AQ_F_0800044_20201101_EI_Cmb-EI-File

2019 Emissions Inventory Review / Data Tracking Form
Facility Name: Avoca LLC FaeiG ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston ETH Confidential Copy Submitted?
Title V ❑ YES
1NO
Initial Review/Data Entry
Enter date received into ED. Date Received: 3 J ZY/20 VO
❑ Assigned to appropriate individual. Date Assigned: 312 41Zo Lb Date Due: (o 13 IIZo2,b
er I� Pap copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and
/ appears generally complete;QK pN"0
�] Electronic copy submitted: All supporting documentation and certification form(with time/date stamp)signed by responsible
official has been received.
Comments: �`�� r � �
Inventory Review
1� All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
u Contact,address,phone number changes entered into I-Bcam/Facilities if necessary.
All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
Check if SCC codes for each OS are accurate and update if needed.
Evaluate"U"sources for significance and address according to policy.
Calculations/forms appear to add up correctly.
All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds, large emissions increase/decrease,installation
d without a permit).
All volatile HAPs/TAPs were included in the VOC total.
Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP42,etc.).
Review facility comments and address any issues.
Update ED(Data Entry Main)if additional information is required(corrections due date and date received).
d Check all ED QA/QC reports.
Q/' Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained.
p Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
Print and attach the facility total report.
Date Into Requested: Date Info Received: Total Days on Hold:
Date Review Complete: t o/ 3 61.2o Z-,O Signature: Z� �
Date Submitted to EI Coordinator: /t-o/12g4
Date Approved: I r f Olt f 21.6 Initials: GTE

CY2019 Inventor+Review Notes
• There are hand-written review notes made within the hard copy of the inventory.
• I reviewed all factors and calculations.There were no changes to Avoca's emissions factors and calculation
methods.
Emergency Engines
• They decided to document the fire pump emissions separately from the generators. However,they used a
Group with fuel oil tanks to quantify fire pump emissions without pulling the pump into the group. I had to
remove it from the generator group,delete the OS,get rid of the group they created for the fire pump,create a
new OS and re-enter the fire pump data.
• Fire Pump fuel use increased by 7.6%,and PkGEN fuel use decreased 31.7% from usage in CY2018. The
Generator fuel usage was 6.36 times greater than usage in 2018.
• I added chromic acid, lead,manganese,mercury and nickel emissions to all of the engines' OS.
• I corrected the PK-GEN throughput in OS 12.
Boilers
• Fuel oil usage drastically decreased on Boilers H101-103 (11.7%of gallons burned in 2018). H103 did not
operate.
• H101 and H102 emissions were split into two operating scenarios;however,Brian used existing Group 9 to
enter emissions for H101,but H101 was tied to GR7/OS60 for the propane boiler.I removed OS60,and
eliminated GR7 so that I could pull H101 in with GR9(which also has fuel oil tanks listed).I then had to re-
enter emissions into a new OS for H104.
• I zeroed the S02 emissions from H101-102 for low sulfur fuel oil in the hard copy of the inventory.
Combined emissions are 0.008 tpy due to 0.0014%sulfur content.
• Wood combustion in the BB1 and BB2 boilers increased 3.8%by weight of wood fired in CY2018.
• I added several toxics to ED using the DAQ spreadsheet for wood combustion. If a combustion HAP in the
spreadsheet was not listed in ED,it is because the facility-wide emissions are below reportable threshold,or
the emission is negligible and won't affect the facility total. A 99%control efficiency was applied to the
metal HAPs. I added these emissions to IBEAM ED CY2017 and CY2018 data as well.
• With the exception of hexanes,ethyl acetate,chloroform,methanol,and toluene,all other HAPs emitted at
Avoca are generated from fuel combustion. The factors have not changed.
• I calculated HCL and Hg emissions using 2016 emissions testing results on the wood boilers.
Process Emissions
• There were no new methods of calculation nor new factors for Avoca's process areas.
• Process VOC emissions are comprised of chloroform,ethanol,hexanes,heptane,methanol,and ethyl acetate.
All of Avoca's process emissions are determined through mass balance. Avoca uses purchasing records,daily
formulation and batch records,daily tank level measurements,waste shipment records,process design
calculations,MACT MON formulas,and fugitive and point source splits based on overall VOC usage.
• The process area operating scenario throughputs are in-feed weights of raw material to the processes(i.e.tons
sage, SFG raw lbs sclareol,SDE raw infeed,etc.).

• The OS numbers on Avoca's calculation spreadsheets need to be updated.
• Note that the MON provides equations to use for calculation of emissions for some of the sources.However,
these calculations do not take fugitive loss into account. Avoca reports both point and fugitive emissions
based on inventory tracking/mass balance.
• Avoca assumes that the bulk of heptane and ethyl acetate emissions from SFG are fugitive.Based on old
hexane values and using MON batch calculations to back into it,approximately 80%of emissions are
estimated fugitive and 201/6 are out the stacks.
• Explanation of the fugitive and point splits for hexanes from Rotocel and Recovery(see calcs in the hard
copy): Accountable emissions are those Avoca can verify along with the emissions coming out the final
stack; hexane going to wastewater,hazardous waste,or in the spent sage material.Using test data,Avoca
calculates the average hexane per day exiting the MO Scrubber was 158.761bs. Then multiply 158.76 times
the number of days run out the stack. The average n-hexane content of the solvent is used to calculate the
split of hexane isomers and n-hexane. Fugitive hexane is calculated by subtracting the accountable hexane
from the total hexane used.
• Reminder: More than a third of the methanol"lost"from the Rotocel&Recovery operation goes to WWTP.
Of that,98-99%is consumed by the biological activity in the WWTP,while emitting the remainder. The
WWTP emission is calculated through the Water 9 program. The other two thirds of methanol"lost"from
Rotocel&Recovery is"fugitive." Brian has noted that some of the"fugitive"losses are also actually going
out the stack of the Mineral Oil Scrubber as well,but most of it would be in the lines and from the tanks
located in recovery
• It was unclear as to what process emitted pentanone(and the lbs emitted). On 11/01/2020 Brian Conner
emailed that 145 lbs pentanone were emitted from Botanical.I added this amount to the total VOC in the OS.
• On 11/01/2020 Brian Conner emailed me the electronic copy of the emissions inventory calculations
spreadsheets. They are saved in SharePoint.
Facility Totals
• While CO emissions from H101-103 decreased,CO emissions are primarily created by the wood boilers,
which increased by 3.8%in combustion for CY2019.There is also a new propane boiler E-104 that
contributed an additional 3.4 new CO tons emissions for CY2019.
• PM/PM10 decreased due to decrease in operation of H101 and H102 boilers. H103 was not operated at all.
Fuel use across these boilers in CY2019 were 11.7%of gallons burned in CY2018.
• Arsenic,beryllium,cadmium, lead,mercury,nickel,and flourides decreased greatly due to reduction in
operation of H101 and H102.Boiler H103 did not operate.
• Chromic acid and manganese decreases from boilers H101-103 were tempered by the 3.8%increase in
operation of the wood boilers.
• Production for CY2019 decreased at EVG, so chloroform usage decreased.
• N-hexane emissions were reduced due to reductions at SDE-2(44,486 lbs in CY2018 down to 23,317.32 lbs
in CY2019).
• Methanol emissions decreased in all production areas of the plant.
• Toluene increased by 1,460.8% because it was used in the PNE extractions process. In CY2018 it was only
emitted from combustion in the boilers and engines.
(SharePoint\Bertie08\00044\CY2019 Avoca EI Review Notes.doc)
i

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr
Pollutant CAS CY 2019 CY 2018 Demini- Change
from ED from Fees mus
Nitrous Oxide (N20) 10024972 1.31 1.29 1.0 1.6%
Methane (CH4) 74-82-8 2.11 2.04 10.0 3.7%
Carbon Dioxide (CO2) 124389 20,375.20 26,872.98 5,000.0 -24.2%
CO2 equivalent(sum of individual GHG pollutant emissiot 18,892.73 metric tons
times their 1995 IPCC Global Warming Potential (GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
CO co 23.73 20.88 0.5 13.V/o
NOx NOx 31.81 30.93 0-57 2.8%
PM(TSP) TSP 0.444000 1.41 0.5 -68.6`%o
PM10 PM10 0.354000 0.584000 0.5 -39.4°/,
PM2.5 PM2.5 0.310000 0.314000 0.5 -1.3%
S02 S02 2.67 2.57 0.5 3.9%
VOC Voc 1,403.40 1,280.53 0.5 9.6%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Arsenic & Compounds (total mass of elemental AS, arsine and 0.100900 0.452930 0.01 -77 7%
all inorganic compounds)
Arsenic Unlisted Compounds - Specify Compound ASC-Other 0.100900 0.452930 0.01 1 -77.7/o
(Component of ASC)
Beryllium & compounds (Total mass) 0.045100 0.310450 1.0 1 -85.5%
Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.045100 0.310450 1.0 -8,5.5°/)
Cadmium & compounds (total mass includes elemental metal) 0.050900 0.316450 0,1 I -83.9
11/01/2020 Page 1 of 5

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Cadmium Metal, elemental, unreacted (Component( 7440-43-9 0.050900 0.316450 0.1 -83.91%o
CDC)
Chromium -A1UTotal(includes Chromium (VI) categories, 0.704900 0.978150 0.1 -27.9%
metal and others)
Chromic acid(VI) (Component of So1CR6 & CRC) 7738-94-5 0.704900 0.978150 0.01 -27.9%
Chromium (VI) Soluble Chromate Compounds (Component of 0.704900 0.978150 0.01 -27.9%
CRC)
Chromic acid (VI) (Component of So1CR6 & CRC) 7738-94-5 0.704900 0.978150 0.01 -27.9
Lead& compounds 0.210700 1.01 1.0 I -79.1%
Lead Unlisted Compounds - Specify Compound PBC-Other 0.210700 1.01 10.0 1 -79.2% 1
(Component of PBC)
Manganese& compounds 3.26 3.68 10.0 -11.4%
Manganese Unlisted Compounds - Specify Compoui MNC-Other 3.26 3.68 10.0 -11.4'11/40
(Component of MNC)
Mercury& Compounds-all total mass includes Hg Vapor 0.095900 0.364150 0.001 1 -73.7%
Mercury, vapor(Component of HGC) 7439-97-6 0.095900 0.364150 0.001 -73.7%,
Nickel& Compounds, sum total mass includes elemental 0.103900 0.368150 1.0 -71.8%
Nickel metal (Component of NIC) 7440-02-0 0.103900 0.368150 1.0 -71.8°/o
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.516610 0.497130 1.0 13.9%
Benzo(a)pyrene (Component of 83329/POMTV& 50-32-8 0.516610 0.497130 1.0 3.9%
56553/7PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 20.13 19.50 1.0 3.2%
or To
Benzo(a)pyrene (Component of 83329/POMTV& 50-32-8 0.516610 0.497130 1.0 3.9%
56553/7PAH)
Naphthalene (Component of 83329/POMTV) 91-20-3 19.62 19.00 1.0 3.2%
Acetaldehyde 75-07-0 164.94 158.81 10.0 3.9%
Acrolein 107_02_8 794.31 764.88 10.0 3.8%
Benzene 71-43-2 836.24 806.38 1.0 3.7%
11/01/2020 Page 2 of 5

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Carbon tetrachloride 56-23-5 8.94 8.61 1.0 3.8%
Chlorine 7782-50-5 156.87 151.06 100.0 3.8%
Chlorobenzene 108-90-7 6.55 6.31 10.0 3.9%
Chloroform 67-66-3 17,687.56 70,014.35 100.0 1 -74.74,
Ethyl acetate 141-78-6 36,922.18 34,981.26 10.0 5.5%
Ethyl benzene 100414 6.23 6.52 100.0 -4.5%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.76 5.54 1.0 4.0%
Fluorides (sum of all fluoride compounds as mass of 16984-48-8 3.15 26.93 10.0 -88.30/0
ion)
Formaldehyde 50-00-0 878.06 876.22 10.0 0.2%
Hexane isomers, except n-hexane HEXANEISO 1,711,221.8 1,580,053.7 100.0 8.3%
9 9
Hexane, n- 110-54-3 53,333.93 64,978.00 100.0 -17.9
Hydrogen chloride (hydrochloric acid) 7647-01-0 13.50 13.00 100.0 3.8%
Methanol (methyl alcohol) 67-56-1 528,700.94 599,327.84 1,000.0 -11.81�.
Methyl bromide (bromomethane) 74-83-9 2.98 2.87 1.0 3.8%
Methyl chloride (chloromethane) 74-87-3 4.57 4.40 1.0 3.9%
Methylene chloride 75-09-2 57.59 55.45 1.0 3.9%
Phenol 108-95-2 10.13 9.75 100.0 3.9%
Polycyclic Organic Matter (Inc PAH, dioxins, etc. N poM 24.80 26.28 1.0 -5.6%
& AP 42 historic)
Propionaldehyde 123-38-6 1.2.11 11.66 10.0 3.9%
Styrene 10042-5 377.29 363.30 100.0 3.8%
Toluene 108-88-3 3,651.28 233.94 100.0 ,460.80/
Vinyl chloride 75-01-4 3.57 3.44 0.1 3.8%
Xylene (mixed isomers) 1330-20-7 5.58 6.12 100.0 -8.7%
11/01/2020 Page 3 of 5

Largest Individual HAP Methanol (methyl alcohol) 528,700.94 lbs
Total HAP Emissions 606,768.43 lbs
Largest Individual CAP VOC 1,403.40 tons
Total CAP Emissions 1,461.96 tons
Total TAP Emissions 1,826,144.10
lbs
Total Aggregate 1,462.08 tons
Emissions
11/01/2020 Page 4 of 5

DAQ's Comments Regarding Inventory
])Hand-written review notes are in the inventory hard copy. There were no changes to Avoca4s emissions factors and calculation
methods.
2)Fire pump and generators have their own OS this year. However,they used a Group with fuel oil tanks to quantify fire pump
emissions without pulling the pump into the group. I had to remove it from the generator group,delete the OS,get rid of the group
they created for the fire pump,create a new OS and re-enter the fire pump data.
3)Fire Pump fuel increased 7.6%,PkGEN fuel decreased 31.7%,generator fuel increased 636%.
4)Added chromic acid,lead,manganese,mercury and nickel emissions to all enginesZ OS.
5)Corrected PK-GEN throughput OS 12.
6)H101 and H102 are now split into two OS;however,Avoca used existing Group 9 to enter emissions for H101,but H 10 1 was tiec
GR7/OS60/propane boiler. I removed OS60,eliminated GR,then pulled H 101 in with GR9).Then re-entered emissions into new O:
H 104.
7)Added several toxics using the DAQ wood combustion XLS.99%control efficiency fo rmetals applied .
8)HCL and Hg emissions calculated using 2016 testing results/wood boilers.
9)Explanations of the fugitive and point splits for hexanes from Rotocel and Recovery and methanol splits are in hard copy review.
10)It was unclear as to what process emitted pentanone(and the lbs emitted). On 11/01/2020 Brian Conner emailed that 145 lbs
pentanone were emitted from Botanical. I added this amount to the total VOC in the OS.
I])While CO emissions from H101-103 decreased,CO emissions are primarily created by the wood boilers,which increased by 3.8
in combustion for CY2019. There is also a new propane boiler E-104 that contributed an additional 3.4 new CO tons emissions for
CY2019.
12)PM/PM 10 decreased due to decrease in operation of H 101 and H 102 boilers. H 103 was not operated at all. Fuel use across then
boilers in CY2019 were 11.7%of gallons burned in CY2018.
13)Arsenic,beryllium,cadmium,lead,mercury,nickel,and flourides decreased greatly due to reduction in operation of H 10 1 and
H 102.Boiler H 103 did not operate.
14)Chromic acid and manganese decreases from boilers H101-103 were tempered by the 3.8%increase in operation of the wood
boilers.
15)Production for CY2019 decreased at EVG,so chloroform usage decreased.
16)N-hexane emissions were reduced due to reductions at SDE-2(44,486 lbs in CY2018 down to 23,317.32 lbs in CY2019).
17)Methanol emissions decreased in all production areas of the plant.
18)Toluene increased by 1,460.8% because it was used in the PNE extractions process. in CY2018 it was only emitted from
combustion in the boilers and engines.
11/01/2020 Page 5 of 5

Emissions by Operating Scenario
for
Hexane, n-
20191nventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
54 Rotocel/Recovery/Concrete Operations Fugitive 25,211.15 16,908.55
Loss
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P 1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-12513 ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
59 SDE-2 23,317.43 44,486.68
C-4001 C-4001
D-4001 D-4001
ES-4000-F ES-4000-F
ES-4000-W ES-4000-W W
R-4004 R-4004
R-4005 R-4005
R-4015 R-4015
R-4044 R-4044
T-4001 T-4001
T-4017 T-4017
T-4018 T-4018
55 Rotocel, Sage, Recovery, and Distillation 3,380.32 2,694.97
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1

Emissions by Operating Scenario
for
Hexane, n-
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-12513 ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
49 Plant Nutrient Extraction(PNE) 1,425.03 159.05
C-31203 C-31203
D31211 D31211
D31214 D31214
ES-1003-2-1 ES-1003-2-1-F
ES-1003-2-1 ES-1003-2-1-P
ES-1003-2-1 ES-1003-2-1-W
ES-TK-PNE ES-TK-PNE-1
40 Botanical extraction process (includes botanical 728.75
vents, condensers,tanks,etc)
ES-1001-11-F
ES-1001-11-P
ES-1001-11-WI
Total: 53,333.93 64,978.00

Emissions by Operating Scenario
for
Methanol (methyl alcohol)
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
54 Rotocel/Recovery/Concrete Operations Fugitive 514,673.18 580,506.85
Loss
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-125B ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
32 Waste Water Treatment 1 st Aeration Chamber 9,45 8.77 12,198.62
(Includes methanol usages from PNE and EVG)
W WTP-AT 1 W WTP-AT 1
53 EVG (batch flavorant) 4,568.99 6,010.68
D-1201 D-1201
D-1215 D-1215
D-1218 D-1218
D-2202 D-2202
ES-1003-2-2 ES-1003-2-2-F
40 Botanical extraction process(includes botanical 611.69
vents,condensers,tanks,etc)
ES-1001-11-F
ES-1001-11-P
ES-1001-11-WN

Emissions by Operating Scenario
for
Methanol (methyl alcohol)
20191nventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
Total: 528,700.94 599,327.84

Emissions by Operating Scenario
for
Toluene
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source Ill (Pounds/Yr) Source ID
49 Plant Nutrient Extraction (PNE) 3,461.13
C-31203 C-31203
D31211 D31211
D31214 D31214
ES-1003-2-1 ES-1003-2-1-F
ES-1003-2-1 ES-1003-2-1-P
ES-1003-2-1 ES-1003-2-1-W
ES-TK-PNE ES-TK-PNE-1
57 Biomass Boiler Operation with Wood Chips as fu, 182.69 175.92
source
ES-BB I ES-BB 1
ES-BB2 ES-BB2
ES-RD.19A ES-RD.19A
61 H-102 Boiler 4.03
H-102 H-102
62 H-101 Boiler 2.71
H-101 H-101
ITK9238 ITK9238
ITK9239 ITK9239
65 Generators 0.44
E101 E101
E102 E102
E104 E104
12 Peak Shaving Generator 0.26 0.37
ES-PkGen 1 ES-PkGenl
66 Fire Pump Engine 0.03
FP FP
42 Generators 0.10
E101
E102
E104
FP

Emissions by Operating O eratin Scenario
for
Toluene
2019 Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
58 Boilers 57.54
H-101
H-102
H-103
Total: 3,651.28 233.94

11/1/2020 Mail-Huddleston,Betsy-Outlook
[External] RE: One question concerning 2019 Emission Inventory
Brian Conner <[e-mail]>
Sun 11/1/2020 8:01 AM
To: Huddleston, Betsy<[e-mail]>
1 1 attachments(751 KB)
2019 AAE Calc.xls;
CAUTION: External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment
to [e-mail]
Betsy,
The pentanone was actually used in the Botanical Extraction (OS-10) operation in December of 2019. 1 went back
and changed this in the spreadsheet.The values should be correct in there now and the VOCs are accounted for in
Botanical Extraction.
I attached the updated spreadsheets with the Pentanone page and the Monthly VOCs page updated.There were
145 lbs. of pentanone emitted from Botanical Extraction in December 2019.
Thanks,
Brian
From: Huddleston, Betsy<[e-mail]>
Sent:Saturday, October 31, 20201:08 AM
To: Brian Conner<[e-mail]>
Subject:One question concerning 2019 Emission Inventory
"'This is an external email message.Confirm the sender before opening attachments or clicking links.Avoid content that looks suspicious.—
Hey Brian,
I noticed that pentanone was reported as emitted from PNE for CY2019 at 36,776 Ibs, but I don't see it
added to the PNE VOC total. May I add this to the total in AERO?
Betsy Huddleston, Regional Supervisor
NCDEQ, Division of Air Quality
Washington Regional Office
943 Washington Sq. Mall, Washington, NC 27889
Phone: [phone]
Fax: [phone]
hopshttps
jLdeq nc.gov/about/divisions/air-quality
************************************************************************
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
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11/1/2020 Mail-Huddleston,Betsy-Outlook
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Huddleston, Betsy
From: [e-mail]
Sent: Tuesday, March 24, 2020 9:14 AM
Subject: Inventory submission confirmation -- 0800044
Dear Brian Conner
Your submittal of the 2019 emission inventory for Avoca LLC, 0800044, has been received by the North Carolina Division of Air Quality (DAQ) on March 24,
2020 at 09:13:58. You have until the due date of the emission inventory or two weeks from this submittal to review and repudiate the data submitted.
Please remember to:
- print the Certification Form (see AERO Closeout page),
- have the Responsible Official sign it in blue ink,
- include copies of spreadsheets or calculations used in creating this inventory, and
- mail (postmark) it to NCDAQ, 943 Washington Square Mall,Washington, NC 27889 by the required due date in order for this submittal to be considered
complete. If you have any questions, please feel free to contact Betsy Huddleston, in the Washington Regional Office, at252-946-6481.
The Division of Air Quality thanks you for using AERO, the on line emissions inventory program.
Sincerely
DAQ
' 1

Avoca,LLC
4rA PO Box 129
Avoca, LLC 841 Avoca Farm Rd forMerry Hill,NC 27957
The World's Premier Botanical Extraction Company Phone: [phone]
Fax: [phone]
March 24,2020
Mr. Robert Fisher
Environmental Regional Supervisor II-Air Quality
NC Division of Air Quality
Washington Regional Office
943 Washington Square Mall
Washington,NC 27889
Subject: Annual Air Emissions Inventory
Air Quality Permit No. 01819T53
Facility ID: 07/08/00044
Avoca, LLC
Merry Hill,North Carolina
Bertie County
Fee Class: Title V
Dear Mr. Fisher:
In accordance to Avoca, LLC's Title V Air Quality Permit, I am forwarding the Inventory Certification
Form and supporting documentation for the Annual Air Emissions Inventory. The inventory was
submitted on March 24, 2020 via the AERO program. The attached certification form and copies of
spreadsheets and calculations used in creating this inventory are being submitted to fulfill the
requirements of the annual report.
If there are any questions or comments concerning the included documentation or inventory report please
contact me at(252)325-0335.
Sincerely,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, LLC
D r�� c
V E DD
MAR 26 2
Qq0 WARO

COPY of RECORD Date Submitted: 3/24/2020 09:13:58
Inventory Certification Form(Title V)
Facility Name: Avoca LLC Facility ID • 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environmental Quality
Division of Air Quality
Air Pollutant Point Source Emissions Inventory-Calendar Year 2019
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of rTecoF for your facility is Augustinus Gerritsen
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC
2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the
following:
1. For a corporation:a president,secretary,treasurer,or vice-president of the corporation in charge of a principal business
function,or any other person who performs similar policy or decision making functions for the overall operation of one or
more manufacturing,production,or operating facilities applying for a or subject to a permit and either
i. the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in
second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2. For partnership or sole proprietorship;a general partner or the proprietor,respectively;
3. For a municipality,state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION STATEMENT:
(Important: Legally Responsible Official,read and sign after all submissions are final.l
I certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in
this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal
penalties of up to$25,000 per occurrence and possible imprisonment as outlined in G.S. § 143-215.3(a)(2))
Responsible Official's Signature Below (use blue ink): Date Signed: 3 2N 0 Z D
Printed Name: Augus . s Ge en
Signature:
This form applies to Title ac' ies. If this facility is not classified asTitle V,please telephone your regional office Emission
Inventory Contact at o or oper forms.
Email address of Responsible Official: Quin , a1�32�rr ► _Ce" C° outs'M Q'^d a i G V I r 1
Information on this Form cannot be held confidential
M A R 2 6 2020
COPY of RECORD Date Submitted: 3/24/2020 09:13:58 W
1

L,r�c�Fe )r�0►�L�
Annual Air Emissions Inventory Summary
2019 Totals Facility ID#:08000"
Prapxn W-- awyN Nb11w Bdxwllb EdxwBdr. 91- Bobrinl Mad Oe1x
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/l/v1/ZpLo
Annual Air Emissions Inventory
Facility ID#:0800044
Pentanone (Methyl Propyl Ketone): OS-7, OS-10
Year: 2019
Info: Lbs/Gal= 6.01
Monthly Inventory of Pentanone(gallons):
Beginning Max Used
Month InventoryReceived (Lbs) New Used Recovered Used Recovered
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
July: 0 0
August: 0 0
September: 0 0
October: 0 0
November: 0 0
December7 0 6144 36922 1 6119 1 1 6095
Total Gallons of Pentanone used during the year: 6119
Gallons of Pentanone used during the year @ PNE(OS-7):
Lbs.Of Pentanone used during the year @ PNE(OS-7): 0
Gallons of Pentanone used during the year@(0S-10): 6119
Lbs.Of Pentanone used during the year @(OS-10): 36775
Lbs.of Pentanone used by Misc.,QA,and R&D:
Lbs.of Pentanone sent to hazardous waste:
Lbs.of Pentanone sent offsite:
Lbs.of Pentanone emitted during year: 145

Disposed Monthly Used Ending
LL9-sl Inventory
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
6095 1 145 24

Annual Air Emissions Inventory Summary
2019 Totals Facility ID#:0800044
POIIUGM Bdw e1 e4d.eR -a.,q Propane OanM Gn82 pyna Oen N4 Pe-0en Flm Pump Biomass "-0 Reco CanrxRa RecrysblllzNbn SCNredMe SNaraolNM Blartrosa BOUnkal PIYII OBIa1
Boyer a4 Boilers e4rY (SFO) (SDE-1) (SOE-3) Ew_tl n Eatractbn f EVO 1V19TP hoeaaan T.W. lath
CO 38e.26136 573.44059 0.00D00 89.53505 9.25083 13,02544 O.000m 12.37417 19.99591 6.20852 19360,T 20470,912 Taa7r
A4elharo Om102 O.m152 0.00000 0.28881 O.m190 0.00265 O.000m 0.00253 0.00108 0.00025 2m 2.388 TarolYr
Ore ox" 0. A0303 0. 1 O.00D28 00318 0. 1. 1. T
P .D5616 0.083216 0.00000 0.02191 0. 110 0. 1 0.00000 O. 813 0 0.011110 0139 0437 T
P 10 0,01702 0. O.Omm 0. 191 110 0. 1 002813 001180 0.138 0. T
PM..S 0.OD53 0.01 0 110 00295 002B13 04Sf 0.01180 0.139 03p4 T r Z 67
Sm 107615 0.00m0 0. 0.02975 0.04175 0.00000 9.03966 O.m579 1 4. Ta Y,
0.OD339 0. 9.00000 5.81 eM11 0.9475 0.00000 0.90014 .45458 0.16789 1. 31.811 T
VO 0.00:410 000505 000000 0.05945 O.O11i88 0. .00000 0.02250 .1eXN 0.01371 18879 31.1 1 .1 I. 1 T
wWYr
CO 012531 0, 3 7 0.00000 1 0.39637 0. 17 19 T
ACN+Men 0.01063 0.0 0.00000 0,01415 002291 0.05M 164.8 5 1 �Yrr
Acrddn 0.00332 0. O.000m 0. 0.00716 0.m704 791
Araank 0.01906 0.00000 769 0.00237 D.ODOM 0. 0.00384 0. LeVYr
Biro 0.m359 .1 OAOODO 032743 0.45955 ODD00 0.43557 0.7 0.07104 834.002 LBW,
a 000011 OOm1 0. 0. 14 0. 0.00001 0.516 r
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8u LearYr
C-i- O.O1Q9 OMIM O.mOm OW127 0.0017 0.00169 O.00Z73 0.00023 ppp
Calcium
Om LlalYr
Careon iNracnq
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Cnbnro 156,872
CnloroGrizene 0,553 156.8nLIu7Yr
Cnbrorarm LBW,
1 17 6553 L r
Cnramium 0.0142. . 1 O.- 0,036 LW14
nromw Dome 7
OEft, -100%mine 14514.341 1434
0.00 .m LDa/Yr
-SDA 0.00 O. 4304.512 L r
EtW acNata 35962.00 172.1f 788.00 ODD 38MAW LIMO
Ern Benzene 781 0.011 6.156 6.225 1
Et nearomirro 0.00 0.
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Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2019
Total Run Time: 2225.0 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 20985.3 41017.7 0.0 62003.0 587.0 512.8 0.0 1099.8 0.035 12.401
February: 544.8 445.9 0.0 990.7 25.1 38.8 0.0 63.9 0.001 0.198
March: 1926.1 5804.8 0.0 7730.9 55.8 193.3 0.0 249.1 0.004 1.546
April: 1078.2 1016.7 0.0 2094.9 31.2 31.6 0.0 62.8 0.001 0.419
May: 124.5 506.8 0.0 631.3 10.8 29.3 0.0 40.1 0.000 0.126
June: 4811.5 25.7 0.0 4837.2 144.2 5.4 0.0 149.6 0.003 0.967
July: 635.0 75.4 0.0 710.4 23.9 10.9 0.0 34.8 1 0.000 0.142
August: 937.2 295.8 0.0 1233.0 38.7 28.5 0.0 67.2 0.001 0.247
September: 1131.1 165.9 0.0 1297.0 55.4 43.3 0.0 98.7 0.001 0.259
October: 675.7 0.0 0.0 675.7 18.9 0.0 0.0 18.9 0.000 0.135
November: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.000 0.000
December: 1184.2 1168.7 0.0 1 2352.9 171.2 1 88.9 0.0 340.1 0.001 0.471
Total: 34033.6 50523.4 0.0 1 84557.0 1162.2 1062.8 0.0 2225.0 0.047 16.911
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 29.3 1162.2 34033.E CY2�i p�J u-�, 7Z,W11M
2 H-102 143 47.5 1062.8 50523.4 V /
3 H-103 180 #DIV/0! 0.0 0.0
Total 466 #DIV/01 2225 84557.0
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. Tons/Yr Tons/Yr Tons/Yr Tons/Yr
TSP 3.30 0.056 0.083 0.000 0.140
PM-10 1.00 0.017 0.025 0.000 0.042
PM-2.5 0.25 0.004 0.006 0.000 0.011
Sox 42.60 0.725 1.076 0.000 1.801 $O (5 fl•0014 �i S So 11L9/1af
Nox 0.20 0.003 0.005 0.000 0.008
VOC 0.20 0.003 0.005 0.000 0.008
CO 5.00 0.085 0.12E 1 0.000 0.211
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.019 0.028 0.000 0.047
Benzene 2.75E-03 0.094 0.139 0.000 0.233
Beryllium 4.20E-04 0.014 0.021 0.000 0.036
Cadmium 4.20E-04 0.014 0.021 0.000 0.036
Chromium 4.20E-04 0.014 0.021 0.000 0.036
Chromium VI 2.90E-05 0.001 0.001 0.000 0.002
-Ethyl benzene 8.17E-04 0.028 0.041 0.000 0.069
Flouride 3.73E-02 1.269 1.885 0.000 3.154
-Formaldehyde 4.80E-02 1.634 2.425 0.000 4.059
Lead 1.26E-03 0.043 0.064 0.000 0.107
Manganese 8.40E-04 0.029 1 0.042 1 0.000 0.071
Mercury 4.20E-04 1 0.014 1 0.021 1 0.000 0.03E
T:\EH&S\EnvironmentalWir Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc
i

