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AQ_F_3200144_20220815_EI_Cmb-EI-File_2021 EI
2021 Emissions Inventory Review / Data Tracking Form Facility Name: Duke University Facility Classification: Title V Assigned to: Jeff Harris Data Entry: Durham County Confidential Copy Submitted? YES NO Enter date received into ED. Date Received: _________________ Assigned to appropriate individual. Date Assigned: _________________ Date Due: __________________ Paper copy submitted: One copy received with supporting documentation, certification form signed by responsible official, and appears generally complete; OR Electronic copy submitted: All supporting documentation and certification form (with time/date stamp) signed by responsible official has been received. Comments: Facility ID: 3200144 Initial Review / Data Entry Inventory Review All forms and supporting documentation appear to be complete if paper submission (check ED OS data if electronic). Contact, address, phone number changes entered into I-Beam/Facilities if necessary. All known operating scenarios, control devices, and emission release points have been entered for each emission source (permitted, insignificant, and unpermitted) or note that the emission source was not operated or not required to report. Check if SCC codes for each OS are accurate and update if needed. Evaluate "U" sources for significance and address according to policy. Calculations / forms appear to add up correctly. All compliance issues are being addressed (e.g. Toxics limits, above TV thresholds, large emissions increase/decrease, installation without a permit). All volatile HAPs/TAPs were included in the VOC total. Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for the reporting facility (e.g. stack testing, AP-42, etc.). Review facility comments and address any issues. Update ED (Data Entry Main) if additional information is required (corrections due date and date received). Check all ED QA/QC reports. Comparison with previous emission inventory must be made and outliers (> 10%) must be investigated and explained. Put inventory review comments and summarize any changes in ED - Data Entry Main "DAQ internal comments". Date Info Requested: ______________ Date Info Received: ______________ Total Days on Hold: ______ Date Review Complete: ___________________ Signature: _____________________________ Date Submitted to EI Coordinator: ___________________ Date Approved: ___________________ Initials: ___________________ decrease in throughput for NG boilers and generators. ~13% decrease in Criteria pollutants & combustion products largely due to corresponding 08/03/2022 Wes Brummer 08/12/2022 08/15/2022 Duke University 03254T43 3200144 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Pollutant CAS Green House Gases Pollutants (GHG)Actual Emissions Tons/Yr % ChangeDemini- mus Not Reported Not Reported N/A CO2 equivalent (sum of individual GHG pollutant emission times their 1995 IPCC Global Warming Potential (GWP), converted to metric tons) No GHGs Reported Criteria Pollutants CY 2021 from ED CY 2020 from Fees (Tons/Year) Actual Emissions % ChangePollutantCASDemini- mus -11.6%78.8469.66CO 0.5CO -12.6%74.5565.13NOx 0.5NOx -13.5%1.331.15TSP 0.5PM(TSP) -12.2%1.311.15PM10 0.5PM10 -13.8%1.231.06PM2.5 0.5PM2.5 -11.3%0.5300000.470000SO2 0.5SO2 -11.7%5.624.96VOC 0.5VOC Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus Arsenic & Compounds (total mass of elemental AS, arsine and all inorganic compounds) 0.290000 0.336060 -13.7%0.01 -13.7%0.3360600.290000ASC-Other 0.01Arsenic Unlisted Compounds - Specify Compound (Component of ASC) Beryllium & compounds (Total mass)0.060550 0.067680 -10.5%1.0 -10.5%0.0676800.0605507440-41-7 1.0Beryllium Metal (unreacted) (Component of BEC) Cadmium & compounds (total mass includes elemental metal)1.29 1.52 -15.1%0.1 -15.1%1.521.297440-43-9 0.1Cadmium Metal, elemental, unreacted (Component of CDC) Chromium - All/Total (includes Chromium (VI) categories, metal and others) 1.63 1.92 -15.1%0.1 Page 1 of 408/02/2022 Duke University 03254T43 3200144 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus -15.1%1.921.637738-94-5 0.01Chromic acid (VI) (Component of SolCR6 & CRC) Chromium (VI) Soluble Chromate Compounds (Component of CRC) 1.63 1.92 -15.1%0.01 -15.1%1.921.637738-94-5 0.01Chromic acid (VI) (Component of SolCR6 & CRC) Cobalt & compounds 0.128600 0.144900 -11.2%1.0 -11.2%0.1449000.128600COC-Other 1.0Cobalt Unlisted Compounds - Specify Compound (Component of COC) Glycol ethers (total all individual glycol ethers)0.420000 3.42 -87.7%100.0 -87.7%3.420.420000GLYET-Other 100.0Glycol Ethers, Unlisted - Specify Compound (component of GLYET) Lead & compounds 0.907420 1.02 -11.0%1.0 -10.8%1.020.907420PBC-Other 10.0Lead Unlisted Compounds - Specify Compound (Component of PBC) Manganese & compounds 0.525770 0.611240 -14.0%10.0 -14.0%0.6112400.525770MNC-Other 10.0Manganese Unlisted Compounds - Specify Compound (Component of MNC) Mercury & Compounds - all total mass includes Hg Vapor 0.335040 0.399110 -16.1%0.001 -16.1%0.3991100.3350407439-97-6 0.001Mercury, vapor (Component of HGC) Nickel & Compounds, sum total mass includes elemental 2.43 2.86 -15.0%1.0 -15.0%2.862.437440-02-0 1.0Nickel metal (Component of NIC) Polycyclic Organic Matter (7 PAH Compounds for NIF)0.005160 0.006080 -15.1%1.0 -15.1%0.0060800.00516050-32-8 1.0Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) Polycyclic Organic Matter (Specific Compounds from OAQPS for TV) 2.63 3.09 -14.9%1.0 -15.1%0.0060800.00516050-32-8 1.0Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) -14.9%3.082.6291-20-3 1.0Naphthalene (Component of 83329/POMTV) Page 2 of 408/02/2022 Duke University 03254T43 3200144 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus -7.6%1.050.97389075-07-0 10.0Acetaldehyde -14.6%0.3132700.267450107-02-8 10.0Acrolein -11.1%5,517.004,903.007664-41-7 100.0Ammonia (as NH3) -15.4%16.1013.6271-43-2 1.0Benzene 2.9%0.0277000.028500106-99-0 1.0Butadiene, 1,3- N/A0.0006600.00050056-23-5 1.0Carbon tetrachloride N/A0.0004800.000370108-90-7 10.0Chlorobenzene N/A0.0005100.00039067-66-3 100.0Chloroform -61.6%0.5393300.207330100-41-4 100.0Ethyl benzene N/A0.0007900.000610106-93-4 1.0Ethylene dibromide (dibromoethane) -92.1%7.980.630000107-21-1 100.0Ethylene glycol -12.5%0.2240000.19600075-21-8 1.0Ethylene oxide 74.7%0.3829000.66900016984-48-8 10.0Fluorides (sum of all fluoride compounds as mass of F ion) -11.1%132.88118.1850-00-0 10.0Formaldehyde N/ANot Reported 0.012500822-06-0 1.0Hexamethylene-1,6-diisocyanate -11.2%3,107.002,758.00110-54-3 100.0Hexane, n- -100.0%0.5300000.00000078-93-3 100.0MEK (methyl ethyl ketone, 2-butanone) -23.5%0.1140000.08720067-56-1 1,000.0Methanol (methyl alcohol) N/A0.0024300.00423071-55-6 100.0Methyl chloroform N/A0.0015300.00117075-09-2 1.0Methylene chloride -16.8%3.242.69POM 1.0Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) -9.6%0.3000100.271350SEC 10.0Selenium Compounds N/A0.0004400.000340100-42-5 100.0Styrene -15.1%12.3010.44108-88-3 100.0Toluene Page 3 of 408/02/2022 Duke University 03254T43 3200144 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus N/A0.0002700.00021075-01-4 0.1Vinyl chloride -33.1%3.932.631330-20-7 100.0Xylene (mixed isomers) Largest Individual HAP 2,758.00 lbs 2,918.89 lbsTotal HAP Emissions Hexane, n- Largest Individual CAP 69.66 tons Total CAP Emissions 141.37 tons Total TAP Emissions 7,814.29 lbs Total Aggregate Emissions 143.82 tons CO DAQ's Comments Regarding Inventory Page 4 of 408/02/2022 ~13% decrease in Criteria pollutants & combustion products largely due to corresponding decrease in throughput for NG boilers and generators. Facility Emissions - Operating Scenarios Per Pollutant Duke University 2021 Inventory Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Acetaldehyde OS-11 0.002270 Pounds 0.002320 Pounds ES-7754-06 ES-7754-06 OS-53 0.006010 Pounds 0.005930 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.066000 Pounds 0.088300 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.558000 Pounds 0.543000 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 8/3/2022 Page 1 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.079500 Pounds 0.104000 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 0.003570 Pounds 0.003550 Pounds ES-7754-03b ES-7754-03b OS-64 0.028100 Pounds 0.040200 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 8/3/2022 Page 2 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.005870 Pounds 0.007190 Pounds ES-7754-01b ES-7754-01b OS-69 0.005570 Pounds 0.007240 Pounds ES-7754-02b ES-7754-02b OS-76 0.219000 Pounds 0.252000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 8/3/2022 Page 3 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.97 Pounds TOTAL in Previous Inventory: 1.05 Pounds Acrolein OS-11 0.002690 Pounds 0.002750 Pounds ES-7754-06 ES-7754-06 OS-53 0.007110 Pounds 0.007020 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.020600 Pounds 0.027600 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.067300 Pounds 0.065500 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 8/3/2022 Page 4 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.074900 Pounds 0.097600 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 0.004230 Pounds 0.004210 Pounds ES-7754-03b ES-7754-03b OS-64 0.008770 Pounds 0.012600 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 8/3/2022 Page 5 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.006950 Pounds 0.008510 Pounds ES-7754-01b ES-7754-01b OS-69 0.006600 Pounds 0.008580 Pounds ES-7754-02b ES-7754-02b OS-76 0.068300 Pounds 0.078900 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 8/3/2022 Page 6 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.27 Pounds TOTAL in Previous Inventory: 0.31 Pounds Ammonia (as NH3) OS-11 478.00 Pounds 489.00 Pounds ES-7754-06 ES-7754-06 OS-53 1,264.00 Pounds 1,250.00 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-61 752.00 Pounds 748.00 Pounds ES-7754-03b ES-7754-03b OS-67 1,236.00 Pounds 1,510.00 Pounds ES-7754-01b ES-7754-01b OS-69 1,173.00 Pounds 1,520.00 Pounds ES-7754-02b ES-7754-02b TOTAL in Current Inventory: 4,903.00 Pounds TOTAL in Previous Inventory: 5,517.00 Pounds Arsenic Unlisted Compounds - Specify Compound (Component of ASC) OS-7 0.000550 Pounds 0.000550 Pounds ES-7754-04 ES-7754-04 OS-9 0.007430 Pounds 0.000710 Pounds ES-7754-05 ES-7754-05 OS-11 0.029900 Pounds 0.030600 Pounds 8/3/2022 Page 7 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-06 ES-7754-06 OS-12 0.000530 Pounds 0.000330 Pounds ES-7754-06 ES-7754-06 OS-54 0.010500 Pounds 0.014000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002910 Pounds 0.002830 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 8/3/2022 Page 8 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-61 0.047000 Pounds 0.046700 Pounds ES-7754-03b ES-7754-03b OS-64 0.004450 Pounds 0.006380 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000510 Pounds 0.000780 Pounds ES-7754-01b ES-7754-01b OS-67 0.077200 Pounds 0.094500 Pounds ES-7754-01b ES-7754-01b OS-68 0.000560 Pounds 0.001730 Pounds ES-7754-02b ES-7754-02b OS-69 0.073300 Pounds 0.095300 Pounds ES-7754-02b ES-7754-02b OS-71 0.000460 Pounds 0.001650 Pounds ES-7754-03b ES-7754-03b OS-76 0.034700 Pounds 0.040000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 8/3/2022 Page 9 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.29 Pounds TOTAL in Previous Inventory: 0.34 Pounds Benzene OS-7 0.002720 Pounds 0.002710 Pounds ES-7754-04 ES-7754-04 OS-9 0.036500 Pounds 0.003490 Pounds ES-7754-05 ES-7754-05 OS-11 0.314000 Pounds 0.321000 Pounds ES-7754-06 ES-7754-06 OS-12 0.002580 Pounds 0.001630 Pounds ES-7754-06 ES-7754-06 OS-53 0.830000 Pounds 0.819000 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 8/3/2022 Page 10 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 2.03 Pounds 2.72 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.679000 Pounds 0.661000 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 8/3/2022 Page 11 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.045000 Pounds 0.058600 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 0.494000 Pounds 0.491000 Pounds ES-7754-03b ES-7754-03b OS-64 0.864000 Pounds 1.24 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.002490 Pounds 0.003810 Pounds ES-7754-01b ES-7754-01b OS-67 0.811000 Pounds 0.993000 Pounds ES-7754-01b ES-7754-01b OS-68 0.002770 Pounds 0.008510 Pounds ES-7754-02b ES-7754-02b OS-69 0.770000 Pounds 1.00 Pounds ES-7754-02b ES-7754-02b 8/3/2022 Page 12 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-71 0.002270 Pounds 0.008100 Pounds ES-7754-03b ES-7754-03b OS-76 6.73 Pounds 7.77 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 13.62 Pounds TOTAL in Previous Inventory: 16.10 Pounds Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) 8/3/2022 Page 13 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-11 0.000180 Pounds 0.000180 Pounds ES-7754-06 ES-7754-06 OS-53 0.000470 Pounds 0.000470 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.000670 Pounds 0.000900 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.000140 Pounds 0.000130 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 8/3/2022 Page 14 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.000280 