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HomeMy WebLinkAboutAQ_F_0800102_20161004_EI_Cmb-EI-File i D 2015 Emission's Inventory Review / Data Tracking Form Facility Name: East Carolina Regional Solid Waste Landfill Facility ID: 0800102 Facility Assigned to: Data Entry: Bertie County Classification: Confidential Copy Submitted? Title V SlZO ❑ s IRr N Initial Review/Data Entry mer date received into ED. Date Received: (o —0.3 —2 n - (p H Assigned to appropriate individual. Date Assigned: /G Date Due: V-?e�Zo_ 0-1*�Paner copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and ppears generally complete;iDW 0-r%J Ef Electronic copy submitted: All supporting documentation and certification form(with time/date stamp)signed by responsible official has been received. f / / Comments: =h G 2 0 /� - k So e!w'/c 0 /- S 7 I * < i P m,t S m a c (ucvs � m n 1 Cl�n c r�. �-g, i o'�- p pr EP 0P•s� imel- e, heh,4 . - ry L�2D�S' -,-A f6zSGmnGenfY+cT%/1 was AkinG ;vt WSll�G � an G�r2o/c� �1/2n /ti lY1,J OIL, W=/TG , Inventory Review All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic). E7'*' Contact,address,phone number changes entered into I-Beam/Facilities if necessary. E'r All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted, insignificant,and unpermitted)or note that the emission source was not operated or not required to report. d Check if SCC codes for each OS are accurate and update if needed. 0' Evaluate "U"sources for significance and address according to policy. Calculations/forms appear to add up correctly. All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds, large emissions increase/decrease,installation without a permit). All volatile HAPs/TAPs were included in the VOC total. Er Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for the reporting facility(e.g.stack testing,AP42,etc.). E�/Review facility comments and address any issues. d Update ED(Data Entry Main)if additional information is required(corrections due date and date received). Ur Check all ED QA/QC reports. i" Comparison with previous emission inventory must be made and outliers(> 10%)must be investigated and explained. 13r Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments". d Print and attach the facility total report. Date Info Requested: — Date Info Received: _ Total Days on Hold: Date Review Complete: U ,? Zo Signature: ` Date Submitted to El Coordinator: Date Approved: �T f Z Initials: Daniels, Steven From: Greene, David <dgreene@scsengineers.com> Sent: Monday, September 26, 2016 3:22 PM To: Daniels, Steven Cc: VanDussen, Marta; Morgan, J Subject: East Carolina Emissions Inventory Follow-up Steven, It was pleasure speaking with you Friday afternoon. To re-cap that conversation regarding the change in SO2 emissions between CY2015 and CY2014: The concentration estimate for H2S to calculate SO2 emissions was harmonized with the H2S concentration factor used elsewhere in the emissions inventory. To calculate SO2 emissions,the H2S concentration is used in the LFG to estimate conversion to SO2 when LFG is combusted, per EPA AP-42 methodology. In CY2014 to calculate SO2 emissions from the flare, the H2S concertation value was not based on the WIAC value (The WIAC value was used for H2S LFG fugitive emissions). For CY2015 reporting, we harmonized the emissions factors for H2S so that the SO2 calculation would be consistent with the H2S concentration value used for fugitive emission calculation. If you have further questions or comments, please let us know. Thank you Steven, David Greene, PE SCS ENGINEERS 20 Battery Park Avenue Suite 505 Asheville, North Carolina 28801 828.285.8951 www.scsengineers.com 1 it Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Green House Gases Pollutant H Actual Emissions s (G G) Tons/Yr o/° Pollutant CAS Demini_ Change mus Not Not N/A Reported Reported CO2 equivalent(sum of individual GHG pollutant emissiot No GHGs times their 1995 IPCC Global Warming Potential (GWP), Reported converted to metric tons) Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS CY 2015 CY2014 Demini- % from ED from Fees mus Change CO CO 121.64 111.33 0.5 9.3% NOx Nox 28.92 27.03 0.5 7.0% PM(TSP) TSP 5.46 5.00 OS 9.2% PM10 PM10 5.46 5.00 0.5 9.2% PM2.5 PM2.5 5.46 5.00 0.5 9.2% S02 S02 2.73 3.58 0.5 -23.7% VOC VOC 12.38 11.87 0.5 4.3% Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPS) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Manganese& compounds 1101.00 101.00 10.0 10.0% Manganese Unlisted Compounds - Specify Compout MNC-Other 101.00 101.00 10.0 0.0% (Component of MNC) Mercury& Compounds-all total mass includes Hg Vapor 0.260000 0.240000 0.001 9.3% Mercury,vapor(Component of HGC) 7439-97-6 0.260000 0.240000 0.001 8.3% Total Reduced Sulfur(TRS as.total mass) 989.44 947.55 4.4% Hydrogen sulfide 7783-06-4 918.40 879.52 1.0 4.4% Methyl mercaptan 74-93-1 71.04 68.03 1.0 4.4% Acetaldehyde 75-07-0 2.40 2.40 10.0 0.0% 10/03/2016 Page 1 of') Facility Total CY 2015 Emission Summary Recorded in ED Facility H)#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Acrolein 107-02-8 0.300000 0.300000 10.0 0.0% Acrylonitrile 107-13-1 2.18 2.09 10.0 4.3% Benzene 71-43-2 89.97 86.36 1.0 4.2% Butadiene, 1,3- 106-99-0 0.100000 0.100000 1.0 0.0% Carbon disulfide 75-15-0 27.84 26.66 10.0 4.4% Carbon tetrachloride 56-23-5 1.29 1.23 1.0 4.9% Carbonyl sulfide 463-58-1 12.57 12.03 1.0 4.5% CFC-12 (Dichlorodifluoromethane) 75-71-8 253.75 242.62 100.0 4.6% Chlorobenzene 108-90-7 30.62 29.29 10.0 4.5% Chloroform 67-66-3 3.01 2.88 100.0 4.5% Dichlorobenzene(p), 1,4- 106-46-7 283.13 270.72 1.0 4.6% Ethyl benzene 100-41-4 824.08 789.28 100.0 4.4% Ethyl chloride(chloroethane) 75-00-3 18.48 17.67 10.0 4.6% Ethyl mercaptan 75-08-1 96.29 92.22 10.0 4.4% Ethylene dibromide (dibromoethane) 106-93-4 10.36 9.91 1.0 4.5% Ethylene dichloride (1,2-dichloroethane) 107-06-2 14.23 13.61 1.0 4.6% Ethylidene dichloride(1,1-dichloroethane) 75-34-3 87.90 82.59 100.0 6.4% Formaldehyde 50-00-0 3.60 3.60 10.0 0.0% Hexane,n- 110-54-3 228.91 219.22 100.0 4.4% Hydrogen chloride(hydrochloric acid) 7647-01-0 5,015.40 4,585.20 100.0 9.4% MEK(methyl ethyl ketone,2-butanone) 78-93-3 887.77 854.62 100.0 3.9% Methyl chloride(chloromethane) 74-87-3 15.08 14.41 1.0 4.6% Methyl chloroform 71-55-6 26.87 25.69 100.0 4.6% Methylene chloride 75-09-2 345.77 330.65 1.0 4.6% MIBK(methyl isobutyl ketone) 108-10-1 86.15 82.58 10.0 4.3% Perchloroethylene(tetrachloroethylene) 127-18-4 237.11 226.72 100.0 4.6°/, 10/03/2016 Page 2 of 3 Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPS) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Polycyclic Organic Matter(Inc PAH,dioxins,etc.N, POM 74.10 74.10 1.0 0.0% &AP 42 historic) Propylene dichloride(1,2-dichloropropane) 78-87-5 3.11 2.98 10.0 4.4% TCE(trichloroethylene) 79-01-6 107.26 102.54 1,000.0 4.6% Tetrachloroethane, 1,1,2,2- 79-34-5 14.08 13.47 100.0 4.5% Toluene 108-88-3 2,677.37 2,564.32 100.0 4.4% Vinyl chloride 75-01-4 80.68 77.14 0.1 4.6% Vinylidene chloride 75-35-4 10.69 10.22 0.1 4.6% Xylene(mixed isomers) 1330-20-7 2,013.65 1,928.63 100.0 4.4% Largest Individual HAP Hydrogen chloride(hydrochloric acid) 5,015.40 lbs Total HAP Emissions 2,449.55 lbs DAO's Comments ReEardina Inventory In CY2014 to calculate S02 emissions from the flare,the H2S concertation value was not based on the WIAC value(The WIAC value was used for H2S LFG fugitive emissions). For CY2015 reporting,we harmonized the emissions factors for HIS so that the S02 calculation would be consistent with the H2S concentration value used for fugitive emission calculation 10/03/2016 Page 3 of 3 eW REPUBLIC SERVICES June 2, 2016 Mr. Robert Fisher Regional Air Quality Supervisor NCDEQ-Washington Regional Office 943 Washington Square Mall Washington, North Carolina 27889 Subject: Air Pollutant Point Source Emissions Inventory-Calendar Year 2015 East Carolina Environmental Landfill Aulander, North Carolina Facility ID No:0800102 Title V Permit No: 08849T06 Dear Mr. Fisher: Republic Services of North Carolina, LLC (Republic) is submitting the attached Air Pollutant Point Source Emissions Inventory for 2015 for the referenced site. If you have any questions or require additional information, please contact me at (919) 354-3227 or J. Morgan with SCS Engineers at (704) 504-3107. Sincerely, Republic Services of North Carolina, LLC Matt Einsmann, PE Environmental Manager cc: Rob Purvis (East Carolina Environmental Landfill) J Morgan P.E. (SCS Engineers) Page 1 of 1 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 Inventory Certification Form(Title V) Facility Name: East Carolina Regional Solid Waste Landfill Facility ID: 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 These forms must be completed and returned even if the facility id not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Drew Isenhour This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars);or ii.the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship;a general partner or the proprietor,respectively; 3. for a muncipality, state, federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). CERTIFICATION STATEMENT* (Imi2ortante Legally Responsible Official, ll I. I certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in this air emissions report, including attached calculations and documentation, is true, accurate and complete. (Subject to legal enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: Drew Isen ur Sign ure: &L�_ -7 This form applies to Title V facilities. If this facility is not classified as Title V, please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: Dlsenhour@Republicservices.com Information on this Form cannot be held confidential JU. COPY of RECORD Date Submitted: 5/6/2016 10:47:19 1 Daniels, Steven From: Daniels, Steven Sent: Thursday, June 30, 2016 8:29 AM To: 'Dlsenhour@Republicservices.com' Subject: FW: Clarification on the date stamp for the inventory certification Mr. Isenhour, I apologize for the misinformation concerning the red header on the certification form. Hope it hasn't caused too much burn. Sincerely Steve Daniels From: Huddleston, Betsy Sent: Wednesday,June 29, 2016 3:50 PM To: Bright, Robert<robe rt.bright@ncdenr.gov>; Fisher, Robert<robert.fisher@ncdenr.gov>; Chen,Yongcheng <yongcheng.chen@ncdenr.gov>; Daniels,Steven <steven.d.daniels@ncdenr.gov>;Jones, Randall <Randall.Jones@ncdenr.gov> Subject: Clarification on the date stamp for the inventory certification I got schooled today on inventory policy........the date stamp on the certifications does NOT need to be printed in red color at the top. The date stamp itself DOES need to show up at the top of the form, and it should match the AERO submittal date in ED. Kim is already checking this for you. The only outstanding electronic submittal is Grady White Boats. However, we still have about 10 hard copies with certs floating out there in the mail........ Betsy Huddleston Division of Air Quality North Carolina Department of Environmental Quality 252 948 3836 office 252 975 3716 fax Betsy.Huddleston(�ncdenr.gov 943 Washington Square Mall Washington, NC 27889 - ::� Nothing Compares -cl _ Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. 1 East Carolina Environmental Landfill 2015 Emission Inventory REPUBLIC SERVICES East Carolina Environmental Landfill 2015 Emission Inventory Air Permit 08849T07 Presented to: Republic Services of North Carolina, LLC East Carolina Environmental Landfill 1922 Republican Road Aulander, NC 27805 Presented by: SCS Engineers, PC 2520 Whitehall Park Drive, Suite 450 Charlotte, North Carolina 28273 (704) 504-3107 May 6, 2016 File No. 02209360.16 Task 3 East Carolina Environmental Landfill 2015 Emission Inventory Table of Contents Section Page SECTION1 Introduction........................................................................................................................ 1 SECTION 2 Uncollected Landfill Gas Fugitives................................................................................2 SECTION3 Landfill Gas Flare............................................................................................................5 SECTION 4 Insignificant Activities.......................................................................................................6 Attachment A CY2015 Annual Emissions Statement and Completed AERO Forms B Detailed Emission Calculations I East Carolina Environmental Landfill 2015 Emission Inventory SECTION 1 INTRODUCTION Per Condition 3.X of East Carolina Environmental Landfill (Landfill) Air Quality Permit No. 08849T07 for its Landfill located at 1922 Republican Road, Aulander, North Carolina, the facility is required to submit an emissions inventory to the Department of Air Quality(DAQ)by June 30 of each year. The emissions inventory presented herein is the basis for the emissions values reported in the CY2015 Annual Emissions Statement, as provided in Attachment A. The emission sources identified were based on discussions and correspondence with Landfill staff, SCS Engineers' (SCS) knowledge of the site, a review of existing permits, compliance reports, and other information provided by the Landfill staff. Facility-wide emissions at the Landfill are provided in Table 1 below. Facility-wide emissions including speciated HAPs are provided in the detailed emission calculations in Attachment B. Emissions for each source are further detailed in the remaining sections of this report. This document is submitted in conjunction with the online reporting using Air Emissions Reporting Online (AERO) system. Table 1 . 2015 Annual Emission Rate Summary (tons/yr) Permit ID Emission Source NMOC VOC HAPs/TAPS NOx CO sox PM10 Municipal Solid ES-01 Waste Landfill 29.61 11.55 3.56 (Fugitive Emission) CD-Flarel Landfill Gas Flare 1 0.31 0.12 1.21 10.36 56.39 1.07 2.54 CD-Flare2 Landfill Gas Flare 2 0.36 0.14 1.36 11.72 63.78 1.21 2.87 Diesel Engines for IES-04 Miscellaneous 0.55 4.28E-02 6.84 1.47 0.45 0.05 Landfill Support IES-05 Welding 5.05E-02 Operations IES-06 Diesel Storage Tank 2.23E-03 2.23E-03 IES-07 Leachate Storage 1.61 E-02 1.61 E-02 0.010 Tanks Total1 30.30 12.38 6.24 28.92 121.64 2.73 5.46 Notes: -- Not Applicable. Due to rounding,'Total"emissions may not exactly equal the sum of the individual source emission rates as they appear in the table above. 1 Site reports solar flares were not operated during this reporting period. Emissions from Welding Operations,and Diesel Engines are"carried forward"from the prior reporting year as allowed by the DEG,DAG AERO reporting system 1 East Carolina Environmental Landfill ortwxympirnarm 2015 Emission Inventory SECTION 2 UNCOLLECTED LANDFILL GAS FUGITIVES LANDFILL GAS FUGITIVE EMISSIONS This section addresses the generation of landfill gas(LFG),non-methane organic compounds (NMOCs),volatile organic compounds(VOCs)and hazardous air pollutants(HAPs),methane, and carbon dioxide and its fugitive emissions. LFG generation from the landfill operation was calculated using SCS Engineers' version of the U.S. EPA Landfill Gas Emissions Model(LandGEM). A description of the model parameters is provided below and the model output is attached. LandGEM uses a first-order decay equation to predict landfill gas generation based on the amount and age of the waste in place. The formula is presented in 40 CFR Part 60.754(a)(1)(i). The parameters La and k used in the LandGEM are the values published in EPA's Compilation of Air Pollutant Emission Factors(AP-42),Volume I, Section 2.4(revised November 1998). The methane generation potential, La, for the MSW landfill cells was set equal to 100 cubic meters(m)of methane(CH4)per megagram(Mg)of waste. The methane generation rate constant,k,was 0.04 yr i and the concentration of NMOC in LFG was set to 595 parts per million by volume(ppmv)as hexane. AP-42 recommends these values of La and k for municipal solid waste(MSW) landfills that are located in geographical regions that receive average or above average annual precipitation, such as Aulander, North Carolina. To calculate landfill emissions, the refuse filling history was input to the LandGEM. Note that this model estimates emissions based on the amount of waste in place at the beginning of each year. Waste in place at the beginning of 2015 was approximately 8.78 million Mg, or 9.68 million tons. The LandGEM estimated that the methane generation rate for CY2015 was approximately 25.19 million cubic meters,or approximately 889.58 million cubic feet. Assuming that the methane content in the LFG is 50 percent, the volume of LFG generated in CY2015 is estimated to be 3,385 cubic feet per minute(ft/min). LandGEM input and output are provided on page 1 of the spreadsheets included with this submittal as Attachment B. Non-Methane Organic Compound (NMOC) Emissions NMOC generation from the Landfill was calculated using LandGEM. Model parameters were similar to the values noted above. LandGEM estimated that the NMOC generation rate for 2015 is 107.45 Mg,or 118.44 tons(See page 2 of the spreadsheets provided in the detailed calculations attachment). The Landfill operates a gas collection and control system(GCCS)to capture LFG and route it to a control flare. Seventy five percent of the LFG is assumed to be captured; therefore,twenty five percent of the NMOC generated is assumed to have been emitted as fugitive. Thus, the fugitive NMOC emission rate for calendar year 2015 is 29.61 tons. 2 East Carolina Environmental Landfill mrsairynamanTy 2015 Emission Inventory Volatile Organic Compound (VOC) Emissions In establishing the VOC emissions from the landfill,VOC generation is assumed to be 39 percent of the NMOC generation. This assumption is based on information contained in AP42 Section 2.4(revised November 1998)Table 2.4-2. VOC emissions were based on the historical tonnages and model parameters noted above. The LFG and NMOC generation rates were extracted from the LandGEM output and represent the emissions from the Landfill during CY2015. The VOC generation rates were calculated by converting the NMOC generation rates(shown in the LandGEM output) from Mg/yr to tons/yr, and then multiplying by 0.39(i.e.,VOC is considered as 39 percent of NMOQ). The VOC generation rate for CY2015 is 46.19 tons/yr. The fugitive VOC emission rate is determined in the same manner as the fugitive emissions rate for NMOC reflecting the operation of the GCCS during the period. The fugitive VOC emission rate for CY2015 is 11.55 tons, as shown in Table 2 below. Table 2. Air Pollutant Generation and Emission Rates NMOC NMOC • • VOC Fugitive HAP Fugitive Year Generation Generation Emissions Generation Emissions Emissions 2015 107.45 118.44 29.61 46.19 11.55 7 3.56 Notes: I VOC generation is assumed to be 39 percent of NMOC generation. Hazardous Air Pollutant (HAP) Emissions The estimation of HAP emissions from the Landfill is based on equations(3)and(4)of AP42 Section 2.4. Those equations are presented below. The first step is to estimate the generation rate of each pollutant in cubic meters per year(m3/yr). Next,the volumetric generation rate estimate is converted to a mass generation rate(ton/yr). 3 CP QP(yr =2.0X QU4 06 where: QP = Pollutant generation rate(m3/yr) QCh4 = Methane generation rate(m3/yr) from the LandGEM Cp = Pollutant concentration in LFG(ppmv) 2.0 = Multiplication factor(assumes LFG is 50 percent methane, and the balance is carbon dioxide,nitrogen, oxygen and other trace gases) 3 East Carolina Environmental Landfill 2015 Emission Inventory M p (tons/yr)= Q p l(MWp(glgmoI))(1 atm�� ton l (gmol—KA _5m3 —atm1000g l( �8.205x10 g )'273+TK)Iwhere: J MP = Pollutant mass generation rate MWP = Molecular weight of pollutant(g/gmole) T = Temperature of LFG(IC) (Standard temp of 25 degrees Celsius) Of the 188 chemical compounds identified as HAPs under Section 112 of the Clean Air Act, 28 of these compounds are listed in AP42 Table 2.4-1 and 2.4-2. Site-specific data from testing performed by Research Triangle Park Laboratories was used to determine the concentration of these compounds. This report is dated May, 5,2005 and was submitted as part or the Compliance Demonstration Report dated June 3,2005. These site specific concentrations are shown on page 4 of the spreadsheets in the detailed emissions attachment. Annual emissions of the remaining HAP compounds(i.e.,those not included in the AP-42 tables)are assumed to be negligible. The HAP fugitive rate for CY2015 was calculated to be 3.56 tons. 4 East Carolina Environmental Landfill 2015 Emission Inventory SECTION 3 LANDFILL GAS FLARE Flare Emissions The landfill operates two (2) flares (permitted as CD-Flarel and CD-Flare2), each with a design capacity of 3,000 scfm, as a landfill gas control devices. The emission factors and annual emissions associated with each flare are summarized in Table 3 below. Table 3. LFG Flare Emissions Data 2015 LFG Flare Emissions Compound LFG Flare Emission Factors NOx 0.068 Ib/MMBtu 1 10.36 11.72 CO 0.37 Ib/MMBtu 1 56.39 63.78 NMOC 99.2 % destruction•2 0.31 0.36 VOC3 99.2 % destruction•2 0.12 0.14 99.8 % destruction for halogenated HAP species2 HAPs 99.7%for non-halogenated HAP species 2 1.21 1.36 0% for mercury species 2 PM10 17 Ib/106 ft3 methane4 2.54 2.87 r--I I I - SO2 H2S concentration: 35.5 ppmv5 1.07 1.21 Notes: Emission factor obtained from AP-42,Table 13.5-1. 