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HomeMy WebLinkAboutAQ_F_0800102_20120627_EI_Fac-EI-Rpt Facility Total CY 2011 Emission Summary Recorded in ED Facility ID#: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit #(s): 08849'1'06 Green House Gases Pollutants(GHG) Actual Emissions Tons/Yr a/0 Change Pollutant CAS Not Not N A Reported Reported CO2 equivalent(sum of individual GHG pollutant emission times their 1995 No GHGs 1PCC Global Warming Potential(GWP),converted to metric tons) Reported Criteria Pollutants Actual Emissions % Change (Tons/Year) Pollutant CAS CY 2011 CY 2010 from ED from ees CO CO 93.38 64.98 43 NOx NOx 23.81 18.66 27 W', PM(TSP) TSP 4.27 3.06 39.:c°/ PM 10 PM I O 4.27 3.06 39.:;'r PM2.5 PM2.5 4.27 3.06 39.E0/., S02 SO2 3.12 2.33 33.4`7, VOC VOC 10.01 14.93 -33.00/. Hazardous Air Pollutants(HAPs) Actual Emissions '%u Change and/or Toxic Air Pollutants(TAPS) (Pounds/Year) Pollutant CAS CY 2011 CY 2010 from ED from Fees Total Reduced Sulfur(TRS as total mass) 1,240.36 1,859.47 33. Hydrogen sulfide 7783-06-4 1,128.61 1,691.94 -33.301'. Methyl mereaptan 74-93-1 111.75 161.53 s3.31b Mercury& Compounds-all total mass includes Hg Vapor 0.200000 0.18O000 1 ' Mercury, vapor(Component of HGQ 7439-97-6 0.200000 0.180000 11 Manganese& compounds 101.00 101.O0 0.0% Manganese Unlisted Compounds-Speck MNC-Other 101.00 101.00 0.0% Compound(Component of MNC) 09/07/2012 Page ] of 3 Facility Total CY 2011 Emission Summary Recorded in Ell Facility ID#: 0800102 Facility Name: Eastern Carolina Regional Solid Wastc Landfill Permit#(s): 088497'06 Hazardous Air Pollutants(HAPs) Actual Emissions 'Yo Change and/or Toxic Air Pollutants(TAPS) (Pounds/Year) Pollutant CAS CY 2011 CY 2010 from ED frnm Fees Acetaldehyde 75-07-0 2.40 2.40 0.0% Acrolein 107-02-8 0.300000 0.300000 0.0% Acrylonitrile 107-13-1 0.020010 0.037020 -45.9%, Benzene 71-43-2 5.62 6.70 -16.1 Butadiene, 1,3- 106-99-0 0.100000 0.100000 0.01% Carbon disulfide 75-15-0 0.020000 0.032000 -37.;0/. Carbon tetrachloride 56-23-5 4.71 6.89 -31.7';s, Carbonyl sulfide 463-58-1 27.46 41.16 13.3 CFC-12(Dichlorodifluoromethane) 75-71-8 312.71 457.41 -91.6% Chlorobenzene 108-90-7 0.020000 0.032000 Chloroform 67-66-3 0.030000 0.051000 Dichlorobenzene(p), 1,4- 106A6-7 0.040010 0.063050 s6.5'%o Ethyl benzene 100-41-4 0.250010 0.045120 454.1 0/6 Ethyl chloride(chloroethane) 75-00-3 0.010000 0.018000 -44.49',, Ethyl mercaptan 75-08-1 132.15 198.10 -33.30%. Ethylene dichloride(1,2-dichloroethane) 107-06-2 0.030010 0.042020 Ethylidene dichloride(I,l-dichloroethane) 7-34-3 ;.20 4.77 Formaldehyde 50-00-0 3.60 3.60 0.0% Hexane,n- 110-54-3 8.47 12.69 -33.3':f, Hydrogen chloride(hydrochloric acid) 7647-01-0 3,82637 2,751.03 MEK(methyl ethyl ketone,2-butanone) 78-93-3 184.99 260.56 29.I111.1 Methyl chloride(chloromethane) 74-87-3 0.004910 0.007030 (0.I"., Methyl chloroform 71-55-6 0.040010 0.057100 -" Methylene chloride 75-09-2 0.080230 0.121460 -33.9's, 09/07/2012 Page 2 of 3 I Facility Total CY 2011 Emission Summary Recorded in ED Facility I D#: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 088491'06. Hazardous Air Pollutants(HAPs) Actual Emissions '% Change and/or Toxic.Air Pollutants(TAPs) (Pounds/Year) Pollutant CAS CY 2011 CY 2010 from ED from Fees MIBK(methyl isobutyl ketone) 108-10-I 0.210010 0.028010 649.80/o Perchloroethylene(tetrachloroethylene) 127-18-4 5.35 7.83 -31.7% Polycyclic Organic Matter(Inc PAH,dioxins,etc.NC POM 74.10 74.10 0.0% &AP 42 historic) Propylene dichloride(1,2-dichloropropane) 78-87-5 0.030000 0.048010 -37.51%, TCE(trichloroethylene) 79-01-6 0.030070 0.038140 -21,20/) Tetrachloroethane, 1,1,2,2- 79-34-5 0.030040 0.048070 -37.511/ Toluene 108-88-3 8.81 11.65 -24.41., Vinyl chloride 75-01-4 23.04 45.33 Vinylidene chloride 75-35-4 0.020000 0.057010 Xylene(mixed isomers) 1330-20= 4.53 5.62 19.3'% Largest Individual HAP Hydrogen chloride(h.drochluric acid) 3,826.37 Ibs I otal HAP Emissions 4,100.19lbs DAO's Comments Regardin¢Inventory 09/07/2012 Page 3 of 3 East Carolina Environmental Landfill REPUBLIC SERVICES East Carolina Environmental Landfill 2011 Emission Inventory Air Permit 08849T05 Presented to: Republic Services of North Carolina, LLC East Carolina Environmental Landfill 1922 Republican Road Aulander, NC 27805 Presented by: SCS Engineers, PC 2520 Whitehall Park Drive, Suite 450 Charlotte, North Carolina 28273 (704) 504-3107 D JUN 2 7 2012 June 26, 2012 DAQ WQR� File No. 07211014.01 -T13 East Carolina Environmental Landfill Table of Contents Section Page SECTION1 Introduction........................................................................................................................ 1 SECTION 2 Uncollected Landfill Gas Fugitives................................................................................ 2 LandfillGas Fugitive Emissions........................................................................................2 Non-Methane Organic Compound (NMOC) Emissions...............................................2 Volatile Organic Compound (VOC) Emissions.............................................................3 Hazardous Air Pollutant (HAP) Emissions......................................................................3 SECTION3 Landfill Gas Flare............................................................................................................4 FlareEmissions...................................................................................................................4 SECTION 4 Insignificant Activities.......................................................................................................5 LeachateStorage Tanks (ES-07)....................................................................................5 DieselStorage Tank (ES-06)...........................................................................................6 Diesel Engines for Miscellaneous Landfill Support (IES-04).......................................6 jWelding Operations (ES-05)..........................................................................................6 SolarFlares (ES-08)..........................................................................................................6 Attachment A 2011 Annual Emissions Statement B Detailed Emissions Calculations DEccEgYE JUN 2 7 2012 DAQ WARD East Carolina Environmental Landfill SECTION 1 INTRODUCTION Per Condition 3.X of East Carolina Environmental Landfill (Landfill) Air Quality Permit No. 08849T05 for its Landfill located at 1922 Republican Road, Aulander, North Carolina, the facility is required to submit an emissions inventory to the Department of Air Quality (DAQ) by June 30 of each year. The emissions inventory presented herein is the basis for the emissions values reported in the 2011 Annual Emissions Statement. The emissions sources identified were based on discussions and correspondence with Landfill staff, SCS Engineers' (SCS) knowledge of the site, review of existing pen-nits, compliance reports, and other information provided by the Landfill. Facility-wide emissions at the Landfill are provided in Table 1 below. Facility-wide emissions including speciated HAPs are provided at the end of this section. Emissions for each source are further detailed in the remaining sections of this report. Table 1 . 2011 Annual Emission Rate Summary (tons/yr) Permit ID Emission Source NMOC TAP/ NOx CO sox PMta Municipal Solid ES-1 Waste Landfill 24.18 9.43 0.96 (Fugitive Emission) CD-Flarel Landfill Gas Flare 0.51 0.20 1.92 16.65 90.59 2.61 4.08 IES-08 Solar Flares 0.04 0.02 .43e-7 0.32 1.32 0.06 0.14 IES-07 Leachate Storage 1.02e-2 1.02e-2 1. 2e-2 Tanks IES-06 Diesel Storage Tank 2.18e-3 2.18e-3 IES-05 Welding -- -- 5.05 -2 -- Operations' Diesel Engines for IES-04 Miscellaneous 0.55 4.28e- 6.84 1.47 0.45 0.05 Landfill Support Totals 24.73 0.21 2.88 23.81 117.2 3.21 4.27 Notes: Not Applicable. Due to rounding,"Total"emissions may not exactly equal the sum of the indivicual source emission rates as they appear in the table above. z The Landfill's welding operations are located entirely indoors and no direct an ibient emissions are anticipated nor estimated for the period covered by this air emissions inventory Emissions from the Diesel Storage Tank,Welding Operations,and Diesel Engine are "carried forward"from the prior reporting year as allowed by the DENR DAQ AERO reporting system /�f EP s Awn IlFoix-IrfYL C'FfI JS �SS' e 5 -I Wks C 0_4*A Q o rrr o 23 . 