AQ_F_0800044_20120319_EI_Fac-EI-Rpt

Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2011
These forms must be completed and returned even if the facW did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal defmition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
ERTIFICATION STATEMENT:
Tm2oMpt7 Legally Respon5ible Official,read aud sign afteX all submissions amLadL
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's SiwiWire Belo use blue' k : Date Signed:
Printed Name: David
Signature
This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: [e-mail]
0 U LS
Information on this Form cannot be held confidential �I MAR 9 2012
DAQ WARO
1

Total Y 2011 Emission Summary Recorded in ED Facility 1D#: 0800044
Facility ota C y ty
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Green House Gases Pollutants(GHG) Actual Emissions
Tons/Vr °/o Change
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Methane(CI-14) 74-82-8 0,025700 0.019800 29.8%
Carbon Dioxide(CO2) 124389 8,970.06 7,200.16 24.6%
Nitrous Oxide(N20) 10024972 0.047500 0.038100 24.7%
CO2 equivalent(sum of individual GHG pollutant emission times their 1995 8,151.49 metric tons
IPCC Global Warming Potential(GWP),converted to metric tons)
Criteria Pollutants Actual Emissions % Change
(Tons/Year)
Pollutant CY 2011 CY 2010
from ED from Fees
CO 2.79 1.90 46.80/4
NOx 13.79 9.07 52.0%r
PM(TSP) TSP 1.06 0.730000 45.20i,,
PM 10 I'm I O 0.660000 0.420000 �Z7.1%,
PM2.5 PM2 S 0.370000 0.180000 105.60/,
S02 S02 17.06 13.60 25.4%,
VOC Voc 491.30 231.31 112.4%
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPS) (Pounds/Year)
Pollutant CY 2011 CY 2010
from ED from Fees
Polycyclic Organic Matter(Specific Compounds from OAQPSJor 1.17 0.876450 1,.E i"',
T
Benzo(a)pyrene(Component of 833291POMTV& 50-32-8 0.000330 0,000130 .
56553/7PAH)
Naphthalene(Component of 83329/POMTV) 91-20-3 1.17 0.876320
Polycyclic Organic Matter(7 PAN Compounds for NIF) 0.000330 0.000130 V,t
09/05/2012 Page I of 4

Facility Total CY 2011 Emission Summar,N Recorded in FD Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 018191'38
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Polycyclie Organic Matter(7 PAH Compounds for NIF) 0.000330 0.000130
Benzo(a)pyrene(Component of 83329/POMTV& 50-32-8 0.000330 0.000130
56553/7PAH)
Nickel& Compounds,sum total mass includes elemental 2.00 1.61
Nickel Unlisted Compounds (Component ofNIC- NIC-other 2.00 1 61 1
Specify)
Mercury& Compounds-all total mass includes Hg Vapor 0.333830 0.268160
Mercury Unlisted Compounds-Specify Compound HGC-Other 0.333830 0.268160 24.50%
(Component of HGC)
Manganese& compounds 1.56 1.25 '4
Manganese Unlisted Compounds-Specify NNC-Other 1.56 j_�
Compound(Component of MNC)
Lead& compounds 0.990370 0.795540 24.5,
Lead Unlisted Compounds-Specify Compound PBC-Other 0.990370 0.795540 24.-5
(Component of PBC)
Chromium(VI)Non-Specific Compounds, as Chrom(VI) 0.023150 0.018590 24.53„
(Component CRC
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-0ther 0.023150 0.018590 24 .;'7..
Specify Compound(Component of NSCR6& CRC)
Chromium-AlMial(includes Chromium(VI)categories,metal 0.48 _5.20
and others
Chromium(VI)Non-Specific Unlisted Compounds- NSCR6-other 0.023150 0.018590 24.5%,
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds-Specify CRC-Other I 1 5.18 24.5%
Compound(Component of CRC)
Cadmium& compounds(total mass includes elemental metal) l 23 0.982620
09/05/2012 Page 2 of

Facility Total CY 2011 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Cadmium&compounds(total mass includes elemental metal) 1.23 0.982620 5.2%,
Cadmium Unlisted Compounds-Specify Compound
CDC-Other 1.23 0.982620 25.111�11
(Component of CDC)
Beryllium& compounds(Total mass) 0.283360 0.223470 26.8%
Beryllium Unlisted Compounds-Specify Compound BEC-Other 0.283360 0.223470 26A'i;,
(Component of BEC)
Arsenic& Compounds(total mass of elemental AS,arsine and all 0.474370 0.375420 16 l
inorganic compounds)
Arsenic Unlisted Compounds-Specify Compound ASC-Other 0.474370 0.375420 26.40/,,
(Component of ASQ
Acetaldehyde 75-07-0 1.32 0.507600 160.0%
Acrolein 107-02-8 0.159980 0.061530 160.00/,
Benzene 71-43-2 1.78 0.754390 135V4,
Chloroform 67-66-3 6,087.00 6,498.00 -6.30G)
Ethyl acetate 141-78-6 11,201.73 13,423.58 -16.6';'„
Ethyl benzene 10041-4 0.050190 0.040310 24.5OX,
Fluorides(sum of all fluoride compounds as mass of F 16984-48-8 29.43 Not NIA
ion) Reported
Formaldehyde 50-00-0 28.07 21.70 29.40/4
Hexane isomers,except n-hexane HEXANEISO 723,161.35 317,924.35 127.50/,
Hexane,n- 110-54-3 104,693.65 105,012.54 -0.4°/,
Methanol(methyl alcohol) 67-56-1 137,066.19 23,366.46 486.60/,
Toluene 108-88-3 5.60 4,20 33.2'i„
Xylene(mixed isomers) 1330-20-7 0.490180 0,188520 160.0%
Xylene,o- 95-47-6 0.086020 0.069100 24.50/,
09/05/2012 Page 3 of 4

Largest Individual HAP Methanol(methyl alcohol) 137,060.19
Ibs
Total HAP Emissions 247,898.91
--j- I Ibs
DAO's Comments Kei,ardin!, Invcnlors
09/05/2012 Page 4 of 4

March 16,2012
Mr. Robert Fisher
Environmental Regional Supervisor II- Air Quality
NC Division of Air Quality
Washington Regional Office
943 Washington Square Mall
Washington,NC 27889
Subject: Annual Air Emissions Inventory ZO t�
Air Quality Permit No. 01819T38 ' (�
Facility ID: 07/08/00044
Avoca, Incorporated
Merry Hill,North Carolina �_ y
Bertie County
Fee Class: Title V
Dear Mr. Fisher:
In accordance to Avoca, Incorporated's Title V Air Quality Permit, I am forwarding the Inventory
Certification Form and supporting documentation for the Annual Air Emissions Inventory. The inventory
was submitted on March 15,2012 via the AERO program. The attached certification form and copies of
spreadsheets and calculations used in creating this inventory are being submitted to fulfill the
requirements of the annual report.
If there are any questions or comments concerning the included documentation or inventory report please
contact me at(252)325-0335.
Sincerely,
CalW
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
it I
1`1
252-482-2133 • Fax: [phone]
Mauins: P.O. Box 129, Merry Hill, NC 27957 • shimins: 841 Avoca Farm Road, Merry Hill, NC 27957

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2011
Total Run Time: 16571.0 HrsNr
Efficiency: 85 %
Sulfur Content 0.0015 %
Number 2 Fuel: 141000 BtufGal
Fuel Useas(oallons) Boller Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total
Month Boller#1 Boller02 Boller03 Boller Boller#1 Boiler#2 Boller#3 Boller (�) 0.bs1
Fuel Used Hours
January: 21038,9 21310.6 23130.0 -- 65479.5 588.5 555.2 514.0 1657.7 0.039 13.096
February: 22980.1 23091.5 433.9 46505.5 642.8 634.3 67.5 1344.6 0.028 9.301
March: 8079.3 8773.2 29529.0 46381.5 364.1 284.7 656.2 1305.0 0.027 9.276
April: 12168,6 5709.7 13628.3 31506.6 378.2 422.3 336.5 1137.0 0.019 6.301
May: 17528.2 6470.3 17806.5 41805.0 490.3 478.2 395.7 1364.2 0.025 8.361
June: 20820.8 51671.7 24399.0 96891.5 582.4 566.5 542.2 1691.1 0.057 19.378
Jul - 21861.1 54153.9 26689.5 - 1027D4.5 611.5 603.0 593.1 1807.6 0.061 20.541
Au ust: - 23856.0 63811.5 25929.0 113596,5 667.3 634.9 576.2 1878.4 0.067 22.719
Se tember. 91181.9 70978.1 20758.5- 112918.5 592.5 609.4 461.3 1663.2 0.067 22.584
October. 2D860.1 57957.9 16546.5 95364.5 583.5 600.9 367.7 1552.1 0.056 19.073
November: 5798.7 3777.9 913.5 10490.1 - 162.2 160.9 21.0 344,1 0.006 2,098
December: - 9863.4 - 13344.1 2173.5 25381.0 275.9 501:8 48.3- 826.0 0.015 5.076
Total: 206037.1 381050.4 201937.2 789024.7 5939.2 8052.1 4579.7 18571.0 0.467 167.805
Boller# ID# I GPH HI-Fire I GalsIHr HrfYr Galafy
1 H•101 143 34.7 5939.2 206037.1
2 H-102 143 63.0 6052.1 381050.4
3 H-103 180 44.1 4579.7 201937.2
Total 466 141.74672 18571 789024.7
Criteria Pollutants
Criteria Emisson Factor Boller#1 Boller#2 Boller#3 Total
Pollutants LbsJ1000 al. ons/Yr onslYr TonsNr onslYr
TSP 2.00 0.206 0.381 0.202 0.789
PM-10 1.00 0.103 0.191 0.101 0.395
PM-2.5 0.25 0.026 0.048 0.025 0.099
Sox 42.60 4.389 8.116 4.301 16.806
Nox 24.00 2.472 4.573 2.423 9.468
VOC 0.20 0.021 0.038 0.020 0.079
CO 5.00 0.516 0.953 0.505 1.973
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boller#1 Boller#2 Boller#3 Total
Pollutants (lbsl1000 gal) (LbsNr) (LbsNO (Lbs/Yr) (LbslYr)
Arsenic 5.92E-04 0.122 0.226 0.120 0.467 � 1
Benzene 2.14E-04 0.044 0.082 0.043 0.169
Beryllium 3.53E-04 0.073 0.134 0.071 0.278 L '�
Cadmium 1.55E-03 0.319 0.591 0.313 1.223
Chromium 8,18E-03 1.685 3.116 1.651 6.453 *1� e�( I�
Chromium VI 2.90E-05 0.0 0.011 0.0 0.0 V n
Ethyl benzene 6.35E-05 0.013 13 0.024 0.013 13 0.050 50 � I[look,
►/V�,r/��'Irpr/� "r
Flouride 3.73E-02 7.685 14.213 7.532 2OA31
Formaldehyde 3.30E-02 6.798 12,572 6.663 26.033 R
Lead 1.25E-03 0.259 0.478 0.253 0.990
Manganese 1.97E-03 0.407 0.752 0.399 1.558
Mercury 4.23E-04 0.087 0.161 0.085 0.334
Napthalene 1.29E-03 0.267 0.493 0.261 1.021
Nickel 2.54E-03 0.523 0.967 0.513 2.003
Toluene 6.20E-03 1.278 2.364 1.253 4.895
o-X lene 1.09E-04 1 0.022 0,041 0.022 0.086
H:1EnvironmemallAir PennhWir ReportsWnnual Air Emissions Inventory@011 ReporH2O11 AAE Calc

