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HomeMy WebLinkAboutAQ_F_1900015_20220901_EI_Cmb-EI-File_2021 EI2021 Emissions Inventory Review / Data Tracking Form Facility Name: Arauco North America, Inc. Facility Classification: Title V Assigned to: Jeff Harris Data Entry: Chatham County Confidential Copy Submitted? YES NO Enter date received into ED. Date Received: _________________ Assigned to appropriate individual. Date Assigned: _________________ Date Due: __________________ Paper copy submitted: One copy received with supporting documentation, certification form signed by responsible official, and appears generally complete; OR Electronic copy submitted: All supporting documentation and certification form (with time/date stamp) signed by responsible official has been received. Comments: Facility ID: 1900015 Initial Review / Data Entry Inventory Review All forms and supporting documentation appear to be complete if paper submission (check ED OS data if electronic). Contact, address, phone number changes entered into I-Beam/Facilities if necessary. All known operating scenarios, control devices, and emission release points have been entered for each emission source (permitted, insignificant, and unpermitted) or note that the emission source was not operated or not required to report. Check if SCC codes for each OS are accurate and update if needed. Evaluate "U" sources for significance and address according to policy. Calculations / forms appear to add up correctly. All compliance issues are being addressed (e.g. Toxics limits, above TV thresholds, large emissions increase/decrease, installation without a permit). All volatile HAPs/TAPs were included in the VOC total. Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for the reporting facility (e.g. stack testing, AP-42, etc.). Review facility comments and address any issues. Update ED (Data Entry Main) if additional information is required (corrections due date and date received). Check all ED QA/QC reports. Comparison with previous emission inventory must be made and outliers (> 10%) must be investigated and explained. Put inventory review comments and summarize any changes in ED - Data Entry Main "DAQ internal comments". Date Review Complete: ___________________ Signature: _____________________________ Date Submitted to EI Coordinator: ___________________ Date Approved: ___________________ Initials: ___________________ Date Info Requested: ______________ Date Info Received: ______________ Total Days on Hold: ______ SC Other changes due to throughput differences. NOx Increase due to new emission factor. VOC decrease due to revaluated control efficiency. 09/01/2022 09/01/2022 09/09/2022 Arauco North America, Inc.03449T57 1900015 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Pollutant CAS Green House Gases Pollutants (GHG)Actual Emissions Tons/Yr % ChangeDemini- mus Not Reported Not Reported N/A CO2 equivalent (sum of individual GHG pollutant emission times their 1995 IPCC Global Warming Potential (GWP), converted to metric tons) No GHGs Reported Criteria Pollutants CY 2021 from ED CY 2020 from Fees (Tons/Year) Actual Emissions % ChangePollutantCASDemini- mus -7.0%194.33180.69CO 0.5CO 100.6%111.15223.02NOx 0.5NOx -0.6%158.19157.17TSP 0.5PM(TSP) -3.7%91.1587.78PM10 0.5PM10 -2.0%88.3786.57PM2.5 0.5PM2.5 -7.4%7.587.02SO2 0.5SO2 -41.8%600.67349.45VOC 0.5VOC Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus Arsenic & Compounds (total mass of elemental AS, arsine and all inorganic compounds) 0.080440 0.096990 -17.1%0.01 -17.1%0.0969900.080440ASC-Other 0.01Arsenic Unlisted Compounds - Specify Compound (Component of ASC) Beryllium & compounds (Total mass)0.013310 0.016070 -17.2%1.0 -17.2%0.0160700.0133107440-41-7 1.0Beryllium Metal (unreacted) (Component of BEC) Cadmium & compounds (total mass includes elemental metal)0.188110 0.200870 -6.4%0.1 -6.4%0.2008700.1881107440-43-9 0.1Cadmium Metal, elemental, unreacted (Component of CDC) Chromium - All/Total (includes Chromium (VI) categories, metal and others) 0.175910 0.171570 2.5%0.1 Page 1 of 409/01/2022 Arauco North America, Inc.03449T57 1900015 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus 2.5%0.1715700.1759107738-94-5 0.01Chromic acid (VI) (Component of SolCR6 & CRC) Chromium (VI) Soluble Chromate Compounds (Component of CRC) 0.175910 0.171570 2.5%0.01 2.5%0.1715700.1759107738-94-5 0.01Chromic acid (VI) (Component of SolCR6 & CRC) Cobalt & compounds 0.016000 0.017700 -9.6%1.0 -9.6%0.0177000.016000COC-Other 1.0Cobalt Unlisted Compounds - Specify Compound (Component of COC) Manganese & compounds 0.823110 1.08 -23.8%10.0 -24.0%1.080.823110MNC-Other 10.0Manganese Unlisted Compounds - Specify Compound (Component of MNC) Mercury & Compounds - all total mass includes Hg Vapor 0.052910 0.056770 -6.8%0.001 -6.8%0.0567700.0529107439-97-6 0.001Mercury, vapor (Component of HGC) Nickel & Compounds, sum total mass includes elemental 0.368410 0.399570 -7.8%1.0 -7.8%0.3995700.3684107440-02-0 1.0Nickel metal (Component of NIC) Polycyclic Organic Matter (7 PAH Compounds for