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HomeMy WebLinkAboutAQ_F_1900015_20130701_EI_Cmb-EI-File CY2012 Emission Inventory Review/Data Tracking Form Check boxes that apply. Facility Name: A GAlA c 67 Facility ID: / U V L) (s Assigned To: \/ p(AkA14^ Confidential Request: Yes ElNo e' r If yes, notify El coordinator and treat as confidential. Submission type: AERO D*/Paper ❑ If Paper, initials of person entering emissions data into ED Inventory Review/IBEAM Data Entry Y N* All forms appear complete and signed by the appropriate official. Supporting calculations, control efficiencies, and documentation of emission factors, if not using AP-42, are included and appear correct. Pertinent compliance and permitting limits checked and facility is at or below limits (If facility has exceeded limit, check calculation and explain). All permitted and known insignificant sources are included and source and control device IDS are the same as the Ids used in the Air Permit. All known operating scenarios, control devices, and emission release points have been entered for each source. For any pollutant, all emissions have been reported for all permitted and insignificant sources that contribute to the facility total (above de minimus reporting limits) of that pollutant to the best of reviewers knowledge. All volatile HAPS/TAPS included in VOC total. (See pollutant list on DAQ external web page) Significant changes (>10%)from previous inventories have been investigated and found acceptable (verified by running QAQC report and Facility Total report in ED-Entry). Print Facility total report and attach. .Reviewer has checked for facility comments and addressed any issues in the facility comments. Reviewer has checked for SCC/source type accuracy and corrected errors when found. (please note errors corrected in summary below). Summary of all changes/additions to inventory: a (,{riI cK�c17Z n PYr"o"�5 iN VO& d YAp'I TAPS O-o5ltV5 4ij ptUtit Dryer- OO j ��`/ r', C—ve#A s l Rut � rS- l) -F64r hPu 5 vow t 70 '3ru/vr $ 4S, b lb vvvt /�r' (ZJsix.&,qtu WzS j4 att# rTwlhY r jj rt t4 Tt1w'oy F5— 17 e yrol-n PoIAs/y fi4 fered 9. 3 2- IM) �'� P1t'1/f?M to � co rre4 ted t,:> fit,02- sous. hra 5ti pNt fr #�u WoJ parni� 0 111 POF P1uyt taus ZaS-h,'. TL WWI Sled be ehr. C�yr��t�d t� S� s-t s -76 NP O , P� et 0 Cdf P ftr -,e,< ,e14a t;ter If No, explain corrective action taken in the summary section of this form. ,��6a"-t 44"S QAQC and Facility Total Reports verified correct? V/ Has the Data Entry Complete daqobeen entered in IBEAM? VXdo so only when totally finished) Signature of Reviewer: G" Date reviewed: (This signature certifies that this r ew was completed to the best of my ability within the time constraints allowed.) Facility Total CY 2012 Emission Summary Recorded in Ell Facility ID#: 1900015 Facility Name: Arauco Panels USA LLC Permit#(s): 03449T41 Hazardous Air Pollutants(HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2012 CY 2011 Demini- 0 from ED from Fees mus Change Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.039500 Not 1.0 N/A Reported Cadmium & cornpattnds (tote/muss ilic'ludes elrntentul metal) 1.11-5 1.517 0.1 11.5 Cadmium Metal, elemental, unreacted(Component 7440-43-9 1 .^5 1.57 0.1 l 1.4':0 of CDC) Chromium-All/Total(includes Chromium (VI) categories, 5.04 4.25 0.1 18.6 metal and others) Chromic acid(VI) (Component of SolCR6& CRC) 7738-94-5 0.265270 0.180390 0.01 47.1% Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-Other Not 0.043600 0.01 N/A Specify Compound(Component of NSCR6& CRC) Reported Chromium Unlisted Compounds-Specify CRC-Other 4.77 4.03 0.1 18.5% Compound(Component of CRC) Chromium (VI)Non-Specific Compounds, as Chrom(i 7) Not 0.043600 0.01 � N/A (Component CRC) Reported Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-other Not 0.043600 0.01 .1 Specify Compound(Component of NSCR6& CRC) Reported Chromium (VI)Soluble Chromate Compounds(Component of 0.205270 0.180390 0.01 4-•1 CRC) Chromic acid(VI) (Component of SolCR6& CRC) 7738-94-5 0.265270 0.180390 0.01 47.1 Cobalt& compounds 0.189100 Not 1.0 N/A Reported Cobalt Unlisted Compounds-Specify Compound COC-Other 0.189100 Not 1 .0 N/A (Component of COC) Reported Lead & compounds 15.98 1 1.59 1.1) 1-.6`,';� Lead Unlisted Compounds-Specify Compound PBC-Other 15.98 13.59 10.0 17.6';„ (Component of PBC) Manganese & compounds 30.85 26.22 10.l) 17.7", Manganese Unlisted Compounds-Sped MNC-Other 30.85 26.22 10.0 1 Compound(Component of AMC) Mercury & Compounds-all total mass includes Hg Vapor 0,673530 0,622090 0.001 8.3 10/09/2013 Page 2 of 5 Puram, Yukiko From: John Bird Dohn.bird@arauco-usa.com] Sent: Thursday, October 03, 2013 4:19 PM To: Puram, Yukiko Subject: RE: Inventory corrections Yukiko, There are not enough characters allowed for entirety of response so here are my comments: �OS30- Data matches calculations from spreadsheet. 3 5 i1 OS49 -WPP1 VOC calculation is as follows= (VOC as propane) + methanol +formaldehyde - (0.65*methanol as propane) Source Test units were in Ibs per hour so WPP1 VOC(Ibs/hr) = 1.74 VOC as propane +0.0897 methanol +0.088 formaldehyde -0.65*(0.0411 methanol as propane) = 1.89 WPP1 VOC Ibs/hr .,V Production rate during test was 26.13 MSF/hr. 26.13/1.89=0.72 Ibs/MSF OS6 -This should be based on source specific emission factors, which should result in emission rate of 188.47 tpy for 2. Spreadsheet was created prior to source test assuming 90%VOC destruction. Actual VOC destruction was—60%. OS81- Device did not operate. Device was never constructed only permitted. Please verify the refiners(ES-01) and the board cooler(ES-06B) were not operated in 2012.—ES-01 (OS-50) is routed directly through dryers(OS-69) during normal operation so emissions are comingled. When in startup emissions are routed to cyclone (OS-74),which were calculated. ES-06B board cooler is routed to OS-69 as well during all operations and does not operate when OS-69 is offline. I do not think I need to change any of the submitted information at this point. Let me know as I am having trouble saving in Aero. John Bird Arauco-USA Moncure 0: 919-642-6658 1 C: 843-544-5277 -----Original Message----- From: Puram, Yukiko [mailto:yuki.puram@ncdenr.gov] Sent: Tuesday, October 01, 2013 3:52 PM To:John Bird Cc: Ricardo Hillmann Subject: FW: Inventory corrections Hi John, I just sent the emissions inventory back to the facility. I discovered some emissions needed to be updated. The following message was sent to Carolyn's email address, so I am forwarding to you as well. Here's my explanation of the disputed operation scenarios: 654F Dryer:The VOC and HAPS/TAPS were off by a factor of 10. It seems to be just simple calculation errors. When you multiply the emission factor by the production rate, it'll come out 10 times more than what's being reported. I've corrected the VOC and HAPs/TAPs emissions. Please verify these values. 1 ES-17: PM/PM10 emissions entered in AERO were different from the calculation sheet. Scrubber Controlling Press ES-16: Can you please explain how you converted from the test results in mg/DSCM or grains/dscf into Ib/MSF3/4" to get the emission factors? Please provide us additional sample calculations. Please verity the refiners (ES-01) and the board cooler(ES-06B) were not operated in 2012. New MDF Plant Log Processing Line: I understand the chipper is in an enclosed building and there was no PM emissions from the chipping operations. How about emissions from debarking or chip and bark handling (conveying and dropping)? Were there not throughputs for those operations? 1 set the deadline for resubmitting those information by Friday. Please feel free to call me if you have any questions. Thank you. Yuki Yuki Puram, Environmental Engineer NC DENR - Division of Air Quality Raleigh Regional Office 3800 Barrett Drive, Raleigh, NC 27609 Phone: (919) 791-4200 Fax: (919) 881-2261 www.ncair.org ***************************************************************** E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties unless the content is exempt by statute or other regulation. ***************************************************************** -----Original Message----- From: DENR.DAQ.Emission_Inventory_UG@lists.ncmail.net [mailto:DENR.DAQ.Emission_Inventory_UG@lists.ncmail.net] Sent: Tuesday, October 01, 2013 1:15 PM Subject: Inventory corrections Dear Carolyn Underwood The submittal of the 2012 emission inventory for Arauco Panels USA LLC, 1900015, has been reviewed by Yukiko Puram of the Division of Air Quality(DAQ) Raleigh Regional Office. This review indicated the emission inventory is not acceptable as received.The data that have been disputed are being returned electronically for completion or correction. This is an initial notification, and more details regarding this issue and the due date for completion will be sent shortly to Ricardo Hillmann Please review the returned data and comments in AERO, correct the data as necessary, and resubmit in AERO. The list of disputed items and DAQ comments are located in the Closeout screen in AERO. Login as you initially did when entering the data. If the reason for return is not obvious to you, please contact Yukiko Puram at 919-791-4200 or Yuki.Puram@ncdenr.gov Your Emission Inventory will not be considered complete until all required information has been received and you remain subject to penalties for non-submittal. Sincerely 2 Puram, Yukiko From: John Bird Dohn.bird@arauco-usa.com] Sent: Friday, October 04, 2013 2:42 PM To: Puram, Yukiko Subject: RE: Inventory corrections Attachments: Scanned Press Vent and Dryer Scrubber Outlet MACT Draft Report for November 2011 with Appendicies.pdf I Page 12 on attached report. Production Rates Below: THC&HAP Production Date/ Rate Run MSF/hr 11/1/2011-1 28.25 11/2/2011-2 25.14 11/2/2011-3 25.14 average 26.18 John Bird Arauco-USA Moncure 0: 919-642-6658 1 C: 843-544-5277 i From: John Bird Sent: Thursday, October 03, 2013 4:18 PM To: 'Puram,Yukiko' i Subject: RE: Inventory corrections Yukiko, There are not enough characters allowed for entirety of response so here are my comments: OS30- Data matches calculations from spreadsheet. OS49-WPP1 VOC calculation is as follows= (VOC as propane)+ methanol+formaldehyde-(0.65*methanol as propane) Source Test units were in Ibs per hour so WPP1 VOC(Ibs/hr)= 1.74 VOC as propane+0.0897 methanol +0.088 formaldehyde-0.65*(0.0411 methanol as propane) = 1.89 WPP1 VOC Ibs/hr Production rate during test was 26.13 MSF/hr. ;1 89/26`:13 0.072 Ibs/MSF(corrected) OS69-This should be based on source specific emission factors,which should result in emission rate of 188.47 tpy for 2012. Spreadsheet was created prior to source test assuming 90%VOC destruction. Actual VOC destruction was—60%. i, OS81- Device did not operate. Device was never constructed only permitted. Please verify the refiners(ES-01) and the board cooler(ES-06B) were not operated in 2012.