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HomeMy WebLinkAboutAQ_F_0800102_20130826_EI_Cmb-EI-File QAPP Audit Form for CY2012 Point Source El data submittals Facility Name:, oS+ Coi-d'i 0.,6V, L Facility lU: Permit Number:13td Assigned to: Confi ential Copy Submitted? Region: W Alt U 0� W YES ❑ NO �R,O Initial Review/Data Entry Receipt of EI properly documented (If submitted through AERO, Receipt of Certification form entered in ED �Das El received by June 30 deadline. 1 not, was the failure to meet the deadline documented? ata entry complete date entered �°a 13 _ ate Approval Due: 011s,4116 Comments: ' �r.ca G �►-� �r��SS�+�`�S ���2� ��11 Qj, cl �OI� CC1i _�1.or_ tsN S_ cl v�a- i►1crLG5,t�{ Wt t«h� c rc� I_n/yentory Audit (verify that the checks below at a minimum have been in%estigated and doeume► t,,(� U�I &11 forms appear to be complete and certification form was signed by appropriate ollicial. LYEmissions reported for all sources (permitted, insignificant, and unpermitted) or marked as not operated or NR I !t VSupporting calculations, control and/or capture efficiencies and emission factor documentation included and apl eat s orrect. Ur All known OSs, control devices and release points reported for each emission source. All emissions above de minimus levels have been reported for all emission sources. Emission Factors are best available/most current. p� Calculations and facility totals add up correctly. fy 'All QA/QC issues addressed. Comparison with previous emission inventory has been conducted; obvious outliers have been investigated and ��/,t�xplained. Vod 11 changes/corrections were made to the inventory and documented either on paper or DataEntry Main page. U� Appropriate additional comments entered on DataEntryMain page. Auditor signature , Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions % Change and/or Toxic Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2012 CY 2011 frgULfJL. from Fees Acrolein 107-02-8 0.300000 0.300000 0.0% Acrylonitrile 107-13-1 0.030010 0.020010 50.0% Benzene 71-43-2 5.73 5.62 2.0% Butadiene, 1,3- 106-99-0 0.100000 0.100000 0.0% Carbon disulfide 75-15-0 0.020000 0.020000 0.0% Carbon tetrachloride 56-23-5 5.05 4.71 7.2% Carbonyl sulfide 463-58-1 29.09 27.46 5.9% CFC-12 (Dichlorodifluoromethane) 75-71-8 335.60 312.71 7.3% Chlorobenzene 108-90-7 0.020000 0.020000 0.0% Chloroform 67-66-3 0.040000 0.030000 33.3% Dichlorobenzene(p), 1,4- 106-46-7 0.040010 0.040010 0.0% Ethyl benzene 100-41-4 0.220010 0.250010 -12.0% Ethyl chloride (chloroethane) 75-00-3 0.010000 0.010000 0.0% Ethyl mercaptan 75-08-1 139.97 132.15 5.9% Ethylene dichloride(1,2-dichloroethane) 107-06-2 0.030010 0.030010 0.0% Ethylidene dichloride (1,1-dichloroethane) 75-34-3 3.50 3.26 7.4% Formaldehyde 50-00-0 3.60 3.60 0.0% Hexane, n- 110-54-3 8.97 8.47 5.9% Hydrogen chloride (hydrochloric acid) 7647-01-0 5,292.48 3,826.37 38.3% MEK (methyl ethyl ketone, 2-butanone) 78-93-3 193.72 184.99 4.7% Methyl chloride (chloromethane) 74-87-3 0.000010 0.004910 N/A Methyl chloroform 71-55-6 0.040010 0.040010 0.0% Methylene chloride 75-09-2 0.080230 0.080230 0.0% MIBK (methyl isobutyl ketone) 108-10-1 0.160010 0.210010 -23.8% Perchloroethylene (tetrachloroethylene) 127-18-4 5.74 5.35 7.3% Polycyclic Organic Matter(Inc PAH, dioxins, etc. NC POM 74.10 74.10 0.0% & AP 42 historic) 08/12/2013 Page 2 of 3 Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Hazardous Air Pollutants (HAPs) Actual Emissions % Change and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2012 CY 2011 from ED from Fees I Propylene dichloride (1,2-dichloropropane) 78-87-5 0.030000 0.030000 0.0% TCE (trichloroethylene) 79-01-6 0.030070 0.030070 0.0% Tetrachloroethane, 1,1,2,2- 79-34-5 0.030040 0.030040 0.0% Toluene 108-88-3 9.12 8.81 3.5% Vinyl chloride 75-01-4 26.06 23.04 13.1% Vinylidene chloride 75-35-4 0.020000 0.020000 0.0% Xylene (mixed isomers) 1330-20-7 4.66 4.53 2.9% Largest Individual HAP Hydrogen chloride (hydrochloric acid) 5,292.48 Ibs Total HAP Emissions 5,572.9G Ibs DAO's Comments Reeardine Inventory Reviewer changed from Hopkins to Mangum-R Fisher.Facility requested end-dating or removal of CS-2 and CS-3. Betsy I end-dated CS-2,and was able to delete CS-3. Also requested end-dating CD-GCCS 1,but this has been permitted as a contrc rather than a descriptor. 08/12/2013 Page 3 of 3 Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07 Green House Gases Pollutants(GHG) Actual Emissions Tons/Yr % Change Pollutant CAS Not Not N/A Reported Reported CO2 equivalent(sum of individual GHG pollutant emission times their 99Ao GHGs IPCC Global Warming Potential(GWP), converted to metric tons) Reported Criteria Pollutants Actual Emissions % Change (Tons/Year) Pollutant CAS CY 2012 CY 2011 CO CO 128.09 93.38 37.2% NOx NOx 30.19 23.81 26.8% PM(TSP) TSP 5.84 4.27 36.8% PM10 PMIO 5.84 4.27 36.8% PM2.5 PM2.5 5.84 4.27 36.8% S02 S02 4.12 3.12 32.1'% VOC VOC 10.81 10.01 8.0% Hazardous Air Pollutants (HAPs) Actual Emissions % Change and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2012 CY 2011 from ED from Fees I Manganese& compounds 101.00 101.00 0.0% Manganese Unlisted Compounds-Specify MNC-Other 101.00 101.00 0.0% Compound(Component of MNC) Mercury & Compounds-all total mass includes Hg Vapor 0.260000 0.200000 30.0% Mercury, vapor (Component of HGC) 7439-97-6 0.260000 0.200000 30.0% Total Reduced Sulfur(TRS as total mass) 1,313.76 1,240.36 5.9% Hydrogen sulfide 7783-06-4 1,195.40 1,128.61 5.9% Methyl mercaptan 74-93-1 118.36 111.75 5.9% Acetaldehyde 75-07-0 2.40 2.40 0.0% 08/12/2013 Page 1 of 3 SCS Engineers, P.C. Environmental Consultants 2520 Whitehall Park Drive 704 504-3107 and Contractors Suite 450 FAX 704 504-3174 Charlotte, NC 28273-3557 www.scsengineers.com SCS ENGINEERS ,, PC June 24,2013 File No.02209360.07 T7 Mr.Robert Fisher Regional Supervisor NCDENR Division of Air Quality Washington Regional Office 943 Washington Square Mall Washington,NC 27889 Subject: CY2012 Annual Emission Inventory East Carolina Environmental Landfill—Aulander,North Carolina Title V Permit No: 08849T05 Dear Mr. Fisher: On behalf of the East Carolina Environmental Landfill, SCS Engineers,PC is pleased to submit this Annual Emission Inventory Report for the East Carolina Environmental located in Aulander, North Carolina. This report is intended to satisfy Title V Permit Condition X. The purpose of the Report is to inventory emissions that occurred during the period of January 1, 2012 and December 31,2012. If you have any questions or comments about this submittal,please contact either of the undersigned at(704)504-3107. Sincerely, ,Z J Morgan,P.E. Steven C.Lamb,P.E. Project Manager Vice President SCS ENGINEERS,PC SCS ENGINEERS,PC Enclosure cc: Matt Einsmann,P.E.,Environmental Manager,Republic Services of NC,LLC Matt East, General Manager,East Carolina Environmental Landfill M:TROrECr FlLESVI2209360 EAST CAROLINA ENVIRONMENTAU02209360.07-ECE 2013 Tkk V ServicesUask 7-Emissions Inv ntory%ECE 2012 cov rlener.doc N �i3 East Carolina Environmental Landfill REPUBLIC 4#14 SERVICES East Carolina Environmental Landfill 2012 Emission Inventory Air Permit 08849T05 Presented to: Republic Services of North Carolina, LLC East Carolina Environmental Landfill 1922 Republican Road Aulander, NC 27805 Presented by: SCS Engineers, PC 2520 Whitehall Park Drive, Suite 450 Charlotte, North Carolina 28273 (704) 504-3107 D JUN 2 6 2013 June 17, 2013 File No. 2209360.07 -- East Carolina Environmental Landfill Table of Contents Section Page SECTION1 Introduction........................................................................................................................ 1 SECTION 2 Uncollected Landfill Gas Fugitives................................................................................ 2 Landfill Gas Fugitive Emissions........................................................................................2 Non-Methane Organic Compound (NMOC) Emissions...............................................2 Volatile Organic Compound (VOC) Emissions.............................................................3 Hazardous Air Pollutant (HAP) Emissions.......................................................................3 SECTION 3 Landfill Gas Flare............................................................................................................ 4 FlareEmissions....................................................................................................................4 SECTION 4 Insignificant Activities.......................................................................................................5 Leachate Storage Tanks (IES-07)...................................................................................5 Diesel Storage Tank (IES-06)..........................................................................................6 Diesel Engines for Miscellaneous Landfill Support (IES-04).......................................6 Welding Operations (IES-05).........................................................................................6 SolarFlares (IES-08).........................................................................................................6 Attachment A 2012 Annual Emissions Statement B Detailed Emissions Calculations East Carolina Environmental Landfill SECTION 1 INTRODUCTION Per Condition 3.X of East Carolina Environmental Landfill (Landfill) Air Quality Permit No. 08849T05 for its Landfill located at 1922 Republican Road, Aulander, North Carolina, the facility is required to submit an emissions inventory to the Department of Air Quality (DAQ)by June 30 of each year. The emissions inventory presented herein is the basis for the emissions values reported in the 2012 Annual Emissions Statement. The emissions sources identified were based on discussions and correspondence with Landfill staff, SCS Engineers' (SCS) knowledge of the site, review of existing permits, compliance reports, and other information provided by the Landfill. Facility-wide emissions at the Landfill are provided in Table 1 below. Facility-wide emissions including spectated HAPs are provided at the end of this section. Emissions for each source are further detailed in the remaining sections of this report. Table 1 . 