HomeMy WebLinkAboutAQ_F_0800102_20130826_EI_Cmb-EI-File QAPP Audit Form for CY2012 Point Source El data submittals
Facility Name:, oS+ Coi-d'i 0.,6V, L Facility lU:
Permit Number:13td Assigned to: Confi ential Copy Submitted?
Region: W Alt U 0� W YES ❑ NO
�R,O
Initial Review/Data Entry
Receipt of EI properly documented
(If submitted through AERO, Receipt of Certification form entered in ED
�Das El received by June 30 deadline. 1 not, was the failure to meet the deadline documented?
ata entry complete date entered �°a 13 _
ate Approval Due: 011s,4116
Comments: ' �r.ca G �►-� �r��SS�+�`�S ���2� ��11 Qj, cl �OI�
CC1i _�1.or_ tsN S_ cl v�a- i►1crLG5,t�{ Wt t«h� c rc�
I_n/yentory Audit (verify that the checks below at a minimum have been in%estigated and doeume► t,,(�
U�I &11 forms appear to be complete and certification form was signed by appropriate ollicial.
LYEmissions reported for all sources (permitted, insignificant, and unpermitted) or marked as not operated or NR I
!t
VSupporting calculations, control and/or capture efficiencies and emission factor documentation included and apl eat s
orrect.
Ur All known OSs, control devices and release points reported for each emission source.
All emissions above de minimus levels have been reported for all emission sources.
Emission Factors are best available/most current.
p� Calculations and facility totals add up correctly.
fy 'All QA/QC issues addressed.
Comparison with previous emission inventory has been conducted; obvious outliers have been investigated and
��/,t�xplained.
Vod 11 changes/corrections were made to the inventory and documented either on paper or DataEntry Main page.
U� Appropriate additional comments entered on DataEntryMain page.
Auditor signature ,
Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102
Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2012 CY 2011
frgULfJL. from Fees
Acrolein 107-02-8 0.300000 0.300000 0.0%
Acrylonitrile 107-13-1 0.030010 0.020010 50.0%
Benzene 71-43-2 5.73 5.62 2.0%
Butadiene, 1,3- 106-99-0 0.100000 0.100000 0.0%
Carbon disulfide 75-15-0 0.020000 0.020000 0.0%
Carbon tetrachloride 56-23-5 5.05 4.71 7.2%
Carbonyl sulfide 463-58-1 29.09 27.46 5.9%
CFC-12 (Dichlorodifluoromethane) 75-71-8 335.60 312.71 7.3%
Chlorobenzene 108-90-7 0.020000 0.020000 0.0%
Chloroform 67-66-3 0.040000 0.030000 33.3%
Dichlorobenzene(p), 1,4- 106-46-7 0.040010 0.040010 0.0%
Ethyl benzene 100-41-4 0.220010 0.250010 -12.0%
Ethyl chloride (chloroethane) 75-00-3 0.010000 0.010000 0.0%
Ethyl mercaptan 75-08-1 139.97 132.15 5.9%
Ethylene dichloride(1,2-dichloroethane) 107-06-2 0.030010 0.030010 0.0%
Ethylidene dichloride (1,1-dichloroethane) 75-34-3 3.50 3.26 7.4%
Formaldehyde 50-00-0 3.60 3.60 0.0%
Hexane, n- 110-54-3 8.97 8.47 5.9%
Hydrogen chloride (hydrochloric acid) 7647-01-0 5,292.48 3,826.37 38.3%
MEK (methyl ethyl ketone, 2-butanone) 78-93-3 193.72 184.99 4.7%
Methyl chloride (chloromethane) 74-87-3 0.000010 0.004910 N/A
Methyl chloroform 71-55-6 0.040010 0.040010 0.0%
Methylene chloride 75-09-2 0.080230 0.080230 0.0%
MIBK (methyl isobutyl ketone) 108-10-1 0.160010 0.210010 -23.8%
Perchloroethylene (tetrachloroethylene) 127-18-4 5.74 5.35 7.3%
Polycyclic Organic Matter(Inc PAH, dioxins, etc. NC POM 74.10 74.10 0.0%
& AP 42 historic)
08/12/2013 Page 2 of 3
Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102
Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2012 CY 2011
from ED from Fees I
Propylene dichloride (1,2-dichloropropane) 78-87-5 0.030000 0.030000 0.0%
TCE (trichloroethylene) 79-01-6 0.030070 0.030070 0.0%
Tetrachloroethane, 1,1,2,2- 79-34-5 0.030040 0.030040 0.0%
Toluene 108-88-3 9.12 8.81 3.5%
Vinyl chloride 75-01-4 26.06 23.04 13.1%
Vinylidene chloride 75-35-4 0.020000 0.020000 0.0%
Xylene (mixed isomers) 1330-20-7 4.66 4.53 2.9%
Largest Individual HAP Hydrogen chloride (hydrochloric acid) 5,292.48 Ibs
Total HAP Emissions 5,572.9G Ibs
DAO's Comments Reeardine Inventory
Reviewer changed from Hopkins to Mangum-R Fisher.Facility requested end-dating or removal of CS-2 and CS-3. Betsy I
end-dated CS-2,and was able to delete CS-3. Also requested end-dating CD-GCCS 1,but this has been permitted as a contrc
rather than a descriptor.
08/12/2013 Page 3 of 3
Facility Total CY 2012 Emission Summary Recorded in ED Facility ID #: 0800102
Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T07
Green House Gases Pollutants(GHG) Actual Emissions
Tons/Yr % Change
Pollutant CAS
Not Not N/A
Reported Reported
CO2 equivalent(sum of individual GHG pollutant emission times their 99Ao GHGs
IPCC Global Warming Potential(GWP), converted to metric tons) Reported
Criteria Pollutants Actual Emissions % Change
(Tons/Year)
Pollutant CAS CY 2012 CY 2011
CO CO 128.09 93.38 37.2%
NOx NOx 30.19 23.81 26.8%
PM(TSP) TSP 5.84 4.27 36.8%
PM10 PMIO 5.84 4.27 36.8%
PM2.5 PM2.5 5.84 4.27 36.8%
S02 S02 4.12 3.12 32.1'%
VOC VOC 10.81 10.01 8.0%
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2012 CY 2011
from ED from Fees I
Manganese& compounds 101.00 101.00 0.0%
Manganese Unlisted Compounds-Specify MNC-Other 101.00 101.00 0.0%
Compound(Component of MNC)
Mercury & Compounds-all total mass includes Hg Vapor 0.260000 0.200000 30.0%
Mercury, vapor (Component of HGC) 7439-97-6 0.260000 0.200000 30.0%
Total Reduced Sulfur(TRS as total mass) 1,313.76 1,240.36 5.9%
Hydrogen sulfide 7783-06-4 1,195.40 1,128.61 5.9%
Methyl mercaptan 74-93-1 118.36 111.75 5.9%
Acetaldehyde 75-07-0 2.40 2.40 0.0%
08/12/2013 Page 1 of 3
SCS Engineers, P.C.
Environmental Consultants 2520 Whitehall Park Drive 704 504-3107
and Contractors Suite 450 FAX 704 504-3174
Charlotte, NC 28273-3557 www.scsengineers.com
SCS ENGINEERS ,, PC
June 24,2013
File No.02209360.07 T7
Mr.Robert Fisher
Regional Supervisor
NCDENR Division of Air Quality
Washington Regional Office
943 Washington Square Mall
Washington,NC 27889
Subject: CY2012 Annual Emission Inventory
East Carolina Environmental Landfill—Aulander,North Carolina
Title V Permit No: 08849T05
Dear Mr. Fisher:
On behalf of the East Carolina Environmental Landfill, SCS Engineers,PC is pleased to submit this
Annual Emission Inventory Report for the East Carolina Environmental located in Aulander, North
Carolina. This report is intended to satisfy Title V Permit Condition X. The purpose of the Report is
to inventory emissions that occurred during the period of January 1, 2012 and December 31,2012.
If you have any questions or comments about this submittal,please contact either of the undersigned
at(704)504-3107.
Sincerely,
,Z
J Morgan,P.E. Steven C.Lamb,P.E.
Project Manager Vice President
SCS ENGINEERS,PC SCS ENGINEERS,PC
Enclosure
cc: Matt Einsmann,P.E.,Environmental Manager,Republic Services of NC,LLC
Matt East, General Manager,East Carolina Environmental Landfill
M:TROrECr FlLESVI2209360 EAST CAROLINA ENVIRONMENTAU02209360.07-ECE 2013 Tkk V ServicesUask 7-Emissions Inv ntory%ECE 2012 cov rlener.doc
N �i3
East Carolina Environmental Landfill
REPUBLIC
4#14 SERVICES
East Carolina Environmental Landfill
2012 Emission Inventory
Air Permit 08849T05
Presented to:
Republic Services of North Carolina, LLC
East Carolina Environmental Landfill
1922 Republican Road
Aulander, NC 27805
Presented by:
SCS Engineers, PC
2520 Whitehall Park Drive, Suite 450
Charlotte, North Carolina 28273
(704) 504-3107
D
JUN 2 6 2013
June 17, 2013
File No. 2209360.07 --
East Carolina Environmental Landfill
Table of Contents
Section Page
SECTION1 Introduction........................................................................................................................ 1
SECTION 2 Uncollected Landfill Gas Fugitives................................................................................ 2
Landfill Gas Fugitive Emissions........................................................................................2
Non-Methane Organic Compound (NMOC) Emissions...............................................2
Volatile Organic Compound (VOC) Emissions.............................................................3
Hazardous Air Pollutant (HAP) Emissions.......................................................................3
SECTION 3 Landfill Gas Flare............................................................................................................ 4
FlareEmissions....................................................................................................................4
SECTION 4 Insignificant Activities.......................................................................................................5
Leachate Storage Tanks (IES-07)...................................................................................5
Diesel Storage Tank (IES-06)..........................................................................................6
Diesel Engines for Miscellaneous Landfill Support (IES-04).......................................6
Welding Operations (IES-05).........................................................................................6
SolarFlares (IES-08).........................................................................................................6
Attachment
A 2012 Annual Emissions Statement
B Detailed Emissions Calculations
East Carolina Environmental Landfill
SECTION 1 INTRODUCTION
Per Condition 3.X of East Carolina Environmental Landfill (Landfill) Air Quality Permit No.
08849T05 for its Landfill located at 1922 Republican Road, Aulander, North Carolina, the
facility is required to submit an emissions inventory to the Department of Air Quality (DAQ)by
June 30 of each year. The emissions inventory presented herein is the basis for the emissions
values reported in the 2012 Annual Emissions Statement. The emissions sources identified were
based on discussions and correspondence with Landfill staff, SCS Engineers' (SCS) knowledge
of the site, review of existing permits, compliance reports, and other information provided by the
Landfill. Facility-wide emissions at the Landfill are provided in Table 1 below. Facility-wide
emissions including spectated HAPs are provided at the end of this section. Emissions for each
source are further detailed in the remaining sections of this report.
Table 1 . 2012 Annual Emission Rate Summary (tons/yr)
Permit ID Emission Source NMOC VOC HAPs/ NOx CO sox PM10
TAPS
Municipal Solid
ES-01 Waste Landfill 25.55 9.96 1.00
(Fugitive Emission)
CD-Flarel Landfill Gas Flare 1 0.57 0.22 2.16 18.67 101.6 2.93 4.58
CD-Flare2 Landfill Gas Flare 2 0.13 0.05 0.51 4.36 23.73 0.68 1.07
IES-08 Solar Flares 0.04 0.02 4.43e-7 0.32 1.32 0.06 0.14
IES-07 Leachate Storage g 78e-3 8.78e-3 8.78e-3
Tanks
IES-06 Diesel Storage Tank 2.24e-3 2.24e-3
IES-05 Welding 5.05e-2
Operations2
Diesel Engines for
IES-04 Miscellaneous 0.55 4.28e-2 6.84 1.47 0.45 0.05
Landfill Support
Total' 26.31 �10.82 3.78 30.18 128.09 4.13 5.83
Notes:
Not Applicable.
Due to rounding, 'Total'emissions may not exactly equal the sum of the individual source emission rates as they
appear in the table above.
Emissions from the Welding Operations, and Diesel Engines are"carried forward"from the prior reporting year as
allowed by the DENR DAQ AERO reporting system
1
East Carolina Environmental Landfill
SECTION 2 UNCOLLECTED LANDFILL GAS FUGITIVES
LANDFILL GAS FUGITIVE EMISSIONS
This section addresses the generation of landfill gas(LFG),non-methane organic compounds
(NMOCs), volatile organic compounds (VOCs) and hazardous air pollutants (HAPs), methane,
and carbon dioxide and their fugitive emissions via passive LFG releases.
LFG generation from the landfill operation was calculated using SCS Engineers' version of the
U.S. EPA Landfill Gas Emissions Model(LandGEM). A description of the model parameters is
provided below and the model output is attached.
LandGEM uses a first-order decay equation to predict landfill gas generation based on the
amount and age of the waste in place. The formula is presented in 40 CFR Part 60.754(a)(1)(i).
The parameters La and k used in the LandGEM are the values published in EPA's Compilation of
Air Pollutant Emission Factors(AP-42), Volume I, Section 2.4(revised Noy;wber 1998). The
methane generation potential, Lo, for the MSW landfill cells was set equal to 100 cubic meters
(in 3)of methane(CH4)per megagram(Mg) of waste. The methane generation rate constant, k,
was4.04 yf t and the concentration of NMOC in LFG was set to 595 parts per million by volume
(ppmv)as hexane. AP-42 recommends these values of Lo and k for municipal solid waste
(MSW) landfills that are located in geographical regions that receive average or above average
annual precipitation, such as Aulander,North Carolina.
