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HomeMy WebLinkAboutAQ_F_0200089_20230108_EI_Fac-EI-Rpt_SDS SAFETY DATA SHEET P A G E7 710 F 8 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name (As Labeled) VA-765 Chemical Names: Trichloroethylene Product Number: VA-765 UN Number: UN 1710 UN Dangerous/goods Class/Subsidiary Risk: Hazard Class 6.1 Packing Group III Manufacture's Name: Volunteer Adhesives Corp. Address: 570 Industrial Dr. Lafayette,TN. 37083 USA Emergency Phone: (800 - CHEMTREC � 4249300 � Business Phone: (615) 688-3030 (Product Information) Date of Preparation: 3/22/2022 Date of last revision: 8/29/2022 SECTION 2 HAZARD IDENTIFICATION OSHA Hazards Carcinogen,Target Organ Effect, Harmful by ingestion, Irritant. GHS Classification Skin Corrosion/Irritation (Category 2) Serious Eye Damage/Eyelrritation (Category 2A) Germ Cell Mutagenicity(Category 2) Carcinogenicity(Category 2) Specific target organ toxicity- single exposure (Category 3) Chronic Aquatic toxicity(Category 3) < t > <4> <e> Signal Word DANGER Hazard Statement's) H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness_ H350 May cause cancer. H411 Very toxic to aquatic life with long lasting effects. Precautionary Statement's) P261 Avoid breathing dust/fume/gas 1 mist/vapours 1 spray. P262+P264 Do not get in eyes,on skin or on clothing. Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/eye protection/face protection. P305+P-351+P-338 IF 1N EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P273+P391 Avoid release to the environment. Collect spillage. P301 + P 310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. PAGE 2 OF 8 HMIS Classification Health Hazard: 2 Chronic Health Hazard: Flammability: 0 Physical Hazard: 0 NFPA Rating Health Hazard: 2 Fire: 0 Reactivity Hazard: 0 Potential Health Effects Inhalation: May be harmful if inhaled. Causes respiratory tract irritation. Vapors may cause drowsiness and dizziness. Skin: May be harmful if absorbed through skin. Causes skin irritation. Eyes: Causes eye irritation. Ingestion: May be harmful if swallowed. Aspiration hazard if swallowed can enter lungs and cause damage. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS ITEM CHEMICAL NAME CAS NO. EC-No. WT% RANGE 1 Trichloroethylene 79-01-6 201-167-4 55-60 % Any remaining ingredients(to comprise t00%of the product)shoWd be considered a proprietary blend of non-hazardous substances,or materials below threshold reporting limits. SECTION 4- FIRST AID MEASURES Consult a physician. Show this safety data sheet to the doctor in attendance. EYE CONTACT: Flush with large quantities of water for at least 15 minutes or until irritation subsides. Contact a Physician. SKIN CONTACT: Wash with soap and water, Consult a physician. INHALATION: Move to fresh air. If not breathing ,give artificial respiration. If breathing is difficult, give oxygen. Contact a Physician immediately. INGESTION: Do not induce vomiting. If irritation or complications arise, contact a Physician or Regional Poison Control Center immediately. SECTION 5- FIRE FIGHTING MEASURES Suitable extinguishing media: Dry chemical foam, Carbon dioxide(CO2), Water spray, Alcohol-resistant foam. Water may be helpful in keeping adjacent containers cool; avoid spreading the liquid with water used for cooling. Water based sprinkler systems may help contain larger fires. PA01=3Ore Hazardous combustion products: Hazardous decomposition products form under fire conditions-Carbon oxides. Special Protective Equipment&firefighting procedures; Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical; Closed containers may rupture if exposed to fire or extreme heat. May produce toxic fumes it burning. SECTION 6 -ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protectective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personal to safe areas. Remove all sources of ignition. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and clean up: Contain spillage, and the collect with an electrically protected vacuum cleaner or wet-brushing and place in container for disposal according to local regulations. SECTION 7- HANDLING AND STORAGE Precautions for safe handling: Use only in area provided with appropriate exhaust ventilation. Do not breathe vapors or spray mist. Wear appropriate personal protective equipment. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from open flames, hot surfaces and sources of ignition. Storage information: Store away from caustics and oxidizers. Keep away form heat, sparks, and flames. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing- Use and store containers in a well ventilated area. SECTION 8 - EXPOSURE CONTROLSIPERSONAL PROTECTION Components CAS-No. value control BASIS Parameters Trichloroethylene 79-01-6 TWA 10 ppm USA,ACGIH Threshold Limit Values(TLV) Trichloroeth lene 79-01-6 STEL 25 ppm USA,ACGIH Threshold Limit Values(TLV) Trichloroeth lene 79-01-6 TWA 100ppm USA,Occupational Exposure Limits-Table Z-2 FTTrichloroeth lene 79-01-6 TWA 50 ppm USA,OSHA-Table Z-1 Limits of air Contaminants richloroethylene 79-0i 6 STEL 200 ppm USA,OSHA-Table Z-1 Limits of air Contaminants Engineering Controls: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposures below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, ect.) for vapors before entering. PAGE 4 OF S Respiratory Protection: When risk assessment shows air-purifying respirators are appropriate use full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges a backup to engineering controls. If the respirator is the sole meads of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand Protection: Handel with gloves. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Eye Protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU) Skin and Body Protection: Impervious clothing, Flame retardant protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liquid, Amber to Clear Odor: Characteristic odor. PH: Not Applicable Boiling Point: 188.0 Deg. F (86.7 Deg. C) Flash Point: Not Applicable Evaporation Rate: Faster than nBuAc Ignition Temperature: No data available Upper Explosion Limits: NIA Lower Explosion Limits: NIA Vapor Pressure: Not Available Bulk Density(lb/gal): 10.60 VOC Less Water & Exempts (g/l): 730 Specific Gravity(gll): 1.240 Water Solubility: Insoluble Partition Coefficients: NIA Ibs Per Gallon: 10.60 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under recommended storage conditions. Possibility of Hazardous Reactions: Vapors may form explosive mixture with air. Conditions to Avoid: Heat, Flames and sparks, Extremes of temperature and direct sunlight. Materials to Avoid: Bases, Oxidizing agents, Reducing agents, Acetone reacts violently with Phosphorous oxychloride. PAGE 5 OF 8 Hazardous Decomposition Products: Hazardous Decomposition Products formed under fire conditions,-Carbon Oxides Other decomposition products- no data available SECTION 11 -TOXICOLOGICAL PROPERTIES Likely Routes of Exposure: Inhalation, skin absorption, eye contact. Acute Exposure: Oral: severely irritating if not removed promptly:chemical burns if contact is prolonged. Skirt: slight-no systemic toxic effects by this route. Eye Contact: liquid severely irritating may damage eyes:vapor irritates some above 160ppm,others at 350ppm. Inhalation: headache,dizzyness,drowsiness,intoxication may occur at above 350ppm;irritating above #oDI)ppm; high concentrations can lead to unconsciousness&death,numbness&muscle weakness also reported. Oral LD50: Rat- 4920 & 5620 mg/kg Mouse-2400 mg/kg Rabbit- >7330 mg/kg Skin LD50: Rabbit- 29,280 mg/kg Inhalation LC50: Mouse- 7175, 7440, 8450, 40,920ppm Rat-26,170ppm Chronic Exposure: General: prolonged or repeated exposure may cause dermatitis;neurological damage (headache, sleeplessness,mood change),plus blurred or tunnel vision may be seen;loss of sensation in hands&feet may occur. Sensitising: not a sensitiser. Carcinogen 1 Tumorigen: probable carcinogen-IARC-Group 1,ACGIH-A2;the NTP rates trichloroethylene a carcinogen. Reproductive Effect: no known effect on humans or animals. Mutagen: mutagen in a few animal test,but not others;not known to be a mutagen or teratogen in humans. Synergistic With: alcohol-prior exposure to trichloroethylene followed by alcohol consumption causes body flush-called"degreasers flush". SECTION 12 - ECOLOGICAL INFORMATION Marine Toxicity: Toxicity to fish LC50 - 28 & 63 mg/litre/96hr (Jordanella floridae), LC50 - 4mg/litre/96hr (Pimephelas promelas) LC50 - 52 &99mg/litre/96hr (Cyprinodon variegatus) LC50 - 45 mg/litre (Lepomis macrochirus) LC50 - 58mg/litre/48hr (Daphnia cucullata) EC50 - 450 mg/litre (Scenedesmus subspicatus) E050 - 235 mg/litre (Bacillus subtilis) PAGE6OF8 