(and their compounds)in welding,brazing,galvanising or smelting operations all give rise to thermally
produced particulates of smaller dimension than may be produced if the metals are divided mechanically.Where insufficient ventilation or respiratory protection is available these
particulates may produce"metal fume fever"in workers from an acute or long term exposure.
r Onset occurs in 4-6 hours generally on the evening following exposure.Tolerance develops in workers but may be lost over the weekend.(Monday Morning Fever)
r Pulmonary function tests may indicate reduced lung volumes,small airway obstruction and decreased carbon monoxide diffusing capacity but these abnormalities resolve after
several months.
r Although mildly elevated urinary levels of heavy metal may occur they do not correlate with clinical effects.
' The general approach to treatment is recognition of the disease,supportive care and prevention of exposure.
' Seriously symptomatic patients should receive chest x-rays,have arterial blood gases determined and be observed for the development of tracheobronchitis and pulmonary
edema.
[Ellenhorn and Barceloux:Medical Toxicology]
For acute or short term repeated exposures to iron and its derivatives:
Always treat symptoms rather than history.
In general,however,toxic doses exceed 20 mg/kg of ingested material(as elemental iron)with lethal doses exceeding 180 mg/kg.
Control of iron stores depend on variation in absorption rather than excretion.Absorption occurs through aspiration,ingestion and burned skin.
Hepatic damage may progress to failure with hypoprothrombinaemia and hypoglycaemia.Hepatorenal syndrome may occur.
Iron intoxication may also result in decreased cardiac output and increased cardiac pooling which subsequently produces hypotension.
Serum iron should be analysed in symptomatic patients.Serum iron levels(2-4 hrs post-ingestion)greater that 100 ug/dL indicate poisoning with levels,in excess of 350 ug/dL,
being potentially serious.Emesis or lavage(for obtunded patients with no gag reflex)are the usual means of decontamination.
r Activated charcoal does not effectively bind iron.
r Catharsis(using sodium sulfate or magnesium sulfate)may only be used if the patient already has diarrhoea.
r Deferoxamine is a specific chelator of ferric(3+)iron and is currently the antidote of choice.It should be administered parenterally.[Ellenhorn and Barceloux:Medical Toxicology]
SECTION 5 Fire-fighting measures
Extinguishing media
Metal dust fires need to be smothered with sand,inert dry powders.
DO NOT USE WATER,CO2 or FOAM.
' Use DRY sand,graphite powder,dry sodium chloride based extinguishers,G-1 or Met L-X to smother fire.
' Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas.
' DO NOT use halogenated fire extinguishing agents.
Special hazards arising from the substrate or mixture
Fire Incompatibility Reacts with acids producing flammable/explosive hydrogen(1-12)gas
Special protective equipment and precautions for fire-fighters
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r Alert Fire Brigade and tell them location and nature of hazard.
Fire Fighting r Wear breathing apparatus plus protective gloves in the event of a fire.
' Prevent,by any means available,spillage from entering drains or water courses.
' Use fire fighting procedures suitable for surrounding area.
r DO NOT disturb burning dust.Explosion may result if dust is stirred into a cloud,by providing oxygen to a large surface of hot metal.
r DO NOT use water or foam as generation of explosive hydrogen may result.
With the exception of the metals that burn in contact with air or water(for example,sodium),masses of combustible metals do not represent
unusual fire risks because they have the ability to conduct heat away from hot spots so efficiently that the heat of combustion cannot be
Fire/Explosion Hazard maintained-this means that it will require a lot of heat to ignite a mass of combustible metal.
Decomposition may produce toxic fumes of:
silicon dioxide(Si02)
metal oxides
May emit poisonous fumes.
May emit corrosive fumes.
SECTION 6 Accidental release measures
Personal precautions,protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
r Remove all ignition sources.
Minor Spills r Clean up all spills immediately.
r Avoid contact with skin and eyes.
r Control personal contact with the substance,by using protective equipment.
If molten:
Contain the flow using dry sand or salt flux as a dam.
r All tooling(e.g.,shovels or hand tools)and containers which come in contact with molten metal must be preheated or specially coated,rust
free and approved for such use.
Major Spills r Allow the spill to cool before remelting scrap.
Moderate hazard.
r CAUTION:Advise personnel in area.
r Alert Emergency Services and tell them location and nature of hazard.
r Control personal contact by wearing protective clothing.
Personal Protective Equipment advice is contained in Section 8 of the SIDS.
SECTION 7 Handling and storage
Precautions for safe handling
For molten metals:
Molten metal and water can be an explosive combination.The risk is greatest when there is sufficient molten metal to entrap or seal off water.
Water and other forms of contamination on or contained in scrap or remelt ingot are known to have caused explosions in melting operations.
While the products may have minimal surface roughness and internal voids,there remains the possibility of moisture contamination or
Safe handling entrapment.
Avoid all personal contact,including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
r Prevent concentration in hollows and sumps.
' Store in original containers.
Other information Keep containers securely sealed.
' Store in a cool,dry area protected from environmental extremes.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage,including any incompatibilities
r Bulk bags:Reinforced bags required for dense materials.
r CARE:Packing of high density product in light weight metal or plastic packages may result in container collapse with product release
Suitable container r Heavy gauge metal packages/Heavy gauge metal drums
r Polyethylene or polypropylene container.
r Check all containers are clearly labelled and free from leaks.
The material is described as an electropositive metal.
The activity or electromotive series of metals is a listing of the metals in decreasing order of their reactivity with hydrogen-ion sources such as
water and acids.In the reaction with a hydrogen-ion source,the metal is oxidised to a metal ion,and the hydrogen ion is reduced to H2.The
ordering of the activity series can be related to the standard reduction potential of a metal cation.
For aluminas(aluminium oxide):
Incompatible with hot chlorinated rubber.
In the presence of chlorine trifluoride may react violently and ignite.
-May initiate explosive polymerisation of olefin oxides including ethylene oxide.
Storage incompatibility -Produces exothermic reaction above 200°C with halocarbons and an exothermic reaction at ambient temperatures with halocarbons in the
presence of other metals.
Titanium:
' reacts with oxidising agents,aluminium,carbon dioxide,chlorinated solvents,strong acids,oxygen,halogens
' reacts violently with cupric or lead oxide when heated
' powder mixtures with potassium perchlorate,with nickel and infusional earth ignite with very small sparks causing severe explosion
with trichloroethylene or trichlorofluoroethylene with flash or spark on heavy impact
reacts with fluorine at 150 deg C,chlorine at 300 deg C,bromine at 360 deg C and iodine at>360 deg C
when heated at red heat(700 deg C)decomposes steam to hydrogen and when heated above above 800 deg C burns vigorously in pure
Continued...

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nitrogen;burns in carbon dioxide above 550 deg C;the hot metal explodes violently on contact with water.
r WARNING:Avoid or control reaction with peroxides.All transition metal peroxides should be considered as potentially explosive.For
example transition metal complexes of alkyl hydroperoxides may decompose explosively.
' The pi-complexes formed between chromium(0),vanadium(0)and other transition metals(haloarene-metal complexes)and mono-or
poly-fluorobenzene show extreme sensitivity to heat and are explosive.
Metals and their oxides or salts may react violently with chlorine trifluoride and bromine trifluoride.
These trifluorides are hypergolic oxidisers.They ignite on contact(without external source of heat or ignition)with recognised fuels-contact
with these materials,following an ambient or slightly elevated temperature,is often violent and may produce ignition.
The state of subdivision may affect the results.
Many metals may incandesce,react violently,ignite or react explosively upon addition of concentrated nitric acid.
SECTION 8 Exposure controls/personal protection
Control parameters
Occupational Exposure Limits(OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
US OSHA Permissible Exposure iron Particulates Not Otherwise Regulated(PNOR)-Total 15 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 dust Available Available
US OSHA Permissible Exposure iron Particulates Not Otherwise Regulated(PNOR)- 5 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 Respirable fraction Available Available
US OSHA Permissible Exposure iron Inert or Nuisance Dust:Respirable fraction 5 mg/m3/15 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US OSHA Permissible Exposure iron Inert or Nuisance Dust:Total Dust 15 mg/m3/50 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US NIOSH Recommended iron Particulates not otherwise regulated Not Available Not Not See Appendix
Exposure Limits(RELs) Available Available D
US OSHA Permissible Exposure silicon Silicon-Respirable fraction 5 mg/m3 Not Not
Limits(PELs)Table Z-1 Available Available Not Available
US OSHA Permissible Exposure silicon Silicon-Total dust 15 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 Available Available
US OSHA Permissible Exposure silicon Inert or Nuisance Dust:Total Dust 15 mg/m3/50 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US OSHA Permissible Exposure silicon Inert or Nuisance Dust:Respirable fraction 5 mg/m3/15 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US NIOSH Recommended silicon Silicon-respirable 5 mg/m3 Not Not Not Available
Exposure Limits(RELs) Available Available
US NIOSH Recommended Not Not
Exposure Limits(RELs) silicon Silicon-total 10 mg/m3 Available Available Not Available
US OSHA Permissible Exposure titanium Particulates Not Otherwise Regulated(PNOR)-Total 15 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 dust Available Available
US OSHA Permissible Exposure titanium Particulates Not Otherwise Regulated(PNOR)- 5 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 Respirable fraction Available Available
US OSHA Permissible Exposure titanium Inert or Nuisance Dust:Total Dust 15 mg/m3/50 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US OSHA Permissible Exposure titanium Inert or Nuisance Dust:Respirable fraction 5 mg/m3/15 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US NIOSH Recommended Not Not See Appendix
Exposure Limits(RELs) titanium Particulates not otherwise regulated Not Available Available Available D
US OSHA Permissible Exposure aluminium Aluminum Metal(as Al)-Respirable fraction 5 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 Available Available
US OSHA Permissible Exposure aluminium Aluminum Metal(as Al)-Total dust 15 mg/m3 Not Not Not Available
Limits(PELs)Table Z-1 Available Available
US OSHA Permissible Exposure aluminium Inert or Nuisance Dust:Total Dust 15 mg/m3/50 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US OSHA Permissible Exposure aluminium Inert or Nuisance Dust:Respirable fraction 5 mg/m3/15 Not Not Not Available
Limits(PELs)Table Z-3 mppcf Available Available
US NIOSH Recommended aluminium Aluminum-total 10 mg/m3 Not Not Not Available
Exposure Limits(RELs) Available Available
US NIOSH Recommended Not Not
Exposure Limits(RELs) aluminium Aluminum-respirable 5 mg/m3 Available Available Not Available
US NIOSH Recommended Not Not
Exposure Limits(RELs) aluminium Aluminum(pyro powders and welding fumes,as Al) 5 mg/m3 Available Available Not Available
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
iron 3.2 mg/m3 35 mg/m3 150 mg/m3
silicon 45 mg/m3 100 mg/m3 630 mg/m3
titanium 30 mg/m3 330 mg/m3 2,000 mg/m3
Ingredient Original IDLH Revised IDLH
Continued...

