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HomeMy WebLinkAboutAQ_GEN_PLNG_20220404_SIP_RH-SIP_AppE2d Appendix E-2d Regional Haze Modeling for Southeastern VISTAS II Regional Haze Analysis Project 2028 CAMx Version 6.32 and 6.40 Comparison Report Benchmark Run #4 August 17, 2020 This page intentionally left blank. CAMx Benchmarking Report #4 Regional Haze Modeling for Southeastern VISTAS II Regional Haze Analysis Project 2028 CAMx Version 6.32 and 6.40 Comparison Report Task 6 Benchmark Report #4 Covering Benchmark Run #4 Prepared for: Southeastern States Air Resource Managers, Inc. (SESARM) 205 Corporate Center Drive, Suite D Stockbridge, GA 30281-7383 Under Contract No. V-2018-03-01 Prepared by: Alpine Geophysics, LLC 387 Pollard Mine Road Burnsville, NC 28714 and Eastern Research Group, Inc. 1600 Perimeter Park Dr., Suite 200 Morrisville, NC 27560 Final – August 17, 2020 Alpine Project Number: TS-527 ERG Project Number: 4133.00.006 CAMx Benchmarking Report #4 August 17, 2020 i This page is intentionally blank. CAMx Benchmarking Report #4 August 17, 2020 ii Contents Page 1.0 INTRODUCTION ............................................................................................................1 1.1 Overview ...............................................................................................................1 1.2 2028 CAMx 6.32 and CAMx 6.40 Comparison ...................................................3 2.0 DIFFERENCES BETWEEN CAMX 6.32 AND 6.40 SIMULATIONS .........................3 2.1 Model Code Differences .......................................................................................3 2.2 Configurations Difference ....................................................................................4 2.3 Emissions Differences ..........................................................................................5 3.0 CONFIRMATION METHODOLOGY ............................................................................5 3.1 CAMx Species Mapping .......................................................................................6 4.0 CAMX 6.32 2028EL AND CAMX 6.40 2028ELV3 COMPARISON ............................7 4.1 Emissions ..............................................................................................................7 4.2 Annual PM2.5 Design Value ................................................................................25 4.3 24-Hour (Daily) PM2.5 Design Value ..................................................................34 4.4 Scatterplots of Ozone and PM Species Concentrations ......................................42 5.0 CONCLUSIONS.............................................................................................................49 CAMx Benchmarking Report #4 August 17, 2020 iii This page is intentionally blank. CAMx Benchmarking Report #4 August 17, 2020 iv TABLES Table 3-1. Species Mapping from CAMx into Aggregated Species ...............................................6 Table 4-1. Comparison of 2028el CAMx 6.32 and 2028elv2/v3 CAMx 6.40 Annual Emissions .............................................................................................................................8 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States ................................26 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) ...........................................................................35 FIGURES Figure 4-1. Comparison of Elevated NOX Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ..........................................................................................9 Figure 4-2. Comparison of Elevated VOC Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................10 Figure 4-3. Comparison of Elevated PEC Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................12 Figure 4-4. Comparison of Elevated PNH4 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................13 Figure 4-5. Comparison of Elevated PNO3 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................14 Figure 4-6. Comparison of Elevated POA Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................15 Figure 4-7. Comparison of Elevated PSO4 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations ........................................................................................16 Figure 4-8. Comparison of Low Level NOX Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................17 Figure 4-9. Comparison of Low Level VOC Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................18 Figure 4-10. Comparison of Low Level SO2 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................19 Figure 4-11. Comparison of Low Level PEC Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................20 Figure 4-12. Comparison of Low Level PNH4 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................21 Figure 4-13. Comparison of Low Level PNO3 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................22 CAMx Benchmarking Report #4 August 17, 2020 v Figure 4-14. Comparison of Low Level POA Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................23 Figure 4-15. Comparison of Low Level PSO4 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations ........................................................................................24 Figure 4-16. Comparison of Annual PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations ....................................................................................32 Figure 4-17. Scatterplot Comparing Annual Average Predicted PM2.5 Design Values (µg/m3) at all Monitor Locations for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations Performed by VISTAS (Alpine) ....................................................................33 Figure 4-18. Comparison of Daily PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations ....................................................................................40 Figure 4-19. Comparison of Daily PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations ....................................................................................41 Figure 4-20. Scatterplot Comparing 24-hour Average Predicted Ozone Concentrations (ppb) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) ...........................................................42 Figure 4-21. Scatterplot Comparing 24-hour Average Predicted PM2.5 Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) ...........................................................43 Figure 4-22. Scatterplot Comparing 24-hour Average Predicted PM2.5 Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine); Modified Scale ........................44 Figure 4-23. Scatterplot Comparing 24-hour Average Predicted Sulfate Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) ...................................................45 Figure 4-24. Scatterplot