Page 2 or 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Green House Gas Pulutants
Emission Boller#1 Boller#2 Boiler#3 Boller#1 Boller#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (lbs/hr) (lbslhr) (Ibs/hr) (tonslyr) (tonslyr) (tonslyr) (tonslyr)
CO2 22700.00 787.49 1429.23 1000.93 2338.52 4324.92 2291.99 8955.43
Methane 0.06 0.0021 0.0038 0.0026 0.0062 0.0114 0.0061 0.0237
(CH4)
Nitrous Oxide 0.12 0.0042 0.0076 0.0053 0.0124 0.0229 1 0.0121 0.0473
(Nz0)
H:1EnvironmentahAir PermiVAir ReportslAnnual Air Emissions Inventory12011 Report12011 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory �^
Facility ID#:0800044 P`G
Generators : OS-2 l'
of
Year: 2011 _1r.
Total Run Time: 479.5 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.0015 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Pk-Gen Total (Lbs.)
January: 30.0 50.0 60.0 144.0 284.0 14.791
February: 30.0 50.0 40.0 0.0 120.0 6.250
March: 30.0 50.0 70.0 72.0 222.0 11.562
April: 37.5 87.5 120.0 468.0 713.0 37.133
May: 37.5 62.5 100.0 360.0 560.0 29.165
June: 142.5 237.5 1 240.0 936.0 1556.0 81.036
July: 37.5 62.5 50.0 828.0 978.0 50.934
August: 1192.5 1987.5 3180.0 540.0 6900.0 359.352
September: 30.0 50.0 80.0 0.0 160.0 8.333
October: 30.0 50.0 80.0 216.0 376.0 19.582
November: 30.0 50.0 80.0 36.0 196.0 10.208
December: 22.5 37.5 60.0 36.0 156.0 8.124
Total: 1650.0 2775.0 4160.0 0.0 3636.0 12221.0 636.5
Heat Rate
Generator No. ID# Bho hp Hr/Yr Gals/Hr GalsNr mm Btu1Hr mm Btu/Yr
1 E101 587 440 110.0 15.0 1650.0 2.12 232.65
2 E102 760 570 111.0 25.0 2775.0 3.53 391.28
3 E103 603 452 208.0 20.0 4160.0 2.82 586.56
4 E104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 2670 2003 50.5 72.0 3636.0 10.15 512.68
Total 5154 3866 480 152 12221.0 21 1723
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.94 Pk-Gen Total
Pollutants (Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.036 0.061 0.091 0.000 0.079 0.267
PM-10 0.31 0.036 0.061 0.091 0.000 0.079 0.267
PM-2.5 0.31 0.036 0.061 0.091 0.000 0.079 0.267
Sox 0.29 0.034 0.057 0.085 0.000 0.074 0.250
Nox 4.41 0.513 0.863 1.293 0.000 1.130 3.800
VOC 0.36 1 0.042 1 0.070 0.106 0.000 0.092 1 0.310
CO 0.95 0.111 1 0.186 0.279 0.000 0.244 1 0.819
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Air Pollutants (Lb/mm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.178 0.300 0.450 0.000 0.393 1.322
Acrolein 9.25E-05 0.022 0.036 0.054 0.000 0.047 0.159
Arsenic 4.00E-06 0.001 0.002 0.002 0.000 0.002 0.007
Benzene 9.33E-04 0.217 0.365 0.547 0.000 0.478 1.608
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.00032
Beryllium 3.00E-06 0.001 0.001 0.002 0.000 0.002 0.00517
Cadmium 3.00E-06 0.001 0.001 0.002 0.000 0.002 0,00517
Formaldehyde 1.18E-03 0.275 0.462 0.692 0.000 0.605 2.033
Na thalene 8.48E-05 0.020 0.033 0.050 0.000 0.043 0.146
Toluene 4.09E-04 0.095 0.160 0.240 0.000 0.210 0.705
Wane 2.85E-04 0.066 0.112 0.167 0.000 0.146 0.491
GAEnvironmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
(Lb/gal. tons/ r tons/ r tons/ r tons/ r tons/ r
CO2 2.0600000 1.70 2.86 4.28 0.00 8.84
Methane 0.0003289 0.00 0.00 0.00 0.00 0.00141
(CH4)
Nitrous Oxide 0.0000470 0.00 0.00 0.00 0.00 0.000202
(N20)
Green House Gas Pulutants for Peak Generator
Emission Factor
GHG Pollutant (Lb/gal.) ibs/yr tons/yr
CO2 2.0600000 7490.16 3.75
Methane 0.0003289 1.20 0.0006
(CH4)
Nitrous Oxide 0.0000470 0.17 0.00009
(N20)
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only!
Year: 2011
Total Run Time: 23.5 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC
Month Fuel
Used Operated hour (lbs.)
January: 40.0 2.0 20.0 2.083
February: 40.0 1 2.0 20.0 2.083
March: 40.0 2.0 20.0 2.083
April: 30.0 1.5 20.0 1.562
May: 50.0 2.5 20.0 2.604
June: 40.0 2.0 20.0 2.083
July: 60.0 3.0 20.0 3.125
August: 30.0 1.5 20.0 1.562
September: 40.0 2.0 20.0 2.083
October: 40.0 2.0 20.0 2.083
November: 30.0 1.5 20.0 1.562
December. 30.0 1.5 20.0 1.562
Total: 1 470.0 23.5 20.0 24.5
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 0 23.5 20.0 470.0 2.82 66.27
Criteria Emisson Factor (Lb/mm FP
Pollutants BTU) (TonsNr
TSP 0.31 0.010
PM-10 0.31 0.010
PM-2.5 0.31 0.010
Sox 0.29 0.010
Nox 4.41 0.146
VOC 0.36 0.012
CO 0.95 0.031
Green House Gases
Hazardous/Toxi Emisson Factor (Lb/mm FP GHG Emisson Factor E101
c Air Pollutants BTU) (Lbs/Yr) Pollutant Lbl al. tons/ r
CO2 2.0600000 0.484
Acetaldehyde 7.67E-04 0.051 Methane 0.0003289 0.000000
Nitrous
Acrolein 9.25E-05 0.006 Oxide 0.0000470 0.000000
(N2O)
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.062
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002
Formaldehyde 1.18E-03 0.078
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.027
X lene 2.85E-04 0.019

Annual Air Emissions Inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2
Fuel Source : Wood Chips
Year: 2011
Total Run Time: 2436.0 Hrs/Yr
Wood Chips 8000000 BTU/ton
Boiler Operation (Hours) Wood Chips Burned (Tons) NOx Emissons (Lbs.1 CO Emissions (lbs.)
Month ES-BB1 ES-BB2 Total Boiler ES-BB1 ES-BB2 Total Wood ES-BB1 ES-BB2 Total ES-BB1 ES-BB2 Total
Hours Chips
January: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
February: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
March: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
June: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
July: 0.0 1 0.0 0.0 0.0 1 0.000 0.0 0.0 0.0
August: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
Se tember: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
October: 1 354.0 186.0 540.0 205.0 100.0 305.0 111.5 54.4 165.920 1.3 0.6 2.0
November: 648.0 480.0 1128.0 474.0 320.0 794.0 257.9 174.1 431.936 3.0 2.0 5.1
December: 384.0 384.0 768.0 1 414.0 414.0 828.0 1 225.2 225.2 4 2 2.6 2.6 5.3
Total: 1386.0 1 1050.0 2436.0 1 1093.0 834.0 1927.0 594.6 453.7 1048.3) 1 7.0 5.3 1-- T .3
Z � 0.01 i Q,✓ S
L� }

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2011
Info: Lbs/Gal= 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 1 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., CIA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
H:\Environmental\Air PermitkAir Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2011 Common Name : Lime
Monthlv In entory of Calcium h droxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 1 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2011
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13696 13696 1 13696
Februarv: 13696 13696 1 13696
March: 13696 13696 13696
April: 13696 13696 527.0 13169
May: 13169 13169 919.0 12250
June: 12250 12250 12250
July: 12250 12250 1275.0 10975
August: 10975 10975 10975
September: 10975 10975 1824.0 9151
October: 9151 9151 November: 9151 9151
5400.0 14551 393.0 1
December: 14158 1 14158 1599.0 12559
Lbs. of chloroform used during the year: 6537
Lbs. of chloro. used by Misc., CIA, and R&D:
Lbs. of chloro. used by EVG: 6537
Lbs. EVG Produced: 3498
Lbs. of chloroform sent to hazardous waste: 450
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 6087
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6 &OS-7
Year:
Info: Lbs/Gal= 7.60
Monthly Inventory of Ethyl acetate(pounda):
Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA Alcohol
Total Beginning Beginning New Recovered Recovered In Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Month Emitted(Lbs.)
Inventory Inventory Inventory
January: '- 3945 3945 0 701.00 3945 701.0 3244 January: 36.87
February: 3244 3244 0 75.00 3244 75.0 3169 February: 52.42
March: 3169 3169 0 2271.00 3169 2271.0 898 March: 2.13
April: BOB 898 0 3320.0 299.00 4218 299.0 3919 April: 24.91
May: 3919 3919 0 381.00 3919 381.0 3536 May: 19.38
June: 3538 3538 0 2579.00 3538 2579.0 959 June: 18.87
July: 959 959 0 3320.0 450.00 4279 Jul 4.83
0 3829 40Au August: 382 3829 1001.00 9 28 August 9.63
28 0September: 28 2828
728.00 2828 728.0 2100 September. 0.00
October. 2100 2100 0 964.00 2100 964.0 1136 October. 31.84
November: 1136 1136 0 3320.0 1051.00 4456 1051.0 3405 November: 17.50
December: 3405 3405 0 439.00 3405 439.0 29M December: 44.29
Lbs.of Ethyl acetate used during the year: 11201.67
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 3807.00
Lbs.of Ethyl acetate used in SFG:OS-6 7132.00 i 7
Lba.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):0S-7 �
Lbs.0f Ethyl acetate VOC from SDA Ethanol Loss 122 73
Crown Process
Gallons sent to Hazardous Waste: 586.67
Lbs.Sent to Hazardous Waste: 4400.00
Total lbs.of Ethyl acetate emitted during year: 6801.67

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethvlenediamine : OS-31
Year: 2011
Info: Lbs/Gal = 7.50 All ethylenediamine is contained and
shipped off-site with the product.
Monthly Inventory of Ethvlenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 1 2011'
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons):
Beginning Max Ending Gallons to
Month InventoryReceived Lbs Used Recovered inventoryWWT
VOC (Lbs.)
January: 4412 29046 4412 0 0
February: 4412 660 33391 5072 0 0
March: 5072 33391 5072 0 0
April: 5072 33391 5072 0 0
May: 5072 33391 5072 0 0
June: 5072 33391 5072 0 0
July: 5072 33391 5072 0 0
August: 5072 33391 5072 0 0
September: 5072 33391 5072 0 0
October: 5072 33391 5072 0 0
November: 5072 33391 1 1 0 0
December: 5072 33391 1 1 5072 0 0
Total Gallons of Ethanol Used: 0
Total Lbs. Ethanol Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. of Ethanol Emitted as VOC: 0