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Ingredient Original IDLH Revised IDLH
iron Not Available Not Available
silicon Not Available Not Available
titanium Not Available Not Available
aluminium Not Available Not Available
Exposure controls
Appropriate engineering Metal dusts must be collected at the source of generation as they are potentially explosive.
controls r Avoid ignition sources.
r Good housekeeping practices must be maintained.
r Dust accumulation on the floor,ledges and beams can present a risk of ignition,flame propagation and secondary explosions.
� i r
Personal protection
:®: ,,�
0
' Safety glasses with side shields.
Eye and face protection ' Chemical goggles.
r Contact lenses may pose a special hazard;soft contact lenses may absorb and concentrate irritants.A written policy document,describing
the wearing of lenses or restrictions on use,should be created for each workplace or task.
Skin protection See Hand protection below
The selection of suitable gloves does not only depend on the material,but also on further marks of quality which vary from manufacturer to
manufacturer.Where the chemical is a preparation of several substances,the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when
making a final choice.
Hands/feet protection Personal hygiene is a key element of effective hand care.
r Protective gloves eg.Leather gloves or gloves with Leather facing
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved,dry solids,where abrasive
particles are not present.
' polychloroprene.
' nitrile rubber.
' butyl rubber.
Body protection See Other protection below
Overalls.
P.V.0 apron.
Other protection
Barrier cream.
Skin cleansing cream.
Respiratory protection
Type-P Filter of sufficient capacity.(AS/NZS 1716&1715,EN 143:2000&149:2001,ANSI Z88 or national equivalent)
Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
up to 10 x ES P1 PAPR-P1
Air-line*
up to 50 x ES Air-line** P2 PAPR-P2
up to 100 x ES P3
Air-line*
100+x ES Air-line** PAPR-P3
Negative pressure demand**-Continuous flow
A(AII classes)=Organic vapours,B AUS or 131=Acid gasses,B2=Acid gas or hydrogen cyanide(HCN),B3=Acid gas or hydrogen cyanide(HCN),E=Sulfur dioxide(S02),G=
Agricultural chemicals,K=Ammonia(NH3),Hg=Mercury,NO=Oxides of nitrogen,MB=Methyl bromide,AX=Low boiling point organic compounds(below 65 degC)
Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.
The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information,exposure measurement data,and frequency and
likelihood of the worker's exposure-ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment(powered,
positive flow,full face apparatus may be an option).
•Published occupational exposure limits,where they exist,will assist in determining the adequacy of the selected respiratory protection.These may be government mandated or
vendor recommended.
Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection program.
Where protection from nuisance levels of dusts are desired,use type N95(US)or type P1(EN143)dust masks.Use respirators and components tested and approved under
appropriate government standards such as NIOSH(US)or CEN(EU)
Use approved positive flow mask if significant quantities of dust becomes airborne.
Try to avoid creating dust conditions.
SECTION 9 Physical and chemical properties
Information on basic physical and chemical properties
Appearance Gray granular solid with no odour;does not mix with water.
Physical state Divided Solid Relative density(Water=1) 6.7
Odour Not Available Partition coefficient n-octanol Not Available
/water
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Odour threshold Not Available Auto-ignition temperature(°C) Not Applicable
pH(as supplied) Not Applicable Decomposition Not Available
temperature(°C)
Melting point/freezing point
VC) 2700 Viscosity(cSt) Not Applicable
Initial boiling point and boiling Not Applicable Molecular weight(g/mol) Not Applicable
range(°C)
Flash point(°C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit(%) Not Applicable Surface Tension(dyn/cm or Not Applicable
mN/m)
Lower Explosive Limit(%) Not Applicable Volatile Component(%vol) Not Available
Vapour pressure(kPa) Not Available Gas group Not Available
Solubility in water Immiscible pH as a solution(1%) Not Applicable
Vapour density(Air=1) Not Available VOC g/L Not Available
SECTION 10 Stability and reactivity
Reactivity See section 7
r Unstable in the presence of incompatible materials.
Chemical stability r Product is considered stable.
r Hazardous polymerisation will not occur.
r Presence of heat source and ignition source
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products
SECTION 11 Toxicological information
Information on toxicological effects
Inhalation of dusts,generated by the material during the course of normal handling,may be damaging to the health of the individual.
There is some evidence to suggest that the material can cause respiratory irritation in some persons.The body's response to such irritation can
cause further lung damage.
In animals,instilling silicon dust in the windpipe caused only slight damage to the epithelium.
Persons with impaired respiratory function,airway diseases and conditions such as emphysema or chronic bronchitis,may incur further disability
Inhaled if excessive concentrations of particulate are inhaled.
If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained,proper screenings should be
conducted on individuals who may be exposed to further risk if handling and use of the material result in excessive exposures.
Effects on lungs are significantly enhanced in the presence of respirable particles.
The inhalation of small particles of metal oxide results in sudden thirst,a sweet,metallic foul taste,throat irritation,cough,dry mucous
membranes,tiredness and general unwellness.Headache,nausea and vomiting,fever or chills,restlessness,sweating,diarrhoea,excessive
urination and prostration may also occur.
Accidental ingestion of the material may be harmful;animal experiments indicate that ingestion of less than 150 gram may be fatal or may
Ingestion produce serious damage to the health of the individual.
Not normally a hazard due to the physical form of product.The material is a physical irritant to the gastro-intestinal tract
There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.
Though considered non-harmful,slight irritation may result from contact because of the abrasive nature of the aluminium oxide particles.Thus it
may cause itching and skin reaction and inflammation.
Skin Contact Irritation and skin reactions are possible with sensitive skin
Open cuts,abraded or irritated skin should not be exposed to this material
Entry into the blood-stream,through,for example,cuts,abrasions or lesions,may produce systemic injury with harmful effects.Examine the skin
prior to the use of the material and ensure that any external damage is suitably protected.
There is some evidence to suggest that this material can cause eye irritation and damage in some persons.
Eye Contact with the eye by metal dusts may produce mechanical abrasion or foreign body penetration of the eyeball.Iron particles embedded in the
eye may cause discolouration of the cornea and iris,and effects on the pupil such as poor rection to light and accommodation.
Substance accumulation,in the human body,may occur and may cause some concern following repeated or long-term occupational exposure.
Animal testing shows long term exposure to aluminium oxides may cause lung disease and cancer,depending on the size of the particle.The
smaller the size,the greater the tendencies of causing harm.
Overexposure to the breathable dust may cause coughing,wheezing,difficulty in breathing and impaired lung function.Chronic symptoms may
include decreased vital lung capacity and chest infections.Repeated exposures in the workplace to high levels of fine-divided dusts may produce
Chronic a condition known as pneumoconiosis,which is the lodgement of any inhaled dusts in the lung,irrespective of the effect.This is particularly true
when a significant number of particles less than 0.5 microns(1/50000 inch)are present.
Chronic excessive intake of iron have been associated with damage to the liver and pancreas.People with a genetic disposition to poor control
over iron are at an increased risk.
Metallic dusts generated by the industrial process give rise to a number of potential health problems.The larger particles,above 5 micron,are
nose and throat irritants.
TOXICITY IRRITATION
Washington Mills Duramet
Not Available Not Available
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TOXICITY IRRITATION
iron
Oral(Rat)LD50:98600 mg/kg121 Not Available
TOXICITY IRRITATION
silicon Dermal(rabbit)LD50:>5000 mg/kg111 Eye:no adverse effect observed(not irritating)111
Oral(Rat)LD50:3160 mg/kg121 Skin:no adverse effect observed(not irritating)111
TOXICITY IRRITATION
titanium
Oral(Rat)LD50:>2000 mg/kg111 Not Available
TOXICITY IRRITATION
aluminium Inhalation(Rat)LC50:>2.3 mg/14h111 Eye:no adverse effect observed(not irritating)111
Oral(Rat)LD50:>2000 mg/kg111 Skin:no adverse effect observed(not irritating)111
Legend. 1.Value obtained from Europe ECHA Registered Substances-Acute toxicity 2.Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS-Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ends.This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome(RADS)which can occur after exposure to high levels of highly irritating compound.Main
criteria for diagnosing RAIDS include the absence of previous airways disease in a non-atopic individual,with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant.Other criteria for diagnosis of RAIDS include a reversible
SILICON airflow pattern on lung function tests,moderate to severe bronchial hyperreactivity on methacholine challenge testing,and the lack of minimal
lymphocytic inflammation,without eosinophilia.
Injection of silicon into the peritoneal cavity produced only minor local trauma and foreign body reaction.In animal testing,silicon dioxide given by
mouth did not cause clinical signs or cell changes.Silicon dioxide was largely eliminated in the faeces.
The material may be irritating to the eye,with prolonged contact causing inflammation.Repeated or prolonged exposure to irritants may produce
conjunctivitis.
Washington Mills Duramet&
SILICON&TITANIUM& No significant acute toxicological data identified in literature search.
ALUMINIUM
Acute Toxicity 1f Carcinogenicity X
Skin Irritation/Corrosion X Reproductivity X
Serious Eye Damage/Irritation %0' STOT-Single Exposure X
Respiratory or Skin X STOT-Repeated Exposure X
sensitisation
Mutagenicity I X Aspiration Hazard I X
Legend. X -Data either not available or does not fill the criteria for classification
✓—Data available to make classification
SECTION 12 Ecological information
Toxicity
Endpoint Test Duration(hr) Species Value Source
Washington Mills Duramet Not Not Not
Available Not Available Not Available Available Available
Endpoint Test Duration(hr) Species Value Source
NOEC(ECx) 48h Algae or other aquatic plants 0.1-4mg/I 4
iron EC50 72h Algae or other aquatic plants 18mg/I 2
LC50 96h Fish 0.00499-0.00819mg/I 4
EC50 48h Crustacea >100mg/I 2
Endpoint Test Duration(hr) Species Value Source
silicon I EC10(ECx) 1.28h Algae or other aquatic plants >=66<=88mg/I 2
EC50 72h Algae or other aquatic plants —250mg/I 2
Endpoint Test Duration(hr) Species Value Source
NOEC(ECx) 48h Crustacea <=lmg/I 2
titanium EC50 72h Algae or other aquatic plants 13mg/I 2
LC50 96h Fish >100mg/I 2
EC50 48h Crustacea >100mg/I 2
Endpoint Test Duration(hr) Species Value Source
aluminium NOEC(ECx) 48h Crustacea >100mg/I 1
EC50 96h Algae or other aquatic plants 0.0054mg/I 2
Continued...