6 C v+� 0.�1 1 East Carolina Environmental Landfill SECTION 2 UNCOLLECTED LANDFILL GAS FUGITIVES LANDFILL GAS FUGITIVE EMISSIONS This section addresses the generation of landfill gas(LFG), non-methane organic compounds (NMOCs),volatile organic compounds(VOCs)and hazardous air pollutants(HAPs),methane, and carbon dioxide and their fugitive emissions via passive LFG releases. LFG generation from the landfill operation was calculated using SCS Engineers' version of the U.S. EPA Landfill Gas Emissions Model(LandGEM). A description of the model parameters is provided below and the model output is attached. LandGEM uses a first-order decay equation to predict landfill gas generation based on the amount and age of the waste in place. The formula is presented in 40 CFR Part 60.754(a)(1)(i). The parameters La and k used in the LandGEM are the values published in EPA's Compilation of Air Pollutant Emission Factors(AP-42), Volume I, Section 2.4(revised November 1998). The methane generation potential, L,,, for the MSW landfill cells was set equal to 100 cubic meters(m3) of methane (CH4)per megagram(Mg) of waste. The methane generation rate constant,k,was 0.04 yr i and the concentration of NMOC in LFG was set to 595 parts per million by volume(ppmv)as hexane. AP-42 recommends these values of Lo and k for municipal solid waste(MSW) landfills that are located in geographical regions that receive average or above average annual precipitation, such as Aulander,North Carolina. To calculate landfill emissions, the refuse filling history was input to the LandGEM. Note that this model estimates emissions based on the amount of waste in place at the beginning of each year. Waste in place at the beginning of 2011 was approximately 6.75 million Mg, or 7.44 million tons. The LandGEM estimated that the methane generation rate for 2011 is approximately 20.57 million cubic meters, or approximately 726.1 million cubic feet. Assuming that the methane content in the LFG is 50 percent, the volume of LFG generated in 2011 is estimated to be 2,764 cubic feet per minute(ft3/min). LandGEM input and output are provided on page 1 of the spreadsheets found at the end of this permit. Non-Methane Organic Compound (NMOC) Emissions NMOC generation from the Landfill was calculated using LandGEM. Model parameters were similar to the values noted above. LandGEM estimated that the NMOC generation rate for 2011 is 87.75 Mg, or 96.72 tons(See page 2 of the spreadsheets provided in the detailed calculations attachment). The Landfill operates a gas collection and control system(GCCS)to capture LFG and route it to a control flare. Seventy five percent of the LFG is assumed to be captured; therefore,twenty five percent of the NMOC generated is assumed to have been emitted as fugitive. Thus,the fugitive NMOC emission rate for 2011 is 24.18 tons. 2 East Carolina Environmental Landfill Volatile Organic Compound (VOC) Emissions In determining the VOC emissions from the landfill, VOC generation is assumed to be 39 percent of the NMOC generation. This assumption is based on information contained in AP-42 Section 2.4(revised November 1998)Table 2.4-2. VOC emissions were based on the historical tonnages and model parameters noted above. The LFG and NMOC generation rates were extracted from the LandGEM output and represent the emissions from the Landfill during 2011. The VOC generation rates were calculated by converting the NMOC generation rates (shown in the LandGEM output)from Mg/yr to tons/yr, and then multiplying by 0.39(i.e., VOC is considered as 39 percent of NMOC). The VOC generation rate for 2011 is 37.72 tons/yr. The fugitive VOC emission rate is determined is the same manner as the fugitive emissions rate for NMOC reflecting the operation of the GCCS during the period. The fugitive VOC emission rate for 2011 is 9.43 tons, as shown in Table 2 below. Table 2. Air Pollutant Generation and Emission Rates NMOC NMOC • • VOC Fugitive Fugitive Year Generation Generation Emissions Generation, Emissions' Emissions 2011 87.75 96.72 24.18 37.72 �9.43 0.96 Notes: VOC generation is assumed to be 39 percent of NMOC generation. Hazardous Air Pollutant (HAP) Emissions The estimation of HAP emissions from the Landfill is based on equations(3)and(4)of AP-42 Section 2.4. Those equations are presented below. The first step is to estimate the generation rate of each pollutant in cubic meters per year(m3/yr). Next,the volumetric generation rate estimate is converted to a mass generation rate(ton/yr). 3 Q m =2.OxQ CP P yr CR4 106 where: QP = Pollutant generation rate(m3/yr) Qeh4 = Methane generation rate (m3/yr) from the LandGEM Cp = Pollutant concentration in LFG(ppmv) 3 East Carolina Environmental Landfill 2.0 = Multiplication factor(assumes LFG is 50 percent methane, and the balance is carbon dioxide,nitrogen,oxygen and other trace gases) M p(tons/yr)= Q p ((M'r(glgmol))(1 atm)) ton s 907.185 k C(8.205x10_S)rgmol-K, II(`m —atml� kg F(211 IOOOg +TK) g l where: Mp = Pollutant mass generation rate MWp = Molecular weight of pollutant(g/gmole) T = Temperature of LFG(°C)(Standard temp of 25 degrees Celsius) Of the 188 chemical compounds identified as HAPs under Section 112 of the Clean Air Act, 28 of these compounds are listed in AP-42 Table 2.4-1 and 2.4-2. Site-specific data from testing performed by Research Triangle Park Laboratories was used to determine the concentration of these compounds. This report is dated May, 5,2005 and was submitted as part or the Compliance Demonstration Report dated June 3,2005. These site specific concentrations are shown on page 4 of the spreadsheets in the detailed emissions attachment. Annual emissions of the remaining HAP compounds(i.e.,those not included in the AP-42 tables)are assumed to be negligible. The HAP fugitive rate for 2011 was calculated to be 0.04 tons. Total HAP and TAP fugitive emissions for 2011 are 0.96 tons. SECTION 3 LANDFILL GAS FLARE Flare Emissions The landfill operates one flare, with a design capacity of 3,000 scfin, as a landfill gas control device. The emission factors and annual emissions associated with the flare(permitted as CD- Flare 1) are summarized in Table 3. 4 East Carolina Environmental Landfill Table 3. LFG Flare Emissions 2011 LFG Flare Compound LFG Flare Emission Factors Emissions NOx 0.068lb/MMBtu 16.65 CO 0.37 Ib/MMBtu 1 90.59 NMOC 99.2 % destruction•2 0.51 VOC3 99.2 % destruction•2 0.2 99.8 % destruction for halogenated HAP species2 HAPs/TAPS 99.7% for non-halogenated HAP species 2 1.92 0% for mercury species 2 PM10 17 Ib/106 ft3 methane4 4.08 S02 H2S concentration: 35.5 ppmv5 2.61 Notes: Emission factor obtained from AP-42,Table 1 3.5-1. 2 Control efficiency obtained from AP-42,Table 2.4-3. 3 VOC generation is estimated to be 39 percent of the NMOC generation per Table 2.4-2 of AP-42 Section 2.4 "Municipal Solid Waste Landfills," revised 11/98. These estimates assume a 60% LFG collection efficiency for the active landfill gas collection system. 4 Control efficiency obtained from AP-42,Table 2.4-5. 