Persistence and Degradability: No data available Bioaccumulative Potential: Indication of bioaccumulation. Mobility in Soil: Shown to have moderate mobility in soil and the water column. PB T and vPvB Assessment: No data available Very toxic to aquatic life. Do not empty into drains. Avoid release to the environment. SECTION 13 - DISPOSAL CONSIDERATIONS Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Discarded material should be incinerated at a permitted facility. Liquids cannot be disposed of in a landfill. Do not reuse empty containers. State and Local regulations/ restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded ( 40 CFR 261 ) : D001-Ignitable. SECTION 14 -TRANSPORTATION INFORMATION DOT (US): DOT PROPER SHIPPING NAME:UN1710, Trichloroethylene Mixture, Class 6.1, PG 111 Reportable Quantity(RQ): 100 Lbs. Marine Pollutant: NO Poison Inhalation Hazard: No IMGG: DOT PROPER SHIPPING NAME:UN1710, Trichloroethylene Mixture, Class 6.1, PG III Reportable Quantity(RQ): 100 Lbs. Marine Pollutant: NO Poison Inhalation Hazard: No IATA: DOT PROPER SHIPPING NAME:UN1710,Trichloroethylene Mixture, Class 6.1, PG III Reportable Quantity(RQ): 100 Lbs. Marine Pollutant: NO Poison Inhalation Hazard: No PAGE 7OF8 SECTION 15- REGULATORY INFORMATION OSHA Hazards Carcinogen, Target Organ Effect, Harmful by ingestion, Irritant. SARA 302 Components: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III Section 302. SARA 313 Components: SARA SECTION 313: The following components are subject to reporting levels established by SARA Title III Section 313. Trichloroethylene CAS #79-01-6 SARA 311/312 Hazard : Acute Health Hazard, Chronic Health hazard. CERCLA REPORTABLE QUANTITY: Components CAS # Components RQ Calculated product (Ibs) RQ (Ibs) Trichloroethylene 79-01-6 100 5.10 lbs per gallon Clean Air Act The following chemical(s) are listed as a hazardous air pollutants (HAPS), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). 79-01-6 Trichloroethylene 59% This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112( r) for Accidental Release Prevention ( 40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or final VOC's (40 CFR 60.489): 79-01-6 Dichloromethane 72% CLEAN WATER ACT: The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116AA: 79-01-6 Oxirane, 2-methyl- The following Hazardous Srlbstance3 are listed under the U.S. GleanWater Act, Section 311, Table 117.3: 79-01-6 Oxirane, 2-methyl- This product does not contain any toxic pollutants listed under the U.S. CleanWater Act Section 307. Massachusetts Right to Know Components: CAS # Revision Date Trichloroethylene 79-01-6 8/29/2022 PAGE 8 OF 8 Pennsylvania Right to Know Components: CAS# Revision Date Trichloroethylene 79-01-6 8/29/2022 New Jersey Right to Know Components: CAS # Revision Date Trichloroethylene 79-01-6 8/29/2022 California Prop. 65 Components: WARNING:T his product contains chemicals known to the state of California to cause cancer and birth defects or other reproductive harm. Trichloroethylene CAS#79-01-6 For more information, go to"www.P65Warnings.ca.gov." The components of this product are reported in the following inventories: Country(s) or Inventory name On inventory region (yes/no) Australia Australian Inventory of Chemical Substances(AICS) Yes Canada Domestic Substances List(DSL) Yes Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China(IECSC) Yes Europe European Inventory of Existing Commerical Chemical Yes Substances(EINECS) Japan Inventory of Existing and New Chemical Substances(ENCS) Yes Inventory of Chemical Substances(ISHL) Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes PNIlippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) Taiwan Taiwan Chemical Substance Inventory(TCSI) Yes United States& Toxic Substances Control Act(TSCA)Inventory Yes Puerto Rico SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 0 REASON FOR REVISION: To Correct MSDS Number/Change OSHA Hazcom Information HAP less water, less exempt solvent: 6.26# Per Gal. VOC less water, less exempt solvent: 6.26 # Per Gal. Product Shelf Life: 12 Months from the date of Mfg. in an unopened sealed container. This data is offered in good faith as typical value and not as a product specification. No warranty either express or implied, is hereby made.The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End of SDS >