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HomeMy WebLinkAboutAQ_AM_20230629_BP_AnnPln_Final 2023-2024 Appendix B Mecklenburg County1 Air Quality Monitoring Group 2023-2024 Annual Monitoring Network Plan - Mecklenburg County Air Quality Mecklenburg County Air Quality A Division of the Mecklenburg County Land Use and Environmental Services Agency 2145 Suttle Avenue Charlotte, NC, 28208 Phone 980-314-3355 • Fax 704-336-4391 June 28, 2023 2 This page intentionally left blank. 3 CERTIFICATION By the signatures below, Mecklenburg County Air Quality (MCAQ) certifies that the information contained in the “2023-2024 Annual Monitoring Network Plan for Mecklenburg County Air Quality” is complete and accurate, to the best of our knowledge, at the time of submittal to USEPA Region 4. However, due to circumstances that may arise during the sampling year, network information may change. A notification of change and a request for approval will be submitted to USEPA Region 4 at that time. Print Name: Danielle Jones Signature: Date: Air Quality Monitoring Manager, MCAQ Print Name: Leslie Rhodes Signature: Date: Director, MCAQ 6/28/2023 6/28/2023 4 This page intentionally left blank. 5 2023- 2024 ANNUAL MONITORING NETWORK PLAN MECKLENBURG COUNTY AIR QUALITY Table of Contents I. INTRODUCTION ........................................................................................................................9 National Ambient Air Quality Standards ..................................................................................10 II. STATION DESCRIPTION BACKGROUND INFORMATION AND DEFINITIONS .........12 1. Station Description................................................................................................................ 12 2. Date Established.................................................................................................................... 12 3. Station Approval Status ........................................................................................................ 12 4. Monitoring Objectives .......................................................................................................... 12 5. Monitoring Station Designations .......................................................................................... 13 6. Monitoring Methods ............................................................................................................. 14 (A) Particulate Matter 10 microns in size (PM10) .....................................................................14 (B) Particulate Matter 2.5 microns in size and coarse (PM2.5, PMC) ........................................15 (C) PM2.5 Speciation Sampling and Analysis ............................................................................15 (D) Sulfur Dioxide (SO2) ..........................................................................................................15 (E) Carbon Monoxide (CO) ......................................................................................................15 (F) Ozone (O3) ...........................................................................................................................16 (G) Nitrogen Dioxide (NO2) ......................................................................................................16 (H) Reactive Oxides of Nitrogen (NOy) ....................................................................................16 (I) Speciated Volatile Organic Compounds (VOCs) .................................................................16 (J) Carbonyls .............................................................................................................................16 (K) Air Toxics ...........................................................................................................................17 (L) Lead (Pb) .............................................................................................................................17 7. Quality Assurance Status ...................................................................................................... 17 8. Scale of Representativeness .................................................................................................. 18 9. Data Processing and Reporting ............................................................................................. 19 III. NETWORK SUMMARY ........................................................................................................20 1. Station Table - Criteria Pollutants, NCORE Parameters, and PAMS Monitored ................. 20 2. Site Map ................................................................................................................................ 21 3. Monitoring Methods ............................................................................................................. 22 4. Network Modifications, Waiver Requests, and MOA’s ....................................................... 25 (A) Monitoring Station Siting Modifications ...........................................................................25 (B) Instrument Operation Modification ....................................................................................26 (C) Waivers ..............................................................................................................................27 (D) Memorandum of Agreement ..............................................................................................27 (E) Plan for Making Photochemical Assessment Monitoring Station (PAMS) Measurements ...................................................................................................................................................27 (D) Special Purpose (Non-Regulatory) Monitoring Related to the Colonial Pipeline Spill .....28 IV. AIR MONITORING STATION DESCRIPTIONS ................................................................30 1. Garinger ................................................................................................................................ 30 (A) Garinger Station Table ........................................................................................................30 (B) Garinger Station Description and Statement of Purpose ....................................................32 (C) Garinger Aerial Photograph ................................................................................................36 (D) Garinger Station Photographs .............................................................................................37 6 2. Remount ................................................................................................................................38 (A) Remount Station Table .......................................................................................................38 (B) Remount Station Description and Statement of Purpose ....................................................39 (C) Remount Aerial Photograph ................................................................................................40 (D) Remount Station Photographs ............................................................................................41 3. University Meadows ............................................................................................................. 42 (A) University Meadows Station Table .....................................................................................42 (B) University Meadows Station Description and Statement of Purpose .................................42 (C) University Meadows Aerial Photograph .............................................................................44 (D) University Meadows Station Photographs ..........................................................................45 4. Ramblewood Park ................................................................................................................. 46 (A) Ramblewood Park Station Table ........................................................................................ 46 (B) Ramblewood Park Station Description and Statement of Purpose .....................................46 (C) Ramblewood Park Aerial Photograph: ...............................................................................48 (D) Ramblewood Park Station Photographs .............................................................................49 5. Friendship Park ..................................................................................................................... 50 (A) Friendship Park Station Table ............................................................................................ 50 (B) Friendship Park Station Description and Statement of Purpose .........................................50 (C) Friendship Park Aerial Photograph: ....................................................................................52 (D) Friendship Park Station Photographs ..................................................................................53 6. Equipment Drive ................................................................................................................... 54 (A) Equipment Drive Station Table .......................................................................................... 54 (B) Equipment Drive Station Description and Statement of Purpose .......................................54 (C) Equipment Drive Aerial Photograph ...................................................................................55 (D) Equipment Drive Site Photographs .....................................................................................56 V. REFERENCES..........................................................................................................................58 VI. APPENDIX A ..........................................................................................................................59 Monitoring Equipment Replacement Tables ............................................................................ 59 VII. APPENDIX B.........................................................................................................................68 Memorandum of Agreement ..................................................................................................... 68 VIII. APPENDIX C .......................................................................................................................77 Site Review Forms Calendar Year 2023 ................................................................................... 77 IX. APPENDIX D ..........................................................................................................................98 PM2.5 Continuous Monitor Comparability Assessment .......................................................... 98 7 ................................................................................................................................................... 99 X. APPENDIX E .........................................................................................................................101 PAMS Parameter Codes - Auto-GC-FID Speciated VOCs .................................................... 