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EC50 72h Algae or other aquatic plants 0.0169mg/I 2
LC50 96h Fish 0.078-0.108mg/I 2
EC50 48h Crustacea 0.7364mg/I 2
Legend., Extracted from 1.IUCLID Toxicity Data 2.Europe ECHA Registered Substances-Ecotoxicological Information-Aquatic Toxicity 4.US EPA,
Ecotox database-Aquatic Toxicity Data 5.ECETOC Aquatic Hazard Assessment Data 6.NITE(Japan)-Bioconcentration Data 7.METI(Japan)
-Bioconcentration Data 8.Vendor Data
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence:Water/Soil Persistence:Air
No Data available for all ingredients No Data available for all ingredients
Bioaccumulative potential
Ingredient Btoaccumulation
No Data available for all ingredients
Mobility in soil
Ingredient Mobility
No Data available for all ingredients
SECTION 13 Disposal considerations
Waste treatment methods
' Containers may still present a chemical hazard/danger when empty.
' Return to supplier for reuse/recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same
product,then puncture containers,to prevent re-use,and bury at an authorised landfill.
Where possible retain label warnings and SIDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country,state and/or territory.Each user must refer to laws operating in their
area.In some areas,certain wastes must be tracked.
A Hierarchy of Controls seems to be common-the user should investigate:
r Reduction
Product/Packaging disposal r Reuse
r Recycling
r Disposal(if all else fails)
This material may be recycled if unused,or if it has not been contaminated so as to make it unsuitable for its intended use.
r DO NOT allow wash water from cleaning or process equipment to enter drains.
r It may be necessary to collect all wash water for treatment before disposal.
' In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
' Where in doubt contact the responsible authority.
' Recycle wherever possible or consult manufacturer for recycling options.
' Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible,or dispose of in an authorised landfill.
SECTION 14 Transport information
Labels Required
Marine Pollutant I NO
Land transport(DOT):NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport(ICAO-IATA/DGR):NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport(IMDG-Code I GGVSee):NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
iron Not Available
silicon Not Available
titanium Not Available
aluminium Not Available
Transport in bulk in accordance with the ICG Code
Product name Ship Type
iron Not Available
silicon Not Available
Continued...

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Product name Ship Type
titanium Not Available
aluminium Not Available
SECTION 15 Regulatory information
Safety,health and environmental regulations/legislation specific for the substance or mixture
iron is found on the following regulatory lists
International WHO List of Proposed Occupational Exposure Limit(OEL)Values for US OSHA Permissible Exposure Limits(PELs)Table Z-1
Manufactured Nanomaterials(MNMS) US OSHA Permissible Exposure Limits(PELs)Table Z-3
US-Alaska Air Quality Control-Concentrations Triggering an Air Quality Episode for US Toxic Substances Control Act(TSCA)-Chemical Substance Inventory
Air Pollutants Other Than PM-2.5 US TSCA Chemical Substance Inventory-Interim List of Active Substances
US DOE Temporary Emergency Exposure Limits(TEELs)
US NIOSH Recommended Exposure Limits(RELs)
silicon is found on the following regulatory lists
International WHO List of Proposed Occupational Exposure Limit(OEL)Values for US OSHA Permissible Exposure Limits(PELs)Table Z-1
Manufactured Nanomaterials(MNMS) US OSHA Permissible Exposure Limits(PELs)Table Z-3
US-Alaska Air Quality Control-Concentrations Triggering an Air Quality Episode for US Toxic Substances Control Act(TSCA)-Chemical Substance Inventory
Air Pollutants Other Than PM-2.5 US TSCA Chemical Substance Inventory-Interim List of Active Substances
US-Massachusetts-Right To Know Listed Chemicals
US DOE Temporary Emergency Exposure Limits(TEELs)
US NIOSH Recommended Exposure Limits(RELs)
titanium is found on the following regulatory lists
International WHO List of Proposed Occupational Exposure Limit(OEL)Values for US OSHA Permissible Exposure Limits(PELs)Table Z-1
Manufactured Nanomaterials(MNMS) US OSHA Permissible Exposure Limits(PELs)Table Z-3
US-Alaska Air Quality Control-Concentrations Triggering an Air Quality Episode for US Toxic Substances Control Act(TSCA)-Chemical Substance Inventory
Air Pollutants Other Than PM-2.5 US TSCA Chemical Substance Inventory-Interim List of Active Substances
US DOE Temporary Emergency Exposure Limits(TEELs)
US NIOSH Recommended Exposure Limits(RELs)
aluminium is found on the following regulatory lists
International WHO List of Proposed Occupational Exposure Limit(OEL)Values for US NIOSH Recommended Exposure Limits(RELs)
Manufactured Nanomaterials(MNMS) US OSHA Permissible Exposure Limits(PELs)Table Z-1
US-Alaska Air Quality Control-Concentrations Triggering an Air Quality Episode for US OSHA Permissible Exposure Limits(PELs)Table Z-3
Air Pollutants Other Than PM-2.5 US Toxic Substances Control Act(TSCA)-Chemical Substance Inventory
US-Massachusetts-Right To Know Listed Chemicals US TSCA Chemical Substance Inventory-Interim List of Active Substances
US ATSDR Minimal Risk Levels for Hazardous Substances(MRLs)
US Department of Homeland Security(DHS)-Chemical Facility Anti-Terrorism
Standards(CFATS)-Chemicals of Interest
US EPCRA Section 313 Chemical List
Federal Regulations
Superfund Amendments and Reauthorization Act of 1986(SARA)
Section 3111312 hazard categories
Flammable(Gases,Aerosols,Liquids,or Solids) No
Gas under pressure No
Explosive No
Self-heating No
Pyrophoric(Liquid or Solid) No
Pyrophoric Gas No
Corrosive to metal No
Oxidizer(Liquid,Solid or Gas) No
Organic Peroxide No
Self-reactive No
In contact with water emits flammable gas No
Combustible Dust No
Carcinogenicity No
Acute toxicity(any route of exposure) Yes
Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No
Serious eye damage or eye irritation No
Specific target organ toxicity(single or repeated exposure) No
Aspiration Hazard No
Germ cell mutagenicity No
Simple Asphyxiant No
Continued...

Chemwatch:9258123 Page 11 of 12 Issue Date:11/01/2019
Version No:4.1 Washington Mills Duramet Print Date:02/01/2023
Hazards Not Otherwise Classified No
US.EPA CERCLA Hazardous Substances and Reportable Quantities(40 CFR 302.4)
None Reported
State Regulations
US.California Proposition 65
None Reported
National Inventory Status
National Inventory Status
Australia-AIIC/Australia Yes
Non-Industrial Use
Canada- DSL Yes
Canada-NDSL No(iron;silicon;titanium;aluminium)
China-IECSC Yes
Europe-EINEC/ELINCS/NLP Yes
Japan-ENCS No(iron;silicon;titanium;aluminium)
Korea-KECI Yes
New Zealand-NZIoC Yes
Philippines-PICCS Yes
USA-TSCA Yes
Taiwan-TCSI Yes
Mexico-INSQ Yes
Vietnam-NCI Yes
Russia-FBEPH Yes
Legend: Yes=All CAS declared ingredients are on the inventory
No=One or more of the CAS listed ingredients are not on the inventory.These ingredients may be exempt or will require registration.
SECTION 16 Other information
Revision Date 11/01/2019
Initial Date 03/11/2014
SIDS Version Summary
Version Date of Update Sections Updated
3.1 03/13/2019 Expiration.Review and Update
4.1 11/01/2019 One-off system update.NOTE:This may or may not change the GHS classification
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
The SIDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.Many factors determine whether the reported Hazards are Risks in the workplace or
other settings.Risks may be determined by reference to Exposures Scenarios.Scale of use,frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations
PC—TWA:Permissible Concentration-Time Weighted Average
PC—STEL:Permissible Concentration-Short Term Exposure Limit
IARC:International Agency for Research on Cancer
ACGIH:American Conference of Governmental Industrial Hygienists
STEL:Short Term Exposure Limit
TEEL:Temporary Emergency Exposure Limit,
IDLH:Immediately Dangerous to Life or Health Concentrations
ES:Exposure Standard
OSF:Odour Safety Factor
NOAEL:No Observed Adverse Effect Level
LOAEL:Lowest Observed Adverse Effect Level
TLV:Threshold Limit Value
LOD:Limit Of Detection
OTV:Odour Threshold Value
BCF:BioConcentration Factors
BEL Biological Exposure Index
AIIC:Australian Inventory of Industrial Chemicals
DSL:Domestic Substances List
NDSL:Non-Domestic Substances List
IECSC:Inventory of Existing Chemical Substance in China
EINECS:European INventory of Existing Commercial chemical Substances
ELINCS:European List of Notified Chemical Substances
NLP:No-Longer Polymers
ENCS:Existing and New Chemical Substances Inventory
KECI:Korea Existing Chemicals Inventory
NZIoC:New Zealand Inventory of Chemicals
PICCS:Philippine Inventory of Chemicals and Chemical Substances
Continued...

