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HomeMy WebLinkAboutAQ_F_0100237_20200827_ST_STO-Rpt (4) NORTH CAROLINA DIVISION OF Winston-Salem Regional Office AIR QUALITY Canfor Southern Pine-Graham Plant NC Facility ID 0100237 Stack Test Observation Report County/FIPS:Alamance/001 Date: 08/30/2020 Facility Data Compliance Data Canfor Southern Pine-Graham Plant Observation Date: 08/27/2020 4408 Mt Hermon-Rock Creek Road Observer's Name:Thomas Gray Graham,NC 27253 Operating Status: Operating Lat: 35d 58.8660m Long: 79d 25.0320m Action Code: 23/STACK TEST OBSERVED SIC: 2421 /Sawmills&Planing Mills General NAICS: 321113/Sawmills Contact Data Permit Data Facility Contact Authorized Contact Technical Contact Permit 06740/T22 Kristie Hill Mark Blalock Kristie Hill Issued 9/6/2019 HR Manager Plant Manager HR Manager Expires 4/30/2023 (336)376-5803 (336)376-5801 (336)376-5803 Classification: Title V Permit Status: Active Comments: Inspector's Signature: rJ1L,,,n Date of Signature: MTH Emission Sources: Emission Emission Source Description Cantrof Control Devace Description Source ID:No. Device II}No. B-2 One wood fuel-fired boiler(28.7 MC-2 Two multicyclones(16 nine-inch diameter tubes NSPS Dc; million Btu per hour maximum heat MC-2A and 44 six-inch diameter tubes,respectively) Case-By-Case MACT' input capacity) MACT DDDDD2 ESP-2* One electrostatic precipitator B-3 One wood fuel-fired boiler(28.7 MC-3 Two multicyclones(16 nine-inch diameter tubes NSPS De; million Btu per hour maximum heat MC-3A and 44 six-inch diameter tubes,respectively) Case-By-Case MACT' input capacity) MACT DDDDD2 ESP-3* One electrostatic precipitator B-4 One wood fuel-fired boiler(57.6 MC-4 Two multicyclones(36 nine-inch diameter tubes NSPS Dc; million Btu per hour maximum heat MC-4A and 44 six-inch diameter tubes,respectively) Case-By-Case MACT' input capacity) ESP-4* One electrostatic precipitator MACT DDDDD2 Introduction: On August 25-27,2020,Mr. Thomas Gray, QSTI(I-IV),Environmental Specialist,of the Winston Salem Regional Office-Division of Air Quality(WSRO-DAQ),contacted Ms.Kristie Hill,HR Manager,of Canfor Southern Pine-Graham plant,for the purpose of observing stack testing being performed on the facility's wood fuel-fired boilers(B2,B3,134).All three boilers are each individually controlled by two multicyclones and an electrostatic precipitator in series.The boilers have heat input capacities of 28.7,28.7 and 57.6 MMBtu/hour,respectively.Testing was required to demonstrate compliance with 40 CFR Part 63 Subpart DDDDD, "NESHAP for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters."listed in permit condition 2.2.C.1. Also, Boilers B-2, B-3,and B-4 are subject to 40 CFR 60 Subpart Dc,"Standards of Performance for Small Industrial-Commercial- Institutional Steam Generating Units,"listed in permit condition 2.1.A.4 and 15A NCAC 2D .0504,"Particulates from Wood Burning Indirect Heat Exchangers,"listed in permit condition 2.1.A.1 (B-2 and B-3 only). Mr. Tyler Mills,of TRC Environmental Solutions, 1 was the leader of the test crew performing the sampling.Testing was conducted over the course of three days.Ms.Kathy Ferry, Environmental Consultant for the facility,was also on site to aid in process data collection. Previous Testing: The facility previously conducted testing on Boilers 2-4 from September 10-12,2019.As detailed in the table below,Boiler 4 exceeded the filterable PM limit for both NSPS Subpart Dc and NESHAP 5D.However,using the