NIF)0.077160 0.103060 -25.1%1.0 -25.1%0.1030600.07716050-32-8 1.0Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) Polycyclic Organic Matter (Specific Compounds from OAQPS for TV) 2.44 3.22 -24.2%1.0 -25.1%0.1030600.07716050-32-8 1.0Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) -24.3%3.122.3691-20-3 1.0Naphthalene (Component of 83329/POMTV) 26.4%3,154.183,987.4075-07-0 10.0Acetaldehyde 28.8%66.5985.74107-02-8 10.0Acrolein -20.8%10.218.0871-43-2 1.0Benzene -25.5%31.3023.337782-50-5 100.0Chlorine 25.1%493.25617.1198-82-8 100.0Cumene -25.5%1.150.856000107-06-2 1.0Ethylene dichloride (1,2-dichloroethane) Page 2 of 409/01/2022 Arauco North America, Inc.03449T57 1900015 Facility Name: Facility ID #: Permit #(s): Facility Total CY 2021 Emission Summary Recorded in ED Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) CY 2021 from ED CY 2020 from Fees (Pounds/Year) Actual Emissions % ChangePollutantCASDemini- mus 42.3%14,370.1820,448.7550-00-0 10.0Formaldehyde -25.4%0.0630000.04700057653-85-7 0.00001Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8 3.2%208.58215.15110-54-3 100.0Hexane, n- -25.5%62.2146.367647-01-0 100.0Hydrogen chloride (hydrochloric acid) -13.8%0.1160000.10000078-93-3 100.0MEK (methyl ethyl ketone, 2-butanone) 8.0%454,362.98490,606.7867-56-1 1,000.0Methanol (methyl alcohol) -25.5%0.9150000.68200074-87-3 1.0Methyl chloride (chloromethane) -25.5%13.8710.3375-09-2 1.0Methylene chloride 28.7%9,341.7112,024.80108-95-2 100.0Phenol -25.5%3.902.917723-14-0 1.0Phosphorus Metal, Yellow or White -25.2%5.043.77POM 1.0Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) 26.4%188.43238.25123-38-6 10.0Propionaldehyde -4.5%3.062.92108-88-3 100.0Toluene -25.5%0.7290000.54300075-01-4 0.1Vinyl chloride Largest Individual HAP 490,606.78 lbs 528,327.90 lbsTotal HAP Emissions Methanol (methyl alcohol) Largest Individual CAP 349.45 tons Total CAP Emissions 847.96 tons Total TAP Emissions 36,856.10 lbs Total Aggregate Emissions 848.00 tons VOC Page 3 of 409/01/2022 DAQ's Comments Regarding Inventory Page 4 of 409/01/2022 100% Increase in NOx (despite only ~10% increase in throughput) for ES-02-B/OS 69, 2-stage dryer. This significant difference is due to an updated emission factor based on a new stack test. ~41% decrease in VOC (despite ~10% increase in throughput) for ES-02B/OS 69, 2-stage dryer. These significant differences are due to revised control efficiency employed in calculations. VOC control efficiency was re- evaluated during stack testing that was completed in October 2021. The control efficiency for total VOC was slightly reduced during the 2021 source test compared to 2018 results which is what yielding an increase in those emissions. Formaldehyde control efficiency in 2018 was 96.8% but was demonstrated at 91.5% in 2021. ~20% decrease in Arsenic, Naphthalene, Benzene, Hexachlorodibenzo-p-dioxin, Methylene Chloride, POM, Vinyl chloride results from ~25% decrease in operation for ES-02A/OS75 Energy system bypass mode. ~26% increase in Acetaldehyde, Acrolein, Cumene, Formaldehyde (~42%), Phenol, Phosphorus, Propionaldehyde, results from ~10% increase in throughput for ES-02B/OS 69, 2-stage dryer and revised control efficiency employed in calculations, as described above. Corrections: 1) 2020 EI, Source ES-02-C1/OS86: Change PM10 from 55.46 tpy to 0.03 tpy Change PM2.5 from 55.46 tpy to 0.03 tpy (Data entry error) 2) 2020 EI, Source ES-02A/OS75: Change Chromic acid (VI) (Component of SolCR6 & CRC) from 0.209 lb/y to 0.009 lb/y (Data entry error) 3) 2021 EI, Source ES-02A/OS75: Change SO2 from 6.35 tpy to 0.37 tpy (Data entry error) Facility Emissions - Operating Scenarios Per Pollutant Arauco North America, Inc. 2021 Inventory Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Acetaldehyde OS-7 0.010000 Pounds 0.010000 Pounds I-ODG I-ODG OS-69 3,985.07 Pounds 3,151.44 Pounds ES-02-B ES-02-B OS-75 2.26 Pounds 2.63 Pounds ES-02-A ES-02-A OS-76 0.040000 Pounds 0.090000 Pounds I-DFP-1 I-DFP-1 OS-80 0.016000 Pounds 0.005620 Pounds ES-21 ES-21 TOTAL in Current Inventory: 3,987.40 Pounds TOTAL in Previous Inventory: 3,154.18 Pounds Acrolein OS-7 0.000890 Pounds 0.000950 Pounds I-ODG I-ODG OS-69 85.15 Pounds 65.90 Pounds ES-02-B ES-02-B OS-75 0.586000 Pounds 0.681000 Pounds ES-02-A ES-02-A OS-76 0.010000 Pounds I-DFP-1 OS-80 0.005010 Pounds 0.001760 Pounds ES-21 ES-21 TOTAL in Current Inventory: 85.74 Pounds TOTAL in Previous Inventory: 66.59 Pounds 9/1/2022 Page 1 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Arsenic Unlisted Compounds - Specify Compound (Component of ASC) OS-75 0.054000 Pounds 0.073000 Pounds ES-02-A ES-02-A OS-79 0.023900 Pounds 0.023100 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.002540 Pounds 0.000890 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.08 Pounds TOTAL in Previous Inventory: 0.10 Pounds Benzene OS-7 0.010000 Pounds 0.010000 Pounds I-ODG I-ODG OS-41 0.350000 Pounds 0.350000 Pounds I-GAS I-GAS OS-75 6.94 Pounds 9.31 Pounds ES-02-A ES-02-A OS-76 0.040000 Pounds 0.120000 Pounds I-DFP-1 I-DFP-1 OS-79 0.250500 Pounds 