To calculate landfill emissions,the refuse filling history was input to the LandGEM. Note that
this model estimates emissions based on the amount of waste in place at the beginning of each
year. Waste in place at the beginning of 2012 was approximately 7.24 million Mg, or 7.99
million tons. The LandGEM estimated that the methane generation rate for 2012 is
approximately 21.73 million cubic meters, or approximately 767.5 million cubic feet. Assuming
that the methanficontent in the LFG is 50 percent,the volume of LFG generated in 2012 is
estimated to be 2,920 cubic feet per minute(ft3/min).
LandGEM input and output are provided on page 1 of the spreadsheets found at the end of this
permit.
Non-Methane Organic Compound (NMOC) Emissions
NMOC generation from the Landfill was calculated using LandGEM. Model parameters were
similar to the values noted above. LandGEM estimated that the NMOC generation rate for 2012
is 92.71 Mg, or 102.19 tons(See page 2 of the spreadsheets provided in the detailed calculations
attachment). The Landfill operates a gas collection and control system(GCCS)to capture LFG
and route it to a control flare. Seventy five percent of the LFG is assumed to be captured;
therefore,twenty five percent of the NMOC generated is assumed to have en emitted as
fugitive. Thus, the fugitive NMOC emission rate for 2012 is 25.55 tons.✓
2
East Carolina Environmental Landfill
Volatile Organic Compound (VOC) Emissions
In determining the VOC emissions from the landfill, VOC generation is assumed to bev39
percent of the NMOC generation. This assumption is based on information contained in AP-42
Section 2.4(revised November 1998) Table 2.4-2.
VOC emissions were based on the historical tonnages and model parameters noted above. The
LFG and NMOC generation rates were extracted from the LandGEM output and represent the
emissions from the Landfill during 2012. The VOC generation rates were calculated by
converting the NMOC generation r5tes (shown in the LandGEM output) from Mg/yr to tons/yr,
and then multiplying by 0.39 (i.eOC is considered as 39 percent of NMOC). The VOC
generation rate for 2012 is 39.86 tons/yr. The fugitive VOC emission rate is determined is the
same manner as the fugitive emissions rate for NMOC reflecting the ope7tion of the GCCS
during the period. The fugitive VOC emission rate for 2012 is 9.96 tong, as shown in Table 2
below.
Table 2. Air Pollutant Generation and Emission Rates
NMOC NMOC • • VOC Fugitive
Year Generation Generation Emissions Generation' Emissions' Fugitive
2012 92.71 102.19 25.55 39.86 9.96 1.00
Notes:
I VOC generation is assumed to be 39 percent of NMOC generation.
Hazardous Air Pollutant (HAP) Emissions
The estimation of HAP emissions from the Landfill is based on equations (3)and(4)of AP-42
Section 2.4. Those equations are presented below. The first step is to estimate the generation
rate of each pollutant in cubic meters per year(m3/yr). Next,the volumetric generation rate
estimate is converted to a mass generation rate (ton/yr).
3 CP
Q IY! 2.OxQr(yr)= Ch4106
where:
QP = Pollutant generation rate(m3/yr)
QCh4 = Methane generation rate(m3/yr) from the LandGEM
Cp = Pollutant concentration in LFG(ppmv)
3
East Carolina Environmental Landfill
2.0 = Multiplication factor(assumes LFG is 50 percent methane, and the
balance is carbon dioxide, nitrogen, oxygen and other trace gases)
Mp(tons/yr)= Qp ((MWP(glgmOl))(1atm)) ton
Cr _5 r m' —atm 1000gT(211 [907.185 kg]
I (8.205x10 gmol—K))( kg +TKj
l
where:
MP = Pollutant mass generation rate
MWp = Molecular weight of pollutant(g/gmole)
T = Temperature of LFG(°C) (Standard temp of 25 degrees Celsius)
Of the 188 chemical compounds identified as HAPs under Section 112 of the Clean Air Act, 28
of these compounds are listed in AP-42 Table 2.4-1 and 2.4-2. Site-specific data from testing
performed by Research Triangle Park Laboratories was used to determine the concentration of
these compounds. This report is dated May, 5, 2005 and was submitted as part or the
Compliance Demonstration Report dated June 3,2005. These site specific concentrations are
shown on page 4 of the spreadsheets in the detailed emissions attachment. Annual emissions of
the remaining HAP compounds (i.e.,those not included in the AP-42 tables) are assumed to be
negligible. The HAP fugitive rate for 2012 was calculated to be 0.04 tons. Total HAP and TAP
fugitive emissions for 2012 are 1.00 tons.
SECTION 3 LANDFILL GAS FLARE
Flare Emissions
The landfill operates two (2)flares, each with a design capacity of 3,000 scfm, as a landfill gas
control devices. The emission factors and annual emissions associated with each flare (permitted
as CD-Flarel and CD-Flare2) are summarized in Table 3.
4
East Carolina Environmental Landfill
Table 3. LFG Flare Emissions
2012 LFG 2012 LFG
Flare Flare
Compound LFG Flare Emission Factors Emissions Emissions
NOx 0.068 Ib/MMBtu 1 18.67 4.36
CO 0.37 Ib/MMBtu 1 101.57 23.73
NMOC 99.2 % destruction-2 0.57 0.13
VOC3 99.2 % destructiorr2 0.22 0.05
99.8 % destruction for halogenated HAP species2
HAPs 99.7%for non-halogenated HAP species 2 2.16 0.51
0% for mercury species 2
PM10 17 Ib/106 ft3 methane4 4.58 1.07
502 H2S concentration: 35.5 ppmV5 2.93 0.68
Notes:
Emission factor obtained from AP-42,Table 13.5-1.
2 Control efficiency obtained from AP-42,Table 2.4-3.
3 VOC generation is estimated to be 39 percent of the NMOC generation per Table 2.4-2
of AP-42 Section 2.4 "Municipal Solid Waste Landfills,"revised 11/98. These estimates
assume a 75% LFG collection efficiency for the active landfill gas collection system.
4 Control efficiency obtained from AP-42,Table 2.4-5.
5 S02 emissions are calculated per AP-42, Section 2.4.4;
SECTION 4 INSIGNIFICANT ACTIVITIES
Leachate Storage Tanks (IES-07)
The Landfill operates two (2) leachate storage tanks to store collected leachate and condensate
from the Landfill prior to disposal at an offsite wastewater treatment system. The throughput of
leachate in 2012 was 3,844,493 gallons.
Table 4. Emission Data
Parameter 2012
Leachate Throughput 3,844,493 gallons
Calculated emissions (VOC) 17.56 Ibs (8.78e-3 tons)
5
East Carolina Environmental Landfill
Detailed emission calculations are provided in the attachment.
Diesel Storage Tank (IES-06)
CY2012 emissions were calculated using EPA's Tank software. According to the program
0.00224 tons per year of VOCs were emitted. NMOC emissions are conservatively estimated to
be equal to VOC emissions.
Diesel Engines for Miscellaneous landfill Support (IES-04)
Emissions from the Landfill's diesel engines for miscellaneous support are"carried forward"as
allowed in the Division's AERO reporting and are therefore identical to the previous reporting
period. As reported in for CY2011, emissions are provided in Table 5:
Table 5. Emissions from Diesel Engines
Diesel2012
Compound tpy
(Carried Forward from CY201 1)
NOx 6.84
CO 1.47
PM 0.05
VOC 0.55
502 0.45
HAPs/TAPS 4.28e-2
Welding Operations (IES-05)
The Landfill's permit also includes an insignificant activity listing for"Welding Operations"
with the emission source ID ES-05. Emissions from the Landfill's welding operations are
"carried forward"as allowed in the Division's AERO reporting and are therefore identical to the
previous reporting period. As reported in 2011, emissions of Manganese total 101 pounds as
reported for calendar year 2012. This is reported as HAPs/TAPs of 5.05e-2 tpy for the welding
operations.
Solar Flares (IES-08)
Three(3) solar flares were used during this period(noted here as IES-08). To estimate
emissions, flow was conservatively assumed to be 60 scfm per each flare (total of 180 scfm) for
6
East Carolina Environmental Landfill
8 hours per day during the entire 365 day period. Based on emission rate data from a solar flare
manufacturer, Landfill Services, emissions were estimated as shown in Table 6:
Table 6. Solar Flare Emissions Data
2012 Solar
Flare
Compound Solar Flare Emission Factors Emissions
NOx 0.072lb/hr 0.32
CO 0.302lb/hr 1.32
NMOC NMOC assumed 1/0.39 of VOC (per AP-42) 0.04
VOC 0.004lb/hr 0.02
99.8 % destruction for halogenated HAP species'
HAPs/TAPS 99.7% for non-halogenated HAP species I 4.43e-7
0% for mercury species
PM10 0.031 Ib/hr 0.14
SO2 0.014lb/hr 0.06
Notes:
Control efficiency obtained from AP-42,Table 2.4-3.
7
East Carolina Environmental Landfill
ATTACHMENT A
2012 ANNUAL EMISSIONS STATEMENT
I
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
Inventory Certification Form(Title V)
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102
1922 Republican Road Permit: 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory-Calendar Year 2012
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is Drew Isenhour
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president,secretary,treasurer,or vice-president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production, or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship; a general partner or the proprietor,respectively;
3. for a muncipality,state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
-ERTIFICATION STATEMENT4
lmporta= Legally Responsiblei after all submissions
certify that I am the responsible official for this facility,as described above, and hereby certify that the information contained
n this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Signature Below use blue ink): Date Signed:
Printed Name: Drew Isenho
i afore: Ob "Z6- /
This form appli s to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: DIsenhour@Republicservices.com
Information on this Form cannot be held confidential
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30 1
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
Listing of Emission Sources and Control Devices on Permit. See instructions
«ES ID on ;ES Description GCS ID GCS Description CD ID's
Air
Permit
Municipal solid waste landfill Flare,One landfill gas—fired open
ES-01 [NSPS,MACT] CS-1,CS-4 flare(3000 scfm maximum flow rate) CD—Flarel,CD—Flare2
[CISWI],
1-8.l0A 18 Solar Flares
IES-04 Diesel engines for
miscellaneous landfill support
IES-05 Welding operations
IES-06 Diesel storage tank
IES-07 One leachate storage tank
2
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit: 08849
Aulander,NC 27805 County: Bertie
DAQ Region : WARO
Emission Source & Operating Scenario List — See Instructions
*ES Group ID DES ID rtOS ID SOS Description
8 CD—Flare 1
ES-01 9 CD—Flare 2
1 Municipal solid waste landfill
Insignificant source small flares used
I-8.10A 7 to point control landfill gas as needed
(conservatively assumed operation of
12/hr/day for period)
IES-04 4 No. 2 fuel oil—diesel engines for
miscellaneous landfill support
IES-05 3 maintenance shop welding rods
IES-06 6 diesel storage tank
IES-07 2 temporary storage of collected
ileachate
3
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bertie
DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit)or ES-01
Emission Source Group ID
2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT]
3. Operating Scenario ID/Description: OS—8/CD—Flare 1
4. SCC Number/Description: Not required by facility,will be completed by DAQ
5. Throughput/units in 2012: 1098041283 FT3/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-1 CD—Flarel One landfill as—fired open flare 3000 scfm maximum flow rate
