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HomeMy WebLinkAboutAQ_F_1900104_20160608_EI_Cmb-EI-File 2015 Emissions Inventory Review / Data Tracking Form Facility Name: 3M Pittsboro - Industrial Mineral Products Facility ID: 1900104 Facility Assigned to: Data Entry: Chatham County Classification: David Miller Confidential Copy Submitted? Title V ❑ YES BNO Initial Review/Data Entry Enter date received into ED. Date Received: CJ� Assigned to appropriate individual. Date Assigned: G _ -20 t 6 Date Due: -] -Z U oc ❑ Paver copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and —/appears generally complete;OR 19 Electronic copy submitted: All supporting documentation and,certification form(with time/date stamp)signed by responsible official has been received. Comments: All changes in emissions where less than+/- 10%or below the deminus. Inventory Review P�All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic). Contact,address,phone number changes entered into I-Beam/Facilities if necessary. All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted, insignificant,and unpermitted)or note that the emission source was not operated or not required to report. Check if SCC codes for each OS are accurate and update if needed. Evaluate"U"sources for significance and address according to policy. Calculations/forms appear to add up correctly. ❑ All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds,large emissions increase/decrease,installation without a permit). ❑ All volatile HAPs/TAPs were included in the VOC total. ❑ Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for the reporting facility(e.g.stack testing,AP-42,etc.). Review facility comments and address any issues. Update ED(Data Entry Main)if additional information is required(corrections due date and date received). Check all ED QA/QC reports. Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained. Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments". Print and attach the facility total report. Date Info Requested: Date Info Received: Total Days on Hold: Date Review Complete: 2 Zo 16 Signature: 7 �� Date Submitted to EI Coordinator: -Z S- Date Approved: 1 I I Initials: W 14, Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 1900104 Facility Name: 3M Pittsboro - Industrial Mineral Products Permit#(s): 09006T06 M Green House Gases Pollutants (GHG) Actual Emissions Tons/Yr Pollutant CAS CY 2015 CY 2014 Demini- Change from ED from Fees mus Carbon Dioxide (CO2) 124389 22,722.57 22,656.29 5,000.0 0.3% Nitrous Oxide (N20) 10024972 0.416200 0.415400 1.0 0.2% Methane (CH4) 74-82-8 0.435000 0.438000 10.0 -0.7% CO2 equivalent(sum of individual GHG pollutant emission 20,739.25 metric tons times their 1995 IPCC Global Warming Potential(GWP), converted to metric tons) Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change CO co 15.92 15.90 0.5 0.1% NOx NOx 18.98 19.07 0.5 -0.5% PM(TSP) T'SP 73.77 75.37 0.5 -2.1% PM10 PM10 56.73 57.96 0.5 -2.1% PM2.5 PM2,5 55.05 56.33 0.5 -2.3% S02 SO2 0.110000 0.120000 0.5 -8.3% VOC VOC 8.57 8.52 0.5 0.6% Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Arsenic& Compounds(total mass of elemental AS, arsine and 0*017360 0*077340 0.01 10.0% all inorganic compounds) Arsenic Unlisted Compounds- Specify Compound ASC-other 0.077360 0.077340 0.01 0.0% (Component of ASC) Beryllium & compounds(Total mass) 0.004670 0.004860 1.0 N/A Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.004610 0.004790 1.0 N/A Beryllium Unlisted Compounds- Specify Compounc BEC-Other 0.000060 0.000070 1.0 N/A (Component of BEC) 07/25/2016 Page 1 of 3 Facility Total CY 2015 Emission Summary Recorded in ED Facility ID #: 1900104 a Facility Name: 3M Pittsboro - Industrial Mineral Products Permit#(s): 09006T06 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Cadmium & compounds(total mass includes elemental metal) 0.421280 0.435540 0.1 I -3.3% Cadmium Metal, elemental, unreacted(Component( 7440-43-9 0.416610 0.415580 0.1 0.2% CDC) Cadmium Unlisted Compounds- Specify Compounc CDC-Other 0.004670 0.019960 0.1 -76.6% (Component of CDC) Chromium-All/Total(includes Chromium (VI) categories, Z90 3.10 0.1 I -6.5% metal and others) r Chromic acid(VI).(Component of So1CR6 &CRC) 7738-94-5 0.530210 0.528860 0.01 0.3% Chromium Unlisted Compounds- Specify Compoun CRC-Other 2.37 2.57 0.1 -7.8% (Component of CRC) Chromium (VI)Soluble Chromate Compounds(Component of 0.530210 0.528860 1 0.01 0.3% CRC) Chromic acid(VI)(Component of So1CR6 &CRC) 7738-94-5 0.530210 0.528860 0.01 0.3% Cobalt& compounds 0.032340 0.032260 1.0 10.2% Cobalt Unlisted Compounds- Specify_Compound COC-Other 0.032340 0.032260 1.0 0.2% (Component of COC) Lead& compounds 0.192080 0.194610 1.0 -1.3% Lead Unlisted Compounds- Specify Compound PBC-Other 0.192080 0.194610 10.0 -1.3% (Component of PBC) Manganese& compounds 0,510550 0.523090 10.0 I -2.4% Manganese Unlisted Compounds- Specify Compoui N4NC-Other 0.510550 0.523090 10.0 -2.4% (Component of MNC) Mercury & Compounds-all total mass includes Hg Vapor 0.098640 0.098610 0.001 0.0% Mercury, aryl and inorganic compounds(Componen M_RCARYL 0.000110 0.000170 0.001 N/A HGC) Mercury,vapor(Component of HGC) 7439-97-6 0.098530 0.098440 0.001 0.l% Nickel& Compounds,sum total mass includes elemental 0.796560 0.794490 1.0 10.3% Nickel metal (Component of NIC) 7440-02-0 0.796560 0.794490 1.0 0.3% 07/25/2016 Page 2 of 3 Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 1900104 Facility Name: 3M Pittsboro - Industrial Mineral Products Permit#(s): 09006T06 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Polycyclic Organic Matter(Specific Compounds from OAQPS 0.233060 0.237550 1.0 I -1.9% for Tip Naphthalene (Component of 83329/POMTV) 91-20-3 0.233060 0.237550 1.0 -1.9% Benzene 71-43-2 0.817910 0.794780 1.0 2.9% Dichlorobenzene(p), 1,4- 106-46-7 0.454400 0.453080 1.0 0.3% Formaldehyde 50-00-0 29.97 29.96 10.0 0.0% Hexane, n- 110-54-3 681.61 679.63 100.0 0.3% Methanol (methyl alcohol) 67-56-1 7,650.00 7,583.00 1,000.0 0.9% Polycyclic Organic Matter(Inc PAH, dioxins, etc.N pom 0.033400 0.033300 1.0 0.3% &AP 42 historic) Selenium Compounds SEC 0.600370 0.001280 10.0 N/A Toluene 108-88-3 855.30 942.32 100.0 -9.2% Xylene (mixed isomers) 1330-20-7 0.006940 0.024300 100.0 1 -71.4% Largest Individual HAP Methanol(methyl alcohol) 7,650.00 lbs Total HAP Emissions 9,223.45 lbs DAQ's Comments Regarding Inventory All changes in emissions where less than+/- 10%or below the deminus. 