Chemwatch:9258123 Page 12 of 12 Issue Date:11/01/2019
Version No:4.1 Washington Mills Duramet Print Date:02/01/2023
TSCA:Toxic Substances Control Act
TCSI:Taiwan Chemical Substance Inventory
INSQ:Inventario Nacional de Sustancias Quimicas
NCI:National Chemical Inventory
FBEPH:Russian Register of Potentially Hazardous Chemical and Biological Substances
This document is copyright.
Apart from any fair dealing for the purposes of private study,research,review or criticism,as permitted under the Copyright Act,no part may be reproduced by any process without
written permission from CHEMWATCH.
TEL[phone].

Brenntag Canada Inc. BRENNTAGA
MA GNA FL 10
PRODUCT DISTRIBUTED BY/PRODUIT DISTRIBUE PAR
Brenntag Canada Inc. WHMIS Number: 00061491
43 Jutland Road. Index: HCI0346/16A
Toronto, Ontario Effective Date: 2016 February 09
M8Z 2G6 Date of Revision: 2016 February 09
(416) 259-8231 Website: http://www.brenntag.ca
EMERGENCY TELEPHONE NUMBER(For Emergencies Involving Chemical Spills or Releases)
1 855 273 6824
NUMERO DE TELEPHONE D'URGENCE(pour les urgences impliquant des rejets on des deversements chimiques)
This document consists of an SDS in English and French in GHS format.
Le present document est une FDS en anglais et en frangais en format SGH.
This product is considered to be non-regulated by WHMIS standards and therefore this SDS will not be
subject to any periodic or time based update.
Le present produit nest pas reglemente par le SIMDUT. La fiche signaletique ne fera donc pas Fobjet
de mises a jour periodiques.
READ THE ENTIRE SAFETY DATA SHEET(SDS)FOR THE COMPLETE HAZARD EVALUATION OF THIS
PRODUCT.
LIRE LA FICHE DE DONNEES DE SECURITE(FDS)POUR UNE EVALUATION COMPLETE DES DANGERS
QUE REPRESENTE CE PRODUIT.

BASF
We create chemistry
Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 1/9
Version: 3.0 (30481447/SDS GEN CA/EN)
1. Identification
Product identifier used on the label
Magnafloc® 10
Recommended use of the chemical and restriction on use
Recommended use*: flocculation agent
*The"Recommended use"identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification.The terms of this Safety Data Sheet(SDS)do not create or infer any warranty,express or
implied,including by incorporation into or reference in the seller's sales agreement.
Details of the supplier of the safety data sheet
Company:
BASF Canada Inc.
100 Milverton Drive
Mississauga, ON L5R41-11, CANADA
Telephone: [phone]
Emergency telephone number
CANUTEC (reverse charges): [phone]
BASF HOTLINE: (800)454-COPE (2673)
Other means of identification
Chemical family: polyacrylamide, anionic
2. Hazards Identification
According to Hazardous Products Regulations (HPR) (SOR/2015-17)
Classification of the product
No need for classification according to GHS criteria for this product.
Label elements
The product does not require a hazard warning label in accordance with GHS criteria.
Hazards not otherwise classified

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 2/9
Version: 3.0 (30481447/SDS GEN CA/EN)
Very slippery when wet.
Labeling of special preparations (GHS):
This product is not combustible in the form in which it is shipped by the manufacturer, but may form a
combustible dust through downstream activities (e.g. grinding, pulverizing)that reduce its particle
size.
According to Controlled Products Regulations (CPR) (SOR/88-66)
Emergency overview
Caution -Slippery when wet!
May cause some eye irritation which should cease after removal of the product.
May cause some irritation to the respiratory system if dust is inhaled.
May cause skin irritation.
This type of product has a tendency to create dust if roughly handled. It does not burn readily but as
with many organic powders, flammable dust clouds may be formed in air.
Take precautionary measures against static discharges.
Use with local exhaust ventilation.
Wear suitable protective clothing, gloves and eye/face protection.
3. Composition / Information on Ingredients
According to Hazardous Products Regulations (HPR) (SOR/2015-17)
This product does not contain any components classified as hazardous under the referenced
regulation.
4. First-Aid Measures
Description of first aid measures
General advice:
Remove contaminated clothing.
If inhaled:
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
If on skin:
Wash thoroughly with soap and water.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
If swallowed:
Rinse mouth and then drink plenty of water. Check breathing and pulse. Place victim in the recovery
position, cover and keep warm. Loosen tight clothing such as a collar, tie, belt or waistband. Seek
medical attention. Never induce vomiting or give anything by mouth if the victim is unconscious or
having convulsions.
Most important symptoms and effects, both acute and delayed

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 3/9
Version: 3.0 (30481447/SDS GEN CA/EN)
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Additional information:
If water is used, restrict pedestrian and vehicular traffic in areas where slip hazard may exist.
Special hazards arising from the substance or mixture
Hazards during fire-fighting:
carbon oxides, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire. Very slippery when
wet.
Advice for fire-fighters
Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.
Further information:
Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.
6. Accidental release measures
Further accidental release measures:
Avoid dispersal of dust in the air(i.e., clearing dust surfaces with compressed air). Avoid the
formation and build-up of dust- danger of dust explosion. Dust in sufficient concentration can result
in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other
sources of ignition. Forms slippery surfaces with water.
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
Nonsparking tools should be used.

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 4/9
Version: 3.0 (30481447/SDS GEN CA/EN)
7. Handling and Storage
Precautions for safe handling
Breathing must be protected when large quantities are decanted without local exhaust ventilation.
Handle in accordance with good industrial hygiene and safety practice. Forms slippery surfaces with
water.
Protection against fire and explosion:
Avoid dust formation. Dust in sufficient concentration can result in an explosive mixture in air. Handle
to minimize dusting and eliminate open flame and other sources of ignition. Routine housekeeping
should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static
electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate
precautions, such as electrical grounding and bonding, or inert atmospheres. Refer to NFPA 654,
Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and
Handling of Combustible Particulate Solids (2013 Edition)for safe handling.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Store in unopened original containers in a cool and dry
place. Avoid wet, damp or humid conditions, temperature extremes and ignition sources.
Storage stability:
Avoid extreme heat.
8. Exposure Controls/Personal Protection
No occupational exposure limits known.
Advice on system design:
It is recommended that all dust control equipment such as local exhaust ventilation and material
transport systems involved in handling of this product contain explosion relief vents or an explosion
suppression system or an oxygen deficient environment. Ensure that dust-handling systems (such as
exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to
prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). Use only
appropriately classified electrical equipment and powered industrial trucks.
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent)organic vapour/particulate respirator.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Safety glasses with side-shields.
Body protection:
light protective clothing
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation.
Wearing of closed work clothing is recommended. Wear protective clothing as necessary to minimize
contact. Handle in accordance with good industrial hygiene and safety practice. No eating, drinking,
smoking or tobacco use at the place of work.

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 5/9
Version: 3.0 (30481447/SDS GEN CA/EN)
9. Physical and Chemical Properties
Form: powder
Odour: odourless
Odour threshold: No applicable information available.
Colour: off-white
pH value: 6-8
( 10 g/1)
The product has not been tested.
The statement has been derived
from substances/products of a
similar structure or composition.
Melting point: The substance/product
decomposes therefore not
determined.
Boiling point: not applicable
Sublimation point: No applicable information available.
Flash point: not applicable
Flammability: not flammable
Lower explosion limit: No data available.
Upper explosion limit: No data available.
Autoignition: No data available.
Vapour pressure: The product has not been tested.
Bulk density: approx. 700 kg/m3
Vapour density: No data available.
Partitioning coefficient n- Study scientifically not justified.
octanol/water(log Pow):
Self-ignition not self-igniting
temperature:
Viscosity, dynamic: 25 -49 mPa.s (DIN 53019)
(0.5 %(m), 25 °C)
% volatiles: not determined
Solubility in water: Forms a viscous solution.
Solubility(quantitative): No data available.
Solubility (qualitative): No data available.
Evaporation rate: The product is a non-volatile solid.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Oxidizing properties:
not fire-propagating
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 6/9
Version: 3.0 (30481447/SDS GEN CA/EN)
The product is not a dust explosion risk as supplied; however the build-up of fine dust can lead to a
risk of dust explosions.
Stable under normal conditions.
No hazardous reactions known.
Conditions to avoid
Avoid extreme temperatures. Avoid humidity.
Incompatible materials
strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: No known acute effects.
Oral
Type of value: LD50
Species: rat
Value: > 5,000 mg/kg (OECD Guideline 401)
Irritation/corrosion
Assessment of irritating effects: Contact with the eyes or skin may cause mechanical irritation. The
product has not been tested. The statement has been derived from the properties of the individual
components.
Skin
Species: rabbit
Result: non-irritant
Method: OECD Guideline 404
Eve
Species: rabbit
Result: non-irritant
Sensitization
Assessment of sensitization: Based on the ingredients, there is no suspicion of a skin-sensitizing
potential.
Aspiration Hazard
No aspiration hazard expected.
Chronic Toxicity/Effects

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 7/9
Version: 3.0 (30481447/SDS GEN CA/EN)
Repeated dose toxicity
Assessment of repeated dose toxicity: Based on our experience and the information available, no
adverse health effects are expected if handled as recommended with suitable precautions for
designated uses. The product has not been tested. The statement has been derived from the
properties of the individual components.
Genetic toxicity
Assessment of mutagenicity: Based on the ingredients, there is no suspicion of a mutagenic effect.
Carcinogenicity
Assessment of carcinogenicity: The whole of the information assessable provides no indication of a
carcinogenic effect.
None of the components in this product at concentrations greater than 0.1% are listed by IARC;
NTP, OSHA or ACGIH as a carcinogen.
Reproductive toxicity
Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effect
on reproduction.
Teratogenicity
Assessment of teratogenicity: Based on the ingredients, there is no suspicion of a teratogenic effect.
Other Information
The product has not been tested. The statements on toxicology have been derived from products of
a similar structure and composition.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11., Further important symptoms and effects are so far not known.
12. Ecological Information
Toxicity
Toxicity to fish
LC50 (96 h) > 100 mg/I, Oncorhynchus mykiss (static)
(under static conditions in the presence of 10 mg/L humic acid)
Aquatic invertebrates
LC50 (48 h) > 100 mg/I, Daphnia magna
Persistence and degradability
Assessment biodegradation and elimination (H2O)
Not readily biodegradable (by OECD criteria).
Bioaccumulative potential
Assessment bioaccumulation potential
Based on its structural properties, the polymer is not biologically available. Accumulation in
organisms is not to be expected.
Mobility in soil

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 8/9
Version: 3.0 (30481447/SDS GEN CA/EN)
Assessment transport between environmental compartments
Information on:Anionic polyacrylamide
Adsorption to solid soil phase is expected.
----------------------------------
Additional information
Other ecotoxicological advice:
The product has not been tested. The statements on ecotoxicology have been derived from products
of a similar structure and composition.
13. Disposal considerations
Waste disposal of substance:
Must be disposed of or incinerated in accordance with local regulations.
Container disposal:
Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent
unauthorized use of used containers.
14. Transport Information
Land transport
TDG
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
VOC content:
not determined
Federal Regulations
Registration status:
Chemical DSL, CA released /listed
Accordinq to Controlled Products Regulations (CPR) (SOR/88-66)
Not WHMIS controlled.