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
Flare VERTICAL STACK 35 1 1500 60 2827.43 Flare
4
Operating Scenario: OS—8 Emission Source/Group ID:ES-01
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25a�o 25"fin uneAug. 25% �012
ept.—Nov. 25
012 Varch—May
12 �012-
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emission
Emissions— Estimation Control
GHG CAS GHG Method Efficiency Emission Ef Control
Pollutants Pollutants Code (Net after Factor
(Tons/Year) (See all controls)
Instructions
2012
Emission
Criteria Emissions— Estimation Control
Pollutant Criteria Method Efficiency Emission
(NAAQS Code Pollutants Code (Net after Factor Ef Control
Pollutantss
(Tons/Year) (See all controls)
Instructions
2012
CO CO 101.57 08 0
NOx NOx 18.67 08 0
TSP TSP 4.58 08 0
PM10 PM10 4.58 08 0
PM2.5 PM2.5 4.58 08 0
S02 S02 2.93 08 0
VOC VOC 0.22 08 0.98 AFTER
Emission
CAS Emissions Estimation Control
HAP/TAP Method Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see HAP/TAPS
instructions) (Pounds/Year) Code (Net after all Factor
(See controls)
Instructions
2012
Acrylonitrile 107-13-1 0 08 0
Benzene 71-43-2 0 08 0
CFC-12 ichlorodifluoromethane 75-71-8 17.93 08 0
Carbon disulfide 75-15-0 0 08 0
Carbon tetrachloride 56-23-5 0.27 08 0
Carbonyl sulfide 463-58-1 0.25 08 0
Chlorobenzene 108-90-7 0 08 0
Chloroform 67-66-3 0 08 0
Dichlorobenzene 14— 106-46-7 0 08 0
5
Eth lbenzene 100-41-4 0 08 0
Ethyl chloride chloroethane 75-00-3 0 08 0
Ethyl merca tan 75-08-1 1.19 08 0
Ethylene dichloride 1 2—dichloroethane 107-06-2 0 08 0
Ethylidene dichloride 75-34-3 0.19 08 0
1 1—dichloroethane
Hexane n— 110-54-3 0.08 08 0
Hydrogen chloride(hydrochloric acid 7647-01-0 4290.1 08 0
Hydrogen sulfide 7783-06-4 10.15 08 0
Mercury,vapor(Component of HGC 7439-97-6 0.16 08 0
Methyl chloride 74-87-3 0 08 0
Methyl chloroform 71-55-6 0 08 0
Methyl ethyl ketone 78-93-3 1.56 08 0
Methyl isobu lketone 108-10-1 0 08 0
Methyl merca tan 74-93-1 1.01 08 0
Methylene chloride 75-09-2 0 08 0
Perchloroeth lene tetrachloroeth lene 127-18-4 0.31 08 0
Propylene dichloride 78-87-5 0 08 0
Tetrachloroethane 1 1 2 2— 79-34-5 0 08 0
Toluene 108-88-3 0.06 08 0
Trichloroeth lene 79-01-6 0 08 0
Vinyl chloride 75-01-4 1.39 08 0
Vin lidene chloride 75-35-4 0 08 0
X lene 1330-20-7 0.03 08 0
6
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bettie
DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit)or ES-01
Emission Source Group ID
2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT)
3. Operating Scenario ID/Description: OS—9/CD—Flare 2
4. SCC Number/Description: Not required by facility,will be completed by DAQ
5. Throughput/units in 2012: 256554953 FT3/yr
(e.g. production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur ro Ash I Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed in ermit
1 CS-4 CD—Flare2 One landfill as—fired open flare 3000 scfrt maximum flow rate CISWI
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
Flare2 VERTICAL STACK 40 1.17 1177 53 3418.91 Flare 2
7
Operating Scenario: OS—9 Emission Source/Group ID: ES-01
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25o�u une—Aug. 25"�o Sept.—Nov. 25%
012 �arch—May
12 �012 012
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emission
Emissions— Estimation Control
GHG CAS GHG Method Efficiency Emission Ef Control
Pollutants Pollutants Code (Net after Factor
(Tons/Year) (See all controls)
Instructions
2012
Emission
Criteria Emissions— Estimation Control
Pollutant Criteria Method Efficiency Emission
(NAAQS) Ef Control
Pollutants Code Pollutants Code (Net after Factor
(Tons/Year) (See all controls)
Instructions
2012
CO CO 23.73 08 0
NOx NOx 4.36 08 0
TSP TSP 1.07 08 0
PM10 PM10 1.07 08 0
PM2.5 PM2.5 1.07 08 0
S02 S02 0.68 08 0
VOC VOC 0.05 08 0.98 At- VER
Emission
CAS Emissions Estimation Control
HAP/TAP Method Efficiency Emission
(see HAP/TAPS EF Control
Pollutants (In Alphabetical Order) instructions) (Pounds/Year) Code (Net after all Factor
(See controls)
Instructions
2012
Acr lonitrile 107-13-1 0 08 0
Benzene 71-43-2 0.01 08 0
CFC-12 Dichlorodifluoromethane 75-71-8 4.19 08 0
Carbon disulfide 75-15-0 0 08 0
Carbon tetrachloride 56-23-5 0.06 08 0
Carbonyl sulfide 463-58-1 0.06 08 0
Chlorobenzene 108-90-7 0 08 0
Chloroform 67-66-3 0 08 0
Dichlorobenzene 14— 106-46-7 0 08 0
8
Eth lbenzene 100-41-4 0 08 0
Ethyl chloride chloroethane 75-00-3 0 08 0
Ethyl merca tan 75-08-1 0.28 08 0
Ethylene dichloride 12—dichloroethane 107-06-2 0 08 0
Ethylidene dichloride 75-34-3 0.04 08 0
1 1—dichloroethane
Hexane n— 110-54-3 0.02 08 U
Hydrogen chloride(hydrochloric acid 7647-01-0 1002.37 08 0
Hydrogen sulfide 7783-06-4 2.37 08 0
Mercury,vapor(Component of HGC 7439-97-6 0.04 08 0
Methyl chloride 74-87-3 0 08 0
Methyl chloroform 71-55-6 0 08 0
Methyl ethyl ketone 78-93-3 0.37 08 0
Methyl isobu lketone 108-10-1 0 08 0
Methyl merca tan 74-93-1 0.23 08 0
Methylene chloride 75-09-2 0 08 0
Perchloroeth lene tetrachloroeth lene 127-18-4 0.07 08 0
Propylene dichloride 78-87-5 0 08 0
Tetrachloroethane 112 2— 79-34-5 0 08 0
Toluene 108-88-3 0.01 08 0
Trichloroeth lene 79-01-6 0 08 0
Vinyl chloride 75-01-4 0.33 08 0
Vin lidene chloride 75-35-4 0 08 0
X lene 1330-20-7 0.01 08 0
9
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID (from permit)or ES-01
Emission Source Group ID
2. Emission Source Description: Municipal solid waste landfill [NSPS,MACT]
3. Operating Scenario ID/Description: OS— I/Municipal solid waste landfill
4. SCC Number/Description: 50100402/1-andfill Dump ;Fugitive Emissions
5. Throughput/units in 2012: 575739 TON/yr
(e.g. production or fuel use):
6. Fuel Information (If fuel is used) F�F
ro
Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpen-nit)
9. Emission Release Point I ERP Information: Sources i cnted to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) (Acfm)
Rectangle(L x W)
in 0.1 feet)
I I FUGITIVE(NO 1 72 Area= 1 fugitive
STACK
10
Operating Scenario: OS— 1 Emission Source/Group ID: ES-01
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25"�u une—Aug. 25"�u Sept.—Nov. 25%
012 �arch—May
12 012� 012
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emission
Emissions— Estimation Control
GHG CAS GHG Method Efficiency Emission Ef Control
Pollutants Pollutants Code (Net after Factor
(Tons/Year) (See all controls)
Instructions
2012
Emission
Criteria Emissions— Estimation Control
Pollutant Criteria Method Efficiency Emission
Po�QS Code Pollutants Code (Net after Factor Ef Control
Pollutantss
(Tons/Year) (See all controls)
Instructions
2012
CO CO 0 08
NOx NOx 0 08
TSP TSP 0 08
PM10 PM10 0 08
PM2.5 PM2.5 0 08
S02 S02 0 08
VOC VOC 9.96 08
Emission
CAS Emissions Estimation Control
HAP/TAP Method Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see HAP
instructions) (Pounds/Year)
Year) Code (Net after all Factor
(See controls)
InstructioiN
2012
Acrylonitrile 107-13-1 0.03 08
Benzene 71-43-2 2.66 08
CFC-12 ichlorodifluoromethane 75-71-8 313.4 08
Carbon disulfide 75-15-0 0.02 08
Carbon tetrachloride 56-23-5 4.72 08
Carbonyl sulfide 463-58-1 28.78 08
Chlorobenzene 108-90-7 0.02 08
Chloroform 67-66-3 0.04 08
Dichlorobenzene 14— 1 106-46-7 1 0.04 08
11
Eth 1 benzene 100-41-4 0.03 08
Ethyl chloride chloroethane 75-00-3 0.01 08
Ethyl merca tan 75-08-1 138.5 08
Ethylene dichloride 1 2—dichloroethane 107-06-2 0.03 08
Ethylidene dichloride 75-34-3 3.27 08
1 1—dichloroethane
Hexane n— 110-54-3 8.87 08
Hydrogen chloride(hydrochloric acid 7647-01-0 0 08
Hydrogen sulfide 7783-06-4 1182.88 08
Mercury,vapor(Component of HGC 7439-97-6 0.06 08
Methyl chloride 74-87-3 0 08
Methyl chloroform 71-55-6 0.04 08
Methyl ethyl ketone 78-93-3 182.17 08
Methyl isobutyl ketone 108-10-1 0 08
Methyl merca tan 74-93-1 117.12 08
Methylene chloride 75-09-2 0.08 08
Perchloroeth lene tetrachloroeth lene 127-18-4 5.36 08
Propylene dichloride 78-87-5 0.03 08
Tetrachloroethane 1 1 2 2— 79-34-5 0.03 08
Toluene 108-88-3 7.24 08
Trichloroeth lene 79-01-6 0.03 08
Vinyl chloride 75-01-4 24.34 08
Vin lidene chloride 75-35-4 0.02 08
X lene 1330-20-7 3.3 08
12
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County :Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID (from permit)or I-8.10A
Emission Source Group ID
2. Emission Source Description: 8 Solar Flares
3. Operating Scenario ID/Description: OS—7/Insignificant source small flares used to point control landfill gas as
needed(conservatively assumed operation of 12/hr/day for period)
4. SCC Number/Description: 31299999/Miscellaneous Machinery; Other Not Classified
5. Throughputlunits in 2012: 4380 HR/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L a W)
in 0.1 feet)
Insignificant Source
Solar Flare VERTICAL STACK 10 0.33 10S0 60 307.9 Solar Flare for odor
control
13
Operating Scenario: OS—7 Emission Source/Group ID: I-8.10A
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o arch—May 25"�o une—Aug. 25"�u �012
ept.—Nov. 25%
012 012 �012
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emission
Emissions— Estimation Control
GHG GHG Method Efficiency Emission
CAS Pollutants Code (N y Ef Control
Pollutants et after Factor
(Tons/Year) (See all controls)
Instructions
2012
Emission
Criteria Emissions— Estimation Control
Pollutant Criteria Method Efficiency Emission
(NAA Code Pollutants Code (Net after Factor Ef Control
Pollutants
(Tons/Year) (See all controls)
Instructions
2012
CO CO 1.32 08
NOx NOx 0.32 08
TSP TSP 0.14 08
PM10 PM10 0.14 08
PM2.5 PM2.5 0.14 08
S02 S02 0.06 08
VOC VOC 0.02 08
Emission
CAS Emissions Estimation Control
HAP/TAP Emission
(see HAP/TAPS Method Efficiency EF Control
Pollutants (In Alphabetical Order) Code (Net after all Factor
instructions) (Pounds/Year) (See controls)
Instructions
2012
Acrylonitrile 107-13-1 0.00001 08
Dichlorobenzene 14— 106-46-7 0.00001 08
Eth lbenzene 100-41-4 0.00001 08
Ethylene dichloride 1 2—dichloroethane 107-06-2 0.00001 08
Ethylidene dichloride 75-34-3 0.00004 08
1 1—dichloroethane
Hexane n— 110-54-3 0.00002 08
Hydrogen chloride(hydrochloric acid 7647-01-0 0.01 08
Hydrogen sulfide 7783-06-4 0.00003 08
14
Methyl chloride 74-87-3 0.00001 08
Methyl chloroform 71-55-6 0.00001 08
Methyl ethyl ketone 78-93-3 0.00002 08
Methyl isobu (ketone 108-10-1 0.00001 08
Methylene chloride 75-09-2 0.00023 08
Perchloroeth lene tetrachloroeth lene 127-18-4 0.00012 08
Tetrachloroethane 1 1 2 2— 79-34-5 0.00004 08
Toluene 108-88-3 0.0001 08
Trichloroeth lene 79-01-6 0.00007 08
Vinyl chloride 75-01-4 0.00009 08
X lene 1330-20-7 0.00004 08
15
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit: 08849
Aulander,NC 27805 County :Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit) or IES-04
Emission Source Group ID
2. Emission Source Description: Diesel engines for miscellaneous landfill support
3. Operating Scenario ID/Description: OS—4/No. 2 fuel oil—diesel engines for miscellaneous landfill support
4. SCC Number/Description: 20200401/Diesel; Diesel
5. Throughput/units in 2012: 60000 GAL/yr
(e.g. production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
RP—DIESEL FUGITIVE(NO 1 72 Area= 1 miscellaneous diesel
STACK) engines
16
Operating Scenario: OS —4 Emission Source/Group ID: IES-04
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25"fin une—Aug. 25"�u ept.—Nov.