07/25/2016 Page 3 of 3 3M Industrial Minerals Product Division 3M 4191 Highway 87 South �, /`+ts��►r1}7c" . Moncure, NC. 27559 'i 1 JUN 8 2016 June 3, 2016 Air Emission Inventory NC DENR Raleigh Regional Office Raleigh Regional Office 3800 Barrett Drive Raleigh, NC 27609 Subject: 2015 Air Emissions Inventory Forms Via Certified Mail: 7014 1820 0002 2821 7193 The 2015 Emissions Inventory was submitted electronically today, 6/3/2016, and this is the supporting documentation. This packet includes the following- - Certification form signed by the responsible official - Signed Form AA - Supporting documents for emission calculations for the year of 2015 If you have any questions about the report or back-up data I can be reached at 919-642-4009. Best Regards, Stanley . Carter Environmental Engineer cc,. James A. Zielgmeier, EHS and Manuf. Services Mngr. Blake Arnett-. 3M Pittsboro Plant Manager Wayne H. Neuman- 3M Corp. P (919)642-4000 F (919)642-4017 COPY of RECORD Date Submitted: 6/3/2016 13:08:18 tnventory Certification Form(Title V) Facility Name: 3M Industrial Mineral Products Facility ID : 1900104 4191 Highway 87 South Permit : 09006 Moncure,NC 27559 County : C DAQ Regio 1",f`,"�+n►�-�,; North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 UN — $ 2016 ' �K These forms must be completed and returned even if the facility did not operate or emitS�eM.Mamo The legally defined "Responsible Official" of record for your facility is Blake Arnett This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation: a president, secretary,treasurer,or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars); or ii. the delegation of authority to such representatives is approved in advance by the permitting authority; 2.For partnership or sole propietorship;a general partner or the proprietor,respectively; 3. for a muncipality,state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). CERTIFICATION STATEMENT: i re fbia1 certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: Bla e tt �n -Signature: This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: B1Arnett@mmm.com Information on this Form cannot be held confidential COPY of RECORD Date Submitted: 6/3/2016 13:08:18 1 FORM AA (continued, page 2 of 2) ` ADMINISTRATIVE APPLICATION REVISED 5/8/13 Application for Air Permit to Construct/Operate AA SECTION AA1-APPLICATION FOR NON-TITLE V PERMIT RENEWAL 3M Company-Pittsoro (Company Name) hereby formally requests renewal of Air Permit No. 09006T06 There have been no modifications to the originally permitted facility or the operations therein that would require an air permit since the last permit was issued. Is your facility subject to 40 CFR Part 68"Prevention of Accidental Releases"-Section 112(r)of the Clean Air Act? ❑Yes ®No If yes,have you already submitted a Risk Manaqement Plan(RMP)to EPA? [:]Yes ❑No Date Submitted!._ Did you attach a current emissions inventory? ®Yes ❑No If no,was it submitted via AERO or by mail(date mailed). SECTION AA2-APPLICATION FOR TITLE V PERMIT RENEWAL In accordance with the provisions of Title 15A 2Q.0513 the responsible official of _ - j (Company Name) hereby formally requests renewal of Air Permit No. (Air Permit No.)and further certifies that: (1)the current air quality permit identifies and describes all emissions units at the above subject facility,except where such units are exempted under the North Carolina Title V regulations at 15A NCAC 2Q.0500, (2)the current air quality permit cites all applicable requirements and provides the method or methods for determining compliance with the applicable requirements, (3)the facility is currently in compliance,and shall continue to comply,with all applicable requirements.(Note:As provided under 15A NCAC 2Q.0512 compliance with the conditions of the permit shall be deemed compliance with the applicable requirements specifically identified in the permit.), (4)for applicable requirements that become effective during the term of the renewed permit that the facility shall comply on a timely basis, (5)the facility shall fulfill applicable enhanced monitoring requirements and submit a compliance certification as required by 40 CFR Part 64. The responsible official(signature on page 1)certifies under the penalty of law that all information and statements provided above,based on information and belief formed after reasonable inquiry,are true,accurate,and complete. SECTION AA3-APPLICATION FOR NAME CHANGE New Facility Name: Former Facility Name: I An official facility name change is requested as described above for the air quality permit mentioned on page 1 of this form.Complete the other sections if there has been modifications to the originally permitted facility that would require an air quality permit since the last permit was issued and if there has been an ownership change associated with this name change. SECTION AA4-APPLICATION FOR AN OWNERSHIP CHANGE By this application we hereby request transfer of Air Quality Permit No. j from the former owner to the new owner as describe below.The transfer of permit responsibility,coveraqe and liability shall be effective (immediately or insert date).The leqal ownership of the facility described on page 1 of this form has been or will be transferred on I (date).There have been no modifications to the originally permitted facility that would require an air quality permit since the last permit was issued. Signature of New(Buyer)Responsible Official/Authorized Contact(as typed on page 1): X Signature(Blue Ink): Date:i—- --New Facility Name: L ----- ---�_Former Facility Facility Name: Signature of Former(Seller)Responsible Official/Authorized Contact: Name(typed or print): Title: X Signature(Blue Ink): Date: Former Legal Corporate/Owner Name:In lieu of the seller's signature on this form,a letter may be submitted with the seller's signature indicating the ownership change. SECTION AA5-APPLICATION FOR AN ADMINISTRATIVE AMENDMENT Describe the requested administrative amendment here(attach additional documents as necessary): Attach Additional Sheets As Necessary Page 2 of 2 ii to�*6Q u A7iA— FORM AA JUN - 6 2016 ADMINISTRATIVE APPLICATION (General Information) NCDENR REVISED 5/8/13 NCDENR/Division of Air Quality-Application for Air Permit to Construct/OpNill DENR RaWo R GENERAL INFORMATION Legal Corporate/Owner Name:13M Company Site Name: 3M Company-Pittsboro Site Address(911 Address)Line 1:14191 Hwy 87 S. --� Site Address Line 2: City: Moncure State: N.C. Zip Code:127559 County: Chatham CONTACT INFORMATION Permit/Technical Contact: Facility/Inspection Contact: Name/Title: Tricia Shearen,Senior Environmental Engineer Name/Title: Blake Arnett.Plant Manager Mailing Address Line 1:13M Company,3M Center Mailing Address Line 1: 4191 Hwy 87 S. Mailing Address Line 2:1 Building 224-5F-29 Mailing Address Line 2: City: St.Paul State: IMN Zip Code: 155144 City: Imoncure I State: NC Zip Code: 127559 Ph.No.(area code) (651)737-2110 Fax No.(area code) Ph.No.(area code) (919)642-4011 Fax No.(area code) (919)642-4017 mail Address: I'tshearen@mmm.com Email Address: blarnett@mmm.com Responsible Official/Authorized Contact: Invoice Contact: Name/Title: I Blake Arnett,Plant Manager Name/Title: 3M EHS Fee Processing Mailing Address Line 1: 14191 Hwy 87 S. Mailing Address Line 1:13M Company,3M Center Mailing Address Line 2: 1 Mailing Address Line 2:1 Building 224-5F-29 City: Moncure State: I NC Zip Code: 127559 City: ISt.Paul State: MN Zip Code: 155144 Ph.No.