Annual Air Emissions Inventory
Facility IDS:0800044
Ethanol-SDA:OS-7&OS-10
OS-18.05-19.OS-27.OS42INCLUDED WITH 05-10.� J. t 5 xt e+ t r 4
Year: 2011
Info: LbslGsl• 6.87 %SDA Ethyl acetate- 4.54
Monthly Inventory of Ethanol IjBig2nsl:
Monthly Bealnnina Inventory Bulk Drums
6748".2
SDA Bulk SDA In Drums Max SDA on Total SDA BOA as Ethyl
SDA SDA SDA In Drums SDA In Drums SDA Ending SDA Used SDA Used SDA VOC Acetate
Month g Beginning Beginning SDA Used SDA Disposed Hand WWT
ry Inventory Inventory Received Transferred Received Used Recovered (�) Inventory (gallons) (Lbs.) (�) (Lbs.) Emlttetl
Janus": 0 36120.8 22381.3 5383.0 1067Z0 4766 438M 57974 5911 40007.9 39795.7 8122 36.87
Februe . 1 30826.8 27147.4 11946.0 5427.0 6932 3955 480351 61617 8404 57732.7 66578.1 1154.7 62.42
March: 6 37345.8 24170.8 5349.0 1061.0 74 794 4068 459366 52456 341 2343.4 2296.6 46.9 2.13
HI: 41633.8 20822.7 3994.0 429078 58462 3994 27438.8 26890.0 S46.8 24.91
May: 37639.8 20822.7 19490.0 17214 0 14108 535M 74846 3106 21339.6 20912.8 426.8 12.38
June: 2 39915.8 34930.5 3120.0 213 308 514193 718M 3025 20778.3 203677 415.6 18.87
Jul : 7 36795.8 36026.0 1 774.0 493416 71048 774 5317.4 5211.0 106.3 4.93
Au cast: 71047.7 36021.8 35026.0 15M.0 488098 69504 1544 10607.3 10395.1 212.1 9.83
Ss mbeC 89503.7 34477.8 35028.0 477490 89501 0 0.0 0.0 0.0 0.00
October. 69ll 344T7.8 135026.0 r W9B.0 5105.0 522132 70897 5105 35071.4 34369.9 701.4 31.84
November. 70898.7 35870.8 35028.0 8572.0 2805.0 532210 74684 2805 19270.4 18884.9 385.4 17.50
December. 1 74683.7 1 39837.8 135028.0 7100.0 512940 1 67664 1 7100 1 48777.0 47801.5 975.5 44.29
Total Gallons of SDA Used: 42108.3
Total Lbs.SDA Used: 289284.0
Gallons sent to Hacardous Waste:
Lbs.SDA Ethanol set to Hatardous Waste: 0.00
Total Gallons sent W W WT: 41266.13
Total Lbs.sent W W WT: 283498.34
Total BOA Ethanol VOC's 5795.68
Lbs.Botanical EsbacBon Ethanol Emitted:05-10 2ZO124
Lbs.PNE Ethanol Emitted:03-7 083.M
Misc.Lbs.SDA Ethanol Emllted:
Total Lbs.of SDA Ethanol Emitted: 5785.68

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS4, OS-5, OS-6, OS-10. OS-28, OS-29
OS-13 OS-14 OS-15 OS-16 OS-17 OS-20 OS-21,OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH OS-10•OS-30 INCLUDED WITH OS-28
Year: 2011
Info: LbslGal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month eginning Received Max Used Ending Inventory
InveJanuary: 10328. 56804 1823 - 8505
February: 85D5 46778 1102 7403
March: 7403 4472 85313 2027 9848
April: 9848 54164 1039 88D9
May: 8809 48450 226 8583
June: 8583 47207 1146 7437
July: 7437 4382 85005 1479 10340
Au ust 10340 56870 1 2044 8296
September. 8296 4023 67755 1 1539 10780
October: 10780 59290 1243 9537
November. 9537 52454 2043 7494
December: 7494 3876 62535 1279 1OD91
Monthly Inventory of HP Hexane-9501,(gallons):
Month Beginning Received Max Used Ending Inventory
InvJanuary: - 1089 59M 358 731
February: 731 5909 36520 941 5699
March: 5699 31345 236 5463
April: 5463 30047 542 4921
May: 4921 27066 1046 3875
June: 3875 21313 1236 2639
Jul ; 2639 14515 1424 1215
Au ust 1215 - 8883 1286 -71
Se tember. -71 5906 32093 15121 4323
October. 4323 1 23777 1392 1 2931
November. 2931 18121 1917 1014
December. 1014 1 1 5577 1 1401 387
Monthly Inventory of IsoHexane-2.5%laallonsl:
Month Beginning Received Mbs ax Used Ending Inventory
January: 41688 229284 41688
February; 41688 229284 41688
March: 41688 229284 992 40696
April: 40696 223828 4D696
May: 40696 8729 271838 2030 47395
June: 47395 25375. 400235 20103 52667
July: 52667 19460 396699 18234 53893
Au ust: 53893 12652 365998 16939 1 49606
Se tember. 49606 19710 1 381238 25051 44265
October: 44265 23479 372592 38082 29662
NovamMr. 29662 163141 29662
December: 29662 163141 29682

Page 2 of 4
Monthly Emissions of IsoHexane from Biomass Bollers(Lbs.l:
Percent n-Hexane: 0.24
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
JUI : 0 0
Au ust: 0 0
September: 0 0
October. 0 0
November. 0 0
December. 0 0
Total Hexane Values
Gallons of LP Hexane Used: 16990.00 Gallons of N-Hexane Used: 18269.68
Gallons of HP Hexane Used: 13291.00 Lbs.of N-Hexane Used: 100463.25
Gallons of IsoHexane Used: 121431.00 Gallons of Hexane Isomers Used: 133442.32
Total Gallons of Hexanes Used: 151712.00 Lbs.of Hexane Isomers Used: 733932.75
Total Lbs.of Hexanes Used: 834416
Sclareolide(SIDE)Operation:OS-5
Percent N-Hexane In Solvent: 39-4
Gallons of Hexane Used In SDE: 16990.00 Lbs,of Fugitive Hexane from SDE: 92021.79
Lbs.of Hexane Used In SDE: 93445 Lbs.ofFugitive - exane from 36256 58
SDE:
Lbs.of SDE Product: 284642.26 Lbs.of Fugitive Hex Isomers hone 55765.20
SDE:
Lb.Hexane per Lb.of SDE
0.005
Product
Lbs.Hexane in SDE Product 1423.21
Lbs.N-Hexane In SIDE Product: 560.75
Accountable Lbs.of Hexane Lost: 1423.21 Accountable and Fugitive Lba. 93445 00
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 560.75 Accountable and Fugitive Lbs. 36817 33
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 862 47 Accountable and Fugitive Lbs.Hex 56627 67
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 9300
Waste:
Lbs.of N-Hex Sent as Hazadarous 2976
Waste:
Lbs.of Hex Isomers in Hazardous 6324
Waste:

Page 3 of 4
Sclarsol Recrvstallization fSFGI Operation:OS-6
Percent N-Hexane in Solvent: 91.4
Gallons of Hexane Used in SFG 13291.00 Lbs.of Fugitive Hexane from SFG 71426.37
Lbs.of Hexane Used in SFG: 73100.5 Lbs.of Fugitive N-Hexane from 65263.70
SFG:
Lbs.of SFG Product: 334826 Lbs.of Fugitive Hex Isomers from 6142.67
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 1674.13
Lbs.N-Hexane In SFG Product: 1530.15
Accountable Lbs.of Hexane Lost 1874.13 Accountable and Fugitive Lbs. 73100 50
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 1530.15 Accountable and Fugitive Lbs. 66813.86
N-Hex Emitted:
Accountable Lbs.of Hex Isomers t43 98 Accountable and Fugitive Lbs,Hex 8286.64
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 22100
Waste:
Lbs.of N-Hex Sent as Hazadarous 20995
Waste:
Lbs.of Hex Isomers in Hazardous 1105
Waste:
Rotocel Concrete 8 Recovery Operations:OSd
Gallons of Hexane Used: 120439.00 Gallons sent to W WT: 2495632
Lbs.of Hexane Used: 662414.5 Lbs.Waste Water per Gal.Waste 8.34
Water:
Percentage of N-Hexane in 0.161 Wt-/,of Hexane in Waste Water: 0.014
Solvent:
Lbs.of Hexane Sent as Hazardous 6561 Lbs.Hexane Lost In Waste Water: 2913.90
Waste:
s.o - ex Sent as aza arous 10 56 - exane Lost n Waste 4.69
Waste: Water.
Lbs.of Hex Isomers in Hazardous 6550.44 Accountable Lbs.of Hexane Lost: 88736.01
Waste:
Lbs.Hex per day exiting Mineral -41.60 Accountable Lbs.of N-Hex Lost 142.87
Oil Scrubber from MO tests
Days of MO Unit operation: 135 Accountable Lbs.of Hex Isomer 88593.15
Lost
Lbs.of Hex exiting MO Unit: 5616
Lbs.of N-Hex exiting MO Unit 9.04
Lbs.of Hex Isomers exiting MO 5606 96 Total Lbs.Hexane Lost as Fugitive: 567117.49
Unit:
Lbs.Sage Processed: 5012 8820 Total Lbs.N-Hex Lost as Fugitive: 913.06
Lbs.Hexane per Lbs.of Spent 0.001600 Total Lbs.Hex Isomers Lost as 566204.43
Sage(from Desolvitizer tests): Fugitive:
Lbs.Hexane in Spent Sage: 80206.11
Lbs.N-Hexane in Spent Sage: 129.13
Lbs.Hexane per Day from A-1 0.000815
Vent Gond.
Days A-1 Operated: 135 Accounta 9 an ug tive ba. 655853.5
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.110 Accountable an ugitive s. 1055.92
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent 0.000177 ccounta a an ugitive Los.Hex 654797.58
Isomers Emitted:

Page 4 of
Biomass Extraction Operation:OS-28
Gallons o1 Hexane Used: s.of Fugitive Hexane from 0
Bio Extraction:
Lbs.of Hexane Used: 0 L s.o ug ve -Hexane from Bio 0.00
Extraction:
Lbs.of Biomass Product Lbs.o ugitive Hex Isomers from 0.00
Bio Extraction:
%n-Hexane 0.17
Botanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.o ug va -Hexane from Rot 0
Extraction:
Lbs.of Botanical Product: L­bs­.orFugltive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction(M-131 Ooerotion:OS-29
Gallons of Hexane Used: 992.00 s.of Fugitive Hexane from 5456
PNE:
Lbs.of Hexane Used: 5456 •of ug UPNE:Hexane from 6.5472
.o Fugitive Hex isomers rom
Lbs.of PNE Product: -733.5 PNE: 5449A528
%n-Hexane 0.12
Lbs.of exane Sent as Hazardous 20600
Waste:
Lbs.of N- ex Sent as Haza arous 24.72
Waste:
15i.—TRex isomers in Hazardouc 20575 28
Waste:
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: ID8602.56 Total Lbs.n-Hexane Released: 104693.66
Fugitive Lbs.Hex Isomers 633561.75 Total Lba.Hex Isomers Released: 723161.34
Emitted:
Accountable Lbs.n-Hexane Lost: 2233.77 Total Lbs.N-Hexane Sent OH Site: 3011.28
Accountable Lbs.Hex Isomers 89599 59 Total Lbs.Hex Isomers Sent OH 33448 72
Lost: Site:
Total Lbs.Hexane Sent Off Site: 36461.00
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane .
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 50924 4458 24520.4
February: 54790 8825 48538.7
March: 56007 9359 51472-4
April: 54426 8511 46811.8
May: 59853 7613 41869.8
June: 62743 6204 34119.6
July: 854" 5810 31957.1
Auclust 57831 1 3827 21050.8
September. 59368 8663 47646.9
October: 1 42130 6578 36178.1
November. 1 38170 4103 22566.1
December. 1 39366 1 3 19816.6
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
65448 9359 51472