012 �arch—May
12 �012 012
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2012
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
(NAAQS) y Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2012
CO CO 1.47 08
NOx NOx 6.84 08
TSP TSP 0.05 08
PM10 PM10 0.05 08
PM2.5 PM2.5 0.05 08
S02 S02 0.45 08
VOC VOC 0.55 08
HAP/TAP Emissions Emission ControlEmission CAS Estimation Efficiency
Pollutants (in HAP/TAPS EF Control
Alphabetical Order) (`cc instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2012
Acetaldehyde 75-07-0 2.4 08
Acrolein 107-02-8 0.3 08
Benzene 71-43-2 2.9 08
Butadiene 13— 106-99-0 0.1 08
Formaldehyde 50-00-0 3.6 08
Polycyclic Organic
Matter(Inc PAR,
dioxins,etc.NC AP 42 POM 74.1 08
historic amorphous
lob
Toluene 108-88-3 1.3 08
X lene 1330-20-7 0.9 08
17
��T - TTT1
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit)or IES-05
Emission Source Group ID
2. Emission Source Description: Welding operations
3. Operating Scenario ID/Description: OS—3/maintenance shop welding rods
4. SCC Number/Description: 30900500/Metal Work—Welding; General
5. Throughput/units in 2012: 5000 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point I ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) (Acfm)
Rectangle(L x W)
in 0.1 feet)
F-1 FUGITIVE(NO 1 72 Area= 1 fugitive
STACK
19
Operating Scenario: OS—3 Emission Source/Group ID: IES-05
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 1 ) Days per Week ( 5 ) Weeks per Year ( 50 )
11.Typical Start& End Times For Operating Scenario: Start: 900 End: 1000
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o 25"�u unc—Aug. 25"�u Sept.—Nov. 25%
012 �arch—May
12 �012 012
7
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See instructions all controls
2012
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission
Po� Code Pollutants Method Code Ef Control
Pollutants an (Net after Factor
(Tons/Year) (See Instructions) all controls)
2012
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP Emissions Emission Control
CAS Estimation Efficiency
Emission
Pollutants (In Alphabetical HAP/TAPS EF Control
Order)
(see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2012
Manganese Unlisted
Compounds(Specify MNC—Other 101 08
Component of MNC
20
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bettie
DAQ Region : WARD
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit)or IES-06
Emission Source Group ID
2. Emission Source Description: Diesel storage tank
3. Operating Scenario ID/Description: OS—6/diesel storage tank
4. SCC Number/Description: 39090004/Fuel Storage—Fixed Roof Tanks ;Distillate Oil(No.2): Working
Loss
5. Throughput/units in 2012: 153019 GAL/yr
(e.g. production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) (Acfm)
Rectangle(L x W)
in 0.1 feet)
F -I FUGITIVE(NO 1 72 Area 1 fugitive
STACK
21
Operating Scenario: OS—6 Emission Source/Group ID:IES-06
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 600 End: 1600
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% �012
ept.—Nov. 25%
012 012 �012
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2012
Criteria Emissions— Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2012
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 0 08
HAP/TAP Emissions Emission Control
Pollutants (In CAS HAP/TAPS Estimation Emission
(see instructions) Method Code Efficiency Factor EF Control
Alphabetical Order) (Pounds/Year) (Net after all controls)
See Instructions
2012
22
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit: 08849
Aulander,NC 27805 County :Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2012
1. Emission Source ID(from permit)or IES-07
Emission Source Group ID
2. Emission Source Description: One leachate storage tank
3. Operating Scenario ID/Description: OS—2/temporary storage of collected leachate
4. SCC Number/Description: 40714698/Fixed Roof Tanks—Miscellaneous; Specify In Comments: Working
Loss
5. Throughput/units in 2012: 3844493 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fitel is used) ro
Sulfur % Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description
(in feet) Circle(enter ft (F) (Feet/see) (Acfm)
Rectangle(L x W)
in 0.1 feet)
F-1 FUGITIVE(NO 1 72 Area= 1 fugitive
STACK
23
Operating Scenario: OS—2 Emission Source/Group ID: IES-07
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2012)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hput:
an—Feb +Dec 25% 25% une—Aug. 25% ept.—Nov. 25%
012 �2rch—May
12 �012 �012
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission
CAS Method Ef Control
Pollutants Pollutants Code eta fter Factor
(Tons/Year) all controls)
See Instructions
2012
Emission
Criteria Emissions— Estimation Control
Pollutant Criteria Method Efficiency Emission
Po�QS Bode Pollutants Code (Net afterFactor Ef Control
Pollutantss
(Tons/Year) (See all controls)
Instructions
2012
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 0.01 08
Emission
CAS Emissions Estimation Control
HAP/TAP Efficiency Emission
Alphabetical (see RAP/TAPS Method EFControl
Pollutants (In AI
p (Net after all Factor
instructions) (Pounds/Year) Code
controls)
See Instructions
2012
Benzene 71-43-2 0.16 08
CFC-12 ichlorodifluoromethane 75-71-8 0.08 08
Eth 1 benzene 100-41-4 0.19 08
Methyl ethyl ketone 78-93-3 9.62 08
Methyl isobutyl ketone 108-10-1 0.16 08
Toluene 108-88-3 0.51 08
X lene 1330-20-7 0.42 08
24
Facility Total CY 2012 Emissions Summary
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit: 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory-Calendar Year 2012
Record Facility-Wide Totals From all Permitted and Non-Permitted Air Pollutant Emission Sources
Green House Gases Pollutants(GHG)
Actual Emissions(Tons/Year)
Pollutant CAS 2012 1 2011 % Difference
Criteria Pollutants
Actual Emissions Tons/Year
Pollutant CAS 2012 2011 %Difference
CO CO 128.09 93.38 37.1707%
NOx NOx 30.19 23.81 26.79547%
PM TSP TSP 5.84 4 27 16.768154%
PM10 PM10 5.84 4.27 36.768154%
PM2.5 PM2.5 5.84 4.27 36.768154%
S02 S02 4.12 3.12 32.051285%
VOC VOC 10.81 10.01 7.992009%
Hazardous Air Pollutants HAPS and/or Toxic Air Pollutants TAPs
Actual Emissions Pounds/Year
Pollutant CAS 2012 2011 1 % Difference
Pollutant Grou :Man anese compounds Group Sum:101
Manganese Unlisted Compounds(Specify MNC-Other 101.0 101 0.0%
Component of MNC
Pollutant Grou :Mercu Compounds-all total mass inc Hg Vapor Group Sum:.26
Mercury,vapor(Component of HGC 7439-97-6 0.26 1 29.999992%
Pollutant Grou :Total Reduced Sulfur TRS as total mass G up Sum:1313.76003
Hydrogen s i t I fi de 7783-06-4 1195.4 1128.61003 5.9179025%
Methyl merca tan 74-93-1 118.36 111.75 5.9149895%
Acetaldehyde 75-07-0 2.4 2.4 0.0%
Acrolein 107-02-8 0.3 .3 0.0%
Acrylonitrile 107-13-1 0.03001 .02001 49.975014%
Benzene 71-43-2 5.73 5.62 1.9572978%
Butadiene 1 3- 106-99-0 0.1 .1 0.0%
CFC-12 Dichlorodifluoromethane 75-71-8 335.6 312.71 7.3198857%
Carbon disulfide 75-15-0 0.02 .02 0.0%
26
Carbon tetrachloride 56-23-5 5.05 4.71 7.218687%
Carbonyl sulfide 463-58-1 29.09 27.46 5.9359107%
Chlorobenzene 108-90-7 0.02 .02 0.0%
Chloroform 67-66-3 0.04 .03 33.333336%
Dichlorobenzene , 1,4- 106-46-7 0.04001 .04001 0.0%
Ethyl benzene 100-41-4 0.22001 .25001 -11.999526%
Ethyl chloride chloroethane 75-00-3 0.01 .01 0.0%
Ethyl merca tan 75-08-1 139.97 132.15 5.917524%
Ethylene dichloride 1 2-dichloroethane 107-06-2 0.03001 .03001 0.0%
Ethylidene dichloride 75-34-3 3.50004 3.26004 7.3618727%
1 1-dichloroethane
Formaldehyde 50-00-0 3.6 3.6 0.0%
Hexane n- 110-54-3 8.97002 8.47002 5.9031734%
Hydrogen chloride(hydrochloric acid 7647-01-0 5292.48 3826.37 38.315945%
Methyl chloride 74-87-3 1.0E-5 .00491 -99.79633%
Methyl chloroform 71-55-6 0.04001 .04001 0.0%
Methyl ethyl ketone 78-93-3 193.72002 184.99002 4.719171%
Methyl isobutyl ketone 108-10-1 0.16001 .21001 -23.808393%
Methylene chloride 75-09-2 0.08023 .08023 0.0%
Perchloroeth lene tetrachloroeth lene 127-18-4 5.74012 5.35012 7.289553%
Polycyclic Organic Matter(Inc PAH,
Toxins, etc.NC AP 42 historic amorphous POM 74.1 74.1 0.0%
lob
Propylene dichloride 78-87-5 0.03 .03 0.00/,
Tetrachlorocthane 1 1 2 2- 79-34-5 0.03004 .03004 0.0%
Toluene 108-88-3 9.1201 8.8101 3.5186937%
Trichloroeth lene 79-01-6 0.03007 .03007 0.0%
Vinyl chloride 75-01-4 26.06009 23.04009 1 13.107581%
Vin lidene chloride 75-35-4 0.02 .02 0.0%
X lene 1330-20-7 4.66004 4.53004 2.8697345%
27
Original COPY of RECORD Date Submitted: 6/19/2013 14:44:30
As entered in AERO
Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102
1922 Republican Road Permit : 08849
Aulander,NC 27805 County : Bertie
DAQ Region : WARO
Comments From Facility:
28
1
East Carolina Environmental Landfill
ATTACHMENT B
DETAILED EMISSIONS CALCULATIONS
SCS ENGINEERS
SHEET 1 of 1
c'LILN"f PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Fugitive Landfill Emissions D.GREENE 4/12/2013
CHECKED DATE
J.MORGAN 6/7/2013
OBJECTIVE:Calculate Fugitive Landfill Emissions
APPROACH:Use USEPA's Landfill Gas Emissions Model(LandGEM)and AP-42 equations and emission factors
SOLUTION:
(1) Methane and LFG Generation*
•As calculated by LandGEM(See Section 2 of 2012 Emission Inventory Report)
Estimated LFG Generation/Emission Rates
MethaneLGeneration
LFG
Disposal Refuse Disposal Refuse Generation Fugitive
Rate In-Place Rate In-Place Rates Rates
Year tons/ r tons M r (D1 ) (m3/yr) cfm
2011 542,909 7,442,454 492,519 6,751.681 2.0571:107 2,764 691
2012 575,739 7,985,363 522,301 7,244,200 2.173E+07 2,920 730
ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv
ASSUMED METHANE CONTENT OF LFG: 50%
ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75%
SELECTED DECAY RATE CONSTANT: 0.04
SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu futon
METRIC EQUIVALENT: 100 cu m/Mg
Conversions: 35.314667 cu ft per cu in
1.1023113 ton per Mg
32.037 cu ft/ton per cu m/Mg
SCS ENGINEERS
SHEET 2 of 4
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Fugitive Landfill Emissions D.GREENE 4/12/2013
CHECKED DATE
J.MORGAN 6/7/2013
(2) NMOC and VOC Emissions*
•As calculated by LandGEM(See Section 2 of 2012 Emission Inventory Report)
NMOC and VOC Generation/E mission Rates
NMOC NMOC NMOC N'OC VOC VOC
Generation Generation Surface Fugitive Generation Generation Surface Fugitive
Rates Rates Rates Rates Rates Rates
fear (tons/vr) M /vr) (tuns/yr) (tons/vr) (.til /%r) tons/vr)
2011 96.72 87.75 ' .18 3 .72 34.22 9,43
2012 102.19 92.71 V25.55 39.86 36.16 9.96
ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv
ASSUMED METHANE CONTENT OF LFG: 50%
AP-42 DEFAULT(11/98)VOC CONTENT OF NMOC: 39%
ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75%
SELECTED DECAY RATE CONSTANT: 0.04
SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu f/ton
METRIC EQUIVALENT: 100 cu m/Mg
Conversions: 35.314667 cu ft per cu m
1.1023113 ton per Mg
32.037 cu ft/ton per cu m/Mg
SCS ENGINEERS
SHEET 3 ot, d
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Fugitive Landfill Emissions D.GREENE 4/12/2013
CHECKED DATE
J.MORGAN 6/7/2013
(3) Hazardous Air Pollutant(HAPs) Emissions
Methane production= 21,732,828 m3/yr (As caculated by LandGEM,see"Estimated LFG Generation/Emission
Methane content of LFG= 50% Rates"table on page I )
Assumed Collection efficiency= 75%
Fugitive LFG production=(21,732,828 m3/0.5)*(1-0.75)_ ✓10,866,414 m3/yr
Example
1,1,14richloroethane Molecular weight= 133.41 g/gmol
Concentration= 0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration
Q1.1.16 I..1h"<=(10,866,414 m3)*(0.0003 ppmv/1E+06)= 0.003 m3/yr
UMLi,1-M,h1",„„ham,,=(0.003 m3/yr)*[(133.41 g/gmol* 1 atm)/(8.205E-5 m?-alm/gmol-K* 1,000 g/kg•(273+25 K))]
UMt.t.i-trcmm"nnene= 0.018 kg/yr
UM1,1,1-#wh1.ah.,=(0.018 kg/yr)*(2.2 lb/kg)= 0.039 Ib/yr 1,1,14richloroethane
UMt,t.t-m m""nh�r=(0.039 lb/yr)/(2,000 Ib/tn)= 1.96E-05 ton/yr 1,1,1-trichloroethane
I
SCS ENGINEERS
SHEET 4 of 1
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Invento 02209360.07
SUBJECT BY DATE
2012 Fugitive Landfill Emissions D.GREENE 4/12/2013
CHECKED DATE
J.MORGAN 6/7/2013
(3)HAP Emissions,continued
2012 Methane Generation(m3/yr)_ t/21,732,828
2012 LFG Generation(m3/yr)= 43,465,656
2012 LFG Fugitive Production(m3/yr)_ V0,866,414
Landfill Gas Temperature ec)r= 25
PollWunl Mol.Wt. colic.' Q(P)' um)" FM(.)'