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Na thalene 3.30E-04 &011 0.017 1 0.000 1 0.028
Nickel 4.20E-04 0.014 0.021 0.000 0.036
Toluene 7.97E-02 2.712 4.027 0.000 6.739
o-X lene 1.40E-03 0.048 0.071 0.000 0.118
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)
COz 22700.00 664.74 1079.11 #DIV/01 386.28 573.44 #DIV/0! #DIV/0!
Methane 0.06 0.0018 0.0029 #DIV/0! 0.0010 0.0015 #DIV/0! #DIV/0!
(CH4)
Nitrous Oxide(N20) 0.12 0.0035 0.0057 #DIV/01 0.0020 0.0030 #DIV/01 #DIV/01
/?"hyf ChI oForr7) Z.3(oE-V !b
/74'as5'e
!'one 3,3 E-3 1b/yaao5 P - 0 .1-79 Ib t6r�
�'26er�ivn" z.I E:-s /b
llcoc9Jt
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc
1

Annual Air Emissions Inventory
Facility ID#: 0800044
Propane Boiler : OS-???
Year: 2019
Total Run Time: 7445.0 Hrs/Yr
Efficiency: 95 %
Sulfur Content: 0 %
Propane 91000 Btu/Gal
Propane Hours VOC
Month Used Operated Emissions
Gallons Lbs
January: 67598.0 432.0 13.5
February: 102863.0 672.0 20.6
March: 135929.0 720.0 27.2
April: 108758.0 720.0 21.8
May: 60801.0 600.0 12.2
June: 23248.0 504.0 4.6
July: 51394.0 744.0 10.3
August: 97763.0 744.0 19.6
September: 91919.0 626.0 18.4
October: 27432.0 648.0 5.5
November: 55277.0 587.0 11.1
December: 71474.0 448.0 14.3
Total: 894456.0 7445.0 178.9
Boiler# ID # GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-104 120.1 7445.0 894456.0
Criteria Pollutants
Criteria Emisson Factor Boiler#4
Pollutants Lbs./1000 al. Tons/Yr
TS P 0.05 0.022
PM-10 0.05 0.022
PM-2.5 0.04 0.018
Sox 0.02 0.009
Nox 13.00 5.814
VOC 0.20 0.089
CO 7.50 3.354
Green House Gas Pulutants
Emission Boiler#4 Boiler#4
GHG Pollutant Factor (Ibs/hr) (tons/yr)
(Ibs/1000 gal)
COz 2^�i12,C! 24.05 89.54
i

Methane 0.60 0.07 0.27
(CH4)
Nitrous Oxide 0.12 0.01 0.05
(N2O)

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only! ( b �
Year: 2019 D r
Total Run Time: 27.0 HrslYr f ` P-
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC /V0 Cp AKGE 1 N 1'r
Month Fuel
Used Operated hour (Ibs.)
January: 50.0 2.50 20.0 2.604
February: 30.0 1.50 20.0 1.562
March: 40.0 2.00 20.0 2.083
April: 30.0 1.50 20.0 1.562
May: 100.0 5.00 20.0 5.208
June: 50.0 2.50 20.0 2.604
July: 40.0 2.00 20.0 2.083
August: 60.0 3.00 20.0 3.125 LY uj/'t 5 p 1 C((,t S
September: 40.0 2.00 20.0 2.083
October: 40.0 2.00 20.0 2.083 Qp�yZ
November: 30.0 1.50 20.0 1.562
December: 30.0 1.50 20.0 1.562
Total: 540.0 27.00 20.0 28.1
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Fir Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 285 214 27.0 20.0 540.0 2.82 76.14
Criteria Emisson Factor (Lb/MM FP
Pollutants BTU) (TonsNr
TSP 0.31 0.012
PM-10 0.31 0.012
PM-2.5 0.31 0.012
Sox 0.152 0.006
Nox 4.41 0.168 �Y`dYAl 4!J
VOC 0.36 0.014
CO 0.95 0.036
Green House Gases
Hazardous/Toxi Emisson Factor (Lb/MM FP GHG Emisson Factor E101
c Air Pollutants BTU) (Lbs/Yr) Pollutant K /MM BTU tons! r
CO2 73.960 6.209
Acetaldehyde 7.67E-04 0.058 0.003 0.000252
Nitrous
Acrolein 9.25E-05 0.007 Oxide 0.0006 0.000050
(N20) J/� �Z7 Er
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.071 �.2,?
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002
-Formaldehyde 1.18E-03 0.090
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.031
X lene 2.85E-04 0.022

GAS&DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR REVISIONS 6/22/2015--OUTPUT SCREEN
�� Instructions: Enter emission source/facility data on the"INPUT'tabiscreen.The air emission results and summary of input data are
4 viewed/printed on the'OUTPIIT"tab/screen.The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the information contained.
�`� This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available.
NCDENR DENR is not responsible for errors or omissions that may be contained herein-
SOURCE/
/USER INPUT SUMMARYPUTS
COMPANY: Avoca PERMIT
ID NO.: 800044
PERMIT NUMBER: 0
EMISSION SOURCE DESCRIPTION: 214 HP POWER OUTPUT DIESEL INTERNAL COMBUSTION ENGINE FACILITY CITY: Merry Hill
EMISSION SOURCE ID NO.: FP FACILITY COUNTY: Bertie / , 'r•UT-�
SPREADSHEET PREPARED BY: ETH POLLUTANT CONTROL EFF.
ACTUAL THROUGHPUT 540 GALS COMBUSTED I FUEL HEATING VALUE: 1400001 BTU/GAL PM 0
REQUESTED ANNUAL LIMITATION 28,000 GALS COMBUSTED CALCULATIONS: 0.138 mm BTU/GAL PM10 0
SULFUR CONTENT OF DIESEL FUEL(%) 0 PM2.5 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF S02 0
CARBON CONTENT USED FOR GHGS(kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN NOX 0
CO 0
VOC 0
CftfrERIA AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
Inr�n carraa. ns/ ra�coemasvr�*sl tacovn:oksnwirsl INhpM
AIR POLLUTANT EMITTED Ib/hr s tons/ Ib/hr tons/yr Ib/hr tons/yr uncontrolled
PARTICULATE MATTER PM 0.47 0.01 0.47 2.06 0.47 0.62 2.20E-03
PARTICULATE MATTER<10 MICRONS(PM1e) 0.47 0.01 0.47 2.06 0.47 0.62 220E-03
PARTICULATE MATTER<2.5 MICRONS(PM,.,) 0.47 0.01 0.47 2.06 0.47 0.62 2.20E-03
SULFUR DIOXIDE S02 0.00 0.00 0.00 0.01 0.00 0.00 1.21E-05
NITROGEN OXIDES NOx 6.63 0.17 6.63 29.06 6.63 8.68 3.10E-02
CARBON MONOXIDE CO 1A3 0.04 143 6.26 1.43 1.87 6.68E-03
VOLATILE ORGANIC COMPOUNDS(VOC) 1 0.54 1 0.01 1 0.54 2.36 1 0.54 0.70 1 2.51E-03
TOXIC/HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
CAS IAFreecoernoksiuunsl (eF-mvmoksi.-) I-.-airnsl Ib/hphr
TOXIC/HAZARDOUS AIR POLLUTANT NUMBER Ib/hr Ib/ Ib/hr Ib/ Ib/hr I uncontrolled
Acetaldehyde(H,T) 75070 1.15E-03 5.80E-02 1.15E-03 1.01E+01 1.15E-03 3.01E+00 5.37E-06
Acrolein H,T 107028 1.39E-04 6.99E-03 1.39E-04 1.21E+00 1.39E-04 3.63E-01 6.48E-07
Arsenic unlisted compounds(H,T) ASC-Other 5.99E-06 3.02E-04 5.99E-06 5.25E-02 5.99E-06 1.57E-02 2.80E-08
Benzene(H,T) 71432 1.40E-03 7.05E-02 1.40E-03 1.22E+01 1.40E-03 3.66E+00 6.53E-06
Benzo(a)pyrene(H,T) 50328 2.82E-07 1.42E-05 2.82E-07 2.47E-03 2.82E-07 7.37E-04 1.32E-09
Beryllium metal unreacted H,T 7440417 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
1,3-Butadiene(H,T) 106990 5.86E-05 2.96E-03 5.86E-05 5.13E-01 5.86E-05 1.53E-01 2.74E-07
Cadmium metal elemental unreacted H,T 7440439 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Chromic Acid(VI)(H,T) T738945 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Formaldehyde(H,T) 50000 1.77E-03 8.92E-02 1.77E-03 1.55E+01 1.77E-03 4.63E+00 8.26E-06
Lead unlisted compounds(H) PBC-Other 1.35E-05 6.80E-04 1.35E-05 1.18E-01 1.35E-05 3.53E-02 6.30E-08
Manganese unlisted compounds(H,T) MNC-Other 8.99E-06 4.54E-04 8.99E-06 7.87E-02 8.99E-06 2.35E-02 4.20E-08
Mercury vapor H,T 7439976 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Na thalene H) 91203 1.27E-04 6.41E-03 127E-04 1.11E+00 1.27E-04 3.32E-01 5.94E-07
Nickel metal H, 7440020 1 4.49E-06 I 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Selenium compounds(H) SEC 2.25E-05 1.13E-03 2.25E-05 1.97E-01 2.25E-05 I 5.88E-02 1.05E-07
Toluene(H,T) 108883 6.13E-04 3.09E-02 6.13E-04 5.37E+00 6.13E-04 1.60E+00 2.86E-06
Xylene H,T 1330207 4.27E-04 2.15E-02 4.27E-04 3.74E+00 4.27E-04 1.12E+00 2.00E-06
Highest HAP(Formaldehyde) 50000 1.77E-03 8.92E-02 1.77E-03 1.55E+01 1.77E-03 4.63E+00 8.26E-06
Total RAPS 5.75E-03 2.90E-01 5.75E-03 5.04E+01 5.75E-03 1.51E+01
TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR PERMITTING PURPOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS EMISSION FACTOR
Ib1hp4v
TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day lblyr uncontrolled
Acetaldehyde(H,T) 75070 1.15E-03 2.76E-02 3.01E+00 5.37E-06
Acrolein(H,T) 107028 1.39E-04 3.33E-03 3.63E-01 6.48E-07
Arsenic unlisted compounds H, ASC-Other 5.99E-06 1.44E-04 1.57E-02 2.80E-08
Benzene(H,T) 71432 1.40E-03 3.35E-02 3.66E+00 6.53E-06
Benzo(a)pyrene H,T 50328 2.82E-07 6.76E-06 7.37E-04 1.32E-09
Beryllium metal(unreacted)(H,T) 7440417 4.49E-06 1.08E-04 1.18E-02 2.10E-08
1,3-Butadiene(H,T) 106990 5.86E-05 1.41E-03 1.53E-01 2.74E-07
Cadmium metal(elemental unreacted)(H,T) 7440439 4.49E-06 1.08E-04 1.18E-02 2.10E-08
soluble chromate compounds,as chromium(VI)equivalent SOLCR6 I 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Formaldehyde(H,T) 50000 1.77E-03 4.24E-02 4.63E+00 826E-06
Manganese unlisted compounds H, MNC-Other 8.99E-06 2.16E-04 2.35E-02 420E-08
Mercury vapor(H,T) 7439976 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Nickel metal(H,T) 7440020 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Toluene(H,T) 108883 6.13E-04 1.47E-02 1.60E+00 2.86E-06
Xyiene(H,T) 1330207 4.27E-04 1.02E-02 I 1.12E+00 2.00E-06
GREENHOUSE GAS EMISSIONS INFORMATION(FOR EMISSIONS INVENTORY PURPOSES)-CONSISTENT WITH EPA GHG-POIEN17AL TO EMIT
MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD
DISTXLATE#2 ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat input POTENTIAL EMISbl(JN.S With
rapacity or horsepower and EPA MRR Emission Reuested Emission Limitation-utilize
Factors requested fuel limit and EPA MRR
GREENHOUSE GAS EMITTED EPA MRR CALCULATION METHOD:TIER 1 Emission Factors
metric tons/yr metric tonstyr,CO2s short ton short tonslyr short tons/ ,CO29 short ton short tons/ ,CO2e
CARBON DIOXIDE(CO2) 5.51 5.51 6.08 1,069.83 1,069.83 319.59 319.59
METHANE(CH4) 224E-04 5.59E-03 2.46E-04 4.34E-02 1.08E+00 1.28E-02 3.19E-01
NITROUS OXIDE(N20) 4.47E-0S 1.33E-02 4.93E-05 8.68E-03 2.59E+00 2.56E-03 7.62E-01
TOTAL 5.53 TOTAL 1,073.51 TOTAL 320.67
NOTE: CO2e means CO2 equivalent-
NOTE, The DAQ Air Emissions Reporting Online(AERO)system requires short tons be reported. The EPA MRR requires metric tons be reported.
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Page 1 of 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year: 2019 Total Run Time: 567.0 Hrs/Yr Cy 201 t 87,9 h6
Efficiency: 75
Sulfur Content: 0_3
Number Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Total (Lbs.)
January: 30.0 62.5 0.0 40.0 132.5 6.9
February: 30.0 37.5 0.0 40.0 107.5 5.6
March: 37.5 50.6 0.0 50.0 137.5 7.2
April: 30.0 50.0 0.0 40.0 120.0 6.2
May: 30.0 50.0 0.0 40.0 120.0 6.2 /NO c jjANG�_ /M
June: 2647.5 3637.5 0.0 3530.0 9815.0 511.2
July: 30.0 50.0 0.0 40.0 120.0 6.2
August: 37.5 62.5 0.0 50.0 150.0 7.8
September: 30.0 50.0 0.0 40.0 120.0 6.2
October: 30.0 50.0 0.0 40.0 120.0 6.2
November: 37.5 62.5 0.0 50.0 150.0 7.8
December: 22.5 1 37.5 0.0 30.0 1 90.0 4.7
Total: 1 2992.5 1 4200.0 0.0 3990.0 1 11182.5 1 582.4
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr MM Btu/Hr MM Btu/Yr
1 E101 587 440 199.5 15.0 2992.5 2.12 421.94
2 E102 760 570 168.0 25.0 4200.0 3.53 592.20
3 E103 603 452 0.0 20.0 0.0 2.82 0.00
4 E104 534 401 199.5 20.0 3990.0 2.82 562.59
Total 2484 1863 667 80 11182.5 11 1577
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Pollutants (Lb'MM BTU) (Tons'Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.100 0.021 0.030 0.000 0.028 0.079
PM-10 0.100 0.021 0.030 0.000 0.028 0.079
PM-2.5 0.100 0.021 0.030 0.000 0.028 0.079
Sox 0.141 1 0.030 1 0.042 0.000 0.040 0.111
Nox 3.200 0.675 0.948 0.000 0.900 2.523
VOC 0.080 0.017 1 0.024 0.000 0.023 0.063
CO 0.850 0.179 1 0.252 0.000 0.239 0.670
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total C, 1.e.Ci d_I 4 �
Air Pollutants (Lb/MM BTU) (Lbs/Yr) (Lbs'Yr) (Lbs'Yr) (Lbs/Yr) (Lbs/Yr) ,,u�I�ym � Mt yM
-Acetaldehyde 2.52E-05 0.010633 0.014923 0.000000 0.014177 0.040 �n'� &
I nt I RA/ /
Acrolein 7.88E-06 0,003325 0.004667 0.000000 0.004433 0.012
Arsenic 4.00E-06 0.001688 0.002369 0.000000 0.002250 0.006 C oJr wns
Benzene 7.76E-04 0.327427 0.459547 0.000000 0.436570 1.224
Benzo a rene 2.57E-07 0.000108 0.000152 0.000000 0.000145 0.0004 L 6,62Y tb
Beryllium 3.00E-06 0.001266 0.001777 0.000000 0.001688 0.005
Cadmium 3.00E-06 0.001266 0.001777 0.000000 0.001688 0.005 Q ��
-Formaldehyde 7.89E-05 0.033291 0.046725 0.000000 0.044388 0.124
Na thalene 1.30E-04 0.054853 0.076986 0.000000 0.073137 0.205
Toluene 2.81E-04 0.118566 0.166408 0.000000 0.158088 0.443
X Iene 1.93E-04 0.081435 0.114295 0.000000 O 08580 0.304 ) A r
t-C C cmt55�°�S
Green House Gas Pulutants M" E- �j,� $/ ^^ af
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total 0 `, � -
(Lb/MM BTU) tons/ r tons' r tons' r tons' r tons' r � 3 E - v
COz 43.990 9.2806 13.0254 0.0000 12.3742 34 668 ,f� +�t� .C
Methane ni CK" 3E-L ' l
(CH4) 0.009 0.0019 0.0027 0.0000 0.0025 0.00710 eh-), ors f OY,S -�
Nitrous Oxide ley ) a-$,yw `7
(N2O) 0.001 0.0002 0.0003 0.0000 0.0003 0.000788 AA j� y�d(OLQ
.�}yY,rYwl d
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc Page 1

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
insruaions.Please provide the information shown in blue below.The applicability of this spreadsheets limited to diesel engines larger than 600 hp and all dual-fuel(dieseVnatural gas)engines.
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
User Inout DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca guarantee the accuracy of the Information contained.This spreadsheet is subject to continual revision
Plant County. Bertie and updating.it Is your responsibility to be aware of the most current information available. DENR
Plant City: Merry Hill is not responsible for erron;or omissions that may be contained herein.
Permit Number. NA
User: ETH
Fuel Sulfur Fuel Input Rates Diesel(gal) N cu Heat Input Rates 212W yy¢
Diesel Fuel Sulfur Content(°/s): 0.00 Hourly Fuel Usage: 0.00 t,000 Hourly Fuel Usage (mmBtu): 0.00 1.05
NG Fuel Sulfur Content r/mm cu ft: 2,00o Annual Fuel Usage: 11,183 4,000 Annual Fuel Usage (mmBtu): 1,577 4
Fuel Heat Content: 141,000 1,050(Btu/gal for diesel,Btu/cu.ft for NG)
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant Ib/hr Ib r t Ib/mm8tu Ratin Pollutant Ib/hr Ib/ t Ib/mmBtu Ratin
PM 0.00 157.67 0.08 1.00E-01 B PM NA NA NA NO NA
PM-10 0.00 157.67 0.08 1.00E-01 B PM-10 NA NA NA NO NA
PM-2.5 0.00 157.67 0.08 1.00E-01 B PM-2.5 NA NA NA NO NA
NO uncont. 0.00 5,045.54 2.52 3.20E+00 B NO.uncont. 2.84 4,268.52 2.13 2.70E+00 D
NO.,cont. 0.00 2,996.79 1.50 1.90E+00 B NO.cont. NA NA NA ND NA
TOC(as CH4) 0.00 141.91 0.07 9.00E-02 C TOC(as CH4) 0.84 1,264.75 0.63 8.00E-01 D
NMTOC 0.00 129.13 0.06 8.19E-02 E NMTOC 0.21 316.19 0.16 2.00E-01 E
CO 0.00 1,340.22 0.67 8.50E-01 C CO 1.22 1,833.88 0.92 1.16E+00 D
SO, 0.00 2.39 0.00 1.52E-03 B SO, 10.001 0.21 0.00 1.31E-04 B
Total HAP O.00E+00 2.76E+00 1.38E-03 1.75E-03 NA
Largest HAP benzene 0.00E+00 1.22E+00 6.12E-04 7.78E-04 NA
Toxic/Hazardous Air Pollutants There are no Tokc/Hazardous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number Ib/hr lb/day blyr
Acetaldehyde 75070 0.00E+00 0.00E+00 3.97E-02 2.52E-05 E
crolein 107028 0.00E+00 0.00E+00 1.24E-02 7.88E-06 E
Arsenic unlisted compounds ASC-Other 0.00E+00 0.00E+00 6.31E-03 4.00E-06 E
Benzene 71432 0.00E+00 0.00E+00 1.22E+00 7.76E-04 E
Benzo(a)pyrene 50328 0.00E+00 0.00E+00 4.05E-04 2.57E-07 E,<
Beryllium metal(unreacted) 7440417 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Chromic Acid(VI) 7738945 0.00E+00 O.00E+00 4.73E-03 3.00E-06 E
Formaldehyde 50000 O.00E+00 0.00E+00 1.24E-01 7.89E-05 E
cad unlisted compounds PBC-Other 0.00E+00 0.00E+00 1.42E-02 9.00E-06 E
Manganese unlisted compounds MNC Other 0.00E+00 0.00E+00 9.48E-03 6.00E-06 E
Mercuryvapor 7439976 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Napthalene 91203 0.00E+00 0.00E+00 2.05E-01 1.30E-04 E
Nickel metal 7440020 0.00E+00 O.00E 3.00E-06 E
Selenium compounds SEC O.00E+00 0.00E+00 2.37E-02 1.50E-05 E
Total PAH 0.00E+00 0.00E+00 3.34E-01 2.12E-04 E,<
Toluene 108883 0.00E+00 0.00E+00 4.43E-01 2.81E-041 E
Ixylenes 11330207 1 0.00E+00 0.00E+00 3.04E-01 1.93E-041 E
Greenhouse Gases-methods consistent with TCR other protocol* Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA MandatorvR000rtinaRule Factor Quality but not with EPA Mandatory Reporting Rule Factor Quality
Pollutant Ib r toy (lb/innil Rating Pollutant Ib/hr lb/vr t Ib/mmBtu Rating
Carbon Dioxide(CO2) 254,320.25 127.16 43.99 NA Carbon Dioxide(CO2) 264,811.61 127A1 43.96 NA
Methane(CH4) 347.67 0.17 0.009 NA Methane(CH4) 21,351.48 10.68 0.540 NA
Nitrous Oxide(N20) 621.63 0.31 0.001 NA Nitrous Oxide(N20) 623.29 0.31 0.001 NA
Total: 255,289.55 127.64 Total: 276,786.38 138.39
Note:Do not use greenhouse gas emission estimates from tits spreadsheet for PSD(Prevention of Significant Deterioration purposes.
NO,control is vie ignition timing retard.
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other toxic/hazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"<"indicate an AP-42 emission factor based on test results being below detection.
Emission factors for criteria pollutants are from AP-42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP-42 Chapter 1.3,Fuel Ol Combustion(revised 5/10). N�ENR
All other toxiclhazardous pollutants are from AP-42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines:Stationary Combustion Sources,June 2008,except for CH4,
which uses AP-42,Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP-42 Chapter 3.4,p.3.4-5(revised 10/96).
Hourly emission rates for all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours.

Annual Air Emissions Inventory
Facility ID#: 0800044
PK- Generator : OS-12
Year: 2019
Total Run Time: 89.6 Hrs/Yr CY 2_0 i�
5 S,
Efficiency: 75
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Emisson Emisson
Hazardous/
Fuel Usag a Hours VOC Criteria Factor Pk-Gen Factor Pk-Gen
ons
Month Pollutants (Lb/MM (T /Yr) Toxic Air (Lb/MM Lbs/Yr
(gallons) Operated (Lbs.) Pollutants ( )
BTU) BTU
TSP 0.1 0.0455 Acetaldehyde 2.52E-05 0.0229
January: 180 2.5 9.37 PM-10 0.1 0.0455 Acrolein 7.88E-06 0.0072
February: 108.0 1.5 5.62 PM-2.5 0.1 0.0455 Arsenic 4.00E-06 0.0036
March: 180.0 2.5 9.37 Sox 0.141 0.0641 Benzene 7.76E-04 0.7055
April: 252.0 3.5 13.12 Nox 3.2 1.4546 Benzo a rene 2.57E-07 0.0002
May: 180.0 2.5 9.37 VOC 0.36 0.1636 Beryllium 3.00E-06 0.0027
June: 900.0 12.5 46.87 CO 0.85 0.3864 Cadmium 3.00E-06 0.0027
July: 874.8 12.2 45.56 Formaldehyde 7.89E-05 0.0717
August: 1288.8 17.9 67.12 Na thalene 1.30E-04 0.1182
September: 2052.0 28.5 106.87 Toluene 2.81E-04 0.2555
October: 144.0 2.0 7.50 X lene 1.93E-04 0.1755
November: 180.0 2.5 9.37
December: 108.0 1.5 5.62 (j 1 oU ` 15�r
Total: 6447.6 89.6 335.8 S
Heat Rate
Generator No. ID# Bhp h Hr/Yr Gals/Hr Gals/Yr MM Btu/Hr MM Btu/Yr
Pk Gen Pk-Gen 2670 2003 89.6 72.0 6447.6 10.15 909.11
Green House Gas Pulutants for Peak Generator G'0 p c ItuK �n O Ore.+ t''CIV-1
Emisson Factor //
GHG Pollutant Ibs/yr tons/yr(Lb/MM BTU) -,At047- fc d'aN
C(�J
CO2 43.990 39991.82 20.00 tors
Methane 0.009 8.18 0.0041 r-vV►om lc Ac>d 3 E-
(CHa) L2CI.0 �
Nitrous Oxide(N20) 0.007 6.36 0.00318 M 6-"
7b.�.P
N44-A c--?

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
I nsructions:Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual-fuel(dieseynatural gas)engines.
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca guarantee the accuracy of the information contained.This spreadsheet is subject to continual revision
Plant County. Bartle and updating.It is your responsibility to be swam of the most current information available. DENR
Plant City: Merry Hill is not responsible for errors or omisslons that may he contained herein.
Permit Number. NA
User: ETH
Fuel SuHur Fuel Input Rates Diesel(gall NG icu Heat Input Rates Diesel NG
Diesel Fuel Sulfur Content(°k): 0.00 Hourly Fuel Usage: 0.00 1,000 Hourly Fuel Usage (mmBtu): 0.00 1.05
NG Fuel Sulfur Content r/mm cu ft): 2,00o Annual Fuel Usage: 6,446 4 000 Annual Fuel Usage (mmBtu): 909 4
Fuel Heal Content: 141,000 1,050 (Btu/gal for diesel,Btu/cu.It for NG)
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Oualrty Criteria Pollutants Factor Quality
Pollutant Ib/hr Ib r t (lb/mmBtu) RatingPollutant Ib/hr Ib/ t lb/mmBtu Ratin
PM 0.00 90.91 0.05 1.00E-01 B PM NA NA NA ND NA
PM-10 0.00 90.91 0.05 1.00E-01 B PM-10 NA NA NA ND NA
PM-2.5 0.00 90.91 0.05 1.00E-01 B PM-2.5 NA NA NA ND NA
NO.,uncont. 0.00 2,909.16 1.45 3.20E+00 B NO uncont. 2.84 2,485.94 123 2.70E+00 D
NO.,cont. 0.00 1,727.31 0.86 1.90E+00 B NO.,cont. NA NA NA ND NA
TOC(as CH4) 0.00 81.82 0.04 9.00E-02 C TOC(as CH4) 0.84 730.65 0.37 8.00E-01 D
NMTOC 0.00 74.46 0.04 8.19E-02 E NMTOC 0.21 182.66 0.09 2.00E-01 E
CO 0.00 772.74 0.39 8.50E-01 C CO 1.22 1,059.44 0.53 1.18E+00 D
6<� 0.00 0.00 1.52E-03 B JSO, 10.001 0.12 0.00 1.31E-041 B
Total HAP 0.00E+00 1.59E+00 7.97E-04 1.75E-03 NA
Largest HAP benzene 0.00E+00 7.05E-01 3.53E-04 7.76E-04 NA
Toxic/Hazardous Air Pollutants There are no Toxic/Hazardcus Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number Ib/hr lb/day Ib/yr
ceteldehyde 75070 0.00E+00 0.00E+00 2.29E-02 2.52E-05 E
croleln 107028 0.00E+00 0.00E+00 7.18E-03 7.88E-06 E
rsenc unlisted compounds ASC-Other 0.00E+00 0.00E+00 3.84E-03 4.00E-06 E
Benzene 71432 0.00E+00 0.00E+00 7.05E-01 7.76E-04 E
Benzo(a)pyrene 50328 0.00E+00 0.00E+00 2.34E-04 2.57E-07 E,<
Beryllium metal(unreacted) 7440417 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Chromic Acid(VI) 7738945 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Formaldehyde 50000 0.00E+00 0.00E+00 7.17E-0Z 7.89E-05 E
Lead unlisted compounds PBC-Other O.00E+00 O.00E+00 8.18E-03 9.00E-06 E
Manganese unlisted compounds MNC-Other 0.00E+00 0.00E+00 5.45E-03 6.00E-06 E
Mercuryvapor 7439976 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Napthalene 91203 0.00E+00 O.00E+00 1.18E-01 1.30E-04 E
Nickel metal 7440020 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Selenium compounds SEC 0.00E+00 O.00E+00 1.36E-02 1.50E-05 E
total PAH 0.00E+00 O.o0E+00 1.93E-01 2.12E-04 E,<
Toluene 108883 O.00E+00 0.00E+00 2.55E-01 2.81E 04 E
1Xylenes 11330207 1 0.00E+00 0.00E+00 1.75E-01 1.93E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandatory Re ortin Rule Factor Quality but not with EPA Mandatory R000rtina Rule Factor Quality
Pollutant Itityr t Ib/mmBtu Rating Pollutant Ib/hr lb/yr t (lb/mmBtu) Rating
Carbon Dioxide(CO2) 146,635.84 73.32 43.99 NA Carbon Dioxide(CO2) 147,127.20 73.56 43.93 NA
Methane(CH4) 200.46 0.10 0.009 NA Methane(CH4) 12,334.84 6.17 0.540 NA
Nitrous Oxide(N20) 358.42 0.18 0.001 NA Nitrous Oxide(N20) 360.08 0.18 0.001 NA
Total: 147,194.72 73.60 Total: 159,822.12 79.91
Note:Do not use rsenhouse gas amisslon astlmaus from this s r edshest for P8D Prevention of significant Deterioration)purpmes.
NO,control Is via ignition timing retard.
Pollutants in ,i are federally regulated hazardous air pollutants(HAPs)only. All other toxicthazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing'<'indicate an AP-42 emission factor based on test results being below detection. ���
Emission factors for criteria pollutants are from AP-42 Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP-42 Chapter 1.3,Fuel Oil Combustion(revised 5/10). NCDENR
All other toxic/hazardous pollutants are from AP-42 Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines:Stationary Combustion Sources,June 2008,except for CH4,
which uses AP-42,Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP-42 Chapter 3.4.p.3.4-5(revised 10/96).
Hourly emission rates for all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly Input rate for 24 hours.