weighted average and filterable PM results from all three boilers,the facility was deemed in compliance with NESHAP 5D.After performing maintenance on the multi- cyclone and ESP,the facility retested B-4 for filterable PM on January 30,2020.Results from that test indicated a filterable PM emission rate of 0.01921b/mmBtu,in compliance with the filterable PM limit for both NSPS Dc and NESHAP 5D. Boiler/; poilutant TestResults Emissions Lt Standard Corripliance L�ate Filterable PM 0.00478 lb/mmBtu 0.45 lb/mmBtu 2D.0504 Yes0.037 lb/mmBtu Yes 9/12/19 HCl 3.9E-5 lb/mmBtu 0.0221b/mmBtu 63 Subpart Yes /1 CO 503 vpmvdp 3%02 1500 mvd 3%02 DDDDD Yes Hg 2.83E-7 lb/mmBtu 5.7 E-61b/mmBtu Yes Filterable PM 0.031 lb/mmBtu 0.45 lb/mmBtu 2D.0504 Yes 0.037 lb/mmBtu Yes B-3 HCl 3.4E-5 lb/mmBtu 0.022 lb/mmBtu 63 Subpart Yes 9/11/19 CO 1006 ppmvdp 3%02 1500 mvd 3%02 DDDDD Yes Hg 2.96E-71b/mmBtu 5.7E-61b/mmBtu Yes Filterable PM 0.04471b/mmBtu 0.03 lb/mmBtu 60 Subpart Dc No 0.037 lb/m mBtu Yesl B-4 HCl 3.7E-5 lb/mmBtu 0.022 lb/mmBtu 63 Subpart 9/10/19 CO 506 mvd 3%02 1500 mvd 3%02 DDDDD H 4.51E-71b/mmBtu 5.7E-6lb/mmBtu Note 1. Boilers B-2,B-3,and B-4 63 Subpart DDDDD PM Com liance 63.7522Equation 1 a B-2 Filterable PM 63 Subpart B-3 Weighted Average 0.034 lb/mmBtu 0.037 lb/mmBtu DDDDD Yes B-4 [Equation I a] Test Methods: On June 11,2020,the WSRO received a protocol submittal form(PSF)indicating the facility wanted to conduct testing August 25, 2020.The proposed test methods as provided on the PSF are listed below. E'A:Test No.of Test Run No.Sampling Target Pollutant Comments Method Te"st Runs Duration Points Stack as flaw rated moisture 1,2,4 3 Sampling points determined O/Co 3A by Method 1 verification C 10 90 Minutes See Comment including absence of cyclonic Filterable PM 5 3 (See Note) flow determination and HCl 26A Method 7E section 8.1.2 Mercu 30B stratification test I The PSF was forwarded to SSCB on June 11,2020 and subsequently approved by the SSCB on August 20,2020.No deviations from the method were requested in the PSF. Testing: Testing commenced on August 25,2020 on Boiler 4.Method 1 criteria was met on each boiler,with maximum sampling points being performed on each boiler(24 points).Boilers 2&3 each have stacks with 24"in diameter,with Boiler 4 having a stack diameter of 36".To ensure minimum detection limits were met for the 30B sampling,and the minimum volume of 2 dscm were met for filterable particulate as required by subpart DDDDD,test runs performed were 96 minutes in duration.Being that each stack had two ports,and 24 points were being traversed,each point was sampled for 4 minutes each(96 minutes/24 points=4 minutes per point).Methods 2 and 4 were performed in conjunction with the Method 5/26A train,and Method 3A for O2/CO2 and Method 10 for CO were completed using a CEMS system.All methods will be discussed in greater detail below. 2 Applicable Limits: Emiss a�ns.Standard Pollutants Limits Notes 40 CFR 63 Subpart DDDDD National Emissions Filterable PM 0.037 lb/mmBtu Standards for Hazardous Air Pollutants for Major HC1 0.022 lb/mmBtu Sources: Industrial, Commercial and Institutional CO 3-hr ave) 1500 m 3%02 Boilers and Process Heaters Hg 5.7E-6 lb/mmBtu 40 CFR 60 Subpart Dc Standards of Performance for Small Industrial-Commercial-Institutional Steam Filterable PM 0.03 lb/mmBtu B-4 only Generating Units 15A NCAC 2D .0504 Particulates from Wood Burning Filterable PM 0.45 lb/mmBtu B-2 and B-3 Indirect Heat Exchangers Method 5/26A- The