2 Control efficiency obtained from AP-42,Table 2.4-3. 3 VOC generation is estimated to be 39 percent of the NMOC generation per Table 2.4-2 of AP-42 Section 2.4 "Municipal Solid Waste Landfills," revised 11/98. These estimates assume a 75%LFG collection efficiency for the active landfill gas collection system. 4 Control efficiency obtained from AP-42,Table 2.4-5. 5 S02 emissions are calculated per AP-42,Section 2.4.4; 5 East Carolina Environmental Landfill 2015 Emission Inventory SECTION 4 INSIGNIFICANT ACTIVITIES Diesel Engines for Miscellaneous Landfill Support (IES-04) The Landfill's permit includes an insignificant activity listing for"Diesel engines for miscellaneous support"with the emission source ID IES-04. Emissions from this source are "carried forward"as allowed in the Division's AERO reporting system and are therefore represented as reported in the previous reporting period. Welding Operations (IES-05 ) The Landfill's permit also includes an insignificant activity listing for"Welding Operations" with the emission source ID IES-05. Emissions from the Landfill's welding operations are "carried forward"as allowed in the Division's AERO reporting system and are therefore identical to the previous reporting period. As reported in previous years, emissions of manganese remain at 101 pounds for this calendar year. This is reported as HAPs/TAPs of 5.05E-02 tons per year for the welding operations. Diesel Storage Tank (IES-06) There is one diesel storage tank at the site designated in the permit as insignificant activity IES- 06. Emissions for calendar year 2015 were"carried forward"from previous year as they were calculated at the time,using EPA's Tank software. The throughput of diesel fuel in calendar year 2015 was 148,697 gallons. Leachate Storage Tanks ( IES-07) The Landfill operates two (2)leachate storage tanks,with emission source ID IES-07, to store collected leachate and condensate from the Landfill prior to disposal at an offsite wastewater treatment system. The throughput of leachate in calendar year 2015 was 7,066,317 gallons. Detailed emission calculations are provided in the Attachment B. Table 4. Leachate Emissions Data Parameter CY201 5 Leachate Throughput (gallons) 7,066,317 Calculated VOC Emissions (Ibs) 32.27 6 East Carolina Environmental Landfill 2015 Emission Inventory ATTACHMENT A CY2015 ANNUAL EMISSIONS STATEMENT AND COMPLETED AERO FORMS •4 :1 COPY of RECORD Date Submitted. 5/6/2016 1 0. 7 9 Inventory Certification Form(Title V) Facility Name: East Carolina Regional Solid Waste Landfill Facility ID: 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 These forma must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Drew Isenhour This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation:a president,secretary,treasurer,or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars);or ii.the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship;a general partner or the proprietor,respectively; 3. for a muncipality,state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). CERTIFICATION STATEMENTi (Importanto Legally Responsible Official- read and sian after all submin I certify that I am the responsible official for this facility, as described above,and hereby certify that the information contained in this air emissions report, including attached calculations and documentation,is true,accurate and complete. (Subject to legal penalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: D w Isenhour Signature: JM ` -- 31 -I fo This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: DIsenhour@Republicservices.com Information on this Form cannot be held confidential COPY of RECORD Date Submitted: 5/6/2016 10.47:19 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO Listing of Emission Sources and Control Devices on Permit. See instructions DES ID on DES Description GCS ID GCS Description CD ID's Air Permit ES-01 Municipal solid waste landfill CS-1,CS-4 Flare,One landfill gas—fired open CD—Flare I, CD—Flare2 [NSPS,MACT] flare(3000 scfrn maximum flow rate) IES-04 Diesel engines for miscellaneous landfill support IES-05 Welding operations IES-06 Diesel storage tank IES-07 One leachate storage tank 2 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Emission Source & Operating Scenario List — See Instructions DES Group ID DES ID SOS ID SOS Description I Municipal solid waste landfill ES-01 H CD—Flare 1 9 CD—Flare 2 IES-04 4 No. 2 fuel oil—diesel engines for miscellaneous landfill support IES-05 3 maintenance shop welding rods IES-06 6 diesel storage tank IES-07 2 temporary storage of collected leachate 3 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT] 3. Operating Scenario ID/Description: OS— l/Municipal solid waste landfill 4. SCC Number/Description: 50100402/Landfill Dump ;Fugitive Emissions 5. Throughput/units in 2015: 444657600 FT3/yr tl�j i (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 4 Operating Scenario: OS— 1 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: Jan—Feb +Dec ° arch—May ° une—Aug. 25% ept.—Nov. 25% 015 25�O 015 25�O �015 �015 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2015 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (N�QS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2015 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 11.55 08 Emission CAS Emissions Estimation Control HAP/TAP Method Efficient Emission Pollutants (In Alphabetical Order) (see HAP/TAPS all Factor EF Control instructions) (Pounds/Year) Code (Net after a (See controls) Instructions 2015 Acr lonitrile 107-13-1 2.16 08 Benzene 71-43-2 86.03 08 CFC-12 ichlorodifluoromethane 75-71-8 239.9 08 Carbon disulfide 75-15-0 27.6 08 Carbon tetrachloride 56-23-5 1.22 08 Carbonyl sulfide 463-58-1 12.46 08 Chlorobenzene 108-90-7 28.95 08 Chloroform 67-66-3 2.84 08 Dichlorobenzene 1 4— 106-46-7 267.68 08 5 Eth lbenzene 100-41-4 816.67 08 Ethyl chloride chloroethane 75-00-3 17.47 08 Ethyl merca tan 75-08-1 95.46 08 Ethylene dibromide 106-93-4 9.79 08 Ethylene dichloride 1 2—dichloroethane 107-06-2 13.46 08 Ethylidene dichloride 75-34-3 83.1 08 1 1—dichloroethane Hexane n— 110-54-3 226.95 08 Hydrogen sulfide 7783-06-4 910.52 08 Mercury,vapor(Component of HGC 7439-97-6 0.07 08 Methyl chloride 74-87-3 14.25 08 Methyl chloroform 71-55-6 25.4 08 Methyl ethyl ketone 78-93-3 862.62 08 Methyl isobutyl ketone 108-10-1 85.12 08 Methyl merca tan 74-93-1 70.43 08 Methylene chloride 75-09-2 326.76 08 Perchloroeth lene tetrachloroeth lene 127-18-4 224.17 08 Provvlene dichloride 78-87-5 2.94 08 Tetrachloroethane 1 1 2 2— 79-34-5 13.31 08 Toluene 108-88-3 2652.17 08 Trichloroeth lene 79-01-6 101.4 08 Vinyl chloride 75-01-4 76.27 08 Vin lidene chloride 75-35-4 10.11 08 X lene 1330-20-7 1994.71 08 6 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT] 3. Operating Scenario ID/Description: OS—8/CD—Flare 1 4. SCC Number/Description: 50300601/Landit11 Dump;Waste Gas Flares 5. Throughput/units in 2015: 602341762 FT3/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control 100 Device or Stack): 8. Control Device Information Order CS—ID CD ID Control Device Description as listed in ermit 1 CS-1 CD—Flarel One landfill as—fired open flare 3000 scfm maximum flow rate 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm) ectangle(L x W) in 0.1 feet) Flare VERTICAL STACK 35 1 1200 28.09 1324 Flare 7 Operating Scenario:OS—8 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec o arch—May o une—Aug. o ept.—Nov. o 015 25/0 015 25 /� �015 25/0 �015 25/o 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2015 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po�QS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2015 CO CO 56.39 08 0 NOz NOa 10.36 08 0 TSP TSP 2.54 08 0 PM10 PM10 2.54 08 0 PM2.5 PM2.5 2.54 08 0 S02 S02 1.07 08 0 VOC VOC 0.12 08 0.98 AFTER Emission CAS Emissions Estimation Control HAP/TAP Method Efficiency Emission Pollutants (In Alphabetical Order) (see HAP/TAPS etaferall Factor l 1 Control instructions) (Pounds/Year) Code (N (See controls) Instructions 2015 Acrylonitrile 107-13-1 0.01 08 98 Benzene 71-43-2 0.35 08 98 CFC-12 ichlorodifluoromethane 75-71-8 6.5 08 98 Carbon disulfide 75-15-0 0.11 08 98 Carbon tetrachloride 56-23-5 0.03 08 98 Carbonyl sulfide 463-58-1 0.05 08 98 Chlorobenzene 108-90-7 0.78 08 98 Chloroform 67-66-3 0.08 08 98 Dichlorobenzene 14— 106-46-7 7.25 08 98 8 Eth I benzene 100-41-4 3.32 08 98 Ethyl chloride chloroethane 75-00-3 0.47 08 98 Ethyl merca tan 75-08-1 0.39 08 98 Ethylene dibromide 106-93-4 0.27 08 98 Ethylene dichloride 1 2—dichloroethane 107-06-2 0.36 08 98 Ethylidene dichloride 1 75-34-3 2.25 08 98 1—dichloroethane Hexane n— 110-54-3 0.92 08 98 Hydrogen chloride(hydrochloric acid 7647-01-0 2353.38 08 98 Hydrogen sulfide 7783-06-4 3.7 08 98 Mercury,vapor(Component of HGC 7439-97-6 0.09 08 98 Methyl chloride 74-87-3 0.39 08 98 Methyl chloroform 71--55-6 0.69 08 98 Methyl ethyl ketone 78-93-3 3.5 08 98 Methyl isobutyl ketone 108-10-1 0.35 08 98 Methyl merca tan 74-93-1 0.29 08 98 Methylene chloride 75-09-2 8.85 08 98 Perchloroeth lene tetrachloroeth lene 127-18-4 6.07 08 98 Propylene dichloride 78-87-5 0.08 08 98 Tetrachloroethane 1 1 2 2— 79-34-5 0.36 08 98 Toluene 108-88-3 10.77 08 98 Trichloroeth lene 79-01-6 2.75 08 98 Vinyl chloride 75-01-4 2.07 08 98 Vin lidene chloride 75-35-4 0.27 08 98 X lene 1330-20-7 8.1 08 98 9 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2015 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT] 3. Operating Scenario ID/Description: OS-9/CD-Flare 2 4. SCC Number/Description: 50300601/Landfill Dump;Waste Gas Flares 5. Throughput/units in 2015: 681338328 FT3/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control 100 Device or Stack): 8. Control Device Information Order CS-ID CD ID Control Device Description as listed in ermit I CS-4 CD-Flare2 One landfill as-fired open flare 3000 scfm maximum flow rate 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntrV lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) Flare2 VERTICAL STACK 40 1.17 1200 22.78 1470 Flare 2 10 Operating Scenario: OS—9 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 250yo June—Aug. 25% �015 ept.