Pounds 0.000280 Pounds ES-7754-03b ES-7754-03b OS-64 0.000290 Pounds 0.000410 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.000460 Pounds 0.000570 Pounds ES-7754-01b ES-7754-01b OS-69 0.000440 Pounds 0.000570 Pounds ES-7754-02b ES-7754-02b OS-76 0.002230 Pounds 0.002570 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 8/3/2022 Page 15 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.01 Pounds TOTAL in Previous Inventory: 0.01 Pounds Beryllium Metal (unreacted) (Component of BEC) OS-7 0.000420 Pounds 0.000410 Pounds ES-7754-04 ES-7754-04 OS-9 0.005570 Pounds 0.000530 Pounds ES-7754-05 ES-7754-05 OS-11 0.001790 Pounds 0.001830 Pounds ES-7754-06 ES-7754-06 8/3/2022 Page 16 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-12 0.000390 Pounds 0.000250 Pounds ES-7754-06 ES-7754-06 OS-54 0.007860 Pounds 0.010500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002180 Pounds 0.002120 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 8/3/2022 Page 17 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-61 0.002820 Pounds 0.002800 Pounds ES-7754-03b ES-7754-03b OS-64 0.003340 Pounds 0.004780 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000380 Pounds 0.000580 Pounds ES-7754-01b ES-7754-01b OS-67 0.004630 Pounds 0.005670 Pounds ES-7754-01b ES-7754-01b OS-68 0.000420 Pounds 0.001300 Pounds ES-7754-02b ES-7754-02b OS-69 0.004400 Pounds 0.005670 Pounds ES-7754-02b ES-7754-02b OS-71 0.000350 Pounds 0.001240 Pounds ES-7754-03b ES-7754-03b OS-76 0.026000 Pounds 0.030000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 8/3/2022 Page 18 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.06 Pounds TOTAL in Previous Inventory: 0.07 Pounds Butadiene, 1,3- OS-58 0.028500 Pounds 0.027700 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 8/3/2022 Page 19 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 TOTAL in Current Inventory: 0.03 Pounds TOTAL in Previous Inventory: 0.03 Pounds Cadmium Metal, elemental, unreacted (Component of CDC) OS-7 0.000420 Pounds 0.000410 Pounds ES-7754-04 ES-7754-04 OS-9 0.005570 Pounds 0.000530 Pounds ES-7754-05 ES-7754-05 OS-11 0.164000 Pounds 0.168000 Pounds ES-7754-06 ES-7754-06 OS-12 0.000390 Pounds 0.000250 Pounds ES-7754-06 ES-7754-06 OS-54 0.000790 Pounds 0.010500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002180 Pounds 0.002120 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 8/3/2022 Page 20 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.259000 Pounds 0.257000 Pounds ES-7754-03b ES-7754-03b OS-64 0.003340 Pounds 0.004780 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 8/3/2022 Page 21 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000380 Pounds 0.000580 Pounds ES-7754-01b ES-7754-01b OS-67 0.425000 Pounds 0.520000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000420 Pounds 0.001300 Pounds ES-7754-02b ES-7754-02b OS-69 0.403000 Pounds 0.524000 Pounds ES-7754-02b ES-7754-02b OS-71 0.000350 Pounds 0.001240 Pounds ES-7754-03b ES-7754-03b OS-76 0.026000 Pounds 0.030000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 8/3/2022 Page 22 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 1.29 Pounds TOTAL in Previous Inventory: 1.52 Pounds Carbon tetrachloride OS-60 0.000500 Pounds 0.000660 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Chlorobenzene OS-60 0.000370 Pounds 0.000480 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Chloroform OS-60 0.000390 Pounds 0.000510 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Chromic acid (VI) (Component of SolCR6 & CRC) OS-7 0.000420 Pounds 0.000410 Pounds 8/3/2022 Page 23 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-04 ES-7754-04 OS-9 0.005570 Pounds 0.000530 Pounds ES-7754-05 ES-7754-05 OS-11 0.209000 Pounds 0.214000 Pounds ES-7754-06 ES-7754-06 OS-12 0.000390 Pounds 0.000250 Pounds ES-7754-06 ES-7754-06 OS-54 0.000790 Pounds 0.010500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002180 Pounds 0.002120 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 8/3/2022 Page 24 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.329000 Pounds 0.327000 Pounds ES-7754-03b ES-7754-03b OS-64 0.003340 Pounds 0.004780 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000380 Pounds 0.000580 Pounds ES-7754-01b ES-7754-01b OS-67 0.541000 Pounds 0.662000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000420 Pounds 0.001300 Pounds ES-7754-02b ES-7754-02b OS-69 0.513000 Pounds 0.667000 Pounds ES-7754-02b ES-7754-02b OS-71 0.000350 Pounds 0.001240 Pounds ES-7754-03b ES-7754-03b OS-76 0.026000 Pounds 0.030000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 8/3/2022 Page 25 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 1.63 Pounds TOTAL in Previous Inventory: 1.92 Pounds CO OS-9 0.030000 Tons ES-7754-05 ES-7754-05 OS-11 6.27 Tons 6.42 Tons ES-7754-06 ES-7754-06 OS-53 16.59 Tons 16.38 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 8/3/2022 Page 26 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 1.03 Tons 1.38 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.350000 Tons 0.340000 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 8/3/2022 Page 27 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.050000 Tons 0.070000 Tons I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 9.87 Tons 9.81 Tons ES-7754-03b ES-7754-03b OS-64 0.440000 Tons 0.630000 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 16.22 Tons 19.85 Tons ES-7754-01b ES-7754-01b OS-68 0.010000 Tons ES-7754-02b OS-69 15.40 Tons 20.01 Tons ES-7754-02b ES-7754-02b OS-71 0.010000 Tons ES-7754-03b 8/3/2022 Page 28 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-76 3.41 Tons 3.93 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 69.66 Tons TOTAL in Previous Inventory: 78.84 Tons Cobalt Unlisted Compounds - Specify Compound (Component of COC) OS-11 0.012500 Pounds 0.012800 Pounds ES-7754-06 ES-7754-06 8/3/2022 Page 29 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-53 0.033200 Pounds 0.032800 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-61 0.019700 Pounds 0.019600 Pounds ES-7754-03b ES-7754-03b OS-67 0.032400 Pounds 0.039700 Pounds ES-7754-01b ES-7754-01b OS-69 0.030800 Pounds 0.040000 Pounds ES-7754-02b ES-7754-02b TOTAL in Current Inventory: 0.13 Pounds TOTAL in Previous Inventory: 0.14 Pounds Ethyl benzene OS-7 0.000810 Pounds 0.000810 Pounds ES-7754-04 ES-7754-04 OS-9 0.010800 Pounds 0.001040 Pounds ES-7754-05 ES-7754-05 OS-12 0.000770 Pounds 0.000490 Pounds ES-7754-06 ES-7754-06 OS-24 0.192000 Pounds 0.530000 Pounds I-030 I-030 I-040 I-040 OS-60 0.000710 Pounds 0.000920 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 8/3/2022 Page 30 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-66 0.000740 Pounds 0.001130 Pounds ES-7754-01b ES-7754-01b OS-68 0.000820 Pounds 0.002530 Pounds ES-7754-02b ES-7754-02b OS-71 0.000680 Pounds 0.002410 Pounds ES-7754-03b ES-7754-03b TOTAL in Current Inventory: 0.21 Pounds TOTAL in Previous Inventory: 0.54 Pounds Ethylene dibromide (dibromoethane) OS-60 0.000610 Pounds 0.000790 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Ethylene glycol OS-24 0.630000 Pounds 7.98 Pounds I-030 I-030 I-040 I-040 TOTAL in Current Inventory: 0.63 Pounds TOTAL in Previous Inventory: 7.98 Pounds Ethylene oxide OS-57 0.196000 Pounds 0.224000 Pounds ES-7531-01 ES-7531-01 ES-7531-02 ES-7531-02 ES-7531-03 ES-7531-03 ES-7547-06 ES-7547-06 ES-7547-07 ES-7547-07 ES-7547-08 ES-7547-08 ES-7547-09 ES-7547-09 TOTAL in Current Inventory: 0.20 Pounds TOTAL in Previous Inventory: 0.22 Pounds Fluorides (sum of all fluoride compounds as mass of F ion) OS-7 0.036900 Pounds 0.036700 Pounds 8/3/2022 Page 31 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-04 ES-7754-04 OS-9 0.495000 Pounds 0.047300 Pounds ES-7754-05 ES-7754-05 OS-12 0.035000 Pounds 0.022200 Pounds ES-7754-06 ES-7754-06 OS-66 0.033800 Pounds 0.051700 Pounds ES-7754-01b ES-7754-01b OS-68 0.037500 Pounds 0.115000 Pounds ES-7754-02b ES-7754-02b OS-71 0.030800 Pounds 0.110000 Pounds ES-7754-03b ES-7754-03b TOTAL in Current Inventory: 0.67 Pounds TOTAL in Previous Inventory: 0.38 Pounds Formaldehyde OS-7 0.047400 Pounds 0.047300 Pounds ES-7754-04 ES-7754-04 OS-9 0.637000 Pounds 0.060900 Pounds ES-7754-05 ES-7754-05 OS-11 11.20 Pounds 11.50 Pounds ES-7754-06 ES-7754-06 OS-12 0.045000 Pounds 0.028500 Pounds ES-7754-06 ES-7754-06 OS-53 29.60 Pounds 29.20 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 8/3/2022 Page 32 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.207000 Pounds 0.276000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.859000 Pounds 0.836000 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.584000 Pounds 0.761000 Pounds 8/3/2022 Page 33 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 17.60 Pounds 17.50 Pounds ES-7754-03b ES-7754-03b OS-64 0.087900 Pounds 0.126000 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.043500 Pounds 0.066500 Pounds ES-7754-01b ES-7754-01b OS-67 29.00 Pounds 35.50 Pounds ES-7754-01b ES-7754-01b OS-68 0.048300 Pounds 0.149000 Pounds ES-7754-02b ES-7754-02b OS-69 27.50 Pounds 35.90 Pounds ES-7754-02b ES-7754-02b OS-71 0.039600 Pounds 0.141000 Pounds ES-7754-03b ES-7754-03b OS-76 0.684000 Pounds 0.790000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 8/3/2022 Page 34 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 118.18 Pounds TOTAL in Previous Inventory: 132.88 Pounds Glycol Ethers, Unlisted - Specify Compound (component of GLYET) OS-24 0.420000 Pounds 3.42 Pounds I-030 I-030 I-040 I-040 TOTAL in Current Inventory: 0.42 Pounds TOTAL in Previous Inventory: 3.42 Pounds Hexamethylene-1,6-diisocyanate OS-24 0.012500 Pounds I-030 I-030 I-040 I-040 8/3/2022 Page 35 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 TOTAL in Current Inventory: 0.01 Pounds Hexane, n- OS-11 269.00 Pounds 275.00 Pounds ES-7754-06 ES-7754-06 OS-53 711.00 Pounds 702.00 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-61 423.00 Pounds 421.00 Pounds ES-7754-03b ES-7754-03b OS-67 695.00 Pounds 851.00 Pounds ES-7754-01b ES-7754-01b OS-69 660.00 Pounds 858.00 Pounds ES-7754-02b ES-7754-02b TOTAL in Current Inventory: 2,758.00 Pounds TOTAL in Previous Inventory: 3,107.00 Pounds Lead Unlisted Compounds - Specify Compound (Component of PBC) OS-7 0.001240 Pounds 0.001240 Pounds ES-7754-04 ES-7754-04 OS-9 0.016700 Pounds 0.001600 Pounds ES-7754-05 ES-7754-05 OS-11 0.074700 Pounds 0.076400 Pounds ES-7754-06 ES-7754-06 OS-12 0.001180 Pounds 0.000750 Pounds 8/3/2022 Page 36 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-06 ES-7754-06 OS-53 0.198000 Pounds 0.195000 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.023600 Pounds 0.031500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.006550 Pounds 0.006370 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 8/3/2022 Page 37 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.118000 Pounds 0.117000 Pounds ES-7754-03b ES-7754-03b OS-64 0.010000 Pounds 0.014300 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.001140 Pounds 0.001750 Pounds ES-7754-01b ES-7754-01b OS-67 0.193000 Pounds 0.236000 Pounds ES-7754-01b ES-7754-01b OS-68 0.001270 Pounds 0.003900 Pounds ES-7754-02b ES-7754-02b OS-69 0.183000 Pounds 0.238000 Pounds ES-7754-02b ES-7754-02b OS-71 0.001040 Pounds 0.003710 Pounds 8/3/2022 Page 38 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-03b ES-7754-03b OS-76 0.078000 Pounds 0.090100 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.91 Pounds TOTAL in Previous Inventory: 1.02 Pounds Manganese Unlisted Compounds - Specify Compound (Component of MNC) OS-7 0.000830 Pounds 0.000830 Pounds 8/3/2022 Page 39 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-04 ES-7754-04 OS-9 0.011100 Pounds 0.001070 Pounds ES-7754-05 ES-7754-05 OS-11 0.056700 Pounds 0.058000 Pounds ES-7754-06 ES-7754-06 OS-12 0.000790 Pounds 0.000500 Pounds ES-7754-06 ES-7754-06 OS-54 0.015700 Pounds 0.021000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.004370 Pounds 0.004250 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 8/3/2022 Page 40 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.089300 Pounds 0.088800 Pounds ES-7754-03b ES-7754-03b OS-64 0.006680 Pounds 0.009560 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000760 Pounds 0.001160 Pounds ES-7754-01b ES-7754-01b OS-67 0.147000 Pounds 0.180000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000850 Pounds 0.002600 Pounds ES-7754-02b ES-7754-02b OS-69 0.139000 Pounds 0.181000 Pounds ES-7754-02b ES-7754-02b OS-71 0.000690 Pounds 0.002470 Pounds ES-7754-03b ES-7754-03b OS-76 0.052000 Pounds 0.060000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 8/3/2022 Page 41 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.53 Pounds TOTAL in Previous Inventory: 0.61 Pounds MEK (methyl ethyl ketone, 2-butanone) OS-24 0.530000 Pounds I-040 I-030 TOTAL in Previous Inventory: 0.53 Pounds Mercury, vapor (Component of HGC) OS-7 0.000420 Pounds 0.000410 Pounds 8/3/2022 Page 42 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-04 ES-7754-04 OS-9 0.005570 Pounds 0.000530 Pounds ES-7754-05 ES-7754-05 OS-11 0.038800 Pounds 0.039700 Pounds ES-7754-06 ES-7754-06 OS-12 0.000390 Pounds 0.000250 Pounds ES-7754-06 ES-7754-06 OS-54 0.000790 Pounds 