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AQ_F_6600016_20221115_EI_Cmb-EI-File_2021 EI
2021 Emissions Inventory Review / Data Tracking Form Facility Name: Bakelite Chemicals LLC - Conway Facility Classification: Title V Assigned to: Dawn Reddix Data Entry: Northampton County Confidential Copy Submitted? YES NO Enter date received into ED. Date Received: _________________ Assigned to appropriate individual. Date Assigned: _________________ Date Due: __________________ Paper copy submitted: One copy received with supporting documentation, certification form signed by responsible official, and appears generally complete; OR Electronic copy submitted: All supporting documentation and certification form (with time/date stamp) signed by responsible official has been received. Comments: Facility ID: 6600016 Initial Review / Data Entry Inventory Review All forms and supporting documentation appear to be complete if paper submission (check ED OS data if electronic). Contact, address, phone number changes entered into I-Beam/Facilities if necessary. All known operating scenarios, control devices, and emission release points have been entered for each emission source (permitted, insignificant, and unpermitted) or note that the emission source was not operated or not required to report. Check if SCC codes for each OS are accurate and update if needed. Evaluate "U" sources for significance and address according to policy. Calculations / forms appear to add up correctly. All compliance issues are being addressed (e.g. Toxics limits, above TV thresholds, large emissions increase/decrease, installation without a permit). All volatile HAPs/TAPs were included in the VOC total. Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for the reporting facility (e.g. stack testing, AP-42, etc.). Review facility comments and address any issues. Update ED (Data Entry Main) if additional information is required (corrections due date and date received). Check all ED QA/QC reports. Comparison with previous emission inventory must be made and outliers (> 10%) must be investigated and explained. Put inventory review comments and summarize any changes in ED - Data Entry Main "DAQ internal comments". Date Review Complete: ___________________ Signature: _____________________________ Date Submitted to EI Coordinator: ___________________ Date Approved: ___________________ Initials: ___________________ Date Info Requested: ______________ Date Info Received: ______________ Total Days on Hold: ______ Alan Drake/Jeff Harris 11/10/2022 Changes due to apparent throughput increase, but also significant changes to calculation methodology. See notes. 11/15/2022 COPY of RECORD Date Submitted: 5/20/2022 08:34:49 Inventory Certification Form(Title V) Facility Name: Georgia-Pacific Chemicals LLC -Conway 200 Ampac Road Conway, NC 27820 North Carolina Department of Environmental Quality Division of Air Quality Facility ID : 6600016Permit : 04243 County : Northampton DAQ Region : RRO Air Pollutant Point Source Emissions Inventory -Calendar Year 2021 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official ti of record for your facility is Robert Dalton This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b) which references and follows the federal definition. 40 CFR Part 70.2 defines a responsible as meaning one of the following: 1.For a corporation: a president, secretary, treasurer, or vice-president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing, production, or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding $25 million(in second quarter 1980 dollars); or ii.the delegation of authority to such representatives is approved in advance by the permitting authority; 2.For partnership or sole proprietorship; a general partner or the proprietor, respectively; 3. For a municipality, state, federal, or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency (e.g., a Regional Administrator of EPA). CERTIFICATION STATEMENT: (lm�ortant: Le2all)'. Resuonsible Official, read and sii:n after all submissions are final.) I certify that I am the responsible official for this facility, as described above, and hereby certify that the information contained in this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal penalties of up to $25,000 per occurrence and possible imprisonment as outlined in G.S. § 143-2 l 5.3(a)(2)) Responsible Official's Signature Below (use blue ink): Date Signed: Printed Name: Robert Dalton 5lzo\ 2 2 Signature: K [. � This form applies to Title V facilities. If this facility is not classified asTitle V, please telephone your regional office Emission Inventory Contact at once for proper forms. Email address of Responsible Official: Robert.Dalton@gapac.com Information on this Form cannot be held confidential COPY of RECORD Date Submitted: 5/2012022 08:34:49 .tal QuaUt)'NC Dept of Env1ronmen MAY 2 3 2022 Raleigh Regional Office Bakelite Chemicals LLC - Conway 04243T27 6600016 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Pollutant CAS CY 2021 from ED CY 2020 from Fees Green House Gases Pollutants (GHG)Actual Emissions Tons/Yr % ChangeDemini- mus Carbon Dioxide (CO2)124389 12,226.43 10,839.12 12.8%5,000.0 Methane (CH4)74-82-8 0.180000 0.180000 0.0%10.0 Nitrous Oxide (N2O)10024972 0.014800 0.010000 48.0%1.0 CO2 equivalent (sum of individual GHG pollutant emission times their 1995 IPCC Global Warming Potential (GWP), converted to metric tons) 11,099.41 metric tons Criteria Pollutants CY 2021 from ED CY 2020 from Fees (Tons/Year) Actual Emissions % ChangePollutantCASDemini- mus -29.9%30.0421.07CO 0.5CO 0.0%7.987.98NOx 0.5NOx 1.2%32.9033.30TSP 0.5PM(TSP) 1.7%26.2326.67PM10 0.5PM10 1.7%24.9525.37PM2.5 0.5PM2.5 40.0%0.0500000.070000SO2 0.5SO2 12.7%85.0695.84VOC 0.5VOC Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus Polycyclic Organic Matter (Specific Compounds from OAQPS for TV) 0.003850 0.004940 N/A1.0 N/A0.0049400.00385091-20-3 1.0Naphthalene (Component of 83329/POMTV) 3.1%238.70246.1375-07-0 10.0Acetaldehyde N/A0.0003000.000230107-02-8 10.0Acrolein 3.0%616.66635.437664-41-7 100.0Ammonia (as NH3) 5.3%0.3965300.41772071-43-2 1.0Benzene 3.2%935.90966.101319-77-3 10.0Cresol (mixed isomers) Page 1 of 211/09/2022 Bakelite Chemicals LLC - Conway 04243T27 6600016 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus 4.3%11,776.3512,287.2350-00-0 10.0Formaldehyde 13.2%304.89345.26110-54-3 100.0Hexane, n- -0.4%196.11195.3378-93-3 100.0MEK (methyl ethyl ketone, 2-butanone) 5.2%101,746.08107,003.2967-56-1 1,000.0Methanol (methyl alcohol) 2.1%3,106.813,171.19108-95-2 100.0Phenol -22.0%0.0080600.006290POM 1.0Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) 2.7%484.00497.00100-42-5 100.0Styrene 12.6%0.5868100.660780108-88-3 100.0Toluene N/ANot Reported 542.00121-44-8 100.0Triethylamine -22.1%0.0073400.0057201330-20-7 100.0Xylene (mixed isomers) Largest Individual HAP 107,003.29 lbs 125,059.29 lbsTotal HAP Emissions Methanol (methyl alcohol) Largest Individual CAP 95.84 tons Total CAP Emissions 151.63 tons Total TAP Emissions 18,344.75 lbs Total Aggregate Emissions 151.95 tons VOC Page 2 of 211/09/2022 DAQ's Comments Regarding Inventory CO decrease linked to OS1 Formaldehyde Mfg, despite apparent increase in production relative to 2020. VOC increase primarily results from cited production increase for OS1 Formaldehyde Mfg relative to 2020. n-Hexane increase linked to increased NG combustion for OS21 resin mfg thermal oxidizer and OS55 spray dryer. Facility added the following: emission differences between 2020RY and 2021RY are due to a change in the calculation methodology and a broken link within the AEI spreadsheet between the two years. While working through the 2021RY report, we realized that the in previous years, the OS1 calculations were based on 100% formaldehyde concentration but should have been based on 50% formaldehyde concentration. Once we changed the gallons to represent the throughput at 50% concentration and properly linked the CO to the 2016 Stack Test value for CO, it gave the appearance that the 2021RY throughput increased while the CO decreased. In summary, it appears that we underreported the CO emissions for the 2020RY. We are comfortable saying that the 2021RY emission values and associated calculations are now correct and that methodology will be transferred to future submissions. Facility Emissions - Operating Scenarios Per Pollutant Bakelite Chemicals LLC - Conway 2021 Inventory Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Acetaldehyde OS-1 20.13 Pounds 18.70 Pounds VS2A-ES-2 VS2A-ES-2 OS-27 0.000750 Pounds 0.000960 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-54 226.00 Pounds 220.00 Pounds VS5A VS5A TOTAL in Current Inventory: 246.13 Pounds TOTAL in Previous Inventory: 238.70 Pounds Acrolein OS-27 0.000230 Pounds 0.000300 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Ammonia (as NH3) OS-12 36.77 Pounds 26.88 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-40 278.66 Pounds 272.78 Pounds ES-S19 ES-S19 OS-54 320.00 Pounds 317.00 Pounds VS5A VS5A TOTAL in Current Inventory: 635.43 Pounds TOTAL in Previous Inventory: 616.66 Pounds Benzene OS-3 0.037900 Pounds 0.036900 Pounds ES-B1 ES-B1 11/9/2022 Page 1 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-20 0.050000 Pounds 0.060000 Pounds VS2A-ES-2 VS2A-ES-2 OS-21 0.050000 Pounds 0.030000 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-27 0.023000 Pounds 0.029500 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-33 0.000010 Pounds I-HTF I-HTF OS-37 0.006810 Pounds 0.010130 Pounds ES-B2 ES-B2 OS-55 0.250000 Pounds 0.230000 Pounds VS5A VS5A TOTAL in Current Inventory: 0.42 Pounds TOTAL in Previous Inventory: 0.40 Pounds Carbon Dioxide (CO2) OS-3 1,076.93 Tons 1,048.39 Tons ES-B1 ES-B1 OS-20 2,290.78 Tons 2,298.32 Tons VS2A-ES-2 VS2A-ES-2 OS-21 1,503.43 Tons 787.73 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-27 3.10 Tons ES-GEN1 ES-GEN2 OS-33 0.400000 Tons 0.400000 Tons I-HTF I-HTF OS-37 193.00 Tons 288.00 Tons ES-B2 ES-B2 OS-55 7,161.89 Tons 6,413.18 Tons VS5A VS5A TOTAL in Current Inventory: 12,226.43 Tons TOTAL in Previous Inventory: 10,839.12 Tons 11/9/2022 Page 2 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 CO OS-1 4.57 Tons 13.81 Tons VS2A-ES-2 VS2A-ES-2 OS-2 4.18 Tons 4.19 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-3 0.760000 Tons 0.740000 Tons ES-B1 ES-B1 OS-27 0.010000 Tons 0.010000 Tons ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-37 0.140000 Tons 0.200000 Tons ES-B2 ES-B2 OS-54 11.41 Tons 11.09 Tons VS5A VS5A TOTAL in Current Inventory: 21.07 Tons TOTAL in Previous Inventory: 30.04 Tons Cresol (mixed isomers) OS-12 108.10 Pounds 99.90 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-54 858.00 Pounds 836.00 Pounds VS5A VS5A TOTAL in Current Inventory: 966.10 Pounds TOTAL in Previous Inventory: 935.90 Pounds Formaldehyde OS-1 3,037.89 Pounds 2,821.25 Pounds VS2A-ES-2 VS2A-ES-2 OS-2 22.29 Pounds 21.72 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-3 1.35 Pounds 1.32 Pounds ES-B1 ES-B1 OS-10 150.00 Pounds 110.00 Pounds VS2A-ES-2 VS2A-ES-2 OS-12 534.10 Pounds 510.40 Pounds 11/9/2022 Page 3 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 VS4A.1-ES4.1 VS4A.1-ES4.1 OS-19 15.01 Pounds 14.97 Pounds PFTF PFTF OS-27 0.002340 Pounds 0.003000 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-29 36.84 Pounds 33.84 Pounds ESR8 ESR8 UFTF UFTF OS-33 0.000500 Pounds I-HTF I-HTF OS-37 0.243220 Pounds 0.361930 Pounds ES-B2 ES-B2 OS-41 1.50 Pounds 1.49 Pounds I-P11 I-P11 I-P12 I-P12 OS-54 8,488.00 Pounds 8,261.00 Pounds VS5A VS5A TOTAL in Current Inventory: 12,287.23 Pounds TOTAL in Previous Inventory: 11,776.35 Pounds Hexane, n- OS-3 32.49 Pounds 31.63 Pounds ES-B1 ES-B1 OS-20 46.79 Pounds 48.61 Pounds VS2A-ES-2 VS2A-ES-2 OS-21 44.05 Pounds 22.46 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-33 0.010000 Pounds 0.010000 Pounds I-HTF I-HTF OS-37 5.84 Pounds 8.69 Pounds ES-B2 ES-B2 OS-55 216.08 Pounds 193.49 Pounds VS5A VS5A 11/9/2022 Page 4 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 TOTAL in Current Inventory: 345.26 Pounds TOTAL in Previous Inventory: 304.89 Pounds MEK (methyl ethyl ketone, 2-butanone) OS-12 194.59 Pounds 195.42 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-44 0.740000 Pounds 0.690000 Pounds I-A2 I-A2 TOTAL in Current Inventory: 195.33 Pounds TOTAL in Previous Inventory: 196.11 Pounds Methane (CH4) OS-3 0.020000 Tons 0.020000 Tons ES-B1 ES-B1 OS-20 0.030000 Tons 0.030000 Tons VS2A-ES-2 VS2A-ES-2 OS-21 0.010000 Tons VS4A.1-ES4.1 OS-55 0.130000 Tons 0.120000 Tons VS5A VS5A TOTAL in Current Inventory: 0.18 Tons TOTAL in Previous Inventory: 0.18 Tons Methanol (methyl alcohol) OS-1 2,558.32 Pounds 2,375.89 Pounds VS2A-ES-2 VS2A-ES-2 OS-2 228.49 Pounds 222.98 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-10 716.00 Pounds 415.00 Pounds VS2A-ES-2 VS2A-ES-2 OS-12 3,790.30 Pounds 3,324.30 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-19 837.21 Pounds 829.66 Pounds PFTF PFTF OS-29 32.66 Pounds 29.99 Pounds ESR8 ESR8 11/9/2022 Page 5 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 UFTF UFTF OS-41 10.31 Pounds 10.26 Pounds I-P11 I-P11 I-P12 I-P12 OS-54 98,830.00 Pounds 94,538.00 Pounds VS5A VS5A TOTAL in Current Inventory: 107,003.29 Pounds TOTAL in Previous Inventory: 101,746.08 Pounds Naphthalene (Component of 83329/POMTV) OS-27 0.003850 Pounds 0.004940 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Nitrous Oxide (N2O) OS-3 0.002000 Tons ES-B1 ES-B1 OS-21 0.002800 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-55 0.010000 Tons 0.010000 Tons VS5A VS5A TOTAL in Current Inventory: 0.01 Tons TOTAL in Previous Inventory: 0.01 Tons NOx OS-2 0.920000 Tons 0.920000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-3 0.900000 Tons 0.880000 Tons ES-B1 ES-B1 OS-20 1.30 Tons 1.35 Tons VS2A-ES-2 VS2A-ES-2 OS-27 0.050000 Tons 0.070000 Tons ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-37 0.160000 Tons 0.240000 Tons 11/9/2022 Page 6 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-B2 ES-B2 OS-54 4.65 Tons 4.52 Tons VS5A VS5A TOTAL in Current Inventory: 7.98 Tons TOTAL in Previous Inventory: 7.98 Tons Phenol OS-2 1.02 Pounds 1.00 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-12 881.20 Pounds 830.70 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-19 3.76 Pounds 3.78 Pounds PFTF PFTF OS-41 0.600000 Pounds 0.600000 Pounds I-P11 I-P11 I-P12 I-P12 OS-46 1,002.57 Pounds 1,002.69 Pounds ESR1 ESR1 ESR10 ESR10 ESR2 ESR2 ESR5 ESR5 OS-47 740.04 Pounds 740.04 Pounds ES-PU ES-PU OS-54 542.00 Pounds 528.00 Pounds VS5A VS5A TOTAL in Current Inventory: 3,171.19 Pounds TOTAL in Previous Inventory: 3,106.81 Pounds PM(TSP) OS-3 0.070000 Tons 0.070000 Tons ES-B1 ES-B1 OS-20 0.100000 Tons 0.100000 Tons VS2A-ES-2 VS2A-ES-2 OS-21 0.090000 Tons 0.050000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-35 0.010000 Tons 0.010000 Tons 11/9/2022 Page 7 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-UH-K3 ES-UH-K3 OS-36 0.010000 Tons 0.010000 Tons ES-UH-K8 ES-UH-K8 OS-37 0.010000 Tons 0.020000 Tons ES-B2 ES-B2 OS-48 0.150000 Tons 0.150000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-49 0.210000 Tons 0.210000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-50 1.12 Tons 1.19 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-51 0.230000 Tons 0.250000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-52 0.230000 Tons 0.250000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-53 8.26 Tons 8.04 Tons ES-MU ES-MU I-D I-D I-DP I-DP I-P28 I-P28 I-R9 I-R9 I-RU1 I-RU1 I-SD1 I-SD1 I-WW1 I-WW1 VS2A-ES-FL VS2A-ES-FL OS-55 22.81 Tons 22.55 Tons VS5A VS5A TOTAL in Current Inventory: 33.30 Tons TOTAL in Previous Inventory: 32.90 Tons PM10 OS-3 0.070000 Tons 0.070000 Tons 11/9/2022 Page 8 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-B1 ES-B1 OS-20 0.100000 Tons 0.100000 Tons VS2A-ES-2 VS2A-ES-2 OS-21 0.090000 Tons 0.050000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-35 0.010000 Tons 0.010000 Tons ES-UH-K3 ES-UH-K3 OS-36 0.010000 Tons 0.010000 Tons ES-UH-K8 ES-UH-K8 OS-37 0.010000 Tons 0.020000 Tons ES-B2 ES-B2 OS-48 0.140000 Tons 0.140000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-49 0.200000 Tons 0.200000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-50 1.12 Tons 1.19 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-51 0.230000 Tons 0.250000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-52 0.230000 Tons 0.030000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-53 1.65 Tons 1.61 Tons ES-MU ES-MU I-D I-D I-DP I-DP I-P28 I-P28 I-R9 I-R9 I-RU1 I-RU1 I-SD1 I-SD1 I-WW1 I-WW1 11/9/2022 Page 9 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 VS2A-ES-FL VS2A-ES-FL OS-55 22.81 Tons 22.55 Tons VS5A VS5A TOTAL in Current Inventory: 26.67 Tons TOTAL in Previous Inventory: 26.23 Tons PM2.5 OS-3 0.070000 Tons 0.070000 Tons ES-B1 ES-B1 OS-20 0.100000 Tons 0.100000 Tons VS2A-ES-2 VS2A-ES-2 OS-21 0.090000 Tons 0.050000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-35 0.010000 Tons 0.010000 Tons ES-UH-K3 ES-UH-K3 OS-36 0.010000 Tons 0.010000 Tons ES-UH-K8 ES-UH-K8 OS-37 0.010000 Tons 0.020000 Tons ES-B2 ES-B2 OS-48 0.120000 Tons 0.120000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-49 0.160000 Tons 0.160000 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-50 1.12 Tons 1.19 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-51 0.230000 Tons 0.250000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 OS-52 0.230000 Tons 0.030000 Tons ES-11.1 ES-11.1 ES-11.2 ES-11.2 11/9/2022 Page 10 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-53 0.410000 Tons 0.390000 Tons ES-MU ES-MU I-D I-D I-DP I-DP I-P28 I-P28 I-R9 I-R9 I-RU1 I-RU1 I-SD1 I-SD1 I-WW1 I-WW1 VS2A-ES-FL VS2A-ES-FL OS-55 22.81 Tons 22.55 Tons VS5A VS5A TOTAL in Current Inventory: 25.37 Tons TOTAL in Previous Inventory: 24.95 Tons Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) OS-27 0.006290 Pounds 0.008060 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 TOTAL in Current Inventory: 0.01 Pounds TOTAL in Previous Inventory: 0.01 Pounds SO2 OS-3 0.010000 Tons 0.010000 Tons ES-B1 ES-B1 OS-20 0.010000 Tons 0.010000 Tons VS2A-ES-2 VS2A-ES-2 OS-21 0.010000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-55 0.040000 Tons 0.030000 Tons VS5A VS5A TOTAL in Current Inventory: 0.07 Tons TOTAL in Previous Inventory: 0.05 Tons Styrene OS-54 497.00 Pounds 484.00 Pounds VS5A VS5A TOTAL in Current Inventory: 497.00 Pounds TOTAL in Previous Inventory: 484.00 Pounds Toluene 11/9/2022 Page 11 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-3 0.061400 Pounds 0.059700 Pounds ES-B1 ES-B1 OS-20 0.090000 Pounds 0.090000 Pounds VS2A-ES-2 VS2A-ES-2 OS-21 0.080000 Pounds 0.040000 Pounds VS4A.1-ES4.1 VS4A.1-ES4.1 OS-27 0.008330 Pounds 0.010700 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 OS-33 0.000020 Pounds I-HTF I-HTF OS-37 0.011030 Pounds 0.016410 Pounds ES-B2 ES-B2 OS-55 0.410000 Pounds 0.370000 Pounds VS5A VS5A TOTAL in Current Inventory: 0.66 Pounds TOTAL in Previous Inventory: 0.59 Pounds Triethylamine OS-54 542.00 Pounds VS5A VS5A TOTAL in Current Inventory: 542.00 Pounds VOC OS-1 10.44 Tons 4.84 Tons VS2A-ES-2 VS2A-ES-2 OS-2 0.130000 Tons 0.120000 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-3 0.050000 Tons 0.050000 Tons ES-B1 ES-B1 OS-12 2.75 Tons VS4A.1-ES4.1 VS4A.1-ES4.1 OS-19 0.430000 Tons 0.420000 Tons PFTF PFTF 11/9/2022 Page 12 of 13 Bakelite Chemicals LLC - Conway 6600016 04243T27 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-29 0.040000 Tons 0.030000 Tons ESR8 ESR8 UFTF UFTF OS-37 0.010000 Tons 0.010000 Tons ES-B2 ES-B2 OS-41 0.010000 Tons 0.010000 Tons I-P11 I-P11 I-P12 I-P12 OS-46 0.500000 Tons 0.500000 Tons ESR1 ESR1 ESR10 ESR10 ESR2 ESR2 ESR5 ESR5 OS-47 0.370000 Tons 0.370000 Tons ES-PU ES-PU OS-48 10.10 Tons 10.10 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-49 14.03 Tons 14.03 Tons ES-T1A ES-T1A ES-T3 ES-T3 OS-54 56.98 Tons 54.58 Tons VS5A VS5A TOTAL in Current Inventory: 95.84 Tons TOTAL in Previous Inventory: 85.06 Tons Xylene (mixed isomers) OS-27 0.005720 Pounds 0.007340 Pounds ES-GEN1 ES-GEN1 ES-GEN2 ES-GEN2 TOTAL in Current Inventory: 0.01 Pounds TOTAL in Previous Inventory: 0.01 Pounds 11/9/2022 Page 13 of 13 1 Drake, Alan From:Riddick, Timothy A <timothy.riddick@bakelite.com> Sent:Friday, November 4, 2022 8:42 AM To:Drake, Alan Subject:RE: [External] RE: Georgia-Pacific Chemicals - Conway CY2021 Emissions Inventory Attachments:Calcs - DEQ Request.pdf CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good morning Alan, I think that you will find this pdf. helpful to zoom in to see what you need. If this format does not suffice or does not include all of the information