—Nov. 25% 7]O15 015 2015 13. Actual Emissions ner Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code Met after Factor (Tons/Year) (See all controls) Instructions 2015 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po`�QS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2015 CO CO 63.78 08 0 NOx NOx 11.72 08 0 TSP TSP 2.87 08 0 PM10 PM10 2.87 08 0 PM2.5 PM2.5 2.87 08 0 S02 7dl I.°r6 S02 1.2 S'. 08 0 VOC VOC 0.14 08 0.98 AFTFR Emission CAS Emissions Estimation Control HAP/TAP Emission (see HAP/TAPS Method Efficiency EF Control Pollutants (In Alphabetical Order) Code (Net after all Factor instructions) (Pounds Year) (See controls) Instructions 2015 Acrylonitrile 107-13-1 0.01 08 98 Benzene 71-43-2 0.4 08 98 CFC-12 ichlorodifluoromethane 75-71-8 7.35 08 98 Carbon disulfide 75-15-0 0.13 08 98 Carbon tetrachloride 56-23-5 0.04 08 98 Carbonyl sulfide 463-58-1 0.06 08 98 Chlorobenzene 108-90-7 0.89 08 98 Chloroform 67-66-3 0.09 08 98 Dichlorobenzene 14— 106-46-7 8.2 08 98 11 I� Eth (benzene 100-41-4 3.75 08 98 Ethyl chloride chloroethane 75-00-3 0.54 08 98 Ethyl merca tan 75-08-1 0.44 08 98 Ethylene dibromide 106-93-4 0.3 08 98 Ethylene dichloride 12—dichloroethane 107-06-2 0.41 08 98 Ethylidene dichloride 75-34-3 2.55 08 98 1 1—dichloroethane Hexane n— 110-54-3 1.04 08 98 Hydrogen chloride(hydrochloric acid 7647-01-0 2662.02 08 98 Hydrogen sulfide 7783-06-4 4.18 08 98 Mercury,vapor(Component of HGC 7439-97-6 0.1 08 98 Methyl chloride 74-87-3 0.44 08 98 Methyl chloroform 71-55-6 0.78 08 98 Methyl ethyl ketone 78-93-3 3.96 08 98 Methyl isobutyl ketone 108-10-1 0.39 08 98 Methyl merca tan 74-93-1 0.32 08 98 Methylene chloride 75-09-2 10.01 08 98 Perchloroeth lene tetrachloroeth lene 127-18-4 6.87 08 98 Propylene dichloride 78-87-5 0.09 08 98 Tetrachloroethane 1 1 2 2— 79-34-5 0.41 08 98 Toluene 108-88-3 12.19 08 98 Trichloroeth lene 79-01-6 3.11 08 98 Vinyl chloride 75-01-4 2.34 08 98 Vin lidene chloride 75-35-4 0.31 08 98 X lene 1330-20-7 9.17 08 98 F- 12 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or IES-04 Emission Source Group ID 2. Emission Source Description: Diesel engines for miscellaneous landfill support 3. Operating Scenario ID/Description: OS—4/No. 2 fuel oil—diesel engines for miscellaneous landfill support 4. SCC Number/Description: 20200401/Diesel;Diesel 5. Throughput/units in 2015: 60000 GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description (as listed inpermit) 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) RP—DIESEL FUGITIVE(NO 1 72 Area= 1 miscellaneous diesel STACK) engines 13 I Operating Scenario: OS—4 Emission Source/Group ID:IES-04 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% �015 V015 1 �015 �015 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG GHG Estimation Efficiency Emission Pollutants CAS Ef Control Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2015 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Po`lu►QS) Code Pollutants Method Code (Net after Factor Ef Control Pollutants (Tons/Year) (See Instructions) all controls) 2015 CO CO 1.47 08 NOx NOx 6.84 08 TSP TSP 0.05 08 PM10 PM10 0.05 08 PM2.5 PM2.5 0.05 08 S02 S02 0.45 08 SG A$ VOC VOC 0.55 08 Emission Control HAP/TAP CAS Emissions Estimation Efficiency Emission Pollutants (In HAP/TAPS y EF Control (see instructions Alphabetical Order) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2015 Acetaldehyde 75-07-0 2.4 08 Acrolein 107-02-8 0.3 08 Benzene 71-43-2 2.9 08 Butadiene 13— 106-99-0 0.1 08 Formaldehyde 50-00-0 3.6 08 Polycyclic Organic Matter(Inc PAR, dioxins,etc.NC AP 42 POM 74.1 08 historic amorphous lob Toluene 108-88-3 1.3 08 X lene 1330-20-7 0.9 08 14 15 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County :Bertie DAQ Region :WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or IES-05 Emission Source Group ID 2. Emission Source Description: Welding operations 3. Operating Scenario ID/Description: OS—3/maintenance shop welding rods 4. SCC Number/Description: 30900500/Metal Work—Welding;General 5. Throughputlunits in 2015: 5000 LB/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) ectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 16 Operating Scenario: OS—3 Emission Source/Group ID: IES-05 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 1 ) Days per Week ( 5 ) Weeks per Year ( 50 ) 11.Typical Start&End Times For Operating Scenario: Start: 900 End: 1000 12. Seasonal Periods Percent Annual Throughput: �an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% 015 1 P015 �015 �015 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor (Tons/Year) See Instructions all controls 2015 Criteria Emissions— Emission Control (NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control Pollutants Code Pollutants Method Code (Net after Factor (Tons/Year) (See Instructions) all controls) 2015 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 08 HAP/TAP Emissions Emission Control CAS Estimation Efficiency Emission Pollutants (In Alphabetical HAP/TAPS EF Control Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2015 Manganese Unlisted Compounds(Specify MNC—Other 101 08 Component of MNC 17 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region :WARD North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or IES-06 Emission Source Group ID 2. Emission Source Description: Diesel storage tank 3. Operating Scenario ID/Description: OS—6/diesel storage tank 4. SCC Number/Description: 39090004/Fuel Storage—Fixed Roof Tanks ;Distillate Oil(No. 2): Working Loss 5. Throughput/units in 2015: 148697 GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) 1—I FUGITIVE(NO 1 72 Area= 1 fugitive STACK 18 Operating Scenario: OS—6 Emission Source/Group ID: IES-06 10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 600 End: 1600 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% �015 015 �015 �015 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor (Tons/Year) See Instructions all controls 2015 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Po�► Code Pollutants Method Code Ef Control Pollutants an (Net after Factor (Tons/Year) (See Instructions) all controls) 2015 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 SO2 SO2 08 VOC VOC 0 08 HAP/TAP Emissions Emission Control CAS Estimation Emission Pollutants (In (see instructions) HAP/TAPS Method Code Efficiency Factor EF Control Alphabetical Order) (Pounds/Year) (Net after all controls) See Instructions 2015 19 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2015 1. Emission Source ID(from permit)or IES-07 Emission Source Group ID 2. Emission Source Description: One leachate storage tank 3. Operating Scenario ID/Description: OS—2/temporary storage of collected leachate 4. SCC Number/Description: 40714698/Fixed Roof Tanks—Miscellaneous ; Specify In Comments: Working Loss 5. Throughput/units in 2015: 7066317 GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 20 Operating Scenario: OS—2 Emission Source/Group ID: IES-07 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2015) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 250yo une—Aug. 25% ept.—Nov. 25% O15 015 �015 �015 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2015 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission co�Qs) Code Pollutants Method Code Ef Control lltt Pollutants (Net after Factor (Tons/Year) (See Instructions) all controls) 2015 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0.02 08 HAP/TAP Emissions Emission Control Pollutants (In Alphabetical CAS HAP/TAPS Estimation Efficiency Emission EF Control Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2015 Benzene 71-43-2 0.29 08 Eth (benzene 100-41-4 0.34 08 Methyl ethyl ketone 78-93-3 17.69 08 Methyl isobutyl ketone 108-10-1 0.29 08 Methylene chloride 75-09-2 0.15 08 Toluene 108-88-3 0.94 08 X lene 1330-20-7 0.77 08 21 Facility Total CY 2015 Emissions Summary COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bettie DAQ Region :WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2015 Record Facility-Wide Totals From all Permitted and Non-Permitted Air Pollutant Emission Sources Green House Gases Pollutants(GHG) Actual Emissions Tons/Year Pollutant CAS 2015 2014 % Chan e Criteria Pollutants Actual Emissions Tons/Year Pollutant CAS 2015 2014 % Change CO CO 121.64 111.33 9,260754% NOx NOx 28.92 27.03 6.9922285% PM TSP TSP 5.46 5 9.200001% PM 10 PM 10 5.46 1 5 9.200001% PM2.5 PM2.5 5.46 5 9.200001% S02 S02 2.73 3.58 -23.743015% VOC VOC 12.38 11.87 4.296548% Hazardous Air Pollutants HAPS and/or Toxic Air Pollutants TAPs Actual Emissions Pounds/Year Pollutant I CAS 2015 2014 % Change Pollutant Grou :Man anese compounds G oup Sum:101 Manganese Unlisted Compounds(Specify MNC-Other 101.0 101 0.0% Component of MNC Pollutant Grou :Mercu Compounds-all total mass inc Hg Vapor Group Sum:.26 Mercury,vapor(Component of HGC 7439-97-6 0.26 1 .24 8.333331% Pollutant Grou :Total Reduced Sulfur TRS as total mass Gr up Sum:989.44 Hydrogen sulfide 7783-06-4 918.4 879.52 4.4205937% Methyl merca tan 74-93-1 71.04 68.03 4.424522% Acetaldehyde 75-07-0 2.4 2.4 0.0% Acrolein 107-02-8 0.3 .3 0.0% Acrylonitrile 107-13-1 2.18 2.09 4.3062277% Benzene 71-43-2 89.97 86.36 4.1801767% Butadiene 1 3- 106-99-0 0.1 1 .1 0.0% CFC-12 ichlorodifluoromethane 75-71-8 253.75 242.62 4.587423% Carbon disulfide 75-15-0 27.84 26.66 4.426108% 22 Carbon tetrachloride 56-23-5 1.29 1.23 4.878044% Carbonyl sulfide 