2012 Annual Emission Rate Summary (tons/yr) Permit ID Emission Source NMOC VOC HAPs/ NOx CO sox PM10 TAPS Municipal Solid ES-01 Waste Landfill 25.55 9.96 1.00 (Fugitive Emission) CD-Flarel Landfill Gas Flare 1 0.57 0.22 2.16 18.67 101.6 2.93 4.58 CD-Flare2 Landfill Gas Flare 2 0.13 0.05 0.51 4.36 23.73 0.68 1.07 IES-08 Solar Flares 0.04 0.02 4.43e-7 0.32 1.32 0.06 0.14 IES-07 Leachate Storage g 78e-3 8.78e-3 8.78e-3 Tanks IES-06 Diesel Storage Tank 2.24e-3 2.24e-3 IES-05 Welding 5.05e-2 Operations2 Diesel Engines for IES-04 Miscellaneous 0.55 4.28e-2 6.84 1.47 0.45 0.05 Landfill Support Total' 26.31 �10.82 3.78 30.18 128.09 4.13 5.83 Notes: Not Applicable. Due to rounding, 'Total'emissions may not exactly equal the sum of the individual source emission rates as they appear in the table above. Emissions from the Welding Operations, and Diesel Engines are"carried forward"from the prior reporting year as allowed by the DENR DAQ AERO reporting system 1 East Carolina Environmental Landfill SECTION 2 UNCOLLECTED LANDFILL GAS FUGITIVES LANDFILL GAS FUGITIVE EMISSIONS This section addresses the generation of landfill gas(LFG),non-methane organic compounds (NMOCs), volatile organic compounds (VOCs) and hazardous air pollutants (HAPs), methane, and carbon dioxide and their fugitive emissions via passive LFG releases. LFG generation from the landfill operation was calculated using SCS Engineers' version of the U.S. EPA Landfill Gas Emissions Model(LandGEM). A description of the model parameters is provided below and the model output is attached. LandGEM uses a first-order decay equation to predict landfill gas generation based on the amount and age of the waste in place. The formula is presented in 40 CFR Part 60.754(a)(1)(i). The parameters La and k used in the LandGEM are the values published in EPA's Compilation of Air Pollutant Emission Factors(AP-42), Volume I, Section 2.4(revised Noy;wber 1998). The methane generation potential, Lo, for the MSW landfill cells was set equal to 100 cubic meters (in 3)of methane(CH4)per megagram(Mg) of waste. The methane generation rate constant, k, was4.04 yf t and the concentration of NMOC in LFG was set to 595 parts per million by volume (ppmv)as hexane. AP-42 recommends these values of Lo and k for municipal solid waste (MSW) landfills that are located in geographical regions that receive average or above average annual precipitation, such as Aulander,North Carolina. To calculate landfill emissions,the refuse filling history was input to the LandGEM. Note that this model estimates emissions based on the amount of waste in place at the beginning of each year. Waste in place at the beginning of 2012 was approximately 7.24 million Mg, or 7.99 million tons. The LandGEM estimated that the methane generation rate for 2012 is approximately 21.73 million cubic meters, or approximately 767.5 million cubic feet. Assuming that the methanficontent in the LFG is 50 percent,the volume of LFG generated in 2012 is estimated to be 2,920 cubic feet per minute(ft3/min). LandGEM input and output are provided on page 1 of the spreadsheets found at the end of this permit. Non-Methane Organic Compound (NMOC) Emissions NMOC generation from the Landfill was calculated using LandGEM. Model parameters were similar to the values noted above. LandGEM estimated that the NMOC generation rate for 2012 is 92.71 Mg, or 102.19 tons(See page 2 of the spreadsheets provided in the detailed calculations attachment). The Landfill operates a gas collection and control system(GCCS)to capture LFG and route it to a control flare. Seventy five percent of the LFG is assumed to be captured; therefore,twenty five percent of the NMOC generated is assumed to have en emitted as fugitive. Thus, the fugitive NMOC emission rate for 2012 is 25.55 tons.✓ 2 East Carolina Environmental Landfill Volatile Organic Compound (VOC) Emissions In determining the VOC emissions from the landfill, VOC generation is assumed to bev39 percent of the NMOC generation. This assumption is based on information contained in AP-42 Section 2.4(revised November 1998) Table 2.4-2. VOC emissions were based on the historical tonnages and model parameters noted above. The LFG and NMOC generation rates were extracted from the LandGEM output and represent the emissions from the Landfill during 2012. The VOC generation rates were calculated by converting the NMOC generation r5tes (shown in the LandGEM output) from Mg/yr to tons/yr, and then multiplying by 0.39 (i.eOC is considered as 39 percent of NMOC). The VOC generation rate for 2012 is 39.86 tons/yr. The fugitive VOC emission rate is determined is the same manner as the fugitive emissions rate for NMOC reflecting the ope7tion of the GCCS during the period. The fugitive VOC emission rate for 2012 is 9.96 tong, as shown in Table 2 below. Table 2. Air Pollutant Generation and Emission Rates NMOC NMOC • • VOC Fugitive Year Generation Generation Emissions Generation' Emissions' Fugitive 2012 92.71 102.19 25.55 39.86 9.96 1.00 Notes: I VOC generation is assumed to be 39 percent of NMOC generation. Hazardous Air Pollutant (HAP) Emissions The estimation of HAP emissions from the Landfill is based on equations (3)and(4)of AP-42 Section 2.4. Those equations are presented below. The first step is to estimate the generation rate of each pollutant in cubic meters per year(m3/yr). Next,the volumetric generation rate estimate is converted to a mass generation rate (ton/yr). 3 CP Q IY! 2.OxQr(yr)= Ch4106 where: QP = Pollutant generation rate(m3/yr) QCh4 = Methane generation rate(m3/yr) from the LandGEM Cp = Pollutant concentration in LFG(ppmv) 3 East Carolina Environmental Landfill 2.0 = Multiplication factor(assumes LFG is 50 percent methane, and the balance is carbon dioxide, nitrogen, oxygen and other trace gases) Mp(tons/yr)= Qp ((MWP(glgmOl))(1atm)) ton Cr _5 r m' —atm 1000gT(211 [907.185 kg] I (8.205x10 gmol—K))( kg +TKj l where: MP = Pollutant mass generation rate MWp = Molecular weight of pollutant(g/gmole) T = Temperature of LFG(°C) (Standard temp of 25 degrees Celsius) Of the 188 chemical compounds identified as HAPs under Section 112 of the Clean Air Act, 28 of these compounds are listed in AP-42 Table 2.4-1 and 2.4-2. Site-specific data from testing performed by Research Triangle Park Laboratories was used to determine the concentration of these compounds. This report is dated May, 5, 2005 and was submitted as part or the Compliance Demonstration Report dated June 3,2005. These site specific concentrations are shown on page 4 of the spreadsheets in the detailed emissions attachment. Annual emissions of the remaining HAP compounds (i.e.,those not included in the AP-42 tables) are assumed to be negligible. The HAP fugitive rate for 2012 was calculated to be 0.04 tons. Total HAP and TAP fugitive emissions for 2012 are 1.00 tons. SECTION 3 LANDFILL GAS FLARE Flare Emissions The landfill operates two (2)flares, each with a design capacity of 3,000 scfm, as a landfill gas control devices. The emission factors and annual emissions associated with each flare (permitted as CD-Flarel and CD-Flare2) are summarized in Table 3. 4 East Carolina Environmental Landfill Table 3. LFG Flare Emissions 2012 LFG 2012 LFG Flare Flare Compound LFG Flare Emission Factors Emissions Emissions NOx 0.068 Ib/MMBtu 1 18.67 4.36 CO 0.37 Ib/MMBtu 1 101.57 23.73 NMOC 99.2 % destruction-2 0.57 0.13 VOC3 99.2 % destructiorr2 0.22 0.05 99.8 % destruction for halogenated HAP species2 HAPs 99.7%for non-halogenated HAP species 2 2.16 0.51 0% for mercury species 2 PM10 17 Ib/106 ft3 methane4 4.58 1.07 502 H2S concentration: 35.5 ppmV5 2.93 0.68 Notes: Emission factor obtained from AP-42,Table 13.5-1. 2 Control efficiency obtained from AP-42,Table 2.4-3. 3 VOC generation is estimated to be 39 percent of the NMOC generation per Table 2.4-2 of AP-42 Section 2.4 "Municipal Solid Waste Landfills,"revised 11/98. These estimates assume a 75% LFG collection efficiency for the active landfill gas collection system. 4 Control efficiency obtained from AP-42,Table 2.4-5. 5 S02 emissions are calculated per AP-42, Section 2.4.4; SECTION 4 INSIGNIFICANT ACTIVITIES Leachate Storage Tanks (IES-07) The Landfill operates two (2) leachate storage tanks to store collected leachate and condensate from the Landfill prior to disposal at an offsite wastewater treatment system. The throughput of leachate in 2012 was 3,844,493 gallons. Table 4. Emission Data Parameter 2012 Leachate Throughput 3,844,493 gallons Calculated emissions (VOC) 17.56 Ibs (8.78e-3 tons) 5 East Carolina Environmental Landfill Detailed emission calculations are provided in the attachment. Diesel Storage Tank (IES-06) CY2012 emissions were calculated using EPA's Tank software. According to the program 0.00224 tons per year of VOCs were emitted. NMOC emissions are conservatively estimated to be equal to VOC emissions. Diesel Engines for Miscellaneous landfill Support (IES-04) Emissions from the Landfill's diesel engines for miscellaneous support are"carried forward"as allowed in the Division's AERO reporting and are therefore identical to the previous reporting period. As reported in for CY2011, emissions are provided in Table 5: Table 5. Emissions from Diesel Engines Diesel2012 Compound tpy (Carried Forward from CY201 1) NOx 6.84 CO 1.47 PM 0.05 VOC 0.55 502 0.45 HAPs/TAPS 4.28e-2 Welding Operations (IES-05) The Landfill's permit also includes an insignificant activity listing for"Welding Operations" with the emission source ID ES-05. Emissions from the Landfill's welding operations are "carried forward"as allowed in the Division's AERO reporting and are therefore identical to the previous reporting period. As reported in 2011, emissions of Manganese total 101 pounds as reported for calendar year 2012. This is reported as HAPs/TAPs of 5.05e-2 tpy for the welding operations. Solar Flares (IES-08) Three(3) solar flares were used during this period(noted here as IES-08). To estimate emissions, flow was conservatively assumed to be 60 scfm per each flare (total of 180 scfm) for 6 East Carolina Environmental Landfill 8 hours per day during the entire 365 day period. Based on emission rate data from a solar flare manufacturer, Landfill Services, emissions were estimated as shown in Table 6: Table 6. Solar Flare Emissions Data 2012 Solar Flare Compound Solar Flare Emission Factors Emissions NOx 0.072lb/hr 0.32 CO 0.302lb/hr 1.32 NMOC NMOC assumed 1/0.39 of VOC (per AP-42) 0.04 VOC 0.004lb/hr 0.02 99.8 % destruction for halogenated HAP species' HAPs/TAPS 99.7% for non-halogenated HAP species I 4.43e-7 0% for mercury species PM10 0.031 Ib/hr 0.14 SO2 0.014lb/hr 0.06 Notes: Control efficiency obtained from AP-42,Table 2.4-3. 