Method 5 and Method 26A sampling were performed in conjunction with each other.TRC used a Teflon filter support,glass probe liner/nozzle,and probe and filter bell temperatures were maintained between 248-273 degrees Fahrenheit to meet the requirements of both Method 5 and Method 26A. The Method 5/26a testing was performed by sampling the stack gas isokinetically with the filterable pm being captured in the front half M5 filter,the hydrogen halides being captured in the acid impingers(charged each with 100 mL 0.1 N H2SO4),and the halogens captured in the basic impingers(each charged with 100 mL0.1 N NaOH). It should be noted the testers used a split train, in which a jumper was used from the filter box to the first impinger. Following the sampling,and the post run leak check,the probe,nozzle,and front half filter bell were rinsed and brushed in triplicate with acetone and captured in a 250 mL amber sample bottle.The jumper used during the testing,was rinsed with DI water to ensure all sample was recovered in impingers.The front half prepared M5 filter was then recovered and sealed in a labeled petri dish. Both the acetone rinse and filter will be analyzed by gravimetric analysis. The impingers were then weighed gravimetrically for moisture analysis(M4).Then the back-half filter bell, as well as the acid impingers and connecting glassware,were rinsed with 100 mL 0.1 N H2SO4 and combined in a 1000 mL PE bottle for analysis by IC(Ion Chromatography).The same recovery was performed for the basic impingers,however using NaOH. Mr. Gray discussed with Mr. Mills that HC1 analysis was only required,Mr.Mills stated they would be archiving the NaOH samples. At the time of the testing,no audit samples for HC1 were required.Per the EPA emission measurement center technical support page,"the general provisions to 40 CFR Parts 60 and 63(see §60.8(g)(1)and§63.7(c)(2)(iii)(A))require that the owner or operator obtain audit samples if the audit samples are"commercially available"and have defined"commercially available" as two or more independent accredited audit sample providers(AASP)to have blind audit samples available for purchase." Since there are no longer two providers,the requirement to obtain these audit samples is no longer in effect until such time as another independent AASP has audit samples available for purchase.".The meter box utilized for this portion of the testing had a gamma of 0.9909,and a delta H @1.924.As mentioned in the introduction, Subpart 5D requires a minimum volume of 2 dscm to be sampled during particulate runs. Being that the runs were only 90 minutes in duration,Mr.Gray ran the preliminary method 5/26A data through spreadsheets to confirm a minimum corrected volume of 2dscm was sampled. Isokinetics were also verified and were within the method allowance of 90-110%for all the boilers. Method 30B- Method 30B for elemental and oxidized mercury(Hg)was also performed on the three boilers.Method 30B was performed by extracting a known volume of stack gas through paired in stack carbon sorbent traps,using a heated 30B sampling probe(heated sufficiently to prevent condensation in traps).The method required paired train sampling to determine measurement precision and verify validity of test results. The method requires a field recovery test which assesses the recovery of an elemental Hg spike with a (90-110)%spike recovery required for run validation. Each sorbent trap consists of two separate carbon sections for breakthrough analysis.The method requires under normal circumstances that breakthrough be less than 10%of the front half value,for the run to be considered valid. Paired traps are also required to have a relative deviation(RD)of less than 10%for Hg concentration <0.1 µg/dscm,and less than 20%RD for Hg concentration<.20 µg/dscm.Also,total sample volume must be within 20%for the A side and B side respectively. 