463-58-1 12.57 12.03 4.4887776% Chlorobenzene 108-90-7 30.62 29.29 4.5407987% Chloroform 67-66-3 3.01 2.88 4.5138845% Dichlorobenzene 1,4- 106-46-7 283.13 270.72 4.5840735% Ethyl benzene 100-41-4 824.08 789.28 4.40908% Ethyl chloride chloroethane 75-00-3 18.48 17.67 4.584038% Ethyl merca tan 75-08-1 96.29 92.22 4.413359% Ethylene dibromide 106-93-4 10.36 9.91 4.540866% Ethylene dichloride 1 2-dichloroethane 107-06-2 14.23 13.61 4.5554733% Ethylidene dichloride 75-34-3 87.9 82.59 6.429356% 1 1-dichloroethane Formaldehyde 50-00-0 3.6 3.6 0.0% Hexane n- 110-54-3 228.91 219.22 4.420218% Hydro en chloride(hydrochloric acid 7647-01-0 5015.4 4585.2 9.382354% Methyl chloride 74-87-3 15.08 14.41 4.6495495% Methyl chloroform 71-55-6 26.87 25.69 4.593228% Methyl ethyl ketone 78-93-3 887.77 854.62 3.8789198% Methyl isobutyl ketone 108-10-1 86.15 82.58 4.32308% Methylene chloride 75-09-2 345.77 330.65 4.5728097% Perchloroeth lene tetrachloroeth lene 127-18-4 237.11 226.72 4.582745% Polycyclic Organic Matter(Inc PAH, dioxins,etc.NC AP 42 historic amorphous POM 74.1 74.1 0.0% lob Propylene dichloride 78-87-5 3.11 2.98 4.362412% Tetrachloroethane 1 1 2 2- 79-34-5 14.08 13.47 4.528579% Toluene 108-88-3 2677.37 2564.32 4.408578% Trichloroeth lene 79-01-6 107.26 102.54 4.6030827% Vinyl chloride 75-01-4 80.68 77.14 4.5890603% Vin lidene chloride 75-35-4 10.69 10.22 4.598819% X lene 1330-20-7 2013.65 1928.63 4.4083114% 23 COPY of RECORD Date Submitted: 5/6/2016 10:47:19 As entered in AERO Facility Name: East Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Comments From Facility: 24 East Carolina Environmental Landfill 201 5 Emission Inventory ATTACHMENT B DETAILED EMISSION CALCULATIONS SCS ENGINEERS SHEET 1 of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CY2015 Fugitive Landfill Emission Calculations M.VanDussen 3/15/2016 CHECKED DATE D.Greene 4/4/2016 OBJECTIVE: Calculate Fugitive Landfill Emissions. APPROACH: Use USEPA's Landfill Gas Emissions Model(LandGEM)and AP-42 equations and emission factors. SOLUTION.• (1) Methane and LFG Generation* *As calculated by LandGEM(See Section 2 of 2015 Emission Inventory Report) Estimated LFG Generation/Emission Rates Methane LFG LFG Disposal Refuse Disposal Refuse Generation Generation Fugitive Rate In-Place Rate In-Place Rates Rates Rates Year (tons/yr) (tons) (Mg/yr) (Mg) m'l/vr (cfm) (cfm) 2015 578,162 9,681,131 524,500 8,782,574 2.519E+07 3,385 846 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 yr' SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu ft/ton METRIC EQUIVALENT: 100 cum/Mg Conversions: 35.314667 cu ft per cu in 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS ENGINEERS SHEET 2 of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Re pub Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CY2015 Fugitive Landfill Emission Calculations M.VanDussen 3/15/2016 CHECKED DATE D.Greene 4/4/2016 (2) NMOC and VOC Emissions* •As calculated by LandGEM(See Section 2 of 2015 Emission Inventory Report) NMOC and VOC Generation/Emission Rates NMOC NMOC NMOC VOC VOC VOC Generation Generation Surface Fugitive Generation Generation Surface Fugitive Rates Rates Rates Rates Rates Rates Year (tonslyr) (Mg/yr) (tons/yr) (tons/yr) (Mg/yr) (tonstyr) 2015 118.44 107.45 29.61 46.19 41.90 11.55 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% AP42 DEFAULT(11/98)VOC CONTENT OF NMOC: 39% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 yr' SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu ft/ton METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35314667 cu ft per cu to 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS EVANEERS SHEET 3 A 4 CLIENT PROJEUI East Carolina Environmental I,roll ill JOB NO. R ublic Services CY2015 Air Emissions Invenw 02209360.16 SUBJECT BY DATE CY2015 Fugitive Landfill Emission Calculations M.VanDussen 3/15/2016 CHECKED DATE D.Greene 4/4/2016 (3) Ila/aidaus 4ir Pollutant(HAPs) Emissions Methane Production= 25,187,440 m'/yr (As caculated by LandGEM,see"Estimated LFG Generation/Emission Methane Content of LFG= 50% Rates"table on page 1.) Assumed Collection Efficiency= 75% Fugitive LFG Production= (25,187,440 m3/yr/0.5)*(1-0.75)=12,593,720.07 m'/yr Example 1,1,1-trichloroethane Molecular Weight= 133.41 g/gmol Concentration= 0.168 ppmv Waste Industry Air Coalition(WIAC);2001 QIJJMchl...d ,"= (12,593,720.07 m3/yr)*(0.168 ppmv/1E+06)= 2.12 ms/yr UMi,i,1.m hj.,ocd M= (2.12 m3/yr)*[(133.41 g/gmol*1 atm)/(8.205E-5 m3-atm/gmol-K*1,000 g/kg*(273+25 K))]= UMIJ,I_Mhior"cd�= 11.54 kg/yr UMj,,,j_n;chj",a,h, = (11.54 kg/yr)*(2.2 lb/kg)= 25.40 Ib/yr 1,1,1-trichloroethane M= (25.40lb/yr)/(2,000lb/ton)= 1.27E-02 ton/yrl,l,l-trichloroethane SCS ENGINEERS SHEET 4 of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Re ublic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CY2015 Fugitive Landfill Emission Calculations M.VanDussen 3/15/2016 CHECKED DATE D.Greene 4/4/2016 (3)HAP Emissions,continued 2015 Methane Generation(mr/yr)= 25,187,440 2015 LFG Generation(ma/yr)= 50,374,880 2015 LFG Fugitive Production(ma/yr)= 12,593,720 Landfill Gas Temperature(4C)t= 25 Pollutant Mot.Wt. Conc.3 Q(P)4 ' F ( y' ' k U s/ M (g/gmol) (ppmv) m/ ( gyr) (lb/yr) (ton/yr) (Ib 1,1,1-trichloroethane TAP,HAP 133.41 0.168 2.12 11.54 25.40 1.27E-02 25.40 1.27E-02 1,1,2,2-tetrachloroethane TAP,HAP 167.85 0.070 0.88 6.05 13.31 6.66E-03 13.31 6.66E-03 I,1-dichloroethane TAP,HAP 98.97 0.741 9.33 37.77 83.10 4.16E-02 83.10 4.16E-02 1,1-dichloroetheneTAP'HAP 96.94 0.092 1.16 4.59 10.11 5.05E-03 10.11 5.05E-03 1,2-dichloroethane TAP,HAP 98.96 0.120 1.51 6.12 13.46 6.73E-03 13.46 6.73E-03 1,2-dichloro ro aneHAP 112.99 0.023 0.29 1.34 2.94 1.47E-03 2.94 1.47E-03 acrylonitrile TAP'HAP 53.06 0.036 0.45 0.98 2.16 1.08E-03 2.16 1.08E-03 benzene TAP•HAP 78.11 0.972 12.24 39.10 86.03 4.30E-02 86.03 4.30E-02 carbon disulfide TAP'HAP 76.13 0.320 4.03 12.55 27.60 1.38E-02 27.60 1.38E-02 carbon tetrachloride TAP'HAP 153.84 0.007 0.09 0.55 1.22 6.10E-04 1.22 6.10E-04 carbonyl sulfide HAP 60.07 0.183 2.30 5.66 12.46 6.23E-03 12.46 6.23E-03 chlombenzene TAP,MP 112.56 0.227 2.86 13.16 28.95 1.45E-02 28.95 1.45E-02 chloroethaneTAP'HAP 64.52 0.239 3.01 7.94 17.47 8.74E-03 17.47 8.74E-03 chloroform TAP'HAP 119.39 0.021 0.26 1.29 2.84 1.42E-03 2.84 1.42E-03 chlororrethane TAP'HAP 50.49 0.249 3.14 6.48 14.25 7.12E-03 14.25 7.12E-03 dichlorobenzene TAP,RAP 147.00 1.607 20.24 121.67 267.68 1.34E-01 267.68 1.34E-01 dichlorodifluoromethane TAP 120.91 1.751 22.05 109.05 239.90 1.20E-01 239.90 1.20E-01 dichloromethane TAP,HAP 84.94 3.395 42.76 148.53 326.76 1.63E-01 326.76 1.63E-01 ethyl mercy tan TAP 62.13 1.356 17.08 43.39 95.46 4.77E-02 95.46 4.77E-02 eth IbenzeneHAP 106.16 6.789 85.50 371.22 816.67 4.08E-01 816.67 4.08E-01 ethylene dibromide TAP'HAP 187.88 0.046 0.58 4.45 9.79 4.90E-03 9.79 4.90E-03 hexane TAP.MP 86.18 2.324 29.27 103.16 226.95 1.13E-01 226.95 1.13E-01 hydrogen sulfide TAP 34.08 23.578 296.93 413.87 910.52 4.55E-01 910.52 4.55E-01 mercury and compounds TAP'HAP 200.61 2.92E-04 3.68E-03 3.02E-02 6.64E-02 3.32E-05 6.64E-02 3.32E-05 methyl ethyl ketone TAP 72.11 10.557 132.95 392.10 862.62 4.31E-01 862.62 4.31E-01 methyl isobu IketoneTAP.MP 100.16 0.750 9.45 38.69 85.12 4.26E-02 85.12 4.26E-02 methyl mercy tan TAP 48.11 1.292 16.27 32.02 70.43 3.52E-02 70.43 3.52E-02 perchloroethylene TAP,aAP 165.83 1.193 15.02 101.90 224.17 1.12E-01 224.17 1.12E-01 toluene TAP'HAP 92.13 25.405 319.94 1,205.53 2,652.17 1.33E+00 2,652.17 1.33E+00 trichloroetIt leneTAP,HAP 131.40 0.681 8.58 46.09 101.40 5.07E-02 101.40 5.07E-02 vin I chloride TAP'HAP 62.50 1.077 13.56 34.67 76.27 3.81E-02 76.27 3.81 E-02 x lenesTAP,RAP 106.16 16.582 208.83 906.69 1,994.71 9.97E-01 1,994.71 9.97E-01 Total HAPs Only --- --- 797.40 3,237.76 7,123.08 3.56 7,123.08 3.56 Notes: I.The landfill gas temperature was obtained from AP42 Page 2.4-5. 2. The AP-42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Pollutant concentrations Waste Industry Coalition(WIAC-2001) . Q(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3). 5 and 6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). "?denotes compounds that are classified as toxic air pollutants per the North Carolina Department of Environmental Quality,Division of Air Quality(DAQ). o'denotes compounds that are classified as hazardous air pollutants per AP-42 and CAA Section 112. "The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112. SCS ENGINEERS SHEET 1 of 5 ( LIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services I CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CD-Flare 1 Emission Calculations M.VanDussen 3/16/2016 NOx,CO,PM CHECKED DATE D.Greene 4/4/2016 OBJECTIVE: Calculate flare emissions based on LEG consumption. LEG Consumption: 602,341,762 scf/yr(CY2015) LEG Heat Content: 506 Btu/scf(assumed at 50%CH4) Calculated MMBTU: 304,785 MMBtu/yr(CY2015) APPROACH: Use manufacturer data and AP42 equations and emission factors. SOLUTION: (1)NOx Emissions NO,Emission Factor= 0.068 lb/MMBtu (AP42,Table 13.5-1) LEG Consumed= 304,785 MMBtu/yr CMNo,= (0.068 lb/MMBtu)*(304,785 MMBtu/yr)= 20,725.38 Ib/yr NOx CMNN= (20,725.38 Ib/yr)/(2,000 lb/ton)= 10.36 ton/yr NOx (2)CO Emissions CO Emission Factor= 0.37 lb/MMBtu (AP42,Table 13.5-1) LEG Consumed= 304,785 MMBtu/yr CMco= (0.37 Ib/MMBtu).