0.010500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002180 Pounds 0.002120 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 8/3/2022 Page 43 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.061100 Pounds 0.060700 Pounds ES-7754-03b ES-7754-03b OS-64 0.003340 Pounds 0.004780 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000380 Pounds 0.000580 Pounds ES-7754-01b ES-7754-01b OS-67 0.100000 Pounds 0.123000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000420 Pounds 0.001300 Pounds ES-7754-02b ES-7754-02b OS-69 0.095300 Pounds 0.124000 Pounds ES-7754-02b ES-7754-02b OS-71 0.000350 Pounds 0.001240 Pounds ES-7754-03b ES-7754-03b OS-76 0.026000 Pounds 0.030000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 8/3/2022 Page 44 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.34 Pounds TOTAL in Previous Inventory: 0.40 Pounds Methanol (methyl alcohol) OS-60 0.087200 Pounds 0.114000 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.09 Pounds TOTAL in Previous Inventory: 0.11 Pounds 8/3/2022 Page 45 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Methyl chloroform OS-7 0.000230 Pounds 0.000230 Pounds ES-7754-04 ES-7754-04 OS-9 0.003130 Pounds 0.000300 Pounds ES-7754-05 ES-7754-05 OS-12 0.000220 Pounds 0.000140 Pounds ES-7754-06 ES-7754-06 OS-66 0.000210 Pounds 0.000330 Pounds ES-7754-01b ES-7754-01b OS-68 0.000240 Pounds 0.000730 Pounds ES-7754-02b ES-7754-02b OS-71 0.000200 Pounds 0.000700 Pounds ES-7754-03b ES-7754-03b TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Methylene chloride OS-60 0.001170 Pounds 0.001530 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Naphthalene (Component of 83329/POMTV) OS-7 0.000330 Pounds 0.000330 Pounds ES-7754-04 ES-7754-04 OS-9 0.004420 Pounds 0.000420 Pounds ES-7754-05 ES-7754-05 OS-11 0.091100 Pounds 0.093200 Pounds ES-7754-06 ES-7754-06 OS-12 0.000310 Pounds 0.000200 Pounds ES-7754-06 ES-7754-06 OS-53 0.241000 Pounds 0.238000 Pounds ES-7254-EC1 ES-7254-EC1 8/3/2022 Page 46 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.341000 Pounds 0.455000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.061700 Pounds 0.060100 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 8/3/2022 Page 47 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.002770 Pounds 0.003600 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 0.143000 Pounds 0.143000 Pounds ES-7754-03b ES-7754-03b OS-64 0.145000 Pounds 0.207000 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000300 Pounds 0.000460 Pounds ES-7754-01b ES-7754-01b OS-67 0.236000 Pounds 0.288000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000340 Pounds 0.001030 Pounds ES-7754-02b ES-7754-02b OS-69 0.224000 Pounds 0.291000 Pounds ES-7754-02b ES-7754-02b 8/3/2022 Page 48 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-71 0.000280 Pounds 0.000980 Pounds ES-7754-03b ES-7754-03b OS-76 1.13 Pounds 1.30 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 2.62 Pounds TOTAL in Previous Inventory: 3.08 Pounds 8/3/2022 Page 49 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Nickel metal (Component of NIC) OS-7 0.000420 Pounds 0.000410 Pounds ES-7754-04 ES-7754-04 OS-9 0.005570 Pounds 0.000530 Pounds ES-7754-05 ES-7754-05 OS-11 0.314000 Pounds 0.321000 Pounds ES-7754-06 ES-7754-06 OS-12 0.000390 Pounds 0.000250 Pounds ES-7754-06 ES-7754-06 OS-54 0.000790 Pounds 0.010500 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.002180 Pounds 0.002120 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 8/3/2022 Page 50 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.494000 Pounds 0.491000 Pounds ES-7754-03b ES-7754-03b OS-64 0.003340 Pounds 0.004780 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.000380 Pounds 0.000580 Pounds ES-7754-01b ES-7754-01b OS-67 0.811000 Pounds 0.993000 Pounds ES-7754-01b ES-7754-01b OS-68 0.000420 Pounds 0.001300 Pounds ES-7754-02b ES-7754-02b OS-69 0.770000 Pounds 1.00 Pounds ES-7754-02b ES-7754-02b OS-71 0.000350 Pounds 0.001240 Pounds ES-7754-03b ES-7754-03b OS-76 0.026000 Pounds 0.030000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 8/3/2022 Page 51 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 2.43 Pounds TOTAL in Previous Inventory: 2.86 Pounds NOx OS-7 0.010000 Tons 0.010000 Tons ES-7754-04 ES-7754-04 OS-9 0.130000 Tons 0.010000 Tons ES-7754-05 ES-7754-05 8/3/2022 Page 52 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-11 7.47 Tons 7.64 Tons ES-7754-06 ES-7754-06 OS-12 0.010000 Tons 0.010000 Tons ES-7754-06 ES-7754-06 OS-53 9.88 Tons 9.75 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 4.49 Tons 6.01 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 1.61 Tons 1.57 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 8/3/2022 Page 53 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.030000 Tons 0.040000 Tons I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 5.88 Tons 5.84 Tons ES-7754-03b ES-7754-03b OS-64 1.91 Tons 2.73 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.010000 Tons 0.010000 Tons ES-7754-01b ES-7754-01b 8/3/2022 Page 54 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-67 9.65 Tons 11.82 Tons ES-7754-01b ES-7754-01b OS-68 0.010000 Tons 0.020000 Tons ES-7754-02b ES-7754-02b OS-69 9.17 Tons 11.91 Tons ES-7754-02b ES-7754-02b OS-71 0.010000 Tons 0.020000 Tons ES-7754-03b ES-7754-03b OS-76 14.86 Tons 17.16 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 8/3/2022 Page 55 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 65.13 Tons TOTAL in Previous Inventory: 74.55 Tons PM(TSP) OS-9 0.020000 Tons ES-7754-05 ES-7754-05 OS-11 0.040000 Tons 0.040000 Tons ES-7754-06 ES-7754-06 OS-53 0.100000 Tons 0.100000 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.130000 Tons 0.180000 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.110000 Tons 0.110000 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 8/3/2022 Page 56 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.060000 Tons 0.060000 Tons ES-7754-03b ES-7754-03b OS-64 0.060000 Tons 0.080000 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 8/3/2022 Page 57 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.100000 Tons 0.120000 Tons ES-7754-01b ES-7754-01b OS-68 0.010000 Tons ES-7754-02b OS-69 0.100000 Tons 0.120000 Tons ES-7754-02b ES-7754-02b OS-71 0.010000 Tons ES-7754-03b OS-76 0.430000 Tons 0.500000 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 8/3/2022 Page 58 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 1.15 Tons TOTAL in Previous Inventory: 1.33 Tons PM10 OS-9 0.020000 Tons ES-7754-05 ES-7754-05 OS-11 0.040000 Tons 0.040000 Tons ES-7754-06 ES-7754-06 OS-53 0.100000 Tons 0.100000 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.130000 Tons 0.180000 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.110000 Tons 0.110000 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 8/3/2022 Page 59 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.060000 Tons 0.060000 Tons ES-7754-03b ES-7754-03b OS-64 0.060000 Tons 0.080000 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 8/3/2022 Page 60 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.100000 Tons 0.120000 Tons ES-7754-01b ES-7754-01b OS-69 0.100000 Tons 0.120000 Tons ES-7754-02b ES-7754-02b OS-76 0.430000 Tons 0.500000 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 8/3/2022 Page 61 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 1.15 Tons TOTAL in Previous Inventory: 1.31 Tons PM2.5 OS-9 0.010000 Tons ES-7754-05 ES-7754-05 OS-11 0.030000 Tons 0.030000 Tons ES-7754-06 ES-7754-06 OS-53 0.080000 Tons 0.080000 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.130000 Tons 0.180000 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.110000 Tons 0.110000 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 8/3/2022 Page 62 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.050000 Tons 0.050000 Tons ES-7754-03b ES-7754-03b OS-64 0.060000 Tons 0.080000 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 0.080000 Tons 0.100000 Tons ES-7754-01b ES-7754-01b 8/3/2022 Page 63 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-69 0.080000 Tons 0.100000 Tons ES-7754-02b ES-7754-02b OS-76 0.430000 Tons 0.500000 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 1.06 Tons TOTAL in Previous Inventory: 1.23 Tons 8/3/2022 Page 64 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) OS-7 0.003260 Pounds 0.003250 Pounds ES-7754-04 ES-7754-04 OS-9 0.043800 Pounds 0.004190 Pounds ES-7754-05 ES-7754-05 OS-12 0.003100 Pounds 0.001960 Pounds ES-7754-06 ES-7754-06 OS-54 0.555000 Pounds 0.743000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-60 0.004020 Pounds 0.005230 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-64 0.236000 Pounds 0.338000 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.002990 Pounds 0.004570 Pounds ES-7754-01b ES-7754-01b OS-68 0.003320 Pounds 0.010200 Pounds ES-7754-02b ES-7754-02b OS-71 0.002730 Pounds 0.009720 Pounds ES-7754-03b ES-7754-03b 8/3/2022 Page 65 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-76 1.84 Pounds 2.12 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 2.69 Pounds TOTAL in Previous Inventory: 3.24 Pounds Selenium Compounds OS-7 0.002070 Pounds 0.002070 Pounds ES-7754-04 ES-7754-04 8/3/2022 Page 66 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-9 0.027900 Pounds 0.002660 Pounds ES-7754-05 ES-7754-05 OS-11 0.003580 Pounds 0.003670 Pounds ES-7754-06 ES-7754-06 OS-12 0.001970 Pounds 0.001250 Pounds ES-7754-06 ES-7754-06 OS-53 0.009480 Pounds 0.009360 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.039300 Pounds 0.052600 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.010900 Pounds 0.010600 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 8/3/2022 Page 67 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.005640 Pounds 0.005610 Pounds ES-7754-03b ES-7754-03b OS-64 0.016700 Pounds 0.023900 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.001900 Pounds 0.002910 Pounds ES-7754-01b ES-7754-01b OS-67 0.009270 Pounds 0.011300 Pounds 8/3/2022 Page 68 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-01b ES-7754-01b OS-68 0.002110 Pounds 0.006500 Pounds ES-7754-02b ES-7754-02b OS-69 0.008800 Pounds 0.011400 Pounds ES-7754-02b ES-7754-02b OS-71 0.001730 Pounds 0.006180 Pounds ES-7754-03b ES-7754-03b OS-76 0.130000 Pounds 0.150000 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 8/3/2022 Page 69 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.27 Pounds TOTAL in Previous Inventory: 0.30 Pounds SO2 OS-11 0.040000 Tons 0.050000 Tons ES-7754-06 ES-7754-06 OS-53 0.120000 Tons 0.120000 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-61 0.070000 Tons 0.070000 Tons ES-7754-03b ES-7754-03b OS-67 0.120000 Tons 0.140000 Tons ES-7754-01b ES-7754-01b OS-69 0.110000 Tons 0.140000 Tons ES-7754-02b ES-7754-02b OS-76 0.010000 Tons 0.010000 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 8/3/2022 Page 70 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 0.47 Tons TOTAL in Previous Inventory: 0.53 Tons Styrene OS-60 0.000340 Pounds 0.000440 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds Toluene OS-7 0.078700 Pounds 0.078500 Pounds 8/3/2022 Page 71 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7754-04 ES-7754-04 OS-9 1.06 Pounds 0.101000 Pounds ES-7754-05 ES-7754-05 OS-11 0.508000 Pounds 0.519000 Pounds ES-7754-06 ES-7754-06 OS-12 0.074700 Pounds 0.047300 Pounds ES-7754-06 ES-7754-06 OS-24 1.05 Pounds I-040 I-030 OS-53 1.34 Pounds 1.33 Pounds ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.736000 Pounds 0.985000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.298000 Pounds 0.290000 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 8/3/2022 Page 72 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.015900 Pounds 0.020700 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-61 0.799000 Pounds 0.794000 Pounds ES-7754-03b ES-7754-03b OS-64 0.313000 Pounds 0.448000 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 8/3/2022 Page 73 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.072300 Pounds 0.110000 Pounds ES-7754-01b ES-7754-01b OS-67 1.31 Pounds 1.61 Pounds ES-7754-01b ES-7754-01b OS-68 0.080200 Pounds 0.247000 Pounds ES-7754-02b ES-7754-02b OS-69 1.25 Pounds 1.62 Pounds ES-7754-02b ES-7754-02b OS-71 0.065800 Pounds 0.235000 Pounds ES-7754-03b ES-7754-03b OS-76 2.44 Pounds 2.81 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 8/3/2022 Page 74 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 10.44 Pounds TOTAL in Previous Inventory: 12.30 Pounds Vinyl chloride OS-60 0.000210 Pounds 0.000270 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing TOTAL in Current Inventory: 0.00 Pounds TOTAL in Previous Inventory: 0.00 Pounds VOC OS-11 0.410000 Tons 0.420000 Tons ES-7754-06 ES-7754-06 OS-15 0.030000 Tons 0.030000 Tons I-Tanks I-Tanks OS-24 0.010000 Tons 0.030000 Tons I-030 I-030 I-040 I-040 OS-53 1.09 Tons 1.07 Tons ES-7254-EC1 ES-7254-EC1 ES-7254-EC10 ES-7254-EC10 ES-7254-EC11 ES-7254-EC11 ES-7254-EC12 ES-7254-EC12 ES-7254-EC13 ES-7254-EC13 ES-7254-EC14 ES-7254-EC14 ES-7254-EC15 ES-7254-EC15 8/3/2022 Page 75 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7254-EC2 ES-7254-EC2 ES-7254-EC3 ES-7254-EC3 ES-7254-EC4 ES-7254-EC4 ES-7254-EC5 ES-7254-EC5 ES-7254-EC6 