7 East Carolina Environmental Landfill ATTACHMENT A 2012 ANNUAL EMISSIONS STATEMENT I Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 Inventory Certification Form(Title V) Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2012 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Drew Isenhour This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation: a president,secretary,treasurer,or vice-president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production, or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars);or ii.the delegation of authority to such representatives is approved in advance by the permitting authority; 2.For partnership or sole propietorship; a general partner or the proprietor,respectively; 3. for a muncipality,state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). -ERTIFICATION STATEMENT4 lmporta= Legally Responsiblei after all submissions certify that I am the responsible official for this facility,as described above, and hereby certify that the information contained n this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: Drew Isenho i afore: Ob "Z6- / This form appli s to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: DIsenhour@Republicservices.com Information on this Form cannot be held confidential Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 1 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Listing of Emission Sources and Control Devices on Permit. See instructions «ES ID on ;ES Description GCS ID GCS Description CD ID's Air Permit Municipal solid waste landfill Flare,One landfill gas—fired open ES-01 [NSPS,MACT] CS-1,CS-4 flare(3000 scfm maximum flow rate) CD—Flarel,CD—Flare2 [CISWI], 1-8.l0A 18 Solar Flares IES-04 Diesel engines for miscellaneous landfill support IES-05 Welding operations IES-06 Diesel storage tank IES-07 One leachate storage tank 2 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO Emission Source & Operating Scenario List — See Instructions *ES Group ID DES ID rtOS ID SOS Description 8 CD—Flare 1 ES-01 9 CD—Flare 2 1 Municipal solid waste landfill Insignificant source small flares used I-8.10A 7 to point control landfill gas as needed (conservatively assumed operation of 12/hr/day for period) IES-04 4 No. 2 fuel oil—diesel engines for miscellaneous landfill support IES-05 3 maintenance shop welding rods IES-06 6 diesel storage tank IES-07 2 temporary storage of collected ileachate 3 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region :WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT] 3. Operating Scenario ID/Description: OS—8/CD—Flare 1 4. SCC Number/Description: Not required by facility,will be completed by DAQ 5. Throughput/units in 2012: 1098041283 FT3/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control 100 Device or Stack): 8. Control Device Information Order CS—ID CD ID Control Device Description as listed inpermit) 1 CS-1 CD—Flarel One landfill as—fired open flare 3000 scfm maximum flow rate 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) Flare VERTICAL STACK 35 1 1500 60 2827.43 Flare 4 Operating Scenario: OS—8 Emission Source/Group ID:ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25a�o 25"fin uneAug. 25% �012 ept.—Nov. 25 012 Varch—May 12 �012- 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2012 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (NAAQS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2012 CO CO 101.57 08 0 NOx NOx 18.67 08 0 TSP TSP 4.58 08 0 PM10 PM10 4.58 08 0 PM2.5 PM2.5 4.58 08 0 S02 S02 2.93 08 0 VOC VOC 0.22 08 0.98 AFTER Emission CAS Emissions Estimation Control HAP/TAP Method Efficiency Emission EF Control Pollutants (In Alphabetical Order) (see HAP/TAPS instructions) (Pounds/Year) Code (Net after all Factor (See controls) Instructions 2012 Acrylonitrile 107-13-1 0 08 0 Benzene 71-43-2 0 08 0 CFC-12 ichlorodifluoromethane 75-71-8 17.93 08 0 Carbon disulfide 75-15-0 0 08 0 Carbon tetrachloride 56-23-5 0.27 08 0 Carbonyl sulfide 463-58-1 0.25 08 0 Chlorobenzene 108-90-7 0 08 0 Chloroform 67-66-3 0 08 0 Dichlorobenzene 14— 106-46-7 0 08 0 5 Eth lbenzene 100-41-4 0 08 0 Ethyl chloride chloroethane 75-00-3 0 08 0 Ethyl merca tan 75-08-1 1.19 08 0 Ethylene dichloride 1 2—dichloroethane 107-06-2 0 08 0 Ethylidene dichloride 75-34-3 0.19 08 0 1 1—dichloroethane Hexane n— 110-54-3 0.08 08 0 Hydrogen chloride(hydrochloric acid 7647-01-0 4290.1 08 0 Hydrogen sulfide 7783-06-4 10.15 08 0 Mercury,vapor(Component of HGC 7439-97-6 0.16 08 0 Methyl chloride 74-87-3 0 08 0 Methyl chloroform 71-55-6 0 08 0 Methyl ethyl ketone 78-93-3 1.56 08 0 Methyl isobu lketone 108-10-1 0 08 0 Methyl merca tan 74-93-1 1.01 08 0 Methylene chloride 75-09-2 0 08 0 Perchloroeth lene tetrachloroeth lene 127-18-4 0.31 08 0 Propylene dichloride 78-87-5 0 08 0 Tetrachloroethane 1 1 2 2— 79-34-5 0 08 0 Toluene 108-88-3 0.06 08 0 Trichloroeth lene 79-01-6 0 08 0 Vinyl chloride 75-01-4 1.39 08 0 Vin lidene chloride 75-35-4 0 08 0 X lene 1330-20-7 0.03 08 0 6 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bettie DAQ Region :WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT) 3. Operating Scenario ID/Description: OS—9/CD—Flare 2 4. SCC Number/Description: Not required by facility,will be completed by DAQ 5. Throughput/units in 2012: 256554953 FT3/yr (e.g. production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur ro Ash I Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control 100 Device or Stack): 8. Control Device Information Order CS—ID CD ID Control Device Description as listed in ermit 1 CS-4 CD—Flare2 One landfill as—fired open flare 3000 scfrt maximum flow rate CISWI 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) Flare2 VERTICAL STACK 40 1.17 1177 53 3418.91 Flare 2 7 Operating Scenario: OS—9 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�o 25o�u une—Aug. 25"�o Sept.—Nov. 25% 012 �arch—May 12 �012 012 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2012 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (NAAQS) Ef Control Pollutants Code Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2012 CO CO 23.73 08 0 NOx NOx 4.36 08 0 TSP TSP 1.07 08 0 PM10 PM10 1.07 08 0 PM2.5 PM2.5 1.07 08 0 S02 S02 0.68 08 0 VOC VOC 0.05 08 0.98 At- VER Emission CAS Emissions Estimation Control HAP/TAP Method Efficiency Emission (see HAP/TAPS EF Control Pollutants (In Alphabetical Order) instructions) (Pounds/Year) Code (Net after all Factor (See controls) Instructions 2012 Acr lonitrile 107-13-1 0 08 0 Benzene 71-43-2 0.01 08 0 CFC-12 Dichlorodifluoromethane 75-71-8 4.19 08 0 Carbon disulfide 75-15-0 0 08 0 Carbon tetrachloride 56-23-5 0.06 08 0 Carbonyl sulfide 463-58-1 0.06 08 0 Chlorobenzene 108-90-7 0 08 0 Chloroform 67-66-3 0 08 0 Dichlorobenzene 14— 106-46-7 0 08 0 8 Eth lbenzene 100-41-4 0 08 0 Ethyl chloride chloroethane 75-00-3 0 08 0 Ethyl merca tan 75-08-1 0.28 08 0 Ethylene dichloride 12—dichloroethane 107-06-2 0 08 0 Ethylidene dichloride 75-34-3 0.04 08 0 1 1—dichloroethane Hexane n— 110-54-3 0.02 08 U Hydrogen chloride(hydrochloric acid 7647-01-0 1002.37 08 0 Hydrogen sulfide 7783-06-4 2.37 08 0 Mercury,vapor(Component of HGC 7439-97-6 0.04 08 0 Methyl chloride 74-87-3 0 08 0 Methyl chloroform 71-55-6 0 08 0 Methyl ethyl ketone 78-93-3 0.37 08 0 Methyl isobu lketone 108-10-1 0 08 0 Methyl merca tan 74-93-1 0.23 08 0 Methylene chloride 75-09-2 0 08 0 Perchloroeth lene tetrachloroeth lene 127-18-4 0.07 08 0 Propylene dichloride 78-87-5 0 08 0 Tetrachloroethane 112 2— 79-34-5 0 08 0 Toluene 108-88-3 0.01 08 0 Trichloroeth lene 79-01-6 0 08 0 Vinyl chloride 75-01-4 0.33 08 0 Vin lidene chloride 75-35-4 0 08 0 X lene 1330-20-7 0.01 08 0 9 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID (from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT] 3. Operating Scenario ID/Description: OS— I/Municipal solid waste landfill 4. SCC Number/Description: 50100402/1-andfill Dump ;Fugitive Emissions 5. Throughput/units in 2012: 575739 TON/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) F�F ro Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpen-nit) 9. Emission Release Point I ERP Information: Sources i cnted to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) I I FUGITIVE(NO 1 72 Area= 1 fugitive STACK 10 Operating Scenario: OS— 1 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�o 25"�u une—Aug. 25"�u Sept.—Nov. 25% 012 �arch—May 12 012� 012 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2012 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po�QS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2012 CO CO 0 08 NOx NOx 0 08 TSP TSP 0 08 PM10 PM10 0 08 PM2.5 PM2.5 0 08 S02 S02 0 08 VOC VOC 9.96 08 Emission CAS Emissions Estimation Control HAP/TAP Method Efficiency Emission EF Control Pollutants (In Alphabetical Order) (see HAP instructions) (Pounds/Year) Year) Code (Net after all Factor (See controls) InstructioiN 2012 Acrylonitrile 107-13-1 0.03 08 Benzene 71-43-2 2.66 08 CFC-12 ichlorodifluoromethane 75-71-8 313.4 08 Carbon disulfide 75-15-0 0.02 08 Carbon tetrachloride 56-23-5 4.72 08 Carbonyl sulfide 463-58-1 28.78 08 Chlorobenzene 108-90-7 0.02 08 Chloroform 67-66-3 0.04 08 Dichlorobenzene 14— 1 106-46-7 1 0.04 08 11 Eth 1 benzene 100-41-4 0.03 08 Ethyl chloride chloroethane 75-00-3 0.01 08 Ethyl merca tan 75-08-1 138.5 08 Ethylene dichloride 1 2—dichloroethane 107-06-2 0.03 08 Ethylidene dichloride 75-34-3 3.27 08 1 1—dichloroethane Hexane n— 110-54-3 8.87 08 Hydrogen chloride(hydrochloric acid 7647-01-0 0 08 Hydrogen sulfide 7783-06-4 1182.88 08 Mercury,vapor(Component of HGC 7439-97-6 0.06 08 Methyl chloride 74-87-3 0 08 Methyl chloroform 71-55-6 0.04 08 Methyl ethyl ketone 78-93-3 182.17 08 Methyl isobutyl ketone 108-10-1 0 08 Methyl merca tan 74-93-1 117.12 08 Methylene chloride 75-09-2 0.08 08 Perchloroeth lene tetrachloroeth lene 127-18-4 5.36 08 Propylene dichloride 78-87-5 0.03 08 Tetrachloroethane 1 1 2 2— 79-34-5 0.03 08 Toluene 108-88-3 7.24 08 Trichloroeth lene 79-01-6 0.03 08 Vinyl chloride 75-01-4 24.34 08 Vin lidene chloride 75-35-4 0.02 08 X lene 1330-20-7 3.3 08 12 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County :Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID (from permit)or I-8.10A Emission Source Group ID 2. Emission Source Description: 8 Solar Flares 3. Operating Scenario ID/Description: OS—7/Insignificant source small flares used to point control landfill gas as needed(conservatively assumed operation of 12/hr/day for period) 4. SCC Number/Description: 31299999/Miscellaneous Machinery; Other Not Classified 5. Throughputlunits in 2012: 4380 HR/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L a W) in 0.1 feet) Insignificant Source Solar Flare VERTICAL STACK 10 0.33 10S0 60 307.9 Solar Flare for odor control 13 Operating Scenario: OS—7 Emission Source/Group ID: I-8.10A 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�o arch—May 25"�o une—Aug. 25"�u �012 ept.