101 8 XI. APPENDIX F ........................................................................................................................104 Responses Public Comments on Annual Network Plan ......................................................... 104 9 I. INTRODUCTION The Mecklenburg County Air Quality (MCAQ) monitoring program, a division of the Mecklenburg County Land Use and Environmental Services Agency (LUESA); provides air quality monitoring services in Mecklenburg County, North Carolina. Mecklenburg County Air Quality is a state “certified local air pollution program” whose purpose is to improve and maintain ambient air quality and reduce exposure to unhealthy levels of air pollution. MCAQ has operated an air quality monitoring program since the 1960’s. The air monitoring services provided by the program measure concentrations of the criteria air pollutants (carbon monoxide - CO, nitrogen dioxide - NO2, sulfur dioxide - SO2, particulate matter - PM, lead - Pb, and ozone - O3) in accordance with USEPA regulatory requirements. The Clean Air Act, which was last amended in 1990, requires EPA to set National Ambient Air Quality Standards or NAAQS (40 CFR part 50) for pollutants considered harmful to public health and the environment. The Clean Air Act established two types of national air quality standards: 1) Primary standards set limits to protect public health, including the health of "sensitive" populations such as asthmatics, children, and the elderly; and 2) Secondary standards set limits to protect public welfare, including protection against decreased visibility, damage to animals, crops, vegetation, and buildings. The EPA Office of Air Quality Planning and Standards (OAQPS) has set National Ambient Air Quality Standards (NAAQS) for six principal pollutants (criteria pollutants). The NAAQS are listed in Table 1: 10 National Ambient Air Quality Standards Pollutant Primary/ Secondary Averaging Time Level Form Carbon Monoxide (CO) primary 8 hours 9 ppm Not to be exceeded more than once per year 1 hour 35 ppm Lead (Pb) primary and secondary Rolling 3 month average 0.15 μg/m3 (1) Not to be exceeded Nitrogen Dioxide (NO2) primary 1 hour 100 ppb 98th percentile of 1-hour daily maximum concentrations, averaged over 3 years primary and secondary 1 year 53 ppb (2) Annual Mean Ozone (O3) primary and secondary 8 hours 0.070 ppm (3) Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years Particle Pollution (PM) PM2.5 primary 1 year 12.0 μg/m3 annual mean, averaged over 3 years secondary 1 year 15.0 μg/m3 annual mean, averaged over 3 years primary and secondary 24 hours 35 μg/m3 98th percentile, averaged over 3 years PM10 primary and secondary 24 hours 150 μg/m3 Not to be exceeded more than once per year on average over 3 years Sulfur Dioxide (SO2) primary 1 hour 75 ppb (4) 99th percentile of 1-hour daily maximum concentrations, averaged over 3 years secondary 3 hours 0.5 ppm Not to be exceeded more than once per year (1) In areas designated nonattainment for the Pb standards prior to the promulgation of the current (2008) standards, and for which implementation plans to attain or maintain the current (2008) standards have not been submitted and approved, the previous standards (1.5 µg/m3 as a calendar quarter average) also remain in effect. (2) The level of the annual NO2 standard is 0.053 ppm. It is shown here in terms of ppb for the purposes of clearer comparison to the 1-hour standard level. (3) Final rule signed October 1, 2015, and effective December 28, 2015. The previous (2008) O3 stan dards additionally remain in effect in some areas. Revocation of the previous (2008) O3 standards and transitioning to the current (2015) standards will be addressed in the implementation rule for the current standards. (4) The previous SO2 standards (0.14 ppm 24-hour and 0.03 ppm annual) will additionally remain in effect in certain areas: (1) any area for which it is not yet 1 year since the effective date of designation under the current (2010) standards, and (2) any area for which an implementation plan providing for attainment of the current (2010) standard has not been submitted and approved and which is designated nonattainment under the previous SO2 standards or is not meeting the requirements of a SIP call under the previous SO2 standards (40 CFR 50 .4(3)). A SIP call is an EPA action requiring a state to resubmit all or part of its State Implementation Plan to demonstrate attainment of the required NAAQS. Table 1. 11 The MCAQ air monitoring program operates a network of state and local air monitoring stations (SLAMS) in Mecklenburg County. The current network configuration consists of five monitoring stations that measure concentrations of criteria air pollutants, and the ongoing implementation of an additional Near-Road NO2 monitoring station. The SLAMS network operated by MCAQ includes monitoring for criteria pollutants, meteorological parameters, NCORE multi-pollutant parameters, and speciation trends network (STN) monitoring. Occasionally, special purpose monitoring (SPM) is conducted. The annual monitoring network plan, as stated in 40 CFR Part 58.10(b)(1-13), Annual Monitoring Network Plan and Periodic Network Assessment; must contain the following information for each existing and proposed site: (1) The AQS site identification number. (2) The location, including street address and geographical coordinates. (3) The sampling and analysis method(s) for each measured parameter. (4) The operating schedules for each monitor. (5) Any proposals to remove or move a monitoring station within a period of 18 months following plan submittal. (6) The monitoring objective and spatial scale of representativeness for each monitor as defined in appendix D to this part. (7) The identification of any sites that are suitable and sites that are not suitable for comparison against the annual PM2.5 NAAQS as described in §58.30. (8) The MSA, CBSA, CSA or other area represented by the monitor. (9) The designation of any Pb monitors as either source-oriented or non-source-oriented according to Appendix D to 40 CFR part 58. (10) Any source-oriented monitors for which a waiver has been requested or granted by the EPA Regional Administrator as allowed for under paragraph 4.5(a)(ii) of Appendix D to 40 CFR part 58. (11) Any source-oriented or non-source-oriented site for which a waiver has been requested or granted by the EPA Regional Administrator for the use of Pb-PM10 monitoring in lieu of Pb-TSP monitoring as allowed for under paragraph 2.10 of Appendix C to 40 CFR part 58. (12) The identification of required NO2 monitors as near-road, area-wide, or vulnerable and susceptible population monitors in accordance with Appendix D, section 4.3 of this part. (13) The identification of any PM2.5 FEMs and/or ARMs used in the monitoring agency's network where the data are not of sufficient quality such that data are not to be compared to the NAAQS. For required SLAMS where the agency identifies that the PM2.5 Class III FEM or ARM does not produce data of sufficient quality for comparison to the NAAQS, the monitoring agency must ensure that an operating FRM or filter-based FEM meeting the sample frequency requirements described in §58.12 or other Class III PM2.5 FEM or ARM with data of sufficient quality is operating and reporting data to meet the network design criteria described in Appendix D to this part. This report constitutes the Mecklenburg County Air Quality “annual monitoring network plan” (ANP). The remaining sections of the plan are summarized below: 12 II. Station Description Background Information and Definitions: This section provides an overview and definition of “Station Description”, “Date Site Established”, “Station Approval Status”, “Monitoring Objectives”, “Monitoring Station Designations”, “Monitoring Methods”, “Quality Assurance Status”, “Scale or Representativeness”, and a “Data Processing and Reporting” summarization. III. Network Summary: This section presents an overview of the sites and monitors in Mecklenburg County. It includes a listing of proposed changes to the current network. IV. Air Monitoring Station Description: In this section each air monitoring station is described in detail. II. STATION DESCRIPTION BACKGROUND INFORMATION AND DEFINITIONS 1. Station Description Specific information is provided to show the location of the monitoring equipment at the site, if the site is in a combined statistical area (CSA), Core-based Statistical Area (CBSA), or Metropolitan Statistical Area (MSA), the AQS identification number, the GPS coordinates, and evidence that the stations monitors and monitor probes conform to the requirements of Appendices A, B, C, D, and E of 40 CFR 58, where applicable. 2. Date Established The date when each existing monitoring station was established is shown in the description. For those stations, which are proposed, an expected startup date is provided. 3. Station Approval Status Each monitoring station in the existing network has been reviewed with the purpose of determining whether it meets all design criteria for inclusion in the SLAMS network. 4. Monitoring Objectives Per 40 CFR 58 Appendix D, Section 1.1: “The ambient air monitoring networks must be designed to meet three basic monitoring objectives. These basic objectives are listed below. The appearance of any one objective in the order of this list is not based upon a prioritized scheme. Each objective is important and must be considered individually. (a) Provide air pollution data to the general public in a timely manner. Data can be presented to the public in a number of attractive ways including through air quality maps, newspapers, internet sites, and as part of weather forecasts and public advisories. (b) Support compliance with ambient air quality standards and emissions strategy development. Data from FRM (Federal Reference Method), FEM (Federal Equivalent Method), and ARM (Approved Regional Method) monitors for NAAQS pollutants will be used for comparing an area’s air pollution levels against the NAAQS. Data from monitors of various types can be used in the development of attainment and maintenance plans. SLAMS, and especially NCORE 13 station data, will be used to evaluate the regional air quality models used in developing emission strategies, and to track trends in air pollution abatement control measures' impact on improving air quality. In monitoring locations near major air pollution sources, source-oriented monitoring data can provide insight into how well industrial sources are controlling their pollutant emissions. (c) Support for air pollution research studies. Air pollution data from the NCORE network can be used to supplement data collected by researchers working on health effects assessments and atmospheric processes, or for monitoring methods development work.” 5. Monitoring Station Designations Most stations described in the air quality surveillance network are designated as State and Local Air Monitoring Stations (SLAMS). The SLAMS include the ambient air quality monitoring sites and monitors that are required by 40 CFR 58 Appendix D and are needed for the monitoring objectives of Appendix D, including NAAQS comparisons, but may serve other data purposes. The SLAMS include National Core multipollutant monitoring stations (NCORE), photochemical assessment monitoring stations (PAMS), Chemical Speciation Network (CSN) / Speciation Trends Network stations (STN), and all other state or locally operated criteria pollutant monitors, operated in accordance with 40 CFR 58, that have not been designated and approved by the Regional Administrator as special purpose monitor (SPM) stations in an annual monitoring network plan. The following are descriptions of the SLAMS (including NCORE, PAMS, and STN) and SPM station designations. (A) SLAMS: The SLAMS make up the ambient air quality monitoring sites that are primarily needed for NAAQS comparisons but may serve other data purposes. SLAMS exclude special purpose monitor (SPM) stations and include NCORE, PAMS, and all other state or locally operated stations that have not been designated as SPM stations. These stations must meet requirements that relate to four major areas: quality assurance, monitoring methodology, sampling interval, and siting of instruments and instrument probes. (B) SPM: Not all monitors and monitoring stations in the air quality surveillance network are included in the SLAMS network. In order to allow the capability of providing monitoring for various reasons such as: special studies, modeling verification and compliance status, and other objectives; certain monitors are designated as Special Purpose Monitors (SPM). These monitors are not committed to any one location or for any specified time period. They may be located as separate monitoring stations or be included at SLAMS locations. Monitoring data may be reported to AQS, provided that the monitors and stations conform to all requirements of the SLAMS network. Specific regulations regarding SPM’s are contained in 40 CFR 58 §58.20. (C) NCORE: The NCORE multipollutant stations are a subset of SLAMS. NCORE stations measure multiple pollutants to provide support to integrated air quality management data needs. NCORE stations include both neighborhood and urban scale measurements in a select number of metropolitan areas and a limited number of rural locations. 14 NCORE stations must measure, at a minimum, PM2.5 particle mass using continuous and integrated/filter-based samplers, speciated PM2.5, PM10-2.5 particle mass, O3, SO2, CO, NO/NOY, wind speed, wind direction, relative humidity, and ambient temperature. (D) Speciation Trends Network (STN): Speciation Trends Network stations are those stations designated to be part of the speciation trends network. These stations collect samples that are analyzed to determine the chemical makeup of PM2.5. The STN is part of the chemical speciation network (CSN) which encompasses the original STN monitoring sites as well as supplemental speciation sites. (E) Photochemical Assessment Monitoring Station (PAMS): These stations are dedicated to obtaining more information about ozone and its precursors. PAMS stations collect and monitor some or all of the following: speciated volatile organic compounds (VOCs), carbonyls, NO/NOy, O3, CO, and meteorological data. 6. Monitoring Methods Sampling and analytical procedures for criteria air pollutant monitoring performed in the MCAQ ambient air monitoring network and used for NAAQS comparison are conducted in accordance with applicable USEPA Designated Federal Reference Methods (FRM) or Federal Equivalent Methods (FEM) unless otherwise noted. Analytical techniques for non-criteria air pollutant monitoring (methods employed that are not USEPA Designated Federal Reference Methods (FRM) or Federal Equivalent Methods (FEM)) are documented in the applicable MCAQ Quality Assurance Project Plan (QAPP) and/or the applicable MCAQ Standard Operating Procedure (SOP). Methods used by MCAQ for criteria pollutant monitoring and selected non-criteria monitoring are listed below: (A) Particulate Matter 10 microns in size (PM10) PM10 samplers operated by MCAQ are operated as federal equivalent method (FEM) samplers and are operated according to the requirements set forth in 40 CFR 50, 40 CFR 58, and 40 CFR 53. Listed below is the USEPA Designated Reference or Equivalent Method used in the MCAQ monitoring network: 15 Method Designation Number Method Code Met One BAM 1020 (PM10)-STP EQPM-0798-122 122 Met One BAM 1020 (PM10)-LC EQPM-0798-122 122 (B) Particulate Matter 2.5 microns in size and coarse (PM2.5, PMC) PM2.5 and PMc (coarse) samplers operated by MCAQ are either FRM or FEM samplers. Listed below are the applicable USEPA Designated Reference or Equivalent Method used in the MCAQ monitoring network: Method Designation Number Method Code R & P Partisol-Plus 2025 PM-2.5 Seq. RFPS-0498-118 145 Met One BAM 1020 (PM2.5) EQPM-0308-170 170 Met One BAM 1022 (PM2.5) EQPM-1013-209 209 Met One BAM 1020 (PM10-2.5) EQPM-0709-185 185 (C) PM2.5 Speciation Sampling and Analysis In addition to operating PM2.5 samplers that determine only PM2.5 mass values, MCAQ operates PM2.5 speciation samplers which collect samples that are analyzed to determine the chemical composition of the PM2.5 fraction. Data collected using these methods cannot be compared to the NAAQS. Listed below is the method used in the MCAQ monitoring network: Method Designation Number Method Code Met One SuperSASS NA 810 URG-3000N (Carbon Channel) NA Various (D) Sulfur Dioxide (SO2) Instruments used to continuously monitor sulfur dioxide levels in the atmosphere employ the pulsed UV fluorescence method. Listed below is the USEPA Designated Reference or Equivalent Method used in the MCAQ monitoring network: Method Designation Number Method Code Thermo Electron 43A, 43C-TLE, 43i , EQSA-0486-060 560 43i-TLE, 43iQ (E) Carbon Monoxide (CO) Continuous monitoring for carbon monoxide is performed using the non-dispersive infrared (gas filter correlation) method. Listed below is the USEPA Designated Reference or Equivalent Method used in the MCAQ monitoring network: Method Designation Number Method Code Thermo Electron or Thermo RFCA-0981-054 554 Environmental Instruments 48, 48C, 48i, 48i-TLE, 48iQ 16 (F) Ozone (O3) Ozone is monitored using the UV photometry method. Listed below is the USEPA Designated Reference or Equivalent Method used in the MCAQ monitoring network: Method Designation Number Method Code Thermo Electron or Thermo EQOA-0880-047 047 Environmental Instruments 49, 49C, 49i (G) Nitrogen Dioxide (NO2) The methods used to monitor the nitrogen dioxide level in ambient air are photolytic- chemiluminescence and Cavity Attenuated Phase Shift (CAPS). Listed below are the USEPA Designated Reference or Equivalent Methods used in the MCAQ monitoring network: Method Designation Number Method Code Teledyne API, T200UP EQNA-0512-200 200 Teledyne API, T200U RFNA-1194-099 599 Teledyne API, N500 EQNA-0320-256 256 (H) Reactive Oxides of Nitrogen (NOy) The chemiluminescence method is used to monitor the reactive oxides of nitrogen levels in ambient air. Listed below is the instrumentation used in the MCAQ monitoring network: Method Designation Number Method Code Thermo Environmental Instr. 42C-Y, NA 674 42i-Y Teledyne API T200U NO/NOy NA 699 (I) Speciated Volatile Organic Compounds (VOCs) The auto-gas chromatograph (auto-GC) flame ionization detection (FID) method is used to monitor speciated volatile organic compounds in ambient air. Listed below is the instrumentation used in the MCAQ monitoring network: Method Designation Number Method Code Agilent Technologies 7890B NA 228 (J) Carbonyls Carbonyl monitoring is performed using the high performance liquid chromatography (HPLC) method. Listed below is the instrumentation used in the MCAQ monitoring network: Method Designation Number Method Code ATEC 8000 Carbonyl Sampler Compendium Method TO-11A 202 17 (K) Air Toxics Air toxics sampling in Mecklenburg County is operated using equipment maintained by the North Carolina Division of Air Quality. Listed below is the method used in the MCAQ monitoring network: Method Designation Number Method Code Compendium Method for Toxic Organics Compendium Method TO-15 150 (L) Lead (Pb) Lead (Pb) monitoring is not currently being conducted and is not currently required per 40 CFR 58 Appendix D §4.5. The most recent Pb monitoring was conducted from January 1, 2012 through April 30, 2016. Pb monitoring at the Garinger High School NCORE monitoring station (37-119-0041) was discontinued on April 30, 2016 in accordance with revisions to NCORE design criteria per 40 CFR 58, Appendix D(3). Concentrations of Pb measured at the station were well below the NAAQS (0.15 g/m3). The maximum rolling three (3) month average for the period January 1, 2012 through April 30, 2016 was 0.003 g/m3, approximately 2% of the NAAQS. The Pb-PM10 low volume method was used for monitoring lead in the MCAQ monitoring network for the period from January 1, 2012 through April 30, 2016. Analysis for lead in PM10 collected on the filters was conducted in accordance with 40 CFR 50, Appendix Q. Listed below is the method used in the MCAQ monitoring network during the period: Method Designation Number Method Code R & P Partisol-Plus 2025 PM-10 Seq. RFPS-1298-127 811 7. Quality Assurance Status MCAQ operates according to EPA approved Quality Assurance Project Plans (QAPP) and Standard Operating Procedures (SOP). The MCAQ QAPP for criteria pollutants (including NCore NOy and near-road NO2) was approved by US EPA on October 19, 2022. The MCAQ PAMS QAPP was approved by US EPA on February 15, 2021. The MCAQ Quality Management Plan (QMP) was approved by US EPA on November 17, 2022. MCAQ has an extensive quality assurance program to ensure that all air monitoring data collected meets established criteria for precision and bias. Staff members perform independent audits of instrumentation on a regularly scheduled basis to ensure that each instrument is calibrated and operating properly. Data validation is performed monthly to ensure data reported by each instrument is recorded accurately in the air quality monitoring database. Air Toxics monitoring in Mecklenburg County is operated in conjunction with NCDAQ and according to NCDAQ Urban Air Toxics’ (UAT) QAPP (Effective date: 12/21/2022) . 18 8. Scale of Representativeness Each station in the monitoring network must be described in terms of the physical dimensions of the air parcel nearest the monitoring station throughout which actual pollutant concentrations are reasonably similar. Area dimensions or scales of representativeness used in the network description are: (a) Microscale - defines the concentration in air volumes associated with area dimensions ranging from several meters up to about 100 meters. (b) Middle scale - defines the concentration typical of areas up to several city blocks in size with dimensions ranging from about 100 meters to 0.5 kilometers. (c) Neighborhood scale – defines concentrations within an extended area of a city that has relatively uniform land use with dimensions ranging from about 0.5 to 4.0 kilometers. (d) Urban scale - defines an overall citywide condition with dimensions on the order of 4 to 50 kilometers. (e) Regional Scale - defines air quality levels over areas having dimensions of 50 to hundreds of kilometers. Closely associated with the area around the monitoring station where pollutant concentrations are reasonably similar are the basic monitoring exposures of the station. There are six basic exposures: (a) Stations located to determine the highest concentrations expected to occur in the area covered by the network. (b) Stations located to determine representative concentrations in areas of high population density. (c) Stations located to determine the impact on ambient pollution levels of significant sources or source categories. (d) Stations located to determine general background concentration levels. (e) Stations located to determine the extent of regional pollutant transport among populated areas; and in support of secondary standards. (f) Stations located to measure air pollution impacts on visibility, vegetation damage, or other welfare-based impacts. The design intent in siting stations is to correctly match the area dimensions represented by the sample of monitored air with the area dimensions most appropriate for the monitoring objective of the station. The following relationship of the six basic objectives and the scales of representativeness are appropriate when siting monitoring stations: 19 Site Type Appropriate Siting Scales 1. Highest concentration..... Micro, middle, neighborhood (sometimes urban or regional for secondarily formed pollutants). 