0.242900 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.493000 Pounds 0.173000 Pounds ES-21 ES-21 TOTAL in Current Inventory: 8.08 Pounds TOTAL in Previous Inventory: 10.21 Pounds Benzo(a)pyrene (Component of 83329/POMTV & 56553/7PAH) OS-75 0.077000 Pounds 0.103000 Pounds ES-02-A ES-02-A OS-80 0.000160 Pounds 0.000060 Pounds ES-21 ES-21 9/1/2022 Page 2 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 TOTAL in Current Inventory: 0.08 Pounds TOTAL in Previous Inventory: 0.10 Pounds Beryllium Metal (unreacted) (Component of BEC) OS-75 0.010000 Pounds 0.014000 Pounds ES-02-A ES-02-A OS-79 0.001400 Pounds 0.001400 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.001910 Pounds 0.000670 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.01 Pounds TOTAL in Previous Inventory: 0.02 Pounds Cadmium Metal, elemental, unreacted (Component of CDC) OS-75 0.055000 Pounds 0.073000 Pounds ES-02-A ES-02-A OS-79 0.131200 Pounds 0.127200 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.001910 Pounds 0.000670 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.19 Pounds TOTAL in Previous Inventory: 0.20 Pounds Chlorine OS-75 23.33 Pounds 31.30 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 23.33 Pounds TOTAL in Previous Inventory: 31.30 Pounds Chromic acid (VI) (Component of SolCR6 & CRC) OS-75 0.007000 Pounds 0.009000 Pounds ES-02-A ES-02-A OS-79 0.167000 Pounds 0.161900 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 9/1/2022 Page 3 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-80 0.001910 Pounds 0.000670 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.18 Pounds TOTAL in Previous Inventory: 0.17 Pounds CO OS-51 8.86 Tons 11.89 Tons ES-02-A ES-02-A OS-69 146.46 Tons 154.68 Tons ES-02-B ES-02-B OS-75 8.86 Tons 11.89 Tons ES-02-A ES-02-A OS-76 0.020000 Tons 0.060000 Tons I-DFP-1 I-DFP-1 OS-79 5.01 Tons 4.86 Tons ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.300000 Tons 0.110000 Tons ES-21 ES-21 OS-86 5.59 Tons 5.42 Tons ES-02-C-1 ES-02-C-1 OS-87 5.59 Tons 5.42 Tons ES-02-C-2 ES-02-C-2 TOTAL in Current Inventory: 180.69 Tons TOTAL in Previous Inventory: 194.33 Tons Cobalt Unlisted Compounds - Specify Compound (Component of COC) OS-75 0.006000 Pounds 0.008000 Pounds ES-02-A ES-02-A OS-79 0.010000 Pounds 0.009700 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 TOTAL in Current Inventory: 0.02 Pounds TOTAL in Previous Inventory: 0.02 Pounds 9/1/2022 Page 4 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Cumene OS-41 0.040000 Pounds 0.040000 Pounds I-GAS I-GAS OS-53 8.38 Pounds 7.73 Pounds ES-03 ES-03 OS-54 8.38 Pounds 7.73 Pounds ES-04 ES-04 OS-55 0.340000 Pounds 0.420000 Pounds ES-05 ES-05 OS-69 599.97 Pounds 477.33 Pounds ES-02-B ES-02-B TOTAL in Current Inventory: 617.11 Pounds TOTAL in Previous Inventory: 493.25 Pounds Ethylene dichloride (1,2-dichloroethane) OS-75 0.856000 Pounds 1.15 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 0.86 Pounds TOTAL in Previous Inventory: 1.15 Pounds Formaldehyde OS-7 0.010000 Pounds 0.010000 Pounds I-ODG I-ODG OS-21 19.05 Pounds 3501 OS-22 33.00 Pounds 3515.19D OS-23 73.92 Pounds 3525.19D OS-24 92.62 Pounds 3535.19D OS-26 79.39 Pounds 3565.19D OS-27 21.17 Pounds 3555.19D 9/1/2022 Page 5 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-28 36.00 Pounds 108.00 Pounds 3575.19D 3575.19D OS-29 38.52 Pounds 3585.19D OS-30 3.88 Pounds 3595.19D OS-35 318.75 Pounds 3577.19D OS-53 2,041.02 Pounds 1,884.31 Pounds ES-03 ES-03 OS-54 2,041.02 Pounds 1,884.31 Pounds ES-04 ES-04 OS-55 75.55 Pounds 92.84 Pounds ES-05 ES-05 OS-57 125.16 Pounds 112.36 Pounds ES-07 ES-07 OS-58 74.29 Pounds 66.69 Pounds ES-08 ES-08 OS-59 31.57 Pounds 76.25 Pounds ES-09 ES-09 OS-60 74.29 Pounds 66.69 Pounds ES-10 ES-10 OS-61 3.21 Pounds 2.96 Pounds ES-12 ES-12 OS-63 63.15 Pounds 76.25 Pounds ES-15 ES-15 OS-64 3.21 Pounds 2.96 Pounds ES-17 ES-17 OS-69 15,814.06 Pounds 9,238.97 Pounds ES-02-B ES-02-B OS-75 26.07 Pounds 34.99 Pounds 9/1/2022 Page 6 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-02-A ES-02-A OS-76 0.050000 Pounds 0.150000 Pounds I-DFP-1 I-DFP-1 OS-78 26.28 Pounds 26.28 Pounds I-MDFR-1 I-MDFR-1 I-MDFR-2 I-MDFR-2 I-MDFR-3 I-MDFR-3 I-MDFR-4 I-MDFR-4 OS-79 8.95 Pounds 8.67 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.050100 Pounds 0.017600 Pounds ES-21 ES-21 OS-82 2.36 Pounds I-Irrigation fugitiv OS-83 4.81 Pounds 4.81 Pounds I-Wastewater ponds I-Wastewater ponds TOTAL in Current Inventory: 20,448.75 Pounds TOTAL in Previous Inventory: 14,370.18 Pounds Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8 OS-75 0.047000 Pounds 0.063000 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 0.05 Pounds TOTAL in Previous Inventory: 0.06 Pounds Hexane, n- OS-41 0.420000 Pounds 0.420000 Pounds I-GAS I-GAS OS-79 214.73 Pounds 208.16 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 TOTAL in Current Inventory: 215.15 Pounds TOTAL in Previous Inventory: 208.58 Pounds Hydrogen chloride (hydrochloric acid) 9/1/2022 Page 7 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-75 46.36 Pounds 62.21 