30B sampling was performed on all 3 boilers with an ESS instruments 30B box that had an A side gamma of 1.0117 and a B side gamma of 1.0211.B side spiked tubes(provided by Ohio Lumex)had a concentration of 50 ng,with the average sampling rate for both sides being I LPM,with a final target volume of 96 L.As mentioned above,test runs were 96 minutes in duration to ensure the minimum detection limits of the method were met.All leak checks were observed and were well within the method allowance of 4%of the total sampling rate(0.04 L),and conducted above the highest vacuum achieved during the run.The 30B sampling probe was heated well above point of saturation,with trap temperatures on average around 260 degrees Fahrenheit. Silica canisters were used for moisture knockouts before the sample was subsequently conveyed to the 30B box. 3 Methods 3A and 10- Method 3A for O2/CO2 and Method 10 for CO were performed in conjunction with the above-mentioned methods on all 3 boilers. Stack gas was extracted through a heated CEMS probe through an out of stack filter,followed by a heated sample line(maintained 248 degrees Fahrenheit plus)to a sampling conditioning system,were it is dried before entering the analyzers.All direct calibrations,bias,and drift checks were within method allowances(Direct Cal<2%of span,bias<5%of direct cal response,drift <3%of initial bias and final bias).All calibration gases were verified as EPA protocol 1 gases,with expiration dates on all gases verified to be within range.A CO span of 2216 PPM CO was used on all three boilers,with an O2/CO2 span of 21.9 and 18.67, respectively,also used.No deviations from the methods were observed during the testing of all three boilers.Calibration data and bias information are provided in the NC DAQ CEMS Observation checklist provided below.A stratification check was conducted during run 1 on each boiler.Results from the stratification check indicated a less than.5%deviation at each point using 02, allowing single point sampling at the centroid of the stack for the remainder of the runs. Preliminary Results and Runtimes: Boiler 4(B4): Testing Performed on August 25,2020 I Run# Run Time CO: mdv CO 3 ercent Ox en mdv 1 09:00- 10:41 570.098 839.28 11:25-13:10 589.260 868.84 3 IN 13:48-15:29 594.405 873.55 Aera a 584.59 860.56 Boiler 3(B3): Testing performed on August 26,2020 Rini# ! Run Time CO mdv CO 3 ercent Ox en nadv 1 08:35-10:18 324.03 490.58 2 11:00-12:51 307.93 452.21 3. 13:15-14:58 305.33 456.93 Avera e 312.43 466.57 Boiler 2(B2): Testing was performed on August 27,2020 Run# Run Time Ct mdv Cb 3 ercent Uz en mdv 1 08:05-09:45 221.23 320.70 2 10:25-12:06 240.47 349.92 3 12:40-14:20 274.73 405.45 Aera e 245.48 358.69 Process Information: Process information for each boiler was recorded every 15 minutes which included the following parameters: steam pressure,steam flow,sawdust reading count,multicyclone OP,and opacity(measured by COMs).Fuel samples were taken from the fuel feed at the j beginning of each run.These samples will be sent to the lab for Fuel analysis to calculate a BTU value.Preliminary calculations indicated the facility was around 85-90%maximum steam flow for the boilers as 3 run average for Boilers 2,3,and 4 were 87.4, 87.6,and 89.4%of their maximum rated steam flow,respectively.Being that the boilers are equipped with electrostatic precipitators,primary and secondary voltage readings were also recorded for Fields 1 (B2-B4)and Field 2(B4 only). 