AQ_F_0800044_20170912_EI_Cmb-EI-File

2016 Emissions Inventory Review / Data Tracking Form
Facile Name: Avoca Inc. Facile ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston ETH Confidential Copy Submitted?
Title V ❑!Rf YES
Initial Review/Data Entry
Enter date received into ED. Date Received: 31zilzol-7
Assigned to appropriate individual. Date Assigned: 3/2 4 /2,0/7 Date Due: 91301247
d Parser WRY submitted: One copy received with supporting documentation,certification form signed by responsible official,and
appears generally complete;9W Q„
0' Electronic copy submitted: All supporting documentation and certification form(with time/date stamp)signed by responsible
official has been received.
Comments: �Fee In vtn ✓�✓l ew n6fe5 PfffucLierl.
Inventory Review
dAll forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
L�l Contact,address,phone number changes entered into I-Beam/Facilities if necessary.
0 All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
L�l Check if SCC codes for each OS are accurate and update if needed.
0 Evaluate"U"sources for significance and address according to policy.
Calculations/forms appear to add up correctly.
LZ All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds, large emissions increase/decrease, installation
without a permit).
L�J All volatile HAPs/TAPS were included in the VOC total.
C3� Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP42,etc.).
Review facility comments and address any issues.
121' Update ED(Data Entry Main) if additional information is required(corrections due date and date received).
Check all ED QA/QC reports.
® Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained.
l2r Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
u Print and attach the facility total report.
Date Info Requested: Date Info Received: Total Days on Hold:
Date Review Complete: -7/2,*) 7 Signature: �✓ - �i�y7
Date Submitted to El Coordinator: 9/0712o1 7
Date Approved: 9/02 7 Initials: �rN

Avoca Emissions Inventory Review Notes CY2016
General Notes
• I reviewed all SCC and Unit types. I did make some changes for several OS, including but not limited to the
following:
- Wood boiler SCC changed to account for wood/bark fuel
- Engines changed to industrial category SCC
- Several process SCC were changed to"Organic Chemical Manufacturing and Processing"so I could
group them with the process area.
- Changed SCC and unit type for the wastewater aeration chamber
• I reviewed all calculations. There were no changes to Avoca's emissions factors and calculation methods in
the CY2016 inventory compared to the CY2015 inventory.
• Almost all of the plant sources have historically been given a not required to report tag in the Source screen
of ED. I'm unsure of why this was done years ago. It has not been an issue for reporting because the
inventory is set up primarily by plant area groups(boilers, generators, Biomass, Biological, SFG, SDE,
Rotocel/Recovery). Most of the sources belong to these groups. To remove this tag,the sources would have
to be pulled out of the groups they are saved to,changed to"required to report" in Source screen,and then
would have to be re-added to their respective group. I requested help from Holly Groce; per my request she
changed all of the sources in the groups to"required to report."
• Most of the process area operating scenario throughputs are in-feed tonnages to the processes(i.e.tons sage,
SFG raw Ibs sclareol, SDE raw infeed, etc.). Since Botanical Extraction uses a variety of solvents,they don't
have one specific sheet in the inventory spreadsheets that has the total Botanical Extraction throughput
(infeed or product). Brian adds up all the processes that were run in the botanical extraction area with a
variety of solvents.
• Because Avoca only reports wastewater emissions specifically at the I`aeration chamber to the WWTS
(MeOH only), I have grouped all permitted wastewater emission sources with their respective plant area.
Boilers H101-103
• Fuel oil usage increased on Boilers H101-103 by 12.9%compared to CY2015.
• For H101-103 I corrected the NOx factor to 20 lbs/MGals. The corrected emission is now 6.73 tons
NOx. The SOz emission was corrected to 0.07 ton using the 0.0014%sulfur content of fuel oil. These
corrections were also done to the CY2015 data.
• 1 applied the filterable+condensable factor of 3.3 lb PM/1000 gals= 1.11 ton PM and corrected the
data in ED.
• I changed the o-xylene emission in ED to xylene mixed isomers.
Wood Boilers
• Wood combustion in the boilers decreased 14.7%by weight in CY2016. I added a number of toxics
to ED using the DAQ spreadsheet for wood combustion. I did the same for the CY2015 inventory. If
a combustion HAP in the spreadsheet was not listed in ED, it is because the facility-wide emissions
are below reportable threshold,or the emission is negligible and won't affect the facility total.

Brian Conner and I agreed there should be a 99%control efficiency applied to the metal HAPs. I
contacted Tammy Manning to re-open the CY2015 data to apply this control efficiency as well(data
entry and re-approval of the CY2015 data is complete).
Emer¢eney Eneines
• The generators used 8.6%more fuel (in gals)than in CY2015. I corrected the NOx and VOC
emissions using AP-42 factors 3.2 lb/MMBtu and 0.08 lb/MMBtu. This same correction was applied
to the CY2015 data. The fire pump is grouped with the generators, but Avoca did not add up their
emissions for the OS. I summed the five engines' emissions and entered them into OS42. Some
metals emissions are not listed due to their emissions being negligible and not affecting the facility
totals.
• PkGEN used 15% less fuel in CY2016. I added the PkGEN GHGs to ED. I also added the PkGEN
chromic acid, lead and mercury emissions to ED. I removed control efficiencies entered for NOx,
VOC and SO2.
Process HAP Emissions
There are many hand-written review notes made within the hard copy of the inventory.
• An explanation for the heptane emissions split between point and fugitive for SFG was provided for
the CY2015 inventory, and applies again to the CY2016 inventory:
Avoca assumes that the bulk of Heptane emissions from SFG are fugitive. Based on old hexane
values and using MON batch calculations to back into it, approximately 80%of SFG heptane
emissions are fugitive and 20%are out the stacks.
• An explanation for the hexane emissions split between point and fugitive for SDE was provided for
the CY2015 inventory,and applies again to the CY2016 inventory:
As with SFG Avoca assumes that the bulk of Hexane emissions from SDE are fugitive. Based on
hexane values and using MON batch calculations to back into it,they saw approximately 17.6%of
SDE hexane emissions are out the stacks.
However, instead of taking 17.6%of the total n-hexane added up from the month-to-month tank
measurements and batch calculations,Avoca calculated the annual n-hexane emission to be the total
Ibs iso-hexane X annual average 38.051%n-hexane content. This created a smaller reportable n-
hexane fraction from point sources.
• The fugitive and point splits for hexanes from Rotocel and Recovery are briefly explained below(see
calcs in the hard copy):
Accountable emissions are those Avoca can verify along with the emissions coming out the final
stack; hexane going to wastewater, hazardous waste, or in the spent sage material. Using test data,
Avoca calculates the average hexane per day exiting the MO Scrubber was 158.76 Ibs. Then multiply
158.76 times the number of days run(324 days)out the stack. The average n-hexane content of the
solvent is used to calculate the split of hexane isomers and n-hexane.
Fugitive hexane is calculated by subtracting the accountable hexane from the total hexane used.
• Reminder: More than a third of the methanol"lost" from the Rotocel& Recovery operation goes to
WWTP. Of that,98-99% is consumed by the biological activity in the WWTP,while emitting the
remainder. The WWTP emission is calculated through the Water 9 program. The other two thirds of
methanol"lost"from Rotocel& Recovery is"fugitive." Brian has noted that some of the"fugitive"
losses are also actually going out the stack of the Mineral Oil Scrubber as well,but most of it would
be in the lines and from the tanks located in recovery

• CY2016 process VOC emissions are comprised of chloroform, hexanes,heptane,methanol, and ethyl
acetate. All of their annual emissions are determined through mass balance. Avoca uses purchasing
records, daily formulation and batch records,daily tank level measurements,waste shipment records,
process design calculations, and MACT MON formulas(fugitive and point source splits). Ultimately,
more VOCs HAPs were used in CY2016,and therefore more were emitted to atmosphere.
Facility-wide Combustion Criteria and HAPs
• The reduction in NOx,CO and SO2 emissions were due to the decreased in fuel to the wood boilers.
• The 30.8% increase in VOC emissions was due to increased chloroform,hexane,ethyl acetate,
methanol and heptane usage.
• The PM increase was due to increase fuel oil combustion in the H101-103 boilers.
• Increases in beryllium, cadmium, lead,mercury,fluorides and nickel are due to increased fuel oil
combustion in H101-103.
• Decreases in chromic acid,manganese,and all other combustion VOC HAP are due to decreased
wood combustion.
(g:\AQ\Shared\Bertie08\00044\20170907 Inventory Review Notes CY2016)

Huddleston, Betsy
From: Brian Conner <[e-mail]>
Sent: Tuesday, September 05, 2017 11:29 AM
To: Huddleston, Betsy
Subject: RE:Question on annual Emissions Inventory
Betsy,
See me responses below:
1 NOx factor changed for Boilers is good. I will replace in m files.
II E N Y
2) NOx and VOC factors changed for emergency engines is good. I will replace in my files.
3) 1 would agree that the bag-filter control efficiency used for the biomass boilers should be good for metal
emissions as well.
4) You are correct in the way chloroform losses are reported for EVG. MON losses only account for calculated
emissions based on the MON calculations per batch.The true emission inventory is based on real daily
inventories and accounts for total real fugitive and point emissions.
5) Yes,the same explanation applies for Ethyl acetate emitted from Botanical Extraction in 2016. 217.08 lbs. of
ethyl acetate was emitted from botanical extraction. All of the ethyl acetate emitted from botanical extraction
was from the denatured ethanol.There was no straight ethyl acetate solvent used in botanical extraction.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
PO Box 129
Merry Hill, NC 27957
Office: [phone]
Cell: [phone]
From: Huddleston, Betsy [mailto:[e-mail]]
Sent: Friday, September 01, 2017 3:32 PM
To: Brian Conner
Subject: Question on annual Emissions Inventory
Hi Brian,
I review all my assigned annual inventories in August and September, and yours is now the next one in line. I've made it
about halfway through, and have a few comments and questions :
1. For Boilers H101-103 I changed the NOx factor to 20 Ibs/MGals based on AP-42 and DAQ spreadsheet
reference. This same change was done in the CY2015 inventory.
2. 1 changed the NOx and VOC factors for the emergency engines to AP-42 factors of 3.2 Ib/MMBtu and 0.08
Ib/MMBtu (since AP-42 is referenced as your source for the factors). This same change was done in the CY2015
inventory.
3. In the last couple of years we have agreed to include some metals emissions in reporting to AERO for the boilers
because they were calculated above reportable thresholds. I just now noticed that we did not apply any control
efficiencies to the metals (arsenic, beryllium,cadmium, lead, manganese, nickel, etc.)for the wood boilers. I
1

i
think we can assume the bagfilter control efficiency for them, if you'd would like to. If so,then I can also go
back to last year's inventory data and apply it there as well.
4. Just to make sure I understand-the chloroform reported emissions cover process emission point and fugitive
loss. The semi-annual report for chloroform emitted under MON is based upon the required MON formula only
accounting for point loss, but not fugitive? That would account for the large gap in difference of reported
emissions?
5. On the ethyl acetate page,does the same explanation from last year apply this year in terms of there
being 217.08 lbs emitted from Botanical? Last year you emailed, "Going back and looking at my
spreadsheets, I referenced the wrong cell on the AAE Inventory Summary spreadsheet....the 30.42 lbs. of
Ethyl acetate was the average cell.The cell below that is the total which is 456.34 lbs. When looking at
my spreadsheet for Ethyl acetate,the final column labeled "Total Ethyl Acetate Emitted from Botanical
Extraction: OS-10" is the total for all Ethyl acetate from Botanical Extraction for all processes. 456.34 is
the correct total lbs. of Ethyl acetate emitted from Botanical Extraction and should replace 30.42 on page
44 of AFRO.
Thanks!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
Betsy.Huddleston 5ncdenr.gov
943 Washington Square Mall
Washington, NC 27889
PC-
-!`- 'Nothing Compares �a
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.
2

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Green House Gases Pollutants (GHG) Actual Emissions %Tons/Yr
Pollutant CAS CY 2016 CY 2015 Demini- Change
from ED from Fees mus
Methane(CH4) 74-82-8 2.14 2.52 10.0 -15.0%
Nitrous Oxide (N20) 10024972 1.35 1.54 1.0 -12.1%
Carbon Dioxide (CO2) 124389 27,323.38 29,856.90 5,000.0 -8.5%
CO2 equivalent(sum of individual GHG pollutant emission 25,209.13 metric tons
times their 1995 IPCC Global Warming Potential (GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
CO c0 21.50 24.70 0.5 -13.0%
NOx NOx 30.68 33.91 0.5 -9.5%
PM(TSP) TSP 1.32 1.22 0.5 8.2%
PM10 PM10 0.505000 0.535000 0.5 -5.6%
PM2.5 PM2.5 0.285000 0.305000 0.5 -6.6%
S02 S02 2.67 3.10. 0.5 -14.1%
VOC VoC 1,221.52 934.06 0.5 30.8%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Arsenic & Compounds (total mass of elemental AS, arsine and 1 0.424690 0.409180 0.01 3.8%
all inorganic compounds)
Arsenic Unlisted Compounds - Specify Compound ASC-Other 0.424690 0.409180 0.01 3.8%
(Component of ASC)
Beryllium& compounds (Total mass) 0.285790 0.250300 1.0 11.5%
Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.285790 0.256300 1.0 11.5%
Cadmium& compounds (total mass includes elemental metal) 0.285190 0.263400 0.1 8.5%
09/12/2017 Page 1 of 5

i
Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2015 Demini- %
from ED from Fees mus Change
Cadmium Metal, elemental, unreacted (Component( 7440-43-9 0.285790 0.263400 0.1 8.5%
CDC)
Chromium-AIUTotal(includes Chromium (VI) categories, 0.994790 1.08 0.1 -7.9%
metal and others)
Chromic acid (VI) (Component of SoICR6 & CRC) 7738-94-5 0.994790 1.08 0.01 -8.2%
Chromium (VI)Soluble Chromate Compounds (Component of 0.994790 1.08 0.01 -7.9%
CRC)
Chromic acid(VI)(Component of So1CR6 &CRC) 7738-94-5 0.994790 1.08 0.01 -8.2%
Cobalt& compounds Not 0.016000 1.0 I N/A
Reported
Cobalt Unlisted Compounds - Specify Compound COC-Other Not 0.016000 1.0 N/A
(Component of COC) Reported
Lead& compounds 0.953280 0.860600 1.0 110.8%
Lead Unlisted Compounds - Specify Compound PBC-Other 0.953280 0.860600 10.0 10.8%
(Component of PBC)
Manganese & compounds 3.79 4.29 10.0 1-11.7%
Manganese Unlisted Compounds - Specify Compout MNC-other ?.79 4.29 10.0 -11.8%
(Component of MNC)
Mercury& Compounds-all total mass includes Mg Vapor 0.342790 0.318800 0.001 7.5%
Mercury, vapor(Component of HGC) 7439-97-6 0.342790 0.318800 0.001 7.50/.
Nickel& Compounds, sum total mass includes elemental 0.349590 0.328300 1.0 6.5%
Nickel metal (Component of NIC) 7440-02-0 0.349590 0.328300 1.0 6.5%
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.524300 0.615300 1.0 -14.8%
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 0.524300 0.615300 1.0 -14.8%
56553/7PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 20.45 23.91 1.0 -14.5%
for TV)
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 0.524300 0.615300 1.0 -14.8%
56553/7PAH)
Naphthalene(Component of 83329/POMTV) 91-20-3 19.92 23.29 1.0
09/12/2017 Page 2 of 5

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Acetaldehyde 75-07-0 167.48 196.44 10.0 -14.7%
Acrolein 107-02-8 806.77 946.28 10.0 -14.7%
Benzene 71-43-2 849.79 996.15 1.0 -14.7%
Carbon tetrachloride 56-23-5 9.08 10.65 1 .0 -14.7%
Chlorine 7782-50-5 159.34 186.89 100.0 -14.7%
Chlorobenzene 108-90-7 6.66 7.81 10.0 -14.7%
Chloroform 67-66-3 30,681.65 16,948.62 100.0 81.0%
Ethyl acetate 141-78-6 31,432.76 21,102.09 10.0 49.0%
Ethyl benzene 100-41-4 6.80 7.82 100.0 -13.0%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.89 6.86 1.0 -14.1%
Fluorides (sum of all fluoride compounds as mass of 16984-48-8 25.10 22.22 10.0 12.9%
ion)
Formaldehyde 50-00-0 919.90 1,069.67 10.0 -14.0%
Hexane isomers, except n-hexane HEXANEIso 1,483,627.7 1,136,915.8 100.0 130.5%
9 2
Hexane, n- 110-54-3 103,238.26 89,975.18 100.0 14.7%
Hydrogen chloride (hydrochloric acid) 7647-01-0 18.15 21.29 100.0 -14.7%
Methanol (methyl alcohol) 67-56-1 539,989.20 414,346.26 1,000.0 30.3%
Methyl bromide(bromomethane) 74-83-9 3.03 3.55 1.0 -14.6%
Methyl chloride (chloromethane) 74-87-3 4.64 5.44 1.0 -14.7%
Methyl chloroform 71-55-6 Not 7.30 100.0 N/A
Reported
Methylene chloride 75-09-2 58.50 68.60 1.0 -14.7%
Phenol 108-95-2 10.29 12.07 100.0 -14.7%
Phosphorus Metal, Yellow or White 7723-14-0 Not 6.39 1.0 N/A
Reported
Polycyclic Organic Matter(Inc PAH,dioxins, etc.N, poM 27.42 31.54 1.0 -13.1%
& AP 42 historic)
09/12/2017 Page 3 of 5
1

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Propionaldehyde 123-38-6 12.30 14.43 10.0 -14.7%
Styrene 100-42-5 383.21 449.48 100.0 -14.7%
Toluene 108-88-3 239.49 265.46 100.0 -9.8%
Vinyl chloride 75-01-4 3.63 4.26 0.1 -14.8%
Xylene (mixed isomers) 1330-20-7 6.20 6.98 100.0 -11.2%
Largest Individual HAP Methanol (methyl alcohol) 539,989.20 lbs
Total HAP Emissions 677,635.54 lbs
Largest Individual CAP VOC 1,221.52 tons
Total CAP Emissions 1,276.88 tons
Total TAP Emissions 19652,656.49
lbs
Total Aggregate 1,277.01 tons
Emissions
09/12/2017 Page 4 of 5

DAQ's Comments Retarding Inventory
SEE THE REVIEW NOTES ATTACHED TO THE HARD COPY OF THE INVENTORY AND THE HAND WRITTEN NOTES
THE INVENTORY HARD COPY.
1) Reviewed all SCC and Unit types-make some changes for several OS(see hard copy notes)
2)I reviewed all calculations. There were no changes to emissions factors and calculation methods compared to CY2015 inventory
3)Almost all of the plant sources been given a not required to report tag in the Source screen of ED These are operating permitted
sources,so for this CY they were changed to"required to report." Holly Groce helped with these changes. See emails.
4)Because Avoca only reports wastewater emissions specifically at the 1 st aeration chamber to the W WTS (MeOH only),I have
grouped all permitted wastewater emission sources with their respective plant area All of the wastewater sources have been given
'not required to report'status in Source screen since W W emissions are accounted at the aeration chamber
5)Fuel oil usage increased on Boilers H101-103 by 12.9%compared to CY2015.
I corrected the NOx factor to 201bs/MGals.The SO2 emission was corrected using 0.0014%sulfur content fuel oil. I applied the
filterable+condensable factor of 3.3 lb PM/1000 gals= 1.11 ton PM and corrected the data in ED. I changed the o-xylene emissioi
in ED to xylene mixed isomers
6)Wood combustion decreased 14.7%by weight in CY2016. I added HAPs to ED using the DAQ wood combustion spreadsheet
Brian Conner and I agreed there should be a 99%control efficiency applied to the metal HAPs. I contacted Tammy Manning to
re-open the CY2015 data to apply this control efficiency as well(data entry and re-approval of the CY2015 data is complete).
7)The generators used 8.6%more fuel(in gals)than CY2015. I corrected the NOx and VOC emissions using AP-42 factors. I add
fire pump emissions to total in OS.
8) PkGEN used 15%less fuel in CY2016. I added the PkGEN GHGs to ED. I also added more HAP. I removed control efficienci
entered for NOx,VOC and SO2.
9)See hand written and review notes on hexane fugitive and point emissions
10) Avoca assumes bulk of SFG heptane emissions are fugitive.Based on old hexane values and using MON batch calculations to
back into it,approximately 80%of SFG heptane emissions are fugitivo-20%are out the stacks.
11)Reminder: More than a third of the methanol LlostL from the Rotocel&Recovery operation goes to W WTP. Of that,98-99%i
consumed. The W WTP emission is calculated through the Water program.
12)CY2016 process VOC emissions are comprised of chloroform,hexanes,heptane,methanol,and ethyl acetate All of their annu
emissions are determined through mass balance. Avoca uses purchasing records,daily formulation and batch records,daily tank
level measurements,waste shipment records, process design-calculations,and MACT MON formulas(fugitive and point source
splits). Ultimately,more VOCs HAPs were used in CY2016,and therefore more were emitted to atmosphere.
13)The reduction in NOx,CO and SO2 emissions were due to the decreased in fuel to the wood boilers
14) The 30.8%increase in VOC emissions was due to increased chloroform,hexane,ethyl acetate,methanol and heptane usage
15) The PM increase was due to increase fuel oil combustion in the HI01-103 boilers.
16) Increases in beryllium,cadmium,lead,mercury,flourides and nickel are due to increased fuel oil combustion in H01-103.
17) Decreases in chromic acid,manganese,and all other combustion VOC HAP are due to decreased wood combustion
09/12/2017 Page 5 of 5

Huddleston, Betsy
From: Groce, Holly
Sent: Tuesday, September 12, 2017 7:48 AM
To: Huddleston, Betsy
Subject: RE: Data Clean Up Question
Hey,
I think I got them all, let me know if any problems.
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
P 1 Y
to third parties.
-----Original Message-----
From: Huddleston, Betsy
Sent: Monday,September 11, 2017 3:28 PM
To: Groce, Holly<[e-mail]>
Subject: RE: Data Clean Up Question
G77 Generators: All sources in this group need to be required
G150 Botanical: All sources in this group need to be required
G96 Recrystallization: All sources except 1003-10-WW wastewater need to be required
G97 PNE: Only TKEPNE-1 needs to be changed to required
G95 Conversions: contains a number of sources that were phased out of the permit last year. Therefore the sources
that need to be changed to required are G-17, 1001-1-3-P, 1001-1-3-F, 1001-1-3-Filter,and D1202
G94 Rotocel/Recovery/Concrete: All sources in this group need to be required, EXCEPT 1001-2-1-WW, 1001-1-1WW,
and 1001-1-2-WW
GR1 Biomass: All of the sources except 1004-2-WW
t

Thanks very much for helping me!!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
[e-mail]
943 Washington Square Mall
Washington, NC 27889
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Groce, Holly
Sent: Monday, September 11, 2017 2:53 PM
To: Huddleston, Betsy<[e-mail]>
Subject: RE: Data Clean Up Question
OK, so go ahead and give me the rest of the groups or whatever that need to have their setting changed and I'll aim to
do those tomorrow.
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
2

-----Original Message-----
From: Huddleston, Betsy
Sent: Monday,September 11, 2017 2:31 PM
To: Groce, Holly<[e-mail]>
Subject: RE: Data Clean Up Question
Hi Holly,
It's great!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
[e-mail]
943 Washington Square Mall
Washington, NC 27889
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Groce, Holly
Sent: Monday,September 11, 2017 12:57 PM
To: Huddleston, Betsy<[e-mail]>
Subject: RE: Data Clean Up Question
Hey,
I have marked all sources belonging to G-99 to required to report. See how that works and let me know...
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
3

[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Huddleston, Betsy
Sent:Wednesday, September 06, 2017 3:07 PM
To: Groce, Holly<[e-mail]>
Subject: Re: Data Clean Up Question
Cops Might be a mistype. I'm not at my desk at moment. I would just stick to testing all of the sources being changed to
required to report in group G-99.
Sent from my iPhone
>On Sep 6, 2017, at 2:23 PM, Groce, Holly<[e-mail]>wrote:
>Are you sure there's a D-2022?
> Holly Groce
>Applications Systems Manager
> North Carolina Division of Air Quality North Carolina Department of
> Information Technology
>919.707.8953
> [e-mail]
>
> I
>
> Email correspondence to and from this address is subject to the North
>Carolina Public Records Law and may be disclosed to third parties.
>
>-----Original Message-----
> From: Huddleston, Betsy
>Sent:Wednesday, September 06, 2017 2:09 PM
>To: Manning,Tammy<[e-mail]>; Groce, Holly
><[e-mail]>
>Subject: RE: Data Clean Up Question
> Hi Holly and Tammy,
> I've chosen a small group to work with. All of the sources are marked as not required to report in the group.
Emissions are reported through mass balance calculations per plant area, so all of these sources contribute to some
degree to the total emissions for the group.
>Group 99-EVG
4

>Sources:
> D-2022
> D-1215
> D-1218
> D-1201
> ES-1003-2-2-F
>Thanks for the help!!
> Betsy Huddleston, Environmental Engineer II NCDENR, Division of Air
>Quality Washington Regional Office
>943 Washington Sq. Mall,Washington, NC 27889
> Phone: [phone]
> Fax: [phone]
> http://www.ncair.org
>** Email correspondence to and from this address is subject to the
> North Carolina Public Records Law and may be disclosed to third parties unless the content is exempt by statute or
other regulation.
> **
> From: Manning,Tammy
>Sent:Wednesday,September 6, 2017 11:47 AM
>To: Huddleston, Betsy
>Subject: FW: Data Clean Up Question
> Hi, can you send Holly some source ids to test making the change in
>the database? Thanks,Tammy
> From: Groce, Holly
>Sent:Wednesday,September 06, 2017 11:37 AM
>To: Manning,Tammy<[e-mail]>;Odulapalli, Suneetha
><[e-mail]>
> p Subject: RE: Data Clean U Question
>
1
> I can change the status setting directly in the database. I'd like to do one or one group of sources first and have
you/Betsy make sure screens function ok,then would do the rest.
> Need the source ID's.
> Holly
> Holly Groce
>Applications Systems Manager
> North Carolina Division of Air Quality North Carolina Department of
> Information Technology
5

>919.707.8953
> [e-mail]<mailto:[e-mail]>
> [1495224421788_Pastedlmage]
> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be
disclosed to third parties.
> From: Manning,Tammy
>Sent: Wednesday,September 06, 2017 8:23 AM
>To: Groce, Holly
><hol ly.groce@ ncden r.gov<ma i Ito:hol ly.groce@ ncdenr.gov>>; Odulapalli,
>Suneetha
><[e-mail]<mailto:suneetha.odula pal [e-mail]>
>Subject: FW: Data Clean Up Question
>Good morning,
> Do you know another way to mark these sources as required to report? In ED-Emission Sources,the Required to
Report/Not Required to Report is not available since they are included in a group. I do not want to change this feature
but I do not think that it was envisioned that facilities would mark numerous sources erroneously as not required to
report.
>
>Thanks,Tammy
> From: Huddleston, Betsy
>Sent:Tuesday,September 05, 2017 5:35 PM
>To: Manning,Tammy
><tammy.man [e-mail]<mailto:tam my.man [e-mail]>>
>Subject: Data Clean Up Question
> Hi Tammy,
> I'm working on the Avoca 0800044 inventory. Much of their sources are grouped together. Historically they have
tagged a lot of the sources in the groups inappropriately as "not required to report." Actually all of the sources in the
groups should be "required to report." I can't change this without pulling the sources out of the groups,changing the
reporting status, and then putting them back into the groups.This is labor intensive since there are a lot of sources in
this state. Is it possible to go in through the back door for all of the groups, and change the sources to "required to
report?"
> Betsy Huddleston
> Division of Air Quality
> North Carolina Department of Environmental Quality
> 252 948 3836 office
>252 975 3716 fax
> Betsy.Huddleston @ncdenr.gov<maiIto:Betsy.H uddleston @ ncdenr.gov>
>943 Washington Square Mall
>Washington, NC 27889
> [cid:[e-mail]36780]
6

> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be
disclosed to third parties.

Annual Air Emissions Inventory Summary
2016 Totals
Facility ID#: o800044
PoNtrtaM Boar#1 Boller#2 Boller 01 Gen ill
Gen 02 Gen hM Gen M Pk-Gen Fire Pump Biomass Ro0ocd Rccrysta"Z20o t SgereOWe Biomass Botarrleal Plant
CO BoNers Recovery Concrete (SFG) (SDE) Extractlon Extractlon t EVG wwrp Dyer
2049.33330 43464178 011 781 12 LGO32 30 1.39558 1.74448 1.45761 1.42660 15.88483 5.99008 19664.74 Processes TWah Units
Methane 0.00542 0.01149 0.00328 0.00029
Nitrous Oxide 0.01083 0.02298 0.00036 0,00030 0.00029 0.00325 0.00024 2.12
TSP 0.18056 0.38294 0- � 0.00003 0.00004 0.00003 0.00003 0.00253 0.00005 1.31
27329.373 Tons/Vr
PM-10 0.10934 0.00317 0.00397 0.00331 0.00, 4 0,03611 0.01139 0.141 2.143 Tons/Yr
0 09028 0.19147 0.05467
PM-2.5 0.02257 0.00317 0.00397 0.00331
0.04787 0.01367 0.D0317 0.00324 0.03611 0.01139 0.141 1.354 T
Sox 3.84589 8.15671 2.32890 0.00397 0.00331 0.00324 0.03611 onslYr
0.01139 0.141 0.675 Tons/Yr
Nox 0.00447 0.00559 0.00467 0.00457 0.05092 0.00558 2.52112 - 0.539 7orhs/Yr
0.16670 d.59533 1.31206 0.01015 0.07269 0.01060 0.01038 1.15552 0.16198 22.1859
VOC 0.0180E 0.03829 0.07093 0.01142 0.01428 ------ 0.01167 0.13000 0.01322 1.7144 684.588 264.828 0.28E Torhs/Yr
CO 0.45140 0.9573E 0.27335 0.02697 0.03371 0.0281E 0.02757 0.30694 0,03489 1 .7144 16.928 Tonstyr Zrto7
68.939 108.845 0.178 2.499 69.204 17.272 3.23 31 621 TonsNr 3 J.(p 0.00050 U.00167 0.00163 0.01820 0.05634 767.402 1227.561 Tons/Yr
Aaokin 0.00200
0.00050
Arserhic 0.10117 0.21445 0.00025 0.000G2 0.00052 0.00051 0.00569 0.00680 806.758 21.503 Tons/Yr
0.06123
Benzene 0.49653 t.05310 0.30p6a 0.00032 0.00027 0.00026 0.00289 0.00029 167.484
Benzo(a ene 0.04924 0.06155 0.05143 0.05033 0,56043 0.06854 847.09E 806.773 Lbs7Yr
tie m 0.00002 0.00002 0.00002 0.00 302 0.00019 0.00001 47.0 U.381 Lt1s/Yr
0.07583 0.16084 0.04592 0.00019 8d9.788 L.pyyr
Butanoi 0,00024 0.00020 0.00019 0.00217 5.00022
Cadmium 0.07583 0.76084
Cakaum Vide 0.04592 0.00019 0.00024 0.00020 0.52466 LbslYr
Carbon
0.00019 0.00217 0.00022 0.286 Lbslyr
tetrachloride 0.000 Lbs(Yr
Chlorine 0.286 Lbs(Yr
Chlorobenzene 9.07E
0.000 Lbs/Yr
Chloroform 159.335 9.076 Lbs/Yr
.65E 159.335 LbslYr
.
Chromium 6
0.07583 0.t6084 0.04592 .6
47 Chromium N 000524 05E LbslYr
.01111 6.6
0.00317 3�6 30681.647 Lbs(Yr
mate
Ethanol-100%acetate Lbs/Yr
283
Ethanol-SDA 0.0. 2 Lbs7Yr
0 0.000 Lbs1Yr
r+e 0.00 E benzene 0.74752 0.31287 0. 312.05 08933 4781.45 0.00 342.053 LbslYr
bhride
E 6.252 31202.00 13.68 217.08 0.00 4781.44E Lbs7Yr
F 6.73481 14.28382 4.07831 31/32760 LbslYr
Fon HC11 de 8.66678 18.38133 5.24822 0.00 6.802 Lbs7Yr
HCI 0.00501 0.0062E 0.00523 0.00512 0.05698 0. 0.000 LbslYr Hexane Isomers
08668 887.434 25.097 LbWr
18.152
N-Hexane 0.000 1 5.13 19.89E Lbs/Yr H tane 90.OW 0.00 134772.12 0.00 0.00 0.p0 18.152 LbsKr
l acetate o.00 a2sr7.8a o.00 o.00 o,ao 1483457.258 Lbsrvr 1 y13342
ISO acetate tos676.sa 0.00 110656.67 10340a.792 Lbs/Yr Lead Com 0.22750 0.48251 0.13777 /�3z36
27751.95 217333.305 Lbr/Yr
M anew 0.15167 0.32167 0.00 0.00 27757.947 Lbs/Yr
0.09184
Me 0.00 0.000 Lbs/Yr
0.07583 0.16084 0.04592
Methanol 0.058 0.00 0.848 Lbs/Yr NaNickelne 0.07583 0.16084 0.03608 0.00825 0.01031 0.00862 0.00843 0.09389 0.00623 19.564 0.565 LL1slYr Nickel 0.07583 529656.30 0.341 Lbs7Yr
Phenol 0.16084 0.04592 0.00 3868.30 6464.60 539989204 LbsJYr Propio e
Sulfur Dioxide 10.28E 19.922 LbslYr
ene 12.303 0.283 Lbs/Yr
✓ 70.28E LbsNr Toluene /4.39047 30.5206E 871424 0.02§3 0.02229 383.210 112.303 LbslYr
0.01862 0.01823 U.20294 0.03005 1185.554 0'00 0.000 Lbs(Yr
o-X ene 0.25278 0.53612 0.75307 0.01225 0.01531 0.01279 0.01252 0.13938 0.02094I 5.042 383.210 Lbs/Yr
0.00 0.00 239.490 Lbs7Yr
✓ 5.255 Lbs1Yr
0.942 Lbs/Yr

FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION G 11/5/2012-OUTPUT SCREEN
Instructions: Enter emission source I facility data on the"INPUT'tablscreen. The air emission results and summary of input data
AMre are viewed/printed on the"OUTPUT'tablscen. The different tabs are on the bottom of this screen.
/ � This•pnatlehM is ter your sea only and•hould"usedwah clarion.DENR does;not guarant«the curacy or the Information mntelned This sprea"heet le
aged to contmutl revblon and updMinp.It b your respon4lMlity to be aMam or the most current Information available. DENR is not reaponalbk for ermn or
NCDENRomMaiona that mry"codalma Mreln.
COMPANY: AVOCB MAXHEATINPUT: 6&80 MMBTU/HR
FACILITY ID NO.: 800044 IFUEL HEAT VALUE: 141,000 BTUIGAL
PERMIT NUMBER: 0 JHHV for GHG CALCULATIONS: 0.138 mm BTU/GAL
FACILITY CITY: Many Hill JACTUAL ANNUAL FUEL USAGE: 672,840 GAL/YR
FACILITY COUNTY: Berne IMAXIMUM ANNUAL FUEL USAGE: 4088.000 GALIYR
USER NAME: E Huddleston MAXIMUM SULFUR CONTENT. 0.0 %
EMISSION SOURCE DESCRIPTION: Na 2 oil-fired Boiler
EMISSION SOURCE ID NO.: H101-103 IMAX.FUEL USAGE: 4.088,DDO GALIYR
MAX.SULFUR CONTENT: 0,0014 %
NONE/OTHER PM 0
NONEIOTHER S02 0
NONE/OTHER I NOx 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1 DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS CI el: CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
ACTUAL EMISSIONS POTENTIAL EMISSIONS :2.00E+01
ISSION FACTOR
yLe .14n JLeruanal 19E.mr.ma•ruallm uRa CCe11RX9rLan911we al
AIR POLLUTANT EMITTED Ibmr ton r b/hr ton Ib/hr ton nali corarollad
TOTAL PARTICULATE MATTER PM FPM+CPM 1.54 1.11 1.54 8,75 1.54 8.75 +00 3.30E+00
FILTERABLE PM FPM 0.93 0.57 0.93 4.D9 0.93 4.09 +00 2.00E+00
CONDENSABLE PM CPM 0.61 0.44 0.61 2.66 0.61 2,66 +00 1.30E+DO
FILTERABLE PM<10 MICRONS(PM,,) 0.47 0.34 0,47 2-04 0,47 2.04 +00 1.00E+00
FILTERABLE PM<2.5 MICRONS(PMzs) 0.12 0.08 0.12 0.51 0.12 0.51E-01 2.50E-01
SULFUR DIOXIDE(SO,) 0,09 0.07 0.09 0,41 0.09 0.41E-01 1.99E-01
NITROGEN OXIDES(NOS 9.33 6.73 9.33 40.88 9.33 40.88 +01 2.00E+01
CARBON MONOXIDE CO 233 1,68 2.33 10.22 2.33 10.22 +00 5.00E+00
VOLATILE ORGANIC COMPOUNDS OC 0.09 0,07 0.D9 0.41 0.09 0.41E-01 2.00E-01
LEAD 0.00 0.00 0.00 0.00 0.00 0.00E-03 1.28E-03
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
CAB I.RER hass I Learil 19Eftl1E NMaW I Llshil NAERCCNhaX.S I Loan) Ibl1 D' a
TOXIC I HAZARDOUS MR POLLUTANT NUMBER I", avy, We Il i"r live Wnrelled
Antiinoriy Unlisted Corn unm H SK-Other 00E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E*00 0.00E+00
Arsenic Umatea Corn n" TH ASC-0Iner 2.6E-04 3.8E-01 26E-04 2.3E+00 2.6E-04 2.3E+00 5.60E-04 5.50E-04
Benzene TH 71432 1.3E-03 1.9E+00 1.3E-03 1.1E+01 1.3E-03 1.1E+01 2.75E-03 2.75E-03
Be Ilium usual unrefined TH 744041/ 2.0E-04 2.8E-01 2.0E-04 1.7E+00 2.0E-04 1.7E+00 4.20E.04 4.20E-04
Cadlun Meth elemenLl unreanad TN 7440439 20E-04 2.8E-01 2.0E-04 1.7E+00 2.0E-04 1.7E+DO 4 20E-04 4.20E-04
Chromic Acid VI TH 7738945 20E-04 2.8E-01 2.0E-04 1 7E+00 2 OE-04 1.7E+00 4 20E-04 4 20E-04
Cohan UnlNtad Can mks H cl c-Omer 0.0E+00 0.0E+00 O.0E+00 0.0E+00 0DE+00 0.0E+00 0.00E+00 0.00E+00
Etn benzene R 100414 3.8E-04 55E-01 3.8E-04 3.3E+00 3.8E-04 3.3E+00 8.17E-04 8.17E-04
Flucndea(win nuon"com oun" T 18984408 1.7E-02 2.5E+01 1.7E-02 1.5E+02 1.7E-02 1.5E+02 3.73E-02 3.73E-02
Fonnsidan Ea TH 50000 2.2E-02 3.2E+01 2.2E-02 2.0E+02 2.2E-02 2-OE+02 4.80E-02 4.80E-02
Lead Unlefud Can nil N PBc-0tha 5.9E-04 8.5E-01 5.9E-04 5.2E+00 5.9E.04 5 2E+001 126E.031 1.28E-03
Manganese Unless!Cam rim TN MNCGher 3.9E-04 5.7E-01 3.9E-04 3.4E+00 39E-04 3.4E+DO 8.40E-04 8.40E-04
Meru .vesper TH 7439975 1 2.0E-04 2.8E-01 2-OE-04 1 7E+00 2.0E-04 1.7E+DO 4.20E-04 4.20E-04
Mail 01bunfohn TH 71588 I 1.1E-04 1.8E-01 1.1E-04 9.6E-01 1.1E-04 9SE-01 2.36E-04 2.38E-04
Na inlana H 91203 1 1.8E-D4 2.2E-01 1.6E-04 1.4E+00 1.8E-04 1.4E+00 3.33E-04 333E-04
Nlcele Metal TH 70002o 2.0E-D4 2.8E-W 2.0E-04 1.7E+00 2DE-04 1.7E+00 4.20E-04 420E-04
Phos horns Mehl.Yonne of W ir, H 7723140 0.0E+00 0.0E+00 O.0E+00 0.0E+00 0.0E+00 O.0E+00 O.00E+OD 0.00E+00
POM rates uncontrolled N POM 1.5E-03 2.2E+00 1.5E-03 1.3E+01 1.5E03 1.3E+01 3.30E-03 3 3DE-03
SHwwrn com aks H SEC 9.8E-04 1.4E+00 9.8E-04 8.8E+00 9.8E-04 8.8E+00 2.10E-03 2.10E-03
Toluene Tii tosm 3.7E-02 5.4E+01 3.7E-02 3.3E+02 I 3.7E-02 3.3E+02 7.97E-02 7.97E-02
X leae TH 133=7 6.5E-04 9.4E-01 6.5E-04 5.7E+00 6.5E-D4 5.7E+00 1.40E-03 1.40E-03
Total ItAP M 87E-02 9.9E+01 a 7E@ S 8E+02 S7E-02 I 5.9E+02 1 1 4E-01 I 1.4E41
Lare•t NAP H 3.nE-02 5.38E+01 3.r2E-el 3.ZBE-W 3.72E-02 3.25E+02 797EV 7WEld
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS I LIMITATIONS EMISSION FACTOR
Ib 10' el
TOXIC AIR POLLUTANT CAB Note Ibrhr Ilvday lWyr uncontrolled eanbmlea
Arsenio UnlisMa com arias TH ASC-0e,ar 2.61E-04 6.27E-03 2.29E+00 5.60E-04 5.60E-04
B4nz«r TH 714sz 1.28E-03 3.08E-02 1.12E+01 2 75E-03 2.75E-03
lium Metal umeaaad Ttf 7441 1 95E-04 4.70E-03 1.72E+00 4.20E-04 4.20E.04
call MMal MMn4nho anreaied TH 74404" 1 96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Soluble rAmmata com unm,as cr.alm VI TH SoICR6 1.96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Fluandes sum it""com uM• 169344" 174E-02 4.18E-01 1.52E+02 3.73E-02 3.73E-02
Fomlelaen TH 51HIX 224E-02 5.3BE-01 1.98E+02 4.80E-02 4.80E-02
Man show Un9Mea Con rids TN MNc-Onas 3.92E-04 941E-03 3.43E+00 8.40E-04 B.40E-04
MMCY 7439978 1.96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Morn cnmrororm Tim 71W 1.10E-04 2.64E-03 9.85E-01 2.36E-04 2.36E-04
Nic9le Meml TN 7440020 1.96E-04 4.70E-03 1 1.72E+00 I 4.20E-04 4.20E-04
toluene TH 109943 3.72E-02 892E-01 3.26E+02 7.97E-02 7.97E-02
x a1m ITH) 13=7 6.54E-04 1.57E-02 5.73E+00 1.40E-03 1.40E-03
SE
- ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit antl EPA
GREENHOUSE OAS EPA MRR CALCULATION METHOD:TIER 1 MRR Emission Factors
POLLUTANT short tons/yr, short tons/yr,
metric tons/r metric tons/r,CO2e short tons/r short tonW CO2e short tonstyr CO2e
CARBON DIOXIDE(CO2) 6,867.33 6,867.33 7,569,93 48.992.73 46,992.73 46,992.73 46,992.73
METHANE(CH4) 2.79E-01 5.85E+00 3.07E-01 1.91E+00 4.00E+01 1.91E+00 4.00E+01
NITROUS OXIDE(N30) I 5.57E-02 1.73E+01 6.14E-02 3,81E-01 1.18E+02 3.81E-01 1.18E+02
TOTAL 6,890.45 TOTAL TOTAL
NOTES. 1)CO2e means CO2 equivalent
2)The DAO Air Emissions Reporting Online(AERO)system requires short tons and the EPA MRR requires metric tons