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 46.36 Pounds TOTAL in Previous Inventory: 62.21 Pounds Manganese Unlisted Compounds - Specify Compound (Component of MNC) OS-75 0.774000 Pounds 1.04 Pounds ES-02-A ES-02-A OS-79 0.045300 Pounds 0.043900 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.003810 Pounds 0.001340 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.82 Pounds TOTAL in Previous Inventory: 1.08 Pounds MEK (methyl ethyl ketone, 2-butanone) OS-75 0.100000 Pounds 0.116000 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 0.10 Pounds TOTAL in Previous Inventory: 0.12 Pounds Mercury, vapor (Component of HGC) OS-75 0.020000 Pounds 0.026000 Pounds ES-02-A ES-02-A OS-79 0.031000 Pounds 0.030100 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.001910 Pounds 0.000670 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.05 Pounds TOTAL in Previous Inventory: 0.06 Pounds Methanol (methyl alcohol) OS-21 312.65 Pounds 3501 OS-22 467.50 Pounds 3515.19D 9/1/2022 Page 8 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-23 14.31 Pounds 3525.19D OS-24 38.17 Pounds 3535.19D OS-26 17.35 Pounds 3565.19D OS-27 94.55 Pounds 3555.19D OS-28 8.00 Pounds 23.00 Pounds 3575.19D 3575.19D OS-29 255.89 Pounds 3585.19D OS-30 30.50 Pounds 3595.19D OS-35 231.82 Pounds 3577.19D OS-53 1,582.37 Pounds 1,460.87 Pounds ES-03 ES-03 OS-54 1,582.37 Pounds 1,460.87 Pounds ES-04 ES-04 OS-55 58.57 Pounds 71.97 Pounds ES-05 ES-05 OS-57 1,738.34 Pounds 1,560.57 Pounds ES-07 ES-07 OS-58 417.20 Pounds 374.54 Pounds ES-08 ES-08 OS-59 24.48 Pounds 59.11 Pounds ES-09 ES-09 OS-60 334.28 Pounds 300.10 Pounds ES-10 ES-10 OS-61 14.45 Pounds 13.34 Pounds 9/1/2022 Page 9 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-12 ES-12 OS-62 4.59 Pounds 4.23 Pounds ES-13 ES-13 OS-63 48.96 Pounds 59.11 Pounds ES-15 ES-15 OS-64 14.45 Pounds 13.34 Pounds ES-17 ES-17 OS-69 484,769.69 Pounds 447,488.70 Pounds ES-02-B ES-02-B OS-75 9.03 Pounds 10.50 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 490,606.78 Pounds TOTAL in Previous Inventory: 454,362.98 Pounds Methyl chloride (chloromethane) OS-75 0.682000 Pounds 0.915000 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 0.68 Pounds TOTAL in Previous Inventory: 0.92 Pounds Methylene chloride OS-75 10.33 Pounds 13.87 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 10.33 Pounds TOTAL in Previous Inventory: 13.87 Pounds Naphthalene (Component of 83329/POMTV) OS-7 0.000810 Pounds 0.000870 Pounds I-ODG I-ODG OS-41 0.090000 Pounds 0.090000 Pounds I-GAS I-GAS OS-75 2.20 Pounds 2.95 Pounds ES-02-A ES-02-A OS-76 0.010000 Pounds I-DFP-1 OS-79 0.072800 Pounds 0.070500 Pounds 9/1/2022 Page 10 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 TOTAL in Current Inventory: 2.36 Pounds TOTAL in Previous Inventory: 3.12 Pounds Nickel metal (Component of NIC) OS-75 0.116000 Pounds 0.156000 Pounds ES-02-A ES-02-A OS-79 0.250500 Pounds 0.242900 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.001910 Pounds 0.000670 Pounds ES-21 ES-21 TOTAL in Current Inventory: 0.37 Pounds TOTAL in Previous Inventory: 0.40 Pounds NOx OS-7 0.020000 Tons 0.020000 Tons I-ODG I-ODG OS-51 4.10 Tons 6.54 Tons ES-02-A ES-02-A OS-69 193.09 Tons 85.07 Tons ES-02-B ES-02-B OS-75 11.68 Tons 6.54 Tons ES-02-A ES-02-A OS-76 0.100000 Tons 0.270000 Tons I-DFP-1 I-DFP-1 OS-79 5.96 Tons 5.78 Tons ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 1.41 Tons 0.490000 Tons ES-21 ES-21 OS-86 3.33 Tons 3.22 Tons ES-02-C-1 ES-02-C-1 9/1/2022 Page 11 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-87 3.33 Tons 3.22 Tons ES-02-C-2 ES-02-C-2 TOTAL in Current Inventory: 223.02 Tons TOTAL in Previous Inventory: 111.15 Tons Phenol OS-62 20.64 Pounds 19.05 Pounds ES-13 ES-13 OS-69 12,003.79 Pounds 9,322.23 Pounds ES-02-B ES-02-B OS-75 0.367000 Pounds 0.427000 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 12,024.80 Pounds TOTAL in Previous Inventory: 9,341.71 Pounds Phosphorus Metal, Yellow or White OS-75 2.91 Pounds 3.90 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 2.91 Pounds TOTAL in Previous Inventory: 3.90 Pounds PM(TSP) OS-21 0.010000 Tons 3501 OS-26 0.570000 Tons 3565.19D OS-28 0.260000 Tons 0.510000 Tons 3575.19D 3575.19D OS-29 2.81 Tons 3585.19D OS-35 0.020000 Tons 3577.19D OS-51 7.38 Tons 9.91 Tons ES-02-A ES-02-A OS-53 2.28 Tons 2.18 Tons ES-03 ES-03 9/1/2022 Page 12 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-54 2.17 Tons 2.07 Tons ES-04 ES-04 OS-55 0.060000 Tons 0.070000 Tons ES-05 ES-05 OS-57 3.31 Tons 3.16 Tons ES-07 ES-07 OS-58 3.54 Tons 3.38 Tons ES-08 ES-08 OS-60 1.77 Tons 1.69 Tons ES-10 ES-10 OS-61 0.040000 Tons 0.040000 Tons ES-12 ES-12 OS-62 0.080000 Tons 0.080000 Tons ES-13 ES-13 OS-64 0.040000 Tons 0.040000 Tons ES-17 ES-17 OS-69 58.48 Tons 53.99 Tons ES-02-B ES-02-B OS-74 0.160000 Tons 0.150000 Tons ES-01 ES-01 OS-75 7.38 Tons 9.91 Tons ES-02-A ES-02-A OS-76 0.010000 Tons 0.020000 Tons I-DFP-1 I-DFP-1 OS-79 0.450000 Tons 0.440000 Tons ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.100000 Tons 0.040000 Tons ES-21 ES-21 OS-86 69.19 Tons 67.07 