Annual Air Emissions Inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2: OS-33
Fuel Source : Wood Chips
Year: 2019
Total Run Time: 8068.0 Hrs/Yr )-
Wood Chips 8000000 BTU /ton So � l�he�5fure C��I� �780�5h►'S ` Z39o1.� ���c�i�P
" Emission Factors determined by Emissions test conducted on 12/19/2013
Boiler Operation (Hours) Wood Chips Burned (Tons) CO PM HCL Hq Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood
Hours Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Chips
January: 608.0 657.0 657.0 681.0 756.2 1437.2 2207.5 16.09664 1.034784 0.00333 11497.6
February: 648.0 672.0 672.0 990.0 1080.5 2070.5 3180.3 23.1896 1.49076 0.00480 16564
March: 701.0 701.0 701.0 718.6 718.6 1437.2 2207.5 16.09664 1,034784 0.00333 11497.6
April: 439.0 439.0 439.0 511.0 512.1 1023.1 1571.5 11.45872 0.736632 0.00237 8184.8
May: 710.0 744.0 744.0 1342.8 1482.8 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
June: 720.0 720.0 720.0 1291.0 1291.0 2582.0 3966.0 28.9184 1.85904 0.00599 20656
July: 744.0 744.0 744.0 1266.0 1267.3 2533.3 3891.1 28.37296 1.823976 0.00588 20266.4
August: 744.0 744.0 2338.4 0.0 2338.4 3591.8 26.19008 1.683648 0.00543 18707.2
September: 624.0 264.0 624.0 1357.0 396.8 1753.8 2693.8 19.64256 1.262736 0.00407 14030.4
October: 744.0 744.0 744.0 1388.5 1388.5 2776.9 4265.3 31.10128 1.999368 0.00644 22215.2
November: 720.0 720.0 1 720.0 1291.0 1291.0 2582.0 3966.0 28.9184 1.85904 0.00599 20656
December: 295.0 559.0 559.0 455.0 1006.5 2244.9 16.3688 1.05228 0.00339 11692
Total: 7697.0 6964.0 8068.0 13630.3 1 11191.3 24821.5 38125.8 278.001 17.871 0.05759 198572.0
Average 641.4 633.1 672.3 1135.9 932.6 8.5 3177.2 23.167 1.489 0.00480 16547.7

06
Criteria Pollutants Z01�
Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler 1al
Pollutants (Lb/MM BTU) (Tons/Yr) Pollutants (Lb/MM BTU) (Lbs/Yr) GY?� 7-0 TA v ZY821.5 1,4S V-00�
TSP 0.0014 0.139 Acetaldehyde 8.30E-04 164.815 S7Z MNtg�U/Y�
PM-10 0.0014 0.139 Acrolein 4.00E-03 794.288
PM-2.5 0.0014 0.139 Benzene 4.20E-03 834.002
Sox 0.03 2.482 Benzo a rene 2.60E-06 0.516
Nox 0.22 21.843 Carbon 4.50E-05 8.936
tetrachloride
VOC 0.02 1.688 r Chlorine 7.90E-04 156.872
CO 0.19 19.063 e 9 Chlorobenzene 3.30E-05 6.553
Chloroform 2.80E-05 5.560
Ethyl benzene 3.10E-05 6.156
Green House Gas Pulutants Formaldehyde 4.40E-03 873.717
Emisson Factor E101
GHG Pollutant (Lb/MM BTU) tons/ r Napthalene 9.70E-05 19.261
CO2 195.000 19360.8 Phenol 5.10E-05 10.127
Methane 0.021 2.1 Propionaldehyde 6.10E-05 12.113
(CH4)
Nitrous Oxide 0.013 1.3 Styrene 1.90E-03 377.287
(N20)
Toluene 9.20E-04 182.686
X lene 2.50E-05 4.964
NO CNAN64 1N
Zo}(, 5 tl�rL,�rs
c� d,000v Ca 8 )V MM 8ttA
fJ o� Z,'1F -7 16/"o & ,�, 5 0.058 1b

WOODWASTE COMBUSTION EMISSIONS CALCULATOR REVISION L 09/03/2019-OUTPUT SCREEN
Instructions: Enter emission source/facility data on the"INPUT"tab/screen. The air emission results and summary of
input data are viewed I printed on the"OUTPUT"tabiscreen. The different tabs are on the bottom of this screen.
A67-
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the
NCDENR Information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware
of the most current information available. DENR is not responsible for errors or omissions that may be contained herein.
SOURCE FA USER SUMMARY MPUT
COMPANY: Facility Name, Inc. FACILITY ID NO.:
01/12100999
PERMIT NUMBER: 9MR02
EMISSION SOURCE DESCRIPTION: 48 MMBTU/HR WET WOOD >19%MOISTURE FIRED BOILER FACILITY CITY: ANYTOWN
EMISSION SOURCE ID NO.: ES-1 FACILITY COUNTY: ANYCOUNTY
PARTICULATE CONTROL DEVICE: MECHANICAL COLLECTOR NO REINJECTION POLLUTANT CONTROL EFF.
SPREADSHEET PREPARED BY: Your Name FUEL HEAT VALUE: 4000 BTU/LB NOX 0
ACTUAL FUEL THROUGHPUT: 24822 TON/YR HHV Used for GHGs HMBTUfrON: 15.38 PM CALC'D AS 31.7%
POTENTIAL FUEL THROUGHPUT: 52560 TON/YR IBOILER TYPE: STOKER PM10 CALC'D AS 29.3%
REQUESTED MAX.FUEL THRPT: 52560 TON/YR IND STACK TEST DATA USED PM2.5 CALC'D AS 48.7%
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS(AS A FRACTION): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
(KlER CntnROts ILY1S) IIiEFORE COMTROLSILrL[ral (AFrER c--Ms ILY ) Ib/mmBW
AIR POLLUTANT EMITTED Ihlhr ton Ib/hr ton Ib/hr tonslyr uncontrolled controlled
PICR'fl SE MK-P" /!/ // 11.38 16.66 72.95 11.38 49.83 0.347 0.237
le ?aJ� Ng P�Q o) 10.42 14.74 64.54 10.42 45.62 0.307 0.217
rJ
� Qr .lP�11Cs) 6.58 /Xebec 12.82 56.13 6.58 28.80 0,267 0.137
SULFUR DIOXIDE S02 1.20 2.48 1.20 5.26 1.20 5.26 0.025 0.025
NITROGEN OXIDES NOx 10.56 21.84 10.56 46.25 10.56 46.25 0.220 0.220
6' 28.80 28.80 126.14 28.80 126.14 0.600 0.600
VOLATILE ORGANIC COMPOUNDS OC 0.82 1.69 0.82 3.57 0.821 3.57 1 0.017 0.017
LEAD I 2.3E-03 4.8E-03 I 2.3E-03 1.0E-02 I 2.3E-03 I 1.0E-02 4.8E-05 4.8E-05
TOJOC/HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
CAS (BEFORE f.ONTROLs/ os) 1/r1ER CONTROLS I LMRS) Ib/mmBW
TOXIC I HAZARDOUS AR POLLUTANT NUMBER Iblhr INyT Ib/hr Ib/ Iblhr lbtyr uncontrolled/controlled
Acetaldehyde(TH) 75070 3.98E-02 164.815 3.98E-02 348.998 3.98E-02 348.998 8.30E-04 8.30E-04
Acetophenone(H) 98862 1.54E-07 6.35E-04 1.54E-07 1.35E-03 1.54E-07 1.35E-03 3.20E-09 320E-09 ,, �, L
Acrulen H 107028 1.92E-01 794.288 1.92E-01 1681.920 1.92E-01 1681.920 4.00E-03 4.00E-03 U/1(Gp/`f T a41�-9
Anbmory Unlisted Compounds(component of SBC)(H) Si 3.79E-04 1.569 3.79E-04 3.322 3.79E-04 3.322 7.90E-06 7.90E-06 (��-rh L >�()')I S$16I�5
Arsenic Unlisted Cm m nds co ntofASC ASC-other 1.06E-03 4.369 1.06E-03 9.251 1.06E-03 9.251 22 0E 0E-05 22 -05
Benzene(TH) 71432 2.02E-01 834.002 2.02E-01 1766.016 2.02E-01 1766.016 4.20E-03 420E-03 � 'hr�CD 7b A.PP(-'/
Beozo(a)pyrene IT) 50328 1.25E-04 0.516 1.25E-04 1.093 1.25E-04 1.093 2.60E-06 2.60E-06 1
Beryllium Metal(unreaded)(component of BEC)(T/H) 7440417 5.28E-05 0.218 5.28E-05 0.463 5.28E-05 0.463 1.10E-06 1.10E-06
Cadmium Metal(unreacted)(comporent or CDC)(TM) 7440439 1.97E-04 0.814 1.97E-04 1.724 1.97E-04 1.724 4.10E-06 4.10E-06 CO NT g4 L
Carbon tetrachloride H 56235 2.16E-03 8.936 2.16E-03 18.922 2.16E-03 18.922 4.50E-05 4.50E-05
Chlorine(TH) 1782505 3.79E-02 156.872 3.79E-02 332.179 3.79E-02 332.179 7.90E-04 7.90E-04 Cj(j l r4 A L
Chlwoberaene(TH) 108907 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 3.30E-05 3.30E-05 r
Chlorotonn(TH) 67663 1.34E-03 5.560 1.34E-03 11.773 1.34E-03 11.773 280E-0s 280E-05 C..Ml S 6 t 01�1
Chromium Unlisted Cmpds(HNadd%Wchrom add to get CRC) CRC-other 8.40E-04 3.475 8.40E-04 7.358 8.40E-04 7.358 1.75E-05 1.75E-05
Chromic acid(VI)(component of soICR6 and CRCXT/H) 7738945 1.68E-04 0.695 1.68E-04 1.472 1.68E-04 1.472 3.50E-06 3.50E-06
Cobalt Unlisted Compounds(component of COC)(H) COCother 3.12E-04 1 1.291 3.12E-04 2.733 3.12E-04 2.733 6.50E-06 6.50E-06
Dinibophenol,2,4-(H) 51285 8.64E-06 I 3.57E-02 8.64E-06 0.076 8.64E-06 0.076 1.80E-07 1.80E-07
Di(2-eth0he )pnerelate(DEHP)(TH) 117817 2.26E-06 I 9.33E-03 2.26E-06 1.98E-02 2.26E-06 1.98E-02 4.70E-08 4.70E-0e
Ethyl benzene(H) 100414 1.49E-03 6.156 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Ethylene dichloride(12-0ichloroetham)(TH) 107062 1.39E-03 5.759 1.39E-03 12.194 1.39E-03 12.194 290E-05 290E-05
Fom,aide 5000D 2.11E-01 873.717 2.11E-01 1850.112 2.11E-01 1850.112 4.40E-03 4.40E-03
Hemchloredeenzo-p-diom 12.3,6,7,8(TH) 57653857 1.53E-09 6.31 E-06 1.53E-09 1.34E-05 1.53E-09 1.34E-05 3.18E-11 3.18E-11
7647010 9.12E-01 3772.868 9.12E-01 7989.120 9.12E-01 7989.120 1.90E-02 1.90E-02
Lead Unlisted Compounds(component of PBC)(H) PBCother 2.30E-03 9.531 2.30E-03 20.183 2.30E-03 1 20.183 4.80E-05 4.80E-05
Manganese Unlisted Compounds(component of MNC)(TH) MNCother 7.68E-02 317.715 7.68E-02 672.768 7.68E-02 672.768 1.60E-03 1.60E-03
w 7439976 1.68E-04 1 0.695 1.68E-04 1.472 1.68E-04 1.472 3.50E-06 3.50E-06
Me bromide(H)(bromomethane) 74839 7.20E-04 1 2.979 7.20E-04 6.307 7.20E-04 6.307 1.50E-05 1.50E-05
Medryl cNonde(H)(chlorornethane) 74873 1.10E-03 4.567 1.10E-03 9.671 1.10E-03 9.671 2.30E-05 2.30E-05
chloroform(TH)(1,1,1 trichloroethane) 71556 1.49E-03 6.156 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Methyl ethyl ketone IT) 78933 2.59E-04 1.072 2.59E-04 2.271 2.59E-04 2.271 5.40E-06 5.40E-06
Methylene chloride(TH)(dichlororneeram) 75092 1.39E-02 57.586 1.39E-02 121.939 1.39E-02 121.939 290E-04 2.90E-04
Naphthalene(H) 912D3 4.66E-03 19.261 4.66E-03 40.787 4.66E-03 40.787 9.70E-05 9.70E-05
Nickel metal(Cornponenl of 373024/NIC)(TM) 744DO20 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 1 3.30E-05 3.30E-05
Ndrophenol,4-(H) 100027 5.28E-06 2.18E-02 5.28E-06 4.63E-02 5.28E-06 4.63E-02 1.10E-07 1.10E-07
Pentachlom H 87865 2.45E-06 1.01E-02 2.45E-06 2.14E-02 2.45E-06 2.14E-02 5.10E-08 5.10E-08
Perchlomethylene(tetrachtoroetlVene)(TH) 127194 1.82E-03 7.546 1.82E-03 15.978 1.82E-03 15.978 3.80E-05 3.80E-05
Phenol(TH) 1D8952 2.45E-03 10.127 2.45E-03 21.444 2.45E-03 21.444 5.10E-05 5.10E 0s
Phosphorus Metal,Yellow or White(H) 7723140 1.30E-03 1 5.361 1.30E-03 11.353 1.30E-03 11.353 2.7DE-05 2.70E-05
Polychktrnated bipheryls(TH) 1336363 3.91E-07 I 1.62E-03 3.91 E-07 3.43E-03 3.91 E-07 3.43E-03 8.15E-09 n.15E-09
Polycyclic Organic Matter(H) POMTV 6.00E-03 24.822 6.00E-03 52.560 6.00E-03 52.560 1.25E-04 1.25E-04
Propionaldehyde(H) 123386 2.93E-03 12.113 2.93E-03 25.649 2.93E-03 25.649 6.1DE-05 6.10E-05
Propylene dichloride(H)(1,2 dichtompmpane) 78875 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 330E-05 3.30E-05
Selenium compounds(H) SEC 1.34E-04 0.556 1.34E-04 1.177 1.34E-04 1.177 280E-06 280E-06
Styrene(TH) 100425 9.12E-02 377.287 9.12E-02 798.912 9.12E-02 798.912 1.90E-03 1.90E-03
Tetrachlorodiibenzo-"iomr,2,3,7,8-(TH) 1746016 4.13E-10 1.71E-06 4.13E-10 3.62E-06 4.13E-10 3.62E-06 8.60E-12 8.6DE-12
Toluene(TH) 108883 4.42E-02 182.686 4.42E-02 386.842 4.42E-02 386.842 920E-o4 9.20E-04
Trichb ene(TH) 79016 1.44E-03 5.957 1.44E-03 12.614 1.44E-03 12.614 300E-05 3.00E05
Trichlorophenol,2,4,6-(H) 88o62 1.06E-06 4.37E-03 1.06E-06 9.25E-03 1.06E-06 9.25E-03 220E-08 220E-08
Vinyl chloride H 75014 8.64E-04 3.574 8.64E-04 7.569 8.64E-04 7.569 1.80E-05 1.80E-05
Xytene(TH) 1330207 1.20E-03 4.964 1.20E-03 10.512 1.20E-03 10.512 250E-05 2.50E-05
•Highest HAP(Hydrogenchloride(hydrochloric add)(TH)) 7647010 9.12E-01 3772.868 9.12E-01 7989.1 9.12E-01 7989.1 1.90E-02 1.90E-02
.Total HAPS NA 1.86E+00 7.71E+03 1.86E+00 1.63E+04 1.86E+00 1.63E+04 3.88E-02 3.88E-02

TOWC AJR POLLUTANT EMISSIONS INFORMATION(FOR PERMITTING PURPOSES)
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS I LWTATIONS(FOR PERMITTING PURPOSES) EMISSION FACTOR
IblmmBW
TOXIC AR POLLUTANT CAS Num. lb/Iv lb/day Iblyr uncontrolled lwnWied
Acetaldehyde(TH) 75070 3.98E-02 9.56E-01 348.998 8.30E-04 8.30E-04
Amolein(TH) 107028 1.92E-01 4.61E+00 1681.920 4.00E-03 4.00E-03
Arsenic Unlisted Compounds(component of ASC)(TH) ASC odw 1.06E-03 2.53E-02 9.251 2.20E-0.5 2.20E-05
Benzene(TH) 71432 2.02E-01 4.84E+00 1766.016 4.20E-03 420E-03
Benzo(a)pyreme IT) 50328 1.25E-04 3.00E-03 1.093 260E-06 2.60E-06
Beryllium Metal(unmacMd)(mmponent of BEC)(TM) 7440417 5.28E-05 1.27E-03 0.463 1.10E-06 1.10E-06
Cadmium Metal(unreacted)(component of CDC)(DH) 7440439 1.97E-04 4.72E-03 1.724 4.10E-06 4.10E-06
Carbon tetrachloride 56235 2.16E-03 5.18E-02 18.922 4.50E-05 4.50E-05
Chlorine(TH) 7782505 3.79E-02 9.10E-01 332.179 7.90E-04 7.90E-04
Chlorobenzene 108907 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E-05
Chloroform(TH) 67663 1.34E-03 3.23E-02 11.773 2.80E-05 2.80E-05
Di2-eth he alate DEHP H 117817 2.26E-06 5.41E-05 1.98E-02 4.70E-08 4.70E-08
Ethylene dichloride(1,2dichlometham)(TH) 107062 1.39E-03 3.34E-02 12.194 2.90E-05 2.9DE-05
Soluble Chromate Cmpds,as chrome(VQ(TH) SOLCR6 1.68E-04 4.03E-03 1.472 3.50E-06 3.50E-06
Formaldehyde(TH) 50000 2.11 E-01 5.07E+00 1850.112 4.40E-03 4.40E-03
Hemchlorodibenzo-pdiman 1,2,3,6,7.8(TH) 57653857 1.53E-09 3.66E-08 0.000 3.18E-11 3.18E-11
Hydrogen chloride(hydrochloric acid)(TH) 7647010 9.12E-01 2.19E+01 7989.120 1.90E-02 1.90E-02
Manganese Unlisted Compounds(component mr WC)(TH) MNC-other 7.68E-02 1.84E+00 672.768 1.60E-03 1.60E-03
Mercury,vapor(component of HGCXTIH) 7439976 1.68E-04 4.03E-03 1.472 3.50E-06 3.50E-06
Methyl chloroform(TH)1,1,1 bichloroethane) 71556 1.49E-03 3.57E-02 13.035 3.10E-05 3.10E-05
Methyl a ketone IT) 78933 2.59E-04 6.22E-03 2.271 5.40E-06 5.40E-06
Methylene chloride H dichlorome8mne 75092 1.39E-02 3.34E-01 121.939 2.90E-04 290E-04
Nickel metal(Component of 373024/1,1IC)(TM) 744OD20 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E-05
Pentechl henol H 87865 2.45E-06 5.88E-05 0.021 5.10E-08 5.10E-08
Perchlmoethylem(tetrachloroethylene)(TH) 127184 1.82E-03 4.38E-02 15.978 3.80E-05 3.80E-05
Phenol(TH) 108952 2.45E-03 5.88E-02 21.444 5.10E-05 5.10E-05
Polychlorinated biphenyls(TH) 1336363 3.91 E-07 9.39E-06 3.43E-03 8.15E-09 8.15E-09
Styre-(TH) 1DD425 9.12E-02 2.19E+00 798.912 1.90E-03 1.90E-03
Tebachlorodibenzo-pAiwdn,2,3,7,8-(TH) 1746016 4.13E-10 9.91E-09 3.62E-06 8.60E-12 8.60E-12
Toluene(TH) 108883 4.42E-02 1.06E+00 386.8429.20E-04 9.20E-04
Trichlome"me(TH) 79016 1.44E-03 3.46E-02 12.6143.00E-05 3.00E-05
Vinyl chloride(TH) 75014 8.64E-04 2.07E-02 7.5691.80E-05 1.80E-os
Xylene(TH) 1330207 1.20E-03 2.88E-02 10.5121250E-05 2.50E-05
GREENHOUSE GAS EMISSIONS INFORMATION(FOR EMISSIONS INVENTORY GREENHOUSE GAS EMISSIONS-POTENTIAL TO EMIT
PURPOSES) -CONSISTENT WITH EPA MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit and EPA
MRR Emission Factors
EPA MRR CALCULATION METHOD:TIER 1
GREENHOUSE GAS metric tons/yr, short tons/yr,
metric tons/yr CO2e short tons/yr short tons/yr short tons/yr,CO2e short tons/yr CO2e
CARBON DIOXIDE(CO2)
BIOGENIC EMISSIONS' 35,808.59 zero 39,472.16 43,476.24 zero` 43,476.24 zero'
METHANE CH4 2.75E+00 6.87E+01 3.03E+00 3.34E+00 8.34E+01 3.34E+00 8.34E+01
NITROUS OXIDE 1,120 1.37E+00 4.10E+02 1.51E+00 1.67E+00 4.97E+02 1.67E+00 4.97E+02
TOTAL
478.26 TOTAL 580.67 TOTAL 580.67
' BIOGENIC CO2 has 0 CO2e NOTE:The DAQ Air Emissions Reporting Online(AERO)system requires short tons
NOTE: CO2e means CO2 equivalent The EPA MRR requires metric tons
Note:Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Annual Air Emissions Inventory
Facility ID#: 0800044
Pentanone (Methyl Propyl Ketone): Us-7 0§4 0
Year: 2019 0550
Info: Lbs/Gal= 6.01 !"N
Monthly Inventory of Pentanone(gallons):
Month Beginning Received Max Used Recovered
Inventory (Lbs) New Used Recovered Used
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
July: 0 0
August: 0 0
September: 0 0
October: 0 0
November: 0 0
December: 0 6144 36922 6119 6095
Gallons of Pentanone used during the year @ PNE(OS-7): 6119
Lbs.Of Pentanone used during the year @ PNE(OS-7): 36776
Gallons of Pentanone used during the year @(OS-10):
Lbs.Of Pentanone used during the year @(OS-10): 0 n
Lbs.of Pentanone used by Misc., QA,and R&D: rcJ� T n �
Lbs.of Pentanone sent to hazardous waste: f `Lbs.of Pentanone sent to wwt: SP-0 1 "'
Lbs.of Pentanone emitted during year: 36776 � 1!!!�L0
► Ll1

Disposed Monthly Used Ending
LBS Inventory
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0
0
6095 145 24
em1

Annual Air Emissions Inventory
Facility ID#:0800044
Chloroform : 010 8S 53 V6
Year: 2019
Info: Lbs/Gal= 12.35
Monthly Inventory of Chloroform(pounds):
Lbs.
Beginning Recovered Chloroform Ending Infeed Product
Month InventoryReceived Max New Used Used Recovered Sent as Haz Total Used Inventory
ry (Lbs.) (Lbs.)
Waste
January: 9181 6634.8 15816 3696.0 11715.0 21104.0 -5693.0 21509 2438 1276
February: 21509 13500.0 35009 1181.0 9637.0 10818.0 24191 4445 2310
March: 24191 716.5 24907 6846.0 7773.0 4200.0 10419.0 14488 2788 1430
April: 14488 4455.0 18943 2751.0 3401.0 22536.0 -16384.0 35327 1756 792
May: 35327 861.4 36189 786.0 770.0 1556.0 34633 4548 2662
June: 34633 34633 1905.0 4259.0 6164.0 28469 4181 2530
July: 28469 13471.7 41940 8486.0 1350.0 7136.0 32104 4945 2728
August: 32104 32104 6154.0 6154.0 25950 4556 2332
rNe
mber: 25950 673.6 26624 3148.0 3004.0 6152.0 20472 2763 1540
ber: 20472 20472 2751.0 2638.0 25781.0 -20392.0 40864 4268 2222
mber: 40864 40864 5824.0 7278.0 13102.0 27762 1848 902
mber: 27762 27762 0.0 27762
Lbs.of chloroform used during the year: 19032
Lbs.of chloro.used by Misc.,QA,and R&D: " ►
Lbs.of chloro.used b EVG: 19032 Cy ZO l 7000 �bS e �>�e
Lbs.of EVG Infeed 29840 �k .t
Lbs.EVG Produced: 15532 rwt��,w' t
Lbs.of chloroform sent to hazardous waste: 1350
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted duringyear.OS-9 17682
Mom LA"", � ,� ',�j
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Diethvlamine : O� OS yp
Year: 2019 l
Info: Lbs/Gal= 5.90 Used for Nicotine Extraction in Botanical Extraction Process
Monthly Inventory of Diethylamine(gallons):
Beginning Received Max Used Used Gal.to Lbs.to Lbs.EDA Ending
Month InventoryEmitted as
(Gals.) (Lbs) (Gals.) (Lbs.) WWTP DTP VOC Inventory
January: 0 0 0 0 0 0 0
February: 0 0 0 0 0 0 0
March: 0 0 0 0 0 0 0
April: 1 0 0 0 0 1 0 0 0
May: 0 0 0 0 0 0 0
June: 0 0 0 0 0 0 0
July: 0 0 0 0 0 0 0
August: 0 0 0 0 0 0 0
—September: 0 0 0 0 0 0 0
October: 0 6481 38238 2752 16238 275 1624 14614 3729
November: 3729 184 23083 0 0 0 0 3912
December: 1 3912 1 23083 0 0 1 0 0 1 3912
Total Gallons of Diethylamine Used: 2752
m i G
Total Lbs.Diethylamine Used: 16238.157 ✓O
Gallons sent to Hazardous Waste:
Lbs.Diethylamine sent to Hazardous Waste:
Total Gallons sent to WWT: 275
Total Lbs.sent to WWT: 1623.8 E)uj V6L
Total Lbs.Diethylamine Emitted:OS-10 14614.3

Annual Air Emissions Inventory
Facility ID#:0800044
Toluene
Year: 2019
Info: Lbs/Gal= 7.23
Monthly Inventory of Toluene(gallons):
Month Beginning Received Max Used In Recovered In Product Disposed Total Emitted Ending
Inventory Lbs Process Inventory
January: 1531 11069 0 1531
February: 1531 11069 0 1531
March: 1531 11069 0 1531
April: 1531 654 15799 0 2185
May: 2185 15799 572 548 548 24 1613
June: 1613 11663 1 0 1613
Jul : 1613 11663 249 0 1364
August: 1364 1745 22476 647 0 2461
September: 2461 17796 1550 1095 455 2007
October: 2007 14509 199 0 1808
November: 1808 13069 0 1808
December: 1808 13069 1 1 0 1808
November: 1808 13069 0 1808
December: 1808 13069 0 1808
Total 2399 2122 1 1643 0 1643 479
Botanical Extraction Operation:OS-10
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Emitted as Toluene Toluene
Operated Product Toluene Used Used Recovered in Product VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/0! #DIV/0!
February: 0.00 0.00 0.00 #DIV/0! #DIV/0!
March: 0.00 0.00 0.00 #DIV/0! #DIV/0!
April: 0.00 0.00 0.00 #DIV/0! #DIV/0!
May: 0.00 0.00 0.00 #DIV/0! #DIV/0!
June: 0.00 0.00 0.00 #DIV/0! #DIV/0i
July: 0.00 0.00 0.00 #DIV/0! #DIV/01
August: 0.00 0.00 0.00 #DIV/0! #DIV/01
September: 0.00 0.00 0.00 #DIV/0! #DIV/0!
October: 0.00 0.00 0.00 #DIV/0! #DIV/0!
November: 0.00 1 0.00 0.00 #DIV/0! #DIV/0!
December: 0.00 0.00 0.00 #DIV/0! #DIV/0!
Average #DIV101 #DIV/01 #DIV/01 1 0.00 1 #DIV/0I 0.00 0.00 #DIV/01 #DIV/01
Total 0 0.00 0.0 0.00 1. 0.00 0.00 0.00 #DIV101 #DIV/01
PNE Operation: 8Q�'7 0s SL
#Days Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Lbs. Product Recovered/ Emitted as Toluene Toluene
Operated Toluene Used Used Disposed in Product VOC Emitted Emitted
January: 0.00 0.00 #DIV/0! #DIV/0!
February: 0.00 0.00 #DIV/0! #DIV/0!
March: 0.00 0.00 #DIV/0! #DIV/0!
April: 0.00 0.00 #DIV/0! #DIV/0!
May: 15 53.90 572.0 4135.56 3962.04 173.52 11.57 0.48
June: 0.00 0.00 #DIV/01 #DIV/0!
July: 0.00 1800.27 -1800.27 #DIV/0! #DIV/0!
August: 0.00 4677.81 -4677.81 #DIV/0! #DIV/01
September: 9 1549.7 11204.46 11204.46 1244.94 51.87
October: 0.00 1438.77 -1438.77 #DIV/0! #DIV/0!
November: 0.00 0.00 #DIV/0! #DIV/0!
December: 0.00 0.00 #DIV/0! #DIV/0!
Average 12 63.90 1060.9 1278.34 2969.72 #DIV/01 #DIV/0! #DIV10!
Total 24 53.90 2121.7 15340.02 11878.89 0.00 3461.13 #DIV101
Gallons of Toluene used during the year: 2122.09
Lbs.of Toluene used during the year: 15342.71
Lbs.Botanical Extraction Toluene Emitted:OS-10 0.00
Lbs.PNE Toluene Emitted:OS-7 3461.13
Lbs.of Toluene sent to hazardous waste:
Total Fugitive Lbs.Toluene Emitted: 3461.13

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: QSI, 0 10
Year: 201 F7 0 550
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Used Gallons IBAC
Month Beginning Received Max Recovered Sent as
Inventory (Lbs) New Used Recovered Hazardous
Used Waste
January: 148 1067
February: 148 972 8087
March: 1120 8087
April: 1120 8087 1101 163
May: 183 1318 163
June: 20 143
July: 20 324 2482 216
August: 128 922 20
September: 107 776
October: 107 776
November: 107 776
December: 107 2269 17156 2220 217
Gallons of IBAC used during the year @ PNE (OS-7): 3537
Lbs. Of IBAC used during the year @ PNE (OS-7): 25534
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 25534

Ending
Inventory
148
1120
1120
183
20
20
128
107
107
107
107
-61

vs sG t3�6m�ss
Annual Air Emissions Inventory OS Yv
Facility ID#:0800044 OS L f^7 Sr-(, F `A1�v -
Ethyl acetate : OS-6, OS-7, OS-10,OS-28 � 7 / C "'7V1 1.
Year: 2019 v,� I J V6 1041 n C
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate(pounds):
7 Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA-35A
Alcohol
Total Beginning Beginning New Recovered Recovered Max Mo hly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Disposed Month
Inventory Inventory Inventory P (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
January: 6210 6210 0 9960.0 4824.00 16170 '4824.0 11346 January: 0.00
February: 11346 11346 0 1540.96 11346 .1541.0 9805 February: 0.00
March: 9805 9805 0 3354.97 9805 .3355.0 6450 March: 0.00
April: 6450 6450 0 8300.0 3045.00 14750 3045.0 11705 Aril: 7.51
May: 11705 11705 0 2015.00 1 11705 2015.0 9690 May: -1.32
June: 9690 9690 0 3290.30 9690 3290.3 6400 June: 0.00
July: 6400 6400 0 3213.51 6400 3213.5 3186 July: -0.38
-August: 3186 3186 0 8300.0 2803.26 11486 2803.3 8683 Au ust: 54.96
September: 8683 8683 0 1342.00 8683 1342.0 7341 September: 54.96
October: 7341 7341 0 8300.0 4425.00 15641 4425.0 11216 October: 48.78
November: 11216 11216 0 3074.40 11216 .3074.4 8142 November: 0.00
December: 8142 8142 0 24900.0 22181.60 1183C60.00 33042 -7500 2 December: -1.54
Ethyl acetate Emissions by Source` 1 4
Ethyl acetate Emitted from Ethyl acetate to Total Ethyl acetate
SDA in Botanical Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted Emitted from
Month Biomass Extraction:OS-28 SDA in PNE:OS-7 PNE:OS-7 from SFG:OS-6 Botanical Extraction
Extraction:OS-10 Botanical
(Lbs.) (Lbs.) (Lbs.) (Lbs.) (Lbs.) OS-10 Extraction:OS-10
(Lbs.) (Lbs.)
January: 0.00 0.00 0.00 4824.00 0.00
February: 0.00 0.00 0.00 1540.96 0.00
March: 0.00 0.00 0.00 3354.97 0.00
April: 0.00 7.51 0.00 3045.00 0.00
May: 0.00 7.51 0.00 2015.00 0.00
June: 0.00 0.00 0.00 3290.30 0.00
July: 0.00 0.00 0.00 3213.51 0.00
August: 0.00 54.96 0.00 2803.26 0.00
-September: 0.00 54.96 0.00 1342.00 0.00
October: 0.00 48.78 0.00 4425.00 0.00
November: 0.00 0.00 0.00 3074.40 0.00
December: 0.00 -1.54 0.00 3033.60 788.00 788.00
Averse 0.00 5 0.00 #DIV101 2 788.00 65.67
Total 0.00 172L 0.00 0.00 35962.00 88.0 788.00
Sim p-� P/lYllSSt

Annual Air Emissions Inventory
Facility IDS:0800044
Ethanol-SDA-35A:OS-7&OS-10
OS-18.OS-19.OS-27,OS-32 INCLUDED WITH OS-10
Year. 1 2019
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4
Monthly Inventory of Ethanol(gallons):
Monthly Beainnina Inventory Bulk Drums
Too Total SDAl SDA Bulk SDA in Drums SDA Max SDA on SDA to Ethyl
SDA SDA SDA in Drums SDA Ending SDA Used SDA Us ad SDA VOC
Month Beginning Inventing Beginning SDA Used Recovered In SDA Disposed Hand WW7 Acetate VOC
InventoryInventory Inventory Received Recovered Received Drums Used Recovered Lba Inventory (gallons) (Lbs.) (Lbs.)
ry ry ( ) (Lbs.) (Lbs.)
Gals.
January: 14469.8 11287.7 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
February: 14469.8 1128707 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
March: 14469.8 11287.7 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
April: 14469.8 11287.7 3182.1 6075.0 4708.5 9940B 13103 1366 9387.6 9199.9 180.2 7.5
May: 13103.3 9921.2 3182.1 5826.3 6075.0 4708.5 1607.0 130040 15955 -240 -1652.0 -1619.0 -31.7 -1.3
June: 15955.1 14380.0 1575.1 109612 15955 0 0.0 0.0 0.0 0.0
July: 15955.1 14380.0 1575.1 69.9 109612 15885 -70 -480.2 -470.6 -9.2 -0.4
Au ust: 15885.2 14380.0 1505.2 24445.0 10000.0 277068 30330 10000 68700.0 67326.0 1319.0 55.0
September: 30330.2 28825.0 1505.2 18708.0 10000.0 336892 39038 10000 68700.0 67326.0 1319.0 55.0
October: 39038.2 37533.0 1505.2 5784.6 11460.0 2585.2 307933 30778 8875 60969.9 5975045 1170.6 48.8
November: 30777.6 31857.6 -1080.0 6235.8 254282 37013 0 0.0 0.0 0.0 0.0
December: 37013.4 38093.4 -1080.0 42840.0 279.5 548693 79574 -280 -1920.2 -1881.8 -36.9 -1.5
Total 103833.7 43610.0 9417.0 0.0 0.0 0.0 4541.6 2471661.3 321041.4 29651.4 203705.1 199631.0 3911.1 163.0
Botanical Extraction Operation:OS-10 63140
D
S Days Lbs.Botanical Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs,EtOH- EtOH-SDA Ethyl Acetate
Month Operated Product SDA Used SDA Used SDA SA to VOC(Lbs.) VOC(Lbs.) Product
Recovered WWTP
January: 0.00 0.00 0.0 0.0
-February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0 Total SDA Ethanol Data
August: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 9417.0
September: 0.00 0.00 0.0 0.0 Total Lbs.SDA Used: 64694.8
0.00 0.00 0.0 0.0 Total Gallons sent to WWT: 30701.76
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0 Total Lbs.sent to WWT: 210921.1
December: 0.00 0.00 0.0 0.0 Total Lbs.SDA Ethanol Emitted as VOC's: 4304.5
Lbs.Botanical Extraction Ethanol Emitted as VOC:OS-10 0.00
Averse SDIV/01 SDI V/01 SDIV101 0 SDIVI01 0 0 0 Lbs.PNE Ethanol Emitted as VOC:OS-7 0.00 r
Total 0 0 0 0 0 0 0 0 Lbs.Biomass Extraction Ethanol Emitted as VOC:OS-28 4304.51 WC, I crrA]i
PNE Operation:OS4 067q
S Days Lbs.PNE Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs.EtOH- EtOH-SDA Ethyl Acetate
Month Operated Product SDA Used SDA Used SDA SDA to VOC(Lbs.) VOC(Lbs.) Product
Recovered WWTP
January: 0.00 0.00 0.0 0.0
-February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0
Au oust: 0.00 0.00 0.0 0.0
September: 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Averse SDIVI01 SDIVI01 SDIV101 0.00 SDIV/01 0.00 0.00 0.00