that you would looking, please let me know. Thanks, Tim Tim Riddick Facility Environmental Manager 200 Ampac Rd Conway NC 27820 US +1 252‐585‐3819 timothy.riddick@bakelite.com This message, including attached files, is confidential and intended for the addressees. It may contain information that is proprietary, privileged or exempt for disclosure under applicable law. Any unauthorized use and dissemination of the information or copying of this message is strictly prohibited. Any views, opinions or conclusions expressed in this message are those of the individual sender and do not necessarily reflect the view of the Bakelite Synthetics group of companies (“Bakelite Synthetics”). If you received this message in error, please immediately advise the sender by reply email, delete all copies of this message and refrain from printing, copying, or disseminating this message or otherwise using the information in it. Thank you. Although Bakelite Synthetics routinely screens incoming and outgoing mail messages for viruses, addressees should scan this e‐mail and any attachments for viruses themselves. Bakelite Synthetics does not guarantee in any way the absence of viruses in this e‐mail or any attachments and disclaims any liability in case of security problem that this message may cause to any system. From: Drake, Alan <alan.drake@ncdenr.gov> Sent: Thursday, November 3, 2022 5:37 PM To: Riddick, Timothy A <timothy.riddick@bakelite.com> Subject: RE: [External] RE: Georgia‐Pacific Chemicals ‐ Conway CY2021 Emissions Inventory CAUTION EXTERNAL EMAIL: Please be cautious when opening links or attachments in email I understand, Tim. I’ve had those days too. Thanks for your attention to this matter. Alan 2 Alan Drake Environmental Engineer, Division of Air Quality North Carolina Department of Environmental Quality 1641 Mail Service Center, Raleigh, NC 27699 Office: (919) 707‐8493 alan.drake@ncdenr.gov From: Riddick, Timothy A <timothy.riddick@bakelite.com> Sent: Thursday, November 3, 2022 5:32 PM To: Drake, Alan <alan.drake@ncdenr.gov> Subject: [External] RE: Georgia‐Pacific Chemicals ‐ Conway CY2021 Emissions Inventory CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Mr. Drake, It’s been one of those days so I apologize for not replying earlier. I will get you the requested information as soon as possible tomorrow if that is acceptable. Thanks, Tim Tim Riddick Facility Environmental Manager 200 Ampac Rd Conway NC 27820 US +1 252‐585‐3819 timothy.riddick@bakelite.com This message, including attached files, is confidential and intended for the addressees. It may contain information that is proprietary, privileged or exempt for disclosure under applicable law. Any unauthorized use and dissemination of the information or copying of this message is strictly prohibited. Any views, opinions or conclusions expressed in this message are those of the individual sender and do not necessarily reflect the view of the Bakelite Synthetics group of companies (“Bakelite Synthetics”). If you received this message in error, please immediately advise the sender by reply email, delete all copies of this message and refrain from printing, copying, or disseminating this message or otherwise using the information in it. Thank you. Although Bakelite Synthetics routinely screens incoming and outgoing mail messages for viruses, addressees should scan this e‐mail and any attachments for viruses themselves. Bakelite Synthetics does not guarantee in any way the absence of viruses in this e‐mail or any attachments and disclaims any liability in case of security problem that this message may cause to any system. 3 From: Drake, Alan <alan.drake@ncdenr.gov> Sent: Thursday, November 3, 2022 9:26 AM To: Riddick, Timothy A <timothy.riddick@bakelite.com> Subject: Georgia‐Pacific Chemicals ‐ Conway CY2021 Emissions Inventory Importance: High CAUTION EXTERNAL EMAIL: Please be cautious when opening links or attachments in email November 3, 2022 Tim, I’m currently reviewing the subject emissions inventory, dated May 20, 2022, and am having a very difficult time reading the attachments. I’ve tried scanning and zooming in on some items but they become pixelated and unreadable especially if they’re on a colored background. The last 12 pages, beginning with boiler ES‐B1 are legible but the previous pages are not. If you could email me the spreadsheets for the first dozen pages attached to the letter, I’d appreciate it. Best regards, Alan Alan Drake Environmental Engineer, Division of Air Quality North Carolina Department of Environmental Quality 1641 Mail Service Center, Raleigh, NC 27699 Office: (919) 707‐8493 alan.drake@ncdenr.gov 1. i. ii. 2. 3. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b) which references and follows the federal definition. 40 CFR Part 70.2 defines a responsible as meaning one of the following: For a corporation: a president, secretary, treasurer, or vice-president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing, production, or operating facilities applying for a or subject to a permit and either the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding $25 million(in second quarter 1980 dollars); or the delegation of authority to such representatives is approved in advance by the permitting authority; For partnership or sole proprietorship; a general partner or the proprietor, respectively; For a municipality, state, federal, or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency (e.g., a Regional Administrator of EPA). COPY of RECORD Date Submitted: 5/20/2022 08:34:49 Inventory Certification Form(Title V) Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Robert Dalton This person or one that meets the definition below must sign this certification form. CERTIFICATION STATEMENT: (Important: Legally Responsible Official, read and sign after all submissions are final.) I certify that I am the responsible official for this facility, as described above, and hereby certify that the information contained in this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal penalties of up to $25,000 per occurrence and possible imprisonment as outlined in G.S. § 143-215.3(a)(2)) Responsible Official's Signature Below (use blue ink): Date Signed: Printed Name: Robert Dalton Signature: This form applies to Title V facilities. If this facility is not classified asTitle V, please telephone your regional office Emission Inventory Contact at once for proper forms. Email address of Responsible Official:Robert.Dalton@gapac.com Information on this Form cannot be held confidential COPY of RECORD Date Submitted: 5/20/2022 08:34:49 1 Listing of Emission Sources and Control Devices on Permit. See instructions COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO *ES ID on Air Permit *ES Description *CS ID *CS Description * CD ID's ES-11.1 Extender storage silo RM3 ES-11.2 Extender storage silo RM4 ES-B1 One natural gas/propane-fired boiler (25.1 million Btu per hour maximum heat input rate) [NSPS Dc, MACT DDDDD] ES-B2 One natural gas-fired temporary boiler (less than 25 million Btu per hour maximum heat input rate) [NSPS Dc, MACT DDDDD] ES-GEN1 Diesel-fired generator (500 kW maximum rated power output) [MACT ZZZZ] ES-GEN2 Diesel-fired generator (500 kW maximum rated power output) [MACT ZZZZ] ES-MU Methanol tank truck/railcar unloading ES-PU Phenol unloading operations [MACT OOO, MACT UU] ES-RLR Resin loading racks comprised of emissions from East Load Rack, West Load Rack, Reactor Load Rack, and Railcar Load Rack ES-S19 Aqueous ammonia storage tank (9,924 gallon capacity) [MACT OOO, MACT UU] CS-6 One scrubber tank (56 inch minimum water level from tank bottom), CD-S19 ES-T1A Cooling Tower HX1 (432,000 gallons per hour capacity) [MACT F] ES-T3 Cooling Tower HX2 (600,000 gallons per hour capacity) [MACT OOO] ES-UH-K3 Urea unloading hopper for reactor #3 ES-UH-K8 Urea unloading hopper for reactor #8 ES4.6 Batch non-reactor vessel, mix/blend tank K6 [MACT OOO, MACT UU] ESR1 Phenol storage tank (22,548 gallon capacity) [MACT OOO, MACT UU] ESR10 Phenol storage tank (22,548 gallon capacity) [MACT OOO, MACT UU] ESR2 Phenol storage tank (22,548 gallon capacity) [MACT OOO, MACT UU] ESR5 Phenol storage tank (22,548 gallon capacity) [MACT OOO, MACT UU] 2 ESR8 Urea-formaldehyde concentrate (UFC) storage tank (25,366 gallon capacity) [MACT OOO, MACT UU] I-A2 Methyl ethyl ketone tank (9,910 gallon capacity) I-C1 Sulfuric acid tank (5,000 gallon capacity) I-C2 GP-4590 Pre-catalyst tank (5,000 gallon capacity) I-C3 GP-4590 Pre-catalyst tank (5,000 gallon capacity) I-CF Resin loading operations - Container loading I-D Diesel fuel dispenser rack I-D1 Diesel fuel tank (12,000 gallon capacity) I-D2 Diesel fuel tank (10,000 gallon capacity) I-DP Solid resins drying pad I-FA Formic acid tank (2,610 gallon capacity) I-FL Formaldehyde loading operations - East Load Rack I-G1 Gasoline tank (2,000 gallon capacity) I-HTF Natural gas/propane-fired heat transfer fluid heater (2.3 million Btu per hour maximum heat input rate) I-HTF1 Heat transfer fluid tank (2,800 gallon capacity) I-MU Methanol/formaldehyde unloading I-N1 PF resin tank (22,559 gallon capacity) I-N2 PF resin tank (22,559 gallon capacity) I-N3 PF resin tank (22,559 gallon capacity) I-N4 PF resin tank (22,559 gallon capacity) I-N5 PF resin tank (22,559 gallon capacity) I-N6 PF resin tank (22,559 gallon capacity) I-N7 PF resin tank (22,559 gallon capacity) I-NMO New motor oil tank (500 gallon capacity) I-P1 PF RESI-MIX resin tank (25,908 gallon capacity) I-P10 PF RESI-MIX resin tank (25,908 gallon capacity) I-P11 PF RESI-MIX resin tank (25,908 gallon capacity) I-P12 PF RESI-MIX resin tank (25,908 gallon capacity) I-P13 PF resin tank (22,669 gallon capacity) I-P14 PF resin tank (22,669 gallon capacity) 3 I-P15 PF resin tank (22,669 gallon capacity) I-P17 PF resin tank (22,669 gallon capacity) I-P19 PF resin tank (22,669 gallon capacity) I-P2 PF RESI-MIX resin tank (25,908 gallon capacity) I-P20 PF resin tank (22,669 gallon capacity) I-P21 PF resin tank (22,669 gallon capacity) I-P22 PF resin tank (22,669 gallon capacity) I-P23 PF resin tank (22,669 gallon capacity) I-P24 PF Resin tank (22,669 gallon capacity) I-P25 PF resin tank (22,669 gallon capacity) I-P26 PF resin tank (22,669 gallon capacity) I-P27 PF resin tank (22,669 gallon capacity) I-P28 PF resin tank (22,669 gallon capacity) I-P3 PF RESI-MIX resin tank (25,908 gallon capacity) I-P30 Process water tank (2,560 gallon capacity) I-P4 PF RESI-MIX resin tank (25,908 gallon capacity) I-P5 PF RESI-MIX resin tank (25,908 gallon capacity) I-P6 PF RESI-MIX resin tank (25,908 gallon capacity) I-P7 PF RESI-MIX resin tank (25,908 gallon capacity) I-P8 PF RESI-MIX resin tank (25,908 gallon capacity) I-P9 PF RESI-MIX resin tank (25,908 gallon capacity) I-PR-1 Paved Roads I-R1.21B Phenol tank (22,540 gallon capacity) I-R10.21B Phenol tank (22,540 gallon capacity) I-R2.21B Phenol tank (22,540 gallon capacity) I-R3 Cresylic acid tank (22,669 gallon capacity) I-R4 Caustic soda tank (29,500 gallon capacity) I-R5.21B Phenol tank (22,540 gallon capacity) I-R6 Process water tank (19,000 gallon capacity) I-R7 Urea solution tank (19,431 gallon capacity) I-R8.21B Urea formaldehyde concentrate tank (25,379 gallon capacity) 4 I-R9 Process water tank (29,000 gallon capacity) I-RMCT1 Resi-Mix Chill Tank (6,141 gallon capacity) I-RU1 Granular urea railcar screw conveyor unloading I-RUR Resin unloading rack No. 7 I-S1 PF flammable resin tank (9,910 gallon capacity) I-S11 PF flammable resin tank (9,910 gallon capacity) I-S12 PF flammable resin tank (9,910 gallon capacity) I-S14 PF specialty resins tank (9,910 gallon capacity) I-S15 PF specialty resins tank (9,910 gallon capacity) I-S16 PF specialty resins tank (9,910 gallon capacity) I-S17 PF specialty resins tank (9,910 gallon capacity) I-S18 PF specialty resins tank (9,910 gallon capacity) I-S2 PF flammable resin tank (9,910 gallon capacity) I-S20 Distillate water tank (9,910 gallon capacity) I-S21 PF specialty resins tank (9,910 gallon capacity) I-S22 PF specialty resins tank (9,910 gallon capacity) I-S3 PF flammable resin tank (9,910 gallon capacity) I-S4 PF flammable resin tank (9,910 gallon capacity) I-S5 PF flammable resin tank (9,910 gallon capacity) I-S6 PF flammable resin tank (9,910 gallon capacity) I-S7 PF flammable resin tank (9,910 gallon capacity) I-S8 PF flammable resin tank (9,910 gallon capacity) I-S9 PF flammable resin tank (9,910 gallon capacity) I-SD1 Truck unloading of spray dry material I-U1 PF flammable resin tank (22,443 gallon capacity) I-U10 UF resin tank (22,443 gallon capacity) I-U2 PF flammable resin tank (22,443 gallon capacity) I-U3 PF flammable resin tank (22,443 gallon capacity) I-U4 UF resin tank (22,443 gallon capacity) I-U5 UF resin tank (22,443 gallon capacity) 5 I-U6 UF resin tank (22,443 gallon capacity) I-U7 UF resin tank (22,443 gallon capacity) I-U8 UF resin tank (22,443 gallon capacity) I-U9 UF resin tank (22,443 gallon capacity) I-UMO Used motor oil tank (500 gallon capacity) I-WW1 Process water tank (27,678 gallon capacity) I-WW2 Process water tank (12,500 gallon capacity) ICT-1 PF RESI-MIX resin tank (27,663 gallon capacity) ICT-2 PF RESI-MIX resin tank (27,663 gallon capacity) ISD-1 PF resin tank (27,663 gallon capacity) ISD-2 PF resin tank (27,663 gallon capacity) PFTF Phenol-formaldehyde resin tank farm [MACT OOO, MACT UU] UFTF Urea-formaldehyde resin tank farm [MACT OOO, MACT UU] VS2A-ES-2 One formaldehyde production process including vaporizers, catalytic converters, cooling systems, an after cooler and an absorber [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A-ES- FL One formaldehyde tank truck loading rack VS2A- ES3M1 One methanol storage tank (507,852 gallon capacity) when this source is operating under its primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F1 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F2 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F3 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F4 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A 6 VS2A- ES7F5 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F6 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F7 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS2A- ES7F8 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the primary compliance scenario [MACT F, MACT G, MACT H] CS-1 Catalytic incinerator (4.5 cf of catalyst, propane fired 4.0 MBtu/hr primary burner CD-2A VS4A.1-ES- 13 one mix/blend tank [MACT OOO, MACT UU] VS4A.1- ES4.1 Batch reactor vessel [MACT OOO, MACT UU] CS-2 Thermal oxidizer (propane/natural gas fired 2.9 million Btu per hour) CD-4A VS4A.1- ES4.1-5WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.1- ES4.2 Batch reactor vessel [MACT OOO, MACT UU] VS4A.1- ES4.2WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.1- ES4.3 Batch reactor vessel [MACT OOO, MACT UU] VS4A.1- ES4.5 Batch reactor vessel [MACT OOO, MACT UU] VS4A.1- ES4.7 Batch reactor vessel [MACT OOO, MACT UU] VS4A.1- ES4.8 Batch reactor vessel [MACT OOO, MACT UU] VS4A.1- ES4.8WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.2-ES- 13 one mix/blend tank [MACT OOO, MACT UU] VS4A.2- ES3M1 One methanol storage tank (507,852 gallon capacity) when this source is operating under its alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES4.1 Batch reactor vessel [MACT OOO, MACT UU] VS4A.2- ES4.1-5WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.2- ES4.2 Batch reactor vessel [MACT OOO, MACT UU] VS4A.2- ES4.2WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.2- ES4.3 Batch reactor vessel [MACT OOO, MACT UU] VS4A.2- ES4.5 Batch reactor vessel [MACT OOO, MACT UU] 7 VS4A.2- ES4.7 Batch reactor vessel [MACT OOO, MACT UU] VS4A.2- ES4.8 Batch reactor vessel [MACT OOO, MACT UU] VS4A.2- ES4.8WT Batch non-reactor vessel (weigh tank) [MACT OOO, MACT UU] VS4A.2- ES7F1 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F2 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F3 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F4 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F5 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F6 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F7 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS4A.2- ES7F8 One formaldehyde/methanol storage tank (26,212 gallon capacity) when operating under the alternate compliance scenario [MACT F, MACT G, MACT H] VS5A Continuous process vent stream comprised of emissions from the spray dry resin production process including a natural gas/propane-fired atomizing air heater (14.6 million Btu per hour maximum heat input rate), a spray dryer, several transfer cyclones and a product bagging operation (No. ES-5) [CAM, MACT OOO, MACT UU] CS-3 Bagfilter (18,600 sf of filter area), Bagfilter (1000 sf of filter area) CD-5A 8 Emission Source & Operating Scenario List - See Instructions COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO *ES Group ID *ES ID *OS ID *OS Description GR92 VS2A-ES7F1, VS2A- ES7F2, VS2A-ES7F3, VS2A-ES7F4, VS2A- ES7F5, VS2A-ES7F6, VS2A-ES7F7, VS2A-ES7F8 13 Formaldehdyde Raw Material Storage Tanks GR93 ESR1, ESR10, ESR2, ESR5 46 Phenol Raw Material Storage Tanks GR95 ESR8, UFTF 29 Urea Formaldehyde Resin Storage Tanks G-105 ES-GEN1, ES-GEN2 27 Industrial engines GR163 I-P11, I-P12 41 Phenol-Formaldehyde Resin Storage Tanks GR166 ES-MU, I-D, I-DP, I-P28, I- R9, I-RU1, I-SD1, I-WW1, VS2A-ES-FL 53 Paved Roads (PR-1) GR181 ES-T1A, ES-T3 48 Cooling Tower (ES-T1A) 49 Cooling Tower (ES-T3) GR186 ES-11.1, ES-11.2 50 RESI-MIXER® (ES4.6) 51 RM3 Extender Storage Silo (ES-11.1) 52 RM4 Extender Storage Silo (ES-11.2) ES-B1 3 Natural gas/propane fired boiler (25.1 MMBtu/hr heat input) ES-B2 37 Temporary Boiler - Used only when on- site boiler is to be out of service for extended period. ES-PU 47 Fugitive emissions from phenol unloading ES-RLR NONE NONE ES-S19 40 Aqueous ammonia storage tank ES-UH-K3 35 Urea Hopper for Reactor #3 ES-UH-K8 36 Urea Hopper for Reactor #8 ES4.6 NONE NONE I-A2 44 MEK Usage I-C1 NONE NONE I-C2 NONE NONE I-C3 NONE NONE I-CF NONE NONE I-D1 NONE NONE I-D2 NONE NONE I-FA NONE NONE I-FL NONE NONE I-G1 NONE NONE I-HTF 33 DowTherm Heater 9 I-HTF1 NONE NONE I-MU NONE NONE I-N1 NONE NONE I-N2 NONE NONE I-N3 NONE NONE I-N4 NONE NONE I-N5 NONE NONE I-N6 NONE NONE I-N7 NONE NONE I-NMO NONE NONE I-P1 NONE NONE I-P10 NONE NONE I-P13 NONE NONE I-P14 NONE NONE I-P15 NONE NONE I-P17 NONE NONE I-P19 NONE NONE I-P2 NONE NONE I-P20 NONE NONE I-P21 NONE NONE I-P22 NONE NONE I-P23 NONE NONE I-P24 NONE NONE I-P25 NONE NONE I-P26 NONE NONE I-P27 NONE NONE I-P3 NONE NONE I-P30 NONE NONE I-P4 NONE NONE I-P5 NONE NONE I-P6 NONE NONE I-P7 NONE NONE I-P8 NONE NONE I-P9 NONE NONE I-PR-1 NONE NONE I-R1.21B NONE NONE I-R10.21B NONE NONE I-R2.21B NONE NONE I-R3 NONE NONE I-R4 NONE NONE I-R5.21B NONE NONE I-R6 NONE NONE I-R7 NONE NONE I-R8.21B NONE NONE I-RMCT1 NONE NONE I-RUR NONE NONE I-S1 NONE NONE I-S11 NONE NONE I-S12 NONE NONE I-S14 NONE NONE I-S15 NONE NONE I-S16 NONE NONE I-S17 NONE NONE 10 I-S18 NONE NONE I-S2 NONE NONE I-S20 NONE NONE I-S21 NONE NONE I-S22 NONE NONE I-S3 NONE NONE I-S4 NONE NONE I-S5 NONE NONE I-S6 NONE NONE I-S7 NONE NONE I-S8 NONE NONE I-S9 NONE NONE I-U1 NONE NONE I-U10 NONE NONE I-U2 NONE NONE I-U3 NONE NONE I-U4 NONE NONE I-U5 NONE NONE I-U6 NONE NONE I-U7 NONE NONE I-U8 NONE NONE I-U9 NONE NONE I-UMO NONE NONE I-WW2 NONE NONE ICT-1 NONE NONE ICT-2 NONE NONE ISD-1 NONE NONE ISD-2 NONE NONE PFTF 19 Phenol-Formaldehyde Resin Storage Tank VS2A-ES-2 1 Formaldehyde manufacturing 10 Fugitive Sources - LDAR, etc. 20 Natural Gas Usage for Catalytic Oxidizer VS2A-ES3M1 15 Methanol Raw Material Storage Tank VS4A.1-ES-13 NONE NONE VS4A.1-ES4.1 2 Resin manufacturing with eight kettles and seven weigh tanks 12 Fugitive Sources - LDAR, Loading Racks, Drying Pad 21 Natural Gas Usage for thermal oxidizer VS4A.1-ES4.1-5WT NONE NONE VS4A.1-ES4.2 NONE NONE VS4A.1-ES4.2WT NONE NONE VS4A.1-ES4.3 NONE NONE VS4A.1-ES4.5 NONE NONE VS4A.1-ES4.7 NONE NONE VS4A.1-ES4.8 NONE NONE VS4A.1-ES4.8WT NONE NONE VS4A.2-ES-13 NONE NONE VS4A.2-ES3M1 NONE NONE VS4A.2-ES4.1 NONE NONE VS4A.2-ES4.1-5WT NONE NONE VS4A.2-ES4.2 NONE NONE VS4A.2-ES4.2WT NONE NONE 11 VS4A.2-ES4.3 NONE NONE VS4A.2-ES4.5 NONE NONE VS4A.2-ES4.7 NONE NONE VS4A.2-ES4.8 NONE NONE VS4A.2-ES4.8WT NONE NONE VS4A.2-ES7F1 NONE NONE VS4A.2-ES7F2 NONE NONE VS4A.2-ES7F3 NONE NONE VS4A.2-ES7F4 NONE NONE VS4A.2-ES7F5 NONE NONE VS4A.2-ES7F6 NONE NONE VS4A.2-ES7F7 NONE NONE VS4A.2-ES7F8 NONE NONE VS5A 54 Spray Dry Resin Manufacturing 55 Natural gas usage in spray dry process 12 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR92 consisting of VS2A-ES7F1, VS2A-ES7F2, VS2A-ES7F3, VS2A-ES7F4, VS2A-ES7F5, VS2A-ES7F6, VS2A-ES7F7, VS2A- ES7F8 