ES-7254-EC6 ES-7254-EC7 ES-7254-EC7 ES-7254-EC8 ES-7254-EC8 ES-7254-EC9 ES-7254-EC9 OS-54 0.120000 Tons 0.160000 Tons ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 OS-58 0.130000 Tons 0.130000 Tons ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 8/3/2022 Page 76 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-61 0.650000 Tons 0.640000 Tons ES-7754-03b ES-7754-03b OS-64 0.050000 Tons 0.070000 Tons ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-67 1.06 Tons 1.30 Tons ES-7754-01b ES-7754-01b OS-69 1.01 Tons 1.31 Tons ES-7754-02b ES-7754-02b OS-76 0.400000 Tons 0.460000 Tons ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B 8/3/2022 Page 77 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 4.96 Tons TOTAL in Previous Inventory: 5.62 Tons Xylene (mixed isomers) OS-7 0.001380 Pounds 0.001380 Pounds ES-7754-04 ES-7754-04 OS-9 0.018600 Pounds 0.001780 Pounds ES-7754-05 ES-7754-05 OS-12 0.001310 Pounds 0.000830 Pounds ES-7754-06 ES-7754-06 OS-24 0.790000 Pounds I-040 I-030 OS-54 0.506000 Pounds 0.676000 Pounds ES-7855-01 ES-7855-01 ES-7855-02 ES-7855-02 ES-7855-03 ES-7855-03 ES-7855-04 ES-7855-04 8/3/2022 Page 78 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-58 0.207000 Pounds 0.202000 Pounds ES-7582-01 ES-7582-01 ES-7777-01 ES-7777-01 I-7196-01 I-7196-01 I-7224-01 I-7224-01 I-7245-01 I-7245-01 I-7505-01 I-7505-01 I-7508-01 I-7508-01 I-7508-04 I-7508-04 I-7517-01 I-7517-01 I-7518-01 I-7518-01 I-7519-01 I-7519-01 I-7524-02 I-7524-02 I-7538-01 I-7538-01 I-7552-01 I-7552-01 I-7577-01 I-7577-01 I-7583-01 I-7583-01 I-7589-01 I-7589-01 I-7686-01 I-7686-01 I-7708-01 I-7708-01 I-7725-01 I-7725-01 I-7733-01 I-7733-01 I-7739-01 I-7739-01 I-7740-01 I-7740-01 I-7740-02 I-7740-02 I-7741-01 I-7741-01 I-7743-01 I-7743-01 I-7756-01 I-7756-01 I-7758-01 I-7758-01 I-7760-01 I-7760-01 I-7766-01 I-7766-01 I-7776-01 I-7776-01 I-7791-01 I-7791-01 I-8092-01 I-8092-01 OS-60 0.005550 Pounds 0.007240 Pounds I-7198-01 I-7198-01 I-7557-01 I-7557-01 I-7636-01 I-7636-01 I-Nursing I-Nursing OS-64 0.215000 Pounds 0.308000 Pounds ES-7514-01 ES-7514-01 ES-7559-01 ES-7559-01 ES-7738-01 ES-7738-01 8/3/2022 Page 79 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7XXA-01 ES-7XXA-01 ES-7XXB-01 ES-7XXB-01 ES-7XXC-01 ES-7XXC-01 ES-7XXD-01 ES-7XXD-01 ES-7XXE-01 ES-7XXE-01 ES-7XXF-01 ES-7XXF-01 ES-7XXG-01 ES-7XXG-01 ES-7XXH-01 ES-7XXH-01 ES-7XXI-01 ES-7XXI-01 ES-7XXJ-01 ES-7XXJ-01 OS-66 0.001270 Pounds 0.001940 Pounds ES-7754-01b ES-7754-01b OS-68 0.001410 Pounds 0.004340 Pounds ES-7754-02b ES-7754-02b OS-71 0.001160 Pounds 0.004120 Pounds ES-7754-03b ES-7754-03b OS-76 1.67 Pounds 1.93 Pounds ES-7254-16 ES-7254-16 ES-7508-03 ES-7508-03 ES-7516-01 ES-7516-01 ES-7524-02 ES-7524-02 ES-7524-03 ES-7524-03 ES-7526-01 ES-7526-01 ES-7531-04 ES-7531-04 ES-7540-01 ES-7540-01 ES-7542-01 ES-7542-01 ES-7542-02 ES-7542-02 ES-7547-01 ES-7547-01 ES-7547-02 ES-7547-02 ES-7547-02B ES-7547-02B ES-7547-03A ES-7547-03A ES-7547-04B ES-7547-04B ES-7547-05 ES-7547-05 ES-7549-01 ES-7549-01 ES-7555-01 ES-7555-01 ES-7558-01 ES-7558-01 ES-7558-02 ES-7558-02 ES-7558-03 ES-7558-03 ES-7561-01 ES-7561-01 ES-7579-01 ES-7579-01 ES-7579-02 ES-7579-02 8/3/2022 Page 80 of 81 Duke University 3200144 03254T43 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-7579-03 ES-7579-03 ES-7593-01 ES-7593-01 ES-7704-02 ES-7704-02 ES-7735-01 ES-7735-01 ES-7746-01 ES-7746-01 ES-7754-09 ES-7754-09 ES-7754-15 ES-7754-15 ES-7764-01 ES-7764-01 ES-7765-01 ES-7765-01 ES-7776-02 ES-7776-02 ES-7795-01 ES-7795-01 ES-7796-01 ES-7796-01 I-7760-02 I-7760-02 TOTAL in Current Inventory: 2.63 Pounds TOTAL in Previous Inventory: 3.93 Pounds 8/3/2022 Page 81 of 81 3200144 Durham, Duke University ID Group OS Name 2020 2021 Units Ratio 69 58 Emergency Generators (Up to 600 hp, diesel-fired)101,188 103,955 hp-hr 1.03 70 24 Paint Spray Booths 32 13 gal 0.40 84 57 Seven Ethylene Oxide Sterilizers 224 196 lb 0.88 86 76 Emergency Gens over 600 hp 1,429,674 1,238,689 hp-hr 0.87 58 64 Emergency Gens (NSR Avoidance Over 600 hp)227,680 159,073 hp-hr 0.70 62 60 NG Emergency Generators (up to 600 hp)14,585 11,195 hp-hr 0.77 63 53 East Campus Miura Boilers 390 395 mmscf 1.01 64 54 Emergency Generators (West Campus CWP)500,546 374,240 hp-hr 0.75 ES-7754-01b 66 Boiler - #2 FO 1,385 907 gpy 0.65 ES-7754-01b 67 Boiler - NG 473 386 mmscf 0.82 ES-7754-02b 68 Boiler - #2 FO 3,095 1,006 gpy 0.33 ES-7754-02b 69 Boiler - NG 476 367 mmscf 0.77 ES-7754-03b 71 Boiler - #2 FO 2,944 826 gpy 0.28 ES-7754-03b 61 Boiler - NG 234 235 mmscf 1.01 ES-7754-04 7 Boiler - #2 FO 985 988 gpy 1.00 ES-7754-05 9 Boiler - #2 FO 1,269 13,267 gpy 10.45 ES-7754-06 12 Boiler - #2 FO 594 938 gpy 1.58 ES-7754-06 11 Boiler - NG 153 149 mmscf 0.98 I-Tanks 15 Fuel storage tanks 13,833 17,932 gpy 1.30 NG Boilers 1,336 1,137 0.85 FO Boilers 10,272 17,932 1.75 Generators 2,273,673 1,887,152 0.83 From:Steven Gerrald To:Harris, Jeff Cc:Wesley Brummer; Wesley Seigler Subject:RE: [External] Re: 2021 Emission Inventory, Duke University (3200144) Date:Friday, August 12, 2022 2:03:16 PM Attachments:image001.png Duke 2021 AEI.pdf CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeff, See attached. Thanks, Steven Gerrald, P.E. Environmental Engineer Leaf Environmental & Engineering, P.C. Phone (919) 484-8536 Mobile (919) 801-5341 Fax (919) 484-8540 Notice of Confidentiality The information contained in and transmitted with this electronic communication (including attachments) is subject to attorney and/or client privileges or is otherwise confidential. It is intended solely for the addressee designated by the sender. If you are not the intended addressee or receive this communication in error, any dissemination, distribution, copying, or other use or reliance on any information contained or transmitted herein by or to anyone other than the addressee designated by the sender is unauthorized and prohibited. If you receive it in error, please notify Leaf Environmental & Engineering PC., by return email or by telephone at (919) 484-8536. From: Wesley Brummer <wes@leafenviro.com> Sent: Friday, August 12, 2022 1:34 PM To: Harris, Jeff <jeff.harris@ncdenr.gov>; Wesley Seigler <wesley.seigler@duke.edu>; Steven Gerrald <steven@leafenviro.com> Subject: RE: [External] Re: 2021 Emission Inventory, Duke University (3200144) Jeff Sorry, I’m confusing the inventory with something else. Steven will send it to you today. Wes Brummer, P.E. Leaf Environmental & Engineering, P.C. Phone (919) 484-8536 Fax (919) 484-8540 wes@leafenviro.com Notice of Confidentiality The information contained in and transmitted with this electronic communication (including attachments) is subject to attorney and/or client privileges or is otherwise confidential. It is intended solely for the addressee designated by the sender. If you are not the intended addressee or receive this communication in error, any dissemination, distribution, copying, or other use or reliance on any information contained or transmitted herein by or to anyone other than the addressee designated by the sender is unauthorized and prohibited. If you receive it in error, please notify Leaf Environmental & Engineering, P.C., by return email or by telephone at (919) 484-8536. From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Friday, August 12, 2022 1:32 PM To: Wesley Brummer <wes@leafenviro.com>; Wesley Seigler <wesley.seigler@duke.edu>; Steven Gerrald <steven@leafenviro.com> Subject: RE: [External] Re: 2021 Emission Inventory, Duke University (3200144) I just would like an electronic copy of the 2021 inventory submittal package to save for our files. I don’t have a big scanner at home to run the paper document through, and an e-copy makes a much better record than a scan of a paper file. In a few years, hopefully we won’t even ask you guys to submit paper Jeff From: Wesley Brummer <wes@leafenviro.com> Sent: Friday, August 12, 2022 1:28 PM To: Harris, Jeff <jeff.harris@ncdenr.gov>; Wesley Seigler <wesley.seigler@duke.edu>; Steven Gerrald <steven@leafenviro.com> Subject: RE: [External] Re: 2021 Emission Inventory, Duke University (3200144) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeff We sent a disk to Tom Anderson’s group. Do you need as well? Wes Brummer, P.E. Leaf Environmental & Engineering, P.C. Phone (919) 484-8536 Fax (919) 484-8540 wes@leafenviro.com Notice of Confidentiality The information contained in and transmitted with this electronic communication (including attachments) is subject to attorney and/or client privileges or is otherwise confidential. It is intended solely for the addressee designated by the sender. If you are not the intended addressee or receive this communication in error, any dissemination, distribution, copying, or other use or reliance on any information contained or transmitted herein by or to anyone other than the addressee designated by the sender is unauthorized and prohibited. If you receive it in error, please notify Leaf Environmental & Engineering, P.C., by return email or by telephone at (919) 484-8536. From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Friday, August 12, 2022 1:27 PM To: Wesley Brummer <wes@leafenviro.com>; Wesley Seigler <wesley.seigler@duke.edu>; Steven Gerrald <steven@leafenviro.com> Subject: RE: [External] Re: 2021 Emission Inventory, Duke University (3200144) Steven, Do you have an electronic copy of the file, please? If you sent it, I didn’t receive it. Thank you, Jeff From: Wesley Brummer <wes@leafenviro.com> Sent: Thursday, August 4, 2022 2:52 PM To: Harris, Jeff <jeff.harris@ncdenr.gov>; Wesley Seigler <wesley.seigler@duke.edu>; Steven Gerrald <steven@leafenviro.com> Subject: [External] Re: 2021 Emission Inventory, Duke University (3200144) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeff Got it. We’ll change the methodology going forward. Steven from our office will forward on an electronic copy. Wesley Z. Brummer, P.E. Vice President / Environmental Engineer (919) 484-8536 - Office (919) 389-4250 - Mobile wes@leafenviro.com From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Wednesday, August 3, 2022 10:08:02 AM To: Wesley Seigler <wesley.seigler@duke.edu> Cc: Wesley Brummer <wes@leafenviro.com> Subject: 2021 Emission Inventory, Duke University (3200144) Hi Wesley(s), I am reviewing the 2021 emission inventory for Duke University (3200144). For the most part, everything seems to be in order, but I do have one observation, and one request: 1. EPA's TANKS Model is obsolete, as it is no longer updated, and does not employ the most current AP-42 emission factors. Please update the tank emission calculation methodology used for future emissions inventories. I understand that this makes a minimal (at best) difference in VOC emissions, but TANKS is no longer an EPA supported/approved model. There is no need to re-do tanks emissions for this year. 2. Can you please send me an electronic copy of the EI submittal package for me to use to put together our e-file copy? Thanks, Jeff Please use Google Voice instead of Office Landline: (919) 307-6457 Listing of Emission Sources and Control Devices on Permit. See instructions COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO *ES ID on Air Permit *ES Description *CS ID *CS Description * CD ID's ES-7254-16 Diesel fuel-fired emergency generator (1370 hp), East Campus Steam Plant [NSPS IIII, GACT ZZZZ] ES-7254- EC1 Boiler #EC1: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC10 Boiler #EC10: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC11 Boiler #EC11: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC12 Boiler #EC12: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC13 Boiler #EC13: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC14 Boiler #EC14: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC15 Boiler #EC15: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC2 Boiler #EC2: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC3 Boiler #EC3: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC4 Boiler #EC4: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] 2 ES-7254- EC5 Boiler #EC5: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC6 Boiler #EC6: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC7 Boiler #EC7: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC8 Boiler #EC8: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7254- EC9 Boiler #EC9: One natural gas/propane-fired boiler (12.25 million Btu per hour heat input) with a low NOx burner [NSPS Dc] ES-7508-03 One diesel fuel-fired emergency generator (1109 hp), Duke Clinics West Infill ES-7514-01 One diesel-fired emergency generator (1700 hp), MSRB#2 ES-7516-01 One Diesel fuel-fired emergency generator (2520 hp), MSRB ES-7524-02 Diesel fuel-fired emergency generator (2,206 hp) located at MSRB No. 3 [NSPS IIII, GACT ZZZZ] ES-7524-03 One diesel-fired emergency generator (765 hp), Surgical Pavilion ES-7526-01 One diesel-fired emergency generator (1,592 hp), GSRB II ES-7531-01 One ethylene oxide sterilizer (8 cubic feet), Duke Eye Center [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7531-02 One ethylene oxide sterilizer (8 cubic feet), Duke Eye Center [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7531-03 One ethylene oxide sterilizer (8 cubic