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2011
Info: Lbs/Gal = 5.70
Mont Iv Inventorvof Heptane allons :
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 1 496 2827 496
December: 1 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in 0.85
Solvent:
Gallons of Heptane Used in 0.00 Lbs. of Fugitive Heptane 0.00
SFG: from SFG:
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane 0.00
SFG: from SFG:
Lbs. of SFG Product: Lbs. of Fugitive Hept. 0.00
Isomers from SFG:
NJ
Lb. Heptane per Lb. of SFG 0.0 55
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG 0.00
Product:
Accountable Lbs. of Hexane 0.00 Accountable and Fugitive 0.00
Lost: Lbs. Heptane Emitted:
Accountable Lbs. of N-Hept. 0.00 Accountable and Fugitive 0.00
Lost: Lbs. N-He t. Emitted:
Accountable Lbs. of Hept. 0.00 Accountable and Fugitive 0.00
Isomers Lost: Lbs. He t. Isomers Emitted:
Lbs. of Heptane Sent as
Hazardous Waste:

Annual Air Emissions Inventory
Facility 0"": 0800044
Hydrochloric Acid : OS-7
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (Ibs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 732 0 0
February: 0 0 0
March: 0 0 0
April; 0 0 0
May: v i U
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 1 0 1 1 0
December: 0 1 0 1 1 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutvl acetate: OS-7, OS-10
Year: 1 2011
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutvl acetate (gallons):
Beginning Max Used Ending
Month Received Recovered Recovered
Inventory (Lbs) New Used Used Inventory
January: 1514 10931 1514
February: 1514 10931 1514
March: 1514 10931 1514
April: 1514 10931 1514
May: 1514 10931 1514
June: 1514 10931 1514
July: 1514 10931 1514
August: 1514 10931 1514
September: 1514 10931 1514
October: 1514 10931 1514
November: 1514 10931 1514
December: 1514 10931 1514
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @(OS-10):
Lbs. Of IBAC used during the year OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyl acetate: OS-7, OS-10
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory (Lbs) Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 1 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0

Annual Air Emissions Inventory Summary
2011 Totals Facility ID#:0800044
Pollutant Boiler et J4M4
Boiler F3 aeon Gen 82 Den N e•II N Pk-0 Fire Pum Blomaaa Rofml Plem
P rF Recry•Wlix•Uon SGareoiWe Bbmue 8alrllcY NYtfbnt EVG V/W7P OOI•r TOGIa UnIN
BWlara ISFGI (BDEi EaVr4bn Ealr•d0on PrOda•••e
CO 23W.52 2261.99 170 2W 428 O.W 3,75 0.48 T.Wr
Me11wIw O.OW18 000600 0.00027 0.00048 O.Mall &MOO O.00060 0.00 0.026 T.n '
N U.Oxi" 0012W 001212 000WI 000001 0.=10 0.MOO OODOD9 000 0. TOnWr
TSP 02W0]71 0201 T2 00360M7 0.OM647 OW091W 0 007918478 001027185 1.066 T.na r
PM-10 0.103018M 0100B686 0.03606W5 O.OBOWIB25 O.OBOHIW 0 001916/]8 0.01027185 0672 TonslVr
PM-2.5 002575b3a 002524215 003606075 O.DBOW]625 D09081M 00)9161)e 00102)185 .3)0 TonWr
d. 4 W1 03) 5 0.05873481 WM512 OON3 00980B15 lt. TaOWf
Nok 24n4452 242324W O.St2BB325 0.M2)813)5 1.2B33W8 0 1.13W O.t1612535 0.52 - 13.9W TonWr
VCC 0.020W371 O.0 IO 0.=193n O.W1an 007W265 0.1055Ma 0 1M OOIIWM 32T92075 6541 40.11 46.T225 .41 4.W, 0.57 W 489491 T.Wr
00 0.51609275 0.952628 05W843 01105W7 0.185855825 1 027WI6 0 1 0.2435211 1003147825 am 2 M TdniNr
A %IdM de 0.1T 4255 0.3WID7925 0.M989152 0.393222492 0OSW2909 1 1.372 IDWr
A Neln 0,0215M125 GONI929M 0.05125W 0 OW742253 O.OD812969 0.1ee Lba/Yr
Awenic 0.12201171 0.22MMW7 0.11BS8 1 0.DD09306 0.W15651 0.002341i24 0 0.0020M7W 000026M8 0.74 Lba/Tr
Benxen• 0.M153751 0M1659101 0NU75142 0/1706245 O.WM69575 O.W728W8 0 0.4783287W O.W182261 I Ino LDWI
Benz a rune 4.3 -0 1.35591E45 0.00011W73 0 6.63831E-05 1.2459E-05 OOOW LDWr
Ilium 0.07MW78 0.1W320280 O.W1182M3 00 OWN 0WI17 5 0.WI759M 0 01101538028 OOW19W1 028 Lb '
Bulanol 0.W 000a LbWr
cadmium 0,31M7!M 0.5BW]8 000/2 0,31=206 0. 097W eWI1 5 0. 175908 0 0.001538028 0.00019M1 1.M Lb ,
Celaum h rodde O.W 0.000 LbL r
Chlorolorm BOB7 0. 0087.00D Lbs r
Chromium 1AB4971d0I 3.116=171 1.651N24M 6,453 Lbs r
Chromium IV 0.0M97M76 00110504e2 0 MSWJ70 00D Lbs r
ENerw1-1001L 0,00 0000 Lbs r
ElhanN-SDA 1 270.24 3a82.N 1 O.W 5786 M Ub r
MA 9. 1 7132 12273 3W7 1IMI 670 Lb r
Mil benb 0013W3H8 1 00241967 0.012823012 0.= I
EMYIm iamine 0 0 ODO LDWI
Fl.0. ].68518]63 1421317M 7,532257N 79431 LEWr
Falmeideh 67979800n 126723769 6.0627169n 0.274527 0.41617N5 089214W 0 0614w" 00781W 211145 LSWr
ne lsomwf 664797570M3 SM7.] 0 0.00 We,4W 723161 311 Lb ,
NJle.ena IOM.M431 =13.957 3681i.M 0 &W 0W72 04683.659 LbIINf
H bne I... 0,00 LbW1
N-He tan• O.OD Lbwr
Isobm lecNela 0 0.00 0.DDO LbWr
Isom iecetale 0.00 0W 0.000 LbWr
lead Com ands 0.256555457 OA741WI47 0253410992 O.m LbslTf
Me mesa 0.4W71n35 0.)5216349 0.398624033 1 1 1 0 1558 Lb '
Mara 008715MO3 0 1116431 O.Oa511W3a 0334 LDWr
MMhanol 13W14.93 SW.n 114B.44 4%7.13 137 . 1 LOWr
Na below 06M.232611 0.40117M 0201326931 001972 M O.W31801 O.W9T402a8 0 OOa3d7aB25 0.005619] 1.1n Lbattr
NickN a5229T218 0.9671M915 0.51251MI1 Lbvyr
Su117 Diaude 0.00 0.000 L r
Toluene 1.2]82W1W 22 OII8682 1252 ISM O.OBS 5385 0.18003f475 0.239803W 0 0.20BBBa18/ 0. 710N3 0.00 5. 7 LBW'
% ens m&)6 5 0,1115133] 0.1871898 0 0.1d6112M OO1WM 5 0.510 Lb•11r
o-% • 1 0.=4374/ 1 0.041498388 1 0021MMI I I 1 0.066 lbe//r
unn n n�
N
o O
N
Q)
r

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: OS-4, OS-7, OS-9
OS-13, OS-14, OS-15, OS-16, OS-17, OS-27, OS-32 INCLUDED WITH OS-4
Year: 2011
Info: Lbs/Gal = 6.62 Specifice Gravity= 0.793
Monthly Inventory of Methanol (gallons):
Month Beginning Received j Max Used Recovered Ending
Inventory Lbs Invento
January: 21109 1 139742 1 21109
February: 21109 1 139742 21109
March: 21109 139742 21109
April: 21109 4400,0 168870 3076.6 22432
May: 22432 13427.0 237389 442.0 35417
June: 35417 6774.0 279307 6146.0 36045
July: 36045 440.0 241533 9251.0 27234
August: 27234 180292 10394.0 16840
September: 16840 8743.0 169362 9977.0 15606
October: 15606 103314 8369.0 7237
November: 7237 6160.0 88691 1935.0 11462
December: 11462 75881 2041.0 9421
Maximum Gallons On-Hand: 42191.4
Maximum Lbs. On-Hand: 279307.068
Gallons Used per Year: 51632
Lbs. Used per Year: 341801.192
Sclareol Recovery Operation: OS-4
Total Gal. of Methanol Used: 39138
Total Lbs. McOH Used: 259093.56 Avg. % MeoH thru Pods: 85
Avg. % McOH in WW: 9.3 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 1.06 Number of Stream Days 135
Number of Stream Days: 135 Total Gal. Thru Pods: 1749600
Total Gal.of WW to WWTP: 4431060 Total Gal. McOH Thru Pods: 1487160
Total Lbs. of WW to WWTP: 36955040.4 Total Lbs. McOH Thru Pods: 9844999.20
Total Lbs. of McOH to WWTP: 128278.63 Total Lbs. Fugitive Emissions 130814.93
from Recovery:
Avg. Removal Efficiency of Total Accountable and Fugitve
WWTP: 97.68 Emissions from Recovery: 133791.00
Accountable Emissions of
McOH from WWTP during 2976.06
Recovery:

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 8674 Accountable Emissions of
Gallons of McOH to WWT: 8500.52 McOH from WWTP during JU227
5.47
Total Lbs. of McOH to WWT: 56273.44 EVG:
Total Lbs. Fugitive Emissions 1148.44 Total Accountable and Fugitve3 9
from EVG: ✓ Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 3819.6 Accountable Emissions of
Gallons of McOH to WWT: 3743.208 Mc OH from WWTP during 495.60 C v�f'N
Total Lbs. of McOH to WWT: 24780.03696 PNE:
Total Accountable and Fugitve Qc ��
Total Lbs. Emissions PNE: 505.71504 1001.32 \� e("
E missions from PNE: AV
C /Totals for All Methanol Operations
Total Lbs. McOH Thru System: 9844999.20 Lbs. of Emissions from Misc., Lab: 505.71504
Total Lbs. McOH to WWTP: 209332.11 Lbs. Fugivtive Emissions from EVG: 1148.44
Removal Efficiency of WWTP: 2976.06 Lbs. Fugivtive Emissions from Recovery: 130814.93
Lbs.Accountable Emissions 4597.13 Total Lbs. Fugitive Emissions: 132469.09
from WWTP:
Total Lbs. McOH Treated at 209332.11 Total Lbs. McOH Released: 137066.22
WWTP:
Total Lbs. McOH Recycled On-Site: 9635667.09

Annual Air Emissions Inventory
'1'4 ln1 nOnn/1A
Fgcl'PLY P,': VVVVVY4
Maqanese
Year: 2011
Info: Potassium permanganate contains 33-35% Manganese.
Month1v In entory of Potassium Permanganate (pounds
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
lfia ' 10537 i6537 10537
June: 16537 16537 16537
July: 16537 16537 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand. 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs.of Sulfur dioxide used by Misc., CIA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2011-
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 1 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc.:
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2011
The Plant Material Grinder (OS-3) is operated in building ID # 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinders operation. Essentially there are no emissions associated with the plant
material grinder.

Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2011
These forms must be completed and returned even if the facW did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal defmition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
ERTIFICATION STATEMENT:
Tm2oMpt7 Legally Respon5ible Official,read aud sign afteX all submissions amLadL
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's SiwiWire Belo use blue' k : Date Signed:
Printed Name: David
Signature
This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: [e-mail]
0 U LS
Information on this Form cannot be held confidential �I MAR 9 2012
DAQ WARO
1

Total Y 2011 Emission Summary Recorded in ED Facility 1D#: 0800044
Facility ota C y ty
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Green House Gases Pollutants(GHG) Actual Emissions
Tons/Vr °/o Change
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Methane(CI-14) 74-82-8 0,025700 0.019800 29.8%
Carbon Dioxide(CO2) 124389 8,970.06 7,200.16 24.6%
Nitrous Oxide(N20) 10024972 0.047500 0.038100 24.7%
CO2 equivalent(sum of individual GHG pollutant emission times their 1995 8,151.49 metric tons
IPCC Global Warming Potential(GWP),converted to metric tons)
Criteria Pollutants Actual Emissions % Change
(Tons/Year)
Pollutant CY 2011 CY 2010
from ED from Fees
CO 2.79 1.90 46.80/4
NOx 13.79 9.07 52.0%r
PM(TSP) TSP 1.06 0.730000 45.20i,,
PM 10 I'm I O 0.660000 0.420000 �Z7.1%,
PM2.5 PM2 S 0.370000 0.180000 105.60/,
S02 S02 17.06 13.60 25.4%,
VOC Voc 491.30 231.31 112.4%
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPS) (Pounds/Year)
Pollutant CY 2011 CY 2010
from ED from Fees
Polycyclic Organic Matter(Specific Compounds from OAQPSJor 1.17 0.876450 1,.E i"',
T
Benzo(a)pyrene(Component of 833291POMTV& 50-32-8 0.000330 0,000130 .
56553/7PAH)
Naphthalene(Component of 83329/POMTV) 91-20-3 1.17 0.876320
Polycyclic Organic Matter(7 PAN Compounds for NIF) 0.000330 0.000130 V,t
09/05/2012 Page I of 4

Facility Total CY 2011 Emission Summar,N Recorded in FD Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 018191'38
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Polycyclie Organic Matter(7 PAH Compounds for NIF) 0.000330 0.000130
Benzo(a)pyrene(Component of 83329/POMTV& 50-32-8 0.000330 0.000130
56553/7PAH)
Nickel& Compounds,sum total mass includes elemental 2.00 1.61
Nickel Unlisted Compounds (Component ofNIC- NIC-other 2.00 1 61 1
Specify)
Mercury& Compounds-all total mass includes Hg Vapor 0.333830 0.268160
Mercury Unlisted Compounds-Specify Compound HGC-Other 0.333830 0.268160 24.50%
(Component of HGC)
Manganese& compounds 1.56 1.25 '4
Manganese Unlisted Compounds-Specify NNC-Other 1.56 j_�
Compound(Component of MNC)
Lead& compounds 0.990370 0.795540 24.5,
Lead Unlisted Compounds-Specify Compound PBC-Other 0.990370 0.795540 24.-5
(Component of PBC)
Chromium(VI)Non-Specific Compounds, as Chrom(VI) 0.023150 0.018590 24.53„
(Component CRC
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-0ther 0.023150 0.018590 24 .;'7..
Specify Compound(Component of NSCR6& CRC)
Chromium-AlMial(includes Chromium(VI)categories,metal 0.48 _5.20
and others
Chromium(VI)Non-Specific Unlisted Compounds- NSCR6-other 0.023150 0.018590 24.5%,
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds-Specify CRC-Other I 1 5.18 24.5%
Compound(Component of CRC)
Cadmium& compounds(total mass includes elemental metal) l 23 0.982620
09/05/2012 Page 2 of

Facility Total CY 2011 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants(HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2011 CY 2010
from ED from Fees
Cadmium&compounds(total mass includes elemental metal) 1.23 0.982620 5.2%,
Cadmium Unlisted Compounds-Specify Compound
CDC-Other 1.23 0.982620 25.111�11
(Component of CDC)
Beryllium& compounds(Total mass) 0.283360 0.223470 26.8%
Beryllium Unlisted Compounds-Specify Compound BEC-Other 0.283360 0.223470 26A'i;,
(Component of BEC)
Arsenic& Compounds(total mass of elemental AS,arsine and all 0.474370 0.375420 16 l
inorganic compounds)
Arsenic Unlisted Compounds-Specify Compound ASC-Other 0.474370 0.375420 26.40/,,
(Component of ASQ
Acetaldehyde 75-07-0 1.32 0.507600 160.0%
Acrolein 107-02-8 0.159980 0.061530 160.00/,
Benzene 71-43-2 1.78 0.754390 135V4,
Chloroform 67-66-3 6,087.00 6,498.00 -6.30G)
Ethyl acetate 141-78-6 11,201.73 13,423.58 -16.6';'„
Ethyl benzene 10041-4 0.050190 0.040310 24.5OX,
Fluorides(sum of all fluoride compounds as mass of F 16984-48-8 29.43 Not NIA
ion) Reported
Formaldehyde 50-00-0 28.07 21.70 29.40/4
Hexane isomers,except n-hexane HEXANEISO 723,161.35 317,924.35 127.50/,
Hexane,n- 110-54-3 104,693.65 105,012.54 -0.4°/,
Methanol(methyl alcohol) 67-56-1 137,066.19 23,366.46 486.60/,
Toluene 108-88-3 5.60 4,20 33.2'i„
Xylene(mixed isomers) 1330-20-7 0.490180 0,188520 160.0%
Xylene,o- 95-47-6 0.086020 0.069100 24.50/,
09/05/2012 Page 3 of 4

Largest Individual HAP Methanol(methyl alcohol) 137,060.19
Ibs
Total HAP Emissions 247,898.91
--j- I Ibs
DAO's Comments Kei,ardin!, Invcnlors
09/05/2012 Page 4 of 4

March 16,2012
Mr. Robert Fisher
Environmental Regional Supervisor II- Air Quality
NC Division of Air Quality
Washington Regional Office
943 Washington Square Mall
Washington,NC 27889
Subject: Annual Air Emissions Inventory ZO t�
Air Quality Permit No. 01819T38 ' (�
Facility ID: 07/08/00044
Avoca, Incorporated
Merry Hill,North Carolina �_ y
Bertie County
Fee Class: Title V
Dear Mr. Fisher:
In accordance to Avoca, Incorporated's Title V Air Quality Permit, I am forwarding the Inventory
Certification Form and supporting documentation for the Annual Air Emissions Inventory. The inventory
was submitted on March 15,2012 via the AERO program. The attached certification form and copies of
spreadsheets and calculations used in creating this inventory are being submitted to fulfill the
requirements of the annual report.
If there are any questions or comments concerning the included documentation or inventory report please
contact me at(252)325-0335.
Sincerely,
CalW
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
it I
1`1
252-482-2133 • Fax: [phone]
Mauins: P.O. Box 129, Merry Hill, NC 27957 • shimins: 841 Avoca Farm Road, Merry Hill, NC 27957

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2011
Total Run Time: 16571.0 HrsNr
Efficiency: 85 %
Sulfur Content 0.0015 %
Number 2 Fuel: 141000 BtufGal
Fuel Useas(oallons) Boller Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total
Month Boller#1 Boller02 Boller03 Boller Boller#1 Boiler#2 Boller#3 Boller (�) 0.bs1
Fuel Used Hours
January: 21038,9 21310.6 23130.0 -- 65479.5 588.5 555.2 514.0 1657.7 0.039 13.096
February: 22980.1 23091.5 433.9 46505.5 642.8 634.3 67.5 1344.6 0.028 9.301
March: 8079.3 8773.2 29529.0 46381.5 364.1 284.7 656.2 1305.0 0.027 9.276
April: 12168,6 5709.7 13628.3 31506.6 378.2 422.3 336.5 1137.0 0.019 6.301
May: 17528.2 6470.3 17806.5 41805.0 490.3 478.2 395.7 1364.2 0.025 8.361
June: 20820.8 51671.7 24399.0 96891.5 582.4 566.5 542.2 1691.1 0.057 19.378
Jul - 21861.1 54153.9 26689.5 - 1027D4.5 611.5 603.0 593.1 1807.6 0.061 20.541
Au ust: - 23856.0 63811.5 25929.0 113596,5 667.3 634.9 576.2 1878.4 0.067 22.719
Se tember. 91181.9 70978.1 20758.5- 112918.5 592.5 609.4 461.3 1663.2 0.067 22.584
October. 2D860.1 57957.9 16546.5 95364.5 583.5 600.9 367.7 1552.1 0.056 19.073
November: 5798.7 3777.9 913.5 10490.1 - 162.2 160.9 21.0 344,1 0.006 2,098
December: - 9863.4 - 13344.1 2173.5 25381.0 275.9 501:8 48.3- 826.0 0.015 5.076
Total: 206037.1 381050.4 201937.2 789024.7 5939.2 8052.1 4579.7 18571.0 0.467 167.805
Boller# ID# I GPH HI-Fire I GalsIHr HrfYr Galafy
1 H•101 143 34.7 5939.2 206037.1
2 H-102 143 63.0 6052.1 381050.4
3 H-103 180 44.1 4579.7 201937.2
Total 466 141.74672 18571 789024.7
Criteria Pollutants
Criteria Emisson Factor Boller#1 Boller#2 Boller#3 Total
Pollutants LbsJ1000 al. ons/Yr onslYr TonsNr onslYr
TSP 2.00 0.206 0.381 0.202 0.789
PM-10 1.00 0.103 0.191 0.101 0.395
PM-2.5 0.25 0.026 0.048 0.025 0.099
Sox 42.60 4.389 8.116 4.301 16.806
Nox 24.00 2.472 4.573 2.423 9.468
VOC 0.20 0.021 0.038 0.020 0.079
CO 5.00 0.516 0.953 0.505 1.973
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boller#1 Boller#2 Boller#3 Total
Pollutants (lbsl1000 gal) (LbsNr) (LbsNO (Lbs/Yr) (LbslYr)
Arsenic 5.92E-04 0.122 0.226 0.120 0.467 � 1
Benzene 2.14E-04 0.044 0.082 0.043 0.169
Beryllium 3.53E-04 0.073 0.134 0.071 0.278 L '�
Cadmium 1.55E-03 0.319 0.591 0.313 1.223
Chromium 8,18E-03 1.685 3.116 1.651 6.453 *1� e�( I�
Chromium VI 2.90E-05 0.0 0.011 0.0 0.0 V n
Ethyl benzene 6.35E-05 0.013 13 0.024 0.013 13 0.050 50 � I[look,
►/V�,r/��'Irpr/� "r
Flouride 3.73E-02 7.685 14.213 7.532 2OA31
Formaldehyde 3.30E-02 6.798 12,572 6.663 26.033 R
Lead 1.25E-03 0.259 0.478 0.253 0.990
Manganese 1.97E-03 0.407 0.752 0.399 1.558
Mercury 4.23E-04 0.087 0.161 0.085 0.334
Napthalene 1.29E-03 0.267 0.493 0.261 1.021
Nickel 2.54E-03 0.523 0.967 0.513 2.003
Toluene 6.20E-03 1.278 2.364 1.253 4.895
o-X lene 1.09E-04 1 0.022 0,041 0.022 0.086
H:1EnvironmemallAir PennhWir ReportsWnnual Air Emissions Inventory@011 ReporH2O11 AAE Calc