Tons ES-02-C-1 ES-02-C-1 9/1/2022 Page 13 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-87 0.030000 Tons 0.030000 Tons ES-02-C-2 ES-02-C-2 OS-90 0.440000 Tons I-ADS I-ADS TOTAL in Current Inventory: 157.17 Tons TOTAL in Previous Inventory: 158.19 Tons PM10 OS-21 0.010000 Tons 3501 OS-26 0.570000 Tons 3565.19D OS-28 0.260000 Tons 0.510000 Tons 3575.19D 3575.19D OS-29 2.81 Tons 3585.19D OS-35 0.020000 Tons 3577.19D OS-51 7.38 Tons 9.91 Tons ES-02-A ES-02-A OS-53 2.28 Tons 2.18 Tons ES-03 ES-03 OS-54 2.17 Tons 2.07 Tons ES-04 ES-04 OS-55 0.060000 Tons 0.070000 Tons ES-05 ES-05 OS-57 3.31 Tons 3.16 Tons ES-07 ES-07 OS-58 3.54 Tons 3.38 Tons ES-08 ES-08 OS-60 1.77 Tons 1.69 Tons ES-10 ES-10 OS-61 0.040000 Tons 0.040000 Tons 9/1/2022 Page 14 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-12 ES-12 OS-62 0.080000 Tons 0.080000 Tons ES-13 ES-13 OS-64 0.040000 Tons 0.040000 Tons ES-17 ES-17 OS-69 58.48 Tons 53.99 Tons ES-02-B ES-02-B OS-74 0.160000 Tons 0.150000 Tons ES-01 ES-01 OS-75 7.38 Tons 9.91 Tons ES-02-A ES-02-A OS-76 0.010000 Tons 0.020000 Tons I-DFP-1 I-DFP-1 OS-79 0.450000 Tons 0.440000 Tons ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.100000 Tons 0.040000 Tons ES-21 ES-21 OS-86 0.030000 Tons 0.030000 Tons ES-02-C-1 ES-02-C-1 OS-87 0.030000 Tons 0.030000 Tons ES-02-C-2 ES-02-C-2 OS-90 0.210000 Tons I-ADS I-ADS TOTAL in Current Inventory: 87.78 Tons TOTAL in Previous Inventory: 91.15 Tons PM2.5 OS-21 0.010000 Tons 3501 OS-26 0.570000 Tons 3565.19D 9/1/2022 Page 15 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-28 0.260000 Tons 0.510000 Tons 3575.19D 3575.19D OS-29 2.81 Tons 3585.19D OS-35 0.020000 Tons 3577.19D OS-51 6.35 Tons 8.52 Tons ES-02-A ES-02-A OS-53 2.28 Tons 2.18 Tons ES-03 ES-03 OS-54 2.17 Tons 2.07 Tons ES-04 ES-04 OS-55 0.060000 Tons 0.070000 Tons ES-05 ES-05 OS-57 3.31 Tons 3.16 Tons ES-07 ES-07 OS-58 3.54 Tons 3.38 Tons ES-08 ES-08 OS-60 1.77 Tons 1.69 Tons ES-10 ES-10 OS-61 0.040000 Tons 0.040000 Tons ES-12 ES-12 OS-62 0.080000 Tons 0.080000 Tons ES-13 ES-13 OS-64 0.040000 Tons 0.040000 Tons ES-17 ES-17 OS-69 58.48 Tons 53.99 Tons ES-02-B ES-02-B OS-74 0.160000 Tons 0.150000 Tons ES-01 ES-01 OS-75 7.38 Tons 8.52 Tons ES-02-A ES-02-A 9/1/2022 Page 16 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-76 0.010000 Tons 0.020000 Tons I-DFP-1 I-DFP-1 OS-79 0.450000 Tons 0.440000 Tons ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.100000 Tons 0.040000 Tons ES-21 ES-21 OS-86 0.030000 Tons 0.030000 Tons ES-02-C-1 ES-02-C-1 OS-87 0.030000 Tons 0.030000 Tons ES-02-C-2 ES-02-C-2 OS-90 0.030000 Tons I-ADS I-ADS TOTAL in Current Inventory: 86.57 Tons TOTAL in Previous Inventory: 88.37 Tons Polycyclic Organic Matter (Inc PAH, dioxins, etc. NC & AP 42 historic) OS-7 0.000800 Pounds 0.000860 Pounds I-ODG I-ODG OS-75 3.69 Pounds 4.95 Pounds ES-02-A ES-02-A OS-76 0.010000 Pounds I-DFP-1 OS-79 0.074900 Pounds 0.072600 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 TOTAL in Current Inventory: 3.77 Pounds TOTAL in Previous Inventory: 5.04 Pounds Propionaldehyde OS-69 237.65 Pounds 187.74 Pounds ES-02-B ES-02-B OS-75 0.595000 Pounds 0.692000 Pounds ES-02-A ES-02-A 9/1/2022 Page 17 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 TOTAL in Current Inventory: 238.25 Pounds TOTAL in Previous Inventory: 188.43 Pounds SO2 OS-51 0.370000 Tons 0.500000 Tons ES-02-A ES-02-A OS-69 6.10 Tons 6.45 Tons ES-02-B ES-02-B OS-75 0.370000 Tons 0.500000 Tons ES-02-A ES-02-A OS-76 0.010000 Tons 0.020000 Tons I-DFP-1 I-DFP-1 OS-80 0.090000 Tons 0.030000 Tons ES-21 ES-21 OS-86 0.040000 Tons 0.040000 Tons ES-02-C-1 ES-02-C-1 OS-87 0.040000 Tons 0.040000 Tons ES-02-C-2 ES-02-C-2 TOTAL in Current Inventory: 7.02 Tons TOTAL in Previous Inventory: 7.58 Tons Toluene OS-41 1.63 Pounds 1.63 Pounds I-GAS I-GAS OS-75 0.691000 Pounds 0.927000 Pounds ES-02-A ES-02-A OS-76 0.020000 Pounds 0.050000 Pounds I-DFP-1 I-DFP-1 OS-79 0.405600 Pounds 0.393200 Pounds ES-18 ES-18 ES-19 ES-19 ES-20 ES-20 OS-80 0.178000 Pounds 0.062600 Pounds ES-21 ES-21 TOTAL in Current Inventory: 2.92 Pounds TOTAL in Previous Inventory: 3.06 Pounds 9/1/2022 Page 18 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 Vinyl chloride OS-75 0.543000 Pounds 0.729000 Pounds ES-02-A ES-02-A TOTAL in Current Inventory: 0.54 Pounds TOTAL in Previous Inventory: 0.73 Pounds VOC OS-21 4.39 Tons 3501 OS-22 17.20 Tons 3515.19D OS-23 0.240000 Tons 3525.19D OS-24 1.86 Tons 3535.19D OS-26 0.340000 Tons 3565.19D OS-27 0.730000 Tons 3555.19D OS-28 0.150000 Tons 0.450000 Tons 3575.19D 3575.19D OS-29 2.47 Tons 3585.19D OS-30 0.170000 Tons 3595.19D OS-35 7.85 Tons 3577.19D OS-51 0.250000 Tons 0.340000 Tons ES-02-A ES-02-A OS-53 10.08 Tons 9.31 Tons ES-03 ES-03 OS-54 10.08 Tons 9.31 Tons ES-04 ES-04 9/1/2022 Page 19 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 OS-55 0.370000 Tons 0.460000 Tons ES-05 ES-05 OS-57 1.01 Tons 0.940000 Tons ES-07 ES-07 OS-58 1.03 Tons 0.930000 Tons ES-08 ES-08 OS-59 0.160000 Tons 0.380000 Tons ES-09 ES-09 OS-60 1.03 Tons 0.930000 Tons ES-10 ES-10 OS-61 0.040000 Tons 0.040000 Tons