feet), Duke Eye Center [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7531-04 One Diesel fuel-fired emergency generator (968 hp), Duke Eye Center ES-7540-01 One Diesel fuel-fired emergency generator (1,591 hp), GSRB I ES-7542-01 One Diesel fuel-fired emergency generator (1586 hp), CCIF No. 1 ES-7542-02 One Diesel fuel-fired emergency generator (1586 hp), CCIF No. 2 ES-7547-01 One diesel fuel-fired emergency generator (1,115 hp), Duke Hospital North No. 1 ES-7547-02 One diesel fuel-fired emergency generator (1,115 hp), Duke Hospital North No. 2 ES-7547- 02B Diesel fuel-fired emergency generator (1,474 hp) Duke located at Hospital North No. 2 [NSPS IIII, GACT ZZZZ] 3 ES-7547- 03A One diesel fuel-fired emergency generator (2,937 hp), Duke Hospital North No. 3 ES-7547-04 One diesel fuel-fired emergency generator (1,115 hp), Duke Hospital North No. 4 ES-7547- 04B Diesel fuel-fired emergency generator (1,474 hp) located at Hospital North No. 4 [NSPS IIII, GACT ZZZZ] ES-7547-05 One Diesel fuel-fired emergency generator (2,304 hp), Duke Hospital North No. 5 ES-7547-06 One ethylene oxide sterilizer (8 cubic feet), Duke Hospital North [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7547-07 One ethylene oxide sterilizer (8 cubic feet), Duke Hospital North [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7547-08 One ethylene oxide sterilizer (8 cubic feet), Duke Hospital North [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7547-09 One ethylene oxide sterilizer (8 cubic feet), Duke Hospital North [GACT WWWWW] CS-9 Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit,Ethylene Oxide Abator Unit, CD-7531-A, CD- 7547-A, CD-7547- B ES-7549-01 One Diesel fuel-fired emergency generator (645 hp), DUMC, Jones Building ES-7555-01 Diesel-fired emergency generator (1141 hp), GHRB [NSPS IIII, GACT ZZZZ] ES-7558-01 Diesel fuel-fired emergency generator (2,937 hp) located at the new Duke Medical Pavilion (DMP) [NSPS IIII, GACT ZZZZ] ES-7558-02 Diesel fuel-fired emergency generator (2,937 hp) located at the new Duke Medical Pavilion (DMP) [NSPS IIII, GACT ZZZZ] ES-7558-03 Diesel fuel-fired emergency generator (2,937 hp) located at the new Duke Medical Pavilion (DMP) [NSPS IIII, GACT ZZZZ] ES-7559-01 One Diesel fuel-fired emergency generator (2937 hp), Cancer Center [NSPS IIII, GACT ZZZZ] ES-7561-01 Diesel fuel-fired emergency generator (619 hp) Hudson [NSPS IIII, GACT ZZZZ] ES-7579-01 One Diesel fuel-fired emergency generator (1809 hp), DUMC, Bryan Res. Bldg., No. 1 ES-7579-02 One Diesel fuel-fired emergency generator (1809 hp), DUMC, Bryan Res. Bldg., No. 2 ES-7579-03 Diesel fuel-fired emergency generator (1,809 hp) located at the Bryan Research Center [NSPS IIII, GACT ZZZZ] ES-7582-01 One Diesel fuel-fired emergency generator (516 hp), DUMC Parking Garage #3 4 ES-7593-01 One Diesel fuel-fired emergency generator (2068 hp), North Pavilion ES-7704-02 One Diesel fuel-fired emergency generator (764 hp), Perkins Library ES-7735-01 One Diesel fuel-fired emergency generator (1,085 hp), CIEMAS Building ES-7738-01 One Diesel fuel-fired emergency generator (2876 hp), French Science Center ES-7746-01 One Diesel fuel-fired emergency generator (850 hp), Tel. Com. Building ES-7754-01b Natural gas/No. 2 fuel oil-fired boiler (96.5 million Btu per hour maximum heat input) at the West Campus Steam Plant. [NSPS Dc] ES-7754-02b No. 2 fuel oil/natural gas-fired boiler (96.5 million Btu per hour maximum heat input) at the West Campus Steam Plant. [NSPS Dc] ES-7754-03b Boiler #3b: one natural gas/No. 2 fuel oil-fired boiler (96.5 million Btu per hour heat input) [NSPS Dc] ES-7754-04 Boiler #4: one No. 2 fuel oil/Low sulfur No. 4 fuel oil/natural gas/recycled No. 2/recycled low sulfur No. 4 oil-fired boiler (69.35 million Btu per hour heat input) [GACT JJJJJJ] ES-7754-05 Boiler #5: one No. 2 fuel oil/Low sulfur No. 4 fuel oil/natural gas/recycled No. 2/recycled low sulfur No. 4 oil-fired boiler (69.35 million Btu per hour heat input) [GACT JJJJJJ] ES-7754-06 Boiler #6: one natural gas/No. 2 fuel oil/Low sulfur No. 4 fuel oil/recycled No. 2/recycled low sulfur No. 4 oil- fired boiler (99.0 million Btu per hour heat input) [NSPS Dc, GACT JJJJJJ] ES-7754-09 One Diesel fuel-fired emergency generator (2168 hp), Steam Plant ES-7754-15 Diesel fuel-fired emergency generator (4,678 hp) West Campus Steam Plant [NSPS IIII, GACT ZZZZ] ES-7764-01 One Diesel fuel-fired emergency generator (772 hp), Primate Center ES-7765-01 One Diesel fuel-fired emergency generator (610 hp), Gross Chemistry ES-7776-02 One Diesel fuel-fired emergency generator (900 hp), Duke University, LSRC I (Indoors) ES-7777-01 One Diesel fuel-fired emergency generator (533 hp), Wilson Rec. ES-7795-01 One Diesel fuel-fired emergency generator (749 hp), WEL Dorm ES-7796-01 Diesel fuel-fired emergency generator (4,678 hp) West Campus Chilled Water Plant [NSPS IIII, GACT ZZZZ] 5 ES-7855-01 Diesel fuel-fired non emergency generator (4678 bhp) located at the West Campus Chilled Water Plant No. 2 [NSPS IIII, GACT ZZZZ] ES-7855-02 Diesel fuel-fired non emergency generator (4678 bhp) located at the West Campus Chilled Water Plant No. 2 [NSPS IIII, GACT ZZZZ] ES-7855-03 Diesel fuel-fired non emergency generator (4678 bhp) located at the West Campus Chilled Water Plant No. 2 [NSPS IIII, GACT ZZZZ] ES-7855-04 Diesel fuel-fired non emergency generator (4678 bhp) located at the West Campus Chilled Water Plant No. 2 [NSPS IIII, GACT ZZZZ] ES-7XXA- 01 Diesel fuel-fired emergency generators (2995 hp) located at A/MC 1 [NSPS IIII, GACT ZZZZ] ES-7XXB-01 Diesel fuel-fired emergency generators (2995 hp) located at A/MC 2 [NSPS IIII, GACT ZZZZ] ES-7XXC-01 Diesel fuel-fired emergency generators (1600 hp) located at A/MC 3 [NSPS IIII, GACT ZZZZ] ES-7XXD- 01 Diesel fuel-fired emergency generators (1600 hp) located at A/MC 4 [NSPS IIII, GACT ZZZZ] ES-7XXE-01 Diesel fuel-fired emergency generators (1600 hp) located at A/MC 5 [NSPS IIII, GACT ZZZZ] ES-7XXF-01 Diesel fuel-fired emergency generators (1600 hp) located at A/MC 6 [NSPS IIII, GACT ZZZZ] ES-7XXG- 01 Diesel fuel-fired emergency generators (749 hp) located at A/MC 7 [NSPS IIII, GACT ZZZZ] ES-7XXH- 01 Diesel fuel-fired emergency generators (749 hp) located at A/MC 8 [NSPS IIII, GACT ZZZZ] ES-7XXI-01 Diesel fuel-fired emergency generators (749 hp) located at A/MC 9 [NSPS IIII, GACT ZZZZ] ES-7XXJ-01 Diesel fuel-fired emergency generators (749 hp) located at A/MC 10 [NSPS IIII, GACT ZZZZ] I-030 Paint spray booth I-040 Paint spray booth I-7196-01 Diesel fuel-fired emergency generator (135 hp), Jordan Building I-7198-01 Natural gas-fired emergency generator (176 hp), Nasher Art Museum I-7224-01 Diesel fuel-fired emergency generator (325 hp), East Campus Science Building [NSPS IIII] I-7245-01 Diesel fuel-fired emergency generator (325 hp), East Dorm Equipment Building I-7505-01 Diesel fuel-fired emergency generator (449 hp), Clinical Research II 6 I-7508-01 Diesel fuel-fired emergency generator (300 hp), Duke Hospital S. 57 Addition I-7508-04 Diesel fuel-fired emergency generator (156 hp), Duke Hospital S. Cobalt I-7517-01 Diesel fuel-fired emergency generator (64 hp), DUMC, RP-1 I-7518-01 Diesel fuel-fired emergency generator (349 hp), Nocturnal Lab I-7519-01 Diesel fuel-fired emergency generator (349 hp), RP #3 I-7524-02 Diesel fuel-fired emergency generator (269 hp), Surgical Pavilion (Vivarium) I-7538-01 Diesel fuel-fired emergency generator (455 hp), DUMC Parking Garage #1 I-7552-01 Diesel fuel-fired emergency generator (50 hp), DUMC, BMT Dialysis I-7557-01 Natural gas-fired emergency generator (333 hp), Research Drive Garage I-7577-01 Diesel fuel-fired emergency generator (192 hp), DUMC, Environmental Safety I-7583-01 Diesel fuel-fired emergency generator (165 hp), Lennox Baker Hospital I-7589-01 Diesel fuel-fired emergency generator (32 hp), DUMC, CFL - Fitness I-7636-01 Natural gas-fired emergency generator (43 hp), Elder Street I-7686-01 Diesel fuel-fired emergency generator (86 hp), Aesthetics I-7708-01 Diesel fuel-fired emergency generator (155 hp), Divinity Addition I-7725-01 Diesel fuel-fired emergency generator (277 hp), Public Policy Building I-7733-01 Diesel fuel-fired emergency generator (130 hp), Center for Athletic Excellence [NSPS IIII] I-7739-01 Diesel fuel-fired emergency generator (122 hp), Rubenstein Hall I-7740-01 Diesel fuel-fired emergency generator (18 hp), Finch-Yeager I-7740-02 Propane-fired emergency generator (15 hp), Free Electron Laser Lab I-7741-01 Diesel fuel-fired emergency generator (250 hp), Schwartz-Butters I-7743-01 Diesel fuel-fired emergency generator (40 hp), Cameron Indoor Stadium I-7756-01 Diesel fuel-fired emergency generator (354 hp), North Building I-7758-01 Diesel fuel-fired emergency generator (68 hp), Biosciences Building I-7760-01 Diesel fuel-fired emergency generator (380 hp), Fuqua School I-7760-02 Diesel fuel-fired emergency generator (779 hp), Fuqua School of Business 2 [NSPS IIII] 7 I-7766-01 Diesel fuel-fired emergency generator (300 hp), Teer Building I-7776-01 Diesel fuel-fired emergency generator (465 hp), Duke Hospital LSRC II I-7791-01 Diesel fuel-fired emergency generator (413 hp), Bryan Center I-8092-01 Diesel fuel-fired emergency generator (349 hp), Rutherford Street I-Nursing One Natural gas-fired emergency generator (80 hp), Nursing School I-Tanks Fuel storage tanks 8 Emission Source & Operating Scenario List - See Instructions COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO *ES Group ID *ES ID *OS ID *OS Description GR58 ES-7514-01, ES-7559-01, ES-7738-01, ES-7XXA-01, ES-7XXB-01, ES-7XXC- 01, ES-7XXD-01, ES- 7XXE-01, ES-7XXF-01, ES-7XXG-01, ES-7XXH- 01, ES-7XXI-01, ES-7XXJ- 01 64 Diesel Fired Emergency Generators Over 600 hp/ NSR Avoidance GR62 I-7198-01, I-7557-01, I- 7636-01, I-Nursing 60 Emergency Generator (up to 600 hp, natural gas-fired) GR63 ES-7254-EC1, ES-7254- EC10, ES-7254-EC11, ES- 7254-EC12, ES-7254-EC13, ES-7254-EC14, ES-7254- EC15, ES-7254-EC2, ES- 7254-EC3, ES-7254-EC4, ES-7254-EC5, ES-7254- EC6, ES-7254-EC7, ES- 7254-EC8, ES-7254-EC9 53 15 12.25 mmBTU/hr watertube boilers 56 Propane GR64 ES-7855-01, ES-7855-02, ES-7855-03, ES-7855-04 54 Four 4,678 HP Emergency Generators G-69 ES-7777-01, ES-7582-01, I- 7196-01, I-7224-01, I-7245- 01, I-7505-01, I-7508-01, I- 7508-04, I-7517-01, I-7518- 01, I-7519-01, I-7524-02, I- 7538-01, I-7552-01, I-7577- 01, I-7583-01, I-7589-01, I- 7686-01, I-7708-01, I-7725- 01, I-7733-01, I-7739-01, I- 7740-01, I-7740-02, I-7741- 01, I-7743-01, I-7756-01, I- 7758-01, I-7760-01, I-7766- 01, I-7776-01, I-7791-01, I- 8092-01 58 Emergency Generators up to 600 hp, non- NSR G-70 I-030, I-040 24 Paint Spray Booths G-84 ES-7531-01, ES-7531-02, ES-7531-03, ES-7547-06, ES-7547-07, ES-7547-08, ES-7547-09 57 Ethylene Oxide Sterilizers 9 G-86 ES-7254-16, ES-7508-03, ES-7516-01, ES-7524-02, ES-7524-03, ES-7526-01, ES-7531-04, ES-7540-01, ES-7542-01, ES-7542-02, ES-7555-01, ES-7558-01, ES-7558-02, ES-7558-03, ES-7547-01, ES-7547-02, ES-7547-02B, ES-7547- 03A, ES-7547-04B, ES- 7547-05, ES-7549-01, ES- 7561-01, ES-7579-01, ES- 7704-02, ES-7735-01, ES- 7746-01, ES-7754-09, ES- 7754-15, ES-7764-01, ES- 7765-01, ES-7776-02, ES- 7579-02, ES-7579-03, ES- 7593-01, ES-7795-01, ES- 7796-01, I-7760-02 76 emergency diesel generators over 600 hp ES-7547-04 NONE NONE ES-7754-01b 66 Combustion of No. 2 Fuel Oil to generate steam. 67 Combustion of Natural Gas to generate steam ES-7754-02b 68 Combustion of No. 2 Fuel Oil to generate steam. 