Page 2 or 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Green House Gas Pulutants
Emission Boller#1 Boller#2 Boiler#3 Boller#1 Boller#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (lbs/hr) (lbslhr) (Ibs/hr) (tonslyr) (tonslyr) (tonslyr) (tonslyr)
CO2 22700.00 787.49 1429.23 1000.93 2338.52 4324.92 2291.99 8955.43
Methane 0.06 0.0021 0.0038 0.0026 0.0062 0.0114 0.0061 0.0237
(CH4)
Nitrous Oxide 0.12 0.0042 0.0076 0.0053 0.0124 0.0229 1 0.0121 0.0473
(Nz0)
H:1EnvironmentahAir PermiVAir ReportslAnnual Air Emissions Inventory12011 Report12011 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory �^
Facility ID#:0800044 P`G
Generators : OS-2 l'
of
Year: 2011 _1r.
Total Run Time: 479.5 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.0015 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Pk-Gen Total (Lbs.)
January: 30.0 50.0 60.0 144.0 284.0 14.791
February: 30.0 50.0 40.0 0.0 120.0 6.250
March: 30.0 50.0 70.0 72.0 222.0 11.562
April: 37.5 87.5 120.0 468.0 713.0 37.133
May: 37.5 62.5 100.0 360.0 560.0 29.165
June: 142.5 237.5 1 240.0 936.0 1556.0 81.036
July: 37.5 62.5 50.0 828.0 978.0 50.934
August: 1192.5 1987.5 3180.0 540.0 6900.0 359.352
September: 30.0 50.0 80.0 0.0 160.0 8.333
October: 30.0 50.0 80.0 216.0 376.0 19.582
November: 30.0 50.0 80.0 36.0 196.0 10.208
December: 22.5 37.5 60.0 36.0 156.0 8.124
Total: 1650.0 2775.0 4160.0 0.0 3636.0 12221.0 636.5
Heat Rate
Generator No. ID# Bho hp Hr/Yr Gals/Hr GalsNr mm Btu1Hr mm Btu/Yr
1 E101 587 440 110.0 15.0 1650.0 2.12 232.65
2 E102 760 570 111.0 25.0 2775.0 3.53 391.28
3 E103 603 452 208.0 20.0 4160.0 2.82 586.56
4 E104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 2670 2003 50.5 72.0 3636.0 10.15 512.68
Total 5154 3866 480 152 12221.0 21 1723
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.94 Pk-Gen Total
Pollutants (Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.036 0.061 0.091 0.000 0.079 0.267
PM-10 0.31 0.036 0.061 0.091 0.000 0.079 0.267
PM-2.5 0.31 0.036 0.061 0.091 0.000 0.079 0.267
Sox 0.29 0.034 0.057 0.085 0.000 0.074 0.250
Nox 4.41 0.513 0.863 1.293 0.000 1.130 3.800
VOC 0.36 1 0.042 1 0.070 0.106 0.000 0.092 1 0.310
CO 0.95 0.111 1 0.186 0.279 0.000 0.244 1 0.819
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Air Pollutants (Lb/mm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.178 0.300 0.450 0.000 0.393 1.322
Acrolein 9.25E-05 0.022 0.036 0.054 0.000 0.047 0.159
Arsenic 4.00E-06 0.001 0.002 0.002 0.000 0.002 0.007
Benzene 9.33E-04 0.217 0.365 0.547 0.000 0.478 1.608
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.00032
Beryllium 3.00E-06 0.001 0.001 0.002 0.000 0.002 0.00517
Cadmium 3.00E-06 0.001 0.001 0.002 0.000 0.002 0,00517
Formaldehyde 1.18E-03 0.275 0.462 0.692 0.000 0.605 2.033
Na thalene 8.48E-05 0.020 0.033 0.050 0.000 0.043 0.146
Toluene 4.09E-04 0.095 0.160 0.240 0.000 0.210 0.705
Wane 2.85E-04 0.066 0.112 0.167 0.000 0.146 0.491
GAEnvironmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
(Lb/gal. tons/ r tons/ r tons/ r tons/ r tons/ r
CO2 2.0600000 1.70 2.86 4.28 0.00 8.84
Methane 0.0003289 0.00 0.00 0.00 0.00 0.00141
(CH4)
Nitrous Oxide 0.0000470 0.00 0.00 0.00 0.00 0.000202
(N20)
Green House Gas Pulutants for Peak Generator
Emission Factor
GHG Pollutant (Lb/gal.) ibs/yr tons/yr
CO2 2.0600000 7490.16 3.75
Methane 0.0003289 1.20 0.0006
(CH4)
Nitrous Oxide 0.0000470 0.17 0.00009
(N20)
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#:0800044
Fire Pumps
Data used for inventory only!
Year: 2011
Total Run Time: 23.5 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC
Month Fuel
Used Operated hour (lbs.)
January: 40.0 2.0 20.0 2.083
February: 40.0 1 2.0 20.0 2.083
March: 40.0 2.0 20.0 2.083
April: 30.0 1.5 20.0 1.562
May: 50.0 2.5 20.0 2.604
June: 40.0 2.0 20.0 2.083
July: 60.0 3.0 20.0 3.125
August: 30.0 1.5 20.0 1.562
September: 40.0 2.0 20.0 2.083
October: 40.0 2.0 20.0 2.083
November: 30.0 1.5 20.0 1.562
December. 30.0 1.5 20.0 1.562
Total: 1 470.0 23.5 20.0 24.5
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 0 23.5 20.0 470.0 2.82 66.27
Criteria Emisson Factor (Lb/mm FP
Pollutants BTU) (TonsNr
TSP 0.31 0.010
PM-10 0.31 0.010
PM-2.5 0.31 0.010
Sox 0.29 0.010
Nox 4.41 0.146
VOC 0.36 0.012
CO 0.95 0.031
Green House Gases
Hazardous/Toxi Emisson Factor (Lb/mm FP GHG Emisson Factor E101
c Air Pollutants BTU) (Lbs/Yr) Pollutant Lbl al. tons/ r
CO2 2.0600000 0.484
Acetaldehyde 7.67E-04 0.051 Methane 0.0003289 0.000000
Nitrous
Acrolein 9.25E-05 0.006 Oxide 0.0000470 0.000000
(N2O)
Arsenic 4.00E-06 0.0003
Benzene 9.33E-04 0.062
Benzo a rene 1.88E-07 0.00001
Beryllium 3.00E-06 0.0002
Cadmium 3.00E-06 0.0002
Formaldehyde 1.18E-03 0.078
Na thalene 8.48E-05 0.006
Toluene 4.09E-04 0.027
X lene 2.85E-04 0.019

Annual Air Emissions Inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2
Fuel Source : Wood Chips
Year: 2011
Total Run Time: 2436.0 Hrs/Yr
Wood Chips 8000000 BTU/ton
Boiler Operation (Hours) Wood Chips Burned (Tons) NOx Emissons (Lbs.1 CO Emissions (lbs.)
Month ES-BB1 ES-BB2 Total Boiler ES-BB1 ES-BB2 Total Wood ES-BB1 ES-BB2 Total ES-BB1 ES-BB2 Total
Hours Chips
January: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
February: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
March: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
June: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
July: 0.0 1 0.0 0.0 0.0 1 0.000 0.0 0.0 0.0
August: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
Se tember: 0.0 0.0 0.0 0.0 0.000 0.0 0.0 0.0
October: 1 354.0 186.0 540.0 205.0 100.0 305.0 111.5 54.4 165.920 1.3 0.6 2.0
November: 648.0 480.0 1128.0 474.0 320.0 794.0 257.9 174.1 431.936 3.0 2.0 5.1
December: 384.0 384.0 768.0 1 414.0 414.0 828.0 1 225.2 225.2 4 2 2.6 2.6 5.3
Total: 1386.0 1 1050.0 2436.0 1 1093.0 834.0 1927.0 594.6 453.7 1048.3) 1 7.0 5.3 1-- T .3
Z � 0.01 i Q,✓ S
L� }

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2011
Info: Lbs/Gal= 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 1 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., CIA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
H:\Environmental\Air PermitkAir Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2011 Common Name : Lime
Monthlv In entory of Calcium h droxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 1 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2011
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13696 13696 1 13696
Februarv: 13696 13696 1 13696
March: 13696 13696 13696
April: 13696 13696 527.0 13169
May: 13169 13169 919.0 12250
June: 12250 12250 12250
July: 12250 12250 1275.0 10975
August: 10975 10975 10975
September: 10975 10975 1824.0 9151
October: 9151 9151 November: 9151 9151
5400.0 14551 393.0 1
December: 14158 1 14158 1599.0 12559
Lbs. of chloroform used during the year: 6537
Lbs. of chloro. used by Misc., CIA, and R&D:
Lbs. of chloro. used by EVG: 6537
Lbs. EVG Produced: 3498
Lbs. of chloroform sent to hazardous waste: 450
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 6087
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6 &OS-7
Year:
Info: Lbs/Gal= 7.60
Monthly Inventory of Ethyl acetate(pounda):
Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA Alcohol
Total Beginning Beginning New Recovered Recovered In Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Month Emitted(Lbs.)
Inventory Inventory Inventory
January: '- 3945 3945 0 701.00 3945 701.0 3244 January: 36.87
February: 3244 3244 0 75.00 3244 75.0 3169 February: 52.42
March: 3169 3169 0 2271.00 3169 2271.0 898 March: 2.13
April: BOB 898 0 3320.0 299.00 4218 299.0 3919 April: 24.91
May: 3919 3919 0 381.00 3919 381.0 3536 May: 19.38
June: 3538 3538 0 2579.00 3538 2579.0 959 June: 18.87
July: 959 959 0 3320.0 450.00 4279 Jul 4.83
0 3829 40Au August: 382 3829 1001.00 9 28 August 9.63
28 0September: 28 2828
728.00 2828 728.0 2100 September. 0.00
October. 2100 2100 0 964.00 2100 964.0 1136 October. 31.84
November: 1136 1136 0 3320.0 1051.00 4456 1051.0 3405 November: 17.50
December: 3405 3405 0 439.00 3405 439.0 29M December: 44.29
Lbs.of Ethyl acetate used during the year: 11201.67
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 3807.00
Lbs.of Ethyl acetate used in SFG:OS-6 7132.00 i 7
Lba.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):0S-7 �
Lbs.0f Ethyl acetate VOC from SDA Ethanol Loss 122 73
Crown Process
Gallons sent to Hazardous Waste: 586.67
Lbs.Sent to Hazardous Waste: 4400.00
Total lbs.of Ethyl acetate emitted during year: 6801.67

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethvlenediamine : OS-31
Year: 2011
Info: Lbs/Gal = 7.50 All ethylenediamine is contained and
shipped off-site with the product.
Monthly Inventory of Ethvlenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 1 2011'
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons):
Beginning Max Ending Gallons to
Month InventoryReceived Lbs Used Recovered inventoryWWT
VOC (Lbs.)
January: 4412 29046 4412 0 0
February: 4412 660 33391 5072 0 0
March: 5072 33391 5072 0 0
April: 5072 33391 5072 0 0
May: 5072 33391 5072 0 0
June: 5072 33391 5072 0 0
July: 5072 33391 5072 0 0
August: 5072 33391 5072 0 0
September: 5072 33391 5072 0 0
October: 5072 33391 5072 0 0
November: 5072 33391 1 1 0 0
December: 5072 33391 1 1 5072 0 0
Total Gallons of Ethanol Used: 0
Total Lbs. Ethanol Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. of Ethanol Emitted as VOC: 0