2. Population oriented....... Neighborhood, urban. 3. Source impact............. Micro, middle, neighborhood. 4. General/background & regional transport........... Urban, regional. 5. Welfare-related impacts... Urban, regional. Table 2. 9. Data Processing and Reporting MCAQ ambient air quality monitoring data are stored in the Agilaire AirVision SQL database located at the Valerie Woodard Center, 3205 Freedom Drive, Charlotte, North Carolina. The database is maintained by the Mecklenburg County Information Technology Services department. Monthly data validation processes are conducted by MCAQ air monitoring specialist and senior air monitoring specialists as data is collected. After monthly data validation procedures are successfully completed; data are transmitted to the US EPA’s national Air Quality System (AQS) database. The AQS database is maintained by US EPA as the official repository of the fully quality assured ambient air quality dataset. Data submitted to the AQS database are certified by the air monitoring program manager by May 1st of each year in accordance with 40 CFR 58 §58.15. 20 III. NETWORK SUMMARY 1. Station Table - Criteria Pollutants, NCORE Parameters, and PAMS Monitored EPA AQS ID Station Name CO NO2 O3 PM2.5 FRM PM2.5 Cont1 FEM PM10 Cont2 SO2 PM10- 2.5 Cont3 NOy Speciate d VOCs Carbonyls 37-119-0041 Garinger (NCORE/ PAMS) X X Area - wide X X4 X X X X X X X 37-119-0045 Remount X X Near - road X5 X 37-119-0046 University Meadows X 37-119-0047 PM10 Ramblewood Park X 37-119-0048 PM2.5 Friendship Park X 37-119-0050 Equipment Dr6 X Near - road 1) PM2.5 Continuous (BAM 1020/1022). 2) PM10 Cont: PM10 Continuous. 3) PM10-2.5 Cont: PM10-2,5 Continuous. 4) NCORE Required 1 in 3 day filter-based sampling (FRM) and collocation for BAM 1020 primary. 5) Collocated 1 in 12 day filter-based FRM collocation for BAM 1022 primary. 6) Proposed 2nd-Near-Road NO2 monitoring site Table 3. 21 2. Site Map AIR QUALITY MONITORING STATIONS MECKLENBURG COUNTY, NC Figure 1. 22 3. Monitoring Methods Site Parameter Instrument / Method Meth. Code1 Param. Code2 POC MT/MNC3 37-119-0041 SO2 Pulsed UV Fluorescent 560 42401 2 SLAMS NCORE 37-119-0041 CO Gas Filter Correlation 554 42101 4 SLAMS NCORE 37-119-0041 NO- NO2-NOx Area-wide Chemi- luminescence 599 42601, 42602, 42603 1 SLAMS NCORE 37-119-0041 NO- NO2-NOx Area-wide CAPS 256 42601, 42602, 42603 1 SLAMS PAMS 37-119-0041 NO-Dif-NOy Chemi- luminescence 674 699 42601, 42612, 42600 2 SLAMS NCORE PAMS 37-119-0041 PM10-2.5 Coarse Met One BAM 1020 System (LC) 185 86101 4 SLAMS NCORE 37-119-0041 PM10 Met One BAM 1020 (LC) 122 85101 4 SLAMS 37-119-0041 PM10 Met One BAM 1020 (STP) 122 81102 4 SLAMS 37-119-0041 PM2.5 Met One BAM 1020 170 88101 3 SLAMS 37-119-0041 Ozone UV Photometric 047 44201 1 SLAMS NCORE PAMS 37-119-0041 PM2.5 FRM 145 88101 1 SLAMS NCORE 37-119-0041 PM2.5 STN-Met One/URG 810 Multiple 5 CSN NCORE 37-119-0041 Speciated VOCs4 Auto-GC-FID 228 Multiple4 6 SLAMS NCORE PAMS 37-119-0041 Carbonyls – Formaldehyde Acetaldehyde HPLC 202 43502 43503 4 SLAMS NCORE PAMS 37-119-0041 Mixing Layer Height Vaisala 011 61301 1 SLAMS PAMS 23 Site Parameter Instrument / Method Meth. Code1 Param. Code2 POC MT/MNC3 37-119-0041 Barometric Pressure R. M. Young 011 64101 1 SLAMS PAMS 37-119-0041 Outdoor Temperature R. M. Young 020 62101 1 SLAMS NCORE PAMS 37-119-0041 Precipitation R. M. Young 011 65102 1 SLAMS PAMS 37-119-0041 Relative Humidity Met One 012 62201 1 SLAMS NCORE PAMS 37-119-0041 Solar Radiation Matrix 011 63301 1 SLAMS PAMS 37-119-0041 Wind Direction- Resultant R. M. Young 068 61104 1 SLAMS NCORE PAMS 37-119-0041 Wind Speed- Resultant R. M. Young 068 61103 1 SLAMS NCORE PAMS 37-119-0041 Wind Direction- Scalar R. M. Young 068 61102 1 SLAMS 37-119-0041 Wind Speed- Scalar R. M. Young 068 61101 1 SLAMS 37-119-0041 UV Radiation Kipp & Zonen 011 63302 1 SLAMS PAMS 37-119-0045 NO- NO2-NOx Near-road FEM 200 42601, 42602, 42603 1 SLAMS 37-119-0045 NO- NO2-NOx Near-road CAPS 256 42601, 42602, 42603 1 SLAMS 37-119-0045 CO Gas Filter Correlation 554 42101 1 SLAMS 37-119-0045 PM2.5 Met One BAM 1022 209 88101 3 SLAMS 37-119-0045 PM2.5 FRM 145 88101 1 SLAMS 37-119-0045 Relative Humidity Met One 012 62201 1 SLAMS 37-119-0045 Outdoor Temperature R. M. Young 020 62101 1 SLAMS 37-119-0045 Wind Direction- Resultant R. M. Young 068 61104 1 SLAMS 37-119-0045 Wind Speed- Resultant R. M. Young 068 61103 1 SLAMS 24 Site Parameter Instrument / Method Meth. Code1 Param. Code2 POC MT/MNC3 37-119-0045 Wind Direction- Scalar R. M. Young 068 61102 1 SLAMS 37-119-0045 Wind Speed- Scalar R. M. Young 068 61101 1 SLAMS 37-119-0046 Ozone UV Photometric 047 44201 1 SLAMS 37-119-0047 PM10 Met One BAM 1020 (STP) 122 81102 4 SLAMS 37-119-0048 PM2.5 Met One BAM 1022 209 88101 3 SLAMS 37-119-0049 NO- NO2-NOx Near-road CAPS 256 42601, 42602, 42603 1 SLAMS Table 4. 1- Meth. Num. = Method Code 2- Param. Num. = Parameter Code 3- MT = Monitor Type: SLAMS – State and Local Air Monitoring Station, SPM – Special Purpose, NON – Non- regulatory. MNC = Monitor Network Code: NCORE – National Core, CSN – Chemical Speciation Network, PAMS – Photochemical Assessment Monitoring Station 4 – See parameter codes for speciated VOCs in Appendix E 25 4. Network Modifications, Waiver Requests, and MOA’s (A) Monitoring Station Siting Modifications 1. Nitrogen Dioxide (NO2) Monitoring – MCAQ currently operates two nitrogen dioxide monitoring stations. An area-wide NO2 monitoring station is operated at the Garinger High School location (37-119-0041) and a near-road NO2 station is operated at the Remount location (37-119-0045). 40 CFR 58 Appendix D, §4.3.2(a) requires implementation of an additional near-road NO2 monitoring station in any CBSA with a population of 2,500,000 persons or more. The July 1, 2019 population estimate for the Charlotte-Concord-Gastonia, NC-SC CBSA was greater than 2.5 million people. The Charlotte-Gastonia-Concord, NC-SC CBSA population estimate for July 1, 2019 is 2,636,883. In consultation with U.S. EPA Region 4, MCAQ conducted a search for suitable near-road sites in accordance siting criteria detailed in the Near-Road NO2 Monitoring Technical Assistance Document (“TAD”). Discussions with U.S. EPA monitoring staff resulted in the determination of the optimal location for the establishment of an additional near-road NO2 station on Equipment Drive in Charlotte, NC. This proposed site is located adjacent to I-85, between exits 40 and 41. This location was identified as the top priority from a list of proposed locations based on safety, ease of access, and limited site prep, in addition to the site meeting near-road NO2 siting requirements. MCAQ prepared a Notification of Change – Addendum to the 2021-2022 Annual Network Plan for Mecklenburg County Air Quality (“MCAQ-Plan”) site to incorporate details about the additional near-road NO2 monitoring station at Equipment Drive, as required by 40 CFR 58 Appendix D, §4.3.2(a) and referenced in Section 4(a) “Monitoring Station Siting Modifications” of the annual network plan. The addendum was posted for public notice and comment on the MCAQ web site for a period of 30 days beginning on March 22, 2022 and ending on April 21, 2022. No comments were received. MCAQ submitted the addendum and a site proposal to U.S. EPA on May 13, 2022, for final approval to establish the Equipment Drive station (proposed new AQS ID: 37-119-0050) in accordance with the “Notification of Change – Addendum to the MCAQ – Plan”. MCAQ secured Armstrong Glenn to provide engineering and design services for the site. Site drawings were drafted, reviewed, and revised to meet site specifications and NC Department of Transportation (NCDOT) requirements. A Non-Utility Encroachment Permit has been obtained from NCDOT, and MCAQ’s project management team for the Equipment Drive site met with Duke Energy at the site to finalize details for a meter service request and to discuss specification requirements for the utility encroachment agreement application. Additionally, a fee proposal has been obtained for electrical engineering design services and coordination to identify contractors to complete the site work has begun. MCAQ has also procured and began and/or completed acceptance testing of the following monitoring equipment for the site: • Teledyne N500 CAPS NO2 analyzer • Teledyne T701H Zero Air System 26 • Teledyne T700 Dynamic Gas Calibrator • ShelterOne Enclosure MCAQ will continue preparing to install and operate the additional near-road NO2 station in the MCAQ monitoring network as funding and personnel resources allow, with the goal of implementation on or before January 1, 2024. This date was extended to account for • Limited/slow response to site development requests for proposals. • Planning delays due to COVID-19. • Necessary network plan addendum revisions and public comment opportunity. • Staffing shortages on the real estate team. • Delayed response time for electrical utility work order requests. (B) Instrument Operation Modification Except for the Photochemical Assessment Monitoring and 2nd Near-Road NO2 implementation (see sections 4(A) and (E)), no startups, shutdowns, or other major “Instrumentation Operation Modifications” are planned at the currently operating monitoring stations in the MCAQ monitoring network for 2023-2024. 