(area code) Fax No.(area code) I Ph.No.(area code) Fax No.(area code) Email Address: Email Address: i APPLICATION IS BEING MADE FOR Renewal(non-Title V) ®Renewal Title V Name Change ❑Ownership Change Administrative Amendment FACILITY CURRENT CLASSIFICATION (Check Only One) Small ❑Synthetic Minor ®Title V FACILITY(Plant Site) INFORMATION Describe nature of(plant site)operation(s): Manufacture of roofing granules Primary SIC/NAICS Code: 13295 Current/Previous Air Permit No.109006TO6 Expiration Date: March 31,2021 Facility Coordinates: Latitude: 35040-00 1 Longitude: 79-10-00 Facility ID No. 11900104 Does this application contain confidential data? YES NO "'If yes,please contact the DAQ Regional Office prior to submitting tis application.*** (See Instructions) PERSON OR FIRM THAT PREPARED APPLICATION Person Name: Stanley B.Carter --J Firm Name: Mailing Address Line 1:4191 Hwy 87 S. Mailing Address Line 2: City: Moncure I State:INC Zip Code: County: Ph.No.(area code) (919)642-4009 7 Fax No.(area code) (919)64i40177 Email Address: SIGNATURE OF RESPONSIBLE OFFICIAL/AUTHORIZED CONTACT Name(typed): -- ---- ------------ ---- Blake Amett Title: (Plant Manager X Signature u Date: 1june 3,2016 Attach Additional Sheets As Necessary Page 1 of 2 05 C� 3M, Incorporated - Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 1 DAQ Group ID G-151 Description Crusher Baghouse#1 Sources Hours of Operation= 4470 hrs Stack Test Annual Emissions Emission Rater Rate PM PM PM-10 (lb/hr) (lb/yr) (tpy) (lb/yr) (tpy) 0.123 549.81 0.27 549.81 0.27 Sample Calculation 0.123 lb/hr* 4470 =549.81 lb/yr 1 Emission rate data from stack tests performed on the emission point for this group on August 5-8, 2002 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 6 of 26 Sheet:EIG 1 (G-151) Crusher#1 BH t 0 -5 O 3M,Incorporated - Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 2 DAQ Group ID G-152 Description Screen Baghouse#1 Sources Hours of Operation= 4470 hrs Stack Test Annual Emissions Emission Rate' Rate PM P I PM-10 (lb/hr) (lb/yr) (tpy) I ,(lb/yr) (tpy) 0.37 11,653.901 0.83 K 1,653.90 1 0.83 Sample Calculation(PM) 0.37 lb/hr*4470 = 1653.9 lb/yr ' Emission rate data from stack tests performed on the emission point for this group on August 5-8,2002 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 7 of 26 Sheet:EIG 2(G-152)Screen#1 BH 3M,Incorporated-Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 3 DAQ Group ID ES1415 Description Dryer with Cyclone and Baghouse control system C&S Dryer(EIG 3) Natural Gas Usage 136,692.70 decatherms/yr 136,692.70 MMBtu/yr 132.07 MMscf/yr Hours of Operation 4,470.00 hrs Pollutant EF 1 Emissions Criteria (lb/ton) lb/hr) (lb/ r) (tpy) PM 0.0268 3.12 13,926.54 6.96 PM-10 0.0146 1.70 7,586.85 3.79 PM2.5 0.0083 0.96 4,313.07 2.16 r/ 1-Emission Factors from AP-42 Table 11.19-2-4-Flash dryer with fabric filter control and actual production rate Using Combustion Emission Factors Pollutant Emission Emissions Factor Units (lb/hr) (lb/yr) (t y) Q S r 3 PM 7.6 Ib/MMscf 0.22 1,003.73 0.50 PM-10 7.6 Ib/MMscf 0.22 1,003.73 0.50 �a�zr�lis%lcxc/ PM 2.5 7.6 lb/MMscf 0.22 1,003.73 0.50 TOTAL PM , Pollutant Emissions Ib/hr) (lb/yr) (t y) PM 3.34 14,930.27 7.47 PM-10 1.92 8,590.58 4.30 PM 2.5 L 19 5,316.80 2.66 Using Combustion Emission Factors Pollutant Emission Emissions Factor Units lb/hr) (lb/yr) (t S02 0.6 lb/MMscf 0.02 79.24 0.040 NOx 100 lb/MMscf 2.95 13,207.02 6.60 CO 84 lb/MMscf 2.48 11,093.90 5.55 VOC 5.5 lb/MMscf 0.16 726.39 0.36 / GHG N20 1.06E-06 I ton/MMBtu 1 0.06501 290.551 0.1453 CO2 5.80E-02 I ton/MMBtu 1 3,545.511 15,848,428.991 7,924.21 CH4 1.11E-06 I ton/MMBtu 1 0.0681 303.761 0.152 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 9 of 26 Sheet:EIG 3(ES 1415)C&S Dryer 0 Os d 3 Heavy Metals Emissions from Total Annual Natural Gas Combustion CAS No. Species Emission Factor Annual Pollutant Emissions b/million sc b/r tons/ear 7440-38-2 arsenic 0.0002 0.0264 1.32E-05 7440-38-3 barium 0.0044 0.5811 2.91E-04 7440-41-7 beryllium 1.20E-05 0.0016 7.92E-07 7440-43-9 cadmium 1.10E-03 0.1453 7.26E-05 7440-47-3 chromium 1.40E-03 0.1849 9.24E-05 7440-48-4 cobalt 8.40E-05 0.0111 5.55E-06 7440-50-8 copper 8.50E-04 0.1123 5.61E-05 7439-96-5 manganese 3.80E-04 0.0502 2.51E-05 7439-97-6 mercury 2.60E-04 0.0343 1.72E-05 7439-98-7 molybdenum 1.10E-03 0.1453 7.26E-05 7440-02-0 nickel 2.10E-03 0.2773 1.39E-04 7782-49-2 selenium 2.40E-05 0.0032 1.58E-06 7440-62-2 vanadium 2.30E-03 0.3038 1.52E-04 7440-66-6 zinc 2.90E-02 3.8300 1.92E-03 Total Annual Metals Emissions. 5.7068 0.0029 Additional Regulated Coml Pound Emissions from Total Annual Natural Gas Combustion(Onl CAS No. Species Emission Factor jAnnual Pollutant Emissions (lb/million sc b/ (tons/ye,,) 71-43-2 benzene 0.0021 0.2773 1.39E-04 25321-22-6 dichlorobenzene 1.20E-03 0.1585 7.92E-05 50-00-0 formaldehyde 7.50E-02 9.9053 4.95E-03 110-54-3 hexane 1.8 237.7264 1.19E-01 lead 0.0005 0.0660 3.30E-05 91-20-3 napthalene 6.10E-04 0.0806 4.03E-05 various POM 8.82E-05 0.0116 5.82E-06 108-88-3 toluene 3.40E-03 0.4490 2.25E-04 7-1 Total Annual: 249 0.12 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 9 of 26 Sheet:EIG 3(ES 1415)C&S Dryer 3M,Incorporated-Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 4 DAQ Group ID G-153 Description Screen Baghouse#2 Sources Hours of Operation= 4,470.0 hrs Stack Test Annual Emissions Emission Ratel Rate PM PM PM-10 (lb/hr) (lb/yr) I (tpy) (lb/yr) I (tpy) 0.3 1,341.00 0.67 /1,341.001 0.67 Sample Calculation(PM) 0.3 lb/hr*4470 =1341 lb/yr ' Emission rate data from stack tests performed on the emission point for this group on August 5-8,2002 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 10 of 26 Sheet:EIG 4(G-153)Screen#2 BH D S 3M,Incorporated -Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 5 DAQ Group ID G-154 Description Crusher Baghouse#2 Sources Hours of Operation= 4470 hrs Stack Test Annual Emissions Emission Rate' Rate PM PM PM-10 (lb/hr) (lb/yr) (tpy) (lb/yr) (tpy) 0.28 1,251.60 0.63 1/ 1,251.60 0.63 Sample Calculation(PM) 0.28 lb/hr*4470 = 1251.6 lb/yr ' Emission rate data from stack tests performed on the emission point for this group on August 5-8,2002 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 11 of 26 Sheet:EIG 5(G-154)Crusher#2 BH 0�S 2, 3M, Incorporated - Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 6 DAQ Group ID G-155 Description 11 Grade Silo Baghouse Sources Hours of Operation= 4470 hrs Stack Test Annual Emissions Emission Ratel Rate PM PM PM-10 (lb/hr) (lb/yr) I (tpy) (lb/yr) (tpy) 0.46 1 2,056.201 1.03 2,056.20 1.03 Sample Calculation(PM) 0.46 lb/hr* 4470 =2056.2 lb/yr 1 Emission rate data from stack tests performed on the emission point for this group on August 5-8, 2002 3M