Total 1 O 0.00 1 0.0 0.00 1 0.00 1 0.00 0.00 1 0.00

Annual Air Emissions Inventory
Facility ID#:0800044
Heptane : 0S-6. OS-7 OS-10
Year: 2019
Info: Lbs/Gal= 5.70
Monthly Inventory of He tane allons:
Beginning Max Recovered Disposed I Ending
Month InventoryReceived Lbs New Used Used Recovered Sent off-Site Haz Waste Inventory
January: 59925 341573 7764.0 0.0 52161
-February: 52161 297318 3373.0 0.0 48788
March: 48788 6600 315712 4256.0 0.0 716 50416
April: 50416 287372 4849.0 0.0 45567
May: 45567 259733 1 22835.0 0.0 2505 20227
June: 20227 6468 152161 1 4253.0 0.0 22442
July: 22442 6186 163179 3961.0 0.0 24667
August: 24667 18006 243236 3437.0 0.0 4175 35061
September: 35061 18241 303818 10488.8 1287.9 44100
October: 44100 6095 286114 15934.7 1535.1 35796
November: 35796 6401 240522 9213.7 247.6 33231
December: 33231 189415 3304.0 0.0 3519 26407
SFG(M-13)Operation:OS-7
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Gallons Heptane Heptane
Month Heptane Used Heptane Sent Heptane Sent as Emitted as
Operated Infeed Product Used to WWTP Recovered Hazardous VOC
Waste (Lbs.)
January: 0.0 0.00
February: 0.0 0.00
March: 0.0 0.00
April: 0.0 0.00
May: 0.0 0.00
June: 0.0 0.00
July: 0.0 0.00
August: 0.0 0.00
September: 1 0.0 0.00
October: 0.0 0.00
November: 0.0 0.00
December: 0.0 0.00
Average #DIV/01 #DIV/0! #DIVI01 #DIV/01 0.0 #DIV/0! #DIV/01 #DN/01 0.00
Total 0 0 0.0 0.0 0.0 0.0 0.0 0.00
Botanical Extraction Operation:OS-10
Gallons Monthly
#Days Lbs. Gallons Lbs.Heptane Gallons Gallons Heptane Sent Heptane
Month Botanical Heptane Used as Hazardous Heptane Sent HeptaneW Emitted as Product
Operated Product Used to WTP Recovered VOC
Waste
Lbs.
-January: 0.0 0
February: 0.0 0
March: 0.0 0
April: 0.0 0
May: 0.0 0
June: 0.0 0
July: 0.0 0
August: 0.0 0
September: 26 25968.80 10488.77 59786.0 2600 1287.9 37624.959 Nicotine
October: 31 39369.42 14307.74 81554.1 4500 1535.1 47153.934 Nicotine
November: 5 6995.58 2307.70 1 13153.9 1200 247.6 4902.57 Nicotine
December: 0.0 0
Average 21 24111.27 9034.74 12874.5 2766.67 1023.5 #DIV/01 7473.46
Total 62 72333.80 27104.21 15"94.0 3070.6 0.0 89681.46
r " .
A99E0 Tot Dv
J�

SFG Operation:OS-6
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Gallons Heptane Heptane
Month Operated Infeed Product Heptane Used Heptane Sent Heptane Sent as Emitted as
Used to WWTP Recovered Hazardous VOC
Waste Lbs.
January: 31 107533 91294.0 7764.0 44254.8 44254.80
-February: 28 173106 146967.0 3373.0 19226.1 19226.10
March: 27 143132 132942.0 4256.0 24259.2 715.8 20179.14
April: 28 131543 117749.0 4849.0 27639.3 27639.30
May: 31 207508 184791.0 22835.0 130159.5 2505.3 115879.29
June: 23 120440 110834.0 4253.0 24242.1 24242.10
July: 25 107174 97367.0 3961.0 22577.7 22577.70
August: 25 114579 96848.0 3437.0 19590.9 4175.4 -4208.88
September: 0 0.00
October: 22 114993 90411.0 1627.0 9273.9 9273.90 Pa)
November: 19 123359 114372.0 6906.0 39364.2 39364.20
December: 20 111070 92105.0 3304.0 18832.8 3519 -1225.50 1t�Qi
Average 25 115971 6051.4 31618.38 #DIV/01 #DIV/Ol 2728.875
Total 279 1454437 1275680 6659-90 379420.50 0.0 10916.500 317202.16 r
� v �
PNE(M-131 Ooeration:OS-7
Gallons Monthly
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Gallons Heptane Sent Heptane
Used as Hazardous
Month Heptane Heptane Sent Heptane Emitted as Process
Operated Product Used to WWTP Recovered VOC
Waste
Lbs.
January: 0.0 0.0
-February: 0.0 0.0
March: 0.0 0.0
April: 0.0 0.0
May: 0.0 0.0
June: 0.0 0.0
July: 0.0 0.0
August: 0.0 0.0
September: 0.0 0.0
October: 0.0 0.0
November: 0.0 0.0
December: 0.0 0.0
Average #DIV/01 #DIV/01 #DIVI01 0.0 #DIVI01 #DIV/O! #DIV/01 0.0
Total 0 0 0.0 0.0 0.0 0.0 0.0

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Methanol:OS-4,OS-7,OS-9
OS-.13,OS-14,OS-15.OS-16,OS-17 OS-27 OS-32 INCLUDED WITH OS-4
Year: 19
Info: Lbs/Gal= 6.62 Specks Gravity=0.793
Monthly Inventory of Methanol faallonsl7 Methanol Used in SDA-3A
Alcohol
Month Beginning Received Max Used Recovered Ending Month Methanol
Invento Lbs Invento Emitted Lbs.
January: 26614.0 15910.0 281509 17399.0 25125 January: 0.00
February: 25125.0 15771.0 270732 15475.0 24421 February: 0.00
March: 24421.0 13371.0 250183 18412.0 19380 March: 0.00
April: 19380.0 13618.0 218447 7776.0 25222April: 0.00
May 25222.0 22477.0 315767 15786.0 31913 May: 0.00
June: 31913.0 7656.0 261947 11747.0 27822 June: 0.00
July: 27822.0 15333.0 28568E 16452.0 26703 July: 0.00
August: 28703.0 7680.0 227615 14540.0 19843 August: 0.D0
September. 19843.0 11857.0 209854 06 126 .0 19094 September 0.00
October. 19094.0 7656.0 177085 13142.0 1360E October: 0.00
November. 13608.0 16413.0 192119 16205.0 12816 November: 0.00
December: 128 66.0 7626.0 13532E 1 8173.0 1 December: 0.00
Maximum Gallons On-Hand: 47699
Maximum Lbs.On-Hand: 315767.3E
Gallons Used per Year: 168713
Lbs.Used per Year: 1116880.0E
Selareol Recovery Operation:0OOP4 i1
FAJ Accountable
l Lb t f T i i E A Month
ly
% Total Gal. o y Avg. Emissions o Total s.
Month #Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg. Total Lbs.
Operated Used Used to WWTP WWTP Methanol in Water to Removal McOH from Fugitive
W WWTP Efficiency WWTP Emissions Emissions
(OS-17)
January 31 11833 78334.4E 1.31 30306.8 7.85 319499 98.9 333.3748 48027.66 48361.035
February 28 12053 79790.88 1.30 31446.9 9.05 307828 98.7 408.8097 48343.96 48752.77
March 31 12779 84596.98 1.29 36050.1 9.49 325852 98.7 468.6513 48546.88 49015.531
April 18 568E 37641.32 1.27 21417.4 10.17 197642 98.8 299.8436 16223.92 16523.764
May 31 15278 101140.36 1.39 41441.2 10.07 350324 98.5 621.618 59699.16 60320.778
June 26 9633 63770.46 1.54 27294.5 7.24 235369 98.8 327.534 36475.96 36803.494
Jul 31 13694 90854.2E 1.42 36001.E 8.59 335454 98.7 468.0234 54852.4E 55120.503
Au ust 31 12552 83094.24 1.54 38310.2 8.47 385341 98.5 574.653 44784.04 45358.693
September 26 9673 64035.26 1.57 29303.5 7.72 198658 98.8 410.249 34731.76 35142.009
October 28 11348 75123.76 1.45 31357 8.11 193710 98.7 407.641 43766.76 44174.401
November 30 11502 78143.24 1.86 30081.7 8.4E 325281 98.7 391.0621 46061.54 46452.602
December 20 8173 54105.26 1.1E 20746.2 9.27 196408 98.7 269.7006 33359.06 33628.761
Averse 27.5E 11183.67 '14035.87 1.41 31146.44 8.54 279280.50 98.6E 43 43304.53
Total 331 134204 888430.4E 373757.3 3341396 4981.160 14673.1E 519654.34
Concrete Operation:OS-4 tiTE R` LOSS
Accountable
Emissions of Total Lbs Avg Monthly
% Total Gal. y . .
#Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg. Total Lbs.
Month Methanol in Water to Removal McOH from Fugitive
Operated Used Used to WW7P WWTP WW WWTP Efficiency WWTP Emissions Emissions
(OS-17)
January 0 0.00 0 0
February 0 0.00 0 0
March 0 0.00 0 0
April 0 0.00 0 0
May 0 0.00 0 0
June 0 0.00 0 0
July 0 0.00 0 0
August 0 0.00 0 0
September 0 0.00 0 0
October 0 0.00 0 0
November 0 0.00 0 1 0
December 0 0.0 0 0
0 0 0
Averse #DIV101 #DIV101 0.00 #DIV101 #DIW #DIV/0101 #DIVI01 #DIVI01 0.00 g.0 .00
Total 0 0 0 0 0 1 0 1 0 1 0 0

Page 2 of 2
EVG Operation:OS-9 D S 5 3
Accountable
Month #Days Gallons MaOH Lbs.McOH Gallons McOH Lbs.McOH to Emissions of Total Lbs. Total Lbs.
Operated Used Used to WWTP WWTp MaOHirom Fugitive Emissions
WWTP Emissions
(OS-17)
January 31 5566.0 38846.92 5454.68 36109.98 722.20 736.94 1459.14
February 21 4422.0 29273.64 4333.58 28688.17 573.76 585.47 1159.24
March 31 5633.0 37290.48 5520.34 36544.65 730.89 745.81 1476.70
April 12 2090.0 13835.8 2048.2 13559.08 271.18 278.72 547.90
May 2 508.0 3362.96 497.84 3295.70 65.91 87.26 133.17
June 20 2114.0 13994.68 2071.72 13714.79 274.30 279.89 554.19
July 19 2758.0 18257.96 2702.84 17892.80 357.86 365.16 723.02
August 12 1986.0 13160.56 1948.24 12897.35 257.95 263.21 521.18
September 14 2933.0 19416.46 2874.34 19028.13 380.50 388.33 768.89
October 10 1794.0 11876.28 1758.12 11638.75 232.78 237.53 470.30
November 17 4703.0 31133.86 4608.94 30511.18 610.22 622.68 1 1232.90
December 0 0 0.00 0.00 0.00 0.00
Avers 17.18 3137.2 19037.47 2818.24 18656.72 753.88
Total 1 189 1 34509.0 1 228449.58 223880.59 4477.61 4568.99 1 9046.60
Botanical Extraction Operation:OS-10 v 'S eI'll ` Gv
Accountable
#Days Gallons McOH Lbs.McOH Gallons MaOH Lbs.McOH to Emissions of Total Lbs.
Total Lbs.
Month Operated Used Used to WWTP VVWTP McOH from Fugitive Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.00 0.00 0.00 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 0.00
July 0 0 0.00 0.00 0.00 0.00
August 0 0 0.DO 0.00 0.00 0.00
September 0 0 0.00 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00 0.00
November 0 0 0.00 0.00 0.00 0.00
December 0 0 0.00 0.00 0.00 0.00
Avers #DIV/01 #DIV/01 0.00 0.00 0.00 0.00 0.00 0.00
rota) o 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol Operations
Total Lbs.McOH Thru System: 3646296.00 Lbs.Fugivtive Emissions from EVG: 4568.99
Total Lbs.McOH Treated at
WWTP: 597637.89 Lbs.Fugivtive Emissions from Recovery: 514673.18
Calculated Removal Efficiency
of WWTP: 98.68 Lbs.Fugitive Emissions from Concrete: 0.00
Lbs.Accountable Emissions from WWTP OS-17 9458.77 Total Lbs.Fugitive Emissions: 524223.33
Lbs.of Emissions from WWTP
During Recovery: 4981.16 Total Lbs.McOH Released: 533682.10
Lbs.of Emissions from W W7P 0 Total Lbs.McOH Recycled On-Site: 3048658.11
During Concrete Recovery:
Lbs.of Emissions from WWTP
1st Aeration Chamber 0117: 4477.61
Lbs.of Emissions from Misc.,
Lab:

Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OSA,OS-6, 0S-6, OS-10, OS-28 OS-29
OS-13,OS-14,OS-15 OS-16 OS-20 OS-21 OS-22 OS-23 O 32 ALL INCLUDED WITH OS-4
OS-18,OS-19INCLUDED WITH OS-10•OS-30INCLUDED WITH OS 28
Year: 2019
Isohexane SIDE Hexane
Info: Lbs/Gal= 5.59 5.785
Monthly Inventory of SIDE-1 LP Hexane-</=40%n-Hexane Igallonsl•
Beginning Max Used Ending Inventory
Month Invento Received Lbs
January: 15654 90558 15654
February: 15654 90558 15654
March: 15654 90558 15654
April: 15654 90558 15654
May: 15654 90558 15654
June: 15654 90558 15654
July: 15654 90558 15654
August: 15654 90558 15654
September: 15654 90558 15654
October: 15654 90558 15654
November: 15654 90558 15654
December: 15654 90558 15654
Monthiv,Inventory of SIDE-2 LP Hexane-</=40%n-Hexane Wallons "Also used in PNE-gDE
Month Beginning Received Max Used Ending Inventory
January: 19370 7833 157368 1530 25673
February: 25673 148517 -2243 27916
March: 27916 161492 897 27019
April: 27019 4829 184239 1670 30178
May: 30178 174578 1334 28844
June: 28844 166861 1395 27449
July: 27449 7113 199939 1228 33334
August: 33334 192835 1551 31783
September: 31783 3315 203043 1039 34059
October: 34059 197032 1004 33055
November: 33055 191224 791 32264
December: 32264 186648 735.7 31528
Monthly Inventory of HP Hexane-</=95%n-Hexane(gallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 5866 32791 5866
February: 5866 32791 5866
March: 5866 32791 5866
April: 5866 32791 5866
May: 5866 32791 5866
June: 5866 32791 5866
July: 5866 32791 5866
August: 5866 32791 5866
September: 5866 32791 5866
October: 5866 32791 5866
November: 5866 32791 5866
December: 5866 32791 5866
Monthly Inventory of IsoHexane-</=5%n-Hexane(gallons)
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 63931 24796 495984 19758 68969
—February: 68969 20600 500691 22916 66653
March: 66653 26883 522866 26595 66941
April: 66941 20520 488907 22503 64958
May: 64958 33068 547965 27060 70966
June: 70966 20019 508606 25768 65217
July: 65217 26415 512223 31071 60561
August: 60561 32443 519892 30261 62743
Se tem be.. 62743 25725 494536 32074 56394
October: 56394 33103 500288 28847 60650
November: 60650 13439 414158 21733 52356
December: 52356 14982 376419 15318 52020

Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers(Lbs 1-
Percentn-Hexane: 1.683
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
July: 0.00 0.00
August: 0.00 0.00
-September: 0.00 0.00
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Averse #DIV/0! #DIV/0! 0.00 0.00
Total 0 0.00 0.00 O.DO
Total Hexane Values
Gallons of LP Hexane Used: 10931.70 Gallons of N-Hexane Used: 5413.58
Gallons of HP Hexane Used: 0.00 Lbs.of N-Hexane Used: 29774.66
Gallons of IsoHexane Used: 303904.00 Gallons of Hexane Isomers Used: 304091.50
Total Gallons of Hexanes Used: 314835.70 Lbs.of Hexane Isomers Used: 1672503.28
Total Lbs.of Hexanes Used: 1762063.245
Sclareolide(SDE-11 Operation:OS-5 Y
Gallons Monthly Monthly Monthly
y
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Month Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0 0.0 0.0 0.00 0.0
February: 0 0.0 0.0 0.00 0.0
March: 0 1 0.0 0.0 0.00 0.0
April: 0 0.0 0.0 0.00 0.0
May: 0 0.0 0.0 0.00 0.0
June: 0 0.0 0.0 0.00 0.0
July: 0 0.0 0.0 0.00 0.0
August: 0 0.0 0.0 0.00 0.0
September: 0 0.0 0.0 0.00 0.0
October: 0 0.0 0.0 0.00 0.0
November: 0 0.0 0.0 0.00 0.0
December: 0 0.0 0.0 0.00 0.0
Average #DIV/01 #DIV/01 #DIV/01 0.0 0.0 #DIV/01 1 #DIV/01 0.000 0.000 0.00
Total 0 0.0 0.0--0 0.0 0.000 1 0.000 _,0..000 0.00
Sclareolide SDE-2 eration: -5 TV91i)`c lilt cam6/(�
Gallons Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Month y Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.)
Lbs.
January: 21 95476.7 77660.0 1530 8851.1 37.7 8851.1 3336.85 5514.2
February: 18 77320.7 59532 -2243 -12975.8 37.7 -12975.8 -4891.86 -8083.9
March: 18 81478.6 64876.2 897 5189.1 37.7 1 5189.1 1956.31 3232.8
April: 20 82620.3 66330.0 1670 9661.0 37.7 9661.0 3642.18 6018.8
May: 21 85476.9 67475.0 1334 7717.2 37.7 123.60 7002.2 2639.82 4362.3
June: 18 85082.6 68809.5 1395 8070.1 37.7 8070.1 3042.42 5027.7
July: 19 72646.5 57860.0 1228 7104.0 37.4 32.70 6914.8 2586.14 4328.7
August: 23 102176.5 84920.0 1551 8972.5 37.4 10.90 8909.5 3332.14 5577.3
September: 17 70095.7 57554.5 1039 6010.6 37.3 6010.6 2241.96 3768.7
October: 22 81559.6 66880.0 1004 5808.1 37.1 5808.1 2154.82 3653.3
November: 15 55213.5 44935.0 791 4575.9 37.1 4575.9 1697.67 2878.3
December: 14 51995.8 43175.0 823 4761.1 37.1 87.30 4256.0 1578.99 26772
Average 19 78428.6 63333.9 918.3 5312.1 37.467 63.625 5189.386 1943.119 1 3246.27
Total 226 941143.4 760007.3 11019 63744.9 254.500 62272.633 23317.427 38955.21
T�o/ 13
o� f>� 3 h,s
��,c,Yv'1 �s}�s�e���

Page 3 of 5
Sclareol Recrvstallization(SFG)Operation:OS-6
Gallons en Monthly Hexane
Hexane Monthly Monthly
Month #Days Lbs.SFG Lbs.SFG Product Gallons Hexane Lbs.Hexane Used %n-Hexane St as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0.0 0.0 0.00 0.0
February: 0.0 0.0 0.00 0.0
March: 0.0 1 0.0 0.00 0.0
April: 0.0 0.0 0.00 0.0
May: 0.0 0.0 0.00 0.0
June: 0.0 0.0 0.00 0.0
July: 0.0 0.0 0.00 0.0
August: 0.0 0.0 0.00 0.0
September: 0.0 0.0 0.00 0.0
October: 0.0 0.0 0.00 0.0
November: 0.0 0.0 0.00 0.0
December: 0.0 0.0 0.00 0.0
Avera a #DIV/01 #DIV/01 #DIV/01 #DIV/01 0.0 #DIV/01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0 0 0.00 0.00 0.00 0.00
Rotocel&Recovery Operations:OS-4
Gallons Monthly
y
Lbs.Sage Monthly Monthly
#Days 9e Lbs.Sae Gallons Hexane Hexane y Hexane
Month Processed 9 Lbs.Hexane Used %n-Hexane Sent as Hexane Emitted
Isomers
Operated Product Used Emitted Emitted
(INFEED) Hazardous (Lbs. Emitted
Waste ) (Lbs.) Lbs.
January: 31 13950000.0 104899.0 19758 110447.2 2.27 110447.2 2507.2 107940.1
February: 28 12600000.0 100110.0 22916 128100.4 2.44 128100A 3125.7 124974.8
March: 31 13950000.0 107489.0 26595 148666.1 2.54 29.10 148503.4 3772.0 144731 A
April: 18 7650000.0 66082.0 22503 125791.8 2.62 125791.8 3295.7 122496.0
May: 31 13950000.0 133527.0 27060 151265.4 1.88 29.10 151102.7 2840.7 148262.0
June: 26 11700000.0 77832.0 25768 144043.1 0.95 144043.1 1368.4 142674.7
July: 31 13950000.0 123375.0 31071 173686.9 0.61 173686.9 1059.5 172627.4
August: 31 13950000.0 118440.0 30261 169159.0 1.62 169159.0 2740.4 166418.6
September: 26 11600000.0 84036.0 32074 179293.7 1.73 179293.7 3101.8 176191.9
October: 28 12431250.0 1 104038.0 28847 161254.7 1.31 161254.7 2112.4 159142.3
November: 30 11700000.0 99601.0 21733 121487.5 1.44 121487.5 1749.4 119738.1
December: 20 9000000.0 65471.0 15318 85627.E 0.79 85627.6 676.5 84951.2
Avera a 28 12 0 98741.7 25325 141568.6 1.683 29.10 141641.5 2362.5 139179.0
Total 331 C 146411250 1184900.0 303904 1698823.4 58.20 ,166984498.0 28349.6 1670148.4
Lbs.Hex per day exiting Mineral (� Accountable Lbs.of Hexane
Oil Scrubber 158.7E n Emitted: 200811.3
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 52550.884 Accountable Lbs.of N-Hex Emitted: I3nO.32= Q G fv UA Ac4 j v 4 4,6 PO,,-f
Lbs.of N-Hex exiting MO Unit: 884.61 Accountable Lbs.of Hexane 197430 I�
Isomers lost: 2
Unit:
Lbs.of Hex Isomers exiting MO 51666.28 Fugitive Lbs.Hexane Emitted: 1497691.96 I' /"GY
Lbs.Hexane per Lbs.of Spent 0.000930 Fugitive Lbs,n-Hexane Emitted: 25211.15
Sage from Desolvitizer tests):
Lbs.Hexane in Spent Sage: 72292.38
6181.0E Fugitve Lbs.Hexane Isomers
P 9 1472480.81,i
Emitted:
Lbs.N-Hexane in Spent Sage: Accountable and Fugitive Lbs. 1698503.2E
Hexane Emitted:Lbs.Hexane per Day from A-1000815 Accountable and Fugitive Lbs.
Vent Cond. N-Hex Emitted: 28591.47
Lbs.Hex ExitingA-1 Vent: 0.270 Accountable and Fugitive Lbs.Hex
1 U Isomers Emitted: 1669911.79
Lbs.N-Hex Exiting A-1 Vent: 0.004541 1_sv1%SP-r4,z eA.
Gallons Water sent to WWT: 10345227 elf[
Lbs.Waste Water perGal.Waste 8.34
Wt%of Hexane in Waste Water: 0.014 U S C b J G 16/C
Lbs.Hexane Lost in Waste Water: 12079.09 J I
Lbs.N-Hexane Lost in Waste
Water: 203.33
[ (,g882-3.Y lbs wA9 - 2oif39,8 16s oc lo(e = !997&63.6 165
AcwwTAg1ES f 3Z8•� lbt- t j2o79 ,O9
I+3�dal •vL. 5 In S � S 4 525So ,$U'Y tfbS -rv>7 S�Cl tl�S to Vow
S
f a

Page 5 of 5
Botanical Extraction Operation;OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used %n-Hexane Isomers
P Used Hazardous Emitted Emitted Emitted
Waste (Lbs.) (Lbs.)
January: Lbs.
Marc 0 0.00 0.0 0
F 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
[fAvera
vember: 0 0.00 0.0 0
cember: 0 0.00 0.0 0
a #DIV/01 #DIV/01 #DIV/O! 0 #DIV/01 #DIV/01 0 0 0
Total 0 0 0 0 0.0 0 0 0 0
Plant Nutrient Extraction(M-13)Operation:W9 L)9
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.PNE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0.0 0 0.00 0.0
-February: 11 SDE 305 1762.7 37.7 15444595 582.31 962.3
March: 31 SIDE 859 . . 2040.0 -7051.915 -2658.57 1 -4393.3
April: 11 SDE 305 1762.7 37.7 1544.595 582.31 962.3
May: 13 SDE 360 2083.2 37.7 1865.084 703.14 1161.9
June: 30 SDE 831 4807.3 37.7 4589.2405 1730.14 2859.1
July: 9 SDE 249 1442.2 37.7 1224.106 461.49 762.6
Au ust: 14 SDE 388 2243.4 37.7 2025.3285 763.55 1261.8
September: 30 SDE 831 4807.3 37.7 4589.2405 1730.14 2859.1
October: 14 SDE 389 2250.4 37.7 1484 1-6550.3555 1 -2469.48 -4080.9
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Average 18 #DIV/OI 502 2177.2 37.70 1761.8 314.993 118.76 196.24
Total 163 0 4516 26126.8 3523.6 3779.919 1425.03 1 2354.69
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1563744451 Total Lbs.Hexane Emitted: 1764555481
Fugitive Lbs.N-Hexane Emitted: #DIV/01 Total Lbs.n-Hexane Emitted: #DIV/O!
Fugitive Lbs.Hexane Isomers
Emitted: #DIV/01 Total Lbs.Hex Isomers Emitted: #DIV/0!
Accountable Lbs.Hexane Emitted: 200811.30 Total Lbs.Hexane Sent Off Site: 21099465
Accountable Lbs.n-Hexane
Emitted: #DIV/O! I Total Lbs.N-Hexane Sent Off Site: #DIV/O!
Accountable Lbs.Hex Isomers #DIV/0! Total Lbs.Hex Isomers ent Off #DIV/0!
Emitted: Site:
Annual Summary:Maximum n-Hexane On-Hand
Month
Total Hexane Total Total N-Hexane(Gallons) n-Hexane
Gallons (Lbs.)
January: 116162 11244 62855.1
February: 116089 12151 67921.6
March: 115480 11886 6644447
April: 116656 13079 73111.0
May: 121330 12208 68244.0
June: 114186 10968 61309.6
July: 115415 12836 71754.5
August: 116046 12903 7212847
September: 111973 13680 76469.4
October: 115225 13058 72994.1
November: 106140 12724 71126.8
December: 105068 1 12108 1 67683.8
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
121330 13680 76469

Page 4 of 5
_Concrete Operations:OS-4
Gallons Monthly
Monthly Monthly
#Days Lbs.Concrete Lbs.Concrete Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Infeed Product Used Lbs.Hexane Used %n-Hexane Sent as Isomers
Hazardous
Emitted Emitted Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0.0 0.0 0.0 0.0
February: 0.0 0.0 0.0 0.0
March: 0.0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0.0 0.0 0.0 0.0
July: 0.0 0.0 0.0 0.0
August: 0.0 0.0 0.0 0.0
-September: 0.0 0.0 0.0 0.0
October: 0.0 0.0 0.0 0.0
November: 0.0 0.0 0.0 0.0
December: 0.0 0.0 0.0 0.0
Average #DIV/01 #DIV/01 #DN/01 #DIV/01 1 0.0 �#D[V/01 #DIV/01 0.0 0.0 0.0
Total 0 0 0.0 0 0.0 0.00 0.0 0.0 0.0
Lbs.Hexane per Day from A-1 Vent Cond. 0.000815 Accountable Lbs.of Hexane Lost: 0.00
Days A-1 Operated: 0 Accountable Lbs.of N-Hex Lost: #DIV/0!
Lbs.Hex Exiting A-1 Vent: 0.000 Accountable Lbs.of HexaneIsomers Lost: #DIV/0!
Lbs.N-Hex Exiting A-1 Vent: #DIV/0! Fugitive Lbs.Hexane Lost: 0.00
Gallons sent to WWT: Fugitive Lbs.n-Hexane Lost: #DIV/0!
Lbs.Waste Water per Gal.Waste
Water: 8.34 Fugitve Lbs,Hexane Isomers Lost: #DIV/0!
Wt%of Hexane in Waste Water: 0.014 Accountable and Fugitive Lbs. 0.00
Hexane Emitted:
Lbs.Hexane Lost in Waste Water: 0.00 Accountable and Fugitive Lbs.
N-Hex Emitted: #DIV/0!
Lbs.N-Hexane Lost in Waste #DIV/0! Accountable and Fugitive Lbs.Hex #DIV/0!
Water: Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Average #DIV/01 #DIV/01 #DIV/01 0.00 #DIV/01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2019
The Plant Material Grinder(OS-3) is operated in building ID# 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAPITAPS, or VOC
associated with the grinder's operation. Essentially there are no emissions associated with
the plant material grinder.
III

2019 Emissions Inventory Review / Data Tracking Form
Facility Name: Avoca LLC FaeiG ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston ETH Confidential Copy Submitted?
Title V ❑ YES
1NO
Initial Review/Data Entry
Enter date received into ED. Date Received: 3 J ZY/20 VO
❑ Assigned to appropriate individual. Date Assigned: 312 41Zo Lb Date Due: (o 13 IIZo2,b
er I� Pap copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and
/ appears generally complete;QK pN"0
�] Electronic copy submitted: All supporting documentation and certification form(with time/date stamp)signed by responsible
official has been received.
Comments: �`�� r � �
Inventory Review
1� All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
u Contact,address,phone number changes entered into I-Bcam/Facilities if necessary.
All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
Check if SCC codes for each OS are accurate and update if needed.
Evaluate"U"sources for significance and address according to policy.
Calculations/forms appear to add up correctly.
All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds, large emissions increase/decrease,installation
d without a permit).
All volatile HAPs/TAPs were included in the VOC total.
Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP42,etc.).
Review facility comments and address any issues.
Update ED(Data Entry Main)if additional information is required(corrections due date and date received).
d Check all ED QA/QC reports.
Q/' Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained.
p Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
Print and attach the facility total report.
Date Into Requested: Date Info Received: Total Days on Hold:
Date Review Complete: t o/ 3 61.2o Z-,O Signature: Z� �
Date Submitted to EI Coordinator: /t-o/12g4
Date Approved: I r f Olt f 21.6 Initials: GTE

CY2019 Inventor+Review Notes
• There are hand-written review notes made within the hard copy of the inventory.
• I reviewed all factors and calculations.There were no changes to Avoca's emissions factors and calculation
methods.
Emergency Engines
• They decided to document the fire pump emissions separately from the generators. However,they used a
Group with fuel oil tanks to quantify fire pump emissions without pulling the pump into the group. I had to
remove it from the generator group,delete the OS,get rid of the group they created for the fire pump,create a
new OS and re-enter the fire pump data.
• Fire Pump fuel use increased by 7.6%,and PkGEN fuel use decreased 31.7% from usage in CY2018. The
Generator fuel usage was 6.36 times greater than usage in 2018.
• I added chromic acid, lead,manganese,mercury and nickel emissions to all of the engines' OS.
• I corrected the PK-GEN throughput in OS 12.
Boilers
• Fuel oil usage drastically decreased on Boilers H101-103 (11.7%of gallons burned in 2018). H103 did not
operate.
• H101 and H102 emissions were split into two operating scenarios;however,Brian used existing Group 9 to
enter emissions for H101,but H101 was tied to GR7/OS60 for the propane boiler.I removed OS60,and
eliminated GR7 so that I could pull H101 in with GR9(which also has fuel oil tanks listed).I then had to re-
enter emissions into a new OS for H104.
• I zeroed the S02 emissions from H101-102 for low sulfur fuel oil in the hard copy of the inventory.
Combined emissions are 0.008 tpy due to 0.0014%sulfur content.
• Wood combustion in the BB1 and BB2 boilers increased 3.8%by weight of wood fired in CY2018.
• I added several toxics to ED using the DAQ spreadsheet for wood combustion. If a combustion HAP in the
spreadsheet was not listed in ED,it is because the facility-wide emissions are below reportable threshold,or
the emission is negligible and won't affect the facility total. A 99%control efficiency was applied to the
metal HAPs. I added these emissions to IBEAM ED CY2017 and CY2018 data as well.
• With the exception of hexanes,ethyl acetate,chloroform,methanol,and toluene,all other HAPs emitted at
Avoca are generated from fuel combustion. The factors have not changed.
• I calculated HCL and Hg emissions using 2016 emissions testing results on the wood boilers.
Process Emissions
• There were no new methods of calculation nor new factors for Avoca's process areas.
• Process VOC emissions are comprised of chloroform,ethanol,hexanes,heptane,methanol,and ethyl acetate.
All of Avoca's process emissions are determined through mass balance. Avoca uses purchasing records,daily
formulation and batch records,daily tank level measurements,waste shipment records,process design
calculations,MACT MON formulas,and fugitive and point source splits based on overall VOC usage.
• The process area operating scenario throughputs are in-feed weights of raw material to the processes(i.e.tons
sage, SFG raw lbs sclareol,SDE raw infeed,etc.).