27 (C) Waivers MCAQ is not requesting waivers in the 2023-2024 Monitoring Plan. (D) Memorandum of Agreement A Memorandum of Agreement (MOA) dated July 1, 2016 was established forming the Charlotte- Concord-Gastonia Metropolitan Statistical Area (MSA) Criteria Pollutant Air Quality Monitoring Agreement among North Carolina Division of Air Quality (NCDAQ), South Carolina Division of Health and Environmental Control (SCDHEC), and Mecklenburg County Air Quality (MCAQ). The MOA was established to collectively meet the US EPA minimum monitoring requirements for criteria pollutant monitoring deemed necessary to meet the needs of the MSA as determined by all parties. MCAQ is submitting the MOA as an attachment to the monitoring plan to provide notification to US EPA of the purpose, agency roles and responsibilities, and limitations of the MOA. A copy of the agreement is attached as Appendix B to this plan. (E) Plan for Making Photochemical Assessment Monitoring Station (PAMS) Measurements MCAQ is participating in the PAMS implementation process that is being directed by USEPA and associated USEPA vendors (currently USEPA and Battelle, collectively - EPA). On December 20, 2019, EPA finalized a revision to the start date for PAMS. The revision provides state and local agencies an additional two years from the original implementation date of June 1, 2019, to implement the PAMS program requirements. MCAQ began measuring the following parameters on June 1, 2021, and will be measuring these parameters during the 2023 PAMS season (June 1st – August 31st): • Auto-GC speciated VOCs • Ozone • NO/NOy • Mixing Layer Height • Ambient Temperature • Relative Humidity • Barometric Pressure • Wind Speed • Wind Direction • Solar Radiation • Precipitation Due to vendor delays, supply chain interruptions, warranty-covered repairs, and staffing shortages, MCAQ’s implementation of the following parameters was delayed: • True NO2 • UV radiation MCAQ will begin measuring True NO2 and UV radiation by June 1, 2023. Additionally, MCAQ has ordered a carbonyls sampler and intends to be measuring PAMS- required TO-11A carbonyls parameters (formaldehyde and acetaldehyde) by mid-summer 2023 28 (D) Special Purpose (Non-Regulatory) Monitoring Related to the Colonial Pipeline Spill In April 2021, MCAQ and NCDAQ installed an air toxics sampler on-site to evaluate specific volatile air pollutants during clean-up efforts related to the Colonial Pipeline Spill in Huntersville, NC. This special purpose monitor (SPM) was established as the Oehler Air Monitoring Station (AQS ID: 37-119-0049) to screen for specific air toxics and help inform decisions about the need for long-term monitoring. Sampling at the Oehler SPM was paused by NCDAQ on February 5, 2023, due to staffing shortages. Oehler SPM Site Map Figure 2. Oehler SPM Description 29 AQS Site ID: 37-119-0049 Site Name: Oehler Street Address: 14108 Huntersville-Concord Rd. City: Huntersville Latitude: N35.413342˚ Longitude: W80.805735˚ MSA: Charlotte-Gastonia-Concord, NC-SC (#16740) Monitor Type: Special Purpose (Non-regulatory) Operating Schedule: 24-hour, midnight to midnight, 1-in-6 day Monitoring Objective: Public information/Source-oriented Statement of Purpose: Screen for volatile air pollutants at pipeline spill site, Scale: Microscale Suitable for NAAQS Comparison: Not applicable SPM Meets Requirements of Part 58, Appendices A, D, and E: No Date Established: April 4, 2021 Date Terminated: N/A; Paused 2/5/2023 Proposal to move or change: N/A Table 5. A Xonteck 911 sampler collects 24-hour composite air sample every 6 days in stainless steel 6- liter pressurized canisters supplied by NCDAQ. NCDAQ maintains the sampler. MCAQ operates the sampler, retrieves sample cannisters, and returns the sample cannisters to NCDAQ’s lab. Samples are analyzed by the NCDAQ lab for the suite air toxics compounds using the Compendium Method for Toxic Organics 15 (TO-15). The list of compounds can be found in Table 7 of this document. The Oehler SPM is not suitable for NAAQS comparison, as there are not any NAAQS for the suite of air toxics compounds screened for at the Oehler SPM. However, there are exposure guidelines for many of the compounds established by the Centers for Disease Control and Prevention’s (CDC) Agency for Toxic Substances and Disease Registry (ATSDR) and National Institute of Occupational Safety and Health (NIOSH) to which the monitoring data can be compared. To date, data collected and analyzed by the NCDAQ have shown concentrations below the CDC and NIOSH guidelines. Additional information about the Oehler SPM air monitoring can be found at https://deq.nc.gov/about/divisions/waste-management/underground- storage-tanks-section/colonial-pipeline-spill-information-huntersville-nc#air-monitoring. 30 IV. AIR MONITORING STATION DESCRIPTIONS 1. Garinger (A) Garinger Station Table Station Name: Garinger AQS Station Identification Number: 37-119-0041 Location: 1130 Eastway Drive Charlotte, NC 28205 Latitude: N35.240100º Datum: WGS84 Longitude: W80.785683º Elevation: 232 meters Parameter Method Method Code Probe Height (m) Sampling Schedule Ozone UV Photometry 47 4.3 Continuous PM2.5 FRM Gravimetric 145 5.0 1 in 3 day PM2.5 Met One, Speciation 810 4.8 1 in 3 day PM2.5 URG-3000n, Carbon Speciation Various 5.0 1 in 3 day PM2.5 BAM 1020 170 5.2 Continuous PM10 (STP) BAM 1020 122 5.1 Continuous PM10 (LC) BAM 1020 122 5.1 Continuous PM10-2.5 BAM 1020 Coarse 185 5.1 Continuous NO2 Chemiluminescence 599 4.2 Continuous NO2 CAPS 256 4.2 Continuous CO NDIR, GFC 554 4.2 Continuous SO2 Pre-cursor Gas UV Pulsed Fluorescence 560 4.2 Continuous NOy Pre-cursor Gas Chemiluminescence 674 699 7.0 Continuous Speciated VOCs Auto-GC-FID 228 4.2 Continuous from June 1- August 31 Carbonyls Formaldehyde Acetaldehyde HPLC 202 4.2 1 in 3 day Wind Speed R. M. Young 68 10 Continuous Wind Direction R. M. Young 68 10 Continuous 31 Pressure R. M. Young 11 2 Continuous Outdoor Temperature R. M. Young 20 4.9 Continuous Solar Radiation Matrix 11 3.9 Continuous UV Radiation Kipp & Zonen 11 3.9 Continuous Precipitation R. M. Young 11 4.2 Continuous Relative Humidity Met One 12 4.9 Continuous Mixing Layer Height Vaisala 11 NA Continuous Parameter Date Established Date Terminated Ozone March 3, 2000 NA PM2.5 FRM July 29, 1999 NA PM2.5 Speciation (Met One) January 13, 2001 NA PM2.5 Speciation (URG) April 1, 2009 NA PM2.5 BAM 1020 March 6, 2017 NA PM10 BAM 1020 March 6, 2017 NA PM10-2.5 BAM Coarse March 6, 2017 NA NO2 November 12, 1999 NA CO November 11, 1999 NA SO2 Precursor Gas January 1, 2006 NA CO Precursor Gas January 1, 2006 NA NOy Precursor Gas May 4, 2007 NA Speciated VOCs June 1, 2021 NA Carbonyls July 1, 2023 (approx..) Meteorological Parameters January 1, 2003 (latest) NA Nearest Road: Shamrock Drive Distance to Road: 298 meters AADT:1 11,000 Year of Count: 2021 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area2 MSA #: 16740 2022 Population (within 1 mile of property) Projected 2024 Population (within 1 mile of property) 13,101 15,415 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2 https://www.huduser.gov/portal/datasets/geotool/summary.odn Table 6. 32 (B) Garinger Station Description and Statement of Purpose The Garinger High School station is an NCORE multi-pollutant station. The monitoring station is located at 1130 Eastway Drive. The station is located in a grassy area in the southwest corner of the Garinger High School property, near the left field line of the baseball field. The station is located 5.3 kilometers ENE of the Charlotte, NC central business district. There is unrestricted airflow in at least a 270º arc of exposure, including the predominant southwest wind direction. Sample inlets are >20 meters from the nearest trees. The station is generally oriented along the primary summer wind vector (SW to NE), downwind of the central business district of Charlotte, NC. The station is an NCORE multi-pollutant monitoring station. NCORE parameters monitored include trace-level CO, trace-level SO2, trace-level NO and NOy, ozone (O3), PM2.5, PM10-2.5, and meteorological parameters. The PM2.5, NO2 and SO2 monitors are used for NAAQS determination. The NO2 monitor is designated as the area wide NO2 monitor for the CBSA. PAMS is also being implemented at the station. PAMS parameters monitored at the station include Speciated VOCs, O3, NO, NOy, Ambient Temperature, Relative Humidity, Barometric Pressure, Wind Speed, Wind Direction, Solar Radiation, Mixing Layer Height, and Precipitation. As of June 1, 2023, MCAQ intends to also be monitoring the following PAMS parameters at the station: UV radiation, True NO2. By mid-summer 2023, MCAQ intends to also be measuring carbonyls (formaldehyde and acetaldehyde) A 1 in 3-day PM2.5 sequential monitor, a PM2.5 Met One SuperSASS Speciation monitor, and a URG-3000n carbon sampler are located on the roof of the monitoring shelter. The PM2.5 speciation monitors are part of the speciation trends network (STN). Data from these monitors (STN – Met One Super SASS and URG-3000n) are not used for compliance determination. PM2.5 data from the Met One BAM PM Coarse System is reported as parameter 88101 and is designated as a SLAMS for AQI determination and forecasting purposes. PM10 (STP), PM10 (LC), and PM10-2.5 reported from the BAM 1020 coarse system are also designated as SLAMS. The continuous PM10 sampler operates as one of two required PM10 monitoring stations in the MSA. The Garinger station is an NCORE station and as such must meet additional probe siting criteria. The meteorological tower at this station does not comply with the 10x rule for spacing from obstructions for meteorological measurements. Due to terrain features in the Mecklenburg County region it is difficult to locate a site that meets the requirements of the EPA Volume 4 QA/QC guidance for wind speed and wind direction measurements. Large trees are a dominant landscape feature in the area. The closest terrain feature is 2.6x and is to the southeast of the WS/WD instrument. The next closest obstructions (trees) are to the west of the sensor at 3.4x. MCAQ’s 2009 NCORE Plan was approved as acceptable for WS/WD and included documentation noting the deviation from 10x siting criteria. Therefore, WS/WD monitoring is conducted at the current location as documented in the 2009 NCORE Plan as approved by USEPA Region 4 and USEPA Office of Air Quality Planning and Standards (OAQPS). 33 NCORE probe siting guidance for NOy is a probe height of 10 meters. The NOy probe inlet is currently mounted at a height of 7.0 meters. The station complies with the siting requirements of 40 CFR 58 for criteria air pollutants. There are no proposed changes for the siting of this station. It is recommended that the current station status be maintained. Additional Monitoring at Garinger High School Monitoring for air toxics is conducted at the Garinger High School station. The North Carolina Division of Air Quality (NCDAQ) maintains a Xontek 911 sampling device at the Garinger High School station. MCAQ operates the sampler on a 1in 6-day sampling schedule as specified by NCDAQ. The sampler operates on standard time. Whole air samples are collected in stainless steel 6 liter- pressurized canisters supplied by NCDAQ. Analysis of samples is conducted by NCDAQ. Samples are analyzed by NCDAQ using cryogenic pre-concentration gas chromatography with mass spectrometric detection (GC/MS) via the Compendium Method for Toxic Organics 15 (TO-15). The list of compounds is shown in Table 7. Air Toxics sampling at Garinger High School was paused on February 5, 2023, by NCDAQ due to staffing shortages. 