—ES-01(OS-50) is routed directly through dryers(OS-69) during normal operation so emissions are comingled. When in startup emissions are 1 ANNUAL ACTIVITY AND USAGE INFORMATION Arauco Panels USA LLC-MONCURE,NORTH CAROLINA 2012 PB Plant Production Data 2012 PB Plant Production Data Activity and Usage 2012 Annual Amount Activity and Usage 2012 Annual Amount Description Total Plant Description Without PGT running PRESS AND BAGFILTERS Dryers PB Production 138,364 MSF 3/4"inch PB Production 5 MSF 3/4"inch Wood processed by mill 190,996 BDT Wood processed by mill 6 BDT Operating Hours 7,175 hours ear Operating Hours 0.25 hours ear Wellons BvDass Hog Fuel Combusted in Wellons: 6,848,394 Ibs/ear Wellons Bypass Hours 19.5 hours/year Sanderdust Combusted in Dryers: 31,928,750 Ibs ear Fire Pump Engine Op.Hours 19.5 hours/year Backup Natural Gas Usage in Dryers: 16.92 MMSCF/yr Backu Generator O .Hours 11.8 hours/ear Activity and Usage 2012 Annual Amount Gasoline Tank 2,590.0 allons ear Description With PGT running Total VOC Emissions 37 Ibs PRESS Laminating Press FM PB Production 138,364 MMSF 3/4"inch Operating Hours 4,401 hours ear Wood processed b mill 190.996 BDT Annual Production 23,382 MSF Board Feet O eratin Hours 7,175.00 hours/year Thermal oil heater Natural Gas Usage 0.037 MMSCF/yr 361530 CCF for NG on PB TFM Diesel Usage 0 qaVyr TFL=935260 panels at avg 40 sqft 2012 MDF Plant Production Data Activity and Usage 2012 Annual Amount Description Total Plant Log Processing Line Log Throughput 0.0 tons/year 5049 Op hrs in 2012 Chip Throughput 0 tons/year Bark Throughput 0.0 tons/year New MDF Plant Cyclones and Ba houses MDF Prod m3 Sander Prod m3 Annual press Production: 118,397 MSF 3/4" 74493 MDF and 43904 HDF in 2012 174997.7 165,574 Refiner Abort Cyclone Operation Hours 208 hr/yr 98894.25223 93568.75501 Fiber sifter system filter Operation Hours 6,145 hr Press producttion Hrs Forming Line Clean-Up Filter Operation Hours 6,145 hr Press product ion Hrs Press prod hrs Sander Prod Hrs Mat reject system Filter Operation Hours 686 hr/yr Press producttion Hrs 6145 3897 Saw System Filter Operation Hours 6,145 hr/yr Press producttion Hrs Sander System No.1 Exhaust Filter Operation Hour 3,897 hr/yr total sander production hrs Recycled Fiber Silo No.1 Filter Operation Hours 686.0 hr/ 10%of press production Sander System No.2 Exhaust Filter Operation Houn 3,897 hr/yr total sander production hrs Sander Dust Silo No.1 Filter Operation Hours 1,949 hrlyr total sander production hrs Dry Sawdust Silo Filter Operation Hours 6,145 hr Press producttion Hrs Recycled Fiber Silo No.2 Filter Operation Hours 0.0 hr 2%of press production hrs Sander Dust Silo No.2 Filter Operation Hours 1,949 hrlyr total sander production hrs MDF Press and Dryer Scrubbers Scrubber controlling Press Operation Hours 6,145 hr/yr Press production hrs Teaford Abort Hours: 2,672 hr/yr Annual Press Production: 146,538 ODT/yr Annual Refiner(Dryer)Production: 146,538 ODT/yr Annual Sander Production: 140,641 ODTtyr Annual Sander Production: 112,689 MSF 3/4-1yr Hog Fuel Combusted in Teaford: 170,858,739 lblyr 72436 MMBTU/yr for Teaford Sanderdust Combusted in Teaford: 31,958,076 Iblyr Dryer Scrubber Operation Hours 6,145 hr/yr Converted Percentages Backup natural as-fired dryer burners 23.44 mmsd/yr 55,600.20 31692.114 Backup Natural Gas Burners-Hot Oil 23908.086 #of Burners: 3# Burner Natural Gas Use: 0.06 mmsd/yr NG Usage off PSNC website=http://www.psncenergy.com/en/large-volume- Backu Diesel Generator MDF is meter#2,user id carolynunderwood,pswd=ni8dixri Diesel Use: galtyr Fu itive Emissions: Resin Tanks #Resin Tanks in Operation: 3# Sanderdust burned in Teaford Fugitive Emissions:Ponds and Sprav Fields 165,574 Formaldehyde Emission Rate 0.1167 lb/hr See individual spreadsheet �2—MW.,m. M B-1 ene12D13 Arauco Panels USA LLC 2012 Annual Emissions Invent ry Summary �,Ok 2" p, C,"A-'�" & wony- w ...... enze i"_ Actual kcrolej hum,... A,313d d1'6 4" -VO petal, phyda,.,�Acet phenone n 0 SOURCE NAME SOURCE ID TONSNR TONSNR TONSNR TONSNR TONSNR TONSNR TONSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR LBSNR MDF MILL Log Debarking LDB 0.00E+00 0.00E+00 Chip Handling CPH 0.00E+00 0.00E+00 Bark Handling BKH 0.00E+00 0.00E+00 Backup TOH burners EP-1 8, 19,20 2.11 E-04 2.11 E-04 2.11 E-04 1.67E-05 2.78E-03 2.34E-03 1.53E-04 1.11 E-05 1.1 7E-04 6.12E-05 Refiner Abort Cyclone EP-01 3.66E-01 3.66E-01 3.66E-01 Dryer Outfeed Scrubbers EP-02,EP-04 4.62E+01 4.62E+01 4.62E+01 1.06E+01 1.05E+02 4.83E+01 #REF! 2.67E+02 1.56E+00 2.67E+00 4.21E-01 1.56E+00 1.99E+02 2.20E+00 2.88E-01 1.56E+00 Teaford Bypass NA 1.87E+01 1.67E+01 1.44E+01 8.35E-01 7.35E+00 2.00E+01 5.68E-01 8.15E+00 1.23E-01 2.11E+00 3.33E-02 1.23E-01 1.57E+01 1.74E-01 2.28E-02 1.24E-01 MDF Press EP-16 1.04E+00 1.04E+00 1.04E+00 #REF! 4.14E+01 8.64E+00 Fiber sifter system filter EP-03 1.78E+00 1.78E+00 1.78E+00 6.01 E+00 Forming Line Clean-Up Filter EP-04 1.69E+00 1.69E+00 1.69E+00 6.01 E+00 Mat reject system Filter EP-05 1.65E-01 1.65E-01 1.65E-01 6.71E-01 Saw System Filter EP-07 2.58E+00 2.58E+00 2.58E+00 7.03E-01 Sander System No.I Exhaust Filter EP-08 1.75E+00 1.75E+00 1.75E+00 5.63E-01 Recycled Fiber Silo No.1 Filter EP-09 6.86E-03 6.86E-03 6.86E-03 6.71E-01 Sander System No.2 Exhaust Filter EP-10 8.77E-01 8.77E-01 8.77E-01 5.63E-01 Sander Dust Silo No.1 Filter EP-12 1.95E-02 1.95E-02 1.95E-02 6.87E-01 Dry Sawdust Silo Filter EP-13 6.15E-02 6.15E-02 6.15E-02 1.10E-01- Recycled Fiber Silo No.2 Filter EP-15 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Sander Dust Silo No.2 Filter EP-17 1.95E-02 1.95E-02 1.95E-02 6.87E-01 Backup Generator ES-21 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Resin Tanks-Fugitive MDFR-1,2,3,4 1.31 E-02 Ponds and Spray Field-Fugitives 1.94E-02 PB MILL O.00E+00 O.00E+00 O.00E+00 O.00E+00 O.00E+00 O.00E+00 O.00E+00 Thermal Oil Heater Pr-Heat'l 0.00E+00 0 .00E+00 0.00E+00 0.00E+00 Laminating Press 3593 1.89E+00 1.21 E+00 6.82E-01 7.92E-02 RK MT Seperator 2008 3.82E-02 3.82E-02 3.82E-02 1.42E+01 PB Dryers 1410,-20,-30,3201 3.15E+01 3.15E+01 3.03E+01 2.19E+00 2.01 E+02 4.45E+02 1.88E+02 7.49E+03 2.30E+03 5.60E-02 4.10E+01 2.50E-01 4.25E+00 6.51 E-02 Wellons Bypass 3201 1.23E-01 1.10E-01 1.10E-01 5.48E-03 4.83E-02 1.32E-01 3.73E-03 5.35E-02 1.39E-02 1.86E-04 1.33E-03 1.03E-01 1.14E-03 1.87E-02 2.05E-03 Fines System 3515 1.97E-02 1.97E-02 1.97E-02 5.61 E+01 Wet MAT'L System 3525 1.89E-02 1.89E-02 1.89E-02 8.10E-01 Dryer MAT'L System 3535 1.75E-02 1.75E-02 1.75E-02 7.45E+00 Steinemann Sander 4100 2.54E-02 2.54E-02 2.54E-02 2.89E+00 Sanderdust System 4110 2.29E+00 2.29E+00 2.29E+00 1.12E+00 Board Trim Transfer 3555 1.47E-02 1.47E-02 1.47E-02 2.34E+00 PB Press DEF 4.24E-04 4.24E-04 1.46E-04 4.96E-05 5.00E-06 5.08E-03 6.75E-02 8.20E-03 PB Board Cooler PBBC 1.57E+01 1.57E+01 5.33E+00 1.04E+01 9.82E+00 1-80E+02 4.98E+01 Sanderdust Silo 3575 2.06E+00 2.06E+00 2.06E+00 1.52E+00 Makers 3585 1.13E+01 1.13E+01 1.13E+01 9.13E+00 Fines Transport 3595 1.28E-03 1.28E-03 1.28E-03 5.43E-01 Gas Tank 8100 1.85E-02 1.20E+00 Diesel Fire Pump and Backup Generator ODG,DFP 9.51 E-03 9.51 E-03 3.99E-03 8.89E-03 1.35E-01 2.91 E-02 1.10E-02 4.70E-02 5.67E-03 5.72E-02 2.40E-03 Dry Waste System 3577 6.03E-02 6.03E-02 6.03E-02 2.57E+01 - TOTALS 140.3 137.6 123.2 13.6 313.0 523.8 #REFI 7987.6 1.7 2360.1 0.5 1.7 256.9 2.6 0.3 4.3 0.0 1.8 de minimus Ib/yr Nil 10 100 10 10 0.01 1 1 1 10 1 0.1 Report in AFRO? Yes Yes Yes Yes Yes Yes Yes j _ Yes No Yes No Yes Yes Yes No No No Yes Arauco Panels USA LLC PB Plant Press(DEF-2010)and Board Cooler(PB-BC)Emissions 2012 Press Operation Hrs: 0 Hrs. 2012 Press Production: 5 MSF(0.75")/year Emission Actual Emissions EF Compound Factor Reference Ib/MSF Ibs/hr lbs/vr tpY PM 3.39E+00 1 0.00 2 PM-10 3.39E+00 1 0.00 2 PM-2.5 1.17E+00 0 0.00 2 NOx 3.97E-01 0 0.00 2 VOC as C 2.12E+01 5 0.00 2 VOC as Propane 2.59E+01 6 0.00 2 VOC as VOC 4.06E+01 10 0.01 3 CO 4.00E-02 0 0.00 2 Acetaldehyde 1.40E-02 1.68E-01 0 0.00 2 Acrolein 1.70E-03 1.81 E-02 0 0.00 2 Formaldehyde 2.30E-01 6.47E+00 1 0.00 2 Methanol 5.20E-01 1.65E+01 3 0.00 2 Methyl Ethyl Ketone 9.30E-04 0 0.00 1 Phenol 1.98E-01 0 0.00 2 Pro ionaldeh de 9.90E-03 0 0.00 2 1. NCASI TB 771,Table 6.3.1,January 1999 2. December 21,2065 Stack Testing. Assume PM10=PM,and assume PM2.5=condensible PM. 3. VOC as VOC=VOC as Propane+Formaldehyde+0.5*Methanol Note:press was capped and source emissions taken into the PB dryers and dryer controls on 10/31/11. 2012 Board Cooler Production: 138,364 MSF(0.75")/year Emission Actual Emissions EF Compound Factor I Reference Ib/MSF lbs/yr t PM 2.27E-01 31409 15.70 2 PM-10 2.27E-01 31409 15.70 2,3 PM-2.5 7.70E-02 10654 5.33 2,3 VOC as C 7.20E-02 9962 4.98 1 VOC as Propane 8.80E-02 12176 6.09 Calculated VOC as VOC 1.42E-01 19648 9.82 5 CO 1.50E-01 20755 10.38 2 Acetaldehyde 1.30E-03 180 0.09 4 Acrolein 3.60E-04 50 0.02 4 Formaldehyde 2.70E-02 3736 1.87 4 Methanol 5.40E-02 7472 3.74 4 Methyl Ethyl Ketone 1.10E-04 15 0.01 2 Phenol 4.70E-03 650 0.33 4 1. Emission Factors from TB771,6.4.1,Board Cooler Average Emissions,January 1999 2. AP-42 Wood Products Industry-Particleboard Manufacturing,10.6.2 June 2002. 