Annual Air Emissions Inventory
Facility IDS:0800044
Ethanol-SDA:OS-7&OS-10
OS-18.05-19.OS-27.OS42INCLUDED WITH 05-10.� J. t 5 xt e+ t r 4
Year: 2011
Info: LbslGsl• 6.87 %SDA Ethyl acetate- 4.54
Monthly Inventory of Ethanol IjBig2nsl:
Monthly Bealnnina Inventory Bulk Drums
6748".2
SDA Bulk SDA In Drums Max SDA on Total SDA BOA as Ethyl
SDA SDA SDA In Drums SDA In Drums SDA Ending SDA Used SDA Used SDA VOC Acetate
Month g Beginning Beginning SDA Used SDA Disposed Hand WWT
ry Inventory Inventory Received Transferred Received Used Recovered (�) Inventory (gallons) (Lbs.) (�) (Lbs.) Emlttetl
Janus": 0 36120.8 22381.3 5383.0 1067Z0 4766 438M 57974 5911 40007.9 39795.7 8122 36.87
Februe . 1 30826.8 27147.4 11946.0 5427.0 6932 3955 480351 61617 8404 57732.7 66578.1 1154.7 62.42
March: 6 37345.8 24170.8 5349.0 1061.0 74 794 4068 459366 52456 341 2343.4 2296.6 46.9 2.13
HI: 41633.8 20822.7 3994.0 429078 58462 3994 27438.8 26890.0 S46.8 24.91
May: 37639.8 20822.7 19490.0 17214 0 14108 535M 74846 3106 21339.6 20912.8 426.8 12.38
June: 2 39915.8 34930.5 3120.0 213 308 514193 718M 3025 20778.3 203677 415.6 18.87
Jul : 7 36795.8 36026.0 1 774.0 493416 71048 774 5317.4 5211.0 106.3 4.93
Au cast: 71047.7 36021.8 35026.0 15M.0 488098 69504 1544 10607.3 10395.1 212.1 9.83
Ss mbeC 89503.7 34477.8 35028.0 477490 89501 0 0.0 0.0 0.0 0.00
October. 69ll 344T7.8 135026.0 r W9B.0 5105.0 522132 70897 5105 35071.4 34369.9 701.4 31.84
November. 70898.7 35870.8 35028.0 8572.0 2805.0 532210 74684 2805 19270.4 18884.9 385.4 17.50
December. 1 74683.7 1 39837.8 135028.0 7100.0 512940 1 67664 1 7100 1 48777.0 47801.5 975.5 44.29
Total Gallons of SDA Used: 42108.3
Total Lbs.SDA Used: 289284.0
Gallons sent to Hacardous Waste:
Lbs.SDA Ethanol set to Hatardous Waste: 0.00
Total Gallons sent W W WT: 41266.13
Total Lbs.sent W W WT: 283498.34
Total BOA Ethanol VOC's 5795.68
Lbs.Botanical EsbacBon Ethanol Emitted:05-10 2ZO124
Lbs.PNE Ethanol Emitted:03-7 083.M
Misc.Lbs.SDA Ethanol Emllted:
Total Lbs.of SDA Ethanol Emitted: 5785.68

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS4, OS-5, OS-6, OS-10. OS-28, OS-29
OS-13 OS-14 OS-15 OS-16 OS-17 OS-20 OS-21,OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH OS-10•OS-30 INCLUDED WITH OS-28
Year: 2011
Info: LbslGal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month eginning Received Max Used Ending Inventory
InveJanuary: 10328. 56804 1823 - 8505
February: 85D5 46778 1102 7403
March: 7403 4472 85313 2027 9848
April: 9848 54164 1039 88D9
May: 8809 48450 226 8583
June: 8583 47207 1146 7437
July: 7437 4382 85005 1479 10340
Au ust 10340 56870 1 2044 8296
September. 8296 4023 67755 1 1539 10780
October: 10780 59290 1243 9537
November. 9537 52454 2043 7494
December: 7494 3876 62535 1279 1OD91
Monthly Inventory of HP Hexane-9501,(gallons):
Month Beginning Received Max Used Ending Inventory
InvJanuary: - 1089 59M 358 731
February: 731 5909 36520 941 5699
March: 5699 31345 236 5463
April: 5463 30047 542 4921
May: 4921 27066 1046 3875
June: 3875 21313 1236 2639
Jul ; 2639 14515 1424 1215
Au ust 1215 - 8883 1286 -71
Se tember. -71 5906 32093 15121 4323
October. 4323 1 23777 1392 1 2931
November. 2931 18121 1917 1014
December. 1014 1 1 5577 1 1401 387
Monthly Inventory of IsoHexane-2.5%laallonsl:
Month Beginning Received Mbs ax Used Ending Inventory
January: 41688 229284 41688
February; 41688 229284 41688
March: 41688 229284 992 40696
April: 40696 223828 4D696
May: 40696 8729 271838 2030 47395
June: 47395 25375. 400235 20103 52667
July: 52667 19460 396699 18234 53893
Au ust: 53893 12652 365998 16939 1 49606
Se tember. 49606 19710 1 381238 25051 44265
October: 44265 23479 372592 38082 29662
NovamMr. 29662 163141 29662
December: 29662 163141 29682

Page 2 of 4
Monthly Emissions of IsoHexane from Biomass Bollers(Lbs.l:
Percent n-Hexane: 0.24
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0 0
February: 0 0
March: 0 0
April: 0 0
May: 0 0
June: 0 0
JUI : 0 0
Au ust: 0 0
September: 0 0
October. 0 0
November. 0 0
December. 0 0
Total Hexane Values
Gallons of LP Hexane Used: 16990.00 Gallons of N-Hexane Used: 18269.68
Gallons of HP Hexane Used: 13291.00 Lbs.of N-Hexane Used: 100463.25
Gallons of IsoHexane Used: 121431.00 Gallons of Hexane Isomers Used: 133442.32
Total Gallons of Hexanes Used: 151712.00 Lbs.of Hexane Isomers Used: 733932.75
Total Lbs.of Hexanes Used: 834416
Sclareolide(SIDE)Operation:OS-5
Percent N-Hexane In Solvent: 39-4
Gallons of Hexane Used In SDE: 16990.00 Lbs,of Fugitive Hexane from SDE: 92021.79
Lbs.of Hexane Used In SDE: 93445 Lbs.ofFugitive - exane from 36256 58
SDE:
Lbs.of SDE Product: 284642.26 Lbs.of Fugitive Hex Isomers hone 55765.20
SDE:
Lb.Hexane per Lb.of SDE
0.005
Product
Lbs.Hexane in SDE Product 1423.21
Lbs.N-Hexane In SIDE Product: 560.75
Accountable Lbs.of Hexane Lost: 1423.21 Accountable and Fugitive Lba. 93445 00
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 560.75 Accountable and Fugitive Lbs. 36817 33
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 862 47 Accountable and Fugitive Lbs.Hex 56627 67
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 9300
Waste:
Lbs.of N-Hex Sent as Hazadarous 2976
Waste:
Lbs.of Hex Isomers in Hazardous 6324
Waste:

Page 3 of 4
Sclarsol Recrvstallization fSFGI Operation:OS-6
Percent N-Hexane in Solvent: 91.4
Gallons of Hexane Used in SFG 13291.00 Lbs.of Fugitive Hexane from SFG 71426.37
Lbs.of Hexane Used in SFG: 73100.5 Lbs.of Fugitive N-Hexane from 65263.70
SFG:
Lbs.of SFG Product: 334826 Lbs.of Fugitive Hex Isomers from 6142.67
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 1674.13
Lbs.N-Hexane In SFG Product: 1530.15
Accountable Lbs.of Hexane Lost 1874.13 Accountable and Fugitive Lbs. 73100 50
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 1530.15 Accountable and Fugitive Lbs. 66813.86
N-Hex Emitted:
Accountable Lbs.of Hex Isomers t43 98 Accountable and Fugitive Lbs,Hex 8286.64
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 22100
Waste:
Lbs.of N-Hex Sent as Hazadarous 20995
Waste:
Lbs.of Hex Isomers in Hazardous 1105
Waste:
Rotocel Concrete 8 Recovery Operations:OSd
Gallons of Hexane Used: 120439.00 Gallons sent to W WT: 2495632
Lbs.of Hexane Used: 662414.5 Lbs.Waste Water per Gal.Waste 8.34
Water:
Percentage of N-Hexane in 0.161 Wt-/,of Hexane in Waste Water: 0.014
Solvent:
Lbs.of Hexane Sent as Hazardous 6561 Lbs.Hexane Lost In Waste Water: 2913.90
Waste:
s.o - ex Sent as aza arous 10 56 - exane Lost n Waste 4.69
Waste: Water.
Lbs.of Hex Isomers in Hazardous 6550.44 Accountable Lbs.of Hexane Lost: 88736.01
Waste:
Lbs.Hex per day exiting Mineral -41.60 Accountable Lbs.of N-Hex Lost 142.87
Oil Scrubber from MO tests
Days of MO Unit operation: 135 Accountable Lbs.of Hex Isomer 88593.15
Lost
Lbs.of Hex exiting MO Unit: 5616
Lbs.of N-Hex exiting MO Unit 9.04
Lbs.of Hex Isomers exiting MO 5606 96 Total Lbs.Hexane Lost as Fugitive: 567117.49
Unit:
Lbs.Sage Processed: 5012 8820 Total Lbs.N-Hex Lost as Fugitive: 913.06
Lbs.Hexane per Lbs.of Spent 0.001600 Total Lbs.Hex Isomers Lost as 566204.43
Sage(from Desolvitizer tests): Fugitive:
Lbs.Hexane in Spent Sage: 80206.11
Lbs.N-Hexane in Spent Sage: 129.13
Lbs.Hexane per Day from A-1 0.000815
Vent Gond.
Days A-1 Operated: 135 Accounta 9 an ug tive ba. 655853.5
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.110 Accountable an ugitive s. 1055.92
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent 0.000177 ccounta a an ugitive Los.Hex 654797.58
Isomers Emitted:

Page 4 of
Biomass Extraction Operation:OS-28
Gallons o1 Hexane Used: s.of Fugitive Hexane from 0
Bio Extraction:
Lbs.of Hexane Used: 0 L s.o ug ve -Hexane from Bio 0.00
Extraction:
Lbs.of Biomass Product Lbs.o ugitive Hex Isomers from 0.00
Bio Extraction:
%n-Hexane 0.17
Botanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.o ug va -Hexane from Rot 0
Extraction:
Lbs.of Botanical Product: L­bs­.orFugltive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction(M-131 Ooerotion:OS-29
Gallons of Hexane Used: 992.00 s.of Fugitive Hexane from 5456
PNE:
Lbs.of Hexane Used: 5456 •of ug UPNE:Hexane from 6.5472
.o Fugitive Hex isomers rom
Lbs.of PNE Product: -733.5 PNE: 5449A528
%n-Hexane 0.12
Lbs.of exane Sent as Hazardous 20600
Waste:
Lbs.of N- ex Sent as Haza arous 24.72
Waste:
15i.—TRex isomers in Hazardouc 20575 28
Waste:
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: ID8602.56 Total Lbs.n-Hexane Released: 104693.66
Fugitive Lbs.Hex Isomers 633561.75 Total Lba.Hex Isomers Released: 723161.34
Emitted:
Accountable Lbs.n-Hexane Lost: 2233.77 Total Lbs.N-Hexane Sent OH Site: 3011.28
Accountable Lbs.Hex Isomers 89599 59 Total Lbs.Hex Isomers Sent OH 33448 72
Lost: Site:
Total Lbs.Hexane Sent Off Site: 36461.00
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane .
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 50924 4458 24520.4
February: 54790 8825 48538.7
March: 56007 9359 51472-4
April: 54426 8511 46811.8
May: 59853 7613 41869.8
June: 62743 6204 34119.6
July: 854" 5810 31957.1
Auclust 57831 1 3827 21050.8
September. 59368 8663 47646.9
October: 1 42130 6578 36178.1
November. 1 38170 4103 22566.1
December. 1 39366 1 3 19816.6
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
65448 9359 51472