GAS&DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR REVISION S 6/22/2015-OUTPUT SCREEN
Instructions: Enter emission source I facility data on the"INPUT"tabiscreen. The air emission results and summary of Input data are� �
viewedlprinted on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the Information contained.
NCDENR This spreadsheet is subject to continual revision and updating. it Is your responsibility to be aware of the most current Information available.
DENR is not responsible for errors or omissions that may be contained herein.
COMPANY: Avoca FACILITY ID NO.: 800044
PERMIT NUMBER: 0
EMISSION SOURCE DESCRIP 1ION. 285 HP POWER OUTPUT DIESEL INTERNAL COMBUSTION ENGINE FACILITY CITY: Merry Hill
EMIS I N OUR E ID NO. Fire Pump FACILITY COUNTY: Berne
SPREADSHEET PREPARED BY: ETH POLLUTANT TR LEFF.
ACTUAL THROUGHPUT 521 AL C MBU TED FUEL H TIN VALUE141DO0 BTU/GAL PM 0
REQUESTED ANNUAL LIMITATION 8,760HRS OF OPERATION CALCULATIONS'. 0138 mm BTU/GAL PM10 0
SULFUR CONTENT OF DIE EL FUEL(%) 0 PM2.5 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1'. DEFAULT HIGH HEAT VALUE AND DEFAULT EF S02 0
CARBON CONTENT USED FOR GHGS k CI al. CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN NOX 0
CO 0
VOC 0
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
NFn.WMT'LMI191 IXll.R CO",FOL4LiM1141 I RW TRIX9AIMIT9) Mp-hr
AIR POLLUTANT EMITTED bdtr ton r Ib01r lonstyrlbfnr tons/r ur.rtnIIW
PARTICULATE MATTER PM 0.83 0.01 0.63 275 063 2.75 2.20 -03
PARTICULATE MATTER<70 MICRONS(PM,,) 0.63 0,01 0.63 2.75 063 2.75 220E-03
PARTICULATE MATTER<2.5 MICRONS(PMps) 0.83 0.01 0.63 2.75 0.63 2.75 2.20E-03
SULFUR DIOXIDE SOY 0.00 0,00 0.00 0,02 0.00 0.02 1.21E-05
NITROGEN OXIDES NOx 8.84 0,10 8.84 38,70 8.84 38.70 3.10E-02
CARBON MONOXIDE CO 1.90 0.04 1.90 8,34 1.90 8.34 6.88E-03
VOLATILE ORGANIC COMPOUNDS(VOC) 0.72 0.01 0 72 3.14 0.72 3.14 2.51 E-03
ACTUALEMISSIOMs, POTENTULL EMISSIONS EMISSION FACTOR
`A AF6RC n*.91L 4 I _Yrt41 UFTEPCQVixOL9 AlYli81 IO1llp-11r
TOXIC I HAZARDOUS AIR POLLUTANT NUMB R Ib/hr lb/. lbtyr III lbtyr uncontrouee
Acetaldehyde H, 75070 1.53E-03 563E U2 1 b3c ca 1 34E+01 153E-03 1.34E-01 3 E-06
Acrolem(H, 107028 1.85E-04 680E-03 1.85E-04 162E+00 1.81 162E+00 8.48E-07
Arsenic unlisted compounds H, ASC-081er 7.9BE-06 294E-04 7.98E-08 699E-02 798E 06 699E-02 2.80E-08
Benzene H,T 71432 1.86E-03 685E-02 1.86E-03 1.63E-01 186E 03 163E+01 I 8.53E-06
Benzoa rene H, 50328 375E-07 138E-05 3.75E-07 3.29E-03 3.75E-07 329E-03 1.32E-09
Beryllium metal unreactetl H, 7440417 5.99E-06 2.20E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E-08
1 3-Butadiene H, 108990 7.80E-05 2.87E-03 7.80E-05 6.83E-01 7.80E-05 6.83E-01 2.74E-07
Cadmium metal(elemental unreactetl)(H,T 7440439 5.99E-06 2.20E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E-08
Chromic Add(VI)(HT) 77381 5.99E-06 2.20E-04 5.99E-06 5.24E-02 599E-06 5.24E-02 2.10E-08
Formaldehyde(H,T) 50DOO 2.35E-03 8.67E-02 2.35E-03 1 2.06E+01 2.35E-03 2.06E+01 826E-06
Lead unlisted Compounds H PSC-Other 1.80E-05 6.61E-04 1.80E-05 1 57E-01 1 BOE-05 1.57E-01 6.30E-08
Manganese unlisted Compounds H, MNC-Other 1.20E-05 4.41E-04 1.20E-05 1.05E-01 1.20E-05 1.05E-01 4.20E-08
Mercury vapor H,T 7439976 5.99E-06 220E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E.08
Na thalene H 91203 1.69E-04 623E-03 1 69E-04 148E+00 169E-04 1,48E+00 5.94E-07
Nickel metal H, 744DO20 5.99E-06 220E-04 599E-06 5.24E-02 5.99E-06 I 5.24E-02 I 2.10E-DB
Selenium Compounds H SEC 2.99E-05 1 lOE-03 2.99E-05 2.62E-01 2.99E-05 2.62E-01 1.05E-07
Toluene 1108883 8.16E-04 3.00E-02 8.16E-04 7.15E+00 8.16E-04 7.15E+DO 2.88E-IS
X lane H, 1339207 589E-04 2.09E-02 5.69E-04 4.98E+00 5.89E-04 4.98E+1X) 2.00E-0fi
Highest HAP(Formaldehyde) 50000 2.35E-03 8.67E-02 2.35E-03 2.06E+01 235E-03 2.06E+01 I 8.26E-06
Total HAPS I I 7.66E-03 282E-01 1 766E-03 871E+01 7.86E-03 16,71E+01
�IIONIFOR
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS EMISSION FACTOR
dhp-hr
TOXIC AIR POLLUTANT CAS Num. Whir lb/day lbtyr uncontrolled
Acetaidetl de H, 75070 1.53E-03 367E-02 1.34E+01 5.37E-06
Acrolein H, 107028 1.85E-04 4.43E-03 1.62E+0O 6.48E-07
Arsenic unlisted Compounds H,T ASC-Other 7.98E-06 1.92E-04 6.99E-02 2.80E-08
Benzene H,T 71432 1.811 4.47E-02 1 63E+01 6.53E-06
Benzo(a)p rene H,T 50328 3.75E07 9,00E-06 3.29E-03 1.32E-09
Beryllium metal unreactetl) H,T 7440417 5.99E-06 144E-04 524E-02 2.10E-08
1,3-Butadiene H, 106990 7.80E-05 1.87E-03 6.83E-01 2.74E-07
Cadmium metal(elemental unreactetl)(H,T) 7440439 5.99E-06 1.44E-04 524E-02 2.10E-08
soluble chromate Compounds.as chromium VI equivalent SOLCR6 5.99E-06 1.44E-04 5.24E-02 2.10E-08
Formaldehyde H,T) 50000 2.35E-03 565E-02 2.06E+01 8.28E-06
Manganese unlisted Compounds H,T MNC-0Mer 1.20E-05 2.87E-04 1.05E-01 4.20E-08
Mercury vapor H,T) 7439976 5.99E-06 1.44E-04 5.24E-02 2.10E-08
Nickel metal H,T) 7440020 5.99E-06 1.44E-D4 524E-02 2.10E-08
Toluene H, '08883 816E-04 1.98E-02 7.15E+00 2.86E-06
X lane H, r,5P1 n4 1.38E-02 4BBE+00 2DOE-06
'SIN CRY. •CW4
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat input
capacity or horsepower and EPA MRR Emission Requested Emission Limitation-utilze
Factors requested fuel lima and EPA MRR
GREENHOUSE GAS EMITTED EPA MRR CALCULATION METHOD:TIER 1 Emission Factors
metric tonstyr metric tonstyr.CO2e short tonstyr short ton r short tori CO2e short tonslyr short tonslyr,CO2e
CARBON DIOXIDE(CO,) 5.32 5.32 5.88 1,424.78 1,424.78 1,424.78 1,424.78
METHANE(CHM) 2.16E-04 5.39E-D3 2.38E-04 5.78E-02 1.44E+00 5.78E-02 1.44E+00
NITROUS OXIDE 1 4,31 E-05 1.29E-02 4.76E-05 1.16E-02 3.44E+00 1.18E-02 3.44E-00
TOTALI 5.34 TOTAL 1429.67 TOTAL 1,429.67
NOTE: CO2e means CO2 equivalent.
NOTE: The DAQ Air Emissions Repomng Online(AERO)system requires short tons be reported The EPA MRR requires metric tons be reported
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
Insnictions Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual-fuel(diesegnatural gas)engines
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
User Input DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name. Hal ISE eempeny guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision
Plant County dalahe and updating. It is your responsibility to be aware of the most current information available. DENR
Plans City. Ralsigh E/Y er7(!) is not responsible for ertors or omissions that may be contained herein.
Permit Number: -NA7 L
User -*41eb C-&Yv v'K*r-s
Fuel Sulfur Fuel Input Rates Diesel trail Ng cu tl Heat Input Rates Diesel N�
Diesel Fuel Sulfur Content(%). 0.00 Hourly Fuel Usage: 80.00 Hourly Fuel Usage (mmBtu): 11.28 0.00
NG Fuel Sulfur Content( r/mm cu ft): 2,000 Annual Fuel Usage: 1,943 Annual Fuel Usage (mmBtu): 274 0
Fuel Heat Content: 141,000 (BlWgal for diesel,Slid=h for NG
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant Ib/hr UrnmEltu Retina Pollutant Ib/hr blvir toy (IbtmmBtul Rate to
PM 1.13 27,39 0.01 100E-01 B PM NA NA NA NO NA
PM-10 1.13 27.39 0.01 100E-01 B PM-10 NA NA NA NO NA
PM-2.5 1.13 27.39 0.01 100E-01 B PM-2.5 NA NA NA ND NA
NO,,uncont 36.10 876,46 0.44 320E+00 B NO.,uncora. 30.46 739.51 0.37 2.70E+00 D
NO,cant 21.43 520.40 0.26 1 90E+00 B NO.,corn. NA NA NA NO NA
OC(as CH4) 1.02 24,65 0.01 9.00E-02 C TOC(as CH,) 9.02 219.11 0,11 8.00E-01 D
NMTOC 0.92 22A3 0.01 8.19E-02 E NMTOC 2.26 54,78 0,03 2.00E-01 E
CO 9,59 232.81 0.12 8.50E-01 C CO 13.08 317.72 0,16 1.16E+00 D
SO, 0.02 0.41 0,00 152E-03 B SO, 0.001 0.041 0.00 131E-04 B
Total HAP 1.98E-02 4.80E-01 2.40E-04 1.75E-03 NA
Lansaw HAP benzene 8.75E-03 2.13E-01 1.06E-04 7.76E-04 NA
Toxic/Hazardous Air Pollutants There arc no ToxiclHazardous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number b fhr lb/dayIll
Acetaldehyde 75070 2.84E-04 6.82E-03 6.90E-03 2.52E-05 E
Acro ion 107028 8.89E-05 2.13E-03 2.16E-03 7 BSE-06 E
Arsenic unlisted compounds ASC-Other 4.51E-05 1.08E-03 1.10E-03 400E-06 E
Benzene 71432 8.75E-03 2.10E-01 2.13E-01 7 76E-04 E
Benzo(a)pyreme 5=8 2.90E-06 6.96E-05 7.04E-05 2.57E-07 E.<
Beryllium metal(unreacled) 7440417 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Chromic Acid(VI) 7738945 3.38E-05 8.12E-04 822E-34 3.00E-06 E
Formaldehyde 50000 8.90E-04 2.14E-02 2.16E-02 7 89E-05 E
Lead unlisted compounds PBC-0ther 1.02E-04 2.44E-03 247E-03 900E-06 E
Manganese unlisted compounds MNCOther 6.77E-05 1.62E-03 1.84E-0;i 6.00E-06 E
Mercury vapor 7439976 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Napmalene 91203 1 47E-03 3.52E-02 3 56E-02 1.30E-04 E
Nickel metal 7440020 3.38E-05 8.12E-04 8.22E-04 300E-06 E
Selenium compounds SEC 1.69E-04 4.06E-03 411E-03 150E-05 E
Total PAH 2.39E-03 5.74E-02 581E-02 212E-04 E.
Toluene 108803 3.17E-03 7.61E-02 7.70E-02 2.81E-04 E
X nes 1330207 1 2.18E-03 5.22E-02 5.29E-02 1.93E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandato Re rtin Rule Factor Quality but not with EPA Mandato Reporting Rule Factor Quality
Pollutant Ib/mmBtu RatingPollutant IbM I UmmBtu Rail
Carbon Dioxide(CO2) 44.177.70 22,09 43.99 NA Carbon Dioxide(CO2) 44,177.70 22.09 43.99 NA
Methane(CH,) 60.39 0.03 0.009 NA Methane(CH4) 3,699.09 1,85 0.540 NA
Nitrous Oxide(NzO) 107.98 0,05 0 001 NA Nitrp.is Oxide(NzO) 107.98 0.05 0.001 NA
44,346.07 22.17 47,954.77 23.99
f1o0s:Do riot use grieuiticese gas emission estimates from this s rwdshast for PSO finvanaan of S'ni cant Deterioration)purposes.
NO,control is via ignition timing retard
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other toxiclhazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"r'indicate an AP42 emission factor based on test results being below detection.
Emission factors for criteria pollutants are from AP42 Chapter 3 4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10195).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP42 Chapter 1.3,Fuel Oil Combustion(revised 5110).
All other toxiGhazardous pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96). -
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines'.Stationary Combustion Sources,June 2008,except for CH4,
which uses AP42,Chapter 3 4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP42 Chapter 3.4,p.3.4-5(revised 10/96),
Hourly emission rates for all pollutants are based on the hourly fuel usage Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours

Large Diesel and All Dual-Fuel Engines Emissions Calculator LG02012 Revision J-06/22/2015
Insructors.Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual fuel(dieseVnatural gas)engines.
Please note that,when used in conjuinct on with permit applications,any value entered far annual operations of these engines may become a permit limit.
User Input DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca PKGEN Engine guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision
Plant County Battle and updating. It is your responsibility to be aware of the most current information available.DENR
Plant City Merry Hill is not responsible for errors or omissions that may be contained herein.
Penult Number
User E Huddleston
Fuel Sulfur Fuel Input Rates Diesel fi ll N cu ftj Heat Input Rates Diesel NQ
Diesel Fuel Sulfur Consent(%): 0.00 Hourly Fuel Usage. 72.00 Hourly Fuel Usage (mmBtu): 10.15 0.00
NG Fuel Sulfur Content(gr/mm cu ft)- 2,000 Annual Fuel Usage: 5,122 Annual Fuel Usage (mmBtu): 722 0
Fuel Heal Content: 141,000 (BUgal far diesel,Btu cu.It far NG
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant lhfhr byr tDv iltiffirml Rana Pollutant Whir lt)dyr t IWmmBtu Rating
PM 1.02 72.22 0,04 100E-01 B PM NA NA NA NO NA
PM-10 1.02 72.22 0.04 100E-01 B PM-10 NA NA NA NO NA
PM-2.5 1.02 72.22 0.04 1 DOE-01 B PM-2.5 NA NA NA NO NA
NO.,uncont. 32.49 2,311.05 1.16 3.20E+00 B NOx,unoont. 27.41 1,949.95 0.97 2.70E+00 D
Nl cont. 19.29 1,372.18 0.69 1.90E+00 B NO.,Cont. NA NA NA NO NA
TOC(as CH,) 0.91 65.00 0.03 9.00E02 C TOC(as CHs) 8.12 577.76 0,29 8.00E-01 D
NMTOC 0.83 59.15 0.03 8 19E-021 E NMTOC 2.03 144.44 0.07 2.00E-01 E
CO 8.63 613.87 0.31 8.50E-01 C CO 11.78 837.75 0.42 116E+00 D
sox 0.02 1.09 0.00 152E-03 B SO, 0.00 0,09 0.00 1.31E-04 8
Total HAP 1.78E-02 1.27E+W 6.33E-04 1.75E-03 NA
Largest HAP benzene 7.88E-03 5.60E-01 2.80E-04 7.76E-04 NA
Toxic/Huardous Air Pollutants There am no ToxidHa umlous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number I IWhr lb/day IW
Acetaldehyde 75070 2.56E-04 6-14E-03 1.82E-02 2.52E-05 E
Acrolein 107028 8.00E-05 1.92E-03 5.69E-03 7 8BE-06 E
Arsenic unlisted compounds ASC-Other 4.06E-05 9.75E-04 2.89E-03 4 ODE-06 E
Benzene 71432 7.88E-03 1.89E-01 5.60E-01 7 76E-04 E
Benno(a)pyrene 50328 2.61E-06 6.26E-05 1.86E-04 2.57E-07 E.<
Beryllium metal(unreaded) 7440417 3.05E-05 7.31E-04 2.17E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 3.05E-05 7.31E-04 2.17E-03 3.ODE-06 E
Chromic Acid(VI) 7738945 3.05E-05 7.31E-14 2.17E-0:3 3.00E-06 E
Formaldehyde 50000 8.01E-04 1.92E-02 5.70E-02 769E-05 E
Lead unlisted compounds PBC-Other 914E-05 2 19E03 6 50E-03 900E-06 E
Manganese unlisted compounds MNC-Other 6.09E-05 1.46E-03 4.33E-03 6 OOE-06 E
Mercury vapor 7439976 3.05E-05 7.31E-04 2.17E-03 3.00E-06 E
Napmalene 91203 132E-03 3.17E-02 9.39E.02 1.30E-04 E
Nickel metal 7440020 3.05E-05 7.31E-04 2,17E-03 300E-06 E
Selenium compounds SEC 1.52E-04 3.65E-03 1 OBE-02 1 50E-05 E
Total PAH 2.15E-03 5.17E-02 1 53E-01 2 12E-04 E,<
Toluene loom 2.85E-03 6.85E02 2.03E-01 2.81E-04 E
Ixyleners 11330207 1 1.96E-03 4.70E02 1.39E-01 193E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandato Re rb. Rule Factor Qualsy but not with EPA Mandato Revortino Rule Factor Quality
Pollutant Iblyr t IWmir Ratina Pollutant IWhr IW t m/mmetu Rating
Carbon Dioxide(CO2) 116,488.11 58.24 43.99 NA Carbon Dioxide(CO2) 116,488.11 58.24 43.99 NA
Methane(CH4) 159.25 0,08 0.009 NA Methane(CHs) 9,753.79 4.88 0.540 NA
Ntrous Oxide(N2O) 254-73 0.14 0 001 NA Nitrous Oxide(N2O) 284.73 0.14 0.001 NA
116.932,09 58.47 126,526.63 63.26
lbta: Do rat uaa raaMwaa m amusb s bit s from Mu sp> shM for PSD(Pnvandon of S-ndunt p norauon)pu s .
NO,control is via ignition timing retard.
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other loxicJhazerdous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"<"indicate an AP42 emission factor based on test results being below detection.
Emission factors for onteria pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP42 Chapter 1.3,Fuel Oil Combustion(revised 5110).
All other loxidhazardous pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines.Stationary Combustion Sources,June 2008,except far CH4,
which uses AP42,Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 96%natural gas and 5%diesel,per AP42 Chapter 3.4,p.3 4-5(revised 10/96).
Hourly emission rates far all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours.

WOODWASTE COMBUSTION EMISSIONS CALCULATOR REVISION K 03/08/2017-OUTPUT SCREEN
�� Instructions: Enter emission source I facility data on the"INPUT•'tab/screen. The air emission results and summary of
input data are viewed I printed on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the
NCDENR Information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware
of the most current information available. DENR is not responsible for errom or omissions that may be contained herein.
COMPANY: AVOCB FACILITY ID NO.: 8000"
PERMIT NUMBER. 0
EMISSION SOURCE DESCRIPTION' 48 MM8TU/HR BARK AND WET WOOD FIRED BOILER FACILITY CITY. Merry Hill
EMISSION SOURCE ID NO.: Wood Balers FACILITY COUNTY. Bertie
PARTICULATE CONTROL DEVICE: FABRIC FILTER POLLUTANT CONTROL EFF.
SPREADSHEET PREPARED BY. E Huddleston FUEL HEAT VALUE: 4000 BTU/LB NOX 0
ACTUAL FUEL THROUGHPUT. 25211 TON/YR HHV Used for GHGs MMBTU/TON: 15.38 PM CALCO AS 25.9%
POTENTIAL FUEL THROUGHPUT: 52560 TON/YR IBOILER TYPE: STOKER PM10 CALCO AS 24.9% -
REQUESTED MAX.FUEL THRPT: 52560 TON/YR ITEST DATA USED:0.0014 LB(MMBTU FPM PM2.5 CALC'D AS 22.2%
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS AS A FRACTION): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
Wren wamaarLaxrsl WF9r1EC9a WILWSI W Rcpa ,uio m) INmmefu
AIR POLLUTANT EMITTED Ib1hr tons/yr Ib1hr tons/rr28.80
Whirtons) unwmrallm wet llad
PARTICULATE MATTER PM 0.88 1.86 1.19 5.22 3.87 0.025 0.018
PARTICULATE MATTER<10 MICRONS(PM10) 0.87 1.82 1.15 E05 3.79 0.024 0.018
PARTICULATE MATTER<2.5 MICRONS(PM2s) 0.86 1.81 1.10 4.84 3,77 0.023 0.018
SULFUR DIOXIDE S02 1.20 2.52 1.20 5.26 5.26 0.025 0.025
NITROGEN OXIDES NOx 10.56 22.19 10.56 46.25 46.25 0,220 0.220
CARBON MONOXIDE CO 28.80 60.51 28.80 126.14 12614 0.600 0,600VOLATILE ORGANIC COMPOUNDS VOC 0.82 1.71 0.82 3.57 3.57 0.017 0.017LEAD 2.3E-03 4.8E-03 2.3E-03 1 OE-02 1.0E-02 4.8E-05 4.8E-05
ACTUAL EMISSIONS7P,0,T.-T-POTENTIAL EMSSIONS EMISSION FACTOR
CAS WIERCO MSILYRa1SILwITS1 (4.R."0.e ILMn IWmmSN ���J, '0 (N•,
TOXIC/HAZARDOUS Apt POLLUTANT NUMBER lamr Ib/r IbR1r lb/r unwMrolled/wnb011ed
Acetaldehyde H 75070 3.90E-02 167.402348.998 3.98E-02 348.998 8.30E-W B.WE-o4
Aceto hemrie H 98852 1.54E-07 6.45E-041.35E-03 1.54E-07 1.35E-03 3.20E-09 3.20E-09
Acrolein H 107028 1.92E-01 806.7581681.920 1.92E-01 1681.920 000E-03 4.00E-03Antimon unlsiw Com unds wet nem of sac SW-tuner 3.79E-04 1.5933.322 3.79E-04 3,322 7.90E-09 7.90E-06Amenc UmIWW Communds(wmWnenl ofASC)(TH) ASC-ether 1.06E-03 4.4379.251 1.06E-03 S251 220E-06 220E-05 64 JyV
Benzene H 71432 2.02E-01 847.096 2.02E-01 1766.016 2.02E-01 1766.016 4.20E-03 4.20E-03
Benzo(a)p ne 50328 1.25E-04 -0.524 1.25E-04 1.093 1.25E-04 1,093 2.60E-W z.e0E-06
Be Iium Metal(unreadm) wet nem of BEC IH 7N0417 5.28E-05 0.222 5.28E-05 0.463 5.28E-05 0.463 1.10E.06 1.10E-OS �.�JLA)7-�-'
admium Metal(unmarred wet nem of CDC /H 7440439 1.97E-04 0.827 1.97E-04 1.724 1 97E-04 1.724 4.10E-08 4.10E-08 Ra ?E-3
Icon tetmchlome(TH) 58235 2.16E-03 9,076 2.16E-03 18.922 2.16E-03 18.922 4.50E-05 4SCE-o5
Chlorine il 77s25a5 3.79E-02 159.335 3.79E-02 332.179 3.79E-02 332.179 7.90E-D4 7.90E-04
CBlorobenzane H 108907 1.58E-03 6.656 1.58E-03 13.876 1.58E-03 13.876 3.30E.05 3.30E-05
Cmorot9ml 87663 1.34E-03 5.647 1.34E-03 11.773 1.34E-03 11.773 2ACE-05 I 2eoE-05
Chromium Unlisted Cm H ado w/carom and to get CRC CROotner 8.40E-04 3.530 8.40E-04 7.358 8.40E-04 7.358 1.75E-05 175E-05
Chromic acid M(aimponent of solCRe and CRC /H 773e945 1.68E-04 0.706 1.6BE-04 1,472 1.68E-04 1.472 3.50E-OB 3.50E.06
Ooealt Unlisted Compoums(wmponem of CDC)(H) CDC-other 3.12E-04 1,311 3.12E-04 2.733 3.12E-04 2,733 6.50E-05 650E-06 f�.0✓I3
Dinbo henol,2.4- H 61285 8.64E-06 3.63E-02 8.64E-06 0.076 8.64E-08 0.076 1.60E-07 1.80E-07
Di 2-eth he phthalate EH H 117817 226E-06 9.48E-03 2.26E-06 1.98E-02 2.26E-06 1.98E-02 4.70E.08 470E-W
Eth benzene(H) 100414 1 49E-03 6.252 1 49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Eth enedchlonde 1,2Eichlomethane 107002 1.39E-03 5.849 1.39E-03 12.194 1.39E-03 12,194 2.90E.05 2.90E-05
Formaldehyde H - 50000 2.11E-01 887.434 2.11E-01 1850.112 2.11E-01 1850,112 4.40E.03 4.40E-03
-Hwachlom0lbenzo- ban 1,2,3,8,7,5 M 57653857 1.53E-09 6.41E-06 1.53E-09 1.34E-05 1.53E-09 1.34E-05 3.18E.11 3.18E.11
Hydrogen chloride(hydrocnlorc acid 7847010 9.12E-01 9.12E-01 7989.120 9.12E-01 7989,120 1.80E-02 1.90E-02
Lead Unlisted Co ums(winponem of Pec PBC-other 2.30E-03 9.681 2.30E-03 20.183 2.30E-03 20.183 4.80E-05 4.80E-05 0,0 9(+P
n anmunwed Com ums wmwnenlof MNC H MNC-ether 768E-02 322.703 7.68E-02 672.768 7.68E-02 672.768 1.80E-03 1.60E-03 �I-Z-L
rou ,ve r wmponent of HGC M) 7439978 1.68E-04 04 1,472 1.68E-04 1.472 3.SOEW 3.50E-0e
Main bmmde H) bmmomethane 74e39 7.20E-04 3.025 7.20E-04 6.307 7.20E-04 6.307 150E-05 1.50E-05
Why!wlonde H chlommethane 74a73 1.10E-03 4.639 1.10E-03 9.671 1.10E-03 9.671 2.30E-05 2.30E-05
Wthlil wlomMan H (1.1,1 mcnlomethane) 71558 1.49E-03 6,252 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 310E-05
Methyl Myl ketone 78933 2.59E-04 1,089 2.59E-04 2,271 2.59E-04 2.271 5.40E-08 5.40E-06
Methylene chlome(TH)(dbhlommethane) 75092 1.39E-02 58.490 1.39E-02 121.939 1.39E02 121,939 2.90E-04 290E-04
Naphthalene(H) 91203 4.66E-03- 19.%4 4.66E-03 40.787 466E-03 40.787 9.70E-05 9,70E-05
Nickel metal Component of 373024MIC M 7440020 1.58E-03 6.656 1.58E-03 13.876 1.58E-03 13.876 3.30E-05 3.30E.05
Nero nenol,4-H 103027 5.28E-06 2.22E-02 5.28E-06 4.63E-02 5.28E-06 4.63E-02 1.10E-07 1.10E-07
Pentachlom henol H 87865 2.45E-06 1.03E-02 2.45E-06 2.14E-02 245E-06 2.14E-02 5.10E-Oe S.ioE-0s
Perwloroeth ene chlometh ene H 127184 1.82E-03 7,664 1.82E-03 15.978 1.82E-03 15.978 3.60E-05 3.80E-05
Phanom H 105952 2.45E-03 10.286 2.45E-03 21.444 2.45E-03 21.444 5.10E-05 5n OE-05
Phosphorus Metal.Yellow or while 7723140 1.30E-03 5.446 1.30E-03 11.353 1.30E-03 11.353 2.70E-05 2.7or-as 6L OS 4
Polycnionnated biphenNs(TM 1336353 3.91E-07 1.64E-03 3.91E-07 343E-03 3.91E-07 3.43E-03 315E-W 8.15E.09
Pot he Organic Minter POMTV 6.00E-03 25.211 6.00E-03 52.560 8.00E-03 62.660 125E-04 125E-04
Pmpbnalden a(H) 123386 2.93E-03 12.303 2.93E-03 25.649 2.93E-03 25.649 8.10E-o5 BAOE-05
Pro ene dichloride H 12 dbnloro roper) 75875 1.58E-03 6.656 1.58E03 13.876 1.SBE-03 13.876 3.30E-05 3.30E-05
Selenium wet unds H SEC 1.34E-04 0,565 1.34E-04 1.177 1.34E-04 1.177 2.80E.09 2.80E-011 5" y
Styrene 100425 9.12E-02 383.210 9.12E-02 798,912 9.12E-02 798.912 1.90E-03 1.80E-03
Telrawlorwibenzo- ban,2.3,7,o- H 174s01e 4.13E-10 1.73E-06 4.13E-10 3.62E-06 4.13E-10 3.62E-06 BADE-12 3SOE-12
aluane H lDS883 4.42E-02 185.554 4.42E-02 386,842 4.42E-02 306.042 9.20E-04 820E-04
Twhloroeth ene 79016 1.44E-03 6.051 1.44E-03 12.614 1.44E-03 12.614 3.00E-05 3.WE-05
Trbnlom8uommethane CFC 111 75694 1.97E-03 8.269 1.97E-03 17.240 1.97E-03 17.240 4.10E-05 4.10E-05
Tnchloro henol,2.4,6 ) $8062 1.06E-06 4.44E-03 1.06E-06 9.25E-03 1.06E-06 925E-03 2.20E-08 220E-0
Vinyl chloride 75014 8.64E-04 3.630 8.64E-04 7.569 8.64E-04 7.569 1.80E-05 180E-05
/X ene H 1330207 1.20E-03 5.042 1.20E-03 10.512 1.20E-03 10.512 2.50E.05 2.50E-05
Highest HAP(Hydmilen cmome(hydimcniore acid H) 7a470t0 I 9.12E-01 1 3832.102 9.12E-01 1 7989.1 9.12E-01 1 7989.1 1 180E-o2 I 180E-02
•Total HAIRS INA I 1.86E+00 I 7.83E+03 1.86E+00 I 1.63E+D4 1.86E+00 I 1.63E+04 3.88E-02 I 3.BBE-02

EXPECTED ACTUAL EMISSIONS LIFTER CONTROLS/LIMITATIONS(FOR PERMITTING PURPOSES) EMISSION FACTOR
INmmBtu
TOXIC AIR POLLUTANT CAS Num. INhr lb/day lby uncontrollae wntmlled
Acelaloen a 750M 3.98E-02 9.56E-01 348.998 8.30E-04 8.30E-a
AcroleN H 107025 1.92E-01 4.61E+00 1681.920 4.00E-03 4.00E-03
Arsenic Unlisted Compounds(wintionent of ASC ASC-other 1.06E-03 2.53E-02 9.251 210E-05 210E-05
Benzene 71432 2.02E-01 4.84E+00 1766,016 4.20E-03 410E43
Benzo a ne M 50328 1.25E-04 3.00E-03 1.093 2.80E-08 2.80E-OB
Beryllium Metal unneeded)(wmponent of BEC IH 7440417 5.28E-05 1.27E-03 0A63 1.10E-08 1.10E-06
Cadmium Metal unmaded)(wmpanera of CDC)(T8Q - 7440439 1.97E-04 472E-03 1.724 4.10E-0B 4.10E-06
Carton tetrachloride H 56235 2.16E-03 5.18E-02 18.922 4.50E-05 4.50E-05
Chlorine 7782505 3.79E-02 9.10E-01 332.179 7.90E-04 7.90E-04
Chlombenzene H) 108907 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E.05
Chloroform H 07063 1.34E-03 3.23E-02 11.773 2.80E-05 2.80E-05
Di(2-eta ne alate EHP) H 117817 2.26E-06 5.41E-05 1.91 470E.08 4.70E-08
Ethylene dichlonda If 24ichlarestnane H 107062 1.39E-03 3.34E-02 12.194 2.90E-05 2.90E-05
Soluble Chmmate Cm s,as Chrome SOLCRB 1.66E-04 4.03E-03 1,472 3.50E+8 3.50E-08
Fonnamen 0 501100 2.11E-01 5.07E+00 1850.112 440E-03 4.40E03
Hexadllorodibenzo- mxn 12,3,6,7,8 M 57653857 1.53E09 3.66E-08 0.000 3.18E-11 3ABE-11
hydrogen Monde(hydrochloric acu)(TH) 7047010 9.12E-01 2.19E+01 7989,120 1.90E-02 150E-02
Manganese Unleted Compounds(aimpinent of MNC)(TI9 ANC-other 268E-02 1.84E+00 672.768 1SOE-03 1SOE-03
Mercury,va r(aimponent of HGC) M 7439976 1.68E-04 4.03E-03 1.472 3.50E+8 3.50E-06
Methyl chlomform 1,1,1 trichmroethene 71556 1.49E-03 3.57E-02 13.035 3.10E-05 3.10E-05
Mel My ketone(T) 75933 2.59E-04 622E-03 2.271 5.40E-08 5.40E-05
Meltr ens chlarde H)dichlommelnane 75092 1.39E-02 3.34E-01 121.939 290E-04 2.90E-04
Nickel mate)(Component of 373024/NIC M 7440020 1.58E-03 3.80E-02 13.876 3.30E.05 3.30E-05
Pentschlomphenol H) 87885 2.45E-06 5.88E-05 0,021 510E-08 5.10E-08
Pemnlomem ene teeachlometh ene H 127184 1.82E-03 4.38E-02 15.978 340E-05 380E-05
Phenal 108952 2.45E-03 5.SBE-02 21.444 5.10E-06 5.10E-05
Poi manned biphenyls(11) 133e383 3.91E-07 9.39E-06 3.43E-03 8.15E-09 6.15E-09
Styrene H 100425 9.12E-02 I 2.19E+00 798.912 1.90E-03 1.90E-03
Tetracnlimdebnzo-pdmtln,23,7,8- 1746010 4.13E-10 9.91E-09 3.62E-06 B.SOE-12 8.90E-12
Toluene H 108883 4.42E-02 1.06E+00 386.842 e20E-04 820E-04
Trichlometn ene H 79018 1.44E-03 3.46E-02 12.614 3.00E-05 3.00E.05
Tdchlomfluommethane CFC 111 75ON 1.97E-03 4.72E-02 17.240 4.10E-05 4.10E-05
Vm Mlorde 75014 8.64E-04 2.07E-02 T569 1.BOE05 1.80E-05
Xylene(TH) 1330207 1.20E-03 2.88E-02 10.512 2.50E-05 2.50E-05
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit and EPA
MRR Emission Factors
EPA MRR CALCULATION METHOD:TIER 1
GREENHOUSE GAS metric tons/yr, short tons/yr,
metric tonstyr CO2e short tons r short tonstyr short tons/ r,CO2e short tonW CO2e
CARBON DIOXIDE(CO2)
BIOGENIC EMISSIONS' 3637079 zero 40,091,88 43,476.24 zero' 43476.24 zero'
METHANE CH4 2.79E+00 6.98E+01 3.08E+00 3.34E+00 8.34E+01 3.34E+00 8.34E+01
NITROUS OXIDE N20 1.40E+00 I 4.16E+02 I 1.54E+00 1.67E+00 4.97E+02 1.67E+00 4.97E+02
TOTAL
485.77 TOTAL 580.67 TOTAL 580.67
BIOGENIC CO2 has 0 CO2e NOTE.The DAO Air Emissions Reporting Online(AERO)system requires short tons
NOTE: CO29 means CO2 equivalent The EPA MRR requires metric tons
Note:Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Si nificzi Deterioration)purposes.

Huddleston, Betsy
From: [e-mail]
Sent: Tuesday, March 28, 2017 1:54 PM
Subject: Inventory submission confirmation -- 0800044
Dear Brian Conner
Your submittal of the 2016 emission inventory for Avoca Incorporated,0800044, has been received by the North
Carolina Division of Air Quality (DAQ) on March 28, 2017 at 13:53:18.You have until the due date of the emission
inventory or two weeks from this submittal to review and repudiate the data submitted.
Please remember to:
-print the Certification Form (see AERO Closeout page),
- have the Responsible Official sign it in blue ink,
-include copies of spreadsheets or calculations used in creating this inventory, and
- mail (postmark) it to NCDAQ, 943 Washington Square Mall,Washington, NC 27889 by the required due date in order
for this submittal to be considered complete. If you have any questions, please feel free to contact Betsy Huddleston, in
the Washington Regional Office, at252-946-6481.
'The Division of Air Quality thanks you for using AERO,the on line emissions inventory program.
Sincerely
DAQ
i ,
1

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president, secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship; a general partner or the proprietor,respectively;
3.for a muncipality, state,federal, or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION
(Important- Legally
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report, including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Si tune Below use blue ink): Date Signed:
Printed Name: Davi ele
Signature: ,,-71
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
i
Email address of Responsible Official: David.Peele@avocainc,com
MAR 3 1
Information on this Form cannot be held confidential _
COPY of RECORD Date Submitted: 3/28/2017 13:53:18 1

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Listing of Emission Sources and Control Devices on Permit. See instructions
DES ID on Air Permit DES Description CS 1D GCS Description CD ID's
One distillation column one(1)jet ejector
(6 gallons per minute venturi—type wet
A-2.16A nominal process rate) CS-1 scrubber(10 GPM CD—M-34
[MACT FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
one condenser(ID No.
C-3001 One centrifuge [PSD] CS-11 CD-3001)installed on CD-3001
centrifuge,reactor and
heat exchanger/dryer
C-3002 One centrifuge [PSD]
C-31203 One centrifuge [MACT
FFFF]
C-4001 One centrifuge [PSD,
MACT FFFF]
One(1)water spray
fume scrubber used in
the EVG Operation
One steam—heated dryer (batch flavorant
D-1201 [MACT FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorant process)
one(1)jet ejector
One steam—heated dryer venturi—type wet
D-1202 with condenser[MACT CS—I scrubber(10 GPM CD—M-34
FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
One(1)water spray
fume scrubber used in
the EVG Operation
One reactor[MACT (batch flavorant
D-1215 FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorantprocess)
D-1218 One reactor[MACT CS-7 I One(1)water spray CD—Z-9215,CD—Z-9216
2

FFFF] fume scrubber used in
the EVG Operation
(batch flavorant
process),One(1)
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorantprocess)
one(1)jet ejector
One batch reactor venturi—type wet
D-1231A.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
One batch reactor venturi—type wet
D-1231B.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide O s.
One(1)water spray
fume scrubber used in
the EVG Operation
One reactor[MACT (batch flavorant
D-2202 FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorant process)
One steam—heated dryer one condenser(ID No.
D-3001 equipped with a chilled CS-11 CD-3001)installed on CD-3001
water process condenser centrifuge,reactor and
(EX-3002) [PSD] heat exchanger/dryer
One steam—heated dryer
D-3002 equipped with a chilled
water process condenser
(EX-3006) [PSD]
One dryer with process
D-4001 condenser(EX-4004)
[PSD,MACT FFFF]
One waste solids
D31211 separator vessel(1,333
gallon capacity) [MACT
FFFF]
D31214 One product extract
reactor MACT FFFF
One No. 2 fuel oil—fired
emergency generator
E 101 (587 horsepower
maximum rated power
,output) [MACT ZZZZ]
E 102 One No. 2 fuel oil—fired
emergency generator
(760 horsepower
3

maximum rated power
output) MACT ZZZZ]
One No. 2 fuel oil—fired
emergency generator
E 103 (603 horsepower
maximum rated power
output) MACT ZZZZ]
One No. 2 fuel oil—fired
emergency generator
E104 (401 horsepower
maximum rated power
output) MACT ZZZZ]
Chilled Water—Cooled
Condenser,Packed
ES-1001-1-1—F Process equipment leaks CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Arwn process tank M-1 Condenser,Packed
Tower Scrubber(10
� '
ES-1001-1-1—P1 [PSD CAM MACT CS-17 CD-31209 CD-1001-2-5-1
FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Stripper T-5 and Condenser,Packed
ES-1001-1-1—P2 receiver M-21 [PSD CS-17 Tower Scrubber(10 CD-31209 CD-1001-2-5-1
CAM,MACT FFFF] gpm mineral oil '
scrubbing liquid
injection rate),
Seven process tanks of Chilled Water—Cooled
various capacities and Condenser,Packed
ES-1001-1-1—P3 one fixed roof methanol CS-17 Tower Scrubber(10 CD-31209,CD—1001-2—S-1
storage tank(7,050 gpm mineral oil
gallon capacity) [PSD, scrubbing liquid
MACT FFFF] injection rate),
Chilled Water—Cooled
Recovery Operations Condenser,Packed
ES-1001-1-1—WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
Process equipment leaks Tower Scrubber(10
ES-1001-1-2—F [MACT FFFF] CS-17 gpm mineral oil CD-31209,CD-1001-2—S-1
scrubbing liquid
injection rate),
ES-1001-1-2—P Six process tanks of CS-17 Chilled Water—Cooled CD-31209,CD-1001-2—S-1
various capacities [PSD, Condenser,Packed
MACT FFFF] Tower Scrubber(10
gpm mineral oil
4

scrubbing liquid
injection rate),
Chilled Water—Cooled
Concrete Operations Condenser,Packed
ES-1001-1-2—WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
[MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
ES-1001-1-3—Filters Filters [MACT FFFF]
Eleven(11)process
tanks of various
capacities: Hexane
storage tank(M-2)
Process tank(M-4)with
chilled water process
condenser(T-6)
Process tank(M-4A)
with chilled water
process condenser
(T-6A)Receiver tank
(M-39)for M-4/T-6 one(1)jet ejector
Process tank(M-44) venturi—type wet
ES-1001-1-3—P with two chilled water CS-1 scrubber(10 GPM CD—M-34
process condensers injection rate, ID No.
(T-13 and T-15) M-34)Sclareolide Ops.
Receiver tank(M-16)
for T-13 and T-15
Crystallizer tank
(M-15)Tank for cooled
hexane for centrifuge
(M-11)Receiver tank
for dryer condenser
(TK-1210)Process tank
(M-17)Process tank
(M-17A) [MACT
FFFF
one(1)jet ejector
SDE-1 wastewater venturi—type wet
ES-1001-1-3—WW stream[MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
Process equipment leaks venturi—type wet
ES-1001-1-4—F.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide Ops.
one(1)jet ejector
venturi—type wet
ES—1001-1-4—P.16A Four process tanks of various capacities CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide Ops.
ES-1001-1-4—WW.16A SDE Operations CS-1 one(1)jet ejector CD—M-34
wastewater stream venturi—type wet
5

[MACT FFFF] scrubber(10 GPM
injection rate,ID No.
M-34) Sclareolide O s.
Chilled Water-Cooled
ES-1001-11-F Process equipment leaks CS-16 Condenser,Liquid CD-100111EX1002,CD-100111EX1003
[PSD,MACT FFFF] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-1001,desolventizer
Z-1002,day tank 90024
(6,000 gallon capacity),
first-stage evaporator Chilled Water-Cooled
ES-1001-11-P EX-1012,second-stage CS-16 Condenser,Liquid CD-100 11 1EX1002,CD-100111EX1003
evaporator EX-1013, Nitrogen-Cooled
distillation column Condenser,
EX-90008,and nine
process tanks of various
capacities [PSD, CAM,
MACT FFFF
Botanical extraction Chilled Water-Cooled
ES-1001-11-WW operation wastewater CS-16 Condenser,Liquid CD-100 11 1EX1002,CD-100I I1EX1003
stream [PSD,MACT Nitrogen-Cooled
FFFF] Condenser,
Chilled Water-Cooled
Condenser,Packed
ES-1001-2-1-F Process equipment leaks CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5--1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Rotocel extractor, Chilled Water-Cooled
desolventizer,and Condenser,Packed
ES-1001-2-1-PI solvent CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
separation/recovery gpm mineral oil
[PSD,CAM,MACT scrubbing liquid
FFFF] injection rate),
Chilled Water-Cooled
Rotocel Operations Condenser,Packed
ES-1001-2-1-WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-S-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
one(1)jet ejector
SDE-1 process venturi-type wet
ES-1001-3-F equipment leaks CS-1 scrubber(10 GPM CD-M-34
[MACT FFFF] injection rate, ID No.
M-34) Sclareolide O s.
one condenser(ID No.
ES-1003-10-F Process equipment leaks CS-11 CD-3001)installed on CD-3001
[PSD] centrifuge,reactor and
heat exchanger/dryer
ES-1003-10-WW SFG Process wastewater CS-11 one condenser(ID No. CD-3001
stream[PSD] CD-3001)installed on
6

centrifuge,reactor and
heat exchanger/dryer
ES-1003-2-1—F Process equipment leaks
[MACT FFFF]
Seven process tanks of
ES-1003-2-1—P various capacities
MACT FFFF
ES-1003-2-1—WW PNE process wastewater
stream MACT FFFF]
one(1)jet ejector
Process equipment leaks venturi—type wet
ES-1003-2-2—F [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide O s.
one(1)jet ejector
EVG Operation venturi—type wet
ES-1003-2-2—WW wastewater stream CS-1 scrubber(10 GPM CD—M-34
[MACT FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
Chilled Water—Cooled
Condenser,Liquid
ES-1004-1 Biomass extraction CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
debagging [PSD] Condenser,
(CD1004-2EX1002 and
1003)
Chilled Water—Cooled
Condenser,Liquid
ES-1004-2—F Process equipment leaks CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
[PSD] Condenser,
(CD 1004-2EX1002 and
1003)
Immersion extractor
Z-41001,desolventizer
Z-41002,day tank
490025 (9,953 gallon
capacity), isohexane
storage tank 490024 Chilled Water—Cooled
(13,536 gallon Condenser,Liquid
ES-1004-2—P capacity),first stage CS-21 Condenser,
Cooled CD-1004-2EX1002,CD-1004-2EX1003
evaporator EX-41012, r,
second stage evaporator CD1004-2EX1002 an 1
EX-41013,distillation 1003)
column EX-490008,
and nine process tanks
of various capacities
[PSD,CAM]
Chilled Water—Cooled
Biomass extraction Condenser,Liquid
ES-1004-2—WW operation wastewater CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
stream [PSD] Condenser,
(CD1004-2EX1002 and
1003)
7

ES-1004-2Silo Biomass silo loadout CS-23 Bagfilter(254 square CD-1004-2—FF2
feet of filter area),
SDE-2 process
ES-4000—F equipment leaks [PSD,
MACT FFFF]
SDE-2 process
ES-4000—WW wastewater stream
SD,MACT FFFF
One biomass/bio—based
solids—fired boiler(24 one simple cyclone
million Btu per hour (144 inches in
ES—BB maximum heat input CS-24 diameter),one bagfilter CD—BB1C,CD—BBIBH
(8
rate) [NSPS —Dc, square feet of
MACT—DDDDD] filtterer area),
One biomass/bio—based
solids—fired boiler(24 one simple cyclone
million Btu per hour (144 inches in
ES—BB2 CS-24 diameter),onebagfilter CD—BBIC,CD—BBIBH
maximum heat input p (8,900 square feet of
rate) [NSPS—Dc,
MACT—DDDDD] filter area),
one storage and recycle
ES—M-125A tank(19,500 gallons
capacity) MACT FFFF]
one storage and recycle
ES—M-125B tank(19,500 gallons
capacity) [MACT FFFF]
ES—MDSU-1024 molecular sieve
One No. 2 fuel oil—feed
limited use emergency Oxidation Catalyst
generator(2,935 [17 070 acfin(6,854 ES—PkGenl kilowatt maximum rated CS-22 scfin)inlet air flow rate CD—CatOxl
power output) [MACT at 695 OF—835 OF],
ZZZZ]
One No. 2 fuel one simple cyclone
oil/propane—fired rotary (144 inches in
ES—RD dryer(30 million Btu CS-24 diameter),one bagfilter CD—BBIC,CD—BBIBH
per hour maximum heat (8,900 square feet of
input rate) filter area),
solvent process tank
ES—TK—PNE-1 (9,500 gallons capacity)
MACT FFFF
One No. 2 fuel oil—fired
emergency fire water
FP pump (285 horsepower
maximum rated power
output) [MACT ZZZZ]
one(1)jet ejector
One centrifuge [MACT venturi—type wet
G 17 FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide O s.
8

One No. 2 fuel oil—feed
boiler(20.3 million Btu
11 101 per hour maximum rated
heat input)[2D.1109
case—by—case MACT
One No. 2 fuel oil—fired
boiler(20.3 million Btu
11 102 per hour maximum rated
heat input) [21) .1109
case—by—case MACT]
One No.2 fuel oil—fired
boiler(25.2 million Btu
H-103 per hour maximum rated
heat input)[2D .1109
case—by—case MACT
Chilled Water—Cooled
Condenser,Packed
HB-1 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-2 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-3 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
box[MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-4 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
I—Briquette sage briquetting
machine
ECS process: batch
IECS preparation of
ethylenediamine/copper
sulfate solution
IES—PV Provane vaporizer
No.2 fuel oil storage
ITK102 tank(495 gallon
capacity)
No. 2 fuel oil storage
ITK103 tank(495 gallon
capacity)
9

No.2 fuel oil storage
ITK9238 tank(50,000 gallon
capacity)
No. 2 fuel oil storage
ITK9239 tank(50,000 gallon
capacity)
No. 2 fuel oil storage
ITKFP tank(270 gallon
capacity)
Wastewater treatment
IWWTP—AT2 plant aeration tank No.2
(63,500 gallon capacity)
Wastewater treatment
IWWTP—AT3 plant aeration tank No. 3
(63,500 gallon capacity)
Wastewater treatment
IWWTP—CLR plant clarifier(1,310
gallon capacity)
Wastewater treatment
I WWTP—ET1 plant equalization tank
No. 1 (65,500 gallon
capacity)
Wastewater treatment
IW WTP—ET2 plant equalization tank
No.2 (65,500 gallon
capacity)
one(1)jet ejector
One batch reactor venturi—type wet
M-10.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
One batch reactor venturi—type wet
M-10A.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide O s.
one(1)jet ejector
One acetic acid storage venturi—type wet
M-20.16A tank(10,135 gallon CS-1 scrubber(10 GPM CD—M-34
capacity) [MACT FFFF] injection rate,ID No.
M-34) Sclareolide O s.
One plant material one(1)fabric filter
grinder(1,011 pounds (244 square feet of filter
MHZ-1002 per hour nominal feed CS-4 surface area,ID No. CD-1003-4-1
rate) CD-1003-4-1)
One reactor equipped one condenser(ID No.
R 3001 with a chilled water CS-11 CD-3001) installed on CD-3001
process condenser centrifuge,reactor and
(EX-3001) [PSD] heat exchanger/dryer
R-3002 One reactor equipped
with a chilled water
10

process condenser
(EX-3003) FPSDI
One reactor equipped
R-3003 with a chilled water
process condenser
(EX-3004) PSD
One reactor equipped
R-3004 with a chilled water
process condenser
(EX-3005) PSD
One 4,200 gallon reactor
R-4004 with process condenser
(EX-4001) [PSD,
MACT FFFF
One 4,200 gallon reactor
R-4005 with process condenser
(EX-4002) [PSD,
MACT FFFF
R 4015 One 1,500 gallon reactor
[PSD,MACT FFFF]
One 4,200 gallon reactor
R-4044 with process condenser
(EX-4003) [PSD,
MACT FFFF
one condenser(ID No.
T-3001 One process tank(6,700 CS-11 CD-3001)installed on CD-3001
gallon capacity) [PSD] centrifuge,reactor and
heat exchanger/dryer
one condenser(ID No.
T-3002 One process tank(2,538 CS-11 CD-3001) installed on CD-3001
gallons capacity) [PSD] centrifuge,reactor and
heat exchanger/dryer
T-3003 One process tank(2,538
gallons capacity) [PSD]
T-3004 One process tank(2,538
gallons capacity) PSD
T-3005 One process tank(2,538
gallons capacity) PSD
T-3006 One storage tank
(12,500gallons) [PSD]
T-3007 One process tank
(12,500 gallons) [PSD]
One 17,900 gallon
T-4001 virgin solvent tank
[PSD,MACT FFFF]
One 6,000 gallon
T-4017 process tank [PSD,
MACT FFFF]
T-4018 One 6,000 gallon
process tank[PSD,
11

MACT FFFF
Wastewater treatment
WWTP—ATI plant aeration tank No. I
[PSD,MACT FFFF]
12

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Emission Source & Operating Scenario List- See Instructions
DES Group ID DES ID *OS ID *OS Description
GRl ES-1004-1,ES-1004-2-F, 28 Extraction of Fermented Biomass
ES-1004-2-P,ES-1004-2-WW
GR2 ES-BB1,ES-BB2,ES-RD 33 Biomass Boiler Operation with Wood
Chips as fuel source
G-76 H-101,H-102,H-103 46 Boilers
G-77 E101,E102,E103,E104,FP 42 Generators
ES-1001-1-1-F,ES-1001-1-1-P1, Rotocel, Sage, Recovery,and
ES-1001-1-1-P2,ES-1001-1-1-P3, 35 Distillation
ES-1001-1-1-WW,
G-94 ES-1001-1-2-F,ES-1001-1-2-P,
ES-1001-1-2-WW, Rotocel/Recovery/Concrete Operations
ES-1001-2-1-F,ES-1001-2-1-P1, 43 Fugitive Loss
ES-1001-2-1-WW,HB-1,HB-2,
HB-3,HB-4
A-2.16A,D-1202,D-1231A.16A, Conversions (Sclareolide SDE:
D-1231B.16A,ES-1001-1-3-P, 36 Biological and Chemical)
ES-1001-1-3-WW,
ES-1001-1-4-F.16A,
G-95 ES-1001-1-4-P.16A,
ES-1001-1-4-WW.16A, 44 SDE Fugitive Emissions
ES-1001-3-F,ES-1003-2-2-F,
ES-1003-2-2-WW,G-17,
M-10.16A,M-IOA.16A,M-20.16A
C-3001,D-3001,ES-1003-10-F, 39 Sclareol Re-crystallization(SFG)
G-96 ES-1003-10-WW,R-3001,T-3001,
T-3002 45 SFG Fugitive Emissions
C-31203,D31211,D31214, 37 Plant Nutrient Extraction NE)
G-97 ES-1003-2-1-F,ES-1003-2-1-P,
ES-1003-2-1-WW 38 PNE-Isohexane Extraction
G-99 D-1201,D-1215,D-1218,D-2202 41 EVG(batch flavorant)
G-150 ES-1001-11-F,ES-1001-I I-P, 40 Botanical extraction process(includes
ES-1001-11-WW botanical vents,condensers,tanks,etc)
C-3002 NONE NONE
C-4001 NONE NONE
D-3002 NONE NONE
D-4001 NONE NONE
ES-1001-1-3-Filters NONE NONE
13

� I
ES-1004-2Silo 30 Silo load out of spent biomass
ES-4000—F NONE NONE
ES-4000—WW NONE NONE
ES—M-125A NONE NONE
ES—M-12513 NONE NONE
ES—MDSU-1024 NONE NONE
ES—PkGenl 12 Peak Shaving Generator
ES—TK—PNE-1 NONE NONE
I—Briquette NONE NONE
IECS 31 EDA Process
IES—PV NONE NONE
ITK102 NONE NONE
ITK103 NONE NONE
ITK9238 NONE NONE
ITK9239 NONE NONE
ITKFP NONE NONE
IWWTP—AT2 NONE NONE
IWWTP—AT3 NONE NONE
IWWTP—CLR NONE NONE
IWWTP—ETI NONE NONE
IWWTP—ET2 NONE NONE
MHZ-1002 34 Misc: Plant Material Grinder
R-3002 NONE NONE
R-3003 NONE NONE
R-3004 NONE NONE
R-4004 NONE NONE
R-4005 NONE NONE
R-4015 NONE NONE
R-4044 NONE NONE
T-3003 NONE NONE
T-3004 NONE NONE
T-3005 NONE NONE
T-3006 NONE NONE
T-3007 NONE NONE
T-4001 NONE NONE
T-4017 NONE NONE
T-4018 NONE NONE
Waste Water Treatment 1st Aeration
WWTP—AT1 32 Chamber(Includes methanol usages
from PNE and EVG)
14