Safety Data Sheet
Magnafloc® 10
Revision date : 2016/02/09 Page: 9/9
Version: 3.0 (30481447/SDS GEN CA/EN)
16. Other Information
SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2016/02/09
We support worldwide Responsible Care®initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.
Magnafloc® 10 is a registered trademark of BASF Canada or BASF SE
END OF DATA SHEET

Cl ariant F.3 3
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA.' Page 1
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
Section 01 - Product Information
Identification of the Clariant Corporation
company: 4000 Monroe Road
Charlotte, NC, 28205
Telephone No.: [phone]
Information of the substance/preparation:
Product Safety 1-704-331-7710
Emergency tel. number: [phone] CHEMTREC
Trade name: FLOTIGAM EDA
Primary product use: Ore processing
Chemical family: Based on an isodecyl ether propylene amine/amino acetate.
Section 02 - Composition information on hazardous ingredients
Hazardous ingredients:
Component CAS-no. (Trade secret Concentration
no.)
3- Isodec lox ro lamine 30113-45-2 40 -60 %
3- 28701-67-9 40 -60 %
(Isodecyloxy)propylammonium
acetate
Section 03 - Hazards identification
Emergency overview: Clear, colorless to pale yellow liquid; slight amine
odor.
Corrosive
Harmful if swallowed.
Toxic to aquatic organisms
Expected Route of entry:
Inhalation: Vapors and/or mists are probably corrosive to
respiratory passages, and may cause ulcerations
of the nose, throat, and larynx.
Skin contact: Corrosive to the skin.
Eye contact: Corrosive to the eye.
Ingestion: This material will probably cause chemical burns of
the mouth , pharynx, esophagus, and stomach in
humans following ingestion.
Skin absorption: yes
Known effects on other illnesses: Pre-existing skin and eye disorders may be
aggravated by exposure to this product.
Listed carcinogen: IARC: No

Clariant
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA Page 2
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
NTP: No
OSHA: No
Other: No
HMIS:
Health: 3 Flammability: 1 Reactivity: 0 Personal protection: X
Section 04 - First aid measures
After inhalation:
Get victim to fresh air. Give artificial respiration or oxygen if breathing has stopped. Get
prompt medical attention. Do not give fluids if victim is unconscious.
After contact with skin:
Immediately wash skin with soap and plenty of water for at least 15 minutes while removing
contaminated clothing and shoes.
Seek medical attention if pain or irritation occurs.
After contact with eyes:
Flush thoroughly with water for 15 minutes. Get immediate medical help.
After ingestion:
Get immediate medical help.
Advice to doctor/Treatment:
None known.
Section 05 - Fire fighting measures
Flashpoint: > 212 OF
Method: ASTM D 93 (closed cup)
Lower explosion limit: Not applicable for Liquids with Flash Point > 70 'C.
Upper explosion limit: Not applicable for Liquids with Flash Point> 70 'C.
Ignition temperature: Not applicable for Liquids with Flash Point> 70 'C.
Hazardous combustion products:
In case of fires, hazardous combustion gases are formed:
Nitrous gases (NOx)
Extinguishing media: water spray jet
foam
sand
carbon dioxide
dry powder
Special fire fighting procedure:
Use self-contained breathing apparatus and full protective clothing.
Use water spray to cool drums in fire area.
Avoid breathing vapors and keep upwind.
Section 06 - Accidental release measures

Clariant
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA Page 3
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
Steps to be taken in case of spill or leak:
Contain spill. Ensure adequate ventilation and wear appropriate personal protective
equipment. Collect onto inert absorbent. Place in sealable container. Do not allow to
contaminate water sources or sewers.
Section 07 - Handling and storage
Advice on safe handling:
Keep away from heat, sparks and open flames. -Avoid breathing vapors or contact with skin,
eyes, and clothing.- Use only with adequate ventilation and proper protective eyewear, face
shield, gloves and clothing. Wash thoroughly after handling. Keep container closed.
Further info on storage conditions:
Store in original container.
Keep from freezing.
Section 08 - Exposure controls / personal protection
No level has been established by OSHA, NIOSH, ACGIH.
Respiratory protection: If airborne concentrations pose a health hazard, become
irritating, or exceed recommended limits, use a NIOSH approved
respirator in accordance with OSHA respiratory protection
requirements under 29CFR1910.134.
Hand protection: Nitrile Gloves.
Eye protection: Safety glasses or chemical splash goggles.
Other protective equipment: Clothing suitable to prevent skin contact.
IDLH:
Not Determined
Section 09 - Physical and chemical properties
Form: Liquid
Color: colourless to pale colour
Odor: slightly ammonia-alkali like
pH: approx. 9 (20 °C, 10 g/1)
Method: ASTM E 70
Solubility in water: Method: OECD Guide-line 105
emulsifiable
Density: 0.9 g/cm3 (20 °C)
Method: DIN 51757
Freezing point : < -4 OF
Method: OECD Guide-line 102

Clariant
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA Page 4
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
Starts to boil : approx. 482 OF
Method: OECD Guide-line 103
Viscosity/ (dynamic): 110 mPa.s (20 °C)
Method: DIN 53015
Further information:
Ionic Characteristic: Cationic
Section 10 - Stability and reactivity
Thermal decomposition: > 200 °C
Method: ASTMD 3417
Chemical stability: Stable.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological information
Product information:
Acute oral toxicity: LD50 ca. 500 mg/kg (rat)
Method: OECD 423
Acute inhalation toxicity: No data available. No information on acute inhalation toxicity
was found in the specialised literature.
Acute dermal toxicity: No data available. No information on acute dermal toxicity was
found in the specialised literature.
Skin irritation: corrosive (rabbit)
By analogy with a similar product.
Eye irritation: corrosive
Information derived from the corrosive effect on skin
Section 12 - Ecological information
Product information:
Biodegradation: > 95 % (28 d)
readily degradable
By analogy with a similar product.
Fish toxicity: LC50 7.81 mg/I (96 h, Brachydanio rerio)
Method: OECD 203
Bacteria toxicity: EC50 49.35 mg/I (3 h, activated sludge)
By analogy with a similar product.
Chemical oxygen demand > 2,000.000 mg/I
(COD): By analogy with a similar product.

Clariant
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA Page 5
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
Remarks:
Do not dispose of in the environment.
Section 13 - Disposal considerations
Waste disposal information:
Consult local, state, and federal regulations.
Recommended disposal is by incineration in approved facilities.
RCRA hazardous waste:
No -- Not as sold.
RCRA number: NONE
Section 14 - Transport information
DOT Regulation:
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Hazard class: 8
Packing group: II
UN/NA-number: UN 2735
Primary hazard class: 8
Technical Name: Alkyletheramine
IATA
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Class: 8
Packing group: 11
UN/ID number: UN 2735
Primary risk: 8
Remarks: Shipment permitted
Hazard inducer(s): Alkyletheramine
IMDG
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Class: 8
Packing group: II
UN no.: UN 2735
Primary risk: 8
Hazard inducer(s): Alkyletheramine
Marine pollutant: Marine Pollutant
EmS: F-A S-B
Section 15 - Regulatory information
TSCA Status:
All components of this product are listed on the TSCA Inventory.
SARA(section 3111312):
Reactive hazard: no
Pressure hazard: no
Fire hazard: yes
Immediate/acute: yes

Clariant
MATERIAL SAFETY DATA SHEET
FLOTIGAM EDA Page 6
Substance key: SXR094488 Revision Date: 04/20/2011
Version : 2 - 1 / USA Date of printing :06/29/2011
Delayed/chronic: no
SARA 313 information:
This product does not contain any toxic chemical listed under Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986.
Clean Water Act:
Contains no known priority pollutants at concentrations greater than 0.1%.
Section 16 - Other information
Label information:
DANGER!
CORROSIVE TO SKIN AND EYES CAUSES BURNS HARMFUL IF SWALLOWED
THIS MATERIAL IS TOXIC TO AQUATIC ORGANISMS.
Avoid breathing vapor or mist. Avoid contact with skin and eyes. Avoid mist formation.
Keep container closed when not in use. Keep away from heat, sparks and flame. Use
ventilation and/or respiratory protection to keep exposure to a minimum.
Eye contact: flush with water for at least 15 minutes while holding eyelids open. Seek
immediate medical attention. Skin contact: wash thoroughly with soap and water for 15
minutes. If skin irritation occurs, seek medical attention. Wash contaminated clothing
before reuse. Ingestion: seek medical attention immediately. Inhalation: remove to
fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen
and seek medical attention.
This information is supplied under the OSHA Hazard Communication Standard, 29 CFR
1910.1200, and is offered in good faith based on data available to us that we believe to be
true and accurate. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable to the material. However, each user should review
these recommendations in the specific context of the intended use and determine whether
they are appropriate for that use. No warranty, express or implied, is made regarding the
accuracy of this data, the hazards connected with the use of the material, or the results to
be obtained from the use thereof. We assume no responsibility for damage or injury from
the use of the product described herein. Data provided here are typical and not intended
for use as product specifications.