(304,785 MMBtu/yr)= 112,770.42 Ih/yr CO CMco= (112,770.42 lb/yr)/(2,000 lb/ton)= 5639 ton/yr CO (3)PM Emissions PM Emission Factor= 17 Ib/106 ft3 CH4 (AP-42,Section 2.4,Table 2.4-5) LFG Consumed= 304,785 MMBtu/yr HHV of Methane= 1,020 Bm/ft3 (AP42,Section 3.2) Equivalent Amount of CH4 Consumed:(304,785 MMBtu/yr)/(1,020 MMBtu/106 ft3)= 298.81 x 106 ft3 CH4 CMPM= (17 lb/10^6 ft3 CH4)•(298.81 x 10^6 ft3 CH4)= 5,079.75 Ib/yr PM CMPM= (5,079.75 Ib/yr)/(2,000 lb/ton)= 1 2.54 ton/yr PM SCS ENGINEERS SHEET 2 of s ('1 11[NT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions hrvento 02209360.16 S1 BJ1lCT BY DATE CD-Flare 1 Emission Calculations M.VanDussen 3/15/2016 NMOC,VOC CHECKED DATE D.Greene 4/4/2016 (4)NMOC Emissions -Use the default concentration of NMOC(as hexane)from AP42 Table 2.4-2. The default NMOC concentration is 595 ppmv. -Use Equations(3),(4),&(5)of AP42,Section 2.4 to determine NMOC emissions. Molecular Weight of Hexane= 86.18 g/gmol LEG Consumed= 304,785 MMBtu/yr HH V of Landfill Gas= 506 Btu/$' Amount of Landfill Gas Consumed=(304,785 MMBtu/yr)/(506 MMBtu/MM ft3): 602.34 x 101 ft3 LEG Eqn(3) QNMoc= (602,34 x 10A6 ft3 LFG)*(1 m3/35.3198 ft3)*(595 ppmV/IOA6)= 10,147.09 m'/yr Eqn(4) UMNMoc= (10,147.09 m3/yr)*[(86.18 g/gmol*1 atm)/(8.205E-5 m3-atm/gmol-K*1,000 g/kg*(273+25 K))]_ UMNMOC= 35,764.60 kg/yr Eqn(5) CM,,MOC= [35,764.60 kg/yr*(I-NCOUI00)]+(35,764.60 kg/yr)*(NCOUI00)*(1-NCNT/100)] NCOt=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. NcNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP-42 Table 2.4-3). CMNMOC= [(35,764.60 kg/yr)*(1-100/100)]+(35,764.60 kg/yr)*(100/100)*(1-99.2/100)]= 286.12 kg<r CMs,,,oc= (286.12 kg/yr)*(2.2 lb/kg) = 1 629.46 Ib/yr NMOC CMNMoc= (629.46 lb/yr)/(2,000 lb/ton)= 0.31 ton/yr NMOC (5)VOC Emissions -Use Note"c"from Table 2.4-2. The default V OC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexane). CMvoc= 629.46 Ib/yr NMOC*0.39= 245.49 Ib/yr VOC CMvoC= 0.31 ton/yr NMOC*0.39= 0.12 ton/yr VOC SCS ENGINEERS SHEET 3 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CD-Flare 1 Emission Calculations M.VanDussen 3/15/2016 SO„Uncombusted HAPs CHECKED DATE D.Greene 4/4/2016 (6)SOr Emissions -Use Equations(3),(4),&(7)from AP42 Section 2A to determine SO,emissions. H;S Concentration= 23.578 ppmv WIAC 2001 Molecular Weight of Sulfur(S)= 32 g/gmol Molecular Weight of Hydrogen Sulfide(H, 34 g/gmol HHVof Landfill Gas= 506 Btu/ftt LFG Consumed= 304,785 MMBtu/yr Amount of Landfill Gas Consumed=(304,785 MMBm1yr)/(506 MMBtu/MM 113)= 60234 V xI06 ftx LFG Eqn(3) / QH2s= (602.34 x 1 V6 ft3)•(m3/35.3198 ft3)*(23.6 ppmv H2S/I V6)= 402.10 tut H2S Qs= (402.10 m3 H2S/yr)•(32 g/gmol S/34 g/gmol H2S)= 378.44 to S Eqn(4) UMs= (378.44 m3/yr)*[(32 g/gmol*1 atm)/(8205E-5 m3-atm/gmol-K*1,000 g/kg*(273+25 K))]_ UMs= 495.29 kg S/yr Eqn(7) CMso2_(495.29 kg S/yr)*(NCOL/100)*2.0*(98%conversion efficiency of S to SO2) Nrot=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. CMso,=495.29 kg S*(100/100)*2.0*0.98= 970.76 kg/yr CMso,_(0,970.76 kg)*(2.2 Mg)= 2,135.68 Ib/yr SO, CMso,_(2,135.68 Ih/yr)/(2,000 lb/ton)= 1.07 ton/}r tiO, (7) Hazardous Air Pollutant(HAPs)Emissions -HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs are substituted into the equations. See Table 3 for a summary of flare HAP emissions. Example L 1,1-trichloroethane Molecular Weight= 133.41 g/gmol Concentration= 0.168 ppmv Waste Industry Air Coalition(WIAC);2001 Qi.i.imauaam.�o- (602.34 x IE+06 113 LFG)'(m3/35.3198 ft3)*(0.168 ppmv/1E+06)= 2.97 mt/yr (2.87 m3/yr)*[(133.41 g/gmol*1 arm)/(8.205E-05 m3-atm/gmol-K*1,000 g(kg*(273+25 K))] CMt,i,i� = 15.63 kg/yr 1,1,1-trichloroethane CMi,1,1.�ad = (15.63 kg/yr)*(2.21btkg)*(ton/2,000lb)= 1.72E-02 ton 1,1,1-trichloroethane to Bare 1,1,1-trichloroethane= CMi.1,1_a;,.w,,„� (tons/yr)•(I-NCNT/100) N,,=98%destruction efficiency(AP-42 Table 2.4-3) I,l,l-trichloroethane- (0.0172 ton/yr)*(1-(98/100))= 3.44F:04 ton 1,1,1-trichloroethane to atmosphere SCS ENGINEERS SHEET 4 of 5 CLIE.N"f PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT CD-Flare I Emission Calculations B1y pDATEVanDussen 3/15/2016 Uncombusted HAPs CHECKED DATE D.Greene 4/4/2016 (7)HAP Emissions,continued 2015 LFG Consumption(MMBtu/yr)= 304,785 HHV of LFG(Btu/fe) 506 2015 LFG Consumption(ft3/yr)= 602,341,762 2015 LFG Consumption(m3/yr)= 17.053,940 Landfill Gas Temperature ec)r= 25 Halogenated Destruction Eff.(%)z= 98.0% Non-Halogenated Destruction Eff.(%)r= 99.7% 3lercury Compound Destruction Eff.(%)l= 0.0% Pollutant* Mol.Wt. Conc.3 Q(p)' UM s CD-Flare 1 (g/grnol) (PPmv) n r (kg/yr) (lb/yr) (lb/yr) (ton/yr) 1-I.I-trichlomethane TAP IMP 133.41 0.168 2,87 15.63 34.39 0.69 3.44E-04 1.1,2.2-tetrachlomethane TAP.IMP 167.85 0.070 1.19 8.20 18.03 0.36 1.80E-04 1,1-dichloroethane TAP,MP 98.97 0.741 12.64 51.15 112.53 2.25 1.13E-03 1.1-dichlomethene TAP.11AP 96.94 0.092 1.57 6.22 13.68 0.27 1.37E-04 1.2-dichloroethane TAP.1 98.96 0.120 2.05 8.28 18.22 0.36 1.82E-04 I.2-dichloropmpancHAP 112.99 0.023 0.39 1.81 3.99 0.08 3.99E-05 acrylonitrileT"P'""P 53.06 0.036 0.61 1.33 2.93 0.01 4.40E-06 benzene TAP.HAP 78.11 0.972 16.58 52.95 116.50 0.35 1.75E-04 carbon disulfide TAP.HAP 76.13 0.320 5.46 16.99 37.38 0.11 5.61E-05 carbon tetrachloride TAP.H"P 153.84 0.007 0.12 0.75 1.65 0.03 1.65E-05 carbonyl sulfide HAP 60.07 0.183 3.12 7.67 16.87 0.05 2.53E-05 chlombenzeneT",' 112.56 0.227 3.87 17.82 39.21 0.78 3.92E-04 chloroethane TAP.HAP 64.52 0.239 4.08 10.76 23.66 0.47 2.37E-04 chloroform TAP.HAP 119.39 0.021 0.36 1.75 3.85 0.08 3.85E-05 chloromethane TAP.HAP 50.49 0.249 4.25 8.77 19.29 0.39 1.93E-04 dichlorobenzew TAP.HM 147.00 1.607 27.41 164.76 362.48 7.25 3.62E-03 dichloroditluoromethane TAP 120.91 1.751 29.86 147,67 324.86 6.50 3.25E-03 dichloromethane TAP.W 84.94 3.395 57.90 201.13 442.49 8.85 4.42E-03 ethyl merca tan TAP 62.13 1.356 23.13 58.76 129.27 0.39 1.94E-04 eth (benzene HAP 106.16 6.789 115.78 502.69 1,105.91 3.32 1.66E-03 ethylene dibromide TAP.HAP 187.88 1 0.046 0.78 6.03 13.26 0.27 1.33E-04 hexane TAP.HAP 86.18 2.324 39.63 139.69 307.32 0.92 4.61E-04 hydrogen chloride TAP.HAP a 35.45 42.0 N/A N/A N/A 2,353.38 1.18E+00 hydrogen sulfide TAP 34.08 23.6 402.10 560.45 1,232.99 3.70 1.85E-03 mercury and compounds TAP.HAP 200.61 2.92E-04 4.98E-03 4.09E-02 8.99E-02 8.99E-02 4.49E-05 methyl ethyl ketone TAP 72.11 10.557 180.04 530.97 1,168.12 3.50 1.75E-03 methyl isobutyl ketone TM.H"P 100.16 0.750 12.79 52.39 115.27 0.35 1.73E-04 methyl merca tan TAP 48.11 1.292 22.03 43.35 95.38 0.29 1.43E-04 perchlometh lene TAP.HAP 165.83 1.193 20.35 137.99 303.57 6.07 3.04E-03 toluene TAP.HAP 92.13 25.405 433.26 1,632.49 3,591.47 10.77 5.39E-03 trichlometh lene TAP.HAP 131.40 0.681 11.61 62.41 137.31 2.75 1.37E-03 vinyl chloride TAP.W 62.50 1.077 18.37 46.95 103.29 2.07 1.03E-03 x lens TAP.HAP 106.16 16.582 282.79 1227.80 2,701.16 8.10 4.05E-03 Total HAPs Only --- --- -- 4,384.46 9,645.81 2.410.47 1.21 Notes: I.The landfill gas temperature was obtained from AP42 Page 2.4-5, 2. The AP42 Section 2.4 default for Flare Destruction EfHciarcy,was assumed. 3. Pollutant concentrations used to compute the estimated emissions are from Waste Industry Coalition(W IAC-2001):HIS referenced from AP42 4.Q(p)=Volumetric minion rate of the pollutant. AP42 Section 2.4 equation(3). 5. UM(p)=Uncontrolled mass missions of pollutant.If no collection exists,this is also equal to the fugitive emission rate.FM(p)of the pollutant.AP42 equation(4). 6. HCI emissions me a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation shears. "r denotes compounds that are classified as toxic air pollutants mpo po per the North Carolina Department of Environmental Quality.Division of Air Quality(DAQ). °r1P denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112. 'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112. SCS ENGINEERS SHEET 5 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Invento 02209360.16 SUBJECT BY DATE CD-Flare I Emission Calculations M.VanDusset 3/152016 Uncombusted HCI CHECKED DATE D.Greene 4/42016 (8)HCI Emissions -Ilse Fquations(3),(4),&(10)from AP42 Section 2.4 to determine HCI emissions. HCI Concentration= 42.0 ppmv (AP42,Page 2.4-9) Molecular Weight of Chlorine(CI)= 35.453 g/gmol HHV of Landfill Gas= 506 Btu/ft' LEG Consumed= 304,785 MMBtu/yr Amount of Landfill Gas Consumed=(304,785 MMBtu/yr)/(506 MMBtt✓MM ft3)= 602.34 x106 fe LFG Eqn(3) QC,_ (602.34 x 10^6 ft3).(m3/35.3198 ft3) (42.0 ppmv CVI0^6)= 716.27 m}Cl Eqn(4) UMC,_ (716.27 m3).[(35.453 g/gmol s I atm)/(8.205E-5 m3-atm/gmol-K'1,000 g/kg'(273+25 K))]_ UMC,= 1,038.56 kg CI Eqn(10) CMHC,_ (1,038.56 kg CVyr)• (NCOL/100).1.03•(NCNT/100) NCoL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. NCNT=100%Assume the flare is capable of converting 100%of the Cl to HCI. CMHC,= (1,038.56kgCVyr)`(100/100)'1.03'(100/100; 1,069.72 kg/yrHCl CMHC,_ (1,069.72 kg/yr)'(2.2 lb/kg) = 1 2,353.38 Ib/yr HCI CMHC,_ (2,353.38 lb/yr)/(2,000 lb/ton)= 1.18 ton/yr HCI SCS ENGINEERS SHEET I of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CD-Flare 2 Emission Calculations M.VanDussen 3/15/2016 NOx,CO,PM CHECKED DATE D.Greene 4/5/2016 OBJECTIVE: Calculate flare emissions based on LFG consumption. LFG Consumption: 681,338,328 scf/yr(CY2015) LFG Heat Content: 506 Btu/scf(assumed at 50%CH4) Calculated MMBTU: 344,757 MMBtu/yr(CY2015) APPROACH: Use manufacturer data and AP-42 equations and emission factors. SOLUTION: (1)NOx Emissions NO,Emission Factor= 0.068 Ib/MMBtu (AP-42,Table 13.5-1) LFG Consumed= 344,757 MMBtu/yr CMNox= (0.068 Ib/MMBtu)*(344,757 MMBtu/yr)= 23,443.49 Ib/yr 10% CMNO.= (23,443.49 Ib/yr)/(2,000 lb/ton)= 11.72 ton/yr NOx (2)CO Emissions CO Emission Factor= 0.37 Ib/MMBtu (AP42,Table 13.5-1) LFG Consumed= 344,757 MMBtu/yr CMco= (0.37 lb/MMBtu)*(344,757 MMBtu/yr)= 127,560.16 Ib/yr CO CMco= (127,560.16 Ib/yr)/(2,000 lb/ton)= 63.78 ton/yr CO (3)PM Emissions PM Emission Factor= 17 Ib/106 ft3 CH4 (AP42,Section 2.4,Table 2.4-5) LFG Consumed= 344,757 MMBtu/yr HHV of Methane= 1,020 Btu/ft3 (AP-42,Section 3.2) Equivalent Amount of CH4 Consumed(344,757 MMBtu/yr)/(1,020 MMBtu/106 ft3)= 338.00 x 106 ft3 CH4 CMpM= (17 lb/10^6 ft3 CH4)*(338.00 x 10^6 ft3 CH4)- 5,745.95 Ib/yr PM CMpM= (5,745.95 lb/yr)/(2,000lb/ton)= 1 2.87 ton/yr PM SCS ENGINEERS SHEET 2 of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Invent 02209360.16 SUBJECT BY DATE CD-Flare 2 Emission Calculations M.VanDussen 3/15/2016 NMOC,VOC CHECKED DATE D.Greene 4/4/2016 (4)NMOC Emissions -Use the default concentration of NMOC(as hexane)from AP-42 Table 2.4-2. The default NMOC concentration is 595 ppmv. -Use Equations(3),(4),&(5)of AP42,Section 2.4 to determine NMOC emissions. Molecular Weight of Hexane= 86.18 g/gmol LFG Consumed= 344,757 MMBtu/yr HHVof Landfill Gas= 506 Btu/fe Amount of Landfill Gas Consumed=(344,757 MMBtu/yr)/(506 MMBtwMM f13)= 681.34 x 106 f LFG Eqn(3) Qwoc= (681.34 x 10^6 ft3 LFG)*(1 m3/35.3198 ft3)*(595 ppmv/10^6)= 11,477.88 mj/yr Eqn(4) UMwoc= (11,477.88 m3/yr)*[(86.18 g/gmol*1 atm)/(8.205E-5 m3-atm/gmol-K*1,000 g/kg"(273+25 K))]_ UMNMoc= 40,455.09 kg/yr Eqn(5) CMNMa= [40,455.09 kg/yr*(1-NCOU100)]+(40,455.09 kg/yr)*(NCOUI00)*(1-NCNT/100)] Ncot=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. NrNr=99.2% assume