34 Parameter Parameter Code Parameter Parameter Code Carbon Disulfide 42153 Bromodichloromethane 43828 Propene 43205 1,2 Dichloropropane (propylene dichloride) 43829 Freon 114 43208 trans-1,3 Dichloropropene 43830 Isobutene 43218 cis-1,3 Dichloropropene 43831 1,3-Butadiene 43220 1,2-Dichloroethene (ethylene dichloride) 43838 Pentane 43231 Ethylene dibromide 43843 Hexane 43242 Vinyl chloride 43860 Cyclopentane 43243 m- & p-Xylene 45109 Isoprene 43248 Benzene 45201 Cyclohexane 43270 Toluene 45202 Freon 22 43359 1,2-Dichloroethane 43815 MTBE 43372 Tetrachloro ethylene (perchloroethylene) 43817 Vinyl Acetate 43447 1,1,2,2-Tetrachloroethane 43818 Acrolein 43505 Bromomethane 43819 Methacrolein 43515 1,1,2-Trichloroethane (vinyl trichloride) 43820 Methyl Ethyl Ketone 43552 Freon 113 43821 3-Pentanone 43553 Ethylbenzene 45203 Ethylpropylketone (3-hexanone) 43557 o-Xylene 45204 Methyl Vinyl Ketone 43558 Bromodichloromethane 43828 Methyl Butyl Ketone 43559 1,2 Dichloropropane (propylene dichloride) 43829 Methyl Isobutyl Ketone 43560 trans-1,3 Dichloropropene 43830 2-Pentanone 43562 cis-1,3 Dichloropropene 43831 Acetonitrile 43702 1,2-Dichloroethene (ethylene dichloride) 43838 Methyl chloride (34hloromethane) 43801 Ethylene dibromide 43843 Methylene chloride 43802 Vinyl chloride 43860 Chloroform 43803 m- & p-Xylene 45109 Carbon tetrachloride 43804 Benzene 45201 Bromoform 43806 1,3,5-Trimethyl-benzene (mesitylene) 45207 Methyl Iodide 43808 1,2,4-Trimethyl-benzene (pseudocumene) 45208 Freon 11 43811 Styrene 45220 Chloroethane 43812 1,2,3-Trimethyl Benzene 45225 1,1-Dichloroethane (Ethylidene Chloride) 43813 Chlorobenzene (phenylchloride) 45801 1,1,1-Trichloroethane (Methyl chloroform) 43814 o-Dichlorobenzene 45805 1,2-Dichloroethane 43815 m-Dichlorobenzene 45806 Tetrachloro ethylene (perchloroethylene) 43817 p-Dichlorobenzene 45807 1,1,2,2-Tetrachloroethane 43818 Benzyl chloride 45809 Bromomethane 43819 1,2,4-Trichlorobenzene 45810 1,1,2-Trichloroethane (vinyl trichloride) 43820 1,4-Dioxane 46201 Freon 113 43821 Freon 12 43823 Trichloroethylene 43824 1,1-Dichloroethene (Vinylidene chloride) 43826 Table 7. 35 OBJECTIVE AND SPATIAL SCALE The monitoring objective of the Garinger O3, CO, NO2, SO2, PM10, and PM2.5 (FRM) monitors is to determine representative concentrations in areas of high population density (population exposure). Maximum concentrations for ozone and PM2.5 may be measured under stagnant meteorological conditions. The station is a neighborhood scale site for all parameters. Data from this station is used to assess compliance with the NAAQS for O3, CO, NO2, SO2, PM10, and PM2.5. The station is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC, NC; Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Chester County, SC; Anson County; Lancaster County, SC; and York County, SC. STATUS AND RECOMMENDATION The Garinger NCORE station meets the required monitoring objectives and siting criteria of 40 CFR 58 Appendices A, B, C, D, and E, where applicable for criteria pollutants. A photochemical assessment station (PAMS) will be implemented at the Garinger NCORE station in accordance with 40 CFR 58 Appendix D, §5(a) and section III.(4). MCAQ will continue preparing to implement the program as funding, supply chain, and personnel resources allow with the goal of full implementation on or before July 1, 2023 for a select set of PAMS parameters. It is recommended that the current site status be maintained. 36 (C) Garinger Aerial Photograph Figure 3. Garinger aerial photograph with 4 km diameter circle. 37 (D) Garinger Station Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 38 2. Remount (A) Remount Station Table Station Name: Remount AQS Station Identification Number: 37-119-0045 Location: 1030 Remount Road Charlotte, NC 28208 Latitude: N35.213171º Datum: WGS84 Longitude: W80.874084º Elevation: 194 meters Parameter Method Method Number Probe Height (m) Sampling Schedule NO2 FEM 200 4.5 Continuous NO2 CAPS 256 4.5 Continuous CO NDIR, GFC 554 4.4 Continuous PM2.5 FRM – Gravimetric 145 2 1 in 12 day PM2.5 BAM 1022 209 2 Continuous Wind Speed R. M. Young 68 10 Continuous Wind Direction R. M. Young 68 10 Continuous Outdoor Temperature R. M. Young 20 4.6 Continuous Relative Humidity Met One 12 4.6 Continuous Parameter Date Established Date Terminated NO2 July 17, 2014 NA CO January 1, 2017 NA PM2.5 FRM 1/3 January 1, 2017 March 30, 2018 PM2.5 FRM Collocated 1/12 April 1, 2018 NA PM2.5 BAM 1022 January 20, 2017 NA Nearest Road: I-77 South Distance to Road: 35 meters AADT:1,2 132,000 Year of Count: 2021 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area2 MSA #: 16740 2022 Population (within 1 mile of property) Projected 2024 Population (within 1 mile of property) 14,919 15,359 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2 https://www.huduser.gov/portal/datasets/geotool/summary.odn Table 8. 39 (B) Remount Station Description and Statement of Purpose The Remount monitoring station is located in a field adjacent to Interstate 77 South (I-77S) between NC Highway 160 and mile marker 8. The station is located 3.2 kilometers SW of the central business district of Charlotte, NC. A federal equivalent method (FEM) NO2 analyzer is located at the Remount monitoring station. The NO2 analyzer monitor type is SLAMS. The NO2 monitor is located 35 meters from the edge of the roadway and is designated as a near-road monitoring station for the CBSA. A federal reference method (FRM) CO analyzer is located at the Remount station and is a SLAMS monitor type. A federal reference method (FRM) PM2.5 and a continuous PM2.5 BAM 1022 are located at the Remount monitoring station. The FRM PM2.5 monitor was designated as a collocated monitor for the PM2.5 BAM 1022 (method 209) on 4/1/2018. FRM sampling was reduced from a frequency of 1in 3 to 1 in 12 on 4/1/2018. The FRM PM2.5 and PM2.5 BAM 1022 monitors are SLAMS. OBJECTIVE AND SPATIAL SCALE The monitoring objective of the Remount NO2 station is to determine the highest concentrations expected to occur in the area covered by the network. The NO2 station is classified as a microscale station. The Remount station is representative of nitrogen dioxide concentrations in the near-road environment. Data is used to assess compliance with the nitrogen dioxide NAAQS. The NO2, CO, FRM-PM2.5, and PM2.5 BAM 1022 monitors are designated as SLAMS. The station is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC, NC; Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Chester County, SC; Anson County: Lancaster County, SC; and York County, SC. STATUS AND RECOMMENDATIONS The station meets the required monitoring objectives and siting criteria of 40 CFR 58 Appendices A, B, C, D, and E; where applicable, for criteria air pollutants. It is recommended that the current station status be maintained. 40 (C) Remount Aerial Photograph Figure 4. Remount aerial photograph with 4 km diameter circle. 41 (D) Remount Station Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 42 3. University Meadows (A) University Meadows Station Table Station Name: University Meadows AQS Station Identification Number: 37-119-0046 Location: 1660 Pavilion Boulevard Charlotte, NC 28262 Latitude: N 35.314158° Datum: WGS84 Longitude: W 80.713469° Elevation: 216 meters Parameter Method Method Number Probe Height (m) Sampling Schedule Ozone UV Photometry 47 4.2 March 1 – Oct. 31, Continuous Parameter Date Established Date Terminated Ozone April 1, 2016 NA Nearest Road: Pavilion Blvd. Distance to Road: 47 meters AADT:1 9200 Year of Count: 2016 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area2 MSA #: 16740 2022 Population (within 1 mile of property) Projected 2024 Population (within 1 mile of property) 14,095 12,725 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2 https://www.huduser.gov/portal/datasets/geotool/summary.odn Table 9. (B) University Meadows Station Description and Statement of Purpose The University Meadows station is located 15 kilometers northeast of the central business district of the city of Charlotte, NC. The station is located approximately 340 meters north of the intersection of Highway 49 and Pavilion Boulevard in Mecklenburg County. The monitoring shelter is in a large grass field at University Meadows Park. There are no obstructions to air flow near the probe. The ozone instrument is operated during the North Carolina ozone monitoring season which begins March 1st and ends October 31st. The ozone instrument operates continuously during the 43 seasonal period. The ozone monitor is a SLAMS monitoring station. Data is used to assess compliance with the NAAQS. OBJECTIVE AND SPATIAL SCALE The monitoring objective of the University Meadows ozone station is to determine the highest concentrations expected to occur in the area covered by the network. The station is an urban scale station which represents ozone levels over several kilometers. Data from this station is used to assess compliance with the NAAQS for ozone. The station is located along the primary summer wind vector in the Charlotte area which is predominated by winds from the southwest (prevailing wind direction). The station should measure peak ozone concentrations in Mecklenburg County. The station is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC, NC; Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Chester County, SC; Anson County; Lancaster County, SC; and York County, SC. . STATUS AND RECOMMENDATIONS The station meets the required monitoring objectives and siting criteria of 40 CFR 58 Appendices A, B, C, D, and E; where applicable, for criteria air pollutants. It is recommended that the current station status be maintained. 44 (C) University Meadows Aerial Photograph Figure 5. University Meadows aerial photograph with 4 km diameter circle. 45 (D) University Meadows Station Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 46 4. Ramblewood Park (A) Ramblewood Park Station Table Station Name: Ramblewood Park AQS Station Identification Number: 37-119-0047 Location: 10200 Nations Ford Road Charlotte, NC 28273 Latitude: N 35.123954° Datum: WGS84 Longitude: W 80.907577° Elevation: 179 meters Parameter Method Method Number Probe Height (m) Sampling Schedule PM10 (STP) BAM 1020 122 2 Continuous Date Monitor Established: PM10 December 16, 2019 Nearest Road: I-485 Distance to Road: 238 meters AADT:1 135,000 Year of Count: 2021 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area 2 MSA #: 16740 2022 Population (within 1 mile of property) Projected 2024 Population (within 1 mile of property) 3,064 2,978 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2 https://www.huduser.gov/portal/datasets/geotool/summary.odn Table 10. (B) Ramblewood Park Station Description and Statement of Purpose The Ramblewood Park station is 238 meters north of I-485 and 920 meters east of the center of the intersection of I-77 and I-485 in southern Mecklenburg County. The station is located 12.9 kilometers (8.0 miles) SSW of the central business district of Charlotte, North Carolina. The monitor is located in a large grass field between soccer field #9 and the baseball field at Ramblewood Park. There are no obstructions to air flow near the probe. The station complies with the siting requirements of 40 CFR §58 Appendices A, C, D, and E for criteria air pollutants (PM10). OBJECTIVE AND SPATIAL SCALE The monitoring objective of the Ramblewood Park station is to measure PM10 concentrations in an area of high population density. The station is a neighborhood scale station which represents PM10 levels over several kilometers. Data from this station is used to assess compliance with the NAAQS for PM10. 47 The station is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC, NC; Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Chester County, SC; Anson County; Lancaster County, SC; and York County, SC. STATUS AND RECOMMENDATIONS The station meets the required monitoring objectives and siting criteria of 40 CFR 58 Appendices A, B, C, D, and E; where applicable, for criteria air pollutants. It is recommended that the current station status be maintained. 