• The OS numbers on Avoca's calculation spreadsheets need to be updated.
• Note that the MON provides equations to use for calculation of emissions for some of the sources.However,
these calculations do not take fugitive loss into account. Avoca reports both point and fugitive emissions
based on inventory tracking/mass balance.
• Avoca assumes that the bulk of heptane and ethyl acetate emissions from SFG are fugitive.Based on old
hexane values and using MON batch calculations to back into it,approximately 80%of emissions are
estimated fugitive and 201/6 are out the stacks.
• Explanation of the fugitive and point splits for hexanes from Rotocel and Recovery(see calcs in the hard
copy): Accountable emissions are those Avoca can verify along with the emissions coming out the final
stack; hexane going to wastewater,hazardous waste,or in the spent sage material.Using test data,Avoca
calculates the average hexane per day exiting the MO Scrubber was 158.761bs. Then multiply 158.76 times
the number of days run out the stack. The average n-hexane content of the solvent is used to calculate the
split of hexane isomers and n-hexane. Fugitive hexane is calculated by subtracting the accountable hexane
from the total hexane used.
• Reminder: More than a third of the methanol"lost"from the Rotocel&Recovery operation goes to WWTP.
Of that,98-99%is consumed by the biological activity in the WWTP,while emitting the remainder. The
WWTP emission is calculated through the Water 9 program. The other two thirds of methanol"lost"from
Rotocel&Recovery is"fugitive." Brian has noted that some of the"fugitive"losses are also actually going
out the stack of the Mineral Oil Scrubber as well,but most of it would be in the lines and from the tanks
located in recovery
• It was unclear as to what process emitted pentanone(and the lbs emitted). On 11/01/2020 Brian Conner
emailed that 145 lbs pentanone were emitted from Botanical.I added this amount to the total VOC in the OS.
• On 11/01/2020 Brian Conner emailed me the electronic copy of the emissions inventory calculations
spreadsheets. They are saved in SharePoint.
Facility Totals
• While CO emissions from H101-103 decreased,CO emissions are primarily created by the wood boilers,
which increased by 3.8%in combustion for CY2019.There is also a new propane boiler E-104 that
contributed an additional 3.4 new CO tons emissions for CY2019.
• PM/PM10 decreased due to decrease in operation of H101 and H102 boilers. H103 was not operated at all.
Fuel use across these boilers in CY2019 were 11.7%of gallons burned in CY2018.
• Arsenic,beryllium,cadmium, lead,mercury,nickel,and flourides decreased greatly due to reduction in
operation of H101 and H102.Boiler H103 did not operate.
• Chromic acid and manganese decreases from boilers H101-103 were tempered by the 3.8%increase in
operation of the wood boilers.
• Production for CY2019 decreased at EVG, so chloroform usage decreased.
• N-hexane emissions were reduced due to reductions at SDE-2(44,486 lbs in CY2018 down to 23,317.32 lbs
in CY2019).
• Methanol emissions decreased in all production areas of the plant.
• Toluene increased by 1,460.8% because it was used in the PNE extractions process. In CY2018 it was only
emitted from combustion in the boilers and engines.
(SharePoint\Bertie08\00044\CY2019 Avoca EI Review Notes.doc)
i

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr
Pollutant CAS CY 2019 CY 2018 Demini- Change
from ED from Fees mus
Nitrous Oxide (N20) 10024972 1.31 1.29 1.0 1.6%
Methane (CH4) 74-82-8 2.11 2.04 10.0 3.7%
Carbon Dioxide (CO2) 124389 20,375.20 26,872.98 5,000.0 -24.2%
CO2 equivalent(sum of individual GHG pollutant emissiot 18,892.73 metric tons
times their 1995 IPCC Global Warming Potential (GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
CO co 23.73 20.88 0.5 13.V/o
NOx NOx 31.81 30.93 0-57 2.8%
PM(TSP) TSP 0.444000 1.41 0.5 -68.6`%o
PM10 PM10 0.354000 0.584000 0.5 -39.4°/,
PM2.5 PM2.5 0.310000 0.314000 0.5 -1.3%
S02 S02 2.67 2.57 0.5 3.9%
VOC Voc 1,403.40 1,280.53 0.5 9.6%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Arsenic & Compounds (total mass of elemental AS, arsine and 0.100900 0.452930 0.01 -77 7%
all inorganic compounds)
Arsenic Unlisted Compounds - Specify Compound ASC-Other 0.100900 0.452930 0.01 1 -77.7/o
(Component of ASC)
Beryllium & compounds (Total mass) 0.045100 0.310450 1.0 1 -85.5%
Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.045100 0.310450 1.0 -8,5.5°/)
Cadmium & compounds (total mass includes elemental metal) 0.050900 0.316450 0,1 I -83.9
11/01/2020 Page 1 of 5

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Cadmium Metal, elemental, unreacted (Component( 7440-43-9 0.050900 0.316450 0.1 -83.91%o
CDC)
Chromium -A1UTotal(includes Chromium (VI) categories, 0.704900 0.978150 0.1 -27.9%
metal and others)
Chromic acid(VI) (Component of So1CR6 & CRC) 7738-94-5 0.704900 0.978150 0.01 -27.9%
Chromium (VI) Soluble Chromate Compounds (Component of 0.704900 0.978150 0.01 -27.9%
CRC)
Chromic acid (VI) (Component of So1CR6 & CRC) 7738-94-5 0.704900 0.978150 0.01 -27.9
Lead& compounds 0.210700 1.01 1.0 I -79.1%
Lead Unlisted Compounds - Specify Compound PBC-Other 0.210700 1.01 10.0 1 -79.2% 1
(Component of PBC)
Manganese& compounds 3.26 3.68 10.0 -11.4%
Manganese Unlisted Compounds - Specify Compoui MNC-Other 3.26 3.68 10.0 -11.4'11/40
(Component of MNC)
Mercury& Compounds-all total mass includes Hg Vapor 0.095900 0.364150 0.001 1 -73.7%
Mercury, vapor(Component of HGC) 7439-97-6 0.095900 0.364150 0.001 -73.7%,
Nickel& Compounds, sum total mass includes elemental 0.103900 0.368150 1.0 -71.8%
Nickel metal (Component of NIC) 7440-02-0 0.103900 0.368150 1.0 -71.8°/o
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.516610 0.497130 1.0 13.9%
Benzo(a)pyrene (Component of 83329/POMTV& 50-32-8 0.516610 0.497130 1.0 3.9%
56553/7PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 20.13 19.50 1.0 3.2%
or To
Benzo(a)pyrene (Component of 83329/POMTV& 50-32-8 0.516610 0.497130 1.0 3.9%
56553/7PAH)
Naphthalene (Component of 83329/POMTV) 91-20-3 19.62 19.00 1.0 3.2%
Acetaldehyde 75-07-0 164.94 158.81 10.0 3.9%
Acrolein 107_02_8 794.31 764.88 10.0 3.8%
Benzene 71-43-2 836.24 806.38 1.0 3.7%
11/01/2020 Page 2 of 5

Facility Total CY 2019 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca LLC Permit#(s): 01819T53
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2019 CY 2018 Demini- %
from ED from Fees mus Change
Carbon tetrachloride 56-23-5 8.94 8.61 1.0 3.8%
Chlorine 7782-50-5 156.87 151.06 100.0 3.8%
Chlorobenzene 108-90-7 6.55 6.31 10.0 3.9%
Chloroform 67-66-3 17,687.56 70,014.35 100.0 1 -74.74,
Ethyl acetate 141-78-6 36,922.18 34,981.26 10.0 5.5%
Ethyl benzene 100414 6.23 6.52 100.0 -4.5%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.76 5.54 1.0 4.0%
Fluorides (sum of all fluoride compounds as mass of 16984-48-8 3.15 26.93 10.0 -88.30/0
ion)
Formaldehyde 50-00-0 878.06 876.22 10.0 0.2%
Hexane isomers, except n-hexane HEXANEISO 1,711,221.8 1,580,053.7 100.0 8.3%
9 9
Hexane, n- 110-54-3 53,333.93 64,978.00 100.0 -17.9
Hydrogen chloride (hydrochloric acid) 7647-01-0 13.50 13.00 100.0 3.8%
Methanol (methyl alcohol) 67-56-1 528,700.94 599,327.84 1,000.0 -11.81�.
Methyl bromide (bromomethane) 74-83-9 2.98 2.87 1.0 3.8%
Methyl chloride (chloromethane) 74-87-3 4.57 4.40 1.0 3.9%
Methylene chloride 75-09-2 57.59 55.45 1.0 3.9%
Phenol 108-95-2 10.13 9.75 100.0 3.9%
Polycyclic Organic Matter (Inc PAH, dioxins, etc. N poM 24.80 26.28 1.0 -5.6%
& AP 42 historic)
Propionaldehyde 123-38-6 1.2.11 11.66 10.0 3.9%
Styrene 10042-5 377.29 363.30 100.0 3.8%
Toluene 108-88-3 3,651.28 233.94 100.0 ,460.80/
Vinyl chloride 75-01-4 3.57 3.44 0.1 3.8%
Xylene (mixed isomers) 1330-20-7 5.58 6.12 100.0 -8.7%
11/01/2020 Page 3 of 5

Largest Individual HAP Methanol (methyl alcohol) 528,700.94 lbs
Total HAP Emissions 606,768.43 lbs
Largest Individual CAP VOC 1,403.40 tons
Total CAP Emissions 1,461.96 tons
Total TAP Emissions 1,826,144.10
lbs
Total Aggregate 1,462.08 tons
Emissions
11/01/2020 Page 4 of 5

DAQ's Comments Regarding Inventory
])Hand-written review notes are in the inventory hard copy. There were no changes to Avoca4s emissions factors and calculation
methods.
2)Fire pump and generators have their own OS this year. However,they used a Group with fuel oil tanks to quantify fire pump
emissions without pulling the pump into the group. I had to remove it from the generator group,delete the OS,get rid of the group
they created for the fire pump,create a new OS and re-enter the fire pump data.
3)Fire Pump fuel increased 7.6%,PkGEN fuel decreased 31.7%,generator fuel increased 636%.
4)Added chromic acid,lead,manganese,mercury and nickel emissions to all enginesZ OS.
5)Corrected PK-GEN throughput OS 12.
6)H101 and H102 are now split into two OS;however,Avoca used existing Group 9 to enter emissions for H101,but H 10 1 was tiec
GR7/OS60/propane boiler. I removed OS60,eliminated GR,then pulled H 101 in with GR9).Then re-entered emissions into new O:
H 104.
7)Added several toxics using the DAQ wood combustion XLS.99%control efficiency fo rmetals applied .
8)HCL and Hg emissions calculated using 2016 testing results/wood boilers.
9)Explanations of the fugitive and point splits for hexanes from Rotocel and Recovery and methanol splits are in hard copy review.
10)It was unclear as to what process emitted pentanone(and the lbs emitted). On 11/01/2020 Brian Conner emailed that 145 lbs
pentanone were emitted from Botanical. I added this amount to the total VOC in the OS.
I])While CO emissions from H101-103 decreased,CO emissions are primarily created by the wood boilers,which increased by 3.8
in combustion for CY2019. There is also a new propane boiler E-104 that contributed an additional 3.4 new CO tons emissions for
CY2019.
12)PM/PM 10 decreased due to decrease in operation of H 101 and H 102 boilers. H 103 was not operated at all. Fuel use across then
boilers in CY2019 were 11.7%of gallons burned in CY2018.
13)Arsenic,beryllium,cadmium,lead,mercury,nickel,and flourides decreased greatly due to reduction in operation of H 10 1 and
H 102.Boiler H 103 did not operate.
14)Chromic acid and manganese decreases from boilers H101-103 were tempered by the 3.8%increase in operation of the wood
boilers.
15)Production for CY2019 decreased at EVG,so chloroform usage decreased.
16)N-hexane emissions were reduced due to reductions at SDE-2(44,486 lbs in CY2018 down to 23,317.32 lbs in CY2019).
17)Methanol emissions decreased in all production areas of the plant.
18)Toluene increased by 1,460.8% because it was used in the PNE extractions process. in CY2018 it was only emitted from
combustion in the boilers and engines.
11/01/2020 Page 5 of 5

Emissions by Operating Scenario
for
Hexane, n-
20191nventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
54 Rotocel/Recovery/Concrete Operations Fugitive 25,211.15 16,908.55
Loss
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P 1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-12513 ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
59 SDE-2 23,317.43 44,486.68
C-4001 C-4001
D-4001 D-4001
ES-4000-F ES-4000-F
ES-4000-W ES-4000-W W
R-4004 R-4004
R-4005 R-4005
R-4015 R-4015
R-4044 R-4044
T-4001 T-4001
T-4017 T-4017
T-4018 T-4018
55 Rotocel, Sage, Recovery, and Distillation 3,380.32 2,694.97
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1

Emissions by Operating Scenario
for
Hexane, n-
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-12513 ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
49 Plant Nutrient Extraction(PNE) 1,425.03 159.05
C-31203 C-31203
D31211 D31211
D31214 D31214
ES-1003-2-1 ES-1003-2-1-F
ES-1003-2-1 ES-1003-2-1-P
ES-1003-2-1 ES-1003-2-1-W
ES-TK-PNE ES-TK-PNE-1
40 Botanical extraction process (includes botanical 728.75
vents, condensers,tanks,etc)
ES-1001-11-F
ES-1001-11-P
ES-1001-11-WI
Total: 53,333.93 64,978.00

Emissions by Operating Scenario
for
Methanol (methyl alcohol)
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
54 Rotocel/Recovery/Concrete Operations Fugitive 514,673.18 580,506.85
Loss
ES-1001-1-1 ES-1001-1-1-F
ES-1001-1-1 ES-1001-1-1-P1
ES-1001-1-1 ES-1001-1-1-P2
ES-1001-1-1 ES-1001-1-1-P3
ES-1001-1-1 ES-1001-1-1-W
ES-1001-1-2 ES-1001-1-2-F
ES-1001-1-2 ES-1001-1-2-P
ES-1001-1-2 ES-1001-1-2-W
ES-1001-2-1 ES-1001-2-1-F
ES-1001-2-1 ES-1001-2-1-P1
ES-1001-2-1 ES-1001-2-1-W
ES-M-125A ES-M-125A
ES-M-125B ES-M-125B
HB-1 HB-1
HB-2 HB-2
HB-3 HB-3
HB-4 HB-4
32 Waste Water Treatment 1 st Aeration Chamber 9,45 8.77 12,198.62
(Includes methanol usages from PNE and EVG)
W WTP-AT 1 W WTP-AT 1
53 EVG (batch flavorant) 4,568.99 6,010.68
D-1201 D-1201
D-1215 D-1215
D-1218 D-1218
D-2202 D-2202
ES-1003-2-2 ES-1003-2-2-F
40 Botanical extraction process(includes botanical 611.69
vents,condensers,tanks,etc)
ES-1001-11-F
ES-1001-11-P
ES-1001-11-WN

Emissions by Operating Scenario
for
Methanol (methyl alcohol)
20191nventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
Total: 528,700.94 599,327.84

Emissions by Operating Scenario
for
Toluene
2019Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source Ill (Pounds/Yr) Source ID
49 Plant Nutrient Extraction (PNE) 3,461.13
C-31203 C-31203
D31211 D31211
D31214 D31214
ES-1003-2-1 ES-1003-2-1-F
ES-1003-2-1 ES-1003-2-1-P
ES-1003-2-1 ES-1003-2-1-W
ES-TK-PNE ES-TK-PNE-1
57 Biomass Boiler Operation with Wood Chips as fu, 182.69 175.92
source
ES-BB I ES-BB 1
ES-BB2 ES-BB2
ES-RD.19A ES-RD.19A
61 H-102 Boiler 4.03
H-102 H-102
62 H-101 Boiler 2.71
H-101 H-101
ITK9238 ITK9238
ITK9239 ITK9239
65 Generators 0.44
E101 E101
E102 E102
E104 E104
12 Peak Shaving Generator 0.26 0.37
ES-PkGen 1 ES-PkGenl
66 Fire Pump Engine 0.03
FP FP
42 Generators 0.10
E101
E102
E104
FP

Emissions by Operating O eratin Scenario
for
Toluene
2019 Inventory
Facility Name: Avoca LLC
Facility ID: 0800044 Permit Number(s): 01819T53
2019 Emission 2018 Emission
Process Rate Emission Rate Emission
ID Operating Scenario (Pounds/Yr) Source ID (Pounds/Yr) Source ID
58 Boilers 57.54
H-101
H-102
H-103
Total: 3,651.28 233.94

11/1/2020 Mail-Huddleston,Betsy-Outlook
[External] RE: One question concerning 2019 Emission Inventory
Brian Conner <[e-mail]>
Sun 11/1/2020 8:01 AM
To: Huddleston, Betsy<[e-mail]>
1 1 attachments(751 KB)
2019 AAE Calc.xls;
CAUTION: External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment
to [e-mail]
Betsy,
The pentanone was actually used in the Botanical Extraction (OS-10) operation in December of 2019. 1 went back
and changed this in the spreadsheet.The values should be correct in there now and the VOCs are accounted for in
Botanical Extraction.
I attached the updated spreadsheets with the Pentanone page and the Monthly VOCs page updated.There were
145 lbs. of pentanone emitted from Botanical Extraction in December 2019.
Thanks,
Brian
From: Huddleston, Betsy<[e-mail]>
Sent:Saturday, October 31, 20201:08 AM
To: Brian Conner<[e-mail]>
Subject:One question concerning 2019 Emission Inventory
"'This is an external email message.Confirm the sender before opening attachments or clicking links.Avoid content that looks suspicious.—
Hey Brian,
I noticed that pentanone was reported as emitted from PNE for CY2019 at 36,776 Ibs, but I don't see it
added to the PNE VOC total. May I add this to the total in AERO?
Betsy Huddleston, Regional Supervisor
NCDEQ, Division of Air Quality
Washington Regional Office
943 Washington Sq. Mall, Washington, NC 27889
Phone: [phone]
Fax: [phone]
hopshttps
jLdeq nc.gov/about/divisions/air-quality
************************************************************************
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
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11/1/2020 Mail-Huddleston,Betsy-Outlook
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This e-mail contains information which may be privileged,confidential,proprietary,trade secret and/or otherwise legally protected.It is not intended for
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Huddleston, Betsy
From: [e-mail]
Sent: Tuesday, March 24, 2020 9:14 AM
Subject: Inventory submission confirmation -- 0800044
Dear Brian Conner
Your submittal of the 2019 emission inventory for Avoca LLC, 0800044, has been received by the North Carolina Division of Air Quality (DAQ) on March 24,
2020 at 09:13:58. You have until the due date of the emission inventory or two weeks from this submittal to review and repudiate the data submitted.
Please remember to:
- print the Certification Form (see AERO Closeout page),
- have the Responsible Official sign it in blue ink,
- include copies of spreadsheets or calculations used in creating this inventory, and
- mail (postmark) it to NCDAQ, 943 Washington Square Mall,Washington, NC 27889 by the required due date in order for this submittal to be considered
complete. If you have any questions, please feel free to contact Betsy Huddleston, in the Washington Regional Office, at252-946-6481.
The Division of Air Quality thanks you for using AERO, the on line emissions inventory program.
Sincerely
DAQ
' 1

Avoca,LLC
4rA PO Box 129
Avoca, LLC 841 Avoca Farm Rd forMerry Hill,NC 27957
The World's Premier Botanical Extraction Company Phone: [phone]
Fax: [phone]
March 24,2020
Mr. Robert Fisher
Environmental Regional Supervisor II-Air Quality
NC Division of Air Quality
Washington Regional Office
943 Washington Square Mall
Washington,NC 27889
Subject: Annual Air Emissions Inventory
Air Quality Permit No. 01819T53
Facility ID: 07/08/00044
Avoca, LLC
Merry Hill,North Carolina
Bertie County
Fee Class: Title V
Dear Mr. Fisher:
In accordance to Avoca, LLC's Title V Air Quality Permit, I am forwarding the Inventory Certification
Form and supporting documentation for the Annual Air Emissions Inventory. The inventory was
submitted on March 24, 2020 via the AERO program. The attached certification form and copies of
spreadsheets and calculations used in creating this inventory are being submitted to fulfill the
requirements of the annual report.
If there are any questions or comments concerning the included documentation or inventory report please
contact me at(252)325-0335.
Sincerely,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, LLC
D r�� c
V E DD
MAR 26 2
Qq0 WARO

COPY of RECORD Date Submitted: 3/24/2020 09:13:58
Inventory Certification Form(Title V)
Facility Name: Avoca LLC Facility ID • 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environmental Quality
Division of Air Quality
Air Pollutant Point Source Emissions Inventory-Calendar Year 2019
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of rTecoF for your facility is Augustinus Gerritsen
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC
2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the
following:
1. For a corporation:a president,secretary,treasurer,or vice-president of the corporation in charge of a principal business
function,or any other person who performs similar policy or decision making functions for the overall operation of one or
more manufacturing,production,or operating facilities applying for a or subject to a permit and either
i. the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in
second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2. For partnership or sole proprietorship;a general partner or the proprietor,respectively;
3. For a municipality,state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION STATEMENT:
(Important: Legally Responsible Official,read and sign after all submissions are final.l
I certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in
this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal
penalties of up to$25,000 per occurrence and possible imprisonment as outlined in G.S. § 143-215.3(a)(2))
Responsible Official's Signature Below (use blue ink): Date Signed: 3 2N 0 Z D
Printed Name: Augus . s Ge en
Signature:
This form applies to Title ac' ies. If this facility is not classified asTitle V,please telephone your regional office Emission
Inventory Contact at o or oper forms.
Email address of Responsible Official: Quin , a1�32�rr ► _Ce" C° outs'M Q'^d a i G V I r 1
Information on this Form cannot be held confidential
M A R 2 6 2020
COPY of RECORD Date Submitted: 3/24/2020 09:13:58 W
1

L,r�c�Fe )r�0►�L�
Annual Air Emissions Inventory Summary
2019 Totals Facility ID#:08000"
Prapxn W-- awyN Nb11w Bdxwllb EdxwBdr. 91- Bobrinl Mad Oe1x
PMYaar4 6dIrt0 BMIx P2 aogxp B.brM 0.01 G.63 WnP3 04n 04 Pk4 Fln Puny 0.1w. aMonl lbenxy C-.r (BPO) (toe-1) MEQ) EWwaon E18ndbn NMdr EVO wwrp Prow4w TMtl4 Ur1Y
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CO 386.28136 673.44059 0.00000 BB.53505 9.28003 13.02544 0.00000 12.37417 18.96501 8.20852 19380.77 20470.012 Tvn/Tr
Wh.. 0.00102 0.00152 0.00000 0.28861 0:00190 0.00288 0.00000 MOM 0.00409 0.00025 2.02 2.308 TmNY
N 0. 1 0. 1 1. 1.353 T
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/l/v1/ZpLo
Annual Air Emissions Inventory
Facility ID#:0800044
Pentanone (Methyl Propyl Ketone): OS-7, OS-10
Year: 2019
Info: Lbs/Gal= 6.01
Monthly Inventory of Pentanone(gallons):
Beginning Max Used
Month InventoryReceived (Lbs) New Used Recovered Used Recovered
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
July: 0 0
August: 0 0
September: 0 0
October: 0 0
November: 0 0
December7 0 6144 36922 1 6119 1 1 6095
Total Gallons of Pentanone used during the year: 6119
Gallons of Pentanone used during the year @ PNE(OS-7):
Lbs.Of Pentanone used during the year @ PNE(OS-7): 0
Gallons of Pentanone used during the year@(0S-10): 6119
Lbs.Of Pentanone used during the year @(OS-10): 36775
Lbs.of Pentanone used by Misc.,QA,and R&D:
Lbs.of Pentanone sent to hazardous waste:
Lbs.of Pentanone sent offsite:
Lbs.of Pentanone emitted during year: 145

Disposed Monthly Used Ending
LL9-sl Inventory
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
6095 1 145 24

Annual Air Emissions Inventory Summary
2019 Totals Facility ID#:0800044
POIIUGM Bdw e1 e4d.eR -a.,q Propane OanM Gn82 pyna Oen N4 Pe-0en Flm Pump Biomass "-0 Reco CanrxRa RecrysblllzNbn SCNredMe SNaraolNM Blartrosa BOUnkal PIYII OBIa1
Boyer a4 Boilers e4rY (SFO) (SDE-1) (SOE-3) Ew_tl n Eatractbn f EVO 1V19TP hoeaaan T.W. lath
CO 38e.26136 573.44059 0.00D00 89.53505 9.25083 13,02544 O.000m 12.37417 19.99591 6.20852 19360,T 20470,912 Taa7r
A4elharo Om102 O.m152 0.00000 0.28881 O.m190 0.00265 O.000m 0.00253 0.00108 0.00025 2m 2.388 TarolYr
Ore ox" 0. A0303 0. 1 O.00D28 00318 0. 1. 1. T
P .D5616 0.083216 0.00000 0.02191 0. 110 0. 1 0.00000 O. 813 0 0.011110 0139 0437 T
P 10 0,01702 0. O.Omm 0. 191 110 0. 1 002813 001180 0.138 0. T
PM..S 0.OD53 0.01 0 110 00295 002B13 04Sf 0.01180 0.139 03p4 T r Z 67
Sm 107615 0.00m0 0. 0.02975 0.04175 0.00000 9.03966 O.m579 1 4. Ta Y,
0.OD339 0. 9.00000 5.81 eM11 0.9475 0.00000 0.90014 .45458 0.16789 1. 31.811 T
VO 0.00:410 000505 000000 0.05945 O.O11i88 0. .00000 0.02250 .1eXN 0.01371 18879 31.1 1 .1 I. 1 T
wWYr
CO 012531 0, 3 7 0.00000 1 0.39637 0. 17 19 T
ACN+Men 0.01063 0.0 0.00000 0,01415 002291 0.05M 164.8 5 1 �Yrr
Acrddn 0.00332 0. O.000m 0. 0.00716 0.m704 791
Araank 0.01906 0.00000 769 0.00237 D.ODOM 0. 0.00384 0. LeVYr
Biro 0.m359 .1 OAOODO 032743 0.45955 ODD00 0.43557 0.7 0.07104 834.002 LBW,
a 000011 OOm1 0. 0. 14 0. 0.00001 0.516 r
D.Mli­ 0.0142S 0021220.00000 0.00127 O.OD178 OAOODD 0.001 0,00023 0.043 UW(r
8u LearYr
C-i- O.O1Q9 OMIM O.mOm OW127 0.0017 0.00169 O.00Z73 0.00023 ppp
Calcium
Om LlalYr
Careon iNracnq
e.lzee e.935 Lever
Cnbnro 156,872
CnloroGrizene 0,553 156.8nLIu7Yr
Cnbrorarm LBW,
1 17 6553 L r
Cnramium 0.0142. . 1 O.- 0,036 LW14
nromw Dome 7
OEft, -100%mine 14514.341 1434
0.00 .m LDa/Yr
-SDA 0.00 O. 4304.512 L r
EtW acNata 35962.00 172.1f 788.00 ODD 38MAW LIMO
Ern Benzene 781 0.011 6.156 6.225 1
Et nearomirro 0.00 0.
F11! 1. i. .MOM
23M
For;1 1AMI 1 0.00000 ONUM 0.00000 0.04439 007173 0.08M M717 875.
HCI 17.871
Hevrolapnxa 0000 670146.39 0. 1]571 LMIVr
N-Howie 0m 380.55.i moo1711458.
28349.H3 0. 23317. O.m i .m7
H.- 31 15 EBBS.48 .m Bi W LBr
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4
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LnE Com unea 0.04259 O. 0.00000 0.107
Man Anna 09 O. " O. D ,071 L1rolYr
Meru 0O.0IQ7429 0. 1 0.00000
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0.011 0.02122 O.000m01505 4 9 7 LNYr
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/.� -Aa� 3

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2019
Total Run Time: 2225.0 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 20985.3 41017.7 0.0 62003.0 587.0 512.8 0.0 1099.8 0.035 12.401
February: 544.8 445.9 0.0 990.7 25.1 38.8 0.0 63.9 0.001 0.198
March: 1926.1 5804.8 0.0 7730.9 55.8 193.3 0.0 249.1 0.004 1.546
April: 1078.2 1016.7 0.0 2094.9 31.2 31.6 0.0 62.8 0.001 0.419
May: 124.5 506.8 0.0 631.3 10.8 29.3 0.0 40.1 0.000 0.126
June: 4811.5 25.7 0.0 4837.2 144.2 5.4 0.0 149.6 0.003 0.967
July: 635.0 75.4 0.0 710.4 23.9 10.9 0.0 34.8 1 0.000 0.142
August: 937.2 295.8 0.0 1233.0 38.7 28.5 0.0 67.2 0.001 0.247
September: 1131.1 165.9 0.0 1297.0 55.4 43.3 0.0 98.7 0.001 0.259
October: 675.7 0.0 0.0 675.7 18.9 0.0 0.0 18.9 0.000 0.135
November: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.000 0.000
December: 1184.2 1168.7 0.0 1 2352.9 171.2 1 88.9 0.0 340.1 0.001 0.471
Total: 34033.6 50523.4 0.0 1 84557.0 1162.2 1062.8 0.0 2225.0 0.047 16.911
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 29.3 1162.2 34033.E CY2�i p�J u-�, 7Z,W11M
2 H-102 143 47.5 1062.8 50523.4 V /
3 H-103 180 #DIV/0! 0.0 0.0
Total 466 #DIV/01 2225 84557.0
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. Tons/Yr Tons/Yr Tons/Yr Tons/Yr
TSP 3.30 0.056 0.083 0.000 0.140
PM-10 1.00 0.017 0.025 0.000 0.042
PM-2.5 0.25 0.004 0.006 0.000 0.011
Sox 42.60 0.725 1.076 0.000 1.801 $O (5 fl•0014 �i S So 11L9/1af
Nox 0.20 0.003 0.005 0.000 0.008
VOC 0.20 0.003 0.005 0.000 0.008
CO 5.00 0.085 0.12E 1 0.000 0.211
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.019 0.028 0.000 0.047
Benzene 2.75E-03 0.094 0.139 0.000 0.233
Beryllium 4.20E-04 0.014 0.021 0.000 0.036
Cadmium 4.20E-04 0.014 0.021 0.000 0.036
Chromium 4.20E-04 0.014 0.021 0.000 0.036
Chromium VI 2.90E-05 0.001 0.001 0.000 0.002
-Ethyl benzene 8.17E-04 0.028 0.041 0.000 0.069
Flouride 3.73E-02 1.269 1.885 0.000 3.154
-Formaldehyde 4.80E-02 1.634 2.425 0.000 4.059
Lead 1.26E-03 0.043 0.064 0.000 0.107
Manganese 8.40E-04 0.029 1 0.042 1 0.000 0.071
Mercury 4.20E-04 1 0.014 1 0.021 1 0.000 0.03E
T:\EH&S\EnvironmentalWir Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc
i