gmol) mv) (in/yr) (k / r) (Ib/ r (ton/ r) (Ibs/
1,1,1-trichloroethane TAP,HAP 133.41 0.0003 0.00 0.02 0.04 0.00 0.04 0.00
1,1,2,2-tetrachloroethane TAP,HAP 167.85 0.0002 0.00 0.01 0.03 0.00 0.03 0.00
I,1-dichloroethane TAP,HAP 98.97 0.0338 0.37 1.49 3.27 0.00 3.27 0.00
I,1-dichloroetheneT"P'H"P 96.94 0.0002 0.00 0.01 0.02 0.00 0.02 0.00
1,2-dichloroethane TAP,HAP 98.96 0.0003 0.00 0.01 0.03 0.00 0.03 0.00
I._-dichloro ro aneRAP 112.99 0.0003 0.00 0.02 0.03 0.00 0.03 0.00
acrylonitrileTAP,HAP 53.06 0.0005 0.01 0.01 0.03 0.00 0.03 0.00
benzene TAP,HAP 78.11 0.0348 0.38 1.21 2.66 0.00 2.66 0.00
carbon disulfide TAP,HAP 76.13 0.0003 0.00 0.01 0.02 0.00 0.02 0.00
carbon tetrachloride TAP,HAP 153.84 0.0314 0.34 2.15 4.72 0.00 4.72 0.00
carbonyl sulfide""" 60.07 0.4900 5.32 13.08 28.78 0.01 28.78 0.01
chlorobenzene TAP,HAP 112.56 0.0002 0.00 0.01 0.02 0.00 0.02 0.00
chloroethane TAP,HAP 64.52 0.0002 0.00 0.01 0.01 0.00 0.01 0.00
chloroform TAP,HAP 119.39 0.0003 0.00 0.02 0.04 0.00 0.04 0.00
chloromethane TAP,HAP 50.49 0.0001 0.00 0.00 0.00 0.00 0.00 0.00
dichlorobenzeneT"P'H"P 147.00 0.0003 0.00 0.02 0.04 0.00 0.04 0.00
dichlorodifiuoromethaneTAP 120.91 2.6511 28.81 142.46 313.40 0.16 313.40 0.16
dichloromethane TAP,HAP 84.94 0.0010 0.01 0.04 0.08 0.00 0.08 0.00
ethyl merca tan TAP 62.13 2.2800 24.78 62.95 138.50 0.07 138.50 0.07
ethvlbenzene TAP,HAP 106.16 0.0003 0.00 0.01 0.03 0.00 0.03 0.00
cth Iene dibromide TAP'HAP 187.88 0.0002 0.00 0.02 0.04 0.00 0.04 0.00
hexane TAP,HAP 86.18 0.1053 1.14 4.03 8.87 0.00 8.87 0.00
hydrogen sulfide TAP 34.08 35.5000 385.76 537.67 1182.88 0.59 1182.88 0.59
mercury and compounds TAP,HAP 200.61 0.0003 0.00 0.03 0.06 0.00 0.06 0.00
methyl ethyl ketone TAP 72.11 2.5838 28.08 82.80 182.17 0.09 182.17 0.09
methyl isobutyl ketone TAP,HAP 100.16 0.0002 0.00 0.01 0.02 0.00 0.02 0.00
methyl merca tan TAP 48.11 2.4900 27.06 53.24 117.12 0.06 117.12 0.06
erchloroeth leneTAP,H"P 165.83 0.0331 0.36 2.44 5.36 0.00 5.36 0.00
toluene TAP,HAP 92.13 0.0804 0.87 3.29 7.24 0.00 7.24 0.00
trichloroeth Iene TAP,HAP 131.40 0.0002 0.00 0.01 0.03 0.00 0.03 0.00
vinyl chloride TAP,HAP 62.50 0.3983 4.33 11.06 24.34 0.01 24.34 0.01
xylenes TAP,HAP 106.16 0.0318 0.35 150 3,10 0.00 3.30 0.00
Total HAPs Only 13.52 40.50 89.11 0.04 89.11 0.04
Total TAPS Onl --- --- 502.67 906.53 1,994.37 1.00 1,994.37 1.00
Votes:
1.The landfill gas temperature was obtained from AP-42 Page 2.4-5.
2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed.
3. Generation rate calculated in 2009.
4. Pollutant concentrations used to compute the estimated emissions are from AP42 and Site Specific Testing for the 2005 Compliance Demonstration
5. Q(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3).
6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4).
TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources.
HAP denotes compounds that are classified as hazardous air pollutants per AP-42 and CAA Section 112.
SCS ENGINEERS
SHEET 1 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inv tory 02209360.07
SUBJECT BY DATE
2012 Flare 1 Emission Calculations-NOx,CO,PM, D.GREENE 1 4/12/2013
NMOC,VOC,5O2,Uncombusted HAPs,HCI CHECKED DATE
J.MORGAN 6/7/2013
OBJECTIVE:Calculate flare emissions based on LFG consumption
LFG Consumption: 1,098,041,283 scUyr(CY12)
Heat Content: 500 Btu/scf(assumed at 50%CH4)
Calculated MMBTU: 549,021 MMBtu/yr(CYl2)
APPROACH:Use manufacturer data and AP42 equations and emission factors
SOLUTION:
(1)NOx Emissions
NO,emission factor= 0.068 lb/MMBtu (AP-42,Table 13.5-1)
LFG consumed= 549,021 MMBtu yr
Hours of operation= 8,398 hr/year
CMNOx=(0.068 Ib/M1vfBtu)'(549,021 MMBtu/yr)= 37,333.4 1b/yr NOx
CMNOx= (37,333.4 lb/yr)/(8,398 hr/yr)= 4.45 Ib/hr NOx
CMNOx= (37,333.4 lb/yr)/(2,000 Ib/m)= I R.67 tn/ r NOx
(2)CO Emissions
CO emission factor— 0.37 Ib/MMBtu (AP42,Table 13.5-1)
LFG consumed= 549,021 MMBm/yr
Hours of operation= 8,398 hr/year
CMCO=(0.370 Ib/MMBtu)•(549,021 MMBtu/yr)= 203,137.6 Ib/ r CO
CMCO= (203,137.6 Ib/yr)/(8,398 hr/yr)= 24.19 10 CO
CMCO= (203,137.6 Ib/yr)/(2,000 Ib/tn)= 101.57 tn/ r CO
(3)PM Emissions
PM emission factor= 17 lb/le ft'CH4 (AP42,Section 2.4,Table 2.4-5)
LFG consumed= 549,021 MMBtu/yr
Hours of operation= 8,398 hr/yr
HHV of natural gas= 1,020 Btu/ft' (AP42,Section 3.2)
Equivalent amount of CH4 consumed=(549,021 MMBtu/yr)/(1,020 MMBtu/106 M)=538.26 x 10'W CH,
CMPM=(17 lb/million ft3 CH4).(538.26 million ft3 CH4) 9,150.3 lb/yr PM
CMCO= (9,150.3 Ib/yr)/(8,398 hr/yr)= L4 1.09 Ib/hr PM
CMPM= (9,150.3 lb/yr)/(2,000 lb/tn)= 4.58 tn/ r PM
SCS ENGINEERS
SHEET 1 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inv ntory 02209360.07
SUBJECT BY DATE
2012 are 2 Emission Calculations-NOx,CO,PM, D.GREENE 1 4/12/2013
NMOC,VOC,SOz,Uncombusted HAPs,HCI CHECKED DATE
J.MORGAN 1 6/7/2013
OBJECTIVE:Calculate flare emissions based on LFG consumption
LFG Consumption: 256,554,953 scf/yr(CY 12)
Heat Content: 500 Btu/scf(assumed at 50%CH4)
Calculated MMBTU: 128,277 MMBtu/yr(CY12)
APPROACH:Use manufacturer data and AP-42 equations and emission factors
SOLUTION:
(1)NOx Emissions
NO,emission factor= 0.068 Ib/MMBtu (AP42,Table 13.5-1)
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/year
CMNOx=(0.068 Ib/MMBtu)•(128,277 MMBtu/yr)= 8,722.9 lb/ r NOx
CMNOx= (8,722.9 lb/yr)/(2,544 hr/yr)= 3.43 Ib/hr NOx
CMNOx— (8,722.9 lb/yr)/(2,000 hr/yr)= 4.36 tn/ r NOx
(2)CO Emissions
CO emission factor= 0.37 Ib/MMBtu (AP42,Table 13.5-1)
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/year
CMCO=(0.3701b/MMBtu)'(128,277 MMBtu/yr)= 47,462.7 lb/ r CO
CMCO= (47,462.7 Ib/yr)/(2,544 hr/yr)= 18.66 Ib/hr CO
CMCO= (47,462.7 Ib/yr)/(2,000 hr/yr)= V1 23.73 tn/ r CO
(3)PM Emissions
PM emission factor= 17 lb/106 ft'CH4 (AP42,Section 2.4,Table 2.4-5)
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/yr
HHV of natural gas= 1,020 Btu/ft' (AP-42,Section 3.2)
Equivalent amount of CH4 consumed=(128,277 MMBhdyr)/(1,020 MMBtu/106 ft3)= 125.76 x 106 fl'CH,
CMPM=(17 lb/million ft3 CH4)"(125.76 million ft3 CH4) 2,138.0 Ib/ r PM
CMCO= (2,138.0lb/yr)/(2,544 hr/yr)= 0.84 lb/hr PM
CMPM= (2,138.0 Ib/yr)/(2,000 hr/yr)= 1.07 tn/ r PM
SCS ENGINEERS
SHEET 2 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare 1 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,S02,Uncombusted HAPs,HCl CHECKED DATE
J.MORGAN 6/7/2013
(4)NMOC Emissions
-Use the default concentration of NMOC(as hexane)from AP-42 Table 2.4-2. The default NMOC concentration is 595 ppmv.
-Use Equations(3),(4),&(5)of AP-42,Section 2.4 to determine NMOC emissions.
Molecular weight of hexane= 86.18 g/gmol
LFG consumed= 549,021 MMBm/yr
Hours of operation= 8,398 hr/yr
HHV of landfill gas= 500 Btu/ft'
Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/million 113)= 1,098.04 x 10'ft'LFG
Eqn(3)
QNMOC=(1,098.04 x 10'ft3)*(m3/35.3198 fl )*(595 ppmv/IC6 = 18,498 m'/yr
Eqn(4)
UMNMoc=(18,498 m3)*[(86.18 g/gmol* 1 arm)/(8.205E-5 m'-atm/gmol-K*1,000 g/kg*(273+25 K))]—
UMNMOC= 65,197.2 kg
Eqn(5)
CMNMOC=[65,197.2 kg*(1 -NcOL/100)]+65,197.2 kg*(NcOL/100)*(1-NcNr/100)]
NCOL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate.
NCNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP42 Table 2.4-3).
CMNMOC=65,197.2 kg*(I -100/100)]+65,197.2 kg*(100/100)*(1-99.2/100)]= 521.58 kg
CMNMOC=(521.58 kg)*(2.2 lb/kg) = 1 1,147.5 Ib/yr NMOC
CMNM0C=(1,147.5 Ib/yr)/(8,398 hr/yr) = 0.14 Ib/hr NMOC
CMNMOC=(1,147.5 lb/yr)/(2,000 Ib/tn)= 0.57 to/yr NMOC
(5)VOC Emissions
-Use Note"c"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexan
CMvOC=1,147.5 Ib/yr NMOC*0.39= 447.5 Ib/yr VOC
CMvoc=0.14 lb/hr NMOC*0.39= 0.05 Ib/hr VOC
CMvoc=0.57 tn/yr NMOC*0.39= 0.22 to/yr VOC
SCS ENGINEERS
SHEET 2 of
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Kc ublic Services 2012 Air Emissions Inventory 02209360.07
tiC'H1ECT BY DATE
2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,S02,Uncombusted HAPs,HCI CHECKED DATE
J.MORGAN 6/7/2013
(a)NMOC Emissions
-Use the default concentration of NMOC(as hexane)from AP-42 Table 2.4-2. The default NMOC concentration is 595 ppmv.
-Use Equations(3),(4),&(5)of AP-42,Section 2.4 to determine NMOC emissions.
Molecular weight of hexane= 86.18 g/gmol
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/yr
HHV of landfill gas= 500 Btu/ft'
Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBtu/million ft3)= 256.55 x l0*ft'LFG
Eqn(3)
QNMOC=(256.55 x 10'ft3)*(m'/35.3198 ft)*(595 ppmv/10*)= 4,322 m'/yr
Eqn(4)
UMNmOC=(4,322 m')*[(86.18 g/gmol* 1 arm)/(8.205E-5 m'-attn/gmol-K* 1,000 g/kg*(273+25 K))]_
UMNMOC= 15,233.2 kg
Eqn(S)
CMNMOC=[15,233.2 kg*(1 -NCOc/100)]+15,233.2 kg*(NcOL/100)*(1-NCNT/100)]
NCOL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate.
NCNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP-42 Table 2.4-3).
CMNMOC=15,233.2 kg*(I-100/100)]+15,233.2 kg*(100/100)*(I -99.2/100)]= 121.87 kg
CMNMOC=(121.58 kg)*(2.2lb/kg) = 1 268.1 Ib/yr NMOC
CMNMOC=(268.1 lb/yr)/(2,544 hr/yr) = 0.11 Ib/hr NMOC
CMNMoc=(268.1 Ib/yr)/(2,000 Ib/tn)= 0.13 to/yr NMOC
(5)VOC Emissions
-Use Note"a"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexan
CMvoC=268.1 Ib/yr NMOC*0.39= 104.6 Ib/yr VOC
CMvoc=0.11 Ib/hr NMOC*0.39= 0.04 Ib/hr VOC
CMvoC=0.13 tn/yr NMOC*0.39= 0.05 tNyr VOC
SCS ENGINEERS
SHEET 3 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare I Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,S02,Uncombusted HAPs,HCI CHECKED DATE
J.MORGAN 6/7/2013
(6)SO2 Emissions
-Use Equations(3),(4),&(7)from AP42 Section 2.4 to determine SO2 emissions.