5 S02 emissions are calculated per AP-42,Section 2.4.4; SECTION 4 INSIGNIFICANT ACTIVITIES Leachate Storage Tanks (IES-07) The Landfill operates two (2) leachate storage tanks to store collected leachate and condensate from the Landfill prior to disposal at an offsite wastewater treatment system. The throughput of leachate in 2011 was 4,466,774 gallons. Table 4. Emission Data Parameter 2010 Leachate Throughput 4,466,774 gallons Calculated emissions (VOC) 20.40 Ibs 5 East Carolina Environmental Landfill Detailed emission calculations are provided in the attachment. Diesel Storage Tank (IES-06) CY2011 emissions were calculated using EPA's Tank software. According to the program 0.00218 tons per year of VOCs were emitted. NMOC emissions are conservatively estimated to be equal to VOC emissions. Diesel Engines for Miscellaneous landfill Support (IES-04) Emissions from the Landfill's diesel engines for miscellaneous support are"carried forward"as allowed in the Division's AERO reporting and are therefore identical to the previous reporting period. As reported in for CY2010, emissions are provided in Table 5: Table 5. Emissions from Diesel Engines Diesel2011 Compound tpy (Carried Forward from CY201 0) NOx 6.84 CO 1.47 PM 0.05 VOC3 0.55 SOz 0.45 HAPs/TAPS 4.28e-2 Welding Operations ( IES-05) The Landfill's permit also includes an insignificant activity listing for"Welding Operations" with the emission source ID ES-05. Emissions from the Landfill's welding operations are "carried forward"as allowed in the Division's AERO reporting and are therefore identical to the previous reporting period. As reported in 2010, emissions of Manganese total 101 pounds. Solar Flares (IES-08) Three (3)solar flares were used during this period(noted here as ES-08). To estimate emissions, flow was conservatively assumed to be 60 scfin per each flare(total of 180 scfm) for 8 hours per day during the entire 365 day period. Based on emission rate data from a solar flare manufacturer, Landfill Services, emissions were estimated as shown in Table 6: 6 East Carolina Environmental Landfill Table 6. Solar Flare Emissions Data 2010 So[a Flare Compound Solar Flare Emission Factors Emissions NOx 0.072lb/hr 0.32 CO 0.302lb/hr 1.32 NMOC NMOC assumed 1/0.39 of VOC (per AP-42) 0.04 VOC3 0.004lb/hr 0.02 99.8 % destruction for halogenated HAP species' HAPs/TAPS 99.7% for non-halogenated HAP species ' 4.43e-7 0% for mercury species PM10 0.031 Ib/hr 0.14 SO2 0.014lb/hr 0.06 Notes: Control efficiency obtained from AP-42,Table 2.4-3. 7 East Carolina Environmental Landfill ATTACHMENT A 2011 ANNUAL EMISSIONS STATEMENT Inventory Certification Form(Title V) Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County :Bettie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Drew Isenhour This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal defmition.40 CFR Part 70.2 defines a responsible as meaning one of the following: I. For a corporation: a president, secretary,treasurer,or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and either i. the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars); or ii. the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship;a general partner or the proprietor,respectively; 3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). CERTIFICATION STATEMENT: UmU certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Z 1 7- rinted NameA Drew Isenh Signature: ( Z"VL,_, This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: Dlsenhour@Republicsmices.com Information on this Form cannot be held confidential 1 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County :Bertie DAQ Region : WARO Listing of Emission Sources and Control Devices on Permit. See instructions DES ID on 'ES Description 'CS ID GCS Description CD ID's Air Permit Municipal solid waste landfill One landfill gas—fired candlestick—type ES-01 [NSPS] CS-2 flare(3000 scfln,90 million Btu per hour CD—Flarel heat input), 1-8 8 Solar Flares I—ES-04 diesel engines for miscellaneous landfill support IES05 Welding operations IES06 Diesel storage tank IES07 ILeachate storage tank 1 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Emission Source & Operating Scenario List — See Instructions DES Group ID +ES ID SOS ID SOS Description ES-01 I Municipal solid waste landfill Insignificant source small flares used 1-8 7 to point control landfill gas as needed (conservatively assumed operation of 12/hr/day forperiod) I—ES-04 4 No.2 fuel oil—diesel engines for miscellaneous landfill support IES05 3 maintenance shop welding rods IES06 6 diesel storage tank IES07 2 temporary storage of collected leachate 2 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source ID(from permit)or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS] 3. Operating Scenario ID/Description: OS— I/Municipal solid waste landfill 4. SCC Number/Description: 50100402/Landfill Dump; Fugitive Emissions 5. Throughput/units in 2011: 542909 TON/yr (e.g.production or fuel use): 6. Fuel Information (if fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control 60 Device or Stack): 8. Control Device Information : Order CS—ID CD ID Control Device Description as listed in ermit 1 CS-2 CD—Flarel One landfill gas—fired candlestick—type flare(3000 scfin,90 million Btu per hour heat input) 9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) Flare VERTICAL STACK 35 1 1�00 60 2827.43 Flare 3 Operating Scenario: OS— 1 Emission Source/Group ID: ES-01 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25o�p 25"�u une—Aug. 25"�u Sept.—Nov. :25:o::::] 011 �arch—May 11 �011 Oil 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2011 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (NAA Code Pollutants Code (Net after Factor Ef Control Pollutants (Tons/Year) (See all controls) Instructions 2011 CO CO 90.59 08 0 NOx NOx 16.65 08 0 TSP TSP 4.08 08 0 PM10 PM10 4.08 08 0 PM2.5 PM2.5 4.08 08 0 SO2 SO2 2.61 08 0 VOC VOC 9.08 08 98 Emission CAS Emissions Estimation Control HAP/TAP Emission (see HAP/TAPS Method Efficiency EF Control Pollutants (In Alphabetical Order) Code (Net after all Factor instructions) (Pounds/Year) (See controls) Instructions 2011 Acr lonitrile 107-13-1 0.02 08 98 Benzene 71-43-2 2.53 08 98 CFC-12 ichlorodifluoromethane 75-71-8 312.62 08 98 Carbon disulfide 75-15-0 0.02 08 98 Carbon tetrachloride 56-23-5 4.71 08 98 Carbonyl sulfide 463-58-1 27.46 08 98 Chlorobenzene 108-90-7 0.02 08 98 Chloroform 67-66-3 0.03 08 98 Dichlorobenzene 1 4— 106-46-7 0.04 08 98 4 Eth (benzene 100-41-4 0.03 08 98 Ethyl chloride chloroethane 75-00-3 0.01 08 98 Ethyl merca tan 75-08-1 132.15 08 98 Ethylene dichloride 12—dichloroethane 107-06-2 0.03 08 98 Ethylidene dichloride 75-34-3 3.26 08 98 1,1—dichloroethane Hexane n— 110-54-3 8.47 08 98 Hydrogen chloride(hydrochloric acid 7647-01-0 3826.36 08 0 Hydrogen sulfide 7783-06-4 1128.61 08 98 Mercury,vapor(Component of HGC 7439-97-6 0.2 08 98 Methyl chloride 74-87-3 0.0049 08 98 Methyl chloroform 71-55-6 0.04 08 98 Methyl eth lketone 78-93-3 173.81 08 98 Methyl isobutyl ketone 108-10-1 0.02 08 98 Methyl merca tan 74-93-1 111.75 08 98 Methylene chloride 75-09-2 0.08 08 98 Perchloroeth lene tetrachloroeth lene 127-18-4 5.35 08 98 Propylene dichloride 78-87-5 0.03 08 98 Tetrachloroethane 1 1 2 2— 79-34-5 0.03 08 98 Toluene 108-88-3 6.91 08 98 Trichloroeth lene 79-01-6 0.03 08 98 Vinyl chloride 75-01-4 45.73 08 98 Vin lidene chloride 75-35-4 0.02 08 98 X lene 1330-20-7 3.15 08 98 5 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source ID(from permit)or I-8 Emission Source Group ID 2. Emission Source Description: 8 Solar Flares 3. Operating Scenario ID/Description: OS—7/Insignificant source small flares used to point control landfill gas as needed(conservatively assumed operation of 12/hr/day for period) 4. SCC Number/Description: 31299999/Miscellaneous Machinery ;Other Not Classified 5. Throughput/units in 2011: 4380 HR/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) rSulfurI /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—tD CD ID Control Device Description as listed inpermit) 9.Emission Release Point(ERP1 Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feettsec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) Insignificant Source Solar Flare VERTICAL STACK 10 0.33 1050 60 307.9 Solar Flare for odor control 6 Operating Scenario: OS—7 Emission Source/Group 1D: I-8 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec o une—Aug. o �01 ept.