Comparing 24-hour Average Predicted Nitrate Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) ...................................................46 Figure 4-25. Scatterplot Comparing 24-hour Average Predicted Organic Carbon Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) ........................47 Figure 4-26. Scatterplot Comparing 24-hour Average Predicted Organic Carbon Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine); Modified Scale ...................................................................................................................................48 CAMx Benchmarking Report #4 August 17, 2020 vi Abbreviations/Acronym List Alpine Alpine Geophysics, LLC CAMx Comprehensive Air Quality Model with Extensions dv Deciview DV Design Value EGU Electric Generating Unit EPA Environmental Protection Agency ERG Eastern Research Group, Inc. ERTAC Eastern Regional Technical Advisory Committee FLM Federal Land Manager FR Federal Register IPM Integrated Planning Model km kilometer µg/m3 microgram per cubic meter NAAQS National Ambient Air Quality Standard NOx Oxides of nitrogen OAQPS Office of Air Quality Planning and Standards O3 Ozone OC Organic carbon OSAT Ozone Source Apportionment Technology PEC Primary elemental carbon PM Particulate matter PM2.5 Fine particle; primary particulate matter less than or equal to 2.5 microns in aerodynamic diameter PNH4 Particulate ammonium PNO3 Particulate nitrate POA Primary Organic Aerosol PSAT Particulate Source Apportionment Technology PSO4 Particulate sulfate R2 Pearson correlation coefficient squared RADM-AQ Regional Acid Deposition Model – aqueous chemistry RHR Regional Haze Rule SESARM Southeastern States Air Resource Managers, Inc. SIP State Implementation Plan SMAT-CE Software for Model Attainment Test – Community Edition SMOKE Sparse Matrix Operator Kernel Emissions SO2 Sulfur dioxide SOA Secondary organic aerosol SOAP Secondary organic aerosol partitioning tpy Tons per year U.S. United States VISTAS Visibility Improvement – State and Tribal Association of the Southeast VOC Volatile organic compounds CAMx Benchmarking Report #4 August 17, 2020 vii This page is intentionally blank. CAMx Benchmarking Report #4 August 17, 2020 1 1.0 INTRODUCTION 1.1 Overview Southeastern States Air Resource Managers, Inc. (SESARM) has been designated by the United States (U.S.) Environmental Protection Agency (EPA) as the entity responsible for coordinating regional haze evaluations for the ten Southeastern states of Alabama, Florida, Georgia, Kentucky, Mississippi, North Carolina, South Carolina, Tennessee, Virginia, and West Virginia. The Eastern Band of Cherokee Indians and the Knox County, Tennessee local air pollution control agency are also participating agencies. These parties are collaborating through the Regional Planning Organization known as Visibility Improvement - State and Tribal Association of the Southeast (VISTAS) in the technical analyses and planning activities associated with visibility and related regional air quality issues. VISTAS analyses will support the VISTAS states in their responsibility to develop, adopt, and implement their State Implementation Plans (SIPs) for regional haze. The state and local air pollution control agencies in the Southeast are mandated to protect human health and the environment from the impacts of air pollutants. They are responsible for air quality planning and management efforts including the evaluation, development, adoption, and implementation of strategies controlling and managing all criteria air pollutants including fine particles and ozone (O3) as well as regional haze. This project will focus on regional haze and regional haze precursor emissions. Control of regional haze precursor emissions will have the additional benefit of reducing criteria pollutants as well. The 1999 Regional Haze Rule (RHR) identified 18 Class I Federal areas (national parks greater than 6,000 acres and wilderness areas greater than 5,000 acres) in the VISTAS region. The 1999 RHR required states to define long-term strategies to improve visibility in Federal Class I national parks and wilderness areas. States were required to establish baseline visibility conditions for the period 2000-2004, natural visibility conditions in the absence of anthropogenic influences, and an expected rate of progress to reduce emissions and incrementally improve visibility to natural conditions by 2064. The original RHR required states to improve visibility on the 20% most impaired days and protect visibility on the 20% least impaired days.1 The RHR 1 RHR summary data is available at: http://vista.cira.colostate.edu/Improve/rhr-summary-data/ CAMx Benchmarking Report #4 August 17, 2020 2 requires states to evaluate progress toward visibility improvement goals every five years and submit revised SIPs every ten years. EPA finalized revisions to various requirements of the RHR in January 2017 (82 FR 3078) that were designed to strengthen, streamline, and clarify certain aspects of the agency’s regional haze program including: A. Strengthening the Federal Land Manager (FLM) consultation requirements to ensure that issues and concerns are brought forward early in the planning process. B. Updating the SIP submittal deadlines for the second planning period from July 31, 2018 to July 31, 2021 to ensure that they align where applicable with other state obligations under the Clean Air Act. The end date for the second planning period remains 2028; that is, the focus of state planning will be to establish reasonable progress goals for each Class I area against which progress will be measured during the second planning period. This extension will allow states to incorporate planning for other Federal programs while conducting their regional haze planning. These other programs include: the Mercury and Air Toxics Standards, the 2010 1-hour sulfur dioxide (SO2) National Ambient Air Quality Standards (NAAQS); the 2012 annual fine particle (PM2.5) NAAQS; and the 2008 and 2015 ozone NAAQS. C. Adjusting interim progress report submission deadlines so that second and subsequent progress reports will be due by: January 31, 2025; July 31, 2033; and every ten years thereafter. This means that one progress report will be required midway through each planning period. D. Removing the requirement for progress reports to take the form of SIP revisions. States will be required to consult with FLMs and obtain public comment on their progress reports before submission to the EPA. EPA will be reviewing but not formally approving or disapproving these progress reports. The RHR defines “clearest days” as the 20% of monitored days in a calendar year with the lowest deciview (dv) index values. “Most impaired days” are defined as the 20% of CAMx Benchmarking Report #4 August 17, 2020 3 monitored days in a calendar year with the highest amounts of anthropogenic visibility impairment. The long-term strategy and the reasonable progress goals must provide for an improvement in visibility for the most impaired days since the baseline period and ensure no degradation in visibility for the clearest days since the baseline period. 