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Na thalene 3.30E-04 &011 0.017 1 0.000 1 0.028
Nickel 4.20E-04 0.014 0.021 0.000 0.036
Toluene 7.97E-02 2.712 4.027 0.000 6.739
o-X lene 1.40E-03 0.048 0.071 0.000 0.118
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)
COz 22700.00 664.74 1079.11 #DIV/01 386.28 573.44 #DIV/0! #DIV/0!
Methane 0.06 0.0018 0.0029 #DIV/0! 0.0010 0.0015 #DIV/0! #DIV/0!
(CH4)
Nitrous Oxide(N20) 0.12 0.0035 0.0057 #DIV/01 0.0020 0.0030 #DIV/01 #DIV/01
/?"hyf ChI oForr7) Z.3(oE-V !b
/74'as5'e
!'one 3,3 E-3 1b/yaao5 P - 0 .1-79 Ib t6r�
�'26er�ivn" z.I E:-s /b
llcoc9Jt
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc
1

Annual Air Emissions Inventory
Facility ID#: 0800044
Propane Boiler : OS-???
Year: 2019
Total Run Time: 7445.0 Hrs/Yr
Efficiency: 95 %
Sulfur Content: 0 %
Propane 91000 Btu/Gal
Propane Hours VOC
Month Used Operated Emissions
Gallons Lbs
January: 67598.0 432.0 13.5
February: 102863.0 672.0 20.6
March: 135929.0 720.0 27.2
April: 108758.0 720.0 21.8
May: 60801.0 600.0 12.2
June: 23248.0 504.0 4.6
July: 51394.0 744.0 10.3
August: 97763.0 744.0 19.6
September: 91919.0 626.0 18.4
October: 27432.0 648.0 5.5
November: 55277.0 587.0 11.1
December: 71474.0 448.0 14.3
Total: 894456.0 7445.0 178.9
Boiler# ID # GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-104 120.1 7445.0 894456.0
Criteria Pollutants
Criteria Emisson Factor Boiler#4
Pollutants Lbs./1000 al. Tons/Yr
TS P 0.05 0.022
PM-10 0.05 0.022
PM-2.5 0.04 0.018
Sox 0.02 0.009
Nox 13.00 5.814
VOC 0.20 0.089
CO 7.50 3.354
Green House Gas Pulutants
Emission Boiler#4 Boiler#4
GHG Pollutant Factor (Ibs/hr) (tons/yr)
(Ibs/1000 gal)
COz 2^�i12,C! 24.05 89.54
i

Methane 0.60 0.07 0.27
(CH4)
Nitrous Oxide 0.12 0.01 0.05
(N2O)

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only! ( b �
Year: 2019 D r
Total Run Time: 27.0 HrslYr f ` P-
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC /V0 Cp AKGE 1 N 1'r
Month Fuel
Used Operated hour (Ibs.)
January: 50.0 2.50 20.0 2.604
February: 30.0 1.50 20.0 1.562
March: 40.0 2.00 20.0 2.083
April: 30.0 1.50 20.0 1.562
May: 100.0 5.00 20.0 5.208
June: 50.0 2.50 20.0 2.604
July: 40.0 2.00 20.0 2.083
August: 60.0 3.00 20.0 3.125 LY uj/'t 5 p 1 C((,t S
September: 40.0 2.00 20.0 2.083
October: 40.0 2.00 20.0 2.083 Qp�yZ
November: 30.0 1.50 20.0 1.562
December: 30.0 1.50 20.0 1.562
Total: 540.0 27.00 20.0 28.1
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Fir Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 285 214 27.0 20.0 540.0 2.82 76.14
Criteria Emisson Factor (Lb/MM FP
Pollutants BTU) (TonsNr
TSP 0.31 0.012
PM-10 0.31 0.012
PM-2.5 0.31 0.012
Sox 0.152 0.006
Nox 4.41 0.168 �Y`dYAl 4!J
VOC 0.36 0.014
CO 0.95 0.036
Green House Gases
Hazardous/Toxi Emisson Factor (Lb/MM FP GHG Emisson Factor E101
c Air Pollutants BTU) (Lbs/Yr) Pollutant K /MM BTU tons! r
CO2 73.960 6.209
Acetaldehyde 7.67E-04 0.058 0.003 0.000252
Nitrous
Acrolein 9.25E-05 0.007 Oxide 0.0006 0.000050
(N20) J/� �Z7 Er
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.071 �.2,?
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002
-Formaldehyde 1.18E-03 0.090
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.031
X lene 2.85E-04 0.022

GAS&DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR REVISIONS 6/22/2015--OUTPUT SCREEN
�� Instructions: Enter emission source/facility data on the"INPUT'tabiscreen.The air emission results and summary of input data are
4 viewed/printed on the'OUTPIIT"tab/screen.The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the information contained.
�`� This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available.
NCDENR DENR is not responsible for errors or omissions that may be contained herein-
SOURCE/
/USER INPUT SUMMARYPUTS
COMPANY: Avoca PERMIT
ID NO.: 800044
PERMIT NUMBER: 0
EMISSION SOURCE DESCRIPTION: 214 HP POWER OUTPUT DIESEL INTERNAL COMBUSTION ENGINE FACILITY CITY: Merry Hill
EMISSION SOURCE ID NO.: FP FACILITY COUNTY: Bertie / , 'r•UT-�
SPREADSHEET PREPARED BY: ETH POLLUTANT CONTROL EFF.
ACTUAL THROUGHPUT 540 GALS COMBUSTED I FUEL HEATING VALUE: 1400001 BTU/GAL PM 0
REQUESTED ANNUAL LIMITATION 28,000 GALS COMBUSTED CALCULATIONS: 0.138 mm BTU/GAL PM10 0
SULFUR CONTENT OF DIESEL FUEL(%) 0 PM2.5 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF S02 0
CARBON CONTENT USED FOR GHGS(kg C/gal): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN NOX 0
CO 0
VOC 0
CftfrERIA AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
Inr�n carraa. ns/ ra�coemasvr�*sl tacovn:oksnwirsl INhpM
AIR POLLUTANT EMITTED Ib/hr s tons/ Ib/hr tons/yr Ib/hr tons/yr uncontrolled
PARTICULATE MATTER PM 0.47 0.01 0.47 2.06 0.47 0.62 2.20E-03
PARTICULATE MATTER<10 MICRONS(PM1e) 0.47 0.01 0.47 2.06 0.47 0.62 220E-03
PARTICULATE MATTER<2.5 MICRONS(PM,.,) 0.47 0.01 0.47 2.06 0.47 0.62 2.20E-03
SULFUR DIOXIDE S02 0.00 0.00 0.00 0.01 0.00 0.00 1.21E-05
NITROGEN OXIDES NOx 6.63 0.17 6.63 29.06 6.63 8.68 3.10E-02
CARBON MONOXIDE CO 1A3 0.04 143 6.26 1.43 1.87 6.68E-03
VOLATILE ORGANIC COMPOUNDS(VOC) 1 0.54 1 0.01 1 0.54 2.36 1 0.54 0.70 1 2.51E-03
TOXIC/HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
CAS IAFreecoernoksiuunsl (eF-mvmoksi.-) I-.-airnsl Ib/hphr
TOXIC/HAZARDOUS AIR POLLUTANT NUMBER Ib/hr Ib/ Ib/hr Ib/ Ib/hr I uncontrolled
Acetaldehyde(H,T) 75070 1.15E-03 5.80E-02 1.15E-03 1.01E+01 1.15E-03 3.01E+00 5.37E-06
Acrolein H,T 107028 1.39E-04 6.99E-03 1.39E-04 1.21E+00 1.39E-04 3.63E-01 6.48E-07
Arsenic unlisted compounds(H,T) ASC-Other 5.99E-06 3.02E-04 5.99E-06 5.25E-02 5.99E-06 1.57E-02 2.80E-08
Benzene(H,T) 71432 1.40E-03 7.05E-02 1.40E-03 1.22E+01 1.40E-03 3.66E+00 6.53E-06
Benzo(a)pyrene(H,T) 50328 2.82E-07 1.42E-05 2.82E-07 2.47E-03 2.82E-07 7.37E-04 1.32E-09
Beryllium metal unreacted H,T 7440417 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
1,3-Butadiene(H,T) 106990 5.86E-05 2.96E-03 5.86E-05 5.13E-01 5.86E-05 1.53E-01 2.74E-07
Cadmium metal elemental unreacted H,T 7440439 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Chromic Acid(VI)(H,T) T738945 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Formaldehyde(H,T) 50000 1.77E-03 8.92E-02 1.77E-03 1.55E+01 1.77E-03 4.63E+00 8.26E-06
Lead unlisted compounds(H) PBC-Other 1.35E-05 6.80E-04 1.35E-05 1.18E-01 1.35E-05 3.53E-02 6.30E-08
Manganese unlisted compounds(H,T) MNC-Other 8.99E-06 4.54E-04 8.99E-06 7.87E-02 8.99E-06 2.35E-02 4.20E-08
Mercury vapor H,T 7439976 4.49E-06 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Na thalene H) 91203 1.27E-04 6.41E-03 127E-04 1.11E+00 1.27E-04 3.32E-01 5.94E-07
Nickel metal H, 7440020 1 4.49E-06 I 2.27E-04 4.49E-06 3.94E-02 4.49E-06 1.18E-02 2.10E-08
Selenium compounds(H) SEC 2.25E-05 1.13E-03 2.25E-05 1.97E-01 2.25E-05 I 5.88E-02 1.05E-07
Toluene(H,T) 108883 6.13E-04 3.09E-02 6.13E-04 5.37E+00 6.13E-04 1.60E+00 2.86E-06
Xylene H,T 1330207 4.27E-04 2.15E-02 4.27E-04 3.74E+00 4.27E-04 1.12E+00 2.00E-06
Highest HAP(Formaldehyde) 50000 1.77E-03 8.92E-02 1.77E-03 1.55E+01 1.77E-03 4.63E+00 8.26E-06
Total RAPS 5.75E-03 2.90E-01 5.75E-03 5.04E+01 5.75E-03 1.51E+01
TOXIC AIR POLLUTANT EMISSIONS INFORMATION FOR PERMITTING PURPOSES
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS EMISSION FACTOR
Ib1hp4v
TOXIC AIR POLLUTANT CAS Num. Ib/hr lb/day lblyr uncontrolled
Acetaldehyde(H,T) 75070 1.15E-03 2.76E-02 3.01E+00 5.37E-06
Acrolein(H,T) 107028 1.39E-04 3.33E-03 3.63E-01 6.48E-07
Arsenic unlisted compounds H, ASC-Other 5.99E-06 1.44E-04 1.57E-02 2.80E-08
Benzene(H,T) 71432 1.40E-03 3.35E-02 3.66E+00 6.53E-06
Benzo(a)pyrene H,T 50328 2.82E-07 6.76E-06 7.37E-04 1.32E-09
Beryllium metal(unreacted)(H,T) 7440417 4.49E-06 1.08E-04 1.18E-02 2.10E-08
1,3-Butadiene(H,T) 106990 5.86E-05 1.41E-03 1.53E-01 2.74E-07
Cadmium metal(elemental unreacted)(H,T) 7440439 4.49E-06 1.08E-04 1.18E-02 2.10E-08
soluble chromate compounds,as chromium(VI)equivalent SOLCR6 I 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Formaldehyde(H,T) 50000 1.77E-03 4.24E-02 4.63E+00 826E-06
Manganese unlisted compounds H, MNC-Other 8.99E-06 2.16E-04 2.35E-02 420E-08
Mercury vapor(H,T) 7439976 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Nickel metal(H,T) 7440020 4.49E-06 1.08E-04 1.18E-02 2.10E-08
Toluene(H,T) 108883 6.13E-04 1.47E-02 1.60E+00 2.86E-06
Xyiene(H,T) 1330207 4.27E-04 1.02E-02 I 1.12E+00 2.00E-06
GREENHOUSE GAS EMISSIONS INFORMATION(FOR EMISSIONS INVENTORY PURPOSES)-CONSISTENT WITH EPA GHG-POIEN17AL TO EMIT
MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD
DISTXLATE#2 ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat input POTENTIAL EMISbl(JN.S With
rapacity or horsepower and EPA MRR Emission Reuested Emission Limitation-utilize
Factors requested fuel limit and EPA MRR
GREENHOUSE GAS EMITTED EPA MRR CALCULATION METHOD:TIER 1 Emission Factors
metric tons/yr metric tonstyr,CO2s short ton short tonslyr short tons/ ,CO29 short ton short tons/ ,CO2e
CARBON DIOXIDE(CO2) 5.51 5.51 6.08 1,069.83 1,069.83 319.59 319.59
METHANE(CH4) 224E-04 5.59E-03 2.46E-04 4.34E-02 1.08E+00 1.28E-02 3.19E-01
NITROUS OXIDE(N20) 4.47E-0S 1.33E-02 4.93E-05 8.68E-03 2.59E+00 2.56E-03 7.62E-01
TOTAL 5.53 TOTAL 1,073.51 TOTAL 320.67
NOTE: CO2e means CO2 equivalent-
NOTE, The DAQ Air Emissions Reporting Online(AERO)system requires short tons be reported. The EPA MRR requires metric tons be reported.
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Page 1 of 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year: 2019 Total Run Time: 567.0 Hrs/Yr Cy 201 t 87,9 h6
Efficiency: 75
Sulfur Content: 0_3
Number Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Total (Lbs.)
January: 30.0 62.5 0.0 40.0 132.5 6.9
February: 30.0 37.5 0.0 40.0 107.5 5.6
March: 37.5 50.6 0.0 50.0 137.5 7.2
April: 30.0 50.0 0.0 40.0 120.0 6.2
May: 30.0 50.0 0.0 40.0 120.0 6.2 /NO c jjANG�_ /M
June: 2647.5 3637.5 0.0 3530.0 9815.0 511.2
July: 30.0 50.0 0.0 40.0 120.0 6.2
August: 37.5 62.5 0.0 50.0 150.0 7.8
September: 30.0 50.0 0.0 40.0 120.0 6.2
October: 30.0 50.0 0.0 40.0 120.0 6.2
November: 37.5 62.5 0.0 50.0 150.0 7.8
December: 22.5 1 37.5 0.0 30.0 1 90.0 4.7
Total: 1 2992.5 1 4200.0 0.0 3990.0 1 11182.5 1 582.4
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr MM Btu/Hr MM Btu/Yr
1 E101 587 440 199.5 15.0 2992.5 2.12 421.94
2 E102 760 570 168.0 25.0 4200.0 3.53 592.20
3 E103 603 452 0.0 20.0 0.0 2.82 0.00
4 E104 534 401 199.5 20.0 3990.0 2.82 562.59
Total 2484 1863 667 80 11182.5 11 1577
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Pollutants (Lb'MM BTU) (Tons'Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.100 0.021 0.030 0.000 0.028 0.079
PM-10 0.100 0.021 0.030 0.000 0.028 0.079
PM-2.5 0.100 0.021 0.030 0.000 0.028 0.079
Sox 0.141 1 0.030 1 0.042 0.000 0.040 0.111
Nox 3.200 0.675 0.948 0.000 0.900 2.523
VOC 0.080 0.017 1 0.024 0.000 0.023 0.063
CO 0.850 0.179 1 0.252 0.000 0.239 0.670
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total C, 1.e.Ci d_I 4 �
Air Pollutants (Lb/MM BTU) (Lbs/Yr) (Lbs'Yr) (Lbs'Yr) (Lbs/Yr) (Lbs/Yr) ,,u�I�ym � Mt yM
-Acetaldehyde 2.52E-05 0.010633 0.014923 0.000000 0.014177 0.040 �n'� &
I nt I RA/ /
Acrolein 7.88E-06 0,003325 0.004667 0.000000 0.004433 0.012
Arsenic 4.00E-06 0.001688 0.002369 0.000000 0.002250 0.006 C oJr wns
Benzene 7.76E-04 0.327427 0.459547 0.000000 0.436570 1.224
Benzo a rene 2.57E-07 0.000108 0.000152 0.000000 0.000145 0.0004 L 6,62Y tb
Beryllium 3.00E-06 0.001266 0.001777 0.000000 0.001688 0.005
Cadmium 3.00E-06 0.001266 0.001777 0.000000 0.001688 0.005 Q ��
-Formaldehyde 7.89E-05 0.033291 0.046725 0.000000 0.044388 0.124
Na thalene 1.30E-04 0.054853 0.076986 0.000000 0.073137 0.205
Toluene 2.81E-04 0.118566 0.166408 0.000000 0.158088 0.443
X Iene 1.93E-04 0.081435 0.114295 0.000000 O 08580 0.304 ) A r
t-C C cmt55�°�S
Green House Gas Pulutants M" E- �j,� $/ ^^ af
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total 0 `, � -
(Lb/MM BTU) tons/ r tons' r tons' r tons' r tons' r � 3 E - v
COz 43.990 9.2806 13.0254 0.0000 12.3742 34 668 ,f� +�t� .C
Methane ni CK" 3E-L ' l
(CH4) 0.009 0.0019 0.0027 0.0000 0.0025 0.00710 eh-), ors f OY,S -�
Nitrous Oxide ley ) a-$,yw `7
(N2O) 0.001 0.0002 0.0003 0.0000 0.0003 0.000788 AA j� y�d(OLQ
.�}yY,rYwl d
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc Page 1

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
insruaions.Please provide the information shown in blue below.The applicability of this spreadsheets limited to diesel engines larger than 600 hp and all dual-fuel(dieseVnatural gas)engines.
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
User Inout DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca guarantee the accuracy of the Information contained.This spreadsheet is subject to continual revision
Plant County. Bertie and updating.it Is your responsibility to be aware of the most current information available. DENR
Plant City: Merry Hill is not responsible for erron;or omissions that may be contained herein.
Permit Number. NA
User: ETH
Fuel Sulfur Fuel Input Rates Diesel(gal) N cu Heat Input Rates 212W yy¢
Diesel Fuel Sulfur Content(°/s): 0.00 Hourly Fuel Usage: 0.00 t,000 Hourly Fuel Usage (mmBtu): 0.00 1.05
NG Fuel Sulfur Content r/mm cu ft: 2,00o Annual Fuel Usage: 11,183 4,000 Annual Fuel Usage (mmBtu): 1,577 4
Fuel Heat Content: 141,000 1,050(Btu/gal for diesel,Btu/cu.ft for NG)
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant Ib/hr Ib r t Ib/mm8tu Ratin Pollutant Ib/hr Ib/ t Ib/mmBtu Ratin
PM 0.00 157.67 0.08 1.00E-01 B PM NA NA NA NO NA
PM-10 0.00 157.67 0.08 1.00E-01 B PM-10 NA NA NA NO NA
PM-2.5 0.00 157.67 0.08 1.00E-01 B PM-2.5 NA NA NA NO NA
NO uncont. 0.00 5,045.54 2.52 3.20E+00 B NO.uncont. 2.84 4,268.52 2.13 2.70E+00 D
NO.,cont. 0.00 2,996.79 1.50 1.90E+00 B NO.cont. NA NA NA ND NA
TOC(as CH4) 0.00 141.91 0.07 9.00E-02 C TOC(as CH4) 0.84 1,264.75 0.63 8.00E-01 D
NMTOC 0.00 129.13 0.06 8.19E-02 E NMTOC 0.21 316.19 0.16 2.00E-01 E
CO 0.00 1,340.22 0.67 8.50E-01 C CO 1.22 1,833.88 0.92 1.16E+00 D
SO, 0.00 2.39 0.00 1.52E-03 B SO, 10.001 0.21 0.00 1.31E-04 B
Total HAP O.00E+00 2.76E+00 1.38E-03 1.75E-03 NA
Largest HAP benzene 0.00E+00 1.22E+00 6.12E-04 7.78E-04 NA
Toxic/Hazardous Air Pollutants There are no Tokc/Hazardous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number Ib/hr lb/day blyr
Acetaldehyde 75070 0.00E+00 0.00E+00 3.97E-02 2.52E-05 E
crolein 107028 0.00E+00 0.00E+00 1.24E-02 7.88E-06 E
Arsenic unlisted compounds ASC-Other 0.00E+00 0.00E+00 6.31E-03 4.00E-06 E
Benzene 71432 0.00E+00 0.00E+00 1.22E+00 7.76E-04 E
Benzo(a)pyrene 50328 0.00E+00 0.00E+00 4.05E-04 2.57E-07 E,<
Beryllium metal(unreacted) 7440417 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Chromic Acid(VI) 7738945 0.00E+00 O.00E+00 4.73E-03 3.00E-06 E
Formaldehyde 50000 O.00E+00 0.00E+00 1.24E-01 7.89E-05 E
cad unlisted compounds PBC-Other 0.00E+00 0.00E+00 1.42E-02 9.00E-06 E
Manganese unlisted compounds MNC Other 0.00E+00 0.00E+00 9.48E-03 6.00E-06 E
Mercuryvapor 7439976 0.00E+00 0.00E+00 4.73E-03 3.00E-06 E
Napthalene 91203 0.00E+00 0.00E+00 2.05E-01 1.30E-04 E
Nickel metal 7440020 0.00E+00 O.00E 3.00E-06 E
Selenium compounds SEC O.00E+00 0.00E+00 2.37E-02 1.50E-05 E
Total PAH 0.00E+00 0.00E+00 3.34E-01 2.12E-04 E,<
Toluene 108883 0.00E+00 0.00E+00 4.43E-01 2.81E-041 E
Ixylenes 11330207 1 0.00E+00 0.00E+00 3.04E-01 1.93E-041 E
Greenhouse Gases-methods consistent with TCR other protocol* Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA MandatorvR000rtinaRule Factor Quality but not with EPA Mandatory Reporting Rule Factor Quality
Pollutant Ib r toy (lb/innil Rating Pollutant Ib/hr lb/vr t Ib/mmBtu Rating
Carbon Dioxide(CO2) 254,320.25 127.16 43.99 NA Carbon Dioxide(CO2) 264,811.61 127A1 43.96 NA
Methane(CH4) 347.67 0.17 0.009 NA Methane(CH4) 21,351.48 10.68 0.540 NA
Nitrous Oxide(N20) 621.63 0.31 0.001 NA Nitrous Oxide(N20) 623.29 0.31 0.001 NA
Total: 255,289.55 127.64 Total: 276,786.38 138.39
Note:Do not use greenhouse gas emission estimates from tits spreadsheet for PSD(Prevention of Significant Deterioration purposes.
NO,control is vie ignition timing retard.
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other toxic/hazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"<"indicate an AP-42 emission factor based on test results being below detection.
Emission factors for criteria pollutants are from AP-42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP-42 Chapter 1.3,Fuel Ol Combustion(revised 5/10). N�ENR
All other toxiclhazardous pollutants are from AP-42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines:Stationary Combustion Sources,June 2008,except for CH4,
which uses AP-42,Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP-42 Chapter 3.4,p.3.4-5(revised 10/96).
Hourly emission rates for all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours.

Annual Air Emissions Inventory
Facility ID#: 0800044
PK- Generator : OS-12
Year: 2019
Total Run Time: 89.6 Hrs/Yr CY 2_0 i�
5 S,
Efficiency: 75
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Emisson Emisson
Hazardous/
Fuel Usag a Hours VOC Criteria Factor Pk-Gen Factor Pk-Gen
ons
Month Pollutants (Lb/MM (T /Yr) Toxic Air (Lb/MM Lbs/Yr
(gallons) Operated (Lbs.) Pollutants ( )
BTU) BTU
TSP 0.1 0.0455 Acetaldehyde 2.52E-05 0.0229
January: 180 2.5 9.37 PM-10 0.1 0.0455 Acrolein 7.88E-06 0.0072
February: 108.0 1.5 5.62 PM-2.5 0.1 0.0455 Arsenic 4.00E-06 0.0036
March: 180.0 2.5 9.37 Sox 0.141 0.0641 Benzene 7.76E-04 0.7055
April: 252.0 3.5 13.12 Nox 3.2 1.4546 Benzo a rene 2.57E-07 0.0002
May: 180.0 2.5 9.37 VOC 0.36 0.1636 Beryllium 3.00E-06 0.0027
June: 900.0 12.5 46.87 CO 0.85 0.3864 Cadmium 3.00E-06 0.0027
July: 874.8 12.2 45.56 Formaldehyde 7.89E-05 0.0717
August: 1288.8 17.9 67.12 Na thalene 1.30E-04 0.1182
September: 2052.0 28.5 106.87 Toluene 2.81E-04 0.2555
October: 144.0 2.0 7.50 X lene 1.93E-04 0.1755
November: 180.0 2.5 9.37
December: 108.0 1.5 5.62 (j 1 oU ` 15�r
Total: 6447.6 89.6 335.8 S
Heat Rate
Generator No. ID# Bhp h Hr/Yr Gals/Hr Gals/Yr MM Btu/Hr MM Btu/Yr
Pk Gen Pk-Gen 2670 2003 89.6 72.0 6447.6 10.15 909.11
Green House Gas Pulutants for Peak Generator G'0 p c ItuK �n O Ore.+ t''CIV-1
Emisson Factor //
GHG Pollutant Ibs/yr tons/yr(Lb/MM BTU) -,At047- fc d'aN
C(�J
CO2 43.990 39991.82 20.00 tors
Methane 0.009 8.18 0.0041 r-vV►om lc Ac>d 3 E-
(CHa) L2CI.0 �
Nitrous Oxide(N20) 0.007 6.36 0.00318 M 6-"
7b.�.P
N44-A c--?

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
I nsructions:Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual-fuel(dieseynatural gas)engines.
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca guarantee the accuracy of the information contained.This spreadsheet is subject to continual revision
Plant County. Bartle and updating.It is your responsibility to be swam of the most current information available. DENR
Plant City: Merry Hill is not responsible for errors or omisslons that may he contained herein.
Permit Number. NA
User: ETH
Fuel SuHur Fuel Input Rates Diesel(gall NG icu Heat Input Rates Diesel NG
Diesel Fuel Sulfur Content(°k): 0.00 Hourly Fuel Usage: 0.00 1,000 Hourly Fuel Usage (mmBtu): 0.00 1.05
NG Fuel Sulfur Content r/mm cu ft): 2,00o Annual Fuel Usage: 6,446 4 000 Annual Fuel Usage (mmBtu): 909 4
Fuel Heal Content: 141,000 1,050 (Btu/gal for diesel,Btu/cu.It for NG)
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Oualrty Criteria Pollutants Factor Quality
Pollutant Ib/hr Ib r t (lb/mmBtu) RatingPollutant Ib/hr Ib/ t lb/mmBtu Ratin
PM 0.00 90.91 0.05 1.00E-01 B PM NA NA NA ND NA
PM-10 0.00 90.91 0.05 1.00E-01 B PM-10 NA NA NA ND NA
PM-2.5 0.00 90.91 0.05 1.00E-01 B PM-2.5 NA NA NA ND NA
NO.,uncont. 0.00 2,909.16 1.45 3.20E+00 B NO uncont. 2.84 2,485.94 123 2.70E+00 D
NO.,cont. 0.00 1,727.31 0.86 1.90E+00 B NO.,cont. NA NA NA ND NA
TOC(as CH4) 0.00 81.82 0.04 9.00E-02 C TOC(as CH4) 0.84 730.65 0.37 8.00E-01 D
NMTOC 0.00 74.46 0.04 8.19E-02 E NMTOC 0.21 182.66 0.09 2.00E-01 E
CO 0.00 772.74 0.39 8.50E-01 C CO 1.22 1,059.44 0.53 1.18E+00 D
6<� 0.00 0.00 1.52E-03 B JSO, 10.001 0.12 0.00 1.31E-041 B
Total HAP 0.00E+00 1.59E+00 7.97E-04 1.75E-03 NA
Largest HAP benzene 0.00E+00 7.05E-01 3.53E-04 7.76E-04 NA
Toxic/Hazardous Air Pollutants There are no Toxic/Hazardcus Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number Ib/hr lb/day Ib/yr
ceteldehyde 75070 0.00E+00 0.00E+00 2.29E-02 2.52E-05 E
croleln 107028 0.00E+00 0.00E+00 7.18E-03 7.88E-06 E
rsenc unlisted compounds ASC-Other 0.00E+00 0.00E+00 3.84E-03 4.00E-06 E
Benzene 71432 0.00E+00 0.00E+00 7.05E-01 7.76E-04 E
Benzo(a)pyrene 50328 0.00E+00 0.00E+00 2.34E-04 2.57E-07 E,<
Beryllium metal(unreacted) 7440417 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Chromic Acid(VI) 7738945 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Formaldehyde 50000 0.00E+00 0.00E+00 7.17E-0Z 7.89E-05 E
Lead unlisted compounds PBC-Other O.00E+00 O.00E+00 8.18E-03 9.00E-06 E
Manganese unlisted compounds MNC-Other 0.00E+00 0.00E+00 5.45E-03 6.00E-06 E
Mercuryvapor 7439976 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Napthalene 91203 0.00E+00 O.00E+00 1.18E-01 1.30E-04 E
Nickel metal 7440020 0.00E+00 0.00E+00 2.73E-03 3.00E-06 E
Selenium compounds SEC 0.00E+00 O.00E+00 1.36E-02 1.50E-05 E
total PAH 0.00E+00 O.o0E+00 1.93E-01 2.12E-04 E,<
Toluene 108883 O.00E+00 0.00E+00 2.55E-01 2.81E 04 E
1Xylenes 11330207 1 0.00E+00 0.00E+00 1.75E-01 1.93E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandatory Re ortin Rule Factor Quality but not with EPA Mandatory R000rtina Rule Factor Quality
Pollutant Itityr t Ib/mmBtu Rating Pollutant Ib/hr lb/yr t (lb/mmBtu) Rating
Carbon Dioxide(CO2) 146,635.84 73.32 43.99 NA Carbon Dioxide(CO2) 147,127.20 73.56 43.93 NA
Methane(CH4) 200.46 0.10 0.009 NA Methane(CH4) 12,334.84 6.17 0.540 NA
Nitrous Oxide(N20) 358.42 0.18 0.001 NA Nitrous Oxide(N20) 360.08 0.18 0.001 NA
Total: 147,194.72 73.60 Total: 159,822.12 79.91
Note:Do not use rsenhouse gas amisslon astlmaus from this s r edshest for P8D Prevention of significant Deterioration)purpmes.
NO,control Is via ignition timing retard.
Pollutants in ,i are federally regulated hazardous air pollutants(HAPs)only. All other toxicthazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing'<'indicate an AP-42 emission factor based on test results being below detection. ���
Emission factors for criteria pollutants are from AP-42 Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP-42 Chapter 1.3,Fuel Oil Combustion(revised 5/10). NCDENR
All other toxic/hazardous pollutants are from AP-42 Chapter 3A,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines:Stationary Combustion Sources,June 2008,except for CH4,
which uses AP-42,Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP-42 Chapter 3.4.p.3.4-5(revised 10/96).
Hourly emission rates for all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly Input rate for 24 hours.