3. Assume PM10=PM,and assume PM2.5=condensible PM. 4. NCASI SARA 313 Guidance Updated 2011 -Median Values 5. VOC as VOC=VOC as Propane+Formaldehyde+0.5*Methanol Arauco Panels USA LLC PB Plant Particleboard Dryer Emissions(1430,1420,1410,3201) 2 Core Layer Dryers,I Surface Layer Dryer,and 1 Wellons Dryer Production: 138,364 MSF(3/4"inch)/yr PB Board Density: 44.5 Ib/ft' Dryer Production: 173,171 ODT/yr Dryer Operation Hours: 7,175 hr/yr Heating Value of Green Wood: 0.0045 MMBtuAb Hog Fuel and Sanderdust Combustion: 38,777,144 Ib/yr Natural Gas Usage(backup) 16.92 MMSCF/yr Hog Fuel and Sanderdust Combustion: 174,497 MMBtu/yr Natural Gas Heating Value: 1020 Btu/scf Total Dryer Heat Input: 160 MMBtu/hr Natural Gas Usage(backup) 107.9 hours Natural as Wood Natural Gas (backup) WESP Total Total Compound Wood Emission Emission REF Emission Control Combustion Combustion Emissions Emissions Factor Factor Units Emissions Emissions Factor nl Ib/MMscf % Iblyr Iblyr Iblyr Tons/yr PM filterable,total 2.35E+00 Ib/hr 3 1.66E+04 0.00E+00 1.66E+04 8.30E+00 PM condensible,total 6.54E+00 Ib/hr 3 4.62E+04 0.00E+00 4.62E+04 2.31E+01 PM total 8.89E+00 Ib/hr 3 7.6 6.28E+04 1.29E+02 6.30E+04 3.15E+01 PM10 filterable,total 2.35E+00 Ib/hr 3 1.66E+04 0.00E+00 1.66E+04 8.30E+00 PM10 condensible,total 6.54E+00 Ib/hr 3 4.62E+04 0.00E+00 4.62E+04 2.31E+01 PM10 total ("J 8.89E+00 Ib/hr (3) 7.6 6.28E+04 1.29E+02 6.30E+04 3.15E+01 PM2.5 filterable,total 2.02E+00 Ib/hr 3, 13 1.43E+04 0.00E+00 1.43E+04 7.14E+00 PM2.5 condensible,total 6.54E+00 Ib/hr 3 4.62E+04 0.00E+00 4.62E+04 2.31E+01 PM2.5 total 8.56E+00 Ib/hr 3, 13 6.05E+04 0.00E+00 6.05E+04 3.03E+01 VOC as C csl 4.03E+01 Ib/hr 3 2.85E+05 O.00E+00 2.85E+05 1.42E+02 VOC as propane 4.93E+01 Ib/hr Calculated 3.48E+05 0.00E+00 3.48E+05 1.74E+02 VOC as VOC t'I 5.31 E+01 Ib/hr 2,3 5.5 3.75E+05 9.31 E+01 3.75E+05 1.88E+02 WPP1 VOC 5.37E+01 Ib/hr 12 3.80E+05 0.00E+00 3.80E+05 1.90E+02 NOx 5.67E+01 Ib/hr 3 50 4.01E+05 8.46E+02 4.02E+05 2.01E+02 CO 1.26E+02 Ib/hr 3 84 8.88E+05 1.42E+03 8.90E+05 4.45E+02 Sox 2.50E-02 Ib/MMBtu 7 0.6 4.36E+03 1.02E+01 4.37E+03 2.19E+00 Acetaldeh de 1.06E+00 Ib/hr 2 7.49E+03 0.00E+00 7.49E+03 3.75E+00 Acetone 1.62E-04 Ib/MMBtu 4 2.83E+01 0.00E+00 2.83E+01 1.41E-02 Acetone as propane 1.97E-02 Ib/hr 11 1.39E+02 O.00E+00 1.39E+02 6.95E-02 Acrolein 3.25E-01 Ib/hr 2 2.30E+03 0.00E+00 2.30E+03 V 1.15E+00 Arsenic 3.21E-07 Ib/MMBtu 5 5.60E-02 0.00E+00 5.60E-02 2.80E-05 Benzene 2.35E-04 Ib/MMBtu 4 2.10E-03 4.10E+01 3.55E-02 4.10E+01 2.05E-02 Benzo a)pyrene 2.60E-06 Ib/MMBtu 7 1.20E-06 45% 2.50E-01 1.12E-05 2.50E-01 1.25E-04 Bromine 2.44E-05 Ib/MMBtu 7 4.25E+00 O.ODE+00 4.25E+00 2.13E-03 Cadmium 3.73E-07 Ib/MMBtu 5 6.51E-02 O.00E+00 6.51E-02 3.25E-05 Chlorine 7.90E-04 Ib/MMBtu 7 1.38E+02 O.ODE+00 1.38E+02 6.89E-02 Chloroform 2.80E-05 Ib/MMBtu 7 4.89E+00 0.00E+00 4.89E+00 I 2.44E-03 Chromium 8.04E-07 Ib/MMBtu 5 1.40E-01 0.00E+00 1.40E-01 7.01E-05 Chromium VI 2.72E-07 Ib/MMBtu 5 4.75E-02 0.00E+00 4.75E-02 2.37E-05 Cobalt 4.68E-07 Ib/MMBtu 5 8.40E-05 8.17E-02 1.42E-03 8.31E-02 4.15E-05 Formaldehyde 2.24E+00 Ib/hr 2 7.50E-02 1.58E+04 1.27E+00 1.58E+04 il 7.92E+00 HCI 1.57E-03 Ib/MMBtu 4 2.74E+02 O.00E+00 2.74E+02 1.37E-01 Lead 4.95E-06 Ib/MMBtu 5 8.64E-01 I 0.00E+00 8.64E-01 4.32E-04 Manganese 3.50E-05 Ib/MMBtu 5 6.11E+00 0.00E+00 6.11E+00 3.05E-03 Methanol 3.17E+00 Ib/hr 2 2.24E+04 0.00E+00 2.24E+04 v 1.12E+01 Methanol as propane 1.45E+00 Ib/hr 11 1.03E+04 0.00E+00 1.03E+04 5.13E+00 M E K 9.60E-03 Ib/ODT 6 1.66E+03 0.00E+00 1.66E+03 8.31E-01 Mercury 4.02E-07 Ib/MMBtu 5 7.01E-02 0.00E+00 7.01E-02 3.51E-05 MIRK 1.40E-03 Ib/ODT 6 2.42E+02 O.o0E+00 2.42E+02` 1.21E-01 Methvlene Chloride 3.50E-04 Ib/MMBtu 4 6.11E+01 0.00E+00 6.11E+01 3.05E-02 n-Hexane 2.88E-04 Ib/MMBtu 4 1.80E+00 5.03E+01 3.05E+01 8.07E+01 4.04E-02 Naphthalene 7.44E-05 Ib/MMBtu 4 6.10E-04 45% 7.14E+00 5.68E-03 7.15E+00 3.57E-03 Nickel 3.45E-06 Ib/MMBtu 5 6.02E-01 O.00E+00 6.02E-01 3.01E-04 Phenol 2.38E-01 Ib/hr 2 1.68E+03 0.00E+00 1.66E+03 8.41E-01 POM 1.74E-04 Ib/MMBtu 7 3.03E+01 0.00E+00 3.03E+01 1.52E-02 Pro anal 3.20E-06 Ib/MMBtu 7 5.58E-01 O.00E+00 5.58E-01 2.79E-04 Pro ionaldeh de 9.30E-02 Ib/hr 2 6.57E+02 0.00E+00 6.57E+02 3.29E-01 Selenium 5.11E-07 Ib/MMBtu 5 2.40E-05 8.92E-02 4.06E-04 8.96E-02 4.48E-05 St rene 6.30E-05 Ib/MMBtu 4 1.10E+01 0.00E+00 1.10E+01 5.50E-03 Toluene 2.34E-05 j b1L 1 u 4 3.40E-03 4.08E+00 5.75E-02 4.14E+00 2.07E-03 X ene 5.22E-06 Ib/MMBtu 4 9.11E-01 0.00E+00 9.11E01 4.55E-04 1.Emission factors based on AP-42,Fifth Edition,Chapter 1,Section 4.Taken from DAO spreadsheet online.July 1998 2.Emission factors from RTO inlet stack testing 12/2005 3.Emission factors from Stack testing 1012009.Assumed condensible PM2.5=condensible PM10 4.Emission Factors from NCASI TB 973,Table 7.1-Uncontrolled,February 2010 5.Emission Factors from NCASI TB 973,Table 7.2-Control:ESP,February 2010 6.Emission Factors from TB 771,Table 6.2.1 Southern Pine Furnish(Dry)Average Emissions,January 1999 7.AP-42 1.6 Wood Residue Combustion,September 2003 8.VOC emission factor.VOC as C from 2009 Method 25A test 9.VOC as VOC(wood firing)=VOC as propane+Formaldehyde as Formaldehyde+0.5•Methanol as Methanol 10.All PM after WET ESP assumed to be PM10. 11.Acetone as propane and methanol as propane calculated and used for the WPPI.VOC calculation purposes only. 12.WPP1 VOC=VOC as propane+methanol+formaldehyde-0.65•methanol as propane-0.65•acetone as propane 13. PM2.5 was not measured in the 2009 test We have applied the ratio of 0.86 PM2.51PM10 from AP-42 Section 1.6,Table 1.6-1 to the tested filterable PM10 value. Arauco Panels USA LLC PB Plant Wellons Bypass Emissions 40 MMBtu/hr 8,000 Btulib dry basis Calculated Firing Rate: .5 Wellons Bypass Hours: 19 hr/yr.5 hr/yr Heating Value of Green Wood: 0.0045 MMBtuAb 'n "it Bypass Wood Combustion: 438.75 MMBtu/yr Emission Emission Factor Actual Emission EF ` O�L ` 6� V Compound Factor Ib/ Units Reference / J (r �q I PM 5.60E-01 � E-01 Ib/MMBtu 2.4 Ibsl r t �� 6E+02 1.23E-01 (3) ;^ v PM-10 5.00E-01 Ib/MMBtu 2.19E+02 1.10E-01 (3) PM-2.5 4.30E-01 Ib/MMBtu 1.89E+02 9.43E-02 (3) VOC 1.70E-02 Ib/MMBtu 7.46E+00 3.73E-03 (3) \ NOx 2.20E-01 Ib/MMBtu 9.65E+01 4.83E-02 (3) ix ✓ Sox 2.50E-02 Ib/MMBtu 1.10E+01 5.48E-03 (3) CO 6.00E-01 Ib/MMBtu 2.63E+02 1.32E-01 3 Acetaldehyde 1.22E-04 Ib/MMBtu 5.35E-02 2.68E-05 (1) Acrolein 3.16E-05 Ib/MMBtu 1.39E-02 6.93E-06 (1) Antimony 4.23E-07 Ib/MMBtu 1.86E-04 9.28E-08 (4) Arsenic 3.02E-06 Ib/MMBtu 1.33E-03 6.63E-07 (2) Benzene 2.35E-04 tMMBtu 1.03E-01 5.16E-05 (1) Benzo(a)pyrene 2.60E-06 Ib/MMBtu 1.14E-03 5.70E-07 (3) Beryllium 4.27E-05 Ib/MMBtu 1.87E-02 9.37E-06 (2) Cadmium 4.67E-06 Ib/MMBtu 2.05E-03 1.02E-06 (2) Chlorine 7.90E-04 Ib/MMBtu 3.47E-01 1.73E-04 (3) Chlorobenze 1.66E-05 Ib/MMBtu 7.28E-03 3.64E-06 (1) Chloroform 3.52E-05 Ib/MMBtu 1.54E-02 7.72E-06 (1) Chromium 3.46E-05 Ib/MMBtu 1.52E-02 7.59E-06 (2) Chromium VI 6.97E-06 Ib/MMBtu 3.06E-03 1.53E-06 (2) Cobalt 1.96E-05 Ib/MMBtu 8.60E-03 4.30E-06 (2) Ethylbenzene 1.76E-05 Ib/MMBtu 7.72E-03 3.86E-06 (1) Formaldehyde 8.83E-04 Ib/MMBtu 3.87E-01 1.94E-04 (1) HCl 1.57E-03 Ib/MMBtu 6.89E-01 3.44E-04 (1) Lead 1.77E-05 Ib/MMBtu 7.77E-03 3.88E-06 (2) Manganese 1.81E-03 Ib/MMBtu 7.94E-01 3.97E-04 (2) MEK 5.39E-06 Ib/MMStu 2.36E-03 1.18E-06 (1) Mercury 5.00E-07 Ib/MMBtu 2.19E-04 1.10E-07 (2) Naphthalene 7.44E-05 Ib/MMBtu 3.26E-02 1.63E-05 (1) Nickel 2.26E-05 Ib/MMBtu 9.92E-03 4.96E-06 (2) Phenol 1.98E-05 Ib/MMBtu 8.69E-03 4.34E-06 (1) POM 1.06E-04 Ib/MMBtu 4.64E-02 2.32E-05 (1),(3) Selenium 2.53E-06 Ib/MMBtu 1.11E-03 5.55E-07 (2) Trichlorolluoromethane 4.05E-05 Ib/MMBtu 1.78E-02 8.88E-06 (1) Styrene 6.30E-05 Ib/MMBtu 2.76E-02 1.38E-05 (1) Toluene 2.34E-05 Ib/MMBtu 1.03E-02 5.13E-06 (1) X lene 5.22E-06 Ib/MMBtu 2.29E-03 1.15E-06 1 1.NCASI TB 973,Table 7.1-Uncontrolled,February 2010 2.NCASI TB 973,Table 7.2-Control:Mechanical Collector,February 2010 3.AP-42 Section 1.6-wood residue combustion in boilers. 4.NCASI TB 973,Table 7.2-Control:Fabric Filter,February 2010 Wellons contributes 24 MMBtu/hr to Core Layer Dryer(74 MMBtu/hr total,normal operation) and contributes 16 MMBtu/hr to Surface Layer Dryer(56 MMBtu/hr total,normal operation) Beginning July 2007 exhaust from this source goes through the PB dryers and Wet ESP.However,during startup,the exhaust is bypassed to atmosphere As designed,this bypass occurs for 0.25-0.5 hour prior to dryers being started. The emissions are counted in the dryers exhaust except startup. Startup emissions are accounted for in this calculation. Arauco Panels USA LLC PB Plant Fire Pump Engine and Backup Generator Emissions Fire Pump Engine: Backup Generator: Fire Pump Engine Hrs of Operation: 19.5 hrs/yr Backup Generator Hrs of Operation: 11.8 hrs/yr Fire Pump MMBtu/yr 47.4 MMBtu/yr Generator MMBtu/yr 14.0 MMBtu/yr Capacity: 347 hp-out`7000 Btu-in/hp-hr 2.429 MMBtu/hr Capacity:465 hp-out"2544.434 Btu-in/hp-hr 1.183 MMBtu/hr 2,429,000 Btu/hr"gal/141,000 Btu 17.2 gal/hr 1,183,161.81 Btu/hr'gal/141,000 Btu 8.39 gal/hr Fire Pump Engine Generator Compound Emission Factor') Actual Emissions Compound Emission Factor(') E4�..33E+00 Emissions Ib/MMBtu Ib/ r t Ib/MMBtu tp PM 3.10E-01 1.47E+01 7.34E-03 PM 3.10E-01 2.16E-03 PM10 3.10E-01 1.47E+01 7.34E-03 PM10 3.10E-01 2.16E-03 PM2.5 1.30E-01 6.17E+00 3.08E-03 PM2.5 1.30E-01 1.82E+00 9.09E-04 SO2 2.90E-01 1.37E+01 6.87E-03 SO2 2.90E-01 4.05E+00 2.02E-03 NOx 4.41 E+00 2.09E+02 1.04E-01 NOx 4.41 E+00 6.16E+01 3.08E-02 VOC 3.60E-01 1.71E+01 8.53E-03 VOC 3.60E-01 5.03E+00 2.51 E-03 CO 9.50E-01 4.50E+01 2.25E-02 CO 9.50E-01 1.33E+01 6.63E-03 Acetaldehyde 7.67E-04 3.63E-02 1.82E-05 Acetaldehyde 7.67E-04 1.07E-02 5.35E-06 Acrolein 9.25E-05 4.38E-03 2.19E-06 Acrolein 9.25E-05 1.29E-03 6.46E-07 Benzene 9.33E-04 4.42E-02 2.21 E-05 Benzene 9.33E-04 1.30E-02 6.51 E-06 Butadiene- 1,3 3.91 E-05 1.85E-03 9.26E-07 Butadiene- 1,3 3.91 E-05 5.46E-04 2.73E-07 Formaldehyde 1.18E-03 5.59E-02 2.79E-05 Formaldehyde 1.18E-03 1.65E-02 8.24E-06 Na thalene 8.48E-05 4.02E-03 2.01 E-06 Na thalene 