115MMIMwww.sigmaainricn.com
vfflppppp�
Version 6.1
SAFETY DATA SHEET
Revision Date 01/15/2020
Print Date 02/08/2020
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name 4-Methyl-2-pentanol
Product Number 109916
Brand Aldrich
Index-No. 603-008-00-8
CAS-No. 108-11-2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Synthesis of substances
1.3 Details of the supplier of the safety data sheet
Company Sigma-Aldrich Inc.
3050 Spruce Street
ST. LOUIS MO 63103
UNITED STATES
Telephone [phone]
Fax [phone]
1.4 Emergency telephone number
Emergency Phone # : [phone]
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 3), H226
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram O
Signal word Warning
Hazard statement(s)
H226 Flammable liquid and vapour.
H319 Causes serious eye irritation.
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H335 May cause respiratory irritation.
Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant
foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal
plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
May form explosive peroxides.
SECTION 3: Composition/information on ingredients
3.1 Substances
Synonyms Isobutyl methyl carbinol
Formula C6H14O
Molecular weight 102.17 g/mol
CAS-No. 108-11-2
EC-No. 203-551-7
Index-No. 603-008-00-8
Component Classification Concentration
4-Methylpentan-2-ol
Flam. Liq. 3; Eye Irrit. 2A; <= 100 %
STOT SE 3; H226, H319,
H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
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SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor
in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Dry powder Dry sand
Unsuitable extinguishing media
Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
For personal protection see section 8.
Aldrich - 109916 Page 3 of 10
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6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 3: Flammable liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Components with workplace control parameters
Component CAS-No. Value Control Basis
parameters
4-Methylpentan- 108-11-2 TWA 25 ppm USA. ACGIH Threshold Limit
2-ol Values (TLV)
Remarks Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Danger of cutaneous absorption
STEL 40 ppm USA. ACGIH Threshold Limit
Values TLV
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Danger of cutaneous absorption
TWA 25 ppm USA. Occupational Exposure
100 mg/m3 Limits (OSHA) - Table Z-1
Limits for Air Contaminants
Skin designation
The value in m /m3 is approximate.
Aldrich - 109916 Page 4 of 10
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TWA 25 ppm USA. NIOSH Recommended
100 m /m3 Exposure Limits
Potential for dermal absorption
ST 40 ppm USA. NIOSH Recommended
165 m /m3 Exposure Limits
Potential for dermal absor tion
PEL 25 ppm California permissible exposure
100 mg/m3 limits for chemical
contaminants (Title 8, Article
107)
Skin
STEL 40 ppm California permissible exposure
165 mg/m3 limits for chemical
contaminants (Title 8, Article
107)
Skin
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands
before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.4 mm
Break through time: 480 min
Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.2 mm
Break through time: 30 min
Material tested:Dermatril® P (KCL 743 / Aldrich Z677388, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone [phone], e-mail
[e-mail], test method: EN374
If used in solution, or mixed with other substances, and under conditions which
differ from EN 374, contact the supplier of the CE approved gloves. This
recommendation is advisory only and must be evaluated by an industrial hygienist
and safety officer familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use
scenario.
Aldrich - 109916 Page 5 of 10
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Body Protection
Impervious clothing, Flame retardant antistatic protective clothing., The type of
protective equipment must be selected according to the concentration and amount
of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-
face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting Melting point/range: -90 °C (-130 OF) - lit.
point/freezing point
f) Initial boiling point 132 °C 270 OF - lit.
and boiling range
g) Flash point 41 °C (106 OF) - closed cup
h) Evaporation rate No data available
i) Flammability (solid, No data available
gas)
j) Upper/lower Upper explosion limit: 5.5 %(V)
flammability or Lower explosion limit: 1 %(V)
explosive limits
k) Vapour pressure 4.9 hPa at 20 °C (68 OF)
1) Vapour density 4.09
m) Relative density 0.802 g/cm3 at 25 °C (77 IF)
n) Water solubility 21.8 g/I at 20 °C (68 IF) - OECD Test Guideline 105 - soluble
o) Partition coefficient: No data available
n-octanol/water
p) Auto-ignition No data available
temperature
q) Decomposition No data available
temperature
r) Viscosity No data available
s) Explosive properties No data available
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t) Oxidizing properties No data available
9.2 Other safety information
Relative vapour 4.09
density
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
Test for peroxide formation before distillation or evaporation. Test for peroxide formation or
discard after 1 year.
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 2,590 mg/kg
(OECD Test Guideline 401)
Inhalation: No data available
LD50 Dermal - Rabbit - 2,870 mg/kg
(OECD Test Guideline 402)
No data available
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Irritating to eyes.
(OECD Test Guideline 405)
Respiratory or skin sensitisation
Maximisation Test - Guinea pig
Aldrich - 109916 Page 7 of 10
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Result: Does not cause skin sensitisation.
(OECD Test Guideline 406)
Germ cell mutagenicity
Ames test
S. typhimurium
Result: negative
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
NTP: No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is
on OSHA's list of regulated carcinogens.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: SA7350000
Central nervous system depression, depression, narcosis, lowering of blood pressure due to
cardiac depression, relaxing of smooth muscle in all regions and depressed skeletal muscle
without influencing nerves.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to fish semi-static test LC50 - Pimephales promelas (fathead minnow) - 359
mg/I - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia semi-static test EC50 - Daphnia magna (Water flea) - 337 mg/I - 48
and other aquatic h
invertebrates (OECD Test Guideline 202)
Toxicity to algae static test EC50 - Pseudokirchneriella subcapitata - 264 mg/I - 72 h
(OECD Test Guideline 201)
Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - > 100 mg/I - 3 h
(OECD Test Guideline 209)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 85 % - Readily biodegradable.
Aldrich - 109916 Page 8 of 10
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(OECD Test Guideline 301F)
Ratio BOD/ThBOD 85 %
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
12.6 Other adverse effects
No data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Contact a licensed professional waste disposal service to dispose of this material. Offer
surplus and non-recyclable solutions to a licensed disposal company. Burn in a chemical
incinerator equipped with an afterburner and scrubber but exert extra care in igniting as
this material is highly flammable.
Contaminated packaging
Dispose of as unused product.
SECTION 14: Transport information
DOT (US)
UN number: 2053 Class: 3 Packing group: III
Proper shipping name: Methyl isobutyl carbinol
Reportable Quantity (RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 2053 Class: 3 Packing group: III EMS-No: F-E, S-D
Proper shipping name: METHYL ISOBUTYL CARBINOL
IATA
UN number: 2053 Class: 3 Packing group: III
Proper shipping name: Methyl isobutyl carbinol
SECTION 15: Regulatory information
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313 Components
Aldrich - 109916 Page 9 of 10
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This material does not contain any chemical components with known CAS numbers that
exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section
313.
SARA 311/312 Hazards
Fire Hazard, Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
4-Methylpentan-2-ol CAS-No. Revision Date
108-11-2 1993-04-24
SECTION 16: Other information
Further information
Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies
for internal use only.
The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. The information in this document is based on the
present state of our knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any guarantee of the properties of
the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any
damage resulting from handling or from contact with the above product. See
www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional
terms and conditions of sale.
The branding on the header and/or footer of this document may temporarily not visually
match the product purchased as we transition our branding. However, all of the
information in the document regarding the product remains unchanged and matches the
product ordered. For further information please contact [e-mail].
Version: 6.1 Revision Date: 01/15/2020 Print Date: 02/08/2020
Aldrich - 109916 Page 10 of 10
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SAFETY DATA SHEET
PIONERA F-100 Powder
Last changed: 02/07/2012 Replaces date: 04/01/2012
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
TRADE NAME PIONERA F-100 Powder
APPLICATION AREA Flotation depressant with selectivity for Clay, Calcite and Barite
NATIONAL MANUFACTURER/IMPORTER
Enterprise Borregaard AS
Address P.O.Box 162
Country NORWAY
Telephone [phone]
Fax [phone]
CONTACT PERSONS
Name E-mail Telephone Country
Nina Faye Haraldstad [e-mail]
Emer enc Phone Type of assistance Opening Hours
112 Emergency 24 h
2. HAZARDS IDENTIFICATION
GENERAL
Not classified. Avoid generation and spreading of dust.
HEALTH
Avoid handling which leads to dust formation.
FIRE AND EXPLOSION
Note the risk of dust explosion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient name Reg.No EC No. CAS No. Conc. Classification
_1 _
Chemically modified natural polymer _ >90 % _
4. FIRST AID MEASURES
INHALATION
Move the exposed person to fresh air at once.
SKIN CONTACT
Rinse the skin immediately with lots of water.
EYE CONTACT
Rinse immediately with plenty of water. Remove any contact lenses and rinse with water for at least 15 minutes (keep
the eyelids open).
INGESTION
Drink plenty of water. Contact physician if symptoms appears.
S. FIRE-FIGHTING MEASURES
1 /5

SAFETY DATA SHEET
PIONERA F-100 Powder
Last changed: 02/07/2012 Replaces date: 04/01/2012
EXTINGUISHING MEDIA
Can be extinguished with water, powder, alcohol-resistant foam or carbon dioxide.
IMPROPER EXTINGUISHING MEDIA
Avoid water in straight hose stream; will scatter and spread fire.
FIRE AND EXPLOSION HAZARDS
High concentrations of dust may form explosive mixture with air. (t > 450'C). Fire causes formation of toxic gases.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS
Use a respirator and other protective equipment.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Mechanical ventilation or local exhaust ventilation is required. Avoid generation and spreading of dust.
SAFETY ACTIONS TO PROTECT EXTERNAL ENVIRONMENT
Prevents major discharge into sewage systems, groundwater and surface water. Provide ventilation and confine spill. Do
not allow runoff to sewer.
METHODS FOR CLEANING UP
Collect with vacuum cleaner or carefully sweep together and collect. Avoid generation and spreading of dust. Rinse clean
with water. Collect in containers and seal securely.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Preparation has low toxicity, therefore risk of damage is limited in normal handling.
HANDLING ADVICE
Provide sufficient ventilation for operations causing dust formation. Mechanical ventilation or local exhaust ventilation
may be required.
STORAGE
Keep container dry.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE CONTROL
Provide good ventilation.
RESPIRATORY PROTECTION
Wear respirator if there is dust formation.
EYE PROTECTION
Use approved safety goggles or face shield.
HAND PROTECTION
No specific hand protection noted, but gloves may still be advisable.
PROTECTIVE CLOTHING
Wear suitable protective clothing.
2/5