1-12S concentration= 35.5 ppmV AP42
Molecular weight of sulfur(S)= 32 g/gmol
Molecular weight of hydrogen sulfide l 34 g/gmol
HHV of landfill gas= 500 Btu/ft3
LFG consumed= 549,021 MMBtu/yr
Hours of operation= 8,398 hr/yr
Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/MM ft3)= 1,098.04 xle ft3 LFG
Eqn(3)
QH2s= (1,098.04 x 106 ft3)*(m3/35.3198 ft3)*(35.5 ppmv H2S/106)= 1,104 m3 1-12S
Qs=(1,104 in 1-12S)*(32 g/gmol S/34 g/gmol 1-2S)= 1,039 m3 S
Eqn(4)
UMs=(1,039 in 3)*[(32 g/gmol* I atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))]_
UMs= 1,359.42 kg S
Eqn(7)
CMso2=1,359 kg S*(NCOL/100)*2.0*(98%conversion efficiency of S to 5O2;
NCoL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate.
CMso2=1359.42 kg S*(100/100)*2.0*0.98= 2,664.47 kg/yr
CMso2=(2,664.47 kg)*(2.2 lb/kg)= F 5,861.84 Ib/yr SO,
CMso2=(5,861.84 lb/yr)/(8,398 hr/yr)_ / 0.70 Ib/hr SO2
CMso2=(5,861.84 lb/yr)/(2,000 hr/yr)_ ✓ 2.93 tn/yr SO2
(7) Hazardous Air Pollutant(HAPs)Emissions
-HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs
arc substituted into the equations. See Table 3 for a summary of flare HAP emissions.
Example
1,1,1-trichloroethane Molecular weight=133.41 g/gmol
Concentration=0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration
Q1,1,,m61x,,,,h* _(1,098.04 x 106 ft)*(m3/35.3198 ft)*(0.0003 ppmV/106)= 0.0093 tn3/yr
CMt,t,t.Q;,h,...„ham,=(0.0093 m3/yr)*[(133.41 g/gmol* I atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))]
CM1,1,1-m,h,orm �,= 0.051 kg/yr 1,1,1-trichloroethane
CM1,1,1.m6l. h.,=(0.051 kg/yr)*(2.2 lb/kg)*(ton/2,000lb)= 5.60E-05 ton 1,1,1-trichloroethane to flare
1,1,1-trichloroethane=CMt,1,1-mxhmro lh.M(tons/yr)*(1-NCNT/100)
NCNT=98%destruction efficiency(AP42 Table 2.4-3)
1,1,1-trichloroethane=5.60e-5tons/yr*(1-(98/100))= I.121I -06 ton1.1,1-trichloroethanetoatmospherc
SCS ENGINEERS
SHEET 3 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Rc ublic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,5O2,Uncombusted HAPs,HCl CHECKED DATE
J.MORGAN 6/7/2013
(6)SO2 Emissions
-Use Equations(3),(4),&(7)from AP42 Section 2.4 to determine SQ emissions.
H2S concentration= 35.5 ppmv AP42
Molecular weight of sulfur(S)= 32 g/gmol
Molecular weight of hydrogen sulfide i 34 g/gmol
HHV of landfill gas= 500 Btu/ft'
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/yr
Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBhr/MM ft3)= 256.55 xlO'ft'LFG
Eqn(3)
QH2S= (256.55 x 10'it')*(m/35.3198 ft')*(35.5 ppmv H2S/106)= 258 m'HZS
Qs=(258 m'HZS)*(32 g/gmol S/34 g/gmol KS)= 243 m'S
Eqn(4)
UMs=(243 m')*[(32 g/gmol* 1 atm)/(8.205E-5 m-atm/gmol-K" 1,000 g/kg"(273+25 K))]_
UMs= 317.63 kg S
Eqn(7)
CMso2=317.63 kg S*(NCOL/100)*2.0*(98%conversion efficiency of S to SO2)
NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate.
CMso2=317.63 kg S*(100/100)*2.0*0.98= 622.55 kg/yr
CMso2=(622.55 kg).(2.2 lb/kg)= 1,369.61 Ib/yr SO2
CMso2=(1,369.61 lb/yr)/(2,544 hr/yr) r 0.54 Ib/hr SOZ
CMso2=(1,369.61 Ib/yr)/(2,000 hr/yr)= 0.68 to/yr SO2
(7) Hazardous Air Pollutant(HAPs)Emissions
-HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs
are substituted into the equations. See Table 3 for a summary of flare HAP emissions.
Example
1,1,1-trichloroethane Molecular weight=133.41 g/gmol
Concentration=0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration
QIJ.1.61.1h.a a=(256.55 x 106 ft)*(m'/35.3198 ft')*(0.0003 ppmv/10)= 0.0022 m'/yr
CM,,1,1.rr;ch,araa,haaa=(0.0022 m'/yr)*[(133.41 g/gmol* 1 atm)/(8.205E-5 m-atm/gmol-K* 1,000 g/kg*(273+25 K))]
CMIJJ-, .hiorwha,,,= 0.012 kg/yr 1,1,1-trichloroethane
CM,,,,W,hl.mhaaa=(0.012 kg/yr)*(2.2 lb/kg)*(ton/2,000lb)= 1.31E-05 ton 1,1,1-trichloroethane to flare
1,1,1-trichloroethane=CMi,i,,.yi�hiaraathaaa(tons/yr)*(I-NCNT/100)
Ncrrr=98%destruction efficiency(AP42 Table 2.4-3)
1,1,1-trichloroethane=1.31e-5 tons/yr*(1-(98/100))= 2.62E07 ton 1,1,1-trichloroethane to atmosphere
SCS ENGINEERS
SHEET 4 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Invento 02209360.07
SUBJECT BY DATE
2012 Flare I Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,SO,,Uncombustcd HAPs,HCI CHECKED DATE
J.MORGAN 6/7/2013
17)HAP Emissions,continued
2012 LFG Consumption(MMBta/yr)= 549,021
HHV of LFG(Btu/ft3) 500
2012 LFG Consumption(ft3/yr)= 1,098,041,283
2012 LFG Consumption(in 3/yr)= 31,088,548
Landfill Gas Temperature(PC)t= 25
Halogenated Destruction Eff.(%)2= 98.0%
Non-Halogenated Destruction Eft.(%)r= 99.7
Mercury Compound Destruction Eff.(%)t= 0.0%
Pollutant Mol.WI. Cone° Q(p)3 UM( )` Flare Flare
if nud (1n% ) (k i r (Ib vr) Ilb i (tn; r
1.1,I-lrichloroethane TAP'IMP 133.41 0.0003 0.01 0.05 0.11 0.00 1.12E-06
I,1,2,2-tetrachlorocthane TAP.IMP 167.85 0.0002 0.01 0.04 0.09 0.00 9.39E-07
I,1-dichlorocthane TAP,IMP 98.97 0.0338 1.05 4.25 9.35 0.19 9.35E-05
1,1-dichlorocthenc TAP'u^P 96.94 0.0002 0.01 0.02 0.05 0.00 5.42E-07
1,2-dichlomethane TAP.HAP 98.96 0.0003 0.01 0.04 0.08 0.00 8.30E-07
1,2-dichloro ro ane HAP 112.99 0.0003 0.01 0.04 0.09 0.00 9.48E-07
au lonlmle T^P'HAP 53.06 0.0005 0.02 0.03 0.07 0.00 I.IIE-07
benzene ' 78.11 0.0348 1.08 3.45 7.60 0.02 1.14E-05
carbon disulfide 76.13 0.0003 0.01 0.03 0.06 0.00 9.58E-08
carbon tetrachloride TA',HAP 153.84 0.0314 0.98 6.14 13.51 0.27 1.35E-04
carbon (sulfide HAP 60.07 0.4900 15.23 37.42 82.33 0.25 1.24E-04
chlorob fide
112.56 0.0002 1 0.01 0.03 0.06 0.00 6.30E-07
hlorocthane 64.52 0.0002 0.01 0.02 0.04 0.00 3.61E-07
hlptefoml TAP.IMP 119.39 0.0003 0.01 0.05 0.10 0.00 1.00E-06
hloromethane TAP.xne 50.49 0.0001 0.00 0.01 0.01 0.00 1.41E-07
ichlorobenzene TAP,HAP 147.00 0.0003 0.01 0.06 0.12 0.00 1.23E-06
ichlorodifluorumcthane TAP 120.91 2.6511 82.42 407.56 896.63 17.93 8.97E-03
ichloromethane TAP.HAP 84.94 0.0010 0.03 0.11 0.24 0.00 2.38E-06
Ali mercy tan TAP 62.13 2.2800 70.88 180.11 396.25 1.19 5.94E-04
th IbenzencHAP 106.16 0.0003 1 0.01 0.04 0.09 0.00 1.34E-07
th leoe dibromide TAP,HAP
187.88 0.0002 0.01 0.05 0.11 0.00 1.05E-06
cxane TAP,HAP 86.18 0.1053 3.27 11.54 25.39 0.08 3.81 E-05
dro en chloride TAP,IMP 7 35.45 42.0000 N/A N/A N/A 4290.10 2.15E+00
dro ct sulfide TAP 34.08 35.5000 1103.64 1538.27 3384.20 10.15 5.08E-03
nercury and compounds TAP,IMP 200.61 0.0003 0.01 0.07 0.16 0.16 8.19E-05
eth I ethyl ketoncTAP 72.11 2.5838 80.33 236.90 521.17 1.56 7.82E-04
eth l isobutylketone TAP,HAP 100.16 0.0002 0.01 0.03 0.06 0.00 8.41E-08
methyl mecca tan TAP 48.11 2.4900 77.41 152.31 335.09 1.01 5.03E-04
rchlorceth Icnc T^P'H^P 165.83 0.0331 1.03 6.97 15.34 0.3I 1.53E-04
toluene,TAP'uAP 92.13 0.0804 2.50 9.41 20.71 0.06 3.11E-05
ttichloroeth lone TAP.HAP 131.40 0.0002 0.01 0.03 0.07 0.00 7.35E-07
vinyl chloride TAP,HAP 62.50 0.3983 12.38 31.65 69.63 1.39 6.96E-04
xylenesTAP.tue 106,16 0.0318 0,99 4.29 9.43 0.03 1.41E-05
Total HAPs Only I I5.88 254.94 4,292.89 2.15
Total TAPS Only -- --- -- 2,593 53 5,705.77 4,324.48 2.16
Notes:
1.The landfill gas temperature was obtained from AP-42 Page 2.4-5.
2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed.
3. Average flow rate recorded in 2009.
4. Pollutant concentrations used to compute the estimated emissions are from AP-42 and Site Specific Testing for the 2005 Compliance Deomonstration.
5. 0(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3).
6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4).
7. HCI emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation she
TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources.
NA`denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112.
'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112.
SCS ENGINEERS
SHEET 4 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare 2 Emission Calculations-NOx,CO,PM, D.GREENE 4/15/2013
NMOC,VOC,SO,,Uncombusted HAPs,HCI CHECKED DATE
J.MORGAN 6/7/2013
7)HAP Emissions,continued
2012 LEG Consumption(MMBtu/yr)= 128,277
HHV of LFG(Btu/B") 500
2012 LFG Consumption(fts/yr)= 256,554,953
2012 LEG Consumption(mrlyr)= 7,263,771
Landfill Gas Temperature($C)I= 25
Halogenated Destruction Eff.(%)r= 98.0%
Von-Halogenated Destruction Eff.(%)r= 99.7%
Mercury Compound Destruction Eff.(%)r= 0.0%
Pollutant Mul,WI, one., Q(P)` UM( )° Flare Flare
lin''T0 (k ' r) (lb T) (Ib T) (ttJ
I,I 1-trichlorccthancrAenAP 133.41 0.0003 0.00 0.01 0.03 0.00 2.62E-07
1,122-tetrachloroethane TAP'... 167.85 0.0002 0.00 0.01 0.02 0.00 2.19E-07
I,1-dichloroethane TAP HAP 98.97 0.0338 0.25 0.99 2.19 0.04 2.19E-05
1,1-dichloroethenc TAP.HAP 96.94 0.0002 0.00 0.01 0.01 0.00 1.27E-07
1_2-dichloroetbane TAP,HAP 98.96 0.0003 0.00 0.01 0.02 0.00 1.94Ed)'
1.2-dichloro ra ane"A' 112.99 0.0003 0.00 0.01 0.02 0.00 2.22E-07
ac lonitrileTAP,"AP 53.06 0.0005 0.00 0.01 0.02 0.00 2.60E-08
benzeneTAP,1W78.11 0.0348 0.25 0.81 1.78 0.01 2.66E-06
carbon disulfide ' 76.13 0.0003 0.00 0.01 0.01 0.00 2.24E-08
carbon tetrachloride TAP'HAP 153.84 0.0314 0.23 1.44 3.16 0.06 3.16E-05
carbon (sulfide"AP 60.07 0.4900 3.56 8.74 19.24 0.06 2.89E-05
chlorobenzene 112.56 0.0002 1 0.00 0.01 0.01 0.00 1.47E-07
chloroethane 64.52 0.0002 0.00 0.00 0.01 0.00 8.43E-08
chloroform TAP"TAP 119.39 0.0003 0.00 0.01 0.02 0.00 2.34E-07
chloromethane TAP,HAP 50.49 0.0001 0.00 0.00 0.00 0.00 3.30E-08
dichlorobenzene TAP'""' 147.00 0.0003 0.00 0.01 0.03 0.00 2.88E-07
dichlorodifluoromethane TAP 120.91 2.6511 19.26 95.23 209.50 4.19 2.09E-03
ichloromethane TAP'"AP 84.94 0.0010 0.01 0.03 0.06 0.00 5.55E-07
ethyl merca tan TAP 62.13 2.2800 16.56 42.08 92.58 0.28 1.39E-04
th Ibenzenc w 106.16 0.0003 0.00 0.01 0.02 0.00 3.12E-08
th Iene dibromide TAP.HAP 187.88 0.0002 0.00 0.01 0.02 0.00 2.46E-07
hexane TAP HAP 86.18 0.1053 0.77 2.70 5.93 0.02 8.90E-06
hydrogen chloride TAP'HAP' 35.45 42.0000 N/A N/A N/A 1002.37 5.01E-01
hydrogen sulfide TAP 34.08 35.5000 257.86 359.41 790.71 2.37 1.19E-03
mercury and compounds TAP"up 200.61 0.0003 0.00 0.02 0.04 0.04 1.91 E-05
methyl ethyl ketoncTAP 72.11 2.5838 18.77 55.35 121.77 0.37 1.83E-04
methyl isobutyl ketone TAP.IUP 100.16 0.0002 0.00 0.01 0.01 0.00 1.96E-08
methyl merca tan TAP 48.11 2.4900 18.09 35.59 78.29 0.23 1.17E-04
crchluroeth Ienc TAP'HAP 165.83 0.0331 0.24 1.63 3.59 0.07 3.59E-05
toluene T"P.HAP 92.13 0.0804 0.58 2.20 4.84 0.01 7.26E-06
trichloroeth lene TAP,HAP 131.40 0.0002 0.00 0.01 0.02 0.00 1.72F-07
vinyl chlmide TAP'"A' 62.50 0.3983 2.89 7.40 16.27 0.33 1.63E-04
xylenesTAP,HAP 106.16 00318 0.21 100 1-.-10 0.01 131G06
Total HAPs Only --- --- --- 27.08 59.57 1,003.02 0,M
Total TAPS Only -- 605.97 1,333.14 1.010.41 0.51
Notes:
1.The landfill gas temperature was obtained from AP42 Page 2.4-5.