8.48E-05 1.18E-03 5.92E-07 POM 8.32E-05 3.94E-03 I 1.97E-06 POM 8.32E-05 1.16E-03 5.81 E-07 Toluene 4.09E-04 1.94E-02 9.69E-06 Toluene 4.09E-04 5.71 E-03 2.86E-06 X lene 2.85E-04 1.35E-02 6.75E-06 X lene 2.85E-04 3.98E-03 1.99E-06 1.AP-42,Table 3.3-1 and 3.3-2,October 1996. PM2.5 is assumed to be 42%of PM per AP-42 Table 1.3-7 Diesel Heating Value: 0.141 MMBtu/gal x -- Arauco Panels USA LLC PB Plant Gasoline Tank Emissions(l) Total VOC Emissions(2), Ibs: 37 Total VOC Emissions(2), tons: 0.02 2012 Throughput, Gallons: 2,590 Actual Hours of Operation 2012: 8760 Compound (3) Vapor Weight Emissions Percent Ibs/ r tpY Benzene 3.25% 1.20 6.01 E-04 Chlorobenzene 0.03% 0.01 5.55E-06 Cumene 0.33% 0.12 6.11 E-05 Ethyl benzene 4.07% 1.51 7.53E-04 Hexane, n- 3.91% 1.45 7.23E-04 Naphthalene 0.80% 0.30 1.48E-04 Styrene 0.17% 0.06 3.15E-05 Toluene 15.22% 5.63 2.82E-03 Trimethyl pentane 0.68% 0.25 1.26E-04 X lenes 21.69% 1 8.03 1 4.01 E-03 Total 18.56 9.28E-03 Notes: (1) RVP-10 gasoline 270 gallon, outside, above-ground tank, painted white put into service mid-2003 (2) Emissions estimated by EPA Tanks Program, V.4.09d (3) EPA SPECIATE database in AIRCHIEF, Oct. 1993. Arauco Panels USA LLC PB Plant Baghouse Emissions PB Plant Production: 190,996 Actual Test Actual PM10 Actual PM10 Source Source Process Annual n Factor /PM2.5 /PM2.5 ID No. Material Operatin� t�I Emissions Emissions Hours n Ib/yr 191 ton/yr(9) Rock-Metal Separator 3501 green sawdust 7,175 )4 76.3 0.04 Fines Transport 3515 dry sawdust 7,175 )4 39.3 0.02 Wet Transport 3525 green wood 7,175 )3 37.8 0.02 Dry Material Transport 3535 dry wood waste 7,175 )3 34.9 0.02 Steinemann Sander 3545 dry sanderdust 7,175 )3 50.8 0.03 PB Sanderdust Transport 35654 dry sanderdust 7,175 )l 4,577 2.29 Board Trim Transfer 3555 dry sawdust 7,175 )4 29.4 0.01 Sanderdust Silo 3575 dry sanderdust 7,175 )1 7 4,126 2.06 Rakers 3585 dry flakes 7,175 )1 8 22 8 11.27 rl v Fines Transport 3595 dry sawdust 7,175 )4 6 -0.00 Dry Material Transport 3577 dry wood waste 7,175 )3 120.6 0.06 These 2 source ID numbers need to switch,a 1) Emission factors based on oven-dried(OD)process material rates �� � Amount of material processed thru each unit bagfifter is calculated based on%of 2) VOC as VOC calculated using converted VOC-carbon equivalent emissions me. 3) Weyco-Moncure emission tests in April 1994 and April 1995 4)Total VOC as VOC calculated using converted VOC-carbon equivalent emissions emissions. Formaldehyde emissions are added directly to VOC-as VOC value 5) No emission test conducted. 6) Emission factor based on engineering judgement for a similiar source. 7) Emission factor based on control equipment manufacturer efficiency guarantee fo 8) Emission factor based on control equipment manufacturer efficiency guarantee fo 9) PM is assumed to equal PM-10 and PM-2.5 Amount of material processed thru each unit bagfifter is calculated based on%of Arauco Panels USA LLC PB Plant Short Cycle Laminating Press Emissions 2011 Actual 2011 Actual Annual Annual Actual Actual Actual Actual VOC HCHO Annual Annual PM Process Annual Annual VOC VOC Annual PM Annual PM Source ID No. Material Operating Production Emissions Emissions Emissions Emissions HCHO Total VOC Emissions Emissions Emissions Hours (MSF) Ib/hr(1) Ib/yr ton/yr lblhr(2) Emissions Emissions Ib/hr Ib/yr tonlyr Ib/yr Iblyr(3) Short Cycle W" Paper 41401 23,382 0.016 70.416 0.035 0.02 88.0 158.44 0.86 3784.86 1.89 LaminatingPresses 3W Tnmmi s i++. PM-10 PM-10 PM-10 PM-2.5 PM-2.5 PM-2.5 Emissions Emissions Emissions Emissions Emissions Emissions Iblhr Ib/yr ton/yr Ib/hr Ib/yr ton/yr �s r 0.55 2420.55 1.21 0.31 1364.31 0.68 1)Emission estimates from a similar source. The similar press is 9MM m2/yr,whereas Uniboard's press has a design of approximately 17.6 MM m21yr,therefore, emission factors from similar source are multiplied by 1.95313 2)Emission estimates from a similar source 3)Total VOC as VOC calculated using converted VOC-carbon equivalent emissions from the sum of Method 25A emissions and formaldehyde emissions. Formaldehyde emissions are added directly to VOC as VOC value,therefore values in table include formaldehyde. The two presses are identical and have identical emissions. Arauco Panels USA LLC PB Plant Laiminator Thermal Oil Heater(Pr-Heatl)-Natural Gas Fired or No.2 Fuel Oil Diesel Usage: 0 gal/yr Compound Factor(') Emissions Ib/M al Ibs/ r tons/year Filterable PM(FPM) 2.00E+00 0.00E+00- 0.00E+00 Condensible PM(CPM) 1.30E+00 0.00E+00 0.00E+00 Total Particulate Matter PM FPM+CPM 3.30E+00 0.00E+00 0.00E+00 Filterable PM<10 Microns(PM10) 1.00E+00 0.00E+00 0.00E+00 Total PM10 2.30E+00 0.00E+00 0.00E+00 Filterable PM<2.5 Microns TWO 2.50E-01 . 0.00E+00 0.00E+00 Total PM2.5 1.55E+00 0.00E+00 0.00E+00 Sulfur Dioxide S02 7.10E+01 0.00E+00 0.00E+00 Nitrogen Oxides NOx 2.00E+01 0.00E+00 0.00E+00 Carbon Monoxide CO 5.00E+00 0.00E+00 0.00E+00 Volatile Organic Compounds VOC 2.00E-01 0.00E+00 0.00E+00 Arsenic&compounds 5.60E-04 0.00E+00 0.00E+00 Benzene 2.75E-03 0.00E+00 0.00E+00 Beryllium&compounds 4.20E-04 0.00E+00 0.00E+00 Cadmium&compounds 4.20E-04 0.00E+00 0.00E+00 Chromium-All/Total 4.20E-04 0.00E+00 0.00E+00 Eth (benzene 8.17E-04 0.00E+00 0.00E+00 Fluorides sum fluoride compounds) 3.73E-02 0.00E+00 0.00E+00 Formaldehyde 4.80E-02 0.00E+00 0.00E+00 Lead and Lead compounds 1.26E-03 0.00E+00 0.00E+00 Manganese&compounds 8.40E-04 0.00E+00 0.00E+00 Mercury&compounds 4.20E-04 0.00E+00 0.00E+00 Methyl chloroform 2.36E-04 0.00E+00 0.00E+00 Naphthalene 3.33E-04 0.00E+00 0.00E+00 Nickel&compounds 4.20E-04 0.00E+00 0.00E+00 POM rates uncontrolled 3.30E-03 0.00E+00 0.00E+00 Selenium compounds 2.10E-03 0.00E+00 0.00E+00 Toluene 7.97E-02 0.00E+00 0.00E+00 X lene 1.40E-03 0.00E+00 I 0.00E+00 1. Emission factors from NC DAQ's fuel oil spreadsheet-based on AP-42,5th edition,Section 1.3. *Only fired No.2 Oil in 2010 Natural Gas Usage 0.037 MMSCF/ r Compound Emission Factor Reference Emission Emissions s1b/ r It T,,FWNQtaut r 1 fhiftatfc� NOx 5.00E+01 Ib/mmscf 2 1.84E+00 9.22E-04 CO 8.40E+01 Ib/mmscf 2 3.10E+00 1.55E-03 PM/PM10/PM2.5 7.60E+00 Ib/mmscf 2 2.80E-01 1.40E-04 S02 6.00E-01 Ib/mmscf 2 2.21 E-02 1.11 E-05 VOC 5.50E+00 Ib/mmscf 2 2.03E-01 1.01 E-04 Benzene 71-43-2 TH 2.10E-03 Ib/mmscf 2 7.74E-05 3.87E-08 Benzo a rene 50-32-8 T 1.20E-06 Ib/mmscf 2 4.43E-08 2.21 E-11 Cobalt compounds H 8.40E-05 Ib/mmscf 2 3.10E-06 1.55E-09 Formaldehyde 50-00-0 TH 7.50E-02 Ib/mmscf 2 2.77E-03 1.38E-06 Hexane 1.80E+00 Ib/mmscf 2 6.64E-02 3.32E-05 Naphthalene 91-20-3 H 6.10E-04 Ib/mmscf 2 2.25E-05 1.12E-08 Selenium compounds H 2.40E-05 Ib/mmscf 2 8.85E-07 4.43E-10 Toluene 108-88-3 TH 3.40E-03 Ib/mmscf 2 1.25E-04 6.27E-08 2. Emission factors based on AP-42, Fifth Edition,Chapter 1,Section 4.Taken from DAQ spreadsheet online.Jul,. t Arauco Panels USA LLC Ponds 2-5 and Spray Field Fugitives Ponds 2-5 Fugitives Spray and Pond Concentration: 0.2 mg/L Total Pond Capacity: 2,879,000 gal/yr Fugitive Fugitive Compound Emission Factor ;Emissions, lbl Emissions,tpyt'�1ns n S r ;Fie[tf _ bOC 0.2 1 m /L 4.8 2.40E-03 Formal deh de 50-00-0 TH 0.2 1 mg/L 4.8 2.40E-03 1.Concentration from 2011 Formaldehyde test.Using half of detection limit since concentration was below the detection limit of 0.4 mg/L. Spray Field Fugitives Spray and Pond Concentration: 0.2 mg/L Permitted Effluent Limit: 56,000 gal/day(monthly average) Fugitive Fugitive Compound Emission Factor Emissions, Ib/ Emissions,tp VOC 0.2 mg/L 34.0 1.70E-02 Formaldehyde 50-00-0 TH 0.2 mg/L 34.0 1.70E-02 1.Concentration from 2011 Formaldehyde test.Using half of detection limit since concentration was below the detection limit of 0.4 mg/L. Arauco Panels USA LLC MDF Plant Dryer Scrubbers Emissions Emission Description Dis,char a Rate O eratin Hours O Point NM/Hr SCFM Hrs/Yr EP-02 Dryer Outfeed Scrubber No.1 116,000 44 73,5 6,145 EP-14 Dryer Outfeed Scrubber No.2 4 NA Energy Plant Outlet 140,000 88,760 Annual Press Production: 118,397 MSF 3/4" ,g-U Annual Press Production: 146,538 ODT/yr Hog Fuel and Sanderdust combused in Teaford: 202,816,815 Ib/yr - Green Wood Heating Value: 0.0045 MMBtu/lb Hog Fuel and Sanderdust combused in Teaford: 912,676 MMBtu/yr Total Firing Rate in Abort: 66,800 MMBtu/yr Teaford Firing Rate excluding Abort: 845,876 MMBtu/yr Energy system wood firing rate: 205 MMBtu/hr Energy System Natural Gas Use: 23.44 mmscf/yr PM/metals control efficiency: 85% Soluble VOC control efficiency: 90% Compound Emission Factor Reference Emissions, Emissions, Ibl r t (� PM from Combined Scrubber Outlet 630E 01 Ib/ODT 12 92,319 46.16 PM10 assumes PM10=98°%PM 6.30E 01 Ib/0DT 12 ff208,193 46.16 /•/ [ PM2.5 assumes PM2.5=PM10 6.30E-01 Ib/ODT 12 CO-at energyplant outlet flow 5.00E+01 m /Nm3 1 2 NOx-at energyplant outlet flow 1.10E+02 m /Nm3 1 0 2 Compound Uncontrolled Emission Reference Emissions, Ewdiswi6ins, Factor Ib/ r tovp WPPt VOC 2.57E+00 Ib/ODT 12 37,660 Methanol as propane 2.09E-01 Ib/ODT Calculated 3,056 Acetone not a VOC,HAP,or TAP 2.50E-02 Ib/ODT 6 366A33 L Acetone as propane 1.90E-02 Ib/ODT Calculated 278 Formaldehyde 50-00-0 TH 1.65E+00 Ib/ODT 6 24 17 Acetaldeh de 75-07-0 TH 1.75E-02 Ib/ODT 6 25-6Methanol 67-56-1 H 4.55E-01Ib/CDT 6 6673 Phenol 108-95-2 TH 8.60E-03 Ib/ODT 6 126M! X V Uncontrolled Emission Emissions, Emissions, Compound Factor Reference lb/ r t VOC as VOC 9.44E-01 Ib/ODT 9 0 0.00 WPP1 VOC 1.10E+00 Ib/ODT 10 0 0.00 VOC as C 9.40E-01 Ib/ODT 8 0 0.00 VOC as propane 1.10E+00 Ib/ODT 8 0 0.00 Acetone not a VOC,HAP,or TAP 6.40E-03 Ib/ODT 8 0 0.00 Acetone as propane 4.86E-03 Ib/ODT Calculated 0 0.00 Methanol 67-56-1 H 7.30E-03 Ib/ODT 8 0 0.00 Methanol as propane 3.35E-03 Ib/ODT I Calculated 1 0 0.00 Phenol 108-95-2 TH 4.50E-03 Ib/ODT 8 0 0.00 Compound Uncontrolled Emission Reference Emissions, Emissions, Factor lb/ r t WPP1 VOC 1.49E-01 Ib/MSF 10 0 0.00 VOC as VOC 1.32E-01 lb/MSF 9 0 0.00 VOC as C 7.70E-02 Ib/MSF 2 0 0.00 VOC as propane 9.41E-02 Ib/MSF Calculated 0 0.00 Acetone 9.20E-03 Ib/MSF 2 0 0.00 Acetone as propane 6.98E-03 Ib/MSF Calculated 0 0.00 Acetaldehyde 