—Nov. 25% 012 012 �012 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG GHG Method Efficiency Emission CAS Pollutants Code (N y Ef Control Pollutants et after Factor (Tons/Year) (See all controls) Instructions 2012 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (NAA Code Pollutants Code (Net after Factor Ef Control Pollutants (Tons/Year) (See all controls) Instructions 2012 CO CO 1.32 08 NOx NOx 0.32 08 TSP TSP 0.14 08 PM10 PM10 0.14 08 PM2.5 PM2.5 0.14 08 S02 S02 0.06 08 VOC VOC 0.02 08 Emission CAS Emissions Estimation Control HAP/TAP Emission (see HAP/TAPS Method Efficiency EF Control Pollutants (In Alphabetical Order) Code (Net after all Factor instructions) (Pounds/Year) (See controls) Instructions 2012 Acrylonitrile 107-13-1 0.00001 08 Dichlorobenzene 14— 106-46-7 0.00001 08 Eth lbenzene 100-41-4 0.00001 08 Ethylene dichloride 1 2—dichloroethane 107-06-2 0.00001 08 Ethylidene dichloride 75-34-3 0.00004 08 1 1—dichloroethane Hexane n— 110-54-3 0.00002 08 Hydrogen chloride(hydrochloric acid 7647-01-0 0.01 08 Hydrogen sulfide 7783-06-4 0.00003 08 14 Methyl chloride 74-87-3 0.00001 08 Methyl chloroform 71-55-6 0.00001 08 Methyl ethyl ketone 78-93-3 0.00002 08 Methyl isobu (ketone 108-10-1 0.00001 08 Methylene chloride 75-09-2 0.00023 08 Perchloroeth lene tetrachloroeth lene 127-18-4 0.00012 08 Tetrachloroethane 1 1 2 2— 79-34-5 0.00004 08 Toluene 108-88-3 0.0001 08 Trichloroeth lene 79-01-6 0.00007 08 Vinyl chloride 75-01-4 0.00009 08 X lene 1330-20-7 0.00004 08 15 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County :Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit) or IES-04 Emission Source Group ID 2. Emission Source Description: Diesel engines for miscellaneous landfill support 3. Operating Scenario ID/Description: OS—4/No. 2 fuel oil—diesel engines for miscellaneous landfill support 4. SCC Number/Description: 20200401/Diesel; Diesel 5. Throughput/units in 2012: 60000 GAL/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) RP—DIESEL FUGITIVE(NO 1 72 Area= 1 miscellaneous diesel STACK) engines 16 Operating Scenario: OS —4 Emission Source/Group ID: IES-04 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�o 25"fin une—Aug. 25"�u ept.—Nov. 012 �arch—May 12 �012 012 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2012 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission (NAAQS) y Ef Control Pollutants Code Pollutants Method Code (Net after Factor (Tons/Year) (See Instructions) all controls) 2012 CO CO 1.47 08 NOx NOx 6.84 08 TSP TSP 0.05 08 PM10 PM10 0.05 08 PM2.5 PM2.5 0.05 08 S02 S02 0.45 08 VOC VOC 0.55 08 HAP/TAP Emissions Emission ControlEmission CAS Estimation Efficiency Pollutants (in HAP/TAPS EF Control Alphabetical Order) (`cc instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2012 Acetaldehyde 75-07-0 2.4 08 Acrolein 107-02-8 0.3 08 Benzene 71-43-2 2.9 08 Butadiene 13— 106-99-0 0.1 08 Formaldehyde 50-00-0 3.6 08 Polycyclic Organic Matter(Inc PAR, dioxins,etc.NC AP 42 POM 74.1 08 historic amorphous lob Toluene 108-88-3 1.3 08 X lene 1330-20-7 0.9 08 17 ��T - TTT1 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit)or IES-05 Emission Source Group ID 2. Emission Source Description: Welding operations 3. Operating Scenario ID/Description: OS—3/maintenance shop welding rods 4. SCC Number/Description: 30900500/Metal Work—Welding; General 5. Throughput/units in 2012: 5000 LB/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point I ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 19 Operating Scenario: OS—3 Emission Source/Group ID: IES-05 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 1 ) Days per Week ( 5 ) Weeks per Year ( 50 ) 11.Typical Start& End Times For Operating Scenario: Start: 900 End: 1000 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�o 25"�u unc—Aug. 25"�u Sept.—Nov. 25% 012 �arch—May 12 �012 012 7 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See instructions all controls 2012 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Po� Code Pollutants Method Code Ef Control Pollutants an (Net after Factor (Tons/Year) (See Instructions) all controls) 2012 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 08 HAP/TAP Emissions Emission Control CAS Estimation Efficiency Emission Pollutants (In Alphabetical HAP/TAPS EF Control Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2012 Manganese Unlisted Compounds(Specify MNC—Other 101 08 Component of MNC 20 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bettie DAQ Region : WARD North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit)or IES-06 Emission Source Group ID 2. Emission Source Description: Diesel storage tank 3. Operating Scenario ID/Description: OS—6/diesel storage tank 4. SCC Number/Description: 39090004/Fuel Storage—Fixed Roof Tanks ;Distillate Oil(No.2): Working Loss 5. Throughput/units in 2012: 153019 GAL/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F -I FUGITIVE(NO 1 72 Area 1 fugitive STACK 21 Operating Scenario: OS—6 Emission Source/Group ID:IES-06 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 600 End: 1600 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 25% une—Aug. 25% �012 ept.—Nov. 25% 012 012 �012 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2012 Criteria Emissions— Emission Control (NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control Pollutants Code Pollutants Method Code (Net after Factor (Tons/Year) (See Instructions) all controls) 2012 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0 08 HAP/TAP Emissions Emission Control Pollutants (In CAS HAP/TAPS Estimation Emission (see instructions) Method Code Efficiency Factor EF Control Alphabetical Order) (Pounds/Year) (Net after all controls) See Instructions 2012 22 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County :Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2012 1. Emission Source ID(from permit)or IES-07 Emission Source Group ID 2. Emission Source Description: One leachate storage tank 3. Operating Scenario ID/Description: OS—2/temporary storage of collected leachate 4. SCC Number/Description: 40714698/Fixed Roof Tanks—Miscellaneous; Specify In Comments: Working Loss 5. Throughput/units in 2012: 3844493 GAL/yr (e.g.production or fuel use): 6. Fuel Information (if fitel is used) ro Sulfur % Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/see) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 23 Operating Scenario: OS—2 Emission Source/Group ID: IES-07 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throu hput: an—Feb +Dec 25% 25% une—Aug. 25% ept.—Nov. 25% 012 �2rch—May 12 �012 �012 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG GHG Estimation Efficiency Emission CAS Method Ef Control Pollutants Pollutants Code eta fter Factor (Tons/Year) all controls) See Instructions 2012 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po�QS Bode Pollutants Code (Net afterFactor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2012 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0.01 08 Emission CAS Emissions Estimation Control HAP/TAP Efficiency Emission Alphabetical (see RAP/TAPS Method EFControl Pollutants (In AI p (Net after all Factor instructions) (Pounds/Year) Code controls) See Instructions 2012 Benzene 71-43-2 0.16 08 CFC-12 ichlorodifluoromethane 75-71-8 0.08 08 Eth 1 benzene 100-41-4 0.19 08 Methyl ethyl ketone 78-93-3 9.62 08 Methyl isobutyl ketone 108-10-1 0.16 08 Toluene 108-88-3 0.51 08 X lene 1330-20-7 0.42 08 24 Facility Total CY 2012 Emissions Summary Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2012 Record Facility-Wide Totals From all Permitted and Non-Permitted Air Pollutant Emission Sources Green House Gases Pollutants(GHG) Actual Emissions(Tons/Year) Pollutant CAS 2012 1 2011 % Difference Criteria Pollutants Actual Emissions Tons/Year Pollutant CAS 2012 2011 %Difference CO CO 128.09 93.38 37.1707% NOx NOx 30.19 23.81 26.79547% PM TSP TSP 5.84 4 27 16.768154% PM10 PM10 5.84 4.27 36.768154% PM2.5 PM2.5 5.84 4.27 36.768154% S02 S02 4.12 3.12 32.051285% VOC VOC 10.81 10.01 7.992009% Hazardous Air Pollutants HAPS and/or Toxic Air Pollutants TAPs Actual Emissions Pounds/Year Pollutant CAS 2012 2011 1 % Difference Pollutant Grou :Man anese compounds Group Sum:101 Manganese Unlisted Compounds(Specify MNC-Other 101.0 101 0.0% Component of MNC Pollutant Grou :Mercu Compounds-all total mass inc Hg Vapor Group Sum:.26 Mercury,vapor(Component of HGC 7439-97-6 0.26 1 29.999992% Pollutant Grou :Total Reduced Sulfur TRS as total mass G up Sum:1313.76003 Hydrogen s i t I fi de 7783-06-4 1195.4 1128.61003 5.9179025% Methyl merca tan 74-93-1 118.36 111.75 5.9149895% Acetaldehyde 75-07-0 2.4 2.4 0.0% Acrolein 107-02-8 0.3 .3 0.0% Acrylonitrile 107-13-1 0.03001 .02001 49.975014% Benzene 71-43-2 5.73 5.62 1.9572978% Butadiene 1 3- 106-99-0 0.1 .1 0.0% CFC-12 Dichlorodifluoromethane 75-71-8 335.6 312.71 7.3198857% Carbon disulfide 75-15-0 0.02 .02 0.0% 26 Carbon tetrachloride 56-23-5 5.05 4.71 7.218687% Carbonyl sulfide 463-58-1 29.09 27.46 5.9359107% Chlorobenzene 108-90-7 0.02 .02 0.0% Chloroform 67-66-3 0.04 .03 33.333336% Dichlorobenzene , 1,4- 106-46-7 0.04001 .04001 0.0% Ethyl benzene 100-41-4 0.22001 .25001 -11.999526% Ethyl chloride chloroethane 75-00-3 0.01 .01 0.0% Ethyl merca tan 75-08-1 139.97 132.15 5.917524% Ethylene dichloride 1 2-dichloroethane 107-06-2 0.03001 .03001 0.0% Ethylidene dichloride 75-34-3 3.50004 3.26004 7.3618727% 1 1-dichloroethane Formaldehyde 50-00-0 3.6 3.6 0.0% Hexane n- 110-54-3 8.97002 8.47002 5.9031734% Hydrogen chloride(hydrochloric acid 7647-01-0 5292.48 3826.37 38.315945% Methyl chloride 74-87-3 1.0E-5 .00491 -99.79633% Methyl chloroform 71-55-6 0.04001 .04001 0.0% Methyl ethyl ketone 78-93-3 193.72002 184.99002 4.719171% Methyl isobutyl ketone 108-10-1 0.16001 .21001 -23.808393% Methylene chloride 75-09-2 0.08023 .08023 0.0% Perchloroeth lene tetrachloroeth lene 127-18-4 5.74012 5.35012 7.289553% Polycyclic Organic Matter(Inc PAH, Toxins, etc.NC AP 42 historic amorphous POM 74.1 74.1 0.0% lob Propylene dichloride 78-87-5 0.03 .03 0.00/, Tetrachlorocthane 1 1 2 2- 79-34-5 0.03004 .03004 0.0% Toluene 108-88-3 9.1201 8.8101 3.5186937% Trichloroeth lene 79-01-6 0.03007 .03007 0.0% Vinyl chloride 75-01-4 26.06009 23.04009 1 13.107581% Vin lidene chloride 75-35-4 0.02 .02 0.0% X lene 1330-20-7 4.66004 4.53004 2.8697345% 27 Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Comments From Facility: 28 1 East Carolina Environmental Landfill ATTACHMENT B DETAILED EMISSIONS CALCULATIONS SCS ENGINEERS SHEET 1 of 1 c'LILN"f PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Fugitive Landfill Emissions D.GREENE 4/12/2013 CHECKED DATE J.MORGAN 6/7/2013 OBJECTIVE:Calculate Fugitive Landfill Emissions APPROACH:Use USEPA's Landfill Gas Emissions Model(LandGEM)and AP-42 equations and emission factors SOLUTION: (1) Methane and LFG Generation* •As calculated by LandGEM(See Section 2 of 2012 Emission Inventory Report) Estimated LFG Generation/Emission Rates MethaneLGeneration LFG Disposal Refuse Disposal Refuse Generation Fugitive Rate In-Place Rate In-Place Rates Rates Year tons/ r tons M r (D1 ) (m3/yr) cfm 2011 542,909 7,442,454 492,519 6,751.681 2.0571:107 2,764 691 2012 575,739 7,985,363 522,301 7,244,200 2.173E+07 2,920 730 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu futon METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35.314667 cu ft per cu in 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS ENGINEERS SHEET 2 of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Fugitive Landfill Emissions D.GREENE 4/12/2013 CHECKED DATE J.MORGAN 6/7/2013 (2) NMOC and VOC Emissions* •As calculated by LandGEM(See Section 2 of 2012 Emission Inventory Report) NMOC and VOC Generation/E mission Rates NMOC NMOC NMOC N'OC VOC VOC Generation Generation Surface Fugitive Generation Generation Surface Fugitive Rates Rates Rates Rates Rates Rates fear (tons/vr) M /vr) (tuns/yr) (tons/vr) (.til /%r) tons/vr) 2011 96.72 87.75 ' .18 3 .72 34.22 9,43 2012 102.19 92.71 V25.55 39.86 36.16 9.96 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% AP-42 DEFAULT(11/98)VOC CONTENT OF NMOC: 39% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu f/ton METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35.314667 cu ft per cu m 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS ENGINEERS SHEET 3 ot, d CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Fugitive Landfill Emissions D.GREENE 4/12/2013 CHECKED DATE J.MORGAN 6/7/2013 (3) Hazardous Air Pollutant(HAPs) Emissions Methane production= 21,732,828 m3/yr (As caculated by LandGEM,see"Estimated LFG Generation/Emission Methane content of LFG= 50% Rates"table on page I ) Assumed Collection efficiency= 75% Fugitive LFG production=(21,732,828 m3/0.5)*(1-0.75)_ ✓10,866,414 m3/yr Example 1,1,14richloroethane Molecular weight= 133.41 g/gmol Concentration= 0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration Q1.1.16 I..1h"<=(10,866,414 m3)*(0.0003 ppmv/1E+06)= 0.003 m3/yr UMLi,1-M,h1",„„ham,,=(0.003 m3/yr)*[(133.41 g/gmol* 1 atm)/(8.205E-5 m?-alm/gmol-K* 1,000 g/kg•(273+25 K))] UMt.t.i-trcmm"nnene= 0.018 kg/yr UM1,1,1-#wh1.ah.,=(0.018 kg/yr)*(2.2 lb/kg)= 0.039 Ib/yr 1,1,14richloroethane UMt,t.t-m m""nh�r=(0.039 lb/yr)/(2,000 Ib/tn)= 1.96E-05 ton/yr 1,1,1-trichloroethane I SCS ENGINEERS SHEET 4 of 1 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Invento 02209360.07 SUBJECT BY DATE 2012 Fugitive Landfill Emissions D.GREENE 4/12/2013 CHECKED DATE J.MORGAN 6/7/2013 (3)HAP Emissions,continued 2012 Methane Generation(m3/yr)_ t/21,732,828 2012 LFG Generation(m3/yr)= 43,465,656 2012 LFG Fugitive Production(m3/yr)_ V0,866,414 Landfill Gas Temperature ec)r= 25 PollWunl Mol.Wt. colic.' Q(P)' um)" FM(.)' gmol) mv) (in/yr) (k / r) (Ib/ r (ton/ r) (Ibs/ 1,1,1-trichloroethane TAP,HAP 133.41 0.0003 0.00 0.02 0.04 0.00 0.04 0.00 1,1,2,2-tetrachloroethane TAP,HAP 167.85 0.0002 0.00 0.01 0.03 0.00 0.03 0.00 I,1-dichloroethane TAP,HAP 98.97 0.0338 0.37 1.49 3.27 0.00 3.27 0.00 I,1-dichloroetheneT"P'H"P 96.94 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 1,2-dichloroethane TAP,HAP 98.96 0.0003 0.00 0.01 0.03 0.00 0.03 0.00 I._-dichloro ro aneRAP 112.99 0.0003 0.00 0.02 0.03 0.00 0.03 0.00 acrylonitrileTAP,HAP 53.06 0.0005 0.01 0.01 0.03 0.00 0.03 0.00 benzene TAP,HAP 78.11 0.0348 0.38 1.21 2.66 0.00 2.66 0.00 carbon disulfide TAP,HAP 76.13 0.0003 0.00 0.01 0.02 0.00 0.02 0.00 carbon tetrachloride TAP,HAP 153.84 0.0314 0.34 2.15 4.72 0.00 4.72 0.00 carbonyl sulfide""" 60.07 0.4900 5.32 13.08 28.78 0.01 28.78 0.01 chlorobenzene TAP,HAP 112.56 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 chloroethane TAP,HAP 64.52 0.0002 0.00 0.01 0.01 0.00 0.01 0.00 chloroform TAP,HAP 119.39 0.0003 0.00 0.02 0.04 0.00 0.04 0.00 chloromethane TAP,HAP 50.49 0.0001 0.00 0.00 0.00 0.00 0.00 0.00 dichlorobenzeneT"P'H"P 147.00 0.0003 0.00 0.02 0.04 0.00 0.04 0.00 dichlorodifiuoromethaneTAP 120.91 2.6511 28.81 142.46 313.40 0.16 313.40 0.16 dichloromethane TAP,HAP 84.94 0.0010 0.01 0.04 0.08 0.00 0.08 0.00 ethyl merca tan TAP 62.13 2.2800 24.78 62.95 138.50 0.07 138.50 0.07 ethvlbenzene TAP,HAP 106.16 0.0003 0.00 0.01 0.03 0.00 0.03 0.00 cth Iene dibromide TAP'HAP 187.88 0.0002 0.00 0.02 0.04 0.00 0.04 0.00 hexane TAP,HAP 86.18 0.1053 1.14 4.03 8.87 0.00 8.87 0.00 hydrogen sulfide TAP 34.08 35.5000 385.76 537.67 1182.88 0.59 1182.88 0.59 mercury and compounds TAP,HAP 200.61 0.0003 0.00 0.03 0.06 0.00 0.06 0.00 methyl ethyl ketone TAP 72.11 2.5838 28.08 82.80 182.17 0.09 182.17 0.09 methyl isobutyl ketone TAP,HAP 100.16 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 methyl merca tan TAP 48.11 2.4900 27.06 53.24 117.12 0.06 117.12 0.06 erchloroeth leneTAP,H"P 165.83 0.0331 0.36 2.44 5.36 0.00 5.36 0.00 toluene TAP,HAP 92.13 0.0804 0.87 3.29 7.24 0.00 7.24 0.00 trichloroeth Iene TAP,HAP 131.40 0.0002 0.00 0.01 0.03 0.00 0.03 0.00 vinyl chloride TAP,HAP 62.50 0.3983 4.33 11.06 24.34 0.01 24.34 0.01 xylenes TAP,HAP 106.16 0.0318 0.35 150 3,10 0.00 3.30 0.00 Total HAPs Only 13.52 40.50 89.11 0.04 89.11 0.04 Total TAPS Onl --- --- 502.67 906.53 1,994.37 1.00 1,994.37 1.00 Votes: 1.The landfill gas temperature was obtained from AP-42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Generation rate calculated in 2009. 4. Pollutant concentrations used to compute the estimated emissions are from AP42 and Site Specific Testing for the 2005 Compliance Demonstration 5. Q(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3). 6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources. HAP denotes compounds that are classified as hazardous air pollutants per AP-42 and CAA Section 112. SCS ENGINEERS SHEET 1 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inv tory 02209360.07 SUBJECT BY DATE 2012 Flare 1 Emission Calculations-NOx,CO,PM, D.GREENE 1 4/12/2013 NMOC,VOC,5O2,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/7/2013 OBJECTIVE:Calculate flare emissions based on LFG consumption LFG Consumption: 1,098,041,283 scUyr(CY12) Heat Content: 500 Btu/scf(assumed at 50%CH4) Calculated MMBTU: 549,021 MMBtu/yr(CYl2) APPROACH:Use manufacturer data and AP42 equations and emission factors SOLUTION: (1)NOx Emissions NO,emission factor= 0.068 lb/MMBtu (AP-42,Table 13.5-1) LFG consumed= 549,021 MMBtu yr Hours of operation= 8,398 hr/year CMNOx=(0.068 Ib/M1vfBtu)'(549,021 MMBtu/yr)= 37,333.4 1b/yr NOx CMNOx= (37,333.4 lb/yr)/(8,398 hr/yr)= 4.45 Ib/hr NOx CMNOx= (37,333.4 lb/yr)/(2,000 Ib/m)= I R.67 tn/ r NOx (2)CO Emissions CO emission factor— 0.37 Ib/MMBtu (AP42,Table 13.5-1) LFG consumed= 549,021 MMBm/yr Hours of operation= 8,398 hr/year CMCO=(0.370 Ib/MMBtu)•(549,021 MMBtu/yr)= 203,137.6 Ib/ r CO CMCO= (203,137.6 Ib/yr)/(8,398 hr/yr)= 24.19 10 CO CMCO= (203,137.6 Ib/yr)/(2,000 Ib/tn)= 101.57 tn/ r CO (3)PM Emissions PM emission factor= 17 lb/le ft'CH4 (AP42,Section 2.4,Table 2.4-5) LFG consumed= 549,021 MMBtu/yr Hours of operation= 8,398 hr/yr HHV of natural gas= 1,020 Btu/ft' (AP42,Section 3.2) Equivalent amount of CH4 consumed=(549,021 MMBtu/yr)/(1,020 MMBtu/106 M)=538.26 x 10'W CH, CMPM=(17 lb/million ft3 CH4).