48 (C) Ramblewood Park Aerial Photograph: Figure 6. Ramblewood Park aerial photograph with 4 km diameter circle 49 (D) Ramblewood Park Station Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 50 5. Friendship Park (A) Friendship Park Station Table Station Name: Friendship Park AQS Station Identification Number: 37-119-0048 Location: 2310 Cindy Lane Charlotte, NC 28216 Latitude: N 35.281791° Datum: WGS84 Longitude: W 80.851473° Elevation: 224 meters Parameter Method Method Number Probe Height (m) Sampling Schedule PM2.5 BAM 1022 209 2 Continuous Date Monitor Established: PM2.5 January 6, 2020 Nearest Road: Cindy Lane1 Distance to Road: 200 meters 2nd Closest Rd: I-77 South2 Distance to Road: 297 meters AADT:1 8,3002, 116,0003 Year of Count: 20212, 20213 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area4 MSA #: 16740 2022 Population (within 1 mile of property) Projected 2024 Population (within 1 mile of property) 5,089 6,111 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2Traffic information for Cindy Lane 3Traffic information for I-77 South 4 https://www.huduser.gov/portal/datasets/geotool/summary.odn Table 11. (B) Friendship Park Station Description and Statement of Purpose The Friendship Park station is 200 meters south of Cindy Lane and 297 meters west of I-77 South. The station is located 6.4 kilometers (4.0 miles) North of the central business district of Charlotte, North Carolina. The monitor is located in a large grass field between two baseball fields at Friendship Park. There are no obstructions to air flow near the probe. The station complies with the siting requirements of 40 CFR §58 Appendices A, C, D, and E for criteria air pollutants (PM2.5). OBJECTIVE AND SPATIAL SCALE The monitoring objective of the Friendship Park station is to measure PM2.5 concentrations in an area of high population density. The station is a neighborhood scale station which represents 51 PM2.5 levels over several kilometers. Data from this station is used to assess compliance with the NAAQS for PM2.5. The station is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC, NC; Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Chester County, SC; Anson County; Lancaster County, SC; and York County, SC. STATUS AND RECOMMENDATIONS The station meets the required monitoring objectives and siting criteria of 40 CFR 58 Appendices A, B, C, D, and E; where applicable, for criteria air pollutants. It is recommended that the current station status be maintained. 52 (C) Friendship Park Aerial Photograph: Figure 7. Friendship Park aerial photograph with 4 km diameter circle 53 (D) Friendship Park Station Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 54 6. Equipment Drive (A) Equipment Drive Station Table Site Name: Equipment Drive AQS Site Identification Number: 37-119-0050 Location: Equipment Drive (address approximate) Charlotte, NC 28269 Latitude: N 35.27831° Datum: WGS84 Longitude: W -80.79698° Elevation: 232 meters Parameter Method Method Number Probe Height (m) Sampling Schedule NO2 CAPS 256 4 Continuous Date Monitor Established: NO2 January 1, 2024 (approximate date) Nearest Road: I-85 Distance to Road: 24 meters (approx. distance) Traffic Count1: 157,000 Year of Count: 2021 MSA: Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area2 MSA #: 16740 2022 Population (within 1 mile radius of property) Projected 2024 Population (within 1 mile radius of property) 7,158 9,367 1Annual Average Daily Traffic (AADT) Data obtained from: NCDOT Annual Average Daily Traffic (AADT) Mapping Application (arcgis.com). 2https://www.huduser.gov/portal/datasets/geotool/summary.odn (B) Equipment Drive Station Description and Statement of Purpose The Equipment Drive monitoring station is located in a grassy area adjacent to Interstate 85 South (I-85S) between North Graham Street and West Sugar Creek Road. The station is located 7.0 kilometers NE of the central business district of Charlotte, NC at latitude N 35.27831°and longitude W -80.79698°. A federal equivalent method (FEM) NO2 analyzer will be located at the Equipment Drive monitoring station. The NO2 analyzer monitor type is SLAMS. The NO2 monitor will be approximately 24 meters from the nearest traffic lane and is designated as a near-road monitoring station for the CBSA. 55 The station meets the required monitoring objectives and siting criteria of 40 CFR Part 58 for criteria air pollutants (NO2). OBJECTIVE AND SPATIAL SCALE The monitoring objective of the Equipment Drive NO2 station is to determine the highest concentrations expected to occur in the area covered by the network. The NO2 station is classified as a microscale station. The Equipment Drive station is representative of nitrogen dioxide concentrations in the near-road environment. Data is used to assess compliance with the nitrogen dioxide NAAQS. The site is located in the Charlotte-Gastonia-Concord, NC-SC Metropolitan Statistical Area. The principal cities and counties in the MSA are Charlotte, NC; Gastonia, NC; Concord, NC; Rock Hill, SC and Cabarrus County, NC; Gaston County, NC; Iredell County, NC; Lincoln County, NC; Mecklenburg County, NC; Rowan County, NC; Union County, NC; Anson County, NC: Chester County, SC; Lancaster County, SC; and York County. (C) Equipment Drive Aerial Photograph: Figure 12. Equipment Drive aerial photograph with 4 km diameter circle 56 (D) Equipment Drive Site Photographs NORTH NORTHEAST EAST SOUTHEAST SOUTH SOUTHWEST WEST NORTHWEST 57 58 V. REFERENCES 1. TITLE 40—Protection of Environment CHAPTER I—ENVIRONMENTAL PROTECTION AGENCY, SUBCHAPTER C—AIR PROGRAMS, PART 58—AMBIENT AIR QUALITY SURVEILLANCE, March 13, 2020. 2. Connect NCDOT. County-Area Traffic Volume Maps (By Year). https://connect.ncdot.gov/resources/State-Mapping/Pages/County-Area-Traffic-Volume-Maps- Year.aspx . North Carolina Department of Transportation, Raleigh, NC 27699-1501. 2018. 3. Connect NCDOT. Urban-Area Traffic Volume Maps. https://connect.ncdot.gov/resources/State-Mapping/Pages/Urban-Area-Traffic-Volume- Maps.aspx . North Carolina Department of Transportation, Raleigh, NC 27699-1501. 2018. 4. Connect NCDOT AADT Mapping Application http://ncdot.maps.arcgis.com/apps/webappviewer/index.html?id=5f6fe58c1d90482ab9107ccc030 26280 North Carolina Department of Transportation, Raleigh, NC 27699-1501. 2018. 5. QA Handbook for Air Pollution Measurement Systems: “Volume IV: Meteorological Measurements Version 2.0" EPA-454/B-08-002, March 2008(PDF) 6. QA Handbook for Air Pollution Measurement Systems: “Volume II: Ambient Air Quality Monitoring Program" EPA-454/B-17-001, January 2017 - Full Document (PDF) 7. Bannister, Beverly. EPA Response Letter to “2018-2019 Monitoring Plan (MCAQ)”, October 22, 2018. 8. EPA Extension of Start Date for Photochemical Assessment Monitoring Stations Fact Sheet PDF. https://www.epa.gov/sites/production/files/2019- 12/documents/final_pams_extension_fact_sheet.pdf, December 20, 2019. 9. Mecklenburg Demographics. Mecklenburg County GIS, Charlotte, NC 28208. 2023 59 VI. APPENDIX A Monitoring Equipment Replacement Tables 60 Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition Additel Barometer 211H170D0003 681 Suttle-Lab Good Agilaire Airvision Server AIRVISION1V Suttle-Lab Good Agilent Technologies GC System US18403039 69097 78908 Suttle-Lab 09/21/19 Includes Unity XR, CIA Advantage, and Kori XR Good AirGas Gas Cylinder C-000669 MCAQ#161 Suttle-Lab Good AirGuide Barometer 3 AirGuide Suttle-Lab Good AirGuide Barometer 4 AirGuide Suttle-Lab Good Alicat Scientific Alicat Flow Meter 45717 M-10SCCM-D/5M Suttle-Lab Good Alicat Scientific Alicat Flow Meter 111447 MW-10SCCM-D/5M Suttle-Lab Good Alicat Scientific Alicat Flow Meter 185930 FP-25BT Suttle-Lab Good Alicat Scientific Alicat Flow Meter 185931 FP-25BT Suttle-Lab Good Alicat Scientific Alicat PCU 111448 PCUW-20SCCM-200SCCM-10SLPM- .25SWCOMP Suttle-Lab Good Alicat Scientific Alicat PCU 111449 PCUW-20SCCM-200SCCM-10SLPM- .25SWCOMP Suttle-Lab Good Alicat Scientific Alicat PCU 111450 PCUW-20SCCM-200SCCM-10SLPM- .25SWCOMP Suttle-Lab Good Apogee Sol-a-meter SP-110 University Meadows Good APW McLean Air Conditioner 04029597-3 CR29-0216-G047 Ramblewood Park Good Arc 3 Gases Gas Cylinder EB0123168 MCAQ#169 150A Garinger Good Arc3 Gases Gas Cylinder EB0061240 MCAQ#168 150A Remount Good Arc3 Gases Gas Cylinder ER0004772 MCAQ#173 80A Garinger Good Bard Air Conditioner 309M112852661-02 W36A1-A05XP4XXJ Garinger Good BGI Instruments Delta Cal 36 Delta Cal Suttle-Lab Good BGI Instruments Delta Cal 78 Delta Cal Suttle-Lab Good BGI Instruments Tetra Cal 345 Tetra Cal Suttle-Lab Spare BGI Instruments Tetra Cal 365 Tetra Cal Suttle-Lab Spare BGI Instruments Tetra Cal 441 Tetra Cal Suttle-Lab Spare Bios International Corp DryCal DC-Lite 7468 DCL-L Suttle-Lab Good Bios International Corp DryCal DC-Lite 103222 DCL-H Suttle-Lab Good Bios International Corp Nexus 1071 DCNS Suttle-Lab Good Brunton Pocket Transit 2611000210 2061 Suttle-Lab Good 61 Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition Chinook Engineering FTS 777 FTS Suttle-Lab Spare Chinook Engineering FTS 981023 FTS Suttle-Lab Good Chinook Engineering FTS 990399 FTS Suttle-Lab Good Chinook Engineering FTS 981016A FTS Suttle-Lab Good Chinook Engineering FTS H981014A FTS Suttle-Lab Good Cradlepoint Cradlepoint MM130504000352 IBR600lpe Suttle-lab Good Cradlepoint Cradlepoint MM160030300417 IBR600lpe Suttle-Lab Good Cradlepoint Cradlepoint MM160075900576 IBR600lpe Suttle-Lab Good Cradlepoint Cradlepoint WA201800290009 IBR600C-150M-D Garinger (PAMS) Good Cradlepoint Cradlepoint WA213700541950 IBR600c University Meadows Good Cradlepoint Cradlepoint WA214500574873 IBR600C-150M-D Ramblewood Good Cradlepoint Cradlepoint WA213800545056 IBR600C-150M-D Friendship Good Cradlepoint Cradlepoint WA213800545139 IBR600C-150M-D Remount Good Cradlepoint Cradlepoint WA213800544905 IBR600C-150M-D Garinger Good Cradlepoint Cradlepoint-Sharon towers MM16012650037 IBR600lpe Suttle-Lab Good Druck Barometer 7401000 DPI 740 Suttle-Lab Good Druck Barometer 74001908 DPI 740 Suttle-Lab Good Dwyer Manometer 2 1230 Suttle-Lab Good Dwyer Manometer 4 1230 Suttle-Lab Good Dwyer Manometer 7 1230 Suttle-Lab Good Dwyer Manometer 8 1230 Suttle-Lab Good Dwyer Manometer 9 1230 Suttle-Lab Good EKTO Shelter 3278-7 432 SP Suttle-Lab 11/01/02 Good EKTO Shelter 3577-8 67847 432SP Ramblewood Park Good Environics Environics 9100 1887 63216 9100 Suttle-Lab 11/01/93 Surplus Environics Environics 6103 3170 67771 6103 Suttle-Lab 10/01/03 Good Environics Environics 6100 4202 63226 6100 Suttle-Lab 04/17/08 Good Environics Environics 6100 6527 72399 6100 Garinger 04/30/15 Good ESC Data Logger 8832 A0064 67667 8832 Suttle-Lab 06/01/02 Good 62 ESC Data Logger 8832 A0160 67697 8832 University Meadows 10/11/02 Good ESC Data Logger 8832 A0304 67729 8832 Ramblewood Park 03/26/03 Good ESC Data Logger 8832 A0409 67773 8832 Suttle-Lab 10/08/03 Good Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition ESC Data Logger 8832 A0896 67860 8832 Suttle-Lab 03/08/05 Good ESC Data Logger 8832 A2333K 63292 8832 Suttle-Lab 02/07/08 Good ESC Data Logger 8832 A4829K 64603 8832 Remount 03/20/14 Good ESC Ambient Temperature Sensor 10 103-4000 Suttle-Lab Good ESC Data Logger 8864 