2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed.
3. Average flow rate recorded in 2009.
4. Pollutant concentrations used to compute the estimated emissions are from AP42 and Site Specific Testing for the 2005 Compliance Deomonstration.
5. Q(p)=Volumetric emission rate of the pollutant. AP-42 Section 2.4 equation(3).
6. UM(p)=Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4).
T HCI emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation she
TAP denotes compounds that are classified as toxic air pollutants par North Carolina Department of Environment and Natural Resources.
"AP denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112.
'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112.
SCS ENGINEERS
SHEET 5 of
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare 1 - Emissions D.GREENE 4/15/2013
Uncombusted HCI CHECKED DATE
J.MORGAN 6/7/2013
(8)HCI Emissions
-Use Equations(3),(4),8c(10)from AP-42 Section 2.4 to determine HCl emissions.
HCI concentration= 42.0 ppmv (AP-42,Page 2.4-9)
Molecular weight of chlorine(CI)= 35.453 g/gm01
HHV of landfill gas= 500 Btu/ft3
LFG consumed= 549,021 MMBtu/yr
Hours of operation= 8,398 hr/yr
Amount of landfill gas consumed=(549,021 MMBtu/yr)/(500 MMBtu/MM ft3)= 1,098.04 x I C�ftt LFG
Eqn(3)
QS= (1,098.04 x MM ft3)*(m3/35.3198 113)*(42.0 ppmv Cl/IV6)= 1,305.72 m'Cl
Eqn(4)
UMCI=(1,305.72 m3)*[(35.453 g/gmol* I atm)/(8.205E-5 m3-atm/gmol-K* 1,000 g/kg*(273+25 K))]_
UMcj= 1,893.2 kg Cl
Eqn(10)
CMHCI=1,893.2 kg Cl* (NCOL/100)* 1.03*(NCNT/100)
NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate.
Ncrrr=100%Assume the flare is capable of converting 100%of the Cl to HCI.
CMHCI=1,893.2 kg Cl*(100/100)* 1.03*(100/100)= 1,950.0 kg/yr HCI
CMHCI=(1,950.0 kg)*(2.2 lb/kg) = 4,290.1 Ib/ r HCI
CMHCI=(4,290.1 lb/yr)/(8,760 hr/yr)= 0.51 Ib/hr HCI
CMHCI=(4,290.1 Ib/yr)/(2,000 lb/tn)= 2.15 tn/yr HCI
SCS ENGINEERS
SHEET 5 of 5
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Flare 2 - Emissions D.GREENE 4/15/2013
Uncombusted HCI CHECKED DATE
J.MORGAN 6/7/2013
(8)HCI Emissions
-Use Equations(3),(4),&(10)from AP-42 Section 2.4 to determine HCI emissions.
HCI concentration= 42.0 ppmv (AP42,Page 2.4-9)
Molecular weight of chlorine(Cl)= 35.453 g/gmol
HHV of landfill gas= 500 Btu/ft3
LFG consumed= 128,277 MMBtu/yr
Hours of operation= 2,544 hr/yr
Amount of landfill gas consumed=(128,277 MMBtu/yr)/(500 MMBtu/MM ft3)= 256.55 xl V f?LFG
Eqn(3)
QS= (256.55 x MM 0)*(m3/35.3198 ft3)*(42.0 ppmv CU10^6)= 305.09 m3 Cl
Eqn(4)
UMCI=(305.08 m3)*[(35.453 g/gmol* 1 atm)/(8.205E-5 m3-atm/gmol-K" 1,000 g/kg*(273+25 K))]_
UMC,= 442.4 kg CI
Eqn(10)
CMHCI=0,442.4 kg Cl* (NCOL/100)* 1.03*(NCNT/100)
NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate.
NcNT=100%Assume the Flare is capable of converting 100%of the CI to HCI.
CMHCI=442.4 kg CI*(100/100)*1.03*(100/100)= 455.6 kg/yr HCI
CMHCI=(455.6 kg)*(2.2 lb/kg) = 1,002.4 Ib/ r HCI
CMHCI=(1,002.4 Ib/yr)/(8,760 hr/yr)= 0.39 Whir HCI
CMHCI=(1,002.4 Ib/yr)/(2,000 lb/tn)= 0.50 tn/ r HCI
SCS ENGINEERS
SHEET I of 3
CLIENT PROJECT East Carolina Environmental landfill JOB NO.
Republic Services 2012 Air Emissions Inventory02209360.07
SUBJECT BY DATE
2012 insignificant Sources-Solar Flares(TES-08) 1D.GREENE 4/15/2013
CHECKED DATE
J.MORGAN 6/7/2013
OBJECTIVE:Estimate emissions resulting from the use of small solar spark flares
APPROACH:Use manufacture and site provided data
SOLUTION:
Number of Solar Flares in operation during CY2012: 3
Estimated flow per flare: 60 scfin
Total Estimated Flow: 180 sefin
Solar Flare Usage
8 hrs/day
365 days/ycar
175,200 min/yr
1)NOx Emissions
NOx Emissions Rate 0.072 Ibs Nox/hr/Flare
Total NOx Emisisons 0.216 Ibs Nox/hr
630.72 Ib/ r NOx
0.22 Ib/hr NOx
0.32 tnh r 1,
(2)CO Emissions
CO Emissions Rate 0.302 Ilia CO/hr/Flare
Total CO Emisisons 0.906 Ibs CO/hr
2,645.52 Ib/ r CO
0.91 Ib/hr CO
1.32 tn/ r CO
13)I'M Emissions
PM Emissions Rate 0.031 Ibs PM/hr/Flare
Total PM Emisisons 0.093 Ibs PM/hr
271.56 Ib/ r PM
0.09 Ib/hr PM
0.14 tn/ r PM
SCS ENGINEERS
SHEET 2 of 3
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT I BY DATE
2012 Insignificant Sources-Solar Flares(JES-08) ID.GREENE 4/15/2013
CHECKED DATE
J.MORGAN 6/7/2013
OBJECTIVE:Estimate emissions resulting from the use of small solar spark Bares
APPROACH:Use manufacture and site provided data
SOLUTION:
Number of Solar Flares in operation during CY2012: 3
Estimated Bow per Bare: 60 scfm
Total Estimated Flow: 180 scfm
Solar Flare Usage
8 hrs/day
365 days/year
175,200 min/yr
(1)SO= Emissions
SOz Emissions Rate 0.014 IN SOZ/hr/Flare
Total SO,Emisisons 0.042 Ibs SOr/hr
122.64 Ib/yr SOi
0.04 Ib/hr SO,
0.06 to/yr SOr
2)VOC Emissions
VOC Emissions Rate 0.004 Ibs VOC/br/Flare
Total VOC Emisisons 0.012 Ibs VOC/hr
35.04 Ib/ r VOC
0.01 Ib/hr VOC
0.02 tn/yr VOC
3)NMOC Emissions
Per AP42,assume NMOC=1/0.39 of VOC
89.85 Ib/ r NMOC
0.39 VOC to NMOC
0.03 lb/hr NMOC
0.04 to/yrNMGC
SCS ENGINEERS
SHEET 3 of 3
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Insignificant Sources-Solar Flares(IES-08) D,GREENE 4/15/2013
CHECKED DATE
J.MORGAN 6/7/2013
Emissions Rates based upon data for compounds common with main Flare and listed by manufacturer
Total Solar Flares: 3
Operational year: 33.3% (percent of full year as operated at 8 hr/d)
Hydrogen chloride emissions calculated from ratio of Solar Flare H2S emission to Main Flare H2S emission:
Main Flare H2S Emissions*(Solar Flare H2S Emissions/Main Flare 112S Emissions)= 0.01 lbs/yr
Pollutant Mot,Wt. Flare Flare Fl 3 3 ares
(g/�mol) (16/ r) (in/T) (Ibl eriodFlaresr) tn'teriod vr)
I,1,1-tnchloroethane TAP HAP 133.41 1.2E-05 6.00E-09 1.20E-05 6.00E-09
1,1,2,2-tetrachloroethane TAP.HAP 167.85 3.5E-05 1.75E-08 3.50E-05 1.75E-08
1,1-dichloroethane TAP'HAP 98.97 4.4E-05 2.20E-08 4.40E-05 2.20E-08
ro I,1-dichloetheneTAP'HAP 96.94 3.7E-06 1.85E-09 3.70E-06 1.85E-09
1,2-dichloroethane TAP,HAP 98.96 7.6E-06 3.80E-09 7.60E-06 3.80E-09
1,2-dichloro ro aneHAP 112.99 3.9E-06 1.95E-09 3.90E-06 1.95E-09
ac IonitrileTAP,HAP 53.06 9.6E-06 4.80E-09 9.60E-06 4.80E-09
benzene TAP,HAP 78.11 4.2E-06 2.10E-09 4.20E-06 2.10E-09
TAP,HAP
carbon disulfide 76.13 1.3E-06 6.50E-10 1.30E-06 6.50E-10
carbon tetrachloride TAP'HAP 153.84 1.2E-07 6.00E-11 1.20E-07 6.00E-1 I
carbonyl sulfide t AP 60.07 8.4E-07 4.20E-10 8.40E-07 4.20E-10
chlorobenzene TAP,HAP 112.56 5.4E-06 2.70E-09 5.40E-06 2.70E-09
chloroform TAP'HAP 119.39 6.8E-07 3.40E-10 6.80E-07 3.40E-10
chloromethane TAP.HAP 50.49 1.2E-05 6.00E-09 1.20E-05 6.00E-09
dichlorobenzene TAP.uAP 147.00 5.9E-06 2.95E-09 5.90E-06 2.95E-09
dichlorodifluoromethaneT5 120.91 3.4E-06 1.70E-09 3.40E-06 1.70E-09
dichloromethane TAP. [AP 84.94 2.3E-04 1.15E-07 2.30E-04 1.15E-07
ethyl merca tan TAP 62.13 4.0E-06 2.00E-09 4.00E-06 2.00E-09
eth (benzene 1AP 106.16 1.4E-05 7.00E-09 1.40E-05 7.00E-09
ethylene dibromide TAP,HAP 187.88 3.6E-08 1.80E-II 3.60E-08 1.80E-II
hexane TAP,HAP 86.18 1.6E-05 8.00E-09 1.60E-05 8.00E-09
hydrogen sulfide TAP 34.08 3.4E-05 1.70E-08 3.40E-05 1.70E-08
mercury and compounds TAP'HAP 200.61 5.6E-07 2.80E-10 5.60E-07 2.80E-10
methyl ethyl ketone TAP 72.11 1.5E-05 7.50E-09 1.50E-05 7.50E-09
methyl isobut I ketone TAP'HAP 100.16 5.3E-06 2.65E-09 5.30E-06 2.65E-09
meth (merca tan TAP 48.11 3.4E-06 1.70E-09 3.40E-06 1.70E-09
erchloroeth IeneTAP'HAP 165.83 1.2E-04 6.00E-08 1.20E-04 6.00E-08
toluene TAP,HAP 92.13 LOE-04 5.00E-08 1.00E-04 5.00E-08
trichloroeth IeneTAP.uAP 131.40 7.0E-05 3.50E-08 7.00E-05 3.50E-08
vinyl chloride TAP HAP 62.50 8.7E-05 4.35E-08 8.70E-05 4.35E-08
xylenesTnr.nAP 106.16 3.7E-OS 1.85E-08 3.70E-05 1.85E-08
Tota111APs,'I'APS --- 8.9E-04 4.43E-07 8.86E-04 443E-07
SCS ENGINEERS
SHEET 1 of
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory02209360.07
SUBJECT BY DATE
2012 Storage Tank Emissions D.GREENE 4/15/2013
CHECKED DATE
J.MORGAN 6/7/2013
OBJECTIVE:Insiginificant source tank emissions based on design capacity and throughput
APPROACH:Use EPA's TANKS 4.09 Program
SOLUTION:
The following information was entered into TANKS 4.09:
Parameter Diesel Tank
Product Diesel Fuel
Volume,gal 3,000
Length,ft 15
Diameter,It 5.8
Throuh ut,gal/yr 153,019
As reported by TANKS 4.09(see attached report):
Diesel Tank 3 000 al
Pollutant Ib/ r ton/ r
VOC 4.47 2.24E-03
NMOC' 4.47 2.24E-03
NMOC emissions are conservatively estimated to be equal to VOC emissions.