75-07-0 TH 1.00E-03 Ib/MSF 2 0.00 0.00 Acrolein 107-02-8 TH 2.20E-04 Ib/MSF 2 0.00 0.00 Formaldehyde 50-00-0 TH 4.20E-02 Ib/MSF 2 0.0 0.00 Methanol 67-56-1 H 2.50E-02 Ib/MSF 2 0.0 0.00 Methanol as propane 1 1.15E-02 Ib/MSF Calculated 0.0 0.00 Exhaust from the Refiners is routed through the dryers. •Exhaust from the board cooler may be used as combustion air for the heat energy system or may be routed directly to the dryers. *Emissions are presented here for routing to dryers(higher than routing to energy system). Arauco Panels USA LLC MDF Plant Dryer Scrubbers Emissions Uncontrolled Emission Expected Emissions, Emissions, Compound Factor Reference Scrubber Ib/yr tpy SO2 2.50E-02 Ib/MMBtu 5 0 2.11E+04 1.06E+01 VOC 1.70E-02 Ib/MMBtu 5 below Acetaldehyde 75-07-0 TH 1.22E-04 Ib/MMBtu 3 0.9 1.03E+01 5.16E-03 Aceto henone 98-86-2 H 1.84E-06 Ib/MMBtu 3 0 1.56E+00 7.78E-04 Acrolein 107-02-8 TH 3.16E-05 Ib/MMBtu 3 0.9 2.67E+00 1.34E-03 Antimon &Compounds H 4.98E-07 Ib/MMBtu 4 0 4.21 E-01 2.11E-04 Arsenic&Compounds TH 1.84E-06 Ib/MMBtu 4 0 1.56E+00 7.78E-04 Benzene 71-43-2 TH 2.35E-04 Ib/MMBtu 3 0 1.99E+02 9.94E-02 Benz a ene 50-32-8 T 2.60E-06 IWMMBtu 5 0 2.20E+00 1.10E-03 Beryllium T/H 3.41E-07 Ib/MMBtu 4 0 2.88E-01 1.44E-04 Cadmium T/H 1.85E-06 Ib/MMBtu 4 0 1.56E+00 7.82E-04 Carbon tetrachloride 56-23-5 TH 1.26E-05 Ib/MMBtu 3 0 1.07E+01 5.33E-03 Chlorine 7782-50-5TH 7.90E-04 Ib/MMBtu 5 0.85 1.00E+02 X 5.01E-02 Chlorobenzene 108-90-7 TH 1.66E-05 Ib/MMBtu 3 0 1.40E+01 7.02E-03 Chloroform 67-66-3 TH 3.52E-05 Ib/MMBtu 3 0 2.98E+01 1.49E-02 Chromium H 5.06E-06 Ib/MMBtu 4 0 4.28E+00 2.14E-03 Chromium VI T/H 2.35E-07 Ib/MMBtu 4 0 1.99E-01 9.94E-05 Cobalt compounds H 1.97E-07 Ib/MMBtu 4 0 1.67E-01 8.33E-05 Dinitro henol,2,4- 51-28-5 H 1.30E-07 Ib/MMBtu 3 0 1.10E-01 5.50E-05 DEHP 117-81-7 TH 4.70E-08 Ib/MMBtu 5 0 3.98E-02 1.99E-05 Ethyl benzene 100-41-4 H 1.76E-05 Ib/MMBtu 3 0 1.49E+01 7.44E-03 Ethylene dichloride 107-06-2 TH 2.90E-05 Ib/MMBtu 5 0 2.45E+01 1.23E-02 Formaldehyde 50-00-0 TH 8.83E-04 Ib/MMBtu 3 below 1,2,3,6,7,8-HCDD T 1.60E-06 Ib/MMBtu 5 0 1.35E+00 6.77E-04 Hydroqen chloride 7647-01-0 TH 1.57E-03 Ib/MMBtu 3 0.85 1.99E+02 9.96E-02 Lead and Lead compounds H 1.66E-05 Ib/MMBtu 4 0 1.40E+01 7.02E-03 Manganese&compounds TH 2.62E-05 Ib/MMBtu 4 0 2.22E+01 1.11 E-02 Mercury T/H 6.61E-07 Ib/MMBtu 4 0 5.59E-01 2.80E-04 Methanol 4.87E-04 Ib/MMBtu 3 0.9 4.12E+01 2.06E-02 Methyl bromide 74-83-9 H bromomethane 1.52E-05 Ib/MMBtu 3 0 1.29E+01 6.43E-03 Methyl chloride 74-87-3 H chloromethane 2.31E-05 Ib/MMBtu 3 0 1.95E+01 9.77E-03 Methyl chloroform 71-55-6 TH 3.10E-05 Ib/MMBtu 5 0 2.62E+01 1.31E-02 Methyl ethyl ketone 78-93-3 T 5.39E-06 Ib/MMBtu 3 0.9 4.56E-01 2.28E-04 Methylene chloride 75-09-2 TH 3.50E-04 Ib/MMBtu 3 0 2.96E+02 1.48E-01 Naphthalene 91-20-3 H 7.44E-05 Ib/MMBtu 3 0 6.29E+01 3.15E-02 Nickel T/H 3.94E-06 Ib/MMBtu 4 0 3.33E+00 1.67E-03 Nitro phenol,4- 100-02-7 H 9.32E-08 Ib/MMBtu 3 0 7.88E-02 3.94E-05 Pentachloro henol 87-86-5 TH 4.48E-08 Ib/MMBtu 3 0 3.79E-02 1.89E-05 Perchloroeth ene 127-18-4 TH 3.80E-05 Ib/MMBtu 5 0 3.21E+01 1.61E-02 Phenol 108-95-2 TH 1.98E-05 Ib/MMBtu 3 0.9 1.67E+00 8.37E-04 Phosphorus 7723-14-0 H 9.85E-05 Ib/MMBtu 4 0 8.33E+01 4.17E-02 Polychlorinated bi hens 1336-36-3 TH 8.15E-09 Ib/MMBtu 5 0 6.89E-03 3.45E-06 Pol c clic Organic Matter H 1.25E-04 Ib/MMBtu 5 0 1.06E+02 5.29E-02 Pro ionaldeh de 123-38-6 H 3.21E-05 Ib/MMBtu 3 0.9 2.72E+00 1.36E-03 Propylene dichloride 78-87-5 H 3.30E-05 Ib/MMBtu 5 0 2.79E+01 1.40E-02 Selenium compounds H 1.85E-06 IWMMBtu 4 0 1.56E+00 7.82E-04 Styrene 100-42-5 TH 6.30E-05 Ib/MMBtu 3 0 5.33E+01 2.66E-02 2,3,7,8-TCDD 1746-01-6 TH 8.60E-12 Ib/MMBtu 5 0 7.27E-06 3.64E-09 Toluene 108-88-3 TH 2.34E-05 Ib/MMBtu 3 0 1.98E+01 9.90E-03 Trichloroeth ene 79-01-6 TH 1.94E-05 Ib/MMBtu 3 0 1.64E+01 8.20E-03 Trichlorofluoromethane 75-69-4T 4.05E-05 Ib/MMBtu 3 0 3.43E+01 1.71E-02 Trichloro henol,2,4,6- 88-06-2 H 2.73E-07 Ib/MMBtu 3 0 2.31E-01 1.15E-04 Vinyl chloride 75-01-4 TH 1.84E-05 Ib/MMBtu 3 0 1.56E+01 7.78E-03 Xylene 1330-20-7TH 5.22E-06 Ib/MMBtu 3 0 4.42E+00 2.21E-03 'Wood is burned in the energy plant and the hot exhaust is routed to the dryers. Natural gas may be burned as auxiliary/startup/standby fuel. Dryer exhaust is routed to 2 wet scrubbers in parallel. Compound Emission Factor Reference Emissions, Emissions, Ib/ r Tpy NOx 5.00E+01 Ib/mmscf 11 1.17E+03 5.86E-01 CO 8.40E+01 Ib/mmscf 11 1.97E+03 9.84E-01 PM/PM10/PM2.5 7.60E+00 Ib/mmscf (11) 1.78E+02 8.91E-02 SO2 6.00E-01 Ib/mmscf 11 1.41E+01 7.03E-03 VOC 5.50E+00 Ib/mmscf 11 1.29E+01 6.45E-03 Benzene 71-43-2 TH 2.10E-03 Ib/mmscf 11 4.92E-02 2.46E-05 Benz a rene 50-32-8 T 1.20E-06 Ib/mmscf 11 2.81E-05 1.41E-08 Cobalt compounds H 8.40E-05 Ib/mmscf 11 2.95E-04 1.48E-07 Formaldehyde 50-00-0 TH 7.50E-02 Ib/mmscf 11 1.76E-01 8.79E-05 Hexane 1.80E+00 Ib/mmscf 11 4.22E+01 2.11E-02 Naphthalene 91-20-3 H 6.10E-04 Ib/mmscf 11 1.43E-02 7.15E-06 Selenium compounds H 2.40E-05 Ib/mmscf 11 8.44E-05 4.22E-08 Toluene 108-88-3 TH 3.40E-03 Ib/mmscf 11 7.97E-02 3.98E-05 Ref: 1.Emission Factors based on Manufacturer data. 2.AP-42,Table 10.6.3-6,2002 3.Emission factors from NCASI TB 973,Table 7.1-Uncontrolled,February 2010 4.Emission factors from NCASI TB 973,Table7.2 Controlled:Wet Scrubber,February 2010 5.Emission factors from AP-42-DAQ spreadsheet 6.Emission factors per NCASI TB770,Table 6.1.2 Mill 132 average.January 1999 7.Emission factors from NCASI TB 770,Table 6.4.2,Mill 142 No.1 Board Cooler,January 1999 8.Emission Factors AP-42 9.VOC as VOC=VOC as C+formaldehyde+0.5 methanol 10.W PP1 VOC=VOC as propane+methanol+formaldehyde-0.65'methanol as propane-0.65'acetone as propane 11.Emission factors based on AP-42,Fifth Edition,Chapter 1,Section 4.Taken from DAQ spreadsheet online.July 1998 r N 12.Source specific testing on November 2011. .E eu n,;1 y/ 4� r D V WOODWASTE COMBUSTION EMISSIONS CALCULATOR REVISION J 7/15/2011 •OUTPUT SCREEN Instructions: Enter emission source/facility data on the"INPUT"tab/screen. The air emission results and summary of input data are viewed/printed on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen. '^ This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the NCDENR information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not responsible for errors or omissions that may be contained herein. SOURCEI FACIUTYIR INPUT SUMMARY(FROM INPUT SN COMPANY: AraucO FACILITY ID NO.: 1900015 PERMIT NUMBER: 0 EMISSION SOURCE DESCRIPTION: 205 MMBTU/HR WET WOOD >19%MOISTURE FIRED BOILER FACILITY CITY: Moncure EMISSION SOURCE ID NO.: ES-02A FACILITY COUNTY: Chatham PARTICULATE CONTROL DEVICE: WET SCRUBBER POLLUTANT I CONTROL EFF. SPREADSHEET PREPARED BY: Yuki Puram FUEL HEAT VALUE: 4500 BTU/LB NOX 0 ACTUAL FUEL THROUGHPUT: 101408 TON/YR HHV Used for GHGs MMBTU/TON: 15.38 PM CALC'D AS 76.1% POTENTIAL FUEL THROUGHPUT: 199533 TON/YR IBOILER TYPE: STOKER PM10 CALC'D AS 73.3% REQUESTED MAX.FUEL THRPT: 199533 TON/YR INO STACK TEST DATA USED PM2.5 CALC'D AS 69.3% METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1. DEFAULT HIGH HEAT VALUE AND DEFAULT EF CARBON CONTENT USED FOR GHGS(AS A FRACTION): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN CRITERIA AIR POLLUTANT EMISSIONS INFORMATION ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR (r1FTER CONTROLS I LIMITS( (BEFORE CONTROLS I LIMITS) (AFTER CONTROLS I LIMITS( Ib/mm Btu AIR POLLUTANT EMITTED Ib/hr tons/r Ib/hr tons r Ib/hr I tons/r uncontrolled controlled PARTICULATE MATTER PM 17.02 37.88 71.14 311.57 17.02 74.53 0.347 0.083 PARTICULATE MATTER<10 MICRONS(PMIO) 16.81 37.42 62.94 275.66 16.81 73.63 0.307 0.082 PARTICULATE MATTER<2.5 MICRONS(PM25) 16.81 37.42 54.74 239.74 16.81 73.63 0.267 0.082 SULFUR DIOXIDE S02 5.13 11.41 5.13 22.45 5.13 22.45 0.025 0.025 NITROGEN OXIDES NOx 45.10 100.39 45.10 197.54 45.10 197.54 0.220 0.220 CARBON MONOXIDE CO 123.00 273.80 123.00 538.74 123.00 538.74 0.600 0.600 VOLATILE ORGANIC COMPOUNDS VOC 3.49 7.761 3.49 41. E526 3.49 1526 7 0.017 LEAD 9.8E-03 2.2E-02 9.8E-03 -02 9.8E-03 4. E 01 .8E-0 5 TOXIC/HAZARDOU AIR POLLUTANT EMISSIONS/NFORMA N ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR CAS (AFTER CONTROLS I LIMITS) (BEFORE CONTROLS I LIMITS) (PETER CONTROLS'LIMITS] Ib/.rI TOXIC/HAZARDOUS AIR POLLUTANT NUMBER Ib/hr lbtyr Ib/hr Ib/r Ib/hr lbtyr uncontrolled/controlled Acetaldehyde(TH) 75070 1.70E-01 757.518 1.70E-01 1490.514 1.70E-01 1490.514 8.30E-04 8.30E-04 Aceto henone H 98862 6.56E-07 2.92E-03 6.56E-07 5.75E-03 6.56E-07 5.75E-03 3.20E-09 3.20E-09 Acrolein(TH) 107028 8.20E-01 3650.688 8.20E-01 7183.200 8.20E-01 7183.200 4.00E-03 4.00E-03 Antimony&Compounds H SBC 1.62E-03 7.210 1.62E-03 14.187 1.62E-03 14,187 7.90E-06 7.90E-06 Arsenic&Compounds(TH) ASC 4.51 E-03 20.079 4.51 E-03 39.508 4.51 E-03 39.508 2.20E-05 2.20E-05 Benzene(TH) 71432 8.61E-01 3833.222 8.61E-01 7542.360 8.61E-01 7542.360 4.20E-03 4.20E-03 Benzo(a)pyrene 50328 5.33E-04 2.373 5.33E-04 4.669 5.33E-04 4.669 2.60E-06 2.60E-06 Beryllium metal un-reacted Also include in BEC)CT/H 7440417 2.26E-04 1.004 2.26E-04 1.975 2.26E-04 1.975 1.10E-06 1.10E-06 Cadmium Metal elemental un-reacted-(Add w/CDC)(T/H) 7440439 8.41E-04 3.742 8.41 E-04 7.363 8.41E-04 7.363 4.10E-06 4.10E-06 Carbon tetrachloride(TH) 56235 9.23E-03 41,070 9.23E-03 80.811 9.23E-03 80.811 4.50E-05 4,50E-05 Chlorine(TH) 7782505 1.62E-01 721.011 1.62E-01 1418.682 1.62E-01 1418.682 7.90E-04 7.90E.04 Chlorobenzene(TH) 108907 6.77E-03 30.118 1 6.77E-03 59.261 6.77E-03 59.261 3.30E-05 3.30E-05 Chloroform H 67663 5.74E-03 25.555 5.74E-03 50.282 5.74E-03 50.282 2.80E-05 2.80E-05 Chromium-Other compds H add w/chrom acid to get CRC) 3.59E-03 15.972 3.59E-03 31,427 3.59E-03 31.427 1.75E-05 1.75E-05 Chromic acid(VI)Add as comp.of soICR6 and CRC /H) 7738945 7.18E-04 3.194 7.18E-04 6.285 7.18E-04 6.285 3.50E-06 3.50E-06 Cobalt compounds(H) COC 1.33E-03 5.932 1.33E-03 11.673 1.33E-03 11.673 6.50E-06 6.50E-06 Dindro henol,2,4- H 51285 3.69E-05 1.64E-01 3.69E-05 0.323 3.69E-05 0.323 1.80E-07 1.80E-07 Di(2-eth the I)phthalate(DEHP)(TH) 