—Nov. o 011 25°/O �arch—May 11 25/O Olt 25/0 1 25/o 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG CAS GHG Method Efficiency Emission Ef Control Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2011 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission (NAA Code Pollutants Code (Net after Factor Ef Control Pollutants (Tons/Year) (See all controls) Instructions 2011 CO CO 1.32 08 NOx NOx 0.32 08 TSP TSP 0.14 08 PM10 PM10 0.14 08 PM2.5 PM2.5 0.14 08 S02 S02 0.06 08 VOC VOC 0.02 08 Emission HAP/TAP CAS Emissions Estimation Control Emission (see HAP/TAPS Method Efficiency EF Control Pollutants (In Alphabetical Order) Code (Net after all Factor instructions) (Pounds/Year) (See controls) Instructions 2011 Acrylonitrile 107-13-1 0.00001 08 Benzene 71-43-2 0 08 CFC-12 ichlorodifluoromethane 75-71-8 0 08 Dichlorobenzene 1 4— 106-46-7 1 0.00001 08 Eth (benzene 100-41-4 0.00001 08 Ethyl merca tan 75-08-1 0 08 Eth lene dichloride 1 2—dichloroethane 107-06-2 0.00001 08 Ethylidene dichloride 75-34-3 0.00004 08 1 1—dichloroethane 7 Hexane n— 110-54-3 0.00002 08 Hydrogen chloride(hydrochloric acid 7647-01-0 0.01 08 Hydrogen sulfide 7783-06-4 0.00003 08 Methyl chloride 74-87-3 0.00001 08 Methyl chloroform 71-55-6 0.00001 08 Methyl ethyl ketone 78-93-3 0,00002 08 Methyl isobutyl ketone 108-10-1 0.00001 08 Methyl merca tan 74-93-1 0 08 Methylene chloride 75-09-2 0.00023 08 Perchloroeth lene tetrachloroeth lene 127-18-4 0.00012 08 Propylene dichloride 78-87-5 0 08 Tetrachloroethane 1 1 2 2— 79-34-5 0.00004 08 Toluene 108-88-3 0.0001 08 Trichloroeth lene 79-01-6 0.00007 08 Vinyl chloride 75-01-4 0.00009 08 Vin lidene chloride 75-35-4 0 08 X lene 1330-20-7 0.00004 08 8 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source ID(from permit)or I—ES-04 Emission Source Group ID 2. Emission Source Description: diesel engines for miscellaneous landfill support 3. Operating Scenario ID/Description: OS—4/No. 2 fuel oil—diesel engines for miscellaneous landfill support 4. SCC Number/Description: 20200401/Diesel ;Diesel 5. Throughput/units in 2011: 60000 GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) in 0.1 feet) ERP—DIESEL FUGITIVE(NO I 72 Area= 1 miscellaneous diesel STACK) engines 9 Operating Scenario: OS—4 Emission Source/Group ID: I—ES-04 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec une—Aug. o �011 ept.—Nov. u Olt 25% �arch—May 11 25% Olt 25/0 25/o 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2011 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Ef Control Pollutants Code Pollutants Method Code (Net after Factor (Tons/Year) (See Instructions) all controls) 2011 CO CO 1.47 08 NOx NOx 6.84 08 TSP TSP 0.05 08 PM10 PM10 0.05 08 PM2.5 PM2.5 0.05 08 S02 S02 0.45 08 VOC VOC 0.55 08 HAP/TAP Emissions Emission Control Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2011 Acetaldehyde 75-07-0 2.4 08 Acrolein 107-02-8 0.3 08 Benzene 71-43-2 2.9 08 Butadiene 13— 106-99-0 0.1 08 Formaldehyde 50-00-0 3.6 08 Polycyclic Organic Matter(Inc PAH, dioxins,etc.NC AP 42 POM 74.1 08 historic amorphous lob Toluene 108-88-3 1.3 08 X lene 1330-20-7 0.9 08 10 11 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source ID(from permit)or IES05 Emission Source Group ID 2. Emission Source Description: Welding operations 3. Operating Scenario ID/Description: OS—3/maintenance shop welding rods 4. SCC Number/Description: 30900500/Metal Work—Welding; General 5. Throughput/units in 2011: 5000 LB/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /a Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entrV lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 12 Operating Scenario: OS—3 Emission Source/Group ID: IES05 10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) llours per Day ( 1 ) Days per Week ( 5 ) Weeks per Year ( 50 ) 11. Typical Start& End Times For Operating Scenario: Start: 900 End: 1000 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 250�oTch—May 25"�o une—Aug. 25"�u ept.—Nov. 25% 011 �011 011 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2011 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission rn`�QS Code Pollutants Method Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See Instructions) all controls) 2011 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PLAIN 08 PM2.5 J(seeons) 08 SO2 08 VOC 08 Emission Control HAP/TAPEmissions Emission Estimation Efficiency Pollutants (in AlphabeticalHAP/TAPS EF Control Method Code (Net after all Factor Order) (Pounds/Year) See Instructions controls) 2011 Manganese Unlisted Compounds (Specify MNC—Other 101 08 Component of MNC 13 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit: 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source M(from permit)or IES06 Emission Source Group ID 2. Emission Source Description: Diesel storage tank 3. Operating Scenario ID/Description: OS—6/diesel storage tank 4. SCC Number/Description: 39090004/Fuel Storage—Fixed Roof Tanks ;Distillate Oil(No. 2): Working Loss 5. Throughput/units in 2011: 158570 GAL/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) /o Sulfur "i, Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9. Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter ft (F) (Feet/see) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 14 Operating Scenario: OS—6 Emission Source/Group ID: IES06 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11.Typical Start& End Times For Operating Scenario: Start: 600 End: 1600 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec 25% oil 25% une—Aug. 25% Sept.—Nov. 25% O11 Oil �011 Oil 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2011 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Po�QS Code Pollutants Method Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See Instructions) all controls) 2011 CO CO 08 NOa NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0 08 HAP/TAP Emissions Emission Control Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control (see instructions) Method Code Factor Alphabetical Order) (Pounds/Year) (Net after all controls) See Instructions 2011 15 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2011 1. Emission Source ID(from permit)or IES07 Emission Source Group ID 2. Emission Source Description: Leachate storage tank 3. Operating Scenario ID/Description: OS—2/temporary storage of collected leachate 4. SCC Number/Description: 40714698/Fixed Roof Tanks—Miscellaneous; Specify In Comments: Working Loss 5. Throughput/units in 2011: 4466774 GAL/yr (e.g. production or fuel use): 6. Fuel Information (If fuel is used) ro Sulfur /o Ash Heat Content Btu/units 7. Capture Efficiency (%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed in permit 9. Emission Release Point i ERP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) Rectangle(L x W) in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 16 Operating Scenario: OS —2 Emission Source/Group ID: IES07 10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2011) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throughput: an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. =0/6Olt Olt Olt 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG GHG Estimation Efficiency Emission CAS Method Ef Control Pollutants Pollutants (Net after Factor (Tons/Year) Code all controls) See Instructions 2011 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po�QS Code Pollutants Code (Net after Factor Ef Control Pollutantss (Tons/Year) (See all controls) Instructions 2011 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0.01 08 Emission CAS Emissions Estimation Control HAP/TAP Efficiency Emission Pollutants (In Alphabetical Order) (see HAP/1 APS Method EF Control (Net after all Factor instructions) (Pounds/Year) Code controls) See Instructions 2011 Benzene 71-43-2 0.19 08 CFC-12 ichlorodifluoromethane 75-71-8 0.09 08 Eth 1 benzene 100-41-4 0.22 08 Methyl ethyl ketone 78-93-3 11.18 08 Methyl isobutyl ketone 108-10-1 0.19 08 Toluene 108-88-3 0.6 08 X lene 1330-20-7 0.48 08 17 Facility Total CY 2011 Emissions Summary As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2011 Record Facility-Wide Totals From all Permitted and Non-Permitted Air Pollutant Emission Sources Green House Gases Pollutants(GHG) Actual Emissions Tons/Year Pollutant CAS 2011 2010 % Difference Criteria Pollutants Actual Emissions Tons/Year Pollutant CAS 2011 2010 %Difference CO CO 93.38 64.98 43.705746% NOx NOx 23.81 18.66 27.59914% PM TSP TSP 4.27 3.06 39.542484% PM 10 PM 10 4.27 3.06 39.542484% PM2.5 PM2.5 4.27 3.06 39.542484% S02 S02 3.12 2.33 33.90558% VOC VOC 9.66 14.93 -35.29806% Hazardous Air Pollutants APS and/or Toxic Air Pollutants TAP' Actual Emissions Pounds/Year Pollutant CAS 2011 2010 1 % Difference Pollutant Grou :Man anese compounds Group Sum:101 Manganese Unlisted Compounds(Specify MNC-Other 101.0 101 0.0% Component of MNC Pollutant Grou :Mercu Compounds-all total mass inc H Va or Grou Sum:.2 Mercury,vapor(Component of HGC 7439-97-6 1 0.2 1 .18 1 1.111108% Pollutant Grou :Total Reduced Sulfur TRS as total mass Gr up Sum:1240.36003 Hydrogen sulfide 7783-06-4 1128.61 1691.94207 -33.295% Methyl merca tan 74-93-1 111.75 167.53001 -33.295536% Acetaldehyde 75-07-0 2.4 2.4 0.0% Acrolein 107-02-8 0.3 .3 0.0% Acrylonitrile 107-13-1 0.02001 .03702 -45.948135% Benzene 71-43-2 5.62 6.69901 -16.107008% Butadiene 1 3- 106-99-0 0.1 .1 0.0% CFC-12 Dichlorodifluoromethane 75-71-8 312.71 457.41001 -31.63464% Carbon disulfide 75-15-0 0.02 .032 -37.500004% Carbon tetrachloride 56-23-5 4.71 6.893 -31.66981% 19 Carbonyl sulfide 463-58-1 27.46 41.163 -33.289604% Chlorobenzene 108-90-7 0.02 .032 -37.500004% Chloroform 67-66-3 0.03 .051 -41.176468% Dichlorobenzene 14- 106-46-7 0.04001 .06305 -36.542427% Eth lbenzene 100-41-4 0.25001 .04512 454.10022% Ethyl chloride chloroethane 75-00-3 0.01 .018 -44.444443% Ethyl merca tan 75-08-1 132.15 198.10401 -33.292618% Ethylene dichloride 1 2-dichloroethane 107-06-2 0.03001 .04202 -28.581629% Ethylidene dichloride 75-34-3 3.26004 4.77109 -31.67096% 1 1-dichloroethane Formaldehyde 50-00-0 3.6 3.6 0.0% Hexane n- 110-54-3 8.47002 12.69303 -33.270306% Hydrogen chloride(hydrochloric acid 7647-01-0 3826.37 2751.0278 39.088745% Methyl chloride 74-87-3 0.00491 .00703 -30.15647% Methyl chloroform 71-55-6 0.04001 .0571 -29.929947% Methyl ethyl ketone 78-93-3 184.99002 260.56203 -29.003466% Methyl isobutyl ketone 108-10-1 0.21001 .02801 649.768% Methylene chloride 75-09-2 0.08023 .12146 -33.945335% Perchloroeth lene tetrachloroeth lene 127-18-4 5.35012 7.82824 -31.656157% Polycyclic Organic Matter(Inc PAH, dioxins,etc.NC AP 42 historic amorphous POM 74.1 74.1 0.0% lob Propylene dichloride 78-87-5 0.03 .04801 -37.51302% Tetrachloroethane 1 12,2 79-34-5 0.03004 .04807 -37.5078% Toluene 108-88-3 8.8101 11.6542 -24.40408% Trichloroeth lene 79-01-6 0.03007 .03814 -21.158886% Vinyl chloride 75-01-4 45.73009 1 45.32517 1 0.89337224% Vin lidene chloride 75-35-4 0.02 .05701 -64.918434% X lene 1330-20-7 4.53004 5.61507 -19.323536% 20 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID :0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Comments From Facility: 21 East Carolina Environmental Landfill ATTACHMENT B DETAILED EMISSIONS CALCULATIONS SCS ENGINEERS SHEET I of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Fugitive Landfill Emissions D.GREENE 5/7/2012 CHECKED DATE J.MORGAN 6/8/2012 Olt.l 1CC'FIVE:Calculate Fugitive Landfill Emissions APPROACH:Use USEPA's Landfill Gas Emissions Model(LandGEM)and AP-42 equations and emission factors. SOLUTION: (1) Methane and LFG Generation* •As calculated by LandGEM(See Section 2 of 2011 Emission Inventory Report) Estimated LFG Generation/Emission Rates Methane LFG LPG Disposal Refuse Disposal Refuse Generation Generation Fugitive Rate In-Place Rate In-Place Rates Rates Rates year (tonshr) tons V1 hr) (Ni ) (in3/vr) (cfm) (cfm) 2010 542,799 6,R99 5 492,419 6.259,Z62 1.9361ii(17 2.601 650 2011 542,909 7,442,454 492,519 6,75I,681 2.057I;+117 2,764 691 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu R/ton METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35.314667 cu It per cu in 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS ENGINEERS SHEET 2 of3 CLI I:N"I' PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Fugitive Landfill Emissions R GREENE 5/7/2012 CHECKED DATE J.MORGAN 6/8/2012 (2) NMOC and VOC Emissions• •As calculated by LandGEM(See Section 2 of 2011 Emission Inventory Report) NMOC and VOC Generation/Emission Rates NMOC NMOC NMOC VOC VOC VOC Generation Generation Surface Fugitive Generation Generation Surface Fugitive Rates Rates Rates Rates Rates Rates Near (tons/ r M r tons/ r tons/ r (11 g/vr) tonshry 2010 91.03 11.18 22.76 35.50 32.21 8,88 2011 96.72 87.75 24.18 37.72 34.22 9.43 ESTIMATED NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% AP42 DEFAULT(11/98)VOC CONTENT OF NMOC: 39% ASSUMED COLLECTION EFFICIENCY OF LFG SYSTEM: 75% SELECTED DECAY RATE CONSTANT: 0.04 SELECTED ULTIMATE METHANE RECOVERY RATE: 3,203.7 cu fit/ton METRIC EQUIVALENT: t00 cu m/Mg Conversions: 35.314667 cu it per cu to 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg SCS ENGINEERS SHEET 3 of 4 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Re ublic Services 2011 Air Emissions Inventory 07211014.01 St I BJECT BY DATE 2011 Fugitive Landfill Emissions D.GREENE 5/7/2012 CHECKED DATE J.MORGAN 6/8/2012 (3) Hazardous Air Pollutant(HAPs) Emissions Methane production= 20,569,281 m3/yr (As caculated by LandGEM,see"Estimated LFG Generation/Emission Methane content of LFG= 50% Rates"table on page 1.) Assumed Collection efficiency= 75% Fugitive LFG production=(20,569,281 m3/0.5)*(1-0.60)= 10,284,641 m'/yr Example I,1,1-trichloroethane Molecular weight= 133.41 g/gmol Concentration= 0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration _(16,455,425 m3)*(0.0003 ppmv/I E+06)= 0.003 mt/yr UM,,t,i-mom,""nh.e=(0.005 m3/yr)*[(133.41 g/gmol* I arm)/(8.205E-5 m'-atm/gmol-K* 1,000 g/kg*(273+25 K))] UMIJJ-vwhk.wh�== 0.017 kg/yr UMI,1,1-mchl".«um (0.027 kg/yr)*(2.2 lb/kg)= 0,037 lb/yr 1,1,1-trichloroethane UM1_1.1-mchW n .=(0.059 lb/yr)/(2,000lb/tn)= 0000 22 ton/yr 1,1,1-trichloroethane SCS ENGINEERS SHEET 4 of 4 C'L1ENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Fugitive Landfill Emissions D.GREENE 5/7/2012 CHECKED DATE J.MORGAN 6/8/2012 (3)HAP Emissions,continued 2011 Methane Generation(m3/yr)= 20,569,281 2011 LFG Generation(m3/yr)= 41,138,563 2011 LFG Fugitive Production(m3/yr)= 10,284,641 Landfill Gas Temperature On,= 25 Pollutant Mal.Wt. Cone. Q(p)3 UM(p)6 FM of my (m3/yr) k Ib/ ton/ r Ibs/ ton/ I,I.I-trichlorocthane IAP-nnr 133.41 0.0003 0.00 0.02 0.04 0.00 0.04 0,00 1,1,2,2-tetrachloroethane IAP'HAP 167.85 0.0002 0.00 0.01 0.03 0.00 0.03 0.00 I,1-dichloroethane TAP,HAP 98.97 0.0338 0.35 1.41 3.09 0.00 3.09 0.00 1,1-dichloroethene TAP'HAP 96.94 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 1,2-dichloroethane TAP.HAP 98.96 0.0003 0.00 0.01 0.03 0.00 0.03 0.00 1,2-dichloro ro aneHAP 112.99 0.0003 0.00 0.01 0.03 0.00 0.03 0.00 acrylonitrileTAP,HAP 53.06 0.0005 0.01 0.01 0.02 0.00 0.02 0.00 benzene TAP,HAP 78.11 0.0348 0.36 1.14 2.51 0.00 2.51 0.00 carbon disulfide TAP'HAP 76.13 0.0003 0.00 0.01 0.02 0.00 0.02 J. 0.00 carbon tetrachloride TAP'HAP 153.84 0.0314 0.32 2.03 4.47 0.00 4.47 R 0.00 carbonyl sulfide HAP 60.07 0.4900 5.04 12.38 27.24 0.01 27.24i o.01 chlorobenzene TAP,HAP 112.56 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 chloroethane TAP.RAP 64.52 0.0002 0.00 0.01 0.01 0.00 0.01 0.00 chloroform TAP'HAP 119.39 0.0003 0.00 0.02 0.03 0.00 0.03 0.00 chloromethane TAP,HAP 50.49 0.0001 0.00 0.00 0.00 0.00 0.00 0.00 dichlorobenzeneTAP'HAP 147.00 0.0003 0.00 0.02 0.04 0.00 0.04 0.00 dichlorodifluoromethane TAP 120.91 2.6511 27.27 134.83 296.62 0.15 296.62- 0.15 dichloromethane TAP'HAP 84.94 0.0010 0.01 0.04 0.08 0.00 0.08 0.00 eth 1 mecca tan TAP 62.13 2.2800 23.45 59.58 131.09 0.07 131.09 0.07 eth (benzene TAP'HAP 106.16 0.0003 0.00 0.01 0.03 0.00 0.03 0.00 ethylene dibromide TAP'HAP 187.88 0.0002 0.00 0.02 0.03 0.00 0.03 0.00 hexane TAP'HAP 86.18 0.1053 1.08 3.82 8.40 0.00 8.40 0.00 h dro en sulfide TAP 34.08 35.5000 365.10 508.89 1119.55 0.56 1119.55 0.56 mercury and compounds TAP'HAP 200.61 0.0003 0.00 0.02 0.05 0.00 0.05 0.00 methyl ethyl ketone TAP 72.11 2.5838 26.57 78.37 172.41 0.09 172.41 0.09 methyl isobutyl ketone TAP'HAP 100.16 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 methyl merca tan TAP 48.11 2.4900 25.61 50.39 110.85 0.06 110.85 0.06 erchloroeth lene TAP'HAP 165.83 0.0331 0.34 2.31 5.08 0.00 5.08 0.00 toluene TAP,RAP 92.13 0.0804 0.83 3.11 6.85 0.00 6.85 0.00 trichloroeth lene TAP'HAP 131.40 0.0002 0.00 0.01 0.02 0.00 0.02 0.00 vin I chloride TAP'HAP 62.50 0.3983 4.10 10.47 23.04 0.01 23.04, --0:01 xvlencsI'W.HNP 106.16 0.0318 033 1.42 3.12 0.00 3-1 0.00 t Total HAPs Only 12.80 38.34 84.34 0.04 84.34 0.04 Total TAPS Only 475.75 858.00 1,887.60 0.94 1,887.60 0.94 Notes: I.The landfill gas temperature was obtained from AP42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Generation rate calculated in 2009. 4. Pollutant concentrations used to compute the estimated emissions are from AP42 and Site Specific Testing for the 2005 Compliance Demonstration 5. Q(p)=Volumetric emission rate of the pollutant. AP42 Section 2.4 equation(3). 