ES-12 ES-12 OS-62 0.060000 Tons 0.050000 Tons ES-13 ES-13 OS-63 0.310000 Tons 0.380000 Tons ES-15 ES-15 OS-64 0.040000 Tons 0.040000 Tons ES-17 ES-17 OS-69 324.10 Tons 540.74 Tons ES-02-B ES-02-B OS-75 0.250000 Tons 0.340000 Tons ES-02-A ES-02-A OS-76 0.010000 Tons 0.020000 Tons I-DFP-1 I-DFP-1 OS-78 0.020000 Tons 0.020000 Tons I-MDFR-1 I-MDFR-1 I-MDFR-2 I-MDFR-2 I-MDFR-3 I-MDFR-3 I-MDFR-4 I-MDFR-4 OS-80 0.110000 Tons 0.040000 Tons ES-21 ES-21 OS-86 0.120000 Tons 0.350000 Tons 9/1/2022 Page 20 of 21 Arauco North America, Inc. 1900015 03449T57 Facility Name: Facility ID:Permit Number(s): Emission Rate - 2021OS ID Emission Source ID Pollutant Emission Rate (Prev) - 2020 ES-02-C-1 ES-02-C-1 OS-87 0.230000 Tons 0.350000 Tons ES-02-C-2 ES-02-C-2 TOTAL in Current Inventory: 349.45 Tons TOTAL in Previous Inventory: 600.67 Tons 9/1/2022 Page 21 of 21 Chatham, Arauco 1900015 ID Group OS Name 2020 2021 Units Ratio CS EP Notes 1420,1410.17B,1430 51 3 Particleboard Dryers 1000sqft 56 1515 DNO I-MDFR-1,I-MDFR-2,I-MDFR-3 2 78 MDF Resin Tanks 8,736 8,736 hr 1.0 fugres ES-18,ES-19,ES-20 3 79 MDF Thermal Oil Heaters 116 119 mmscf 1.03 es18,19,20 ES-02-C.17D,ES-02-D,6 88 MDF Dryer Burners (Natural Gas) Backup - 133 mmbtu cs50 es02,14 Combined into OS87 3201.17B 36 Wellons Bypass for PB process mmscf 3235 DNO 3501 21 Rock and metal separator sawdust cleaning system 47,660 tons 0 29 4003 DNO 3515 22 Surface Material Transport 47,660 tons 0 35 3515 DNO 3525 23 Surface Formers and Mat Dumps 1,573 tons 0 14 3525 DNO 3535 24 Flying Cut Off Saw, Pretrim Saws, & Production Collection 4,194 tons 0 15 3535 DNO 3545 25 Particleboard Mill Steinemann Finishing Sander - - tons 30 3565 DNO 3555 27 Schelling Saw Board Trim 10,390 tons 0 18 3555 DNO 3565 26 Particleboard Mill Steinemann Calibrating Sander 6,339 tons 0 31 3545 DNO 3575 28 Sander Filter Transport 2,574 21,879 tons 8.5 17 3575 inactivated on 5/18/2021 3577 35 Dry waste tranport system 14,489 tons 0 19 3577 DNO 3585 29 PZKR Green Chip Fla 2,279 tons 0 32 3585 DNO 3593 43 Short Cycle Laminating Press DNO 3594 48 Short Cycle Laminating Press DNO 3595 30 Oversize material Pallmann mill 2,279 tons 0 16 3595 DNO DEF2010 4 Particleboard Press 1000sqft 2010 DNO ES01 50 Refiner 7,365 8,760 hr 1.2 50 02,14 ES01 74 Refiner startup cyclone 86 89 hr 1.03 1 ES-02-A 75 Energy System Bypass mode 39,623 29,525 MMBTU 0.75 02byp ES-02-A 51 Energy System wood burning 515,606 29,525 MMBTU 0.1 42 02,14 ES-02-B 69 Two Stage Dryer System 7,365 7,838 hr 1.1 50 02,14 ES-02-C1 86 Backup natural gas-fired dryer burner 129 133 MMSCF 1.03 ES-02-C2 87 Backup natural gas-fired dryer burner 129 133 MMSCF 1.03 ES03 53 Fiber Sifter System 7,517 7,876 hr 1.05 43 3 ES04 54 Forming Line Clean-Up System 7,517 7,876 hr 1.05 44 4 es05 55 Mat Reject System 298 243 hr 0.82 15 5 es06b 56 MDF Board Cooler and Press Hall 166,722 185,713 Kftsq 1.11 50 02,14 Included in dryer calculations MDF-ES-02C&D. es07 57 Saw System 7,517 7,876 hr 1.05 46 7 es08 58 Sander System No.1 7,517 7,876 hr 1.05 47 8 es09 59 Recycled Fiber Silo No.1 298 121 hr 0.41 48 9 es10 60 Sander System No. 2 7,517 7,876 hr 1.05 49 10 es12 61 Sander Dust Silo No. 1 3,758 3,938 hr 1.05 52 12 es13 62 Dry Sawdust Silo 7,517 7,876 hr 1.05 53 13 es15 63 Recycled Fiber Silo No. 2 298 243 hr 0.82 es16 49 MDF Press and Press Hall 166,722 - 1000sqft 0.00 50 02,14 DNO es17 64 Sander Dust Silo No. 2 3,758 3,938 hr 1.05 55 17 es21 80 Diesel Fuel-fired Emergency Generator 20 57 hr 2.85 edg ES-M1A MDF moulding line 1 - moulding zone DNO ES-M1B MDF moulding line 1 - coating and drying zone DNO EVAP1 85 Wastewater evaporator gal evap1 DNO I-IADS 90 Material Separator System 1,458 hr I-DFP-1 76 Diesel Fuel-fired Fire Pump Eng 51 19 hr 0.38 esfdp1 I-GAS 41 above ground gasoline storage tank 8,760 8,760 hr 1.00 gas tank I-Irrigation 82 Spray Irrigation Field Fugitives 1.4 mmgal 0.00 fugitive DNO LPA Log Processing - never comissioned I-ODG 7 Diesel-fired emergency generator 8.7 8.1 hr 0.93 odg I-Wastewater ponds,83 Wastewater ponds 2.879 2.879 mmgal 1.00 fugitive PBBC 39 Particleboard Cooler 1000sqft erp-pbc DNO Pr-Heat1 46 Natural gas or No. 2 fuel oil-fired hot oil heater DNO From:Savannah Carroll To:Harris, Jeff Subject:RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) Date:Wednesday, August 31, 2022 9:29:49 AM Attachments:image001.png image002.png CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeff, This all looks great to me! Thanks for verifying with me and following up, especially on the data entry errors! Please let me know if you have any other questions. Savannah Savannah Carroll Corporate Environmental Manager 985 Corinth Road, Moncure NC 27559 Phone: (919) 545-5848 Mobile: (843) 544-3025 www.arauco-na.com From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Friday, August 26, 2022 2:07 PM To: Savannah Carroll <savannah.carroll@arauco.com> Subject: RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) ADVERTENCIA: Este es un correo externo a la organización. NO HAGA CLIC en enlaces ni descargue adjuntos antes de reconocer al remitente y saber que el contenido es seguro. Ante sospechas reporte a spamO365@arauco.com Savannah, Your response RE OS 51 makes perfect sense. I think I have this all sorted now, but I want to send you my final conclusions to get your approval before I make the revisions to the dataset. Please confirm that this is correct: Corrections: Here are my proposed corrections to Arauco’s Emissions Inventory Data for 2020-2021: 1. 