2. Emission Source Description :Formaldehyde Storage Tanks 3. Operating Scenario ID/ Description: OS - 13/Formaldehdyde Raw Material Storage Tanks 4. SCC Number/Description:40799999/Miscellaneous ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 14169818 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-1 CD-2A Natural gas/propane-fired catalytic oxidizer (4.5 cubic feet of catalyst, 4.0 million Btu per hour maximum heat input primary burner) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E401 VERTICAL STACK 36 1.5 700 33 3500 Formaldehyde process plant catalytic oxidizer 13 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 13 Emission Source/Group ID: GR92 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 0 NOx NOx 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 0 08 99.99 0 BEFORE HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 0 02 99.99 0 AFTER Methanol 67-56-1 0 02 99.99 0 AFTER 15 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR93 consisting of ESR1, ESR10, ESR2, ESR5 2. Emission Source Description :Phenol Storage Tanks 3. Operating Scenario ID/ Description: OS - 46/Phenol Raw Material Storage Tanks 4. SCC Number/Description:40708404/Fixed Roof Tanks - Phenols ; Phenol: Working Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 8312830 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Raw Ma FUGITIVE (NO STACK) 1 72 Area = 1 Raw Material fugitive tank emissiona 16 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 46 Emission Source/Group ID: GR93 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.5 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Phenol 108-95-2 1002.57 08 17 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR95 consisting of ESR8, UFTF 2. Emission Source Description :Urea-Formaldehyde Storage Tanks 3. Operating Scenario ID/ Description: OS - 29/Urea Formaldehyde Resin Storage Tanks 4. SCC Number/Description:40714698/Fixed Roof Tanks - Miscellaneous ; Specify In Comments: Working Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 1542292 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 18 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 29 Emission Source/Group ID: GR95 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.04 02 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 36.84 02 Methanol 67-56-1 32.66 02 19 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group G-105 consisting of ES-GEN1, ES-GEN2 2. Emission Source Description :Industrial engines 3. Operating Scenario ID/ Description: OS - 27/Industrial engines 4. SCC Number/Description:20100107/Distillate Oil (Diesel) ; Reciprocating: Exhaust 5. Throughput/units in 2021: (e.g. production or fuel use): 215 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E111-2 VERTICAL STACK 17 0.5 855 365.41 4305 Generator stack 20 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 27 Emission Source/Group ID: G-105 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.01 08 NOx NOx 0.05 08 TSP TSP 008 PM10 PM10 008 PM2.5 PM2.5 008 SO2 SO2 008 VOC VOC 008 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00075 08 Acrolein 107-02-8 0.00023 08 Benzene 71-43-2 0.023 08 Formaldehyde 50-00-0 0.00234 08 Naphthalene (Component of POMTV)91-20-3 0.00385 08 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00629 08 Toluene 108-88-3 0.00833 08 Xylene 1330-20-7 0.00572 08 21 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR163 consisting of I-P11, I-P12 2. Emission Source Description :Phenol-Formaldehyde Resin Storage Tanks 3. Operating Scenario ID/ Description: OS - 41/Phenol-Formaldehyde Resin Storage Tanks 4. SCC Number/Description:40799999/Miscellaneous ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 2381178 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 22 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 41 Emission Source/Group ID: GR163 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.01 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 1.5 08 Methanol 67-56-1 10.31 08 Phenol 108-95-2 0.6 08 23 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR166 consisting of ES-MU, I-D, I-DP, I-P28, I-R9, I-RU1, I- SD1, I-WW1, VS2A-ES-FL 2. Emission Source Description :Insignificant Sources 3. Operating Scenario ID/ Description: OS - 53/Paved Roads (PR-1) 4. SCC Number/Description:31499999/Other Not Classified ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 24 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 53 Emission Source/Group ID: GR166 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 8.26 08 PM10 PM10 1.65 08 PM2.5 PM2.5 0.41 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 25 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR181 consisting of ES-T1A, ES-T3 2. Emission Source Description :Cooling Towers 3. Operating Scenario ID/ Description: OS - 48/Cooling Tower (ES-T1A) 4. SCC Number/Description:39999995/Miscellaneous Industrial Processes ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 26 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 48 Emission Source/Group ID: GR181 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.15 08 PM10 PM10 0.14 08 PM2.5 PM2.5 0.12 08 SO2 SO2 08 VOC VOC 10.1 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 27 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR181 consisting of ES-T1A, ES-T3 2. Emission Source Description :Cooling Towers 3. Operating Scenario ID/ Description: OS - 49/Cooling Tower (ES-T3) 4. SCC Number/Description:39999995/Miscellaneous Industrial Processes ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 28 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 49 Emission Source/Group ID: GR181 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.21 08 PM10 PM10 0.2 08 PM2.5 PM2.5 0.16 08 SO2 SO2 08 VOC VOC 14.03 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 29 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR186 consisting of ES-11.1, ES-11.2 2. Emission Source Description :Resi-Mixer 3. Operating Scenario ID/ Description: OS - 50/RESI-MIXER® (ES4.6) 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description K-6 BH 6.1 VERTICAL STACK 2 1.4 77 41.57 3840 K-6 Baghouse Exhaust 30 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 50 Emission Source/Group ID: GR186 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 1.12 08 PM10 PM10 1.12 08 PM2.5 PM2.5 1.12 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 31 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR186 consisting of ES-11.1, ES-11.2 2. Emission Source Description :Resi-Mixer 3. Operating Scenario ID/ Description: OS - 51/RM3 Extender Storage Silo (ES-11.1) 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description RM-3 CD11.1 VERTICAL STACK 1.5 1.67 77 6.08 800 RM-3 Bin Vent 32 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 51 Emission Source/Group ID: GR186 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.23 08 PM10 PM10 0.23 08 PM2.5 PM2.5 0.23 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 33 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR186 consisting of ES-11.1, ES-11.2 2. Emission Source Description :Resi-Mixer 3. Operating Scenario ID/ Description: OS - 52/RM4 Extender Storage Silo (ES-11.2) 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description RM-4 CD-11.2 VERTICAL STACK 2.78 1.67 77 6.08 800 RM-4 Bin Vent 34 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 52 Emission Source/Group ID: GR186 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.23 08 PM10 PM10 0.23 08 PM2.5 PM2.5 0.23 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 35 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-B1 2. Emission Source Description :One natural gas/propane-fired boiler (25.1 million Btu per hour maximum heat input rate) [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 3/Natural gas/propane fired boiler (25.1 MMBtu/hr heat input) 4. SCC Number/Description:10200602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 18051 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E201 VERTICAL STACK 36 2.67 367 19.8 6651.64 boiler group stack 36 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 3 Emission Source/Group ID: ES-B1 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 1076.93 08 Methane (CH4) 74-82-8 0.02 08 Nitrous Oxide (N2O) 10024972 0.002 08 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.76 08 NOx NOx 0.9 08 TSP TSP 0.07 08 PM10 PM10 0.07 08 PM2.5 PM2.5 0.07 08 SO2 SO2 0.01 08 VOC VOC 0.05 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.0379 08 Formaldehyde 50-00-0 1.35 08 Hexane, n- 110-54-3 32.49 08 Toluene 108-88-3 0.0614 08 37 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-B2 2. Emission Source Description :One natural gas/propane/No. 2 fuel oil-fired temporary boiler (less than 25 million Btu per hour maximum heat input rate) [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 37/Temporary Boiler - Used only when on-site boiler is to be out of service for extended period. 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 3243 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E201 VERTICAL STACK 36 2.67 367 19.8 6651.64 boiler group stack 38 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 37 Emission Source/Group ID: ES-B2 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 193 08 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.14 08 NOx NOx 0.16 08 TSP TSP 0.01 08 PM10 PM10 0.01 08 PM2.5 PM2.5 0.01 08 SO2 SO2 008 VOC VOC 0.01 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.00681 08 Formaldehyde 50-00-0 0.24322 08 Hexane, n- 110-54-3 5.83737 08 Toluene 108-88-3 0.01103 08 39 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-PU 2. Emission Source Description :Phenol unloading operations [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 47/Fugitive emissions from phenol unloading 4. SCC Number/Description:31499999/Other Not Classified ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 78473113 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description EP-PU VERTICAL STACK 13.2 2 160 0.1 18.84 Phenol Unloading Process 40 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 47 Emission Source/Group ID: ES-PU Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.37 02 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Phenol 108-95-2 740.04 02 41 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-S19 2. Emission Source Description :Aqueous ammonia storage tank (9,924 gallon capacity) [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 40/Aqueous ammonia storage tank 4. SCC Number/Description:40714698/Fixed Roof Tanks - Miscellaneous ; Specify In Comments: Working Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 703953 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-6 CD-S19 One scrubber tank (56 inch minimum water level from tank bottom) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description S-19 Tank Vent VERTICAL STACK 15 1 77 1 47.12 Tank Vent 42 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 40 Emission Source/Group ID: ES-S19 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 0 NOx NOx 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 08 0 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Ammonia (as NH3) 7664-41-7 278.66 08 75 BEFORE 43 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-UH-K3 2. Emission Source Description :Urea unloading hopper for reactor #3 3. Operating Scenario ID/ Description: OS - 35/Urea Hopper for Reactor #3 4. SCC Number/Description:40799999/Miscellaneous ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 14273876 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description EP-K3A FUGITIVE (NO STACK) 1 72 Area = 1 Exhaust from Urea Hopper for Reactor #3 44 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 35 Emission Source/Group ID: ES-UH-K3 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.01 08 PM10 PM10 0.01 08 PM2.5 PM2.5 0.01 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 45 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-UH-K8 2. Emission Source Description :Urea unloading hopper for reactor #8 3. Operating Scenario ID/ Description: OS - 36/Urea Hopper for Reactor #8 4. SCC Number/Description:40799999/Miscellaneous ; Other Not Classified 5. Throughput/units in 2021: (e.g. production or fuel use): 19569046 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description EP-K8A FUGITIVE (NO STACK) 1 72 Area = 1 Exhaust from urea hopper for Reactor #8 46 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 36 Emission Source/Group ID: ES-UH-K8 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.01 08 PM10 PM10 0.01 08 PM2.5 PM2.5 0.01 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 47 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID I-A2 2. Emission Source Description :Acetone distillate tank (9,924 gallon capacity) 3. Operating Scenario ID/ Description: OS - 44/MEK Usage 4. SCC Number/Description:40706806/Fixed Roof Tanks - Ketones ; Methyl Ethyl Ketone: Working Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 19851 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description STK-A2 DOWNWARD- FACING VENT 1 0.25 70 0.1 0.29 I-A2 MEK Storage Tank Vent 48 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 44 Emission Source/Group ID: I-A2 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 008 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Methyl ethyl ketone 78-93-3 0.74 02 49 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID I-HTF 2. Emission Source Description :Natural gas/propane-fired heat transfer fluid heater (2.3 million Btu per hour maximum heat input rate) 3. Operating Scenario ID/ Description: OS - 33/DowTherm Heater 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 7 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description DowThe rm Heater VERTICAL STACK 35 1 350 31.83 1500 Dowtherm Heater Exhaust 50 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 33 Emission Source/Group ID: I-HTF Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 0.4 08 Nitrous Oxide (N2O) 10024972 008 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 008 NOx NOx 008 TSP TSP 008 PM10 PM10 008 PM2.5 PM2.5 008 SO2 SO2 008 VOC VOC 008 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.00001 08 Formaldehyde 50-00-0 0.0005 08 Hexane, n- 110-54-3 0.01 08 Toluene 108-88-3 0.00002 08 51 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID PFTF 2. Emission Source Description :Phenol-formaldehyde resin tank farm [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 19/Phenol-Formaldehyde Resin Storage Tank 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 40818321 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 52 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 19 Emission Source/Group ID: PFTF Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.43 04 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 15.01 04 Methanol 67-56-1 837.21 04 Phenol 108-95-2 3.76 04 53 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS2A-ES-2 2. Emission Source Description :One formaldehyde production process including vaporizers, catalytic converters, cooling systems, an after cooler and an absorber [MACT F, MACT G, MACT H] 3. Operating Scenario ID/ Description: OS - 1/Formaldehyde manufacturing 4. SCC Number/Description:30112002/Formaldahyde, Acrolein, Acetaldehyde, Butyraldehyde MFG ; Formaldehyde: Mixed Oxide Catalyst 5. Throughput/units in 2021: (e.g. production or fuel use): 13150360 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-1 CD-2A Natural gas/propane-fired catalytic oxidizer (4.5 cubic feet of catalyst, 4.0 million Btu per hour maximum heat input primary burner) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E401 VERTICAL STACK 36 1.5 700 33 3500 Formaldehyde process plant catalytic oxidizer 54 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 1 Emission Source/Group ID: VS2A-ES- 2 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 4.57 08 98.6 AFTER NOx NOx 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 10.44 08 98.6 AFTER HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 20.13 04 98.6 AFTER Formaldehyde 50-00-0 3037.89 04 98.6 AFTER Methanol 67-56-1 2558.32 04 98.6 AFTER 56 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS2A-ES-2 2. Emission Source Description :One formaldehyde production process including vaporizers, catalytic converters, cooling systems, an after cooler and an absorber [MACT F, MACT G, MACT H] 3. Operating Scenario ID/ Description: OS - 10/Fugitive Sources - LDAR, etc. 4. SCC Number/Description:30112002/Formaldahyde, Acrolein, Acetaldehyde, Butyraldehyde MFG ; Formaldehyde: Mixed Oxide Catalyst 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 57 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 10 Emission Source/Group ID: VS2A-ES- 2 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 150 02 Methanol 67-56-1 716 02 58 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS2A-ES-2 2. Emission Source Description :One formaldehyde production process including vaporizers, catalytic converters, cooling systems, an after cooler and an absorber [MACT F, MACT G, MACT H] 3. Operating Scenario ID/ Description: OS - 20/Natural Gas Usage for Catalytic Oxidizer 4. SCC Number/Description:30112002/Formaldahyde, Acrolein, Acetaldehyde, Butyraldehyde MFG ; Formaldehyde: Mixed Oxide Catalyst 5. Throughput/units in 2021: (e.g. production or fuel use): 25995 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E401 VERTICAL STACK 36 1.5 700 33 3500 Formaldehyde process plant catalytic oxidizer 59 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 20 Emission Source/Group ID: VS2A-ES- 2 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 2290.78 08 Methane (CH4) 74-82-8 0.03 08 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 1.3 08 TSP TSP 0.1 08 PM10 PM10 0.1 08 PM2.5 PM2.5 0.1 08 SO2 SO2 0.01 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.05 08 Hexane, n- 110-54-3 46.79 08 Toluene 108-88-3 0.09 08 60 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS2A-ES3M1 2. Emission Source Description :One methanol storage tank (507,852 gallon capacity) when this source is operating under its primary compliance scenario [MACT F, MACT G, MACT H] 3. Operating Scenario ID/ Description: OS - 15/Methanol Raw Material Storage Tank 4. SCC Number/Description:40700816/Fixed Roof Tanks - Alcohols ; Methyl Alcohol: Working Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 11587854 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-1 CD-2A Natural gas/propane-fired catalytic oxidizer (4.5 cubic feet of catalyst, 4.0 million Btu per hour maximum heat input primary burner) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E401 VERTICAL STACK 36 1.5 700 33 3500 Formaldehyde process plant catalytic oxidizer 61 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 15 Emission Source/Group ID: VS2A- ES3M1 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 0 NOx NOx 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 0 08 99.99 0 BEFORE HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Methanol 67-56-1 0 08 99.99 0 BEFORE 63 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS4A.1-ES4.1 2. Emission Source Description :Batch reactor vessel [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 2/Resin manufacturing with eight kettles and seven weigh tanks 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 324298106 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-2 CD-4A Natural gas/propane-fired thermal oxidizer (2.9 million Btu per hour maximum heat input) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E501-8 VERTICAL STACK 20 0.5 91 8.82 104 Thermal Oxidizer 64 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 2 Emission Source/Group ID: VS4A.1- ES4.1 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 4.18 08 0 NOx NOx 0.92 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 0.13 08 98 AFTER HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Formaldehyde 50-00-0 22.29 04 96 AFTER Methanol 67-56-1 228.49 04 99 AFTER Phenol 108-95-2 1.02 04 97.5 AFTER 65 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS4A.1-ES4.1 2. Emission Source Description :Batch reactor vessel [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 12/Fugitive Sources - LDAR, Loading Racks, Drying Pad 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 1 EACH/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description Fugitive FUGITIVE (NO STACK) 1 77 Area = 1 Fugitive Releases 66 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 12 Emission Source/Group ID: VS4A.1- ES4.1 