117817 9.64E-06 4.29E-02 9.64E-06 8.44E-02 9.64E-06 8.44E-02 4.70E-08 4.70E-08 Ethyl benzene H) 100414 6.36E-03 28.293 6.36E-03 55,670 6.36E-03 55.670 3.10E-05 3.10E-05 Ethylene dichloride(1,2-dichloroethane H) 107062 5.95E-03 26.467 5.95E-03 52.078 5.95E-03 52.078 2.90E-05 2.90E-05 Formaldehyde H) 50000 9.02E-01 4015.757 9.02E-01 7901.520 9.02E-01 7901.520 4.40E-03 440E-03 Hexachlorodibenzo- ioxin 1,2,3,6,7,8 M 57653857 6.52E-09 2.90E-05 6.52E-09 5.71 E-05 6.52E-09 5.71 E-05 3.18E-11 3.18E-11 Hydrogen chloride hydrochloric acid) H 7647010 3.90E+00 17340.768 3.90E+00 34120,200 3.90E+00 34120.200 1.90E-02 1.90E-02 Lead and Lead compounds(H) PBC 9.84E-03 43.808 9.84E-03 86.198 9.84E-03 86.198 4.80E-05 4.80E-05 Manganese&compounds H MNC 3.28E-01 1460.275 3.28E-01 2873.280 3.28E-01 2873.280 1.60E-03 1.60E-03 Mercury,vapor(Include in Mercu &Com s)(TIH 7439976 7.18E-04 3.194 7.18E-04 6.285 7.18E-04 6.285 3.50E-06 3.50E-06 Methyl bromide H bromomethane 74839 3.08E-03 13.690 3.08E-03 26.937 3.08E-03 26.937 1.50E-05 1.50E-05 Methyl chloride(H)(chloromethane) 74873 4.72E-03 20.991 4.72E-03 41.303 4.72E-03 41.303 2.30E-05 2.30E-05 Meth chloroform(TH) 1,1,1 trichloroethane) 71556 6.36E-03 28.293 1 6.36E-03 55.670 6.36E-03 55.670 3.10E-05 3.10E-05 Methyl ethyl ketone M 78933 1.11 E-03 4.928 1.11 E-03 9.697 1.11 E-03 9.697 5.40E-06 5.40E-06 Methylene chloride H)dichloromethane) 75092 5.95E-02 264.675 5.95E-02 520.782 5.95E-02 520.782 2.90E-04 2.90E-04 Naphthalene(H) 91203 1.99E-02 88.529 1.99E-02 174.193 1.99E-02 174.193 9.70E-05 9.70E-05 Nickel metal(Component of Nickel&compounds) /H 7440020 6.77E-03 30.118 6.77E-03 59.261 6.77E-03 59.261 3.30E-05 3.30E-05 Nitrophenol,4-(H) 100027 2.26E-05 1.00E-01 2.26E-05 1.98E-01 2.26E-05 1.98E-01 110E-07 1.10E-07 Pentachloro henol H 87865 1.05E-05 4.65E-02 1.05E-05 9.16E-02 1.05E-05 9.16E-02 5.10E-08 5.10E-08 Perchloroeth lens tetrachloroethylene (TH) 127184 7.79E-03 34.682 7.79E-03 68.240 7.79E-03 68.240 3.80E-05 3.80E-05 Phenol(TH) 108952 1.05E-02 46.546 1.05E-02 91.586 1.05E-02 91.586 5.10E-05 5.10E-05 Phosphorus Metal,Yellow or White H) 7723140 5.54E-03 24.642 5.54E-03 48.487 5.54E-03 48.487 2.70E-05 2.70E-05 Polychlorinated bi hen Is H) 1336363 1.67E-06 7.44E-03 1.67E-06 1.46E-02 1.67E-06 1.46E-02 8.15E-09 8.15E-09 Pal c clic Organic Matter H POMTV 2.56E-02 114.084 2.56E-02 224.475 2.56E-02 224.475 25E-04 1.25E-04 Pro ioneldeh de H 23386 1.25E-02 55.673 1.25E-02 109.544 1.25E-02 109.544 6.10E-05 6.10E-05 Propylene dichloride(H 1.2 dichloro ro aria) 78875 6.77E-03 30.118 6.77E-03 59.261 6.77E-03 59.261 3.30E-05 3.30E-05 Selenium compounds H SEC 5.74E-04 5.74E-04 5.028 5.74E-04 5.028 2.80E-06 2.80E-06 S rene H) W1�3 90E-01 1734.077 3.90E-01 3412.020 3.90E-01 3412.020 1.90E-03 1.90E-03 Tetrachlorodibenzo- ioxin,2,3,7,8- H 76E-09 7.85E-06 1.76E-09 1.54E-05 1.76E-09 1.54E-05 8.60E-12 8.60E-12 Toluene H) .89E-01 839.658 1.89E-01 1652.136 1.89E-01 1652.136 9.20E-04 9.20E-04 Trichloroeth lens H .15E-03 27.380 6.15E-03 53.874 6.15E-03 53.874 3.00E-05 3.00E-05 Tdchloro0uoromethane CFC 111)M .41E-03 37.420 8.41 E-03 73.628 8.41 E-03 73.628 4.10E-05 4.10E-05 Trichloro henol,2,4,6-(H) .51E-06 2.01 E-02 4.51 E-06 3.95E-02 4.51E-06 3.95E-02 2.20E-08 2.20E-08 Vinyl chloride H .69E-03 16.428 3.69E-03 32.324 3.69E-03 32.324 1.80E-05 1.80E-05 X lane H .13E-03 22.817 5.13E-03 44.895 5.13E-03 44.895 2.50E-05 2.50E-05 H'hest HAP(H ro en chloride(hydrochloric acid (TH) 7647010 1 3.90E+00 17340.768 3.90E+00 34120.2 3.90E+00 34120.2 1.90E-02 1.90E-02 Total HAPs NA 7.96E+00 3.54E+04 7.96E+00 6.97E+04 7.96E+00 6.97E+04 3.88E-02 3.88E-02 TOXIC AIR POLLUTANT EMISSIONS INFORMATION(FOR PERMITTING PURPOSES) ' EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS(FOR PERMITTING PURPOSES) EMISSION FACTOR Ib/mmBtu TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day Ib r uncontrolled controlled Acetaldehyde(TH) 75070 1.70E-01 4.08E+00 1490.514 8.30E-04 8.30E O4 Acrolein H 107028 8.20E-01 1.97E+01 7183+200 4.00E-03 4.00E-03 Arsenic&Compounds H ASC 4.51 E-03 1.08E-01 39.508 2.20E-05 220E-05 Benzene H 71432 8.61 E-01 2.07E+01 7542.360 4.20E-03 4.20E-03 Benzo(a) rene 50328 5.33E-04 1.28E-02 4.669 2.60E-06 2.60E-06 Beryllium metal un-reacted Also include in BEC)(TM) 7440417 2.26E-04 5.41 E-03 1.975 1.10E-06 1.10E-06 Cadmium Metal elemental un-reacted-(Add w/CDC /H) 7440439 8.41 E-04 2.02E-02 7,363 4.10E-06 4.10E-06 Carbon tetrachloride(TH) 56235 9.23E-03 2.21 E-01 80.811 4 50E-05 4.50E-05 Chlorine H 7782505 1.62E-01 3.89E+00 1418.682 7.90E-04 7.90E-04 Chlorobenzene H) 108907 6.77E-03 1.62E-01 59.261 3.30E-05 330E-05 Chloroform H 67663 5.74E-03 1.38E-01 50,282 2.80E-05 2.80E-05 Di(2-eth the phthalate DEHP H) 117817 9.64E-06 2.31E-04 8.44E-02 4.70E-08 4.70E-06 Ethylene dichloride(1,2Eichloroethane)(TH) 107062 5.95E-03 1.43E-01 52.078 2.90E-05 2.90E-05 Soluble Chromate Cmpds,as Chrome(VI) H) SOLCR6 7.18E-04 1.72E-02 6.285 3.50E-06 3 50E-06 Formaldehyde(TH) 50000 9.02E-01 2.16E+01 7901.520 4.40E-03 4.40E-03 Hexachlorodibenzo- ioxin 1,2,3,6,7,8 M 57653857 6.52E-09 1.56E-07 0.000 3.18E-11 3.16E-11 Hydrogen chloride(hydrochloric acid)(TH 7647010 3.90E+00 9.35E+01 34120.200 1.90E-02 1.90E-02 Manganese a compounds(TH) MNC 3.28E-01 7.87E+00 2873.280 1.60E-03 1.60E-03 Mercury,vapor(Include in Mercu &Com s)(T/H 7439976 7.18E-04 1.72E-02 6.285 3.50E-06 3.50E-06 Methyl chloroform H 1,1,1 trichloroethane) 71556 6.36E-03 1.53E-01 55.670 3.10E-05 3.10E-05 Methyl ethyl ketone m 78933 1.11 E-03 2.66E-02 9.697 5.40E-06 5.40E-06 Methylene chloride(TH)(dichloromethane) 75092 5.95E-02 1.43E+00 520.782 2.90E-04 2.90E-04 Nickel metal lComponent of Nickel&Compounds)(TM) 7440020 6.77E-03 1.62E-01 59.261 3.30E-05 3.30E05 Pentachloro henol H) 87865 1.05E-05 2.51E-04 0.092 5.10E-08 5.10E-08 Perchloroeth lens tetrachloroethylene H 127184 7.79E-03 1.87E-01 68.240 3.80E-05 3.80E-05 Phenol(TH) 108952 1.05E-02 2.51E-01 91.586 5.10E-05 5.10E-05 Polychlorinated bi hen Is(TH) 1336363 1.67E-06 4.01E-05 1.46E-02 8.15E-09 815E-09 Styrene(TH) 100425 3.90E-01 9.35E+00 3412.020 1.90E-03 1.90E-03 Tetrachlorodibenzo- iozin,2,3,7,8- H 174606 1.76E-09 4.23E-08 1.54E-05 8.60E-12 8.60E-12 188Toluene H) 1.89E-01 4.53E+00 1652.136 920E-04 9.20E-04 Tnchloroeth ene(TH) 7901 66.15E-03 1.48E-01 53.874 300E-05 3.00E-05 Trichloro6uoromethane(CFC 111)m 75694 8.41E-03 2.02E-01 73.628 4.10E-05 4.10E-05 Vinyl chloride(TH) 75014 3.69E-03 8.86E-02 32.324 1.80E-05 1.80E-05 Xylene(TH) 1330207 5.13E-03 1.23E-01 44.895 2.50E-05 2.50E-05 GREENHOUSE GAS EMISSIONS INFORMATION(FOR EMISSIONS INVENTORY GREENHOUSE GAS EMISSIONS-POTENTIAL TO EMIT PURPOSES) -CONSISTENT WITH EPA MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With input capacity and EPA MRR Emission Requested Emission Limitation- Factors utilize requested fuel limit and EPA MRR Emission Factors EPA MRR CALCULATION METHOD:TIER 1 GREENHOUSE GAS metric tons/yr, short tons/yr, metric tons/ r CO2e short tons/yr short tons/yr short tons/ r,CO2e short tons/yr CO2e CARBON DIOXIDE(CO2) BIOGENIC EMISSIONS' 146,295.64 zero 161,263.15 185,679.75 zero' 185,679.75 zero' METHANE CH4 4.99E+01 1.05E+03 I 5.50E+01 6.33E+01 1.33E+03 6.33E+01 1.33E+03 NITROUS OXIDE N20 6.55E+00 2.03E+03 7.22E+00 8.31E+00 2.58E+03 8.31E+00 2.58E+03 TOTAL 3,078.76 TOTAL 3,907.59 TOTAL 3,907.59 BIOGENIC CO2 has 0 CO2e NOTE:The DAQ Air Emissions Reporting Online(AERO)system requires short tons NOTE: CO2e means CO2 equivalent The EPA MRR requires metric tons Note:Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes. Arauco Panels USA LLC MDF Teaford Abort Abort Hours: 2,672 hr/yr Energy Plant Outlet: 140000 NM3/Hr Abort Firing Rate(5): /hr Wood Burned during Abort: 66800 MMBtu/ Annual Press Production: 146,53 DT/yr Uncontrolled Emission Emissions, Emissions, Compound Factor Reference Ibl r t a' : ..' ov PM Total 5.60E-01 lb/MMBtu 4 3.74E+04 1.87E+01 PM10 5.00E-01 lb/MMBtu 4 3.34E+04 1.67E+01 60 PM2.5 4.30E-01 lb/MMBtu 4 2.87E+04 1.44E+01 CO 6.00E-01 lb/MMBtu 4 4.01 E+04 2.00E+01 NOx 2.20E-01 Ib/MMBtu 4 1.47E+04 7.35E+00 SO2 2.50E-02 IV lb/MMBtu 4 1.67E+03 8.35E-01 VOC 1.70E-02 lb/MMBtu 4 1.14E+03 5.68E-01 Acetaldehyde 75-07-0 TH 1.22E-04 lb/MMBtu 2 8.15E+00 4.07E-03 Aceto henone 98-86-2 H 1.84E-06 lb/MMBtu 2 1.23E-01 6.15E-05 Acrolein 107-02-8 TH 3.16E-05 lb/MMBtu 2 2.11 E+00 1.06E-03 Antimon &Compounds H 4.98E-07 lb/MMBtu 3 3.33E-02 1.66E-05 Arsenic&Compounds TH 1.84E-06 lb/MMBtu 3 1.23E-01 6.15E-05 Benzene 71-43-2 TH 2.35E-04 lb/MMBtu 2 1.57E+01 7.85E-03 Benzo a rene 50-32-8 T 2.60E-06 lb/MMBtu 4 1.74E-01 8.68E-05 Beryllium T/H 3.41 E-07 lb/MMBtu 3 2.28E-02 1.14E-05 Cadmium T/H 1.85E-06 lb/MMBtu 3 1.24E-01 6.18E-05 Carbon tetrachloride 56-23-5 TH 1.26E-05 lb/MMBtu 2 8.42E-01 4.21 E-04 Chlorine 7782-50-5 TH 7.90E-04 lb/MMBtu 4 5.28E+01 2.64E-02 Chlorobenzene 108-90-7 TH 1.66E-05 lb/MMBtu 2 1.11E+00 5.54E-04 Chloroform 67-66-3 TH 3.52E-05 lb/MMBtu 2 2.35E+00 1.18E-03 Chromium H 5.06E-06 lb/MMBtu 3 3.38E-01 1.69E-04 Chromium I T/H 2.35E-07 lb/MMBtu 3 1.57E-02 7.85E-06 Cobalt compounds H 1.97E-07 lb/MMBtu 3 1.32E-02 6.58E-06 Dinitro henol,2,4 51-28-5 H 1.30E-07 lb/MMBtu 2 8.68E-03 4.34E-06 DEHP 117-81-7 TH 4.70E-08 lb/MMBtu 4 3.14E-03 1.57E-06 Ethyl benzene 100-41-4 H 1.76E-05 lb/MMBtu 2 1.18E+00 5.88E-04 Ethylene dichloride 107-06-2 TH --2.90E-05--lb/MMBtu 4 1.94E+00 9.69E=04 -Formaldehyde 50-00-0 TH 8.83E-04 lb/MMBtu 2 5.90E+01 2.95E-02 1,2,3,6,7,8-HCDD T 1.60E-06 lb/MMBtu 4 1.07E-01 5.34E-05 Hydrogen chloride 7647-01-0 TH 1.57E-03 lb/MMBtu 2 1.05E+02 5.24E-02 Lead and Lead compounds H 1.66E-05 lb/MMBtu 3 1.11E+00 5.54E-04 Manganese&compounds TH 2.62E-05 lb/MMBtu 3 1.75E+00 8.75E-04 Mercury T/H 6.61 E-07 lb/MMBtu 3 4.42E-02 2.21 E-05 Methanol 4.87E-04 lb/MMBtu 2 3.25E+01 1.63E-02 Methyl bromide 74-83-9 H bromomethane 1.52E-05 lb/MMBtu 2 1.02E+00 5.08E-04 Methyl chloride 74-87-3 H chloromethane 2.31 E-05 lb/MMBtu 2 1.54E+00 7.72E-04 Methyl chloroform 71-55-6 TH 3.10E-05 lb/MMBtu 4 2.07E+00 1.04E-03 Methyl ethyl ketone 78-93-3 T 5.39E-06 lb/MMBtu 2 3.60E-01 1.80E-04 Methylene chloride 75-09-2 TH 3.50E-04 