that the flare is capable of reducing NMOCs 99.2%by weight(AP42 Table 2.4-3). CMNMa= [40,455.09 kg/yr*(1-100/100)]+(40,455.09 kg/yr)*(100/100)*(1-99.2/100)]= 323.64 kg/yr CMNMa= (323.64 kg/yr)*(2.2 lb/kg) = 1 712.01 lb/yr NMOC CMNMa= (712.01 lb/yr)/(2,000 lb/ton)= 0.36 ton/yr NMOC (5)VOC Emissions -Use Note"c"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexane). CMva= 712.01 Ib/yr NMOC*0.39= 277.68 lb/yr VOC CMva= 0.36 ton/yr NMOC*0.39= 0.14 ton/yr VOC Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Green House Gases Pollutants (GHG) Actual Emissions Tons/Yr Pollutant CAS Demini- Change mus Not Not NSA Reported Reported CO2 equivalent(sum of individual GHG pollutant emissiol No GHGs times their 1995 IPCC Global Warming Potential (GWP), Reported converted to metric tons) Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change CO CO 121.64 111.33 0.5 9.3% NOx NOx 28.92 27.03 0.5 7.0% PM(TSP) TSP 5.46 5.00 0.5 9.2% PMIO PM10 5.46 5.00 0.5 9.2% PM2.5 PM2.5 5.46 5.00 0.5 9.2% S02 Sot 1 2.73 3.58 0.5 -23.7% VOC VOC 12.38 11.87 0.5 4.3% Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Manganese& compounds 101.00 101.00 10.0 0.0% Manganese Unlisted Compounds - Specify Compout MNC-Other 101.00 101.00 10.0 0.0% (Component of MNC) Mercury& Compounds-all total mass includes Hg Vapor 0.260000 0.240000 0,001 18.3 Mercury,vapor(Component of HGC) 7439-97-6 0.260000 0.240000 0.001 8.3% Total Reduced Sulfur(TRS as total mass) 989.44 947.55 4.4% Hydrogen sulfide 7783-06-4 918.40 879.52 1.0 4.4% Methyl mercaptan 74-93-1 71.04 68.03 1.0 4.4% Acetaldehyde 75-07-0 2.40 2.40 10.0 0.0% 09/21/2016 Page 1 of 3 2 5� 2v1 2106 1 ' ^ �3 (ak133831$�'�SJ _25U DLO 31s�°,�OL 1, 283, � L f / ks ����� �JA r'�x �ca5 Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Acrolein 107-02-8 0.300000 0.300000 10.0 0.0% Acrylonitrile 107-13-1 2.18 2.09 10.0 4.3% Benzene 71-4 i-2 89.97 86.36 1.0 4.2% Butadiene, 1,3- 106-99-0 0.100000 0.100000 1.0 0.0% Carbon disulfide 75-15-0 27.84 26.66 10.0 4.4% Carbon tetrachloride 56-23-5 1.29 1.23 1.0 4.9% Carbonyl sulfide 463-58-1 12.57 12.03 1.0 4.5% CFC-12 (Dichlorodifluoromethane) 75-71-8 253.75 242.62 100.0 4.6% Chlorobenzene 108-90-7 30.62 29.29 10.0 4.5% Chloroform 67-66-3 3.01 2.88 100.0 4.5% Dichlorobenzene(p), 1,4- 106-46-7 283.13 270.72 1.0 4.6% Ethyl benzene 100-41-4 824.08 789.28 100.0 4.4% Ethyl chloride (chloroethane) 75-00-3 18.48 17.67 10.0 4.6% Ethyl mercaptan 75-08-1 96.29 92.22 10.0 4.4% Ethylene dibromide(dibromoethane) 106-93-4 10.36 9.91 1.0 4.5% Ethylene dichloride(1,2-dichloroethane) 107-06-2 14.23 13.61 1.0 4.6% Ethylidene dichloride(1,1-dichloroethane) 75-34-3 87.90 82.59 100.0 6.4% Formaldehyde 50-00-0 3.60 3.60 10.0 0.0% Hexane, n- 110-54-3 228.91 219.22 100.0 4.4% Hydrogen chloride(hydrochloric acid) 7647-01-0 5,015.40 4,585.20 100.0 9.4% MEK(methyl ethyl ketone,2-butanone) 78-93-3 887.77 854.62 100.0 3.9% Methyl chloride(chloromethane) 74-87-3 15.08 14.41 1.0 4.6% Methyl chloroform 71-55-6 26.87 25.69 100.0 4.6% Methylene chloride 75-09-2 3451.77 330.65 1.0 4.6% MIBK (methyl isobutyl ketone) 108-10-1 86.1 82.58 10.0 4.3% Perchloroethylene (tetrachloroethylene) 127.18.4 237.1 1 226.72 100.0 4.6% 09/21/2016 Page 2 of 3 Facility Total CY 2015 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: East Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2015 CY 2014 Demini- % from ED from Fees mus Change Polycyclic Organic Matter(Inc PAH,dioxins,etc.N, poly( 74.10 74.10 1.0 0.0% &AP 42 historic) Propylene dichloride (1,2-dichloropropane) 78-87-5 3.11 2.98 10.0 4.4% WE (trichloroethylene) 79-01-6 107.26 102.54 1,000.0 4.6% Tetrachloroethane, I,1,2,2- 79-34-5 14.08 13.47 100.0 4.5% Toluene 108-88-3 2,677.37 2,564.32 100.0 4.4% Vinyl chloride 75-01-4 80.68 77.14 0.1 4.6% Vinylidene chloride 75-35-4 10.69 10.22 0.1 4.6% Xylene (mixed isomers) 1330-20-7 2,013.65 1,928.63 100.0 4.4% Largest Individual HAP Hydrogen chloride (hydrochloric acid) 5,015.40 lbs Total HAP Emissions 2,449.55 lbs DAO's Comments Rmardina Inventory 09/21/2016 Page 3 of 3 SCS ENGINEERS SHEET 3 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory02209360.16 SUBJECT BY DATE CD-Flare 2 Emission Calculations M.VanDussen 1 3/15/2016 SO,Uncombusted HAPs CHECKED DATE D.Greene 4/5/2016 (6)SO=Emissions -Use Equations(3),(4),&(7)from AP42 Section 2.4 to determine SO,emissions. / - - 20� S w i3 H2S Concentration= _23.M_ ppmv I WIAC2001 �I Molecular Weight of Sulfur(S)= 32 g/gmot - Molecular Weight of Hydrogen Sulfide(H,! 34 g/gmol HHVof Landfill Gas= 506 Btu/ft3 LFG Consumed= 344,757 MMBtu/yr Amount of Landfill Gas Consumed=(344,757 MMBtu/yr)/(506 MMBtu/MM 0 68134 x106 ft3 LFG Eqn(3) Qrus= (681.34 x 10^6 ft3) (m3/35.3198 ft3)*(23.6 ppmv H2S/1V6)= 454.83 m3 H,S Qs= (454.83 m3 H2S/yr)*(32 g/gmol S/34 g/gmol H2S)= 428.08 m3 S Eqn(4) UMs= (428.08 m3/yr)•[(32 g/gmol*I atm)/(8.205E-5 m3-atm/gmol-K*1,000 gfkg*(273+25 K))]_ UMs= 560.24 kgS/yr Eqn(7) CMso,_(560.24 kg S/yr)*(NCOU100)*2.0*(98%conversion efficiency of S to SO2) Nco.=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. CMso,_(560.24 kg S/yr)*(100/100)*2.0*0.98= 1,098.08 kg/yr CMso,_(1,098.08 kg)*(2.2lb/kg)= 1 2,415.78 Ib/yr SO, CMso,_(2,415.781b/yr)/(2,000 lb/ton)= 1.21 ton/yr SO, (7) Hazardous Air Pollutant(HAPs)Emissions -HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs are substituted into the equations. See Table 3 for a summary of flare HAP emissions. Example 1,1.1-1 rich loroethane Molecular Weight= 133.41 g/gmol Concentmtion= 0.168 ppmv Waste Industry Air Coalition(WIAC);2001 Ql.�.imwuoalunc= (681.34 x 1E+06 ft3 LFG)*(m3/35.3198 0)*(0.168 ppmv/1 E+06)= 3.24 m3/yr (3.24 m3/yr)*[(133.41 g/gmol*1 arm)/(8.205E-05 m3-atm/gmot-K"1,000 g/kg*(273+25 K))] CMi,t,i v;r i� 17.68 kg/yr 1,1,1-trichloroethane CMt.i.t amtw,n.oe= (17.68 kg/yr)•(2.2 lh(kg)*(ton/2,000 lb)= 1.95E-02 ton 1,1,1-trichloroethane to flare 1,1,1-trichloroethane= CMI,1,1-,ad ,,,d„e(ton/yr)*(1-NCNT/100) N,,=98%destruction efficiency(AP42 Table 2.4-3) l,l,l-trichloroethane= (0.0195 ton/yr)*(I-(98/100)) 3.8911-04 ton 1,1,1-trichlorocthanc to atmosphere SCS ENGINEERS SHEET 4 of 5 CLIENT PROJECT East Carolina Environmental landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CD-Flare 2 Emission Calculations M.VanDussen 3/15/2016 Uncombusted HAPs CHECKED DATE D.Greene 4/4/2016 (7)HAP Emissions,continued 2015 LFG Consumption(MMBta/yr)= 344,757 HHV of LFG(Btu/fts) 506 2015 LFG Consumption(ffr/yr)= 681,338,328 2015 LFG Consumption(ma/yr)= 19,290,549 Landfill Gas Temperature ec)r= 25 Halogenated Destruction Eff.(%)_= 98.0% Non-Halogenated Destruction Etf.(%)_= 99.7% Mercury Compound Destruction Elf.(%)r= 0.0% Pollutant Mol.Wt. Cone.' Qlpl' UM( )' CD-Flare2 (g/gmol) (Ppmv) (in''vr) (kg/yr) (lb/yr) (16;vr) (ton/yr) 1.1,1-trichloroethane'"' "" 133.41 0.168 3.24 17.68 38.90 0.78 3.89E-04 1.1,22-tetrachlonaethane uv'tw 167.85 0.070 1.35 9.27 20.39 0.41 2.04E-04 I.I-dichloroethane T"'rue 98.97 0.741 14.29 57.86 127.29 2.55 1.27E-03 I,1-dichloroethenc`fm "" 96.94 0.092 1.77 7.04 15.48 0.31 1.55E-04 1.2-dichloroethaner"'rr"" 98.96 0.120 2.31 9.37 20.61 0.41 2.06E-04 1.2-dichlo ro anetr"P 112.99 0.023 0.44 2.05 4.51 0.09 4.51E-05 ac lonitrile T"r'HAe 53.06 0.036 0.69 1.51 3.32 0.01 4.97E-06 benzene I",rue 78.11 0.972 18.75 59.90 131.78 0.40 1.98E-04 carbon disulfide T"'n" 76.13 0.320 6.17 19.22 42.28 0.13 6.34E-05 carbon tetrachloride T""'HAP 153.84 0.007 0.14 0.85 1.87 0.04 1.87E-05 carbonyl sulfide rwr 60.07 0.183 3.53 8.67 19.08 0.06 2.86E-05 chlorobenzene Tm.]W 112.56 0.227 4.38 20.16 44.35 0.89 4.43E-04 chloroethane T""'u"" 64.52 0.239 4.61 12.17 26.76 0.54 2.68E-04 chloroform r"'n" 119.39 0.021 0.41 1.98 4.35 0.09 4.35E-05 chlommethane T"JIM 50.49 0.249 4.80 9.92 2L82 0.44 2.18E-04 dichloroberzenei"'f1dY 147.00 1.607 31.00 186.37 410.02 8.20 4.10E-03 dichlorodifiuoromethane rAe 120.91 1.751 33.78 167.03 367.47 7.35 3.67E-03 dichloromethane r".1W 84.94 3.395 65.49 227.51 500.52 10.01 5.01E-03 ethyl mercy ran r"" 62.13 L356 26.16 66.47 146.23 0.44 2.19E-04 ethylbenzene xAP 106.16 6.789 130.96 568.61 1250.95 3.75 1.88E-03 ethylene dibMMide T".1 187.88 0.046 0.89 6.82 15.00 0.30 1.50E-04 hexane TM.UM 86.18 2.324 44.83 158.01 347.63 1.04 521 E-04 h dro ren chloride I",HAP 7 35.45 42.0000 N/A N/A N/A 2.662.02 1.33E+00 hydrogen sulfide TAP 34.08 23.578 454.83 633.95 1.394.69 4.18 2.09E-03 inercury and compounds T""'n"" 200.61 2.92E-04 5.63E-03 4.62E-02 1.02E-01 1.02E-01 5.08E-05 methyl ethyl ketone T" 72.11 10.557 203.65 600.60 1321.32 3.96 1.98E-03 methyl isobutyl ketone T""'rr"" 100.16 0.750 14.47 59.27 130.39 0.39 1.96E-04 meth lineica tan 1" 48.11 1.292 24.92 49.04 107.89 0.32 1.62E-04 pemhloroeth Iene T".1W 165.83 1.193 23.01 156.08 343.38 6.87 3.43E-03 toluene T"'rr"" 92.13 25.405 490.08 1846.59 4062.49 12.19 6.09E-03 trichlorneth Iene T".FIAP 131.40 0.681 13.14 70.60 155.32 3.11 1.55E-03 vinyl chloride'AP,HAP 62.50 1.077 20.78 51.11 116,83 2.34 1.17E-03 xvlenes TAe 1A 106.16 16.582 319.88 1388.81 1055.42 9.17 458E-03 total HAPs Onh -- -- --- 4,959.48 10,910.85 2.726.60 136 Notes: 1.The landfill an temperature was obtained from AP42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3.Flow rate in CY2015. 4.Pollutant concentrations used to compute the estimated emissions an:from Waste Industry Coalition(WIAC-2001) 5. Q(p)=Volumetric emission rate of the pollutant. AP42 Section 2.4 equation(3). 6.UM(p)=Uncontrolled mass emissions of pollutant If no collection exists,this is also equal to the fugirive emission rate,FM(p)of the pollutant AP42 equation(4). 7. HCI emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation sheets. I''P denotes compounds that are classified as toxic air pollutants per the North Carolina Department of Environmental Quality,Division of Air Quality(DAQ). n,v1 denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section It 2. 