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 2.75 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Ammonia (as NH3) 7664-41-7 36.77 08 Cresol (mixed isomers) 1319-77-3 108.1 02 Formaldehyde 50-00-0 534.1 02 Methanol 67-56-1 3790.3 02 Methyl ethyl ketone 78-93-3 194.59 08 Phenol 108-95-2 881.2 02 67 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS4A.1-ES4.1 2. Emission Source Description :Batch reactor vessel [MACT OOO, MACT UU] 3. Operating Scenario ID/ Description: OS - 21/Natural Gas Usage for thermal oxidizer 4. SCC Number/Description:30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in Comments Field 5. Throughput/units in 2021: (e.g. production or fuel use): 24472 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description E501-8 VERTICAL STACK 20 0.5 91 8.82 104 Thermal Oxidizer 68 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 21 Emission Source/Group ID: VS4A.1- ES4.1 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 1503.43 08 Methane (CH4) 74-82-8 008 Nitrous Oxide (N2O) 10024972 0.0028 08 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 0.09 08 PM10 PM10 0.09 08 PM2.5 PM2.5 0.09 08 SO2 SO2 0.01 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.05 08 Hexane, n- 110-54-3 44.05 08 Toluene 108-88-3 0.08 08 69 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS5A 2. Emission Source Description :Continuous process vent stream comprised of emissions from the spray dry resin production process including a natural gas/propane-fired atomizing air heater (14.6 million Btu per hour maximum heat inp 3. Operating Scenario ID/ Description: OS - 54/Spray Dry Resin Manufacturing 4. SCC Number/Description:30190003/*Fuel Fired Process Equipment ; Natural Gas: Process Heaters 5. Throughput/units in 2021: (e.g. production or fuel use): 34649858 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-3 CD-5A Bagfilter (14,500 square feet of filter area) ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description e131 VERTICAL STACK 110 6 160 29.47 50000 Spray Dry Operations 70 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 54 Emission Source/Group ID: VS5A Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 11.41 08 0 NOx NOx 4.65 08 0 TSP TSP 08 99 PM10 PM10 08 99 PM2.5 PM2.5 08 99 SO2 SO2 08 0 VOC VOC 56.98 08 0 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 226 08 0 Ammonia (as NH3) 7664-41-7 320 04 0 Cresol (mixed isomers) 1319-77-3 858 08 0 Formaldehyde 50-00-0 8488 04 0 Methanol 67-56-1 98830 04 0 Phenol 108-95-2 542 04 0 Styrene 100-42-5 497 04 0 Triethylamine 121-44-8 542 08 0 71 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID VS5A 2. Emission Source Description :Continuous process vent stream comprised of emissions from the spray dry resin production process including a natural gas/propane-fired atomizing air heater (14.6 million Btu per hour maximum heat inp 3. Operating Scenario ID/ Description: OS - 55/Natural gas usage in spray dry process 4. SCC Number/Description:30190003/*Fuel Fired Process Equipment ; Natural Gas: Process Heaters 5. Throughput/units in 2021: (e.g. production or fuel use): 120046 E3FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description e131 VERTICAL STACK 110 6 160 29.47 50000 Spray Dry Operations 72 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 55 Emission Source/Group ID: VS5A Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Carbon Dioxide (CO2) 124389 7161.89 08 Methane (CH4) 74-82-8 0.13 08 Nitrous Oxide (N2O) 10024972 0.01 08 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 22.81 08 PM10 PM10 22.81 08 PM2.5 PM2.5 22.81 08 SO2 SO2 0.04 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Benzene 71-43-2 0.25 08 Hexane, n- 110-54-3 216.08 08 Toluene 108-88-3 0.41 08 73 Record Facility-Wide Totals From all Permitted and Non-Permitted AirPollutant Emission Sources Facility Total CY 2021 Emissions Summary COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 Green House Gases Pollutants(GHG) Actual Emissions (Tons/Year) Pollutant CAS 2021 2020 % Change Carbon Dioxide (CO2) 124389 12226.43 10839.12 12.799097% Methane (CH4) 74-82-8 0.18 .18 0.0% Nitrous Oxide (N2O) 10024972 0.0148 .01 48.000004% Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS 2021 2020 % Change CO CO 21.07 30.04 -29.86019% NOx NOx 7.98 7.98 0.0% PM(TSP) TSP 33.3 32.9 1.2157985% PM10 PM10 26.67 26.23 1.6774706% PM2.5 PM2.5 25.37 24.95 1.683367% SO2 SO2 0.07 .05 40.0% VOC VOC 95.84 85.06 12.673406% Hazardous Air Pollutants(HAPS) and/or Toxic Air Pollutants(TAPs) Actual Emissions (Pounds/Year) Pollutant CAS 2021 2020 % Change Pollutant Group:Polycyclic Organic Matter (Specific Compounds from OAQPS for TV) Group Sum:.00385 Naphthalene (Component of POMTV)91-20-3 0.00385 .00494 -22.064775% Acetaldehyde 75-07-0 246.13075 238.70096 3.112595% Acrolein 107-02-8 2.3E-4 .0003 -23.333336% Ammonia (as NH3) 7664-41-7 635.43 616.66 3.04382% Benzene 71-43-2 0.41772 .39653 5.343855% Cresol (mixed isomers) 1319-77-3 966.1 935.9 3.2268353% Formaldehyde 50-00-0 12287.226 11776.35493 4.338109% Hexane, n- 110-54-3 345.2574 304.88635 13.241338% Methanol 67-56-1 107003.29 101746.08 5.1669917% Methyl ethyl ketone 78-93-3 195.33 196.11 -0.39773533% 74 Phenol 108-95-2 3171.19 3106.81 2.0722182% Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00629 .00806 -21.960299% Styrene 100-42-5 497.0 484 2.6859505% Toluene 108-88-3 0.66078 .58681 12.605447% Triethylamine 121-44-8 542.0 Not reported N/A Xylene 1330-20-7 0.00572 .00734 -22.070848% 75 COPY of RECORD Date Submitted: 5/20/2022 08:34:49 As entered in AERO Facility Name: Georgia-Pacific Chemicals LLC - Conway 200 Ampac Road Conway, NC 27820 Facility ID : 6600016 Permit : 04243 County : Northampton DAQ Region : RRO Comments From Facility: 76 Tanks Emissions Estimates Calendar Year: 2021RY Yellow = User Must Check Each Year Template Owner: Divisional Environmental Manager Plant Location: Conway, NC AP-42, 7-1 Organic Liquid Storage Tanks 59.2833 F = daily average ambient temperature (Taa) Blue = User Linked to Other Tab (Typically Production)Version: 1.02 21.7167 F = daily ambient temperature range (dTa) (F or R) Green = User Must Review and Confirm Accuracy 1,393.0797 = Solar Index Gray = Locked Calculation or Constant Columns AX through AZ are hidden and contain intermediate calculations & values ==> 14.53 psi = ambient pressure (psi) Others = If input, may be entered, but should typically be constant. Tank or Tank Group Product or Description Paint Factor (see table below) Tank Dia (Ft) Tank Ht. (Ft)Max. Liq. Ht (Ft)Avg. Liq. Ht (Ft)Cone or Dome Dome Height (ft) Tank Shell Capacity (Gal) Tank Working Volume (Gal) Liquid Temp (F or Amb) Product Density (lb/gal) TOTAL Throughput (Gal)# Tanks Throughput (Gal / Tank) Controlled Temp? (% Eff.) Vapor Collection? (% Eff.) Vapor Return? (% Eff.) Conservation Vent dP (psi) (pres - vac) Chemical Percent of Free Chemical MW Partial vp at Storage Condition (psi) Controlled Working Loss (lb per tank) Controlled Breathing Loss (lb per tank) Controlled TOTAL Losses (all tanks) A B C Calc. partial vapor pressure (based on Tla) N Turnovers per tank Kn Calculated Working Losses (lbs) Calculated Standing Losses (lbs) Hvo Hro Vv Wv Tb dTv Tla ( R )Tlx Tln Pvx Pvn dPv F1-F8 HCHO Soln. - HCHO 0.17 12 31 15.5 Cone 1.0 26,225 26,225 145 9.12 14,169,818 8 1,771,227 100% 100% HCHO 50.00%30 0.35519 <=HCHO Eq.0.00 0.00 0.00 na na na 0.35519 67.5 0.611 274.50 38.08 15.833 0.333 1,790.71 0.0016422 518.9733 22.2671 604.67 610.23677 599.10323 0.42600 0.29514 0.13086 F1-F8 HCHO Soln. - MeOH 0.17 12 31 15.5 Cone 1.0 26,225 26,225 145 9.12 14,169,818 8 1,771,227 100% 100% MeOH 0.40%32.04 0.05440 <=Calc Antoine 0.00 0.00 0.00 7.897 1474.1 229.13 0.05440 67.5 0.611 44.90 6.34 15.833 0.333 1,790.71 0.0002686 518.9733 22.2671 604.67 610.23677 599.10323 0.06146 0.04803 0.01342 R-8 UFC Soln. - HCHO 0.17 12 30 15.0 Cone 1.0 25,379 25,379 100 11.04 685,141 1 685,141 100% HCHO 30.00%30 0.05890 <=HCHO Eq.28.83 0.00 28.83 na na na 0.05890 27.0 1.000 28.83 7.38 15.333 0.333 1,734.16 0.0002942 518.9733 22.2671 559.67 565.23677 554.10323 0.07282 0.04744 0.02537 R-8 UFC Soln. - MeOH 0.17 12 30 15.0 Cone 1.0 25,379 25,379 100 11.04 685,141 1 685,141 100% MeOH 0.40%32.04 0.01831 <=Calc Antoine 9.57 0.00 9.57 7.897 1474.1 229.13 0.01831 27.0 1.000 9.57 2.45 15.333 0.333 1,734.16 9.767E-05 518.9733 22.2671 559.67 565.23677 554.10323 0.02118 0.01577 0.00541 M-1 Methanol 0.17 46.5 40 20.0 Cone 1.0 508,104 508,104 Amb 6.63 11,587,854 1 11,587,854 100% .06 psi MeOH 100.00%32.04 1.49589 <=Calc Antoine 0.00 0.00 0.00 7.897 1474.1 229.13 1.49589 22.8 1.000 13,223.73 3,239.96 20.333 0.333 34,530.70 0.0085753 518.9733 22.2671 520.835 526.40218 515.26864 1.77705 1.25369 0.52336 R-1, R-2 R-5, R-10 Phenol 0.17 10.5 34.8 17.4 Cone 1.0 22,540 22,540 145 9.44 8,312,830 4 2,078,207 100% Phenol 100.00%94.1 0.10940 <=Calc Antoine 250.64 0.00 1,002.57 7.133 1516.8 174.95 0.10940 92.2 0.492 250.64 32.04 17.733 0.333 1,535.54 0.0015865 518.9733 22.2671 604.67 610.23677 599.10323 0.13212 0.09014 0.04198 S-19 Aqua Ammonia (adjusted to 28%)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 50 7.48 703,953 1 703,953 100% 75% Ammonia 30.00%17.03 6.63000 <=Enter vp 278.66 0.00 278.66 N/A N/A N/A 0.00000 71.0 0.589 1,114.63 704.38 7.983 0.333 691.28 0.0206442 518.9733 22.2671 509.67 515.23677 504.10323 Hand CalcHand Calc=>3.72000 <=Hand Enter! C-1 Sulfuric Acid 0.17 8 12.33 6.2 Cone 1.0 4,636 4,636 85 10.40 0 1 0 100% .06 psi NON VOC 0.00000 <=Enter vp 0.00 0.00 0.00 N/A N/A N/A 0.00000 0.0 1.000 0.00 0.00 6.498 0.333 326.64 0 518.9733 22.2671 544.67 550.23677 539.10323 Hand CalcHand Calc=>0.10000 C-2 CCKC- 902G03 (NON VOC)0.17 8 12.33 6.2 Cone 1.0 4,636 4,636 85 10.40 0 1 0 100% .06 psi NON VOC 0.00000 <=Enter vp 0.00 0.00 0.00 N/A N/A N/A 0.00000 0.0 1.000 0.00 0.00 6.498 0.333 326.64 0 518.9733 22.2671 544.67 550.23677 539.10323 Hand CalcHand Calc=>0.10000 C-3 CCKC- 902G03 (NON VOC)0.17 8 12.33 6.2 Cone 1.0 4,636 4,636 85 10.40 0 1 0 100% .06 psi NON VOC 0.00000 <=Enter vp 0.00 0.00 0.00 N/A N/A N/A 0.00000 0.0 1.000 0.00 0.00 6.498 0.333 326.64 0 518.9733 22.2671 544.67 550.23677 539.10323 Hand CalcHand Calc=>0.10000 CT-1, 2, SD-1,2 (Spray Dry Base)PF Resin - HCHO 0.17 12 32.7 16.4 Cone 1.0 27,663 27,663 55 10.40 6,422,204 4 1,605,551 100% HCHO 0.50%30 0.00075 <=HCHO Eq.0.59 0.00 2.35 na na na 0.00075 58.0 0.684 0.59 0.12 16.683 0.333 1,886.84 4.074E-06 518.9733 22.2671 514.67 520.23677 509.10323 0.00096 0.00058 0.00038 CT-1, 2, SD-1,2 (Spray Dry Base)PF Resin - Phenol 0.17 12 32.7 16.4 Cone 1.0 27,663 27,663 55 10.40 6,422,204 4 1,605,551 100% Phenol 1.00%94.1 0.00002 <=Calc Antoine 0.05 0.00 0.22 7.133 1516.8 174.95 0.00002 58.0 0.684 0.05 0.01 16.683 0.333 1,886.84 3.725E-07 518.9733 22.2671 514.67 520.23677 509.10323 0.00003 0.00002 0.00001 CT-1, 2, SD-1,2 (Spray Dry Base)PF Resin - MeOH 0.17 12 32.7 16.4 Cone 1.0 27,663 27,663 55 10.40 6,422,204 4 1,605,551 100% MeOH 0.10%32.04 0.00123 <=Calc Antoine 1.03 0.00 4.12 7.897 1474.1 229.13 0.00123 58.0 0.684 1.03 0.21 16.683 0.333 1,886.84 7.134E-06 518.9733 22.2671 514.67 520.23677 509.10323 0.00147 0.00103 0.00044 N1-N7 (Resi-Mix Base)PF Resin - HCHO 0.17 10.5 34.83 17.4 Cone 1.0 22,559 22,559 80 10.40 8,764,556 7 1,252,079 100% HCHO 0.20%30 0.00089 <=HCHO Eq.0.56 0.00 3.93 na na na 0.00089 55.5 0.707 0.56 0.11 17.748 0.333 1,536.83 4.599E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00112 0.00070 0.00041 N1-N7 (Resi-Mix Base)PF Resin - Phenol 0.17 10.5 34.83 17.4 Cone 1.0 22,559 22,559 80 10.40 8,764,556 7 1,252,079 100% Phenol 0.20%94.1 0.00002 <=Calc Antoine 0.03 0.00 0.22 7.133 1516.8 174.95 0.00002 55.5 0.707 0.03 0.01 17.748 0.333 1,536.83 2.559E-07 518.9733 22.2671 539.67 545.23677 534.10323 0.00002 0.00001 0.00001 N1-N7 (Resi-Mix Base)PF Resin - MeOH 0.17 10.5 34.83 17.4 Cone 1.0 22,559 22,559 80 10.40 8,764,556 7 1,252,079 100% MeOH 0.50%32.04 0.01317 <=Calc Antoine 8.90 0.00 62.28 7.897 1474.1 229.13 0.01317 55.5 0.707 8.90 1.68 17.748 0.333 1,536.83 7.287E-05 518.9733 22.2671 539.67 545.23677 534.10323 0.01543 0.01120 0.00424 Resi-Mixer (K-6)PF Resin - HCHO 0.17 9 11 5.5 Cone 1.0 5,234 5,234 80 10.40 10,955,695 1 10,955,695 HCHO 0.30%30 0.00133 <=HCHO Eq.1.89 0.04 1.92 na na na 0.00133 2,093.0 0.181 1.89 0.04 5.833 0.333 371.10 6.898E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00167 0.00106 0.00062 Resi-Mixer (K-6)PF Resin - Phenol 0.17 9 11 5.5 Cone 1.0 5,234 5,234 80 10.40 10,955,695 1 10,955,695 Phenol 0.00%94.1 0.00000 <=Calc Antoine 0.00 0.00 0.00 7.133 1516.8 174.95 0.00000 2,093.0 0.181 0.00 0.00 5.833 0.333 371.10 0 518.9733 22.2671 539.67 545.23677 534.10323 0.00000 0.00000 0.00000 Resi-Mixer (K-6)PF Resin - MeOH 0.17 9 11 5.5 Cone 1.0 5,234 5,234 80 10.40 10,955,695 1 10,955,695 MeOH 0.00%32.04 0.00000 <=Calc Antoine 0.00 0.00 0.00 7.897 1474.1 229.13 0.00000 2,093.0 0.181 0.00 0.00 5.833 0.333 371.10 0 518.9733 22.2671 539.67 545.23677 534.10323 0.00000 0.00000 0.00000 P1-P6, P8-P10 (Resimix)PF Resin - HCHO 0.17 10.5 32.0 16.0 Cone 1.0 20,726 20,726 80 10.40 11,130,426 9 1,236,714 100% HCHO 0.20%30 0.00089 <=HCHO Eq.0.52 0.00 4.72 na na na 0.00089 59.7 0.669 0.52 0.10 16.333 0.333 1,414.31 4.599E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00112 0.00070 0.00041 P1-P6, P8-P10 (Resimix)PF Resin - Phenol 0.17 10.5 32.0 16.0 Cone 1.0 20,726 20,726 80 10.40 11,130,426 9 1,236,714 100% Phenol 0.20%94.1 0.00002 <=Calc Antoine 0.03 0.00 0.26 7.133 1516.8 174.95 0.00002 59.7 0.669 0.03 0.01 16.333 0.333 1,414.31 2.559E-07 518.9733 22.2671 539.67 545.23677 534.10323 0.00002 0.00001 0.00001 P1-P6, P8-P10 (Resimix)PF Resin - MeOH 0.17 10.5 32.0 16.0 Cone 1.0 20,726 20,726 80 10.40 11,130,426 9 1,236,714 100% MeOH 0.50%32.04 0.01317 <=Calc Antoine 8.32 0.00 74.87 7.897 1474.1 229.13 0.01317 59.7 0.669 8.32 1.55 16.333 0.333 1,414.31 7.287E-05 518.9733 22.2671 539.67 545.23677 534.10323 0.01543 0.01120 0.00424 P11-P12 (WW Tanks) PF Resin - HCHO 0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 80 10.40 529,151 2 264,575 HCHO 0.20%30 0.00089 <=HCHO Eq.0.17 0.11 0.55 na na na 0.00089 11.7 1.000 0.17 0.11 17.833 0.333 1,544.19 4.599E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00112 0.00070 0.00041 P11-P12 (WW Tanks) PF Resin - Phenol 0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 80 10.40 529,151 2 264,575 Phenol 1.50%94.1 0.00012 <=Calc Antoine 0.07 0.04 0.23 7.133 1516.8 174.95 0.00012 11.7 1.000 0.07 0.04 17.833 0.333 1,544.19 1.919E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00015 0.00009 0.00006 P11-P12 (WW Tanks) PF Resin - MeOH 0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 80 10.40 529,151 2 264,575 MeOH 0.20%32.04 0.00527 <=Calc Antoine 1.06 0.68 3.48 7.897 1474.1 229.13 0.00527 11.7 1.000 1.06 0.68 17.833 0.333 1,544.19 2.915E-05 518.9733 22.2671 539.67 545.23677 534.10323 0.00617 0.00448 0.00169 P13-P17, P19-23, P25- 27 (RPPB;RPPD)PF Resin - HCHO 0.17 10.5 34.6 17.3 Cone 1.0 22,410 22,410 80 10.40 0 13 0 100% HCHO 0.20%30 0.00089 <=HCHO Eq.0.00 0.00 0.00 na na na 0.00089 0.0 1.000 0.00 0.11 17.633 0.333 1,526.88 4.599E-06 518.9733 22.2671 539.67 545.23677 534.10323 0.00112 0.00070 0.00041 P13-P17, P19-23, P25- 27 (RPPB;RPPD)PF Resin - Phenol 0.17 10.5 34.6 17.3 Cone 1.0 22,410 22,410 80 10.40 0 13 0 100% Phenol 0.20%94.1 0.00002 <=Calc Antoine 0.00 0.00 0.00 7.133 1516.8 174.95 0.00002 0.0 1.000 0.00 0.01 17.633 0.333 1,526.88 2.559E-07 518.9733 22.2671 539.67 545.23677 534.10323 0.00002 0.00001 0.00001 P13-P17, P19-23, P25- 27 (RPPB;RPPD)PF Resin - MeOH 0.17 10.5 34.6 17.3 Cone 1.0 22,410 22,410 80 10.40 0 13 0 100% MeOH 0.50%32.04 0.01317 <=Calc Antoine 0.00 0.00 0.00 7.897 1474.1 229.13 0.01317 0.0 1.000 0.00 1.67 17.633 0.333 1,526.88 7.287E-05 518.9733 22.2671 539.67 545.23677 534.10323 0.01543 0.01120 0.00424 S-1, S-8 (RPPI)PF Resin - HCHO 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 0 2 0 100% HCHO 9.40%30 0.00734 <=HCHO Eq.0.00 0.00 0.00 na na na 0.00734 0.0 1.000 0.00 0.41 7.983 0.333 691.28 3.874E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00930 0.00576 0.00354 S-1, S-8 (RPPI)PF Resin - Phenol 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 0 2 0 100% Phenol 0.60%94.1 0.00003 <=Calc Antoine 0.00 0.00 0.00 7.133 1516.8 174.95 0.00003 0.0 1.000 0.00 0.01 7.983 0.333 691.28 4.788E-07 518.9733 22.2671 529.67 535.23677 524.10323 0.00004 0.00002 0.00002 S-1, S-8 (RPPI)PF Resin - MeOH 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 0 2 0 100% MeOH 0.10%32.04 0.00196 <=Calc Antoine 0.00 0.00 0.00 7.897 1474.1 229.13 0.00196 0.0 1.000 0.00 0.12 7.983 0.333 691.28 1.106E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00232 0.00166 0.00066 S-3 (RPAB)PF Resin - HCHO 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 1 87,792 100% HCHO 3.00%30 0.00383 <=HCHO Eq.0.24 0.00 0.24 na na na 0.00383 8.9 1.000 0.24 0.21 7.983 0.333 691.28 2.019E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00485 0.00300 0.00184 S-3 (RPAB)PF Resin - Phenol 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 1 87,792 100% Phenol 14.90%94.1 0.00072 <=Calc Antoine 0.14 0.00 0.14 7.133 1516.8 174.95 0.00072 8.9 1.000 0.14 0.13 7.983 0.333 691.28 1.189E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00095 0.00054 0.00041 S-3 (RPAB)PF Resin - MeOH 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 1 87,792 100% MeOH 0.10%32.04 0.00196 <=Calc Antoine 0.13 0.00 0.13 7.897 1474.1 229.13 0.00196 8.9 1.000 0.13 0.12 7.983 0.333 691.28 1.106E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00232 0.00166 0.00066 S-2-4-5-9 (Alcohol Soluble)PF Resin - HCHO 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 9.40 34,362 4 8,590 100% .06 psi HCHO 1.00%30 0.00291 <=HCHO Eq.0.02 0.00 0.07 na na na 0.00291 0.9 1.000 0.02 0.15 7.983 0.333 691.28 1.537E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00369 0.00229 0.00140 S-2-4-5-9 (Alcohol Soluble)PF Resin - Phenol 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 9.40 34,362 4 8,590 100% .06 psi Phenol 11.00%94.1 0.00053 <=Calc Antoine 0.01 0.00 0.04 7.133 1516.8 174.95 0.00053 0.9 1.000 0.01 0.08 7.983 0.333 691.28 8.778E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00070 0.00040 0.00030 S-2-4-5-9 (Alcohol Soluble)PF Resin - MeOH 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 9.40 34,362 4 8,590 100% .06 psi MeOH 25.00%32.04 0.49055 <=Calc Antoine 3.21 0.00 12.86 7.897 1474.1 229.13 0.49055 0.9 1.000 3.21 28.61 7.983 0.333 691.28 0.0027652 518.9733 22.2671 529.67 535.23677 524.10323 0.57889 0.41398 0.16492 U1-U3 (Alcohol Soluble)PF Resin - HCHO 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 2,806,343 3 935,448 100% .06 psi HCHO 0.20%30 0.00058 <=HCHO Eq.0.34 0.00 1.03 na na na 0.00058 41.7 0.886 0.34 0.07 17.333 0.333 1,529.62 3.074E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00074 0.00046 0.00028 U1-U3 (Alcohol Soluble)PF Resin - Phenol 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 2,806,343 3 935,448 100% .06 psi Phenol 9.50%94.1 0.00046 <=Calc Antoine 0.85 0.00 2.55 7.133 1516.8 174.95 0.00046 41.7 0.886 0.85 0.16 17.333 0.333 1,529.62 7.581E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00060 0.00034 0.00026 U1-U3 (Alcohol Soluble)PF Resin - MeOH 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 2,806,343 3 935,448 100% .06 psi MeOH 18.00%32.04 0.35320 <=Calc Antoine 223.42 0.00 670.27 7.897 1474.1 229.13 0.35320 41.7 0.886 223.42 38.76 17.333 0.333 1,529.62 0.001991 518.9733 22.2671 529.67 535.23677 524.10323 0.41680 0.29806 0.11874 S-12 & S-22 PF Resin - HCHO 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 2 43,896 100% .06 psi HCHO 1.00%30 0.00291 <=HCHO Eq.0.09 0.00 0.18 na na na 0.00291 4.4 1.000 0.09 0.15 7.983 0.333 691.28 1.537E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00369 0.00229 0.00140 S-12 & S-22 PF Resin - Phenol 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 2 43,896 100% .06 psi Phenol 11.00%94.1 0.00053 <=Calc Antoine 0.05 0.00 0.10 7.133 1516.8 174.95 0.00053 4.4 1.000 0.05 0.08 7.983 0.333 691.28 8.778E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00070 0.00040 0.00030 S-12 & S-22 PF Resin - MeOH 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 70 10.40 87,792 2 43,896 100% .06 psi MeOH 7.00%32.04 0.13736 <=Calc Antoine 4.60 0.00 9.20 7.897 1474.1 229.13 0.13736 4.4 1.000 4.60 7.58 7.983 0.333 691.28 0.0007743 518.9733 22.2671 529.67 535.23677 524.10323 0.16209 0.11591 0.04618 S14-S17 & S21 Process Washwater - HCHO 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 75 10.40 1,852,027 5 370,405 HCHO 0.20%30 0.00072 <=HCHO Eq.0.18 0.04 1.12 na na na 0.00072 37.4 0.969 0.18 0.04 7.983 0.333 691.28 3.767E-06 518.9733 22.2671 534.67 540.23677 529.10323 0.00091 0.00057 0.00034 S14-S17 & S21 Process Washwater - Phenol 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 75 10.40 1,852,027 5 370,405 Phenol 1.50%94.1 0.00009 <=Calc Antoine 0.07 0.02 0.45 7.133 1516.8 174.95 0.00009 37.4 0.969 0.07 0.02 7.983 0.333 691.28 1.521E-06 518.9733 22.2671 534.67 540.23677 529.10323 0.00012 0.00007 0.00005 S14-S17 & S21 Process Washwater - MeOH 0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 75 10.40 1,852,027 5 370,405 MeOH 0.20%32.04 0.00455 <=Calc Antoine 1.25 0.27 7.57 7.897 1474.1 229.13 0.00455 37.4 0.969 1.25 0.27 7.983 0.333 691.28 2.543E-05 518.9733 22.2671 534.67 540.23677 529.10323 0.00536 0.00386 0.00150 S20 (K-5 Distillate Accumulation Tank)Distillate (< 0.5% HCHO)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% HCHO 0.50%30 0.00047 <=HCHO Eq.0.01 0.00 0.01 na na na 0.00047 3.6 1.000 0.01 0.03 7.983 0.333 691.28 2.612E-06 518.9733 22.2671 504.67 510.23677 499.10323 0.00061 0.00036 0.00025 S20 (K-5 Distillate Accumulation Tank)Distillate (< 0.1% MeOH)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% MeOH 0.10%32.04 0.00088 <=Calc Antoine 0.02 0.00 0.02 7.897 1474.1 229.13 0.00088 3.6 1.000 0.02 0.06 7.983 0.333 691.28 5.232E-06 518.9733 22.2671 504.67 510.23677 499.10323 0.00106 0.00073 0.00033 S20 (K-5 Distillate Accumulation Tank)Distillate (< 15% Phenol)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% Phenol 15.00%94.1 0.00019 <=Calc Antoine 0.01 0.00 0.01 7.133 1516.8 174.95 0.00019 3.6 1.000 0.01 0.04 7.983 0.333 691.28 3.231E-06 518.9733 22.2671 504.67 510.23677 499.10323 0.00026 0.00013 0.00012 S20 (K-5 Distillate Accumulation Tank)Distillate (< 5% Cresols)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% Cresols (Mixed) 5.00%108.1 0.00300 <=Enter vp 0.28 0.00 0.28 N/A N/A N/A 0.00000 3.6 1.000 0.28 0.77 7.983 0.333 691.28 5.988E-05 518.9733 22.2671 504.67 510.23677 499.