4 Canfor Southern Pine-Graham Plant Stack Test Log Sheet Boller 283 MMBtulhrR.ated Heat Input 20,700 Rated Steam-flow Test.Datc 8/27/2020 Gxygen Iviultidont Steam:Pressure Steam Flow Sawdust Reading Opacity Trim Pressure Drop ESP Zone I Moo. PSI I:b/h.t Count % (I R201 VAC kVDC I.O.-Mals Run Number 1 8:05 113.2 18,480 20717532 ME 5.5 2.5 366 55 NB 8:20 116.7 11,340 2.0717752 1.52 5.5 2..5 366 55 Na 8.35 114.0 18,110 20717.938 2.58 5.8 14 3.67 55 NB 85D 116,3 17,930 29718135 L44 542 2.5 354 55 NB 9:05 115.5 18,240 20718309 L46 5.8 2.5 366 55 NB 9;20 114.0 17,340 20718495 1.34 5.6 2A 366 55 No 935 1133 18,330 20718690 1;40 5.0 16 165 55 N.B 9.1.50 116.7 17,770 2071-0867 1.41 5.5 2.5 365 55 NS Average 115.0 17,930 1.45 SIS 2,5 366 55 Rust NuMbee 2 10:25 114.1 17,780 20719321 1-.43 5A 2.4 366 55 P48 1.0-:40 114.0 18,160 20719491 Las 5.3 2-4 366 55 JNB 10455 1133 18,120 20719681. LAS 14 2.5 367 55 ICAB 11:10 113,2 18,L80 20719861 1A2 5.2 2.4 368 55 NB 125.1 18,600 207217052 2,49 5.4 2.5 3,65 55 NB 11:40 114A 1.9,580 20720239 L44 5.2 IS 368 55 NB 1155 115.1 18,110 2G720423 1.46 5.6 2.4 367 55 U-B 12:10 112.9 18,090 20720651 1A-1 5.1 2,.5 369 55 K-B Average 114.1. .18,196 1.44 5.3 24 .367 55 Run Number 3 12:40 112.8. 17,400 20720997 L45 5.6 3,.0 367 55 To 12455 112.9 17 1 1420 2G721169 1,42 53 21 369 55 Ne 1:10 114,3 18,1A0 20721362, IA4 5.9 2A9 3fi$ 55 JNB 1.25 113.9 :1.8,590 20721552 1,44 5.0 2.9 369 55 NB 1.A0 113-4 19,000 20721742 1.45 5.2 3.1 368 55 NS 155 114.8 1B,280 20721925 1.41 5:8 2.8 37:1 55 No 2:10 1153 18,300 20712115, 1.38 5.41 10 170 55 KB 2.1.5 118A 1B,220 207-12302F 1441 5.8 3.1 3619 55 .B Average 114.4 18,169 .1,4.3 5.6 3,,0 369 55 Canfor Southern Pine-Graham Plant Stack Test Log,Sheet Boller 3 28.7 MM8tu/hr Rated Heat Input 20,700 Rated Steam Flow Test Date: 8/26./2020 Multiclane Steam Pressure Steam Flow Sawdust Reading Opacity Oxygen Trim Pressure Drop. ESP Zone I Time PSI lb/hr Count .% % H20) VAC kVbC Initials Run Number I 8'35 11.2.4 18,570 629721.16 I'll 5.5 2.2 aso 55 TB 8:50 114.2. 19,800 62972270 1.10 5.2 2.2 3A8 .55 T9 9:0.5 115,9 14,810 62974,410 1108 5�1 21 352 55 TB 9,20 115,2 19,080 62972604 IM 5.7 21 351 55 TR 9.,35 115.1. 62972764 1.27 5.4. 21 337 55 T8 9.50 116.2 6297294.1 1,06 5.2 2T a51 85 TB 1011D5 114A 18�,M 62974125 tO2 6.0 12 454 55 TB Average 114.8 18,787 1.11 S.S 2.2 349 :55 :Run Number 2 11.00 11.5.2 18,810 62973719 1,31 5.2 2.2 349 55 NO 11A.5 116.4 1.8,720 62971947 1.14 5.4 21 .142 .5.5 T6 11,10 119..2 17,930 6297404S 1,40 5A 2.1 M $5 N8 IIAS 11910 18,9fi41 62574221 139 51 2,1 156 55 NO 12 00 120,5 1.8,69t1 62974367 1.12 5.3, 12 a .55 T8 ta� 12-15 121.0 18,580 62974546 1,03 5.5 2.2 ass 55 TB 12:10 122w9 1%170 6297471.4 OM 5-5 2.1 AV 55 NO 12*45 123.4 17,840 6297488,0 1,20 5.5 12 355 $5 TB Average 120.3 18,413 1.17 544 2.2 352 55 .Run Number 3 r 1.,15 1203 18,40 62975231 0.99 6.1 2,2.. 