C2568 69146 8864 Garinger Good ESC Site Temperature 6 103-4000 University Meadows Good Fisher Scientific Excursion-Trac Thermometer 181376177 15-081-125,15214026 Suttle-Lab Good Fisher Scientific Toxics Flow Meter 292328 520 Garinger Good Fluke Voltmeter 5690145 27 Suttle-Lab Good Fluke Voltmeter 78540313 87III Suttle-Lab Good Fluke Voltmeter 97410278 87V Suttle-Lab Good Fourtec Fourtec Thermometer 7014421 EC850 Suttle-Lab Good Frost Boats Trailer 1F9FC1425FG127185 6387 University Meadows 10/13/15 Good GAST Compressor 5Z675A M550EX Suttle-Lab Good Hampshire Controls Site Temperature 1902-3445-27484 140-100HV-MB Garinger Good Hart Scientific Micro Bath A32653 7102 Suttle-Lab Next priority for replacement. Good Jun-Air Compressor 552774 OF302 Suttle-Lab 04/07/04 Good Keuffel & Esser Company Transit 169553 P5137 Suttle-Lab Good Markes International Canister Auto Sampler GB00H10293-18/11 69097 CIA Advantage-XR Suttle-Lab 09/21/19 Good Markes International Thermal Desorber GB00U33144-18/11 69097 Unity XR Suttle-Lab 09/21/19 Good Markes International Water Condenser GB00W10188-18/11 69097 Kori XR Suttle-Lab 09/21/19 Good Matrix Inc. Sol-a-meter 4776 MK 1-G Suttle-Lab Good Matrix Inc. Sol-a-meter 4998 MK 1-G Suttle-Lab Good Matrix Inc. Sol-a-meter 5873 MK 1-G Suttle-Lab Good Matrix Inc. Sol-a-meter 5937 MK 1-G Garinger Good 63 Mesa Laboratories Definer 111971 Definer 220-L Suttle-Lab Good Mesa Laboratories Definer 112233 Definer 220-H Suttle-Lab Good Mesa Laboratories Definer 133693 Definer 220-H Suttle-Lab Good Mesa Laboratories Definer 133703 Definer 220-L Suttle-Lab Good Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition Met One Instruments SASS Y4594 67704 SASS Suttle-Lab 10/01/00 Spare Met One Instruments SASS D7162 67849 SASS Suttle-Lab 12/07/04 Spare Met One Instruments BAM-1020 H1935 63263 1020 Lab 04/17/08 Spare Met One Instruments SASS N1099 72214 Super SASS Garinger 04/11/12 Good Met One BAM-1020 1020 Ramblewood 12/2022 Good Met One Instruments BAM-1020 U20336 69786 1020 Garinger 11/23/16 Good Met One Instruments BAM-1020 U20337 69787 1020 Garinger 11/23/16 Good Met One Instruments BAM-1022 U13546 69784 1022 Friendship Park 11/23/16 Good Met One Instruments BAM-1022 X15279 69785 1022 Remount 11/23/16 Good Met One Instruments BAM-1020 H7548 BAM 1020 Suttle-Lab Good Met One Instruments Relative Humidity Sensor R17904 083E-0-35 Garinger Good Met One Instruments Relative Humidity Sensor R20523 083E-0-35 Suttle-Lab Good Met One Instruments Relative Humidity Sensor T19893 083E-0-35 Remount Good Met One Instruments Relative Humidity Sensor Y20492 083E-0-35 Suttle-Lab Good Met One Instruments SASS Temperature Resistance Box J7455 9099 Suttle-Lab Good Met One Instruments Sonic Anemometer J6601 50.5H Remount Good Met One Instruments Sonic Anemometer R13845 50.5H Garinger Good NovaLynx Corp. Precipitation Calibrator 946-001 260-2595 Suttle-Lab Good NovaLynx Corp. Precipitation Calibrator 946-002 260-2595 Suttle-Lab Good OMEGA OMEGA Thermometer 98:8B:AD:00:38:94 OM-EL-WIFI-TH-PLUS Suttle-Lab Good Praxair Gas Cylinder DT0021631 MCAQ#165 150A Garinger Good Praxair Gas Cylinder JB02884 MCAQ#166 50A Remount Good R.M. Young Barometric Pressure Sensor BPA 7587 BPA 7587 Garinger Good 64 R.M. Young Temperature Sensor 19041 41342VC Garinger Good R.M. Young Temperature Sensor 25844 41342VC Remount Good R.M. Young Tipping Bucket Rain Gauge TB 05899 52202 Suttle-Lab Good R.M. Young Tipping Bucket Rain Gauge TB01473 52202 Garinger Good RM Young Sonic Anemometer UD00004438 86000 Suttle-Lab Good Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition Sartorius Balance 20902085 61749 AC2105 Suttle-Lab 06/14/95 Spare Scott Marrin Gas Cylinder CA01400 MCAQ#159 150A Remount Good Scott Marrin Gas Cylinder CC105072 MCAQ#162 150A Garinger Good Scott Marrin Gas Cylinder CC37915 MCAQ#148 150A Garinger Good Scott Marrin, Inc Gas Cylinder CC106586 MCAQ#95 150A Suttle-Lab Good Scott Marrin, Inc Gas Cylinder CC42695 MCAQ#164 150A Suttle-Lab Good Scott-Marrin, Inc Gas Cylinder CC286 MCAQ#152 150A Suttle-Lab Good Scott-Marrin, Inc Gas Cylinder CC89561 MCAQ#158 150A Suttle-Lab Good Scott-Marrin, Inc Gas Cylinder JJ21192 MCAQ#150 50A Suttle-Lab Good Shelter One Shelter 20053-01 C1152095 20053 Garinger 12/01/11 Good Shelter One Shelter 23053-01 66088 C101695 23053 Remount 04/09/14 Good Shelter One Shelter 25040-01 72258 MMS8 25040 University Meadows 10/13/15 Good Shelter One Shelter Remount 10/2022 For 2nd near-road site (Equipment Dr); Temporarily being stored at Remount. Good Teledyne Hastings-Raydist Bubble Meter 549 HBM-1A Suttle-Lab Good Teledyne Instruments Zero Air System T701H Suttle-Lab 3//2022 For 2nd near-road site (Equipment Dr.) Good Teledyne Instruments N500 CAPS True NO2 N500 Garinger Good Teledyne Instruments N500 CAPS True NO2 N500 Remount 7/2022 Good Teledyne Instruments N500 CAPS True NO2 N500 Lab For 2nd near-road site (Equipment Dr.) Good Teledyne Instruments CO Analyzer 68 67861 300EU Suttle-Lab 03/11/05 Spare Teledyne Instruments Zero Air System 2809 64822 M701H Suttle-Lab 10/17/08 Next priority for replacement Good Teledyne Instruments Zero Air System 3033 67371 M701H Garinger 11/05/09 Next priority for replacement Good Teledyne Instruments Zero Air System 3035 67371 M701H University Meadows 11/05/09 Next priority for replacement Good 65 Teledyne Instruments Zero Air System 98 72991 M701H Suttle-Lab 10/26/10 Next priority for replacement Good Teledyne Instruments NO2 Analyzer 81 69969 T200UP Lab 08/26/13 Good Teledyne Instruments T700U Calibrator 182 64608 T700U Remount 01/20/14 Good Teledyne Instruments T700U Calibrator 725 T700U Suttle-Lab For 2nd Near-road NO2 site Good Teledyne Instruments Zero Air System 793 64609 M701H Remount 01/20/14 Good Teledyne Instruments NO2 Analyzer 114 T200U Garinger Good Teledyne Instruments SO2 Analyzer 101 T100U Suttle-Lab Good Teledyne Instruments NO2 Analyzer 93 N500 Garinger Good Teledyne Instruments NO2 Analyzer 115 70059 N500 Remount Good Thermo Ozone Analyzer 49C-56618-309 66331 49C Suttle-Lab 11/01/96 Spare Thermo Ozone Primary Standard 49CPS-56545-309 66332 49CPS Suttle-Lab 11/01/96 Spare Parts Thermo Ozone Primary Standard 49CPS-73995-375 67660 49C Suttle-Lab 04/01/02 Spare Parts Thermo Ozone Primary Standard 49CPS-73996-375 67658 49CPS Suttle-Lab 04/01/02 Good Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Next priority for replacement. Condition Thermo Ozone Primary Standard 49CPS-73997-375 67659 49CPS Suttle-Lab 04/01/02 Good Thermo FRM 2025B217200408 67843 2025B Suttle-Lab 11/03/04 Spare Thermo Ozone Analyzer 432209351 67841 49C Suttle-Lab 11/23/04 Spare Parts Thermo Ozone Primary Standard 432209352 67842 49CPS Suttle-Lab 11/23/04 Good Thermo Ozone Analyzer 636319876 67965 49I Suttle-Lab 12/22/06 Good Thermo Ozone Analyzer 636319877 67966 49I Suttle-Lab 12/22/06 Spare Thermo 146I Gas Calibrator 717821846 68014 146I Suttle-Lab 06/30/07 Spare Thermo Ozone Primary Standard 734726810 99068 49IPS Suttle-Lab 01/14/08 Good Thermo FRM 2025B219590706 2025B Suttle-Lab 05/01/08 Spare Thermo FRM 2025B221720804 68066 2025B Suttle-Lab 06/11/08 Spare Thermo FRM 2025B226221002 66044 2025B Suttle-Lab 05/13/10 Spare Thermo Ozone Primary Standard 1027444721 49IPS Garinger 01/01/11 Next priority for replacement Good Thermo NOy Analyzer 1213152833 72314 42IY Garinger 06/20/12 Good Thermo SO2 Analyzer 1213152834 72361 43I Garinger 07/17/12 Good Thermo CO Analyzer 1220753779 72356 48I Garinger 10/17/12 Good 66 Thermo FRM 2025I2 02341205 72358 2025I Lab 10/24/12 Spare Thermo FRM 2025i-AW 2025i Garinger 1/2023 Good Thermo Ozone Analyzer 1152660035 72272 49I Garinger 01/13/16 Good Thermo NO2 Analyzer 1153170016 69870 42I Suttle-Lab 01/13/16 Spare Thermo Ozone Primary Standard 1153380012 72256 49IPS University Meadows 02/02/16 Good Thermo Ozone Analyzer 728225131 68048 49I University Meadows 10/22/17 Good Thermo CO Analyzer 1502064047 201077 48I-TLE Remount Monitoring began 01/01/2017 On loan from NCDAQ-Near-road CO. Good Thermo FRM 2025IW2 0996 1603 300348 2025IW Remount Monitoring began 01/01/2017 On loan from NCDAQ-Near-road PM 2.5. Good Thermo Zero Air System 111-28998-233 111 Suttle-Lab Good Thermo Environmental PM2.5 FRM 2025A204679807 67702 2025a Suttle-Storage 10/01/98 Spare Thermo-GAST Laboratory Compressor NXGTE-4870 Suttle-Storage Spare Transcat Voltage Calibrator 9733019 23894E Suttle-Lab Good URG Corp. URG 3N-B0428 URG-3000N Suttle-Lab 02/01/09 Spare URG Corp. URG 3N-B0524 3N-3000N Lab Spare URG Corp. URG Garinger Monitoring began 6/2022 Loan from OAQPS Vaisala Humidity Calibrator M210185en-A HMK15 Suttle-Lab Good Manufacturer Type Equipment Serial # Asset Number Model Site Date Purchased Notes Condition Vaisala Relative Humidity Wand R3340580 HM70 Suttle-Lab Good Vaisala Relative Humidity Wand R3340581 HM70 Suttle-Lab Good Vaisala Ceilometer S3240436 CL51 Garinger 07/30/20 Good VWR Barometer 5 15551-024 Suttle-Lab Good VWR Thermometer 90185236 61220-601 Suttle-Lab Good VWR Thermometer 130189334 61220-601 Suttle-Lab Good VWR Thermometer 140432915 61220-601 Suttle-Lab Good Xonteck Toxics 911 Garinger Good Xonteck Toxics 911 Oehler On loan from NCDAQ for pipeline spill site SPM Good Community Science Station Garinger Good Visibility Camera- Sharon towers Suttle-Lab Good 67 68 VII. APPENDIX B Memorandum of Agreement 69 70 71 72 73 74 75 76 77 VIII. APPENDIX C Site Review Forms Calendar Year 2023 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 IX. APPENDIX D PM2.5 Continuous Monitor Comparability Assessment 99 100 101 X. APPENDIX E PAMS Parameter Codes - Auto-GC-FID Speciated VOCs 102 PAMS parameter list: The method code for the Agilent Auto-GC-FID systems is 228, unit code 078 and interval 1. Parameter Code Parameter Name 43202 Ethane 43203 Ethylene 43204 Propane 43205 Propylene 43214 Isobutane 43212 n-Butane 43206 Acetylene 43216 trans-2-Butene 43280 1-Butene 43217 cis-2-Butene 43242 Cyclopentane 43221 Isopentane 43220 n-Pentane 43218 1,3-Butadiene 43226 trans-2-Pentene 43224 1-Pentene 43227 cis-2-Pentene 43244 2,2-Dimethlybutane 43284 2,3-Dimethlybutane 43285 2-Methlypentane 43230 3-Methlypentane 43243 Isoprene 43245 1-Hexene 43231 n-Hexane 43262 Methylcyclopentane 43247 2,4-Dimethlypentane 45201 Benzene 43248 Cyclohexane 43263 2-Methlyhexane 43291 2,3-Dimethylpentane 43249 3-Methlyhexane 43250 2,2,4-Trimethlypentane 43232 n-Heptane 43261 Methylcyclohexane 43252 2,3,4-Trimethlypentane 45202 Toluene 43960 2-Methlyheptane 43253 3-Methlyheptane 43233 n-Octane 45203 Ethylbenzene 45109 m/p-Xylene 103 45220 Styrene 45204 o-Xylene 43235 n-Nonane 45210 Isopropylbenzene 43256 α-pinene 45209 n-Propylbenzene 45212 m-ethyltoluene 45213 p-Ethyltoluene 45207 1,3,5-Trimethlybenzene 45211 o-Ethyltoluene 43257 β-pinene 45208 1,2,4-Trimethlybenzene 43238 n-Decane 45225 1,2,3-Trimethlybenzene 45218 m-Diethylbenzene 45219 p-Diethylbenzene 43954 n-Undecane 43141 n-Dodecane 43102 TNMHC 43000 TNMTC 104 XI. APPENDIX F Responses Public Comments on Annual Network Plan 105 On May 22, 2023, the “2023-2024 Annual Monitoring Network Plan - MCAQ” was released for public comment during a meeting of the Mecklenburg County Air Quality Commission (AQC). The public comment period was open May 22, 2023 through June 22, 2023. Summary of Public Comment Period No comments were received during the public comment period. Comment: N/A MCAQ Response: N/A