Emission Calculations File:3M AEI Calcs - CY 2015.xlsx Moncure,NC Page 12 of 26 Sheet:EIG 6 (G-155) 11 Grade Silo BH C) .S Z 3M,Incorporated-Pittsboro Plant Emission Calculations Crushing and Screening Plant 3M Group ID EIG 7 DAQ Group ID G-156 Description Waste Handling Baghouse Sources Hours of Operation= 4470 hrs Stack Test Annual Emissions Emission Ratel Rate PM PMI PM-10 (Ib/hr) (Ib/yr) (tpy) (lb/yr) (tpy) 0.104 464.88 0.23 464.88 0.23 Sample Calculation(PM) 0.104 lb/hr*4470 =464.88 lb/yr ' Emission rate data from stack tests performed on the emission point for this group on August 5-8,2002 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 13 of 26 Sheet:EIG 7(G-156)Waste Hnding BH 3M, Incorporated -Pittsboro Plant Emission Calculations Coloring Plant 3M Group ID EIG 8 DAQ Group ID G-157 Description Raw Granule Baghouse Sources Hours of Operation= 4458.9 hrs . Hourly Emissions Annual Emissions Ratel Rate PM PM-10 PM PM-10 (lb/hr) (lb/hr) (lb/yr) (tpy) (lb/yr) (tpy) 1.97 1.97 8,790.40 4.40 8,790.40 4.40 Sample Calculation 0.01 * 1/7000 lb/gr*23000 * 60 min/hr= 1.971b/hr 1.97 lb/hr*4458.9 =8790.41b/yr 1 Hourly emission rates calculated using grain loading and baghouse flowrate 2 Annual emission rates calculated based upon the coloring plant operating hours Metals Emissions from Additives (Refer to page 22,23 for additonal details) CAS No. Species Annual Pollutant Emissions (lb/yr) (tons/year) -ri-//z 5 /Z 7440-38-2 arsenic 1.82E-04 / 9.10E-08 6 9 F 7440-41-7 beryllium 6.82E-06 / 3.41 E-09 _ 7440-43-9 cadmium 5.55E-04 / 2.77E-07 I 1 Fz 7440-47-3 chromium 2.81E-01 / 1.41E-04 Lo R A Cd 7440-48-4 cobalt 6.26E-05 r 3.13E-08 GA S 7439-92-1 lead 3.00E-04 / 1.50E-07 7439-96-5 manganese 4.35E-02 / 2.18E-05 7439-97-6 mercury 1.33E-05 r 6.66E-09 7440-02-0 nickel 1.53E-04 a 7.64E-08 Total Annual Metals Emissions: 3.26E-01 1.63E-04 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 14 of 26 Sheet:EIG 8 (G-157)Raw Granule 1311 3M,Incorporated-Pittsboro Plant Emission Calculations Coloring Plant 3M Group ID EIG 9 DAQ Group ED G-158 Description Coloring Plant Combustion Units Coloring Plant Combustion Units(EIG-9) Natural Gas Usage 252,540.00 decatherms/yr 252,540.00 M Mtu/yr 244.00 MMscf/yr Hours of Operation 4,458.90 hrs Combustion Emissions Pollutant Emission Emissions I S Factor Units (lb/hr) Ib/yr) (tpy) PM 7.6 lb/MMscf 0.42 1,854.40 0.93 d S Z 4 PM-10 7.6 Ib/NlMscf 0.42 1,854.40 / 0.93 C o N1/,jUs PM 2.5 7.6 IbAQ&cf 0.42 1,854.401 0.93 Pollutant Emission Total Emissions Criteria Factor Units (lb/hr) (lb/yr) (tpy) S02 0.6 Ib/MvUcf 0.03 146.40 / 0.07 NOx 100 lb/NMcf 5.47 24,400.00 12.20 CO 84 lb/NIMscf 4.60 20,496.00 10.25 VOC 5.5 lb/NMef 0.30 1,342.00 / 0.67 GHG N20 I 1.06E-061 tonA vIBtu 0.1201 536.801 0.268 CO2 I 5.80E-02 ton/M Mtu 6,566.641 29,280,000.00 / 14,640.00 CH4 1 1.11E-06 ton/MNMtu 0.131 561.201 0.28 Processing PM Emissions-Dryers Pollutant Stack Test Total Criteria Emission Emissions /Z A `- a Rate 1 Units (lb/hr) (lb/yr) ((tpy) ! 0 Dryer#1 0.15 lb/hr 0.15 668.84 0.33 �1 Dryer#2 0.115 lb/hr 0.115 512.77 0.26 S 3 S Total(Assumes Includes Combustion)= 0.27 1,181.61 0.59 1-Dryer#1 and#2 tested at the 3M NC facility on August 5-8,2002. ' Z O Processing PM Emissions-Kilns Hourly Emissions Annual Emissions Ratel Rate' PM PM-10 PM PM-10 (lb/hr) (lb/hr) (ib/yr) (tpy) (lb/yr) (tpy) 8.57 8.57 38,219.14 19.11 38,219.14 19.11 Sample Calculation c� v j D A/rT 0.01 *1/7000 lb/gr* 100000 *60 min/hr=8.57 lb/lir ' 8.57 lb/hr*4458.9 hrs=38219.141b/yr 1 Hourly emission rates calculated using grain loading and baghouse flowrate 'Annual emission rates calculated based upon the coloring plant operating hours 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 16 of 26 Sheet:EIG 9(G-158)Color Plt Cmbstn Total PM Sources PM PM-10 PM2.5 (lb/yr) (Ib/yr) (lb/yr) Combustion 1,854 1,854 1,854 D ers 1,182 1,182 1,182 I q G S S Kilns 38,219 38,219 38,219 TOTAL(lb/yr) 41,255 41,255 41,255 TOTAL(tpy) 20.63 20.63 20.63 Heavy Metals Emissions from Total Annual Natural Gas Combustion CAS No. Species Emission Factor Annual Pollutant Emissions S b/million scfi (Ib/yr) (tons ear 7440-38-2 arsenic 2.00E-04 0.0488 2.44E-05 7440-38-3 barium 4.40E-03 1.0736 5.37E-04 7440-41-7 beryllium 1.20E-05 0.0029 1.46E-06 7440-43-9 cadmium 1.10E-03 0.2684 1.34E-04 7440-47-3 chromium 1.40E-03 0.3416 1.71E-04 744048-4 cobalt 8.40E-05 0.0205 1.02E-05 7440-50-8 copper 8.50E-04 0.2074 1.04E-04 7439-96-5 manganese 3.80E-04 0.0927 4.64E-05 7439-97-6 mercury 2.60E-04 0.0634 3.17E-05 7439-98-7 molybdenum 1.10E-03 0.2684 1.34E-04 7440-02-0 nickel 2.10E-03 0.5124 2.56E-04 7782-49-2 selenium 2.40E-05 0.0059 2.93E-06 7440-62-2 vanadium 2.30E-03 0.5612 2.81E-04 7440-66-6 zinc 2.90E-02 7.0760 3.54E-03 Total Annual Metals Emissions: 10.5432 0.0053 ?additional Regulated Compound Emissions from Total Annual Natural Gas Combustion(Only CAS No. Species Emission Factor Annual Pollutant Emissions (Ib/million sc) (lb/yr) tons/year) 71-43-2 benzene 2.10E-03 0.5124 2.56E-04 25321-22-6 dichlorobenze 1.20E-03 0.2928 1.46E-04 50-00-0 formaldehyde 7.50E-02 18.3000 9.15E-03 110-54-3 hexane 1.8 439.2000 2.20E-01 lead 5.00E-04 0.1220 6.10E-05 91-20-3 na thalene 6.10E-04 0.1488 7.44E-05 various POM 8.82E-05 0.0215 1.08E-05 108-88-3 toluene 3.40E-03 0.8296 4.15E-04 Total Annual: 459 0.23 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 16 of 26 Sheet:EIG 9(G-158)Color Ph Cmbstn ' C7.S Ye � 05 3l 611/ !L4- 1�19121T}v/ZS 3M,Incorporated-Pittsboro Plant v 5? l v w Emission Calculations 6 S o M Coloring Plant 3M Group ID EIG 10 DAQ Group ID G-159 Description Mixer Baghouses Hours of Operation= 4458.9 hrs Mixer#1 BH Flowrate= 13,000 acfm Mixer#2 BH Flowrate= 13,000 acfm Total Baghouse Flowrate= 26,000 aofrn Grain Loading= 0.01 gr/ft3 Hourly Emissions Annual Emissions o Sa Rate' Rate' 1 PM PM-10 PM3 PM-103 (lb/hr) (lb/hr) (Ib/yr) (tpy) (lb/yr) (tpy) 2.23 2.23 9,936.98 4.97 9,936.98 4.97 Sample Calculation 0.01 gr/ft3*1/7000 lb/gr*26000 acfm*60 min/hr=2.23 lb/hr 2.23 lb/hr*4458.9 hrs=9936.98 lb/yr Hourly emission rates calculated using grain loading and baghouse flowrate 2 Annual emission rates calculated based upon the coloring plant operating hours 3 Reported in OS31 in AERO submission. There are small burners on each mixer and the flue gas/exhaust goes through the Mixer Baghouses Natural Gas Usage 2,731.71 decatherms/yr 2,731.71 MMBtu/yr 2.60 MMscf/yr Hours of Operation 4,458.90 hrs Combustion Emissions Total �, s 3 Z Emission Emissions Pollutant Factor Units b/hr lb/ r t Criteria PM 7.6 lb/MMscf 0.00 19.76 0.010 PM-10 7.6 lb/MMscf 0.00 19.76 0.010 PM2.5 7.6 lb/NWscf 0.00 19.76 0.010 TOTAL PM Emissions Total O 3 1 Pollutant Emissions Criteria (lb/hr) b/ r) (tpy) PM 2.23 9,956.74 4.98 I v rz PM-10 2.23 9,956.74 4.98 PM2.5 2.23 9,956.74 4.98 �CT� Other Combustion Emissions Pollutant Emission Emissions Factor Units (lb/hr) (lb/yr) (tpy) 902 