Annual Air Emissions Inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2: OS-33
Fuel Source : Wood Chips
Year: 2019
Total Run Time: 8068.0 Hrs/Yr )-
Wood Chips 8000000 BTU /ton So � l�he�5fure C��I� �780�5h►'S ` Z39o1.� ���c�i�P
" Emission Factors determined by Emissions test conducted on 12/19/2013
Boiler Operation (Hours) Wood Chips Burned (Tons) CO PM HCL Hq Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood
Hours Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Chips
January: 608.0 657.0 657.0 681.0 756.2 1437.2 2207.5 16.09664 1.034784 0.00333 11497.6
February: 648.0 672.0 672.0 990.0 1080.5 2070.5 3180.3 23.1896 1.49076 0.00480 16564
March: 701.0 701.0 701.0 718.6 718.6 1437.2 2207.5 16.09664 1,034784 0.00333 11497.6
April: 439.0 439.0 439.0 511.0 512.1 1023.1 1571.5 11.45872 0.736632 0.00237 8184.8
May: 710.0 744.0 744.0 1342.8 1482.8 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
June: 720.0 720.0 720.0 1291.0 1291.0 2582.0 3966.0 28.9184 1.85904 0.00599 20656
July: 744.0 744.0 744.0 1266.0 1267.3 2533.3 3891.1 28.37296 1.823976 0.00588 20266.4
August: 744.0 744.0 2338.4 0.0 2338.4 3591.8 26.19008 1.683648 0.00543 18707.2
September: 624.0 264.0 624.0 1357.0 396.8 1753.8 2693.8 19.64256 1.262736 0.00407 14030.4
October: 744.0 744.0 744.0 1388.5 1388.5 2776.9 4265.3 31.10128 1.999368 0.00644 22215.2
November: 720.0 720.0 1 720.0 1291.0 1291.0 2582.0 3966.0 28.9184 1.85904 0.00599 20656
December: 295.0 559.0 559.0 455.0 1006.5 2244.9 16.3688 1.05228 0.00339 11692
Total: 7697.0 6964.0 8068.0 13630.3 1 11191.3 24821.5 38125.8 278.001 17.871 0.05759 198572.0
Average 641.4 633.1 672.3 1135.9 932.6 8.5 3177.2 23.167 1.489 0.00480 16547.7

06
Criteria Pollutants Z01�
Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler 1al
Pollutants (Lb/MM BTU) (Tons/Yr) Pollutants (Lb/MM BTU) (Lbs/Yr) GY?� 7-0 TA v ZY821.5 1,4S V-00�
TSP 0.0014 0.139 Acetaldehyde 8.30E-04 164.815 S7Z MNtg�U/Y�
PM-10 0.0014 0.139 Acrolein 4.00E-03 794.288
PM-2.5 0.0014 0.139 Benzene 4.20E-03 834.002
Sox 0.03 2.482 Benzo a rene 2.60E-06 0.516
Nox 0.22 21.843 Carbon 4.50E-05 8.936
tetrachloride
VOC 0.02 1.688 r Chlorine 7.90E-04 156.872
CO 0.19 19.063 e 9 Chlorobenzene 3.30E-05 6.553
Chloroform 2.80E-05 5.560
Ethyl benzene 3.10E-05 6.156
Green House Gas Pulutants Formaldehyde 4.40E-03 873.717
Emisson Factor E101
GHG Pollutant (Lb/MM BTU) tons/ r Napthalene 9.70E-05 19.261
CO2 195.000 19360.8 Phenol 5.10E-05 10.127
Methane 0.021 2.1 Propionaldehyde 6.10E-05 12.113
(CH4)
Nitrous Oxide 0.013 1.3 Styrene 1.90E-03 377.287
(N20)
Toluene 9.20E-04 182.686
X lene 2.50E-05 4.964
NO CNAN64 1N
Zo}(, 5 tl�rL,�rs
c� d,000v Ca 8 )V MM 8ttA
fJ o� Z,'1F -7 16/"o & ,�, 5 0.058 1b

WOODWASTE COMBUSTION EMISSIONS CALCULATOR REVISION L 09/03/2019-OUTPUT SCREEN
Instructions: Enter emission source/facility data on the"INPUT"tab/screen. The air emission results and summary of
input data are viewed I printed on the"OUTPUT"tabiscreen. The different tabs are on the bottom of this screen.
A67-
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the
NCDENR Information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware
of the most current information available. DENR is not responsible for errors or omissions that may be contained herein.
SOURCE FA USER SUMMARY MPUT
COMPANY: Facility Name, Inc. FACILITY ID NO.:
01/12100999
PERMIT NUMBER: 9MR02
EMISSION SOURCE DESCRIPTION: 48 MMBTU/HR WET WOOD >19%MOISTURE FIRED BOILER FACILITY CITY: ANYTOWN
EMISSION SOURCE ID NO.: ES-1 FACILITY COUNTY: ANYCOUNTY
PARTICULATE CONTROL DEVICE: MECHANICAL COLLECTOR NO REINJECTION POLLUTANT CONTROL EFF.
SPREADSHEET PREPARED BY: Your Name FUEL HEAT VALUE: 4000 BTU/LB NOX 0
ACTUAL FUEL THROUGHPUT: 24822 TON/YR HHV Used for GHGs HMBTUfrON: 15.38 PM CALC'D AS 31.7%
POTENTIAL FUEL THROUGHPUT: 52560 TON/YR IBOILER TYPE: STOKER PM10 CALC'D AS 29.3%
REQUESTED MAX.FUEL THRPT: 52560 TON/YR IND STACK TEST DATA USED PM2.5 CALC'D AS 48.7%
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS(AS A FRACTION): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
(KlER CntnROts ILY1S) IIiEFORE COMTROLSILrL[ral (AFrER c--Ms ILY ) Ib/mmBW
AIR POLLUTANT EMITTED Ihlhr ton Ib/hr ton Ib/hr tonslyr uncontrolled controlled
PICR'fl SE MK-P" /!/ // 11.38 16.66 72.95 11.38 49.83 0.347 0.237
le ?aJ� Ng P�Q o) 10.42 14.74 64.54 10.42 45.62 0.307 0.217
rJ
� Qr .lP�11Cs) 6.58 /Xebec 12.82 56.13 6.58 28.80 0,267 0.137
SULFUR DIOXIDE S02 1.20 2.48 1.20 5.26 1.20 5.26 0.025 0.025
NITROGEN OXIDES NOx 10.56 21.84 10.56 46.25 10.56 46.25 0.220 0.220
6' 28.80 28.80 126.14 28.80 126.14 0.600 0.600
VOLATILE ORGANIC COMPOUNDS OC 0.82 1.69 0.82 3.57 0.821 3.57 1 0.017 0.017
LEAD I 2.3E-03 4.8E-03 I 2.3E-03 1.0E-02 I 2.3E-03 I 1.0E-02 4.8E-05 4.8E-05
TOJOC/HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
CAS (BEFORE f.ONTROLs/ os) 1/r1ER CONTROLS I LMRS) Ib/mmBW
TOXIC I HAZARDOUS AR POLLUTANT NUMBER Iblhr INyT Ib/hr Ib/ Iblhr lbtyr uncontrolled/controlled
Acetaldehyde(TH) 75070 3.98E-02 164.815 3.98E-02 348.998 3.98E-02 348.998 8.30E-04 8.30E-04
Acetophenone(H) 98862 1.54E-07 6.35E-04 1.54E-07 1.35E-03 1.54E-07 1.35E-03 3.20E-09 320E-09 ,, �, L
Acrulen H 107028 1.92E-01 794.288 1.92E-01 1681.920 1.92E-01 1681.920 4.00E-03 4.00E-03 U/1(Gp/`f T a41�-9
Anbmory Unlisted Compounds(component of SBC)(H) Si 3.79E-04 1.569 3.79E-04 3.322 3.79E-04 3.322 7.90E-06 7.90E-06 (��-rh L >�()')I S$16I�5
Arsenic Unlisted Cm m nds co ntofASC ASC-other 1.06E-03 4.369 1.06E-03 9.251 1.06E-03 9.251 22 0E 0E-05 22 -05
Benzene(TH) 71432 2.02E-01 834.002 2.02E-01 1766.016 2.02E-01 1766.016 4.20E-03 420E-03 � 'hr�CD 7b A.PP(-'/
Beozo(a)pyrene IT) 50328 1.25E-04 0.516 1.25E-04 1.093 1.25E-04 1.093 2.60E-06 2.60E-06 1
Beryllium Metal(unreaded)(component of BEC)(T/H) 7440417 5.28E-05 0.218 5.28E-05 0.463 5.28E-05 0.463 1.10E-06 1.10E-06
Cadmium Metal(unreacted)(comporent or CDC)(TM) 7440439 1.97E-04 0.814 1.97E-04 1.724 1.97E-04 1.724 4.10E-06 4.10E-06 CO NT g4 L
Carbon tetrachloride H 56235 2.16E-03 8.936 2.16E-03 18.922 2.16E-03 18.922 4.50E-05 4.50E-05
Chlorine(TH) 1782505 3.79E-02 156.872 3.79E-02 332.179 3.79E-02 332.179 7.90E-04 7.90E-04 Cj(j l r4 A L
Chlwoberaene(TH) 108907 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 3.30E-05 3.30E-05 r
Chlorotonn(TH) 67663 1.34E-03 5.560 1.34E-03 11.773 1.34E-03 11.773 280E-0s 280E-05 C..Ml S 6 t 01�1
Chromium Unlisted Cmpds(HNadd%Wchrom add to get CRC) CRC-other 8.40E-04 3.475 8.40E-04 7.358 8.40E-04 7.358 1.75E-05 1.75E-05
Chromic acid(VI)(component of soICR6 and CRCXT/H) 7738945 1.68E-04 0.695 1.68E-04 1.472 1.68E-04 1.472 3.50E-06 3.50E-06
Cobalt Unlisted Compounds(component of COC)(H) COCother 3.12E-04 1 1.291 3.12E-04 2.733 3.12E-04 2.733 6.50E-06 6.50E-06
Dinibophenol,2,4-(H) 51285 8.64E-06 I 3.57E-02 8.64E-06 0.076 8.64E-06 0.076 1.80E-07 1.80E-07
Di(2-eth0he )pnerelate(DEHP)(TH) 117817 2.26E-06 I 9.33E-03 2.26E-06 1.98E-02 2.26E-06 1.98E-02 4.70E-08 4.70E-0e
Ethyl benzene(H) 100414 1.49E-03 6.156 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Ethylene dichloride(12-0ichloroetham)(TH) 107062 1.39E-03 5.759 1.39E-03 12.194 1.39E-03 12.194 290E-05 290E-05
Fom,aide 5000D 2.11E-01 873.717 2.11E-01 1850.112 2.11E-01 1850.112 4.40E-03 4.40E-03
Hemchloredeenzo-p-diom 12.3,6,7,8(TH) 57653857 1.53E-09 6.31 E-06 1.53E-09 1.34E-05 1.53E-09 1.34E-05 3.18E-11 3.18E-11
7647010 9.12E-01 3772.868 9.12E-01 7989.120 9.12E-01 7989.120 1.90E-02 1.90E-02
Lead Unlisted Compounds(component of PBC)(H) PBCother 2.30E-03 9.531 2.30E-03 20.183 2.30E-03 1 20.183 4.80E-05 4.80E-05
Manganese Unlisted Compounds(component of MNC)(TH) MNCother 7.68E-02 317.715 7.68E-02 672.768 7.68E-02 672.768 1.60E-03 1.60E-03
w 7439976 1.68E-04 1 0.695 1.68E-04 1.472 1.68E-04 1.472 3.50E-06 3.50E-06
Me bromide(H)(bromomethane) 74839 7.20E-04 1 2.979 7.20E-04 6.307 7.20E-04 6.307 1.50E-05 1.50E-05
Medryl cNonde(H)(chlorornethane) 74873 1.10E-03 4.567 1.10E-03 9.671 1.10E-03 9.671 2.30E-05 2.30E-05
chloroform(TH)(1,1,1 trichloroethane) 71556 1.49E-03 6.156 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Methyl ethyl ketone IT) 78933 2.59E-04 1.072 2.59E-04 2.271 2.59E-04 2.271 5.40E-06 5.40E-06
Methylene chloride(TH)(dichlororneeram) 75092 1.39E-02 57.586 1.39E-02 121.939 1.39E-02 121.939 290E-04 2.90E-04
Naphthalene(H) 912D3 4.66E-03 19.261 4.66E-03 40.787 4.66E-03 40.787 9.70E-05 9.70E-05
Nickel metal(Cornponenl of 373024/NIC)(TM) 744DO20 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 1 3.30E-05 3.30E-05
Ndrophenol,4-(H) 100027 5.28E-06 2.18E-02 5.28E-06 4.63E-02 5.28E-06 4.63E-02 1.10E-07 1.10E-07
Pentachlom H 87865 2.45E-06 1.01E-02 2.45E-06 2.14E-02 2.45E-06 2.14E-02 5.10E-08 5.10E-08
Perchlomethylene(tetrachtoroetlVene)(TH) 127194 1.82E-03 7.546 1.82E-03 15.978 1.82E-03 15.978 3.80E-05 3.80E-05
Phenol(TH) 1D8952 2.45E-03 10.127 2.45E-03 21.444 2.45E-03 21.444 5.10E-05 5.10E 0s
Phosphorus Metal,Yellow or White(H) 7723140 1.30E-03 1 5.361 1.30E-03 11.353 1.30E-03 11.353 2.7DE-05 2.70E-05
Polychktrnated bipheryls(TH) 1336363 3.91E-07 I 1.62E-03 3.91 E-07 3.43E-03 3.91 E-07 3.43E-03 8.15E-09 n.15E-09
Polycyclic Organic Matter(H) POMTV 6.00E-03 24.822 6.00E-03 52.560 6.00E-03 52.560 1.25E-04 1.25E-04
Propionaldehyde(H) 123386 2.93E-03 12.113 2.93E-03 25.649 2.93E-03 25.649 6.1DE-05 6.10E-05
Propylene dichloride(H)(1,2 dichtompmpane) 78875 1.58E-03 6.553 1.58E-03 13.876 1.58E-03 13.876 330E-05 3.30E-05
Selenium compounds(H) SEC 1.34E-04 0.556 1.34E-04 1.177 1.34E-04 1.177 280E-06 280E-06
Styrene(TH) 100425 9.12E-02 377.287 9.12E-02 798.912 9.12E-02 798.912 1.90E-03 1.90E-03
Tetrachlorodiibenzo-"iomr,2,3,7,8-(TH) 1746016 4.13E-10 1.71E-06 4.13E-10 3.62E-06 4.13E-10 3.62E-06 8.60E-12 8.6DE-12
Toluene(TH) 108883 4.42E-02 182.686 4.42E-02 386.842 4.42E-02 386.842 920E-o4 9.20E-04
Trichb ene(TH) 79016 1.44E-03 5.957 1.44E-03 12.614 1.44E-03 12.614 300E-05 3.00E05
Trichlorophenol,2,4,6-(H) 88o62 1.06E-06 4.37E-03 1.06E-06 9.25E-03 1.06E-06 9.25E-03 220E-08 220E-08
Vinyl chloride H 75014 8.64E-04 3.574 8.64E-04 7.569 8.64E-04 7.569 1.80E-05 1.80E-05
Xytene(TH) 1330207 1.20E-03 4.964 1.20E-03 10.512 1.20E-03 10.512 250E-05 2.50E-05
•Highest HAP(Hydrogenchloride(hydrochloric add)(TH)) 7647010 9.12E-01 3772.868 9.12E-01 7989.1 9.12E-01 7989.1 1.90E-02 1.90E-02
.Total HAPS NA 1.86E+00 7.71E+03 1.86E+00 1.63E+04 1.86E+00 1.63E+04 3.88E-02 3.88E-02

TOWC AJR POLLUTANT EMISSIONS INFORMATION(FOR PERMITTING PURPOSES)
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS I LWTATIONS(FOR PERMITTING PURPOSES) EMISSION FACTOR
IblmmBW
TOXIC AR POLLUTANT CAS Num. lb/Iv lb/day Iblyr uncontrolled lwnWied
Acetaldehyde(TH) 75070 3.98E-02 9.56E-01 348.998 8.30E-04 8.30E-04
Amolein(TH) 107028 1.92E-01 4.61E+00 1681.920 4.00E-03 4.00E-03
Arsenic Unlisted Compounds(component of ASC)(TH) ASC odw 1.06E-03 2.53E-02 9.251 2.20E-0.5 2.20E-05
Benzene(TH) 71432 2.02E-01 4.84E+00 1766.016 4.20E-03 420E-03
Benzo(a)pyreme IT) 50328 1.25E-04 3.00E-03 1.093 260E-06 2.60E-06
Beryllium Metal(unmacMd)(mmponent of BEC)(TM) 7440417 5.28E-05 1.27E-03 0.463 1.10E-06 1.10E-06
Cadmium Metal(unreacted)(component of CDC)(DH) 7440439 1.97E-04 4.72E-03 1.724 4.10E-06 4.10E-06
Carbon tetrachloride 56235 2.16E-03 5.18E-02 18.922 4.50E-05 4.50E-05
Chlorine(TH) 7782505 3.79E-02 9.10E-01 332.179 7.90E-04 7.90E-04
Chlorobenzene 108907 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E-05
Chloroform(TH) 67663 1.34E-03 3.23E-02 11.773 2.80E-05 2.80E-05
Di2-eth he alate DEHP H 117817 2.26E-06 5.41E-05 1.98E-02 4.70E-08 4.70E-08
Ethylene dichloride(1,2dichlometham)(TH) 107062 1.39E-03 3.34E-02 12.194 2.90E-05 2.9DE-05
Soluble Chromate Cmpds,as chrome(VQ(TH) SOLCR6 1.68E-04 4.03E-03 1.472 3.50E-06 3.50E-06
Formaldehyde(TH) 50000 2.11 E-01 5.07E+00 1850.112 4.40E-03 4.40E-03
Hemchlorodibenzo-pdiman 1,2,3,6,7.8(TH) 57653857 1.53E-09 3.66E-08 0.000 3.18E-11 3.18E-11
Hydrogen chloride(hydrochloric acid)(TH) 7647010 9.12E-01 2.19E+01 7989.120 1.90E-02 1.90E-02
Manganese Unlisted Compounds(component mr WC)(TH) MNC-other 7.68E-02 1.84E+00 672.768 1.60E-03 1.60E-03
Mercury,vapor(component of HGCXTIH) 7439976 1.68E-04 4.03E-03 1.472 3.50E-06 3.50E-06
Methyl chloroform(TH)1,1,1 bichloroethane) 71556 1.49E-03 3.57E-02 13.035 3.10E-05 3.10E-05
Methyl a ketone IT) 78933 2.59E-04 6.22E-03 2.271 5.40E-06 5.40E-06
Methylene chloride H dichlorome8mne 75092 1.39E-02 3.34E-01 121.939 2.90E-04 290E-04
Nickel metal(Component of 373024/1,1IC)(TM) 744OD20 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E-05
Pentechl henol H 87865 2.45E-06 5.88E-05 0.021 5.10E-08 5.10E-08
Perchlmoethylem(tetrachloroethylene)(TH) 127184 1.82E-03 4.38E-02 15.978 3.80E-05 3.80E-05
Phenol(TH) 108952 2.45E-03 5.88E-02 21.444 5.10E-05 5.10E-05
Polychlorinated biphenyls(TH) 1336363 3.91 E-07 9.39E-06 3.43E-03 8.15E-09 8.15E-09
Styre-(TH) 1DD425 9.12E-02 2.19E+00 798.912 1.90E-03 1.90E-03
Tebachlorodibenzo-pAiwdn,2,3,7,8-(TH) 1746016 4.13E-10 9.91E-09 3.62E-06 8.60E-12 8.60E-12
Toluene(TH) 108883 4.42E-02 1.06E+00 386.8429.20E-04 9.20E-04
Trichlome"me(TH) 79016 1.44E-03 3.46E-02 12.6143.00E-05 3.00E-05
Vinyl chloride(TH) 75014 8.64E-04 2.07E-02 7.5691.80E-05 1.80E-os
Xylene(TH) 1330207 1.20E-03 2.88E-02 10.5121250E-05 2.50E-05
GREENHOUSE GAS EMISSIONS INFORMATION(FOR EMISSIONS INVENTORY GREENHOUSE GAS EMISSIONS-POTENTIAL TO EMIT
PURPOSES) -CONSISTENT WITH EPA MANDATORY REPORTING RULE(MRR)METHOD NOT BASED ON EPA MRR METHOD
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit and EPA
MRR Emission Factors
EPA MRR CALCULATION METHOD:TIER 1
GREENHOUSE GAS metric tons/yr, short tons/yr,
metric tons/yr CO2e short tons/yr short tons/yr short tons/yr,CO2e short tons/yr CO2e
CARBON DIOXIDE(CO2)
BIOGENIC EMISSIONS' 35,808.59 zero 39,472.16 43,476.24 zero` 43,476.24 zero'
METHANE CH4 2.75E+00 6.87E+01 3.03E+00 3.34E+00 8.34E+01 3.34E+00 8.34E+01
NITROUS OXIDE 1,120 1.37E+00 4.10E+02 1.51E+00 1.67E+00 4.97E+02 1.67E+00 4.97E+02
TOTAL
478.26 TOTAL 580.67 TOTAL 580.67
' BIOGENIC CO2 has 0 CO2e NOTE:The DAQ Air Emissions Reporting Online(AERO)system requires short tons
NOTE: CO2e means CO2 equivalent The EPA MRR requires metric tons
Note:Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Annual Air Emissions Inventory
Facility ID#: 0800044
Pentanone (Methyl Propyl Ketone): Us-7 0§4 0
Year: 2019 0550
Info: Lbs/Gal= 6.01 !"N
Monthly Inventory of Pentanone(gallons):
Month Beginning Received Max Used Recovered
Inventory (Lbs) New Used Recovered Used
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
July: 0 0
August: 0 0
September: 0 0
October: 0 0
November: 0 0
December: 0 6144 36922 6119 6095
Gallons of Pentanone used during the year @ PNE(OS-7): 6119
Lbs.Of Pentanone used during the year @ PNE(OS-7): 36776
Gallons of Pentanone used during the year @(OS-10):
Lbs.Of Pentanone used during the year @(OS-10): 0 n
Lbs.of Pentanone used by Misc., QA,and R&D: rcJ� T n �
Lbs.of Pentanone sent to hazardous waste: f `Lbs.of Pentanone sent to wwt: SP-0 1 "'
Lbs.of Pentanone emitted during year: 36776 � 1!!!�L0
► Ll1

Disposed Monthly Used Ending
LBS Inventory
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0
0
6095 145 24
em1

Annual Air Emissions Inventory
Facility ID#:0800044
Chloroform : 010 8S 53 V6
Year: 2019
Info: Lbs/Gal= 12.35
Monthly Inventory of Chloroform(pounds):
Lbs.
Beginning Recovered Chloroform Ending Infeed Product
Month InventoryReceived Max New Used Used Recovered Sent as Haz Total Used Inventory
ry (Lbs.) (Lbs.)
Waste
January: 9181 6634.8 15816 3696.0 11715.0 21104.0 -5693.0 21509 2438 1276
February: 21509 13500.0 35009 1181.0 9637.0 10818.0 24191 4445 2310
March: 24191 716.5 24907 6846.0 7773.0 4200.0 10419.0 14488 2788 1430
April: 14488 4455.0 18943 2751.0 3401.0 22536.0 -16384.0 35327 1756 792
May: 35327 861.4 36189 786.0 770.0 1556.0 34633 4548 2662
June: 34633 34633 1905.0 4259.0 6164.0 28469 4181 2530
July: 28469 13471.7 41940 8486.0 1350.0 7136.0 32104 4945 2728
August: 32104 32104 6154.0 6154.0 25950 4556 2332
rNe
mber: 25950 673.6 26624 3148.0 3004.0 6152.0 20472 2763 1540
ber: 20472 20472 2751.0 2638.0 25781.0 -20392.0 40864 4268 2222
mber: 40864 40864 5824.0 7278.0 13102.0 27762 1848 902
mber: 27762 27762 0.0 27762
Lbs.of chloroform used during the year: 19032
Lbs.of chloro.used by Misc.,QA,and R&D: " ►
Lbs.of chloro.used b EVG: 19032 Cy ZO l 7000 �bS e �>�e
Lbs.of EVG Infeed 29840 �k .t
Lbs.EVG Produced: 15532 rwt��,w' t
Lbs.of chloroform sent to hazardous waste: 1350
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted duringyear.OS-9 17682
Mom LA"", � ,� ',�j
T:\EH&S\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2019 Report\2019 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Diethvlamine : O� OS yp
Year: 2019 l
Info: Lbs/Gal= 5.90 Used for Nicotine Extraction in Botanical Extraction Process
Monthly Inventory of Diethylamine(gallons):
Beginning Received Max Used Used Gal.to Lbs.to Lbs.EDA Ending
Month InventoryEmitted as
(Gals.) (Lbs) (Gals.) (Lbs.) WWTP DTP VOC Inventory
January: 0 0 0 0 0 0 0
February: 0 0 0 0 0 0 0
March: 0 0 0 0 0 0 0
April: 1 0 0 0 0 1 0 0 0
May: 0 0 0 0 0 0 0
June: 0 0 0 0 0 0 0
July: 0 0 0 0 0 0 0
August: 0 0 0 0 0 0 0
—September: 0 0 0 0 0 0 0
October: 0 6481 38238 2752 16238 275 1624 14614 3729
November: 3729 184 23083 0 0 0 0 3912
December: 1 3912 1 23083 0 0 1 0 0 1 3912
Total Gallons of Diethylamine Used: 2752
m i G
Total Lbs.Diethylamine Used: 16238.157 ✓O
Gallons sent to Hazardous Waste:
Lbs.Diethylamine sent to Hazardous Waste:
Total Gallons sent to WWT: 275
Total Lbs.sent to WWT: 1623.8 E)uj V6L
Total Lbs.Diethylamine Emitted:OS-10 14614.3

Annual Air Emissions Inventory
Facility ID#:0800044
Toluene
Year: 2019
Info: Lbs/Gal= 7.23
Monthly Inventory of Toluene(gallons):
Month Beginning Received Max Used In Recovered In Product Disposed Total Emitted Ending
Inventory Lbs Process Inventory
January: 1531 11069 0 1531
February: 1531 11069 0 1531
March: 1531 11069 0 1531
April: 1531 654 15799 0 2185
May: 2185 15799 572 548 548 24 1613
June: 1613 11663 1 0 1613
Jul : 1613 11663 249 0 1364
August: 1364 1745 22476 647 0 2461
September: 2461 17796 1550 1095 455 2007
October: 2007 14509 199 0 1808
November: 1808 13069 0 1808
December: 1808 13069 1 1 0 1808
November: 1808 13069 0 1808
December: 1808 13069 0 1808
Total 2399 2122 1 1643 0 1643 479
Botanical Extraction Operation:OS-10
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Emitted as Toluene Toluene
Operated Product Toluene Used Used Recovered in Product VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/0! #DIV/0!
February: 0.00 0.00 0.00 #DIV/0! #DIV/0!
March: 0.00 0.00 0.00 #DIV/0! #DIV/0!
April: 0.00 0.00 0.00 #DIV/0! #DIV/0!
May: 0.00 0.00 0.00 #DIV/0! #DIV/0!
June: 0.00 0.00 0.00 #DIV/0! #DIV/0i
July: 0.00 0.00 0.00 #DIV/0! #DIV/01
August: 0.00 0.00 0.00 #DIV/0! #DIV/01
September: 0.00 0.00 0.00 #DIV/0! #DIV/0!
October: 0.00 0.00 0.00 #DIV/0! #DIV/0!
November: 0.00 1 0.00 0.00 #DIV/0! #DIV/0!
December: 0.00 0.00 0.00 #DIV/0! #DIV/0!
Average #DIV101 #DIV/01 #DIV/01 1 0.00 1 #DIV/0I 0.00 0.00 #DIV/01 #DIV/01
Total 0 0.00 0.0 0.00 1. 0.00 0.00 0.00 #DIV101 #DIV/01
PNE Operation: 8Q�'7 0s SL
#Days Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Lbs. Product Recovered/ Emitted as Toluene Toluene
Operated Toluene Used Used Disposed in Product VOC Emitted Emitted
January: 0.00 0.00 #DIV/0! #DIV/0!
February: 0.00 0.00 #DIV/0! #DIV/0!
March: 0.00 0.00 #DIV/0! #DIV/0!
April: 0.00 0.00 #DIV/0! #DIV/0!
May: 15 53.90 572.0 4135.56 3962.04 173.52 11.57 0.48
June: 0.00 0.00 #DIV/01 #DIV/0!
July: 0.00 1800.27 -1800.27 #DIV/0! #DIV/0!
August: 0.00 4677.81 -4677.81 #DIV/0! #DIV/01
September: 9 1549.7 11204.46 11204.46 1244.94 51.87
October: 0.00 1438.77 -1438.77 #DIV/0! #DIV/0!
November: 0.00 0.00 #DIV/0! #DIV/0!
December: 0.00 0.00 #DIV/0! #DIV/0!
Average 12 63.90 1060.9 1278.34 2969.72 #DIV/01 #DIV/0! #DIV10!
Total 24 53.90 2121.7 15340.02 11878.89 0.00 3461.13 #DIV101
Gallons of Toluene used during the year: 2122.09
Lbs.of Toluene used during the year: 15342.71
Lbs.Botanical Extraction Toluene Emitted:OS-10 0.00
Lbs.PNE Toluene Emitted:OS-7 3461.13
Lbs.of Toluene sent to hazardous waste:
Total Fugitive Lbs.Toluene Emitted: 3461.13

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: QSI, 0 10
Year: 201 F7 0 550
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Used Gallons IBAC
Month Beginning Received Max Recovered Sent as
Inventory (Lbs) New Used Recovered Hazardous
Used Waste
January: 148 1067
February: 148 972 8087
March: 1120 8087
April: 1120 8087 1101 163
May: 183 1318 163
June: 20 143
July: 20 324 2482 216
August: 128 922 20
September: 107 776
October: 107 776
November: 107 776
December: 107 2269 17156 2220 217
Gallons of IBAC used during the year @ PNE (OS-7): 3537
Lbs. Of IBAC used during the year @ PNE (OS-7): 25534
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 25534

Ending
Inventory
148
1120
1120
183
20
20
128
107
107
107
107
-61

vs sG t3�6m�ss
Annual Air Emissions Inventory OS Yv
Facility ID#:0800044 OS L f^7 Sr-(, F `A1�v -
Ethyl acetate : OS-6, OS-7, OS-10,OS-28 � 7 / C "'7V1 1.
Year: 2019 v,� I J V6 1041 n C
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate(pounds):
7 Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA-35A
Alcohol
Total Beginning Beginning New Recovered Recovered Max Mo hly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Disposed Month
Inventory Inventory Inventory P (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
January: 6210 6210 0 9960.0 4824.00 16170 '4824.0 11346 January: 0.00
February: 11346 11346 0 1540.96 11346 .1541.0 9805 February: 0.00
March: 9805 9805 0 3354.97 9805 .3355.0 6450 March: 0.00
April: 6450 6450 0 8300.0 3045.00 14750 3045.0 11705 Aril: 7.51
May: 11705 11705 0 2015.00 1 11705 2015.0 9690 May: -1.32
June: 9690 9690 0 3290.30 9690 3290.3 6400 June: 0.00
July: 6400 6400 0 3213.51 6400 3213.5 3186 July: -0.38
-August: 3186 3186 0 8300.0 2803.26 11486 2803.3 8683 Au ust: 54.96
September: 8683 8683 0 1342.00 8683 1342.0 7341 September: 54.96
October: 7341 7341 0 8300.0 4425.00 15641 4425.0 11216 October: 48.78
November: 11216 11216 0 3074.40 11216 .3074.4 8142 November: 0.00
December: 8142 8142 0 24900.0 22181.60 1183C60.00 33042 -7500 2 December: -1.54
Ethyl acetate Emissions by Source` 1 4
Ethyl acetate Emitted from Ethyl acetate to Total Ethyl acetate
SDA in Botanical Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted Emitted from
Month Biomass Extraction:OS-28 SDA in PNE:OS-7 PNE:OS-7 from SFG:OS-6 Botanical Extraction
Extraction:OS-10 Botanical
(Lbs.) (Lbs.) (Lbs.) (Lbs.) (Lbs.) OS-10 Extraction:OS-10
(Lbs.) (Lbs.)
January: 0.00 0.00 0.00 4824.00 0.00
February: 0.00 0.00 0.00 1540.96 0.00
March: 0.00 0.00 0.00 3354.97 0.00
April: 0.00 7.51 0.00 3045.00 0.00
May: 0.00 7.51 0.00 2015.00 0.00
June: 0.00 0.00 0.00 3290.30 0.00
July: 0.00 0.00 0.00 3213.51 0.00
August: 0.00 54.96 0.00 2803.26 0.00
-September: 0.00 54.96 0.00 1342.00 0.00
October: 0.00 48.78 0.00 4425.00 0.00
November: 0.00 0.00 0.00 3074.40 0.00
December: 0.00 -1.54 0.00 3033.60 788.00 788.00
Averse 0.00 5 0.00 #DIV101 2 788.00 65.67
Total 0.00 172L 0.00 0.00 35962.00 88.0 788.00
Sim p-� P/lYllSSt