For emissions purposes waste oil modeled as Petroleum Distillate#2
SCS ENGINEERS
SHEET 1 of I
CLIENT PROJECT East Carolina Environmental Landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Leachate Tanks Emission Calculations-NMOC,VOC,HAPs D.GREENE 4/15/2013
CHECKED DATE
J. MORGAN 6/7/2013
OBJECTIVE:Calculate emissions for leachate storage tanks based on laboratory analysis and throughput
APPROACH:Use mass balance approach,assumes that all organic content volatilizes.
SOLUTION:
Leachate throughput: 3,844,493 gal/yr (Data obtained from landfill)
Organic content: 547.3 µg/L (See Below)
CMva=(547.3 µg/L)*(3,844,493 gal/yr)*(3.785 L/gal)*(1 lb/453.6E+03 mg)*(I mg/1,000 µ 17.56 Ib/yr VOC
CMva._(17.56 Ib/yr)/(8,760 hr/yr)= 2.00E-03 Ib/hr V OC
CMva=(17.56 lb/yr)/(2,000 lb/tn)= 8.78E-03 ton/yr VOC
Note: VOC emissions are conservatively estimated to equal NMOC,HAP,and TAP emissions.
VOc P91L Ib/ r Ib/d
Acetone 200 6.42 1.76E-02
Benzene 5 0.16 4.39E-04
Dichloromethane 2.5 0.08 2.20E-04
Ethyl benzene 5.8 0.19 5.10E-04
Methyl Ethyl Ketone 300 9.62 2.64E-02
Methyl Isobut I Ketone 5 0.16 4.39E-04
Toluene 16 0.5] 1.41E-03
X lenes 13 0.42 1.14E-03
547.3
Notes:
1 "Municipal Solid Waste Landfill Leachate Charatcterization Study,"Environmental Research&Educationa.
Foundation,September 2007,(Table 4"Extended VOCs")
Assumes data is representative of East Carolina Landfill leachate VOC content(Table 4"Extended VOCs")
2 Acetone neither HAP or TAP,but included as a VOC for VOC purposes
SCS ENGINEERS
SHEET 1 of I
CLIENT PROJECT East Carolina Environmental landfill JOB NO.
Republic Services 2012 Air Emissions Inventory 02209360.07
SUBJECT BY DATE
2012 Facility Wide Emissions Summary .GREENE 4/15/2013
CHECKED DATE
J.MORGAN 6/7/2013
Welding
Diesel Diesel Leachate Solar
Pollutant L Elarel Flare) Tank Engines Operation Took Flares TOTAL TOTAL
(lb/yrb/yr) (Ib/yr) (Ib/yr) (Ib/yr) (lb/yr) s (Iblyr) (Ib/yr) pb/yr) todyr
(lb/yr)
Oz --- 37,333 8,723 13,680 631 60,367 30.18
S02 5,862 1,370 900 122.6 8,254 4.13
CO 203138 47,463 2,940 2646 256,186 128.09
PM --- 9,150 2,138 100 - -- 272 11,660 5.83
MOC 51.097 1,147.5 268.1 4.47 17.56 89.8 52625 26.31
VOC 19,928 447.5 104.6 4.47 1100 17.56 35.0 21,637 10.82
I11-bichloroethane TAP,HAP 0.04 0.00 0.00 1.20E-05 0.04 2.10E-05
1,1 2,2-tetrachloroethane TAP,HAP 0.03 0.00 0.00 3.50E-05 0.03 1.74E-05
1,1-dichloroethane TAP,HAP 3.27 0.19 0.04 4.40E-05 3.46 1.73E-03
I I-dicbloroethene TAP,HAP 0.02 0.001 0.00 3.70E.06 0.02 I.00E-05
1 2-dichloroethane TAP,HAP 0.03 0.002 0.00 7.60E-06 0.03 1.53E-05
1 2-dichloro ro ane HAP 0.03 0.002 0.00 3.90E-06 0.04 1.75E-05
acetaldehyde 2.40 2.40 1.20E-03
acrolein 0.30 0.30 1.50E-04
acrylonithic TAP,HAP 0.03 0.0002 0.00 9.60E-06 0.03 1.31E-05
dune TAP,HAP 2.66 0.02 0.01 2,90 0.16 4.20E-06 5.74 2.87E-03
carbon disulfide TAP,HAP 0.02 0.0002 0.00 1.30E-06 0.02 1.13E-05
carbon tetrachloride TAP,HAP 4.72 0.27 0.06 1.20E-07 4.99 2.50E-03
carbonyl sulfide HAP 28.78 0.25 0.06 8.40E-07 29.03 1.45E-02
chlorobenzene TAP,HAP 0.02 0.00 0.00 5.40E-06 0.02 1.16E-05
chloroethane TAP,HAP 0.01 0.00 0.00 0.01 6.67E-06
chloroform TAP,HAP 0.04 0.002 0.00 6.80E-07 0.04 1.85E-05
chloromethane TAP,HAP 0.005 0.0003 0.00 1.20E-05 0.01 2.62E-06
dichlorobenzene TAP,HAP 0.04 0.00 OM 5.90E-06 0.05 2.28E-05
dichlorodifluoromethane TAP 313.40 17.93 4.19 0.08 3.40E-06 331.34 1.66E-01
ichloromethane TAP,HAP 0.08 0,00 0.00 2.30E-04 0.17 8.41E-05
cdi I mecca tan TAP 138.50 1.19 0.28 4.00E-06 l39.69 6.98E-02
eth (benzene TAP,HAP 0.03 0.00 0.00 0.19 1.40E-05 0.22 1.09E-04
ethylene dibromide TAP,HAP 0.04 0.00 0.00 3.60E-08 0.04 1.94E-05
formaldehyde 3.60 3.60 I.80E-03
hexane TAP,HAP 8.87 0.08 0.02 1.60E-05 8.97 4.48E-03
h dro en chloride TAP.HAP 4,290 1002.37 1.44E-02 5292.49 2.65E+00
h dro en sulfide TAP 1,182.88 10.15 2.37 3.40E-05 1195.41 5.98E-01
Manganese 101.00 101.00 5.05E-02
nercury and compounds TAP,HAP 0.06 0.16 0.04 5.60E-07 0.26 1.30E-04
methyl ethyl ketone TAP 182.17 1.56 0.37 9.62 1.50E-05 193.72 9.69E-02
methyl isobut I ketone TAP,HAP 0.02 0.00 0.00 0.16 5.30E-06 0.18 9.01E-05
methyl merca tan TAP 117.12 1.01 0.23 3.40E-06 118.36 5.92E-02
I c chc organic matter 74.10 74.10 3.71E-02
erchloroeth lene TAP,HAP 5.36 0.31 0.07 I.2011-04 5.74 2.87E-03
toluene TAP,HAP 7.24 0.06 0.01 1.30 0.51 1.00E-04 9.13 4.56E-03
tdchloroeth lene TAP,HAP 0.03 0.00 0.00 7.00E-05 0.03 1.38E-05
1 uni dil,nde TAP,HAP 24.34 1.39 0.33 8.70E-05 46.21 2.31E-02
x genes TAP,HAP 3.30 1 0.03 0.01 0.90 0.42 3.70E-05 4.65 2.32E-03
Total HAPs Only li 2,034.26 1 4,292.39 1 1,003.02 85.50 101.00 1.52 0.02 7,518.03 3.76
Total TAPS Only2,039.59 4,324.49 1,010.41 85.50 101.00 9.62 0.02 7,565.03 3.78
Notes:
r u em.,a,.�.e,w1 .,a„as,a 1....,wuw,w�HnN t uelx hplwu^N Fina®m a1 x,u,1 r.+�..+
HAP eennrv.i.nw.ml.iN ue.I,aankJ as-&-a IoIl IMAl4I CAAL 112
•Th com mnds lisud abavc were com ilcd from AP42(mvlsed Nov.1998)and CAA Section 112.
TANKS 4.0 Report Page 1 of 6
TANKS 4.0.9d
Emissions Report-Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification: ECE Tank 01
City: Aulander
Stale: North Carolina
Company: Republic Services of NC,LLC
Type of Tank: Horizontal Tank
Description:
Tank Dimensions
Shell Length(it): 15.00
Diameter(k): 5.90
Volume(gallons): 3,000.00
Tumovem: 0.00
Net Throughput(gal/yr): 153,019.00
Is Tank Heated(y/n): N
Is Tank Underground(y/n): N
Paint Characteristics
Shell Color/Shade: Gray/Medium
Shell Condition Good
Breather Vent Settings
Vacuum Settings(psig): -0.03
Pressure Settings(psig) 0.03
Meterological Data used in Emissions Calculations:Norfolk,Virginia(Avg Atmospheric Pressure=14.75 psia)
file:///C:/Program°/D2OFilesg/o20(x86)/Tanks4O9d/summarydisplay.htm 6/13/2013
TANKS 4.0 Report Page 2 of 6
TANKS 4.0.9d
Emissions Report-Detail Format
Liquid Contents of Storage Tank
ECE Tank 01 -Horizontal Tank
Aulander,North Carolina
uewe
Dairy UeuiedZ BWN Vepa LIyuM Ve
empMe TW F) Temp VaporP . (PM) Meu Moe..
W. BmeM1r VaparFinan
Mi.tu�e/Com{wneni MmB, qvg MN.. eB Mu. le F) Ary. W MM. Mu. Wept0L Fie. Feel WaBl,l Caku4tlau
Oisuila,e fuei oil no x M am SBA" rr.49 Q.W 0.O 0.M 0.0112 12OAOOO IMM opti tVPBO=.GOBS MO-.00B
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TANKS 4.0 Report Page 3 of 6
TANKS 4.0.9d
Emissions Report-Detail Format
Detail Calculations(AP-42)
ECE Tank 01-Horizontal Tank
Aulander,North Carolina
Annual Emission Calmulaams
Standing Lasaea Rb). 1.217I
Vapor Spam volume(.ft) 252,4280
Vapor Densely Ilblcu ft) 0.00p2
Vapor Spam Eapanaan FaWd. 0.0822
Vented Vapor Samna.Facbr. 0.9987
Tank Vapor Spam Vdwns:
Vapor Spam Vduma(m it). 252A260
Tank Demeter(ft): 5.8000
EReave Daman,(ft). 1.5275
Vapor Spam OUMge pit. 29000
Tank Shall Langer(n). MODD)
Vapor Dan id,
Vapor Denalty(Ib/m nl: D0003
VePM Mdaagw Wa9kl(dlbmde)'. 13 OM)
Vapm Pressure at Only Average Liquid
Stakm TempemWM(1..), 0.0085
Daily A,,,Lagwd Sudaim Temp.plait.R): 522.2a60
Daly Avenge Ambiem Temp.(lag.F) 59.2MB
Waal Gas Constam R
(psia tuft/(Wmol,"R)('. 10131
Lewd Bulk TamppaWm(dp.R). 521.9708
Tank Paint err Abxaptaam(SbNI) 0.6800
Daily Tonal Solar Inauletmn
Fades(OW1,11 day). 1.327.3255
Vapor Spam Eayanno,FMW
Vepm Spam Eamnvm Fedor: 0.0877
Deily Vapor Temperature Range(leg.R): 37.6743
Dady Vapor Pressure Range(Pala)'. DM50
BresMa Vent PMsa.Selling Ran on,da): DOM
Vepm Prea tune at Daly Avenge LiquW
Sudan T.MinaWM(Pall) 0.0085
Vapor Pressure at Daily Minimum UWW
SmMm Tampaream(P.). 0.0062
Vapor Pressure at Daily Meimum LWuW
Smlam Temperate(Pala) 0.0112
Daily AW,Ligwd Sumice Temp(leg R). 5271a60
Daily Min.LW Wd Sudara Tang.(d,R). 518.3275
Daily Max.kgwd SMlam Tarp.(de,,R): 537.16s6
Daily A ni ant Temp.Range(dap.R). 17.22W
VWMI Vamr SaWmbm Fwtor
V W W Vapor Saturation Fedor. 0.9987
Vapor Preseme al Wily Amrpa Ln al:
Sudan Temperaure(pall): 00085
vapor Spam Duege(ft) S 9000
Wank,Cusses db): 4.0349
Vapor McWcula Weight Dtalbmde): MOM
Vapor Pdal at Daly innakee LqW
SIWam Tamperate(P.). O'IMS
Annual Net Tbrougk Wt(BetAyr.): 153.019.0DDD
Amual TMro , 0.0000
I.,F.W. 1.0000
Tank Damodar(R): 5MI00
Working Was Pri Farb: 1.00D0
TgW W.pb) 5.2W3
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TANKS 4.0 Report Page 5 of 6
TANKS 4.0.9d
Emissions Report-Detail Format
Individual Tank Emission Totals
Emissions Report for:Annual
ECE Tank 01-Horizontal Tank
Aulander,North Carolina
Losses(lbs)
Components Working Loss Breathing Loss Total Emissions
Distillate fuel oil no.2 4.03 1.22 5.25
file:///C:/Program%20Files%20(x86)/Tanks4O9d/summarydisplay.htm 6/13/2013