158 55 NO 11-30 117.5 14,320 6297538A 1130 SA 2,2 156 55 NS IAS 122.6 17,960 62975575: 0..96 5.5 2.4 ass 55 TB 2,00 121.6 17,260 6297571,9 0.84 5.9 2A 359 55 NO 2.u5 122.5 17j.'m 62075891 0,88 5.5 2,0 ass 55 N9 2.3o 12319 16,270 62576060 0.79 5,9 2.,0 160 .5.5 NO 2--45 122.9 16,540 6297621.3 0.83 SA 2.0 361 55: NO 3.,00 11.4.8 17,0501 62976381 036 5.4 2.0 Aso 55 N9 Average 120.8 17,2191 0,91 S-61 2.1 ass 55 6 Can(br Southern Pine-Graham Plant Stack Test Log Sheet Boller 4 $7.6 MMBtulhr Rated Meat Input 41,400 Baited Stearn Flow Test.C3atc, a/a5/Z020 51caeYt P-r u:re 5tea m Float Sawdust:R eadlog apWity Mygen Trim: Nfultidrx e--preswe Drop� J XO) ESOP Zorn 1 ESP Zane.2 Tcfflo PSI Ibli a Roker 1 calunt Stoker 2 ount .% MC# MC4A1: VAC kVDC VAC kVDC latitN6 Run PlssInbef 1 9 i1<0 11.6 1.9160 9380240 3955497 0.,64 f..1 &D. 3.,Z 374 55 .391, 55 T8 q::15 115 37 290 9390393 395sw 0.,61 6.1 6.2 3.2 374 55 391 55 To 114 37A00 93BLI598 395 i53 0,77 6.0 3.4 374 55 391 55 TS 114 36.1920 9381906 3956075 0,65 0..2 3.2 374 55 383 55 To. 10aiN) 113 N>1990 9381004 5956274 0.7.2. 6.1 5-5 3.fl 376 55 353 55 TU 10.,IS 114 37510 938.12:10 39564889 0.9.2. 5..8 62 3.1 372 55 340 55 TR 10:3 113 37,320 9381411 3956694 €3.7.2 6..2 3.2 374 55 3N8 55 ITS Aivetqe 114, 37,411 0.72 &1 6A 12 374 55 399 S5 Run Number 2: 11 2:5 1161 37;7'3l3 938Z 37 395753S 1'1 5,7 &2 3.2 363 55 369 55 TS LIAO 122..5 M-,740 9382444 395775:3 1.1 5.9 &2 .3.2 NM 55 39D 55 TO 11`5 125"? 371940 9362615 39FIN25 1-01 5.3 fi.-D 3..7 3.74 55 390 55 IS 11,10 116.9 377,4 0 938284:1 3•9561,55 Lo 5..9 SIR 310 'v4j 555 39D 55 711 12.25 1.117 37`.62:5. 9333 95 39SE364 1.1 5.2 SIR .3.2 x-14 55 390 55 TT! 13.. 1143 .36.,250 9383293 195861L 1.4 0..1 3.2 372 55 39.0 55!�i3 12.155 115.7 37,640 9333456 .3959717 1.61 &.2. 3.2 3V. 55 .390 .55 T0: 13:1.0 116.0 38"077 9393705 395907 1.2 5.2 0..1. 12 572 55 .390 55.0 t4 fia a 118 37,:2:50 1 1& 5:9 6.,0 32 372 55 390 55 E"fiun Number. 1150 115.7 35.,340 9334,252 39.59591 IJ 6,0 51.6 2.9 374 55 369 55 T1l 14.05 1:18.0 35.6610 9384465 39.59,817 1.2 .5.7 5Z .3.0 372 389 55 T1? 1:1 20 120..8 361,210 9384675 3960033 L2 5.9 0 12 350 55 390 SS T 1435 123.6 V-kso 9354393 396OZ44 1.1 6.0 1D47 3.2 3W 55 3s'9 55 T31 14,50 122,0 16,240 9385102 39SU466 1.3 5.7 318 10 343 55 396 55 To ISMS 123.9 37.+N 93852.97 M0€"S 13 5.2 519 3.2 362 55 359 5579 1:510 125.1 36,240 9395519 MORN 1..2 6,0 6.0 10 372 55 389 M T9: Average 122. 3,6 366 1 :1,Z3 5.3 5.9 3A 364 5:5 389 55 Conclusion Preliminary results indicate compliance with the CO limit.However,compliance with the HCl and particulate limit will be determined upon analysis of the samples at the laboratory.The test report will be due to the WSRO-DAQ by October 26,2020. 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M . !Ct,)nxC flow aeck uraalttil trcrr. test A (A��t*e,�,f W�laaAc v4la�::r�faxll:ra�r3cs r,2tt : !;►Z��E�t �t�l���.�����;<aa�.lct�ci ate art a�tta`� ° �� �.��a�►arrl,;tr�=w�a,t; �s't tubc-Tt���a�l�.> e5�a�ra:rraclatara►�i" _.�<��.�,�.,»»_ 4. ).Stearn• x5iu ro.nuoixtared d Uri n the test dose+fir Static Pmsgurc: tric . arom�ctxic_ r &sera;,rccordcd mir1 adjkste foT d v��itt ta3(%MM3) k A Pitot laibo i ds crri iuml fa trxis of flues l pDot ta.►lt�• �iyaltcrrlrxr'fxa Marti�>t il�t�r�k' T'etrr rcrr►tatr rrta al3aa laarrrrhrIFirt '.8)T .i rsrtaar tars! lk:cal3r Cl l��tl,r ir'r (r<ar r l rfi l tiler ttt". �t1+n� ` a $ 1} a w[ a,.aala WBel la oin ��5 ut d`'Alt ra,�>� ��� ► t>v k r rrtl r� t x 2)AIM ubl.-I.tt�lt° .31 Twlrtntez.farml,,' t :of CITSuA{ a„ri rra �l.ira trrlat � ararta varrtt�f;r. tt } laaas�_.. . ... 