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! S20 (K-5 Distillate Accumulation Tank)Distillate (< 0.2% MEK)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% MEK 0.20%72.12 0.00139 <=Enter vp 0.09 0.00 0.09 N/A N/A N/A 0.00000 3.6 1.000 0.09 0.24 7.983 0.333 691.28 1.85E-05 518.9733 22.2671 504.67 510.23677 499.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! S20 (K-5 Distillate Accumulation Tank)Distillate (< 0.1% N-Butanol)0.17 10.5 15.3 7.7 Cone 1.0 9,910 9,910 45 8.50 35,746 1 35,746 100% N-Butanol 0.01%74.122 0.00011 <=Enter vp 0.01 0.00 0.01 N/A N/A N/A 0.00000 3.6 1.000 0.01 0.02 7.983 0.333 691.28 1.506E-06 518.9733 22.2671 504.67 510.23677 499.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! K-5 Distillate Tank Distillate (< 0.5% HCHO)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 HCHO 0.50%30 0.00262 <=HCHO Eq.0.07 0.04 0.11 na na na 0.00262 11.9 1.000 0.07 0.04 4.333 0.333 217.82 1.345E-05 518.9733 22.2671 543.67 549.23677 538.10323 0.00327 0.00208 0.00120 K-5 Distillate Tank Distillate (< 0.1% MeOH)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 MeOH 0.10%32.04 0.00295 <=Calc Antoine 0.08 0.05 0.13 7.897 1474.1 229.13 0.00295 11.9 1.000 0.08 0.05 4.333 0.333 217.82 1.622E-05 518.9733 22.2671 543.67 549.23677 538.10323 0.00345 0.00252 0.00093 K-5 Distillate Tank Distillate (< 15% Phenol)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 Phenol 15.00%94.1 0.00143 <=Calc Antoine 0.11 0.08 0.19 7.133 1516.8 174.95 0.00143 11.9 1.000 0.11 0.08 4.333 0.333 217.82 2.301E-05 518.9733 22.2671 543.67 549.23677 538.10323 0.00184 0.00110 0.00075 K-5 Distillate Tank Distillate (< 5% Cresols)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 Cresols (Mixed) 5.00%108.1 0.00650 <=Enter vp 0.60 0.46 1.06 N/A N/A N/A 0.00000 11.9 1.000 0.60 0.46 4.333 0.333 217.82 0.0001204 518.9733 22.2671 543.67 549.23677 538.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! K-5 Distillate Tank Distillate (< 0.1% MEK)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 MEK 0.10%72.12 0.00210 <=Enter vp 0.13 0.10 0.23 N/A N/A N/A 0.00000 11.9 1.000 0.13 0.10 4.333 0.333 217.82 2.59E-05 518.9733 22.2671 543.67 549.23677 538.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! K-5 Distillate Tank Distillate (< 0.4% N-Butanol)0.17 8 8.0 4.0 Cone 1.0 3,008 3,008 84 8.50 35,746 1 35,746 N-Butanol 0.40%74.122 0.00067 <=Enter vp 0.04 0.03 0.07 N/A N/A N/A 0.00000 11.9 1.000 0.04 0.03 4.333 0.333 217.82 8.512E-06 518.9733 22.2671 543.67 549.23677 538.10323 Hand CalcHand Calc=>0.10000 <=Hand Enter! MEK Tank (A-1)MEK 0.17 10.5 15.3 7.7 Cone 1.0 9,929 9,929 Amb 6.72 19,851 1 19,851 100% 98% MEK 100.00%72.12 1.08840 <=Enter vp 0.74 0.00 0.74 N/A N/A N/A 0.00000 2.0 1.000 37.10 776.21 7.998 0.333 692.58 0.0140444 518.9733 22.2671 520.835 526.40218 515.26864 Hand CalcHand Calc=>3.72000 <=Hand Enter! U-5, U-7, U-9 (RUSR)UF Resin - HCHO 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 2,313,438 3 771,146 100% HCHO 1.00%30 0.00291 <=HCHO Eq.1.60 0.00 4.81 na na na 0.00291 34.4 1.000 1.60 0.36 17.333 0.333 1,529.62 1.537E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00369 0.00229 0.00140 U-5, U-7, U-9 (RUSR)UF Resin - MeOH 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 2,313,438 3 771,146 100% MeOH 0.40%32.04 0.00785 <=Calc Antoine 4.62 0.00 13.85 7.897 1474.1 229.13 0.00785 34.4 1.000 4.62 1.04 17.333 0.333 1,529.62 4.424E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00926 0.00662 0.00264 U-4 (WW) Process Washwater - HCHO 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 264,575 1 264,575 HCHO 0.20%30 0.00058 <=HCHO Eq.0.11 0.07 0.18 na na na 0.00058 11.8 1.000 0.11 0.07 17.333 0.333 1,529.62 3.074E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00074 0.00046 0.00028 U-4 (WW)Process Washwater - Phenol 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 264,575 1 264,575 Phenol 1.50%94.1 0.00007 <=Calc Antoine 0.04 0.03 0.07 7.133 1516.8 174.95 0.00007 11.8 1.000 0.04 0.03 17.333 0.333 1,529.62 1.197E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00010 0.00005 0.00004 U-4 (WW) Process Washwater - MeOH 0.17 10.6 34.0 17.0 Cone 1.0 22,443 22,443 70 10.40 264,575 1 264,575 MeOH 0.20%32.04 0.00392 <=Calc Antoine 0.79 0.52 1.31 7.897 1474.1 229.13 0.00392 11.8 1.000 0.79 0.52 17.333 0.333 1,529.62 2.212E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00463 0.00331 0.00132 U-6 (WW) Process Washwater - HCHO 0.17 12 32.5 16.3 Cone 1.0 27,494 27,494 70 10.40 264,575 1 264,575 HCHO 0.20%30 0.00058 <=HCHO Eq.0.11 0.09 0.20 na na na 0.00058 9.6 1.000 0.11 0.09 16.583 0.333 1,875.54 3.074E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00074 0.00046 0.00028 U-6 (WW)Process Washwater - Phenol 0.17 12 32.5 16.3 Cone 1.0 27,494 27,494 70 10.40 264,575 1 264,575 Phenol 1.50%94.1 0.00007 <=Calc Antoine 0.04 0.03 0.08 7.133 1516.8 174.95 0.00007 9.6 1.000 0.04 0.03 16.583 0.333 1,875.54 1.197E-06 518.9733 22.2671 529.67 535.23677 524.10323 0.00010 0.00005 0.00004 U-6 (WW) Process Washwater - MeOH 0.17 12 32.5 16.3 Cone 1.0 27,494 27,494 70 10.40 264,575 1 264,575 MeOH 0.20%32.04 0.00392 <=Calc Antoine 0.79 0.64 1.43 7.897 1474.1 229.13 0.00392 9.6 1.000 0.79 0.64 16.583 0.333 1,875.54 2.212E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00463 0.00331 0.00132 U-8, U-10 (RUSR)UF Resin - HCHO 0.17 12 32.5 16.3 Cone 1.0 27,494 27,494 70 10.40 1,542,292 3 514,097 100% HCHO 1.00%30 0.00291 <=HCHO Eq.1.07 0.00 3.21 na na na 0.00291 18.7 1.000 1.07 0.44 16.583 0.333 1,875.54 1.537E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00369 0.00229 0.00140 U-8, U-10 (RUSR)UF Resin - MeOH 0.17 12 32.5 16.3 Cone 1.0 27,494 27,494 70 10.40 1,542,292 3 514,097 100% MeOH 0.40%32.04 0.00785 <=Calc Antoine 3.08 0.00 9.23 7.897 1474.1 229.13 0.00785 18.7 1.000 3.08 1.27 16.583 0.333 1,875.54 4.424E-05 518.9733 22.2671 529.67 535.23677 524.10323 0.00926 0.00662 0.00264 Phenol = 2.5%0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 Amb 8.66 43,096 1 4,975 Phenol 2.50%94.1 0.00008 <=Calc Antoine 0.00 0.03 0.03 7.133 1516.8 174.95 0.00008 0.2 1.000 0.00 0.03 17.833 0.333 1,544.19 1.284E-06 518.9733 22.2671 520.835 526.40218 515.26864 0.00010 0.00006 0.00005 Catechol = 0.5%0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 Amb 8.66 43,096 1 4,975 Catechol 0.50%110.11 0.00058 <=Enter vp 0.01 0.32 0.33 N/A N/A N/A 0.00000 0.2 1.000 0.01 0.32 17.833 0.333 1,544.19 1.143E-05 518.9733 22.2671 520.835 526.40218 515.26864 Hand CalcHand Calc=>0.10000 Cresols (Mixed) = 85% (MAX)0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 Amb 8.66 43,096 1 4,975 Cresols (Mixed) 85.00%108.1 0.007 <=Enter vp 0.09 3.76 3.85 N/A N/A N/A 0.00000 0.2 1.000 0.09 3.76 17.833 0.333 1,544.19 0.0001354 518.9733 22.2671 520.835 526.40218 515.26864 Hand CalcHand Calc=>0.10000 Naphthalene = 1%0.17 10.5 35.0 17.5 Cone 1.0 22,669 22,669 Amb 8.66 43,096 1 4,975 Naphthalene 1.00%128.17 0.00159 <=Enter vp 0.02 1.02 1.04 N/A N/A N/A 0.00000 0.2 1.000 0.02 1.02 17.833 0.333 1,544.19 3.636E-05 518.9733 22.2671 520.835 526.40218 515.26864 Hand CalcHand Calc=>0.10000 Formic Acid Storage 60% Formic 0.17 6 12.3 6.1 Cone 1.0 2,591 2,591 Amb 10.18 725 1 725 Formic 60.00%46 0.32292 <=Calc Antoine 0.26 7.97 8.22 7.581 1699.2 260.7 0.32292 0.3 1.000 0.26 7.97 6.458 0.333 182.61 0.0026577 518.9733 22.2671 520.835 526.40218 515.26864 0.37746 0.27528 0.10218 Acid Quench A 60% Formic 0.17 6 10.0 5.0 Cone 1.0 2,115 2,115 Amb 10.18 1 0 100% Formic 60.00%46 0.32292 <=Calc Antoine 0.00 0.00 0.00 7.581 1699.2 260.7 0.32292 0.0 1.000 0.00 6.69 5.333 0.333 150.80 0.0026577 518.9733 22.2671 520.835 526.40218 515.26864 0.37746 0.27528 0.10218 Acid Quench B 60% Formic 0.17 7 12.0 6.0 Cone 1.5 3,454 3,454 Amb 10.18 1 0 100% Formic 60.00%46 0.32292 <=Calc Antoine 0.00 0.00 0.00 7.581 1699.2 260.7 0.32292 0.0 1.000 0.00 10.91 6.500 0.500 250.15 0.0026577 518.9733 22.2671 520.835 526.40218 515.26864 0.37746 0.27528 0.10218 0 0.00000 <=Enter vp 0.00 0.00 0.00 N/A N/A N/A 0.00000 0.0 1.000 0.00 0.00 0.000 0.000 0.00 0 517.9533 15.6360 459.67 463.57901 455.76099 Hand CalcHand Calc=>0.10000 If not controlled temperature enter Amb. Enter the pressure difference between the positive pressure setting and vacuum setting (e.g. .03 - (-.03) = .06) Hand Calculated vp's (psi) Control of Working losses. Vapor returns typically assume 98% efficiency for working/filling losses. HCHO 53.5 lb/yr Ammonia Ammonia Cresol Control of Breathing and Working losses. If controlled by oxidizer, assume 100% (emissions are already accounted for at oxidizer). MeOH 880.3 lb/yr MW =17.03 17.03 Contorl of Breathing Losses. Tanks with a controlled temperature =100% . Phenol 1,007.2 lb/yr Percentage =28%1% Ammonia 278.7 lb/yr Temp (F) = Formic 8.2 lb/yr Temp (F) = Cresols (Mixed)5.2 lb/yr Temp (F) = Cresols (m) 1.7 lb/yr Temp (F) = Cresols (o).9 lb/yr Temp (F) = 95 0.308 Cresols (p)1.3 lb/yr Temp (F) = Catechol .3 lb/yr Average Maximum Temp. (Tlx) (F) = 55.566771 12.14 <== Temperatures taken from Ammonia tank, which is under ambient conditions. Naphthalene 1. lb/yr Average Annual Temp (Tla) (F) = 50 10.4 <== Ammonia Solution VP's from GPRI_Vapor Pressures EPI . lb/yr Average Minimum Temp. (Tln) (F) = 44.4 8.42 MEK 1.1 lb/yr Temp (F) = 50 6.63 N-Butanol .1 lb/yr Check: OK dPv = (Tlx-Tln) = 3.72 n/a n/a n/a n/a n/a Comments for Tanks Calculations Table 7.1-6 Paint Factor Table 7.1-5 Vapor Pressure Equation Constants Paint Factor Based on Celsius Paint Condition A B C MW Density Paint Color Shade Good Poor HCHO Special Equation (based on K)30 9.5 Aluminum Specular 0.39 0.49 MeOH 7.897 1474.08 229.13 32.04 6.63 Aluminum Diffuse 0.6 0.68 Phenol 7.133 1516.79 174.95 94.1 8.92 Gray Light 0.54 0.63 Formic 7.581 1699.2 260.7 46.0 10.18 Gray Medium 0.68 0.74 EPI 8.2294 2086.806 273.16 92.5 9.848 Red Primer 0.89 0.91 Acetone 7.117 1210.595 229.664 58.08 6.628 White NA 0.17 0.34 (1) If Roof and Shell are different, factor = average. (2) Assume White and Good Condition if specific Information is not available. Raleigh, North Carolina 1) For consistency, forced usage is used for tanks throughputs rather and receipts. 3) Acid quench tanks are pressurized and have no emissions. 7) 2009RY: Remeoved MSBP from 2008 switch to CTP. 5) 4/30/07: Changed CA83 tank to MSBP tank with 0.3% Phenol & remainder VOC. 4) The CA83BL Tank has zero Cresols. The throughput for the CA41 & CA44 is used for this tank to simulate the emissions from the drums and/or totes of CA41 & CA44. 6) 2008RY: Changed Cresylic tank to Cresylic CTP with cresols Tank Emissions Summary (Section 5.2) R-3 Cresylic Acid (CTP) 2) HCHO and MeOH Tanks are controlled by oxidizer. Emissions are captured in those calculations. 10) The following are NOT stored in bulk: Styrene, N-Butanol, MIBK, CA41 8) Converted S-20 tank to K-5 Distillate Accumulation Tank 9) Added K-5 Distillate Tank 12) 2011RY: Changed service of C(1-3) to non VOC / Form R chemicals 11) 2011RY: Ajusted use of all tanks (minor tweaks) 12) 2011RY: Accounting for all (16) WW tanks. 11) 2011RY: Added Recycle logic for methanol/HCHO tanks as well as ammonia scrubber. Antoine's Constants This is a controlled document. https://thebakelite.sharepoint.com/sites/GP_BPEnvDocuments/NC090_DL/01 Air/Reports/AEI/Emissions Inventory/2021RY/04 - Calculation Spreadsheet - Final/CON_2021RY_EI_SARA 313_Calcs_FINAL Tanks Tanks Page 1 . HCHO Plant(s) Reporting Year 7,992 <==Calculaed Production Hours based on 23gpm methanol feedrate Location 8,446 <==2021RY Actual run time Emissions from RCI Formaldehyde Plant: DT Hours 313.97 Con- 50% Oxidizer Oxidizer Uncontrolled Annual Prod. Treated Oxidizer Total MeOH version HCHO Inlet Outlet DRE Emiss. Rate (50% HCHO Onsite Emiss.Emiss. Plant Pollutant (gpm)Ratio (tons/hr)(lb/hr)(lb/hr)(%)(lbs/ton) & UFC) (tpy)(lbs/yr)(lbs/yr)(lbs/yr) Methanol 23.0 11.28 7.783 19.97 0.320 98.4%2.57 62,201 157,037 2,557 2,558 0.52 90%1.0 1.0 0.1 5.7 6.8 21.6 Formaldehyde 23.0 11.28 7.783 18.70 0.380 98.0%2.40 62,201 146,408 3,037 3,038 0.00 75%0.0 0.0 0.0 0.0 0.0 0.0 Acetaldehyde 23.0 11.28 7.783 2.87 0.0025 99.9% 0.37 62,201 22,916 20 20.13 0.0 0.0 0.0 0.0 0.0 0.0 DME 23.0 11.28 7.783 109.87 2.230 98.0% 14.12 62,201 860,229 17,822 17,827 0.0 0.0 0.0 0.0 0.0 0.0 VOC 23.0 11.28 7.783 131.44 2.61 98.0% 16.89 62,201 1,029,554 20,878 20,885 0.0 0.0 0.0 0.0 0.0 0.0 CO 23.0 11.28 7.783 415.46 1.140 99.7% 53.38 62,201 3,311,132 9,111 9,132 0.0 0.0 0.0 0.0 0.0 0.0 Total 1 1 0 6 7 22 NOTE: The Conway RCI process is interlocked to prevent bypass of HCHO Plant. 24,240.11 168.00 Resin Plant 226 Spray Dryer 24,634.11 VOC CO RCI Plant <== Short flameout with minor low delta T <== Longer flameouts with low delta T <== Other <== Other Annual Excess Emissions (Hours) % DRE HCHOMeOH Acetalde hyde DME <== Other <== Other Annual Emissions from Bypasses in (lbs): 2021RY Conway, NC Catalytic Oxidizer Stack Test dated: 4/26/2016 Current Production and Emissions Georgia-Pacific Resins 2 CON_2021RY_EI_SARA 313_Calcs_FINAL Resin Plant Reporting Year TO Annual Downtime Hours =42.57 Location Emissions from Resin Process Oxidizer # of Kettles Uncontrolled Emission Oxidizer Destruction Resin Prod. Emission Inlet Contributing to Factor Outlet Efficiency during test Factor Pollutant (lbs/hr) to Emissions (lbs / kettle hr) (lbs/hr) DRE (%) (lbs/ kettle hr) (lbs / ton Resin) MeOH 2.58 4 0.65 0.041 98.4% 13,737 0.0939 HCHO 0.1 4 0.03 0.004 96.0% 13,737 0.0036 Phenol 0.01 3 0.003 0.004 98.4% 14,796 0.0005 <==Calculated ND values calculated as MDL * 50% Acetaldehyde 0.03 4 0.008 0.002 98.4%13,737 0.0011 <==Calculated ND values calculated as MDL * 50% N-Butanol 0.0025 1 0.003 0.0035 98.4% 1,555 0.0032 <==Calculated ND values calculated as MDL * 50% Styrene 0.002 1 0.002 0.0025 98.4% 1,732 0.0023 <==Calculated ND values calculated as MDL * 50% DEA 0.003 1 0.003 0.004 98.4% 12,987 0.0005 <==Calculated ND values calculated as MDL * 50% MIBK 0.0025 1 0.003 0.003 98.4% 0 0.0000 <==Calculated ND values calculated as MDL * 50% MEK 0.0015 1 0.002 0.002 98.4% 1,346 0.0022 <==Calculated ND values calculated as MDL * 50% m-Cresol 0.0025 1 0.003 0.0035 98.4% 0 0.0000 <==Calculated ND values calculated as MDL * 50% o-Cresol 0.0025 1 0.003 0.0035 98.4% 1,585 0.0032 <==Calculated ND values calculated as MDL * 50% p-Cresol 0.003 1 0.003 0.004 98.4% 0 0.0000 <==Calculated ND values calculated as MDL * 50% Cresols (Mixed Isomers) 0.008 1 0.008 0.011 98.4% 15,183 0.0011 <==Calculated ND values calculated as MDL * 50% DME (VOC)0.71 4 0.18 0.009 98.7% 13,737 0.0258 Total HAPs 50%MDL 2.74 4 0.68 0.077 97.2%13,737 0.0997 <==Calculated with MDL * 50% Total VOCs 50%MDL 3.45 4 0.86 0.086 97.5%13,737 0.1256 <==Calculated with MDL * 50% Total HAPs 2.72 4 0.68 0.045 98.3% 13,737 0.0990 <==Calculated withOUT MDL * 50% Total VOCs 3.43 4 0.86 0.054 98.4%13,737 0.1248 <==Calculated withOUT MDL * 50%. This Method 320 VOC DRE which is believed to me most representative should be used as DRE for compounds which were non detect. Total VOCs M25A as MeOH 3.36 4 0.84 0.10 97.0%13,737 0.1223 <==Method 25A destruction efficiency (DRE) should be used in lieu of DRE with trace detection amounts NOx --- 0.00 0.21 0.0% 13,737 0.0306 <==Outlet values used vs. inlet because more impacted from combusion vs process. CO 0.001 0.00 0.96 0.0% 13,737 0.1398 <==Outlet values used vs. inlet because more impacted from combusion vs process. Ammonia 0.013 3 0.004 0.004 69.2%13,737 0.0019 <==DRE is actually greater than calculated because ammonia is formed in combustion of VOCs and natural gas. Kettle Numbers K(1,3,5,7)K(2,8)Total Product Type / Chemical PF UF N-Butanol Styrene DEA MIBK MEK Cresols - O Cresols - Mixed Annual Production (lbs)284,198,506 40,099,600 769,100 195,880 0 0 557,100 259,250 20,735,508 324,298,106 <==Because all chemical compounds in column D-J are also UF or PF Resins, they around not included in Resin Total Annual Production (Tons)142,099 20,050 385 98 0 0 279 130 10,368 162,149 <==Because all chemical compounds in column D-J are also UF or PF Resins, they around not included in Resin Total Total Kettle (Hrs) 19,393 2,895 598.3 146.2 0.0 0.0 399.6 133.1 1,069.1 22,288 <==Because all chemical compounds in column D-J are also UF or PF Resins, the hours of opoeration is not included in Resin Total Prod. Rate (tons/hr)7.33 6.93 0.64 0.67 0.00 0.00 0.70 0.97 9.70 7.28 Event Event Minutes Number of Reactors PF/UF/Boils PF/Boils N-Butanol Styrene DEA MIBK MEK Cresols - O Cresols - Mixed MeOH 162,149 14,985 242 MeOH 22,288 14,147 228 4 0.0 228 01/11/21 0 0 0 0 HCHO 162,149 567 24 HCHO 22,288 535 22 4 0.0 22 03/27/21 0 0 0 0 Phenol 142,099 63 1 Phenol 19,393 64 1 2 0.0 1.0 04/28/21 0 0 0 0 Acetaldehyde 162,149 174 3 Acetaldehyde 22,288 165 3 4 0.0 2.63 06/03/21 0 0 0 0 N-Butanol 385 1 0 N-Butanol 598 1.5 0.024 0 0.0 0.02 07/08/21 0 0 0 0 Styrene 98 0 0 Styrene 146 0.3 0 0 0.0 0.005 09/02/21 0 0 0 0 DEA 0 0 0 DEA 0 0.0 0 0 0.0 0.000 11/04/21 2 2 2 1 MIBK 0 0 0 MIBK 0 0.0 0 0 0.0 0.000 11/11/21 0 0 0 0 MEK 279 1 0 MEK 400 0.6 0 0 0.0 0.009 11/11/21 0 0 0 0 m-Cresol 10,368 0 0 m-Cresol 1,069 2.6 0 0 0.0 0.042 12/28/21 0 0 0 0 o-Cresol 130 0.4 0.0 o-Cresol 133 0.3 0 0 0.0 0.005 12/29/21 0 0 0 0 p-Cresol 10,368 0 0 p-Cresol 1,069 3.2 0 0 0.0 0.050 Cresols (Mixed Isomers)10,368 11 0 Cresols (Mixed Isomers)1,069 8.4 0.1 0 0.0 0.13 DME (VOC)162,149 4,137 53 DME (VOC)22,288 3,906 50 4 0.0 50.2 Total HAPs 162,149 15,713 454 Total HAPs 22,288 14,835 429 0.0 429.0 Total VOCs 162,149 19,851 508 Total VOCs 22,288 18,741 479 0.0 479.2 4 2 - - - - - - - Total HAPs 162,149 15,787 266 Total HAPs 22,288 14,905 251 0.0 250.7 Total VOCs 162,149 19,924 319 Total VOCs 22,288 18,811 301 0.0 300.9 NOx 0 0 0 NOx 8,717 0 1,831 0 0.0 1,831 CO 0 0 0 CO 8,717 0 8,369 0 0.0 8,369 Ammonia 0 0 0 Ammonia 8,717 37 35 4 0.0 35 2021RY Conway, NC Thermal Oxidizer Stack Test dated 4/26/16 Kettle Production Data for current Reporting Year Oxidizer Emissions (lbs/yr) Kettles (Specialty Chemicals) Reactor Bypasses (Reactor Minutes) Bypass Emissions (lbs) TOTAL Emissions (lbs) Production Basis (Hrs) Emissions using (lb/ton) Emission Factor Emissions using (lb/hr) Emission Factor using "Actual" kettle hours Annual Emissions (lbs) Pollutant Production Basis (tons) Treated Onsite (lbs/yr) Oxidizer Emissions (lbs/yr)Pollutant Treated Onsite (lbs/yr) 2020 Bypass Events Georgia-Pacific Resin CON_2021RY_EI_SARA 313_Calcs_FINAL GPRI Environmental Reporting Year 2021RY Plant Location Conway, NC Note: The ELDACs online database was used for equipment counts. A backup PDF of these reports is posted with the SARA calculations. MeOH (LL) HCHO (HL) MeOH (LL) HCHO (HL) UFC (HL) Phenol (HL) Cresols (HL) MEK (LL) MIBK (LL) MeOH (LL) HCHO (HL) Phenol (HL) Cresols (HL) MEK (LL) MIBK (LL) Emission LDAR Average Plant A 100% 50% 100% 50% 30% 100% 85% 100% 100% 100% 50% 100% 85% 100%100% Factor Control Operating Hrs. Equipment % of Counts % of Counts Equipment Equipment Equipment Equipment Equipment Equipment Equipment Equipment % of Counts % of Counts % of Counts % of Counts % of Counts % of Counts Component Type (lb/hr/source) Efficiency (hr/yr) Counts in Stream in Stream Counts Counts Counts Counts Counts Counts Counts Counts Mixed Stream Mixed Stream Mixed Stream Mixed Stream Mixed Stream Mixed Stream Agitators (LL/GV) 0.0386 0.93 8,760 0 0 0 0 0 0 0 0 13 60% 25% 11% 2% 2% 0%Sum = 100% Agitators (HL) 0.0161 0.93 8,760 0 0 0 0 0 0 0 0 0 0% 0% 0% 0% 0% 0%Check Percentages Closed Vent Systems Connectors (LL) 0.0005 0.75 8,760 210 100% 0% 80 0 0 0 0 110 0 357 15% 40% 40% 5% 0% 0%Sum = 100% Connectors (GV) 0.0029 0.75 8,760 76 64% 36% 41 0 0 21 0 0 0 365 60% 25% 13% 2% 0% 0%Sum = 100% Connectors (HL) 0.00007 0.75 8,760 373 0% 100% 69 0 50 250 58 0 0 519 57% 25% 10% 5% 3% 0%Sum = 100% End Caps for Open Ended Lines Group Tag Instrumentation Systems (LL) 0.0005 0.75 8,760 0 100% 0 Instrumentation Systems (GV) 0.0029 0.75 8,760 0 50% 50% 0 Instrumentation Systems (HL) 0.00007 0.75 8,760 0 100% 0 Other (LL) 0.0005 0.75 8,760 0 100% 0 Other (GV) 0.0029 0.75 8,760 0 50% 50% 0 Other (HL) 0.00007 0.75 8,760 0 100% 0 PRD (LL) 0.0005 0.75 8,760 1 100% 0 PRD (GV) 0.0029 0.75 8,760 5 100% 1 1 16 60% 25% 11% 2% 2% 0%Sum = 100% PRD (HL) 0.00007 0.75 8,760 0 100% 0 Pumps (LL) 0.0386 0.93 8,760 3 100% 1 0 0 0 0 1 0 4 55% 10% 30% 5%Sum = 100% Pumps (HL) 0.0161 0.93 8,760 3 100% 0 2 2 4 2 0 0 15 55% 10% 30% 5%Sum = 100% Sampling System Valves (LL) 0.0035 0.97 8,760 59 100% 30 0 0 0 0 32 0 93 20% 40% 40%Sum = 100% Valves (GV) 0.0089 0.97 8,760 18 44% 56% 5 0 0 0 0 0 0 41 41% 27% 26% 3% 3% 0%Sum = 100% Valves (HL) 0.0007 0.97 8,760 84 100% 13 62 19 80 23 0 0 134 25% 40% 25% 5% 5% 0%Sum = 100% Misc & Other (LL) 0.0005 0.75 8,760 0 100%. Misc & Other (GV) 0.0029 0.75 8,760 0 50% 50% Misc & Other (HL) 0.00007 0.75 8,760 0 100% Sub -total Emissions (lbs/yr) => 716 150 430 16 9 226 28 180 0 1,937 476 649 80 15 0 HCHO Plant Resin Plant Chemical Emissions (lbs/yr)Emissions (lbs/yr) Emissions (lbs/yr) Methanol 3,083 Formaldehyde 651 150 501 Phenol 875 Cresols (Mixed) 108 Cresols (m) 47 Cresols (o) 24 Cresols (p) 38 MEK 195 MIBK 0 Emissions Factor(1)Control Component Type (lb/hr/source) Efficiency (%)(1) Valves (GV) 0.0089 97% Valves (LL) 0.0035 97% Valves (HL) 0.0007 97% Pumps (LL) & Agitators (GV/LL)0.0386 93% Pumps (HL) & Agitators (HL)0.0161 93% Connectors, PRD, Misc. (G/V)0.0029 75% Connectors, PRD, Misc. (LL)0.0005 75% Connetors, PRD, Misc. (HL)0.00007 75% (1)Emission factors and control efficiencies are taken from the TNRCC "Technical Guidance for Chemical Sources Equipment Leak Fugitives" (March 1995). Factors based on SOCMI without C2. See supporting guidance document for details. Weekly audio/visual/olfactory inspections w/ leak repair. Note GPRI conducts weekly area inspections. Policy & training also in place to repair any leak discovered during normal activities. Same efficiency as the annual monitioring is appropriate. 