(538.26 million ft3 CH4) 9,150.3 lb/yr PM CMCO= (9,150.3 Ib/yr)/(8,398 hr/yr)= L4 1.09 Ib/hr PM CMPM= (9,150.3 lb/yr)/(2,000 lb/tn)= 4.58 tn/ r PM SCS ENGINEERS SHEET 1 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inv ntory 02209360.07 SUBJECT BY DATE 2012 are 2 Emission Calculations-NOx,CO,PM, D.GREENE 1 4/12/2013 NMOC,VOC,SOz,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 1 6/7/2013 OBJECTIVE:Calculate flare emissions based on LFG consumption LFG Consumption: 256,554,953 scf/yr(CY 12) Heat Content: 500 Btu/scf(assumed at 50%CH4) Calculated MMBTU: 128,277 MMBtu/yr(CY12) APPROACH:Use manufacturer data and AP-42 equations and emission factors SOLUTION: (1)NOx Emissions NO,emission factor= 0.068 Ib/MMBtu (AP42,Table 13.5-1) LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/year CMNOx=(0.068 Ib/MMBtu)•(128,277 MMBtu/yr)= 8,722.9 lb/ r NOx CMNOx= (8,722.9 lb/yr)/(2,544 hr/yr)= 3.43 Ib/hr NOx CMNOx— (8,722.9 lb/yr)/(2,000 hr/yr)= 4.36 tn/ r NOx (2)CO Emissions CO emission factor= 0.37 Ib/MMBtu (AP42,Table 13.5-1) LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/year CMCO=(0.3701b/MMBtu)'(128,277 MMBtu/yr)= 47,462.7 lb/ r CO CMCO= (47,462.7 Ib/yr)/(2,544 hr/yr)= 18.66 Ib/hr CO CMCO= (47,462.7 Ib/yr)/(2,000 hr/yr)= V1 23.73 tn/ r CO (3)PM Emissions PM emission factor= 17 lb/106 ft'CH4 (AP42,Section 2.4,Table 2.4-5) LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/yr HHV of natural gas= 1,020 Btu/ft' (AP-42,Section 3.2) Equivalent amount of CH4 consumed=(128,277 MMBhdyr)/(1,020 MMBtu/106 ft3)= 125.76 x 106 fl'CH, CMPM=(17 lb/million ft3 CH4)"(125.76 million ft3 CH4) 2,138.0 Ib/ r PM CMCO= (2,138.0lb/yr)/(2,544 hr/yr)= 0.84 lb/hr PM CMPM= (2,138.0 Ib/yr)/(2,000 hr/yr)= 1.07 tn/ r PM SCS ENGINEERS SHEET 2 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare 1 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,S02,Uncombusted HAPs,HCl CHECKED DATE J.MORGAN 6/7/2013 (4)NMOC Emissions -Use the default concentration of NMOC(as hexane)from AP-42 Table 2.4-2. The default NMOC concentration is 595 ppmv. -Use Equations(3),(4),&(5)of AP-42,Section 2.4 to determine NMOC emissions. Molecular weight of hexane= 86.18 g/gmol LFG consumed= 549,021 MMBm/yr Hours of operation= 8,398 hr/yr HHV of landfill gas= 500 Btu/ft' Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/million 113)= 1,098.04 x 10'ft'LFG Eqn(3) QNMOC=(1,098.04 x 10'ft3)*(m3/35.3198 fl )*(595 ppmv/IC6 = 18,498 m'/yr Eqn(4) UMNMoc=(18,498 m3)*[(86.18 g/gmol* 1 arm)/(8.205E-5 m'-atm/gmol-K*1,000 g/kg*(273+25 K))]— UMNMOC= 65,197.2 kg Eqn(5) CMNMOC=[65,197.2 kg*(1 -NcOL/100)]+65,197.2 kg*(NcOL/100)*(1-NcNr/100)] NCOL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. NCNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP42 Table 2.4-3). CMNMOC=65,197.2 kg*(I -100/100)]+65,197.2 kg*(100/100)*(1-99.2/100)]= 521.58 kg CMNMOC=(521.58 kg)*(2.2 lb/kg) = 1 1,147.5 Ib/yr NMOC CMNM0C=(1,147.5 Ib/yr)/(8,398 hr/yr) = 0.14 Ib/hr NMOC CMNMOC=(1,147.5 lb/yr)/(2,000 Ib/tn)= 0.57 to/yr NMOC (5)VOC Emissions -Use Note"c"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexan CMvOC=1,147.5 Ib/yr NMOC*0.39= 447.5 Ib/yr VOC CMvoc=0.14 lb/hr NMOC*0.39= 0.05 Ib/hr VOC CMvoc=0.57 tn/yr NMOC*0.39= 0.22 to/yr VOC SCS ENGINEERS SHEET 2 of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Kc ublic Services 2012 Air Emissions Inventory 02209360.07 tiC'H1ECT BY DATE 2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,S02,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/7/2013 (a)NMOC Emissions -Use the default concentration of NMOC(as hexane)from AP-42 Table 2.4-2. The default NMOC concentration is 595 ppmv. -Use Equations(3),(4),&(5)of AP-42,Section 2.4 to determine NMOC emissions. Molecular weight of hexane= 86.18 g/gmol LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/yr HHV of landfill gas= 500 Btu/ft' Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBtu/million ft3)= 256.55 x l0*ft'LFG Eqn(3) QNMOC=(256.55 x 10'ft3)*(m'/35.3198 ft)*(595 ppmv/10*)= 4,322 m'/yr Eqn(4) UMNmOC=(4,322 m')*[(86.18 g/gmol* 1 arm)/(8.205E-5 m'-attn/gmol-K* 1,000 g/kg*(273+25 K))]_ UMNMOC= 15,233.2 kg Eqn(S) CMNMOC=[15,233.2 kg*(1 -NCOc/100)]+15,233.2 kg*(NcOL/100)*(1-NCNT/100)] NCOL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. NCNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP-42 Table 2.4-3). CMNMOC=15,233.2 kg*(I-100/100)]+15,233.2 kg*(100/100)*(I -99.2/100)]= 121.87 kg CMNMOC=(121.58 kg)*(2.2lb/kg) = 1 268.1 Ib/yr NMOC CMNMOC=(268.1 lb/yr)/(2,544 hr/yr) = 0.11 Ib/hr NMOC CMNMoc=(268.1 Ib/yr)/(2,000 Ib/tn)= 0.13 to/yr NMOC (5)VOC Emissions -Use Note"a"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexan CMvoC=268.1 Ib/yr NMOC*0.39= 104.6 Ib/yr VOC CMvoc=0.11 Ib/hr NMOC*0.39= 0.04 Ib/hr VOC CMvoC=0.13 tn/yr NMOC*0.39= 0.05 tNyr VOC SCS ENGINEERS SHEET 3 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare I Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,S02,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/7/2013 (6)SO2 Emissions -Use Equations(3),(4),&(7)from AP42 Section 2.4 to determine SO2 emissions. 1-12S concentration= 35.5 ppmV AP42 Molecular weight of sulfur(S)= 32 g/gmol Molecular weight of hydrogen sulfide l 34 g/gmol HHV of landfill gas= 500 Btu/ft3 LFG consumed= 549,021 MMBtu/yr Hours of operation= 8,398 hr/yr Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/MM ft3)= 1,098.04 xle ft3 LFG Eqn(3) QH2s= (1,098.04 x 106 ft3)*(m3/35.3198 ft3)*(35.5 ppmv H2S/106)= 1,104 m3 1-12S Qs=(1,104 in 1-12S)*(32 g/gmol S/34 g/gmol 1-2S)= 1,039 m3 S Eqn(4) UMs=(1,039 in 3)*[(32 g/gmol* I atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))]_ UMs= 1,359.42 kg S Eqn(7) CMso2=1,359 kg S*(NCOL/100)*2.0*(98%conversion efficiency of S to 5O2; NCoL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. CMso2=1359.42 kg S*(100/100)*2.0*0.98= 2,664.47 kg/yr CMso2=(2,664.47 kg)*(2.2 lb/kg)= F 5,861.84 Ib/yr SO, CMso2=(5,861.84 lb/yr)/(8,398 hr/yr)_ / 0.70 Ib/hr SO2 CMso2=(5,861.84 lb/yr)/(2,000 hr/yr)_ ✓ 2.93 tn/yr SO2 (7) Hazardous Air Pollutant(HAPs)Emissions -HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs arc substituted into the equations. See Table 3 for a summary of flare HAP emissions. Example 1,1,1-trichloroethane Molecular weight=133.41 g/gmol Concentration=0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration Q1,1,,m61x,,,,h* _(1,098.04 x 106 ft)*(m3/35.3198 ft)*(0.0003 ppmV/106)= 0.0093 tn3/yr CMt,t,t.Q;,h,...„ham,=(0.0093 m3/yr)*[(133.41 g/gmol* I atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))] CM1,1,1-m,h,orm �,= 0.051 kg/yr 1,1,1-trichloroethane CM1,1,1.m6l. h.,=(0.051 kg/yr)*(2.2 lb/kg)*(ton/2,000lb)= 5.60E-05 ton 1,1,1-trichloroethane to flare 1,1,1-trichloroethane=CMt,1,1-mxhmro lh.M(tons/yr)*(1-NCNT/100) NCNT=98%destruction efficiency(AP42 Table 2.4-3) 1,1,1-trichloroethane=5.60e-5tons/yr*(1-(98/100))= I.121I -06 ton1.1,1-trichloroethanetoatmospherc SCS ENGINEERS SHEET 3 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Rc ublic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,5O2,Uncombusted HAPs,HCl CHECKED DATE J.MORGAN 6/7/2013 (6)SO2 Emissions -Use Equations(3),(4),&(7)from AP42 Section 2.4 to determine SQ emissions. H2S concentration= 35.5 ppmv AP42 Molecular weight of sulfur(S)= 32 g/gmol Molecular weight of hydrogen sulfide i 34 g/gmol HHV of landfill gas= 500 Btu/ft' LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/yr Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBhr/MM ft3)= 256.55 xlO'ft'LFG Eqn(3) QH2S= (256.55 x 10'it')*(m/35.3198 ft')*(35.5 ppmv H2S/106)= 258 m'HZS Qs=(258 m'HZS)*(32 g/gmol S/34 g/gmol KS)= 243 m'S Eqn(4) UMs=(243 m')*[(32 g/gmol* 1 atm)/(8.205E-5 m-atm/gmol-K" 1,000 g/kg"(273+25 K))]_ UMs= 317.63 kg S Eqn(7) CMso2=317.63 kg S*(NCOL/100)*2.0*(98%conversion efficiency of S to SO2) NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. CMso2=317.63 kg S*(100/100)*2.0*0.98= 622.55 kg/yr CMso2=(622.55 kg).(2.2 lb/kg)= 1,369.61 Ib/yr SO2 CMso2=(1,369.61 lb/yr)/(2,544 hr/yr) r 0.54 Ib/hr SOZ CMso2=(1,369.61 Ib/yr)/(2,000 hr/yr)= 0.68 to/yr SO2 (7) Hazardous Air Pollutant(HAPs)Emissions -HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs are substituted into the equations. See Table 3 for a summary of flare HAP emissions. Example 1,1,1-trichloroethane Molecular weight=133.41 g/gmol Concentration=0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration QIJ.1.61.1h.a a=(256.55 x 106 ft)*(m'/35.3198 ft')*(0.0003 ppmv/10)= 0.0022 m'/yr CM,,1,1.rr;ch,araa,haaa=(0.0022 m'/yr)*[(133.41 g/gmol* 1 atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))] CMIJJ-, .hiorwha,,,= 0.012 kg/yr 1,1,1-trichloroethane CM,,,,W,hl.mhaaa=(0.012 kg/yr)*(2.2 lb/kg)*(ton/2,000lb)= 1.31E-05 ton 1,1,1-trichloroethane to flare 1,1,1-trichloroethane=CMi,i,,.yi�hiaraathaaa(tons/yr)*(I-NCNT/100) Ncrrr=98%destruction efficiency(AP42 Table 2.4-3) 1,1,1-trichloroethane=1.31e-5 tons/yr*(1-(98/100))= 2.62E07 ton 1,1,1-trichloroethane to atmosphere SCS ENGINEERS SHEET 4 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Invento 02209360.07 SUBJECT BY DATE 2012 Flare I Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,SO,,Uncombustcd HAPs,HCI CHECKED DATE J.MORGAN 6/7/2013 17)HAP Emissions,continued 2012 LFG Consumption(MMBta/yr)= 549,021 HHV of LFG(Btu/ft3) 500 2012 LFG Consumption(ft3/yr)= 1,098,041,283 2012 LFG Consumption(in 3/yr)= 31,088,548 Landfill Gas Temperature(PC)t= 25 Halogenated Destruction Eff.(%)2= 98.0% Non-Halogenated Destruction Eft.(%)r= 99.7 Mercury Compound Destruction Eff.(%)t= 0.0% Pollutant Mol.WI. Cone° Q(p)3 UM( )` Flare Flare if nud (1n% ) (k i r (Ib vr) Ilb i (tn; r 1.1,I-lrichloroethane TAP'IMP 133.41 0.0003 0.01 0.05 0.11 0.00 1.12E-06 I,1,2,2-tetrachlorocthane TAP.IMP 167.85 0.0002 0.01 0.04 0.09 0.00 9.39E-07 I,1-dichlorocthane TAP,IMP 98.97 0.0338 1.05 4.25 9.35 0.19 9.35E-05 1,1-dichlorocthenc TAP'u^P 96.94 0.0002 0.01 0.02 0.05 0.00 5.42E-07 1,2-dichlomethane TAP.HAP 98.96 0.0003 0.01 0.04 0.08 0.00 8.30E-07 1,2-dichloro ro ane HAP 112.99 0.0003 0.01 0.04 0.09 0.00 9.48E-07 au lonlmle T^P'HAP 53.06 0.0005 0.02 0.03 0.07 0.00 I.IIE-07 benzene ' 78.11 0.0348 1.08 3.45 7.60 0.02 1.14E-05 carbon disulfide 76.13 0.0003 0.01 0.03 0.06 0.00 9.58E-08 carbon tetrachloride TA',HAP 153.84 0.0314 0.98 6.14 13.51 0.27 1.35E-04 carbon (sulfide HAP 60.07 0.4900 15.23 37.42 82.33 0.25 1.24E-04 chlorob fide 112.56 0.0002 1 0.01 0.03 0.06 0.00 6.30E-07 hlorocthane 64.52 0.0002 0.01 0.02 0.04 0.00 3.61E-07 hlptefoml TAP.IMP 119.39 0.0003 0.01 0.05 0.10 0.00 1.00E-06 hloromethane TAP.xne 50.49 0.0001 0.00 0.01 0.01 0.00 1.41E-07 ichlorobenzene TAP,HAP 147.00 0.0003 0.01 0.06 0.12 0.00 1.23E-06 ichlorodifluorumcthane TAP 120.91 2.6511 82.42 407.56 896.63 17.93 8.97E-03 ichloromethane TAP.HAP 84.94 0.0010 0.03 0.11 0.24 0.00 2.38E-06 Ali mercy tan TAP 62.13 2.2800 70.88 180.11 396.25 1.19 5.94E-04 th IbenzencHAP 106.16 0.0003 1 0.01 0.04 0.09 0.00 1.34E-07 th leoe dibromide TAP,HAP 187.88 0.0002 0.01 0.05 0.11 0.00 1.05E-06 cxane TAP,HAP 86.18 0.1053 3.27 11.54 25.39 0.08 3.81 E-05 dro en chloride TAP,IMP 7 35.45 42.0000 N/A N/A N/A 4290.10 2.15E+00 dro ct sulfide TAP 34.08 35.5000 1103.64 1538.27 3384.20 10.15 5.08E-03 nercury and compounds TAP,IMP 200.61 0.0003 0.01 0.07 0.16 0.16 8.19E-05 eth I ethyl ketoncTAP 72.11 2.5838 80.33 236.90 521.17 1.56 7.82E-04 eth l isobutylketone TAP,HAP 100.16 0.0002 0.01 0.03 0.06 0.00 8.41E-08 methyl mecca tan TAP 48.11 2.4900 77.41 152.31 335.09 1.01 5.03E-04 rchlorceth Icnc T^P'H^P 165.83 0.0331 1.03 6.97 15.34 0.3I 1.53E-04 toluene,TAP'uAP 92.13 0.0804 2.50 9.41 20.71 0.06 3.11E-05 ttichloroeth lone TAP.HAP 131.40 0.0002 0.01 0.03 0.07 0.00 7.35E-07 vinyl chloride TAP,HAP 62.50 0.3983 12.38 31.65 69.63 1.39 6.96E-04 xylenesTAP.tue 106,16 0.0318 0,99 4.29 9.43 0.03 1.41E-05 Total HAPs Only I I5.88 254.94 4,292.89 2.15 Total TAPS Only -- --- -- 2,593 53 5,705.77 4,324.48 2.16 Notes: 1.The landfill gas temperature was obtained from AP-42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Average flow rate recorded in 2009. 