SAFETY DATA SHEET
PIONERA F-100 Powder
Last changed: 02/07/2012 Replaces date: 04/01/2012
OEL value
Ingredient name (CAS no. Range �ppm m m3 Year Notification
Nuisance dust, total 8 h 10 �2010
R=Toxic for reproduction, H=Skin absorption, K=Carcinogenic, A=Sensitising, T=Upper limit, M=Mutagenic
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Powder.
COLOUR Brown.
ODOUR Mild.
SOLUBILITY Water soluble.
Physical and chemical parameters
Parameter Value/unit Method/reference Observation
pH in solution — 8.50
10. STABILITY AND REACTIVITY
STABILITY
Stable under recommended storage and handling conditions.
CONDITIONS TO AVOID
No information available
MATERIALS TO AVOID
No information available
HAZARDOUS DECOMPOSITION PRODUCTS
No dangerous reactions known.
11. TOXICOLOGICAL INFORMATION
SKIN CONTACT
OECD 404, "Not classified as irritating to skin". Non-irritant.
EYE CONTACT
OECD-test 405: "Not classified as eye irritant". Non-irritant.
SENSITISATION
No known information.
ACUTE AND CHRONIC TOXICITY
No known information.
12. ECOLOGICAL INFORMATION
MOBILITY
Water soluble.
DEGRADABILITY
Expected to be readily biodegradable.
3/5

SAFETY DATA SHEET
PIONERA F-100 Powder
Last changed: 02/07/2012 Replaces date: 04/01/2012
CONCLUSION
Not regarded as dangerous for the environment.
13. DISPOSAL CONSIDERATIONS
GENERAL REGULATIONS
Dump or destroy in accordance with official recommendations and applicable legislation.
14. TRANSPORT INFORMATION
Classified as Dangerous Goods: No
OTHER INFORMATION
Class 55
Harmonized Tariff Code for US:3804.00.1000-0
15. REGULATORY INFORMATION
EC-Label: No
REFERENCES
GLOBAL CHEMICAL INVENTORY STATUS
Country List Status
United States Toxic Substance Control Act (TSCA) Included
Canada Domestic Substance List (DSL) Included
Europe European Inventory of Existing Chemical Substances (EINECS) Exempt - Polymer
Australia Australian Inventory of Chemical Substances (AICS) Included
Japan Existing and New Chemical List (ENCS) Included
Korea Korean Existing Chemical List (ECL) Included
Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Included
China Chemical Inventory INV (CN) - IECSC Included
New Zealand New Zealand Inventory of Chemicals (NZIoQ Included
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). This material is not known to contain
any
chemicals, currently listed as carcinogens or reproductive toxins under California Proposition 65 at levels which would be
subject to
the proposition.
Not classified as dangerous for supply or conveyance - Marpol, Annex II, Appendix III.
Regulation (EC) 1907/2006 (REACH) (September 2008)
16. OTHER INFORMATION
VENDOR NOTES
Information is based on our present knowledge and applies product in deliverd form.The meaning is to describe our
products safety demand and not its characteristics. It is the responsibility of the recipient of this safety data sheet to
ensure that information given here is read and understood by all who use, handle, dispose of or in any way come in
contact with the product. The information given in this SDS is based on our present knowledge and describe security for
our products. It is not a sales specification. Assessed on the basis of available data
ISSUED: 04/01/2012
REVISION HISTORY
Version (Rev. date Responsible IChanges
0.0.2 __]02/07/2012 Borregaard AS lUpdated according to current regulations (NIHA)
4/5

SAFETY DATA SHEET
PIONERA F-100 Powder
Last changed: 02/07/2012 Replaces date: 04/01/2012
5/5

General
Chern�cal
Material Safety Data Sheet DENSE SODA ASH
A. PRODUCT INFORMATION
TRADE NAME (PRODUCT IDENTIFIER): CLASSIFICATION &SYMBOL:
SODA ASH
T
Class D2B
CHEMICAL NAME AND/OR SYNONYM: FORMULA CAS NO:
Sodium Carbonate Na2CO3 497-19-8
PRODUCT USE:
Soda salts;glass;soap,cleaners and water softeners;pulp and paper; photographical agent.
MANUFACTURER/IMPORTER: SUPPLIER/DISTRIBUTOR:
General Chemical Performance Products,Ltd. General Chemical Performance Products, Ltd.
201 City Centre Drive 201 City Centre Drive
Mississauga, Ontario 1_513 3A3 Mississauga,Ontario 1_513 3A3
EMERGENCY TELEPHONE NO: 866-543-3896
PREPARATIONB. • ' •
PREPARED BY: PREVIOUS ISSUE DATE: 4/00
General Chemical Corporation
Product Safety Department CURRENT ISSUE DATE: 6/01
973-515-1840
C. TOXICOLOGICAL PROPERTIES
INHALATION:
Inhalation of product may irritate nose,throat,and lung.
INGESTION:
Although low in toxicity, ingestion can be harmful. May cause nausea,vomiting,stomachache,and diarrhea.
SKIN:
May cause skin irritation from prolonged contact,especially in hot weather. Dermal(rodent-rabbit)500 mg/24 Hr-mild irritation. Standard draize test.
EYES:
May irritate or burn eyes.
ACUTE TOXICITY: EXPOSURE LIMITS:
Moderately toxic LD50(rat): 2800 mg/kg. Ontario Ministry of Labour Time-Weighted Average
See section K Exposure Value(TWAEV)for Nuisance Particulate is 10
mg/m3.
CHRONIC TOXICITY:
Excessive contact may produce"soda ulcers"on hands and perforation of the nasal
septum.Sensitivity reactions may occur from prolonged and repeated exposure.
OTHER: BIOLOGICAL EXPOSURE INDICES(BEI):
Not available. NA
1

D. PHYSICAL DATA
MATERIAL IS AT NORMAL APPEARANCE AND COLOR: ODOR THRESHOLD:
CONDITIONS: Odorless,white powder NA
LIQUID ❑ SOLID ® GAS ❑
BOILING POINT: °C SPECIFIC GRAVITY: g/cc VAPOR DENSITY:
(HZO= 1) (AIR=1)
FREEZING POINT: 8540C 2.533 @ 25°C Not available
(MELTING POINT)
SOLUBILITY IN WATER: pH VAPOR PRESSURE:
17%solution @ 20°C 1 %solution;pH= 11.3 (MM Hg @ 20°C not available
38%solution;pH= 11.8 (PSIG)
EVAPORATION RATE: %VOLATILES BY VOLUME: MOLECULAR WEIGHT:
(Ether= 1.0) (AT 20°C) 105.99
Not available Not available
E. REACTIVITY DATA
STABILITY: CONDITIONS TO AVOID:
Simultaneous exposure to soda ash and lime dusts(CaO). In the presence of moisture(i.e.perspiration)
UNSTABLE ❑ STABLE ® the two materials combine to form corrosive caustic soda(NaOH)which may cause burns.
INCOMPATIBILITY(MATERIALS TO AVOID):
Contact with acids will release carbon dioxide gas. Can react violently with red hot aluminum metal;fluorine gas;lithium;and 2.4.6-trinitrotoluene.
HAZARDOUS DECOMPOSITION PRODUCTS:
Heating soda ash liberates COz
Na2CO3(solid)=Na2O(solid)+CO2(gas)
HAZARDOUS POLYMERIZATION: OTHER PRECAUTIONS:
When dissolving,add to water cautiously and with stirring;solutions can
WILL NOT OCCUR ® get hot.
MAY OCCUR ❑
F. FIRE OR EXPLOSION HAZARD
CONDITIONS OF FLAMMABILITY: FLASH POINT:
NA METHOD Not applicable
HAZARDOUS COMBUSTION PRODUCTS:
See Section E. Hazardous Decomposition Products.
%BY VOL. IN AIR EXPLOSION HAZARDS:
UPPER FLAMMABLE LIMIT: NA
Not applicable
LOWER FLAMMABLE LIMIT:
AUTOIGNITION TEMPERATURE:
SENSITIVITY TO MECHANICAL IMPACT:
Not applicable
SENSITIVITY TO STATIC DISCHARGE:
Not applicable
FIRE EXTINGUISHING PROCEDURES:
Using extinguishing media appropriate for surrounding fire. For fire fighting wear NIOSH-approved,self-contained breathing apparatus.
2

HAZARDOUSG. ONLY)
MATERIAL OR COMPONENT/C.A.S.# CONCENTRATION HAZARD DATA
Not applicable
H. PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
For dusty or misty conditions,wear NIOSH-approved dust or mist respirator.
EYES AND FACE:
For dusty or misty conditions,or when handling solutions where there is reasonable probability of eye contact,wear chemical safety goggles and hard
hat. Under these conditions do not wear contact lenses.
HANDS,ARMS,AND BODY:
As a minimum,wear long-sleeve shirts,trousers,and gloves for routine product use. Cotton gloves permitted for dry product, impervious gloves when
handling solutions.
STORAGE:
Cool,dry area away from acids. Prolonged storage may cause product to cake and become wet from atmospheric moisture.
NORMAL HANDLING:
Avoid contact with eyes or prolonged skin contact.Avoid breathing dust. Use good personal hygiene and housekeeping.
ENGINEERING CONTROLS:
Ventilation: Local Exhaust: In all areas where dusty or misty conditions prevail.
Natural Ventilation: Adequate for other areas
Eye wash facility should be provided in storage and general work area.
ENVIRONMENTAL:
DEGRADABILITY: AQUATIC TOXICITY:
Not available. TLm 48 hr.mosquito-fish=840 mg/1
TLm 96 hr.mosquito-fish= 1200 mg/1
SPILL OR LEAK(ALWAYS WEAR PERSONAL PROTECTIVE EQUIPMENT):
Shovel up dry chemical and place into an empty container with cover. Cautiously spray residue with plenty of water. Keep contaminated water from
entering showers and water courses.
WASTE DISPOSAL:
Consistent with the requirements of local waste disposal authorities. If permitted by applicable disposal regulations,bury in a solid waste landfill or
dissolve and neutralize as follows: Dissolve in water using caution as solution can get hot. Neutralize with acid and flush to sewer with plenty of water.
Good ventilaton is required during neutralization due to release of COz gas. Neutralized waste may have to be disposed of by an approved contractor.
3