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2011
Info: Lbs/Gal = 5.70
Mont Iv Inventorvof Heptane allons :
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 1 496 2827 496
December: 1 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in 0.85
Solvent:
Gallons of Heptane Used in 0.00 Lbs. of Fugitive Heptane 0.00
SFG: from SFG:
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane 0.00
SFG: from SFG:
Lbs. of SFG Product: Lbs. of Fugitive Hept. 0.00
Isomers from SFG:
NJ
Lb. Heptane per Lb. of SFG 0.0 55
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG 0.00
Product:
Accountable Lbs. of Hexane 0.00 Accountable and Fugitive 0.00
Lost: Lbs. Heptane Emitted:
Accountable Lbs. of N-Hept. 0.00 Accountable and Fugitive 0.00
Lost: Lbs. N-He t. Emitted:
Accountable Lbs. of Hept. 0.00 Accountable and Fugitive 0.00
Isomers Lost: Lbs. He t. Isomers Emitted:
Lbs. of Heptane Sent as
Hazardous Waste:

Annual Air Emissions Inventory
Facility 0"": 0800044
Hydrochloric Acid : OS-7
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (Ibs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 732 0 0
February: 0 0 0
March: 0 0 0
April; 0 0 0
May: v i U
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 1 0 1 1 0
December: 0 1 0 1 1 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutvl acetate: OS-7, OS-10
Year: 1 2011
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutvl acetate (gallons):
Beginning Max Used Ending
Month Received Recovered Recovered
Inventory (Lbs) New Used Used Inventory
January: 1514 10931 1514
February: 1514 10931 1514
March: 1514 10931 1514
April: 1514 10931 1514
May: 1514 10931 1514
June: 1514 10931 1514
July: 1514 10931 1514
August: 1514 10931 1514
September: 1514 10931 1514
October: 1514 10931 1514
November: 1514 10931 1514
December: 1514 10931 1514
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @(OS-10):
Lbs. Of IBAC used during the year OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyl acetate: OS-7, OS-10
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory (Lbs) Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 1 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0

Annual Air Emissions Inventory Summary
2011 Totals Facility ID#:0800044
Pollutant Boiler et J4M4
Boiler F3 aeon Gen 82 Den N e•II N Pk-0 Fire Pum Blomaaa Rofml Plem
P rF Recry•Wlix•Uon SGareoiWe Bbmue 8alrllcY NYtfbnt EVG V/W7P OOI•r TOGIa UnIN
BWlara ISFGI (BDEi EaVr4bn Ealr•d0on PrOda•••e
CO 23W.52 2261.99 170 2W 428 O.W 3,75 0.48 T.Wr
Me11wIw O.OW18 000600 0.00027 0.00048 O.Mall &MOO O.00060 0.00 0.026 T.n '
N U.Oxi" 0012W 001212 000WI 000001 0.=10 0.MOO OODOD9 000 0. TOnWr
TSP 02W0]71 0201 T2 00360M7 0.OM647 OW091W 0 007918478 001027185 1.066 T.na r
PM-10 0.103018M 0100B686 0.03606W5 O.OBOWIB25 O.OBOHIW 0 001916/]8 0.01027185 0672 TonslVr
PM-2.5 002575b3a 002524215 003606075 O.DBOW]625 D09081M 00)9161)e 00102)185 .3)0 TonWr
d. 4 W1 03) 5 0.05873481 WM512 OON3 00980B15 lt. TaOWf
Nok 24n4452 242324W O.St2BB325 0.M2)813)5 1.2B33W8 0 1.13W O.t1612535 0.52 - 13.9W TonWr
VCC 0.020W371 O.0 IO 0.=193n O.W1an 007W265 0.1055Ma 0 1M OOIIWM 32T92075 6541 40.11 46.T225 .41 4.W, 0.57 W 489491 T.Wr
00 0.51609275 0.952628 05W843 01105W7 0.185855825 1 027WI6 0 1 0.2435211 1003147825 am 2 M TdniNr
A %IdM de 0.1T 4255 0.3WID7925 0.M989152 0.393222492 0OSW2909 1 1.372 IDWr
A Neln 0,0215M125 GONI929M 0.05125W 0 OW742253 O.OD812969 0.1ee Lba/Yr
Awenic 0.12201171 0.22MMW7 0.11BS8 1 0.DD09306 0.W15651 0.002341i24 0 0.0020M7W 000026M8 0.74 Lba/Tr
Benxen• 0.M153751 0M1659101 0NU75142 0/1706245 O.WM69575 O.W728W8 0 0.4783287W O.W182261 I Ino LDWI
Benz a rune 4.3 -0 1.35591E45 0.00011W73 0 6.63831E-05 1.2459E-05 OOOW LDWr
Ilium 0.07MW78 0.1W320280 O.W1182M3 00 OWN 0WI17 5 0.WI759M 0 01101538028 OOW19W1 028 Lb '
Bulanol 0.W 000a LbWr
cadmium 0,31M7!M 0.5BW]8 000/2 0,31=206 0. 097W eWI1 5 0. 175908 0 0.001538028 0.00019M1 1.M Lb ,
Celaum h rodde O.W 0.000 LbL r
Chlorolorm BOB7 0. 0087.00D Lbs r
Chromium 1AB4971d0I 3.116=171 1.651N24M 6,453 Lbs r
Chromium IV 0.0M97M76 00110504e2 0 MSWJ70 00D Lbs r
ENerw1-1001L 0,00 0000 Lbs r
ElhanN-SDA 1 270.24 3a82.N 1 O.W 5786 M Ub r
MA 9. 1 7132 12273 3W7 1IMI 670 Lb r
Mil benb 0013W3H8 1 00241967 0.012823012 0.= I
EMYIm iamine 0 0 ODO LDWI
Fl.0. ].68518]63 1421317M 7,532257N 79431 LEWr
Falmeideh 67979800n 126723769 6.0627169n 0.274527 0.41617N5 089214W 0 0614w" 00781W 211145 LSWr
ne lsomwf 664797570M3 SM7.] 0 0.00 We,4W 723161 311 Lb ,
NJle.ena IOM.M431 =13.957 3681i.M 0 &W 0W72 04683.659 LbIINf
H bne I... 0,00 LbW1
N-He tan• O.OD Lbwr
Isobm lecNela 0 0.00 0.DDO LbWr
Isom iecetale 0.00 0W 0.000 LbWr
lead Com ands 0.256555457 OA741WI47 0253410992 O.m LbslTf
Me mesa 0.4W71n35 0.)5216349 0.398624033 1 1 1 0 1558 Lb '
Mara 008715MO3 0 1116431 O.Oa511W3a 0334 LDWr
MMhanol 13W14.93 SW.n 114B.44 4%7.13 137 . 1 LOWr
Na below 06M.232611 0.40117M 0201326931 001972 M O.W31801 O.W9T402a8 0 OOa3d7aB25 0.005619] 1.1n Lbattr
NickN a5229T218 0.9671M915 0.51251MI1 Lbvyr
Su117 Diaude 0.00 0.000 L r
Toluene 1.2]82W1W 22 OII8682 1252 ISM O.OBS 5385 0.18003f475 0.239803W 0 0.20BBBa18/ 0. 710N3 0.00 5. 7 LBW'
% ens m&)6 5 0,1115133] 0.1871898 0 0.1d6112M OO1WM 5 0.510 Lb•11r
o-% • 1 0.=4374/ 1 0.041498388 1 0021MMI I I 1 0.066 lbe//r
unn n n�
N
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Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: OS-4, OS-7, OS-9
OS-13, OS-14, OS-15, OS-16, OS-17, OS-27, OS-32 INCLUDED WITH OS-4
Year: 2011
Info: Lbs/Gal = 6.62 Specifice Gravity= 0.793
Monthly Inventory of Methanol (gallons):
Month Beginning Received j Max Used Recovered Ending
Inventory Lbs Invento
January: 21109 1 139742 1 21109
February: 21109 1 139742 21109
March: 21109 139742 21109
April: 21109 4400,0 168870 3076.6 22432
May: 22432 13427.0 237389 442.0 35417
June: 35417 6774.0 279307 6146.0 36045
July: 36045 440.0 241533 9251.0 27234
August: 27234 180292 10394.0 16840
September: 16840 8743.0 169362 9977.0 15606
October: 15606 103314 8369.0 7237
November: 7237 6160.0 88691 1935.0 11462
December: 11462 75881 2041.0 9421
Maximum Gallons On-Hand: 42191.4
Maximum Lbs. On-Hand: 279307.068
Gallons Used per Year: 51632
Lbs. Used per Year: 341801.192
Sclareol Recovery Operation: OS-4
Total Gal. of Methanol Used: 39138
Total Lbs. McOH Used: 259093.56 Avg. % MeoH thru Pods: 85
Avg. % McOH in WW: 9.3 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 1.06 Number of Stream Days 135
Number of Stream Days: 135 Total Gal. Thru Pods: 1749600
Total Gal.of WW to WWTP: 4431060 Total Gal. McOH Thru Pods: 1487160
Total Lbs. of WW to WWTP: 36955040.4 Total Lbs. McOH Thru Pods: 9844999.20
Total Lbs. of McOH to WWTP: 128278.63 Total Lbs. Fugitive Emissions 130814.93
from Recovery:
Avg. Removal Efficiency of Total Accountable and Fugitve
WWTP: 97.68 Emissions from Recovery: 133791.00
Accountable Emissions of
McOH from WWTP during 2976.06
Recovery:

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 8674 Accountable Emissions of
Gallons of McOH to WWT: 8500.52 McOH from WWTP during JU227
5.47
Total Lbs. of McOH to WWT: 56273.44 EVG:
Total Lbs. Fugitive Emissions 1148.44 Total Accountable and Fugitve3 9
from EVG: ✓ Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 3819.6 Accountable Emissions of
Gallons of McOH to WWT: 3743.208 Mc OH from WWTP during 495.60 C v�f'N
Total Lbs. of McOH to WWT: 24780.03696 PNE:
Total Accountable and Fugitve Qc ��
Total Lbs. Emissions PNE: 505.71504 1001.32 \� e("
E missions from PNE: AV
C /Totals for All Methanol Operations
Total Lbs. McOH Thru System: 9844999.20 Lbs. of Emissions from Misc., Lab: 505.71504
Total Lbs. McOH to WWTP: 209332.11 Lbs. Fugivtive Emissions from EVG: 1148.44
Removal Efficiency of WWTP: 2976.06 Lbs. Fugivtive Emissions from Recovery: 130814.93
Lbs.Accountable Emissions 4597.13 Total Lbs. Fugitive Emissions: 132469.09
from WWTP:
Total Lbs. McOH Treated at 209332.11 Total Lbs. McOH Released: 137066.22
WWTP:
Total Lbs. McOH Recycled On-Site: 9635667.09

Annual Air Emissions Inventory
'1'4 ln1 nOnn/1A
Fgcl'PLY P,': VVVVVY4
Maqanese
Year: 2011
Info: Potassium permanganate contains 33-35% Manganese.
Month1v In entory of Potassium Permanganate (pounds
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
lfia ' 10537 i6537 10537
June: 16537 16537 16537
July: 16537 16537 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand. 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2011
Info: Lbs/Gal =
Monthly Inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs.of Sulfur dioxide used by Misc., CIA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2011-
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 1 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc.:
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2011
The Plant Material Grinder (OS-3) is operated in building ID # 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinders operation. Essentially there are no emissions associated with the plant
material grinder.