28MID program (500 ppm leak definition & quarterly monitoring). Note GPRI repairs leaks >100 ppm. 28MID program (500 ppm leak definition & quarterly monitoring). Note GPRI repairs leaks >100 ppm. Weekly audio/visual/olfactory inspections w/ leak repair. Note GPRI conducts weekly area inspections. Policy & training also in place to repair any leak discovered during normal activities. 28MID program (500 ppm leak definition & quarterly monitoring). Note GPRI monitors monthly and repairs leaks >100 ppm. Weekly audio/visual/olfactory inspections w/ leak repair. Note GPRI conducts weekly area inspections. Policy & training also in place to repair any leak discovered during normal activities. Gas/Vapor and Light Liquid Connectors are monitored annually and are included in weekly walk around inspections. While a greater efficiency could be justified, the lower 75% control factor was conservatively selected to account for the areas that are les Gas/Vapor and Light Liquid Connectors are monitored annually and are included in weekly walk around inspections. While a greater efficiency could be justified, the lower 75% control factor was conservatively selected to account for the areas that are les Basis GPRI Fugitive Emission Factors for LDAR Equipment Leaks: Formaldehyde Plant(s)Individual Liquid LDAR Streams (Resin MACT)Mixed Streams (Resin MACT) Template Revision 1.1 02/16/2005 This "Template" is a controlled electronic document. CON_2021RY_EI_SARA 313_Calcs_FINAL LDAR Template Owner: Division Environmental Manager Tanker_DrumFilling Reporting Year 2021RY Location Conway, NC Loading Rack & Drum/Tote Filling Emissions: Note #1: Unless otherwise inputted, all "Resin" throughput is assumed to equal the forced production. Throughput (pounds) Density (lb/gal) Throughput (gallons) 59.2833 F = average ambient temperature for Raleigh, NC. Taken from TANKS Program Resimix (RPMX / RPMM)115,756,430 10.00 11,575,643 Insulating Resins (RPPI)0 10.00 0 OSB (RPPB)92,172,956 10.20 9,036,564 Equation: For Tank Loading Hardboard (RPPD)0 10.10 0 L = 12.46 x (S*pp*MW/T) Abbrasives (RPAB)913,040 10.40 87,792 L = Loading loss, lb/1000 gal Electrical Laminates (RPEL)323,000 9.35 34,545 S = Saturation Factor (AP42 Table 5.2-1, 01/95) High Pressure Laminates (RPHP)29,185,963 9.60 3,040,204 RPPC 2112 Resin = 414,000 9.35 44,278 Note: S = 0.6 for "Submerged" filling & S = 1.45 for "non Submerged" filling RPPC 2640 Resin = 259,250 8.34 31,085 RPPC 791C99 Resin = 144,450 8.92 16,194 Equation 11 OTHER (RPPC)1,018,293 8.84 115,192 E = mass emitted per fill Saturating (RPPF)0 9.50 0 E = V/(R*T) x (pp)(MW) Floral Foam (RPFM)0 10.85 0 Gas Constant (R) =10.73 ft3 x psia / lb-mole x ºR Filter Resins (RPLS)1,170,519 10.35 113,094 Total Emissions = E x Throughput/Vessel Size Impregnating Resins (RPMS)654,729 10.45 62,653 Note: This equation yields the same results as a Splash Factor of 1.0 Calculated "Other PF Resins (non-specialty resins)"0 10.45 0 Resorcinol Resin - "RR" Total 0 9.60 0 pp = Partial Pressure of Liquid, psia UF / MUF Resin - "RU" Total 40,099,600 10.85 3,695,816 M = Molecular Weight of vapors AF Resin (CORM)0 9.70 0 T = Temp of liquids, R (460 + F) AF Resi Mix (COCM)0 10.42 0 MF Resin - "RM" Total 14,633 10.10 1,449 Total HCHO Shipped = 7,261,560 9.12 796,224 Total UFC Shipped = 0 10.40 0 Total Methanol Shipped = 0 6.63 0 Product Loaded Throughput (gal) S Temp at Load Condition (F) +5% OHAP (Resin Affected Source) Chemical Percent of Free Chemical MW Control Efficiency (%) Partial vp at Storage Condition (psi) Emission Factor (lbs/1,000 gal) Controlled Emissions (lbs)A B C Calc. partial vapor pressure (psi) 11,575,643 1.45 85.00 HCHO 0.10%30 0%0.00054 <=HCHO Eq.0.0005 6.27 na na na 0.00054 11,575,643 1.45 85.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 11,575,643 1.45 85.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 0 1.45 50.00 HCHO 9.00%30 0%0.00291 <=HCHO Eq.0.0031 0.00 na na na 0.00291 0 1.45 50.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 50.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 9,036,564 1.45 78.00 HCHO 0.20%30 0%0.00082 <=HCHO Eq.0.0008 7.44 na na na 0.00082 9,036,564 1.45 78.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 9,036,564 1.45 78.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 0 1.45 72.00 HCHO 0.20%30 0%0.00063 <=HCHO Eq.0.0006 0.00 na na na 0.00063 0 1.45 72.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 72.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 87,792 1.45 75.00 HCHO 0.80%30 0%0.00288 <=HCHO Eq.0.0029 0.26 na na na 0.00288 87,792 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 87,792 1.45 75.00 Phenol 7.00%94.1 0%0.00043 <=Calc Antoine 0.0014 0.12 7.133 1516.79 174.95 0.00043 34,545 1.45 72.00 HCHO 1.00%30 0%0.00317 <=HCHO Eq.0.0032 0.11 na na na 0.00317 34,545 1.45 72.00 MeOH 25.00%32.04 0%0.52087 <=Calc Antoine 0.5668 19.58 7.897 1474.08 229.13 0.52087 34,545 1.45 72.00 Phenol 11.00%94.1 0%0.00059 <=Calc Antoine 0.0019 0.06 7.133 1516.79 174.95 0.00059 3,040,204 1.45 72.00 HCHO 0.20%30 0%0.00063 <=HCHO Eq.0.0006 1.96 na na na 0.00063 3,040,204 1.45 72.00 MeOH 18.00%32.04 0%0.37502 <=Calc Antoine 0.4081 1,240.59 7.897 1474.08 229.13 0.37502 3,040,204 1.45 72.00 Phenol 9.50%94.1 0%0.00051 <=Calc Antoine 0.0016 4.92 7.133 1516.79 174.95 0.00051 44,278 1.00 108 HCHO 1.00%30 100%0.01335 <=HCHO Eq.0.0088 0.00 na na na 0.01335 44,278 1.00 108 MeOH 0.00%32.04 100%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 44,278 1.00 108 Phenol 8.50%94.1 100%0.00231 <=Calc Antoine 0.0048 0.00 7.133 1516.79 174.95 0.00231 44,278 1.00 108 N-Butanol 0.00%74.12 98%0.00000 <=Enter vp 0.0000 0.00 N/A N/A N/A 0.00000 44,278 1.00 108 Cresols 0.00%108.1 100%0.00000 <=Enter vp 0.0000 0.00 N/A N/A N/A 0.00000 44,278 1.00 108 MEK 24.00%72.12 100%0.90461 <=Enter vp 1.4312 0.00 N/A N/A N/A 0.00000 31,085 1.00 104 HCHO 0.50%30 100%0.00574 <=HCHO Eq.0.0038 0.00 na na na 0.00574 31,085 1.00 104 MeOH 0.00%32.04 100%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 31,085 1.00 104 Phenol 7.50%94.1 100%0.00173 <=Calc Antoine 0.0036 0.00 7.133 1516.79 174.95 0.00173 31,085 1.00 104 N-Butanol 50.00%74.12 98%0.18274 <=Enter vp 0.2992 0.19 N/A N/A N/A 0.00000 31,085 1.00 104 Cresols 2.00%108.1 100%0.00032 <=Enter vp 0.0008 0.00 N/A N/A N/A 0.00000 31,085 1.00 104 MEK 0.00%72.12 100%0.00000 <=Enter vp 0.0000 0.00 N/A N/A N/A 0.00000 16,194 1.00 104 HCHO 0.80%30 100%0.00919 <=HCHO Eq.0.0061 0.00 na na na 0.00919 16,194 1.00 104 MeOH 0.00%32.04 100%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 16,194 1.00 104 Phenol 5.00%94.1 100%0.00115 <=Calc Antoine 0.0024 0.00 7.133 1516.79 174.95 0.00115 16,194 1.00 104 N-Butanol 45.00%74.12 98%0.16447 <=Enter vp 0.2693 0.09 N/A N/A N/A 0.00000 16,194 1.00 104 Cresols 0.00%108.1 100%0.00000 <=Enter vp 0.0000 0.00 N/A N/A N/A 0.00000 16,194 1.00 104 MEK 0.00%72.12 0%0.00000 <=Enter vp 0.0000 0.00 N/A N/A N/A 0.00000 115,192 1.00 65.00 HCHO 0.50%30 100%0.00117 <=HCHO Eq.0.0008 0.00 na na na 0.00117 115,192 1.00 65.00 MeOH 4.00%32.04 100%0.06740 <=Calc Antoine 0.0513 0.00 7.897 1474.08 229.13 0.06740 115,192 1.00 65.00 Phenol 7.50%94.1 100%0.00028 <=Calc Antoine 0.0006 0.00 7.133 1516.79 174.95 0.00028 0 1.45 75.00 HCHO 0.80%30 0%0.00288 <=HCHO Eq.0.0029 0.00 na na na 0.00288 0 1.45 75.00 MeOH 24.00%32.04 0%0.54655 <=Calc Antoine 0.5914 0.00 7.897 1474.08 229.13 0.54655 0 1.45 75.00 Phenol 4.50%94.1 0%0.00028 <=Calc Antoine 0.0009 0.00 7.133 1516.79 174.95 0.00028 0 1.45 62.00 HCHO 5.50%30 0%0.00361 <=HCHO Eq.0.0037 0.00 na na na 0.00361 0 1.45 62.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 62.00 Phenol 3.70%94.1 0%0.00012 <=Calc Antoine 0.0004 0.00 7.133 1516.79 174.95 0.00012 113,094 1.45 70.00 HCHO 3.00%30 0%0.00383 <=HCHO Eq.0.0039 0.44 na na na 0.00383 113,094 1.45 70.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 113,094 1.45 70.00 Phenol 14.90%94.1 0%0.00072 <=Calc Antoine 0.0023 0.26 7.133 1516.79 174.95 0.00072 62,653 1.00 75.00 HCHO 1.00%30 0%0.00360 <=HCHO Eq.0.0025 0.16 na na na 0.00360 62,653 1.00 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 62,653 1.00 75.00 Phenol 12.50%94.1 0%0.00077 <=Calc Antoine 0.0017 0.11 7.133 1516.79 174.95 0.00077 0 1.45 50.00 HCHO 0.20%30 0%0.00024 <=HCHO Eq.0.0003 0.00 na na na 0.00024 0 1.45 50.00 MeOH 0.10%32.04 0%0.00104 <=Calc Antoine 0.0012 0.00 7.897 1474.08 229.13 0.00104 0 1.45 50.00 Phenol 0.20%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 0 1.45 75.00 HCHO 0.10%30 0%0.00036 <=HCHO Eq.0.0004 0.00 na na na 0.00036 0 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 75.00 Phenol 10.00%94.1 0%0.00062 <=Calc Antoine 0.0020 0.00 7.133 1516.79 174.95 0.00062 3,695,816 1.45 75.00 HCHO 0.20%30 0%0.00072 <=HCHO Eq.0.0007 2.70 na na na 0.00072 3,695,816 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 3,695,816 1.45 75.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 0 1.45 75.00 HCHO 0.30%30 0%0.00108 <=HCHO Eq.0.0011 0.00 na na na 0.00108 0 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 75.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 0 1.45 75.00 HCHO 0.20%30 0%0.00072 <=HCHO Eq.0.0007 0.00 na na na 0.00072 0 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 0 1.45 75.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 1,449 1.45 75.00 HCHO 0.10%30 0%0.00036 <=HCHO Eq.0.0004 0.00 na na na 0.00036 1,449 1.45 75.00 MeOH 0.00%32.04 0%0.00000 <=Calc Antoine 0.0000 0.00 7.897 1474.08 229.13 0.00000 1,449 1.45 75.00 Phenol 0.00%94.1 0%0.00000 <=Calc Antoine 0.0000 0.00 7.133 1516.79 174.95 0.00000 796,224 1.45 140.00 HCHO 50.50%30 100%0.30145 <=HCHO Eq.0.2723 0.00 na na na 0.30145 796,224 1.45 140.00 MeOH 1.50%32.04 100%0.18245 <=Calc Antoine 0.1760 0.00 7.897 1474.08 229.13 0.18245 0 1.45 90.00 HCHO 30.00%30 0%0.03981 <=HCHO Eq.0.0392 0.00 na na na 0.03981 0 1.45 90.00 MeOH 0.50%32.04 0%0.01746 <=Calc Antoine 0.0184 0.00 7.897 1474.08 229.13 0.01746 Methanol 0 1.45 59.28 NA MeOH 100.00%32.04 0%1.40988 <=Calc Antoine 1.5716 0.00 7.897 1474.08 229.13 1.40988 S = 0.6 for "Submerged" Tanker filling S = 1.45 for "non Submerged" Tanker filling S = 1.0 for Tote or Drum filling 365478 <==Not Controlled or vapor balanced Resin Gallon with +5% OHAPs = 100,462 Enter 98% if Vapor Exchange is used or Annual Throughput < 800,000 gal.No Controls Required (<800K Gal/yr)<==Transfer Racks loading liquids with +98% HAPs 100% if controlled by Oxidizer and accounted for in the HCHO plant emissions. Annual Throughput (+10,000,000 gal) <10MM gal - No Controls Required<==Transfer Racks loading liquids with (5 - 97.9%) HAPs Annual Throughput (+3,117,230 gal) Low Throughput Rack <==Not Controlled or vapor balanced Resin Gallon with +5% OHAPs = 235,431 Annual Throughput < 800,000 gal.No Controls Required (<800K Gal/yr)<==Transfer Racks loading liquids with +98% HAPs Annual Throughput (+10,000,000 gal) <10MM gal - No Controls Required<==Transfer Racks loading liquids with (5 - 97.9%) HAPs Annual Throughput (+3,117,230 gal) Low Throughput Rack <==Not Controlled or vapor balanced Resin Gallon with +5% OHAPs = 2,939,742 Annual Throughput < 800,000 gal.95% Controls or Vap. Bal Required<==Transfer Racks loading liquids with +98% HAPs Annual Throughput (+10,000,000 gal) <10MM gal - No Controls Required<==Transfer Racks loading liquids with (5 - 97.9%) HAPs Annual Throughput (+3,117,230 gal) Low Throughput Rack <==Existing OLD Sources do not regulate drum/tote loading. Resin Gallon with +5% OHAPs = 269,402 Annual Throughput < 800,000 gal.No Controls Required (<800K Gal/yr)<==Transfer Racks loading liquids with +98% HAPs Annual Throughput (+10,000,000 gal) <10MM gal - No Controls Required<==Transfer Racks loading liquids with (5 - 97.9%) HAPs Annual Throughput (+3,117,230 gal) Low Throughput Rack Resin Gallon with +5% OHAPs = 3,275,636 Annual Throughput < 800,000 gal.Regulated Transfer Rack Annual Throughput (+10,000,000 gal) <10MM gal - No Controls Required Annual Throughput (+3,117,230 gal) High Throughput Rack Resin Gallon with +5% OHAPs = 3,275,636 Annual Throughput <800,000 gal. Regulated Transfer Rack Annual Throughput (+3,117,230 gal) High Throughput Rack Table 7.1-5 Vapor Pressure Euqation Constants HCHO 19.3 lb/yr Based on Celcius MeOH 1,260.2 lb/yr A B C MW Phenol 5.5 lb/yr HCHO Special Equation (based on K)30 EPI . lb/yr MeOH 7.897 1474.08 229.13 32.04 Ammonia . lb/yr Phenol 7.133 1516.79 174.95 94.1 MEK . lb/yr Formic 7.581 1699.2 260.7 N-Butanol .3 lb/yr EPI 8.2294 2086.806 273.16 92.05 Cresols . lb/yr Acetone 7.117 1210.595 229.664 MIBK . lb/yr Check:OK N NA NA N Y N N N Container Y Y Y Container Y Y Container Container Container N Y N N Y Resimix (RPMX / RPMM) OSB (RPPB) Insulating Resins (RPPI) Electrical Laminates (RPEL) Hardboard (RPPD) Abbrasives (RPAB) Calculated "Other PF Resins (non- specialty resins)" Floral Foam (RPFM) Filter Resins (RPLS) High Pressure Laminates (RPHP) RPPC 2112 Resin = RPPC 2640 Resin = RPPC 791C99 Resin = OTHER (RPPC) Saturating (RPPF) Impregnating Resins (RPMS) Loading Rack Emissions Summary UFC Resorcinol Resin - "RR" Total UF / MUF Resin - "RU" Total AF Resi Mix (COCM) MF Resin - "RM" Total AF Resin (CORM) Formaldehyde If Considered New Affected Source (OLD MACT) If Considered Existing Affected Source (OLD MACT) - Speciality Load Rack If Considered Existing Affected Source (OLD MACT) - Rail Loading If Considered Existing Affected Source (OLD MACT) - PF Loading Rack If Considered Existing Affected Source (OLD MACT) - Cumulative If Considered Existing Affected Source (OLD MACT) - Container Loading Georgia-Pacific Resins 5 CON_2021RY_EI_SARA 313_Calcs_FINAL Resin Drying Pad_Air Reporting Year 2021RY Location Conway, NC Fugitive Emissions Associated with Resin Solids Drying Pad Background information Plant Date of Test Liquid Resin Feed (type) MeOH (lbs / lbs wet feed) HCHO (lbs / lbs wet feed) Phenol (lbs / lbs wet feed) NH3 (lbs / lbs wet feed) Chemical Volitalizati on Rate TAY Jan-09 351C05 0.002108203 0.00030603 4.37E-05 MeOH 30%estimated CON Aug-06 217G77 0.003054484 0.00064934 0 HCHO 25%estimated CON Aug-06 22C92 0.001767632 0.00021595 7.97E-05 0.000312 Phenol 10%estimated 0.002310106 0.00039044 4.11E-05 0.000312 Ammonia 100%worst case Estimated %1,484,600 100%1,484,600 <-- estmated % based on production [UF & PF]/[total Resin] 100%1,484,600 <-- estmated % based on production [UF & PF]/[total Resin] 100% 1,484,600 <-- estmated % based on production [PF]/[total Resin] 50% 742,300 <-- estmated % based on production [UF & PF]/[total Resin] Chemical of Concern Emission Factor Volitalization Rate Adjustment for % Liquid (4) Drying Pad Air Emissions By Chemical (lb/lb-liquid resin) (%) [10%/63%] (lb/yr) Methanol 0.002310106 30%16%163 Formaldehyde 0.000390439 25%16%23 Phenol 4.11238E-05 10%16%1 Ammonia 0.000312032 100%16%37 (6) All data supporting these values are backed up in the Division's Spray Dryer Emissions Spreadsheet, tab "Division Summary_Emission Factors". The lbs/lbs emission factors are hidden Emissions Factors developed from Divisional Test Data Provided by Decatur Assumptions (this method is a best judgement estimate) (1) A conservative estimate of air emission losses from the plant resin drying pad can be developed based on simple index of lbs of pollutant per pound of material placed on pad. (2) Use Spray Dry Resins test data to represent the average consituents in the liquid resin. Data used is documented below. (3) An average of the Taylorsville (2009) and Conway (2006) compound specific spray dry test results will be utilized to develop a generic index to be used by any facility that has a resin (4) Resin solids on the pad are generated from fully or partially reacted resin. The emission factors are based on liquid based resin (typically ~37% solids & 63% liquid). (5) Per R&D suggestion, resin drying pad volatilization rates: Methanol (0.30); Formaldehyde (0.25) ; Phenol (0.1) AVERAGE = Resin and Resin Solids to Drying Pad Resins & Resin Solids to Drying Pad (lbs) = Annual Resin Drying Pad Air Emissions Percentage of Solids belived to contain MeOH Percentage of Solids belived to contain HCHO Percentage of Solids belived to contain Phenol Percentage of Solids belived to contain Ammonia Georgia-Pacific Chemicals LLC CON_2021RY_EI_SARA 313_Calcs_FINAL Phenol Railcar Unloading Reporting Year Location Phenol Railcar Emission Estimates: Temperature Vapor Pressure Emission Rate Time Emissions (oF)(PSI) (lbs/hr) (Hours) (lbs) 100 0.0195 0.091 1 0.091 110 0.0296 0.138 1 0.138 120 0.0440 0.205 1 0.205 130 0.0642 0.298 1 0.298 140 0.0920 0.428 1 0.428 150 0.1296 0.602 1 0.602 Total 6 1.762 Phenol Emissions Per Railcar (lbs):1.762 lbs. Phenol Usage (lbs):78,473,113 lbs. Number of Railcars Unloaded Annually:420 Annual Phenol Emissions From Railcars (lbs):740 lbs. Notes: Emissions Estimated by EPA TANKS4.0 Software Program. Railcar dimensions are 48 feet by 9.5 feet. Railcar holds 185,000 (lbs) or 20,740 (gal) of phenol. Phenol is solid at 100F Railcars are equiped with steam jackets 2021RY Conway, NC Georgia-Pacific Resins CON_2021RY_EI_SARA 313_Calcs_FINAL OS-12 RESIN MANUFACTURING LDAR Chemical Emissions (lbs/yr) Methanol 2,366.83 Formaldehyde 491.76 Phenol 874.75 Cresols (Mixed)108.11 MEK 194.59 Loading Racks Loading Rack Emissions Summary Emissions (lbs/yr) HCHO 19.34 MeOH 1,260.17 Phenol 5.47 EPI - Ammonia - MEK - N-Butanol 0.27 Cresols - MIBK - Drying Pad Chemical of Concern Emission Factor Drying Pad Air Emissions By Chemical (lb/lb-liquid resin)(lb/yr) Methanol 0.002310106 163.31 Formaldehyde 0.000390439 23.00 Phenol 4.11238E-05 0.97 Ammonia 0.000312032 36.77 Cresol (lb/yr)108.1 Formaldehyde (lb/yr)534.1 Methanol (lb/yr)3,790.3 Phenol (lb/yr)881.2 Ammonia (lb/yr)36.77 MEK (lb/yr)194.59 VOC (tpy)2.75 