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group GRI consisting of ES—1004-1,ES—1004-2—F, ES—1004-2—P,
Emission Source Group ID ES-1004-2—WW
2. Emission Source Description: Biomass Extraction Operation
3. Operating Scenario ED/Description: OS—28/Extraction of Fermented Biomass
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 1 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur %Asli Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
] CS-21 CD-1004-2EX1002 One chilled water condenser
2 CS-21 CD-1004-2EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-4 IVERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
15

Operating Scenario:OS—28 Emission Source/Group ID: GR1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 100% 0% une—Aug. 0% ept.—Nov. Il
016 Varch—May
16 �016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission
CAS Gf Control
Pollutants
Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficient Emission
(NAAant Code Pollutants Method Code y l?f Control
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
SO2 SO2 08 0
VOC VOC 0.18 03 98
HAP/TAP Emissions Emission Control
Efficient Emission CAS Estimation
Pollutants (In HHAP/TAPSy i EF Control
Alphabetical Order)
(see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 13.68 03 98
16

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group GR2 consisting of ES—BB I,ES—BB2,ES—RD
Emission Source Group ID
2. Emission Source Description: Biomass Boilers
3. Operating Scenario ID/Description: OS—33Biomass Boiler Operation with Wood Chips as fuel source
4. SCC Number/Description: 10200904Bark ; Bark—fired Boiler(<50,000 Lb Steam)
5. Throughput/units in 2016: 25211.2 TON/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur %Ash Heat Content 8000000 Btu/ton
Btu/units
7. Capture Efficiency
(°/u of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-24 CD—BB1C one simple cyclone 144 inches in diameter
CS-24 CD—BB1BH one ba filter(8,900 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry fines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP—BB1 VERTICAL STACK GO 3 240.8 24 10178.76 Biomass BoilersExhaust
17

Operating Scenario: OS—33 Emission Source/Group ID: GR2
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
016 016 �016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Inswctions all controls
2016
Carbon Dioxide CO2 124389 19664.74 08 0
Methane CH4 74-82-8 2.12 08 0
Nitrous Oxide 20 10024972 1.31 08 0
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 19.36 04
NOx NOx 22.19 09
TSP TSP 0.14 04 99
PM10 PM10 0.14 04 99
PM2.5 PM2.5 0.14 04 99
S02 S02 2.52 09
VOC VOC 1.71 09
Emissions Emission Control
HAP/TAP CAS Estimation Efticienc� Emission
Pollutants (In Alphabetical Order) (see instructions)ctions) HAP/TAPS Method Code (Net after all Factor EF Control
See Instructions) controls)
2016
Acetaldehyde 75-07-0 167.402 09
Acrolein 107-02-8 806.758 09
Benzene 71-43-2 847.096 09
Benzo(a)pyrene(Component of 50-32-8 0.524 09
POMTV POM7
Carbon tetrachloride 56-23-5 9.076 09
Chlorine 7782-50-5 159.335 09
Chlorobenzene 108-90-7 6.656 09
Chloroform 67-66-3 5.647 09
Eth lbenzene 100-41-4 6.252 09
Formaldehyde 50-00-0 887.434 09
18

Hydrogen chloride 7647-01-0 18.152 04 0
(by drochloric acid
Mercury,vapor(Component of 7439-97-6 0.058 04 0
HGC
Naphthalene(Component of 91-20-3 19.564 09
POM
Phenol 108-95-2 10.286 09
Pro ionaldeh de 123-38-6 12.303 09
Styrene 100-42-5 383.21 09
Toluene 108-88-3 185.554 09
X lene 1330-20-7 5.042 09
19

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-76 consisting of H-101,H-102,H-103
Emission Source Group ID
2. Emission Source Description: Boilers
3. Operating Scenario ID/Description: OS—46Boilers
4. SCC Number/Description: 10200501/Distillate Oil(No. 1 2) ; Grades 1 and 2 Oil
5. Throughputtunits in 2016: 672840.3 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed in ertnit
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP—B-1 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler: vertical with
rain ran
EP—B-3 VERTICAL STACK 45 2.5 500 34.6 10190.54 boiler: vertical with
rain cap
EP—B-2 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler: Horizontal
20

Operating Scenario: OS-46 Emission Source/Group ID: G-76
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an-Feb +Dec 27% arch-May 13% une-Aug. 18% ept.-Nov. 42%
�016 1 016 1 �016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions- Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 7636.7375 08 22.7
Methane CH4 74-82-8 0.0202 08 0.00006
Nitrous Oxide 20 10024972 0.0404 08 0.00012
Criteria Emissions- Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) enc y Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 1.68 09 0.005
NOx NOx 8.07 09 0.024
TSP TSP 0.67 09 0.002
PM10 PM10 0.3 09 0.0009
PM2.5 PM2.5 0.08 09 0.00025
S02 S02 14.33 09 0.0426
VOC VOC 0.07 09 0.0002
HAP/TAP Emissions Emission Control
Pollutants (In Alphabetical CAS HAP/TAPS Estimation Efficiency Emission EF Control
Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions) controls)
2016
Arsenic Unlisted
Compounds(Specify ASC-Other 0.37679 09 5.6E-7
Component of ASC
Benzene 71-43-2 1.85031 09 0.00000275
Beryllium metal(unreacted) 7440-41-7 0.28259 09 4.2E-7
(Component of BEC
Cadmium Metal(elemental
unreacted,Component of 7440-43-9 0.28259 09 4.2E-7
CDC
Chromic acid(VI)
(Component of So1CR6 7738-94-5 0.28259 09 4.2E-7
CRC
21

Eth I benzene 100-41-4 0.54971 09 8.17E-7
Fluorides(sum of all 16984-48-8 25,09694 09 0.0000373
fluoride compounds)
Formaldehyde 50-00-0 32,29634 09 0.000048
Lead Unlisted Compounds
(Specify and Component of PBC—Other 0.84778 09 0.00000126
PBC
Manganese Unlisted
Compounds(Specify MNC—Other 0.56519 09 8.4E-7
Component of MNC
Mercury,vapor(Component 7439-97-6 0.28259 09 4.2E-7
of HGC
Naphthalene(Component of 91-20-3 0.22406 09 3.33E-7
POMT
Nickel metal(Component of 7440-02-0 0.28259 09 4.2E-7
NIC
Polycyclic Organic Matter
(Inc PAH,dioxins,etc.NC POINI 2.22037 W) 0.0000033
AP 42 historic amorphous
lob
Toluene 108-88-3 53.62537 09 0.0000797
X lene o— 95-47-6 0.94198 09 0.0000014
22

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-77 consisting of E101,E102,E103,E104,FP
Emission Source Group ID
2. Emission Source Description: Generators
3. Operating Scenario ID/Description: OS—42/Generators
4. SCC Number/Description: 20100102/Distillate Oil(Diesel) ; Reciprocating
5. Throughput/units in 2016: 1942.5 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP104 VERTICAL STACK 11 0.67 1000 96.9 2049.81 Generator ES104
EP101 IVERTICAL STACKI 12 1 0.67 1 1063 160.9 3403.66 Vertical
EP102 VERTICAL STACK 11 1 0.67 1 885 203.4 4302.7 Vertical
EP103 JVFRTICAL STACK 10 0.67 1 1063 174.4 3689.24 Vertical
23

Operating Scenario: OS—42 Emission Source/Group ID: G-77
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 24% arch—May 29% une—Aug. 24% ept.—Nov. 23%
016 016 2016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and.documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 6.02 09
Methane CH4 74-82-8 0.0012 09
Nitrous Oxide 20 10024972 0.0001 09
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po� Code Pollutants Method Code Ef Control
Pollutants an (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 0.12 09
NOx NOx 0.04 09
TSP TSP 0.01 09
PM10 PM10 0.01 09
PM2.5 PM2.5 0.01 09
S02 S02 0.02 09
VOC VOC 0.05 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Acetaldehyde 75-07-0 0.007 09
Acrolein 107-02-8 0.002 09
Arsenic Unlisted Compounds( ASC—Other 0.001 09
Specify Component of ASC
Benzene 71-43-2 0.213 09
Benzo(a)pyrene(Component of 50-32-8 0.0001 09
POMTV POM7
Beryllium metal(unreacted) 7440-41-7 0.001 09
(Component of BEC
Cadmium Metal(elemental 7440-43-9 0.001 09
unreacted Component of CDC
24

Formaldehyde 50-00-0 0.022 09
Naphthalene (Component of 91-20-3 0.036 09
POMTV
Toluene 108-88-3 0.077 09
X lene 1330-20-7 0.053 09
25

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID (from permit)or Group G-94 consisting of ES-1001-1-1—F, ES-1001-1-1—P1,
Emission Source Group ID ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2—F,
ES-1001-1-2—P,ES-1001-1-2—WW,ES-1001-2-1—F,ES-1001-2-1—P1,
ES-1001-2-1—WW,HB-1,HB-2,HB-3,HB-4
2. Emission Source Description: Rotocel,Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—35/Rotocel, Sage,Recovery, and Distillation
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 136749927 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-17 CD-31209 One chilled water condenser
2 CS-17 CD-1001-2—S-1 One packed tower scrubber(8 gallons per minute minimum mineral oil
in'ection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try fines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1001-11-1 VERTICAL STACK 42 0.5 68 127.4 1500.89 Vertical
26

Operating Scenario:OS—35 Emission Source/Group ID: G-94
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 24% arch—May 22a�o uneAug. 26% Sept.—Nov. 28%
016 016 �016_
016
13. Actual Emis ions o r Poll utant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(N�QS Code Pollutants Method Code (Net after Factor Ef Control
Pollutants
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 95.2 03 98
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 187584.93 03 98
except n—hexane
Hexane n— 110-54-3 2817.48 03 98
27

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-94 consisting of ES-1001-1-1—F,ES-1001-1-1—P1,
Emission Source Group ID ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2-17,
ES—100 1—1-2—P,ES—100 1—1—2—WW,ES—100 1—2—1—F,ES—100 1-2—1—P 1,
ES-1001-2-1—WW,HB-1,HB-2,HB-3,HB-4
2. Emission Source Description: Rotocel, Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—43/Rotocel/Recovery/Concrete Operations Fugitive Loss
4. SCC Number/Description: 30188801/*Fugitive Emissions ; Specify in Comments Field
5. Throughput/units in 2016: 136749927 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /a Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume ERP Description
(in feet) Circle(enter (F) (Feet/sec) Flow
): Rate
Rectangle(L (Acfm)
W)
in 0.1 feet)
IG-94 FUGITIVES FUGITIVE(NO 1 72 Area= 1 Rotocel/Recovery/Concrete Fugitives
STACK
28

Operating Scenario:OS—43 Emission Source/Group ID: G-94
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec arch—May ° une—Aug. ° ept.—Nov. °
016 24°�° 016 22�° �016 26�° �016
13. Actual Emissions Fer Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor [If Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(N�QS Code Pollutants Method Code h:f Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 854.22 02
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 1161330.74 02
except n—hexane
Hexane n— 110-54-3 17442.9 02
Methanol 67-56-1 529656.3 02
29

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-95 consisting of A-2.16A,D-1202,D-123 IA.16A,D-1231B.16A,
Emission Source Group ID ES-1001-1-3—P, ES-1001-1-3—WW,ES-1001-1-4—F.16A,
ES-1001-1-4—P.16A,ES-1001-1-4—WW.16A,ES-1001-3—F,
ES-1003-2-2—F, ES-1003-2-2—WW,G-17,M-10.16A,M-10A.16A,
M-20.16A
2. Emission Source Description: Conversions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—36/Conversions(Sclareolide SDE: Biological and Chemical)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 882348.9 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-1 CD—M-34 One venturi—type wet scrubber(10 gallons per minute minimum liquid
injection rate
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-1 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
30

� I
Operating Scenario:OS—36 Emission Source/Group ID: G-95
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec une—Aug. u Sept.—Nov. o
�016 20% �arch—May
16 28% �016 28/0 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG ma GHG Estimation Efficiency Emission
Pollutants CAS l?f Control
Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 16.46 03 98
l
HAP/TAP Emissions Emission ControEmissio n CAS Estimation Efficiency Pollutants (1n HAP/TAPS y EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 23769.86 03 98
except n—hexane
Hexane n— 110-54-3 9044.67 03 98
31

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-95 consisting of A-2.16A,D-1202,D-123 IA.16A,D-123113.16A,
Emission Source Group ID ES-1001-1-3—P,ES-1001-1-3—WW,ES-1001-1-4—F.16A,
ES-1001-1-4—P.16A,ES-1001-1-4—WW.16A,ES-1001-3—F,
ES-1003-2-2—F,ES—1003-2-2—WW, G-17, M-10.16A,M—IOA.16A,
M-20.16A
2. Emission Source Description: Conventions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—44/SDE Fugitive Emissions
4. SCC Number/Description: 30188801/*Fugitive Emissions ; Specify in Comments Field
5. Throughput/units in 2016: 882348.9 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
Y
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
SDE FUGITIVES FUGITIVE(NO 1 72 Area= 1 SDE fugitive
STACK emissions
32

Operating Scenario: OS—44 Emission Source/Group ID: G-95
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 20% arch—May 28% une—Aug. 28% ept.—Nov. 24%
016 016 1 �016 016
13. Actual Emissions ner Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 92.39 02
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 110942.26 02
except n—hexane
Hexane n— 110-54-3 73933.21 02
33

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-96 consisting of C-3001,D-3001,ES—1003—1 0—F,
Emission Source Group ID ES-1003-10—WW,R-3001,T-3001,T-3002
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—39/Sclareol Re—crystallization(SFG)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 769376 LB/yr
(e.g. production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7, Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
I CS-11 CD-3001 One chilled water condenser
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume ERP
(in feet) Circle(enter (F) (Feet/sec) Flow Rate Description
): (Acfm)
Rectangle(L x
W)
in 0.1 feet)
P-1003-10-1 DOWNWARD—FACING VENT 19 0.17 80 3 4.08 Horizontal
P-1003-10-3 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-4 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-5 HORIZONTAL STACK 25 0.17 80 10.2 13.89 Horizontal
[EP-1003-10-61 HORIZONTAL STACK 30 0.17 1 100 0.1 0.13 Horizontal
34
I

�P-1003-10-71 VERTICAL STACK 1 19 0.17 80 53 72.17 Vertical
�P-1003-10-21 HORIZONTAL STACK 1 18 0.17 80 0.1 0.13 Horizontal
35

Operating Scenario: OS—39 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throngh ut:
an—Feb +Dec 28% arch—May 31% une—Aug. 15% �016
ept.—Nov. 26%
016 016 �016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission
Pollutants CAS Pollutants Method Code (Net after Factor Ef Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 13.79 02 98
HAP/TAP Emissions Emission Control
CAS Estimation Efficiency Emission EF Control
Alphabetical Order) (Pounds/Year)
Pollutants (see instructions) HAP/TAPS Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 6240.4 03 98
36

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-96 consisting of C-3001,D-3001,ES-1003-10—F,
Emission Source Group ID ES-1003-10—WW,R-3001,T-3001,T-3002
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—45/SFG Fugitive Emissions
4. SCC Number/Description: 30188801/*Fugitive Emissions; Specify in Comments Field
5. Throughputtunits in 2016: 769376 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur NOAsh Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
SFG FUGITIVES FUGITIVE(NO 1 72 Area= 1 SFG fugitive
STACK) emissions
37

l
Operating Scenario: OS—45 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 28% 31% une—Aug. 15% �016
ept.—Nov. 26%
016 �arch—May
16 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net afterFactor Ef Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 55.15 02
HAP/TAP Emissions Emission Control
Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 24961.6 08
38

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit) or Group G-97 consisting of C-31203,D31211, D31214,ES-1003-2-1—F,
Emission Source Group ID ES-1003-2-1—P,ES-1003-2-1—WW
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS—37/Plant Nutrient Extraction(PNE)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputlunits in 2016: 358445 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfiir /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point RP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feettsec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
39

Operating Scenario: OS—37 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 34% arch—May 31% une—Aug. 30% �016
ept.—Nov. o
016 016 �016 5/o
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 69.2 03
Emission Control
HAP/TAP Emissions Emission I
CAS Estimation Efficiency
Pollutants (in HAP/TAPS EF Control
Alphabetical Order)
(see instructions) (Pounds/Year) Method Code (Net after all Factor
i
See Instructions controls)
2016
Ethyl acetate 141-78-6 0 03
40

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-97 consisting of C-31203,D31211,D31214,ES-1003-2-1—F,
Emission Source Group ID ES-1003-2-1—P,ES-1003-2-1—WW
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS—38/PNE—Isohexane Extraction
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur r,,Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
41

Operating Scenario:OS—38 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
016 4016 1 �016 Olb
13. Actual Emissi lollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss an (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP Emissions Control
CAS Estimation Emission
Pollutants (In (see instructions) y HAP/TAPS Method Code Efficiency Factor EF Control
See Instructions
Alphabetical Order) (Pounds/Year) (Net after all controls)
2016
42

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bettie
Meng Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-99 consisting of D-1201,D-1215, D-1218,D-2202
Emission Source Group ID
2. Emission Source Description: EVG(batch flavorant)
3. Operating Scenario ID/Description: OS—41/EVG(batch flavorant)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 21998.7 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-7 CD—Z-9215 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
2 CS-7 CD—Z-9216 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
43

Operating Scenario: OS—41 Emission Source/Group ID: G-99
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 100�o 350�o une—Aug. 400�o �016
ept.—Nov. 15%
016 �arch—May
16 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) y Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 17.27 03 98
HAP/TAP CAS Emissions Emission Estimation Control Emission
Pollutants (in HAP/TAPS Method Code Efficiency EF Control
(see instructions)
Alphabetical Order) (Pounds/Year) et after all controls) Factor
See Instructions
2016
Chloroform 67-66-3 30676 03 0
Methanol 67-56-1 3868.3 03
44

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-150 consisting of ES-1001-11—F,ES-1001-11—P,
Emission Source Group ID ES-1001-11—WW
2. Emission Source Description: Botanical Extraction Operations
3. Operating Scenario ID/Description: OS—40Botanical extraction process(includes botanical vents,condensers,
tanks,etc)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 1298526.6 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur ro Ash I Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-16 CD-100111EX1002 One chilled water condenser
2 CS-16 CD-100111EX1003 One cryogenic(nitrogen)condenser system(-40 IF maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
(in 0.1 feet)
EP-1-11 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
45
i

Operating Scenario: OS—40 Emission Source/Group ID: G-150
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 37a�o 48a�e une—Aug. 0"�u ept.—Nov.
016 �arch—May
16 �016 �016
13. Actual Emissions Der Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code (Net after Factor Ef Control
Pollutantss
(Tons/Year) (See instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 2.5 03 98
HAP/TAP Emissions Emission ControlEmission CAS Estimation Efficiency
Pollutants (In HAP/TAPS EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
lath I acetate 141-78-6 217.08 03 0
46

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or ES-1004-2Silo
Emission Source Group ID
2. Emission Source Description: Biomass silo loadout
3. Operating Scenario ID/Description: OS—30/Silo load out of spent biomass
4. SCC Number/Description: 39999994/Misceilaneous Industrial Processes ; Other Not Classified
5. Throughputtunits in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-23 CD-1004-2—FF2 One ba filter 254 square feet of filter area
9.Emission Release Point(EPP) Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1004-2—FF2 HORIZONTAL STACK 10 1 8.5 1 72 0.64 2180 Dust Collector on
Silo
47

Operating Scenario:OS—30 Emission Source/Group ID:
ES-1004-2Silo
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25"�u une—Aug. 25"�o Sept.—Nov.
�016 �arch­May
16 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all wntrols
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Code Pollutants Method Code Ef Control
an
Pollutants (Net after Factor
(Tons(Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
SO2 SO2 08
VOC VOC 08
HAP/TAP Emissions Emission Control
CAS Estimation Emission
Pollutants (In HAP/TAPS Efficiency EF Control
Alphabetical Order (see instructions) Pounds/Year p ) ( ) Method Code (Net after all controls) Factor
See Instructions
2016
48

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or ES—PkGenl
Emission Source Group ID
2. Emission Source Description: One No. 2 fuel oil—fired limited use emergency generator(2,935 kilowatt
maximum rated power output) [MACT ZZZZ]
3. Operating Scenario ID/Description: OS— 12/Peak Shaving Generator
4. SCC Number/Description: 20300 10 1/Distillate Oil(Diesel) ;Reciprocating
5. Throughputtunits in 2016: 5122 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-22 CD—CatOx I One catalytic oxidizer 695 °F minimum inlet temperature)
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height lam
Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F') (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-9 VERTICAL STACK 20 0.17 SRO 0.1 0.13 Horizontal
49

Operating Scenario:OS— 12 Emission Source/Group ID: ES—PkGenl
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 13%u arch—May 13% une—Aug. 54% �016
ept.—Nov. 20%
016 016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 15.88 09 0
Methane CH4 74-82-8 0.0032 09 0
Nitrous Oxide 20 10024972 0.0025 09 0
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 0.31 09 95 AFTER
NOx NOx 1.16 09 98 AFTER
TSP TSP 0.04 09 98 AFTER
PM10 PM10 0.04 09 98 AFTER
PM2.5 PM2.5 0.04 09 98 AFTER
S02 S02 0.05 09 98 AFTER
VOC VOC 0.13 09 98 AFTER
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Acetaldehyde 75-07-0 0.0182 09
Acrolein 107-02-8 0.0057 09
Arsenic Unlisted Compounds ( ASC—Other 0.0029 09
Specify Component of ASC
Benzene 71-43-2 0.5604 09
Benzo(a)pyrene(Component of 50-32-8 0.0002 09
POMTV POM7
Beryllium metal(unreacted) 7440-41-7 0.0022 09 0
(Component of BEC
Cadmium Metal(elemental 7440-43-9 0.0022 09 0
unreacted Component of CDC
50

Formaldehyde 50-00-0 0.057 09
Naphthalene(Component of 91-20-3 0.0939 09
POM
Toluene 108-88-3 0.2029 09
X lene 1330-20-7 0.1394 09
51

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or IECS
Emission Source Group ID
2. Emission Source Description: ECS process:batch preparation of ethylenediamine/copper sulfate solution
3. Operating Scenario ID/Description: OS—31/EDA Process
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur ro Ash I Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
52

Operating Scenario:OS—31 Emission Source/Group ID: IECS
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25%%u arch—May 25% une—Aug. 25% ept.—Nov. 25%
016 016 1 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor Et'Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
AA S Pollutant Criteria Estimation Efficiency Emission
Q ) F,f Control
Code Pollutants Method Code
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP CAS Emissions Emission Control
Pollutants (In HAP/TAPS Estimation E Emission EF Control
Efficiency
(see instructions) Method Code y Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
See Instructions
2016
53

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or MHZ-1002
Emission Source Group ID
2. Emission Source Description: Misc: Grinder,air stripper,lime silo,and Aphios
3. Operating Scenario ED/Description: OS—34/Misc: Plant Material Grinder
4. SCC Number/Description: 31299999/Miscellaneous Machinery ; Other Not Classified
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o Sulfur FoAsh Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD H) Control Device Description
as listed inpermit)
1 CS-4 CD-1003-4-1 One ba filter 244 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP H) ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1003-4-1 HORIZONTAL STACK 20 1.3 75 37.7 3002.4 Horizontal
54

Operating Scenario: OS—34 Emission Source/Group ID: MHZ-1002
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25%
016 016 �016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor Ef Control
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation EfficiencyEmission
m�QS Code Pollutants Method Code Ef Control
Pollutantss ants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP CAS Emissions Emission
Control
Pollutants (In HAP/TAPS Estimation Emission
(see instructions) Efficiency EF Control
Alphabetical Order Pounds/Year Method Code Factor
P ) ( ) (Net after all controls)
See Instructions
2016
55

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or WWTP—AT1
Emission Source Group ID
2. Emission Source Description: Wastewater treatment plant aeration tank No. 1 [PSD,MACT FFFF]
3. Operating Scenario ID/Description: OS—32/Waste Water Treatment Ist Aeration Chamber(Includes methanol
usages from PNE and EVG)
4. SCC Number/Description: 30182006/Wastewater Treatment;Chemical Plant Wastewater System:
Aerated Impoundment
5. Throughput/units in 2016: 14127317 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur %) Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
i
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-14 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
56
I

Operating Scenario: OS—32 Emission Source/Group ID: WWTP—AT1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%016 016 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Et'Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po� Code Pollutants Method Code Ef Control
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 3.23 03
HAP/TAP CAS Emissions Emission Control
Pollutants (in HAP/TAPS Estimation EfficiencyEmission EF Control
(see instructions) Method Code Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
See Instructions
2016
Methanol 67-56-1 6464.6 03
57
1

Facility Total CY 2016 Emissions Summary
COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
Record Facility—Wide Totals From all Permitted and Non—Permitted Air Pollutant Emission Sources
Green House Gases Pollutants(GHG)
Actual Emissions Tons/Year
Pollutant CAS 2016 2015 % Change
Carbon Dioxide CO2 124389 27323,377 29856.902 —8.485559%
Methane CH4 74-82-8 2.1446 2.523 —14.998021%
Nitrous Oxide 20 10024972 1.353 1.5388 —12.074341%
Criteria Pollutants
Actual Emissions Tons/Year
Pollutant CAS 2016 2015 % Change
CO CO 21.47 24.702 —13.083962%
NOx NOx 31.46 33.91 —7.2250094%
PM TSP TSP 0.86 1.215 —29.218105%
PM10 PM10 0.49 .535 —8.411218%
PM2.5 PM2.5 0.27 .305 —11.475408%
S02 S02 16.92 3.104 445.10306%
VOC VOC 1221.55 934.061 30.778406%
Hazardous Air Pollutants PS and/or Toxic Air Pollutants TAPS
Actual Emissions Pounds/Year
Pollutant I CAS 1 2016 1 2015 % Change
Pollutant Grou :Arsenic Compounds total mass of elemental AS arsine and all inorganic compounds) Group Sum:.38069
Arsenic Unlisted Compounds( ASC—Other 0.38069 5.55718 —93.14958%
Specify Component of ASC
Pollutant Group:Beryllium compounds Total mass Group Sum:.28579
Beryllium metal(unreacted) 7440-41-7 0.28579 .5137 —44.366364%
(Component of BEC
Pollutant Grou :Cadmium compounds total mass inc elemental metal GroupSum:.28579
Cadmium Metal(elemental 7440-43-9 0.28579 1.2237 —76,645424%
unreacted Component of,CrC
Pollutant Grou :Chromium VI Soluble Chromate Com ounds(Component of CRC Group Sum:.28259
Chromic acid(VI)(Component o 7738-94-5 0.28259 1.0842 —73.935616%
SolCR6 CRC
58

Pollutant Grou :Chromium-All/Total Inc Chromium VI categories,metal and Others Group Sum:.28259
Chromic acid(VI)(Component o 7738-94-5 0.28259 1.0842 -73.935616%
So1CR6 CRC
Pollutant Grou :Lead and Lead compounds Group Sum:.84778
Lead Unlisted Compounds PBC-Other 0.84778 12.1106 -92.99968% I
(Specify and Com onent of PBC
Pollutant Grou :Man anese compounds Group Sum:.56519
Manganese Unlisted Compounds MNC-Other 0.56519 379.0104 -99.85088%
(Specify Component of MNC
Pollutant Group:Mercury Compounds-all total mass inc H&Vapor Group Sum:.34059
Mercury,vapor(Component of 7439-97-6 0.34059 .3188 6.8350058%
HGC
Pollutant Grou :Nickel Compounds, sum total mass inc elemental Group Sum:.28259
Nickel metal(Component of NIC 7440-02-0 1 0.28259 1 8.0602 -96.49401%
Pollutant Grou :Pol c clic Organic Matter 7 PAH Compounds for NIF Group Sum:.5243
Benzo(a)pyrene(Component of 50-32-8 0.5243 .6153 -14.789537%
POMTV POM7
Pollutant Grou :Pol c clic Or anic Matter(Specific Co m ounds from OA PS for TV Group Sum:20.44226
Benzo(a)pyrene(Component of 50-32-8 0.5243 .6153 -14.7895370/0
POMTV POM7
Naphthalene(Component of 91-20-3 19.91796 23.29457 -14.495273%
POMTV
Acetaldehyde 75-07-0 167.4272 196.4354 -14.767295%
Acrolein 107-02-8 806.7657 946.2847 -14.7438755%
Benzene 71-43-2 849.7197 996.14801 -14.6994505%
Carbon tetrachloride 56-23-5 9.076 10.646 -14.74732%
Chlorine 7782-50-5 159.335 186.888 -14.743051%
Chlorobenzene 108-90-7 6.656 7.807 -14.743179%
Chloroform 67-66-3 30681.646 16948.624 81.027374%
Ethyl acetate 141-78-6 31432.76 21102.09 48.955673%
Ethyl benzene 100-41-4 6.80171 7.8207 -13.029396%
Fluorides(sum of all fluoride 16984-48-8 25.09694 22.22003 12.947369%
compounds)
Formaldehyde 50-00-0 919.8093 1069.66504 -14.009592%
Hexane(isomers,except HEXANEISO 1483627.8 1136915.82 30.495825%
n-hexane
Hexane n- 110-54-3 103238.26 89975.18 14.740818%
Hydrogen chloride(hydrochloric 7647-01-0 18.152 21.29 -14.739316%
acid
Methanol 67-56-1 539989.2 414346.26 30.323175%
Phenol 108-95-2 10.286 12.065 -14.745126%
Polycyclic Organic Matter(Inc
PAH,dioxins,etc.NC AP 42 POM 2.22037 31.53585 -92.95922%
historic amorphous lob
Pro ionaldeh de 123-38-6 12.303 14.431 -14.746028%
Styrene 100-42-5 383.21 449.478 -14.743326%
Toluene 108-88-3 239,45927 265.46038 -9.794724%
X lene 1330-20-7 5.2344 6.1476 -14.854583%
X lene o- 95-47-6 1 0.94198 .834 12.947244%
59

f
COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Comments From Facility:
i
60

NNW
Annual Air Emissions Inventory Summary
2016 Totals Facility ID#:0800044
pokdav 1e W a99erR e W Oee01 Gang a 03 OenW Pk4 Fire Pump Ba9aMlf RPEorJ aem'ury COnOrte FMvysie tWl Sklefetlge Blontess BohNul NutrbM EVO VYWTP , Tobb II,9b
(9F0) (80E) E80ao000 Extractlon FJNa00011 P essss
C 2W9.33330 1318A1761 1210.90030 1.]9558 110 1A5761 1AM6O 15.8W83 IWOM lW5411 TwNYr
kleNne O.MW2 001149 0.M326 OOOOM 003.M6 OW COO OMOM 0=25 0.=24 2 2T329.3]].12 2.143 7m
Nb O Oa1W3 0R2W 0.00858 O.00W3 00004 0WW3 0W003 000253 aDW05 1.31 1351 TN r
TSP 0.10056 om8 aimm 0.M317 0.00M7 0.W331 aW324 0.03611 0.01139 0.141 0875 Tp
PM-10 O09R6 019147 0.0516) 0.003%7 0.M39] 0.00331 000326 003611 001139 0141 0.539 TOM}
PM-2.5 0=57 0N787 0.01367 O,W317 0.=97 0.W331 0.M324 0.0361, 001139 0141 0.288 Ta ,
Sw 3W569 0.15671 2.32M 0.00M7 0.00559 0.W487 OM457 005092 000550 2.52112 16.928 Ta r
Nm 2.1M70 A59533 131M 001015 001M 0.01W0 0610M 115552 0161W 22.1859 34621 Tatar
VOc 001806 003829 001M3 001142 0.01428 001,93 001167 013M 0013M 17144 8W.S86 2W.R8 68.939 108.W5 0.178 2A99 0M4 176222 3.23 1221 W1 T~ft
c0 045140 095736 0.27335 0.02697 0.03)1 0.02818 0W57 03WW 003ae9 193622 21 W3 Ta l
&.LWd,hyd, 0.M1M 0M2M 1 OW167 060163 0.018M OOSBW 167 402 167 4M IOWYr
8udek� 0MWO 0WW2 a ON051 060568 O.Mac 806.758 BOB.773 UWYr
Nxnc 010111 031M5 O.W123 000025 060032 OOW27 0.M038 0.M269 O.OMM 0.381 LtreM
Beraene 0.49653 1M310 030W8 001921 O.W155 0,0143 005033 aNC43 aM851 W7.096 I W9.7M uWY,
Bxu a O600R 0MM2 000002 0.00002 OOW19 000001 0,524 0.52180 LWYr
Be 0.07583 OAM414 0.01592 00M19 00M21 0W(M 0M019 0.M217 O.W022 0395 LOW,
Bu aw
0.00 LWWr
C d..M OWM DAWt1 0904502 0.00019 OM024 OM020 0.OMt9 0=17 000022
CaIrJ1mO ai6e 0
2M LWYr
cwm 9.aM LOW'r
rekxNa;ae 00]6 9.0)6 LWYr
c51f.(kM 159.335 159.335 llulYr
CMMObe,¢aM all% 66% IWY,
CIVorOlorm SWT MIS M881,W LOWr
c1,.. O.O7583 0.1BOW O.WSM 0.283 UWY,
CtYo.W 0W524 0.01111 0.W317 am LWY,
O1e 0 0.W0 lOeffr
Effy 100% 7t W DOO 342 053 IWYr
EB�d-6DA e78115 0.M 4761M6 LOW,
E ece,We 31M2.00 13M 217.W OM 31432.760 l r
EOMWereN1e 011752 0.3128) O.W933 6.252 6002 LOWr
E ON O.OM LEWYr
FbuiOe 6.23181 14.28382 4.07B:3t 25.W7 LbWr
F 8.BB6)8 1OU133 52M22 000501 0W&M 0.M523 0.0012 0OSBW OO ffia 687.43e 919M LEWY,
MCI 18.152 18.152 UWft
Heine Isomers 0.0M 1]16T15.13 O.M 131712.12 OW 0.00 a00 118415).250 LOWYr
N-H.. O6M 2W30.R OM BMTT.88 0.M a 0.M 103108.]92 lOelYr
M 108875W 0.00 11W5067 1 21T333,305 LYWYr
Ise xebM I I I 2]51.95 OM M51617 LbslYr
Iso acebb a I 0.M 0W LWY,
Leaf Ca O.WW OM251 0.13M am LOWY,
M w O.I516T (IM167 O.M1W 0.M 0MS LOWr
Me OeM3 0.16081 OWSR O.WB out LOW,
MaMawl 529856.M 0.M 36611.M BIW.M 539989.M1 LOWr
N 0.05958 0.12631 DCe6M 0.00825 00101 OWBR OAOW3 O.W146, 09OOR3 19.SW 19.M LOW,
Nrkel 007SB3 OMM80 OWSR 0,20 1W)Yr
PMmI 10.= 102W LDWr
R M e 12M3
12.133 LWY,
Star POnh OM 0.0M lMl3Y
383.210 389.210 LOWr
Tduae 14.39W7 M.52006 571124 001763 0.02229 0.01862 001823 O.M2W &MCOM 1BS.SW 0.M OM MAN LWY,
xvW, 001M5 taint 001 79 001252 0.139W O.OMW 5.W2 5.253 1 IWY,
o-% 0.M278 0.53612 i al3suT iOW2 LOWr

r
Monthly VOC's
YEAR: 2016
Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
No.2 Fuel Oil #2 Fuel Oil 11.276 8.692 5.277 6.124 6.436 1.128 9.251 14.437 29.039 21.550 5.600 15.758 134.57 0.067
BOILERS
GENERATORS #2 Fuel Oil 7.942 8.333 8.333 16.275 4.687 8.333 7.682 8.333 6.250 8.333 8.333 8.333 101.17 0.051
FIRE PUMP #2 Fuel Oil 4.166 5.208 2.083 2.604 1.562 1.562 2.083 1.614 1.562 1.562 1.562 1.562 27.13 0.014
Hexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
Biomass Boilers n-Hexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
Isohexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
EVG Chloroform 0.00 6343.00 4059.00 7203.00 12330.00 -19444.00 13317.00 4527.D0 -10118.00 5272.00 7187.00 0.D0 30676.00 15.338
Methanol 0.00 393.23 277.93 376.70 621.55 114.09 725.56 747.13 0.00 294.81 317.31 0.00 3868.30 1.934
Ethyl acetate(from 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
SDA-35A
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
from SDA-3A
Ethylacetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Eth famine 0.00 0.000
Ethanol-SDA 3A 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.D0 0.00 0.00 0.00 0.00 0.000
PNE Ethanol-SDA 35A 0.00 0.D0 0.00 0.D0 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 0.00 0.00 0.000
He tane 13191.85 16029.54 22.80 13602.48 14124.60 21640.62 1042.47 217.17 15041.73 0.00 11622.30 4121.10 110656.67 55.328
Isobutyl acetate 0.00 0.00 10712.75 0.00 0.00 0.00 0.00 0.00 11604.991 5434.21 0.00 0.00 27751.95 13.876
Toluene 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 - 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Biomass Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Extraction Ethanol-200P 0.00 0.00 0.00 0.00 0.D0 0.00 0.00 0.00 0.00 0.00 0.00 342.06 342.05 0.171
Ethyl acetate from Ethano1200 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 13.68 13.68 0.007
Diethylamine 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Ethyl Acetate 0.00 92.82 56.39 0.00 0.00 0.00 0.00 0.00 0.00 52.81 0.00 15.05 217.08 0.109
Ethanol-SDA 35A 0.00 2044.51 1242.16 0.00 0.00 0.00 0.00 0.00 0.00 1163.30 0.00 331.48 4781.45 2.391
Botanical Ethanol-200 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Extraction Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 O.DD 0.00 0.00 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Toluene 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.D0 0.000
He tane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 123601.50 109469.25 165192.50 85520.05 145211.00 193283.75 16808.00 109246.50 128188.50 128238.00 127770.50 36888.50 1369176.05 684.588
Rotocel& n-Hexane 849.t4 667.76 818.05 945.85 2889.70 4832.09 354.65 2250.48 2435.16 2013.34 1929.33 447.38 20430.92 10.215
Recovery Isohexane 122752.36 108801.49 164376.45 84574.20 142321.30 188451.66 16453.35 106996.02 125731.34 126224.66 125841.17 36221.14 1348745.13 674.373
Methanol 55098.08 35714.38 36964.12 24960.34 48154.80 46197.94 2925720 55697.12 58096.98 54934.66 41280.62 43320.08 529656.30 284.828
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 I 0.00 0.00 0.00 0.00 0.00 0.00 0.000

Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
Concrete n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 17627.50 19855.00 23072.50 16093,00 18650.50 18656.00 18282.00 21824.00 23617,00 11814.00 12952.50 15246.00 217690.00 108.845
Sclareolide n-Hexane 6839A7 7683.89 8905.99 6227.99 7217.74 7219.87 7086.10 8227.65 8820.95 4371A8 4766.52 5610.53 82977.88 41.489
Isohexane 10788.03 12171.12 14166.52 9865.01 11432.76 11436.13 11195.90 13596.35 14796.05 7442.82 8185.98 9635.47 134712.12 67.356
-Ethyl acetate 1909.00 2275.00 1936.00 3202.00 1751.00 2555.00 3796.00 2444.00 1682.00 2761.00 2512.00 4379.00 31202.00 15.601
Recrystallization Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
(SFG) n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
He tane 12215.10 12625.50 9137.10 13782.60 3402.90 3283.20 -560.31 9678.60 -26579.10 10941.15 24823.50 33926.40 1 106676.64 53.338
Methanol(EVG) 0.00 385.36 272.38 369.17 609.12 111.81 711.04 732.19 0.00 288.91 310.96 0.00 3790.94 1.895
Methanol 437.03 226.26 302.27 18.69 15.90 13.75 44.31 111.71 77.19 389.23 704.59 332.74 2673.66 1.337
WVVTP Recove
Methanol(Concrete) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Methanol PNE 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
MonthlyTotal Lbs.VOC 224103.45 206476.09 253263.59 165153.04 244884.06 266423.18 83442.28 205249.81 201626.13 221615.51 229476.78 136721.73 2439435.63 1219.72
MonthlyTotal Tons VOC 112.05 102.74 126.63 82.58 122.44 133.21 41.72 102.62 100.81 110.81 114.74 69.36 1219.72

I
Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : Or-11 05-t/6
Year: 2016 41
Od 60 `n n
Total Run Time: 11953.1 Hr% '/A 9� /�� CY?.o1-�
Efficiency: 85 ! Y
Sulfur Content: 0.0014 % (r 4 ZU/
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 17921.5 25374.0 13086.0 56381.5 501.3 468.0 290.8 1260.1 0.032 11.276
February: 15802.0 20924.5 6732.0 43458.5 457.8 409.6 149.6 1017.0 0.024 1 8.692
March: 15122.2 9519.3 1741.5 26383.0 423.0 250.2 38.7 711.9 0.015 1 5.277
April: 12673.4 13211A 4736.3 30621.1 354.5 273.6 126.3 754.4 0.017 6.124
May: 95.1 13456.0 18627.8 32178.9 27.5 57.8 442.5 527.8 0.018 6.436
June: 4035.0 459.6 1147.4 5642.0 169.3 13.3 30.5 213.1 0.003 1A28
July: 19955.4 23368.1 2933.1 46256.6 539.4 438.5 118.8 1096.7 0.026 9.251
August: 21432.1 45190.1 5561.0 72183.2 599.5 487.6 132.1 1219.2 0.040 14.437
September: 24013.3 94103.2 27076.5 145193.0 671.7 664.8 601.7 1938.2 0.081 29.039
October: 21997.0 73276.9 12476.1 107750.0 615.3 596.3 319.9 1531.5 0.060 21.550
November: 12104.9 12382.6 3514.5 28002.0 338.6 177.7 78A 594.4 0.016 5.600
December: 15406.1 51678.6 11705.8 78790.5 445.8 374.2 268.8 1088.8 0.044 15.758
Total: 180558.0 382944.3 109338.0 672840.3 5143.7 4211.6 2597.8 11953.1 0.377 134.568
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 35.1 5143.7 180558.0
2 H-102 143 90.9 4211.6 382944.3
3 H-103 180 42.1 2597.8 109338.0
Total 466 168.11752 11953.1 672840.3
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. TonsNr TonsNr TonsNr TonsNr
TSP 2.00 0.181 0.383 0.109 0.673
PM-10 1.00 0.090 0.191 0.055 0.336
PsoxS z60 3.846 e157 z.329 14,32 a,067 f-hp- �i^ EDD
Nox 24.00 ) 2.167 4.595 1.312 8,0 (,.')3 Cha a"
VOC 0.20 0.018 0.038 0.011 0.067 1 7/4
CO 5.00 0.451 0.957 0.273 1.682 A 1°,y
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.101 0.214 0.061 0.377 C
Benzene 2.75E-03 0.497 1.053 0.301 1.850 L fa�1 r(A(i3O✓
Be I Ilium 420E-04 0.076 0.161 0.046 0.283 'lT Nr,4 b �a
CV�'O(f ` cadmium 0.076 0.161 0.046 o.za3 3,3/b (000 9
Chr07171M C9 2 0.076 0.161 0.046 0.283 �-�15 /
cs�' Ghromiuni 2-99&4* -"1-1 4ee3 1 O.oaa // �o,r TS!'
Eth I benzene 8.17E-04 0.148 0.313 0.089 0.550
Flounce 3.73E-02 6.735 14.284 4.078 25.097
Formaldehyde 4.80E-02 8.667 18.381 5.248 32.296
Lead 1.26E-03 0.228 0.483 0.138 0.848 �(
Manganese 8.40E-04 0.152 0.322 0.092 0.565
Mercu 4.20E-04 0.076 0.161 0.046 0.283
Na thalene 3.30E-04 0.060 0.126 0.036 0.222
H:\EnvironmentalV\ir Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : O$-1
Nickel 4.20E-04 10.076 0.161 0.046 1
- 0.283
Toluene 7.97E-02 14.390 30.521 8.714 53.625
o-X lene 1.40E-03 1 0.253 0.536 0.153 10.942
Green House Gas Pulutants
s®re�tclsh�f
Emission goiter#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total p&j
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)COz 22700.00 796.83 2064.02 955 yy.41 2049.33 4346.42 1240.99 7636.74 !I :5 -3
Methane(CHe) 0.06 0.0021 0.0055 0.0025 0.0054 0.0115 0.0033 0.0202 0. 31
Nitrous Oxide 0.12 0.0042(NzO) 0.0109 0.0051 0.0108 0.0230 0.0066 0.0404 0 ,06
hl/ fh / c��loru�6rm p.
�/ b
10M ollbs
G-7(,
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044 1 , 7
Biomass Boilers : ES-BB1 & ES-BB2: OS-33 7 / �yZO/G
Fuel Source : Wood Chips 'Ju rr d1n
Year: 2016 � C yZols
Total Run Time: 7138.0 Hrs/Yr
Wood Chips 8000000 BTU/ton 50%/z"/ n
' Emission Factors determined by Emissions test conducted on 12/19/2013
Boiler Operation (Hours) Wood Chips Burned (Tons) CO PM HCL Hoc Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Hours Chips
January: 744.0 456.0 744.0 1826.6 999.0 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
February: 696.0 432.0 696.0 1505.0 736.0 2241.0 3442.2 25.0992 1.61352 0.00520 17928
March: 744.0 744.0 744.0 1510.5 1510.0 3020.5 4639.5 33.8296 2.17476 0.00701 24164
April: 720.0 720.0 720.0 950.0 950.0 1900.0 2918.4 21.28 1.368 0.00441 15200
May: 744.0 672.0 744.0 1570.7 1328.0 2898.7 4452.4 32.46544 2.087064 0.00672 23189.6
June: 696.0 720.0 720.0 1412.8 1412.8 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
July: 300.0 300.0 300.0 560.0 560.5 1120.5 1721.1 12.5496 1 0.80676 0.00260 8964
August: 240.0 659.0 659.0 472.3 1281.5 1753.8 2693.8 19.64256 1.262736 0.00407 14030.4
September: 65.0 65.0 65.0 146.0 146.3 292.3 449.0 3.27376 0.210456 0.00068 2338.4
October: 432.0 432.0 432.0 669.0 670.7 1339.7 2057.8 15.00464 0.964584 0.00311 10717.6
November: 720.0 720.0 720.0 1400.6 1400.6 2801.2 4302.6 31.37344 2.016864 0.00650 22409.6
December: 594.0 594.0 594.0 1096.0 1096.3 2192.3 3367.4 24.55376 1.578456 0.00509 17538.4
Total: 6695.0 6514.0 7138.0 13119.5 12091.7 25211.2 38724.4 282.365 18.152 0.05849 201689.6
Average 557.9 542.8 594.8 1093.3 1007.6 2100.9 3227.0 23.530 1 1.513 0.00487 16807.5
S-fP- (,wJd Ce7-n4w2-1)oyi /Vcv&� s�o���t�she�„�' ,a,�,�� >/ G .�,�, ���� /✓,o p�Ta�
5-cc fps [,moo /bra

Criteria Pollutants Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler
Pollutants (Lb/MM BTU) (TonsNr) Pollutants (Lb/MM BTU) (LbsNr)
TSP 0.0014 0.141 Acetaldehyde 8.30E-04 167.402
PM-10 0.0014 0.141 Acrolein 4.00E-03 806.758 AP 9 Z
PM-2.5 0.0014 V 0.141 Benzene 4.20E-03 847.096 e,JayS
Sox 0.03 2.521 Benzo a rene 2.60E-06 0.524 7
Nox 0.22 22.186 Carbon 4.50E-05 9.076
tetrachloride
VOC 0.02 1.714 Chlorine 7.90E-04 159.335
CO 0.19 19.362 Chlorobenzene 3.30E-05 6.656
Chloroform 2.80E-05 5.647
Ethyl benzene 3.10E-05 6.252
Green House Gas Pulutants Formaldehyde 4.40E-03 887.434
GHG Pollutant Emisson Factor E101 Napthalene 9.70E-05 19.564
Lb/MM BTU tons/ r
CO2 195.000 19664.7 Phenol 5.10E-05 10.286
Methane 0.021 2.1 Propionaldehyde 6.10E-05 12.303
(CH4)
Nitrous Oxide 0.013 1.3 Styrene 1.90E-03 383.210
(N2O)
Toluene 9.20E-04 185.554
X lene 2.50E-05 5.042
[VW gful�r
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set a So 0,d4I l JJ,�,�� l✓AP�?Q f� `
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Page 1 of 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year: 2016
Total Run Time: 99.0 Hrs/Yr
Efficiency: 75 00 �2
Sulfur Content: 0. 14 /, (p
Number Fuel: 141000 Btu1Gal /� -6 Ll/
���� cv,7 is /`
Fuel Usane(oallonsl VOC U/✓ ! 1..•�'
Month E101 E102 E103 E104 Total (Lbs.) n
January: 22.5 50.0 40.0 40.0 152.5 7.9 77
February: 30.0 50.0 40.0 40.0 160.0 8.3 lll��7 I
March: 30.0 50.0 40.0 40.0 160.0 8.3 7 OS.
April: 150.0 62.5 50.0 50.0 312.5 16.3 7
May: 15.0 25.0 30.0 20.0 90.0 4.7
June: 30.0 50.0 40.0 40.0 160.0 8.3
July; 30.0 37.5 40.0 40.0 147.5 7.7
amb
30.0 50.0 40.0 40.0 180.0 8.3
S 22.5 37.5 30.0 30.0 120.0 6.2
30.0 50.0 40.0 40.0 160.0 8.3
N 30.0 50.0 40.0 40.0 160.0 8.3 ��ID
D 30.0 50.0 40.0 40.0 160.0 6.3 C
450.0 562.5 470.0 460.0 1942.5 101.2 /l Yl//rt
Heat Rate
Generator No. I10 Bh h H0l O G15.0 G 50.0 MM Bt2 MM BtulYr ,rf
1 E101 567 440 30.0 15.0 450.0 2.12 63.45
2 E102 760 570 22.5 25.0 562.5 3.53 79.31
3 E103 603 452 23.5 20.0 470.0 2.82 66.27
4 E104 534 401 23.0 20.0 460.0 2.82 64.86
Total 2484 1863 99 80 1942.5 11 274
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Pollutants (LbIMM BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (TonsNr)
AP-srz
TSP 0.100 0.003 0.004 0.003 0.003 0.014
PM-10 0.100 0.003 0.004 0.003 0.003 0.014
PM-2.5 0.100 0.003 0.004 0.003 0.003 0.014
Sox 0.141 0.004 0.006 0.005 0.005 0.019 _
Ncx .320 0.010 0.013 0.011 0.010 0.044 O yy
vOC o 36 0.011 1 0.014 1 0.012 1 0.012 0.049 p.0//
CO 0. 0 0.027 1 0.034 1 0.028 1 0.028 1 0.116
HazardouslToxlc Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total ijY0711/G QU t/�
Air Pollutants (LbIMM BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 2.52E-05 0,001599 0,001999 0.001670 0.001634 0.007 /too f( 2.-5
Acrolein 7.88E-06 0.000500 0.000625 0.000522 0.000511 0.002
0 Benzene 7.76E-04 0.049237 0,0611547 0.051426 0.0503311 0.213
Benzoa rene 2.57E-07 0.000016 0,000020 0.000017 0.000017 0.0001
Beryllium 3.00E-06 0.000190 0.000238 0.000199 0.000195 0.001 '••' _ fo
Cadmium 3.00E-06 0.000190 0.000238 0.000199 0.000195 0.001 h1 L�ttQ RE-y
Formaldeh de 7.89E-05 0.005006 0.006258 0.005229 0.005117 0.022
Na thalene 1.30E.04 0.008249 0.010311 0.008615 0.008432 0.036 / `1
Toluene 2.81E-04 0.017829 0.022287 0.018622 0.018226 0.077
X lene 1.93E-04 0.012246 0.015307 0.012790 0.012518 0.053 D E
C��f tyI)urY1 se SY17n/Il """'
Green House Gas Pulutants .fj� � I
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total 5���nl v rr' �,yy1le r)
LbIMM BTU tons r tonsl r tons/ r tons/ r tonsl r E- 3
CO2 43.990 1.3956 1.7445 1.4576 1.4266 6.02
Methane 0.009 0.0003 0.0004 0.0003 0.0003 0.00123
(CH4)
Nitrous Oxide 0.001 0.0000 0.0000 0.0000 0.0000 0,000137
(N20) See tdlaciuc�S1ytiaJl-
u tCAk CP
H:\EnvironmentaKAir PermMAir Repons\Annual Air Emissions Inventory\2016 Repon\2016 AAE Calc Page 1