'The compounds listed above were compiled from AP-42 frerised Nor_1009)and CAA Section 112. SCS ENGINEERS SHEET 5 0l' CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Invert 02209360.16 S1113.11:("f BY DATE CD-Flare 2 Emission Calculations M.VanDussen 3/15/2016 Uncombusted HCI CHECKED DATE D.Greene 4/4/2016 (8)IICI Emissions -Use Equations(3),(4),&(10)from AP42 Section 2.4 to determine HCI emissions. HCI Concentration= 42.0 ppmv (AP42,Page 2.4-9) Molecular Weight of Chlorine(Cl)= 35.453 g/gmol HHV of Landfill Gas= 506 Btu/ft` LFG Consumed= 344,757 MMBtu/yr Amount of Landfill Gas Consumed=(344,757 MMBtu/yr)/(506 MMBtu/MM 113)= 68134 x106 f?LFG Eqn(3) Qc,_ (681.34 x 1 V6 ft3)*(m3/35.3198 ft3)*(42.0 ppmv CV10^6)= 810.20 m-CI Eqn(4) UMC)= (810.20 m3)*[(35.453 g/gmol* 1 arm)/(8.205E-5 m3-atm/gmol-K*1,000 g/kg*(273+25 K))]_ UMc]= 1,174.77 kg CI Eqn(J0) CMHc1= 1,174.77 kg CI* (NCOUI00)*1.03*(NCNT/100) NCoL=100%since calc is based on actual flow rate to the flare and not an assumed co8ection rate. NCNT=100%Assume the flare is capable of converting 100%of the CI to HCI. CMHcl= 1,174.77 kg CI*(100/100)*1.03*(100/100)= 1,210.01 kg/yr HCI CMHC1= (1,210.01 kg/yr)*(2.2 lb/kg) = 1 2,662.02 Ib/yr HCI CMHC1= (2,662.02lb/yr)/(2,000lb/ton)= 133 ton/yrHCI SCS ENGINEERS SHEET I of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Invent 02209360.16 SUBJECT BY DATE Diesel Fuel Storage Tank(IES-06) M.VanDussen 1 4/15/2016 CY2015 Emission Calculations CHECKED DATE D.Greene 4/182016 OBJECTIVE: Insiginificant source tank emissions based on design capacity and throughput. APPROACH: Use EPA's TANKS 4.0.9d Program. SOLUTION: The following information was entered into TANKS 4.0.9d: Parameter Diesel Tank Product Diesel Fuel Volume(gal) 3,000 Length(feet) 15 Diameter(feet) 5.8 Throuhgput(gaVyr) 148,697 As reported by TANKS 4.0.9d(See attached report): Diesel Tank Pollutant (Ib/yr) (todyr) VOC 4.45 2.23E-03 NMOC• 4.45 2.23E-03 NMOC emissions are conservatively estimated to be equal to VOC emissions. SCS ENGINEERS SHEET I of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE Leachate Storage Tanks(IES-07) M.VanDussen 4/15/2016 CY2015 Emission Calculations(NMOC,VOC,HAPs) CHECKED DATE D.Greene 4/18/2016 OBJECTIVE: Calculate emissions for leachate storage tanks based on laboratory analysis and throughput. APPROACH: Use mass balance approach,assumes that all organic content volatilizes. SOLUTION: Leachate Throughput: 7,066,317 gal/yr (Data obtained from landfill) Organic Content: 547.3 µg/L (See Below) CMva= (547.3 µg/L)*(7,066,317 gal/yr)•(3.785 Ugal)•(I Ib/453.6E+03 mg)•(1 mg/1,000 µg) 32.27 Ib/yr VOC CMvoc= (32.27 Ib/yr)/(8,760 hr/yr)= 3.68E-03 Ib/hr VOC CMva= (32.27 lb/yr)/(2,000 lb/ton)= 1.61 E-02 ton/yr VOC Note: VOC emissions are conservatively estimated to equal NMOC,HAP,and TAP emissions. VOC r (lb/yr) (lb/day) (ton/yr) Acetonc2 200 11.79 3.23E-02 5.90E-03 Benzene 5 0.29 8.08E-04 1.47E-04 Dichloromethane 2.5 0.15 4.04E-04 7.37E-05 Fthylbenzene 5.8 0.34 9.37E-04 1.71E-04 Methyl Ethyl Ketone 300 17.69 4.85E-02 8.84E-03 Methyl Isobutyl Ketone 5 0.29 8.08E-04 I.47E-04 Toluene 16 0.94 2.58E-03 4.72E-04 Xvlemw 13 0.77 2.10E-03 3.83E-04 547.3 HAPslTAP% 0.010 Notes: I. "Municipal Solid Waste Landfill Leachate Characterization Study,"Environmental Research&Educational Foundation,September 2007,(Table 4"Extended VOCs"). Assumes data is representative of East Carolina Environmental Landfill leachate VOC content(Table 4"Extended VOCs"). 2. Acetone is neither HAP or TAP,but included as a VOC for VOC purposes. SCS ENGINEERS SHEET I of I CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services CY2015 Air Emissions Inventory 02209360.16 SUBJECT BY DATE CY2015 Facility Wide Emissions Summary M.VanDussen 4/182016 CHECKED DATE D.Greene 4/18/2016 Landfill Flare 1 Flare 2 Diesel Welding Diesel Leschate Pollutant Engines Operations Storage Tank Tank TOTAL (ES-01) (CD-Flarel) (CD-Flare2) (IES-04) (IESAS) (IES-06) (IES-07) (Ib/yr) (IWyr) (IWyr) pb/yr) (IWyr) (INyr) (INyr) (IWyr) (ton/yr) "OX -- 20,725.38 23,443.49 13,680 - - - 57,849 28.92 sO, -- 2,135.68 2,415.78 900 -- - - 5,451 2.73 co - 112,770.42 127,560.16 2,940 -- -- - 243,271 121.64 I'M - 5,079.75 5,745.95 100 -- - - 10,926 5.46 NMOC 59,220 629.46 712.01 - - 4.45 32.27 60,598 30.30 VOC 23,096 245.49 277.68 1,100 - 4.45 32.27 24,756 12.38 1.1.1-trichloroethaner"-. p 25.40 0.69 0.78 - --- - - 26.86 1.34E-02 1.1,2.2-tetrachloroethane T"'tt" 13.31 0.36 0.41 - - 14.08 7.04E-03 I,I dichlomethane T".HA]s 83.10 2.25 2.55 --- - 87.90 4.39E-02 I,I-dichlomethene TAP.nAP 10.11 0.27 0.31 - --- --- - 10.69 5.34E-03 1.2dichloroethanel"P'u"P 13.46 0.36 0.41 - --- --- - 14.23 7.12E-03 1,2-dichloro ro ni 2.94 0.08 0.09 - -- --- - 3.11 1.56E-03 acetaldehyde - - - 2.40 -- --- - 2.40 1.20E-03 scrolein - •- - 0.30 --- --- -- 0.30 1.50E-04 acrylonitrile T".HAP 2.16 0.01 0.01 - -- --- - 2.18 1.09E-03 benzene TAP.HAP 86.03 0.35 0.40 2.90 --- 0.29 89.97 4.50E-02 carbon disulfide r"P,RX, 27.60 0A 1 0.13 - --- - - 27.94 1.39E-02 carbon tetrachloride W.W 1.22 0.03 0.04 --- -- - - 1.29 6.45E-04 carbonyl sulficle"A" 12.46 0.05 0.06 - - 12.56 6.28E-03 chlorobemiene T".r1AP 28.95 0.78 0.89 -- --- -- - 30.62 1.53E-02 rhloroethane T".nA, 17.47 0.47 0.54 --- -- --- - 18.49 9.24E-03 e h loroform Mu" 2,84 0.08 0.09 - --- --- -- 3.00 1.50E-03 chloromedune T".1W 14.25 0.39 0.44 - -- -- - 15.07 7.53E-03 dichlorobenzene TAP.HAP 267.68 7.25 8.20 - --- - - 283.13 1.42E-01 dichlorodifiuoromethane TAP 239.90 6.50 7.35 - --- --- - 253.75 1.27E-01 dichloromethane TAP.11 P 326.76 8.85 10.01 -- -- -- 0.15 345.77 1.73E-01 rthvl mercy tan TAP 95.46 0.39 0.44 - --- --- - 96.29 4.81 E-02 ethvlbenzene HAP 816.67 3.32 3.75 - --- --- 0.34 824.09 4.12E-01 ethylene dibromide T"P'""P 9.79 0.27 0.30 - -- --- - 10.36 5.18E-03 formaldehyde - - -- 3.60 -- --- --- 3.60 1.80E-03 hexane TAP,i 226.95 0.92 1.04 - -- --- --- 228.91 1.14E-01 hydrogen chloride T"P'w -- 2,353.38 2,662.02 - --- --- --- 5,015.40 2.51 hydrogen sulfide T"P 910.52 3.70 4.18 -- -- 918.40 4.59E-01 manganese --- - - - 101.00 - --- 101.00 5.05E-02 mercury and compounds'"'a" 0.07 0.09 0.10 - -- - -- 0.26 1.29E-04 meth leth 1 ketone TAe 862.62 3.50 3.96 - 17.69 887.77 4.44E-01 meth l isobutylketone T"P'n" 85.12 0.35 0.39 -- -- - 0.29 86.15 4.31E-02 methyl merea tan 1" 70.43 0.29 0.32 - -- 71.04 3.55E-02 polycyclic organic matter - - -- 74.10 --- - - 74.10 3.71E-02 perchloroeth Iene T"P*RAP 224.17 6.07 6.87 - - 237.11 1.19E-01 toluene T".MP 2,652.17 10.77 12.19 1.30 -- --- 0.94 2,677.38 1.34E+00 trichloroeth Iene T"P'""P 101.40 2.75 3.11 107.25 5.36E-02 cinvl chloride T"P'""P 76.27 2.07 2.34 80.68 4.03E-02 I c l ones T".MP 1,994.71 8.10 9.17 0.90 --- --- 0.77 2,013.65 1.01 I'mal H.APs Only 7,123.O8 2,410.47 2,726.60 85.50 101.00 -- 2.79 12.444.45 6.22 Notes: denotes compounds that are classified as toxic air pollu miss per the North Carolina Department ofEmcom i Quality.Division of Art Quality(DAQ). denies compounds that are classified is hazardous air polluanis per AP42 and CAA Section 112. the compou ds listed above were compiled from AP42(revised Nor I`)u81 and CAA Seclim 112. I TANKS 4.0.9d Emissions Report - Detail Format Tank Indentification and Physical Characteristics Identification User Identification: ECE 3000gal Diesel City: State: North Carolina Company: Type of Tank: Horizontal Tank Description: East Carolina 3,000 gallon Diesel Tank Tank Dimensions Shell Length(ft): 15.00 Diameter(ft): 5.80 Volume(gallons): 3,000.00 Turnovers: 49.57 Net Throughput(gal/yr): 148,697.00 Is Tank Heated(y/n): N Is Tank Underground(y/n): N Paint Characteristics Shell Color/Shade: Gray/Medium Shell Condition Good Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig) 0.03 Meterological Data used in Emissions Calculations: Raleigh.North Carolina(Avg Atmospheric Pressure=14.53 psia) TANKS 4.0.9d Emissions Report - Detail Format Liquid Contents of Storage Tank ECE 3000gal Diesel -Horizontal Tank North Carolina Liquid Daily Liquid Surf. Bulk Vapor Liquid Vapor Temperature(deg F) Temp Vapor Pressure(psia) Mol. Mass Mass Mol. Oasis for Vapor Pressure Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. Fract. Weight Calculations Distillate fuel oil no.2 All 68.49 57.95 79.03 62.36 0.0086 0.0061 0.0117 130.0000 188.00 Option 1:VP60=.0065 VP70= 009 TANKS 4.0.9d Emissions Report - Detail Format Detail Calculations (AP-42) ECE 3000gal Diesel - Horizontal Tank North Carolina Annual Emission Calcaulations Standing Losses(Ib): 1.3846 Vapor Space Volume(cu ft): 252.4280 Vapor Density(lb/cu ft): 0.0002 Vapor Space Expansion Factor: 0.0761 Vented Vapor Saturation Factor: 0.9987 Tank Vapor Space Volume: Vapor Space Volume(cu ft): 252.4280 Tank Diameter(ft): 5.8000 Effective Diameter(ft): 10.5275 Vapor Space Outage(ft): 2.9000 Tank Shell Length(ft): 15.0000 Vapor Density Vapor Density(Ib/a ft): 0.0002 Vapor Molecular Weight(IbAb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.0086 Daily Avg.liquid Surface Temp.(deg.R): 528.1618 Daily Average Ambient Temp.(deg.F): 59.2833 Ideal Gas Constant R (psia cuft/(lb-moldeg R)): 10.731 Liquid Bulk Temperature(deg.R): 522.0333 Tank Paint Solar Absorptance(Shell): 0.6800 Daily Total Solar Insulation Fact"(Btu/sqft day): 1,393.0797 Vapor Space Expansion Fact" Vapor Space Expansion Factor: M0761 Daily Vapor Temperature Range(deg.R): 42.1602 Daily Vapor Pressure Range(psia): 0,0056 Breather Vent Press.Setting Range(psia): 0.0800 Vapor Pressure at Daily Average Liquid Surface Temperature(psis): 0.0086 Vapor Pressure at Daily Minimum Liquid Surface Temperature(psia): 0.0061 Vapor Pressure at Daily Maximum Liquid Surface Temperature(psia): 0.0117 Daily Avg.Liquid Surface Temp.(deg R): 528.1618 Daily Min.Liquid Surface Temp.(deg R): 517.6217 Daily Max.Liquid Surface Temp.(deg R): 538.7018 Daily Ambient Temp.Range(deg.R): 21.7167 Vented Vapor Saturation Factor Vented Vapor Saturation Factor: 0.9987 Vapor Pressure at Daily Average Liquid: Surface Temperature(psia): 0.0086 Vapor Space Outage(ft): 2,9000 Working Losses(Ib): 3.0636 Vapor Molecular Weight(Ib4b-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.0086 Annual Net Throughput(ga(/yr.): 148,697.0000 Annual Turnovers: 49.5657 Turnover Factor. 0.7719 Tank Diameter(ft): 5.8000 Working Loss Product Factor: 1.0000 Total Losses(lb): 4.4481 TANKS 4.0.9d Emissions Report - Detail Format Individual Tank Emission Totals Emissions Report for: Annual ECE 3000gal Diesel - Horizontal Tank North Carolina Losseslbs) Components Working Lossi Breathing Loss Total Emissions Distillate fuel oil no.2 3.06 1.38 4.45