1.2 2028 CAMx 6.32 and CAMx 6.40 Comparison Recent EPA 2011el and 2028el platform simulations were performed with the Comprehensive Air Quality Model with Extensions (CAMx) version 6.32. Since that time the CAMx model has been updated to include better physical treatment, and to correct any model flaws that were discovered after the release of 6.32. Under subcontract to Eastern Research Group, Inc, (ERG), Alpine Geophysics, LLC (Alpine) has executed two air quality simulations for the 2028el projection year modeling platform; one run with CAMx 6.32 and one with CAMx 6.40. We note that CAMx 6.50 has now been released, however that model release was too late to be included with sufficient certainty in the VISTAS II project schedule. This comparison is to document the differences in model estimates between 2028el simulated with CAMx 6.32 and 2028elv3 CAMx 6.40 as is discussed in the VISTAS II Modeling Protocol 2 in Section 6.5.2 model comparison number 4. 2.0 DIFFERENCES BETWEEN CAMX 6.32 AND 6.40 SIMULATIONS Differences in modeled output concentrations between the 2028el CAMx 6.32 and 2028elv3 6.40 simulations were as a result both of changes to the CAMx model code, changes to the model configuration and changes to the emissions inventory. 2.1 Model Code Differences Many updates to the CAMx model were implemented between the 6.32 and 6.40 release. According to the CAMx 6.40 release notes, the significant changes included: 2 “Regional Haze Modeling for Southeastern VISTAS II Region Haze Analysis Project, Final Modeling Protocol.” Prepared for SESARM under Contract No. V-2018-03-01. Prepared by Alpine Geophysics, LLC and Eastern Research Group, Inc. June 27, 2018. CAMx Benchmarking Report #4 August 17, 2020 4 1. Updates to the chemistry to include a condensed halogen mechanism for ocean-borne inorganic reactive iodine, hydrolysis of isoprene-derived organic nitrate and SO2 oxidation on primary crustal fine particulate matter (PM). This update includes the changes to the Ozone and Particulate Source Apportionment Technology (OSAT/PSAT) algorithms; 2. Inclusion of in-line inorganic iodine emissions to support halogen chemical mechanisms; 3. A major revision to the secondary organic aerosol partitioning (SOAP) secondary algorithm; 4. Updates to the Regional Acid Deposition Model – aqueous chemistry (RADM-AQ) algorithm; and 5. A major revision to the wet deposition algorithm to identify assumptions or processes that were unintentionally or otherwise unreasonably limiting gas and PM update into precipitation. The wet deposition algorithm was simplified and improved in several ways, resulting in the increased scavenging of gases and PM. 2.2 Configurations Difference In addition to the model version, the CAMx 6.32 and 6.40 simulations contained differences in the EPA modeling platform that had been made subsequent to the 2011el/2028el model release. In the most current 2023en simulation, EPA developed new photolysis rates and ozone column data. These updates were included in the updated modeling platform and resulting CAMx 6.40 simulation and were consistent with those used in the VISTAS II 2011el simulations. Another configuration difference is how the boundary conditions were mapped for speciation in the two versions of the model. EPA and the VISTAS CAMx 6.32 and 6.40 simulations all used the same boundary condition files. However, when CAMx was updated from 6.32 to 6.40 the species in the secondary organic aerosol (SOA) scheme changed. The SOA5, SOA6, and SOA7 were removed and SOA3 and SOA4 were redefined. Neither EPA nor CAMx Benchmarking Report #4 August 17, 2020 5 this study remapped the boundary conditions to account for this change. EPA examined the regional haze summary data for all Class I areas and found the total organic carbon (OC) species (not just SOA) accounted for 1-5% of the boundary condition impairment at the Southeastern Class I areas.3 This is a small impact on regional haze and the impact of SOA on regional haze is even smaller. 2.3 Emissions Differences Finally, there are notable emissions inventory differences used in the modeling by SESARM compared to EPA’s 2028el modeling platform. SESARM updated the 2028 emissions inventory used in this analysis (2028elv2) with changes to both electric generating unit (EGU) and non-EGU point source emissions. A summary of the emission differences are presented in the Task 2 emissions inventory report 4 for this study and summarized in Section 4.1. 3.0 CONFIRMATION METHODOLOGY The presented comparison of model simulations are based on annual and 24-hour PM2.5 design values as generated from the output of the two 12US2-based simulations; CAMx 6.32 with 2028el and CAMx 6.40 with 2028elv2 emissions. This report does not compare hourly concentrations for each PM species as the model version, platform configuration and processing methods, and the underlying projection year emissions inventories differ significantly between the two model runs making it difficult, if not impossible, to determine the cause of any differences seen in concentrations. We also provide a comparison of gridded 12-kilometer (km) annual elevated and low level emissions for the domain. The metric for comparison of the design values are the absolute difference (Equation 1) and percent difference (Equation 2) defined as: (Equation 1) (𝐶𝐶6.40 −𝐶𝐶6.32 ) (Equation 2) (𝐶𝐶6.40−𝐶𝐶6.32 )(𝐶𝐶6.32 ) Where C6.40 is the design value at each receptor for the CAMx 6.40 simulation and C6.32 is the design value at each receptor for the CAMx 6.32 simulation. The order of the comparison 3 Brian Timin, EPA Office of Air Quality Planning and Standards (OAQPS) personal communication October 11, 2018. 4 Southeastern States Air Resource Managers, Inc. "Southeastern VISTAS II Regional Haze Analysis Project - Task 2 Emission Inventory Report." Prepared by Eastern Research Group, Inc. under Contract V-2018-03-01. Revised Final. August 28, 2018. CAMx Benchmarking Report #4 August 17, 2020 6 variables differs from earlier benchmark reports as the intention of this report is to confirm appropriate use of the CAMx 6.40 configuration as compared to the CAMx 6.32 configuration and therefore by using the switched order, we give more weight to the CAMx 6.40 run. For the emission comparison plots, only Equation 1 results were calculated for each grid cell and plotted for review. The results are presented for each receptor in the VISTAS states within the larger 12US2 domain for each of the two design values. Spatial maps are presented for the domain as a whole. On each spatial emissions difference plot presented, the maximum positive and negative values, along with the grid cell in which these occur, are presented at the top of the graphic. The coordinates refer to the row and columns of the