OS-15 Thruput 11,587,854 gallons VOC Emissions 0.00 ton/yr Methanol Emissions 0.00E+00 lbs/yr OS-10 Throughput (Each)1 HCHO 150 Methanol 716 Thruput 19,851 gallons MEK Emissions 0.74 lb/yr VOC Emissions 0.00 ton/yr MEK/VOC Emission Factor 3.74E-05 lb/gallon Thruput 703,953 gallons Ammonia Emissions 278.66 lbs/yr Emission Factor 1.5834E-03 lbs/gallon Thruput 13,150,360 gallons Pollutant Emissions (lbs/yr)Emission Factor (lb/gal) Methanol 2,558.39 1.95E-04 Formaldehyde 3,037.83 2.31E-04 Acetaldehyde 20.13 1.53E-06 Emissions (tons/yr) CO 4.57 3.47E-07 VOC 10.44 7.94E-07 Thruput 34,649,858 pounds Annual Spray Dry Production (tons / yr)Calculated AVG Emission Factor (lb/ton)Emissions (lbs/yr) Emissions (tons/yr)Emission Factor (lb/lb) MeOH 17,325 5.70 98,830 2.852E-03 HCHO 17,325 0.49 8,488 2.450E-04 Phenol (BDL)17,325 0.03 542 1.564E-05 Acetaldehyde (BDL)17,325 0.01 226 6.517E-06 Triethyamine (BDL)17,325 0.03 542 1.564E-05 Styrene (BDL)17,325 0.03 497 1.434E-05 Cresols (BDL)17,325 0.05 858 2.476E-05 Dimethyl Ether (DME)17,325 0.23 3,967 1.145E-04 Nox 17,325 0.54 9,294 4.65 2.682E-04 Ammonia 17,325 0.02 320 9.233E-06 CO 17,325 1.32 22,813 11.41 6.584E-04 VOC 56.98 tons/yr 3.289E-03 OS-40 Aqua Ammonia Tank OS-1 Formaldehyde Plant OS-54 Spray Dry Manufacturing Spray Dryer Stack Test dated: OS-44 MEK Tank May 2019 Fugitive Sources-LDAR, Loading Racks, Drying Pad Annual Resin Drying Pad Air Emissions Summary Methanol Storage Tank (Operating Under Primary Scenario) Fugitive Sources - LDAR, etc from Formaldehyde plant (lbs/yr) 8 Kettles and 7 Weigh Tanks Thruput 324,298,106 lbs Pollutant Emissions lb/lb emission factor Methanol 228.49 7.05E-07 Formaldehyde 22.29 6.87E-08 Phenol 1.02 3.14E-09 CO (tons)4.18 2.58E-05 Nox (tons)0.92 5.64E-06 EPI - 0.00E+00 HCL - 0.00E+00 VOC (tons)0.13 7.76E-07 Thruput 14,169,818 gallons Emissions 0.00E+00 pounds Throughput (gal/yr)1,542,292 Emission Factor (lb/gal) HCHO (lbs)36.84 2.39E-05 MEOH (lbs)32.66 2.12E-05 VOC (tons)0.035 4.51E-05 Throughput (gal/yr)40,818,321 Emission Factor (lb/gal) HCHO (lbs)15.01 3.68E-07 MEOH (lbs)837.21 2.05E-05 Phenol (lbs)3.76 9.22E-08 VOC (tons)0.43 2.097E-05 NOTE: According to AERO, OS-41 is for Tanks P11-P12. Should the description be updated to tanks S14-S17 & S21? P11-P12 are resin storage tanks. Thoughput (gal/yr)2,381,178 Emission Factor (lb/gal)A little more to it. Let's discuss HCHO(lbs)1.50 6.31E-07 MEOH (lbs)10.31 4.33E-06 Phenol (lbs)0.60 2.52E-07 VOC (tons)0.01 5.214E-06 Thruput 8,312,830 gallons Emission Factor (lb/gal) Phenol (lbs)1,002.57 1.21E-04 VOC (tons)0.50 1.21E-04 Thruput 78,473,113 lbs Emission Factor (lb/lb) Phenol (lbs)740.04 9.43E-06 VOC (tons)0.37 9.43E-06 Throughput (scf*1000/year)120,046 mscf/yr CO2 7,161.89 tons/yr Methane 0.13 tons/yr N2O 0.01 tons/yr TSP 22.81 tons/yr PM10 22.81 tons/yr PM2.5 22.81 tons/yr SO2 0.04 tons/yr Benzene 0.25 lbs/yr Hexane, n-216.08 lbs/yr Toluene 0.41 lbs/yr Throughput (Gallons)215 CO2 2.42 tons/yr CO 0.01 tons/yr NOx 0.05 tons/yr TSP 9.19E-04 tons/yr PM10 8.50E-04 tons/yr PM2.5 8.50E-04 tons/yr SO2 0.00 tons/yr VOC 1.36E-03 tons/yr Acetaldehyde 7.47E-04 lbs/yr Acrolein 2.34E-04 lbs/yr Benzene 2.30E-02 lbs/yr Formaldehyde 2.34E-03 lbs/yr Napthalene (Component of POMTV)3.85E-03 lbs/yr Polycyclic Organic Matter (Inc. PAH, Dioxins, etc)6.29E-03 lbs/yr Toluene 8.33E-03 lbs/yr Xylene 5.72E-03 lbs/yr Throughput (scf*1000/year)18,051 CO2 1,076.93 tons/yr Methane 0.02 tons/yr N2O 2.03E-03 tons/yr CO 0.76 tons/yr NOx 0.90 tons/yr TSP 0.07 tons/yr PM10 0.07 tons/yr PM2.5 0.07 tons/yr SO2 0.01 tons/yr VOC 0.05 tons/yr Benzene 3.79E-02 lbs/yr Formaldehyde 1.35E+00 lbs/yr Hexane, n-32.49 lbs/yr Toluene 6.14E-02 lbs/yr Throughput (scf*1000/year)3,243 CO2 193 tons/yr Methane 0.00 tons/yr N2O 0.00 tons/yr CO 0.14 tons/yr NOx 0.16 tons/yr TSP 0.01 tons/yr PM10 0.01 tons/yr PM2.5 0.01 tons/yr SO2 0.00 tons/yr VOC 0.01 tons/yr Benzene 0.00681 lbs/yr Formaldehyde 0.24322 lbs/yr Hexane, n-5.83737 lbs/yr Toluene 0.01103 lbs/yr Throughput (lbs/yr)14,273,876 TSP 0.01 tpy PM10 0.01 tpy PM2.5 0.01 tpy Throughput (lbs/yr)19,569,046 TSP 0.01 tpy PM10 0.01 tpy PM2.5 0.01 tpy Throughput (scf*1000/year)7 CO2 0.40 tons/yr Methane 7.51E-06 tons/yr N2O 7.51E-07 tons/yr CO 2.81E-04 tons/yr NOx 3.34E-04 tons/yr TSP 2.54E-05 tons/yr PM10 2.54E-05 tons/yr PM2.5 2.54E-05 tons/yr SO2 2.00E-06 tons/yr VOC 1.84E-05 tons/yr Benzene 0.00001 lbs/yr Formaldehyde 0.00050 lbs/yr Hexane, n-0.01202 lbs/yr Toluene 0.00002 lbs/yr Throughput (scf*1000/year)25,995 CO2 3,030.70 tons/yr Methane 0.03 tons/yr N2O 0.00 tons/yr NOx 1.30 tons/yr TSP 0.10 tons/yr PM10 0.10 tons/yr PM2.5 0.10 tons/yr SO2 0.01 tons/yr Benzene 0.05 lbs/yr Hexane, n-46.79 lbs/yr Toluene 0.09 lbs/yr Throughput (scf*1000/year)24,472 OS36-Urea Hopper for Reactor #8 OS33-Dowtherm Heater OS20-Natural Gas Usage for CatOx OS21-Natural Gas Usage for Thermal Oxidizer OS-47 Phenol Unloading OS55-NG Usage in Spray Dry Process OS27-Industrial Engines (Generators) OS3-NG/Propane Fired Boiler OS37-Temporary Boiler OS35-Urea Hopper for Reactor #3 OS-46 Phenol Storage Tanks Total Emissions (lbs) OS-13 Formaldehyde Raw Material Storage Tanks OS-29 UF/UFC Resin Storage Tanks OS-19 PF Resin Storage Tanks OS41-Process Water Storage Tanks OS-2 Resin Manufacturing CO2 1,503.43 tons/yr Methane 0.03 tons/yr N2O 2.75E-03 tons/yr TSP 0.09 tons/yr PM10 0.09 tons/yr PM2.5 0.09 tons/yr SO2 0.01 tons/yr Benzene 0.05 lbs/yr Hexane, n-44.05 lbs/yr Toluene 0.08 lbs/yr 1986 TSP 0.23 tons/yr PM10 0.23 tons/yr PM2.5 0.23 tons/yr 1986 TSP 0.23 tons/yr PM10 0.23 tons/yr PM2.5 0.23 tons/yr 1986 TSP 1.12 tons/yr PM10 1.12 tons/yr PM2.5 1.12 tons/yr 1980 TSP 0.15 tons/yr PM10 0.14 tons/yr PM2.5 0.12 tons/yr VOC 10.10 tons/yr 1989 TSP 0.21 tons/yr PM10 0.20 tons/yr PM2.5 0.16 tons/yr VOC 14.03 tons/yr 1980 TSP 8.26 tons/yr PM10 1.65 tons/yr PM2.5 0.41 tons/yr NOx 7.98 tons/yr PM10 (FIlterable)26.69 tons/yr PM2.5 (FIlterable)25.38 tons/yr SO2 0.06 tons/yr TSP 33.22 tons/yr VOC (as Carbon)82.63 tons/yr Note: BDL = Below Detection Limit sDATA - Total Summary Table Paved Roads (PR-1) OS51 - RM3 Extender Storage Silo (ES-11.1) OS52 - RM4 Extender Storage Silo (ES-11.2) OS50 - RESI-MIXER® (ES4.6) OS-48 Cooling Tower (ES-T1A) OS-49 Cooling Tower (ES-T3) �•-I • ..,. ____ t1' .. . .., ____ ,,. .... ·--,....j ------,.0,0 ��� we---- .__ ... .�, ... ... -.-, -_.,.,...,..,....""'-""'"''--I o7 c.': -���� --.., C,.l -���� CI.IIIQ.t?(lfrsf CT•• :':o'7;:._ 1------1 ()J1Mo1 C''r.t711),+1� .,_, -·� C-H�'<�f 1------ --4!.--N:--Hf�lc_f------j ,,.,,.,....,. ..� ,tN,�f'IO :� : ====�� == -::-� :� :: �1, : ==== :::!i = :: :.·: :: ..;-'°' lol tM-1 t0 ff,WD JU"O ----___ µu ------ --,01 Ill C... •O •. 110 l'llO ---� ___ -',L __ ----• ,t.u _ ---_u_ c-··-·-·-.. -•-1� ---_j,J_ � ,. 4ta ·-• -·-� ---�- � -··-____!!!_ � -IJ JJ1 C-,o 11• ,.,..., 1' -----,.,. _______ _•: J;!J c.-,, 1'AU n_m -------Ml� .. ------ -it ,:, � ,o n.-u ruu -------"-'----- -----Ill Ml.I C:-10 22.W J:lidil ------n,_ ------·-,u JoON C-Ill UW ZLW - -----!!'!. ... ---•---+---l •O .. fJ c:--,---;;-----lL• ---1-.,..-+,-... -1 ------_..__ __ l·--+--1--1 ,. c-U'W ------_.._ ---•---+---+--t II C-10 U'M fZJ,t 1G - ---._..__ --------��---,....a.I....:.�-··-�� .. 1n »o c-,e .a,na: •m ------- _!IL ------ ------""""L-1------< .. , ...... ,._ ♦ol 1t1, WO C-:,:I,� :IQ.not �,-------<---,-------_,._.._ ---•---,--... f'n.l'•l�'-1 1------f'0,111),WWf-· 1------1 .. , � ---.-'L'-..'.:'.. _ .. _ --"---1--1 ,., .a,, c-n-n--- -----1!L.. ---f--+---1 ,o,aa c-•t zz.• n.• ------_,,.__ ------»t ,01 C- 10 D4'18 2Ulf 1G ----->U. -----------IPl>,PII •••J:J ,-:,. ,,,_...., ,------...... .-. -.;, -c�-c:. ::�::::=--:':.. .--� "'"=-"'-"' �� c;_"'_;�.:.:i : :� .. ,.� .. ,W4IIIMII •"-"•--OIi a.)�... ,,; .. , ,., )'II c.... ,. zu• ZUMt ______ ...J!.L ______ _ ,,, c-io "" .,.,. -------'-'- ------•- � � ___ ....!.L. --•·-·•_,_ __ • _ __, .. .,, .... .,...MWI "--·-,.. c-. io zr� ::i:t..., 11 '°"° ,----➔------➔---,--- --- --"-'- ----1-----1-=:;··�-:;;;::::::-;;;:;:-;;::;:;;::·�-:;;::j:::·�·:::· =_.,_� ___ ....!ILL, c- ,. 11'.-11'.. 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It_ ____r,_ ---"'il2t �'M. t"'t-- t-1 -e-� -'!': --!! �� �--:� �� � _Jtl;IR_ ♦.00"', _Jf _.,,_ .....lll1!L.. �k._ _l,,NIII ... _ __,. -!"fL-�--1!';' � �-�,.,...,_ �� l-!!-�� _. ... -== =;; * -!-��-�� === � --:: -:::.� -�L-·� :::t== �= *� :r:ll.- �� ffll_ �� � ½!:-�r---t- .. ......__,,,,,. 5-•0flar-a...-..rl-lllrG S•14$b-._�,.,.._..._ 5-• t':b' ld:aorOnn� Ji".. -I: .J.lll•L �"--- ____.� �� :,,-� � � . ·-'� ::---....._ roi.r.1-t v-'"'"""'•' c..,.w �.,_ A ■ C tlMI �= 1 �i=1 Vear -,,-,:.!M_sj��l.f9.m,J�d..t....eJl.ru.i CataJv,jc Oxic:llur Stack Test da11d: Con- MeOH vusion Plant PollvUin1 loom! Ratio M•th.anol 23.0 1\.28 Formaldthyd• 23.0 11.28 RCI Act:taldt:hrde 23.0 11.28 Pla,it DME 23.0 11.28 VDC 23.0 11.28 co 23.0 11.28 Georgia•Paafic Resins 50% HCHO (tons/hr) 7 783 7 783 7.783 7.783 7.783 7.783 1,9.tZ < .. Ceilculeied Prod�n Ho1,111, beMd o,i 23gpm metl\enol f&edr,I& -<••2021RV Actual run bme . ··-·-·---OT Hours J f�"""!J 412612016 Oxidiz:■r Oxidizer lnSet Ot.1tJet DRE """''' 110/hrl 1%1 19.97 D.32D 96.-611!. 18.70 0.380 OS.0"° 2.87 0.0025 99.9% t0U7 2230 98.0% 131.4-4 281 98.0% 415.46 11'0 99.7% UncontroUed EmtSs.Rate f!OS11on1 2.57 2.40 0.37 14.12 1U9 53.38 t!Ot!Ol'l,illll1j 2•.2 •011 168.00 Res.Jn Plant 228 St)fl)'D�r 24,834 It Annual etnt1.s1ons lrom Byoasses In Ubs): Annual E11,;n1, � M•OH HCHO Acetafd• DME voe co Emlnlons ORE hyde IHOUr$I 0 52 90% .0 1.0 0.1 5.7 8-8 21.8 a 00 75% 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 ao 0,0 a.o 0.0 0.0 o.o 0.0 a.o o.a o.o o.o 0.0 0.0 0.0 0.0 0.0 0.0 Total 1 1 a • 7 22 NOTE: Th& Conway RCI ptocess ts Interlocked lo ptevflnt bypa&s of HCHO Plant ·--- -c.'ti ... St1011 flameout with minor Jow dett. T Longer ftameouts ""1th low dettl T Othor OtMr Othu Other CON_�1RY E!I SARA 313_Calcs_flNN.. Reportin g Year Location � :Ji ..,, -wl'.:.i-t, lli Fugitive Emissions Associated with Resin Solids Drying Pad Assumption s (this method is a best judgement estimate) Resin Drying Pad_Air (I) A conservative estimate of air emission losses from the plant resin drying pad can be developed based on simple index of lbs of pollutant per pound of material placed on pad. (2) Use Spray Dry Resins test data to represent the average consituents in the liquid resin. Data used is documented below (3)An average of the Taylorsville (2009) and Com,a} (2006) compound specific spray dry test results will be utilized to develop a generic index to be used by any facility that has a resin (4) Resin solids on the pad are generated from fully or partially reacted resin. The emission factors are based on liquid based resin (typically -37% solids & 63% liquid). (5) Per R&D suggestion, resin drying pad volatilization rates: Methanol (0.30); Formaldehyde (0.25) ; Phenol (0.1) l6) All data supporting these values are backed up in the Division's Spray Dryer Emissions Spreadsheet, tab "Division Summary Emission Factors".. The lbs/lbs emission factors are hidden Backgroun d information Emissions Factors devel oped from Divisional Test Data Plant Date of Test Liquid Resin Feed {type) MeOH (lbs / lbs wet feed) TAY Jan,09 351C05 0 002108203 CON Auq-06 217G77 0.003054484 CON AuQ-06 22C92 0.001767632 AVERAGE= 0.002310106 Resin and Resin Solids to Drying Pad Resins & Resin Solids to Drying Pad (lbs)= I Estimated % HCHO (lbs I lbs wet feed) 0.00030603 0.00064934 0.00021595 0.00039044 Provided bt' Decatur Phenol NH3 (lbs/ (lbs/ lbs lbs wet wet feed) feed) Chemical Volitalizati on Rate 4.37E-05 ��i. MeOH 30% 0 ''"it;'i:.-"'Jll� HCHO 25% 7.97E-05 0.000312 Phenol 10% 4.11 E-05 0.000312 Ammonia 100% estfmated estimated estimated worst case Percenta2e of Solids belived to contain MeOH 100%. 1 484 600 <-estmated % based on production [UF & PF]/[total Resin] Percenta2e of Solids belived to contain HCHO 100% 1,484,600 <-estmated % based on production [UF & PF]/[total Resin] Percentage of Solids belived to contain Phenol 100% 1,484,600 <-estmated % based on production [PF]/(total Resin) Percenta2e of Solids belived to contain Ammonia 50% 742,300 <--estmated % based on production [UF & PF)/{total Resin] n . � Drying Pad Chemical of Concern I Emission Factor I Volitalization Rate Adjustment for % Liquid ( 4) Air Emissions By Chemical lb/lb-Ii uid resin) % 10%/63%1 I (lb/yr' Methanol 0.002310106 30% 16% Formaldehyde 0.000390439 25% 16% Phenol 4. I I 238E-05 10% 16% Ammonia 0. 0003 I 2032 100% 16% Georgia-Pacific Chemicals LLC CON_2021RY_EI_SARA 313_Calcs_FINAL Phenol Railcar Unloading Phenol Railcar Emission Estimates: Temperature Vapor Pressure Emission Rate (OF) (PSI) (lbs/hr) 0.0195 0.091 110 0.0296 0.138 120 0.0440 0.205 130 0.0642 0.298 140 0.0920 0.428 150 0.1296 0.602 Total Phenol Emissions Per Railcar (lbs): Phenol Usage (lbs): Number of Railcars Unloaded Annually: Annual Phenol Emissions From Railcars (lbs): Notes: Emissions Estimated by EPA TANKS4.0 Software Program. Railcar dimensions are 48/eel by 9.5 feet. Railcar holds 185,000 (lbs) or 20,740 (gal) of phenol. Phenol is solid at I00F Railcars are equiped with steam jackets Time Emissions (Hours) (lbs) 1 0.091 1 0.138 1 0.205 1 0.298 1 0.428 1 0.602 1.762 .___1._76_2 _ __.l lbs. lbs. lbs. Georgia-Pacific Resins CON_2021 RY _EI_SARA 313_Calcs_FINAL Thrupul voe Emissions Methanol Emissions Thrupul MEK Emissions voe Emissions MEKNOC Emisston Fae.tor Thrupul Arnmonla Emsslons Emission Factor Pollutant Metnanot Fonnaldef\yde Ace\a1dehyde MeOH HCHO Phenol(BOL) Aeetaldehyde (BDL) Tnelhya,mine-(BDL) Stytene (BDL) CtHWl(BOl) Dim<e:thyi Ethet(OME) Nox Ammonia Fuvh�ve Sourcea-LOAR, Loading Rack•� Drying Pad Loadin Rac:k Emissions Summ MeOH Phenol EPI Ammonia MEK N•Bll1ano1 Cresols MIBK l�Pad Air Emissions Emission Faetot' lbllb-U uld rttln 0.002310\06 0.000390439 4.11238E-05 0.000312032 Cr�Obly,) F-aldehy<le Ob/yr) Melhanol Ob/yr) Phenol Ob/yr) Ammonia Ob/yr) MEK 0blyr) VQC I Emissions (lbs/ Summary Methanol Storage Tank (Operating Under Primary Scenario� 1 \ ,587 ,8S4 gallons 000 Ion/yr 0.OOE+OO I Chemical 163.31 23.00 097 36.77 108.1 S34_1 3.790.3 881.2 36.77 194.59 H� Fughlve Sources• LOAR:, etc rrom ,:ormaldetayde plant (lbs/yr) TJ,toughpul (Each) I H�O 150 Methanol 716 17,325 17,325 17,325 17,325 17,325 17,325 17,325 17,325 17,325 17,325 17.325 19,851 gallons 0.74 lb/yr 0.00 Ion/yr :l 7•E-05 11>1 allon 703,953 gallOflJ 27Ull lbs/'jr 1.5834E-03 lbs lion Emissk>n Fattor (lb/gal) \.95E-04 2.31E·04 \.53E 06 3.47E-07 7.94E-07 $698 Em1 .. 1ono (tonOlyrl Emluion •·actor (lb/lb) 2.852 -03 2.•50E-04 1.564E-05 6.517E-06 1.564E-05 1.434E-05 2.476E-05 I 145E-04 2 882E 04 9 233E-06 1141 6584E 04 ---------------- ----------05·2 Resin Ma nufacturmg TM,put Pollutant Methanol FormaldehydePhenol cd'jfonsr !'!211.� �Pl >fCL 110!:"llons Total Emissions (lbs) Emlssk>ns 1€56@ fl A®·ik54if W·Ufoiiti rhrupul Emissions Thrcughpu1 (gal/yr) HCHOpbs) MEOHpbs) VOC.flons Thrcughpu1 (gal/yr) HCHOPbs) MEOHPbs) Phenol Pbs) VOC Ions Thoughpu1 (gal/yr) HCHOpbs) MEOHpbs) Phenol pbs) voe ions Thtuput PloMol Pbsl voe ons Thrupul Phenol Qbs) voe ons Throughpu1 (strtOOOlyear) CO2 Methane N20 TSP PM10 PM2 5 S02 Benzel\6 11iu1;:ine, n Toluene ,._ 16'A11 0011!';+011 1 542,292 38.84 32.66 0.035 0S27 lndu�tnal E_ng,n�s (Generators} Throughpu1 (Gallons) CO2 co NOX TSP PM10 PM2 5 502 voe Acet;ldehyde Acro1e,n Benzene Formaldehyde Nap1halene (Component of POMTV) Pol)'cy<lic organic Matter (Int. PAI-I. Dioxins, ett) TOiuene Xylene 0S3-NGIPropane Fired 801ler Throughpu1 (scr 1000,'Jeari CO2 Metl'liloe N20 co NOx TSP PMtO PM2 5 S02 voe Benzene, Formaldehyde Hexane, n-Toluene 8 Kettles �nd 7 Weigh Tank, 324.298.106 lbs 2211.49 22.29 1.02 "lf C, �l� __ _,..,... 7.05E-07 4�.iltB,321 15.01 837.21 3.76 00 2,381,178 1.50 10 .31 0.60 0.01 8,312,830 gallons 1,002 57 0.50 78,473.113 lbs 740.04 0.37 120,048 mscf/yr 7181 89 Ions/yr 01 3 lonsfyr 001 tons/yr 22 81 tonstyr 2281 tonsr,, 2281 tons/yr 004 tonstyr 025 lbstyr 218.0B lbsfyr 0.,1 lbs,Yr 215 2.,2 tons/yr 0.01 tons,yr 0.05 tons/yr 9.19E·04 tonsl)'r 8.SOE·04 tons/yr 8.SOE 04 tons/yr 0.00 tons/yr 1.36E 03 1ons1yr 7.47E 04 lbs/yr 2.34E 04 lbs/yf 2.30E 02 lbs/yr 2 34E 03 lbs/yr 3.85E 03 lbs/yr 6.29E,03 lbsl)'r B.33E-03 lbSl)'r 5.72E 03 lbs/yr 18,051 1,076.93 tons/yr 0.02 tons/yr 203E-03 tonslys 076 tons/yr 0.90 tons/yr 0.07 tonslyr 007 lons/)lr 007 1D0$/IJT 0.01 tonsl)'r 0.05 Ion.,.,_., 3.79E•02 lbs/yr t 35E+OO lbs/yr 32.49 lbsl'fr B 14E-02 lbsl)'r 6.87E-OB 3.1 4E-09 2� 5��06 O.OOE•OO O.OOE+OO nn•:01 t..ltlllll> ,.010< �jl) 2.39E-05 212E-05 4.51E•OS Emission Fae.tar Ob/gaY;I 3.68E-07 2.0SE-05 9.22E-OB 2.097E•OS EmiSSIOO F1ct a,(lblg ai;I 6.JIE-07 4-JJE-06 2.S2E-07 5.214E 06 Emission Factor (lb/gJJIJ l.21E•04 l.21E•04 Emission Factor (1�1 9.43E-06 9.43E-06 0S37-Temporary Boiler co voe 0S33-Dowttierm Healer voe 7 2 o. voe NO• voe as Cal'bo1t Emission Equipment Description: Emission Unit ID No.: Maximum Ho urly Heat Input (MMBtu/hr): Annual Natural Gas Usage (set/yr): Annual Natural Gas Usage (MMBtu/yr): HHV of Natural Gas (Btu/sd): Criteria Emissions from the Boiler (ES-B1) Compound PM (Filterable) PM10/ PM2.5 (Condensable) PM10 (Total) PM2_5 (Total} NOx co S02 voe Lead (Pb) Total GHGb Total C0 2e b Permanent Boiler -OS-3 ES-Bl 25.1 18,051,215 18,412 1,020 Em1ss1on Factor" fib/MM Btu) l.86E-03 S.59E-03 7.45E-03 7.45E-03 9.BOE-02 8.24E-02 5.88E-04 S.39E-03 4.90E-07 116.98 117.10 219,876 Emission Rate c,d (lb/hr) (tpv) 0.05 0.02 0.14 0.05 0.19 0.07 0.19 0.07 2.46 0.90 2.07 0.76 0.01 0.01 0.14 0.05 1.23E-05 4.SlE-06 2,936 1,077 2,939 1,078 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Tables 1.4-1 and 1.4-2, converted from lb/MMscf to lb/MMBtuusing the heating value of 1,020 Btu/scf. PM 10 (Total) and PM 2 .s (Total) assumed the same and include both filterable plus condensable emissions. b.EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2. c.Emission Rate (lb/hr)= Emission Factor (lb/MMBtu) * Hourly Heat Input (MMBtu/hr) d.Emission Rate (tpy) = Emission Factor (lb/MMBtu) * Annual Heat Input {MM Btu/yr) * (ton/2,000 lb) HAP Emissions from the Bo iler (ES-B1) Compound Benzene Formaldehyde Hexane Naphthalene Polycyclic Organic Matter Toluene METAL HAP Arsenic Compounds Cadmium Compounds Chromium Compounds Cobalt Compounds Lead Compounds Manganese Compounds Mercury Compounds Nickel Compounds Em1ss1on Factor" (lb/MM Btu) 2.06E-06 7.35E-05 l.76E-03 5.98E-07 6.49E-07 3.33E-06 1.96E-07 l.08E-06 l.37E-06 8.24E-08 4.90E-07 3.73E-07 2.SSE-07 2.06E-06 Total HAP Emission Rate b,c (lb/hr) (tpy) 5.17E-05 l.90E-05 1.85E-03 6.77E-04 4.43E-02 0.02 1.SOE-05 5.SlE-06 1.63E-05 5.97E-06 8.37E-05 3.07E-05 4.92E-06 1.81E-06 2.71E-05 9.93E-06 3.45E-05 1.26E-05 2.07E-06 7.58E-07 1.23E-05 4.SlE-06 9.35E-06 3.43E-06 6.40E-06 2.3SE-06 5.17E-05 1.90E-OS 0.05 0.02 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4-4 for metal HAP, converted from lb/MMscf to lb/MM Btu using the heating value of 1,020 Btu/scf. b.Emission Rate (lb/hr)= Emission Factor (lb/MM Btu)* Hourly Heat Input {MM Btu/hr) c.Emission Rate (tpy) = Emission Factor (lb/MM Btu) • Annual Heat Input (MM Btu/yr) * (ton/2,000 lb) Emission Equipment Description: Emission Unit ID No.: Maximum Hourly Heat Input (MM Btu/hr): Annual Natural Gas Usage (sd/yr): Annual Natural Gas Usage (MMBtu/yr): HHV of Natural Gas (Btu/scf): Criteria Emissions from the Boiler (ES-B2) Compound PM (Filterable) PM 1o/PM 2_5 (Condensable) PM 10 (Tota l} PM2_5 (Total) NOx co SO2 voe Lead (Pb} Total GHGb Total CO2eb Temporary Boiler -OS-37 ES-B2 25 3,242,982 3,308 1,020 Emission Factor8 (lb/MM Btu) 1.86E-03 S.59E-03 7.4SE-03 7.4SE-03 9.B0E-02 8.24E-02 S.88E-04 S.39E-03 4.90E-07 116.98 117.10 Emission Rate c,d (lb/hr) (tpy) 0.05 3.08E-03 0.14 9.24E-03 0.19 l.23E-02 0.19 1.23E-02 2.45 1.62E-01 2.06 l.36E-01 0.01 9.73E-04 0.13 8.92E-03 1.23E-0S 8.llE-07 2,924 193 2,927 194 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Tables 1.4-1 and 1.4-2, converted from lb/MMscf to lb/MMBtuusing the heating value of 1,020 Btu/set. PM10 (Total) and PM2_5 (Total) assumed the same and include both filterable plus condensable emissions. b.EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2. c.Emission Rate (lb/hr)= Emission Factor (lb/MM Btu)* Hourly Heat Input (MMBtu/hr) d.Emission Rate (tpy) = Emission Factor (lb/MM Btu) * Annual Heat Input (MMBtu/yr) * (ton/2,000 lb) HAP Emissions from the Boil er (ES-B2) t.m1ss1on Emission Rate b,, Compound Factor8 (lb/MMBtu) (lb/hr) (tp y) Benzene 2.0GE-06 S.lSE-05 3.41E-06 Formaldehyde 7.3SE-0S 1.84E-03 1.22E-04 Hexane 1.76E-03 4.41E-02 2.92E-03 Naphthalene S.98E-07 l.S0E-05 9.89E-07 Polycyclic Organic Matter 6.49E-07 1.62E-05 1.07E-06 Toluene 3.33E-06 8.33E-05 S.SlE-06 METAL HAP Arsenic Compounds 1.96E-07 4.90E-06 