69 Combustion of Natural Gas to generate steam. ES-7754-03b 61 Boiler No. 3: Natural gas combustion 71 Combustion of No. 2 fuel Oil to generate steam. ES-7754-04 7 Boiler No. 4: No. 2 fuel oil combustion 8 Boiler No. 4: natural gas combustion ES-7754-05 9 Boiler No. 5: No. 2 fuel oil combustion 10 Boiler No. 5: natural gas combustion ES-7754-06 11 [NSPS] Boiler No. 6: natural gas combustion 12 [NSPS] Boiler No. 6: No.2 fuel oil combustion I-Tanks 15 Fuel storage tanks 10 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR58 consisting of ES-7514-01, ES-7559-01, ES-7738-01, ES- 7XXA-01, ES-7XXB-01, ES-7XXC-01, ES-7XXD-01, ES-7XXE-01, ES-7XXF-01, ES-7XXG-01, ES-7XXH-01, ES-7XXI-01, ES-7XXJ-01 2. Emission Source Description :Emergency Gens (NSR Avoidance Over 600 hp) 3. Operating Scenario ID/ Description: OS - 64/Diesel Fired Emergency Generators Over 600 hp/ NSR Avoidance 4. SCC Number/Description:20200401/Diesel ; Diesel 5. Throughput/units in 2021: (e.g. production or fuel use): 159073 HP-HR/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7514 VERTICAL STACK 10 1.34 750 127.63 10800 Generator Emissions 7738 VERTICAL STACK 10 1.34 750 180.75 15295 Generator Emissions 7559 VERTICAL STACK 10 1.34 750 180.75 15295 Generator Emissions 11 12 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 1 ) Days per Week ( 1 ) Weeks per Year ( 50 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 64 Emission Source/Group ID: GR58 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.44 09 NOx NOx 1.91 09 TSP TSP 0.06 09 PM10 PM10 0.06 09 PM2.5 PM2.5 0.06 09 SO2 SO2 0 08 VOC VOC 0.05 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.0281 09 Acrolein 107-02-8 0.00877 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00445 09 Benzene 71-43-2 0.864 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00029 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00334 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00334 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00334 09 13 Formaldehyde 50-00-0 0.0879 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.01 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00668 09 Mercury, vapor (Component of HGC)7439-97-6 0.00334 09 Naphthalene (Component of POMTV)91-20-3 0.145 09 Nickel metal (Component of NIC)7440-02-0 0.00334 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.236 09 Selenium Compounds SEC 0.0167 09 Toluene 108-88-3 0.313 09 Xylene 1330-20-7 0.215 09 14 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR62 consisting of I-7198-01, I-7557-01, I-7636-01, I-Nursing 2. Emission Source Description :Emergency Generators (up to 600 hp, Natural Gas) 3. Operating Scenario ID/ Description: OS - 60/Emergency Generator (up to 600 hp, natural gas-fired) 4. SCC Number/Description:20300201/Natural Gas ; Reciprocating 5. Throughput/units in 2021: (e.g. production or fuel use): 11195 HP-HR/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7198 VERTICAL STACK 10 0.5 1219 77.9 917.73 Generator Emissions 7557 VERTICAL STACK 10 0.5 1219 77.9 917.73 Generator Emissions 7636 VERTICAL STACK 10 0.5 1219 77.9 917.73 Generator Emissions 15 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 1 ) Days per Week ( 1 ) Weeks per Year ( 50 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 60 Emission Source/Group ID: GR62 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.05 09 NOx NOx 0.03 09 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.0795 09 Acrolein 107-02-8 0.0749 09 Benzene 71-43-2 0.045 09 Carbon tetrachloride 56-23-5 0.0005 09 Chlorobenzene 108-90-7 0.00037 09 Chloroform 67-66-3 0.00039 09 Ethyl benzene 100-41-4 0.00071 09 Ethylene dibromide 106-93-4 0.00061 09 Formaldehyde 50-00-0 0.584 09 Methanol 67-56-1 0.0872 09 Methylene chloride 75-09-2 0.00117 09 Naphthalene (Component of POMTV)91-20-3 0.00277 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00402 09 Styrene 100-42-5 0.00034 09 16 Toluene 108-88-3 0.0159 09 Vinyl chloride 75-01-4 0.00021 09 Xylene 1330-20-7 0.00555 09 17 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR63 consisting of ES-7254-EC1, ES-7254-EC10, ES-7254- EC11, ES-7254-EC12, ES-7254-EC13, ES-7254-EC14, ES-7254-EC15, ES-7254-EC2, ES-7254-EC3, ES-7254-EC4, ES-7254-EC5, ES-7254- EC6, ES-7254-EC7, ES-7254-EC8, ES-7254-EC9 2. Emission Source Description :East Campus Miura Boilers 3. Operating Scenario ID/ Description: OS - 53/15 12.25 mmBTU/hr watertube boilers 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 395.11 E6FT3S/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description ES7254 04 VERTICAL STACK 35 4 320.3 10.41 7848.95 Boilers 10, 11, & 12 ES- 725403 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 7, 8, & 9 ES- 725401 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 1, 2, & 3 ES- 725402 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 4, 5, & 6 18 ES- 725405 VERTICAL STACK 35 4 320.3 10.41 7848.95 Boilers 13, 14, & 15 19 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 53 Emission Source/Group ID: GR63 Jan-Feb + Dec 2021 38%March-May 2021 19%June-Aug. 2021 15%Sept.-Nov. 2021 28% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 16.59 09 NOx NOx 9.88 29 TSP TSP 0.1 09 PM10 PM10 0.1 09 PM2.5 PM2.5 0.08 09 SO2 SO2 0.12 09 VOC VOC 1.09 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00601 09 Acrolein 107-02-8 0.00711 09 Ammonia (as NH3)7664-41-7 1264 09 Benzene 71-43-2 0.83 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00047 09 Cobalt Unlisted Compound (Specify & Component of COC) COC- Other 0.0332 09 Formaldehyde 50-00-0 29.6 09 Hexane, n-110-54-3 711 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.198 09 Naphthalene (Component of POMTV)91-20-3 0.241 09 Selenium Compounds SEC 0.00948 09 20 Toluene 108-88-3 1.34 09 21 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR63 consisting of ES-7254-EC1, ES-7254-EC10, ES-7254- EC11, ES-7254-EC12, ES-7254-EC13, ES-7254-EC14, ES-7254-EC15, ES-7254-EC2, ES-7254-EC3, ES-7254-EC4, ES-7254-EC5, ES-7254- EC6, ES-7254-EC7, ES-7254-EC8, ES-7254-EC9 2. Emission Source Description :East Campus Miura Boilers 3. Operating Scenario ID/ Description: OS - 56/Propane 4. SCC Number/Description:10500210/Liquified Petroleum Gas (LPG) ; Space Heaters 5. Throughput/units in 2021: (e.g. production or fuel use): 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description ES- 725402 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 4, 5, & 6 ES7254 04 VERTICAL STACK 35 4 320.3 10.41 7848.95 Boilers 10, 11, & 12 ES- 725403 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 7, 8, & 9 ES- 725405 VERTICAL STACK 35 4 320.3 10.41 7848.95 Boilers 13, 14, & 15 22 ES- 725401 VERTICAL STACK 35 4 320.3 10.4 7841.41 Boilers 1, 2, & 3 23 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 56 Emission Source/Group ID: GR63 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 24 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group GR64 consisting of ES-7855-01, ES-7855-02, ES-7855-03, ES- 7855-04 2. Emission Source Description :Emergency Generators (West Campus CWP) 3. Operating Scenario ID/ Description: OS - 54/Four 4,678 HP Emergency Generators 4. SCC Number/Description:20100102/Distillate Oil (Diesel) ; Reciprocating 5. Throughput/units in 2021: (e.g. production or fuel use): 374240 HP-HR/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7855-02 VERTICAL STACK 10 1.99 977 132.84 24791 Generator Emissions 7855-03 VERTICAL STACK 10 1.99 977 132.84 24791 Generator Emissions 7855-01 VERTICAL STACK 10 1.99 977 132.84 24791 Generator Emissions 7855-04 VERTICAL STACK 10 1.99 977 132.84 24791 Generator Emissions 25 26 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 1 ) Days per Week ( 1 ) Weeks per Year ( 50 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 54 Emission Source/Group ID: GR64 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 1.03 09 NOx NOx 4.49 09 TSP TSP 0.13 09 PM10 PM10 0.13 09 PM2.5 PM2.5 0.13 09 SO2 SO2 0 08 VOC VOC 0.12 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.066 09 Acrolein 107-02-8 0.0206 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.0105 09 Benzene 71-43-2 2.03 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00067 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00786 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00079 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00079 09 27 Formaldehyde 50-00-0 0.207 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.0236 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.0157 09 Mercury, vapor (Component of HGC)7439-97-6 0.00079 09 Naphthalene (Component of POMTV)91-20-3 0.341 09 Nickel metal (Component of NIC)7440-02-0 0.00079 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.555 09 Selenium Compounds SEC 0.0393 09 Toluene 108-88-3 0.736 09 Xylene 1330-20-7 0.506 09 28 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group G-69 consisting of ES-7777-01, ES-7582-01, I-7196-01, I-7224- 01, I-7245-01, I-7505-01, I-7508-01, I-7508-04, I-7517-01, I-7518-01, I- 7519-01, I-7524-02, I-7538-01, I-7552-01, I-7577-01, I-7583-01, I-7589- 01, I-7686-01, I-7708-01, I-7725-01, I-7733-01, I-7739-01, I-7740-01, I- 7740-02, I-7741-01, I-7743-01, I-7756-01, I-7758-01, I-7760-01, I-7766- 01, I-7776-01, I-7791-01, I-8092-01 2. Emission Source Description :Emergency Generators (Up to 600 hp, diesel-fired) 3. Operating Scenario ID/ Description: OS - 58/Emergency Generators up to 600 hp, non-NSR 4. SCC Number/Description:20300101/Distillate Oil (Diesel) ; Reciprocating 5. Throughput/units in 2021: (e.g. production or fuel use): 103955 HP-HR/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description F5 VERTICAL STACK 10 0.67 865 146.78 3105 Generator Emissions 29 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 1 ) Days per Week ( 1 ) Weeks per Year ( 50 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 58 Emission Source/Group ID: G-69 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.35 09 NOx NOx 1.61 09 TSP TSP 0.11 09 PM10 PM10 0.11 09 PM2.5 PM2.5 0.11 09 SO2 SO2 08 VOC VOC 0.13 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.558 09 Acrolein 107-02-8 0.0673 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00291 09 Benzene 71-43-2 0.679 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00014 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00218 09 Butadiene, 1,3-106-99-0 0.0285 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00218 09 30 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00218 09 Formaldehyde 50-00-0 0.859 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00655 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00437 09 Mercury, vapor (Component of HGC)7439-97-6 0.00218 09 Naphthalene (Component of POMTV)91-20-3 0.0617 09 Nickel metal (Component of NIC)7440-02-0 0.00218 09 Selenium Compounds SEC 0.0109 09 Toluene 108-88-3 0.298 09 Xylene 1330-20-7 0.207 09 31 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group G-70 consisting of I-030, I-040 2. Emission Source Description :Paint Spray Booths 3. Operating Scenario ID/ Description: OS - 24/Paint Spray Booths 4. SCC Number/Description:40200101/Surface Coating Application - General ; Paint: Solvent-base 5. Throughput/units in 2021: (e.g. production or fuel use): 12.75 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 020 VERTICAL STACK 40 3 68 33 13995.79 Paint Booth Stack 030 HORIZONTAL STACK 15 3.1 68 13 5887.18 Paint Booth Stack 32 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 8 ) Days per Week ( 5 ) Weeks per Year ( 50 ) 11. Typical Start & End Times For Operating Scenario: Start: 700 End: 1600 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 24 Emission Source/Group ID: G-70 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.01 03 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Ethyl benzene 100-41-4 0.192 03 Ethylene glycol 107-21-1 0.63 03 Glycol Ethers, Unlisted (Specify & Component of GLYET) (See http://daq.state.nc.us/toxic s/glycol/) GLYET- Other 0.42 03 Hexamethylene-1,6- diisocyanate 822-06-0 0.0125 08 Methyl ethyl ketone 78-93-3 0 03 Toluene 108-88-3 0 03 Xylene 1330-20-7 0 03 33 8. Control Device Information : 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group G-84 consisting of ES-7531-01, ES-7531-02, ES-7531-03, ES- 7547-06, ES-7547-07, ES-7547-08, ES-7547-09 2. Emission Source Description :Seven Ethylene Oxide Sterilizers 3. Operating Scenario ID/ Description: OS - 57/Ethylene Oxide Sterilizers 4. SCC Number/Description:31502001/Health Care - Hospitals ; Sterilization with Ethylene Oxide 5. Throughput/units in 2021: (e.g. production or fuel use): 196 LB/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): 100 Order CS-ID CD ID (as listed in permit) Control Device Description 1 CS-9 CD-7531-A Ethylene Oxide Abator Unit 2 CS-9 CD-7547-A Ethylene Oxide Abator Unit 3 CS-9 CD-7547-B Ethylene Oxide Abator Unit ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7531-A VERTICAL STACK 10 0.25 390 17 50.06 Sterilizers 7547- A&B VERTICAL STACK 10 0.25 390 17 50.06 Sterilizers 34 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 57 Emission Source/Group ID: G-84 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 0 NOx NOx 08 0 TSP TSP 08 0 PM10 PM10 08 0 PM2.5 PM2.5 08 0 SO2 SO2 08 0 VOC VOC 0 02 99.9 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Ethylene oxide 75-21-8 0.196 02 99.9 35 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID Group G-86 consisting of ES-7254-16, ES-7508-03, ES-7516-01, ES- 7524-02, ES-7524-03, ES-7526-01, ES-7531-04, ES-7540-01, ES-7542- 01, ES-7542-02, ES-7555-01, ES-7558-01, ES-7558-02, ES-7558-03, ES-7547-01, ES-7547-02, ES-7547-02B, ES-7547-03A, ES-7547-04B, ES-7547-05, ES-7549-01, ES-7561-01, ES-7579-01, ES-7704-02, ES- 7735-01, ES-7746-01, ES-7754-09, ES-7754-15, ES-7764-01, ES-7765- 01, ES-7776-02, ES-7579-02, ES-7579-03, ES-7593-01, ES-7795-01, ES-7796-01, I-7760-02 2. Emission Source Description :Emergency Gens over 600 hp 3. Operating Scenario ID/ Description: OS - 76/emergency diesel generators over 600 hp 4. SCC Number/Description:20200102/Distillate Oil (Diesel) ; Reciprocating 5. Throughput/units in 2021: (e.g. production or fuel use): 1238689 HP-HR/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description F6 VERTICAL STACK 10 1.34 750 127.63 10800 Generator Emissions F7 HORIZONTAL STACK 17 1.67 977 188.63 24791 Generator Emissions 36 37 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 76 Emission Source/Group ID: G-86 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 3.41 09 NOx NOx 14.86 09 TSP TSP 0.43 09 PM10 PM10 0.43 09 PM2.5 PM2.5 0.43 09 SO2 SO2 0.01 09 VOC VOC 0.4 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.219 09 Acrolein 107-02-8 0.0683 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.0347 09 Benzene 71-43-2 6.73 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00223 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.026 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.026 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.026 09 38 Formaldehyde 50-00-0 0.684 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.078 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.052 09 Mercury, vapor (Component of HGC)7439-97-6 0.026 09 Naphthalene (Component of POMTV)91-20-3 1.13 09 Nickel metal (Component of NIC)7440-02-0 0.026 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 1.84 09 Selenium Compounds SEC 0.13 09 Toluene 108-88-3 2.44 09 Xylene 1330-20-7 1.67 09 39 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-01b 2. Emission Source Description :Natural gas/No. 2 fuel oil fired boiler (96.5 million BTU/hr maximum heat input) at the West Campus Steam Plant. [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 66/Combustion of No. 2 Fuel Oil to generate steam. 