Annual Air Emissions Inventory
Facility IDS:0800044
Ethanol-SDA-35A:OS-7&OS-10
OS-18.OS-19.OS-27,OS-32 INCLUDED WITH OS-10
Year. 1 2019
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4
Monthly Inventory of Ethanol(gallons):
Monthly Beainnina Inventory Bulk Drums
Too Total SDAl SDA Bulk SDA in Drums SDA Max SDA on SDA to Ethyl
SDA SDA SDA in Drums SDA Ending SDA Used SDA Us ad SDA VOC
Month Beginning Inventing Beginning SDA Used Recovered In SDA Disposed Hand WW7 Acetate VOC
InventoryInventory Inventory Received Recovered Received Drums Used Recovered Lba Inventory (gallons) (Lbs.) (Lbs.)
ry ry ( ) (Lbs.) (Lbs.)
Gals.
January: 14469.8 11287.7 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
February: 14469.8 1128707 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
March: 14469.8 11287.7 3182.1 99408 14470 0 0.0 0.0 0.0 0.0
April: 14469.8 11287.7 3182.1 6075.0 4708.5 9940B 13103 1366 9387.6 9199.9 180.2 7.5
May: 13103.3 9921.2 3182.1 5826.3 6075.0 4708.5 1607.0 130040 15955 -240 -1652.0 -1619.0 -31.7 -1.3
June: 15955.1 14380.0 1575.1 109612 15955 0 0.0 0.0 0.0 0.0
July: 15955.1 14380.0 1575.1 69.9 109612 15885 -70 -480.2 -470.6 -9.2 -0.4
Au ust: 15885.2 14380.0 1505.2 24445.0 10000.0 277068 30330 10000 68700.0 67326.0 1319.0 55.0
September: 30330.2 28825.0 1505.2 18708.0 10000.0 336892 39038 10000 68700.0 67326.0 1319.0 55.0
October: 39038.2 37533.0 1505.2 5784.6 11460.0 2585.2 307933 30778 8875 60969.9 5975045 1170.6 48.8
November: 30777.6 31857.6 -1080.0 6235.8 254282 37013 0 0.0 0.0 0.0 0.0
December: 37013.4 38093.4 -1080.0 42840.0 279.5 548693 79574 -280 -1920.2 -1881.8 -36.9 -1.5
Total 103833.7 43610.0 9417.0 0.0 0.0 0.0 4541.6 2471661.3 321041.4 29651.4 203705.1 199631.0 3911.1 163.0
Botanical Extraction Operation:OS-10 63140
D
S Days Lbs.Botanical Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs,EtOH- EtOH-SDA Ethyl Acetate
Month Operated Product SDA Used SDA Used SDA SA to VOC(Lbs.) VOC(Lbs.) Product
Recovered WWTP
January: 0.00 0.00 0.0 0.0
-February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0 Total SDA Ethanol Data
August: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 9417.0
September: 0.00 0.00 0.0 0.0 Total Lbs.SDA Used: 64694.8
0.00 0.00 0.0 0.0 Total Gallons sent to WWT: 30701.76
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0 Total Lbs.sent to WWT: 210921.1
December: 0.00 0.00 0.0 0.0 Total Lbs.SDA Ethanol Emitted as VOC's: 4304.5
Lbs.Botanical Extraction Ethanol Emitted as VOC:OS-10 0.00
Averse SDIV/01 SDI V/01 SDIV101 0 SDIVI01 0 0 0 Lbs.PNE Ethanol Emitted as VOC:OS-7 0.00 r
Total 0 0 0 0 0 0 0 0 Lbs.Biomass Extraction Ethanol Emitted as VOC:OS-28 4304.51 WC, I crrA]i
PNE Operation:OS4 067q
S Days Lbs.PNE Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs.EtOH- EtOH-SDA Ethyl Acetate
Month Operated Product SDA Used SDA Used SDA SDA to VOC(Lbs.) VOC(Lbs.) Product
Recovered WWTP
January: 0.00 0.00 0.0 0.0
-February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0
Au oust: 0.00 0.00 0.0 0.0
September: 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Averse SDIVI01 SDIVI01 SDIV101 0.00 SDIV/01 0.00 0.00 0.00

Total 1 O 0.00 1 0.0 0.00 1 0.00 1 0.00 0.00 1 0.00

Annual Air Emissions Inventory
Facility ID#:0800044
Heptane : 0S-6. OS-7 OS-10
Year: 2019
Info: Lbs/Gal= 5.70
Monthly Inventory of He tane allons:
Beginning Max Recovered Disposed I Ending
Month InventoryReceived Lbs New Used Used Recovered Sent off-Site Haz Waste Inventory
January: 59925 341573 7764.0 0.0 52161
-February: 52161 297318 3373.0 0.0 48788
March: 48788 6600 315712 4256.0 0.0 716 50416
April: 50416 287372 4849.0 0.0 45567
May: 45567 259733 1 22835.0 0.0 2505 20227
June: 20227 6468 152161 1 4253.0 0.0 22442
July: 22442 6186 163179 3961.0 0.0 24667
August: 24667 18006 243236 3437.0 0.0 4175 35061
September: 35061 18241 303818 10488.8 1287.9 44100
October: 44100 6095 286114 15934.7 1535.1 35796
November: 35796 6401 240522 9213.7 247.6 33231
December: 33231 189415 3304.0 0.0 3519 26407
SFG(M-13)Operation:OS-7
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Gallons Heptane Heptane
Month Heptane Used Heptane Sent Heptane Sent as Emitted as
Operated Infeed Product Used to WWTP Recovered Hazardous VOC
Waste (Lbs.)
January: 0.0 0.00
February: 0.0 0.00
March: 0.0 0.00
April: 0.0 0.00
May: 0.0 0.00
June: 0.0 0.00
July: 0.0 0.00
August: 0.0 0.00
September: 1 0.0 0.00
October: 0.0 0.00
November: 0.0 0.00
December: 0.0 0.00
Average #DIV/01 #DIV/0! #DIVI01 #DIV/01 0.0 #DIV/0! #DIV/01 #DN/01 0.00
Total 0 0 0.0 0.0 0.0 0.0 0.0 0.00
Botanical Extraction Operation:OS-10
Gallons Monthly
#Days Lbs. Gallons Lbs.Heptane Gallons Gallons Heptane Sent Heptane
Month Botanical Heptane Used as Hazardous Heptane Sent HeptaneW Emitted as Product
Operated Product Used to WTP Recovered VOC
Waste
Lbs.
-January: 0.0 0
February: 0.0 0
March: 0.0 0
April: 0.0 0
May: 0.0 0
June: 0.0 0
July: 0.0 0
August: 0.0 0
September: 26 25968.80 10488.77 59786.0 2600 1287.9 37624.959 Nicotine
October: 31 39369.42 14307.74 81554.1 4500 1535.1 47153.934 Nicotine
November: 5 6995.58 2307.70 1 13153.9 1200 247.6 4902.57 Nicotine
December: 0.0 0
Average 21 24111.27 9034.74 12874.5 2766.67 1023.5 #DIV/01 7473.46
Total 62 72333.80 27104.21 15"94.0 3070.6 0.0 89681.46
r " .
A99E0 Tot Dv
J�

SFG Operation:OS-6
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Gallons Heptane Heptane
Month Operated Infeed Product Heptane Used Heptane Sent Heptane Sent as Emitted as
Used to WWTP Recovered Hazardous VOC
Waste Lbs.
January: 31 107533 91294.0 7764.0 44254.8 44254.80
-February: 28 173106 146967.0 3373.0 19226.1 19226.10
March: 27 143132 132942.0 4256.0 24259.2 715.8 20179.14
April: 28 131543 117749.0 4849.0 27639.3 27639.30
May: 31 207508 184791.0 22835.0 130159.5 2505.3 115879.29
June: 23 120440 110834.0 4253.0 24242.1 24242.10
July: 25 107174 97367.0 3961.0 22577.7 22577.70
August: 25 114579 96848.0 3437.0 19590.9 4175.4 -4208.88
September: 0 0.00
October: 22 114993 90411.0 1627.0 9273.9 9273.90 Pa)
November: 19 123359 114372.0 6906.0 39364.2 39364.20
December: 20 111070 92105.0 3304.0 18832.8 3519 -1225.50 1t�Qi
Average 25 115971 6051.4 31618.38 #DIV/01 #DIV/Ol 2728.875
Total 279 1454437 1275680 6659-90 379420.50 0.0 10916.500 317202.16 r
� v �
PNE(M-131 Ooeration:OS-7
Gallons Monthly
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Gallons Heptane Sent Heptane
Used as Hazardous
Month Heptane Heptane Sent Heptane Emitted as Process
Operated Product Used to WWTP Recovered VOC
Waste
Lbs.
January: 0.0 0.0
-February: 0.0 0.0
March: 0.0 0.0
April: 0.0 0.0
May: 0.0 0.0
June: 0.0 0.0
July: 0.0 0.0
August: 0.0 0.0
September: 0.0 0.0
October: 0.0 0.0
November: 0.0 0.0
December: 0.0 0.0
Average #DIV/01 #DIV/01 #DIVI01 0.0 #DIVI01 #DIV/O! #DIV/01 0.0
Total 0 0 0.0 0.0 0.0 0.0 0.0

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Methanol:OS-4,OS-7,OS-9
OS-.13,OS-14,OS-15.OS-16,OS-17 OS-27 OS-32 INCLUDED WITH OS-4
Year: 19
Info: Lbs/Gal= 6.62 Specks Gravity=0.793
Monthly Inventory of Methanol faallonsl7 Methanol Used in SDA-3A
Alcohol
Month Beginning Received Max Used Recovered Ending Month Methanol
Invento Lbs Invento Emitted Lbs.
January: 26614.0 15910.0 281509 17399.0 25125 January: 0.00
February: 25125.0 15771.0 270732 15475.0 24421 February: 0.00
March: 24421.0 13371.0 250183 18412.0 19380 March: 0.00
April: 19380.0 13618.0 218447 7776.0 25222April: 0.00
May 25222.0 22477.0 315767 15786.0 31913 May: 0.00
June: 31913.0 7656.0 261947 11747.0 27822 June: 0.00
July: 27822.0 15333.0 28568E 16452.0 26703 July: 0.00
August: 28703.0 7680.0 227615 14540.0 19843 August: 0.D0
September. 19843.0 11857.0 209854 06 126 .0 19094 September 0.00
October. 19094.0 7656.0 177085 13142.0 1360E October: 0.00
November. 13608.0 16413.0 192119 16205.0 12816 November: 0.00
December: 128 66.0 7626.0 13532E 1 8173.0 1 December: 0.00
Maximum Gallons On-Hand: 47699
Maximum Lbs.On-Hand: 315767.3E
Gallons Used per Year: 168713
Lbs.Used per Year: 1116880.0E
Selareol Recovery Operation:0OOP4 i1
FAJ Accountable
l Lb t f T i i E A Month
ly
% Total Gal. o y Avg. Emissions o Total s.
Month #Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg. Total Lbs.
Operated Used Used to WWTP WWTP Methanol in Water to Removal McOH from Fugitive
W WWTP Efficiency WWTP Emissions Emissions
(OS-17)
January 31 11833 78334.4E 1.31 30306.8 7.85 319499 98.9 333.3748 48027.66 48361.035
February 28 12053 79790.88 1.30 31446.9 9.05 307828 98.7 408.8097 48343.96 48752.77
March 31 12779 84596.98 1.29 36050.1 9.49 325852 98.7 468.6513 48546.88 49015.531
April 18 568E 37641.32 1.27 21417.4 10.17 197642 98.8 299.8436 16223.92 16523.764
May 31 15278 101140.36 1.39 41441.2 10.07 350324 98.5 621.618 59699.16 60320.778
June 26 9633 63770.46 1.54 27294.5 7.24 235369 98.8 327.534 36475.96 36803.494
Jul 31 13694 90854.2E 1.42 36001.E 8.59 335454 98.7 468.0234 54852.4E 55120.503
Au ust 31 12552 83094.24 1.54 38310.2 8.47 385341 98.5 574.653 44784.04 45358.693
September 26 9673 64035.26 1.57 29303.5 7.72 198658 98.8 410.249 34731.76 35142.009
October 28 11348 75123.76 1.45 31357 8.11 193710 98.7 407.641 43766.76 44174.401
November 30 11502 78143.24 1.86 30081.7 8.4E 325281 98.7 391.0621 46061.54 46452.602
December 20 8173 54105.26 1.1E 20746.2 9.27 196408 98.7 269.7006 33359.06 33628.761
Averse 27.5E 11183.67 '14035.87 1.41 31146.44 8.54 279280.50 98.6E 43 43304.53
Total 331 134204 888430.4E 373757.3 3341396 4981.160 14673.1E 519654.34
Concrete Operation:OS-4 tiTE R` LOSS
Accountable
Emissions of Total Lbs Avg Monthly
% Total Gal. y . .
#Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg. Total Lbs.
Month Methanol in Water to Removal McOH from Fugitive
Operated Used Used to WW7P WWTP WW WWTP Efficiency WWTP Emissions Emissions
(OS-17)
January 0 0.00 0 0
February 0 0.00 0 0
March 0 0.00 0 0
April 0 0.00 0 0
May 0 0.00 0 0
June 0 0.00 0 0
July 0 0.00 0 0
August 0 0.00 0 0
September 0 0.00 0 0
October 0 0.00 0 0
November 0 0.00 0 1 0
December 0 0.0 0 0
0 0 0
Averse #DIV101 #DIV101 0.00 #DIV101 #DIW #DIV/0101 #DIVI01 #DIVI01 0.00 g.0 .00
Total 0 0 0 0 0 1 0 1 0 1 0 0

Page 2 of 2
EVG Operation:OS-9 D S 5 3
Accountable
Month #Days Gallons MaOH Lbs.McOH Gallons McOH Lbs.McOH to Emissions of Total Lbs. Total Lbs.
Operated Used Used to WWTP WWTp MaOHirom Fugitive Emissions
WWTP Emissions
(OS-17)
January 31 5566.0 38846.92 5454.68 36109.98 722.20 736.94 1459.14
February 21 4422.0 29273.64 4333.58 28688.17 573.76 585.47 1159.24
March 31 5633.0 37290.48 5520.34 36544.65 730.89 745.81 1476.70
April 12 2090.0 13835.8 2048.2 13559.08 271.18 278.72 547.90
May 2 508.0 3362.96 497.84 3295.70 65.91 87.26 133.17
June 20 2114.0 13994.68 2071.72 13714.79 274.30 279.89 554.19
July 19 2758.0 18257.96 2702.84 17892.80 357.86 365.16 723.02
August 12 1986.0 13160.56 1948.24 12897.35 257.95 263.21 521.18
September 14 2933.0 19416.46 2874.34 19028.13 380.50 388.33 768.89
October 10 1794.0 11876.28 1758.12 11638.75 232.78 237.53 470.30
November 17 4703.0 31133.86 4608.94 30511.18 610.22 622.68 1 1232.90
December 0 0 0.00 0.00 0.00 0.00
Avers 17.18 3137.2 19037.47 2818.24 18656.72 753.88
Total 1 189 1 34509.0 1 228449.58 223880.59 4477.61 4568.99 1 9046.60
Botanical Extraction Operation:OS-10 v 'S eI'll ` Gv
Accountable
#Days Gallons McOH Lbs.McOH Gallons MaOH Lbs.McOH to Emissions of Total Lbs.
Total Lbs.
Month Operated Used Used to WWTP VVWTP McOH from Fugitive Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.00 0.00 0.00 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 0.00
July 0 0 0.00 0.00 0.00 0.00
August 0 0 0.DO 0.00 0.00 0.00
September 0 0 0.00 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00 0.00
November 0 0 0.00 0.00 0.00 0.00
December 0 0 0.00 0.00 0.00 0.00
Avers #DIV/01 #DIV/01 0.00 0.00 0.00 0.00 0.00 0.00
rota) o 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol Operations
Total Lbs.McOH Thru System: 3646296.00 Lbs.Fugivtive Emissions from EVG: 4568.99
Total Lbs.McOH Treated at
WWTP: 597637.89 Lbs.Fugivtive Emissions from Recovery: 514673.18
Calculated Removal Efficiency
of WWTP: 98.68 Lbs.Fugitive Emissions from Concrete: 0.00
Lbs.Accountable Emissions from WWTP OS-17 9458.77 Total Lbs.Fugitive Emissions: 524223.33
Lbs.of Emissions from WWTP
During Recovery: 4981.16 Total Lbs.McOH Released: 533682.10
Lbs.of Emissions from W W7P 0 Total Lbs.McOH Recycled On-Site: 3048658.11
During Concrete Recovery:
Lbs.of Emissions from WWTP
1st Aeration Chamber 0117: 4477.61
Lbs.of Emissions from Misc.,
Lab:

Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OSA,OS-6, 0S-6, OS-10, OS-28 OS-29
OS-13,OS-14,OS-15 OS-16 OS-20 OS-21 OS-22 OS-23 O 32 ALL INCLUDED WITH OS-4
OS-18,OS-19INCLUDED WITH OS-10•OS-30INCLUDED WITH OS 28
Year: 2019
Isohexane SIDE Hexane
Info: Lbs/Gal= 5.59 5.785
Monthly Inventory of SIDE-1 LP Hexane-</=40%n-Hexane Igallonsl•
Beginning Max Used Ending Inventory
Month Invento Received Lbs
January: 15654 90558 15654
February: 15654 90558 15654
March: 15654 90558 15654
April: 15654 90558 15654
May: 15654 90558 15654
June: 15654 90558 15654
July: 15654 90558 15654
August: 15654 90558 15654
September: 15654 90558 15654
October: 15654 90558 15654
November: 15654 90558 15654
December: 15654 90558 15654
Monthiv,Inventory of SIDE-2 LP Hexane-</=40%n-Hexane Wallons "Also used in PNE-gDE
Month Beginning Received Max Used Ending Inventory
January: 19370 7833 157368 1530 25673
February: 25673 148517 -2243 27916
March: 27916 161492 897 27019
April: 27019 4829 184239 1670 30178
May: 30178 174578 1334 28844
June: 28844 166861 1395 27449
July: 27449 7113 199939 1228 33334
August: 33334 192835 1551 31783
September: 31783 3315 203043 1039 34059
October: 34059 197032 1004 33055
November: 33055 191224 791 32264
December: 32264 186648 735.7 31528
Monthly Inventory of HP Hexane-</=95%n-Hexane(gallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 5866 32791 5866
February: 5866 32791 5866
March: 5866 32791 5866
April: 5866 32791 5866
May: 5866 32791 5866
June: 5866 32791 5866
July: 5866 32791 5866
August: 5866 32791 5866
September: 5866 32791 5866
October: 5866 32791 5866
November: 5866 32791 5866
December: 5866 32791 5866
Monthly Inventory of IsoHexane-</=5%n-Hexane(gallons)
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 63931 24796 495984 19758 68969
—February: 68969 20600 500691 22916 66653
March: 66653 26883 522866 26595 66941
April: 66941 20520 488907 22503 64958
May: 64958 33068 547965 27060 70966
June: 70966 20019 508606 25768 65217
July: 65217 26415 512223 31071 60561
August: 60561 32443 519892 30261 62743
Se tem be.. 62743 25725 494536 32074 56394
October: 56394 33103 500288 28847 60650
November: 60650 13439 414158 21733 52356
December: 52356 14982 376419 15318 52020

Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers(Lbs 1-
Percentn-Hexane: 1.683
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
July: 0.00 0.00
August: 0.00 0.00
-September: 0.00 0.00
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Averse #DIV/0! #DIV/0! 0.00 0.00
Total 0 0.00 0.00 O.DO
Total Hexane Values
Gallons of LP Hexane Used: 10931.70 Gallons of N-Hexane Used: 5413.58
Gallons of HP Hexane Used: 0.00 Lbs.of N-Hexane Used: 29774.66
Gallons of IsoHexane Used: 303904.00 Gallons of Hexane Isomers Used: 304091.50
Total Gallons of Hexanes Used: 314835.70 Lbs.of Hexane Isomers Used: 1672503.28
Total Lbs.of Hexanes Used: 1762063.245
Sclareolide(SDE-11 Operation:OS-5 Y
Gallons Monthly Monthly Monthly
y
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Month Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0 0.0 0.0 0.00 0.0
February: 0 0.0 0.0 0.00 0.0
March: 0 1 0.0 0.0 0.00 0.0
April: 0 0.0 0.0 0.00 0.0
May: 0 0.0 0.0 0.00 0.0
June: 0 0.0 0.0 0.00 0.0
July: 0 0.0 0.0 0.00 0.0
August: 0 0.0 0.0 0.00 0.0
September: 0 0.0 0.0 0.00 0.0
October: 0 0.0 0.0 0.00 0.0
November: 0 0.0 0.0 0.00 0.0
December: 0 0.0 0.0 0.00 0.0
Average #DIV/01 #DIV/01 #DIV/01 0.0 0.0 #DIV/01 1 #DIV/01 0.000 0.000 0.00
Total 0 0.0 0.0--0 0.0 0.000 1 0.000 _,0..000 0.00
Sclareolide SDE-2 eration: -5 TV91i)`c lilt cam6/(�
Gallons Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Month y Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.)
Lbs.
January: 21 95476.7 77660.0 1530 8851.1 37.7 8851.1 3336.85 5514.2
February: 18 77320.7 59532 -2243 -12975.8 37.7 -12975.8 -4891.86 -8083.9
March: 18 81478.6 64876.2 897 5189.1 37.7 1 5189.1 1956.31 3232.8
April: 20 82620.3 66330.0 1670 9661.0 37.7 9661.0 3642.18 6018.8
May: 21 85476.9 67475.0 1334 7717.2 37.7 123.60 7002.2 2639.82 4362.3
June: 18 85082.6 68809.5 1395 8070.1 37.7 8070.1 3042.42 5027.7
July: 19 72646.5 57860.0 1228 7104.0 37.4 32.70 6914.8 2586.14 4328.7
August: 23 102176.5 84920.0 1551 8972.5 37.4 10.90 8909.5 3332.14 5577.3
September: 17 70095.7 57554.5 1039 6010.6 37.3 6010.6 2241.96 3768.7
October: 22 81559.6 66880.0 1004 5808.1 37.1 5808.1 2154.82 3653.3
November: 15 55213.5 44935.0 791 4575.9 37.1 4575.9 1697.67 2878.3
December: 14 51995.8 43175.0 823 4761.1 37.1 87.30 4256.0 1578.99 26772
Average 19 78428.6 63333.9 918.3 5312.1 37.467 63.625 5189.386 1943.119 1 3246.27
Total 226 941143.4 760007.3 11019 63744.9 254.500 62272.633 23317.427 38955.21
T�o/ 13
o� f>� 3 h,s
��,c,Yv'1 �s}�s�e���

Page 3 of 5
Sclareol Recrvstallization(SFG)Operation:OS-6
Gallons en Monthly Hexane
Hexane Monthly Monthly
Month #Days Lbs.SFG Lbs.SFG Product Gallons Hexane Lbs.Hexane Used %n-Hexane St as Hexane n-Hexane Isomers
Operated Infeed Used Emitted Emitted
Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0.0 0.0 0.00 0.0
February: 0.0 0.0 0.00 0.0
March: 0.0 1 0.0 0.00 0.0
April: 0.0 0.0 0.00 0.0
May: 0.0 0.0 0.00 0.0
June: 0.0 0.0 0.00 0.0
July: 0.0 0.0 0.00 0.0
August: 0.0 0.0 0.00 0.0
September: 0.0 0.0 0.00 0.0
October: 0.0 0.0 0.00 0.0
November: 0.0 0.0 0.00 0.0
December: 0.0 0.0 0.00 0.0
Avera a #DIV/01 #DIV/01 #DIV/01 #DIV/01 0.0 #DIV/01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0 0 0.00 0.00 0.00 0.00
Rotocel&Recovery Operations:OS-4
Gallons Monthly
y
Lbs.Sage Monthly Monthly
#Days 9e Lbs.Sae Gallons Hexane Hexane y Hexane
Month Processed 9 Lbs.Hexane Used %n-Hexane Sent as Hexane Emitted
Isomers
Operated Product Used Emitted Emitted
(INFEED) Hazardous (Lbs. Emitted
Waste ) (Lbs.) Lbs.
January: 31 13950000.0 104899.0 19758 110447.2 2.27 110447.2 2507.2 107940.1
February: 28 12600000.0 100110.0 22916 128100.4 2.44 128100A 3125.7 124974.8
March: 31 13950000.0 107489.0 26595 148666.1 2.54 29.10 148503.4 3772.0 144731 A
April: 18 7650000.0 66082.0 22503 125791.8 2.62 125791.8 3295.7 122496.0
May: 31 13950000.0 133527.0 27060 151265.4 1.88 29.10 151102.7 2840.7 148262.0
June: 26 11700000.0 77832.0 25768 144043.1 0.95 144043.1 1368.4 142674.7
July: 31 13950000.0 123375.0 31071 173686.9 0.61 173686.9 1059.5 172627.4
August: 31 13950000.0 118440.0 30261 169159.0 1.62 169159.0 2740.4 166418.6
September: 26 11600000.0 84036.0 32074 179293.7 1.73 179293.7 3101.8 176191.9
October: 28 12431250.0 1 104038.0 28847 161254.7 1.31 161254.7 2112.4 159142.3
November: 30 11700000.0 99601.0 21733 121487.5 1.44 121487.5 1749.4 119738.1
December: 20 9000000.0 65471.0 15318 85627.E 0.79 85627.6 676.5 84951.2
Avera a 28 12 0 98741.7 25325 141568.6 1.683 29.10 141641.5 2362.5 139179.0
Total 331 C 146411250 1184900.0 303904 1698823.4 58.20 ,166984498.0 28349.6 1670148.4
Lbs.Hex per day exiting Mineral (� Accountable Lbs.of Hexane
Oil Scrubber 158.7E n Emitted: 200811.3
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 52550.884 Accountable Lbs.of N-Hex Emitted: I3nO.32= Q G fv UA Ac4 j v 4 4,6 PO,,-f
Lbs.of N-Hex exiting MO Unit: 884.61 Accountable Lbs.of Hexane 197430 I�
Isomers lost: 2
Unit:
Lbs.of Hex Isomers exiting MO 51666.28 Fugitive Lbs.Hexane Emitted: 1497691.96 I' /"GY
Lbs.Hexane per Lbs.of Spent 0.000930 Fugitive Lbs,n-Hexane Emitted: 25211.15
Sage from Desolvitizer tests):
Lbs.Hexane in Spent Sage: 72292.38
6181.0E Fugitve Lbs.Hexane Isomers
P 9 1472480.81,i
Emitted:
Lbs.N-Hexane in Spent Sage: Accountable and Fugitive Lbs. 1698503.2E
Hexane Emitted:Lbs.Hexane per Day from A-1000815 Accountable and Fugitive Lbs.
Vent Cond. N-Hex Emitted: 28591.47
Lbs.Hex ExitingA-1 Vent: 0.270 Accountable and Fugitive Lbs.Hex
1 U Isomers Emitted: 1669911.79
Lbs.N-Hex Exiting A-1 Vent: 0.004541 1_sv1%SP-r4,z eA.
Gallons Water sent to WWT: 10345227 elf[
Lbs.Waste Water perGal.Waste 8.34
Wt%of Hexane in Waste Water: 0.014 U S C b J G 16/C
Lbs.Hexane Lost in Waste Water: 12079.09 J I
Lbs.N-Hexane Lost in Waste
Water: 203.33
[ (,g882-3.Y lbs wA9 - 2oif39,8 16s oc lo(e = !997&63.6 165
AcwwTAg1ES f 3Z8•� lbt- t j2o79 ,O9
I+3�dal •vL. 5 In S � S 4 525So ,$U'Y tfbS -rv>7 S�Cl tl�S to Vow
S
f a

Page 5 of 5
Botanical Extraction Operation;OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used %n-Hexane Isomers
P Used Hazardous Emitted Emitted Emitted
Waste (Lbs.) (Lbs.)
January: Lbs.
Marc 0 0.00 0.0 0
F 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
[fAvera
vember: 0 0.00 0.0 0
cember: 0 0.00 0.0 0
a #DIV/01 #DIV/01 #DIV/O! 0 #DIV/01 #DIV/01 0 0 0
Total 0 0 0 0 0.0 0 0 0 0
Plant Nutrient Extraction(M-13)Operation:W9 L)9
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.PNE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0.0 0 0.00 0.0
-February: 11 SDE 305 1762.7 37.7 15444595 582.31 962.3
March: 31 SIDE 859 . . 2040.0 -7051.915 -2658.57 1 -4393.3
April: 11 SDE 305 1762.7 37.7 1544.595 582.31 962.3
May: 13 SDE 360 2083.2 37.7 1865.084 703.14 1161.9
June: 30 SDE 831 4807.3 37.7 4589.2405 1730.14 2859.1
July: 9 SDE 249 1442.2 37.7 1224.106 461.49 762.6
Au ust: 14 SDE 388 2243.4 37.7 2025.3285 763.55 1261.8
September: 30 SDE 831 4807.3 37.7 4589.2405 1730.14 2859.1
October: 14 SDE 389 2250.4 37.7 1484 1-6550.3555 1 -2469.48 -4080.9
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Average 18 #DIV/OI 502 2177.2 37.70 1761.8 314.993 118.76 196.24
Total 163 0 4516 26126.8 3523.6 3779.919 1425.03 1 2354.69
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1563744451 Total Lbs.Hexane Emitted: 1764555481
Fugitive Lbs.N-Hexane Emitted: #DIV/01 Total Lbs.n-Hexane Emitted: #DIV/O!
Fugitive Lbs.Hexane Isomers
Emitted: #DIV/01 Total Lbs.Hex Isomers Emitted: #DIV/0!
Accountable Lbs.Hexane Emitted: 200811.30 Total Lbs.Hexane Sent Off Site: 21099465
Accountable Lbs.n-Hexane
Emitted: #DIV/O! I Total Lbs.N-Hexane Sent Off Site: #DIV/O!
Accountable Lbs.Hex Isomers #DIV/0! Total Lbs.Hex Isomers ent Off #DIV/0!
Emitted: Site:
Annual Summary:Maximum n-Hexane On-Hand
Month
Total Hexane Total Total N-Hexane(Gallons) n-Hexane
Gallons (Lbs.)
January: 116162 11244 62855.1
February: 116089 12151 67921.6
March: 115480 11886 6644447
April: 116656 13079 73111.0
May: 121330 12208 68244.0
June: 114186 10968 61309.6
July: 115415 12836 71754.5
August: 116046 12903 7212847
September: 111973 13680 76469.4
October: 115225 13058 72994.1
November: 106140 12724 71126.8
December: 105068 1 12108 1 67683.8
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
121330 13680 76469

Page 4 of 5
_Concrete Operations:OS-4
Gallons Monthly
Monthly Monthly
#Days Lbs.Concrete Lbs.Concrete Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Infeed Product Used Lbs.Hexane Used %n-Hexane Sent as Isomers
Hazardous
Emitted Emitted Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0.0 0.0 0.0 0.0
February: 0.0 0.0 0.0 0.0
March: 0.0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0.0 0.0 0.0 0.0
July: 0.0 0.0 0.0 0.0
August: 0.0 0.0 0.0 0.0
-September: 0.0 0.0 0.0 0.0
October: 0.0 0.0 0.0 0.0
November: 0.0 0.0 0.0 0.0
December: 0.0 0.0 0.0 0.0
Average #DIV/01 #DIV/01 #DN/01 #DIV/01 1 0.0 �#D[V/01 #DIV/01 0.0 0.0 0.0
Total 0 0 0.0 0 0.0 0.00 0.0 0.0 0.0
Lbs.Hexane per Day from A-1 Vent Cond. 0.000815 Accountable Lbs.of Hexane Lost: 0.00
Days A-1 Operated: 0 Accountable Lbs.of N-Hex Lost: #DIV/0!
Lbs.Hex Exiting A-1 Vent: 0.000 Accountable Lbs.of HexaneIsomers Lost: #DIV/0!
Lbs.N-Hex Exiting A-1 Vent: #DIV/0! Fugitive Lbs.Hexane Lost: 0.00
Gallons sent to WWT: Fugitive Lbs.n-Hexane Lost: #DIV/0!
Lbs.Waste Water per Gal.Waste
Water: 8.34 Fugitve Lbs,Hexane Isomers Lost: #DIV/0!
Wt%of Hexane in Waste Water: 0.014 Accountable and Fugitive Lbs. 0.00
Hexane Emitted:
Lbs.Hexane Lost in Waste Water: 0.00 Accountable and Fugitive Lbs.
N-Hex Emitted: #DIV/0!
Lbs.N-Hexane Lost in Waste #DIV/0! Accountable and Fugitive Lbs.Hex #DIV/0!
Water: Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Lbs.
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Average #DIV/01 #DIV/01 #DIV/01 0.00 #DIV/01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2019
The Plant Material Grinder(OS-3) is operated in building ID# 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAPITAPS, or VOC
associated with the grinder's operation. Essentially there are no emissions associated with
the plant material grinder.
III