2020 EI, Source ES-02-C1/OS86: Change PM10 from 55.46 tpy to 0.03 tpy Change PM2.5 from 55.46 tpy to 0.03 tpy (Correcting data entry error) 2. 2020 EI, Source ES-02A/OS75: Change Chromic acid (VI) (Component of SolCR6 & CRC) from 0.209 lb/y to 0.009 lb/y (Correcting data entry error) 3. 2021 EI, Source ES-02A/OS75: Change SO2 from 6.35 tpy to 0.37 tpy (Correcting data entry error) I spoke to our internal inventory Guru, who says she can open up last year’s data for me so I can change it now, which will eliminate the appearance of large % changes in the emissions from last year for these instances. Explanations for changes in emissions from 2020 to 2021: These are my proposed explanatory notes regarding changes in emissions from the 2020 EI. Please take a look and see if there’s anything you disagree with. 100% Increase in NOx (despite only ~10% increase in throughput) for ES-02-B/OS 69, 2-stage dryer. This significant difference is due to an updated emission factor based on a new stack test. ~41% decrease in VOC (despite ~10% increase in throughput) for ES-02B/OS 69, 2-stage dryer. These significant differences are due to revised control efficiency employed in calculations. VOC control efficiency was re-evaluated during stack testing that was completed in October 2021. The control efficiency for total VOC was slightly reduced during the 2021 source test compared to 2018 results which is what yielding an increase in those emissions. Formaldehyde control efficiency in 2018 was 96.8% but was demonstrated at 91.5% in 2021. ~20% decrease in Arsenic, Naphthalene, Benzene, Chromic acid (VI), Hexachlorodibenzo-p-dioxin, Methylene Chloride, POM, Vinyl chloride results from ~25% decrease in operation for ES-02A/OS75 Energy system bypass mode. ~26% increase in Acetaldehyde, Acrolein, Cumene, Formaldehyde (~42%), Phenol, Phosphorus, Propionaldehyde, results from ~10% increase in throughput for ES-02B/OS 69, 2-stage dryer and revised control efficiency employed in calculations, as described above. Thanks, Jeff From: Savannah Carroll <savannah.carroll@arauco.com> Sent: Friday, August 26, 2022 11:44 AM To: Harris, Jeff <jeff.harris@ncdenr.gov> Subject: RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeff, My apologies for the delay and missing your calls! I have been offsite at another of our facilities supporting environmental compliance activities. I accepted a corporate role in the last 2 months and am now supporting all of our North America sites and we are working on transitioning Moncure site environmental compliance to another individual! The emissions for OS51 are different than emissions from OS75. OS75 are emissions related strictly to when the Energy unit is going to the abort bunker (during malfunctions, start up, shut down, etc). OS51 are emissions associated with the unit whenever wood (as opposed to natural gas) is the combustion fuel source (emissions routed to the biofilter, not the abort bunker). Please let me know if this makes sense or you have any questions! Happy Friday, Savannah Savannah Carroll Corporate Environmental Manager 985 Corinth Road, Moncure NC 27559 Phone: (919) 545-5848 Mobile: (843) 544-3025 www.arauco-na.com From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Wednesday, August 24, 2022 11:54 AM To: Savannah Carroll <savannah.carroll@arauco.com> Subject: RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) ADVERTENCIA: Este es un correo externo a la organización. NO HAGA CLIC en enlaces ni descargue adjuntos antes de reconocer al remitente y saber que el contenido es seguro. Ante sospechas reporte a spamO365@arauco.com No worries, this is very helpful. This sort of thing is the reason why we do these QA reviews every year. I greatly appreciate your quick responses and clear answers. I’ll look this over more closely and put together a specific list of the changes to be made to both this year and last year’s data so you can approve it. If I remember correctly, we can’t make changes to last year’s data until this year’s data is locked, which happens later in the fall, once they have all been reviewed. I still have one thing that still I don’t feel like I understand – What is the origin of the emissions entered in AERO for OS51/ ES02-A Energy Plant Wood Burning? Are those emissions separate/distinct/different from OS75? Jeff From: Savannah Carroll <savannah.carroll@arauco.com> Sent: Wednesday, August 24, 2022 11:28 AM To: Harris, Jeff <jeff.harris@ncdenr.gov> Subject: RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Hi Jeff, Please see my answers below in red. I apologize for any errors in reporting! Last year was my first year