4. SCC Number/Description:10300502/Distillate Oil ; 10-100 Million Btu/hr ** 5. Throughput/units in 2021: (e.g. production or fuel use): 907 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-1b VERTICAL STACK WITH RAIN CAP 35 3.5 450 39.7 22917.52 Boiler 1 Stack 40 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 47 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 66 Emission Source/Group ID: ES-7754- 01b Jan-Feb + Dec 2021 0%March-May 2021 0%June-Aug. 2021 100%Sept.-Nov. 2021 0% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0 08 NOx NOx 0.01 29 TSP TSP 0 08 PM10 PM10 0 08 PM2.5 PM2.5 0 08 SO2 SO2 0 08 VOC VOC 0 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00051 09 Benzene 71-43-2 0.00249 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00038 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00038 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00038 09 Ethyl benzene 100-41-4 0.00074 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.0338 09 Formaldehyde 50-00-0 0.0435 09 41 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00114 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00076 09 Mercury, vapor (Component of HGC)7439-97-6 0.00038 09 Methyl chloroform 71-55-6 0.00021 09 Naphthalene (Component of POMTV)91-20-3 0.0003 09 Nickel metal (Component of NIC)7440-02-0 0.00038 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00299 09 Selenium Compounds SEC 0.0019 09 Toluene 108-88-3 0.0723 09 Xylene 1330-20-7 0.00127 09 42 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-01b 2. Emission Source Description :Natural gas/No. 2 fuel oil fired boiler (96.5 million BTU/hr maximum heat input) at the West Campus Steam Plant. [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 67/Combustion of Natural Gas to generate steam 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 386106962 FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-1b VERTICAL STACK WITH RAIN CAP 35 3.5 450 39.7 22917.52 Boiler 1 Stack 43 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 47 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 67 Emission Source/Group ID: ES-7754- 01b Jan-Feb + Dec 2021 27%March-May 2021 12%June-Aug. 2021 27%Sept.-Nov. 2021 34% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 16.22 09 NOx NOx 9.65 29 TSP TSP 0.1 09 PM10 PM10 0.1 09 PM2.5 PM2.5 0.08 09 SO2 SO2 0.12 09 VOC VOC 1.06 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00587 09 Acrolein 107-02-8 0.00695 09 Ammonia (as NH3)7664-41-7 1236 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.0772 09 Benzene 71-43-2 0.811 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00046 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00463 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.425 09 44 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.541 09 Cobalt Unlisted Compound (Specify & Component of COC) COC- Other 0.0324 09 Formaldehyde 50-00-0 29 09 Hexane, n-110-54-3 695 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.193 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.147 09 Mercury, vapor (Component of HGC)7439-97-6 0.1 09 Naphthalene (Component of POMTV)91-20-3 0.236 09 Nickel metal (Component of NIC)7440-02-0 0.811 09 Selenium Compounds SEC 0.00927 09 Toluene 108-88-3 1.31 09 45 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-02b 2. Emission Source Description :Natural gas/No. 2 fuel oil fired boiler (96.5 million BTU/hr maximum heat input) at the West Campus Steam Plant. [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 68/Combustion of No. 2 Fuel Oil to generate steam. 4. SCC Number/Description:10300502/Distillate Oil ; 10-100 Million Btu/hr ** 5. Throughput/units in 2021: (e.g. production or fuel use): 1006 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-2b VERTICAL STACK WITH RAIN CAP 35 3.5 450 39.7 22917.52 Boiler 2 Stack 46 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 48 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 68 Emission Source/Group ID: ES-7754- 02b Jan-Feb + Dec 2021 0%March-May 2021 0%June-Aug. 2021 0%Sept.-Nov. 2021 100% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0 09 NOx NOx 0.01 29 TSP TSP 0 09 PM10 PM10 0 08 PM2.5 PM2.5 0 08 SO2 SO2 0 08 VOC VOC 0 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00056 09 Benzene 71-43-2 0.00277 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00042 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00042 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00042 09 Ethyl benzene 100-41-4 0.00082 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.0375 09 Formaldehyde 50-00-0 0.0483 09 47 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00127 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00085 09 Mercury, vapor (Component of HGC)7439-97-6 0.00042 09 Methyl chloroform 71-55-6 0.00024 09 Naphthalene (Component of POMTV)91-20-3 0.00034 09 Nickel metal (Component of NIC)7440-02-0 0.00042 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00332 09 Selenium Compounds SEC 0.00211 09 Toluene 108-88-3 0.0802 09 Xylene 1330-20-7 0.00141 09 48 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-02b 2. Emission Source Description :Natural gas/No. 2 fuel oil fired boiler (96.5 million BTU/hr maximum heat input) at the West Campus Steam Plant. [NSPS Dc] 3. Operating Scenario ID/ Description: OS - 69/Combustion of Natural Gas to generate steam. 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 366684819 FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-2b VERTICAL STACK WITH RAIN CAP 35 3.5 450 39.7 22917.52 Boiler 2 Stack 49 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 48 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 69 Emission Source/Group ID: ES-7754- 02b Jan-Feb + Dec 2021 28%March-May 2021 18%June-Aug. 2021 22%Sept.-Nov. 2021 32% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 15.4 09 NOx NOx 9.17 29 TSP TSP 0.1 09 PM10 PM10 0.1 09 PM2.5 PM2.5 0.08 09 SO2 SO2 0.11 09 VOC VOC 1.01 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00557 09 Acrolein 107-02-8 0.0066 09 Ammonia (as NH3)7664-41-7 1173 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.0733 09 Benzene 71-43-2 0.77 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00044 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.0044 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.403 09 50 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.513 09 Cobalt Unlisted Compound (Specify & Component of COC) COC- Other 0.0308 09 Formaldehyde 50-00-0 27.5 09 Hexane, n-110-54-3 660 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.183 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.139 09 Mercury, vapor (Component of HGC)7439-97-6 0.0953 09 Naphthalene (Component of POMTV)91-20-3 0.224 09 Nickel metal (Component of NIC)7440-02-0 0.77 09 Selenium Compounds SEC 0.0088 09 Toluene 108-88-3 1.25 09 51 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-03b 2. Emission Source Description :Boiler #3b: one natural gas/No. 2 fuel oil-fired boiler (96.5 million Btu per hour heat input) [NSPS] 3. Operating Scenario ID/ Description: OS - 61/Boiler No. 3: Natural gas combustion 4. SCC Number/Description:10300602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 235005028 FT3/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-3b VERTICAL STACK WITH RAIN CAP 50 3.5 450 39.7 22917.52 Boiler 3 Stack 52 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 32 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 61 Emission Source/Group ID: ES-7754- 03b Jan-Feb + Dec 2021 35%March-May 2021 24%June-Aug. 2021 14%Sept.-Nov. 2021 27% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 9.87 09 NOx NOx 5.88 29 TSP TSP 0.06 09 PM10 PM10 0.06 09 PM2.5 PM2.5 0.05 09 SO2 SO2 0.07 09 VOC VOC 0.65 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00357 09 Acrolein 107-02-8 0.00423 09 Ammonia (as NH3)7664-41-7 752 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.047 09 Benzene 71-43-2 0.494 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00028 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00282 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.259 09 53 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.329 09 Cobalt Unlisted Compound (Specify & Component of COC) COC- Other 0.0197 09 Formaldehyde 50-00-0 17.6 09 Hexane, n-110-54-3 423 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.118 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.0893 09 Mercury, vapor (Component of HGC)7439-97-6 0.0611 09 Naphthalene (Component of POMTV)91-20-3 0.143 09 Nickel metal (Component of NIC)7440-02-0 0.494 09 Selenium Compounds SEC 0.00564 09 Toluene 108-88-3 0.799 09 54 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-03b 2. Emission Source Description :Boiler #3b: one natural gas/No. 2 fuel oil-fired boiler (96.5 million Btu per hour heat input) [NSPS] 3. Operating Scenario ID/ Description: OS - 71/Combustion of No. 2 fuel Oil to generate steam. 4. SCC Number/Description:10300502/Distillate Oil ; 10-100 Million Btu/hr ** 5. Throughput/units in 2021: (e.g. production or fuel use): 826 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-3b VERTICAL STACK WITH RAIN CAP 50 3.5 450 39.7 22917.52 Boiler 3 Stack 55 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 32 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 71 Emission Source/Group ID: ES-7754- 03b Jan-Feb + Dec 2021 0%March-May 2021 0%June-Aug. 2021 0%Sept.-Nov. 2021 100% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0 09 NOx NOx 0.01 29 TSP TSP 0 09 PM10 PM10 0 08 PM2.5 PM2.5 0 08 SO2 SO2 0 08 VOC VOC 0 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00046 09 Benzene 71-43-2 0.00227 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00035 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00035 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00035 09 Ethyl benzene 100-41-4 0.00068 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.0308 09 Formaldehyde 50-00-0 0.0396 09 56 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00104 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00069 09 Mercury, vapor (Component of HGC)7439-97-6 0.00035 09 Methyl chloroform 71-55-6 0.0002 09 Naphthalene (Component of POMTV)91-20-3 0.00028 09 Nickel metal (Component of NIC)7440-02-0 0.00035 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00273 09 Selenium Compounds SEC 0.00173 09 Toluene 108-88-3 0.0658 09 Xylene 1330-20-7 0.00116 09 57 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-04 2. Emission Source Description :Boiler No. 4: one No. 2 fuel oil/natural gas-fired boiler (69.35 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 7/Boiler No. 4: No. 2 fuel oil combustion 4. SCC Number/Description:10200501/Distillate Oil (No. 1 & 2) ; Grades 1 and 2 Oil 5. Throughput/units in 2021: (e.g. production or fuel use): 988 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-04 VERTICAL STACK WITH RAIN CAP 25 3 450 45.7 19382.05 Boiler 4 Stack 58 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 4 ) Weeks per Year ( 1 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 7 Emission Source/Group ID: ES-7754- 04 Jan-Feb + Dec 2021 4%March-May 2021 0%June-Aug. 2021 64%Sept.-Nov. 2021 32% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 0.01 09 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00055 09 Benzene 71-43-2 0.00272 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00042 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00042 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00042 09 Ethyl benzene 100-41-4 0.00081 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.0369 09 Formaldehyde 50-00-0 0.0474 09 59 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00124 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00083 09 Mercury, vapor (Component of HGC)7439-97-6 0.00042 09 Methyl chloroform 71-55-6 0.00023 09 Naphthalene (Component of POMTV)91-20-3 0.00033 09 Nickel metal (Component of NIC)7440-02-0 0.00042 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.00326 09 Selenium Compounds SEC 0.00207 09 Toluene 108-88-3 0.0787 09 Xylene 1330-20-7 0.00138 09 60 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-04 2. Emission Source Description :Boiler No. 4: one No. 2 fuel oil/natural gas-fired boiler (69.35 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 8/Boiler No. 4: natural gas combustion 4. SCC Number/Description:10200602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-04 VERTICAL STACK WITH RAIN CAP 25 3 450 45.7 19382.05 Boiler 4 Stack 61 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 8 Emission Source/Group ID: ES-7754- 04 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 62 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-05 2. Emission Source Description :Boiler No. 5: one No. 2 fuel oil/natural gas-fired boiler (69.35 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 9/Boiler No. 5: No. 2 fuel oil combustion 4. SCC Number/Description:10200501/Distillate Oil (No. 1 & 2) ; Grades 1 and 2 Oil 5. Throughput/units in 2021: (e.g. production or fuel use): 13267 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-05 VERTICAL STACK WITH RAIN CAP 25 3 450 45.7 19385 Boiler 5 Stack 63 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 6 ) Weeks per Year ( 1 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 9 Emission Source/Group ID: ES-7754- 05 Jan-Feb + Dec 2021 0%March-May 2021 95%June-Aug. 2021 1%Sept.