0.6 lb/MMscf 0.00 1.56 0.0008 NOx 100 lb/MMscf 0.06 260.00 0.13 CO 84 lb/MMscf 0.051, 218.40 0.11 VOC 5.5 lb/MMscf 0.00 14.30 0.007 GHG N20 1.06E-061 ton/MMBtu 1 0.001 5.807 0.002903 CO2 5.80E-02 ton/UMBtu 1 71.031 316,720.00 158.36 CH4 1.11E-06 ton/MMBtu 1 0.00141 6.07 0.00304 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 18 of 26 Sheet:EIG 10(G-159)Mixer BHs Heavy Metals Emissions from Total Annual Natural Gas Combustion S 3 Z CAS No. Species Emission Factor nnual Pollutant Emissions b/millions b/ tons/ear 7440-38-2 arsenic 0.0002 0.0005 2.60E-07 7440-38-3 barium 0.0044 0.0114 5.72E-06 744041-7 beryllium 1.20E-05 0.0000 1.56E-08 7440-43-9 cadmium 1.10E-03 0.0029 1.43E-06 7440-47-3 chromium 1.40E-03 0.0036 1.82E-06 7440-48-4 cobalt 8.40E-05 0.0002 1.09E-07 7440-50-8 copper 8.50E-04 0.0022 1.11E-06 7439-96-5 manganese 3.80E-04 0.0010 4.94E-07 7439-97-6 mercury 2.60E-04 0.0007 3.38E-07 7439-98-7 molybdenum 1.IOE-03 0.0029 1.43E-06 7440-02-0 nickel 2.10E-03 0.0055 2.73E-06 778249-2 selenium 2.40E-05 0.0001 3.12E-08 7440-62-2 vanadium 2.30E-03 0.0060 2.99E-06 7440-66-6 zinc 2.90E-02 0,0754 3.77E-05 Total Annual Metals Emissions: 0.1123 5.62E-05 Additional Regulated Compound Emissions from Total Annual Natural Gas Combustion(Only) CAS No. Specie Emission Factor nnual Pollutant Emissions b/million sc b tons/year) 7143-2 benzene 2.10E-03 0.0055 2.73E-06 25321-22-6 dichlorobenzene 1.20E-03 0.0031 1.56E-06 50-00-0 formaldehyde 7.50E-02 0.1950 9.75E-05 110-54-3 hexane 1.80E+00 4.6800 2.34E- 33 lead 5.00E-04 0.0013 6.50E-07 91-20-3 na thalene 6.10E-04 0.0016 7.93E-07 ' various POM 8.82E-05 1 0.0002 1.15E-07 108-88-3 toluene 3.40E-03 0.0088 4.42E-06 Total Annual: 4.9 2.45E-03 Reported in OS32 in AERO. Additive AE(VOC/Formaldehyde) 2015 Usage Rate of Additive AE= 3,072 lb/yr VOC concentration in Additive AE= 0.05% HAP(Formaldehyde)concentration in Additive AE= 0.05% VOC and HAP contents from the MSDS. Additive Formaldehyde/VOC Calculations Pollutant Emission Rate C)S 3 b/ r) (t ) Formaldehyde 1.54 0.00 VOC 1.54 0.00 Sample Calculation VOC(lb/yr)= (3072 1b/yr*0.0005) = 1.54 lb/yr Total Formaldehyde/VOCs(Natural Gas and Additive) Pollutant Emission Rate' Ib/ r t Formaldehyde 1.73 0.00 VOC 15.84 0.01 Reported in OS31 in AFRO. 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 18 of 26 Sheet:EIG 10(G-159)Mixer BHs 6160 C9 © s Iv ° 3M,Incorporated-Pittsboro Plant 'D Ay r2 A 6r- K 11_W En'tission Calculations S �- Coloring Plant ► 4 if° 3M Group ID EIG 11 �,Zf 15 S d S DAQ Group H) G-160 '= Description Coolers Hours of Operation= 4458.9 hrs Pollutant EF Emission Rate U 10 Criteria (lb/hr) (lb/yr) (t y) 6— PM 9.11 40,639 20.32 PM-10 3.38 15,052 7.53 PM2.5 3.38 15,052 7.53 Emission Factors from AP-42 Table 11.20-Clinker Cooler with settling chamber PM filterable+PM condensable and actual production rate. The cooler applies water and dust suppressant to the materials in the cooler,therefore 70%control of PM due to wet suppression is included in the emission calculations. Dust Suppressant and Adhesion Promoter added in the cooler 2015 Usage Rate of Dust Suppressant A= 1,409,640 lb/yr 2015 Usage Rate of Dust Suppressant B= 426,790 lb/yr 2015 Usage Rate of Adhesion Promoter= 54,179 lb/yr VOC concentration in Dust Suppressant A= 0.31% VOC concentration in Dust Suppressant B= 0.71% VOC(Methanol)concentration in Adhesion Promoter= 14.12% HAP concentration in Dust Suppressant A= 0.00% HAP(Toluene)concentration in Dust Suppressant B= 0.20% HAP(Methanol)concentration in Adhesion Promotrer= 14.12% Dust Suppressant A VOC contents from the MSDS. Dust Suppressant B VOC and HAP contents from the MSDS. VOC Calcualtions for Dust Suppressants Pollutant Emission Rate lb/yr) (t y) Dust Su pressant A 42369.88 2.18 Dust Suppressant B 3,030.21 1.52 Sample Calculation VOC(lb/yr)_ (1409640 lb/yr*0.0031) = 4,369.88 lb/yr Dust Suppressant A contains no HAPs per MSDS. Dust Suppressant B HAP(Toluene)contents from the MSDS(using Maximum Concentration Amount) HAP Calcualtions for Dust Suppressants Pollutant Emission Rate (lb/ r) (t y) Dust Suppressant A 0.00 0.00 Dust Suppressant B 853.58 0.43 Sample Calculation HAP(lb/yr)_ (426790 lb/yr*0.002) = 853.58 lb/yr 3M Emission Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page 20 of 26 Sheet:EIG 11(G-160)Coolers 7 Adhesion Promoter emission factor from 3M(Wausau)stack testing performed in Oct,2011. The adhesive promoter contains methanol,which is a HAP and a VOC. Adhesion Promoter Pollutant Emission Rate (lb/ r (t ) Methanol(&VOC) 7650.07 3.83 Sample Calculation Methanol(lb/yr)_ (54179 lb/yr*0.1412) = 7650.07 lb/yr Total Pollutant Emission Rate (lb/yr) (t y) 2 i i z f VOC 15,050 7.53 Toluene 854 / 0.43 Methanol 7,650 3.83 — 3M Emission Calculations File:3M AEI Calcs-CY 2015.xtsx Moncure,NC Page 20 of 26 Sheet:EIG I 1(G-160)Coolers h Y O 3M, Incorporated - Pittsboro Plant Emission Calculations Coloring Plant 3M Group ID EIG 12 DAQ Group ED G-161 Description Finished Granule Baghouse Sources Hours of Operation= 4458.9 hrs Hourly Emissions Annual Emissions Ratel Rate PM PM-10 PM PM-10 (lb/hr) (lb/hr) (lb/yr) (tpy) (lb/yr) (tpy) 2.36 2.36 10,510.26 5.26 10,510.26 5.26 Sample Calculation 0.01 * 1/7000 lb/gr*27500 * 60 min/hr=2.36 lb/hr 2.36 lb/hr* 4458.9 = 10510.26 lb/yr 1 Hourly emission rates calculated using grain loading and baghouse flowrate 2 Annual emission rates calculated based upon the coloring plant operating hours Metals Emissions from Additives CAS No. Species Annual Pollutant Emissions (lb/yr) (tons/year) 7440-38-2 arsenic 1.35E-03 6.75E-07 7440-41-7 beryllium 5.06E-05 2.53E-08 l/ 7440-43-9 cadmium 4.12E-03 2.06E-06 7440-47-3 chromium 2.09E+00 1.04E-03 7440-48-4 cobalt 4.65E-04 2.32E-07 7439-92-1 lead 2.22E-03 1.11E-06 7439-96-5 manganese 3.23E-01 1.61E-04 7439-97-6 mercury 9.88E-05 4.94E-08 7440-02-0 nickel 1.13E-03 5.67E-07 Total Annual Metals Emissions: 2.42E+00 1.21E-03 (Refer to page 22,23 for additonal details) 3M Emission Calculations File:3M AEI Calcs-.CY 2015.xlsx Moncure,NC Page 21 of 26 Sheet:EIG 12(G-161)Finished Gran BH c 3M,Incorporated-Pittsboro Plant Emission Calculations 2015 Coloring Plant Additive HAPS and TAPS Additive Annual Additive ID Usage(lb) Data Arsenic Beryllium Cadmium Chromium Cobalt Lead Manganese Mercury Nickel A 1,409,640 Concentration( m) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 B 0 Concentration 0.040 0.050 0.060 0.200 0.070 0.780 0.000 0.003 0.490 Metals Total(lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions Ohs/yr) 0.00000 0.00000 0.00000 0.000001 0.00000 0.00000 0.00000 0.00000 0.00000 C 0 Concentration 0.500 1.000 2.200 5.500 82.000 4.800 390.000 0.022 69.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 D 31,537 Concentration 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total(lbs( 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 E 0 Concentration 1.000 0.000 1.000 990000.000 1.000 2.000 10.000 0.500 10.