lb/MMBtu 2 2.34E+01 1.17E-02 Naphthalene 91-20-3 H 7.44E-05 lb/MMBtu 2 4.97E+00 2.48E-03 Nickel T/H 3.94E-06 lb/MMBtu 3 2.63E-01 1.32E-04 Nitro phenol,4 100-02-7 H 9.32E-08 lb/MMBtu 2 6.23E-03 3.11E-06 Pentachloro henol 87-86-5 TH 4.48E-08 lb/MMBtu 2 2.99E-03 1.50E-06 Perchloroeth lene 127-18-4 TH 3.80E-05 lb/MMBtu 4 2.54E+00 1.27E-03 Phenol 108-95-2TH 1.98E-05 lb/MMBtu 2 1.32E+00 6.61E-04 Phosphorus 7723-14-0 H 9.85E-05 lb/MMBtu 3 6.58E+00 3.29E-03 Polychlorinated bi hens 1336-36-3 TH 8.15E-09 lb/MMBtu 4 5.44E-04 2.72E-07 Pol c clic Organic Matter H 1.25E-04 lb/MMBtu 4 8.35E+00 4.18E-03 Pro ionaldeh de 123-38-6 H 3.21 E-05 lb/MMBtu 2 2.14E+00 1.07E-03 Propylene dichloride 78-87-5 H 3.30E-05 lb/MMBtu 4 2.20E+00 1.10E-03 Selenium compounds H 1.85E-06 lb/MMBtu 3 1.24E-01 6.18E-05 Styrene 100-42-5 TH 6.30E-05 lb/MMBtu 2 4.21 E+00 2.10E-03 2,3,7,8-TCDD 1746-01-6 TH 8.60E-12 lb/MMBtu 4 5.74E-07 2.87E-10 Toluene 108-88-3 TH 2.34E-05 lb/MMBtu 2 1.56E+00 7.82E-04 Trichloroeth lene 79-01-6 TH 1.94E-05 lb/MMBtu 2 1.30E+00 6.48E-04 Trichlorofluoromethane 75-69-4 T 4.05E-05 lb/MMBtu 2 2.71 E+00 1.35E-03 Tdchloro henol,2,4,6- 88-06-2 H 2.73E-07 lb/MMBtu 2 1.82E-02 9.12E-06 Vinyl chloride 75-01-4 TH 1.84E-05 lb/MMBtu 2 1.23E+00 6.15E-04 X lene 1330-20-7 TH 5.22E-06 lb/MMBtu 2 3.49E-01 1.74E-04 Wood is burned in the energy plant and the hot exhaust is routed to the dryers. Natural gas may be burned as auxiliary/startup/standby fuel. Dryer exhaust is routed to 2 wet scrubbers in parallel. Notes: 1.Emission Factors based on Manufacturer data. 2.Emission factors from NCASI TB 973,Table 7.1-Uncontrolled,February 2010 3.Emission factors from NCASI TB 973,Table7.2 Controlled:Wet Scrubber,February 2010 4.Emission factors from AP-42-DAQ spreadsheet 5.Firing rate based on tracking data,20-25 MMBtu and using 25 MMBtu as a conservative estimate. Arauco Panels USA LLC MDF Press Emissions Emission Description Annual Press Production Source ES-16 Scrubber controlling Press 118,397 MSF 34' ES-16 Scrubber controlling Press 6,145 hr/ r Scrubber Control Efficiencies VOC,Formaldehyde,and Methanol removal: 90% PM removal: 80% Compound EF Uncontrolled Controlled Controlled Reference Emission Factor Emissions,t Emisslons,Mly r A tft a' wa :` F WPP1 VOC 1 "' 7.00E-02'. Ib/MSF'.,. 0.41 829 PM 1;, 8.80E-02:; Ib/MSF 1.04 2084 PM10 1'' B.SOE 02 IblM5F=;;iii 1.04 2084 PM2.5 (1') 8.80E-02. Ib/MSF 1.04 2084 Acetone 2 2.90E-02 Ib/MSF 0.17 343 Acetone as propane 3 2.20E-02 Ib/MSF 0.13 260 Acetaldehyde 75-07-0 TH 4 3.50E-03 Ib/MSF 0.02 41.4 Acrolein 107-02-8 TH 4 7.30E-04 Ib/MSF 0.004 8.6 Formaldehyde 50-00-0 TH 1' 1.37E+0Q: Ib/hr 4.21 8419 Methanol 67-56-1 H 1 2.12E+0Q Ib/hr 6.51 13027 Methanol as propane 3 9.72E-01 Ib/MSF 5.75 11504 Phenol 4 2.60E-02 Ib/MSF 0.15 308 Pro ionaldeh de 4 5.40E-04 Ib/MSF 0.0032 6.4 1.Source specific compliance testing November 2011 2.AP-42,Section 10.6.3,Table 10.6.3-4. 3.Calculated Emission Factor 4.NCASI SARA 313 Guidance for Wood Products Facilities Updated March 2011 Note. Stack testing was done in 2011 on the MDF press but the testing has not yet been accepted by the DAQ therefore,factors are not being used in the AEI. r � Arauco Panels USA LLC MDF Backup Generator Emissions(ES-21) Diesel Usage: 0 gal/yr Diesel Usage: 0 MMBtu/yr Emission Actual Emissions Compound Factor(1) Ib/MMBtu Ib/yr tpy PM 6.97E-02 0.00E+00 0.00E+00 PM10 5.73E-02 0.00E+00 0.00E+00 PM2.5 2.93E-02 0.00E+00 0.00E+00 SO2 4.04E-01 0.00E+00 0.00E+00 NOx 3.20E+00 0.00E+00 0.00E+00 VOC 8.19E-02 0.00E+00 0.00E+00 CO 8.50E-01 0.00E+00 0.00E+00 WWI"WWk { B Acetaldehyde 2.20E-05 0.00E+00 0.00E+00 Acrolein 7.88E-06 0.00E+00 0.00E+00 Benzene 7.76E-04 0.00E+00 0.00E+00 Butadiene-1,3 3.91E-05 0.00E+00 0.00E+00 Formaldehyde 7.89E-05 0.00E+00 0.00E+00 Na thalene 1.30E-04 0.00E+00 0.00E+00 Toluene 2.81 E-04 0.00E+00 0.00E+00 X lene 1.93E-04 0.00E+00 0.00E+00 1. Emission Factor from AP-42,Section 3.4. PM2.5 is assumed to be 42%of PM per AP-42 Table 1.3-7 `Source did not operate in 2010 j Arauco Panels USA LLC MDF Plant Fugitive Emissions: Resin Tanks(MDFR-1, MDFR-2, MDFR-3) Number of Resin Tanks: 3 resin tanks Uncontrolled Fugitive Fugitive Compound Emission Factor(1) Emissions,Ib/yr Emissions, tDv VOC 0.001 Ib/hr/tank 1 26.3 1 1.31 E-02 Formaldehyde 50-00-0 TH 0.001 Ib/hr/tank 26.3 1.31 E-02 1. Emission Factor based on PCWP Rule Table 2A NC DAQ - EMISSIONS INVENTORY Page 1 of 2 Facility Total CY 2012 Emission Summary Facility Id : 1900015 Green House Gases Pollutants GHG Actual Emissions Tons/Year Pollutant CAS 2012_____T 2011 %Chan e Criteria Pollutants Actual Emissions Tons/Year Pollutant CAS 2012 2011 %Change CO CO 523.84 493.05 6.244811% NOx NOx 313.22 290.11 7.9659495% PM TSP TSP 149.66 127.59 17.2976% PM10 PM10 146.97 122.81 19.67267% PM2.5 PM2.5 132.53 99.43 33.28975% S02 S02 13.66 14.94 -8.567602% VOC VOC 364.09 492.995 -26.147324% Hazardous Air Pollutants HAPS and/or Toxic Air Pollutants TAPs Actual Emissions Pounds/Year Pollutant CAS 2012 2011 %Change timon &Compounds total mass, inc elemental SB .00019 In 9 Antimony Metal-add to SBC 1 7440-36-0 1 1.9E-4 Not reported N/A Arsenic&Compounds total mass of elemental AS,arsine and all inorganic com ounds 1.74034 Arsenic Metal,elemental unreacted 7440-38-2 0.056 .0514 8.949423% (Component of ASC Arsenic Unlisted Compounds(Specify& ASC-Other 1.68434 1.4681 14.729245% Component of ASC Beryllium&compounds Total mass .0395 Beryllium Compound, Unlisted(Specify& BEC-Other 0.0395 Not reported N/AComponent of BEC Cadmium&compounds total mass inc elemental metal 1.75121 Cadmium Metal(elemental unreacted, 7440-43-9 1.75121 1.57183 11.412 Component of CDC 171 Cobalt compounds.1891 Cobalt Unlisted Compound(Specify& COC-Other 0.1891 Not reported N/AComponent of COC Lead and Lead com ounds15.9818 Lead Unlisted Compounds(Specify and PBC-Other 15.9818 13.59057 17.59477% Component of PBC Manganese&com ounds30.85402 Manganese Unlisted Compounds Component of MNC (Specify& MNC-Other 30.85402 26.2158 17.692461% Mercury&Compounds-all total mass, inc H Va or.67353 Mercury Unlisted Compounds(Specify&Component of HGC) HGC-Other 0.0701 .0644 8.85093% Mercury,vapor(Component of HGC 7439-97-6 0.60343 .55769 8.201679% Nickel&Compounds,sum total mass, inc elementa14.20504 Nickel Unlisted Compounds(Specify&Component of NIC) NIC-Other 0.602 .553 8.8607645% Nickel metal(Component of NIC 7440-02-0 3.60304 3.16449 13.858473% Chromium VI Non-Specific Compounds,as Chrom VI (Component CRC .0475 Chromium(VI)Non-Specific, Unlisted I (Specify&Component of NSCR6&CRC NSCR6-0ther 0.0475 .0436 8.944952% Chromium VI Soluble Chromate Com ounds(Component of CRC .21776 Chromic acid(VI)(Component of SolCR6& 7738-94-5 0.21776 .18039 20.716223% CRC Chlorinated Dioxin Compounds of interest as HAP or TAP1.457 Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8 Component of CLDC 57653-85-7 1.457 1.218 19.622328% Chromium-All/Total Inc Chromium NO cat eciories,metal and Others 5.03847 Chromic acid(VI)(Component of SolCR6& CRC) 7738-94-5 0.21776 .18039 20.716223% Chromium(VI)Non-Specific, Unlisted NSCR6-Other 0.0475(Specify&Component of NSCR6&CRC .0436 8.944952% Chromium Unlisted Compounds(Specify&Component of CRC) CRC-Other 4.77321 4.02958 18.454277% Pol c clic Or anic Matter(Specific Com ounds from OAQPS for TV 77.99732 Benzo(a)pyrene(Component of POMTV&POM7) 50-32-8 2.62517 2.20107 19.267897% Naphthalene(Component of POMTV 91-2073 75.37215 64.16976 17.45742% Pol c clic Organic Matter 7 PAH Com ounds for NIF 2.62517 Benzo(a)pyrene(Component of POMTV&POM7) 50-32-8 2.62517 2.20107 19.267897% Acetaldehyde 75-07-0 7985.918 8978.8282 -11.058349% Acrolein- 107-02-8 2363.3997 2375.40652 -0.5054645% Benzene 71-43-2 257.1096 220.56213 16.57014% Butadiene, 1,3- 106-99-0 0.0024 Not reported N/A Carbon tetrachloride 56-23-5 11.542 9.56 20.73221% Chlorine 7782-50-5 291.147 279.493. 4.1696897% Chlorobenzene 108-90-7 15.12728 Not reported N/A Chloroform 67-66-3 37.0554 Not reported N/A Cumene 98-82-8 23091.12 79440.434 -70.93279% Dinitro henol,2,4- 51-28-5 0.11 Not reported N/A Ethyl benzene 100-41-4 17.59772 Not reported N/A Ethylene dichloride 1,2-dichloroethane 107-06-2 26.44 21.99 '20.236475% Formaldehyde 50-00-0 64130.85 84237.7824 -23.869253% Hexane,n- 110-54-3 124.4164 229.64 -45.821114% Hydrogen chloride(hydrochloric acid 7647-01-0 578.689 555.583 4.158878% Methanol 67-56-1 59294.7 141882.4 -58.20856% Methyl bromide 74-83-9 13.92 11.51 20.938313% Methyl chloride 74-87-3 21.04 17.54 19.95439% Methyl chloroform 71-55-6 28.27 Not reported N/A Methyl ethyl ketone 78-93-3 1675.8184 1814.861 -7.661336% Methyl isobut I ketone 108-10-1 242.0 246 -1.6260163% Methylene chloride 75-09-2 380.5 1 321.6 18.314674% http://xapps.ncdenr.org/aq/aero/EDFacTotals.jsp 6/26/2013 NC DAQ - EMISSIONS INVENTORY Page 2 of 2 e Perchloroeth lene tetrachloroeth lene 127-18-4 34.64 Not reported N/A ` Phenol 108-95-2 2766.9988 3713.46735 -25.487461% Phosphorus Metal,Yellow or White 7723-14-0 89.88 74.74 20.256891% Polychlorinated bi hen Is PCB 1336-36-3 0.00743 Not reported N/A Polycyclic Organic Matter(Inc PAH,dioxins, POM 144.7015 122.96762 17.674479% etc. NC&AP 42 historic amorphous lob Pro ionaldeh de 123-38-6 668.26 668.43 -0.025430175% Propylene dichloride 78-87-5 30.1 25.06 20.111736% Selenium Compounds SEC 1.77479 Not reported N/A Styrene 100-42-5 68.57176 Not reported N/A Tetrachloroethane, 1,1,2,2- 79-34-5 1.3 Not reported N/A Toluene 108-88-3 31.24543 Not reported N/A Trichloroeth lene 79-01-6 16.4 Not reported N/A Trichloro henol,2,4,6- 88-06-2 0.231 Not reported N/A Trimeth I entane,2,2,4- 540-84-1 0.25 Not reported N/A Vinyl chloride 75-01-4 16.83 14.01 20.128477% X lene 1330-20-7 13.72977 Not reported N/A close http://xapps.ncdenr.org/aq/aero/EDFacTotals.jsp 6/26/2013 Arauco Panels USA LLC MDF Plant Cyclones and Banhouses [- Annual Press Production: 146,538 ODT/yr Annual Refiner Production: 146,538 ODT/yr Annual Sander Production: 140,641 ODT/yr Annual Sander Production: 112,689 MSF 3/4" PMIPM10 Emissions:I0 Controlled Emissions uttite�PIMA ' Emission Op.Hours EF Annual Annual EF Annual Annual Point Description HrslYr Lba/Hr LbslYr ons/Yr LbslHr, LbslYr Tons/Yr EP-01 Refiner Startup Cyclone t31 208 3.52 732 0.37 3.52 732 0.37 EP-03 Fiber sifters stem filter 6145 •i0.5B': 3564 1.78 -'.038 3564 1.78 JEP-04 Forming Line Clean-Up Filter 6145 O.W 3380 1.69 "1,:,045 3380 1.69 EP-05 Mat re ect system Filter 686 ;0.48 329 0.16 .,•0.48. 