Annual Air Emissions Inventory
Facility ID#: 0800044 0
PK- Generator : OS-12 rW adt dtWaS,qd l�
Year: 2016 I, � >,,,tOyy) C�;wm,
Total Run Time: 71.1 Hrs/Yr N � rr'��p� 1�,f/ '
Efficiency: 75 % o , Z L
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Emisson Emisson
Hazardous/
Fuel Usag a Hours VOC Criteria Factor Pk-Gen Toxic Air Factor Pk-Gen
Month Pollutants (Lb/MM (Tons/Yr) (Lb/MM (Lbs/Yr)
(gallons) Operated (Lbs.) BTU Pollutants BTU
TSP 0.1 0.0361 Acetaldehyde 2.52E-05 0.0182
Janua : 144 2 7.50 PM-10 0.1 0.0361 Acrolein 7.88E-06 0.0057
-February: 396.0 5.5 20.62 PM-2.5 0.1 0.0361 Arsenic 4.00E-06 0.0029
March: 144.0 2.0 7.50 Sox 0.141 0.0509 Benzene 7.76E-04 0.5604
April: 396.0 5.5 20.62 Nox 3.2 1.1555 Benzo a rene 2.57E-07 0.0002
May: 108.0 1.5 5.62 VOC .090126 I ojao0 , Beryllium 3.00E-06 0.0022
June: 1188.0 16.5 61.87 CO 0.85 0.3069 Cadmium 3.00E-06 0.0022
July: 540.0 7.5 28.12 Formaldehyde 7.89E-05 0.0570
August: 1018.0 14.2 53.02 Na thalene 1.30E-04 0.6939
September: 792.0 11.0 41.25 Toluene 2.81 E-04 0.2029
October: 108.0 1.5 5.62 X lene I 1.93E-04 1 0.1394
November: 144.0 2.0 7.50
December: 144.0 2.0 7.50
Total: 1 5122.0 71.2 11266.8
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr I Gals/Yr I MM Btu/Hr MM Btu/Yr
Pk-Gen Pk-Gen 1 2670 2003 71.1 72.0 1 5122.0 1 10.15 722.20
Green House Gas Pulutants for Peak Generator C�?wrn16 6tvcy 2.17
GHG Pollutant Emisson Factor Ibs/yr tons/y
(Lb/MM BTU) r J PU d (D S E"3
CO2 43.990 31769.67 15.88
Methane
(
0.009 6.50 0.0032
Nitrousus Oxide 0.007 5.06 0.00253
(N20)
a

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only! l�
Year: 206
Total Run Time: 26.1 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 400
Number 2 Fuel: 141000 Btu/Gal d a�
F,� S3� >�
Month Gallons Hours Gallons/ VOC � �,y���,,, �
Used Operated hour (lbs.) Z 'b -O4, - "
January: 80.0 4.0 20.0 4.166 ou
February: 100.0 5.0 20.0 5.208
March: 40.0 2.0 20.0 2.083
April: 50.0 2.5 20.0 2.604
May: 30.0 1.5 20.0 1.562
June: 30.0 1.5 20.0 1.562
July: 40.0 2.0 20.0 2.083
August: 31.0 1.6 20.0 1.614
September: 30.0 1.5 20.0 1.562
October: 30.0 1.5 20.0 1.562
November: 30.0 1.5 20.0 1.562
December: 30.0 1.5 20.0 1.562
Total: 521. 1 26.1 1 20.0 27.1
Heat Rate
FP ID# Bhp hp HrlYr Gals/Hr Gals/Yr mm mm
Btu/Hr BtulYr
FP 1 285 214 26.1 20.0 521.0 2.82 1 73.46
Criteria Emisson Factor (Lb1MM FP
Pollutants BTU) (Tons/Yr
TSP 0.31 0.011
PM-10 0.31 0.011 N
PM-2.5 0.31 0.011
Sox 0.152 0.006
Nox 4.41 0.162
VOC 1 0.36 0.013
CO 0.95 0.035 Green House Gases
Hazardous/Toxi Emisson Factor (Lb/MM FP GHG Emisson Factor E101
tons/ r
c Air Pollutants BTU) (Lbs/Yr) Pollutant K /MM BTUCO2 73.960 5.990
Acetaldehyde 7.67E-04 0.056 Methane 0.003 0.000243
Nitrous
Acrolein 9.25E-05 0.007 Oxide 0.0006 0.000049
(N2O)
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.069
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002 � �
Formaldehyde 1.18E-03 0.087
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.030
X lene 2.85E-04 0.021
C/uLT�„e 6-6t Q
h7ci-gP zZE- y

Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4,OS-5, OS-6 OS-10 OS-28 OS-29
OS-13.OS-14 OS-15 OS-16 OS-20 05-21 OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18.OS-19 INCLUDED WITH OS-10•OS-30 INCLUDED WITH 91S-28
Year: 2016
Info: Lbs/Gal= 5.60
Monthly Inventory of LP Hexane-</=40%n-Hexane loallonsl,
Month I n
Beginning
ventory Received Max Used Ending Inventory
Januss : 9979 3571 74525 3365 10185
Februa 10185 3489 75207 3900 9774
March: 9774 3496 72985 4470 8800
April: 8800 4043 7 6637 3 886 9657
May: 9657 53114 3636 6021
June: 6021 3556 52674 3702 5875
July: 5875 10551 90343 36D4 12822
Au oust: 12822 70521 4259 8563
Se [ember. 8563 7154 86444 4414 11303
October: 11_3 82167 2308 8995
November. 8995 7101 88528 2355 11741
December: 1 3741 1 f 75576 1 2892 10849
Monthly Inventory of HP Hexane-<I-95%n-Hexane Wallonsl•
Month Beginning Received Max
Invento Lbs Used Ending Inventory
January: 5886 32263 5866
February: 5866 32263 5866
March: 5866 32263 5866
April: 5866 32263 5866
May: 5866 32263 5866
June: 5866 32263 5g6g
July: 5866 32263 5866
Au ust: 5866 32263 5866
September: 5866 32263 5866
October: 5866 32263 5866
November: 5866 32263 5866
December. 5866 32263 5866
Monthly Inventory of IsoHexane-</-5%n-Hexane laallonsl�
Monts 1nvgentorV - Received Lbs Used Ending Inventory
Janus 48405 18723 369204 22473 44655
Februa : 44655 14760 326783 19918 39497
March: 39497 26162 361125 30035 35624
April: 35624 13826 271975 15M 33850
May: 33850 20488 298859 26402 27936
June: 27936 33741 339224 35693 25984
July: 25984 12852 213598 3056 35780
August: 35780 20605 310118 19883 36522
Se tember: 36522 32166 377784 23303 45385
October: 45385 21085 385585 23316 43154
November: 43154 1 20855 I350950 1 23231 40578
December. 1 40578 1 10775 1 282442 6687 44686

Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers iLbs 1: /
Percent n-Hexane: 1.480 JJJ
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted lbs. Emitted Lbs.
Janus 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
July: 0.00 0.00
Au oust: 0.00 0.00
September. 0.00 0.00
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Average SDIV101 1DIV/01 0.00 0.00
Total 0 0.00 0.00 0.00
Total Hexane Values
Gallons of LP Hexane Used: 1 42091.00 1 Gallons of N-Haxa-n7U-%-ad--.- -F 43294.71
Gallons of HP Hexane Used: 0.00 Lbs.of N-Hexane Used; 238120.92
Gallons of IsoHexane Used: 249557.00 Gallons of Hexane Isomers Used: 260313.27
Total Gallons of Hexanes Used: 291648.00 1 Lbs.of Hexane Isomers Used: 1431723.01
Total Lbs.of Hexanes Used: 1604064
Sclareolide iSDEI Operation:OS-5
Gallons Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Montle y Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane Emitted
Isomers
Operated Infeed Used Hazardous Emitted Emitted Emitted
(Lbs.) (Lbs.)
January: 31 86402.9 60282.2 3365 18507.5 38.8 160.00 17627.5 6839.47 10788.0
February: 29 82590.2 60293.2 3900 21450.0 38.7 290.00 19855.0 7683.89 12171.1
March: 31 82210.8 60064.4 4470 24585.0 38.6 275.00 23072.5 6905.99 14168.5
April: 30 79832.3 82493.2 3188 17523.0 38.7 260.00 16093.0 6227.99 9665.0
May: 31 91316.9 68776.4 3636 19998.0 38.7 245.00 18650.5 7217.74 11432.8
June: 30 86314.4 66055.0 3702 20361.0 38.7 310.00 18656.0 7219.87 11436.1
July: 29 69913.9 52614.5 3604 19822.0 38.76 280.00 18282.0 7086.10 11195.9
Au ust: 31 89105.0 69202.3 4259 23424.5 37.7 291.00 21824.0 8227.65 13596.4
September: 30 80587.9 60786.0 4414 24277.0 37.35 120.00 23617.0 8820.95 14796.1
October: 20 43818.1 33134.2 2308 12694.0 37 160.00 11814.0 4371.18 7442.8
November: 20 43998.2 32430.2 2355 12952.5 36.8 0.00 12952.5 4766.52 8186.0
December: 23 46258.3 34293.6 2892 15906.0 120.00 15246.0 5610.53 9635.5
Averse 28 5 55035.4 3507.6 19291.7 38.051 209.250 18140.833 6914.823 11226.01
Total 336 882348.9 D 660425.3 42091 231500.6 2511.000 217690.000 82977.875 134712.12
I WILY
IY\ (1� 1 3 9?) ul 1p1S � �1 5
LcSSw»� ,rl� S (�/Xa� �a7 ��JN Cn �°ir7f VS/ i�rrr
insl � gl jakirl)
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Page 3 of 5
Sclareol Recrvstallization ISFGf Operation:OS-6
Gallons Monthly Monthly Monthly
#Days Lbs.SFG Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Inroad Lbs.SFG Product Used Lbs.Hexane Used %n-Hexane Sent as Emitted Emitted
W Isomers
Hazardous (Lbs) (Lbs) Emitted
January: 0.0 0.0 0.00 0.0
February: 0.0 0.0 0.00 0.0
March: 0.0 0.0 0.00 0.0
April: 0.0 0.0 0.00 0.0
Ma : 0.0 0.0 0.00 0.0
June: 0.0 0.0 0.00 0.0
July: 0.0 0.0 0.00 0.0
Atioust. 0.0 0.0 0.00 0.0
September: 0.0 0.0 0.00 0.0
October. 0.0 0.0 0.00 0.0
November: 0.0 0.0 0.00 0.0
December: 0.0 0.0 0.00 0.0
Averse #DIVI01 #DIVI01 #DIVl01 #DWI01 0.0 #DIVl01 #DIVIOf 0.00 0.00 0.00
Total 0 0 0.0 0 0 0.00 0.00 0.00 0.00
Rotocel&Recovery Operations:OS-4 1Sq S IP
Gallons Monthly
i Monthly Monthly
#Days Lbs.Sage Lbs.Saga Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Processed Product Used Lbs.Hexane Used %n-H some Sentas Emitted Emitted Isomers
(INFEED) Hazardous Waste (Lbs) (Lbs) Emitted
January: 31 12769900.0 114902.0 22473 123601.5 0.487 123601.5 849.1 122752.4
February: 22 8393630.0 74636.0 19918 109549.0 0 1 14.50 109469.3 667.8 108801.5
March: 29 9897403.0 91509.0 30035 165192.5 0. 94 165192.6 816.1 164376.4
April: 18 6711014.0 49773.0 15600 85800.0 1.106 50.90 86520.1 945.9 84574.2
May: 31 13018810.0 1 89394.0 26402 145211.0 1 9 145211.0 2889.7 142321.3
June: 30 17604170.0 85149.0 35693 196311.5 .5 550.50 193283.8 4832.1 188451.7
July: 16 4350000.0 42770.0 3056 16808.0 211 16808.0 354.6 16453.4
August: 31 13485000.0 97866.0 19863 109246.5 06 109246.5 2250.5 106996.0
September. 30 13050000.0 100345.0 23303 128166.5 .9 128166.5 2435.2 125731.3
October: 29 12615000.0 116184.0 23316 128238.0 157 128238.0 2013.3 126224.7
November: 30 13050000.0 105139.0 23231 127770.5 151 10770.5 1929.3 125841.2
December: 27 11745000.0 69535.0 6667 36668.6 122 36668.5 447.4 36221.1
Averse 27 1139 88105.2 20796 11 1.,0 20 114098.0 1702.6 112395.4
Total 324 49927 1057262.0 249557 1615.90 136.9176.1 20430.9 1348745.1
Lbs.Hex per day exiting Mineral Accounts of Hexane S,b S/6/y�
Oil Scrubber 158.76 fv. Emitted 190402 41 " 3y 79, 8 ih S
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 51439.536 Accountable Lbs.of N-Hex Emitted:
Lbs.of N-Hex exiting MO Unit: 761.18 Accountable Lbs.of Hexane R87584.93 1Isomers Lost:Lbs.of Hex Isomers exiting MO 50678.36 Fugitive Lbs.Hexane Emitted:Unit:
Lbs.Hexane par Lbs.of Spent 0.000930 Fugitive Lbs.n-Hexane Emitted:Sae from Desolvitizer tests: 0 '�Lbs.Hexane in Spent Sage: 127177.43 ug the s. eed, somars /(5 9 33
1. Emitted,
Lbs.N-Hexane in Spent Sage: 1881.91 Accountable and Fugitive Lbs. 1389176.05
Hexane Emitted:
Lbs.Hexane per Day from A-1 0.000815 Accountable and Fugitive Lbs. 20260.38
Vent Cond. N-Hex Emitted:
Lbs.Hex Exiting A-1 Vent: 0.264 Accountable and Fugitive Lbs.Hex 1348915.67
Isomers Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.003907
Gallons Water sent to W Wi: 10093507
Lbs.Waste Water persteL lr .01 �13I25G 3. Dft,-� - 193882,►( Gcuw�abk ' l Q
Wt%of Hexane in Waste Wateater:: 0.014
Lbs.Hexane Lost In Waste Water: 11785.18 (fllgk f *A,07 `�Oo
Lbs.N-Hexane Lost In Waste 17439 )jj WlNR
Water:
i, t� / /, S/ y3J .21f lbs hcaar`t
(58.76 �6S /IFI(GiN/dlr1 aa 4&/4Q SGrvi&dA (3Z1 d.+y5a-p/U"�1 ZS 7 �a»s puJ STacIL/
t uv /.4/Y7 /, = 7G i, 3 /b s rl-h1�y out /
4_ ",�,,,, can to
(1culd 501-"Co) t✓.&, / O�aina/ fo WWrh/ N0.3 heivfti 'lo,n Se�Tflylafl�io�
372 5&3. S /0 /'1"6-e
Accaurifwblt s /,,71»[. 1b s f�s"�` .f Si y3�,s 3 !6s { sfU�l� /i��s.1 A)
(/)/WT P
4 -,.w79,j /b j h h&3 w2*2�e = ,-193 t581.11 /s s

Page 4 of 5
Concrete Operations:OS-4
Gallons Monthly Monthly Monthly,
#Days Lbs.Concrete Lbs.Concrete Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Lbs.Hexane Used %n-Hexane Sent as Isomers
Operated Indeed Product Used Emitted Emitted
Hazardous We to (Lbs.) (Lbs.) Emitted
January: 0.0 0.0 0.0 0.0
February: 0 0.0 0.0 0.0
March: 0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0 0.0 0.0 1 0.0
July: 0 0.0 0.0 0.0
August: 0 0.0 0.0 0.0
September. 0 0.0 0.0 0.0
October: 0 0.0 0.0 0.0
November: 0 0.0 0.0 0.0
December: 0 0.0 0.0 0.0
Averse #DIV101 #DIV/01 #DIV101 #DIV/01 0.0 #DIVl01 #DN101 0.0 0.0 0.0
Total 0 0 0.0 0 0.0 0.00 0.0 0.0 0.0
Lbs.Hexane per Day from A-1 0.000815 Accountable Lbs.of Hexane Lost: 0.00
Vent Cond.
Days A-1 Operated: 0 Accountable Lbs.of N-Hex Lost: #DN/01
Lbs.Hex Exiting A-1 Vent: 0.000 Accountable Lbs.of Hexane Isomers Lost: #DNI01
Liza.N-Hex Ez1U A-1 Vent: #DIV/0! Fugitive Lbs.Hexane Lost: 0.00
Gallons sent to WWT: Fugitive Lbs.n-Hexane Lost: #DN/OI
Lbs.Waste Water per Gal.Waste 8.34 Fugitve Lbs.Hexane Isomers Lost: #DN/01
Water:
Accountable and Fugitive Lbs.
Wt%of Hexane in Waste Water. 0.014 Hexane Emitted: 0'00
Lbs.Hexane Lost in Waste Water: 0.00 Accountable and Fugitive Lbs. #DNI01
N-Hex Emitted:
Lbs.N-Hexane Lost In Waste #DIV/01 Accountable and Fugitive Lbs.Hex #DN/01
Water: Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Santos Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September; 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Averse #DIV101 #DN/01 #DIV/01 0.00 #DNI01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00

Page 5 of 5
Botanical Extraction Operation:OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sant as Hexane n-Hexane Hexane
Monty Operated Product Used Used '4 n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
A ril: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
Au ust: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Averse #DIVI01 #DIV/01 #DIV/01 0.00 #DIV/01 #DIVI01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00
Plant Nutrient Extraction IM-1310peration:OS-29
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.PNE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Janus 0.0 0 0.00 0.0
February: 0.0 0 0.00 0.0
March: 0.0 0 0.00 0.0
April: 0.0 247.3 0 0.00 0.0
May: 0.0 0 0.00 0.0
June: 0.0 0 0.00 0.0
July: 0.0 0 0.00 0.0
August: 0.0 0 0.00 0.0
September. 0.0 0 0.00 0.0
October. 0.0 0 0.00 0.0
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Avers a #DIV/01 #DIV/01 #DIVI01 0.0 #DIVI01 247.3 0.000 0.00 0.00
Total 0 0 0 0.0 247.3 0.000 0.00 0.0g
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1396463.64 Total Lbs.Hexane Released: 1586866.05
Fugitive Lbs.N.Hexane Emitted: #DN/01 Total Lbs.n-Hexane Released: #DIV/01
Fugitive Lbs.Hexane Isomers #DIV/01 Total Lbs.Hex Isomers Released: #DIV/01
Emitted:
Accountable Lbs.Hexane Lost: 190402.41 Total Lbs.Hexane Sent Off Site: 18558.10
Accountable Lbs.n-Hexane Lost: #DIV/01 Total Lbs.N-Hexane Sent Off Site: #DIV/01
Accountable Los.Hex Isomers #DIV/01 Site:
s. ex Isomers en #DIV/01
Lost: Site:
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 60706 1885296 10369126.1
February: 55137 2096764 11532201.6
March: 50290 2163656 11900107.9
April: 49373 1692570 9309137.7
May: 39823 1204636 6625495.3
June: 37725 1196858 6582720.9
July: 54468 2542332 13982824.9
August: 50951 12666592 11036257.E
Se [ember: 62554 2744892 15096903.9
October: 58015 1142503 6283765.5
November: 1 60185 1780416 9792286.6
December: 1 61401 1726187 9494029.1
Max Hexane Max N-Hexane I Max N-Hexane
Maximum Hexane On-Hand Gal. al. Lbs.
62554 2744892 15096904

1
Pane 1 0l
Annual Air Emis 08on s In ntory
MethanolFac:OS S-7OS-s 0535 pSY �
5-13 OS-14 O -15 -16 -17 S-27 S-32INCLUDED WITH OSA
Year: 2016
Imo: Lbs/Ga1= 6.62 Specifics Gravity-0.793
Monthly Inventory of Methanol foallonsP Methanol Used in SDA-3A
Alcohol
Month Beginning Received Max Used Recovered Inventory Ending Methanol
Inventory (Lbs( Inventory Emitted(Lbs.)
January: 9074.0 15656.0 163713 12449.0 12281 January: 0.00
February: 1228190 14350A 176298 10994.0 15637 February: 0.00
March: 15637.1 7781.0 155028 11195.2 12223 March: 0.00
April: 122229 7753.0 132240 8027.2 11949April: 0.00
May 1194807 7486.0 128557 13169.5 6265 May; 0.00
June: 0265.2 12798.8 126203 8878.7 10185 June: 0.00
July: 10185.3 7780.0 118930 11015.0 09M July: 0.00
Au ust: 3.03 3121357 i86.00 3125
Se 5 Au ust: 0.00
embe 0 r: 31245 3 .00
October: -359.4 13149.0 84667 14444.5 -1S55
October. 0.00
November: 1 -1655.0 1 19650.7 1 110131 1 13897.8 4298 November. 0.00
December: 4298.0 7910.0 80817 10134.0 2074 December: 1 0.00
Maximum Gallons On-Hand: 26631.1
Maximum Lbs.On-Hand: 176297.882
Gallons Used perYear: 1 141982
Lt 1 939919,9132 1
clareol Recovery O erasion: 1 OS
Accountable
/Days Gallons M90H Lbs.McOH Avg.GPM Sent Lbs.M90H to Avg.% Total Gal. Monthly Avg. Emissions of Total Lbs. Total Lbs
Month Operated Used Used to WWTP WWTP Methanol in Water to Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP (O Emissions
17
Janus 31 12449 82412.38 1.2 27314.3 7.70 218928 98.4 437.0288 55098908 55535.109
Febnlary 22 8024 53118.88 1.2 17404.5 7.61 205712 98.7 226.2585 36714.38 35940.639
March 29 9096 60215.52 1.2 23251.4 7.53 183359 98.7 302.2682 36964.12 37266.388
April 18 5182 34304.84 1.2 9344.5 4.54 105094 99.8 18.689 24960.34 24979.029 ` 2 L
May 31 8475 56104.5 1.2 7949.7 2.24 173373 99.8 15.8994 48154.8 48170.899 05 J J
June 30 1 6017 53072.54 1 0.97 6874.6 2.49 165440 99.8 13.7492 48197.94 46211,689
Jul t0 5535 36641.7 1.19 7384.5 3.97 107494 99.4 44.307 29257.2 29301,507
Au ust 31 1122e 74316.12 0.96 18819 6.54 211560 99.4 111.714 5559Z12 55808,834 q Li
September 30 11108 7353C98 0.95 15438 5.68 189289 99.5 77.19 58098.96 58174.15
October 29 12218 80883.16 1.08 25948.5 7.88 205839 98.6 389,2275 5493486 55323,888
November 30 11301 74812.62 1.83 33552 6.56 203449 97.9 704.592 41280.62 41965.212
December 27 10134 67087.08 1.47 23767 5.59 192507 98.6 332,738 43320,08 43652.818
Averse 27.00 9397.08 62208.69 1.20 19070.67 5.69 180170.17 99.04 222.81 44360.83
Total 324 112765 746504.3 216846 2162042 2673.6616 '629856.3 32329.98
Concrete Operation:OS-4
Accountable
/Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg.% Total Gal. Monthly AV Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP, WIN
in Water to Remov MaOH from Fugitive Emissions
W WWTP Efficlen y WWTP Emissions
(OS-17)
January 0 0.00 0 0
Febmary 0 1 0.00 0 0
March 0 1 0.00 0 0
April 0 1 0.00 0 0
May 0 0.00 0 0
June 0 0.00 0 1 0
July 0 0.00 MO.) .
Au ust 0 0.00
September 0 0.00
October 0 0.00
November 0
December 0 0.00
0.00
Average /DW/01 YDIV101 0.00 /DIVI01 /WVI01 MDIVI01 MOIV/01 MD I01 0.00
Total 0 0 0 0 0 0
ua��wu�'1°.✓ 1 as s

Page 2 of 2
,l
EVG Operation:
S`11
Accountable
t Days Gallons M90H Lbs.MaOH Gallons McOH s.MOOR to Emissions of Total Lbs. Total Lbs.
Mom W Operated Used Used to VVWTP WWTp MoOH from Fugitive Emissions
WWTP Emissions
(OS-17)
January 0 0 0.00 0.00 0.00 0.00
February 18 2970.0 19881.4 2910.6 19268.17 385.36 393.23 778.59
March 10 2099.2 13896,704 2057.216 13818.77 272.38 277.93 550.31
April 30 2815.2 18835.224 2788.296 18458.52 369.17 376.70 745.87
May 31 4694.5 31077.59 46W.61 30458.04 809.12 621.55 1230.67
June 4 861.7 5704A54 WAN 6590.38 111.81 114.09 22590
July 27 5480.0 36277.5 5370.4 35552606 711,04 725,55 1436.59
Audiat 27 564&0 37356.5938 5530.1302 3eW9.48 732.19 747.13 1479.32
September 0 0 0.00 0.00 0.00 0.00
October 12 2226.6 14740.2906 2182.0974 14445.48 288.91 294.81 583.72
November OE
2398.6 15885.3596 2348.8484 15548.05 310.98 317.31 828.27
December 0 0 0.00 0.00 1 0.00 10.00
Ave, 19.11 3248.3 16117.93 2386.04 15795.58 15.9 838.27
Total 172 29216.8 193415.216 189548.91 3790.94 3888.30 7659.24
PNE Operation:OS.7
Accountable
N Days Gallons MOOH Lbs.MCOH Gallons M90H Lbs.McOH to Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP M90H from Fugitive Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.00 0.00 0.00 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 1 0.00
July 0 0 0.00 0.00 0.00 0.00
August 0 0 0.00 0.00 0.00 0.00
September0 0 0.00 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00 0.00
November 0 0 0.00 0.00 0.00 0.00
December 0 0 0.00 0.00 0.00 0.00
Avera a NDIV/01 tDNl01 0.00 0.00 0.00 0.00 0.00 0.00
Total 0 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol OPerations
Total Lbs.M90H Thru System: 3669184.00 Lbs.Fugivttve Emissions from EVG: 3868.30
Total s.M90H Treatedat
VJWTP: 408394.91 Lbs.Fughtive Emissions from Recovery: 529558.30
Calculated emova c ncy
of WWTP: 99.04 Lbs.Fugitive Emissions from Concrete: 0.00
Lbs.Accountable Emissions
from W WTP OS-17: 6464.60 Total Lbs.Fugitive Emissions: 5W198.27
Lbs.of Emissions from W WTp
DuringRecove : 2673,86 Total Lbs.MOOH Released: 542882.87
i.os.of emissions from WWTP
During Concrete Recovery: 0 Total Lbs.MCOH Recycled OnShe: 3152789.09
Lbs.Of Emission.from W WTP
1st Aention Chamber OS-17: 3790.94
s.Of Emissions from Misc., 0
Lab:

Annual Air Emissions Inventory
Facility ID#:0800044 /
Chloroform : 0£-9
Year: 2016
EV 6 05Y 1
Info: Lbs/Gal= 12.35
Monthly Inventory of Chloroform(pounds):
Lbs.
Beginning Recovered Chloroform Ending Infeed Product
Month Inventory Received Max New Used Used Recovered Sent as Haz Total Used Inventory (Lbs.) (Lbs.)
Waste
January: 24832 24832 0.0 24832
February: 24832 13500.0 38332 4361.0 3782.0 1800.0 6343.0 28389 2284 1100
March: 28389 28389 2478.0 1581.0 4059.0 24330 1735 1012
April: 1 24330 24330 3986.0 3667.0 450.0 7203.0 16227 2259 1320
May: 16227 16227 6250.0 6080.0 12330.0 3897 3764 2178
June: 3897 2700.0 6597 3552.0 22996.0 -19444.0 26041 866 480
July: 26041 13500.0 39541 6723.0 6594.0 13317.0 1 26224 1 3862 2090
August: 26224 26224 6670.0 6957.0 9100.0 4527.0 21697 4124 2464
September: 21697 21697 107.0 1735.0 11960.0 -10118.0 31815
October: 31815 10800.0 42615 2589.0 2683.0 5272.0 37343 1561 946
November: 37343 37343 4525.0 2662.0 7187.0 30156 1545 836
December: 30156 30156 0.0 30156
Lbs.of chloroform used during the year: 32926
Lbs.of chloro.used by Misc.,CIA,and R&D: 0
Lbs.of chloro.used by EVG: 32926
Lbs.of EVG Infeed 21999 C ZJI Lbs.EVG Produced: 12426 /
Lbs.of chloroform sent to hazardous waste: 2250
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted during year:OS-9 f 30676
/✓IJn/ red G 41�'7 PeA
y ��
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Heptane : OS-6.OS-7, OS-10
Year: 2018
Info: Lbs1Gal= 5.70
MonthN Inventoryof He tans(as llons:
Month Received
Beginning Max Recovered Disposed l Ending
InventoryLbs New Used Recovered
Used Sent off-She Inventory
January: 18331 1 3078 122033 4457.4 16952
February: 16952 11687 163243 5027.2 23612
March: 23612 328 136458 1607.0 22333
April: 22333 127298 5162.3 368 16813
May: 16813 4454 121220 3075.0 18192
June: 18192 6818 142554 4372.6 20637
July: 20637 3079 135179 5238.1 2648.2 2505 188 1
Au oust:, 18621 413 108489 3158.1 1422.0 17297
September: 17297 98593 -2024.1 1 19321
October: 19321 110131 3530.0 16111 14181
November: 14181 3289 99577 8394.0 11076
December: 11076 1323 70673 6675.0 5724
SFG 3 er n:OS-7 N� M
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Heptane Heptane
Month Operated Infeed Product Heptane Used %n-Heptane Heptane Sent as Emitted as
Used Recovered Hazardous VOC
Waste )Lbs.)
Jan - 45449 32880.0 2314.4 1 13191.9 13191.85
February, 4599 39701.0 2812.2 16029.5 16029.54
March: 11 1696 10474.0 4.0 22.8 22.80
April: 30 44692 42869.0 2744.3 15642.5 1 357.9 13602.48
May: 31 49689 45199.0 2478.0 14124.6 14124.60
June: 27 41586 36482.0 3796.6 21640.6 21640.62
July; 31 44891 40647.0 2831.1 16137.3 2648.2 1042.47
August: 14 20116 17780.0 1460.1 8322.6 1422.0 217.17
September. 13 18048 12974.0 2638.9 15041.7 15041.73
October. 0.0 0.00
November. 13 18048 12974.0 2039.0 11622.3 11622.30
December: 26 31020 22921.0 723.0 4121.1 4121.10
Avera a 23 28845.5 2187.4 11324.7 #DIV/01 2035.1 357.9 9221.39 t
Total 252 376493 315101.0 23841.8 135896.9 4070.2 357.9 110656.67 .S.S, 'i3 i�T j
Botanical Extraction Operation:OS-10
Lbs. Gallons Gallons Gallons Heptane
Monthly ns Monthly
Month #Days Botanical Heptane Lbs.Heptane %n-Heptane Heptane Hap no Sent Emitted as n-Heptane
Operated Product Used Used as Hazardous Emitted
Recovered Waste VOC (Lbs.)
January: 0.0
February: 0 0.00
0.0 March: .0 0 0.00
0
April: 0 0.00
0.0 0 0.00
May: 0.0 1 0 0.00
June: 0.0
0 0.00
July: 0.0 0 0.00
August 0.0
0 0.00
September. 0.0 0 0.00
October. 0.0
0 0.00
November: 0.0 0 0.00
December: 0.0 0 0.00
Avera a #DN101 #DIV/01 #DN/01 0.0 #DNI01 #DIV/0l #DN/01 0.00 0.00
Total 0 0.00 0.00 0.0 0.0 0.0 f 0.00 1 0.00

SFG Ooeratlon:OS-6 as 39 04 0,5V5
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs Heptane Gallons Heptane Heptane
.
Month Operated Infeed Product Heptane Used y,n-Heptane Heptane Sent as Emitted as
Used Recovered Hazardous VOC
Waste
January: 29 82757 71585.0 2143.0 12215.1 12216.10
February: 29 80683 73359.0 2215.0 12625.5 12625.50
March: 31 85027 74087.0 1603.0 9137.1 9137.10
April: 30 73621 64860.0 2418.0 13782.6 13782.60
May: 9 25253 20446.0 597.0 3402.9 3402.90
June: 9 23060 18078.0 576.0 3283.2 3283.20
July: 31 69129 66881.0 2407.0 13719.9 2505.3 -560.31
Au usC 31 64345 53123.0 1698.0 9678.6 9678.60
September: 30 67194 58249.0 -4663.0 -26579.1 -26579.10
October. 30 65437 55482.0 3530.0 20121 1610.5 10941.15
November: 28 59480 52916.0 4356.0 24823.5 24823.50
December: 27 73310 52417.0 5952.0 33926.4 33926,40
Avers s 25 64115 55124 1902.6 10844.73 #DN/01 #DNI01 2057.900 8889.72
Total 314 769378 1 661483 22831 A 130136. 00 0.0 4115.800 1 106676.64 1 53,3 3 1Vn S
PNE(M-13t O eration:OS-7
Gallons Monthly
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Heptane Sent Heptane
Month Heptane %n-Heptane Heptane Emitted as Process
Operated Product Used Used Recovered as Hazardous VOC
Waste
January: 0.0 0.0
February: 0.0 0.0
March: 0.0 0.0
April: 0.0 0.0
May: 0.0 0.0
June: 0.0 0.0
July: 0.0 0.0
August, 0.0 0.0
September: 0.0 0.0
October: 0.0 0.0
November: 0.0 0.0
December: 0.0 0.0
Avers a #DNI01 #DIVI01 #DIV101 0.0 #DNI01 #DIVI01 #DNI01 0.0
Total 0 0 0.0 0.0 0.0 0.0 0.0
SQe >L�io �� Ldc-S /n 7` 0 I nSAZA0W 1pe f-1S
U0 % j fa�� ���
�2, 476 y/e7n l /Z yg funs ti� {,�,�57-6

Annual Air Emissions Inventory
Facility lD#:0800044
EthV1 acetate : OS-6 OS-7,OS-10, OS-28
Year. 2016
Info: LbslGal= 7.50
Monthly Inventory of Ethyl acetate(pounds): 3J12o 2
Month B"innind Inventory Bulk Drums Ethyl acetate Used in SDA35A
Alcohol
Total Beginning Beginning New Recovered Recovered Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Disposed (Lbs) Used(Lbs.) Inventory Month Emitted(Lbs.)
Inventory Inventory Inventory
January: 1962 1962 3272.0 1909.00 5234 1909.0 3325 January: 0.00
February: 3325 3325 0 4908.0 2275.00 8233 2275.0 5958 February: 92.82
March: 5958 5958 0 4764.0 1936.00 10722 1936.0 8786 March: 56.36
April: 8786 8786 0 3202.00 8786 3202.0 5584 Aril: 0.00
May: SW 5584 0 4764.0 1751.00 10348 1751.0 8597 May: 0.00
June: 8597 8597 0 4764.0 2555.00 13361 2555.0 10806 June: 0.00
Jul 10806 10806 0 3796.00 10806 3796.0 7010 July: 0.00
Au Et: 7010 7010 0 41.0 2444.00 11774 2444.0 9330 August; 0.00
September. 9330 9330 0 1682.00 9330 1682.0 7648 September. 52.81
October. 7648 7648 1 0 1 1 2761.00 7648 2761.0 4887 October. 15.05
November: 4887 4887 0 12800.0 2512.00 17687 2512.0 15175 November. 0.00
December: 1 15175 15175 1 0 1 1 4379.00 15175 4379.0 1n7= December. 1 0.00
Ethyl acetate Emissions by Source
Ethyl acetate Emiled Ethyl acetate[o Total Ethyl acetate
from SDA a Botan al Ethyl acetate Emitt Ethyl acetate Emitt from Ethyl acetate Emitted from Ethyl acetate Emlttad Emitted from
Botanical Extraction
Month Biomass Extracticlrl:OS-28 SDA in PNE: -7 PNE:OS-7 from SFG:npc�'' OS.10 Botanical
Extraction: St0 (Lbs.) (Lbs.) U537 (Lbs.) (Lbs. O* SLS (Lbs.) OS-
(Lbs.) 4V
Lbs.) (Lbs.)
January: 0.00 0.00 0.00 1909.00 0.00
February: 92.82 0.00 0.D0 2275.00 92.82
March: 56.39 0.00 0.00 1936.00 56.39
April: 0.00 0.00 0.00 3202.00 0.00
May: 0.00 0.00 0.00 1751.00 0.00
June: 0.00 0.00 0.00 2555.00 0.00
July: 0.00 0.00 0.00 3796.00 0.00
August: 0.00 0.00 0.00 2444.00 0.00
September: 0.00 0.00 a00 1682.00 0.00
October. 52.81 0.00 0.00 2761.00 52.81
November: 0.00 0.00 0.00 2512.00 0.00
December: 15.05 13.68 0.00 4379.00 15.05
Average 18.09 1.14 0.00 *DIV10! 26 17 •DIV/01 18.09
Total 217.08 13.68 0.00 0.00 ! 1202.00 0.00 217.08
K 217,0? Ib5
S�0

Annual Air Emissions Inventory
Facility IDB:0800044
Ethanol(200 proof)-OS-10.
Year: 2018 �-
Info: Lbs/Gal= 6.58 %SDA Ethyl acetate = 4.0
Monthly Inventory of Ethanol(gallons):
Ethyl
Beginning Recovered
New inventory Recovered Max Recovered Ending Gallons to Ethanol Acetate
Month Inventory Inventory New Received New Used Recovered Total Used Disposed
(Total) (Beginning) (Begining) Received (Lbs) Used Inventory WWT VOC(Lbs.) VOC
Lbs.
January: 20225 10506 9719 0 0 20225 0 0.0 0.0
February: 20225 10506 9719 0 0 20225 0 0.0 0.0
March: 20225 10506 9719 0 0 20225 0 &0 0.0
April: 20225 105W 9719 55 0 0 20280 0 0.0 0.0
—May: 20280 10561 9719 0 0 20280 0 0.0 0.0
June: 20280 10561 9719 0 0 20280 0 0.0 0.0
July: 20280 10561 9719 0 1 0 1 1 20280 1 0 1 ao 1 0.0
August: 20280 10561 9719 0 0 1 20280 0 0,0 0.0
September: 20280 10561 9719 14 0 0 20294 0 0.0 0.0
October: 20294 10575 9719 0 0 1 20294 0 DO 0.0
November: 20294 10575 9719 0 1
0 20294 0 1 0.0
December: 20294 10575 9719 11000 0 2598 2598 28696 2546 2.1 1 0.0
Total Gallons of Ethanol Used: 2598
Total Lbs.Ethanol Used: 17102.634 I J
Gallons sent to Hazardous Waste: 0
Lbs.Ethanol sent to Hazardous Waste: 0
Total Gallons sent to WWT: 2546
Total Lbs.sent to WWT: 32
Total Lbs.of Ethanol Emitted as VOC: 342

Botanical Extraction Operation:OS-10
Lbs.Ethyl Lbs.Ethanol
Montt #Days Lbs.Botanical Gallons EtOH. Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate Emitted as Product
Operated Product BOA Used Used Recovered W WTP Emitted as VOC
VOC
January: 0.00 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
April: 0.00 0.00 0.00 0.00
-May: 0.00 0.00 0.00 0.00
June: 0.00 0.00 0.00 0.00
July: 0.00 1 0.00 0.00 0.00
Au ust: 0.00 0.00 0.00 0.00
September 0.00 0.00 0.00 0.00
October: 0.00 0.00 0.00 0.00
November: 0.00 0.00 0.00 0.00
December. 0.00 0.00 0.00 0.00
Averse #DIV101 #DN101 #DN/OI 0.00 #DN/01 0.00 0.00 0.00
Total 0 0 0 0.00 0.0 0.00 0.00 0.00
Biomass Extraction Operation:OS-28
Lbs.Ethyl Lbs.Ethanol
#Days Lbs.Biomass Gallons EtOH. Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate
Month Operated Product SDA Used Used Recovered VJTP Emitted as Emitted VOC as Product
W
VOC
VOC
January: 0.00 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
April: 0.00 0.00 0.00 0.00
May: 0.00 0.00 0.00 0.00
June: 0.00 0.00 0.00 0.00
July: 1 0.00 1 0.00 1 0.00 0.00
August: 0.00 N167960.5813.68
0 0.00
September. 0.00 0 0.00
October: 0.00 0 0.00
November: 0.00 0 0.00
December. 2598 17102.63 . Nutrati
Averse #DIV/01 #DIV/01 2598 1426.22 #DN/01 4 28.50
Total 0 0 2598 17102.63 0.0 .68 342.05
0,5 2A

Annual Air Emissions Inventory
Facility ID6:0800044
Ethanol-SDA-35A:OS-7&OS-10
0S-18.OS.19.OS-27,OS-32 INCLUDED WITH OS-10
Year. 2016
Info: LbWGal= 6.97 .SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol laallonsl:
Monthly Bealnnina Inventory Bulk Drums
Total SDA
Total SDA Bunk SDA in Drums SDA Max SDA on SDAte Ethyl
Month Beginning Beginning Beginning SDA SDA SDA Used SDA in Drums Recovered in SDA SDA Disposed Hand Ending SDA Used SDA Used WWr SDA VOC Acetate VOC
InventoryInventory Inventory Received Transferred Received Drums Usetl Recovered Lbs Inventory (gallons) (Lbs.) (Etas.)
ry ry (Lbs) Is. (Etas.) (Lbs.)
fGaJanuary: 234025 22278.8 1123.7 160775 23403 0 0.0 0.0 0.0 0.0
February: 234025 222768 1123.7 16169.4 1340701 14729 271859 24692 14880 102225.6 1DO181.1 19517 92.8
March: 24691.9 25041.1 -349.2 5400.0 9231.0 196.0 206731 21057 9035 62070.5 60829.0 1185.0 56.4
April: 21056.9 21210.1 -153.2 144661 21057 0 0.0 0.0 0.0 0.0
mar, 21056.9 21210.1 .163.2 144661 21057 0 0.0 0.0 0.0 0.0
Jute: 21056.9 21210.1 -153.2 144661 21057 0 0.0 0.0 0.0 0.0
July: 21056.9 21210.1 -163.2 1 144661 21057 0 0.0 0.0 0.0 0.0
August: 21068.9 21210.1 .153.2 144661 21057 0 0.0 0.0 0.0 0.0
Se mbar. 21066.9 21210.1 .153.2 12338.0 8466.5 3611.5 226123 21417 8467 58164.9 570016 11 f0.5 52.8
October. 21616 9 25081.6 .3664.7 1568.7 3122.5 710.0 157917 W573 2413 16573.9 16242.4 316.4 15.0
November. 20573.1 23627.8 -2954.7 141337 2GS73 0 0.0 0.0 0.0 0.0
December: 20673.1 23 227.R .2954.7 1 1 1 1 141337 1 20573 1 0 1 0.0 1 0.0 1 0.0 1 0.0
Teel I I I I 35476.1 1 0.0 1 34227.1 1 0.0 1472.9 1 906.0 1 3511.5 1 2032677.8 1 257571.9 1 34794.0 1 239034.8 1 234254.1 1 4563.7 1 217.0
Botanical Extraction Operation:OS-10 Osy a 09110
9 Days Lbs.Botanical Gallons EtOH- Lbs.EIOW Lbs.Et0H- Lbs.EtOH- EtOH-SDA ENyl Acetate
Monty SDA SDA to ProductOporate0 Product SDA Used SDA Used L p VOC(Lbs.) VOC(Lbs.)
Jan"": 0.00 0.00 0.0 0.0
February: 15 9894.00 7947.0 54595.89 53503.97 1091.9 49.6 Deus
7 2558.00 6933.0 47629.71 46677.12 952.6 43.2 Ocean Spray
March: 29 22855.60 9231.0 63416.97 1309.00 60865.81 12422 56.4 Ocean Spray
April: 0.00 0.w 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
0.00 0.00 0.0 0.0
July: 0.00 O.9D 0.0 0.0 Total SDA Ethanol Data
August: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 35700.0
September 12 8775.50 8466.5 58164.88 57001,56 1163.3 52.5 Deus Tote)Lbs.SDA Used: 245269.0
0.00 0.00 0.0 0.0 Total Gallons 98M W 1VWr: 2273.56
October. d 2258.50 3122.5 21d51.5B 4877.70 18242.40 331.5 15.0 Decas
November: 0.00 0.00 0.0 0.0 Total Los.sate to WWr: 15619.39
December. 0.00 0.00 0.0 0.0 Total Lbs.SDA Ethanol Emitted as VOCS: 310.76
Us.Botanical Extraction Ethanol Embtetl as VOC:OS-10 318.76
Awra c 73 8868 7140 16331 3093 15619 Lbs.PNE Ethanol Emitted as VOC:OS.7 0.00
Total fi7 44342 3570 2245259 6187 9""1 4781 217
PNE Operation:OS-7
8 Days Lbs.PNE Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs.EIOH- EtOH-SDA Ethyl Acoustic
MonthOperated Product SDA Used SDA Used SDA SDA to VOC(L�.) VOC(LDs.I Product
Recovered WTI`January-, 0.00 0.00 0.0 0.0
February: 0.00 0.00 0.0 0.0
arch: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
John. 0.00 0.00 0.0 0.0
August: 0.00 0.00 0.0 GO
September 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
Oeumber. I I I 1 0.00 1 1 0.00 0.0 1 0.0
Averse I 8DN/01 I BDWIOt I 8DIV101 0.00 1 pONI01 1 0.00 1 0.00 1 0.00
Total 1 0 1 0.00 1 0.0 0.00 1 0.00 1 0.00 1 0.00 1 0.00

2016 Emissions Inventory Review / Data Tracking Form
Facile Name: Avoca Inc. Facile ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston ETH Confidential Copy Submitted?
Title V ❑!Rf YES
Initial Review/Data Entry
Enter date received into ED. Date Received: 31zilzol-7
Assigned to appropriate individual. Date Assigned: 3/2 4 /2,0/7 Date Due: 91301247
d Parser WRY submitted: One copy received with supporting documentation,certification form signed by responsible official,and
appears generally complete;9W Q„
0' Electronic copy submitted: All supporting documentation and certification form(with time/date stamp)signed by responsible
official has been received.
Comments: �Fee In vtn ✓�✓l ew n6fe5 PfffucLierl.
Inventory Review
dAll forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
L�l Contact,address,phone number changes entered into I-Beam/Facilities if necessary.
0 All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
L�l Check if SCC codes for each OS are accurate and update if needed.
0 Evaluate"U"sources for significance and address according to policy.
Calculations/forms appear to add up correctly.
LZ All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds, large emissions increase/decrease, installation
without a permit).
L�J All volatile HAPs/TAPS were included in the VOC total.
C3� Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP42,etc.).
Review facility comments and address any issues.
121' Update ED(Data Entry Main) if additional information is required(corrections due date and date received).
Check all ED QA/QC reports.
® Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained.
l2r Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
u Print and attach the facility total report.
Date Info Requested: Date Info Received: Total Days on Hold:
Date Review Complete: -7/2,*) 7 Signature: �✓ - �i�y7
Date Submitted to El Coordinator: 9/0712o1 7
Date Approved: 9/02 7 Initials: �rN

Avoca Emissions Inventory Review Notes CY2016
General Notes
• I reviewed all SCC and Unit types. I did make some changes for several OS, including but not limited to the
following:
- Wood boiler SCC changed to account for wood/bark fuel
- Engines changed to industrial category SCC
- Several process SCC were changed to"Organic Chemical Manufacturing and Processing"so I could
group them with the process area.
- Changed SCC and unit type for the wastewater aeration chamber
• I reviewed all calculations. There were no changes to Avoca's emissions factors and calculation methods in
the CY2016 inventory compared to the CY2015 inventory.
• Almost all of the plant sources have historically been given a not required to report tag in the Source screen
of ED. I'm unsure of why this was done years ago. It has not been an issue for reporting because the
inventory is set up primarily by plant area groups(boilers, generators, Biomass, Biological, SFG, SDE,
Rotocel/Recovery). Most of the sources belong to these groups. To remove this tag,the sources would have
to be pulled out of the groups they are saved to,changed to"required to report" in Source screen,and then
would have to be re-added to their respective group. I requested help from Holly Groce; per my request she
changed all of the sources in the groups to"required to report."
• Most of the process area operating scenario throughputs are in-feed tonnages to the processes(i.e.tons sage,
SFG raw Ibs sclareol, SDE raw infeed, etc.). Since Botanical Extraction uses a variety of solvents,they don't
have one specific sheet in the inventory spreadsheets that has the total Botanical Extraction throughput
(infeed or product). Brian adds up all the processes that were run in the botanical extraction area with a
variety of solvents.
• Because Avoca only reports wastewater emissions specifically at the I`aeration chamber to the WWTS
(MeOH only), I have grouped all permitted wastewater emission sources with their respective plant area.
Boilers H101-103
• Fuel oil usage increased on Boilers H101-103 by 12.9%compared to CY2015.
• For H101-103 I corrected the NOx factor to 20 lbs/MGals. The corrected emission is now 6.73 tons
NOx. The SOz emission was corrected to 0.07 ton using the 0.0014%sulfur content of fuel oil. These
corrections were also done to the CY2015 data.
• 1 applied the filterable+condensable factor of 3.3 lb PM/1000 gals= 1.11 ton PM and corrected the
data in ED.
• I changed the o-xylene emission in ED to xylene mixed isomers.
Wood Boilers
• Wood combustion in the boilers decreased 14.7%by weight in CY2016. I added a number of toxics
to ED using the DAQ spreadsheet for wood combustion. I did the same for the CY2015 inventory. If
a combustion HAP in the spreadsheet was not listed in ED, it is because the facility-wide emissions
are below reportable threshold,or the emission is negligible and won't affect the facility total.