4. Pollutant concentrations used to compute the estimated emissions are from AP-42 and Site Specific Testing for the 2005 Compliance Deomonstration. 5. 0(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3). 6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). 7. HCI emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation she TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources. NA`denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112. 'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112. SCS ENGINEERS SHEET 4 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013 NMOC,VOC,SO,,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/7/2013 7)HAP Emissions,continued 2012 LEG Consumption(MMBtu/yr)= 128,277 HHV of LFG(Btu/B") 500 2012 LFG Consumption(fts/yr)= 256,554,953 2012 LEG Consumption(mrlyr)= 7,263,771 Landfill Gas Temperature($C)I= 25 Halogenated Destruction Eff.(%)r= 98.0% Von-Halogenated Destruction Eff.(%)r= 99.7% Mercury Compound Destruction Eff.(%)r= 0.0% Pollutant Mul,WI, one., Q(P)` UM( )° Flare Flare lin''T0 (k ' r) (lb T) (Ib T) (ttJ I,I 1-trichlorccthancrAenAP 133.41 0.0003 0.00 0.01 0.03 0.00 2.62E-07 1,122-tetrachloroethane TAP'... 167.85 0.0002 0.00 0.01 0.02 0.00 2.19E-07 I,1-dichloroethane TAP HAP 98.97 0.0338 0.25 0.99 2.19 0.04 2.19E-05 1,1-dichloroethenc TAP.HAP 96.94 0.0002 0.00 0.01 0.01 0.00 1.27E-07 1_2-dichloroetbane TAP,HAP 98.96 0.0003 0.00 0.01 0.02 0.00 1.94Ed)' 1.2-dichloro ra ane"A' 112.99 0.0003 0.00 0.01 0.02 0.00 2.22E-07 ac lonitrileTAP,"AP 53.06 0.0005 0.00 0.01 0.02 0.00 2.60E-08 benzeneTAP,1W78.11 0.0348 0.25 0.81 1.78 0.01 2.66E-06 carbon disulfide ' 76.13 0.0003 0.00 0.01 0.01 0.00 2.24E-08 carbon tetrachloride TAP'HAP 153.84 0.0314 0.23 1.44 3.16 0.06 3.16E-05 carbon (sulfide"AP 60.07 0.4900 3.56 8.74 19.24 0.06 2.89E-05 chlorobenzene 112.56 0.0002 1 0.00 0.01 0.01 0.00 1.47E-07 chloroethane 64.52 0.0002 0.00 0.00 0.01 0.00 8.43E-08 chloroform TAP"TAP 119.39 0.0003 0.00 0.01 0.02 0.00 2.34E-07 chloromethane TAP,HAP 50.49 0.0001 0.00 0.00 0.00 0.00 3.30E-08 dichlorobenzene TAP'""' 147.00 0.0003 0.00 0.01 0.03 0.00 2.88E-07 dichlorodifluoromethane TAP 120.91 2.6511 19.26 95.23 209.50 4.19 2.09E-03 ichloromethane TAP'"AP 84.94 0.0010 0.01 0.03 0.06 0.00 5.55E-07 ethyl merca tan TAP 62.13 2.2800 16.56 42.08 92.58 0.28 1.39E-04 th Ibenzenc w 106.16 0.0003 0.00 0.01 0.02 0.00 3.12E-08 th Iene dibromide TAP.HAP 187.88 0.0002 0.00 0.01 0.02 0.00 2.46E-07 hexane TAP HAP 86.18 0.1053 0.77 2.70 5.93 0.02 8.90E-06 hydrogen chloride TAP'HAP' 35.45 42.0000 N/A N/A N/A 1002.37 5.01E-01 hydrogen sulfide TAP 34.08 35.5000 257.86 359.41 790.71 2.37 1.19E-03 mercury and compounds TAP"up 200.61 0.0003 0.00 0.02 0.04 0.04 1.91 E-05 methyl ethyl ketoncTAP 72.11 2.5838 18.77 55.35 121.77 0.37 1.83E-04 methyl isobutyl ketone TAP.IUP 100.16 0.0002 0.00 0.01 0.01 0.00 1.96E-08 methyl merca tan TAP 48.11 2.4900 18.09 35.59 78.29 0.23 1.17E-04 crchluroeth Ienc TAP'HAP 165.83 0.0331 0.24 1.63 3.59 0.07 3.59E-05 toluene T"P.HAP 92.13 0.0804 0.58 2.20 4.84 0.01 7.26E-06 trichloroeth lene TAP,HAP 131.40 0.0002 0.00 0.01 0.02 0.00 1.72F-07 vinyl chlmide TAP'"A' 62.50 0.3983 2.89 7.40 16.27 0.33 1.63E-04 xylenesTAP,HAP 106.16 00318 0.21 100 1-.-10 0.01 131G06 Total HAPs Only --- --- --- 27.08 59.57 1,003.02 0,M Total TAPS Only -- 605.97 1,333.14 1.010.41 0.51 Notes: 1.The landfill gas temperature was obtained from AP42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Average flow rate recorded in 2009. 4. Pollutant concentrations used to compute the estimated emissions are from AP42 and Site Specific Testing for the 2005 Compliance Deomonstration. 5. Q(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3). 6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). T HCI emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation she TAP denotes compounds that are classified as toxic air pollutants par North Carolina Department of Environment and Natural Resources. "AP denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112. 'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112. SCS ENGINEERS SHEET 5 of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare 1 - Emissions D.GREENE 4/15/2013 Uncombusted HCI CHECKED DATE J.MORGAN 6/7/2013 (8)HCI Emissions -Use Equations(3),(4),8c(10)from AP-42 Section 2.4 to determine HCl emissions. HCI concentration= 42.0 ppmv (AP-42,Page 2.4-9) Molecular weight of chlorine(CI)= 35.453 g/gm01 HHV of landfill gas= 500 Btu/ft3 LFG consumed= 549,021 MMBtu/yr Hours of operation= 8,398 hr/yr Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/MM ft3)= 1,098.04 x I C�ftt LFG Eqn(3) QS= (1,098.04 x MM ft3)*(m3/35.3198 113)*(42.0 ppmv Cl/IV6)= 1,305.72 m'Cl Eqn(4) UMCI=(1,305.72 m3)*[(35.453 g/gmol* I atm)/(8.205E-5 m3-atm/gmol-K* 1,000 g/kg*(273+25 K))]_ UMcj= 1,893.2 kg Cl Eqn(10) CMHCI=1,893.2 kg Cl* (NCOL/100)* 1.03*(NCNT/100) NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. Ncrrr=100%Assume the flare is capable of converting 100%of the Cl to HCI. CMHCI=1,893.2 kg Cl*(100/100)* 1.03*(100/100)= 1,950.0 kg/yr HCI CMHCI=(1,950.0 kg)*(2.2 lb/kg) = 4,290.1 Ib/ r HCI CMHCI=(4,290.1 lb/yr)/(8,760 hr/yr)= 0.51 Ib/hr HCI CMHCI=(4,290.1 Ib/yr)/(2,000 lb/tn)= 2.15 tn/yr HCI SCS ENGINEERS SHEET 5 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Flare 2 - Emissions D.GREENE 4/15/2013 Uncombusted HCI CHECKED DATE J.MORGAN 6/7/2013 (8)HCI Emissions -Use Equations(3),(4),&(10)from AP-42 Section 2.4 to determine HCI emissions. HCI concentration= 42.0 ppmv (AP42,Page 2.4-9) Molecular weight of chlorine(Cl)= 35.453 g/gmol HHV of landfill gas= 500 Btu/ft3 LFG consumed= 128,277 MMBtu/yr Hours of operation= 2,544 hr/yr Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBtu/MM ft3)= 256.55 xl V f?LFG Eqn(3) QS= (256.55 x MM 0)*(m3/35.3198 ft3)*(42.0 ppmv CU10^6)= 305.09 m3 Cl Eqn(4) UMCI=(305.08 m3)*[(35.453 g/gmol* 1 atm)/(8.205E-5 m3-atm/gmol-K" 1,000 g/kg*(273+25 K))]_ UMC,= 442.4 kg CI Eqn(10) CMHCI=0,442.4 kg Cl* (NCOL/100)* 1.03*(NCNT/100) NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. NcNT=100%Assume the Flare is capable of converting 100%of the CI to HCI. CMHCI=442.4 kg CI*(100/100)*1.03*(100/100)= 455.6 kg/yr HCI CMHCI=(455.6 kg)*(2.2 lb/kg) = 1,002.4 Ib/ r HCI CMHCI=(1,002.4 Ib/yr)/(8,760 hr/yr)= 0.39 Whir HCI CMHCI=(1,002.4 Ib/yr)/(2,000 lb/tn)= 0.50 tn/ r HCI SCS ENGINEERS SHEET I of 3 CLIENT PROJECT East Carolina Environmental landfill JOB NO. Republic Services 2012 Air Emissions Inventory02209360.07 SUBJECT BY DATE 2012 insignificant Sources-Solar Flares(TES-08) 1D.GREENE 4/15/2013 CHECKED DATE J.MORGAN 6/7/2013 OBJECTIVE:Estimate emissions resulting from the use of small solar spark flares APPROACH:Use manufacture and site provided data SOLUTION: Number of Solar Flares in operation during CY2012: 3 Estimated flow per flare: 60 scfin Total Estimated Flow: 180 sefin Solar Flare Usage 8 hrs/day 365 days/ycar 175,200 min/yr 1)NOx Emissions NOx Emissions Rate 0.072 Ibs Nox/hr/Flare Total NOx Emisisons 0.216 Ibs Nox/hr 630.72 Ib/ r NOx 0.22 Ib/hr NOx 0.32 tnh r 1, (2)CO Emissions CO Emissions Rate 0.302 Ilia CO/hr/Flare Total CO Emisisons 0.906 Ibs CO/hr 2,645.52 Ib/ r CO 0.91 Ib/hr CO 1.32 tn/ r CO 13)I'M Emissions PM Emissions Rate 0.031 Ibs PM/hr/Flare Total PM Emisisons 0.093 Ibs PM/hr 271.56 Ib/ r PM 0.09 Ib/hr PM 0.14 tn/ r PM SCS ENGINEERS SHEET 2 of 3 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT I BY DATE 2012 Insignificant Sources-Solar Flares(JES-08) ID.GREENE 4/15/2013 CHECKED DATE J.MORGAN 6/7/2013 OBJECTIVE:Estimate emissions resulting from the use of small solar spark Bares APPROACH:Use manufacture and site provided data SOLUTION: Number of Solar Flares in operation during CY2012: 3 Estimated Bow per Bare: 60 scfm Total Estimated Flow: 180 scfm Solar Flare Usage 8 hrs/day 365 days/year 175,200 min/yr (1)SO= Emissions SOz Emissions Rate 0.014 IN SOZ/hr/Flare Total SO,Emisisons 0.042 Ibs SOr/hr 122.64 Ib/yr SOi 0.04 Ib/hr SO, 0.06 to/yr SOr 2)VOC Emissions VOC Emissions Rate 0.004 Ibs VOC/br/Flare Total VOC Emisisons 0.012 Ibs VOC/hr 35.04 Ib/ r VOC 0.01 Ib/hr VOC 0.02 tn/yr VOC 3)NMOC Emissions Per AP42,assume NMOC=1/0.39 of VOC 89.85 Ib/ r NMOC 0.39 VOC to NMOC 0.03 lb/hr NMOC 0.04 to/yrNMGC SCS ENGINEERS SHEET 3 of 3 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Insignificant Sources-Solar Flares(IES-08) D,GREENE 4/15/2013 CHECKED DATE J.MORGAN 6/7/2013 Emissions Rates based upon data for compounds common with main Flare and listed by manufacturer Total Solar Flares: 3 Operational year: 33.3% (percent of full year as operated at 8 hr/d) Hydrogen chloride emissions calculated from ratio of Solar Flare H2S emission to Main Flare H2S emission: Main Flare H2S Emissions*(Solar Flare H2S Emissions/Main Flare 112S Emissions)= 0.01 lbs/yr Pollutant Mot,Wt. Flare Flare Fl 3 3 ares (g/�mol) (16/ r) (in/T) (Ibl eriodFlaresr) tn'teriod vr) I,1,1-tnchloroethane TAP HAP 133.41 1.2E-05 6.00E-09 1.20E-05 6.00E-09 1,1,2,2-tetrachloroethane TAP.HAP 167.85 3.5E-05 1.75E-08 3.50E-05 1.75E-08 1,1-dichloroethane TAP'HAP 98.97 4.4E-05 2.20E-08 4.40E-05 2.20E-08 ro I,1-dichloetheneTAP'HAP 96.94 3.7E-06 1.85E-09 3.70E-06 1.85E-09 1,2-dichloroethane TAP,HAP 98.96 7.6E-06 3.80E-09 7.60E-06 3.80E-09 1,2-dichloro ro aneHAP 112.99 3.9E-06 1.95E-09 3.90E-06 1.95E-09 ac IonitrileTAP,HAP 53.06 9.6E-06 4.80E-09 9.60E-06 4.80E-09 benzene TAP,HAP 78.11 4.2E-06 2.10E-09 4.20E-06 2.10E-09 TAP,HAP carbon disulfide 76.13 1.3E-06 6.50E-10 1.30E-06 6.50E-10 carbon tetrachloride TAP'HAP 153.84 1.2E-07 6.00E-11 1.20E-07 6.00E-1 I carbonyl sulfide t AP 60.07 8.4E-07 4.20E-10 8.40E-07 4.20E-10 chlorobenzene TAP,HAP 112.56 5.4E-06 2.70E-09 5.40E-06 2.70E-09 chloroform TAP'HAP 119.39 6.8E-07 3.40E-10 6.80E-07 3.40E-10 chloromethane TAP.HAP 50.49 1.2E-05 6.00E-09 1.20E-05 6.00E-09 dichlorobenzene TAP.uAP 