-Nov. 2021 4% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 0.03 08 NOx NOx 0.13 09 TSP TSP 0.02 08 PM10 PM10 0.02 08 PM2.5 PM2.5 0.01 08 SO2 SO2 0 08 VOC VOC 0 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00743 09 Benzene 71-43-2 0.0365 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00557 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00557 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00557 09 Ethyl benzene 100-41-4 0.0108 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.495 09 Formaldehyde 50-00-0 0.637 09 64 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.0167 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.0111 09 Mercury, vapor (Component of HGC)7439-97-6 0.00557 09 Methyl chloroform 71-55-6 0.00313 09 Naphthalene (Component of POMTV)91-20-3 0.00442 09 Nickel metal (Component of NIC)7440-02-0 0.00557 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.0438 09 Selenium Compounds SEC 0.0279 09 Toluene 108-88-3 1.06 09 Xylene 1330-20-7 0.0186 09 65 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-05 2. Emission Source Description :Boiler No. 5: one No. 2 fuel oil/natural gas-fired boiler (69.35 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 10/Boiler No. 5: natural gas combustion 4. SCC Number/Description:10200602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-05 VERTICAL STACK WITH RAIN CAP 25 3 450 45.7 19385 Boiler 5 Stack 66 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 10 Emission Source/Group ID: ES-7754- 05 Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 67 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-06 2. Emission Source Description :[NSPS] Boiler No. 6: natural gas/No.2 fuel oil-fired boiler (99.00 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 11/[NSPS] Boiler No. 6: natural gas combustion 4. SCC Number/Description:10200602/Natural Gas ; 10-100 Million Btu/hr 5. Throughput/units in 2021: (e.g. production or fuel use): 149323239 FT3S/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 1020 Btu/CF 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-06 VERTICAL STACK WITH RAIN CAP 32 4 450 30.36 22894 Boiler 6 Stack 68 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 29 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2259 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 11 Emission Source/Group ID: ES-7754- 06 Jan-Feb + Dec 2021 30%March-May 2021 18%June-Aug. 2021 24%Sept.-Nov. 2021 28% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 6.27 09 NOx NOx 7.47 09 TSP TSP 0.04 09 PM10 PM10 0.04 09 PM2.5 PM2.5 0.03 09 SO2 SO2 0.04 09 VOC VOC 0.41 09 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Acetaldehyde 75-07-0 0.00227 09 Acrolein 107-02-8 0.00269 09 Ammonia (as NH3)7664-41-7 478 09 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.0299 09 Benzene 71-43-2 0.314 09 Benzo(a)pyrene (Component of POMTV & POM7) 50-32-8 0.00018 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00179 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.164 09 69 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.209 09 Cobalt Unlisted Compound (Specify & Component of COC) COC- Other 0.0125 09 Formaldehyde 50-00-0 11.2 09 Hexane, n-110-54-3 269 09 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.0747 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.0567 09 Mercury, vapor (Component of HGC)7439-97-6 0.0388 09 Naphthalene (Component of POMTV)91-20-3 0.0911 09 Nickel metal (Component of NIC)7440-02-0 0.314 09 Selenium Compounds SEC 0.00358 09 Toluene 108-88-3 0.508 09 70 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID ES-7754-06 2. Emission Source Description :[NSPS] Boiler No. 6: natural gas/No.2 fuel oil-fired boiler (99.00 million Btu per hour heat input rate) 3. Operating Scenario ID/ Description: OS - 12/[NSPS] Boiler No. 6: No.2 fuel oil combustion 4. SCC Number/Description:10200501/Distillate Oil (No. 1 & 2) ; Grades 1 and 2 Oil 5. Throughput/units in 2021: (e.g. production or fuel use): 938 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur 0.0015 %Ash Heat Content (Btu/units) 137500 Btu/gallon 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description 7754-06 VERTICAL STACK WITH RAIN CAP 32 4 450 30.36 22894 Boiler 6 Stack 71 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 29 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 12 Emission Source/Group ID: ES-7754- 06 Jan-Feb + Dec 2021 0%March-May 2021 0%June-Aug. 2021 0%Sept.-Nov. 2021 100% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 0.01 09 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 Arsenic Unlisted Compounds ( Specify & Component of ASC) ASC-Other 0.00053 09 Benzene 71-43-2 0.00258 09 Beryllium metal (unreacted) (Component of BEC) 7440-41-7 0.00039 09 Cadmium Metal (elemental unreacted, Component of CDC) 7440-43-9 0.00039 09 Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.00039 09 Ethyl benzene 100-41-4 0.00077 09 Fluorides (sum of all fluoride compounds)16984-48-8 0.035 09 Formaldehyde 50-00-0 0.045 09 72 Lead Unlisted Compounds (Specify and Component of PBC) PBC-Other 0.00118 09 Manganese Unlisted Compounds (Specify & Component of MNC) MNC- Other 0.00079 09 Mercury, vapor (Component of HGC)7439-97-6 0.00039 09 Methyl chloroform 71-55-6 0.00022 09 Naphthalene (Component of POMTV)91-20-3 0.00031 09 Nickel metal (Component of NIC)7440-02-0 0.00039 09 Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 0.0031 09 Selenium Compounds SEC 0.00197 09 Toluene 108-88-3 0.0747 09 Xylene 1330-20-7 0.00131 09 73 8. Control Device Information :None 9. Emission Release Point (ERP) Information: (Sources vented to more than one ERP use additional entry lines): COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 1. Emission Source ID (from permit) or Emission Source Group ID I-Tanks 2. Emission Source Description :Fuel storage tanks 3. Operating Scenario ID/ Description: OS - 15/Fuel storage tanks 4. SCC Number/Description:39090003/Fuel Storage - Fixed Roof Tanks ; Distillate Oil (No. 2): Breathing Loss 5. Throughput/units in 2021: (e.g. production or fuel use): 17932 GAL/yr 6. Fuel Information (If fuel is used) %Sulfur %Ash Heat Content (Btu/units) 7. Capture Efficiency (% of Emissions from this Process Vented to Control Device or Stack): Order CS-ID CD ID (as listed in permit) Control Device Description ERP ID ERP Type Height (in feet) Diameter Circle (enter #): Rectangle (L x W) (in 0.1 feet) Temperature (F) Velocity (Feet/sec) Volume Flow Rate (Acfm) ERP Description F2 FUGITIVE (NO STACK) 1 72 Area = 1 Fuel Storage Tanks 74 10. Operating Schedule:(Source/OperatingScenario that best characterizes Calendar Year 2021) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11. Typical Start & End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Operating Scenario: OS - 15 Emission Source/Group ID: I-Tanks Jan-Feb + Dec 2021 25%March-May 2021 25%June-Aug. 2021 25%Sept.-Nov. 2021 25% GHG Pollutants CAS Emissions- GHG Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 Criteria (NAAQS) Pollutants Pollutant Code Emissions- Criteria Pollutants (Tons/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor Ef Control 2021 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0.03 08 HAP/TAP Pollutants (In Alphabetical Order) CAS (see instructions) Emissions HAP/TAPS (Pounds/Year) Emission Estimation Method Code (See Instructions) Control Efficiency (Net after all controls) Emission Factor EF Control 2021 75 Record Facility-Wide Totals From all Permitted and Non-Permitted AirPollutant Emission Sources Facility Total CY 2021 Emissions Summary COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO North Carolina Department of Environmental Quality Division of Air Quality Air Pollutant Point Source Emissions Inventory - Calendar Year 2021 Green House Gases Pollutants(GHG) Actual Emissions (Tons/Year) Pollutant CAS 2021 2020 % Change Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS 2021 2020 % Change CO CO 69.66 78.84 -11.6438265% NOx NOx 65.13 74.55 -12.635822% PM(TSP)TSP 1.15 1.33 -13.53384% PM10 PM10 1.15 1.31 -12.213738% PM2.5 PM2.5 1.06 1.23 -13.821144% SO2 SO2 0.47 .53 -11.32075% VOC VOC 4.96 5.62 -11.74377% Hazardous Air Pollutants(HAPS) and/or Toxic Air Pollutants(TAPs) Actual Emissions (Pounds/Year) Pollutant CAS 2021 2020 % Change Pollutant Group:Arsenic & Compounds (total mass of elemental AS, arsine and all inorganic compounds) Group Sum:.29 Arsenic Unlisted Compounds ( Specify & Component of ASC)ASC-Other 0.29 .33606 -13.705885% Pollutant Group:Beryllium & compounds (Total mass) Group Sum:.06055 Beryllium metal (unreacted) (Component of BEC)7440-41-7 0.06055 .06768 -10.534871% Pollutant Group:Cadmium & compounds (total mass inc elemental metal) Group Sum:1.29084 Cadmium Metal (elemental unreacted, Component of CDC)7440-43-9 1.29084 1.52071 -15.115963% Pollutant Group:Chromium (VI) Soluble Chromate Compounds (Component of CRC) Group Sum:1.63184 Chromic acid (VI) (Component of SolCR6 & CRC)7738-94-5 1.63184 1.92171 -15.083963% Pollutant Group:Chromium - All/Total (Inc Chromium (VI) categories, metal and Others) Group Sum:1.63184 Chromic acid (VI) (Component of SolCR6 & CRC)7738-94-5 1.63184 1.92171 -15.083963% Pollutant Group:Cobalt compounds Group Sum:.1286 76 Cobalt Unlisted Compound (Specify & Component of COC)COC-Other 0.1286 .1449 -11.249133% Pollutant Group:Glycol ethers (total all individual glycol ethers-See http://daq.state.nc.us/toxics/glycol/) Group Sum:.42 Glycol Ethers, Unlisted (Specify & Component of GLYET) (See http://daq.state.nc.us/toxics/glycol/ ) GLYET-Other 0.42 3.42 -87.7193% Pollutant Group:Lead and Lead compounds Group Sum:.90742 Lead Unlisted Compounds (Specify and Component of PBC)PBC-Other 0.90742 1.01762 -10.829188% Pollutant Group:Manganese & compounds Group Sum:.52577 Manganese Unlisted Compounds (Specify & Component of MNC)MNC-Other 0.52577 .61124 -13.983053% Pollutant Group:Mercury & Compounds - all total mass, inc Hg Vapor Group Sum:.33504 Mercury, vapor (Component of HGC)7439-97-6 0.33504 .39911 -16.053215% Pollutant Group:Nickel & Compounds, sum total mass, inc elemental Group Sum:2.42884 Nickel metal (Component of NIC)7440-02-0 2.42884 2.85671 -14.97772% Pollutant Group:Polycyclic Organic Matter (7 PAH Compounds for NIF) Group Sum:.00516 Benzo(a)pyrene (Component of POMTV & POM7)50-32-8 0.00516 .00608 -15.131578% Pollutant Group:Polycyclic Organic Matter (Specific Compounds from OAQPS for TV) Group Sum:2.62671 Benzo(a)pyrene (Component of POMTV & POM7)50-32-8 0.00516 .00608 -15.131578% Naphthalene (Component of POMTV)91-20-3 2.62155 3.08232 -14.948801% Acetaldehyde 75-07-0 0.97389 1.05373 -7.576894% Acrolein 107-02-8 0.26745 .31327 -14.62636% Ammonia (as NH3)7664-41-7 4903.0 5517 -11.129237% Benzene 71-43-2 13.61633 16.10185 -15.43624% Butadiene, 1,3-106-99-0 0.0285 .0277 2.8880885% Carbon tetrachloride 56-23-5 5.0E-4 .00066 -24.242422% Chlorobenzene 108-90-7 3.7E-4 .00048 -22.916666% Chloroform 67-66-3 3.9E-4 .00051 -23.52941% Ethyl benzene 100-41-4 0.20733 .53933 -61.55786% Ethylene dibromide 106-93-4 6.1E-4 .00079 -22.784813% Ethylene glycol 107-21-1 0.63 7.98 -92.10526% Ethylene oxide 75-21-8 0.196 .224 -12.500005% Fluorides (sum of all fluoride compounds)16984-48-8 0.669 .3829 74.71925% Formaldehyde 50-00-0 118.1827 132.8822 -11.062054% Hexamethylene-1,6-diisocyanate 822-06-0 0.0125 Not reported N/A Hexane, n-110-54-3 2758.0 3107 -11.2327% Methanol 67-56-1 0.0872 .114 -23.50877% Methyl chloroform 71-55-6 0.00423 .00243 74.074066% Methyl ethyl ketone 78-93-3 0.0 .53 -100.0% Methylene chloride 75-09-2 0.00117 .00153 -23.529415% Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic amorphous glob) POM 2.69422 3.24012 -16.848139% Selenium Compounds SEC 0.27135 .30001 -9.553015% Styrene 100-42-5 3.4E-4 .00044 -22.727274% Toluene 108-88-3 10.4416 12.2955 -15.077874% Vinyl chloride 75-01-4 2.1E-4 .00027 -22.22222% Xylene 1330-20-7 2.62868 3.92763 -33.072105% 77 78 COPY of RECORD Date Submitted: 6/24/2022 09:55:09 As entered in AERO Facility Name: Duke University 501 Douglas Street DFC/OHS Room 151 Durham, NC 27705 Facility ID : 3200144 Permit : 03254 County : Durham DAQ Region : RRO Comments From Facility: 79