Brian Conner and I agreed there should be a 99%control efficiency applied to the metal HAPs. I
contacted Tammy Manning to re-open the CY2015 data to apply this control efficiency as well(data
entry and re-approval of the CY2015 data is complete).
Emer¢eney Eneines
• The generators used 8.6%more fuel (in gals)than in CY2015. I corrected the NOx and VOC
emissions using AP-42 factors 3.2 lb/MMBtu and 0.08 lb/MMBtu. This same correction was applied
to the CY2015 data. The fire pump is grouped with the generators, but Avoca did not add up their
emissions for the OS. I summed the five engines' emissions and entered them into OS42. Some
metals emissions are not listed due to their emissions being negligible and not affecting the facility
totals.
• PkGEN used 15% less fuel in CY2016. I added the PkGEN GHGs to ED. I also added the PkGEN
chromic acid, lead and mercury emissions to ED. I removed control efficiencies entered for NOx,
VOC and SO2.
Process HAP Emissions
There are many hand-written review notes made within the hard copy of the inventory.
• An explanation for the heptane emissions split between point and fugitive for SFG was provided for
the CY2015 inventory, and applies again to the CY2016 inventory:
Avoca assumes that the bulk of Heptane emissions from SFG are fugitive. Based on old hexane
values and using MON batch calculations to back into it, approximately 80%of SFG heptane
emissions are fugitive and 20%are out the stacks.
• An explanation for the hexane emissions split between point and fugitive for SDE was provided for
the CY2015 inventory,and applies again to the CY2016 inventory:
As with SFG Avoca assumes that the bulk of Hexane emissions from SDE are fugitive. Based on
hexane values and using MON batch calculations to back into it,they saw approximately 17.6%of
SDE hexane emissions are out the stacks.
However, instead of taking 17.6%of the total n-hexane added up from the month-to-month tank
measurements and batch calculations,Avoca calculated the annual n-hexane emission to be the total
Ibs iso-hexane X annual average 38.051%n-hexane content. This created a smaller reportable n-
hexane fraction from point sources.
• The fugitive and point splits for hexanes from Rotocel and Recovery are briefly explained below(see
calcs in the hard copy):
Accountable emissions are those Avoca can verify along with the emissions coming out the final
stack; hexane going to wastewater, hazardous waste, or in the spent sage material. Using test data,
Avoca calculates the average hexane per day exiting the MO Scrubber was 158.76 Ibs. Then multiply
158.76 times the number of days run(324 days)out the stack. The average n-hexane content of the
solvent is used to calculate the split of hexane isomers and n-hexane.
Fugitive hexane is calculated by subtracting the accountable hexane from the total hexane used.
• Reminder: More than a third of the methanol"lost" from the Rotocel& Recovery operation goes to
WWTP. Of that,98-99% is consumed by the biological activity in the WWTP,while emitting the
remainder. The WWTP emission is calculated through the Water 9 program. The other two thirds of
methanol"lost"from Rotocel& Recovery is"fugitive." Brian has noted that some of the"fugitive"
losses are also actually going out the stack of the Mineral Oil Scrubber as well,but most of it would
be in the lines and from the tanks located in recovery

• CY2016 process VOC emissions are comprised of chloroform, hexanes,heptane,methanol, and ethyl
acetate. All of their annual emissions are determined through mass balance. Avoca uses purchasing
records, daily formulation and batch records,daily tank level measurements,waste shipment records,
process design calculations, and MACT MON formulas(fugitive and point source splits). Ultimately,
more VOCs HAPs were used in CY2016,and therefore more were emitted to atmosphere.
Facility-wide Combustion Criteria and HAPs
• The reduction in NOx,CO and SO2 emissions were due to the decreased in fuel to the wood boilers.
• The 30.8% increase in VOC emissions was due to increased chloroform,hexane,ethyl acetate,
methanol and heptane usage.
• The PM increase was due to increase fuel oil combustion in the H101-103 boilers.
• Increases in beryllium, cadmium, lead,mercury,fluorides and nickel are due to increased fuel oil
combustion in H101-103.
• Decreases in chromic acid,manganese,and all other combustion VOC HAP are due to decreased
wood combustion.
(g:\AQ\Shared\Bertie08\00044\20170907 Inventory Review Notes CY2016)

Huddleston, Betsy
From: Brian Conner <[e-mail]>
Sent: Tuesday, September 05, 2017 11:29 AM
To: Huddleston, Betsy
Subject: RE:Question on annual Emissions Inventory
Betsy,
See me responses below:
1 NOx factor changed for Boilers is good. I will replace in m files.
II E N Y
2) NOx and VOC factors changed for emergency engines is good. I will replace in my files.
3) 1 would agree that the bag-filter control efficiency used for the biomass boilers should be good for metal
emissions as well.
4) You are correct in the way chloroform losses are reported for EVG. MON losses only account for calculated
emissions based on the MON calculations per batch.The true emission inventory is based on real daily
inventories and accounts for total real fugitive and point emissions.
5) Yes,the same explanation applies for Ethyl acetate emitted from Botanical Extraction in 2016. 217.08 lbs. of
ethyl acetate was emitted from botanical extraction. All of the ethyl acetate emitted from botanical extraction
was from the denatured ethanol.There was no straight ethyl acetate solvent used in botanical extraction.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
PO Box 129
Merry Hill, NC 27957
Office: [phone]
Cell: [phone]
From: Huddleston, Betsy [mailto:[e-mail]]
Sent: Friday, September 01, 2017 3:32 PM
To: Brian Conner
Subject: Question on annual Emissions Inventory
Hi Brian,
I review all my assigned annual inventories in August and September, and yours is now the next one in line. I've made it
about halfway through, and have a few comments and questions :
1. For Boilers H101-103 I changed the NOx factor to 20 Ibs/MGals based on AP-42 and DAQ spreadsheet
reference. This same change was done in the CY2015 inventory.
2. 1 changed the NOx and VOC factors for the emergency engines to AP-42 factors of 3.2 Ib/MMBtu and 0.08
Ib/MMBtu (since AP-42 is referenced as your source for the factors). This same change was done in the CY2015
inventory.
3. In the last couple of years we have agreed to include some metals emissions in reporting to AERO for the boilers
because they were calculated above reportable thresholds. I just now noticed that we did not apply any control
efficiencies to the metals (arsenic, beryllium,cadmium, lead, manganese, nickel, etc.)for the wood boilers. I
1

i
think we can assume the bagfilter control efficiency for them, if you'd would like to. If so,then I can also go
back to last year's inventory data and apply it there as well.
4. Just to make sure I understand-the chloroform reported emissions cover process emission point and fugitive
loss. The semi-annual report for chloroform emitted under MON is based upon the required MON formula only
accounting for point loss, but not fugitive? That would account for the large gap in difference of reported
emissions?
5. On the ethyl acetate page,does the same explanation from last year apply this year in terms of there
being 217.08 lbs emitted from Botanical? Last year you emailed, "Going back and looking at my
spreadsheets, I referenced the wrong cell on the AAE Inventory Summary spreadsheet....the 30.42 lbs. of
Ethyl acetate was the average cell.The cell below that is the total which is 456.34 lbs. When looking at
my spreadsheet for Ethyl acetate,the final column labeled "Total Ethyl Acetate Emitted from Botanical
Extraction: OS-10" is the total for all Ethyl acetate from Botanical Extraction for all processes. 456.34 is
the correct total lbs. of Ethyl acetate emitted from Botanical Extraction and should replace 30.42 on page
44 of AFRO.
Thanks!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
Betsy.Huddleston 5ncdenr.gov
943 Washington Square Mall
Washington, NC 27889
PC-
-!`- 'Nothing Compares �a
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.
2

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Green House Gases Pollutants (GHG) Actual Emissions %Tons/Yr
Pollutant CAS CY 2016 CY 2015 Demini- Change
from ED from Fees mus
Methane(CH4) 74-82-8 2.14 2.52 10.0 -15.0%
Nitrous Oxide (N20) 10024972 1.35 1.54 1.0 -12.1%
Carbon Dioxide (CO2) 124389 27,323.38 29,856.90 5,000.0 -8.5%
CO2 equivalent(sum of individual GHG pollutant emission 25,209.13 metric tons
times their 1995 IPCC Global Warming Potential (GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
CO c0 21.50 24.70 0.5 -13.0%
NOx NOx 30.68 33.91 0.5 -9.5%
PM(TSP) TSP 1.32 1.22 0.5 8.2%
PM10 PM10 0.505000 0.535000 0.5 -5.6%
PM2.5 PM2.5 0.285000 0.305000 0.5 -6.6%
S02 S02 2.67 3.10. 0.5 -14.1%
VOC VoC 1,221.52 934.06 0.5 30.8%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Arsenic & Compounds (total mass of elemental AS, arsine and 1 0.424690 0.409180 0.01 3.8%
all inorganic compounds)
Arsenic Unlisted Compounds - Specify Compound ASC-Other 0.424690 0.409180 0.01 3.8%
(Component of ASC)
Beryllium& compounds (Total mass) 0.285790 0.250300 1.0 11.5%
Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.285790 0.256300 1.0 11.5%
Cadmium& compounds (total mass includes elemental metal) 0.285190 0.263400 0.1 8.5%
09/12/2017 Page 1 of 5

i
Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2015 Demini- %
from ED from Fees mus Change
Cadmium Metal, elemental, unreacted (Component( 7440-43-9 0.285790 0.263400 0.1 8.5%
CDC)
Chromium-AIUTotal(includes Chromium (VI) categories, 0.994790 1.08 0.1 -7.9%
metal and others)
Chromic acid (VI) (Component of SoICR6 & CRC) 7738-94-5 0.994790 1.08 0.01 -8.2%
Chromium (VI)Soluble Chromate Compounds (Component of 0.994790 1.08 0.01 -7.9%
CRC)
Chromic acid(VI)(Component of So1CR6 &CRC) 7738-94-5 0.994790 1.08 0.01 -8.2%
Cobalt& compounds Not 0.016000 1.0 I N/A
Reported
Cobalt Unlisted Compounds - Specify Compound COC-Other Not 0.016000 1.0 N/A
(Component of COC) Reported
Lead& compounds 0.953280 0.860600 1.0 110.8%
Lead Unlisted Compounds - Specify Compound PBC-Other 0.953280 0.860600 10.0 10.8%
(Component of PBC)
Manganese & compounds 3.79 4.29 10.0 1-11.7%
Manganese Unlisted Compounds - Specify Compout MNC-other ?.79 4.29 10.0 -11.8%
(Component of MNC)
Mercury& Compounds-all total mass includes Mg Vapor 0.342790 0.318800 0.001 7.5%
Mercury, vapor(Component of HGC) 7439-97-6 0.342790 0.318800 0.001 7.50/.
Nickel& Compounds, sum total mass includes elemental 0.349590 0.328300 1.0 6.5%
Nickel metal (Component of NIC) 7440-02-0 0.349590 0.328300 1.0 6.5%
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.524300 0.615300 1.0 -14.8%
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 0.524300 0.615300 1.0 -14.8%
56553/7PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 20.45 23.91 1.0 -14.5%
for TV)
Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 0.524300 0.615300 1.0 -14.8%
56553/7PAH)
Naphthalene(Component of 83329/POMTV) 91-20-3 19.92 23.29 1.0
09/12/2017 Page 2 of 5

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Acetaldehyde 75-07-0 167.48 196.44 10.0 -14.7%
Acrolein 107-02-8 806.77 946.28 10.0 -14.7%
Benzene 71-43-2 849.79 996.15 1.0 -14.7%
Carbon tetrachloride 56-23-5 9.08 10.65 1 .0 -14.7%
Chlorine 7782-50-5 159.34 186.89 100.0 -14.7%
Chlorobenzene 108-90-7 6.66 7.81 10.0 -14.7%
Chloroform 67-66-3 30,681.65 16,948.62 100.0 81.0%
Ethyl acetate 141-78-6 31,432.76 21,102.09 10.0 49.0%
Ethyl benzene 100-41-4 6.80 7.82 100.0 -13.0%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.89 6.86 1.0 -14.1%
Fluorides (sum of all fluoride compounds as mass of 16984-48-8 25.10 22.22 10.0 12.9%
ion)
Formaldehyde 50-00-0 919.90 1,069.67 10.0 -14.0%
Hexane isomers, except n-hexane HEXANEIso 1,483,627.7 1,136,915.8 100.0 130.5%
9 2
Hexane, n- 110-54-3 103,238.26 89,975.18 100.0 14.7%
Hydrogen chloride (hydrochloric acid) 7647-01-0 18.15 21.29 100.0 -14.7%
Methanol (methyl alcohol) 67-56-1 539,989.20 414,346.26 1,000.0 30.3%
Methyl bromide(bromomethane) 74-83-9 3.03 3.55 1.0 -14.6%
Methyl chloride (chloromethane) 74-87-3 4.64 5.44 1.0 -14.7%
Methyl chloroform 71-55-6 Not 7.30 100.0 N/A
Reported
Methylene chloride 75-09-2 58.50 68.60 1.0 -14.7%
Phenol 108-95-2 10.29 12.07 100.0 -14.7%
Phosphorus Metal, Yellow or White 7723-14-0 Not 6.39 1.0 N/A
Reported
Polycyclic Organic Matter(Inc PAH,dioxins, etc.N, poM 27.42 31.54 1.0 -13.1%
& AP 42 historic)
09/12/2017 Page 3 of 5
1

Facility Total CY 2016 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca, Inc. Permit#(s): 01819T49
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2016 CY 2015 Demini- %
from ED from Fees mus Change
Propionaldehyde 123-38-6 12.30 14.43 10.0 -14.7%
Styrene 100-42-5 383.21 449.48 100.0 -14.7%
Toluene 108-88-3 239.49 265.46 100.0 -9.8%
Vinyl chloride 75-01-4 3.63 4.26 0.1 -14.8%
Xylene (mixed isomers) 1330-20-7 6.20 6.98 100.0 -11.2%
Largest Individual HAP Methanol (methyl alcohol) 539,989.20 lbs
Total HAP Emissions 677,635.54 lbs
Largest Individual CAP VOC 1,221.52 tons
Total CAP Emissions 1,276.88 tons
Total TAP Emissions 19652,656.49
lbs
Total Aggregate 1,277.01 tons
Emissions
09/12/2017 Page 4 of 5

DAQ's Comments Retarding Inventory
SEE THE REVIEW NOTES ATTACHED TO THE HARD COPY OF THE INVENTORY AND THE HAND WRITTEN NOTES
THE INVENTORY HARD COPY.
1) Reviewed all SCC and Unit types-make some changes for several OS(see hard copy notes)
2)I reviewed all calculations. There were no changes to emissions factors and calculation methods compared to CY2015 inventory
3)Almost all of the plant sources been given a not required to report tag in the Source screen of ED These are operating permitted
sources,so for this CY they were changed to"required to report." Holly Groce helped with these changes. See emails.
4)Because Avoca only reports wastewater emissions specifically at the 1 st aeration chamber to the W WTS (MeOH only),I have
grouped all permitted wastewater emission sources with their respective plant area All of the wastewater sources have been given
'not required to report'status in Source screen since W W emissions are accounted at the aeration chamber
5)Fuel oil usage increased on Boilers H101-103 by 12.9%compared to CY2015.
I corrected the NOx factor to 201bs/MGals.The SO2 emission was corrected using 0.0014%sulfur content fuel oil. I applied the
filterable+condensable factor of 3.3 lb PM/1000 gals= 1.11 ton PM and corrected the data in ED. I changed the o-xylene emissioi
in ED to xylene mixed isomers
6)Wood combustion decreased 14.7%by weight in CY2016. I added HAPs to ED using the DAQ wood combustion spreadsheet
Brian Conner and I agreed there should be a 99%control efficiency applied to the metal HAPs. I contacted Tammy Manning to
re-open the CY2015 data to apply this control efficiency as well(data entry and re-approval of the CY2015 data is complete).
7)The generators used 8.6%more fuel(in gals)than CY2015. I corrected the NOx and VOC emissions using AP-42 factors. I add
fire pump emissions to total in OS.
8) PkGEN used 15%less fuel in CY2016. I added the PkGEN GHGs to ED. I also added more HAP. I removed control efficienci
entered for NOx,VOC and SO2.
9)See hand written and review notes on hexane fugitive and point emissions
10) Avoca assumes bulk of SFG heptane emissions are fugitive.Based on old hexane values and using MON batch calculations to
back into it,approximately 80%of SFG heptane emissions are fugitivo-20%are out the stacks.
11)Reminder: More than a third of the methanol LlostL from the Rotocel&Recovery operation goes to W WTP. Of that,98-99%i
consumed. The W WTP emission is calculated through the Water program.
12)CY2016 process VOC emissions are comprised of chloroform,hexanes,heptane,methanol,and ethyl acetate All of their annu
emissions are determined through mass balance. Avoca uses purchasing records,daily formulation and batch records,daily tank
level measurements,waste shipment records, process design-calculations,and MACT MON formulas(fugitive and point source
splits). Ultimately,more VOCs HAPs were used in CY2016,and therefore more were emitted to atmosphere.
13)The reduction in NOx,CO and SO2 emissions were due to the decreased in fuel to the wood boilers
14) The 30.8%increase in VOC emissions was due to increased chloroform,hexane,ethyl acetate,methanol and heptane usage
15) The PM increase was due to increase fuel oil combustion in the HI01-103 boilers.
16) Increases in beryllium,cadmium,lead,mercury,flourides and nickel are due to increased fuel oil combustion in H01-103.
17) Decreases in chromic acid,manganese,and all other combustion VOC HAP are due to decreased wood combustion
09/12/2017 Page 5 of 5

Huddleston, Betsy
From: Groce, Holly
Sent: Tuesday, September 12, 2017 7:48 AM
To: Huddleston, Betsy
Subject: RE: Data Clean Up Question
Hey,
I think I got them all, let me know if any problems.
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
P 1 Y
to third parties.
-----Original Message-----
From: Huddleston, Betsy
Sent: Monday,September 11, 2017 3:28 PM
To: Groce, Holly<[e-mail]>
Subject: RE: Data Clean Up Question
G77 Generators: All sources in this group need to be required
G150 Botanical: All sources in this group need to be required
G96 Recrystallization: All sources except 1003-10-WW wastewater need to be required
G97 PNE: Only TKEPNE-1 needs to be changed to required
G95 Conversions: contains a number of sources that were phased out of the permit last year. Therefore the sources
that need to be changed to required are G-17, 1001-1-3-P, 1001-1-3-F, 1001-1-3-Filter,and D1202
G94 Rotocel/Recovery/Concrete: All sources in this group need to be required, EXCEPT 1001-2-1-WW, 1001-1-1WW,
and 1001-1-2-WW
GR1 Biomass: All of the sources except 1004-2-WW
t

Thanks very much for helping me!!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
[e-mail]
943 Washington Square Mall
Washington, NC 27889
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Groce, Holly
Sent: Monday, September 11, 2017 2:53 PM
To: Huddleston, Betsy<[e-mail]>
Subject: RE: Data Clean Up Question
OK, so go ahead and give me the rest of the groups or whatever that need to have their setting changed and I'll aim to
do those tomorrow.
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
2

-----Original Message-----
From: Huddleston, Betsy
Sent: Monday,September 11, 2017 2:31 PM
To: Groce, Holly<[e-mail]>
Subject: RE: Data Clean Up Question
Hi Holly,
It's great!
Betsy Huddleston
Division of Air Quality
North Carolina Department of Environmental Quality
252 948 3836 office
252 975 3716 fax
[e-mail]
943 Washington Square Mall
Washington, NC 27889
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Groce, Holly
Sent: Monday,September 11, 2017 12:57 PM
To: Huddleston, Betsy<[e-mail]>
Subject: RE: Data Clean Up Question
Hey,
I have marked all sources belonging to G-99 to required to report. See how that works and let me know...
Holly
Holly Groce
Applications Systems Manager
North Carolina Division of Air Quality
North Carolina Department of Information Technology
919.707.8953
3

[e-mail]
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed
to third parties.
-----Original Message-----
From: Huddleston, Betsy
Sent:Wednesday, September 06, 2017 3:07 PM
To: Groce, Holly<[e-mail]>
Subject: Re: Data Clean Up Question
Cops Might be a mistype. I'm not at my desk at moment. I would just stick to testing all of the sources being changed to
required to report in group G-99.
Sent from my iPhone
>On Sep 6, 2017, at 2:23 PM, Groce, Holly<[e-mail]>wrote:
>Are you sure there's a D-2022?
> Holly Groce
>Applications Systems Manager
> North Carolina Division of Air Quality North Carolina Department of
> Information Technology
>919.707.8953
> [e-mail]
>
> I
>
> Email correspondence to and from this address is subject to the North
>Carolina Public Records Law and may be disclosed to third parties.
>
>-----Original Message-----
> From: Huddleston, Betsy
>Sent:Wednesday, September 06, 2017 2:09 PM
>To: Manning,Tammy<[e-mail]>; Groce, Holly
><[e-mail]>
>Subject: RE: Data Clean Up Question
> Hi Holly and Tammy,
> I've chosen a small group to work with. All of the sources are marked as not required to report in the group.
Emissions are reported through mass balance calculations per plant area, so all of these sources contribute to some
degree to the total emissions for the group.
>Group 99-EVG
4

>Sources:
> D-2022
> D-1215
> D-1218
> D-1201
> ES-1003-2-2-F
>Thanks for the help!!
> Betsy Huddleston, Environmental Engineer II NCDENR, Division of Air
>Quality Washington Regional Office
>943 Washington Sq. Mall,Washington, NC 27889
> Phone: [phone]
> Fax: [phone]
> http://www.ncair.org
>** Email correspondence to and from this address is subject to the
> North Carolina Public Records Law and may be disclosed to third parties unless the content is exempt by statute or
other regulation.
> **
> From: Manning,Tammy
>Sent:Wednesday,September 6, 2017 11:47 AM
>To: Huddleston, Betsy
>Subject: FW: Data Clean Up Question
> Hi, can you send Holly some source ids to test making the change in
>the database? Thanks,Tammy
> From: Groce, Holly
>Sent:Wednesday,September 06, 2017 11:37 AM
>To: Manning,Tammy<[e-mail]>;Odulapalli, Suneetha
><[e-mail]>
> p Subject: RE: Data Clean U Question
>
1
> I can change the status setting directly in the database. I'd like to do one or one group of sources first and have
you/Betsy make sure screens function ok,then would do the rest.
> Need the source ID's.
> Holly
> Holly Groce
>Applications Systems Manager
> North Carolina Division of Air Quality North Carolina Department of
> Information Technology
5

>919.707.8953
> [e-mail]<mailto:[e-mail]>
> [1495224421788_Pastedlmage]
> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be
disclosed to third parties.
> From: Manning,Tammy
>Sent: Wednesday,September 06, 2017 8:23 AM
>To: Groce, Holly
><hol ly.groce@ ncden r.gov<ma i Ito:hol ly.groce@ ncdenr.gov>>; Odulapalli,
>Suneetha
><[e-mail]<mailto:suneetha.odula pal [e-mail]>
>Subject: FW: Data Clean Up Question
>Good morning,
> Do you know another way to mark these sources as required to report? In ED-Emission Sources,the Required to
Report/Not Required to Report is not available since they are included in a group. I do not want to change this feature
but I do not think that it was envisioned that facilities would mark numerous sources erroneously as not required to
report.
>
>Thanks,Tammy
> From: Huddleston, Betsy
>Sent:Tuesday,September 05, 2017 5:35 PM
>To: Manning,Tammy
><tammy.man [e-mail]<mailto:tam my.man [e-mail]>>
>Subject: Data Clean Up Question
> Hi Tammy,
> I'm working on the Avoca 0800044 inventory. Much of their sources are grouped together. Historically they have
tagged a lot of the sources in the groups inappropriately as "not required to report." Actually all of the sources in the
groups should be "required to report." I can't change this without pulling the sources out of the groups,changing the
reporting status, and then putting them back into the groups.This is labor intensive since there are a lot of sources in
this state. Is it possible to go in through the back door for all of the groups, and change the sources to "required to
report?"
> Betsy Huddleston
> Division of Air Quality
> North Carolina Department of Environmental Quality
> 252 948 3836 office
>252 975 3716 fax
> Betsy.Huddleston @ncdenr.gov<maiIto:Betsy.H uddleston @ ncdenr.gov>
>943 Washington Square Mall
>Washington, NC 27889
> [cid:[e-mail]36780]
6

> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be
disclosed to third parties.

Annual Air Emissions Inventory Summary
2016 Totals
Facility ID#: o800044
PoNtrtaM Boar#1 Boller#2 Boller 01 Gen ill
Gen 02 Gen hM Gen M Pk-Gen Fire Pump Biomass Ro0ocd Rccrysta"Z20o t SgereOWe Biomass Botarrleal Plant
CO BoNers Recovery Concrete (SFG) (SDE) Extractlon Extractlon t EVG wwrp Dyer
2049.33330 43464178 011 781 12 LGO32 30 1.39558 1.74448 1.45761 1.42660 15.88483 5.99008 19664.74 Processes TWah Units
Methane 0.00542 0.01149 0.00328 0.00029
Nitrous Oxide 0.01083 0.02298 0.00036 0,00030 0.00029 0.00325 0.00024 2.12
TSP 0.18056 0.38294 0- � 0.00003 0.00004 0.00003 0.00003 0.00253 0.00005 1.31
27329.373 Tons/Vr
PM-10 0.10934 0.00317 0.00397 0.00331 0.00, 4 0,03611 0.01139 0.141 2.143 Tons/Yr
0 09028 0.19147 0.05467
PM-2.5 0.02257 0.00317 0.00397 0.00331
0.04787 0.01367 0.D0317 0.00324 0.03611 0.01139 0.141 1.354 T
Sox 3.84589 8.15671 2.32890 0.00397 0.00331 0.00324 0.03611 onslYr
0.01139 0.141 0.675 Tons/Yr
Nox 0.00447 0.00559 0.00467 0.00457 0.05092 0.00558 2.52112 - 0.539 7orhs/Yr
0.16670 d.59533 1.31206 0.01015 0.07269 0.01060 0.01038 1.15552 0.16198 22.1859
VOC 0.0180E 0.03829 0.07093 0.01142 0.01428 ------ 0.01167 0.13000 0.01322 1.7144 684.588 264.828 0.28E Torhs/Yr
CO 0.45140 0.9573E 0.27335 0.02697 0.03371 0.0281E 0.02757 0.30694 0,03489 1 .7144 16.928 Tonstyr Zrto7
68.939 108.845 0.178 2.499 69.204 17.272 3.23 31 621 TonsNr 3 J.(p 0.00050 U.00167 0.00163 0.01820 0.05634 767.402 1227.561 Tons/Yr
Aaokin 0.00200
0.00050
Arserhic 0.10117 0.21445 0.00025 0.000G2 0.00052 0.00051 0.00569 0.00680 806.758 21.503 Tons/Yr
0.06123
Benzene 0.49653 t.05310 0.30p6a 0.00032 0.00027 0.00026 0.00289 0.00029 167.484
Benzo(a ene 0.04924 0.06155 0.05143 0.05033 0,56043 0.06854 847.09E 806.773 Lbs7Yr
tie m 0.00002 0.00002 0.00002 0.00 302 0.00019 0.00001 47.0 U.381 Lt1s/Yr
0.07583 0.16084 0.04592 0.00019 8d9.788 L.pyyr
Butanoi 0,00024 0.00020 0.00019 0.00217 5.00022
Cadmium 0.07583 0.76084
Cakaum Vide 0.04592 0.00019 0.00024 0.00020 0.52466 LbslYr
Carbon
0.00019 0.00217 0.00022 0.286 Lbslyr
tetrachloride 0.000 Lbs(Yr
Chlorine 0.286 Lbs(Yr
Chlorobenzene 9.07E
0.000 Lbs/Yr
Chloroform 159.335 9.076 Lbs/Yr
.65E 159.335 LbslYr
.
Chromium 6
0.07583 0.t6084 0.04592 .6
47 Chromium N 000524 05E LbslYr
.01111 6.6
0.00317 3�6 30681.647 Lbs(Yr
mate
Ethanol-100%acetate Lbs/Yr
283
Ethanol-SDA 0.0. 2 Lbs7Yr
0 0.000 Lbs1Yr
r+e 0.00 E benzene 0.74752 0.31287 0. 312.05 08933 4781.45 0.00 342.053 LbslYr
bhride
E 6.252 31202.00 13.68 217.08 0.00 4781.44E Lbs7Yr
F 6.73481 14.28382 4.07831 31/32760 LbslYr
Fon HC11 de 8.66678 18.38133 5.24822 0.00 6.802 Lbs7Yr
HCI 0.00501 0.0062E 0.00523 0.00512 0.05698 0. 0.000 LbslYr Hexane Isomers
08668 887.434 25.097 LbWr
18.152
N-Hexane 0.000 1 5.13 19.89E Lbs/Yr H tane 90.OW 0.00 134772.12 0.00 0.00 0.p0 18.152 LbsKr
l acetate o.00 a2sr7.8a o.00 o.00 o,ao 1483457.258 Lbsrvr 1 y13342
ISO acetate tos676.sa 0.00 110656.67 10340a.792 Lbs/Yr Lead Com 0.22750 0.48251 0.13777 /�3z36
27751.95 217333.305 Lbr/Yr
M anew 0.15167 0.32167 0.00 0.00 27757.947 Lbs/Yr
0.09184
Me 0.00 0.000 Lbs/Yr
0.07583 0.16084 0.04592
Methanol 0.058 0.00 0.848 Lbs/Yr NaNickelne 0.07583 0.16084 0.03608 0.00825 0.01031 0.00862 0.00843 0.09389 0.00623 19.564 0.565 LL1slYr Nickel 0.07583 529656.30 0.341 Lbs7Yr
Phenol 0.16084 0.04592 0.00 3868.30 6464.60 539989204 LbsJYr Propio e
Sulfur Dioxide 10.28E 19.922 LbslYr
ene 12.303 0.283 Lbs/Yr
✓ 70.28E LbsNr Toluene /4.39047 30.5206E 871424 0.02§3 0.02229 383.210 112.303 LbslYr
0.01862 0.01823 U.20294 0.03005 1185.554 0'00 0.000 Lbs(Yr
o-X ene 0.25278 0.53612 0.75307 0.01225 0.01531 0.01279 0.01252 0.13938 0.02094I 5.042 383.210 Lbs/Yr
0.00 0.00 239.490 Lbs7Yr
✓ 5.255 Lbs1Yr
0.942 Lbs/Yr

FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION G 11/5/2012-OUTPUT SCREEN
Instructions: Enter emission source I facility data on the"INPUT'tablscreen. The air emission results and summary of input data
AMre are viewed/printed on the"OUTPUT'tablscen. The different tabs are on the bottom of this screen.
/ � This•pnatlehM is ter your sea only and•hould"usedwah clarion.DENR does;not guarant«the curacy or the Information mntelned This sprea"heet le
aged to contmutl revblon and updMinp.It b your respon4lMlity to be aMam or the most current Information available. DENR is not reaponalbk for ermn or
NCDENRomMaiona that mry"codalma Mreln.
COMPANY: AVOCB MAXHEATINPUT: 6&80 MMBTU/HR
FACILITY ID NO.: 800044 IFUEL HEAT VALUE: 141,000 BTUIGAL
PERMIT NUMBER: 0 JHHV for GHG CALCULATIONS: 0.138 mm BTU/GAL
FACILITY CITY: Many Hill JACTUAL ANNUAL FUEL USAGE: 672,840 GAL/YR
FACILITY COUNTY: Berne IMAXIMUM ANNUAL FUEL USAGE: 4088.000 GALIYR
USER NAME: E Huddleston MAXIMUM SULFUR CONTENT. 0.0 %
EMISSION SOURCE DESCRIPTION: Na 2 oil-fired Boiler
EMISSION SOURCE ID NO.: H101-103 IMAX.FUEL USAGE: 4.088,DDO GALIYR
MAX.SULFUR CONTENT: 0,0014 %
NONE/OTHER PM 0
NONEIOTHER S02 0
NONE/OTHER I NOx 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1 DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS CI el: CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
ACTUAL EMISSIONS POTENTIAL EMISSIONS :2.00E+01
ISSION FACTOR
yLe .14n JLeruanal 19E.mr.ma•ruallm uRa CCe11RX9rLan911we al
AIR POLLUTANT EMITTED Ibmr ton r b/hr ton Ib/hr ton nali corarollad
TOTAL PARTICULATE MATTER PM FPM+CPM 1.54 1.11 1.54 8,75 1.54 8.75 +00 3.30E+00
FILTERABLE PM FPM 0.93 0.57 0.93 4.D9 0.93 4.09 +00 2.00E+00
CONDENSABLE PM CPM 0.61 0.44 0.61 2.66 0.61 2,66 +00 1.30E+DO
FILTERABLE PM<10 MICRONS(PM,,) 0.47 0.34 0,47 2-04 0,47 2.04 +00 1.00E+00
FILTERABLE PM<2.5 MICRONS(PMzs) 0.12 0.08 0.12 0.51 0.12 0.51E-01 2.50E-01
SULFUR DIOXIDE(SO,) 0,09 0.07 0.09 0,41 0.09 0.41E-01 1.99E-01
NITROGEN OXIDES(NOS 9.33 6.73 9.33 40.88 9.33 40.88 +01 2.00E+01
CARBON MONOXIDE CO 233 1,68 2.33 10.22 2.33 10.22 +00 5.00E+00
VOLATILE ORGANIC COMPOUNDS OC 0.09 0,07 0.D9 0.41 0.09 0.41E-01 2.00E-01
LEAD 0.00 0.00 0.00 0.00 0.00 0.00E-03 1.28E-03
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
CAB I.RER hass I Learil 19Eftl1E NMaW I Llshil NAERCCNhaX.S I Loan) Ibl1 D' a
TOXIC I HAZARDOUS MR POLLUTANT NUMBER I", avy, We Il i"r live Wnrelled
Antiinoriy Unlisted Corn unm H SK-Other 00E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.00E*00 0.00E+00
Arsenic Umatea Corn n" TH ASC-0Iner 2.6E-04 3.8E-01 26E-04 2.3E+00 2.6E-04 2.3E+00 5.60E-04 5.50E-04
Benzene TH 71432 1.3E-03 1.9E+00 1.3E-03 1.1E+01 1.3E-03 1.1E+01 2.75E-03 2.75E-03
Be Ilium usual unrefined TH 744041/ 2.0E-04 2.8E-01 2.0E-04 1.7E+00 2.0E-04 1.7E+00 4.20E.04 4.20E-04
Cadlun Meth elemenLl unreanad TN 7440439 20E-04 2.8E-01 2.0E-04 1.7E+00 2.0E-04 1.7E+DO 4 20E-04 4.20E-04
Chromic Acid VI TH 7738945 20E-04 2.8E-01 2.0E-04 1 7E+00 2 OE-04 1.7E+00 4 20E-04 4 20E-04
Cohan UnlNtad Can mks H cl c-Omer 0.0E+00 0.0E+00 O.0E+00 0.0E+00 0DE+00 0.0E+00 0.00E+00 0.00E+00
Etn benzene R 100414 3.8E-04 55E-01 3.8E-04 3.3E+00 3.8E-04 3.3E+00 8.17E-04 8.17E-04
Flucndea(win nuon"com oun" T 18984408 1.7E-02 2.5E+01 1.7E-02 1.5E+02 1.7E-02 1.5E+02 3.73E-02 3.73E-02
Fonnsidan Ea TH 50000 2.2E-02 3.2E+01 2.2E-02 2.0E+02 2.2E-02 2-OE+02 4.80E-02 4.80E-02
Lead Unlefud Can nil N PBc-0tha 5.9E-04 8.5E-01 5.9E-04 5.2E+00 5.9E.04 5 2E+001 126E.031 1.28E-03
Manganese Unless!Cam rim TN MNCGher 3.9E-04 5.7E-01 3.9E-04 3.4E+00 39E-04 3.4E+DO 8.40E-04 8.40E-04
Meru .vesper TH 7439975 1 2.0E-04 2.8E-01 2-OE-04 1 7E+00 2.0E-04 1.7E+DO 4.20E-04 4.20E-04
Mail 01bunfohn TH 71588 I 1.1E-04 1.8E-01 1.1E-04 9.6E-01 1.1E-04 9SE-01 2.36E-04 2.38E-04
Na inlana H 91203 1 1.8E-D4 2.2E-01 1.6E-04 1.4E+00 1.8E-04 1.4E+00 3.33E-04 333E-04
Nlcele Metal TH 70002o 2.0E-D4 2.8E-W 2.0E-04 1.7E+00 2DE-04 1.7E+00 4.20E-04 420E-04
Phos horns Mehl.Yonne of W ir, H 7723140 0.0E+00 0.0E+00 O.0E+00 0.0E+00 0.0E+00 O.0E+00 O.00E+OD 0.00E+00
POM rates uncontrolled N POM 1.5E-03 2.2E+00 1.5E-03 1.3E+01 1.5E03 1.3E+01 3.30E-03 3 3DE-03
SHwwrn com aks H SEC 9.8E-04 1.4E+00 9.8E-04 8.8E+00 9.8E-04 8.8E+00 2.10E-03 2.10E-03
Toluene Tii tosm 3.7E-02 5.4E+01 3.7E-02 3.3E+02 I 3.7E-02 3.3E+02 7.97E-02 7.97E-02
X leae TH 133=7 6.5E-04 9.4E-01 6.5E-04 5.7E+00 6.5E-D4 5.7E+00 1.40E-03 1.40E-03
Total ItAP M 87E-02 9.9E+01 a 7E@ S 8E+02 S7E-02 I 5.9E+02 1 1 4E-01 I 1.4E41
Lare•t NAP H 3.nE-02 5.38E+01 3.r2E-el 3.ZBE-W 3.72E-02 3.25E+02 797EV 7WEld
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS I LIMITATIONS EMISSION FACTOR
Ib 10' el
TOXIC AIR POLLUTANT CAB Note Ibrhr Ilvday lWyr uncontrolled eanbmlea
Arsenio UnlisMa com arias TH ASC-0e,ar 2.61E-04 6.27E-03 2.29E+00 5.60E-04 5.60E-04
B4nz«r TH 714sz 1.28E-03 3.08E-02 1.12E+01 2 75E-03 2.75E-03
lium Metal umeaaad Ttf 7441 1 95E-04 4.70E-03 1.72E+00 4.20E-04 4.20E.04
call MMal MMn4nho anreaied TH 74404" 1 96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Soluble rAmmata com unm,as cr.alm VI TH SoICR6 1.96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Fluandes sum it""com uM• 169344" 174E-02 4.18E-01 1.52E+02 3.73E-02 3.73E-02
Fomlelaen TH 51HIX 224E-02 5.3BE-01 1.98E+02 4.80E-02 4.80E-02
Man show Un9Mea Con rids TN MNc-Onas 3.92E-04 941E-03 3.43E+00 8.40E-04 B.40E-04
MMCY 7439978 1.96E-04 4.70E-03 1.72E+00 4.20E-04 4.20E-04
Morn cnmrororm Tim 71W 1.10E-04 2.64E-03 9.85E-01 2.36E-04 2.36E-04
Nic9le Meml TN 7440020 1.96E-04 4.70E-03 1 1.72E+00 I 4.20E-04 4.20E-04
toluene TH 109943 3.72E-02 892E-01 3.26E+02 7.97E-02 7.97E-02
x a1m ITH) 13=7 6.54E-04 1.57E-02 5.73E+00 1.40E-03 1.40E-03
SE
- ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit antl EPA
GREENHOUSE OAS EPA MRR CALCULATION METHOD:TIER 1 MRR Emission Factors
POLLUTANT short tons/yr, short tons/yr,
metric tons/r metric tons/r,CO2e short tons/r short tonW CO2e short tonstyr CO2e
CARBON DIOXIDE(CO2) 6,867.33 6,867.33 7,569,93 48.992.73 46,992.73 46,992.73 46,992.73
METHANE(CH4) 2.79E-01 5.85E+00 3.07E-01 1.91E+00 4.00E+01 1.91E+00 4.00E+01
NITROUS OXIDE(N30) I 5.57E-02 1.73E+01 6.14E-02 3,81E-01 1.18E+02 3.81E-01 1.18E+02
TOTAL 6,890.45 TOTAL TOTAL
NOTES. 1)CO2e means CO2 equivalent
2)The DAO Air Emissions Reporting Online(AERO)system requires short tons and the EPA MRR requires metric tons

GAS&DIESEL INTERNAL COMBUSTION ENGINES EMISSIONS CALCULATOR REVISION S 6/22/2015-OUTPUT SCREEN
Instructions: Enter emission source I facility data on the"INPUT"tabiscreen. The air emission results and summary of Input data are� �
viewedlprinted on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the Information contained.
NCDENR This spreadsheet is subject to continual revision and updating. it Is your responsibility to be aware of the most current Information available.
DENR is not responsible for errors or omissions that may be contained herein.
COMPANY: Avoca FACILITY ID NO.: 800044
PERMIT NUMBER: 0
EMISSION SOURCE DESCRIP 1ION. 285 HP POWER OUTPUT DIESEL INTERNAL COMBUSTION ENGINE FACILITY CITY: Merry Hill
EMIS I N OUR E ID NO. Fire Pump FACILITY COUNTY: Berne
SPREADSHEET PREPARED BY: ETH POLLUTANT TR LEFF.
ACTUAL THROUGHPUT 521 AL C MBU TED FUEL H TIN VALUE141DO0 BTU/GAL PM 0
REQUESTED ANNUAL LIMITATION 8,760HRS OF OPERATION CALCULATIONS'. 0138 mm BTU/GAL PM10 0
SULFUR CONTENT OF DIE EL FUEL(%) 0 PM2.5 0
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1'. DEFAULT HIGH HEAT VALUE AND DEFAULT EF S02 0
CARBON CONTENT USED FOR GHGS k CI al. CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN NOX 0
CO 0
VOC 0
ACTUAL EMISSIONS POTENTIAL EMISSIONS EMISSION FACTOR
NFn.WMT'LMI191 IXll.R CO",FOL4LiM1141 I RW TRIX9AIMIT9) Mp-hr
AIR POLLUTANT EMITTED bdtr ton r Ib01r lonstyrlbfnr tons/r ur.rtnIIW
PARTICULATE MATTER PM 0.83 0.01 0.63 275 063 2.75 2.20 -03
PARTICULATE MATTER<70 MICRONS(PM,,) 0.63 0,01 0.63 2.75 063 2.75 220E-03
PARTICULATE MATTER<2.5 MICRONS(PMps) 0.83 0.01 0.63 2.75 0.63 2.75 2.20E-03
SULFUR DIOXIDE SOY 0.00 0,00 0.00 0,02 0.00 0.02 1.21E-05
NITROGEN OXIDES NOx 8.84 0,10 8.84 38,70 8.84 38.70 3.10E-02
CARBON MONOXIDE CO 1.90 0.04 1.90 8,34 1.90 8.34 6.88E-03
VOLATILE ORGANIC COMPOUNDS(VOC) 0.72 0.01 0 72 3.14 0.72 3.14 2.51 E-03
ACTUALEMISSIOMs, POTENTULL EMISSIONS EMISSION FACTOR
`A AF6RC n*.91L 4 I _Yrt41 UFTEPCQVixOL9 AlYli81 IO1llp-11r
TOXIC I HAZARDOUS AIR POLLUTANT NUMB R Ib/hr lb/. lbtyr III lbtyr uncontrouee
Acetaldehyde H, 75070 1.53E-03 563E U2 1 b3c ca 1 34E+01 153E-03 1.34E-01 3 E-06
Acrolem(H, 107028 1.85E-04 680E-03 1.85E-04 162E+00 1.81 162E+00 8.48E-07
Arsenic unlisted compounds H, ASC-081er 7.9BE-06 294E-04 7.98E-08 699E-02 798E 06 699E-02 2.80E-08
Benzene H,T 71432 1.86E-03 685E-02 1.86E-03 1.63E-01 186E 03 163E+01 I 8.53E-06
Benzoa rene H, 50328 375E-07 138E-05 3.75E-07 3.29E-03 3.75E-07 329E-03 1.32E-09
Beryllium metal unreactetl H, 7440417 5.99E-06 2.20E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E-08
1 3-Butadiene H, 108990 7.80E-05 2.87E-03 7.80E-05 6.83E-01 7.80E-05 6.83E-01 2.74E-07
Cadmium metal(elemental unreactetl)(H,T 7440439 5.99E-06 2.20E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E-08
Chromic Add(VI)(HT) 77381 5.99E-06 2.20E-04 5.99E-06 5.24E-02 599E-06 5.24E-02 2.10E-08
Formaldehyde(H,T) 50DOO 2.35E-03 8.67E-02 2.35E-03 1 2.06E+01 2.35E-03 2.06E+01 826E-06
Lead unlisted Compounds H PSC-Other 1.80E-05 6.61E-04 1.80E-05 1 57E-01 1 BOE-05 1.57E-01 6.30E-08
Manganese unlisted Compounds H, MNC-Other 1.20E-05 4.41E-04 1.20E-05 1.05E-01 1.20E-05 1.05E-01 4.20E-08
Mercury vapor H,T 7439976 5.99E-06 220E-04 5.99E-06 5.24E-02 5.99E-06 5.24E-02 2.10E.08
Na thalene H 91203 1.69E-04 623E-03 1 69E-04 148E+00 169E-04 1,48E+00 5.94E-07
Nickel metal H, 744DO20 5.99E-06 220E-04 599E-06 5.24E-02 5.99E-06 I 5.24E-02 I 2.10E-DB
Selenium Compounds H SEC 2.99E-05 1 lOE-03 2.99E-05 2.62E-01 2.99E-05 2.62E-01 1.05E-07
Toluene 1108883 8.16E-04 3.00E-02 8.16E-04 7.15E+00 8.16E-04 7.15E+DO 2.88E-IS
X lane H, 1339207 589E-04 2.09E-02 5.69E-04 4.98E+00 5.89E-04 4.98E+1X) 2.00E-0fi
Highest HAP(Formaldehyde) 50000 2.35E-03 8.67E-02 2.35E-03 2.06E+01 235E-03 2.06E+01 I 8.26E-06
Total HAPS I I 7.66E-03 282E-01 1 766E-03 871E+01 7.86E-03 16,71E+01
�IIONIFOR
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS/LIMITATIONS EMISSION FACTOR
dhp-hr
TOXIC AIR POLLUTANT CAS Num. Whir lb/day lbtyr uncontrolled
Acetaidetl de H, 75070 1.53E-03 367E-02 1.34E+01 5.37E-06
Acrolein H, 107028 1.85E-04 4.43E-03 1.62E+0O 6.48E-07
Arsenic unlisted Compounds H,T ASC-Other 7.98E-06 1.92E-04 6.99E-02 2.80E-08
Benzene H,T 71432 1.811 4.47E-02 1 63E+01 6.53E-06
Benzo(a)p rene H,T 50328 3.75E07 9,00E-06 3.29E-03 1.32E-09
Beryllium metal unreactetl) H,T 7440417 5.99E-06 144E-04 524E-02 2.10E-08
1,3-Butadiene H, 106990 7.80E-05 1.87E-03 6.83E-01 2.74E-07
Cadmium metal(elemental unreactetl)(H,T) 7440439 5.99E-06 1.44E-04 524E-02 2.10E-08
soluble chromate Compounds.as chromium VI equivalent SOLCR6 5.99E-06 1.44E-04 5.24E-02 2.10E-08
Formaldehyde H,T) 50000 2.35E-03 565E-02 2.06E+01 8.28E-06
Manganese unlisted Compounds H,T MNC-0Mer 1.20E-05 2.87E-04 1.05E-01 4.20E-08
Mercury vapor H,T) 7439976 5.99E-06 1.44E-04 5.24E-02 2.10E-08
Nickel metal H,T) 7440020 5.99E-06 1.44E-D4 524E-02 2.10E-08
Toluene H, '08883 816E-04 1.98E-02 7.15E+00 2.86E-06
X lane H, r,5P1 n4 1.38E-02 4BBE+00 2DOE-06
'SIN CRY. •CW4
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat input
capacity or horsepower and EPA MRR Emission Requested Emission Limitation-utilze
Factors requested fuel lima and EPA MRR
GREENHOUSE GAS EMITTED EPA MRR CALCULATION METHOD:TIER 1 Emission Factors
metric tonstyr metric tonstyr.CO2e short tonstyr short ton r short tori CO2e short tonslyr short tonslyr,CO2e
CARBON DIOXIDE(CO,) 5.32 5.32 5.88 1,424.78 1,424.78 1,424.78 1,424.78
METHANE(CHM) 2.16E-04 5.39E-D3 2.38E-04 5.78E-02 1.44E+00 5.78E-02 1.44E+00
NITROUS OXIDE 1 4,31 E-05 1.29E-02 4.76E-05 1.16E-02 3.44E+00 1.18E-02 3.44E-00
TOTALI 5.34 TOTAL 1429.67 TOTAL 1,429.67
NOTE: CO2e means CO2 equivalent.
NOTE: The DAQ Air Emissions Repomng Online(AERO)system requires short tons be reported The EPA MRR requires metric tons be reported
NOTE: Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Significant Deterioration)purposes.