3.24E-07 Cadmium Compounds 1.08E-06 2.70E·OS 1.78E-06 Chromium Compounds 1.37E-06 3.43E-05 2.27E-06 Cobalt Compounds 8.24E-08 2.0GE-06 1.36E-07 Lead Compounds 4.90E-07 1.23E-05 8.llE-07 Manganese Compounds 3.73E-07 9.31E-06 6.16E-07 Mercury Compounds 2.SSE-07 6.37E-06 4.22E-07 Nickel Compounds 2.0GE-06 S .lSE-05 3.41E-06 Total HAP 0.05 3.06E-03 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4-4 for metal HAP, converted from lb/MMscf to lb/MM Btu using the heating va1ue of 1,020 Btu/scf. b.Emission Rate (lb/hr)= Emission Factor (lb/MM Btu) * Hourly Heat Input (MM Btu/hr) c.Emission Rate (tpy) = Emission Factor (lb/MMBtu} * Annual Heat Input (MM Btu/yr) * (ton/2,000 lb) Emission Equipment Description: Emission Unit ID No.: Diesel Engines -OS-27 ES-GENl Maximum Hourly Heat Input (hp/hr): 755 Fuels Fired: Diesel Annual Heat Input (hp/yr): 4,236 Criteria Emissions from the Diesel-Fired Generator (ES-GEN1) Compound Emission Factor" (lb/hp-hr) PM (Filterable) 4.34E-04 PM10 (Total} 4.0lE-04 PM2.5 (Total) 4.0lE-04 NOx 2.40E-02 co 5.S0E-03 SO2 l.21E-05voe 6.42E-04 Total GHGb 1.14 Total CO2eb 1.15 ' Emission Rate c,d (lb/hr) (tpy) 0.33 9.19E-04 0.30 8.50E-04 0.30 8.50E-04 18.12 0.05 4.15 0.01 9.16E-03 2.57E-05 0.48 l.36 E-03 862 2.42 865 2.43 a.Compounds other than Particulate emissions from AP-42 Section 3.4, Large Stationary Diesel and All Stationary Duel-fuel Engines (October 1996), Table 3.4-1. Diesel fuel sulfur content(%} 0.0015 Particulate emissions per AP-42 Section 3.4, Large Stationary Diesel and All Stationary Duel-fuel Engines (October 1996), Table 3.4-2, converted from lb/MM Btu to lb/hp-hr using an average brake specific fuel consumption (BSFC) of 7,000 Btu/hp-hr from AP-42, Section 3.3, Table 3.4-1. PM 10 (Total) and PM 2_5 (Total) assumed the same and include both filterable plus condensable emissions. b.GHGs from EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2, converted from lb/MM Btu to lb/hp-hr using an average brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr from AP-42, Section 3.3, Table 3.3-1. c.Emission Rate (lb/hr)= Emission Factor (lb/hp-hr) * Engine Rating (hp) d.Emission Rate (tpy) = Emission Rate (lb/hr)* Hours of Operation {hr/yr)• {ton/2,000 lb} HAP Emissions from the Diesel-Fired Generator (ES-GEN1) Compound Emission Factora {lb/hp-hr) Acetaldehyde 1.76E-07 Acrolein 5.52E-08 Benzene 5.43E-06 Formaldehyde S.52E-07 Naphthalene 9.l0E-07 Polycyclic Organic Matter l.48E-06 Toluene l.97E-06 Xylenes (Mixed Isomers) 1.35E-06 Total HAP Emission Rate b,c (lb/hr) (tpy) l.33E-04 3.74E-07 4.16E-05 l.17E-07 4.lOE-03 l.lSE-05 4.17E-04 l.17E-06 6.87E-04 1.93E-06 l.12E-03 3.14E-06 1.49E-03 4.17E-06 l.02E-03 2.86E-06 9.0lE-03 2.53£-05 a.AP-42 Section 3.4, Large Stationary Diesel and All Stationary Duel-fuel Engines (October 1996}, Table 3.4-3, converted from lb/MM Btu to lb/hp-hr using an average brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr from AP-42, Section 3.4, Table 3.4-1. Emission Equipment Description: Emission Unit ID No.: Control Device Description: Maximum Methanol Feed Rate: Average Conversion Ratio: Maximum Hourly HCHO Production Rate: Maximum Annual HCHO Production Rate: Maximum Hourly Heat Input: Annual Natural Gas Usage (sd/yr): Annual Natural Gas Usage (MMBtu/yr): HHV of Natural Gas: Formaldehyde (HCHO) Manufacturing Process (VS2A) • Natural Gas Combustion Only Formaldehyde Production Process (ES-2) Formaldehyde Tank Truck Loading Rack (ES·FL) One Methanol Storage Tank (ES3Ml) Eight Formaldehyde/Methanol Storage Tanks (ES7Fl-F8) Catalytic Oxidizer (CD-2A) 32 gallons per min (gpm) 11.28 lbs. 50% HCOH/gallon MEOH 10.83 74,168 4.0 25,995,073 26,515 1,020 tons/hr tons/yr MMBtu/hr Btu/scf Criteria Emissions h rom t e Formal d h d e ,y e Manu acturing Process Nb Em1ss1on Process Compound Factor• Related b (lb/MM Btu) (lb/ton) PM (Filterable) l.86E-03 .. PM 1o/PM 25 (Condensable) S.59E-03 .. PM 10 (Total) 7.45E-03 .. PM2 .5 (Total) 7.45E-03 .. NOx 9.80E-02 .. S0 2 5.88E-04 Lead (Pb) 4.90E-07 Total GHG0 116.98 39.91 Total co2e• 117.10 39.91 Emission Rate d,e !lb/hr)(tnvl 0.01 0.02 0.02 0,07 0.03 0.10 0.03 0.10 0.39 1.30 2.35E-03 0.01 l.96E-06 6.SOE-06 900 3,031 901 3,032 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Tables 1.4·1 and 1.4-2, converted from lb/M Mscf to lb/M MB tu using the heating value of 1,020 Btu/scf. PM 10 (Total) and PM 2•5 (Total) assumed the same and include both filterable plus condensable emissions. b. Emission factors based on Stack Test dated 4/26/2016. c. EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C·l and C-2. d.Emission Rate (lb/hr)= Emission Factor (lb/MM Btu)• Hourly Heat Input (MMBtu/hr) Emission Rate (lb/hr) = Emission Factor (lb/ton) • Hourly HCHO Production Rate (ton/hr) • (1 • DRE(%)) e.Emission Rate (tpy) = Emission Factor (lb/MMBtu) • Annual Heat Input (MMBtu/yr) • (ton/2,000 lb) Emission Rate (tpy) = Emission Factor (lb/ton) • Annual HCHO Production Rate (tons/yr) • (ton/2,000 lb) • (1-DRE(%)) HAP Emissions from t e Formalde 1y, e Manu acturing Process h h d Nb Em1ss1on Process Emission Rate b.c Compound Factor" Relatedb (lb/MMBtul (lb/ton) llb/hrl (tpvl Benzene 2.0GE-06 ..8.24E-06 2.73E-OS Hexane 1.76E-03 7.0GE-03 0.02 Naphthalene 5.98E•07 --2.39E-06 7.93E-06 Polvcvclic Organic Matter 6.49E-07 ..2.GOE-06 8.GOE-06 Toluene 3.33E-06 .. 1.33E·OS 4.42E·OS METAL HAP Arsenic Compounds 1.96E-07 .. 7.84E-07 2.GOE-06 Cadmium Compounds 1.08E-06 ..4.31E-06 1.43E-OS Chromium Compounds 1.37E-06 --5.49E-06 1.82E-OS Cobalt Comoounds 8.24E-08 -·3.29E-07 1.09E-06 Lead Comoounds 4.90E-07 --1.96E·06 6.SOE-06 Man2anese Comoounds 3.73E-07 .. 1.49E-06 4.94E-06 Mercurv Compounds 2.SSE-07 --1.02E-06 3.38E-06 Nickel Compounds 2.0GE-06 -·8.24E-06 2.73E-OS Total HAP 0.01 0.02 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4·4 for metal HAP, converted from lb/MMscf to lb/MMBtu using the heating value of 1,020 Btu/scf. b.Emission Rate (lb/hr)= Emission Factor (lb/MMBtu) • Hourly Heat Input (MMBtu/hr) c. Emission Rate (tpy)" Emission Factor (lb/MMBtu) • Annual Heat Input (MM Btu/yr)• (ton/2,000 lb) Emission Equipment Description: Emission Unit ID No.: Control Device Description: Maximum Hourly (UF + PF) Resin Production Rate: Maximum Annual Resin Production Rate: Maximum Hourly Heat Input: Annual Natural Gas Usage (scf/yr): Annual Natural Gas Usage (MM Btu/yr): HHV of Natural Gas: Resin Manufacturing Process (VS4A.l & VS4A.2] -Emissions From Natural Gas Combustion Only TP-n Resin Vessels including Four batch non-reactor vessels which includes- Three Weigh Tanks (ES4.9 -4.11 and one Mix/Blend Tank (S-13) and six Batch Reactor Vessels ( ES4.1 through 4.3, ES4.5, ES4. 7, & ES4.81 Alternate Compliance Scenario One Methanol Storage Tank (ES3Mll Eight Formaldehyde/Methanol Storage Tanks {ES7Fl-F8 ) Thermal Oxidizer (CD-4A) 38 tons/hr 162,149 tons/yr 2.9 MM Btu/hr 24,471,733 24,961 1,020 Btu/scf CI I E •• r ter a m1ss1ons rom e esin anu actur nl! th R . M p rocess ""' tm1ss1on Process Emission Rate d,• Compound Factor• Related• (lb/MMBtu) (lb/ton Resinl (lb/hr) PM (Filterable\ 1.86E-03 --0.01 PM1o/PM 2_5 (Condensable) S.59E-03 .. 0.02 PM10 (Total) 7.45E-03 --0.02 PM2.s (Total) 7.45E-03 --0.02 S02 S.SSE-04 1.71E-03 Lead (Pb) 4.90E-07 1.42E-06 Total GHG' 116.98 S.36E-01 359 Total C02e' 117.10 S.36E-Ol 360 a.AP-42 Section 1.4, Natural Gos Combustion (July 1998), Tables 1.4-1 and 1.4-2, converted from lb/MMscf to lb/MM Btu using the heating value of 1,020 Btu/scf. (tovl 0-02 0.07 0.09 0.09 0.01 6.12E-06 1,503 1,505 PM 10 (Total I and PM 2•5 (Total) assumed the same and include both filterable plus condensable emissions. b.Emission factors based on Stack Test dated 4/26/2016. c.EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2. d.Emission Rate (lb/hr)= Emission Factor (lb/MMBtu) • Hourly Heat Input {MM Btu/hr) Emission Rate (lb/hr)= Emission Factor (lb/ton)• Hourly (UF + PF) Resin Product,on Rate {ton/hr) • (1 -ORE(%)) e.Emission Rate (tpy) = Emission Factor (lb/MMBtu) • Annual Heat Input (MMBtu/yr) • {ton/2,000 lb) Emission Rate (tpy) = Emission Factor (lb/ton)• Annual (UF + PF) Resin Production Rate (tons/yr)• (ton/2,000 lb)• (1 -DRE(%)) HAP Em1ss1ons f h romt e Resin Manu acturing Process rtu cm1ss1on Compound Factor• Process Related Emission Rate b,c llb/MMBtu) (lb/ton) (lb/hr) Benzene 2.06E-06 --S.97E 06 Hexane 1.76E-03 S.l2E-03 Naphthalene 5.98E-07 --1.73E-06 Po[vrvclic On1anic Matter 6.49E-07 --1.88E-06 Toluene 3.33E-06 --9.67E-06 METAL HAP Arsenic Compounds 1.96E-07 ..S.69E-07 Cadmium Compounds 1.0SE-06 ..3.13E-06 Chromium Compounds 1.37E-06 --3.98E-06 Cobalt Comoounds 8.24E-08 --2.39E-07 Lead Comoounds 4.90E-07 --1.42E-06 Manl!anese Comoounds 3.73E-07 --1.0SE 06 Mercurv Compounds 2.SSE-07 -7.39E-07 Nickel Compounds 2.0GE-06 -5.97E-06 Total HAP 0.01 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4-4 for metal HAP, converted from lb/MMscf to lb/MMBtu using the heating value of 1,020 Btu/scf. b.Emission Rate (lb/hr) = Emission Factor (lb/MMBtu) • Hourly Heat Input (MMBtu/hrl c. Emission Rate (tpy) = Emission Factor (lb/MMBtu) • Annual Heat Input (MMBtu/yr) • (ton/2,000 lb) (tpy) 2.57E-05 0.02 7.46E·06 8.lOE-06 4.16E-05 2.45E-06 1.35E-05 1.71E-OS 1.03E-06 6.12E-06 4.6SE·06 3.lSE-06 2.57E-05 o.oz Emission Equipment Description: Emission Unit ID No.: Control Device Description: Maximum Hourly Heat Input: Annual Natural Gas Usage (scf/yrl: Annual Natural Gas Usage (MMBtu/yr): Fuels Fired: HHV of Natural Gas: Bagfilter (CD·SA) flowrate Annual Hours of Operation: Spray Dry Resin Manufacturing Process (VSSA) • Emissions From Natural Gas Combustion Only Spray Dry Resin Process (ES·S) Including Natural Gas Fired Atomizing Air Heater Spray Dryer Several Transfer Cyclones and a Product Bagging Operation Bagfilter (CO-SA) 14.6 MM Btu/hr 120,045.956 122,447 Natural Gas 1,020 65,000 8,188 Btu/scf dscfm hr/yr Criteria Emissions from the Sorav Orv Resin Manufacturing Process Nb Em1ss1on Process Emission Rate d.• Compound Factor• Related b llb/MMBtul lib/ton) llb/hr) PM/PM 1o/PM2.s .. 0.01 gr/dscf 5.57 S02 5.88E-04 8.59E 03 Lead (Pb) 4.90E-07 7.16E -06 Total GHG" 116.98 ..1,708 Total C02e" 117.10 .. 1,710 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Tables 1.4-1 and 1.4-2, converted from lb/MMscf to lb/MM Btu using the heating value of 1,020 Btu/scf. (tpy) 22.81 0.04 3.00E-05 7,162 7,169 CO and NOx emissions from the natural gas combustion were included with process emissions calculations. b.PM/PM 1of PM zs emission factors based on engineering estimate. c.EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2. d.Emission Rate (lb/hr)= Emission Factor (gr/dscf) • Maximum Air Flow Rate (dscfm) • (lb/7,000 grl • (60 min/hr) Emission Rate (lb/hr)= Emission Factor (lb/MM Btu)• Hourly Heat Input (MMBtu/hr) Emission Rate (lb/hr) = Emission Factor (lb/ton) • Hourly Dry Resin Production Rate (ton/hr) e.Emission Rate (tpy) = Emission Factor (gr/dscf) • Maximum Air Flow Rate (dscfm) • (lb/7,000 gr)• (ton/2,000 lb)• (60 min/hr)• (8,760 hr/yr} Emission Rate (tpy) = Emission Factor (lb/MM Btu)• Annual Heat Input (MM Btu/yr)• (ton/2,000 lb) HAP Emissions h rom t e Spray Dry Resin Manu acturing p rocess NU Em1ss1on Compound Factor• llb/MMBtul Benzene 2.06E·06 Hexane l.76E-03 Naphthalene 5.98E-07 Polvcvclic OrRanic Matter 6.49E-07 Toluene 3.33E-06 METAL HAP Arsenic Compounds l.96E-07 Cadmium Compounds l.OSE-06 Chromium Compounds ·1.37E-06 Cobalt Compounds 8.24E-08 Lead Comoounds 4.90E-07 ManRanese Compounds 3.73E-07 Mercury Compounds 2.SSE-07 Nickel Compounds 2.06E-06 Process Related llb/tonl .. .. .. .. .. .. ·- .. .. -- .. ·- .. Total HAP Emission Rate b,c !lb/hr)(tpvl 3.0lE-05 1.26E-04 2.58E-02 l.OSE-01 8.73E-06 3.66E-05 9.47E-06 3.97E-05 4.87E-OS 2.04E-04 2.86E-06 1.20E-05 1.57E-OS 6.60E-05 2.00E-05 8.40E-05 1.20E-06 5.04E-06 7.16E-06 3.00E-05 S.44E-06 2.28E-05 3.72E-06 l.56E-05 3.0lE-05 1.26E-04 0.03 0.11 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4-4 for metal HAP, converted from lb/MMscf to lb/MM Btu using the heating value of 1,020 Btu/scf. b.Emission Rate (lb/hr)= Emission Factor (lb/MM Btu)• Hourly Heat Input (MMBtu/hr) c.Emission Rate (tpy) = Emission Factor (lb/MM Btu) • Annual Heat Input (MM Btu/yr)• (ton/2,000 lb) Emission Equipment Description: Emission Unit ID No.: Maximum Hourly Heat Input (MM Btu/hr): Annual Natural Gas Usage (scf/yr): Annual Natural Gas Usage (MMBtu/yr): HHV of Natural Gas (Btu/scf): Natural Gas fired Heat Transfer Fluid Heater ES-HTF 2.3 6,680 6.81 1,020 Criteria Emissions from the Heat Transfer Fluid Heater (1-HTF) Em1ss1on Compound Factora (lb/MM Btu) PM (Filterable) l.86E-03 PM 10 / PM 2.5 (Condensable) 5.59E-03 PM10 (Total) 7.45E-03 PM2 •5 (Total) 7.4SE-03 NOx 9.80E-02 co 8.24E-02 SO2 5.88E-04 voe S.39E-03 Lead (Pb) 4.90E-07 Total GHG b 116.98 Total CO2eb 117.10 Emission Rate c,d (lb/hr) (tpy) 4.28E-03 6.35E-06 1.29E-02 1.90E-05 1.71E-02 2.54E-05 1.71E-02 2.54E-05 2.25E-01 3.34E-04 1.89E-01 2.81E-04 l.35E-03 2.00E-06 1.24E-02 1.84E-0S l.13E-06 1.67E-09 269 0.40 269 0.40 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Tables 1.4-1 and 1.4-2, converted from lb/MMscf to lb/MMBtuusing the heating value of 1,020 Btu/set. PM 10 (Total) and PM2.5 (Total} assumed the same and include both filterable plus condensable emissions. b.EPA's Mandatory Reporting Rule for Greenhouse Gases, 40 CFR Part 98, Subpart C, Tables C-1 and C-2. c.Emission Rate (lb/hr)= Emission Factor (lb/MMBtu) * Hourly Heat Input {MM Btu/hr) d.Emission Rate {tpy) a: Emission Factor {lb/MMBtu) * Annual Heat Input (MM Btu/yr) * (ton/2,000 lb) Potential HAP Emissions from the Heat Transfer Fluid Heater (1-HTF) Compound Benzene Formaldehyde Hexane Naphthalene Polycyclic Organic Matter Toluene METAL HAP Arsenic Compounds Cadmium Compounds Chromium Compounds Cobalt Compounds Lead Compounds Manganese Compounds Mercury Compounds Nickel Compounds Em1ss1on Factora (lb/MMBtu) 2.06E-06 7.3SE-0S 1.76E-03 S.98E-07 6.49E-07 3.33E-06 1.96E-07 1.08E-06 1.37E-06 8.24E-08 4.90E-07 3.73E-07 2.SSE-07 2.06E-06 Total HAP Emission Rate b,c (lb/hr) (tpy) 4.74E-06 7.0lE-09 l.69E-04 2.S0E-07 4.06E-03 6.0lE-06 1.38E-06 2.04E-09 1.49E-06 2.21E-09 7.67E-06 1.14E-08 4.SlE-07 6.68E-10 2.48E-06 3.67E-09 3.16E-06 4.68E-09 l.89E-07 2.81E-10 l.13E-06 1.67E-09 8.57E-07 1.27E-09 S.86E-07 8.68E-10 4.74E-06 7.0lE-09 4.26E-03 6.30E-06 a.AP-42 Section 1.4, Natural Gas Combustion (July 1998), Table 1.4-3 for organic HAP and Table 1.4-4 for metal HAP, converted from lb/MMscf to lb/MM Btu using the heating value of 1,020 Btu/scf. b.Emission Rate (lb/hr)= Emission Factor {lb/MMBtu) * Hourly Heat Input (MM Btu/hr) c.Emission Rate (tpy) a: Emission Factor (lb/MMBtu) * Annual Heat Input (MM Btu/yr) * (ton/2,000 lb) Emission Equipment Description, Emission Unit ID No.; PRODUCTION/OPERATION DATA Bin Vent Filter [CD·UH-K3) flowrate Bin Vent Filter [CO-UH-K8) flowrate Annual Hours of Operation Criteria Emissions from U F Resin Additives Source Urea Unloadin� Hoooer CES·UH·K3l • OS-35 Urea Unloadine Ho ooer /ES·UH-K8l • 0S-36 UF Resin Additives Urea Unloading Hopper (ES·UH·K3) OS 35 Urea Unloading Hopper (ES-UH-KB) OS 36 1,200dscfm 1,200dscfm ZBB hriyr Control Device ID CD·UH·K3 CD•UH•K8 Emission Factor (gr/dscf)" llb/hr\ 0.01 0.10 0.01 0.10 a. PM/PM1o/PM2 , emission factors based on engineering estimate. Controlled Emission Rates'·' PM PM 10 I lt.,vl (lb/hr) I (tnvl I 0.10 I 0.01 I 0.01 0.10 I 0.01 b. Emission Rate (lb/hr)= Emission Factor (gr/dscf) • Maximum Air Flow Rate [dscfm) • [lb/7,000 gr)• [60 min/hr) (lb/hr) 0.10 0.10 c. Emission Rate (t py l = Emission Factor [gr/dscf) • Maximum Air Flow Rate [dscfm} • (lb/7,000 gr) • (ton/2,000 lbl • (60 min/hr) • (8,760 hr/yr) Thoughput 12,054,380 13,378,630 PM2_5 l (tnvl 0.01 0.01 Total Urea hr/yr 25,433,009 288.36 Emission Equipment Description: Emission Unit ID No.: PRODUCTION/OPERATION DATA Bin Vent Filter {C0-11.1) flowrate Bin Vent Filter {CD-11.2) flowrate Bin Vent Filter {CD-11.6) flowrate Annual Hours of Operation RESl•MIX• Manufacturing RM3 Extender Storage Silo (ES-11.1) RM4 Extender Storage Silo (ES•ll.2) RESl•MIXER• (ES4.6) 800 dscfm 800 dscfm 3,840 dscfm �781 hr /yr Criteria Emissions from UF Resin Additives Emlsslon Control Device Source Factor ID (gr/dscf)• llb/hrl RM3 Extender StoraRe Silo (ES-11.ll CD-11.1 0.01 O.Q7 RM4 Extender Storage Silo (ES-11.2) CD-11.2 o.oi 0.07 RESI-MIXER• (ES4.6l CD-11.6 0.01 0.33 a.PM/PMw'PM2.s emission factors based on engineering estimate. Controlled Emission Rates b,, PM PM10 PM2.s (tnvl Clb/hrl (tpy) (lb/hr) 0.23 O.o7 0.23 0.07 0.23 0.07 0.23 0.07 1.12 0.33 1.12 0.33 b.Emission Rate (lb/hr)= Emission Factor (gr/dscf) • Maximum Air Flow Rate (dscfm) • (lb/7,000 gr) • (60 min/hr) (tpy) 0.23 0.23 1.12 c.Emission Rate {tpy) = Emission Factor (gr/dscf] • Maximum Air Flow Rate (dscfm) • (lb/7,000 gr)• [ton/2,000 lb)• (60 min/hr)• (8,760 hr/yr) Emission Equipment Description: Emission Unit ID No.: OPERATION DATA Circulation Rate: Total Dissolved Solids: Drift Factor: Drew 2105 Concentration•: Drew 2105% voe•: Annual Hours of Operation: Cooling Tower ES-TlA 7,200 gpm 960 ppm 0.001% 100 ppm 0.64% 8,760 hr/vr a.Based on the data provided by the manufactuerer. Emissions Calculations Pollutant Emission Factor a,b Emission Rate (lb/gal) (lb/hr) (tpy) PM 8.0lE-08 0.03 0.15 PM10 --0.03 0.14 PM2 .s --0.03 0.12 voe 5.34E-06 2.31 10.10 a.PM Emission Factor= Density of Water (lb/gal)* Drift Factor(%)• Total Dissolved Solids (ppm)/ 106 voe Emission Factor= Density of Water (lb/gal) • Drew 2105 voe Concentration (ppm)/106 • Drew 21055 % voe(%) b.PM10 and PM2_5 speciation based on EPA PMCALC speciation. Reisman and Frisbie values not provided for TDS below 1,000 ppm. PM10 =94% PM PM2 .s =78% PM Emission Equipment Description: Emission Unit ID No.: OPERATION DATA Circulation Rate: Total Dissolved Solids: Drift Factor: Drew 2105 Concentration• Drew 210s % voe• Annual Hours of Operation: Cooling Tower ES-T3 10,000 gpm 960 ppm 0.001% 100 ppm 0.64% 8,760 hr/vr a.Based on the data provided by the manufactuerer. Emissions Calculations Pollutant Emission Factor a,b Emission Rate (lb/gal) (lb/hr) (tpy) PM 8.0lE-08 0.05 0.21 PM 10 --0.05 0.20 PM2.s --0.04 0.16 voe 5.34E-06 3.20 14.03 a.PM Emission Factor= Density of Water (lb/gal)* Drift Factor (%)• Total Dissolved Solids (ppm)/ 106 voe Emission Factor= Density of Water (lb/gal) * Drew 2105 voe Concentration (ppm)/106 * Drew 21055 % voe(%) b.PM10 and PM2.s speciation based on EPA PMeALe speciation. Reisman and Frisbie values not provided for TDS below 1,000 ppm. PM10= 94% PM 78% PM Emission Unit 01ucripUon: P1ved Ro1ds (PR·ll Road Se1menl Data Road se-ame-nt Paved/Unpaved A B C D Pavt'd Pavfl'd Paved Poved True• Traffic Del.alls• Potenllal Lenctti 1ml) Trucks 0 36 Urt-1/Ammonl.a/Re,jn Addmvu 0.38 c,ustk/Methanol 0.40 Spr.ayOry/Ware�•e 0.46 Resin. Miscelbneous Truck Wel1ht1 A.ve-r.ase Truck ltons) TruckWei.1,ht N1,1mberof Unloaded loaded (1ons1 TIU<ltSJ u,ea/Ammonla/Resln Additives 15 40 27.S 506 Caustic 15 40 275 347 Methanol lS 40 2H l,428 �pray Ory 15 40 27S 764 Warehouse 15 40 27.S 520 Resin 15 40 27.S 6,440 Miuelbneous 15 40 27S 520 1. l,uck weight b.asNI on eng.lnffflna: �timate1.. 2. Numbe1 of trucks b.ased on rncJneering estimate. Fleet Mean Emb,lon Futor1 Sesmient W11Jht PM PMao PM._. VMT fto.,sl (lb/VMT) llbNMn Ub/VMTI Paved A 27.5 2.00 0.4, 0.1):)8 364 B 27.S 2.00 0.40 0.098 1.349 C 27.5 2.00 0.40 0.008 l.<ll1 0 27.S 2.00 0.40 0.098 640, Total Emissions l. P•ved route emi'Hlon factor is b•scd an Equation 2 of AP--42 Section 13 2.1 (J.anuary 2011): E = [k x (sl )"' x (w )' u.t ]x ( I 4� ) E • sl.te specific emission h1ct01 (lb/VMT] Routes Re1.in 8.ad: g.ate in/Sad, gate out Resin fronl g.ale In/Front 1,.ate out Spray Dry 1ate ln/Spcay Ory 1alt'OUl kesin Back Gate In/Front Gate· out Route1, Traveled A B C D t i I t , t 2 Emlsslons:I PM PM,. llb/hrl Uovl llb/hrl ltovl 0.08 0.33 0.02 0.07 0 31 1.22 0.06 0.24 0.23 0.93 0.05 0.19 1.46 5.78 0.29 116 2.09 8.26 0.42 1.65 PMu Hb/h,l Uovl o.oo 0.02 0.02 0.06 0.01 0.05 0.07 0.28 0.10 0.41 Ir.• O.Oll (PMI �nide size multipliier for panlde sire nnee �nd uniu,of lnterHt. AP-42. St-ctlOn 13.l.l, Tabte 13.2.1•1. 0.0022 (PMI0) 0.00054 (PM2 SI sl • 7.4 ro•d surface silt ki•d<ln,: �m tl, based on th,e va\Jefor mun •if>al �td wutet.andfi'h in AP-42 Se-ction 13.2 1. Tible 13.21 3 W = mHn v�hicle wei1h1 (1om-J P• 140 number of da�in th .ave,.agingperiod with at leutei.2S4mm [O.Olln .of pre(lpitaUon..AP-42 Section 13.2 1, flsure 13 2 1·1 N • 36S number of days. In the avenging period (e.e., 36S fDf' annual� Note that rain correction f�<tor (1·P/4N)only appl�s to annual, n01 hourfyemlssk>ns. 2. EmissioAs ufculated from emlss.lon facto, times VMT per route. Hourly emission, an:ume 8,760 hours of opera.