onsite filling out the emissions inventory and a significant amount of the process emissions calcs/operating scenarios were changed from previous years so there is a good chance I made some errors in entry. Please let me know of any questions or concerns! Thanks, Savannah Savannah Carroll Corporate Environmental Manager 985 Corinth Road, Moncure NC 27559 Phone: (919) 545-5848 Mobile: (843) 544-3025 www.arauco-na.com From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Wednesday, August 24, 2022 10:15 AM To: Savannah Carroll <savannah.carroll@arauco.com> Subject: RE: [External] RE: 2021 Emission Inventory for Arauco (1900015) ADVERTENCIA: Este es un correo externo a la organización. NO HAGA CLIC en enlaces ni descargue adjuntos antes de reconocer al remitente y saber que el contenido es seguro. Ante sospechas reporte a spamO365@arauco.com Hi Savannah, I’m making good progress reviewing the 2021 inventory for Arauco, and the spreadsheet you sent was very helpful, but there are a few things I can’t quite sort out when I compare the emissions to last year’s. For convenience in discussion, I’ll make a list: 1. ~40% decrease in PM10/PM2.5 from a 3% INCREASE in operation for ES-02-C1/OS86, Backup NG fired dryer burner? It looks to me as though this difference is due to a typo in last year's emissions. It looks like 55.46 lb/yr was entered as tpy rather than the correct value of 0.03 tpy for 2020 and was not caught because 2020 was the first year for the OS. Do you agree with this assessment? You are correct, lb/yr were entered instead of tpy. The correct value for 2020 is .03 tpy. If this is the case, this is a significant difference in reported criteria pollutant emissions, and we will probably want to go back and revise last year’s inventory data. (I’ll do it, all I’ll need from you is confirmation.) 2. ~70% increase in SO2 from a 25% DECREASE in operation for ES-02A/OS75 Energy system bypass mode? Is this an error in data entry? The SO2 emissions in the spreadsheet you provided (0.37 tpy) don’t match the value entered in ED/AERO (6.35 tpy). 6.35 tpy SO2 appears to be the value entered for ES02-A/ OS51 wood burning – maybe it was entered accidentally? Honestly, I’m a little confused here, because I don’t see OS51/ ES02-A Energy Plant Wood Burning in the spreadsheet you sent. Are these emissions being double-counted in OS75 and OS51? If so, which values are correct? The correct value is .37 tpy for bypass mode for 2021. I incorrectly entered for OS-02 softwood firing, which is found in the tab title “MDF-ES-02B.” 3. ~52% decrease in CrVI from a 25% decrease in operation for ES-02A/OS75 Energy system bypass mode. This also seems to be due to an error in data entry for 2020. ED/AERO shows OS75 emissions of 0.209 lb/yr for 2020, while the spreadsheet you gave me last year says 0.009. Again this probably was not caught because 2020 was the first year for the OS, so there was no previous data for comparison. Do you agree with this assessment? I agree, I believe this is an entry error (“fat finger”). 4. ~26% increase in Acetaldehyde, Acrolein, Cumene, Formaldehyde (~42%), Phenol, Phosphorus, Propionaldehyde, from a ~10% increase in throughput for ES-02B/OS 69, 2-stage dryer and reduced control efficiency employed in calculations. Do you have any explanation for the change in control efficiencies used in the calculations from the previous year? This was due to a VOC control efficiency change during stack testing that was completed in October 2021. The control efficiency for total VOC was slightly reduced during the 2021 source test compared to 2018 results which is what yielding an increase in those emissions. Formaldehyde control efficiency in 2018 was 96.8% but was demonstrated at 91.5% in 2021. Please don’t hesitate to call me if this isn’t clear, or you want to discuss. These are fairly arcane issues, I know. Thanks, Jeff From: Savannah Carroll <savannah.carroll@arauco.com> Sent: Tuesday, August 23, 2022 11:43 AM To: Harris, Jeff <jeff.harris@ncdenr.gov> Subject: [External] RE: 2021 Emission Inventory for Arauco (1900015) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Hi Jeff, I hope you are doing well. Of course. Please see attached and let me know of any questions or concerns. Thank you, Savannah Savannah Carroll Corporate Environmental Manager 985 Corinth Road, Moncure NC 27559 Phone: (919) 545-5848 Mobile: (843) 544-3025 www.arauco-na.com From: Harris, Jeff <jeff.harris@ncdenr.gov> Sent: Tuesday, August 23, 2022 10:43 AM To: Savannah Carroll <savannah.carroll@arauco.com> Subject: 2021 Emission Inventory for Arauco (1900015) ADVERTENCIA: Este es un correo externo a la organización. NO HAGA CLIC en enlaces ni descargue adjuntos antes de reconocer al remitente y saber que el contenido es seguro. Ante sospechas reporte a spamO365@arauco.com Hi Savannah, I’m starting my review of the 2021 inventory for Arauco. Last year you sent me a copy of the excel file with the emissions calculations, which was very helpful in my review. Can you please send me this year’s version? Thank you, Jeff