Large Diesel and All Dual-Fuel Engines Emissions Calculator LGD2012 Revision J-06/22/2015
Insnictions Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual-fuel(diesegnatural gas)engines
Please note that,when used in conjunction with permit applications,any value entered for annual operations of these engines may become a permit limit.
User Input DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name. Hal ISE eempeny guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision
Plant County dalahe and updating. It is your responsibility to be aware of the most current information available. DENR
Plans City. Ralsigh E/Y er7(!) is not responsible for ertors or omissions that may be contained herein.
Permit Number: -NA7 L
User -*41eb C-&Yv v'K*r-s
Fuel Sulfur Fuel Input Rates Diesel trail Ng cu tl Heat Input Rates Diesel N�
Diesel Fuel Sulfur Content(%). 0.00 Hourly Fuel Usage: 80.00 Hourly Fuel Usage (mmBtu): 11.28 0.00
NG Fuel Sulfur Content( r/mm cu ft): 2,000 Annual Fuel Usage: 1,943 Annual Fuel Usage (mmBtu): 274 0
Fuel Heat Content: 141,000 (BlWgal for diesel,Slid=h for NG
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant Ib/hr UrnmEltu Retina Pollutant Ib/hr blvir toy (IbtmmBtul Rate to
PM 1.13 27,39 0.01 100E-01 B PM NA NA NA NO NA
PM-10 1.13 27.39 0.01 100E-01 B PM-10 NA NA NA NO NA
PM-2.5 1.13 27.39 0.01 100E-01 B PM-2.5 NA NA NA ND NA
NO,,uncont 36.10 876,46 0.44 320E+00 B NO.,uncora. 30.46 739.51 0.37 2.70E+00 D
NO,cant 21.43 520.40 0.26 1 90E+00 B NO.,corn. NA NA NA NO NA
OC(as CH4) 1.02 24,65 0.01 9.00E-02 C TOC(as CH,) 9.02 219.11 0,11 8.00E-01 D
NMTOC 0.92 22A3 0.01 8.19E-02 E NMTOC 2.26 54,78 0,03 2.00E-01 E
CO 9,59 232.81 0.12 8.50E-01 C CO 13.08 317.72 0,16 1.16E+00 D
SO, 0.02 0.41 0,00 152E-03 B SO, 0.001 0.041 0.00 131E-04 B
Total HAP 1.98E-02 4.80E-01 2.40E-04 1.75E-03 NA
Lansaw HAP benzene 8.75E-03 2.13E-01 1.06E-04 7.76E-04 NA
Toxic/Hazardous Air Pollutants There arc no ToxiclHazardous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number b fhr lb/dayIll
Acetaldehyde 75070 2.84E-04 6.82E-03 6.90E-03 2.52E-05 E
Acro ion 107028 8.89E-05 2.13E-03 2.16E-03 7 BSE-06 E
Arsenic unlisted compounds ASC-Other 4.51E-05 1.08E-03 1.10E-03 400E-06 E
Benzene 71432 8.75E-03 2.10E-01 2.13E-01 7 76E-04 E
Benzo(a)pyreme 5=8 2.90E-06 6.96E-05 7.04E-05 2.57E-07 E.<
Beryllium metal(unreacled) 7440417 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Chromic Acid(VI) 7738945 3.38E-05 8.12E-04 822E-34 3.00E-06 E
Formaldehyde 50000 8.90E-04 2.14E-02 2.16E-02 7 89E-05 E
Lead unlisted compounds PBC-0ther 1.02E-04 2.44E-03 247E-03 900E-06 E
Manganese unlisted compounds MNCOther 6.77E-05 1.62E-03 1.84E-0;i 6.00E-06 E
Mercury vapor 7439976 3.38E-05 8.12E-04 8.22E-04 3.00E-06 E
Napmalene 91203 1 47E-03 3.52E-02 3 56E-02 1.30E-04 E
Nickel metal 7440020 3.38E-05 8.12E-04 8.22E-04 300E-06 E
Selenium compounds SEC 1.69E-04 4.06E-03 411E-03 150E-05 E
Total PAH 2.39E-03 5.74E-02 581E-02 212E-04 E.
Toluene 108803 3.17E-03 7.61E-02 7.70E-02 2.81E-04 E
X nes 1330207 1 2.18E-03 5.22E-02 5.29E-02 1.93E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandato Re rtin Rule Factor Quality but not with EPA Mandato Reporting Rule Factor Quality
Pollutant Ib/mmBtu RatingPollutant IbM I UmmBtu Rail
Carbon Dioxide(CO2) 44.177.70 22,09 43.99 NA Carbon Dioxide(CO2) 44,177.70 22.09 43.99 NA
Methane(CH,) 60.39 0.03 0.009 NA Methane(CH4) 3,699.09 1,85 0.540 NA
Nitrous Oxide(NzO) 107.98 0,05 0 001 NA Nitrp.is Oxide(NzO) 107.98 0.05 0.001 NA
44,346.07 22.17 47,954.77 23.99
f1o0s:Do riot use grieuiticese gas emission estimates from this s rwdshast for PSO finvanaan of S'ni cant Deterioration)purposes.
NO,control is via ignition timing retard
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other toxiclhazardous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"r'indicate an AP42 emission factor based on test results being below detection.
Emission factors for criteria pollutants are from AP42 Chapter 3 4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10195).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP42 Chapter 1.3,Fuel Oil Combustion(revised 5110).
All other toxiGhazardous pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96). -
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines'.Stationary Combustion Sources,June 2008,except for CH4,
which uses AP42,Chapter 3 4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 95%natural gas and 5%diesel,per AP42 Chapter 3.4,p.3.4-5(revised 10/96),
Hourly emission rates for all pollutants are based on the hourly fuel usage Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours

Large Diesel and All Dual-Fuel Engines Emissions Calculator LG02012 Revision J-06/22/2015
Insructors.Please provide the information shown in blue below.The applicability of this spreadsheet is limited to diesel engines larger than 600 hp and all dual fuel(dieseVnatural gas)engines.
Please note that,when used in conjuinct on with permit applications,any value entered far annual operations of these engines may become a permit limit.
User Input DISCLAIMER:This spreadsheet is for your use only and should be used with caution.DENR does not
Company Name: Avoca PKGEN Engine guarantee the accuracy of the information contained. This spreadsheet is subject to continual revision
Plant County Battle and updating. It is your responsibility to be aware of the most current information available.DENR
Plant City Merry Hill is not responsible for errors or omissions that may be contained herein.
Penult Number
User E Huddleston
Fuel Sulfur Fuel Input Rates Diesel fi ll N cu ftj Heat Input Rates Diesel NQ
Diesel Fuel Sulfur Consent(%): 0.00 Hourly Fuel Usage. 72.00 Hourly Fuel Usage (mmBtu): 10.15 0.00
NG Fuel Sulfur Content(gr/mm cu ft)- 2,000 Annual Fuel Usage: 5,122 Annual Fuel Usage (mmBtu): 722 0
Fuel Heal Content: 141,000 (BUgal far diesel,Btu cu.It far NG
Emissions Output for Diesel Engines Emission Factor Emissions Output for Dual-fuel Engines Emission Factor
Criteria Pollutants Factor Quality Criteria Pollutants Factor Quality
Pollutant lhfhr byr tDv iltiffirml Rana Pollutant Whir lt)dyr t IWmmBtu Rating
PM 1.02 72.22 0,04 100E-01 B PM NA NA NA NO NA
PM-10 1.02 72.22 0.04 100E-01 B PM-10 NA NA NA NO NA
PM-2.5 1.02 72.22 0.04 1 DOE-01 B PM-2.5 NA NA NA NO NA
NO.,uncont. 32.49 2,311.05 1.16 3.20E+00 B NOx,unoont. 27.41 1,949.95 0.97 2.70E+00 D
Nl cont. 19.29 1,372.18 0.69 1.90E+00 B NO.,Cont. NA NA NA NO NA
TOC(as CH,) 0.91 65.00 0.03 9.00E02 C TOC(as CHs) 8.12 577.76 0,29 8.00E-01 D
NMTOC 0.83 59.15 0.03 8 19E-021 E NMTOC 2.03 144.44 0.07 2.00E-01 E
CO 8.63 613.87 0.31 8.50E-01 C CO 11.78 837.75 0.42 116E+00 D
sox 0.02 1.09 0.00 152E-03 B SO, 0.00 0,09 0.00 1.31E-04 8
Total HAP 1.78E-02 1.27E+W 6.33E-04 1.75E-03 NA
Largest HAP benzene 7.88E-03 5.60E-01 2.80E-04 7.76E-04 NA
Toxic/Huardous Air Pollutants There am no ToxidHa umlous Air Pollutant emission factors for dual-fuel engines.
Pollutant CAS Number I IWhr lb/day IW
Acetaldehyde 75070 2.56E-04 6-14E-03 1.82E-02 2.52E-05 E
Acrolein 107028 8.00E-05 1.92E-03 5.69E-03 7 8BE-06 E
Arsenic unlisted compounds ASC-Other 4.06E-05 9.75E-04 2.89E-03 4 ODE-06 E
Benzene 71432 7.88E-03 1.89E-01 5.60E-01 7 76E-04 E
Benno(a)pyrene 50328 2.61E-06 6.26E-05 1.86E-04 2.57E-07 E.<
Beryllium metal(unreaded) 7440417 3.05E-05 7.31E-04 2.17E-03 3.00E-06 E
Cadmium metal(elemental unreacted) 7440439 3.05E-05 7.31E-04 2.17E-03 3.ODE-06 E
Chromic Acid(VI) 7738945 3.05E-05 7.31E-14 2.17E-0:3 3.00E-06 E
Formaldehyde 50000 8.01E-04 1.92E-02 5.70E-02 769E-05 E
Lead unlisted compounds PBC-Other 914E-05 2 19E03 6 50E-03 900E-06 E
Manganese unlisted compounds MNC-Other 6.09E-05 1.46E-03 4.33E-03 6 OOE-06 E
Mercury vapor 7439976 3.05E-05 7.31E-04 2.17E-03 3.00E-06 E
Napmalene 91203 132E-03 3.17E-02 9.39E.02 1.30E-04 E
Nickel metal 7440020 3.05E-05 7.31E-04 2,17E-03 300E-06 E
Selenium compounds SEC 1.52E-04 3.65E-03 1 OBE-02 1 50E-05 E
Total PAH 2.15E-03 5.17E-02 1 53E-01 2 12E-04 E,<
Toluene loom 2.85E-03 6.85E02 2.03E-01 2.81E-04 E
Ixyleners 11330207 1 1.96E-03 4.70E02 1.39E-01 193E-04 E
Greenhouse Gases-methods consistent with TCR other protocols Emission Factor Greenhouse Gases-methods consistent with TCR other protocols Emission Factor
but not with EPA Mandato Re rb. Rule Factor Qualsy but not with EPA Mandato Revortino Rule Factor Quality
Pollutant Iblyr t IWmir Ratina Pollutant IWhr IW t m/mmetu Rating
Carbon Dioxide(CO2) 116,488.11 58.24 43.99 NA Carbon Dioxide(CO2) 116,488.11 58.24 43.99 NA
Methane(CH4) 159.25 0,08 0.009 NA Methane(CHs) 9,753.79 4.88 0.540 NA
Ntrous Oxide(N2O) 254-73 0.14 0 001 NA Nitrous Oxide(N2O) 284.73 0.14 0.001 NA
116.932,09 58.47 126,526.63 63.26
lbta: Do rat uaa raaMwaa m amusb s bit s from Mu sp> shM for PSD(Pnvandon of S-ndunt p norauon)pu s .
NO,control is via ignition timing retard.
Pollutants in red are federally regulated hazardous air pollutants(HAPs)only. All other loxicJhazerdous air pollutants are regulated as both HAPs and TAPS.
Factor quality ratings containing"<"indicate an AP42 emission factor based on test results being below detection.
Emission factors for onteria pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10/96).
Emission factors for arsenic,beryllium,cadmium,chromium,lead,manganese,mercury,nickel,and selenium are from AP42 Chapter 1.3,Fuel Oil Combustion(revised 5110).
All other loxidhazardous pollutants are from AP42 Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Emission factors for greenhouse gases are from DAQ's Greenhouse Gas Emission Guidelines.Stationary Combustion Sources,June 2008,except far CH4,
which uses AP42,Chapter 3.4,Large Stationary Diesel and All Stationary Dual-fuel Engines(revised 10196).
Carbon dioxide emission factor for dual-fuel engines is calculated based on 96%natural gas and 5%diesel,per AP42 Chapter 3.4,p.3 4-5(revised 10/96).
Hourly emission rates far all pollutants are based on the hourly fuel usage.Annual emissions are based on the annual fuel usage.
Daily emissions are based on operation at the hourly input rate for 24 hours.

WOODWASTE COMBUSTION EMISSIONS CALCULATOR REVISION K 03/08/2017-OUTPUT SCREEN
�� Instructions: Enter emission source I facility data on the"INPUT•'tab/screen. The air emission results and summary of
input data are viewed I printed on the"OUTPUT"tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution.DENR does not guarantee the accuracy of the
NCDENR Information contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware
of the most current information available. DENR is not responsible for errom or omissions that may be contained herein.
COMPANY: AVOCB FACILITY ID NO.: 8000"
PERMIT NUMBER. 0
EMISSION SOURCE DESCRIPTION' 48 MM8TU/HR BARK AND WET WOOD FIRED BOILER FACILITY CITY. Merry Hill
EMISSION SOURCE ID NO.: Wood Balers FACILITY COUNTY. Bertie
PARTICULATE CONTROL DEVICE: FABRIC FILTER POLLUTANT CONTROL EFF.
SPREADSHEET PREPARED BY. E Huddleston FUEL HEAT VALUE: 4000 BTU/LB NOX 0
ACTUAL FUEL THROUGHPUT. 25211 TON/YR HHV Used for GHGs MMBTU/TON: 15.38 PM CALCO AS 25.9%
POTENTIAL FUEL THROUGHPUT: 52560 TON/YR IBOILER TYPE: STOKER PM10 CALCO AS 24.9% -
REQUESTED MAX.FUEL THRPT: 52560 TON/YR ITEST DATA USED:0.0014 LB(MMBTU FPM PM2.5 CALC'D AS 22.2%
METHOD USED TO COMPUTE ACTUAL GHG EMISSIONS: TIER 1: DEFAULT HIGH HEAT VALUE AND DEFAULT EF
CARBON CONTENT USED FOR GHGS AS A FRACTION): CARBON CONTENT NOT USED FOR CALCULATION TIER CHOSEN
ACTUAL EMISSIONS POTENTIAL EMSSIONS EMISSION FACTOR
Wren wamaarLaxrsl WF9r1EC9a WILWSI W Rcpa ,uio m) INmmefu
AIR POLLUTANT EMITTED Ib1hr tons/yr Ib1hr tons/rr28.80
Whirtons) unwmrallm wet llad
PARTICULATE MATTER PM 0.88 1.86 1.19 5.22 3.87 0.025 0.018
PARTICULATE MATTER<10 MICRONS(PM10) 0.87 1.82 1.15 E05 3.79 0.024 0.018
PARTICULATE MATTER<2.5 MICRONS(PM2s) 0.86 1.81 1.10 4.84 3,77 0.023 0.018
SULFUR DIOXIDE S02 1.20 2.52 1.20 5.26 5.26 0.025 0.025
NITROGEN OXIDES NOx 10.56 22.19 10.56 46.25 46.25 0,220 0.220
CARBON MONOXIDE CO 28.80 60.51 28.80 126.14 12614 0.600 0,600VOLATILE ORGANIC COMPOUNDS VOC 0.82 1.71 0.82 3.57 3.57 0.017 0.017LEAD 2.3E-03 4.8E-03 2.3E-03 1 OE-02 1.0E-02 4.8E-05 4.8E-05
ACTUAL EMISSIONS7P,0,T.-T-POTENTIAL EMSSIONS EMISSION FACTOR
CAS WIERCO MSILYRa1SILwITS1 (4.R."0.e ILMn IWmmSN ���J, '0 (N•,
TOXIC/HAZARDOUS Apt POLLUTANT NUMBER lamr Ib/r IbR1r lb/r unwMrolled/wnb011ed
Acetaldehyde H 75070 3.90E-02 167.402348.998 3.98E-02 348.998 8.30E-W B.WE-o4
Aceto hemrie H 98852 1.54E-07 6.45E-041.35E-03 1.54E-07 1.35E-03 3.20E-09 3.20E-09
Acrolein H 107028 1.92E-01 806.7581681.920 1.92E-01 1681.920 000E-03 4.00E-03Antimon unlsiw Com unds wet nem of sac SW-tuner 3.79E-04 1.5933.322 3.79E-04 3,322 7.90E-09 7.90E-06Amenc UmIWW Communds(wmWnenl ofASC)(TH) ASC-ether 1.06E-03 4.4379.251 1.06E-03 S251 220E-06 220E-05 64 JyV
Benzene H 71432 2.02E-01 847.096 2.02E-01 1766.016 2.02E-01 1766.016 4.20E-03 4.20E-03
Benzo(a)p ne 50328 1.25E-04 -0.524 1.25E-04 1.093 1.25E-04 1,093 2.60E-W z.e0E-06
Be Iium Metal(unreadm) wet nem of BEC IH 7N0417 5.28E-05 0.222 5.28E-05 0.463 5.28E-05 0.463 1.10E.06 1.10E-OS �.�JLA)7-�-'
admium Metal(unmarred wet nem of CDC /H 7440439 1.97E-04 0.827 1.97E-04 1.724 1 97E-04 1.724 4.10E-08 4.10E-08 Ra ?E-3
Icon tetmchlome(TH) 58235 2.16E-03 9,076 2.16E-03 18.922 2.16E-03 18.922 4.50E-05 4SCE-o5
Chlorine il 77s25a5 3.79E-02 159.335 3.79E-02 332.179 3.79E-02 332.179 7.90E-D4 7.90E-04
CBlorobenzane H 108907 1.58E-03 6.656 1.58E-03 13.876 1.58E-03 13.876 3.30E.05 3.30E-05
Cmorot9ml 87663 1.34E-03 5.647 1.34E-03 11.773 1.34E-03 11.773 2ACE-05 I 2eoE-05
Chromium Unlisted Cm H ado w/carom and to get CRC CROotner 8.40E-04 3.530 8.40E-04 7.358 8.40E-04 7.358 1.75E-05 175E-05
Chromic acid M(aimponent of solCRe and CRC /H 773e945 1.68E-04 0.706 1.6BE-04 1,472 1.68E-04 1.472 3.50E-OB 3.50E.06
Ooealt Unlisted Compoums(wmponem of CDC)(H) CDC-other 3.12E-04 1,311 3.12E-04 2.733 3.12E-04 2,733 6.50E-05 650E-06 f�.0✓I3
Dinbo henol,2.4- H 61285 8.64E-06 3.63E-02 8.64E-06 0.076 8.64E-08 0.076 1.60E-07 1.80E-07
Di 2-eth he phthalate EH H 117817 226E-06 9.48E-03 2.26E-06 1.98E-02 2.26E-06 1.98E-02 4.70E.08 470E-W
Eth benzene(H) 100414 1 49E-03 6.252 1 49E-03 13.035 1.49E-03 13.035 3.10E-05 3.10E-05
Eth enedchlonde 1,2Eichlomethane 107002 1.39E-03 5.849 1.39E-03 12.194 1.39E-03 12,194 2.90E.05 2.90E-05
Formaldehyde H - 50000 2.11E-01 887.434 2.11E-01 1850.112 2.11E-01 1850,112 4.40E.03 4.40E-03
-Hwachlom0lbenzo- ban 1,2,3,8,7,5 M 57653857 1.53E-09 6.41E-06 1.53E-09 1.34E-05 1.53E-09 1.34E-05 3.18E.11 3.18E.11
Hydrogen chloride(hydrocnlorc acid 7847010 9.12E-01 9.12E-01 7989.120 9.12E-01 7989,120 1.80E-02 1.90E-02
Lead Unlisted Co ums(winponem of Pec PBC-other 2.30E-03 9.681 2.30E-03 20.183 2.30E-03 20.183 4.80E-05 4.80E-05 0,0 9(+P
n anmunwed Com ums wmwnenlof MNC H MNC-ether 768E-02 322.703 7.68E-02 672.768 7.68E-02 672.768 1.80E-03 1.60E-03 �I-Z-L
rou ,ve r wmponent of HGC M) 7439978 1.68E-04 04 1,472 1.68E-04 1.472 3.SOEW 3.50E-0e
Main bmmde H) bmmomethane 74e39 7.20E-04 3.025 7.20E-04 6.307 7.20E-04 6.307 150E-05 1.50E-05
Why!wlonde H chlommethane 74a73 1.10E-03 4.639 1.10E-03 9.671 1.10E-03 9.671 2.30E-05 2.30E-05
Wthlil wlomMan H (1.1,1 mcnlomethane) 71558 1.49E-03 6,252 1.49E-03 13.035 1.49E-03 13.035 3.10E-05 310E-05
Methyl Myl ketone 78933 2.59E-04 1,089 2.59E-04 2,271 2.59E-04 2.271 5.40E-08 5.40E-06
Methylene chlome(TH)(dbhlommethane) 75092 1.39E-02 58.490 1.39E-02 121.939 1.39E02 121,939 2.90E-04 290E-04
Naphthalene(H) 91203 4.66E-03- 19.%4 4.66E-03 40.787 466E-03 40.787 9.70E-05 9,70E-05
Nickel metal Component of 373024MIC M 7440020 1.58E-03 6.656 1.58E-03 13.876 1.58E-03 13.876 3.30E-05 3.30E.05
Nero nenol,4-H 103027 5.28E-06 2.22E-02 5.28E-06 4.63E-02 5.28E-06 4.63E-02 1.10E-07 1.10E-07
Pentachlom henol H 87865 2.45E-06 1.03E-02 2.45E-06 2.14E-02 245E-06 2.14E-02 5.10E-Oe S.ioE-0s
Perwloroeth ene chlometh ene H 127184 1.82E-03 7,664 1.82E-03 15.978 1.82E-03 15.978 3.60E-05 3.80E-05
Phanom H 105952 2.45E-03 10.286 2.45E-03 21.444 2.45E-03 21.444 5.10E-05 5n OE-05
Phosphorus Metal.Yellow or while 7723140 1.30E-03 5.446 1.30E-03 11.353 1.30E-03 11.353 2.70E-05 2.7or-as 6L OS 4
Polycnionnated biphenNs(TM 1336353 3.91E-07 1.64E-03 3.91E-07 343E-03 3.91E-07 3.43E-03 315E-W 8.15E.09
Pot he Organic Minter POMTV 6.00E-03 25.211 6.00E-03 52.560 8.00E-03 62.660 125E-04 125E-04
Pmpbnalden a(H) 123386 2.93E-03 12.303 2.93E-03 25.649 2.93E-03 25.649 8.10E-o5 BAOE-05
Pro ene dichloride H 12 dbnloro roper) 75875 1.58E-03 6.656 1.58E03 13.876 1.SBE-03 13.876 3.30E-05 3.30E-05
Selenium wet unds H SEC 1.34E-04 0,565 1.34E-04 1.177 1.34E-04 1.177 2.80E.09 2.80E-011 5" y
Styrene 100425 9.12E-02 383.210 9.12E-02 798,912 9.12E-02 798.912 1.90E-03 1.80E-03
Telrawlorwibenzo- ban,2.3,7,o- H 174s01e 4.13E-10 1.73E-06 4.13E-10 3.62E-06 4.13E-10 3.62E-06 BADE-12 3SOE-12
aluane H lDS883 4.42E-02 185.554 4.42E-02 386,842 4.42E-02 306.042 9.20E-04 820E-04
Twhloroeth ene 79016 1.44E-03 6.051 1.44E-03 12.614 1.44E-03 12.614 3.00E-05 3.WE-05
Trbnlom8uommethane CFC 111 75694 1.97E-03 8.269 1.97E-03 17.240 1.97E-03 17.240 4.10E-05 4.10E-05
Tnchloro henol,2.4,6 ) $8062 1.06E-06 4.44E-03 1.06E-06 9.25E-03 1.06E-06 925E-03 2.20E-08 220E-0
Vinyl chloride 75014 8.64E-04 3.630 8.64E-04 7.569 8.64E-04 7.569 1.80E-05 180E-05
/X ene H 1330207 1.20E-03 5.042 1.20E-03 10.512 1.20E-03 10.512 2.50E.05 2.50E-05
Highest HAP(Hydmilen cmome(hydimcniore acid H) 7a470t0 I 9.12E-01 1 3832.102 9.12E-01 1 7989.1 9.12E-01 1 7989.1 1 180E-o2 I 180E-02
•Total HAIRS INA I 1.86E+00 I 7.83E+03 1.86E+00 I 1.63E+D4 1.86E+00 I 1.63E+04 3.88E-02 I 3.BBE-02

EXPECTED ACTUAL EMISSIONS LIFTER CONTROLS/LIMITATIONS(FOR PERMITTING PURPOSES) EMISSION FACTOR
INmmBtu
TOXIC AIR POLLUTANT CAS Num. INhr lb/day lby uncontrollae wntmlled
Acelaloen a 750M 3.98E-02 9.56E-01 348.998 8.30E-04 8.30E-a
AcroleN H 107025 1.92E-01 4.61E+00 1681.920 4.00E-03 4.00E-03
Arsenic Unlisted Compounds(wintionent of ASC ASC-other 1.06E-03 2.53E-02 9.251 210E-05 210E-05
Benzene 71432 2.02E-01 4.84E+00 1766,016 4.20E-03 410E43
Benzo a ne M 50328 1.25E-04 3.00E-03 1.093 2.80E-08 2.80E-OB
Beryllium Metal unneeded)(wmponent of BEC IH 7440417 5.28E-05 1.27E-03 0A63 1.10E-08 1.10E-06
Cadmium Metal unmaded)(wmpanera of CDC)(T8Q - 7440439 1.97E-04 472E-03 1.724 4.10E-0B 4.10E-06
Carton tetrachloride H 56235 2.16E-03 5.18E-02 18.922 4.50E-05 4.50E-05
Chlorine 7782505 3.79E-02 9.10E-01 332.179 7.90E-04 7.90E-04
Chlombenzene H) 108907 1.58E-03 3.80E-02 13.876 3.30E-05 3.30E.05
Chloroform H 07063 1.34E-03 3.23E-02 11.773 2.80E-05 2.80E-05
Di(2-eta ne alate EHP) H 117817 2.26E-06 5.41E-05 1.91 470E.08 4.70E-08
Ethylene dichlonda If 24ichlarestnane H 107062 1.39E-03 3.34E-02 12.194 2.90E-05 2.90E-05
Soluble Chmmate Cm s,as Chrome SOLCRB 1.66E-04 4.03E-03 1,472 3.50E+8 3.50E-08
Fonnamen 0 501100 2.11E-01 5.07E+00 1850.112 440E-03 4.40E03
Hexadllorodibenzo- mxn 12,3,6,7,8 M 57653857 1.53E09 3.66E-08 0.000 3.18E-11 3ABE-11
hydrogen Monde(hydrochloric acu)(TH) 7047010 9.12E-01 2.19E+01 7989,120 1.90E-02 150E-02
Manganese Unleted Compounds(aimpinent of MNC)(TI9 ANC-other 268E-02 1.84E+00 672.768 1SOE-03 1SOE-03
Mercury,va r(aimponent of HGC) M 7439976 1.68E-04 4.03E-03 1.472 3.50E+8 3.50E-06
Methyl chlomform 1,1,1 trichmroethene 71556 1.49E-03 3.57E-02 13.035 3.10E-05 3.10E-05
Mel My ketone(T) 75933 2.59E-04 622E-03 2.271 5.40E-08 5.40E-05
Meltr ens chlarde H)dichlommelnane 75092 1.39E-02 3.34E-01 121.939 290E-04 2.90E-04
Nickel mate)(Component of 373024/NIC M 7440020 1.58E-03 3.80E-02 13.876 3.30E.05 3.30E-05
Pentschlomphenol H) 87885 2.45E-06 5.88E-05 0,021 510E-08 5.10E-08
Pemnlomem ene teeachlometh ene H 127184 1.82E-03 4.38E-02 15.978 340E-05 380E-05
Phenal 108952 2.45E-03 5.SBE-02 21.444 5.10E-06 5.10E-05
Poi manned biphenyls(11) 133e383 3.91E-07 9.39E-06 3.43E-03 8.15E-09 6.15E-09
Styrene H 100425 9.12E-02 I 2.19E+00 798.912 1.90E-03 1.90E-03
Tetracnlimdebnzo-pdmtln,23,7,8- 1746010 4.13E-10 9.91E-09 3.62E-06 B.SOE-12 8.90E-12
Toluene H 108883 4.42E-02 1.06E+00 386.842 e20E-04 820E-04
Trichlometn ene H 79018 1.44E-03 3.46E-02 12.614 3.00E-05 3.00E.05
Tdchlomfluommethane CFC 111 75ON 1.97E-03 4.72E-02 17.240 4.10E-05 4.10E-05
Vm Mlorde 75014 8.64E-04 2.07E-02 T569 1.BOE05 1.80E-05
Xylene(TH) 1330207 1.20E-03 2.88E-02 10.512 2.50E-05 2.50E-05
ACTUAL EMISSIONS POTENTIAL EMISSIONS-utilize max heat POTENTIAL EMISSIONS With
input capacity and EPA MRR Emission Requested Emission Limitation-
Factors utilize requested fuel limit and EPA
MRR Emission Factors
EPA MRR CALCULATION METHOD:TIER 1
GREENHOUSE GAS metric tons/yr, short tons/yr,
metric tonstyr CO2e short tons r short tonstyr short tons/ r,CO2e short tonW CO2e
CARBON DIOXIDE(CO2)
BIOGENIC EMISSIONS' 3637079 zero 40,091,88 43,476.24 zero' 43476.24 zero'
METHANE CH4 2.79E+00 6.98E+01 3.08E+00 3.34E+00 8.34E+01 3.34E+00 8.34E+01
NITROUS OXIDE N20 1.40E+00 I 4.16E+02 I 1.54E+00 1.67E+00 4.97E+02 1.67E+00 4.97E+02
TOTAL
485.77 TOTAL 580.67 TOTAL 580.67
BIOGENIC CO2 has 0 CO2e NOTE.The DAO Air Emissions Reporting Online(AERO)system requires short tons
NOTE: CO29 means CO2 equivalent The EPA MRR requires metric tons
Note:Do not use greenhouse gas emission estimates from this spreadsheet for PSD(Prevention of Si nificzi Deterioration)purposes.

Huddleston, Betsy
From: [e-mail]
Sent: Tuesday, March 28, 2017 1:54 PM
Subject: Inventory submission confirmation -- 0800044
Dear Brian Conner
Your submittal of the 2016 emission inventory for Avoca Incorporated,0800044, has been received by the North
Carolina Division of Air Quality (DAQ) on March 28, 2017 at 13:53:18.You have until the due date of the emission
inventory or two weeks from this submittal to review and repudiate the data submitted.
Please remember to:
-print the Certification Form (see AERO Closeout page),
- have the Responsible Official sign it in blue ink,
-include copies of spreadsheets or calculations used in creating this inventory, and
- mail (postmark) it to NCDAQ, 943 Washington Square Mall,Washington, NC 27889 by the required due date in order
for this submittal to be considered complete. If you have any questions, please feel free to contact Betsy Huddleston, in
the Washington Regional Office, at252-946-6481.
'The Division of Air Quality thanks you for using AERO,the on line emissions inventory program.
Sincerely
DAQ
i ,
1

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president, secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship; a general partner or the proprietor,respectively;
3.for a muncipality, state,federal, or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION
(Important- Legally
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report, including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Si tune Below use blue ink): Date Signed:
Printed Name: Davi ele
Signature: ,,-71
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
i
Email address of Responsible Official: David.Peele@avocainc,com
MAR 3 1
Information on this Form cannot be held confidential _
COPY of RECORD Date Submitted: 3/28/2017 13:53:18 1

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Listing of Emission Sources and Control Devices on Permit. See instructions
DES ID on Air Permit DES Description CS 1D GCS Description CD ID's
One distillation column one(1)jet ejector
(6 gallons per minute venturi—type wet
A-2.16A nominal process rate) CS-1 scrubber(10 GPM CD—M-34
[MACT FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
one condenser(ID No.
C-3001 One centrifuge [PSD] CS-11 CD-3001)installed on CD-3001
centrifuge,reactor and
heat exchanger/dryer
C-3002 One centrifuge [PSD]
C-31203 One centrifuge [MACT
FFFF]
C-4001 One centrifuge [PSD,
MACT FFFF]
One(1)water spray
fume scrubber used in
the EVG Operation
One steam—heated dryer (batch flavorant
D-1201 [MACT FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorant process)
one(1)jet ejector
One steam—heated dryer venturi—type wet
D-1202 with condenser[MACT CS—I scrubber(10 GPM CD—M-34
FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
One(1)water spray
fume scrubber used in
the EVG Operation
One reactor[MACT (batch flavorant
D-1215 FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorantprocess)
D-1218 One reactor[MACT CS-7 I One(1)water spray CD—Z-9215,CD—Z-9216
2

FFFF] fume scrubber used in
the EVG Operation
(batch flavorant
process),One(1)
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorantprocess)
one(1)jet ejector
One batch reactor venturi—type wet
D-1231A.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
One batch reactor venturi—type wet
D-1231B.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide O s.
One(1)water spray
fume scrubber used in
the EVG Operation
One reactor[MACT (batch flavorant
D-2202 FFFF] CS-7 process),One(1) CD—Z-9215,CD—Z-9216
caustic solution fume
scrubber used in the
EVG Operation(batch
flavorant process)
One steam—heated dryer one condenser(ID No.
D-3001 equipped with a chilled CS-11 CD-3001)installed on CD-3001
water process condenser centrifuge,reactor and
(EX-3002) [PSD] heat exchanger/dryer
One steam—heated dryer
D-3002 equipped with a chilled
water process condenser
(EX-3006) [PSD]
One dryer with process
D-4001 condenser(EX-4004)
[PSD,MACT FFFF]
One waste solids
D31211 separator vessel(1,333
gallon capacity) [MACT
FFFF]
D31214 One product extract
reactor MACT FFFF
One No. 2 fuel oil—fired
emergency generator
E 101 (587 horsepower
maximum rated power
,output) [MACT ZZZZ]
E 102 One No. 2 fuel oil—fired
emergency generator
(760 horsepower
3

maximum rated power
output) MACT ZZZZ]
One No. 2 fuel oil—fired
emergency generator
E 103 (603 horsepower
maximum rated power
output) MACT ZZZZ]
One No. 2 fuel oil—fired
emergency generator
E104 (401 horsepower
maximum rated power
output) MACT ZZZZ]
Chilled Water—Cooled
Condenser,Packed
ES-1001-1-1—F Process equipment leaks CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Arwn process tank M-1 Condenser,Packed
Tower Scrubber(10
� '
ES-1001-1-1—P1 [PSD CAM MACT CS-17 CD-31209 CD-1001-2-5-1
FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Stripper T-5 and Condenser,Packed
ES-1001-1-1—P2 receiver M-21 [PSD CS-17 Tower Scrubber(10 CD-31209 CD-1001-2-5-1
CAM,MACT FFFF] gpm mineral oil '
scrubbing liquid
injection rate),
Seven process tanks of Chilled Water—Cooled
various capacities and Condenser,Packed
ES-1001-1-1—P3 one fixed roof methanol CS-17 Tower Scrubber(10 CD-31209,CD—1001-2—S-1
storage tank(7,050 gpm mineral oil
gallon capacity) [PSD, scrubbing liquid
MACT FFFF] injection rate),
Chilled Water—Cooled
Recovery Operations Condenser,Packed
ES-1001-1-1—WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
Process equipment leaks Tower Scrubber(10
ES-1001-1-2—F [MACT FFFF] CS-17 gpm mineral oil CD-31209,CD-1001-2—S-1
scrubbing liquid
injection rate),
ES-1001-1-2—P Six process tanks of CS-17 Chilled Water—Cooled CD-31209,CD-1001-2—S-1
various capacities [PSD, Condenser,Packed
MACT FFFF] Tower Scrubber(10
gpm mineral oil
4

scrubbing liquid
injection rate),
Chilled Water—Cooled
Concrete Operations Condenser,Packed
ES-1001-1-2—WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
[MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
ES-1001-1-3—Filters Filters [MACT FFFF]
Eleven(11)process
tanks of various
capacities: Hexane
storage tank(M-2)
Process tank(M-4)with
chilled water process
condenser(T-6)
Process tank(M-4A)
with chilled water
process condenser
(T-6A)Receiver tank
(M-39)for M-4/T-6 one(1)jet ejector
Process tank(M-44) venturi—type wet
ES-1001-1-3—P with two chilled water CS-1 scrubber(10 GPM CD—M-34
process condensers injection rate, ID No.
(T-13 and T-15) M-34)Sclareolide Ops.
Receiver tank(M-16)
for T-13 and T-15
Crystallizer tank
(M-15)Tank for cooled
hexane for centrifuge
(M-11)Receiver tank
for dryer condenser
(TK-1210)Process tank
(M-17)Process tank
(M-17A) [MACT
FFFF
one(1)jet ejector
SDE-1 wastewater venturi—type wet
ES-1001-1-3—WW stream[MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
Process equipment leaks venturi—type wet
ES-1001-1-4—F.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide Ops.
one(1)jet ejector
venturi—type wet
ES—1001-1-4—P.16A Four process tanks of various capacities CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide Ops.
ES-1001-1-4—WW.16A SDE Operations CS-1 one(1)jet ejector CD—M-34
wastewater stream venturi—type wet
5

[MACT FFFF] scrubber(10 GPM
injection rate,ID No.
M-34) Sclareolide O s.
Chilled Water-Cooled
ES-1001-11-F Process equipment leaks CS-16 Condenser,Liquid CD-100111EX1002,CD-100111EX1003
[PSD,MACT FFFF] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-1001,desolventizer
Z-1002,day tank 90024
(6,000 gallon capacity),
first-stage evaporator Chilled Water-Cooled
ES-1001-11-P EX-1012,second-stage CS-16 Condenser,Liquid CD-100 11 1EX1002,CD-100111EX1003
evaporator EX-1013, Nitrogen-Cooled
distillation column Condenser,
EX-90008,and nine
process tanks of various
capacities [PSD, CAM,
MACT FFFF
Botanical extraction Chilled Water-Cooled
ES-1001-11-WW operation wastewater CS-16 Condenser,Liquid CD-100 11 1EX1002,CD-100I I1EX1003
stream [PSD,MACT Nitrogen-Cooled
FFFF] Condenser,
Chilled Water-Cooled
Condenser,Packed
ES-1001-2-1-F Process equipment leaks CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5--1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Rotocel extractor, Chilled Water-Cooled
desolventizer,and Condenser,Packed
ES-1001-2-1-PI solvent CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
separation/recovery gpm mineral oil
[PSD,CAM,MACT scrubbing liquid
FFFF] injection rate),
Chilled Water-Cooled
Rotocel Operations Condenser,Packed
ES-1001-2-1-WW wastewater stream CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-S-1
[PSD,MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
one(1)jet ejector
SDE-1 process venturi-type wet
ES-1001-3-F equipment leaks CS-1 scrubber(10 GPM CD-M-34
[MACT FFFF] injection rate, ID No.
M-34) Sclareolide O s.
one condenser(ID No.
ES-1003-10-F Process equipment leaks CS-11 CD-3001)installed on CD-3001
[PSD] centrifuge,reactor and
heat exchanger/dryer
ES-1003-10-WW SFG Process wastewater CS-11 one condenser(ID No. CD-3001
stream[PSD] CD-3001)installed on
6

centrifuge,reactor and
heat exchanger/dryer
ES-1003-2-1—F Process equipment leaks
[MACT FFFF]
Seven process tanks of
ES-1003-2-1—P various capacities
MACT FFFF
ES-1003-2-1—WW PNE process wastewater
stream MACT FFFF]
one(1)jet ejector
Process equipment leaks venturi—type wet
ES-1003-2-2—F [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide O s.
one(1)jet ejector
EVG Operation venturi—type wet
ES-1003-2-2—WW wastewater stream CS-1 scrubber(10 GPM CD—M-34
[MACT FFFF] injection rate,ID No.
M-34) Sclareolide Ops.
Chilled Water—Cooled
Condenser,Liquid
ES-1004-1 Biomass extraction CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
debagging [PSD] Condenser,
(CD1004-2EX1002 and
1003)
Chilled Water—Cooled
Condenser,Liquid
ES-1004-2—F Process equipment leaks CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
[PSD] Condenser,
(CD 1004-2EX1002 and
1003)
Immersion extractor
Z-41001,desolventizer
Z-41002,day tank
490025 (9,953 gallon
capacity), isohexane
storage tank 490024 Chilled Water—Cooled
(13,536 gallon Condenser,Liquid
ES-1004-2—P capacity),first stage CS-21 Condenser,
Cooled CD-1004-2EX1002,CD-1004-2EX1003
evaporator EX-41012, r,
second stage evaporator CD1004-2EX1002 an 1
EX-41013,distillation 1003)
column EX-490008,
and nine process tanks
of various capacities
[PSD,CAM]
Chilled Water—Cooled
Biomass extraction Condenser,Liquid
ES-1004-2—WW operation wastewater CS-21 Nitrogen—Cooled CD-1004-2EX1002,CD-1004-2EX1003
stream [PSD] Condenser,
(CD1004-2EX1002 and
1003)
7

ES-1004-2Silo Biomass silo loadout CS-23 Bagfilter(254 square CD-1004-2—FF2
feet of filter area),
SDE-2 process
ES-4000—F equipment leaks [PSD,
MACT FFFF]
SDE-2 process
ES-4000—WW wastewater stream
SD,MACT FFFF
One biomass/bio—based
solids—fired boiler(24 one simple cyclone
million Btu per hour (144 inches in
ES—BB maximum heat input CS-24 diameter),one bagfilter CD—BB1C,CD—BBIBH
(8
rate) [NSPS —Dc, square feet of
MACT—DDDDD] filtterer area),
One biomass/bio—based
solids—fired boiler(24 one simple cyclone
million Btu per hour (144 inches in
ES—BB2 CS-24 diameter),onebagfilter CD—BBIC,CD—BBIBH
maximum heat input p (8,900 square feet of
rate) [NSPS—Dc,
MACT—DDDDD] filter area),
one storage and recycle
ES—M-125A tank(19,500 gallons
capacity) MACT FFFF]
one storage and recycle
ES—M-125B tank(19,500 gallons
capacity) [MACT FFFF]
ES—MDSU-1024 molecular sieve
One No. 2 fuel oil—feed
limited use emergency Oxidation Catalyst
generator(2,935 [17 070 acfin(6,854 ES—PkGenl kilowatt maximum rated CS-22 scfin)inlet air flow rate CD—CatOxl
power output) [MACT at 695 OF—835 OF],
ZZZZ]
One No. 2 fuel one simple cyclone
oil/propane—fired rotary (144 inches in
ES—RD dryer(30 million Btu CS-24 diameter),one bagfilter CD—BBIC,CD—BBIBH
per hour maximum heat (8,900 square feet of
input rate) filter area),
solvent process tank
ES—TK—PNE-1 (9,500 gallons capacity)
MACT FFFF
One No. 2 fuel oil—fired
emergency fire water
FP pump (285 horsepower
maximum rated power
output) [MACT ZZZZ]
one(1)jet ejector
One centrifuge [MACT venturi—type wet
G 17 FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34)Sclareolide O s.
8

One No. 2 fuel oil—feed
boiler(20.3 million Btu
11 101 per hour maximum rated
heat input)[2D.1109
case—by—case MACT
One No. 2 fuel oil—fired
boiler(20.3 million Btu
11 102 per hour maximum rated
heat input) [21) .1109
case—by—case MACT]
One No.2 fuel oil—fired
boiler(25.2 million Btu
H-103 per hour maximum rated
heat input)[2D .1109
case—by—case MACT
Chilled Water—Cooled
Condenser,Packed
HB-1 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-2 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2—S-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-3 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
box[MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed
HB-4 One steam—heated hot CS-17 Tower Scrubber(10 CD-31209,CD-1001-2-5-1
box [MACT FFFF] gpm mineral oil
scrubbing liquid
injection rate),
I—Briquette sage briquetting
machine
ECS process: batch
IECS preparation of
ethylenediamine/copper
sulfate solution
IES—PV Provane vaporizer
No.2 fuel oil storage
ITK102 tank(495 gallon
capacity)
No. 2 fuel oil storage
ITK103 tank(495 gallon
capacity)
9

No.2 fuel oil storage
ITK9238 tank(50,000 gallon
capacity)
No. 2 fuel oil storage
ITK9239 tank(50,000 gallon
capacity)
No. 2 fuel oil storage
ITKFP tank(270 gallon
capacity)
Wastewater treatment
IWWTP—AT2 plant aeration tank No.2
(63,500 gallon capacity)
Wastewater treatment
IWWTP—AT3 plant aeration tank No. 3
(63,500 gallon capacity)
Wastewater treatment
IWWTP—CLR plant clarifier(1,310
gallon capacity)
Wastewater treatment
I WWTP—ET1 plant equalization tank
No. 1 (65,500 gallon
capacity)
Wastewater treatment
IW WTP—ET2 plant equalization tank
No.2 (65,500 gallon
capacity)
one(1)jet ejector
One batch reactor venturi—type wet
M-10.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide Ops.
one(1)jet ejector
One batch reactor venturi—type wet
M-10A.16A [MACT FFFF] CS-1 scrubber(10 GPM CD—M-34
injection rate,ID No.
M-34) Sclareolide O s.
one(1)jet ejector
One acetic acid storage venturi—type wet
M-20.16A tank(10,135 gallon CS-1 scrubber(10 GPM CD—M-34
capacity) [MACT FFFF] injection rate,ID No.
M-34) Sclareolide O s.
One plant material one(1)fabric filter
grinder(1,011 pounds (244 square feet of filter
MHZ-1002 per hour nominal feed CS-4 surface area,ID No. CD-1003-4-1
rate) CD-1003-4-1)
One reactor equipped one condenser(ID No.
R 3001 with a chilled water CS-11 CD-3001) installed on CD-3001
process condenser centrifuge,reactor and
(EX-3001) [PSD] heat exchanger/dryer
R-3002 One reactor equipped
with a chilled water
10

process condenser
(EX-3003) FPSDI
One reactor equipped
R-3003 with a chilled water
process condenser
(EX-3004) PSD
One reactor equipped
R-3004 with a chilled water
process condenser
(EX-3005) PSD
One 4,200 gallon reactor
R-4004 with process condenser
(EX-4001) [PSD,
MACT FFFF
One 4,200 gallon reactor
R-4005 with process condenser
(EX-4002) [PSD,
MACT FFFF
R 4015 One 1,500 gallon reactor
[PSD,MACT FFFF]
One 4,200 gallon reactor
R-4044 with process condenser
(EX-4003) [PSD,
MACT FFFF
one condenser(ID No.
T-3001 One process tank(6,700 CS-11 CD-3001)installed on CD-3001
gallon capacity) [PSD] centrifuge,reactor and
heat exchanger/dryer
one condenser(ID No.
T-3002 One process tank(2,538 CS-11 CD-3001) installed on CD-3001
gallons capacity) [PSD] centrifuge,reactor and
heat exchanger/dryer
T-3003 One process tank(2,538
gallons capacity) [PSD]
T-3004 One process tank(2,538
gallons capacity) PSD
T-3005 One process tank(2,538
gallons capacity) PSD
T-3006 One storage tank
(12,500gallons) [PSD]
T-3007 One process tank
(12,500 gallons) [PSD]
One 17,900 gallon
T-4001 virgin solvent tank
[PSD,MACT FFFF]
One 6,000 gallon
T-4017 process tank [PSD,
MACT FFFF]
T-4018 One 6,000 gallon
process tank[PSD,
11

MACT FFFF
Wastewater treatment
WWTP—ATI plant aeration tank No. I
[PSD,MACT FFFF]
12

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Emission Source & Operating Scenario List- See Instructions
DES Group ID DES ID *OS ID *OS Description
GRl ES-1004-1,ES-1004-2-F, 28 Extraction of Fermented Biomass
ES-1004-2-P,ES-1004-2-WW
GR2 ES-BB1,ES-BB2,ES-RD 33 Biomass Boiler Operation with Wood
Chips as fuel source
G-76 H-101,H-102,H-103 46 Boilers
G-77 E101,E102,E103,E104,FP 42 Generators
ES-1001-1-1-F,ES-1001-1-1-P1, Rotocel, Sage, Recovery,and
ES-1001-1-1-P2,ES-1001-1-1-P3, 35 Distillation
ES-1001-1-1-WW,
G-94 ES-1001-1-2-F,ES-1001-1-2-P,
ES-1001-1-2-WW, Rotocel/Recovery/Concrete Operations
ES-1001-2-1-F,ES-1001-2-1-P1, 43 Fugitive Loss
ES-1001-2-1-WW,HB-1,HB-2,
HB-3,HB-4
A-2.16A,D-1202,D-1231A.16A, Conversions (Sclareolide SDE:
D-1231B.16A,ES-1001-1-3-P, 36 Biological and Chemical)
ES-1001-1-3-WW,
ES-1001-1-4-F.16A,
G-95 ES-1001-1-4-P.16A,
ES-1001-1-4-WW.16A, 44 SDE Fugitive Emissions
ES-1001-3-F,ES-1003-2-2-F,
ES-1003-2-2-WW,G-17,
M-10.16A,M-IOA.16A,M-20.16A
C-3001,D-3001,ES-1003-10-F, 39 Sclareol Re-crystallization(SFG)
G-96 ES-1003-10-WW,R-3001,T-3001,
T-3002 45 SFG Fugitive Emissions
C-31203,D31211,D31214, 37 Plant Nutrient Extraction NE)
G-97 ES-1003-2-1-F,ES-1003-2-1-P,
ES-1003-2-1-WW 38 PNE-Isohexane Extraction
G-99 D-1201,D-1215,D-1218,D-2202 41 EVG(batch flavorant)
G-150 ES-1001-11-F,ES-1001-I I-P, 40 Botanical extraction process(includes
ES-1001-11-WW botanical vents,condensers,tanks,etc)
C-3002 NONE NONE
C-4001 NONE NONE
D-3002 NONE NONE
D-4001 NONE NONE
ES-1001-1-3-Filters NONE NONE
13