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 F 0 Concentration 5.200 0.000 5.800 1.000 0.000 3.000 0.000 0.050 6.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 G 20,878 Concentration 17.000 0.000 1.000 145.000 5.000 2.000 59.000 1.000 20.000 Metals Total lbs/ 0.355 0.000 0.021 3.027 0.104 0.042 1.232 0.021 0.418 Emissions(lbs/yr) 0.00001 0.00000 0.00000 0.00010 0.00000 0.00000 0.00004 0.00000 0.00001 H 221,930 Concentration 40.000 0.000 30.000 0.000 0.000 150.000 40000.000 5.000 0.000 Metals Total(lbs/ 8.877 0.000 6.658 0.000 0.000 33.290 8877.200 1.110 0.000 Emissions(lbs/yr) 0.00030 0.00000 0.00023 0.00000 0.00000 0.00113 0.30182 0.00004 0.00000 I 268,785 Concentration 20.000 1.000 1.000 30.000 50.000 10.000 650.000 0.200 100A00 Metals Total Ohs/ 5.376 0.269 0.269 8.064 13.439 2.688 174.710 0.054 26.879 Emissions(lbs/yr) 0.00018 0.00001 0.00001 0.00027 0.00046 0.00009 0.00594 0.00000 0.00091 J 0 Concentration 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total(lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 K 11,484 Concentration 350.000 0.000 10.000 30.000 0.000 250.000 150000.000 0.010 0.000 Metals Total(lbs/ 4.019 0.000 0.115 0.345 0.000 2.871 1722.600 0.000 0.000 Emissions(lbs/yr) 0.00014 0.00000 0.00000 0.00001 0.00000 0.00010 0.05857 0.00000 0.00000 L 0 Concentration 10.000 100.000 300.000 0.050 300.000 0.020 1000.000 0.050 300.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 M 206,574 Concentration 1.000 0.000 1.000 0.500 0.000 1.000 0.500 5.000 0.000 Metals Total lbs/ 0.207 0.000 0.207 0.103 0.000 0.207 0.103 1.033 0.000 Emissions(lbs/yr) 0.00001 0.00000 0.00001 0.00000 0.00000 0.00001 0.00000 0.00004 0.00000 N 0 Concentration 1.000 0.000 1.000 1.000 0.000 1.000 0,000 1.000 2.000 Metals Total(lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 O 0 Concentration 10.800 0.000 0.500 5.000 0.000 5.500 0.100 0.100 0.100 Metals Total(lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.000001 0.000001 0.00000 0.00000 0.00000 P 10,982 Concentration 0.050 0.000 0.005 0.050 0.1031 0.0151 0.000 0.001 0.188 Metals Total lbs/ 0.001 0.000 0.000 0.001 0.0011 0.0001 0.000 0.000 0.002 Emissions(lbs/yr) 0.000001 0.00000 0.00000 0.00000 0.000001 0.000001 0.00000 0.00000 0.00000 3M Emissions Calculations File:3M AEI Calcs-CY 2015.xlsx Moncure,NC Page:23 of 26 Sheet:EIG 12(0-161)Additive HAP-TAP b Q 0 Concentration 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 R 8,577 Concentration 2.000 0.000 2.000 4.000 1.000 9.000 0.000 2.000 5.000 Metals Total(lbs/ 0.017 0.000 0.017 0.034 0.009 0.077 0.000 0.017 0.043 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 S 6,434,581 Concentration 0.000 0.000 20.000 20.000 0.000 3.200 0.000 0.070 0.000 Metals Total lbs/ 0.000 0.000 128.692 128.692 0.000 20.591 0.000 0.450 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00438 0.00438 0.00000 0.00070 0.00000 0.00002 0.00000 T 67,838 Concentration 0.000 0.000 0.000 0.945 0.000 0.000 0.000 0.013 0.000 Metals Total(lbs/yr) 0.000 0.000 0.000 0.064 0.000 0.000 0.000 0.001 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 U 407,781 Concentration 60.000 0.500 0.500 30.000 1.000 0.500 0.500 1.000 4.000 Metals Total(lbs/yr) 24.467 0.204 0.204 12.233 0.408 0.204 0.204 0.408 1.631 Emissions(lbs/yr) 0.00083 0.00001 0.00001 0.00042 0.00001 0.00001 0.00001 0.00001 0.00006 V 19,921 Concentration 0.450 0.000 0.015 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total(lbs/yr) 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 W 0 Concentration 5.000 0.000 0.500 11.000 0.000 17.000 400.000 0.001 107.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 X 196,957 Concentration 3.000 0.000 0.500 2.000 0.000 5.000 0.000 0.250 0.000 Metals Total lbs/ 0.591 0.000 0.098 0.394 0.000 0.985 0.000 0.049 0.000 Emissions(lbs/yr) 0.00002 0.00000 0.00000 0.00001 0.00000 0.00003 0.00000 0.00000 0.00000 Y 15,741 Concentration 25.000 0.000 1.000 232.000 0.000 3.000 0.000 1.000 42.500 Metals Total lbs/ 0.394 0.000 0.016 3.652 0.000 0.047 0.000 0.016 0.669 Emissions(lbs/yr) 0.00001 0.00000 0.00000 0.00012 0.00000 0.00000 0.00000 0.00000 0.00002 Z 396,234 Concentration 0.050 1.000 0.050 1.600 1.000 0.600 2.700 0.050 0.400 Metals Total lbs/ ) 0.020 0.396 0.020 0.634 0.396 0.238 1.070 0.020 0.158 Emissions(lbs/yr) 0.00000 0.00001 0.00000 0.00002 0.00001 0.00001 0.00004 0.00000 0.00001 AA 70,540 Concentration 1.000 0.000 1.000 985000.000 0.050 3.000 0.000 1.000 0.000 Metals Total lbs/ 0.071 0.000 0.071 69481.900 0.004 0.212 0.000 0.071 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 2.36238 0.00000 0.00001 0.00000 0.00000 0.00000 AB 4,033 Concentration 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Metals Total(lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0,00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 AC 16,394,725 Concentration 0.040 0.050 0.060 0.200 0.070 0.780 0.000 0.003 0.490 Metals Total lbs/ 0.656 0.820 0.984 3.279 1.148 12.788 0.000 0.049 8.033 Emissions(lbs/yr) 0.00002 0.00003 0.00003 0.00011 0.00004 0.00043 0.00000 0.00000 0.00027 AD 0 Concentration 100.000 0.000 5.000 0.100 0.000 100.000 0.000 1.000 400.000 Metals Total lbs/ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Emissions(lbs/yr) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.000001 0.00000 0.00000 Total Metals Used(lbs/yr) 45.058 1.689 137.370 69642.421 15.509 74.238 10777.119 3.298 37.833 Metals Emissions(lbs/yr) 1.53197E-03 5.74140E-05 4.67059E-03 2.36784E+00 5.27290E-04 2.52409E-03 3.66422E-01 1.12133E-04 1.28632E-03 Metals Emissions(ton/yr) 7.65984E-07 2.8707E-08 2.33529E-06 1.1 8E-031 2.63645E-07 1.26204E-06 1.83E-041 5.60663E-08 6.43162EA7 Notes: Arlen c I Beryllium I Cadmium I Chromium I Cobalt Lead Manganese Mercury Nickel 1)This table was constructed to compare all additives. 2)Whenever multiple addive products were potentially avalaible,the worst case(most toxic)additive was used for this table.One worst case additives were listed in the table for each formula. 3)The trade names for each additive not used for any product because this table is meant as a generic comparison/evaluation. 4)These additives are wet when mixed and therefore,based on historical calculations a release to air factor of 1.7%is applied to the metals emissions calculation. 5)A baghouse efficiency of 99.8%has been utilized for the metal emissions calculation. Note:Metal emissions are split between the Raw and Finished Granule Baghouses.The split is based on the amount of inprocess product run through the source. Raw Granule Baghouse%= 12% Finished Granule Baghouse= 88% Refer to pages 14 and 21 for additive HAP and TAP summary and reporting information. 