1 Okulate fir.,_Witkrxi. r l MAYfc,r=axe i r Tfqut-r:pax IL ;3') _3 Si i< l r�c�: aaraf it�crei l It r a t rrriz txtt(raatxrlile to absorb.tx`,or�}�zd.') �� t �rl tlraxcl ' r►raz c t trcx rt trial wit tx axrrt M WIVE amurod xr�on ira r►re't rbox t:lmta of ogle.241r.sbnA pOiOO 1 rr ttrt n H< xror r 5)�No mn.Sec check,optimal('watch)Ul O OMr r `) 1,4)Poo rtxtr lonk Chock,mxtWuwy P,Wt Kato-)&..oA.RhMy:xstet 02dIA?ConducuA a tatatag nata' 5_�l�tk i► tta xtsrrusr. Can��arty l 1 bra?ter a rrt,= «t l� K. t�aa tut: ; E�a taw to r+r r;ttarsa r is r,� per l tea 1,tx tit cy tr irciricIgs.fig MnMd 26A tf,=McOKA 5t .. ... :... Nmwvn m w.w........�..,..'.ucc .. .fl F ............. .....Tarrrtr .�t.rattyvrxsrr`� araaara� lr� t�.tiler x,r►a ��,tray tgtrrt +� Tr aacrlcxrx, «a " '�►a ti a l�c�rMlc rixrzxr7, ara t i�r tlt:a: trr�aaNrt c}rta r (MAY r►,at be uppl►rnwo) o rr ?r xxt-1ra T tirt trl,aaay x xer lr r,f.uaaaa to ua art , star ennt r:lt r vraa�x1!� 1 saachat.-,$IACT�I 1).'t AY lrasirlo e`xt'ouzzla'.it tail l �waar apt r tla iil� r ritx5r t rxr tr xts i lt�ta n rraaraa►�xtrarx,' `, ,elk:i IN filtor Kold.ef c1.isa traT l �,ta trH rtr tr sar±r�r,t laa kt7l i►r t r i'` t sr . > ?l3tl ar►:l sod-ono bl,ant, t purod" elatxrta ra t tt tar __< lrar cla Carl a K 10 NC DAO ou".e Fast Observers Checklist w SPA. +e h s 1 15 26,E ji"Lvirogen HaDd s and, f � • R s.. z ; yqyq ��,. a iR � C. � • { Vi 3' r i 4 - :> P tax .1a P m b e:tic€ezIe,�aaid praabe Iin,vr brrrc+ilic zat� ar17�1as�'�� � ra llit l ata� lip�ttart a[ iaayta1 aM� 17r�alea,litti:.r ar�1 lalt�r bfal�a r'x �< �` 26,A.1 C.) l cl�lnn irtat l klclor ia�wor r a�'�.,1(1)Bieck Corms>41da '1.i G� u€rrir tr[1>t r�,t;1,6,I,a�e'a1 �raet�tra i4�r xl�r t€€� 1 1ar a na ra.>a car .la lra�pia;r r a�'1 t:al tc�za l lcrt l4:aak t d r. ra €le at.;aft ftrtlaiia. rf M;:l.lrt t asa d. .71 �Cem.)5 $cal rr:l'O 1 N fLsO4 SFr 1 ti Ctrs c ubat.r'a.Srtaltlattralarr Tip lli rt€l of t1.1 €F+ 0��. .tel CttYi.rc rl Iff A.l g)Imp ii i g er 3 ro'ell ur`g S) t.1J Si�aPAI&�1 i a�x 100 n11€�t t1..I 14l SC a)�Ac i lr��tt ir)tter �I ° f'a.lh lzs ri rr>�' ��clr€tcr C1t�cMt1twre o-illy IGO rr�€1o:E .l N'NmOt��Cr�1ki�►1aa lrra. rya,r1 21;6A f rci�as r, 1ct .f:ra i 1ra 'a la i� rrtallt :I.I Cr rr 1 f Ct I i 1�ii 1J d 11 i 1 raa�12r p to c r ,. ICt+rtar a :lii�'k' �1 la°i.tfras .: tsrl agel) `W6A.[!k)Acid W.mncl A.l. i� 1y t'4 t''0lrt60.,P.,P',rah l pa�=ethod 7 ?6A.2.:a Prrobo a�tail 1iltyr�rtittt�r�t�ar�°tea i��t����rt�s1�t�i�V3.D. mom 26 3 al 0 nil l'sl��rk~ fepftVad llrr c �t<�asetak�ir��-a<ul�tcrtrt'�(1-5 al cal acAdi Sol C e�llftut� l t1 p�rr.;t � � �Csaj.A.b Blanks clilaatul fca C:lm vole o f 5044 ticra`r`pits(w al,r:bplaavw•).using bla:rrl�sra lal:c of DI-finge��atcr'3 6 ,c)1 b,i esm ntb acre,-Tem r�a xal IOptt:ondl aril t;�pkzlll ttret�car�cli�t l��j r 14 j�ktt:a�il��lzaat�.'tlaa�ti l:i��raxal aa�cloa�ts 1390d"��vlaa�n lgaai. is viisible wi t1f�.filter at ilv ��nd of th 3-a r le nun. 26A.1d)Acid.Iraaping r Catch_;�e �rrrd l qukrk fiino a nPia'aOIS. gtr'l 3,rinse irxYpingers wo-*eor r:cfing glum � „f> veil )l'w,,m,r�and.,idd call liqui (impuagk..a•catch mild rrra e��a'wr) ogle=?t€�a ag 20A 3.c x�lkul.ir t Impi ler('-web r;�,�fi rmur`e lialuids i`ror. irr�tring.crh#4 r�OV5f.,rinse se.ir':�pinj{erg:ttld[w:asrm'ctift� r:l 1 u Kl drat to Batt rx rrtxrti } cxrra �araC rirrcrt Az id`ii64akl:�s-3`�ttl`a l 44c?tt":I',t:�rall�i: 1€rll'.1.)