� I
ES-1004-2Silo 30 Silo load out of spent biomass
ES-4000—F NONE NONE
ES-4000—WW NONE NONE
ES—M-125A NONE NONE
ES—M-12513 NONE NONE
ES—MDSU-1024 NONE NONE
ES—PkGenl 12 Peak Shaving Generator
ES—TK—PNE-1 NONE NONE
I—Briquette NONE NONE
IECS 31 EDA Process
IES—PV NONE NONE
ITK102 NONE NONE
ITK103 NONE NONE
ITK9238 NONE NONE
ITK9239 NONE NONE
ITKFP NONE NONE
IWWTP—AT2 NONE NONE
IWWTP—AT3 NONE NONE
IWWTP—CLR NONE NONE
IWWTP—ETI NONE NONE
IWWTP—ET2 NONE NONE
MHZ-1002 34 Misc: Plant Material Grinder
R-3002 NONE NONE
R-3003 NONE NONE
R-3004 NONE NONE
R-4004 NONE NONE
R-4005 NONE NONE
R-4015 NONE NONE
R-4044 NONE NONE
T-3003 NONE NONE
T-3004 NONE NONE
T-3005 NONE NONE
T-3006 NONE NONE
T-3007 NONE NONE
T-4001 NONE NONE
T-4017 NONE NONE
T-4018 NONE NONE
Waste Water Treatment 1st Aeration
WWTP—AT1 32 Chamber(Includes methanol usages
from PNE and EVG)
14

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group GRI consisting of ES—1004-1,ES—1004-2—F, ES—1004-2—P,
Emission Source Group ID ES-1004-2—WW
2. Emission Source Description: Biomass Extraction Operation
3. Operating Scenario ED/Description: OS—28/Extraction of Fermented Biomass
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 1 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur %Asli Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
] CS-21 CD-1004-2EX1002 One chilled water condenser
2 CS-21 CD-1004-2EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-4 IVERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
15

Operating Scenario:OS—28 Emission Source/Group ID: GR1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 100% 0% une—Aug. 0% ept.—Nov. Il
016 Varch—May
16 �016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission
CAS Gf Control
Pollutants
Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficient Emission
(NAAant Code Pollutants Method Code y l?f Control
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
SO2 SO2 08 0
VOC VOC 0.18 03 98
HAP/TAP Emissions Emission Control
Efficient Emission CAS Estimation
Pollutants (In HHAP/TAPSy i EF Control
Alphabetical Order)
(see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 13.68 03 98
16

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group GR2 consisting of ES—BB I,ES—BB2,ES—RD
Emission Source Group ID
2. Emission Source Description: Biomass Boilers
3. Operating Scenario ID/Description: OS—33Biomass Boiler Operation with Wood Chips as fuel source
4. SCC Number/Description: 10200904Bark ; Bark—fired Boiler(<50,000 Lb Steam)
5. Throughput/units in 2016: 25211.2 TON/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur %Ash Heat Content 8000000 Btu/ton
Btu/units
7. Capture Efficiency
(°/u of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-24 CD—BB1C one simple cyclone 144 inches in diameter
CS-24 CD—BB1BH one ba filter(8,900 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry fines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP—BB1 VERTICAL STACK GO 3 240.8 24 10178.76 Biomass BoilersExhaust
17

Operating Scenario: OS—33 Emission Source/Group ID: GR2
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
016 016 �016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Inswctions all controls
2016
Carbon Dioxide CO2 124389 19664.74 08 0
Methane CH4 74-82-8 2.12 08 0
Nitrous Oxide 20 10024972 1.31 08 0
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 19.36 04
NOx NOx 22.19 09
TSP TSP 0.14 04 99
PM10 PM10 0.14 04 99
PM2.5 PM2.5 0.14 04 99
S02 S02 2.52 09
VOC VOC 1.71 09
Emissions Emission Control
HAP/TAP CAS Estimation Efticienc� Emission
Pollutants (In Alphabetical Order) (see instructions)ctions) HAP/TAPS Method Code (Net after all Factor EF Control
See Instructions) controls)
2016
Acetaldehyde 75-07-0 167.402 09
Acrolein 107-02-8 806.758 09
Benzene 71-43-2 847.096 09
Benzo(a)pyrene(Component of 50-32-8 0.524 09
POMTV POM7
Carbon tetrachloride 56-23-5 9.076 09
Chlorine 7782-50-5 159.335 09
Chlorobenzene 108-90-7 6.656 09
Chloroform 67-66-3 5.647 09
Eth lbenzene 100-41-4 6.252 09
Formaldehyde 50-00-0 887.434 09
18

Hydrogen chloride 7647-01-0 18.152 04 0
(by drochloric acid
Mercury,vapor(Component of 7439-97-6 0.058 04 0
HGC
Naphthalene(Component of 91-20-3 19.564 09
POM
Phenol 108-95-2 10.286 09
Pro ionaldeh de 123-38-6 12.303 09
Styrene 100-42-5 383.21 09
Toluene 108-88-3 185.554 09
X lene 1330-20-7 5.042 09
19

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-76 consisting of H-101,H-102,H-103
Emission Source Group ID
2. Emission Source Description: Boilers
3. Operating Scenario ID/Description: OS—46Boilers
4. SCC Number/Description: 10200501/Distillate Oil(No. 1 2) ; Grades 1 and 2 Oil
5. Throughputtunits in 2016: 672840.3 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed in ertnit
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP—B-1 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler: vertical with
rain ran
EP—B-3 VERTICAL STACK 45 2.5 500 34.6 10190.54 boiler: vertical with
rain cap
EP—B-2 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler: Horizontal
20

Operating Scenario: OS-46 Emission Source/Group ID: G-76
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an-Feb +Dec 27% arch-May 13% une-Aug. 18% ept.-Nov. 42%
�016 1 016 1 �016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions- Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 7636.7375 08 22.7
Methane CH4 74-82-8 0.0202 08 0.00006
Nitrous Oxide 20 10024972 0.0404 08 0.00012
Criteria Emissions- Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) enc y Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 1.68 09 0.005
NOx NOx 8.07 09 0.024
TSP TSP 0.67 09 0.002
PM10 PM10 0.3 09 0.0009
PM2.5 PM2.5 0.08 09 0.00025
S02 S02 14.33 09 0.0426
VOC VOC 0.07 09 0.0002
HAP/TAP Emissions Emission Control
Pollutants (In Alphabetical CAS HAP/TAPS Estimation Efficiency Emission EF Control
Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions) controls)
2016
Arsenic Unlisted
Compounds(Specify ASC-Other 0.37679 09 5.6E-7
Component of ASC
Benzene 71-43-2 1.85031 09 0.00000275
Beryllium metal(unreacted) 7440-41-7 0.28259 09 4.2E-7
(Component of BEC
Cadmium Metal(elemental
unreacted,Component of 7440-43-9 0.28259 09 4.2E-7
CDC
Chromic acid(VI)
(Component of So1CR6 7738-94-5 0.28259 09 4.2E-7
CRC
21

Eth I benzene 100-41-4 0.54971 09 8.17E-7
Fluorides(sum of all 16984-48-8 25,09694 09 0.0000373
fluoride compounds)
Formaldehyde 50-00-0 32,29634 09 0.000048
Lead Unlisted Compounds
(Specify and Component of PBC—Other 0.84778 09 0.00000126
PBC
Manganese Unlisted
Compounds(Specify MNC—Other 0.56519 09 8.4E-7
Component of MNC
Mercury,vapor(Component 7439-97-6 0.28259 09 4.2E-7
of HGC
Naphthalene(Component of 91-20-3 0.22406 09 3.33E-7
POMT
Nickel metal(Component of 7440-02-0 0.28259 09 4.2E-7
NIC
Polycyclic Organic Matter
(Inc PAH,dioxins,etc.NC POINI 2.22037 W) 0.0000033
AP 42 historic amorphous
lob
Toluene 108-88-3 53.62537 09 0.0000797
X lene o— 95-47-6 0.94198 09 0.0000014
22

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-77 consisting of E101,E102,E103,E104,FP
Emission Source Group ID
2. Emission Source Description: Generators
3. Operating Scenario ID/Description: OS—42/Generators
4. SCC Number/Description: 20100102/Distillate Oil(Diesel) ; Reciprocating
5. Throughput/units in 2016: 1942.5 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP104 VERTICAL STACK 11 0.67 1000 96.9 2049.81 Generator ES104
EP101 IVERTICAL STACKI 12 1 0.67 1 1063 160.9 3403.66 Vertical
EP102 VERTICAL STACK 11 1 0.67 1 885 203.4 4302.7 Vertical
EP103 JVFRTICAL STACK 10 0.67 1 1063 174.4 3689.24 Vertical
23

Operating Scenario: OS—42 Emission Source/Group ID: G-77
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 24% arch—May 29% une—Aug. 24% ept.—Nov. 23%
016 016 2016 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and.documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 6.02 09
Methane CH4 74-82-8 0.0012 09
Nitrous Oxide 20 10024972 0.0001 09
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po� Code Pollutants Method Code Ef Control
Pollutants an (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 0.12 09
NOx NOx 0.04 09
TSP TSP 0.01 09
PM10 PM10 0.01 09
PM2.5 PM2.5 0.01 09
S02 S02 0.02 09
VOC VOC 0.05 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Acetaldehyde 75-07-0 0.007 09
Acrolein 107-02-8 0.002 09
Arsenic Unlisted Compounds( ASC—Other 0.001 09
Specify Component of ASC
Benzene 71-43-2 0.213 09
Benzo(a)pyrene(Component of 50-32-8 0.0001 09
POMTV POM7
Beryllium metal(unreacted) 7440-41-7 0.001 09
(Component of BEC
Cadmium Metal(elemental 7440-43-9 0.001 09
unreacted Component of CDC
24

Formaldehyde 50-00-0 0.022 09
Naphthalene (Component of 91-20-3 0.036 09
POMTV
Toluene 108-88-3 0.077 09
X lene 1330-20-7 0.053 09
25

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID (from permit)or Group G-94 consisting of ES-1001-1-1—F, ES-1001-1-1—P1,
Emission Source Group ID ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2—F,
ES-1001-1-2—P,ES-1001-1-2—WW,ES-1001-2-1—F,ES-1001-2-1—P1,
ES-1001-2-1—WW,HB-1,HB-2,HB-3,HB-4
2. Emission Source Description: Rotocel,Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—35/Rotocel, Sage,Recovery, and Distillation
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 136749927 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-17 CD-31209 One chilled water condenser
2 CS-17 CD-1001-2—S-1 One packed tower scrubber(8 gallons per minute minimum mineral oil
in'ection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try fines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1001-11-1 VERTICAL STACK 42 0.5 68 127.4 1500.89 Vertical
26

Operating Scenario:OS—35 Emission Source/Group ID: G-94
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 24% arch—May 22a�o uneAug. 26% Sept.—Nov. 28%
016 016 �016_
016
13. Actual Emis ions o r Poll utant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(N�QS Code Pollutants Method Code (Net after Factor Ef Control
Pollutants
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 95.2 03 98
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 187584.93 03 98
except n—hexane
Hexane n— 110-54-3 2817.48 03 98
27

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-94 consisting of ES-1001-1-1—F,ES-1001-1-1—P1,
Emission Source Group ID ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2-17,
ES—100 1—1-2—P,ES—100 1—1—2—WW,ES—100 1—2—1—F,ES—100 1-2—1—P 1,
ES-1001-2-1—WW,HB-1,HB-2,HB-3,HB-4
2. Emission Source Description: Rotocel, Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—43/Rotocel/Recovery/Concrete Operations Fugitive Loss
4. SCC Number/Description: 30188801/*Fugitive Emissions ; Specify in Comments Field
5. Throughput/units in 2016: 136749927 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /a Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume ERP Description
(in feet) Circle(enter (F) (Feet/sec) Flow
): Rate
Rectangle(L (Acfm)
W)
in 0.1 feet)
IG-94 FUGITIVES FUGITIVE(NO 1 72 Area= 1 Rotocel/Recovery/Concrete Fugitives
STACK
28

Operating Scenario:OS—43 Emission Source/Group ID: G-94
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec arch—May ° une—Aug. ° ept.—Nov. °
016 24°�° 016 22�° �016 26�° �016
13. Actual Emissions Fer Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor [If Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(N�QS Code Pollutants Method Code h:f Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 854.22 02
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 1161330.74 02
except n—hexane
Hexane n— 110-54-3 17442.9 02
Methanol 67-56-1 529656.3 02
29

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-95 consisting of A-2.16A,D-1202,D-123 IA.16A,D-1231B.16A,
Emission Source Group ID ES-1001-1-3—P, ES-1001-1-3—WW,ES-1001-1-4—F.16A,
ES-1001-1-4—P.16A,ES-1001-1-4—WW.16A,ES-1001-3—F,
ES-1003-2-2—F, ES-1003-2-2—WW,G-17,M-10.16A,M-10A.16A,
M-20.16A
2. Emission Source Description: Conversions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—36/Conversions(Sclareolide SDE: Biological and Chemical)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 882348.9 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-1 CD—M-34 One venturi—type wet scrubber(10 gallons per minute minimum liquid
injection rate
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-1 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
30

� I
Operating Scenario:OS—36 Emission Source/Group ID: G-95
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec une—Aug. u Sept.—Nov. o
�016 20% �arch—May
16 28% �016 28/0 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG ma GHG Estimation Efficiency Emission
Pollutants CAS l?f Control
Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 16.46 03 98
l
HAP/TAP Emissions Emission ControEmissio n CAS Estimation Efficiency Pollutants (1n HAP/TAPS y EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 23769.86 03 98
except n—hexane
Hexane n— 110-54-3 9044.67 03 98
31

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-95 consisting of A-2.16A,D-1202,D-123 IA.16A,D-123113.16A,
Emission Source Group ID ES-1001-1-3—P,ES-1001-1-3—WW,ES-1001-1-4—F.16A,
ES-1001-1-4—P.16A,ES-1001-1-4—WW.16A,ES-1001-3—F,
ES-1003-2-2—F,ES—1003-2-2—WW, G-17, M-10.16A,M—IOA.16A,
M-20.16A
2. Emission Source Description: Conventions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—44/SDE Fugitive Emissions
4. SCC Number/Description: 30188801/*Fugitive Emissions ; Specify in Comments Field
5. Throughput/units in 2016: 882348.9 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
Y
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
SDE FUGITIVES FUGITIVE(NO 1 72 Area= 1 SDE fugitive
STACK emissions
32

Operating Scenario: OS—44 Emission Source/Group ID: G-95
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 20% arch—May 28% une—Aug. 28% ept.—Nov. 24%
016 016 1 �016 016
13. Actual Emissions ner Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 92.39 02
HAP/TAP Emissions Emission Control
Pollutants (in CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Hexane(isomers, HEXANEISO 110942.26 02
except n—hexane
Hexane n— 110-54-3 73933.21 02
33

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-96 consisting of C-3001,D-3001,ES—1003—1 0—F,
Emission Source Group ID ES-1003-10—WW,R-3001,T-3001,T-3002
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—39/Sclareol Re—crystallization(SFG)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 769376 LB/yr
(e.g. production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7, Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
I CS-11 CD-3001 One chilled water condenser
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume ERP
(in feet) Circle(enter (F) (Feet/sec) Flow Rate Description
): (Acfm)
Rectangle(L x
W)
in 0.1 feet)
P-1003-10-1 DOWNWARD—FACING VENT 19 0.17 80 3 4.08 Horizontal
P-1003-10-3 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-4 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-5 HORIZONTAL STACK 25 0.17 80 10.2 13.89 Horizontal
[EP-1003-10-61 HORIZONTAL STACK 30 0.17 1 100 0.1 0.13 Horizontal
34
I

�P-1003-10-71 VERTICAL STACK 1 19 0.17 80 53 72.17 Vertical
�P-1003-10-21 HORIZONTAL STACK 1 18 0.17 80 0.1 0.13 Horizontal
35

Operating Scenario: OS—39 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throngh ut:
an—Feb +Dec 28% arch—May 31% une—Aug. 15% �016
ept.—Nov. 26%
016 016 �016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission
Pollutants CAS Pollutants Method Code (Net after Factor Ef Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 13.79 02 98
HAP/TAP Emissions Emission Control
CAS Estimation Efficiency Emission EF Control
Alphabetical Order) (Pounds/Year)
Pollutants (see instructions) HAP/TAPS Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 6240.4 03 98
36

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-96 consisting of C-3001,D-3001,ES-1003-10—F,
Emission Source Group ID ES-1003-10—WW,R-3001,T-3001,T-3002
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—45/SFG Fugitive Emissions
4. SCC Number/Description: 30188801/*Fugitive Emissions; Specify in Comments Field
5. Throughputtunits in 2016: 769376 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur NOAsh Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
SFG FUGITIVES FUGITIVE(NO 1 72 Area= 1 SFG fugitive
STACK) emissions
37

l
Operating Scenario: OS—45 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 28% 31% une—Aug. 15% �016
ept.—Nov. 26%
016 �arch—May
16 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net afterFactor Ef Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 55.15 02
HAP/TAP Emissions Emission Control
Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Ethyl acetate 141-78-6 24961.6 08
38

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit) or Group G-97 consisting of C-31203,D31211, D31214,ES-1003-2-1—F,
Emission Source Group ID ES-1003-2-1—P,ES-1003-2-1—WW
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS—37/Plant Nutrient Extraction(PNE)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputlunits in 2016: 358445 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfiir /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point RP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feettsec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
39

Operating Scenario: OS—37 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 34% arch—May 31% une—Aug. 30% �016
ept.—Nov. o
016 016 �016 5/o
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 69.2 03
Emission Control
HAP/TAP Emissions Emission I
CAS Estimation Efficiency
Pollutants (in HAP/TAPS EF Control
Alphabetical Order)
(see instructions) (Pounds/Year) Method Code (Net after all Factor
i
See Instructions controls)
2016
Ethyl acetate 141-78-6 0 03
40

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-97 consisting of C-31203,D31211,D31214,ES-1003-2-1—F,
Emission Source Group ID ES-1003-2-1—P,ES-1003-2-1—WW
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS—38/PNE—Isohexane Extraction
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur r,,Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
41

Operating Scenario:OS—38 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
016 4016 1 �016 Olb
13. Actual Emissi lollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code Ef Control
Pollutantss an (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP Emissions Control
CAS Estimation Emission
Pollutants (In (see instructions) y HAP/TAPS Method Code Efficiency Factor EF Control
See Instructions
Alphabetical Order) (Pounds/Year) (Net after all controls)
2016
42

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bettie
Meng Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-99 consisting of D-1201,D-1215, D-1218,D-2202
Emission Source Group ID
2. Emission Source Description: EVG(batch flavorant)
3. Operating Scenario ID/Description: OS—41/EVG(batch flavorant)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 21998.7 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-7 CD—Z-9215 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
2 CS-7 CD—Z-9216 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
43

Operating Scenario: OS—41 Emission Source/Group ID: G-99
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 100�o 350�o une—Aug. 400�o �016
ept.—Nov. 15%
016 �arch—May
16 �016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) y Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 17.27 03 98
HAP/TAP CAS Emissions Emission Estimation Control Emission
Pollutants (in HAP/TAPS Method Code Efficiency EF Control
(see instructions)
Alphabetical Order) (Pounds/Year) et after all controls) Factor
See Instructions
2016
Chloroform 67-66-3 30676 03 0
Methanol 67-56-1 3868.3 03
44

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or Group G-150 consisting of ES-1001-11—F,ES-1001-11—P,
Emission Source Group ID ES-1001-11—WW
2. Emission Source Description: Botanical Extraction Operations
3. Operating Scenario ID/Description: OS—40Botanical extraction process(includes botanical vents,condensers,
tanks,etc)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016: 1298526.6 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur ro Ash I Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-16 CD-100111EX1002 One chilled water condenser
2 CS-16 CD-100111EX1003 One cryogenic(nitrogen)condenser system(-40 IF maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
(in 0.1 feet)
EP-1-11 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
45
i

Operating Scenario: OS—40 Emission Source/Group ID: G-150
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 37a�o 48a�e une—Aug. 0"�u ept.—Nov.
016 �arch—May
16 �016 �016
13. Actual Emissions Der Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po�QS Code Pollutants Method Code (Net after Factor Ef Control
Pollutantss
(Tons/Year) (See instructions) all controls)
2016
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 2.5 03 98
HAP/TAP Emissions Emission ControlEmission CAS Estimation Efficiency
Pollutants (In HAP/TAPS EF Control
Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
lath I acetate 141-78-6 217.08 03 0
46

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or ES-1004-2Silo
Emission Source Group ID
2. Emission Source Description: Biomass silo loadout
3. Operating Scenario ID/Description: OS—30/Silo load out of spent biomass
4. SCC Number/Description: 39999994/Misceilaneous Industrial Processes ; Other Not Classified
5. Throughputtunits in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-23 CD-1004-2—FF2 One ba filter 254 square feet of filter area
9.Emission Release Point(EPP) Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1004-2—FF2 HORIZONTAL STACK 10 1 8.5 1 72 0.64 2180 Dust Collector on
Silo
47

Operating Scenario:OS—30 Emission Source/Group ID:
ES-1004-2Silo
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25"�u une—Aug. 25"�o Sept.—Nov.
�016 �arch­May
16 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all wntrols
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Code Pollutants Method Code Ef Control
an
Pollutants (Net after Factor
(Tons(Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
SO2 SO2 08
VOC VOC 08
HAP/TAP Emissions Emission Control
CAS Estimation Emission
Pollutants (In HAP/TAPS Efficiency EF Control
Alphabetical Order (see instructions) Pounds/Year p ) ( ) Method Code (Net after all controls) Factor
See Instructions
2016
48

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or ES—PkGenl
Emission Source Group ID
2. Emission Source Description: One No. 2 fuel oil—fired limited use emergency generator(2,935 kilowatt
maximum rated power output) [MACT ZZZZ]
3. Operating Scenario ID/Description: OS— 12/Peak Shaving Generator
4. SCC Number/Description: 20300 10 1/Distillate Oil(Diesel) ;Reciprocating
5. Throughputtunits in 2016: 5122 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur 0.0014 /o Ash I Heat Content 141000 Btu/gallon
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-22 CD—CatOx I One catalytic oxidizer 695 °F minimum inlet temperature)
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height lam
Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F') (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-9 VERTICAL STACK 20 0.17 SRO 0.1 0.13 Horizontal
49

Operating Scenario:OS— 12 Emission Source/Group ID: ES—PkGenl
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 13%u arch—May 13% une—Aug. 54% �016
ept.—Nov. 20%
016 016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2016
Carbon Dioxide CO2 124389 15.88 09 0
Methane CH4 74-82-8 0.0032 09 0
Nitrous Oxide 20 10024972 0.0025 09 0
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 0.31 09 95 AFTER
NOx NOx 1.16 09 98 AFTER
TSP TSP 0.04 09 98 AFTER
PM10 PM10 0.04 09 98 AFTER
PM2.5 PM2.5 0.04 09 98 AFTER
S02 S02 0.05 09 98 AFTER
VOC VOC 0.13 09 98 AFTER
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2016
Acetaldehyde 75-07-0 0.0182 09
Acrolein 107-02-8 0.0057 09
Arsenic Unlisted Compounds ( ASC—Other 0.0029 09
Specify Component of ASC
Benzene 71-43-2 0.5604 09
Benzo(a)pyrene(Component of 50-32-8 0.0002 09
POMTV POM7
Beryllium metal(unreacted) 7440-41-7 0.0022 09 0
(Component of BEC
Cadmium Metal(elemental 7440-43-9 0.0022 09 0
unreacted Component of CDC
50

Formaldehyde 50-00-0 0.057 09
Naphthalene(Component of 91-20-3 0.0939 09
POM
Toluene 108-88-3 0.2029 09
X lene 1330-20-7 0.1394 09
51

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or IECS
Emission Source Group ID
2. Emission Source Description: ECS process:batch preparation of ethylenediamine/copper sulfate solution
3. Operating Scenario ID/Description: OS—31/EDA Process
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur ro Ash I Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
52

Operating Scenario:OS—31 Emission Source/Group ID: IECS
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25%%u arch—May 25% une—Aug. 25% ept.—Nov. 25%
016 016 1 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor Et'Control
Tons/Year See Instructions all controls
2016
Criteria Emissions— Emission Control
AA S Pollutant Criteria Estimation Efficiency Emission
Q ) F,f Control
Code Pollutants Method Code
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP CAS Emissions Emission Control
Pollutants (In HAP/TAPS Estimation E Emission EF Control
Efficiency
(see instructions) Method Code y Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
See Instructions
2016
53

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or MHZ-1002
Emission Source Group ID
2. Emission Source Description: Misc: Grinder,air stripper,lime silo,and Aphios
3. Operating Scenario ED/Description: OS—34/Misc: Plant Material Grinder
4. SCC Number/Description: 31299999/Miscellaneous Machinery ; Other Not Classified
5. Throughput/units in 2016:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o Sulfur FoAsh Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD H) Control Device Description
as listed inpermit)
1 CS-4 CD-1003-4-1 One ba filter 244 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP H) ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1003-4-1 HORIZONTAL STACK 20 1.3 75 37.7 3002.4 Horizontal
54

Operating Scenario: OS—34 Emission Source/Group ID: MHZ-1002
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25%
016 016 �016 016
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission
Pollutants Pollutants Method Code (Net after Factor Ef Control
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation EfficiencyEmission
m�QS Code Pollutants Method Code Ef Control
Pollutantss ants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP CAS Emissions Emission
Control
Pollutants (In HAP/TAPS Estimation Emission
(see instructions) Efficiency EF Control
Alphabetical Order Pounds/Year Method Code Factor
P ) ( ) (Net after all controls)
See Instructions
2016
55

COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
1. Emission Source ID(from permit)or WWTP—AT1
Emission Source Group ID
2. Emission Source Description: Wastewater treatment plant aeration tank No. 1 [PSD,MACT FFFF]
3. Operating Scenario ID/Description: OS—32/Waste Water Treatment Ist Aeration Chamber(Includes methanol
usages from PNE and EVG)
4. SCC Number/Description: 30182006/Wastewater Treatment;Chemical Plant Wastewater System:
Aerated Impoundment
5. Throughput/units in 2016: 14127317 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur %) Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
i
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-14 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
56
I

Operating Scenario: OS—32 Emission Source/Group ID: WWTP—AT1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2016)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%016 016 �016 016
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Et'Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2016
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po� Code Pollutants Method Code Ef Control
Pollutants (Net after Factor
(Tons/Year) (See Instructions) all controls)
2016
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 3.23 03
HAP/TAP CAS Emissions Emission Control
Pollutants (in HAP/TAPS Estimation EfficiencyEmission EF Control
(see instructions) Method Code Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
See Instructions
2016
Methanol 67-56-1 6464.6 03
57
1

Facility Total CY 2016 Emissions Summary
COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2016
Record Facility—Wide Totals From all Permitted and Non—Permitted Air Pollutant Emission Sources
Green House Gases Pollutants(GHG)
Actual Emissions Tons/Year
Pollutant CAS 2016 2015 % Change
Carbon Dioxide CO2 124389 27323,377 29856.902 —8.485559%
Methane CH4 74-82-8 2.1446 2.523 —14.998021%
Nitrous Oxide 20 10024972 1.353 1.5388 —12.074341%
Criteria Pollutants
Actual Emissions Tons/Year
Pollutant CAS 2016 2015 % Change
CO CO 21.47 24.702 —13.083962%
NOx NOx 31.46 33.91 —7.2250094%
PM TSP TSP 0.86 1.215 —29.218105%
PM10 PM10 0.49 .535 —8.411218%
PM2.5 PM2.5 0.27 .305 —11.475408%
S02 S02 16.92 3.104 445.10306%
VOC VOC 1221.55 934.061 30.778406%
Hazardous Air Pollutants PS and/or Toxic Air Pollutants TAPS
Actual Emissions Pounds/Year
Pollutant I CAS 1 2016 1 2015 % Change
Pollutant Grou :Arsenic Compounds total mass of elemental AS arsine and all inorganic compounds) Group Sum:.38069
Arsenic Unlisted Compounds( ASC—Other 0.38069 5.55718 —93.14958%
Specify Component of ASC
Pollutant Group:Beryllium compounds Total mass Group Sum:.28579
Beryllium metal(unreacted) 7440-41-7 0.28579 .5137 —44.366364%
(Component of BEC
Pollutant Grou :Cadmium compounds total mass inc elemental metal GroupSum:.28579
Cadmium Metal(elemental 7440-43-9 0.28579 1.2237 —76,645424%
unreacted Component of,CrC
Pollutant Grou :Chromium VI Soluble Chromate Com ounds(Component of CRC Group Sum:.28259
Chromic acid(VI)(Component o 7738-94-5 0.28259 1.0842 —73.935616%
SolCR6 CRC
58

Pollutant Grou :Chromium-All/Total Inc Chromium VI categories,metal and Others Group Sum:.28259
Chromic acid(VI)(Component o 7738-94-5 0.28259 1.0842 -73.935616%
So1CR6 CRC
Pollutant Grou :Lead and Lead compounds Group Sum:.84778
Lead Unlisted Compounds PBC-Other 0.84778 12.1106 -92.99968% I
(Specify and Com onent of PBC
Pollutant Grou :Man anese compounds Group Sum:.56519
Manganese Unlisted Compounds MNC-Other 0.56519 379.0104 -99.85088%
(Specify Component of MNC
Pollutant Group:Mercury Compounds-all total mass inc H&Vapor Group Sum:.34059
Mercury,vapor(Component of 7439-97-6 0.34059 .3188 6.8350058%
HGC
Pollutant Grou :Nickel Compounds, sum total mass inc elemental Group Sum:.28259
Nickel metal(Component of NIC 7440-02-0 1 0.28259 1 8.0602 -96.49401%
Pollutant Grou :Pol c clic Organic Matter 7 PAH Compounds for NIF Group Sum:.5243
Benzo(a)pyrene(Component of 50-32-8 0.5243 .6153 -14.789537%
POMTV POM7
Pollutant Grou :Pol c clic Or anic Matter(Specific Co m ounds from OA PS for TV Group Sum:20.44226
Benzo(a)pyrene(Component of 50-32-8 0.5243 .6153 -14.7895370/0
POMTV POM7
Naphthalene(Component of 91-20-3 19.91796 23.29457 -14.495273%
POMTV
Acetaldehyde 75-07-0 167.4272 196.4354 -14.767295%
Acrolein 107-02-8 806.7657 946.2847 -14.7438755%
Benzene 71-43-2 849.7197 996.14801 -14.6994505%
Carbon tetrachloride 56-23-5 9.076 10.646 -14.74732%
Chlorine 7782-50-5 159.335 186.888 -14.743051%
Chlorobenzene 108-90-7 6.656 7.807 -14.743179%
Chloroform 67-66-3 30681.646 16948.624 81.027374%
Ethyl acetate 141-78-6 31432.76 21102.09 48.955673%
Ethyl benzene 100-41-4 6.80171 7.8207 -13.029396%
Fluorides(sum of all fluoride 16984-48-8 25.09694 22.22003 12.947369%
compounds)
Formaldehyde 50-00-0 919.8093 1069.66504 -14.009592%
Hexane(isomers,except HEXANEISO 1483627.8 1136915.82 30.495825%
n-hexane
Hexane n- 110-54-3 103238.26 89975.18 14.740818%
Hydrogen chloride(hydrochloric 7647-01-0 18.152 21.29 -14.739316%
acid
Methanol 67-56-1 539989.2 414346.26 30.323175%
Phenol 108-95-2 10.286 12.065 -14.745126%
Polycyclic Organic Matter(Inc
PAH,dioxins,etc.NC AP 42 POM 2.22037 31.53585 -92.95922%
historic amorphous lob
Pro ionaldeh de 123-38-6 12.303 14.431 -14.746028%
Styrene 100-42-5 383.21 449.478 -14.743326%
Toluene 108-88-3 239,45927 265.46038 -9.794724%
X lene 1330-20-7 5.2344 6.1476 -14.854583%
X lene o- 95-47-6 1 0.94198 .834 12.947244%
59

f
COPY of RECORD Date Submitted: 3/28/2017 13:53:18
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Comments From Facility:
i
60

NNW
Annual Air Emissions Inventory Summary
2016 Totals Facility ID#:0800044
pokdav 1e W a99erR e W Oee01 Gang a 03 OenW Pk4 Fire Pump Ba9aMlf RPEorJ aem'ury COnOrte FMvysie tWl Sklefetlge Blontess BohNul NutrbM EVO VYWTP , Tobb II,9b
(9F0) (80E) E80ao000 Extractlon FJNa00011 P essss
C 2W9.33330 1318A1761 1210.90030 1.]9558 110 1A5761 1AM6O 15.8W83 IWOM lW5411 TwNYr
kleNne O.MW2 001149 0.M326 OOOOM 003.M6 OW COO OMOM 0=25 0.=24 2 2T329.3]].12 2.143 7m
Nb O Oa1W3 0R2W 0.00858 O.00W3 00004 0WW3 0W003 000253 aDW05 1.31 1351 TN r
TSP 0.10056 om8 aimm 0.M317 0.00M7 0.W331 aW324 0.03611 0.01139 0.141 0875 Tp
PM-10 O09R6 019147 0.0516) 0.003%7 0.M39] 0.00331 000326 003611 001139 0141 0.539 TOM}
PM-2.5 0=57 0N787 0.01367 O,W317 0.=97 0.W331 0.M324 0.0361, 001139 0141 0.288 Ta ,
Sw 3W569 0.15671 2.32M 0.00M7 0.00559 0.W487 OM457 005092 000550 2.52112 16.928 Ta r
Nm 2.1M70 A59533 131M 001015 001M 0.01W0 0610M 115552 0161W 22.1859 34621 Tatar
VOc 001806 003829 001M3 001142 0.01428 001,93 001167 013M 0013M 17144 8W.S86 2W.R8 68.939 108.W5 0.178 2A99 0M4 176222 3.23 1221 W1 T~ft
c0 045140 095736 0.27335 0.02697 0.03)1 0.02818 0W57 03WW 003ae9 193622 21 W3 Ta l
&.LWd,hyd, 0.M1M 0M2M 1 OW167 060163 0.018M OOSBW 167 402 167 4M IOWYr
8udek� 0MWO 0WW2 a ON051 060568 O.Mac 806.758 BOB.773 UWYr
Nxnc 010111 031M5 O.W123 000025 060032 OOW27 0.M038 0.M269 O.OMM 0.381 LtreM
Beraene 0.49653 1M310 030W8 001921 O.W155 0,0143 005033 aNC43 aM851 W7.096 I W9.7M uWY,
Bxu a O600R 0MM2 000002 0.00002 OOW19 000001 0,524 0.52180 LWYr
Be 0.07583 OAM414 0.01592 00M19 00M21 0W(M 0M019 0.M217 O.W022 0395 LOW,
Bu aw
0.00 LWWr
C d..M OWM DAWt1 0904502 0.00019 OM024 OM020 0.OMt9 0=17 000022
CaIrJ1mO ai6e 0
2M LWYr
cwm 9.aM LOW'r
rekxNa;ae 00]6 9.0)6 LWYr
c51f.(kM 159.335 159.335 llulYr
CMMObe,¢aM all% 66% IWY,
CIVorOlorm SWT MIS M881,W LOWr
c1,.. O.O7583 0.1BOW O.WSM 0.283 UWY,
CtYo.W 0W524 0.01111 0.W317 am LWY,
O1e 0 0.W0 lOeffr
Effy 100% 7t W DOO 342 053 IWYr
EB�d-6DA e78115 0.M 4761M6 LOW,
E ece,We 31M2.00 13M 217.W OM 31432.760 l r
EOMWereN1e 011752 0.3128) O.W933 6.252 6002 LOWr
E ON O.OM LEWYr
FbuiOe 6.23181 14.28382 4.07B:3t 25.W7 LbWr
F 8.BB6)8 1OU133 52M22 000501 0W&M 0.M523 0.0012 0OSBW OO ffia 687.43e 919M LEWY,
MCI 18.152 18.152 UWft
Heine Isomers 0.0M 1]16T15.13 O.M 131712.12 OW 0.00 a00 118415).250 LOWYr
N-H.. O6M 2W30.R OM BMTT.88 0.M a 0.M 103108.]92 lOelYr
M 108875W 0.00 11W5067 1 21T333,305 LYWYr
Ise xebM I I I 2]51.95 OM M51617 LbslYr
Iso acebb a I 0.M 0W LWY,
Leaf Ca O.WW OM251 0.13M am LOWY,
M w O.I516T (IM167 O.M1W 0.M 0MS LOWr
Me OeM3 0.16081 OWSR O.WB out LOW,
MaMawl 529856.M 0.M 36611.M BIW.M 539989.M1 LOWr
N 0.05958 0.12631 DCe6M 0.00825 00101 OWBR OAOW3 O.W146, 09OOR3 19.SW 19.M LOW,
Nrkel 007SB3 OMM80 OWSR 0,20 1W)Yr
PMmI 10.= 102W LDWr
R M e 12M3
12.133 LWY,
Star POnh OM 0.0M lMl3Y
383.210 389.210 LOWr
Tduae 14.39W7 M.52006 571124 001763 0.02229 0.01862 001823 O.M2W &MCOM 1BS.SW 0.M OM MAN LWY,
xvW, 001M5 taint 001 79 001252 0.139W O.OMW 5.W2 5.253 1 IWY,
o-% 0.M278 0.53612 i al3suT iOW2 LOWr

r
Monthly VOC's
YEAR: 2016
Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
No.2 Fuel Oil #2 Fuel Oil 11.276 8.692 5.277 6.124 6.436 1.128 9.251 14.437 29.039 21.550 5.600 15.758 134.57 0.067
BOILERS
GENERATORS #2 Fuel Oil 7.942 8.333 8.333 16.275 4.687 8.333 7.682 8.333 6.250 8.333 8.333 8.333 101.17 0.051
FIRE PUMP #2 Fuel Oil 4.166 5.208 2.083 2.604 1.562 1.562 2.083 1.614 1.562 1.562 1.562 1.562 27.13 0.014
Hexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
Biomass Boilers n-Hexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
Isohexane 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.000
EVG Chloroform 0.00 6343.00 4059.00 7203.00 12330.00 -19444.00 13317.00 4527.D0 -10118.00 5272.00 7187.00 0.D0 30676.00 15.338
Methanol 0.00 393.23 277.93 376.70 621.55 114.09 725.56 747.13 0.00 294.81 317.31 0.00 3868.30 1.934
Ethyl acetate(from 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
SDA-35A
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
from SDA-3A
Ethylacetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Eth famine 0.00 0.000
Ethanol-SDA 3A 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.D0 0.00 0.00 0.00 0.00 0.000
PNE Ethanol-SDA 35A 0.00 0.D0 0.00 0.D0 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 O.DO 0.00 0.00 0.00 0.00 0.00 0.000
He tane 13191.85 16029.54 22.80 13602.48 14124.60 21640.62 1042.47 217.17 15041.73 0.00 11622.30 4121.10 110656.67 55.328
Isobutyl acetate 0.00 0.00 10712.75 0.00 0.00 0.00 0.00 0.00 11604.991 5434.21 0.00 0.00 27751.95 13.876
Toluene 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 - 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Biomass Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Extraction Ethanol-200P 0.00 0.00 0.00 0.00 0.D0 0.00 0.00 0.00 0.00 0.00 0.00 342.06 342.05 0.171
Ethyl acetate from Ethano1200 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 13.68 13.68 0.007
Diethylamine 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Ethyl Acetate 0.00 92.82 56.39 0.00 0.00 0.00 0.00 0.00 0.00 52.81 0.00 15.05 217.08 0.109
Ethanol-SDA 35A 0.00 2044.51 1242.16 0.00 0.00 0.00 0.00 0.00 0.00 1163.30 0.00 331.48 4781.45 2.391
Botanical Ethanol-200 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Extraction Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 O.DD 0.00 0.00 0.000
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Toluene 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.D0 0.000
He tane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 123601.50 109469.25 165192.50 85520.05 145211.00 193283.75 16808.00 109246.50 128188.50 128238.00 127770.50 36888.50 1369176.05 684.588
Rotocel& n-Hexane 849.t4 667.76 818.05 945.85 2889.70 4832.09 354.65 2250.48 2435.16 2013.34 1929.33 447.38 20430.92 10.215
Recovery Isohexane 122752.36 108801.49 164376.45 84574.20 142321.30 188451.66 16453.35 106996.02 125731.34 126224.66 125841.17 36221.14 1348745.13 674.373
Methanol 55098.08 35714.38 36964.12 24960.34 48154.80 46197.94 2925720 55697.12 58096.98 54934.66 41280.62 43320.08 529656.30 284.828
Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 I 0.00 0.00 0.00 0.00 0.00 0.00 0.000

Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
Concrete n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Methanol 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Hexane 17627.50 19855.00 23072.50 16093,00 18650.50 18656.00 18282.00 21824.00 23617,00 11814.00 12952.50 15246.00 217690.00 108.845
Sclareolide n-Hexane 6839A7 7683.89 8905.99 6227.99 7217.74 7219.87 7086.10 8227.65 8820.95 4371A8 4766.52 5610.53 82977.88 41.489
Isohexane 10788.03 12171.12 14166.52 9865.01 11432.76 11436.13 11195.90 13596.35 14796.05 7442.82 8185.98 9635.47 134712.12 67.356
-Ethyl acetate 1909.00 2275.00 1936.00 3202.00 1751.00 2555.00 3796.00 2444.00 1682.00 2761.00 2512.00 4379.00 31202.00 15.601
Recrystallization Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
(SFG) n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000
He tane 12215.10 12625.50 9137.10 13782.60 3402.90 3283.20 -560.31 9678.60 -26579.10 10941.15 24823.50 33926.40 1 106676.64 53.338
Methanol(EVG) 0.00 385.36 272.38 369.17 609.12 111.81 711.04 732.19 0.00 288.91 310.96 0.00 3790.94 1.895
Methanol 437.03 226.26 302.27 18.69 15.90 13.75 44.31 111.71 77.19 389.23 704.59 332.74 2673.66 1.337
WVVTP Recove
Methanol(Concrete) 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Methanol PNE 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
MonthlyTotal Lbs.VOC 224103.45 206476.09 253263.59 165153.04 244884.06 266423.18 83442.28 205249.81 201626.13 221615.51 229476.78 136721.73 2439435.63 1219.72
MonthlyTotal Tons VOC 112.05 102.74 126.63 82.58 122.44 133.21 41.72 102.62 100.81 110.81 114.74 69.36 1219.72

I
Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : Or-11 05-t/6
Year: 2016 41
Od 60 `n n
Total Run Time: 11953.1 Hr% '/A 9� /�� CY?.o1-�
Efficiency: 85 ! Y
Sulfur Content: 0.0014 % (r 4 ZU/
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 17921.5 25374.0 13086.0 56381.5 501.3 468.0 290.8 1260.1 0.032 11.276
February: 15802.0 20924.5 6732.0 43458.5 457.8 409.6 149.6 1017.0 0.024 1 8.692
March: 15122.2 9519.3 1741.5 26383.0 423.0 250.2 38.7 711.9 0.015 1 5.277
April: 12673.4 13211A 4736.3 30621.1 354.5 273.6 126.3 754.4 0.017 6.124
May: 95.1 13456.0 18627.8 32178.9 27.5 57.8 442.5 527.8 0.018 6.436
June: 4035.0 459.6 1147.4 5642.0 169.3 13.3 30.5 213.1 0.003 1A28
July: 19955.4 23368.1 2933.1 46256.6 539.4 438.5 118.8 1096.7 0.026 9.251
August: 21432.1 45190.1 5561.0 72183.2 599.5 487.6 132.1 1219.2 0.040 14.437
September: 24013.3 94103.2 27076.5 145193.0 671.7 664.8 601.7 1938.2 0.081 29.039
October: 21997.0 73276.9 12476.1 107750.0 615.3 596.3 319.9 1531.5 0.060 21.550
November: 12104.9 12382.6 3514.5 28002.0 338.6 177.7 78A 594.4 0.016 5.600
December: 15406.1 51678.6 11705.8 78790.5 445.8 374.2 268.8 1088.8 0.044 15.758
Total: 180558.0 382944.3 109338.0 672840.3 5143.7 4211.6 2597.8 11953.1 0.377 134.568
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 35.1 5143.7 180558.0
2 H-102 143 90.9 4211.6 382944.3
3 H-103 180 42.1 2597.8 109338.0
Total 466 168.11752 11953.1 672840.3
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. TonsNr TonsNr TonsNr TonsNr
TSP 2.00 0.181 0.383 0.109 0.673
PM-10 1.00 0.090 0.191 0.055 0.336
PsoxS z60 3.846 e157 z.329 14,32 a,067 f-hp- �i^ EDD
Nox 24.00 ) 2.167 4.595 1.312 8,0 (,.')3 Cha a"
VOC 0.20 0.018 0.038 0.011 0.067 1 7/4
CO 5.00 0.451 0.957 0.273 1.682 A 1°,y
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.101 0.214 0.061 0.377 C
Benzene 2.75E-03 0.497 1.053 0.301 1.850 L fa�1 r(A(i3O✓
Be I Ilium 420E-04 0.076 0.161 0.046 0.283 'lT Nr,4 b �a
CV�'O(f ` cadmium 0.076 0.161 0.046 o.za3 3,3/b (000 9
Chr07171M C9 2 0.076 0.161 0.046 0.283 �-�15 /
cs�' Ghromiuni 2-99&4* -"1-1 4ee3 1 O.oaa // �o,r TS!'
Eth I benzene 8.17E-04 0.148 0.313 0.089 0.550
Flounce 3.73E-02 6.735 14.284 4.078 25.097
Formaldehyde 4.80E-02 8.667 18.381 5.248 32.296
Lead 1.26E-03 0.228 0.483 0.138 0.848 �(
Manganese 8.40E-04 0.152 0.322 0.092 0.565
Mercu 4.20E-04 0.076 0.161 0.046 0.283
Na thalene 3.30E-04 0.060 0.126 0.036 0.222
H:\EnvironmentalV\ir Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : O$-1
Nickel 4.20E-04 10.076 0.161 0.046 1
- 0.283
Toluene 7.97E-02 14.390 30.521 8.714 53.625
o-X lene 1.40E-03 1 0.253 0.536 0.153 10.942
Green House Gas Pulutants
s®re�tclsh�f
Emission goiter#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total p&j
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)COz 22700.00 796.83 2064.02 955 yy.41 2049.33 4346.42 1240.99 7636.74 !I :5 -3
Methane(CHe) 0.06 0.0021 0.0055 0.0025 0.0054 0.0115 0.0033 0.0202 0. 31
Nitrous Oxide 0.12 0.0042(NzO) 0.0109 0.0051 0.0108 0.0230 0.0066 0.0404 0 ,06
hl/ fh / c��loru�6rm p.
�/ b
10M ollbs
G-7(,
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044 1 , 7
Biomass Boilers : ES-BB1 & ES-BB2: OS-33 7 / �yZO/G
Fuel Source : Wood Chips 'Ju rr d1n
Year: 2016 � C yZols
Total Run Time: 7138.0 Hrs/Yr
Wood Chips 8000000 BTU/ton 50%/z"/ n
' Emission Factors determined by Emissions test conducted on 12/19/2013
Boiler Operation (Hours) Wood Chips Burned (Tons) CO PM HCL Hoc Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Hours Chips
January: 744.0 456.0 744.0 1826.6 999.0 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
February: 696.0 432.0 696.0 1505.0 736.0 2241.0 3442.2 25.0992 1.61352 0.00520 17928
March: 744.0 744.0 744.0 1510.5 1510.0 3020.5 4639.5 33.8296 2.17476 0.00701 24164
April: 720.0 720.0 720.0 950.0 950.0 1900.0 2918.4 21.28 1.368 0.00441 15200
May: 744.0 672.0 744.0 1570.7 1328.0 2898.7 4452.4 32.46544 2.087064 0.00672 23189.6
June: 696.0 720.0 720.0 1412.8 1412.8 2825.6 4340.1 31.64672 2.034432 0.00656 22604.8
July: 300.0 300.0 300.0 560.0 560.5 1120.5 1721.1 12.5496 1 0.80676 0.00260 8964
August: 240.0 659.0 659.0 472.3 1281.5 1753.8 2693.8 19.64256 1.262736 0.00407 14030.4
September: 65.0 65.0 65.0 146.0 146.3 292.3 449.0 3.27376 0.210456 0.00068 2338.4
October: 432.0 432.0 432.0 669.0 670.7 1339.7 2057.8 15.00464 0.964584 0.00311 10717.6
November: 720.0 720.0 720.0 1400.6 1400.6 2801.2 4302.6 31.37344 2.016864 0.00650 22409.6
December: 594.0 594.0 594.0 1096.0 1096.3 2192.3 3367.4 24.55376 1.578456 0.00509 17538.4
Total: 6695.0 6514.0 7138.0 13119.5 12091.7 25211.2 38724.4 282.365 18.152 0.05849 201689.6
Average 557.9 542.8 594.8 1093.3 1007.6 2100.9 3227.0 23.530 1 1.513 0.00487 16807.5
S-fP- (,wJd Ce7-n4w2-1)oyi /Vcv&� s�o���t�she�„�' ,a,�,�� >/ G .�,�, ���� /✓,o p�Ta�
5-cc fps [,moo /bra

Criteria Pollutants Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler
Pollutants (Lb/MM BTU) (TonsNr) Pollutants (Lb/MM BTU) (LbsNr)
TSP 0.0014 0.141 Acetaldehyde 8.30E-04 167.402
PM-10 0.0014 0.141 Acrolein 4.00E-03 806.758 AP 9 Z
PM-2.5 0.0014 V 0.141 Benzene 4.20E-03 847.096 e,JayS
Sox 0.03 2.521 Benzo a rene 2.60E-06 0.524 7
Nox 0.22 22.186 Carbon 4.50E-05 9.076
tetrachloride
VOC 0.02 1.714 Chlorine 7.90E-04 159.335
CO 0.19 19.362 Chlorobenzene 3.30E-05 6.656
Chloroform 2.80E-05 5.647
Ethyl benzene 3.10E-05 6.252
Green House Gas Pulutants Formaldehyde 4.40E-03 887.434
GHG Pollutant Emisson Factor E101 Napthalene 9.70E-05 19.564
Lb/MM BTU tons/ r
CO2 195.000 19664.7 Phenol 5.10E-05 10.286
Methane 0.021 2.1 Propionaldehyde 6.10E-05 12.303
(CH4)
Nitrous Oxide 0.013 1.3 Styrene 1.90E-03 383.210
(N2O)
Toluene 9.20E-04 185.554
X lene 2.50E-05 5.042
[VW gful�r
`�/';W-4 �e 5-&'—% pi►>7�SS16�^U do PS )'70�
set a So 0,d4I l JJ,�,�� l✓AP�?Q f� `
Fa'4�PSSCfj ° f. c Q J��u dc— 7-e S
/,id Z, 97 E- 7 /6110n �u
NCI 9E-S 1611vnm&tit , /�. z Ib g
/es�i„� 1,2„ Gandr afcd �� scrra �Ja//1 �un�s on /2/y/?,) resVAS