cell referenced to the cell coordinates on the bottom (column) and left (row) of the graphic. Scatterplots of the daily average concentrations of ozone and the various calculated PM species in local standard time at the Interagency Monitoring for Protected Visual Environment (IMPROVE) monitors across all modeled days are also presented with the CAMx 6.40 results plotted on the x-axis and the CAMx 6.32 results plotted on the y-axis. 3.1 CAMx Species Mapping Updates to the CAMx model between version 6.32 and 6.40 necessitated making changes to how the individual CAMx species were aggregated to the presented species. The CAMx species mapping between the two compared versions are presented in Table 3-1. Table 3-1. Species Mapping from CAMx into Aggregated Species Aggregated Species CAMx 6.32 Species CAMx 6.40 Species Ozone O3 O3 PM2.5 PSO4+PNO3+PNH4+SOA1+SOA2+SOA3 +SOA4+SOA5+SOA6+SOA7+SOPA+SOP B+POA+PEC+FPRM+FCRS+NA+PCL PSO4+PNO3+PNH4+SOA1+SOA2 +SOA3+SOA4+SOPA+SOPB+POA +PEC+FPRM+FCRS+NA+PCL Sulfate PSO4 PSO4 Nitrate PNO3 PNO3 Organic Matter (OM) SOA1+SOA2+SOA3+SOA4+SOA5+SOA6 +SOA7+SOPA+SOPB+POA1 SOA1+SOA2+SOA3+SOA4+SOPA +SOPB+POA 1 SOAH was not included in the 6.32 comparison since it was not included as an output species in the EPA simulation. CAMx Benchmarking Report #4 August 17, 2020 7 4.0 CAMX 6.32 2028EL AND CAMX 6.40 2028ELV3 COMPARISON This section presents comparisons of the simulations using CAMx 6.32 2028el and CAMx 6.40 2028elv3 performed on the Alpine computer system. Emissions presented are the post-processed results of the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions tool, including oxides of nitrogen (NOX), volatile organic compounds (VOC), and speciated PM2.5 components (e.g., particulate nitrate (PNO3), particulate sulfate (PSO4), etc.) for elevated and low level sources. Annual and 24-Hour PM2.5 design values are the result of running each of the model platforms through the Software for the Modeled Attainment Test - Community Edition (SMAT-CE) tool to generate receptor-level values. 4.1 Emissions Annual emission summaries have been prepared from the model-ready input files for both elevated and low level sources. Elevated sources include all CEM-based emissions in the modeling platform, non-EGU point sources with explicit latitude and longitude release coordinates and calculated plume rise greater than or equal to twenty (20) meters, emissions from wildfires, and international commercial marine emissions not otherwise associated with specific U.S. states. Low-level sources are comprised of all other anthropogenic source types including non-EGU point sources with a calculated plume rise of less than twenty (20) meters, agricultural and prescribed fires, biogenic and other natural source emissions, and commercial marine emissions associated with sources assigned to specific U.S. states. Results presented include maps of the 12US2 domain with annual emissions (tons per year) and emission differences by grid cell and pollutant. Table 4-1 presents summary results by pollutant over the entire 12US2 domain for elevated and low level comparisons. Figures 4-1 through 4-7 present the annual emissions and emission differences for elevated sources by pollutant in the 12US2 modeling domain. Figures 4-8 through 4-15 present annual emissions and emission differences for low level sources, by pollutant, in the 12US2 modeling domain. As expected with the changes in emission inventories between the EPA 2028el and SESARM 2028elv2 platforms, we see the largest changes in elevated (point source) emissions largely concentrated in the southeastern sector of the modeling domain with scattered differences in other regions. These changes are related to the replacement of 2028 Integrated Planning Model (IPM) EGU emissions with 2028 Eastern Regional Technical Advisory Committee CAMx Benchmarking Report #4 August 17, 2020 8 (ERTAC) EGU emissions in the 2028elv2 emissions platform. These differences are consistent with the emission inventory changes documented4 for this project. Low-level emission changes are also seen predominantly in the VISTAS states for areas where emission inventory modifications were applied for this analysis with scattered changes elsewhere due to the replacement of IPM with ERTAC as noted above. Note that as a result of reprocessing the 2028elv2 elevated emissions to correct an earlier omission, results are reported in this document 2028elv3 where appropriate. Table 4-1. Comparison of 2028el CAMx 6.32 and 2028elv2/v3 CAMx 6.40 Annual Emissions Source Type Pollutant 2028 Annual Emissions CAMx 6.40 6.40 - 6.32 Domain Wide Individual Grid Cell Total Tons Total Change % Change Max Increase Max Decrease Elevated NOX 4,512,000 489,300 10.84% 25,810 -25,250 Elevated VOCa 4,707,000 -8,096 -0.17% 2,046 -2,615 Elevated SO2 3,977,000 795,000 19.99% 54,910 -38,780 Elevated PEC 261,300 16,620 6.36% 358 -126 Elevated PNH4b 14,690 3.47E+01 0.24% 32 -15 Elevated PNO3 15,460 8.64E+02 5.59% 20 -25 Elevated POA 1,734,000 12,240 0.71% 323 -1,269 Elevated PSO4 83,570 1,814 2.17% 388 -298 Low Level NOX 7,302,000 5,788 0.08% 632 -1,695 Low Level VOC 60,670,000 45,170 0.07% 2,615 -861 Low Level SO2 321,500 2,623 0.82% 1,487 -501 Low Level PEC 151,900 324 0.21% 77 -9 Low Level PNH4b 6,696 13 0.20% 6 -3 Low Level PNO3 4,671 44 0.95% 12 -5 Low Level POA 909,600 -2,630 -0.29% 54 -87 Low Level PSO4 198,300 1,223 0.62% 82 -19 a VOC emissions are approximate since calculated from CB6 speciated emissions. b PNH4 = Particulate ammonium CAMx Benchmarking Report #4 August 17, 2020 9 Annual NOX Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-1. Comparison of Elevated NOX Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 10 Annual VOC Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-2. Comparison of Elevated VOC Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 11 Annual SO2 Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-3. Comparison of Elevated SO2 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 12 Annual PEC Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-3. Comparison of Elevated PEC Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 13 Annual PNH4 Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-4. Comparison of Elevated PNH4 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 14 Annual PNO3 Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-5. Comparison of Elevated PNO3 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 15 Annual POA Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-6. Comparison of Elevated POA Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 16 Annual PSO4 Emissions – Elevated Sources 2028elv3 Difference (2028elv3 - 2028el) Figure 4-7. Comparison of Elevated PSO4 Emissions (tpy) for CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 17 Annual NOX Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-8. Comparison of Low Level NOX Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 18 Annual