3M Emissions Calculations File:3M AEl Calcs-CY 2015.xlsx Moncure,NC Page:23 of26 Sheet:EIG 12(G-161)Additive HAP-TAP 3M,Incorporated-Pittsboro Plant Emission Calculations Coloring Plant Storage Tanks 3M Group ID N/A DAQ Group ID G-162 Description Liquid Storage Tanks(Insignificant Sources) Emissions Tanks Pollutant Emitted (tpy) (lblyr) At,A2,A3,A4,A5,A6,A7, A9,A10,All,A13,A15,A16, N/A N/A N/A A17 All,Al2 PM 0.0002 0.3525 Tank Throughput 9.41 lb per min Emission Factor 0.00014 lb/ton throughput AP42,Table 11.19.2-2 Hours of Operation 4,458.90 hrs Location Emission Material Storage Information Emitted Maximum Annual Emissions Determination Unit Material Temperature Pressure Pollutant Uncontrolled Recovery Device Hourly Annual Emissions Designation Stored (deg.F) (psig) Classification Emission Factor Device Description Effectiveness Emissions (Criteria or HAP) (as noted % lb/hr) (lb/ ) Coloring Plant Tank Farm Aa Hold Tank ambient ambient PM 0.00014 hood w!fabric filter 90 0.00000 0.01762 O.000OI Al2 Hold Tank ambient ambient PM 0.00014 hood w/fabric filter 90 0.00000 0.01762 0.00001 O i-: 3M Emission Calculations File:3M AEI Cates-CY 2015.xlsx Moncure,NC Page 24 of 26 Sheet:lnsig(G-162)Storage Tanks 05 3M, Incorporated - Pittsboro Plant Emission Calculations 3M Group ID N/A DAQ Group ID G-163 Description Truck Loading and Loadout (Fugitive) Truck Loading throughput= 1.10 loads/hr Control Efficiency2= 90.00% Hours of Operation= 18447 hrs AP-42 Annual Emissions Emission Factors Rate PM PM-10 PM PM-10 (lb/load) (lb/load) (lb/yr) (tpy) (lb/yr) (tpy) Truck Loadout 2.325 1.1 4,717.82 2.36 2,232.09 1.12 Total 4,717.82 2.36 2,232.09 1.12 Sample Calculation 1.1 loads/hr * 2.325 lb/load * 18447 hrs * (1-0.9)=4717.82 lb/yr s Emission factors from AP-42, Eqn. 1 of 13.2.4-3 in lb/ton of materials. Converted to lb/load. 2 Control Efficiency from AP-42, 13.2.4.4 3M Emission Calculations File:3M AEI Calcs - CY 2015.xlsx Moncure,NC Page 25 of 26 Sheet:Fug(G-163)Truck Load&Loadout + 3NI.InmmocaUd-Flits, Plml P dinar ComlaWm (bbriss PIaW JM n—an NA OAOComm GIW ➢•mrotlm MM14-5 FlomrdOpmnov(argil dPm M Emission Sours Foform-Non Fad slouUnit Onrdptlomin This v PermltApplimtlom AnnaalAvg Annual PMIO Emissions Determination Au nu.I TSPEmisslon]Ddernalrotio. NCBENB Imbrivn Sourm BeaerlDtlart NPermlt AppBmtlen UrW Pad5abn 6oarte DeserlptlovNCmatmctlort Pervdt APDllntlart SCCN b/vteAW Arfertnm morass UmaWroded hivmry CanaollMripnm Pmne:yr—d Sm.Cmtml SmC I Ilomly Annuo1PM10IF Uvravn Um Pd aaal Sec.Conwl Doody AmvmI TSP Fivissiom IdeatlOratiort (pm eorreetive rmtn) Pmltter 'nut rant PgWpmmI SCC DeJlpmtlov>✓DeveAptlava UaM NAP-0a TMvve6put fnr Urtmvtm0ed Fm'vim Facto FIf'vm�ar IMaipim FB'yacv Fmiav'om E®aim Fvctm EB'afirenm Fd iverm Emissiam Number vtlon tom rhr Psdn^lon Padon 164n Man brM amted:^S veauti rddYe De F61 Idmwmowra�aJJe •F61 61 MC73AIvadoW OWn Z4^austmnvryorvB(DTQ3B) 3-0s-020-06 2 AD.(;rmm ul.tD.:n 0.0011 Totaltmad'a punt mrlosurc 0.9000 bidaemlouoe 0.700 7.17E-05 0.32 0.0030 0.9000 0.7000 1.96E-04 I 4.37E-04 �m5msmnv;a.auPrnem-aada.m• F6771 •F6T/1 6771 Poe NIM(MMI) 98 Ae.a;rmmll.tgsa 0.0022 Tuadmdosw 1—pis—ion 0.8730 bldg eadcauc 0.700 0.008 37 0.0060 0.8730 0.7000 0.022 100 0.050 n�e.am a,ae emr5v xaa.m nn F72 des®-I�nmea:e•+nry• F72 n wlysC2Slmd—osawmtonx ,Ue 98 Auv;E�i am— 0.044 wdmppeaim 0.9700 Trial cod 0.900 0,013 58 0.0930 0.9700 0.9000 0.027 123 0.061 Mvr.Ama1PM10 Panlatlav Tvlab: 0.02 95 Mar.AdvW TSPP WaIov Tofab: 0.05 224 0.11 IMr PMIO PMIO @4v TSP TSP TSP Nolen: I. The AP42 emission factorsarebased upon information presented in Washed section ofUSEPA Publication AP-02,"Compilation ofA1r Pollutant Emission Fsetom" 2. Conveyors located outdoors me completely enclosed 3. inside conveyors me totally=closed unless otherwise noted 4. PM/PMIO ratio is 0.74/0.35-2.1 unless otherwise specified This ratio is based uponAPA2,Section 13.2A,and NCDENR Spreadsheet fan Stone Quarry/Granite Crushing. 5. Silos and surge bins are considered as hsv trans(operations unless the bin loads out directly into a crusher or screen assembly.In rases where surge him feed directly into crashing rescreening operetioq only the loading emissions are cM1maaerized.This approach is necessary to avoid doublo-counting, since loadout of We bin is We loading for the crushing or screening operation-which is already accounted in the operation's emission facmr(see We preceding note).DasM upon this aptmach,a silo or an isolated surge bin will haven uncontrolled emission factor ofO.0022.A surge bin which feeds directly into a crashing or screening operation will have an ummntmilcd emission factor of 0.0011. 6. Although many of'b trensf"points with their emissions laded m a baghouse are=closed by a building,the credit fan building enclosure is not applied because these points are under negative pressure and would actually"take in'particulates in the building,air. 7.Eecouse fabric fill=ore=asidered 100%effective for particulate larger than 10 microns,their net TSP control effectiveness exceeds their net PMIO control eR tiveness.The spreadsheet values reflect this reality. � o c 3M Fd—AFJCeIo-CY2015x �� Pa8e 76 r(a6 ShaOG 13,1a rid IS GAS DIESEL INTERNAL COMBUSTION ENGINES with power rating of<=600 HP for diesel engines and<=250 HP for gasoline engines EMISSIONS CALCULATOR REVISION S 6/22/2015-INPUT SCREEN Instructions: Enter emission source/facility data on the"INPUT"tab/screen. The air emission results and summary of input data are viewed/printed on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen. A This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the information contained. This NCDENR spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or omissions that may be contained herein. FIELDS SELECTIONS COMPANY NAME: 3M Pittsboro FACILITY ID NUMBER: 1900104 PERMIT NUMBER 09006T06 FACILITY CITY: Moncure FACILITY COUNTY: Chatham SPREADSHEET PREPARED BY: SC EMISSION SOURCE ID NO.: IS-FP RATING and FUEL TYPE 290.00 HP POWER OUTPUT,DIESEL SULFUR CONTENT OF DIESEL FUEL FUEL HEATING VALUE FUEL HEATING VALUE(BTU/GAL): 140,000 BTU/GAL is equal to 0.1400 mm Btu/gal DEFAULT VALUES BY FUEL TYPE(not used for Greenhouse Gas calcs--See below for GHG defaults): 116,485 BTU/GALLON GASOLINE 140,000 BTU/GALLON DIESEL USAGE DATA ACTUALS(GALLONS COMBUSTED OR HRS OF OPERATION) 12 HRS OF OPERATION REQUESTED ANNUAL LIMITATION GALS COMBUSTED (GALLONS COMBUSTED OR HRS OF OPERATION) ADDITIONAL INFORMATION FOR GREENHOUSE GAS(GHG)EMISSIONS ENTER CALCULATION TIER I TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF from EPA Mandatory Reporting Rule(MRR)Subpart C- www.epa.gov/climatechange/emissions/ghgrulemaking.htmi NOTE: EF is"Emission Factor' SELECT FUEL TYPE(more detailed fuel type needed for GHGs) DISTILLATE s2 SINCE TIER 3 IS NOT BEING USED, T0000 kg Carbon/gal FUEL CARBON CONTENT WILL NOT BE USED HIGH HEAT VALUE(HHV)FOR GHGs FOR TIER 1 and TIER 3,the FUEL HEATING VALUE entered above is overriden with the EPA DEFAULT from Table C-1 of the EPA MRR: GASOLINE(Motor) 0.125 mm Btu/gal DISTILLATE#1 0.139 mm