CANADIAN SHIPPING INFORMATION:
TDGA CLASS: PIN: LABEL:
NA NA NA
1. FIRST AID MEASURES
INHALATION:
Promptly remove to fresh air. Restore and/or support breathing. Consult a physician for observation and treatment.
INGESTION:
If conscious give 2-3 glasses of water to drink to dilute the material. DO NOT INDUCE VOMITING. Contact a physician.
SKIN:
Remove contaminated clothing. Wash affected area of skin with soap and plenty of water. Get medical attention if irritation persists.
EYES:
Flush eyes promptly with plenty of running water,continuing at least 15 minutes.Get medical attention.
J. Soda ash is produced in two principal grades: Light soda ash and Dense soda ash. These grades differ only in physical characteristics such
as bulk density and size and shape of particles,which influence flow characteristics and angle of response. Other physical properties,as well
as chemical properties and properties of solutions,are common to both grades of soda ash.
K. LC50(guinea pig): 800 mg/m3,20-hr exposure
The study was based on the effects of sodium combustion products which included sodium hydroxide and sodium carbonate.The test
aerosols, however,consisted of<4 micrometer diameter particles which are much smaller than the smallest particle in this product.
THIS MATERIAL SAFETY DATA SHEET IS OFFERED FOR YOUR INFORMATION, CONSIDERATION AND INVESTIGATION AS
REQUIRED BY FEDERAL HAZARDOUS PRODUCTS ACT AND RELATED LEGISLATION.THE INFORMATION IS BELIEVED TO
BE ACCURATE BUT GENERAL CHEMICAL CANADA LTD. PROVIDES NO WARRANTIES, EITHER EXPRESSED OR IMPLIED.
GCC-1
4

Thermo Fisher
S C I E N T I F I C
SAFETY DATA SHEET
Creation Date 16-June-2009 Revision Date 14-January-2019 Revision Number 6
1. Identification
Product Name Sodium hydroxide
Cat No. : AC206060000; AC206060010; AC206060025; AC206060250;
AC206060100
CAS-No 1310-73-2
Synonyms Caustic soda
Recommended Use Laboratory chemicals.
Uses advised against Food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Company
Importer/Distributor Manufacturer
Fisher Scientific Acros Organics Fisher Scientific
112 Colonnade Road, One Reagent Lane One Reagent Lane
Ottawa, ON K2E 71-6, Fair Lawn, NJ 07410 Fair Lawn, NJ 07410
Canada Tel: [phone]
Tel: [phone]
Emergency Telephone Number
For information US call: 001-800-ACROS-01 /Europe call: [phone]
Emergency Number US:001-201-796-7100/Europe: [phone]
CHEMTREC Tel. No.US:001-800-424-9300/Europe:001-703-527-3887
2. Hazard(s) identification
Classification
WHMIS 2015 Classification Classified as hazardous under the Hazardous Products Regulations(SOR/2015-17)
Corrosive to metals Category 1
Skin Corrosion/irritation Category 1 A
Serious Eye Damage/Eye Irritation Category 1
Specific target organ toxicity(single exposure) Category 3
Target Organs- Respiratory system.
Label Elements
Signal Word
Danger
Hazard Statements
May be corrosive to metals
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Sodium hydroxide Revision Date 14-January-2019
Causes severe skin burns and eye damage
May cause respiratory irritation
< >
Precautionary Statements
Prevention
Keep only in original container
Do not breathe dust/fumes/gas/mist/vapours/spray
Wash face, hands and any exposed skin thoroughly after handling
Use only outdoors or in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
Response
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove person to fresh air and keep comfortable for breathing
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER/doctor
Wash contaminated clothing before reuse
Absorb spillage to prevent material damage
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Store in corrosive resistant polypropylene container with a resistant inliner
Store in a dry place
Disposal
Dispose of contents/container to an approved waste disposal plant
3. Composition/Information on Ingredients
Component CAS-No Weight%
Sodium hydroxide 1310-73-2 100
4. First-aid measures
General Advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids,for at least 15 minutes.
Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Call a physician immediately.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if
victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory medical device. Call a
physician or Poison Control Center immediately.
Ingestion Do not induce vomiting. Immediate medical attention is required. Never give anything by
mouth to an unconscious person. Drink plenty of water.
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Sodium hydroxide Revision Date 14-January-2019
Most important symptoms/effects Causes burns by all exposure routes. . Product is a corrosive material. Use of gastric
lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should
be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue
and danger of perforation
Notes to Physician Treat symptomatically
5. Fire-fighting measures
Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam.
Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire
Flash Point No information available
Method - No information available
Autoignition Temperature
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes.
Hazardous Combustion Products
Sodium oxides Hydrogen
Protective Equipment and Precautions for Firefighters
As in any fire,wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)and full
protective gear.Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health Flammability Instability Physical hazards
3 0 1 N/A
6. Accidental release measures
Personal Precautions Use personal protective equipment. Evacuate personnel to safe areas.Avoid contact with
skin, eyes and clothing.
Environmental Precautions Do not allow material to contaminate ground water system. Should not be released into the
environment. Do not flush into surface water or sanitary sewer system. See Section 12 for
additional ecological information.
Methods for Containment and Clean Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for
Up disposal.
7. Handling and storage
Handling Wear personal protective equipment. Use only under a chemical fume hood. Do not get in
eyes, on skin, or on clothing. Do not breathe dust. Do not ingest.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.
8. Exposure controls / personal protection
Exposure Guidelines
Component Alberta British Ontario TWAEV Quebec ACGIH TLV OSHA PEL NIOSH IDLH
Columbia
Sodium hydroxide Ceiling:2 mg/m3 Ceiling:2 mg/m3 CEV:2 mg/m3 Ceiling:2 mg/m3 Ceiling:2 mg/m3 Ceiling:2 mg/m3 IDLH: 10 mg/m3
TWA:2 m /m3 Ceiling:2 m /m3
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Sodium hydroxide Revision Date 14-January-2019
Legend
ACGIH-American Conference of Governmental Industrial Hygienists
OSHA-Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures
Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location.
Wherever possible, engineering control measures such as the isolation or enclosure of the process,the introduction of process or
equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to
control hazardous materials at source
Personal protective equipment
Eye Protection Goggles
Hand Protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Glove material Breakthrough time Glove thickness Glove comments
Neoprene >480 minutes 0.45 mm As tested under EN374-3
Butyl rubber >480 minutes 0.35 mm Determination of Resistance to
Permeation by Chemicals
Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. (Refer to manufacturer/supplier for information)gloves are suitable for the task: Chemical compatability,
Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local
conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.
Respiratory Protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Follow the
OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European
Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly
Recommended Filter type: Particulates filter conforming to EN 143
When RPE is used a face piece Fit Test should be conducted
Environmental exposure controls
Prevent product from entering drains.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use.Wash hands before
breaks and at the end of workday.
9. Physical and chemical properties
Physical State Solid
Appearance White
Odor Odorless
Odor Threshold No information available
pH 14 (5 %)
Melting Point/Range 318 °C / 604.4 °F
Boiling Point/Range 1390 °C / 2534 °F @ 760 mmHg
Flash Point No information available
Evaporation Rate Not applicable
Flammability(solid,gas) Not flammable
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure 1 mbar @ 700 °C
Vapor Density Not applicable
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Sodium hydroxide Revision Date 14-January-2019
Specific Gravity No information available
Bulk Density 2.13 g/cm3
Solubility Soluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula H Na O
Molecular Weight 40
10. Stability and reactivity
Reactive Hazard Yes
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Excess heat.
Incompatible Materials Strong oxidizing agents,Acids, Metals, Water
Hazardous Decomposition Products Sodium oxides, Hydrogen
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
11. Toxicological information
Acute Toxicity
Product Information
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Sodium hydroxide 140-340 mg/kg (Rat) 1350 mg/kg (Rabbit) Not listed
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Causes severe burns by all exposure routes
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Sodium hydroxide 1310-73-2 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT-single exposure Respiratory system
STOT-repeated exposure None known
Aspiration hazard No information available
Symptoms /effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
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Sodium hydroxide Revision Date 14-January-2019
delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
12. Ecological information
Ecotoxicity
Do not empty into drains. Large amounts will affect pH and harm aquatic organisms.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
Sodium hydroxide Not listed LC50:=45.4 mg/L,96h Not listed Not listed
static(Oncorhynchus
mykiss)
Persistence and Degradability Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.
13. Disposal considerations
Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
14. Transport information
DOT
UN-No UN1823
Proper Shipping Name SODIUM HYDROXIDE, SOLID
Hazard Class 8
Packing Group II
TDG
UN-No UN1823
Proper Shipping Name SODIUM HYDROXIDE, SOLID
Hazard Class 8
Packing Group II
IATA
UN-No UN1823
Proper Shipping Name Sodium hydroxide, solid
Hazard Class 8
Packing Group II
IMDG/IMO
UN-No UN1823
Proper Shipping Name Sodium hydroxide, solid
Hazard Class 8
Packing Group II
15. Regulatory information
All of the components in the product are on the following Inventory lists: X= listed
International Inventories
Component DSL I NDSL I TSCA I EINECS I ELINCS I NLP I PICCS ENCS AICS IECSC KECL
Sodium hydroxide I X X 215-185-5 X I X I X I X I X
Canada
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Sodium hydroxide Revision Date 14-January-2019
SDS in compliance with provisions of information as set out in Canadian Standard- Part 4, Schedule 1 and 2 of the Hazardous
Products Regulations(HPR)and meets the requirements of the HPR(Paragraph 13(1)(a)of the Hazardous Products Act(HPA)).
16. Other information
Prepared By Regulatory Affairs
Thermo Fisher Scientific
Email: [e-mail]
Creation Date 16-June-2009
Revision Date 14-January-2019
Print Date 14-January-2019
Revision Summary This document has been updated to comply with the requirements of WHMIS 2015 to align
with the Globally Harmonised System (GHS)for the Classification and Labelling of
Chemicals.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication.The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification.The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
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