VOC Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-9. Comparison of Low Level VOC Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 19 Annual SO2 Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-10. Comparison of Low Level SO2 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 20 Annual PEC Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-11. Comparison of Low Level PEC Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 21 Annual PNH4 Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-12. Comparison of Low Level PNH4 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 22 Annual PNO3 Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-13. Comparison of Low Level PNO3 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 23 Annual POA Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-14. Comparison of Low Level POA Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 24 Annual PSO4 Emissions – Low Level Sources 2028elv2 Difference (2028elv2 - 2028el) Figure 4-15. Comparison of Low Level PSO4 Emissions (tpy) for CAMx 6.40 2028elv2 and CAMx 6.32 2028el Simulations CAMx Benchmarking Report #4 August 17, 2020 25 4.2 Annual PM2.5 Design Value Annual PM2.5 design values were generated using the results of each individual CAMx simulation (version 6.32 with EPA’s 2028el platform and version 6.40 with SESARM’s 2028elv3 emissions platform) and the SMAT-CE tool. Results for each individual receptor in the VISTAS states are presented in tabular format in Table 4-2 along with the absolute difference and percent difference in design value. The maximum calculated increase is 0.51 µg/m3 at monitor 510590030 in Fairfax, Virginia (7% increase between 6.32 and 6.40) and maximum decrease is 0.43 µg/m3 at monitor 210290006 in Bullitt County, Kentucky (4% decrease going from 6.32 to 6.40). The average change in annual design value for all monitors in the VISTAS states is an increase of 0.20 µg/m3, with an average annual percent increase of 3% at these same locations. Geographic distribution of the 6.40 annual PM2.5 design values and differences in design values compared to the 6.32 simulation is presented in Figure 4-16. In the VISTAS state region, the largest annual PM2.5 design value fractional change is seen along the Atlantic coast and through much of North Carolina. The smallest fractional changes seen inside the heart of the SESARM state domain consistent with significant emission reductions modeled from updated EGU inventories within these states. A scatterplot of the annual PM2.5 design values for all FRM monitors in the 12US2 domain is presented in Figure 4-17. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has a high degree of correlation with a line of best fit with a slope of 0.9875, an intercept of -0.1058 µg/m3and an R2 of 0.9825. The agreement between the models is higher at lower concentrations. CAMx 6.40 concentrations appear to be marginally higher compared to CAMx 6.32 at low and medium concentration ranges and slightly lower than the CAMx 6.32 results in high concentration ranges. CAMx Benchmarking Report #4 August 17, 2020 26 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 010030010 Alabama Baldwin 7.98 8.06 0.08 1% 010270001 Alabama Clay 7.78 7.92 0.14 2% 010331002 Alabama Colbert 8.21 8.37 0.16 2% 010491003 Alabama DeKalb 8.33 8.52 0.19 2% 010550010 Alabama Etowah 8.66 8.84 0.18 2% 010690003 Alabama Houston 8.12 8.25 0.13 2% 010730023 Alabama Jefferson 10.92 11.17 0.25 2% 010731005 Alabama Jefferson 9.25 9.33 0.08 1% 010731009 Alabama Jefferson 8.16 8.24 0.08 1% 010731010 Alabama Jefferson 9.44 9.56 0.12 1% 010732003 Alabama Jefferson 10.14 10.31 0.17 2% 010732006 Alabama Jefferson 9.42 9.50 0.08 1% 010735002 Alabama Jefferson 8.74 8.97 0.23 3% 010735003 Alabama Jefferson 8.55 8.68 0.13 2% 010890014 Alabama Madison 8.94 9.15 0.21 2% 010970003 Alabama Mobile 8.02 8.16 0.14 2% 010972005 Alabama Mobile 7.74 7.83 0.09 1% 011011002 Alabama Montgomery 9.33 9.58 0.25 3% 011030011 Alabama Morgan 8.53 8.73 0.20 2% 011130001 Alabama Russell 9.98 10.17 0.19 2% 011170006 Alabama Shelby 8.11 8.18 0.07 1% 011210002 Alabama Talladega 9.02 9.14 0.12 1% 011250004 Alabama Tuscaloosa 8.60 8.74 0.14 2% 011270002 Alabama Walker 9.00 9.12 0.12 1% 120990008 Florida Palm Beach 6.84 6.94 0.10 1% 120990009 Florida Palm Beach 5.70 5.85 0.15 3% 130210007 Georgia Bibb 10.70 10.60 -0.10 -1% 130210012 Georgia Bibb 8.08 7.95 -0.13 -2% CAMx Benchmarking Report #4 August 17, 2020 27 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 130510091 Georgia Chatham 8.57 8.54 -0.03 0% 130590002 Georgia Clarke 8.01 8.13 0.12 1% 130630091 Georgia Clayton 9.30 9.43 0.13 1% 130670004 Georgia Cobb 8.48 8.73 0.25 3% 130890002 Georgia DeKalb 8.60 8.76 0.16 2% 130950007 Georgia Dougherty 10.33 10.41 0.08 1% 131150003 Georgia Floyd 9.31 9.48 0.17 2% 131210039 Georgia Fulton 10.18 10.36 0.18 2% 131390003 Georgia Hall 7.94 8.07 0.13 2% 131530001 Georgia Houston 8.60 8.55 -0.05 -1% 132150001 Georgia Muscogee 10.59 10.78 0.19 2% 132450005 Georgia Richmond 9.53 9.27 -0.26 -3% 132450091 Georgia Richmond 9.87 9.54 -0.33 -3% 132950002 Georgia Walker 7.90 8.02 0.12 2% 133190001 Georgia Wilkinson 10.26 9.97 -0.29 -3% 210130002 Kentucky Bell 8.68 8.80 0.12 1% 210190017 Kentucky Boyd 8.00 8.31 0.31 4% 210290006 Kentucky Bullitt 9.75 9.32 -0.43 -4% 210373002 Kentucky Campbell 7.36 7.61 0.25 3% 210430500 Kentucky Carter 6.57 6.80 0.23 4% 210470006 Kentucky Christian 8.28 8.39 0.11 1% 210590005 Kentucky Daviess 9.11 9.25 0.14 2% 210670012 Kentucky Fayette 7.76 7.97 0.21 3% 210930006 Kentucky Hardin 8.30 8.40 0.10 1% 211010014 Kentucky Henderson 8.68 8.96 0.28 3% 211110067 Kentucky Jefferson 9.53 9.44 -0.09 -1% 211451004 Kentucky McCracken 8.57 8.84 0.27 3% 211510003 Kentucky Madison 6.77 6.97 0.20 3% CAMx Benchmarking Report #4 August 17, 2020 28 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 211950002 Kentucky Pike 7.71 8.03 0.32 4% 212270008 Kentucky Warren 8.72 8.83 0.11 1% 280330002 Mississippi DeSoto 8.15 8.36 0.21 3% 280350004 Mississippi Forrest 9.81 9.92 0.11 1% 280430001 Mississippi Grenada 7.81 8.00 0.19 2% 280450003 Mississippi Hancock 8.31 8.23 -0.08 -1% 280470008 Mississippi Harrison 7.99 7.99 0.00 0% 280490010 Mississippi Hinds 9.45 9.58 0.13 1% 280590006 Mississippi Jackson 7.91 7.90 -0.01 0% 280670002 Mississippi Jones 10.01 10.10 0.09 1% 280750003 Mississippi Lauderdale 9.13 9.20 0.07 1% 280810005 Mississippi Lee 9.21 9.36 0.15 2% 370010002 North Carolina Alamance 7.01 7.36 0.35 5% 370210034 North Carolina Buncombe 6.77 6.97 0.20 3% 370330001 North Carolina Caswell 6.22 6.57 0.35 6% 370350004 North Carolina Catawba 7.71 7.98 0.27 4% 370370004 North Carolina Chatham 5.73 6.07 0.34 6% 370510009 North Carolina Cumberland 7.38 7.65 0.27 4% 370570002 North Carolina Davidson 8.14 8.54 0.40 5% 370610002 North Carolina Duplin 6.36 6.48 0.12 2% 370630015 North Carolina Durham 6.69 7.00 0.31 5% 370650004 North Carolina Edgecombe 6.35 6.66 0.31 5% 370670022 