6. UM(p)-Uncontrolled mass emissions of pollutant. If no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources. H"P denotes compounds that are classified as hazardous air pollutants per AP42 and CAA Section 112. SCS ENGINEERS SHEET I of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inv tory 07211014.01 SUBJECT BY DATE 2011 Flare Emission Calculations-NOx,CO,PM, D.GREENE I 5/7/2012 NMOC,VOC,SO2,Uncombusted HAPs,HCl CHECKED DATE J.MORGAN 1 6/8/2012 OBJECTIVE:Calculate flare emissions based on LFG consumption LFG Consumption: 979,346,976 scf/yr(CY11) Heat Content: 500 Btu/scf Calculated MMBTU: 489,673 MMBtu/yr(CY10) A PPROACH:Use manufacturer data and AP42 equations and emission factors SOLUTION: (I)NOx Emissions NOx emission factor= 0.068 lb/MMBtu (AP42,Table 13.5-1) LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 hr/year CMNOx=(0.068 lb/MMBtu)•(489,673 MMBtu/yr)= 33,297.8 Ib/ r NOz CMNOx= (33,297.8 lb/yr)/(8,760 fir/yr)— 3.80 1b/hr NOz CMNOx= (33,297.8 lb/yr)/(2,000 hr/yr)— 16.65 tn/ r NOx (2)CO Emissions CO emission factor= 0.37 lb/MMBtu (AP42,Table 13.5-1) LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 fir/year CMCO=(0.370 lb/MMBtu)'(489,673 MMBtu/yr)— 181,179.2 1b/ r CO CMCO= (181,179.2 Ib/yr)/(8,760 hr/yr)= 20.68 lb/hr CO CMCO= (181,179.2 Ib/yr)/(2,000 hr/yr)= 90.59 tn/ r CO (3)PNt Emissions PM emission factor= 17 Ib/l06 W CHq (AP42,Section 2.4,Table 2.4-5) LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 hr/yr HHV of natural gas= 1,020 Btu/ft3 (AP42,Section 3.2) Equivalent amount of CH4 consumed—(489,673 MMBtu/yr)/(1,020 MMBtu/l06 ft3)= 480.07 x 106 ft'CH4 CMPM=(17 lb/million ft3 CH4).(480.07 million ft3 C114)= 8,161.2 Ib/ r PM CMPM=(8,161.2 lb/yr)/(8,760 hr/yr)= 0.93 Ib/hr PM CMPM= (8,161.2 Ib/yr)/(2,000 hr/yr)= 4.08 tn/ r PM SCS ENGINEERS SHEET 2 of C'LILN'I PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inv ento 07211014.01 SUBJECT BY DATE 2011 Flare Emission Calculations-NOx,CO,PM, D.GREENE 5/7/2012 NMOC,VOC,S02,Uncombusted HAPs,HCl CHECKED DATE J.MORGAN 6/8/2012 (4)NMOC Emissions -Use the default concentration of NMOC(as hexane)from AP42 Table 2.4-2. The default NMOC concentration is 595 ppmv. -Use Equations(3),(4),&(5)of AP-42,Section 2.4 to determine NMOC emissions. Molecular weight of hexane= 86.18 g/gmol LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 hr/yr HHV of landfill gas= 500 Btu/ft' Amount of landfill gas consumed=(489,673 MMBtu/yr)/(500 MMBtu/million ft3)= 979.35 x106 ft3 LFG Eqn(3) QNMOC=(979.35 x 10*113)*(m3/35.3198 ft)*(595 ppmv/106)= 16,498 m'/yr Eqn(4) UMNMOC=(16,498 m3)*[(86.18 g/gmol* I atm)/(8.205E-5 m3-atm/gmol-K*1,000 g/kg*(273+25 K))]_ UMNMOC= 58,149.6 kg Eqn(5) CMNMOC=[58,149.6 kg*(I -NCO /100)]+58,I49.6 kg*(NCOL/100)*0 -N(,B/100)] NCOL=100%since talc is based on actual flow rate to the flare and not an assumed collection rate. NCNT=99.2% Assume that the flare is capable of reducing NMOCs 99.2%by weight(AP42 Table 2.4-3). CMNMOC=58,149.6 kg*(I -100/100)]+58,149.6 kg*(100/100)*(1-99.2/100)]= 465.20 kg CMNMOC=(465.20 kg)*(2.2lb/kg) = 11,023.4 Ib/yr NMOC CMNMOC=(1,023.4 lb/yr)/(8,760 hr/yr) = 0.12 Ib/hr NMOC CMNMOC=(1,023.4 lb/yr)/(2,000 lb/tn)= U.SI tn/yr NMOC (5)VOC Emissions - Use Note"c"from Table 2.4-2. The default VOC content at non-co-disposal sites is 39%of NMOC by weight(235 ppmv as hexane). CMva=1,023.4 lb/yr NMOC*0.39= 399.14 lb/yr VOC CMva=0.12 Ib/hr NMOC*0.39= 0.05 lb/hr VOC CMva=0.51 tn/yr NMOC*0.39= 0.20 tn/yr VOC f SCS ENGINEERS SHEET 3 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Flare Emission Calculations-NOx,CO,PM, D.GREENE 5/7/2012 NMOC,VOC,S02,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/8/2012 (6)S02 Emissions -Use Equations(3),(4),&(7)from AP-42 Section 2.4 to determine SO,emissions. H2S concentration= 35.5 ppmv AP-42 Molecular weight of sulfur(S)= 32 g/gmol Molecular weight of hydrogen sulfide(1 34 g/gmol HHV of landfill gas= 500 Btu/ft' LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 hr/yr Amount of landfill gas consumed=(489,673 MMBtu/yr)/(500 MMBtu/MM ft3)= 979.35 x106 ft'LFG Eqn(3) Qu2s= (979.35 x 106 ft)*(m'/35.3198 ft)*(35.5 ppmv H2S/106)= 984 m'HZS Qs=(984 in HZS)*(32 g/gmol S/34 g/gmol H2S)= 926 in S Eqn(4) UMs=(926 in 3)*[(32 g/gmol*I atm)/(8.205E-5 m'-atm/gmol-K•1,000 g/kg"(273+25 K))]_ UMs= 1,212.48 kg S Eqn(7) CMso2=1,212 kg S*(NCOU100)*2.0"(98%conversion efficiency of S to S02) Ncoc=100%since cale is based on actual flow rate to the flare and not an assumed collection rate. CMso2=1212.48 kg S*(100/100)*2.0"0.98= 2,376A5 kg/yr CMso2=(2,376.45 kg)*(2.2 Ib/kg)= r 5,228.19 Ib/yr SO, CMso2=(5,228.19 Ib/yr)/(8,760 hr/yr) r 0.60 lb/hr S02 CMso2=(5,228.19 lb/yr)/(2,000 hr/yr)= 2. 11 to/yr S02 (7) Hazardous Air Pollutant(HAPs)Emissions -HAPs are calculated in a manner consistent with NMOCs,except that the concentration and molecular weight of the individual HAPs are substituted into the equations. See Table 3 for a summary of flare HAP emissions. Example 1,1,1-trichloroethane Molecular weight=133.41g/gmol Concentration=0.0003 ppmv Site Specific Testing for the 2005 Compliance Demonstration Qtj,jd mom jwe=(979.35 x le ft)•(m'/35.3198 ft')*(0.0003 ppmv/106)= 0,0083 m'/yr Clvlj j j_,„chji h•,c=(0.0083 m'/yr)*[(133.41 g/gmol* I atm)/(8.205E-5 m'-atm/gmol-K* 1,000 g/kg*(273+25 K))] CMl.t.t-tmhlm hmc= 0.045 kg/yr 1,1,1-trichloroethane CMI,i,i_mchi�h.n (0.045 kg/yr)*(2.2lb/kg)*(ton/2,000Ib)= 4.99E-05 ton 1,1,1-trichloroethane to flare 1,1,1-trichloroethane=CM1,1,1.1.ch~h,*c(tons/yr)•(I-Near/100) Ncmm=98%destruction efficiency(AP42 Table 2.4-3) 1,1,1-tfichloroethane=4.99e-5 tons/yr*(1-(98/100)) r 9.99E-07 ton1,1,1-trichloroethane toatmos her SCS ENGINEERS SHEET 4 of 5 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventor 07211014.01 SUBJECT BY DATE 2011 Flare Emission Calculations-NOx,CO,PM, D.GREENE 5/7/2012 NMOC,VOC,SO2,Uncombusted HAPs,HCI CHECKED DATE J.MORGAN 6/8/2012 (7)HAP Emissions,continued 2011 LFG Consumption(MMBtu/yr)= 489,673 HHV of LFG(Btu/fe) Soo 2011 LFG Consumption(fts/yr)= 979,346,976 2011 LFG Consumption(ms/yr)= 27,727,988 Landfill Gas Temperature(sC)'= 25 Halogenated Destruction Eff.(%)_= 98.0% Non-Halogenated Destruction ER.(%)I= 99.7% Mercury Compound Destruction Eft(%)s= 0.0% Pollutant Mot.WL Care.$ Q(p)` um( )" Flare Flare of my On,/yrl (k,br) Ib/ (lb DTI pN I.LI-inchloroethane TAP,HAP 133.41 0.0003 0.01 0.05 0.10 0.00 9.99E07 I,1,2,2-tetrachloroethane TAP.HAP 167.85 0.0002 0.01 0.04 0.08 0.00 8.38E-07 I Idichlomcthanc1 AP.H"P 98.97 0.0338 0.94 3.79 8.34 0.17 8.34E-05 I I dichlorocthrnc TAP.tuP 96.94 0,0002 0.01 0.02 0.05 0.00 4.84E-07 12dichloroethane TAP.MP 98.96 0.0003 0.01 0.03 0.07 0.00 7.41E-07 1 2dichloro ro ane HAP 112.99 0.0003 0.01 0.04 0.08 0.00 8.46E-07 aa Ionenitrilc T"P'rur 53.06 0.0005 0.01 0.03 0.07 0.00 9.93F.-O8 benze 1r. 78.11 0.0348 0.96 3.08 6.78 0.02. 1.022E-05 carbon disulfide 1AP.11AP76.13 0.0003 0.01 0.03 0.06 0.00 8.55E-U8 carbon tetrachloride TAP'H"P 153.84 0.0314 0.87 5.48 12.05 0.24 - 1.21 E-04 carbon I sulfide H"P 60.07 0.4900 13.59 33.38 73.43 0.22 1.10E-04 chlorobcnzrne 112.56 0.0002 0.01 0.03 0.06 0.00 5.62E-07 chlomethanc 1AP.11AP64.52 0.0002 1 0.01 0.01 0.03 0.00 3.22E-07 chloroform TAP.HAP 119.39 0.0003 OAI 0.04 0.09 0.00 8.94E-07 chlmomethane TAP,HAP 50.49 0.0001 0.00 0.01 0.01 0.00 1.26E-07 dichlorobenzenc TAP.tun 147.00 0.0003 0.01 0.05 0.11 0.00 L IOE-06 dichlorodifluoromethane TAP 120.91 2.6511 73.51 363.50 799.71 15.99 8.00E-03 dichloromethanc T"P'HAP 84.94 0.0010 0.03 0.10 0.21 0.00 2.12E-06 ethyl merca tan TAP 62A3 2.2800 63.22 160.64 353.41 1.06 5.30E-04 eth (benzene uP 106.16 0.0003 0.01 0.04 0.08 0.00 1.19E-07 cdaylenc dibromide TAP' 187.88 0.0002 0.01 0.04 0.09 0.00 9.37E-07 hexane TAP.HAP 86.18 0.1053 2.92 10.29 22.64 0.07 3.40E-05 hydrogen chloride TAP.uPT 35.45 42.0000 N/A N/A N/A 3826.36- 1.91E+00 hydrogen sulfide TAP 34.08 35.5000 984.34 1371.99 3018.38 9.06 4.53E-03 mcrcure and compounds TAP'"Ar 200.61 0.0003 0.01 0.07 0.15 0.15 7.31E-05 methyl ethyl ketone TAP 72.11 2.5838 71.64 211.29 464.84 1.39 6.97E-04 myth l isobutyl ketone TAP.HAP 100.16 0.0002 0.01 0.02 0.05 0.00 7.50E-08 methyl merca tan TAP 48A 1 2.4900 69.04 135.85 298.87 L 0. 4.48E-04 chloroeth Iene TAP,MP 165.83 0.0331 0.92 6.22 13.69 0.27 1.37E-04 toluene TAP.HAP 92.13 0.0804 2.23 8.40 18.47 0.06 2.77E-05 trichloroeth Iene T"P'ruP 131.40 0.0002 0.01 0.03 0.07 0.00 6.56E-07 vinyl chloride TAP.HAP 62.50 0.3983 11.04 28.23 62.11 I.24 z lens TAP,RAP 106.16 0.0318 0.88 3.82 8.41 0.03 1.26F.