Btulgal DISTILLATE#2 0.138 mm Btu/gal THIS VALUE WILL BE USED DISTILLATE#4 0.146 mm Btu/gal RESIDUAL#5 0.14 mm Btu/gal RESIDUAL#6 0.15 mm Btu/gal FOR TIER 2,the FUEL HEATING VALUE entered above is used. The value entered must be the annual average HHV of the fuel determined using procedures in the EPA MRR(see 98.33(a)(2)) HHV TO BE USED FOR GHG IS: DISTILLATE#2 DEFAULT 0.1380 Btulgal THIS VALUE WILL BE USED HHV OF GAS&DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR REVISION S 6/22/2015-OUTPUT SCREEN Instructions: Enter emiss!on source/facility data on the"INPUT tablscreen. The air emission results and summary of input data are .,g3r viewediprinted on the"OUTPUT'tab/screen. The different tabs are on the bottom of this screen. This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the information container, � This spreadsheet is subject to continual revision and upd•�,ting. It is your responsibility to be aware of the most current information availabl: NCDENRDENR is not responsible for errors or omissions that IT, contained herein. SOURCE/FA USER INPUT SUMMARY R NPU S RE COMPANY. 3M Plttsboro FACILITY ID PERMIT NUMBER 09006T06 EMISSION SOURCE DESCRIPTION 290 HP POWER OUTPUT DIESEL INTERNAL COMB- FACILITY CITY: Moncure EMISSION SOURCE ID NO.: S-F FACILITY COUNTY: Chatham SPR DSHEET REPARED BY: SC POLLUTANT NTR LEFF ACTUAL THROUGHPUT 12 H S PERAT N I -FUEL HEATING VALUE:1 1400001 BTUIGAL PM 0 REQUESTED ANNUAL LIMITATION GALS COMBUSTED CALCULATIONS: 0.138 Trim BTUIGAL PM10 0 ULFUR ENT UF DIE L FU L % 0 PM2.5 0 METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF S02 0 CARBON CONTENT USED FOR GHGS k C/al: CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN NOX 0 CO 0 VOC 0 EL CRITERIA AIR POLLUTANT EMISSIONS INFORMATION ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR (AFTER CONTROLS/WTS) (BEFORE CONlROLS&"M (AFTER CONmOlB IWM ItMhp-hr AIR POLLUTANT EMITTED Ib/hr tons/ Ib/hr I tonslyr Whir I tonslyr uncontrolled PARTICULATE MATTER PM 0.64 0.00 0.64 2.79 0.64 JVL PARTICULATE MATTER<10 MICRONS(PM10) 0.64 0.00 0.64 2.79 0.64 2.20E-03 PARTICULATE MATTER<2.5 MICRONS(Pli 0.64 0.00 0.64 2.79 0.64 #VALUEI 2.20E-03 SULFUR DIOXIDE S02 0.35 0.00 0.35 1.54 0.35 1.21E-03 NITROGEN OXIDES NOx 8.99 0.05 8.99 39.38 8.99 3.10E 2 CARBON MONOXIDE CO 1.94 0.01 1.94 8.48 1.94 6.68E-03 VOLATILE ORGANIC COMPOUNDS(VOC) 0.73 0.00 0.73 3.19 0.73 2.51E-03 WF TOXIC/HAZARDOUS AIR EMISSIONS INFORMATION ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR MASC-Other (ARERCONTROLSIWTS) (9EFORE CONTROLS I WTS) (AFTER CONTROLS INATS) Ib/hp-hr TOXIC/HAZARDOUS AIR POLLUTANT Whir Whir Ib r Ib/hr Ib r uncontrolled Acetaldeh de(H,T) 1.56E-03 1.87E-02 1.56E-03 1.36E+01 1.56E-03 #VALUE! 3 Acrolein(H,T) 1.88E-04 2.25E-03 1.88E-04 1.64E+00 1.86E-04 #VALUE! 6.48E-07 Arsenic unlisted Compounds H,T) 8.12E-06 9.74E-05 8.12E-06 7.11E-02 8.12E-06 #VALUE! 2.80E-08Benzene(H, 1.89E-03 2.27E-02 1.89E-03 1.66E+01 1.89E-03 #VALUEI6.53E-06 Benzo(a)pyrene H,T) 3.82E-07 4.58E-06 3.82E-07 3.34E-03 3.82E-07 #VALUE! 1.32E-09 Beryllium metal(unreacted) H,T) 7440417 6.09E-06 7.31E-05 6.09E-06 5.33E-02 6.09E-06RVAE 2.10E-08 1,3-Butadiene(H,T 106990 7.94E-05 9.52E-04 7.94E-05 6.95E-01 7.94E-05 2.74E-07 Cadmium metal elemental unreacted)(H,T) 7440439 6.09E-06 7.31E-05 6.09E-06 5.33E-02 6.09E-06 2.10E-08 Chromic Acid(VI)(H,T) 7738945 8.09E-06 7.31 E-05 6.09E-06 5.33E-02 6.09E-06 2.1 DE-08 Formaldehyde H,T 50000 2.40E-03 2.87E-02 2.40E-03 2.10E+01 2.40E-03 8.26E-06 Lead unlisted com ounds(H) PBC-Other 1.83E-05 2.19E-04 1.63E-05 1.60E-01 1.83E-05 6.30E-08 Manganese unlisted compounds H,T) MNC-Other 1.22E-05 1.46E-04 1.22E-05 1.07E-01 1.22E-05 4.20E-08 Mercury vapor(H,T) 7439976 6.09E-06 7.31E-05 6.09E-06 5.33E-02 6.09E-06 2.10E-08 Napthalene(H) 91203 1.72E-04 2.07E-03 1.72E-04 1.51E+00 1.72E-04 #VALUE! M2.S6E-06 Nickel metal(H,T 7440020 6.09E-06 7.31E-05 6.09E-06 5.33E-02 6.09E-06 #VALUE! Selenium compounds(H SEC 3.05E-05 3.65E-04 3.05E-05 2.67E-01 3.05E-05 #VALUE! Toluene(H,T) 108883 8.30E-04 9.96E-03 8.30E-04 7.27E+00 8.30E-04 #VALUE!X lane H,T 1330207 5.79E-04 6.94E-03 5.79E-04 5.07E+00 5.79E-04 #VALUE!Highest HAP(Formaldehyde) 50000 2.40E-03 2.87E-02 2.40E-03 2.10E+01 2.40E-03 #VALUEI Total HAPs 7.79E-03 9.35E-02 7.79E-03 6.83E+01 7.79E-03 #VALUE! TOXIC AIR POLLUTANT EMISSIONS INFORMATION(FOR PERMITTING PURPOSES) EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS EMISSION FACTOR Itr/hp� TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Itityr uncontrolled Acetaldehyde H, 75070 1.56E-03 3.74E-02 #VALUE! 5.37E-06 Acrolein H,T) 107028 1.88E-04 4.51E-03 #VALUE! 6.48E-07 Arsenic unlisted compounds H, ASC-Other 8.12E-06 1.95E-04 #VALUEI 2.80E-08 Benzene(H,T) 71432 1.89E-03 4.55E-02 #VALUEI 6.53E-06 Benzo a rene H,T) 50328 3.82E-07 9.16E-06 #VALUE! 1.32E-09 Beryllium metal unreacted) H, 7440417 6.09E-06 1.46E-04 #VALUE! 2.10E-08 1,3-Butadiene(H,T) 106990 7.94E-05 1.90E-03 #VALUE! 2.74E-07 Cadmium metal(elemental unreacted)(H,T) 7440439 1 6.09E-06 1.46E-04 #VALUE! 2.10E-08 soluble chromate compounds,as ro chmium VI equivalent SOLCR6 I 6.09E-06 1.46E-04 #VALUE! 2.10E-08 Formaldehyde H,T) 50000 2.40E-03 5.75E-02 #VALUE! 8.26E-06 Manganese unlisted compounds H,T MNC-Other 1.22E-05 2.92E-04 #VALUEI 4.20E-08 Mercury vapor(H,T) 7439976 6.09E-06 1.46E-04 #VALUE! 2.10E-08 Nickel metal H, 744DO20 6.09E-06 1.46E-04 #VALUEI 2.10E-08 Toluene H, 108883 8. E-04 1.99E-02 #VALUE! 2.86E-06 X lene H,T) 1330207 5.79E-04 1.39E-02 #VALUE! 2.00E-06 GREENHOUSE GAS EPAISNIIIIIIIIIIIFORMATION(FOR EMISSIONS INVENTORY PURPOSES) -CONSISTENT WITH EPA GHG-POTENTIAL TO EMIT MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD DISTILLATE#2 ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat input Requested Emission Limitation 1utilize capacity or horsepower and EPA MRR Emission requested fuel limit and EPA MRR GREENHOUSE GAS EMITTED WILL NOT USE EPA MRR METHOD IF ONLY HOURS OF OPERATION ARE GIVEN Factors Emission Factors metric ton metric ton r,CO2e short ton r short ton r short ton r,CO2e short ton r short tonslyr,CO29 CARBON DIOXIDE(CO,) no EPA method no EPA method no EPA method 1,449.78 1,449.78 #VALUEI #VALUE! METHANE(CH4) no EPA method no EPA method no EPA method 5.88E-02 1 47E+00 #VALUEI #VALUE! NITROUS OXIDE(N=O) no EPA method no EPA method no EPA method 1.18E-02 3.50E+00 #VALUE! #VALUE! TOTAL no EPA method TOTALI 1,454.75 T T L I NOTE: CO2e means CO2 equivalent. NOTE: The DAO Air Emissions Reporting Online(AERO)system requires short tons be reported. The EPA MRR requires metric tons be reported. NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes. 0 Fire Pump Hours of Operation for 2015 Dec. 31, 2014 reading on fire pump meter: 280 hrs August 13,2015 reading on fire pump meter 292 hrs The pump was shut down and put in storage on 8/21 and will be moved to new location 12 hrs for year of 2015 and reinstalled at a later date.