North Carolina Forsyth 6.91 7.33 0.42 6% 370670030 North Carolina Forsyth 6.91 7.34 0.43 6% 370710016 North Carolina Gaston 7.52 7.77 0.25 3% 370810013 North Carolina Guilford 6.59 6.97 0.38 6% 370810014 North Carolina Guilford 6.72 7.13 0.41 6% 370870012 North Carolina Haywood 7.84 7.86 0.02 0% CAMx Benchmarking Report #4 August 17, 2020 29 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 370990006 North Carolina Jackson 7.06 7.15 0.09 1% 371010002 North Carolina Johnston 6.38 6.70 0.32 5% 371070004 North Carolina Lenoir 6.59 6.85 0.26 4% 371110004 North Carolina McDowell 7.37 7.60 0.23 3% 371170001 North Carolina Martin 6.01 6.38 0.37 6% 371190041 North Carolina Mecklenburg 7.86 8.11 0.25 3% 371190042 North Carolina Mecklenburg 8.21 8.45 0.24 3% 371190043 North Carolina Mecklenburg 7.37 7.64 0.27 4% 371210001 North Carolina Mitchell 7.04 7.19 0.15 2% 371230001 North Carolina Montgomery 6.62 6.95 0.33 5% 371290002 North Carolina New Hanover 5.39 5.61 0.22 4% 371470006 North Carolina Pitt 5.98 6.29 0.31 5% 371550005 North Carolina Robeson 7.29 7.51 0.22 3% 371590021 North Carolina Rowan 7.54 7.84 0.30 4% 371730002 North Carolina Swain 7.40 7.50 0.10 1% 371830014 North Carolina Wake 7.58 7.89 0.31 4% 371830020 North Carolina Wake 6.78 7.09 0.31 5% 371890003 North Carolina Watauga 6.07 6.28 0.21 3% 371910005 North Carolina Wayne 7.14 7.40 0.26 4% 450190048 South Carolina Charleston 6.91 7.11 0.20 3% 450190049 South Carolina Charleston 6.66 6.88 0.22 3% 450250001 South Carolina Chesterfield 7.46 7.69 0.23 3% 450370001 South Carolina Edgefield 8.01 8.03 0.02 0% 450410003 South Carolina Florence 8.45 8.65 0.20 2% 450450009 South Carolina Greenville 8.41 8.65 0.24 3% 450450015 South Carolina Greenville 8.68 8.92 0.24 3% 450630008 South Carolina Lexington 8.57 8.64 0.07 1% 450830011 South Carolina Spartanburg 8.26 8.47 0.21 3% CAMx Benchmarking Report #4 August 17, 2020 30 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 470650031 Tennessee Hamilton 8.43 8.55 0.12 1% 470651011 Tennessee Hamilton 8.32 8.45 0.13 2% 470654002 Tennessee Hamilton 8.16 8.30 0.14 2% 510030001 Virginia Albemarle 6.32 6.67 0.35 6% 510360002 Virginia Charles 6.23 6.57 0.34 5% 510410003 Virginia Chesterfield 7.06 7.44 0.38 5% 510590030 Virginia Fairfax 6.87 7.38 0.51 7% 510690010 Virginia Frederick 7.70 8.19 0.49 6% 510870014 Virginia Henrico 6.81 7.17 0.36 5% 510870015 Virginia Henrico 6.38 6.76 0.38 6% 511071005 Virginia Loudoun 7.08 7.57 0.49 7% 511390004 Virginia Page 6.77 7.13 0.36 5% 511650003 Virginia Rockingham 7.56 7.89 0.33 4% 515200006 Virginia Bristol City 7.53 7.73 0.20 3% 516500008 Virginia Hampton City 5.65 5.93 0.28 5% 516800015 Virginia Lynchburg City 6.24 6.52 0.28 4% 517100024 Virginia Norfolk City 6.77 7.04 0.27 4% 517700015 Virginia Roanoke City 7.47 7.73 0.26 3% 517750011 Virginia Salem City 7.24 7.50 0.26 4% 518100008 Virginia Virginia Beach City 6.71 6.98 0.27 4% 540030003 West Virginia Berkeley 8.90 9.38 0.48 5% 540090005 West Virginia Brooke 9.10 9.59 0.49 5% 540110006 West Virginia Cabell 8.81 9.09 0.28 3% 540291004 West Virginia Hancock 8.27 8.73 0.46 6% 540390010 West Virginia Kanawha 7.84 8.14 0.30 4% 540391005 West Virginia Kanawha 8.97 9.27 0.30 3% 540490006 West Virginia Marion 8.75 9.21 0.46 5% 540511002 West Virginia Marshall 9.85 10.03 0.18 2% CAMx Benchmarking Report #4 August 17, 2020 31 Table 4-2. Comparison of 2028el CAMx 6.32 and 2028elv3 CAMx 6.40 Predicted Annual PM2.5 Design Values (µg/m3) for FRM Monitors in VISTAS States Monitor State County 2028 Annual PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 540610003 West Virginia Monongalia 7.57 8.07 0.50 7% 540690010 West Virginia Ohio 8.37 8.72 0.35 4% 540810002 West Virginia Raleigh 6.68 6.99 0.31 5% 541071002 West Virginia Wood 8.91 9.12 0.21 2% CAMx Benchmarking Report #4 August 17, 2020 32 Annual PM2.5 Design Value – 12US2 Domain CAMx 6.40 Percent Difference (CAMx 6.40 - CAMx 6.32) / CAMx 6.32 Figure 4-16. Comparison of Annual PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations CAMx Benchmarking Report #4 August 17, 2020 33 Figure 4-17. Scatterplot Comparing Annual Average Predicted PM2.5 Design Values (µg/m3) at all Monitor Locations for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations Performed by VISTAS (Alpine) CAMx Benchmarking Report #4 August 17, 2020 34 4.3 24-Hour (Daily) PM2.5 Design Value Daily PM2.5 design values were generated using the results of each individual CAMx simulation (version 6.32 with EPA’s 2028el platform and version 6.40 with SESARM’s 2028elv3 platform) and the SMAT-CE tool. Results for each individual receptor in the VISTAS states are presented in tabular format in Table 4-3 along with the absolute difference and percent difference in design value. The maximum calculated increase is 1.1 µg/m3 at monitor 510030001 in Albemarle, Virginia (9% increase going from CAMx 6.32 to 6.40) and maximum calculated decrease is 0.7 µg/m3 at monitor 130210007 in Bibb, Georgia (3% decrease going from CAMx 6.32 to 6.40). The average change in daily design value for all monitors in the VISTAS states is 0.20 µg/m3, with an average daily percent difference of 2% at these same locations. Geographic distribution of the 6.40 daily PM2.5 design values and differences in design values compared to the 6.32 simulation is presented in Figure 4-18. As similarly seen in the annual PM2.5 design values, daily PM2.5 design values have the smallest fractional change within the middle of the VISTAS state domain and the largest daily design value fractional changes are seen across much of the central states region, running north to south along the western border of the VISTAS domain and along the northeastern boundary of the VISTAS domain, adjacent to MARAMA state boundaries. A scatterplot of the daily PM2.5 design values for all FRM monitors in the 12US2 domain is presented in Figure 4-19. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has a high degree of correlation with a line of best fit with a slope of 1.0395, an intercept of -1.1381 µg/m3 and an R2 of 0.9895. CAMx 6.40 concentrations appear to be marginally higher compared to CAMx 6.32 at low concentration ranges and slightly lower than the CAMx 6.32 results in medium to high concentration ranges. CAMx Benchmarking Report #4 August 17, 2020 35 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) Monitor State County 2028 Daily (24-Hr) PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 010030010 Alabama Baldwin 15.8 15.9 0.1 1% 010270001 Alabama Clay 17.1 17.2 0.1 1% 010331002 Alabama Colbert 16.4 16.2 -0.2 -1% 010491003 Alabama DeKalb 16.9 17.1 0.2 1% 010550010 Alabama Etowah 17.8 17.7 -0.1 -1% 010690003 Alabama Houston 17.0 17.0 0.0 0% 010730023 Alabama Jefferson 22.8 22.9 0.1 0% 010731005 Alabama Jefferson 18.0 17.8 -0.2 -1% 010731009 Alabama Jefferson 17.8 17.8 0.0 0% 010731010 Alabama Jefferson 18.2 18.3 0.1 1% 010732003 Alabama Jefferson 20.9 21.2 0.3 1% 010732006 Alabama Jefferson 18.6 18.6 0.0 0% 