-05 Total HAPs Only --- 103.36 227.39 3,828.84 1.91 Total TAPS Only --- 2,313.181 5,089.011 1 3,857.02 1.93 Notes: 1.The landfill gas temperature was obtained from AP42 Page 2.4-5. 2. The AP42 Section 2.4 default for Flare Destruction Efficiency was assumed. 3. Average flow rate recorded in 2009. 4. Pollutant concentrations used to compute the estimated emissions are from AP-42 and Site Specific Testing for the 2005 Compliance Deomonsoation, 5. Clip)=Volumetric emission rate of the pollutant. APA2 Section 2.4 equation(3). S. J Wp)=Uncontrolled mass emissions of pollutant. 8 no collection exists,this is also equal to the fugitive emission rate,FM(p)of the pollutant. AP42 equation(4). 7. HG emissions are a product of the combustion process and are calculated in a manner different than the other pollutants listed above. See page 5 of the calculation sher TAP denotes compounds that are classified as toxic air pollutants per North Carolina Department of Environment and Natural Resources. HAr denotes compounds that are classed as hazardous air pollutants per AP42 and CAA Section 112, 'The compounds listed above were compiled from AP42(revised Nov.1998)and CAA Section 112. SCS ENGINEERS SHGBT 5 ul I PROJECT East Carolina Environmental Landfill JOB NO. Its public Services 2011 Air Emissions Inventory 07211014.01 l 1 BJECT BY DATE 2011 Flare -Emissions D.GREENE 5/7/2012 Uncombusted HCl CHECKED DATE J.MORGAN 6/8/2012 (8)HCI Emissions -Use Equations(3),(4),&(10)from AP-42 Section 2.4 to determine HCl emissions. HCl concentration= 42.0 ppmv (AP-42,Page 2.4-9) Molecular weight of chlorine(Cl)= 35.453 g/gmol HHV of landfill gas= 500 Btu/ft' LFG consumed= 489,673 MMBtu/yr Hours of operation= 8,760 hr/yr Amount of landfill gas consumed=(489,673 MMBtu/yr)/(500 MMBtu/MM 113)= 979.35 x106 ft3 LFG Eqn(3) QS= (979.35 x MM 0)*(m3/35.3198 ft3)*(42.0 ppmv C1110^6)= 1,164.59 m3 CI Eqn(4) UMCI=(1,164.58 m3)*[(35.453 g/gmol* 1 atm)/(8.205E-5 m3-atm/gmol-K* 1,000 g/kg*(273+25 K))]_ UMci= 1,688.6 kg Cl Eqn(10) CMHCI=1,688.6 kg Cl* (NCOU100)* 1.03*(NCNT/100) NCoL=100%since calc is based on actual flow rate to the flare and not an assumed collection rate. NcNT=100%Assume the flare is capable of converting 100%of the Cl to HCI. CMHCI=1,688.6 kg CI*(100/100)*1.03*(100/100)= 1,739.3 kg/yr HCl CMHC1=(1,739.3 kg)*(2.2 lb/kg) = 3,826.4 Ib/ r HCI CMHCI=(3,826.4 lb/yr)/(8,760 hr/yr)= 0.44 Ib/hr HCI CMHCI=(3,826.4 Ib/yr)/(2,000 Ib/tn)= 1.91 to r HCI SCS ENGINEERS SHEET I of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 072I 1014.01 SUBJECT BY DATE 2011 Insignificant Sources-Solar Flares(ES-06) D.GREENE 6/8/2012 CHECKED DATE J.MORGAN 6/8/2012 OBJECTIVE:Estimate emissions resulting from the use of small solar spark flares APPROACH:Use manufacture and site provided data SOLUTION: Number of Solar Flares in operation during CY10: 3 Estimated flow per flare: 60 scfm Total Estimated Flow: 180 scfm Solar Flare Usage 8 hrs/day 365 days/year 175,200 min/yr (I)NOx Emissions NOx Emissions Rate 0.072 Ibs Nox/hr/Flare Total NOx Emisisons 0,216 Ibs Nox/hr 630.72 lb/ r NOx 0.22 Ib/hr NOs 0.32 tn/ r NOx (2)CO Emissions CO Emissions Rate 0.302 Ibs CO/hr/Flare Total CO Emisisons 0.906 Ibs CO/hr 2,645.52 1b/y r CO 0.91 Ib/hr CO 1.32 tn/ r CO (3)PM Emissions PM Emissions Rate 0.031 Ibs PM/hr/Flarc Total PM Emisisons 0.093 Ibs PM/hr 271.56 Ib/yr PM 0.09 Ib/hr PM 0.14 in/ r PM SCS ENGINEERS SHEET 2 of (LIENT PROJECT East Carolina Environmental Landfill JOB NO. Rc ublic Services 2011 Air Emissions inventory 072I 1014.01 SUBJECT BY DATE 2011 Insignificant Sources-Solar Flares(ES-06) D.GREENE 6/8/2012 CHECKED DATE J.MORGAN 6/8/2012 OBJECTIVE:Estimate emissions resulting from the use of small solar spark flares APPROACH:Use manufacture and site provided data SOLUTION: Number of Solar Flares in operation during CY 10: 3 Estimated Flow per flare: 60 wf n Total Estimated Flow: 180 Kim Solar Flarc Usage 8 hrs/day 365 days/year 175,200 min/yr f 1)SOt Emissions SO,Emissions Rate 0.014 Ibs SOr/hr/Flare Total SO,Emisisons 0.042 IN SO,/hr 122.64 Ib/yr SO: 0.04 Ib/hr SO, 0.06 to/yr SOr (2)VOC Emissions VOC Emissions Rate 0.004 IN VOC/hr/Flare Total VOC Emisisons 0.012 Ibs VOC/hr 35.04 Ib/ r VOC 0.01 Ib/hr VOC 0.02 tn/ r VOC (3)NMOC Emissions Per AP42,assume NMOC=110.39 of VOC 89.85 lbhr NMOC 0.39 VOC to NMOC 0.03 Ib/hr NMOC 0.04 tn/yr NMOC SCS ENGINEERS SHEET 3 of 3 CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY I DATE 2011 Insignificant Sources-Solar Flares(ES-06) D.GREENE 6/8/2012 CHECKED DATE J.MORGAN 6/8/2012 Emissions Rates based upon data for compounds common with main Flare and listed by manufacturer Total Solar Flares: 3 Operational year: 33.3% (percent of full year as operated at 8 hr/d) Hydrogen chloride emissions calculated from ratio of Solar Flare 112S emission to Main Flare H2S emission: Main Flare H2S Emissions*(Solar Flare 112S Emissions/Main Flare 112S Emissions)= 0.01 Ibs/yr Pollutant Mol.Wt. Flare Flare 3 Flares 3 Flares (g/gmol) (lb/yr) (tn/yr) (lb/ eriod tn/ eriod yr 1.1,1-trichloroethaneI"P�I[AP 133.41 1.2E-05 6.00E-09 120E-05 6.00E-09 1,1,2 -tetmchloroethaneTAP,IAP 167.85 3.5E-05 1.75E-08 3.50E-05 1.75E-08 1,1-dichloroethane TAP, HAP 98.97 4.4E-05 2.20E-08 4.40E-05 2.20E-08 1,1-dichloroetheneTAP'11AP 96.94 3.7E-06 1.85E-09 3.70E-06 1.85E-09 1.2-dichloroethane TAP,IMP 98.96 7.6E-06 3.80E-09 7.60E-06 3.80E-09 1.2-dichloTopropaneHAP 112.99 3.9E-06 1.95E-09 3.90E-06 1.95E-09 acrylonitrileTAP.HAP 53.06 9.6E-06 4.80E-09 9.60E-06 4.80E-09 benzene TAP.HAP 78.11 4.2E-06 2.10E-09 4.20E-06 2.10E-09 carbon disulfide TAP,HAP 76.13 1.3E-06 6.50E-10 1.30E-06 6.50E-10 carbon tetrachloride TAP.HAP 153.84 1.2E-07 6.00E-I1 1.20E-07 6.00E-I I carbonyl sulfide HAP 60.07 8.4E-07 4.20E-10 8.40E-07 4.20E-10 chlorobenzeneTAP,HAP 112.56 5.4E-06 2.70E-09 5.40E-06 2.70E-09 chloroformTAP.HIAP 119.39 6.8E-07 3.40E-10 6.80E-07 3.40E-10 chloromethane TAP HAP 50.49 1.2E-05 6.00E-09 1.20E-05 6.00E-09 dichlorobenzene TAP.[]A? 147.00 5.9E-06 2.95E-09 5.90E-06 2.95E-09 dichlorodifluoromethaneTAP 120.91 3.4E-06 1.70E-09 3.40E-06 1.70E-09 dichloromethane TAP.HAP 84.94 2.3E-04 1.15E-07 2.30E-04 1.15E-07 ethyl merca tan TAP 62.13 4.0E-06 2.00E-09 4.00E-06 2.00E-09 cth (benzene HAP 106.16 1.4E-05 7.00E-09 1 AOE-05 7.00E-09 ethylene dibromide TAP.11AP 187.88 3.6E-08 1.80E-II 3.60E-08 1.80E-I1 hexane TAP.HAP 86.18 1.6E-05 8.00E-09 1.60E-05 8.00E-09 hydrogen sulfide TAP 34.08 3.4E-05 1.70E-08 3.40E-05 1.70F.-08 mercury and compounds TAP.HAP 200.61 5.6E-07 2.80E-10 5.60E-07 2.80E-10 methyl ethyl ketone TAP 72.11 1.5E-05 7.50E-09 1.50E-05 7.50E-09 methyl isobut I ketone TAP,nAP 100.16 5.3E-06 2.65E-09 5.30E-06 2.65E-09 methyl merca tan TAP 48.11 3.4E-06 1.70E-09 3.40E-06 1.70E-09 erchloroeth leneTAP.HAP 165.83 12E-04 6.00E-08 1.20E-04 6.00E-08 toluene TAP,HAP 92.13 LOE-04 5.00E-08 1.00E-04 5.00E-08 trichloroeth lene TAP,HAP 131.40 7.0E-05 3.50E-08 7.00E-05 3.50E-08 vin lchlorideTAP'HAP 62.50 8.7E-05 4.35E-08 r8j70E-OS 4.35E-08 xylenes H"P°AP 106.16 3.7E-05 1.85E-08 3.70E-05 1.85E-08 Total IIAPs/TAPS --- 8.9E-04 4.43E-07 8.86E-04 4.43E-07 SCS ENGINEERS SHEET 1 of CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Storage Tank Emissions D.GREENE 6/8/201 CHECKED DATE J.MORGAN 6/8/2012 OBJEC"I IN E:Insiginificant source tank emissions based on design capacity and throughput APPROACH:Use EPA's TANKS 4.09 Program SOLUTION: The following information was entered into TANKS 4.09: Parameter Diesel Tank Product Dicscl Fuel Volume,gal 3,000 Length,It IS Diameter,ft 5.8 Throuh ut,gal/yr 128,906 As reported by TANKS 4.09(see attached report): Diesel Tank 3 000 al Pollutant Ib/ r ton/ r VOC 4.36 2.18E-03 NMOC* 4.36 2.18E-03 NMOC emissions are conservatively estimated to be equal to VOC emissions. For emissions purposes waste oil modeled as Petroleum Distillate#2 SCS ENGINEERS SHEET I of I CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Leachate Tanks Emission Calculations-NMOC,VOC,HAPs D.GREENE 6/8/2012 CHECKED DATE J. MORGAN 6/8/2012 OBJECTIVE:Calculate emissions for leachate storage tanks based on laboratory analysis and throughput. APPROACH:Use mass balance approach,assumes that all organic content volatilizes. SOLUTION: L.eachate throughput: 4,466,774 gal/yr (Data obtained from landfill) Organic content: 547.3 µg/L (See Below) CMva=(547.3 µg/L)•(4,466,774 gal/yr)'(3.785 Ugal)•(1 lb/453.6E+03 mg)'(1 mg/1,000 µg) 20.40 Ib/yr VOC CMva=(20.40 Ib/yr)/(8,760 hr/yr)= 2.33E-03 Ib/hr VOC CMvor.