=:a 3 •c =a'. a x -�r,' '�v t ., �. li u a N ,()Sodium t io xul6te added walk alien irnlaan er calch.per la�=::itae�tl'`'���:;Y � 26 k b)is tlw r imse.w ates a eior ar„�: N dtstr3lod water that ctrnfbmr,to�ea��t�ri€;ate ac,x t,y gal"�c�st arid„and. � l+i=t1*t t lw t ` i p4 afar tlnra 1 111 3;fair 91 x l� u a a l vrarrl Clac ran l tr atl 1 1 tag l ip yr+,cai fir�aucrl mitt: e� �y 6 3.J}Aa;talit:s.WVlt obtain fif x,ea�i imd aea.ri ctatrt ert tally ar�=zariz�lrl���. ARK ......... 11 , NC 1 Q Soarce Test t"lbserverst Check.a I t�� a�� t .�i=5 4�.t���. k�fir �t�1: glides �n �.# 10v� kE ' ',' t► lrt�t i tl 4 r the f cilll: y and Me observer to orecerd The �rti knt d ta during the, O q that Me melsuurV4 cm4'skans rvo:la be cnrvvjated to a.production.ratr#anal comparked to the perrrrtlit H l :1.11 be.unacceptable without production.data,.C'ontrOl.device operuti[ng laattaumten-Should Aso be morded. DATA TABLE:DOPU1 ;t wds for'ilt m.s meter",the-volrartrg rtrf dr�� �ts collected t;ptoalJy in c 'The N 1ys"is the DO NA etnr cNinge finin the tn-ginming to Otte Brad Dff c ruff.,vets=h is the i0¢a1.dry 5 votume c llwted.."a=vc,Ap is the Averog Rot lubc Aociq!hpl&tr tlt tar:inns sstm led(in luhcs H.2%" o-ade o"is the mizzle d Mlle.°.,"ically. illvlam°''.H2, COIL is hc °ma collected hy'Nlcth-O f 4, "Post Iw-V k the cyst Ica .clamk.o aa.atmt itt ct'c sw,below), 7 tt c.k is.1ti t °c -l t:l1 -n M.vCho d.1�t tt t b ra� 1�,�bcd>:lt duct r�<4"'then tittcm�tt x�q t�tk����ltt ra�usi 1� used. r ram r :� �raa f DOM- l� s ��r et a t.a st A tt fxcf�tt:dt fur sit, (, I ,, r W A. ..° Upstream lttrrw (, 1 4, POODi5t:, a"wialtrcatrtfaaar cla+rrrr trc ( ): jejo �. wItI)Ownsf am Mom s � •^ s�sg � 1 X� ��s`.' �`' �' g��'t> �y- '3� YtY saiE :1 a 5 �` 4 ,w „" :�.sh' _ €+ a gra ess k;, b? ,. ':"�'""` aii`;z^5:a.`Y'.':ez'a^s w.k i r4•`,'i:d�>�>'£,<i.^'l4 suGS,s ysk3da>s,9h',Z r a3'�;`s'$Ev.f a.tg@�.w€3kr9i�1?aP ,"�u,$l.:$:.° '$�W C81 P1`:•a'"`i'BSf. 4. S a 7 a 10 Pumu coffectly marked on the pitcyt tube?' 'rootImp a , Purl letr F'lh ar:cau tcd fk i cal.culrttaOn O'ke EPA .. 8 artYrirrMAC ,rv. .tare:presiur'~must Ids !diIm..t:d minor tl,j"If g pcm ltlCtt# ow Act'aLTml(vt t lE Ytlih4"sn dx"umc. 2.9 Sample Wluu* IP Sburccs.mquire-ltr% rrmullty test rtrrrs Mr°A a o,00 dscf.N:SPS rugulatictrit t ~ly re.quirc- di: n<at sir pt +t y t.tn � r t rrsr .rtur�ns.In e4 :r r_lr to 1 k, Chcek Wm"dimnowl nfio > ' -cwr)41< t o�is Immolly peribxtr d q tl'mm"mmjpwr Orkas my be US.&I,lout rim Moot Lrrady6ts uxtt ri>z(we ti idnu r3��r;.trtr utl. �!s rrr ring:��rrr bica:t Mir and.Yr rrrr f°rtrl r xa et l t rra 41 r,.c€. tkt lrlr Isar .rrrrr stacks s trlru3t zl irr;twt, .... K # CW �rr ar € t rrit t Q no C. otn t,�x t 36. iMarl�. t : O. Ittr : t' , t° t METHOD+So Mctbud 2 .A(pajgp 2)fbr'imy,irrOr"'Oup° unpin IV x.r1'Tcrrti r•=�ttrrc I C tr:'mrcr ture of the dry��r r leegvllag i-h-v fm t:Tg rat tdczt;m mm be below(19 De"R.R tylgi3 di unbicnt totxrperaturv,as strove:69 Delp,l°rIt= taltca pToxim. tely:mimrat s fur"t'k thomm.I effeclsofthe ice Will to 0)t11 the exit t1remrrrmrter bdwv 68 Deg F, Lrrrk Or.cl;.:Ifdi:e(twMsuht rt14icioc a leA 1,4.02cfint,ru�;�mi.I&lu.�'r.:u;mle.Su c trtittti'i i-v rnrs,but it.ii tJm&x retip n of t rr tmt Uarn mw fab i.lit}'in a.m pi dw,l.:ak. I?lavmver,flwr mpt o[tit t�,r�i Il fir,�rsl�crxuly trttjst Eza�C c.lt��r�t:h�f��l�:�r��r ttc.. lsol:,twlirr;,If the w.m.t m hidicw s tt m tl.• i"Oki cl.ic mic rsrm run iN amr l IM,r rtti4ker 90 in lhc..rrrt7 sliould be*,,r lv l 3nd re���:te . ttrrricut t 'Sunp clean-up:If any,to"lrtit ttldt:tq Nam le is loci:dttr n.,g,l;J rr-trpy t c:run sbould 4e Y o and.nmmued. 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