Page 1 of 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year: 2016
Total Run Time: 99.0 Hrs/Yr
Efficiency: 75 00 �2
Sulfur Content: 0. 14 /, (p
Number Fuel: 141000 Btu1Gal /� -6 Ll/
���� cv,7 is /`
Fuel Usane(oallonsl VOC U/✓ ! 1..•�'
Month E101 E102 E103 E104 Total (Lbs.) n
January: 22.5 50.0 40.0 40.0 152.5 7.9 77
February: 30.0 50.0 40.0 40.0 160.0 8.3 lll��7 I
March: 30.0 50.0 40.0 40.0 160.0 8.3 7 OS.
April: 150.0 62.5 50.0 50.0 312.5 16.3 7
May: 15.0 25.0 30.0 20.0 90.0 4.7
June: 30.0 50.0 40.0 40.0 160.0 8.3
July; 30.0 37.5 40.0 40.0 147.5 7.7
amb
30.0 50.0 40.0 40.0 180.0 8.3
S 22.5 37.5 30.0 30.0 120.0 6.2
30.0 50.0 40.0 40.0 160.0 8.3
N 30.0 50.0 40.0 40.0 160.0 8.3 ��ID
D 30.0 50.0 40.0 40.0 160.0 6.3 C
450.0 562.5 470.0 460.0 1942.5 101.2 /l Yl//rt
Heat Rate
Generator No. I10 Bh h H0l O G15.0 G 50.0 MM Bt2 MM BtulYr ,rf
1 E101 567 440 30.0 15.0 450.0 2.12 63.45
2 E102 760 570 22.5 25.0 562.5 3.53 79.31
3 E103 603 452 23.5 20.0 470.0 2.82 66.27
4 E104 534 401 23.0 20.0 460.0 2.82 64.86
Total 2484 1863 99 80 1942.5 11 274
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Pollutants (LbIMM BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (TonsNr)
AP-srz
TSP 0.100 0.003 0.004 0.003 0.003 0.014
PM-10 0.100 0.003 0.004 0.003 0.003 0.014
PM-2.5 0.100 0.003 0.004 0.003 0.003 0.014
Sox 0.141 0.004 0.006 0.005 0.005 0.019 _
Ncx .320 0.010 0.013 0.011 0.010 0.044 O yy
vOC o 36 0.011 1 0.014 1 0.012 1 0.012 0.049 p.0//
CO 0. 0 0.027 1 0.034 1 0.028 1 0.028 1 0.116
HazardouslToxlc Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total ijY0711/G QU t/�
Air Pollutants (LbIMM BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 2.52E-05 0,001599 0,001999 0.001670 0.001634 0.007 /too f( 2.-5
Acrolein 7.88E-06 0.000500 0.000625 0.000522 0.000511 0.002
0 Benzene 7.76E-04 0.049237 0,0611547 0.051426 0.0503311 0.213
Benzoa rene 2.57E-07 0.000016 0,000020 0.000017 0.000017 0.0001
Beryllium 3.00E-06 0.000190 0.000238 0.000199 0.000195 0.001 '••' _ fo
Cadmium 3.00E-06 0.000190 0.000238 0.000199 0.000195 0.001 h1 L�ttQ RE-y
Formaldeh de 7.89E-05 0.005006 0.006258 0.005229 0.005117 0.022
Na thalene 1.30E.04 0.008249 0.010311 0.008615 0.008432 0.036 / `1
Toluene 2.81E-04 0.017829 0.022287 0.018622 0.018226 0.077
X lene 1.93E-04 0.012246 0.015307 0.012790 0.012518 0.053 D E
C��f tyI)urY1 se SY17n/Il """'
Green House Gas Pulutants .fj� � I
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total 5���nl v rr' �,yy1le r)
LbIMM BTU tons r tonsl r tons/ r tons/ r tonsl r E- 3
CO2 43.990 1.3956 1.7445 1.4576 1.4266 6.02
Methane 0.009 0.0003 0.0004 0.0003 0.0003 0.00123
(CH4)
Nitrous Oxide 0.001 0.0000 0.0000 0.0000 0.0000 0,000137
(N20) See tdlaciuc�S1ytiaJl-
u tCAk CP
H:\EnvironmentaKAir PermMAir Repons\Annual Air Emissions Inventory\2016 Repon\2016 AAE Calc Page 1

Annual Air Emissions Inventory
Facility ID#: 0800044 0
PK- Generator : OS-12 rW adt dtWaS,qd l�
Year: 2016 I, � >,,,tOyy) C�;wm,
Total Run Time: 71.1 Hrs/Yr N � rr'��p� 1�,f/ '
Efficiency: 75 % o , Z L
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Emisson Emisson
Hazardous/
Fuel Usag a Hours VOC Criteria Factor Pk-Gen Toxic Air Factor Pk-Gen
Month Pollutants (Lb/MM (Tons/Yr) (Lb/MM (Lbs/Yr)
(gallons) Operated (Lbs.) BTU Pollutants BTU
TSP 0.1 0.0361 Acetaldehyde 2.52E-05 0.0182
Janua : 144 2 7.50 PM-10 0.1 0.0361 Acrolein 7.88E-06 0.0057
-February: 396.0 5.5 20.62 PM-2.5 0.1 0.0361 Arsenic 4.00E-06 0.0029
March: 144.0 2.0 7.50 Sox 0.141 0.0509 Benzene 7.76E-04 0.5604
April: 396.0 5.5 20.62 Nox 3.2 1.1555 Benzo a rene 2.57E-07 0.0002
May: 108.0 1.5 5.62 VOC .090126 I ojao0 , Beryllium 3.00E-06 0.0022
June: 1188.0 16.5 61.87 CO 0.85 0.3069 Cadmium 3.00E-06 0.0022
July: 540.0 7.5 28.12 Formaldehyde 7.89E-05 0.0570
August: 1018.0 14.2 53.02 Na thalene 1.30E-04 0.6939
September: 792.0 11.0 41.25 Toluene 2.81 E-04 0.2029
October: 108.0 1.5 5.62 X lene I 1.93E-04 1 0.1394
November: 144.0 2.0 7.50
December: 144.0 2.0 7.50
Total: 1 5122.0 71.2 11266.8
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr I Gals/Yr I MM Btu/Hr MM Btu/Yr
Pk-Gen Pk-Gen 1 2670 2003 71.1 72.0 1 5122.0 1 10.15 722.20
Green House Gas Pulutants for Peak Generator C�?wrn16 6tvcy 2.17
GHG Pollutant Emisson Factor Ibs/yr tons/y
(Lb/MM BTU) r J PU d (D S E"3
CO2 43.990 31769.67 15.88
Methane
(
0.009 6.50 0.0032
Nitrousus Oxide 0.007 5.06 0.00253
(N20)
a

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only! l�
Year: 206
Total Run Time: 26.1 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 400
Number 2 Fuel: 141000 Btu/Gal d a�
F,� S3� >�
Month Gallons Hours Gallons/ VOC � �,y���,,, �
Used Operated hour (lbs.) Z 'b -O4, - "
January: 80.0 4.0 20.0 4.166 ou
February: 100.0 5.0 20.0 5.208
March: 40.0 2.0 20.0 2.083
April: 50.0 2.5 20.0 2.604
May: 30.0 1.5 20.0 1.562
June: 30.0 1.5 20.0 1.562
July: 40.0 2.0 20.0 2.083
August: 31.0 1.6 20.0 1.614
September: 30.0 1.5 20.0 1.562
October: 30.0 1.5 20.0 1.562
November: 30.0 1.5 20.0 1.562
December: 30.0 1.5 20.0 1.562
Total: 521. 1 26.1 1 20.0 27.1
Heat Rate
FP ID# Bhp hp HrlYr Gals/Hr Gals/Yr mm mm
Btu/Hr BtulYr
FP 1 285 214 26.1 20.0 521.0 2.82 1 73.46
Criteria Emisson Factor (Lb1MM FP
Pollutants BTU) (Tons/Yr
TSP 0.31 0.011
PM-10 0.31 0.011 N
PM-2.5 0.31 0.011
Sox 0.152 0.006
Nox 4.41 0.162
VOC 1 0.36 0.013
CO 0.95 0.035 Green House Gases
Hazardous/Toxi Emisson Factor (Lb/MM FP GHG Emisson Factor E101
tons/ r
c Air Pollutants BTU) (Lbs/Yr) Pollutant K /MM BTUCO2 73.960 5.990
Acetaldehyde 7.67E-04 0.056 Methane 0.003 0.000243
Nitrous
Acrolein 9.25E-05 0.007 Oxide 0.0006 0.000049
(N2O)
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.069
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002 � �
Formaldehyde 1.18E-03 0.087
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.030
X lene 2.85E-04 0.021
C/uLT�„e 6-6t Q
h7ci-gP zZE- y

Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4,OS-5, OS-6 OS-10 OS-28 OS-29
OS-13.OS-14 OS-15 OS-16 OS-20 05-21 OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18.OS-19 INCLUDED WITH OS-10•OS-30 INCLUDED WITH 91S-28
Year: 2016
Info: Lbs/Gal= 5.60
Monthly Inventory of LP Hexane-</=40%n-Hexane loallonsl,
Month I n
Beginning
ventory Received Max Used Ending Inventory
Januss : 9979 3571 74525 3365 10185
Februa 10185 3489 75207 3900 9774
March: 9774 3496 72985 4470 8800
April: 8800 4043 7 6637 3 886 9657
May: 9657 53114 3636 6021
June: 6021 3556 52674 3702 5875
July: 5875 10551 90343 36D4 12822
Au oust: 12822 70521 4259 8563
Se [ember. 8563 7154 86444 4414 11303
October: 11_3 82167 2308 8995
November. 8995 7101 88528 2355 11741
December: 1 3741 1 f 75576 1 2892 10849
Monthly Inventory of HP Hexane-<I-95%n-Hexane Wallonsl•
Month Beginning Received Max
Invento Lbs Used Ending Inventory
January: 5886 32263 5866
February: 5866 32263 5866
March: 5866 32263 5866
April: 5866 32263 5866
May: 5866 32263 5866
June: 5866 32263 5g6g
July: 5866 32263 5866
Au ust: 5866 32263 5866
September: 5866 32263 5866
October: 5866 32263 5866
November: 5866 32263 5866
December. 5866 32263 5866
Monthly Inventory of IsoHexane-</-5%n-Hexane laallonsl�
Monts 1nvgentorV - Received Lbs Used Ending Inventory
Janus 48405 18723 369204 22473 44655
Februa : 44655 14760 326783 19918 39497
March: 39497 26162 361125 30035 35624
April: 35624 13826 271975 15M 33850
May: 33850 20488 298859 26402 27936
June: 27936 33741 339224 35693 25984
July: 25984 12852 213598 3056 35780
August: 35780 20605 310118 19883 36522
Se tember: 36522 32166 377784 23303 45385
October: 45385 21085 385585 23316 43154
November: 43154 1 20855 I350950 1 23231 40578
December. 1 40578 1 10775 1 282442 6687 44686

Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers iLbs 1: /
Percent n-Hexane: 1.480 JJJ
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted lbs. Emitted Lbs.
Janus 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
July: 0.00 0.00
Au oust: 0.00 0.00
September. 0.00 0.00
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Average SDIV101 1DIV/01 0.00 0.00
Total 0 0.00 0.00 0.00
Total Hexane Values
Gallons of LP Hexane Used: 1 42091.00 1 Gallons of N-Haxa-n7U-%-ad--.- -F 43294.71
Gallons of HP Hexane Used: 0.00 Lbs.of N-Hexane Used; 238120.92
Gallons of IsoHexane Used: 249557.00 Gallons of Hexane Isomers Used: 260313.27
Total Gallons of Hexanes Used: 291648.00 1 Lbs.of Hexane Isomers Used: 1431723.01
Total Lbs.of Hexanes Used: 1604064
Sclareolide iSDEI Operation:OS-5
Gallons Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Hexane Hexane
Montle y Lbs.SDE Product Lbs.Hexane Used %n-Hexane Sent as Hexane Emitted
Isomers
Operated Infeed Used Hazardous Emitted Emitted Emitted
(Lbs.) (Lbs.)
January: 31 86402.9 60282.2 3365 18507.5 38.8 160.00 17627.5 6839.47 10788.0
February: 29 82590.2 60293.2 3900 21450.0 38.7 290.00 19855.0 7683.89 12171.1
March: 31 82210.8 60064.4 4470 24585.0 38.6 275.00 23072.5 6905.99 14168.5
April: 30 79832.3 82493.2 3188 17523.0 38.7 260.00 16093.0 6227.99 9665.0
May: 31 91316.9 68776.4 3636 19998.0 38.7 245.00 18650.5 7217.74 11432.8
June: 30 86314.4 66055.0 3702 20361.0 38.7 310.00 18656.0 7219.87 11436.1
July: 29 69913.9 52614.5 3604 19822.0 38.76 280.00 18282.0 7086.10 11195.9
Au ust: 31 89105.0 69202.3 4259 23424.5 37.7 291.00 21824.0 8227.65 13596.4
September: 30 80587.9 60786.0 4414 24277.0 37.35 120.00 23617.0 8820.95 14796.1
October: 20 43818.1 33134.2 2308 12694.0 37 160.00 11814.0 4371.18 7442.8
November: 20 43998.2 32430.2 2355 12952.5 36.8 0.00 12952.5 4766.52 8186.0
December: 23 46258.3 34293.6 2892 15906.0 120.00 15246.0 5610.53 9635.5
Averse 28 5 55035.4 3507.6 19291.7 38.051 209.250 18140.833 6914.823 11226.01
Total 336 882348.9 D 660425.3 42091 231500.6 2511.000 217690.000 82977.875 134712.12
I WILY
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Page 3 of 5
Sclareol Recrvstallization ISFGf Operation:OS-6
Gallons Monthly Monthly Monthly
#Days Lbs.SFG Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Inroad Lbs.SFG Product Used Lbs.Hexane Used %n-Hexane Sent as Emitted Emitted
W Isomers
Hazardous (Lbs) (Lbs) Emitted
January: 0.0 0.0 0.00 0.0
February: 0.0 0.0 0.00 0.0
March: 0.0 0.0 0.00 0.0
April: 0.0 0.0 0.00 0.0
Ma : 0.0 0.0 0.00 0.0
June: 0.0 0.0 0.00 0.0
July: 0.0 0.0 0.00 0.0
Atioust. 0.0 0.0 0.00 0.0
September: 0.0 0.0 0.00 0.0
October. 0.0 0.0 0.00 0.0
November: 0.0 0.0 0.00 0.0
December: 0.0 0.0 0.00 0.0
Averse #DIVI01 #DIVI01 #DIVl01 #DWI01 0.0 #DIVl01 #DIVIOf 0.00 0.00 0.00
Total 0 0 0.0 0 0 0.00 0.00 0.00 0.00
Rotocel&Recovery Operations:OS-4 1Sq S IP
Gallons Monthly
i Monthly Monthly
#Days Lbs.Sage Lbs.Saga Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Operated Processed Product Used Lbs.Hexane Used %n-H some Sentas Emitted Emitted Isomers
(INFEED) Hazardous Waste (Lbs) (Lbs) Emitted
January: 31 12769900.0 114902.0 22473 123601.5 0.487 123601.5 849.1 122752.4
February: 22 8393630.0 74636.0 19918 109549.0 0 1 14.50 109469.3 667.8 108801.5
March: 29 9897403.0 91509.0 30035 165192.5 0. 94 165192.6 816.1 164376.4
April: 18 6711014.0 49773.0 15600 85800.0 1.106 50.90 86520.1 945.9 84574.2
May: 31 13018810.0 1 89394.0 26402 145211.0 1 9 145211.0 2889.7 142321.3
June: 30 17604170.0 85149.0 35693 196311.5 .5 550.50 193283.8 4832.1 188451.7
July: 16 4350000.0 42770.0 3056 16808.0 211 16808.0 354.6 16453.4
August: 31 13485000.0 97866.0 19863 109246.5 06 109246.5 2250.5 106996.0
September. 30 13050000.0 100345.0 23303 128166.5 .9 128166.5 2435.2 125731.3
October: 29 12615000.0 116184.0 23316 128238.0 157 128238.0 2013.3 126224.7
November: 30 13050000.0 105139.0 23231 127770.5 151 10770.5 1929.3 125841.2
December: 27 11745000.0 69535.0 6667 36668.6 122 36668.5 447.4 36221.1
Averse 27 1139 88105.2 20796 11 1.,0 20 114098.0 1702.6 112395.4
Total 324 49927 1057262.0 249557 1615.90 136.9176.1 20430.9 1348745.1
Lbs.Hex per day exiting Mineral Accounts of Hexane S,b S/6/y�
Oil Scrubber 158.76 fv. Emitted 190402 41 " 3y 79, 8 ih S
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 51439.536 Accountable Lbs.of N-Hex Emitted:
Lbs.of N-Hex exiting MO Unit: 761.18 Accountable Lbs.of Hexane R87584.93 1Isomers Lost:Lbs.of Hex Isomers exiting MO 50678.36 Fugitive Lbs.Hexane Emitted:Unit:
Lbs.Hexane par Lbs.of Spent 0.000930 Fugitive Lbs.n-Hexane Emitted:Sae from Desolvitizer tests: 0 '�Lbs.Hexane in Spent Sage: 127177.43 ug the s. eed, somars /(5 9 33
1. Emitted,
Lbs.N-Hexane in Spent Sage: 1881.91 Accountable and Fugitive Lbs. 1389176.05
Hexane Emitted:
Lbs.Hexane per Day from A-1 0.000815 Accountable and Fugitive Lbs. 20260.38
Vent Cond. N-Hex Emitted:
Lbs.Hex Exiting A-1 Vent: 0.264 Accountable and Fugitive Lbs.Hex 1348915.67
Isomers Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.003907
Gallons Water sent to W Wi: 10093507
Lbs.Waste Water persteL lr .01 �13I25G 3. Dft,-� - 193882,►( Gcuw�abk ' l Q
Wt%of Hexane in Waste Wateater:: 0.014
Lbs.Hexane Lost In Waste Water: 11785.18 (fllgk f *A,07 `�Oo
Lbs.N-Hexane Lost In Waste 17439 )jj WlNR
Water:
i, t� / /, S/ y3J .21f lbs hcaar`t
(58.76 �6S /IFI(GiN/dlr1 aa 4&/4Q SGrvi&dA (3Z1 d.+y5a-p/U"�1 ZS 7 �a»s puJ STacIL/
t uv /.4/Y7 /, = 7G i, 3 /b s rl-h1�y out /
4_ ",�,,,, can to
(1culd 501-"Co) t✓.&, / O�aina/ fo WWrh/ N0.3 heivfti 'lo,n Se�Tflylafl�io�
372 5&3. S /0 /'1"6-e
Accaurifwblt s /,,71»[. 1b s f�s"�` .f Si y3�,s 3 !6s { sfU�l� /i��s.1 A)
(/)/WT P
4 -,.w79,j /b j h h&3 w2*2�e = ,-193 t581.11 /s s

Page 4 of 5
Concrete Operations:OS-4
Gallons Monthly Monthly Monthly,
#Days Lbs.Concrete Lbs.Concrete Gallons Hexane Hexane Hexane n-Hexane Hexane
Month Lbs.Hexane Used %n-Hexane Sent as Isomers
Operated Indeed Product Used Emitted Emitted
Hazardous We to (Lbs.) (Lbs.) Emitted
January: 0.0 0.0 0.0 0.0
February: 0 0.0 0.0 0.0
March: 0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0 0.0 0.0 1 0.0
July: 0 0.0 0.0 0.0
August: 0 0.0 0.0 0.0
September. 0 0.0 0.0 0.0
October: 0 0.0 0.0 0.0
November: 0 0.0 0.0 0.0
December: 0 0.0 0.0 0.0
Averse #DIV101 #DIV/01 #DIV101 #DIV/01 0.0 #DIVl01 #DN101 0.0 0.0 0.0
Total 0 0 0.0 0 0.0 0.00 0.0 0.0 0.0
Lbs.Hexane per Day from A-1 0.000815 Accountable Lbs.of Hexane Lost: 0.00
Vent Cond.
Days A-1 Operated: 0 Accountable Lbs.of N-Hex Lost: #DN/01
Lbs.Hex Exiting A-1 Vent: 0.000 Accountable Lbs.of Hexane Isomers Lost: #DNI01
Liza.N-Hex Ez1U A-1 Vent: #DIV/0! Fugitive Lbs.Hexane Lost: 0.00
Gallons sent to WWT: Fugitive Lbs.n-Hexane Lost: #DN/OI
Lbs.Waste Water per Gal.Waste 8.34 Fugitve Lbs.Hexane Isomers Lost: #DN/01
Water:
Accountable and Fugitive Lbs.
Wt%of Hexane in Waste Water. 0.014 Hexane Emitted: 0'00
Lbs.Hexane Lost in Waste Water: 0.00 Accountable and Fugitive Lbs. #DNI01
N-Hex Emitted:
Lbs.N-Hexane Lost In Waste #DIV/01 Accountable and Fugitive Lbs.Hex #DN/01
Water: Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Santos Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September; 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Averse #DIV101 #DN/01 #DIV/01 0.00 #DNI01 #DIV/01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00

Page 5 of 5
Botanical Extraction Operation:OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sant as Hexane n-Hexane Hexane
Monty Operated Product Used Used '4 n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
A ril: 0 0.00 0.0 0
May: 0 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
Au ust: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Averse #DIVI01 #DIV/01 #DIV/01 0.00 #DIV/01 #DIVI01 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00
Plant Nutrient Extraction IM-1310peration:OS-29
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.PNE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used n-Hexane Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.) Emitted
Janus 0.0 0 0.00 0.0
February: 0.0 0 0.00 0.0
March: 0.0 0 0.00 0.0
April: 0.0 247.3 0 0.00 0.0
May: 0.0 0 0.00 0.0
June: 0.0 0 0.00 0.0
July: 0.0 0 0.00 0.0
August: 0.0 0 0.00 0.0
September. 0.0 0 0.00 0.0
October. 0.0 0 0.00 0.0
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Avers a #DIV/01 #DIV/01 #DIVI01 0.0 #DIVI01 247.3 0.000 0.00 0.00
Total 0 0 0 0.0 247.3 0.000 0.00 0.0g
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1396463.64 Total Lbs.Hexane Released: 1586866.05
Fugitive Lbs.N.Hexane Emitted: #DN/01 Total Lbs.n-Hexane Released: #DIV/01
Fugitive Lbs.Hexane Isomers #DIV/01 Total Lbs.Hex Isomers Released: #DIV/01
Emitted:
Accountable Lbs.Hexane Lost: 190402.41 Total Lbs.Hexane Sent Off Site: 18558.10
Accountable Lbs.n-Hexane Lost: #DIV/01 Total Lbs.N-Hexane Sent Off Site: #DIV/01
Accountable Los.Hex Isomers #DIV/01 Site:
s. ex Isomers en #DIV/01
Lost: Site:
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 60706 1885296 10369126.1
February: 55137 2096764 11532201.6
March: 50290 2163656 11900107.9
April: 49373 1692570 9309137.7
May: 39823 1204636 6625495.3
June: 37725 1196858 6582720.9
July: 54468 2542332 13982824.9
August: 50951 12666592 11036257.E
Se [ember: 62554 2744892 15096903.9
October: 58015 1142503 6283765.5
November: 1 60185 1780416 9792286.6
December: 1 61401 1726187 9494029.1
Max Hexane Max N-Hexane I Max N-Hexane
Maximum Hexane On-Hand Gal. al. Lbs.
62554 2744892 15096904

1
Pane 1 0l
Annual Air Emis 08on s In ntory
MethanolFac:OS S-7OS-s 0535 pSY �
5-13 OS-14 O -15 -16 -17 S-27 S-32INCLUDED WITH OSA
Year: 2016
Imo: Lbs/Ga1= 6.62 Specifics Gravity-0.793
Monthly Inventory of Methanol foallonsP Methanol Used in SDA-3A
Alcohol
Month Beginning Received Max Used Recovered Inventory Ending Methanol
Inventory (Lbs( Inventory Emitted(Lbs.)
January: 9074.0 15656.0 163713 12449.0 12281 January: 0.00
February: 1228190 14350A 176298 10994.0 15637 February: 0.00
March: 15637.1 7781.0 155028 11195.2 12223 March: 0.00
April: 122229 7753.0 132240 8027.2 11949April: 0.00
May 1194807 7486.0 128557 13169.5 6265 May; 0.00
June: 0265.2 12798.8 126203 8878.7 10185 June: 0.00
July: 10185.3 7780.0 118930 11015.0 09M July: 0.00
Au ust: 3.03 3121357 i86.00 3125
Se 5 Au ust: 0.00
embe 0 r: 31245 3 .00
October: -359.4 13149.0 84667 14444.5 -1S55
October. 0.00
November: 1 -1655.0 1 19650.7 1 110131 1 13897.8 4298 November. 0.00
December: 4298.0 7910.0 80817 10134.0 2074 December: 1 0.00
Maximum Gallons On-Hand: 26631.1
Maximum Lbs.On-Hand: 176297.882
Gallons Used perYear: 1 141982
Lt 1 939919,9132 1
clareol Recovery O erasion: 1 OS
Accountable
/Days Gallons M90H Lbs.McOH Avg.GPM Sent Lbs.M90H to Avg.% Total Gal. Monthly Avg. Emissions of Total Lbs. Total Lbs
Month Operated Used Used to WWTP WWTP Methanol in Water to Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP (O Emissions
17
Janus 31 12449 82412.38 1.2 27314.3 7.70 218928 98.4 437.0288 55098908 55535.109
Febnlary 22 8024 53118.88 1.2 17404.5 7.61 205712 98.7 226.2585 36714.38 35940.639
March 29 9096 60215.52 1.2 23251.4 7.53 183359 98.7 302.2682 36964.12 37266.388
April 18 5182 34304.84 1.2 9344.5 4.54 105094 99.8 18.689 24960.34 24979.029 ` 2 L
May 31 8475 56104.5 1.2 7949.7 2.24 173373 99.8 15.8994 48154.8 48170.899 05 J J
June 30 1 6017 53072.54 1 0.97 6874.6 2.49 165440 99.8 13.7492 48197.94 46211,689
Jul t0 5535 36641.7 1.19 7384.5 3.97 107494 99.4 44.307 29257.2 29301,507
Au ust 31 1122e 74316.12 0.96 18819 6.54 211560 99.4 111.714 5559Z12 55808,834 q Li
September 30 11108 7353C98 0.95 15438 5.68 189289 99.5 77.19 58098.96 58174.15
October 29 12218 80883.16 1.08 25948.5 7.88 205839 98.6 389,2275 5493486 55323,888
November 30 11301 74812.62 1.83 33552 6.56 203449 97.9 704.592 41280.62 41965.212
December 27 10134 67087.08 1.47 23767 5.59 192507 98.6 332,738 43320,08 43652.818
Averse 27.00 9397.08 62208.69 1.20 19070.67 5.69 180170.17 99.04 222.81 44360.83
Total 324 112765 746504.3 216846 2162042 2673.6616 '629856.3 32329.98
Concrete Operation:OS-4
Accountable
/Days Gallons McOH Lbs.McOH Avg.GPM Sent Lbs.McOH to Avg.% Total Gal. Monthly AV Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP, WIN
in Water to Remov MaOH from Fugitive Emissions
W WWTP Efficlen y WWTP Emissions
(OS-17)
January 0 0.00 0 0
Febmary 0 1 0.00 0 0
March 0 1 0.00 0 0
April 0 1 0.00 0 0
May 0 0.00 0 0
June 0 0.00 0 1 0
July 0 0.00 MO.) .
Au ust 0 0.00
September 0 0.00
October 0 0.00
November 0
December 0 0.00
0.00
Average /DW/01 YDIV101 0.00 /DIVI01 /WVI01 MDIVI01 MOIV/01 MD I01 0.00
Total 0 0 0 0 0 0
ua��wu�'1°.✓ 1 as s

Page 2 of 2
,l
EVG Operation:
S`11
Accountable
t Days Gallons M90H Lbs.MaOH Gallons McOH s.MOOR to Emissions of Total Lbs. Total Lbs.
Mom W Operated Used Used to VVWTP WWTp MoOH from Fugitive Emissions
WWTP Emissions
(OS-17)
January 0 0 0.00 0.00 0.00 0.00
February 18 2970.0 19881.4 2910.6 19268.17 385.36 393.23 778.59
March 10 2099.2 13896,704 2057.216 13818.77 272.38 277.93 550.31
April 30 2815.2 18835.224 2788.296 18458.52 369.17 376.70 745.87
May 31 4694.5 31077.59 46W.61 30458.04 809.12 621.55 1230.67
June 4 861.7 5704A54 WAN 6590.38 111.81 114.09 22590
July 27 5480.0 36277.5 5370.4 35552606 711,04 725,55 1436.59
Audiat 27 564&0 37356.5938 5530.1302 3eW9.48 732.19 747.13 1479.32
September 0 0 0.00 0.00 0.00 0.00
October 12 2226.6 14740.2906 2182.0974 14445.48 288.91 294.81 583.72
November OE
2398.6 15885.3596 2348.8484 15548.05 310.98 317.31 828.27
December 0 0 0.00 0.00 1 0.00 10.00
Ave, 19.11 3248.3 16117.93 2386.04 15795.58 15.9 838.27
Total 172 29216.8 193415.216 189548.91 3790.94 3888.30 7659.24
PNE Operation:OS.7
Accountable
N Days Gallons MOOH Lbs.MCOH Gallons M90H Lbs.McOH to Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP M90H from Fugitive Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.00 0.00 0.00 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 1 0.00
July 0 0 0.00 0.00 0.00 0.00
August 0 0 0.00 0.00 0.00 0.00
September0 0 0.00 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00 0.00
November 0 0 0.00 0.00 0.00 0.00
December 0 0 0.00 0.00 0.00 0.00
Avera a NDIV/01 tDNl01 0.00 0.00 0.00 0.00 0.00 0.00
Total 0 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol OPerations
Total Lbs.M90H Thru System: 3669184.00 Lbs.Fugivttve Emissions from EVG: 3868.30
Total s.M90H Treatedat
VJWTP: 408394.91 Lbs.Fughtive Emissions from Recovery: 529558.30
Calculated emova c ncy
of WWTP: 99.04 Lbs.Fugitive Emissions from Concrete: 0.00
Lbs.Accountable Emissions
from W WTP OS-17: 6464.60 Total Lbs.Fugitive Emissions: 5W198.27
Lbs.of Emissions from W WTp
DuringRecove : 2673,86 Total Lbs.MOOH Released: 542882.87
i.os.of emissions from WWTP
During Concrete Recovery: 0 Total Lbs.MCOH Recycled OnShe: 3152789.09
Lbs.Of Emission.from W WTP
1st Aention Chamber OS-17: 3790.94
s.Of Emissions from Misc., 0
Lab:

Annual Air Emissions Inventory
Facility ID#:0800044 /
Chloroform : 0£-9
Year: 2016
EV 6 05Y 1
Info: Lbs/Gal= 12.35
Monthly Inventory of Chloroform(pounds):
Lbs.
Beginning Recovered Chloroform Ending Infeed Product
Month Inventory Received Max New Used Used Recovered Sent as Haz Total Used Inventory (Lbs.) (Lbs.)
Waste
January: 24832 24832 0.0 24832
February: 24832 13500.0 38332 4361.0 3782.0 1800.0 6343.0 28389 2284 1100
March: 28389 28389 2478.0 1581.0 4059.0 24330 1735 1012
April: 1 24330 24330 3986.0 3667.0 450.0 7203.0 16227 2259 1320
May: 16227 16227 6250.0 6080.0 12330.0 3897 3764 2178
June: 3897 2700.0 6597 3552.0 22996.0 -19444.0 26041 866 480
July: 26041 13500.0 39541 6723.0 6594.0 13317.0 1 26224 1 3862 2090
August: 26224 26224 6670.0 6957.0 9100.0 4527.0 21697 4124 2464
September: 21697 21697 107.0 1735.0 11960.0 -10118.0 31815
October: 31815 10800.0 42615 2589.0 2683.0 5272.0 37343 1561 946
November: 37343 37343 4525.0 2662.0 7187.0 30156 1545 836
December: 30156 30156 0.0 30156
Lbs.of chloroform used during the year: 32926
Lbs.of chloro.used by Misc.,CIA,and R&D: 0
Lbs.of chloro.used by EVG: 32926
Lbs.of EVG Infeed 21999 C ZJI Lbs.EVG Produced: 12426 /
Lbs.of chloroform sent to hazardous waste: 2250
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted during year:OS-9 f 30676
/✓IJn/ red G 41�'7 PeA
y ��
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2016 Report\2016 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Heptane : OS-6.OS-7, OS-10
Year: 2018
Info: Lbs1Gal= 5.70
MonthN Inventoryof He tans(as llons:
Month Received
Beginning Max Recovered Disposed l Ending
InventoryLbs New Used Recovered
Used Sent off-She Inventory
January: 18331 1 3078 122033 4457.4 16952
February: 16952 11687 163243 5027.2 23612
March: 23612 328 136458 1607.0 22333
April: 22333 127298 5162.3 368 16813
May: 16813 4454 121220 3075.0 18192
June: 18192 6818 142554 4372.6 20637
July: 20637 3079 135179 5238.1 2648.2 2505 188 1
Au oust:, 18621 413 108489 3158.1 1422.0 17297
September: 17297 98593 -2024.1 1 19321
October: 19321 110131 3530.0 16111 14181
November: 14181 3289 99577 8394.0 11076
December: 11076 1323 70673 6675.0 5724
SFG 3 er n:OS-7 N� M
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs.Heptane Gallons Heptane Heptane
Month Operated Infeed Product Heptane Used %n-Heptane Heptane Sent as Emitted as
Used Recovered Hazardous VOC
Waste )Lbs.)
Jan - 45449 32880.0 2314.4 1 13191.9 13191.85
February, 4599 39701.0 2812.2 16029.5 16029.54
March: 11 1696 10474.0 4.0 22.8 22.80
April: 30 44692 42869.0 2744.3 15642.5 1 357.9 13602.48
May: 31 49689 45199.0 2478.0 14124.6 14124.60
June: 27 41586 36482.0 3796.6 21640.6 21640.62
July; 31 44891 40647.0 2831.1 16137.3 2648.2 1042.47
August: 14 20116 17780.0 1460.1 8322.6 1422.0 217.17
September. 13 18048 12974.0 2638.9 15041.7 15041.73
October. 0.0 0.00
November. 13 18048 12974.0 2039.0 11622.3 11622.30
December: 26 31020 22921.0 723.0 4121.1 4121.10
Avera a 23 28845.5 2187.4 11324.7 #DIV/01 2035.1 357.9 9221.39 t
Total 252 376493 315101.0 23841.8 135896.9 4070.2 357.9 110656.67 .S.S, 'i3 i�T j
Botanical Extraction Operation:OS-10
Lbs. Gallons Gallons Gallons Heptane
Monthly ns Monthly
Month #Days Botanical Heptane Lbs.Heptane %n-Heptane Heptane Hap no Sent Emitted as n-Heptane
Operated Product Used Used as Hazardous Emitted
Recovered Waste VOC (Lbs.)
January: 0.0
February: 0 0.00
0.0 March: .0 0 0.00
0
April: 0 0.00
0.0 0 0.00
May: 0.0 1 0 0.00
June: 0.0
0 0.00
July: 0.0 0 0.00
August 0.0
0 0.00
September. 0.0 0 0.00
October. 0.0
0 0.00
November: 0.0 0 0.00
December: 0.0 0 0.00
Avera a #DN101 #DIV/01 #DN/01 0.0 #DNI01 #DIV/0l #DN/01 0.00 0.00
Total 0 0.00 0.00 0.0 0.0 0.0 f 0.00 1 0.00

SFG Ooeratlon:OS-6 as 39 04 0,5V5
Gallons Monthly
#Days Lbs.SFG Lbs.SFG Gallons Lbs Heptane Gallons Heptane Heptane
.
Month Operated Infeed Product Heptane Used y,n-Heptane Heptane Sent as Emitted as
Used Recovered Hazardous VOC
Waste
January: 29 82757 71585.0 2143.0 12215.1 12216.10
February: 29 80683 73359.0 2215.0 12625.5 12625.50
March: 31 85027 74087.0 1603.0 9137.1 9137.10
April: 30 73621 64860.0 2418.0 13782.6 13782.60
May: 9 25253 20446.0 597.0 3402.9 3402.90
June: 9 23060 18078.0 576.0 3283.2 3283.20
July: 31 69129 66881.0 2407.0 13719.9 2505.3 -560.31
Au usC 31 64345 53123.0 1698.0 9678.6 9678.60
September: 30 67194 58249.0 -4663.0 -26579.1 -26579.10
October. 30 65437 55482.0 3530.0 20121 1610.5 10941.15
November: 28 59480 52916.0 4356.0 24823.5 24823.50
December: 27 73310 52417.0 5952.0 33926.4 33926,40
Avers s 25 64115 55124 1902.6 10844.73 #DN/01 #DNI01 2057.900 8889.72
Total 314 769378 1 661483 22831 A 130136. 00 0.0 4115.800 1 106676.64 1 53,3 3 1Vn S
PNE(M-13t O eration:OS-7
Gallons Monthly
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Heptane Sent Heptane
Month Heptane %n-Heptane Heptane Emitted as Process
Operated Product Used Used Recovered as Hazardous VOC
Waste
January: 0.0 0.0
February: 0.0 0.0
March: 0.0 0.0
April: 0.0 0.0
May: 0.0 0.0
June: 0.0 0.0
July: 0.0 0.0
August, 0.0 0.0
September: 0.0 0.0
October: 0.0 0.0
November: 0.0 0.0
December: 0.0 0.0
Avers a #DNI01 #DIVI01 #DIV101 0.0 #DNI01 #DIVI01 #DNI01 0.0
Total 0 0 0.0 0.0 0.0 0.0 0.0
SQe >L�io �� Ldc-S /n 7` 0 I nSAZA0W 1pe f-1S
U0 % j fa�� ���
�2, 476 y/e7n l /Z yg funs ti� {,�,�57-6

Annual Air Emissions Inventory
Facility lD#:0800044
EthV1 acetate : OS-6 OS-7,OS-10, OS-28
Year. 2016
Info: LbslGal= 7.50
Monthly Inventory of Ethyl acetate(pounds): 3J12o 2
Month B"innind Inventory Bulk Drums Ethyl acetate Used in SDA35A
Alcohol
Total Beginning Beginning New Recovered Recovered Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Disposed (Lbs) Used(Lbs.) Inventory Month Emitted(Lbs.)
Inventory Inventory Inventory
January: 1962 1962 3272.0 1909.00 5234 1909.0 3325 January: 0.00
February: 3325 3325 0 4908.0 2275.00 8233 2275.0 5958 February: 92.82
March: 5958 5958 0 4764.0 1936.00 10722 1936.0 8786 March: 56.36
April: 8786 8786 0 3202.00 8786 3202.0 5584 Aril: 0.00
May: SW 5584 0 4764.0 1751.00 10348 1751.0 8597 May: 0.00
June: 8597 8597 0 4764.0 2555.00 13361 2555.0 10806 June: 0.00
Jul 10806 10806 0 3796.00 10806 3796.0 7010 July: 0.00
Au Et: 7010 7010 0 41.0 2444.00 11774 2444.0 9330 August; 0.00
September. 9330 9330 0 1682.00 9330 1682.0 7648 September. 52.81
October. 7648 7648 1 0 1 1 2761.00 7648 2761.0 4887 October. 15.05
November: 4887 4887 0 12800.0 2512.00 17687 2512.0 15175 November. 0.00
December: 1 15175 15175 1 0 1 1 4379.00 15175 4379.0 1n7= December. 1 0.00
Ethyl acetate Emissions by Source
Ethyl acetate Emiled Ethyl acetate[o Total Ethyl acetate
from SDA a Botan al Ethyl acetate Emitt Ethyl acetate Emitt from Ethyl acetate Emitted from Ethyl acetate Emlttad Emitted from
Botanical Extraction
Month Biomass Extracticlrl:OS-28 SDA in PNE: -7 PNE:OS-7 from SFG:npc�'' OS.10 Botanical
Extraction: St0 (Lbs.) (Lbs.) U537 (Lbs.) (Lbs. O* SLS (Lbs.) OS-
(Lbs.) 4V
Lbs.) (Lbs.)
January: 0.00 0.00 0.00 1909.00 0.00
February: 92.82 0.00 0.D0 2275.00 92.82
March: 56.39 0.00 0.00 1936.00 56.39
April: 0.00 0.00 0.00 3202.00 0.00
May: 0.00 0.00 0.00 1751.00 0.00
June: 0.00 0.00 0.00 2555.00 0.00
July: 0.00 0.00 0.00 3796.00 0.00
August: 0.00 0.00 0.00 2444.00 0.00
September: 0.00 0.00 a00 1682.00 0.00
October. 52.81 0.00 0.00 2761.00 52.81
November: 0.00 0.00 0.00 2512.00 0.00
December: 15.05 13.68 0.00 4379.00 15.05
Average 18.09 1.14 0.00 *DIV10! 26 17 •DIV/01 18.09
Total 217.08 13.68 0.00 0.00 ! 1202.00 0.00 217.08
K 217,0? Ib5
S�0

Annual Air Emissions Inventory
Facility IDB:0800044
Ethanol(200 proof)-OS-10.
Year: 2018 �-
Info: Lbs/Gal= 6.58 %SDA Ethyl acetate = 4.0
Monthly Inventory of Ethanol(gallons):
Ethyl
Beginning Recovered
New inventory Recovered Max Recovered Ending Gallons to Ethanol Acetate
Month Inventory Inventory New Received New Used Recovered Total Used Disposed
(Total) (Beginning) (Begining) Received (Lbs) Used Inventory WWT VOC(Lbs.) VOC
Lbs.
January: 20225 10506 9719 0 0 20225 0 0.0 0.0
February: 20225 10506 9719 0 0 20225 0 0.0 0.0
March: 20225 10506 9719 0 0 20225 0 &0 0.0
April: 20225 105W 9719 55 0 0 20280 0 0.0 0.0
—May: 20280 10561 9719 0 0 20280 0 0.0 0.0
June: 20280 10561 9719 0 0 20280 0 0.0 0.0
July: 20280 10561 9719 0 1 0 1 1 20280 1 0 1 ao 1 0.0
August: 20280 10561 9719 0 0 1 20280 0 0,0 0.0
September: 20280 10561 9719 14 0 0 20294 0 0.0 0.0
October: 20294 10575 9719 0 0 1 20294 0 DO 0.0
November: 20294 10575 9719 0 1
0 20294 0 1 0.0
December: 20294 10575 9719 11000 0 2598 2598 28696 2546 2.1 1 0.0
Total Gallons of Ethanol Used: 2598
Total Lbs.Ethanol Used: 17102.634 I J
Gallons sent to Hazardous Waste: 0
Lbs.Ethanol sent to Hazardous Waste: 0
Total Gallons sent to WWT: 2546
Total Lbs.sent to WWT: 32
Total Lbs.of Ethanol Emitted as VOC: 342

Botanical Extraction Operation:OS-10
Lbs.Ethyl Lbs.Ethanol
Montt #Days Lbs.Botanical Gallons EtOH. Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate Emitted as Product
Operated Product BOA Used Used Recovered W WTP Emitted as VOC
VOC
January: 0.00 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
April: 0.00 0.00 0.00 0.00
-May: 0.00 0.00 0.00 0.00
June: 0.00 0.00 0.00 0.00
July: 0.00 1 0.00 0.00 0.00
Au ust: 0.00 0.00 0.00 0.00
September 0.00 0.00 0.00 0.00
October: 0.00 0.00 0.00 0.00
November: 0.00 0.00 0.00 0.00
December. 0.00 0.00 0.00 0.00
Averse #DIV101 #DN101 #DN/OI 0.00 #DN/01 0.00 0.00 0.00
Total 0 0 0 0.00 0.0 0.00 0.00 0.00
Biomass Extraction Operation:OS-28
Lbs.Ethyl Lbs.Ethanol
#Days Lbs.Biomass Gallons EtOH. Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate
Month Operated Product SDA Used Used Recovered VJTP Emitted as Emitted VOC as Product
W
VOC
VOC
January: 0.00 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
April: 0.00 0.00 0.00 0.00
May: 0.00 0.00 0.00 0.00
June: 0.00 0.00 0.00 0.00
July: 1 0.00 1 0.00 1 0.00 0.00
August: 0.00 N167960.5813.68
0 0.00
September. 0.00 0 0.00
October: 0.00 0 0.00
November: 0.00 0 0.00
December. 2598 17102.63 . Nutrati
Averse #DIV/01 #DIV/01 2598 1426.22 #DN/01 4 28.50
Total 0 0 2598 17102.63 0.0 .68 342.05
0,5 2A

Annual Air Emissions Inventory
Facility ID6:0800044
Ethanol-SDA-35A:OS-7&OS-10
0S-18.OS.19.OS-27,OS-32 INCLUDED WITH OS-10
Year. 2016
Info: LbWGal= 6.97 .SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol laallonsl:
Monthly Bealnnina Inventory Bulk Drums
Total SDA
Total SDA Bunk SDA in Drums SDA Max SDA on SDAte Ethyl
Month Beginning Beginning Beginning SDA SDA SDA Used SDA in Drums Recovered in SDA SDA Disposed Hand Ending SDA Used SDA Used WWr SDA VOC Acetate VOC
InventoryInventory Inventory Received Transferred Received Drums Usetl Recovered Lbs Inventory (gallons) (Lbs.) (Etas.)
ry ry (Lbs) Is. (Etas.) (Lbs.)
fGaJanuary: 234025 22278.8 1123.7 160775 23403 0 0.0 0.0 0.0 0.0
February: 234025 222768 1123.7 16169.4 1340701 14729 271859 24692 14880 102225.6 1DO181.1 19517 92.8
March: 24691.9 25041.1 -349.2 5400.0 9231.0 196.0 206731 21057 9035 62070.5 60829.0 1185.0 56.4
April: 21056.9 21210.1 -153.2 144661 21057 0 0.0 0.0 0.0 0.0
mar, 21056.9 21210.1 .163.2 144661 21057 0 0.0 0.0 0.0 0.0
Jute: 21056.9 21210.1 -153.2 144661 21057 0 0.0 0.0 0.0 0.0
July: 21056.9 21210.1 -163.2 1 144661 21057 0 0.0 0.0 0.0 0.0
August: 21068.9 21210.1 .153.2 144661 21057 0 0.0 0.0 0.0 0.0
Se mbar. 21066.9 21210.1 .153.2 12338.0 8466.5 3611.5 226123 21417 8467 58164.9 570016 11 f0.5 52.8
October. 21616 9 25081.6 .3664.7 1568.7 3122.5 710.0 157917 W573 2413 16573.9 16242.4 316.4 15.0
November. 20573.1 23627.8 -2954.7 141337 2GS73 0 0.0 0.0 0.0 0.0
December: 20673.1 23 227.R .2954.7 1 1 1 1 141337 1 20573 1 0 1 0.0 1 0.0 1 0.0 1 0.0
Teel I I I I 35476.1 1 0.0 1 34227.1 1 0.0 1472.9 1 906.0 1 3511.5 1 2032677.8 1 257571.9 1 34794.0 1 239034.8 1 234254.1 1 4563.7 1 217.0
Botanical Extraction Operation:OS-10 Osy a 09110
9 Days Lbs.Botanical Gallons EtOH- Lbs.EIOW Lbs.Et0H- Lbs.EtOH- EtOH-SDA ENyl Acetate
Monty SDA SDA to ProductOporate0 Product SDA Used SDA Used L p VOC(Lbs.) VOC(Lbs.)
Jan"": 0.00 0.00 0.0 0.0
February: 15 9894.00 7947.0 54595.89 53503.97 1091.9 49.6 Deus
7 2558.00 6933.0 47629.71 46677.12 952.6 43.2 Ocean Spray
March: 29 22855.60 9231.0 63416.97 1309.00 60865.81 12422 56.4 Ocean Spray
April: 0.00 0.w 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
0.00 0.00 0.0 0.0
July: 0.00 O.9D 0.0 0.0 Total SDA Ethanol Data
August: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 35700.0
September 12 8775.50 8466.5 58164.88 57001,56 1163.3 52.5 Deus Tote)Lbs.SDA Used: 245269.0
0.00 0.00 0.0 0.0 Total Gallons 98M W 1VWr: 2273.56
October. d 2258.50 3122.5 21d51.5B 4877.70 18242.40 331.5 15.0 Decas
November: 0.00 0.00 0.0 0.0 Total Los.sate to WWr: 15619.39
December. 0.00 0.00 0.0 0.0 Total Lbs.SDA Ethanol Emitted as VOCS: 310.76
Us.Botanical Extraction Ethanol Embtetl as VOC:OS-10 318.76
Awra c 73 8868 7140 16331 3093 15619 Lbs.PNE Ethanol Emitted as VOC:OS.7 0.00
Total fi7 44342 3570 2245259 6187 9""1 4781 217
PNE Operation:OS-7
8 Days Lbs.PNE Gallons EtOH- Lbs.EtOH- Lbs.EtOH- Lbs.EIOH- EtOH-SDA Ethyl Acoustic
MonthOperated Product SDA Used SDA Used SDA SDA to VOC(L�.) VOC(LDs.I Product
Recovered WTI`January-, 0.00 0.00 0.0 0.0
February: 0.00 0.00 0.0 0.0
arch: 0.00 0.00 0.0 0.0
April: 0.00 0.00 0.0 0.0
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
John. 0.00 0.00 0.0 0.0
August: 0.00 0.00 0.0 GO
September 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
Oeumber. I I I 1 0.00 1 1 0.00 0.0 1 0.0
Averse I 8DN/01 I BDWIOt I 8DIV101 0.00 1 pONI01 1 0.00 1 0.00 1 0.00
Total 1 0 1 0.00 1 0.0 0.00 1 0.00 1 0.00 1 0.00 1 0.00