=(20.40 Ib/yr)/(2,000 Ib/bt)= 1.02E-02 ton/yr VOC Note: VOC emissions arc conservatively estimated to equal NMOC,HAP,and TAP emissions. VOC L' Ib/ r Ib/d Acetone= 200 7.45 2.04E-02 Benzene 5 n.19 5.11E-04 Dichloromethane 2.5 0.09 2.55E-04 Ethyl ben/enc 5.8 0.22 5.92E-04 Methyl Ethyl Ketone 300 11.18 3.06E-02 Methyl Isobu (Ketone 5 0.19 5.11E-04 Toluene Ifi 0.60 1.63E-03 X lens 0.48 L33F,-03 547.3 Notes: 1 "Municipal Solid Waste Landfill Leachate Charatcterization Study,"Environmental Research&Educational Foundation,September 2007,(Table 4'Extended VOCs") Assumes data is representative of East Carolina Landfill leachate VOC content(Table 4"Extended VOCs") 2 Acetone neither HAP or TAP,but included as a VOC for VOC purposes SCS ENGINEERS SHEET 1 of I CLIENT PROJECT East Carolina Environmental Landfill JOB NO. Republic Services 2011 Air Emissions Inventory 07211014.01 SUBJECT BY DATE 2011 Facility Wide Emissions Surnmary D.GREENE 6/8/2012 CHECKED DATE J.MORGAN 6/8/2012 Diesel Diesel Welding Leachate Solar Pollutant Landfill Flare Tank Engines Operations Tank Flares TOTAL TOTAL. (lb/yr) (lb/yr) (lb/yr) (Ib/vr) Ob/yr) (Ib/yr) (lb/yr) Qb/yr) ton/yr NOx 33,298 13,680 631 47,609 23.80 SO2 5,228 900 122.6 6 251 3.13 CO 181,179 2,940 2,646 186,765 93.38 PM 8161 too 272 8533 4.27 NMOC 45515 1023.4 4.36 20.40 89.8 46653 23.33 VOC 17751 399.1 4.36 1,100 20.40 35.0 19,310 9.65 1.1,I-trichloroethaneT"."AP 0.04 0.00 1.20E-05 4.E-02 1.95E-05 1,1,22-tetrachloroethane TAP"AP 0.03 0.00 3.50E-05 3.E-02 1.64E-05 I.I dichloroethanc TAP'"AP 3.09 0.17 4.40E05 3.26 1.63E-03 I.I dichlorocthcncTAP'"AP 0.02 0.001 3.70E-06 0.02 9.46E-06 1.2-dichloroethanc TAP'HAP 0.03 0.001 7.60E-06 3.E-02 1.45E-05 1,2dichloro ro ane HAP 0.03 0.002 3.90E-0fi 3.E-02 1.65E-05 acetaldch do 2.40 2.4 1.20E-03 acrolcin - - -0.30 3.0.E-01 1.50E-04 actvlonitrile TAP'xAP 0.02 0.0002 9.60E-06 2.E-02 1.24E-05 benzene r+,HAP 2,51 0.02 2.90 0.19 4.20E-06 5.62 2.81E-03 carbon disulfide TAP'HAP 0.02 0.0002 1.30E-06 2.E-02 1.07E-05 carbon tetrachloride TAP'""P 4.47 0.24 1.20E-07 4.71 2.36E-03 carbonyl suffli 27.24 0.22 8.40E-07 27.5 1.37E-02 chlorobemcnc TAP'HAP 0.02 0.00 - SAOE-06 2.E-02 LIOE-05 lo chvclhanc TAP.HAP 0.01 0.00 _ - LE-02 6.29E-06 chloroform TAP'HAP 0.03 0.002 6.80E-07 3.E-02 1.75E-05 chloromethave TAP HAP 0.005 0,0003 1.20E-05 5.E-03 2.4712.-OE- dwhlorobcnzcnc TAP.111 0.04 0.00 5.90E-06 4.E-02 2.15L-05 dichlorodifluaromethene TAP 296.62 15.99 3.40E-06 312.6 1.56E-UI dichlommethane TAP'"AP 0.08 0.00 0.09 2.30E-04 2.E-01 8.81E-05 cth 1 merc AP a tan T 131.09 1.06 -- - 4.00E-06 132.1 6.61E-02 et111benzenc'1 HM 0.03 0.00 0.22 1.40E-05 2.5.E-01 1.23E-04 ethylene dibromide TAP"AP 0.03 0.00 3.60E-08 4.E-02 1.83E-05 furinaldch de - 3.60 3.6 1.60E-03 hexane TAP'i^P -8.40 0.07 _- - 1.60E-05 8.47 4.23E-03 hvdro yen chloride Ter HAP 3,826 _ - 1.44E.-02 3,826 1.91E+00 h dnTmn sulfide TV 1.119.55 9.06 3.40E-05 1129 5.64E-01 Manganese 101.00 t01 5.05E-02 incticury,and compounds TAP.HAr 0.05 0.15 5.60E-07 2.E-01 1.00E.-04 methyl ethyl ketone T'P 172.41 1.39 11.18 1.50E-05 185.0 9.25E-02 meth I isohu[ I ketone I1P'HAP 0.02 0.00 0.19 5.30E-06 2.E-01 1.03E-174 methyl coerce tan TAP 110.85 0.90 - -- 3.40E-06 111.8 5.59E-02 of c clico organic urr -74.10 74.1 3.71E-02 crchlorocth lent TAP.HAP 5.08 0.27 - - 1.20E-04 5.35 1 2.68E-03 tolucncTAP.HAP 6.85 0.06 1.30 0.60 1.00E-04 8.8 4.40E-03 trichloroetit lens TAP.HM 0.02 0.00 - ___ - 7.00E-05 3.E-02 129L 01 vinyl chloride rAe'Hoe 44.49 1.24 - - 8.70E-05 45.7 191.-02 x tomes TAP'HA 3.12 0.03 0.911 --- 0.48 170E1)5 4.53 `d-Ili Total HAPs Only 1,927.73 3,828.84 85.50 101.01) 1.76 0.02 5,944.85 2.97 Total TAPS Only 1,931.82 3,857.02 85.50 101.011 11.18 0.02 5 986.54 2.99 Total l 1APs1TAPs 1,936.32 3,657.24 85.50 101.01) 12.94 1 0.02 5993.02 3.00 Noms. T"P denotes rompowds that arc claui6d as toxic ait pdMatns per North Camlvas Ueputnent of Emironrmo and Nataral Rmam,za. TIAP d.i9c,crnm,.,6 That are class;bed as buardma au Pdl...,ox per AP-42 ead CAA Sato.112. -The canifooad..Ilsted elxrve woe con i1cJ[iota AP42(tew.ed Noe 1998)aml CM Section 112. fil�.,,� .\Prus.Qu1 Fix.a xanks�v7J\suuu„a,ydiaYYay.htn, Oagc i ur'6 TANKS 4.0.9d Emissions Report - Detail Format Tank Indentification and Physical Characteristics Identification User Identification: ECE 3000gal Diesel City: State: North Carolina Company: Type of Tank: Horizontal Tank Description: East Carolina 3,000 gallon Diesel Tank Tank Dimensions Shell Length(ft): 15.00 Diameter(ft): 5.80 Volume(gallons): 3,000.00 Turnovers: 42.97 Net Throughpul(gal/yr): 128,906.25 Is Tank Heated(y/n): N Is Tank Underground(y/n): N Paint Characteristics Shell Color/Shade: Gray/Medium Shell Condition Good Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig) 0.03 Meterological Data used in Emissions Calculations:Raleigh,North Carolina(Avg Atmospheric Pressure=14.53 psia) Friday, June 08, 2012 flt.fi� .�Pivgraul FiivN\tanks-tvyd\sutucttarydisptay.htnt ?age ui 6 TANKS 4.0.9d Emissions Report - Detail Format Liquid Contents of Storage Tank ECE 3000gal Diesel -Horizontal Tank North Carolina Liquid Daily liquid Surf. Bulk Vapor Liquid Vapor Temperature(deg F) Temp Vapor Pressure(psia) Mol. Mass Mass Mol. Basis for Vapor Pressure Mixture/Component Month Avg, Min. Max. (deg F) Avg. Min. Max. Weight. Fracl. Fracl. Weight Calculations Distillate fuel oil no.2 All 68.49 57.95 79.03 62.36 0.0086 0.0061 0.0117 130.0000 188.00 Option l:VP60=.0065 VP70=.009 Friday, June 08, 2012 file:u%,:\Program Fiies\i anks,+uvd\summarydispiay.htm Page S of 6 TANKS 4.0.9d Emissions Report - Detail Format Detail Calculations (AP-42) ECE 3000gal Diesel -Horizontal Tank North Carolina Annual Emission Calcaulations Standing Losses(Ib): 1.3946 Vapor Space Volume(cu ft): 252.4280 Vapor Density(lb/cu ft): 0.0002 Vapor Space Expansion Factor: 0.0761 Vented Vapor Saturation Factor: 0.9987 Tank Vapor Space Volume: Vapor Space Volume(cu ft): 252.4280 Tank Diameter(ft): 5.8000 Effective Diameter(ft): 10.5275 Vapor Space Outage(ft): 2.9000 Tank Shell Length(ft): 15.0000 Vapor Density Vapor Density(lb/cu ft): 0.0002 Vapor Molecular Weight(IbBb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.0086 Daily Avg.Liquid Surface Temp.(deg.R): 528.1618 Daily Average Ambient Temp.(deg.F): 59.2833 Ideal Gas Constant R (psia cuft/(Ib-mcl-deg R)): 10.731 Liquid Bulk Temperature(deg.R): 522.0333 Tank Paint Solar Absorptance(Shell): 0.6800 Daily Total Solar Insulation Factor(Btu/sgft day): 1,393.0797 Vapor Space Expansion Factor Vapor Space Expansion Factor: 0.0761 Daily Vapor Temperature Range(deg.R): 42.1602 Daily Vapor Pressure Range(psia): 0.0056 Breather Vent Press.Setting Range(psia): 0.0600 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.0086 Vapor Pressure at Daily Minimum Liquid Surface Temperature(psia): 0.0061 Vapor Pressure at Daily Maximum Liquid Surface Temperature(psia): 0.0117 Daily Avg.Liquid Surface Temp.(deg R): 528.1618 Daily Min,Liquid Surface Temp.(deg R): 517.6217 Daily Max.Liquid Surface Temp.(deg R): 538.7018 Daily Ambient Temp.Range(deg.R): 21.7167 Vented Vapor Saturation Factor Vented Vapor Saturation Factor: 0.9987 Vapor Pressure at Daily Average Liquid: Surface Temperature(psia): 0.0086 Vapor Space Outage(ft): 2.9000 Working Losses(Ib): 2.9755 Vapor Molecular Weight(IbAb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.0086 Annual Net Throughput(ga9yr.): 128,906.2500 Annual Turnovers: 42.9688 Turnover Factor: 0.8648 Tank Diameter(ft): 5.8000 Working Loss Product Factor: 1.0000 Friday,June 08, 2012 filu.i/L—Trograrn Fiius\ianks+u7d\summarydispiay.htm Page,+ ut'6 Total Losses Qb): 4.3601 Friday, June 08, 2012 fitc.ii%-,.\Prugiain Fiic�, ialks-tv7d\Suiilularydispiay.htnl Page D oI 6 TANKS 4.0.9d Emissions Report - Detail Format Individual Tank Emission Totals Emissions Report for: Annual ECE 3000gal Diesel - Horizontal Tank North Carolina Losses(lbs) Components I Working LossI Breathing LossI Total Emissions Distillate fuel oil no.2 �j 2.98 1.38 4.3611 Friday, June 08, 2012