147.00 5.9E-06 2.95E-09 5.90E-06 2.95E-09 dichlorodifluoromethaneT5 120.91 3.4E-06 1.70E-09 3.40E-06 1.70E-09 dichloromethane TAP. [AP 84.94 2.3E-04 1.15E-07 2.30E-04 1.15E-07 ethyl merca tan TAP 62.13 4.0E-06 2.00E-09 4.00E-06 2.00E-09 eth (benzene 1AP 106.16 1.4E-05 7.00E-09 1.40E-05 7.00E-09 ethylene dibromide TAP,HAP 187.88 3.6E-08 1.80E-II 3.60E-08 1.80E-II hexane TAP,HAP 86.18 1.6E-05 8.00E-09 1.60E-05 8.00E-09 hydrogen sulfide TAP 34.08 3.4E-05 1.70E-08 3.40E-05 1.70E-08 mercury and compounds TAP'HAP 200.61 5.6E-07 2.80E-10 5.60E-07 2.80E-10 methyl ethyl ketone TAP 72.11 1.5E-05 7.50E-09 1.50E-05 7.50E-09 methyl isobut I ketone TAP'HAP 100.16 5.3E-06 2.65E-09 5.30E-06 2.65E-09 meth (merca tan TAP 48.11 3.4E-06 1.70E-09 3.40E-06 1.70E-09 erchloroeth IeneTAP'HAP 165.83 1.2E-04 6.00E-08 1.20E-04 6.00E-08 toluene TAP,HAP 92.13 LOE-04 5.00E-08 1.00E-04 5.00E-08 trichloroeth IeneTAP.uAP 131.40 7.0E-05 3.50E-08 7.00E-05 3.50E-08 vinyl chloride TAP HAP 62.50 8.7E-05 4.35E-08 8.70E-05 4.35E-08 xylenesTnr.nAP 106.16 3.7E-OS 1.85E-08 3.70E-05 1.85E-08 Tota111APs,'I'APS --- 8.9E-04 4.43E-07 8.86E-04 443E-07 SCS ENGINEERS SHEET 1 of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory02209360.07 SUBJECT BY DATE 2012 Storage Tank Emissions D.GREENE 4/15/2013 CHECKED DATE J.MORGAN 6/7/2013 OBJECTIVE:Insiginificant source tank emissions based on design capacity and throughput APPROACH:Use EPA's TANKS 4.09 Program SOLUTION: The following information was entered into TANKS 4.09: Parameter Diesel Tank Product Diesel Fuel Volume,gal 3,000 Length,ft 15 Diameter,It 5.8 Throuh ut,gal/yr 153,019 As reported by TANKS 4.09(see attached report): Diesel Tank 3 000 al Pollutant Ib/ r ton/ r VOC 4.47 2.24E-03 NMOC' 4.47 2.24E-03 NMOC emissions are conservatively estimated to be equal to VOC emissions. For emissions purposes waste oil modeled as Petroleum Distillate#2 SCS ENGINEERS SHEET 1 of I CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Leachate Tanks Emission Calculations-NMOC,VOC,HAPs D.GREENE 4/15/2013 CHECKED DATE J. MORGAN 6/7/2013 OBJECTIVE:Calculate emissions for leachate storage tanks based on laboratory analysis and throughput APPROACH:Use mass balance approach,assumes that all organic content volatilizes. SOLUTION: Leachate throughput: 3,844,493 gal/yr (Data obtained from landfill) Organic content: 547.3 µg/L (See Below) CMva=(547.3 µg/L)*(3,844,493 gal/yr)*(3.785 L/gal)*(1 lb/453.6E+03 mg)*(I mg/1,000 µ 17.56 Ib/yr VOC CMva._(17.56 Ib/yr)/(8,760 hr/yr)= 2.00E-03 Ib/hr V OC CMva=(17.56 lb/yr)/(2,000 lb/tn)= 8.78E-03 ton/yr VOC Note: VOC emissions are conservatively estimated to equal NMOC,HAP,and TAP emissions. VOc P91L Ib/ r Ib/d Acetone 200 6.42 1.76E-02 Benzene 5 0.16 4.39E-04 Dichloromethane 2.5 0.08 2.20E-04 Ethyl benzene 5.8 0.19 5.10E-04 Methyl Ethyl Ketone 300 9.62 2.64E-02 Methyl Isobut I Ketone 5 0.16 4.39E-04 Toluene 16 0.5] 1.41E-03 X lenes 13 0.42 1.14E-03 547.3 Notes: 1 "Municipal Solid Waste Landfill Leachate Charatcterization Study,"Environmental Research&Educationa. Foundation,September 2007,(Table 4"Extended VOCs") Assumes data is representative of East Carolina Landfill leachate VOC content(Table 4"Extended VOCs") 2 Acetone neither HAP or TAP,but included as a VOC for VOC purposes SCS ENGINEERS SHEET 1 of I CLIENT PROJECT East Carolina Environmental landfill JOB NO. Republic Services 2012 Air Emissions Inventory 02209360.07 SUBJECT BY DATE 2012 Facility Wide Emissions Summary .GREENE 4/15/2013 CHECKED DATE J.MORGAN 6/7/2013 Welding Diesel Diesel Leachate Solar Pollutant L Elarel Flare) Tank Engines Operation Took Flares TOTAL TOTAL (lb/yrb/yr) (Ib/yr) (Ib/yr) (Ib/yr) (lb/yr) s (Iblyr) (Ib/yr) pb/yr) todyr (lb/yr) Oz --- 37,333 8,723 13,680 631 60,367 30.18 S02 5,862 1,370 900 122.6 8,254 4.13 CO 203138 47,463 2,940 2646 256,186 128.09 PM --- 9,150 2,138 100 - -- 272 11,660 5.83 MOC 51.097 1,147.5 268.1 4.47 17.56 89.8 52625 26.31 VOC 19,928 447.5 104.6 4.47 1100 17.56 35.0 21,637 10.82 I11-bichloroethane TAP,HAP 0.04 0.00 0.00 1.20E-05 0.04 2.10E-05 1,1 2,2-tetrachloroethane TAP,HAP 0.03 0.00 0.00 3.50E-05 0.03 1.74E-05 1,1-dichloroethane TAP,HAP 3.27 0.19 0.04 4.40E-05 3.46 1.73E-03 I I-dicbloroethene TAP,HAP 0.02 0.001 0.00 3.70E.06 0.02 I.00E-05 1 2-dichloroethane TAP,HAP 0.03 0.002 0.00 7.60E-06 0.03 1.53E-05 1 2-dichloro ro ane HAP 0.03 0.002 0.00 3.90E-06 0.04 1.75E-05 acetaldehyde 2.40 2.40 1.20E-03 acrolein 0.30 0.30 1.50E-04 acrylonithic TAP,HAP 0.03 0.0002 0.00 9.60E-06 0.03 1.31E-05 dune TAP,HAP 2.66 0.02 0.01 2,90 0.16 4.20E-06 5.74 2.87E-03 carbon disulfide TAP,HAP 0.02 0.0002 0.00 1.30E-06 0.02 1.13E-05 carbon tetrachloride TAP,HAP 4.72 0.27 0.06 1.20E-07 4.99 2.50E-03 carbonyl sulfide HAP 28.78 0.25 0.06 8.40E-07 29.03 1.45E-02 chlorobenzene TAP,HAP 0.02 0.00 0.00 5.40E-06 0.02 1.16E-05 chloroethane TAP,HAP 0.01 0.00 0.00 0.01 6.67E-06 chloroform TAP,HAP 0.04 0.002 0.00 6.80E-07 0.04 1.85E-05 chloromethane TAP,HAP 0.005 0.0003 0.00 1.20E-05 0.01 2.62E-06 dichlorobenzene TAP,HAP 0.04 0.00 OM 5.90E-06 0.05 2.28E-05 dichlorodifluoromethane TAP 313.40 17.93 4.19 0.08 3.40E-06 331.34 1.66E-01 ichloromethane TAP,HAP 0.08 0,00 0.00 2.30E-04 0.17 8.41E-05 cdi I mecca tan TAP 138.50 1.19 0.28 4.00E-06 l39.69 6.98E-02 eth (benzene TAP,HAP 0.03 0.00 0.00 0.19 1.40E-05 0.22 1.09E-04 ethylene dibromide TAP,HAP 0.04 0.00 0.00 3.60E-08 0.04 1.94E-05 formaldehyde 3.60 3.60 I.80E-03 hexane TAP,HAP 8.87 0.08 0.02 1.60E-05 8.97 4.48E-03 h dro en chloride TAP.HAP 4,290 1002.37 1.44E-02 5292.49 2.65E+00 h dro en sulfide TAP 1,182.88 10.15 2.37 3.40E-05 1195.41 5.98E-01 Manganese 101.00 101.00 5.05E-02 nercury and compounds TAP,HAP 0.06 0.16 0.04 5.60E-07 0.26 1.30E-04 methyl ethyl ketone TAP 182.17 1.56 0.37 9.62 1.50E-05 193.72 9.69E-02 methyl isobut I ketone TAP,HAP 0.02 0.00 0.00 0.16 5.30E-06 0.18 9.01E-05 methyl merca tan TAP 117.12 1.01 0.23 3.40E-06 118.36 5.92E-02 I c chc organic matter 74.10 74.10 3.71E-02 erchloroeth lene TAP,HAP 5.36 0.31 0.07 I.2011-04 5.74 2.87E-03 toluene TAP,HAP 7.24 0.06 0.01 1.30 0.51 1.00E-04 9.13 4.56E-03 tdchloroeth lene TAP,HAP 0.03 0.00 0.00 7.00E-05 0.03 1.38E-05 1 uni dil,nde TAP,HAP 24.34 1.39 0.33 8.70E-05 46.21 2.31E-02 x genes TAP,HAP 3.30 1 0.03 0.01 0.90 0.42 3.70E-05 4.65 2.32E-03 Total HAPs Only li 2,034.26 1 4,292.39 1 1,003.02 85.50 101.00 1.52 0.02 7,518.03 3.76 Total TAPS Only2,039.59 4,324.49 1,010.41 85.50 101.00 9.62 0.02 7,565.03 3.78 Notes: r u em.,a,.�.e,w1 .,a„as,a 1....,wuw,w�HnN t uelx hplwu^N Fina®m a1 x,u,1 r.+�..+ HAP eennrv.i.nw.ml.iN ue.I,aankJ as-&-a IoIl IMAl4I CAAL 112 •Th com mnds lisud abavc were com ilcd from AP42(mvlsed Nov.1998)and CAA Section 112. TANKS 4.0 Report Page 1 of 6 TANKS 4.0.9d Emissions Report-Detail Format Tank Indentification and Physical Characteristics Identification User Identification: ECE Tank 01 City: Aulander Stale: North Carolina Company: Republic Services of NC,LLC Type of Tank: Horizontal Tank Description: Tank Dimensions Shell Length(it): 15.00 Diameter(k): 5.90 Volume(gallons): 3,000.00 Tumovem: 0.00 Net Throughput(gal/yr): 153,019.00 Is Tank Heated(y/n): N Is Tank Underground(y/n): N Paint Characteristics Shell Color/Shade: Gray/Medium Shell Condition Good Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig) 0.03 Meterological Data used in Emissions Calculations:Norfolk,Virginia(Avg Atmospheric Pressure=14.75 psia) file:///C:/Program°/D2OFilesg/o20(x86)/Tanks4O9d/summarydisplay.htm 6/13/2013 TANKS 4.0 Report Page 2 of 6 TANKS 4.0.9d Emissions Report-Detail Format Liquid Contents of Storage Tank ECE Tank 01 -Horizontal Tank Aulander,North Carolina uewe Dairy UeuiedZ BWN Vepa LIyuM Ve empMe TW F) Temp VaporP . (PM) Meu Moe.. W. BmeM1r VaparFinan Mi.tu�e/Com{wneni MmB, qvg MN.. eB Mu. le F) Ary. W MM. Mu. Wept0L Fie. Feel WaBl,l Caku4tlau Oisuila,e fuei oil no x M am SBA" rr.49 Q.W 0.O 0.M 0.0112 12OAOOO IMM opti tVPBO=.GOBS MO-.00B file:///C:/Program%20Files%20(x 86)/Tanks4O9d/summarydi splay.htm 6/13/2013 TANKS 4.0 Report Page 3 of 6 TANKS 4.0.9d Emissions Report-Detail Format Detail Calculations(AP-42) ECE Tank 01-Horizontal Tank Aulander,North Carolina Annual Emission Calmulaams Standing Lasaea Rb). 1.217I Vapor Spam volume(.ft) 252,4280 Vapor Densely Ilblcu ft) 0.00p2 Vapor Spam Eapanaan FaWd. 0.0822 Vented Vapor Samna.Facbr. 0.9987 Tank Vapor Spam Vdwns: Vapor Spam Vduma(m it). 252A260 Tank Demeter(ft): 5.8000 EReave Daman,(ft). 1.5275 Vapor Spam OUMge pit. 29000 Tank Shall Langer(n). MODD) Vapor Dan id, Vapor Denalty(Ib/m nl: D0003 VePM Mdaagw Wa9kl(dlbmde)'. 13 OM) Vapm Pressure at Only Average Liquid Stakm TempemWM(1..), 0.0085 Daily A,,,Lagwd Sudaim Temp.plait.R): 522.2a60 Daly Avenge Ambiem Temp.(lag.F) 59.2MB Waal Gas Constam R (psia tuft/(Wmol,"R)('. 10131 Lewd Bulk TamppaWm(dp.R). 521.9708 Tank Paint err Abxaptaam(SbNI) 0.6800 Daily Tonal Solar Inauletmn Fades(OW1,11 day). 1.327.3255 Vapor Spam Eayanno,FMW Vepm Spam Eamnvm Fedor: 0.0877 Deily Vapor Temperature Range(leg.R): 37.6743 Dady Vapor Pressure Range(Pala)'. DM50 BresMa Vent PMsa.Selling Ran on,da): DOM Vepm Prea tune at Daly Avenge LiquW Sudan T.MinaWM(Pall) 0.0085 Vapor Pressure at Daily Minimum UWW SmMm Tampaream(P.). 0.0062 Vapor Pressure at Daily Meimum LWuW Smlam Temperate(Pala) 0.0112 Daily AW,Ligwd Sumice Temp(leg R). 5271a60 Daily Min.LW Wd Sudara Tang.(d,R). 518.3275 Daily Max.kgwd SMlam Tarp.(de,,R): 537.16s6 Daily A ni ant Temp.Range(dap.R). 17.22W VWMI Vamr SaWmbm Fwtor V W W Vapor Saturation Fedor. 0.9987 Vapor Preseme al Wily Amrpa Ln al: Sudan Temperaure(pall): 00085 vapor Spam Duege(ft) S 9000 Wank,Cusses db): 4.0349 Vapor McWcula Weight Dtalbmde): MOM Vapor Pdal at Daly innakee LqW SIWam Tamperate(P.). O'IMS Annual Net Tbrougk Wt(BetAyr.): 153.019.0DDD Amual TMro , 0.0000 I.,F.W. 1.0000 Tank Damodar(R): 5MI00 Working Was Pri Farb: 1.00D0 TgW W.pb) 5.2W3 file:///C:/Program%20Files%20(x 86)/Tanks4O9d/summarydisplay.htm 6/13/2013 TANKS 4.0 Report Page 5 of 6 TANKS 4.0.9d Emissions Report-Detail Format Individual Tank Emission Totals Emissions Report for:Annual ECE Tank 01-Horizontal Tank Aulander,North Carolina Losses(lbs) Components Working Loss Breathing Loss Total Emissions Distillate fuel oil no.2 4.03 1.22 5.25 file:///C:/Program%20Files%20(x86)/Tanks4O9d/summarydisplay.htm 6/13/2013