329 0.16 EP-07 Saws stem Filter 6145 °°_ .84 5162 2.58 .84 5 662 2.58 EP-08 SanderS tern No.1 Exhaust Filter 3 897 '•-0.9D - 3507 1.75 090 :i 3 507 1.75 , EP-09 Rec clad Fiber Silo No.1 Filter 686 0.02 14 0.01 0.02 14 0.01 y/ EP-10 SanderSystem No.2 Exhaust Filter 3,897 --0.45, 1754 0.88 "°0:05'": 1 754 0.88 EP42 Sander Dust Silo No.1 Filler 1,949 0.02 39 0.02 0.02 39 0.02 I V EP-13 Dry Sawdust Silo Filter 6145 0.02 123 0.06 0.02 123 0.06EP-15 Rao ,r/ Vol j� EP-17 Sender DusltSilo ft_ iNo.2 Flfeir 1949 0.02 39 0.02 002 39 0.02 �" �O�' CO "Grp V\O� t��s- Totals 7.42 18643 9.32 7.42 18543 9.32 l: VOCIHAPITAP Emissions: Emission issi n Description Throughput Units E'-;u umam 4 ---_ -D at'- dab ' 04, ^�. . 'I "�-„ { C..: +�<o '"„ outVOC`ML-. pmission Factor Ibl r tonal r Emission Factor Ib r tons)r Emission Factor Ibl r tone r Emission Factor Ib r tonal r Emission Factor Ib r tonal r EP-03 Fiber sifter system filter 146538 ODT!r 2.60E-02 Ib/ODT 3810 1.90 8.90E-03lb/ODT 1304 0.65 6.90E-03 Ib/ODT 1011 0.51 5.60E-02 Ib/ODT 8206 4.10 -:8.20E-02 ib/ODT=:.:; 12016 6.01 EP-04 FormingLine Clean-UpFiller 146538 ODT/r 2.60E-02 Ib/ODT 3810 1.90 8.90E-03 Ib/ODT 1304 0.65 6.90E-03 Ib/ODT 1011 0.51 8.20E-02 Ib/ODT 12016 6.01 :820E 2Ib/ODT:" 12016 6.01 EP-05 Mat re act system Filter k'16359-- ODT/r 2.60E-02 Ib/ODT 425 0.21 8.90E-03 Ib/ODT 146 0.07 6.90E-03 Ib/ODTA 0.06 8.20E-02 Ib/ODT 1341 0.67 �8.20S-02 ib/ODT 1341 0.67 / EP-07 Saw System Filter 140641 MS, 1.15E-02 IblMSF 1617 0.81 8.90E-03 Ib/MSF 1252 0.63 1.80E-03 IblMSF0.13 1.00E-02 Ib/MSF 1406 0.70 '1:00E-02 Ib/MSF 1406 0.70 ✓ EP-08 Sender System No.1 Exhaust Filler 112689 MSF!r 1.15E-02 IblMSF 1296 0.65 4.00E-04 IblMSF 45 0.02 1.80E-03 Ib/MSF0.10 1.00E-02 Ib/MSF 1127 0.56 -1.00E-02 ib/MSF, 1127 0.56 ,J EP-09 Recycled Fiber Silo No.1 Filter i16359.<ODT/r 3.95E-01 Ib10DT 6462 3.23 9.00E-03 Ib/ODT 147 0.07 2.50E-01 Ib/ODT2.04- 6.80E-02 Ib/ODT 1112 0.56 8:20E-02 IbIODT": '1341 0.67 EP-10 Sander S stem No.2 Exhaust Filter 112689 MSF! +. 1.15E-02 IblMSF 1296 0.65 8.90E-03 IblMSF 1003 0.50 1.80E-03 IblMSF0.10 1.00E-02 Ib/MSF 1127 0.56 1:00E-02 IbIODT: 1127 0.56 EP-12 Sander Dust Silo No.1 Filter 55129 +ODTI 3.95E-01 Ib/ODT 2026 1.01 9.00E-03 Ib/ODT 46 0.02 2.50E-01 IbIODT0.. 6.80E-02 Ib/ODT 349 0.17 -268E-01 Ib/0DT; 1375 0.69 EP-13 D Sawdust Silo Filter a.818,r. ODT!r 3.95E-01 Ib/ODT 323 0.16 9.00E-03 Ib/ODT 7 0.00 2.50EA1 Ib/ODT0.10 6.80E-02 IbIODT 56 0.03 2.68E-01 Ib/0Q7 219 0.11 EP-15 Recycled Fiber Silo No.2 Filter 0 ':ODTI r 3.95E-01 Ib10DT 0 0.00 9.00E-03 IbIODT 0 0.00 2.50E-01 Ib/ODT0.00 6.80E-02 Ib/ODT 0 0.00 812 E-02 Ib/ODT. 0 0.00 EP-17 Sander Dust Silo No.2 Filter •.05129 . ODT/ 3.95E-01 IblODT 2026 1.01 9.00E-03 Ib/ODT 46 0.02 2.50E-01 IblODT0.64 6.80E-02 Ib/ODT 1 349 1 0.17 2P68E-01 IbIODT 1375 0.69 Note-all runs were non-detect,but cumene Is added at request of DAO at 112 the detection limit,since detection limit Is>1 ppm. WPP1 VOC Calculation:14) Emission .aa�;..: r 'vl�K°Nfothaha asp Point Description Emission Factor I Ibl r tonstvr Emission Factor Iblvir I tonal r Emission FactorF72.66 tone r Emission Factor Ib r tons)r J EP-03 Fiber sifters stem filter 3.16E-03 Ib/ODT 463 0.232 0.07 Ib/ODT 10030 5.01 8.22E-02 IbIODT 12044 6.02 / EP-04 FormingLine Clean-UpFilter 3.16E-03 Ib/ODT 463 0.232 0.10 Ib/ODT 14686 7.34 1.14E-01 IbIODT 16700 8.35 V EP-05 Mat reject system Filter 3.16E-03 Ib/ODT 52 0.026 0.10 Ib/ODT 1640 0.82 1.14E-01 lb/ODT 1864 0.93 EP-07 Saw System Filter 8.25E-041b10DT 116 0.058 0.01 Ib/ODT 1719 0.86 2.24E-02 Ib/ODT 3148 1.57 EP-08 Sander System No.1 Exhaust Filter 8.25E-04 Ib/MSF 93 0.046 0.01 IblMSF 1377 0.69 6.45E-04 Ib/MSF 0.04 1.35E-02 IblMSF 1518 0.76EP-09 Re cled Fiber Silo No.1 Filter 1.15E-01 Ib10DT 1874 0.937 0.08 WODT 1360 0.68 2.68E-01 IbIODT 4378 2.19 l/ EP-10 SanderS tem No.2 Exhaust Filter 8.25E-04 Ib/ODT 93 0.046 0.01 IblODT 1377 0.69 2.24E-02 Ib/ODT 2523 1.26 Sander Dust Silo No.1 Filter 1.15E-01 IblMSF 588 0.294 0.08 IblMSF 426 0.21 6.45E-04 IblMSF 0.00 2.67E-01 IblMSF 1370 0.69 EP-13 D Savidust Silo Filter 1.15E-01 IblMSF 94 0.047 0.08 IblMSF 68 0.03 6.45E-04 IblMSF 0.00 2.67E-01 IblMSF 219 0.11 JEP-15 Rec clad Fter Silo No.2 Filter 1.15E-01 IbIODT 0 0.000 0.08 Ib/ODT 0 2.68E-01 Ib/ODT 0 0.00 EP-17 ISander Dust Silo No.2 Fit I 1.15E-01 Ib/MSF 1 588 1 0.2941 0.08 IIbfMSF 1 426 1 0.21 6.45E-04IblMSF 1 3.31 1 0.00 2.67E-01 IblMSF 1370 0.69 Emission Factor References 1.Emission factors based on Manufacturer Data. 2.For baghouses,it is assumed that PM=PM10. 3. Per Oregon DEO Emission Factors for Wood Products,0.2 lb PM/ton for cyclones handling preen wood.PM10 is assumed equal to 40%of PM based on EPA AIRS data forwaod cyclones. 4.NCASI Technical Bulletin 770.Mill 132 emission factors.Tables 5.2.3 and 5.2.4,January 1999.Total VOC calculated as M25A VOC+.5Methanol+Formaldehyde.Where emission factors are ND,1/2 detection limit is used. HAP/TAP compounds with all runs non-detect treated as zero.As acetone is subtracted out of the WPP1 VOC,It Is more conservative to leave blank for those that are ND. j V Arauco Panels USA LLC MDF Plant Emissions for Backup Natural Gas Burners for Thermal Oil Heater(ES-18,-19,-20) If the wood energy system is offline and the MDF process is still running,backup natural gas burners can be used . to provide heat to the thermal oil system. These burners will have their own emission points,EP-18,-19,-20. #of Burners: 3 Burner Size: 24 MMbtu/hr Natural Gas Heating Value: 1020 BTU/scf Burner Natural Gas Use: 0.06 MMscf/yr ICI s Compound Emission Factor Emission EmissionsIb/ r t py PM 7.60E+00 Ib/MMscf 4.23E-01 2.11E-04 PM10 7.60E+00 Ib/MMscf 4.23E-01 2.11E-04 PM2.5 7.60E+00 Ib/MMscf 4.23E-01 2.11E-04 S02 6.00E-01 Ib/MMscf 3.34E-02 1.67E-05 NOx 1.00E+02 Ib/MMscf 5.56E+00 2.78E-03 CO 8.40E+01 Ib/MMscf 4.67E+00 2.34E-03 VOC 5.50E+00 Ib/MMscf 3.06E-01 1.53E-04 Arsenic 2.00E-04 Ib/MMscf 1.11E-05 5.56E-09 Barium 4.40E-03 Ib/MMscf 2.45E-04 1.22E-07 Benzene 2.10E-03 Ib/MMscf 1.17E-04 5.84E-08 Cadmium 1.10E-03 Ib/MMscf 6.12E-05 3.06E-08 Chromium 1.40E-04 Ib/MMscf 7.78E-06 3.89E-09 Cobalt 8.40E-05 Ib/MMscf 4.67E-06 2.34E-09 Formaldehyde 7.50E-02 Ib/MMscf 4.17E-03 2.09E-06 Lead 5.00E-04 Ib/MMscf 2.78E-05 1.39E-08 Manganese 3.80E-04 Ib/MMscf 2.11 E-05 1.06E-08 Mercury 2.60E-04 Ib/MMscf 1.45E-05 7.23E-09 Naphthalene 6.10E-04 Ib/MMscf 3.39E-05 1.70E-08 Nickel 2.10E-03 Ib/MMscf 1.17E-04 5.84E-08 Toluene 3.40E-03 Ib/MMscf 1.89E-04 9.45E-08 1.AP-42 Section 1.4.July 1998 TABLE 2.1 SUMMARY OF THE MDF PRESS VENT VENTURI SCRUBBER (CONTROL DEVICE ID CD16) INLET AND OUTLET TEST RESULTS FOR UNIBOARD USA LLC; M NCURE,NC; NOVEMBER 1-2,2011 _efp Date November 1, November 2, November 2, ---- 2011 2011 2011 Time 16:40-17:50 18:33-19:39 19:57-21:03 ---- Inlet Temperature(IF) 111.7 104.1 110.6 108.8 Inlet Moisture 3.5% 1.7% 1.9% 2.4% Inlet Flow Rate actual cubic-feet/minute 19,000 19,500 19,700 19,400 dry,standard cubic-feet/minute 16,600 17,600 17,500 17,200 Inlet Methanol concentration,PPnlv,d 32.3 20.0 24.0 25.4 emission rate(lbs/hr) 2.68 1.76 2.10 2.18 Inlet Formaldehyde concentration,ppm,, 25.0 15.4 16.6 19.0 emission rate(lbs/hr) 1 1.94 1.27 1.36 1.52 Outlet Temperature(IF) 84.9 82,2 86.8 84.6 Outlet Moisture 3.9% 3.6% 3.6% 3.7% Outlet Flow Rate actual cubic-feet/minute 23,900 21,500 22,700 22,700 dry,standard cubic-feet/minute 22,200 20,200 21,100 21,200 Outlet Methanol concentration,pprn,,,y 0.87 0.76 0.91 0.85 emission rate(lbs/hr) 0.097 0.076 0.096 0.090 Methanol Reduction Efficiency 96.4% 95.7% 95.4% 95.8% Outlet Formaldehyde concentration,ppmdy 1.01 0.76 0.91 0.89 emission rate(lbs/hr) 0.104 0.072 0.089 0.088 Formaldehyde Reduction Efficiency 94.6% 94.3% 93.4% 94.1% 7 Arauco Panels USA LLC New MDF Plant Log Processing Line The revised MDF project includes a new log processing line. Logs will be debarked and chipped. The chipper is in an enclosed building and there are no PM emissions. Emissions from log debarking are estimated below. Emissions from transport of bark and chips to piles are also estimated below. Log Throughput: 0 tons/yr Chip Throughput: 0 tons/yr Bark Throughput: 0 tons/yr Compound Emission Factor Potential Emissions Ib/ r ton/ r PM 0.0024 Ib/ton log 0.00E+00 0.00E+00 PM-10 0.00048 Ib/ton log 0.00E+00 0.00E+00 No PM2.5 emissions are expected from log debarking There are no log debarking emission factors in the current version of AP-42. Log debarking factor is estimated at 10%of 0.024 lb PM/GT logs in 1980 AP-42 Plywood section,table 10.3-1 (Rated E). PM-10 is estimated as 30%of total PM. This emission factor is used by similar sources in NC for the purpose of air emissions inventories. Chip and Bark Handling Emissions The factor for chip/bark conveying and drops is determined using the predictive equation found on page 13.2.4-3(Aggregate Handling and Storage Piles-Section 13.2.4)of AP-42, 11/06 edition. The equation takes into account particle size,wind speed,and material moisture content. An average wind speed of 15 mph is used. The value for particle size,k @<30 um is given as 0.74. A 50%moisture content is used for chips and bark. The equation is given as where E is the emission factor,U is the wind speed, M is the moisture content and k is the particle size: E=k(0.0032)*({U/511-'/{M/2}1.4) lb/ton PM E= 1.09E-04 lb/ton PM10 E= 5.16E-05 lb/ton or 47.3%of PM Compound Emission Factor Potential Emissions COW,Halll�€� n Ib/ r ton/ r fi PM 1.09E-04 lb/ton chips 0.00E+00 0.00E+00 PM-10 5.16E-05 lb/ton chips 0.00E+00 0.00E+00 _ PM 1.09E-04 Ib/ton bark 0.00E+00 0.00E+00 PM-10 5.16E-05 Ib/ton bark I 0.00E+00 0.00E+00 No PM2.5 emissions are expected from chip and bark handling