010735002 Alabama Jefferson 17.6 17.4 -0.2 -1% 010735003 Alabama Jefferson 17.8 17.7 -0.1 -1% 010890014 Alabama Madison 18.5 18.6 0.1 1% 010970003 Alabama Mobile 16.0 16.1 0.1 1% 010972005 Alabama Mobile 16.6 16.7 0.1 1% 011011002 Alabama Montgomery 19.9 19.9 0.0 0% 011030011 Alabama Morgan 16.5 16.5 0.0 0% 011130001 Alabama Russell 23.3 23.4 0.1 0% 011170006 Alabama Shelby 15.8 15.8 0.0 0% 011210002 Alabama Talladega 18.5 18.5 0.0 0% 011250004 Alabama Tuscaloosa 18.9 19.0 0.1 1% 011270002 Alabama Walker 17.8 17.8 0.0 0% 120990008 Florida Palm Beach 15.6 15.7 0.1 1% 120990009 Florida Palm Beach 13.5 13.6 0.1 1% 130210007 Georgia Bibb 22.8 22.1 -0.7 -3% 130210012 Georgia Bibb 18.3 17.9 -0.4 -2% CAMx Benchmarking Report #4 August 17, 2020 36 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) Monitor State County 2028 Daily (24-Hr) PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 130510017 Georgia Chatham 24.7 24.3 -0.4 -2% 130510091 Georgia Chatham 24.3 24.4 0.1 0% 130590002 Georgia Clarke 17.4 17.6 0.2 1% 130670004 Georgia Cobb 16.9 17.1 0.2 1% 130890002 Georgia DeKalb 17.1 17.2 0.1 1% 130950007 Georgia Dougherty 24.4 24.3 -0.1 0% 131390003 Georgia Hall 16.3 16.5 0.2 1% 131530001 Georgia Houston 19.7 19.5 -0.2 -1% 132950002 Georgia Walker 17.5 17.2 -0.3 -2% 133190001 Georgia Wilkinson 20.5 20.2 -0.3 -1% 280330002 Mississippi DeSoto 15.6 15.9 0.3 2% 280350004 Mississippi Forrest 19.5 19.5 0.0 0% 280430001 Mississippi Grenada 15.5 15.8 0.3 2% 280450003 Mississippi Hancock 18.4 18.3 -0.1 -1% 280470008 Mississippi Harrison 15.3 15.1 -0.2 -1% 280490010 Mississippi Hinds 18.1 18.5 0.4 2% 280590006 Mississippi Jackson 17.7 17.6 -0.1 -1% 280670002 Mississippi Jones 20.1 20.3 0.2 1% 280750003 Mississippi Lauderdale 18.5 18.6 0.1 1% 280810005 Mississippi Lee 17.0 17.4 0.4 2% 370010002 North Carolina Alamance 14.7 15.2 0.5 3% 370210034 North Carolina Buncombe 13.0 13.5 0.5 4% 370330001 North Carolina Caswell 12.7 12.8 0.1 1% 370350004 North Carolina Catawba 16.3 16.4 0.1 1% 370370004 North Carolina Chatham 12.6 13.0 0.4 3% 370510009 North Carolina Cumberland 16.6 17.0 0.4 2% 370570002 North Carolina Davidson 15.4 15.9 0.5 3% 370610002 North Carolina Duplin 14.2 14.4 0.2 1% CAMx Benchmarking Report #4 August 17, 2020 37 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) Monitor State County 2028 Daily (24-Hr) PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 370630015 North Carolina Durham 13.6 13.9 0.3 2% 370650004 North Carolina Edgecombe 14.3 14.7 0.4 3% 370670022 North Carolina Forsyth 14.9 15.3 0.4 3% 370670030 North Carolina Forsyth 14.4 14.8 0.4 3% 370710016 North Carolina Gaston 16.2 16.4 0.2 1% 370810013 North Carolina Guilford 15.5 16.1 0.6 4% 370810014 North Carolina Guilford 13.5 14.4 0.9 7% 370870012 North Carolina Haywood 18.7 18.8 0.1 1% 370990006 North Carolina Jackson 13.9 13.8 -0.1 -1% 371010002 North Carolina Johnston 13.8 14.1 0.3 2% 371070004 North Carolina Lenoir 15.3 15.8 0.5 3% 371110004 North Carolina McDowell 15.1 15.4 0.3 2% 371170001 North Carolina Martin 16.5 17.3 0.8 5% 371190041 North Carolina Mecklenburg 17.2 17.5 0.3 2% 371190042 North Carolina Mecklenburg 17.7 17.9 0.2 1% 371190043 North Carolina Mecklenburg 15.0 15.2 0.2 1% 371210001 North Carolina Mitchell 13.8 13.8 0.0 0% 371230001 North Carolina Montgomery 14.5 14.9 0.4 3% 371290002 North Carolina New Hanover 15.6 15.9 0.3 2% 371470006 North Carolina Pitt 14.8 15.4 0.6 4% 371550005 North Carolina Robeson 16.3 16.9 0.6 4% 371590021 North Carolina Rowan 14.9 15.3 0.4 3% 371730002 North Carolina Swain 15.5 15.6 0.1 1% 371830014 North Carolina Wake 16.9 17.4 0.5 3% 371830020 North Carolina Wake 14.1 14.4 0.3 2% 371890003 North Carolina Watauga 12.6 13.0 0.4 3% 371910005 North Carolina Wayne 15.3 15.8 0.5 3% 450190048 South Carolina Charleston 16.2 16.3 0.1 1% CAMx Benchmarking Report #4 August 17, 2020 38 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) Monitor State County 2028 Daily (24-Hr) PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 450190049 South Carolina Charleston 15.6 15.9 0.3 2% 450250001 South Carolina Chesterfield 15.5 15.5 0.0 0% 450370001 South Carolina Edgefield 17.0 16.9 -0.1 -1% 450410003 South Carolina Florence 18.2 18.4 0.2 1% 450450009 South Carolina Greenville 17.9 18.1 0.2 1% 450450015 South Carolina Greenville 19.2 19.3 0.1 1% 450630008 South Carolina Lexington 18.9 19.0 0.1 1% 450790019 South Carolina Richland 19.5 19.4 -0.1 -1% 450830011 South Carolina Spartanburg 17.2 17.4 0.2 1% 470650031 Tennessee Hamilton 18.6 18.6 0.0 0% 470651011 Tennessee Hamilton 17.3 17.0 -0.3 -2% 470654002 Tennessee Hamilton 17.0 16.7 -0.3 -2% 510030001 Virginia Albemarle 12.7 13.8 1.1 9% 510360002 Virginia Charles 13.2 13.9 0.7 5% 510410003 Virginia Chesterfield 14.7 15.5 0.8 5% 510590030 Virginia Fairfax 17.3 18.0 0.7 4% 510690010 Virginia Frederick 18.1 18.6 0.5 3% 510870014 Virginia Henrico 15.4 16.1 0.7 5% 510870015 Virginia Henrico 13.1 14.1 1.0 8% 511071005 Virginia Loudoun 16.1 16.5 0.4 2% 511390004 Virginia Page 15.2 16.1 0.9 6% 511650003 Virginia Rockingham 17.1 17.7 0.6 4% 515200006 Virginia Bristol City 15.7 16.2 0.5 3% 516500008 Virginia Hampton City 14.1 14.9 0.8 6% 516800015 Virginia Lynchburg City 13.4 13.9 0.5 4% 517100024 Virginia Norfolk City 15.0 15.7 0.7 5% 517700015 Virginia Roanoke City 16.4 16.9 0.5 3% 517750011 Virginia Salem City 14.6 15.0 0.4 3% CAMx Benchmarking Report #4 August 17, 2020 39 Table 4-3. Comparison of CAMx 6.40 2028elv3 and CAMx 6.32 2028el Simulation of Daily (24-Hour) PM2.5 Design Values (µg/m3) Monitor State County 2028 Daily (24-Hr) PM2.5 Design Value (µg/m3) 6.32 2028el 6.40 2028elv3 Difference Percent Difference 518100008 Virginia Virginia Beach City 16.4 16.8 0.4 2% 540030003 West Virginia Berkeley 22.8 23.5 0.7 3% 540090005 West Virginia Brooke 18.9 19.2 0.3 2% 540110006 West Virginia Cabell 17.9 18.8 0.9 5% 540291004 West Virginia Hancock 19.6 20.5 0.9 5% 540390010 West Virginia Kanawha 16.1 17.0 0.9 6% 540391005 West Virginia Kanawha 18.2 18.6 0.4 2% 540490006 West Virginia Marion 19.1 19.3 0.2 1% 540511002 West Virginia Marshall 23.1 23.3 0.2 1% 540610003 West Virginia Monongalia 16.2 17.1 0.9 6% 540690010 West Virginia Ohio 17.7 17.9 0.2 1% 540810002 West Virginia Raleigh 13.9 14.3 0.4 3% 541071002 West Virginia Wood 18.6 18.6 0.0 0% CAMx Benchmarking Report #4 August 17, 2020 40 Daily PM2.5 Design Value – 12US2 Domain CAMx 6.40 Percent Difference (CAMx 6.40 – CAMx 6.32) / CAMx 6.32 Figure 4-18. Comparison of Daily PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations CAMx Benchmarking Report #4 August 17, 2020 41 Figure 4-19. Comparison of Daily PM2.5 Design Values (µg/m3) for CAMx 6.32 2028el and CAMx 6.40 2028elv3 Simulations CAMx Benchmarking Report #4 August 17, 2020 42 4.4 Scatterplots of Ozone and PM Species Concentrations Scatterplots of the daily average concentrations of ozone and the various calculated PM species in local standard time at the Interagency Monitoring for Protected Visual Environment (IMPROVE) monitors across all modeled days are presented in Figures 4-20 through 4-26. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. Figure 4-20 exhibits concentrations for ozone have a high degree of correlation with a line of best fit with a slope of 0.9754, an intercept of 0.5203 ppb and an R2 of 0.9974. Results are scattered both above and below the 1:1 line, with marginally higher concentrations estimated by CAMx 6.40 across the concentration range. Figure 4-20. Scatterplot Comparing 24-hour Average Predicted Ozone Concentrations (ppb) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) CAMx Benchmarking Report #4 August 17, 2020 43 Scatterplots of the daily average PM2.5 concentrations in local standard time at the IMPROVE monitors are presented in Figures 4-21 and 4-22 with different axis scaling to facilitate analysis over the full range of concentrations. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has a high degree of correlation with a line of best fit with a slope of 0.9973, an intercept of 0.3731 µg/m3and an R2 of 0.9845. The agreement between the models is higher at higher concentrations. At lower concentrations the CAMx 6.32 results are slightly higher than the CAMx 6.40 results. Figure 4-21. Scatterplot Comparing 24-hour Average Predicted PM2.5 Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) CAMx Benchmarking Report #4 August 17, 2020 44 Figure 4-22. Scatterplot Comparing 24-hour Average Predicted PM2.5 Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine); Modified Scale Scatterplots of the daily average sulfate concentrations in local standard time at the IMPROVE monitors are presented in Figure 4-23. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has considerably more scatter than the ozone or PM2.5 results with a line of best fit with a slope of 0.9057, an intercept of 0.0.092 µg/m3 and an R2 of 0.8566. The vast majority of the points at low concentrations are above the 1:1 line, meaning that the CAMx 6.32 modeled values are higher than the CAMx 6.40 results. The reverse is true at medium and high concentrations where CAMx 6.40 tends to estimate higher concentrations than CAMx 6.32. These are likely a result of the changes in the wet deposition algorithms and the oxidation of SO2 on primary crustal particles and updates to the RADM aqueous chemistry algorithm in addition to the changes in the elevated SO2 emissions. CAMx Benchmarking Report #4 August 17, 2020 45 Figure 4-23. Scatterplot Comparing 24-hour Average Predicted Sulfate Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) Scatterplots of the daily average nitrate concentrations in local standard time at the IMPROVE monitors are presented in Figure 4-24. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has slightly more scatter than the ozone or PM2.5 results with a line of best fit with a slope of 0.9266, an intercept of 0.0009 µg/m3 and an R2 of 0.9743. Unlike the sulfate results which showed more uniform scatter around the 1:1 line, the CAMx 6.40 nitrate results are marginally higher than CAMx 6.32 except at low concentrations. CAMx Benchmarking Report #4 August 17, 2020 46 Figure 4-24. Scatterplot Comparing 24-hour Average Predicted Nitrate Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) Scatterplots of the daily average organic carbon concentrations in local standard time at the IMPROVE monitors are presented in Figures 4-24 and 4-25 with different axis scaling to facilitate analysis over the full range of concentrations. The CAMx 6.40 results are plotted on the x-axis and the CAMx 6.32 results are plotted on the y-axis. The data has a high degree of correlation with a line of best fit with a slope of 1.0146, an intercept of 0.3025 ppb and an R2 of 0.9837. The CAMx 6.40 results are slightly lower than CAMx 6.32 across the concentration range. CAMx Benchmarking Report #4 August 17, 2020 47 Figure 4-25. Scatterplot Comparing 24-hour Average Predicted Organic Carbon Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine) CAMx Benchmarking Report #4 August 17, 2020 48 Figure 4-26. Scatterplot Comparing 24-hour Average Predicted Organic Carbon Concentrations (µg/m3) for All Days at all IMPROVE Monitor Locations for CAMx 6.32 and CAMx 6.40 2028 Simulations Performed by VISTAS (Alpine); Modified Scale CAMx Benchmarking Report #4 August 17, 2020 49 5.0 CONCLUSIONS A comparison has been made between CAMx 6.32 and CAMx 6.40 simulations using EPA’s 2028el and SESARM’s 2028elv3 modeling platform as performed on the Alpine Geophysics computer system. The comparison was conducted for PM2.5 and included an examination both of annual emissions for elevated and low level sources and annual and daily future year design values at monitors in the modeling domain. The annual emissions comparisons showed areas of differences across the domain that are consistent with documented changes in the 2028 emissions inventories used by SESARM for this analysis. A comparison of the annual and daily PM2.5 design values at the monitors in the 12US2 modeling domain showed a systematic increase for the majority of FRM monitors for both values between the CAMx 6.32 and CAMx 6.40 platform. The greatest change in design values are seen in and around boundaries of VISTAS states and other outside regions (e.g., OTC and CENRAP) with smallest change noted centrally within the VISTAS state domain itself. A comparison of the daily average concentrations at the IMPROVE monitors showed fairly small differences for ozone between the two simulations with CAMx 6.40 estimating slightly larger values in the high concentration range. Organic Carbon was estimated as slightly lower across all concentration ranges using CAMx 6.40 compared to CAMx 6.32. For sulfate, the CAMx 6.40 results were generally higher than CAMx 6.32, especially across the medium and high concentration ranges. This is likely a result of the changes in the wet deposition algorithms, the oxidation of SO2 on primary crustal particles, and updates to the RADM aqueous chemistry algorithm and changes in SO2 emissions. For nitrate, the CAMx 6.40 results were consistently higher across all ranges compared to CAMx 6.32 except at very low concentrations. The PM2.5 results generally showed lower CAMx 6.40 concentrations compared to CAMx 6.32 at low concentration levels. The comparison of CAMx 6.32 and 6.40 showed differences in both annual and daily PM2.5 design values as well as in daily concentrations of various PM2.5 species. This is to be expected given the changes to the model from the inclusion of new science into CAMx 6.40 over that which was included in CAMx 6.32 and the changes made in the 2028 projection emission inventory across the modeling domain. Alpine Geophysics does not see any features in the CAMx Benchmarking Report #4 August 17, 2020 50 modeling that would preclude the use of the better science and updated emission inventories in CAMx 6.40 for use in the VISTAS air quality planning.