HomeMy WebLinkAboutAQ_F_0800044_20140918_EI_Cmb-EI-File 200 Emissions Inventory Review / Data Tracking Form
Facility Name: Avoca Incorporated Facility ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston eth Confidential Copy Submitted?
Title V ❑ YES
NO
Initial Review/Data Entry
Er Enter date received into ED. Date Received: y/4 j2oi t1
Assigned to appropriate individual. Date Assigned: � IQI`/ Date Due:
E!f Paper copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and
` appears generally complete;?Roo+A
)J Electronic copy submitted: All supporting documentation and certification form (with time/date stamp)signed by responsible
official has been received. , l
Comments: coo tvotPSr ac—
/ Inventory Review
(a All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
Contact,address,phone number changes entered into I-Beam/Facilities if necessary.
All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
d Evaluate"U"sources for significance and address according to olicy.
® Calculations/forms appear to add up correctly.CO&P c f a as �, 16,,✓7a
db
I f All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds,large emissions increase/decrease,installation
without a permit).
EI' All volatile HAPs/TAPs were included in the VOC total.
[( Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP-42,etc.).
[�( Review facility comments and address any issues.
{� Update ED(Data Entry Main)if additional information is required(corrections due date and date received).
if Check all ED QA/QC reports.
Comparison with previous emission inventory must be made and outliers(> 101/6)must be investigated and explained.
L� Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
R/ Print and attach the facility total report.
Date Review Complete: 20i If Signature:
Date Submitted to El Coordinator:
Date Approved: s/ZoI y Initials:"r
1. Fuel oil consumption on H101-103 was 80%of the previous year. Generator fuel usage increased 1,589 gallons. Wood
boiler fuel usage increased in 2013 by 4,A36 tpy.
2. The metals categories for combustion established by the June 6, 2005 email from Brendan Davey(TPB and PWG approved)
were corrected in ED.
3. NOx emissions from H101-103 were recalculated to 4.42 tons (EF is 20.0 Ib/1000 gals).
4. NOx emissions from generators 101-104 was off an order of magnitude. The emission was corrected to 9.96 ton.
5. Generators 101-04 VOC emissions were corrected to 0.3 ton.
6. 1 added metal emissions to ED for the fire pup generator. I corrected NOx emission to 0.17 ton for the generator.
7. 1 added metals and corrected SO2 and VOC emissions for PK-generator.
8. Metals were added to the wood boiler emissions in ED.
9. 1 asked Brian Conner to separate the isohexane, n-hexane and methanol emissions into the controlled and fugitive fractions
at Rotocel/Recovery/Concrete, SFG and SDE. They have been reporting a total for each pollutant in each area of the plant. I
have created new OS and emission points in ED for the fugitives.
10. In the inventory forms several pollutants are quantified in the negative. Brian said that a campaign often does not end with
the month's end so at that point in the run the recovered solvent may show more than the used. At the campaign's end, the
actual final numbers will balance out (mass balance approach) as can be seen in the following month's totals. Therefore, if
the annual emissions total is in the negative, emissions are considered zero.
11. Avoca uses 3 varieties of Ethanol depending on the product/process and extraction requirements. I inventory each variety
separately just because it makes it easier to keep up with on my end and to match up with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs. of SDA Ethanol for a total of 8378 lbs. of Ethanol
emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs. of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment.Their bugs thrive on ethanol and Avoca assumes all ethanol is
consumed by the bugs.
12. The following notes concern pollutants that changed +/- 10%from 2012.
a) CO emissions decreased due to new stack test value on the wood boilers.
b) NOx emissions increased due to more wood combustion on the wood boilers.
c) The SO2 decrease is due to less firing in H101-103.
d) Metals increases are due to wood fuel increase. The metals categories for fuel combustion were changed this year, so
the totals look different in comparison to 2012. As a result the increases and decreases compared to 2012 appear large.
The increase in emissions for all metals except manganese is less than a pound.
e) Fluoride emissions decreased due to less operation of H101-103.
f) HCI emissions drastically decreased due to the difference between two stack tests (done 2/21/2013 and 12/2013).
g) Process solvent emissions are dependent on client demand. The associated HAPs are chloroform, ethyl acetate,
methanol, isohexane, n-hexane, and toluene.
h) All combustion HAPs increased due to the increase in wood combustion. I added ethylene dichloride,vinyl chloride,
methyl bromide, methyl chloride, methylene chloride, and phosphorus emissions to the wood combustion emissions
using DAQ spreadsheet. I also added several combustion toxics to the AERO data for the engines(NCDAQ
spreadsheets).
13. 1 added n-hexane and isohexane emissions to the WWTP, which accounts for the difference e in VOCs between what is now
in ED and what Avoca reported.
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Green House Gases Pollutants (GHG) Actual Emissions %Tons/Yr
Pollutant CAS CY 2013 CY 2012 Demini- Change
from ED from Fees mus
Carbon Dioxide (CO2) 124389 22,048.40 33,942.18 5,000.0 -35.0%
Nitrous Oxide(N20) 10024972 1.16 1.26 I .0 -8.1%
Methane (CH4) 74-82-8 1.85 9.44 10.0 -80.4%
CO2 equivalent(sum of individual GHG pollutant emission 20,364.32 metric tons
times their 1995 IPCC Global Warming Potential(GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
CO Co 18.70 43.64 0.5 -57.1%
NOx Nox 27.84 24.08 0.5 15.6%
PM(TSP) TSP 0.970000 1.07 0.5 -9.6%
PM10 PM10 0.460000 0.4430010 0.5 3.8%
PM2.5 PM2.5 0.300000 0.233000 0.5 28.8%
S02 S02 11.85 13.64 0.5 -13.1%
VOC VoC 1,055.94 931.29 0.5 13.4%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
Antimony & Compounds(total mass, inc elemental SB) Not 1.10 10.0 N/A
Reported
Antimony Unlisted Compounds-Speck Compound SBC-other Not 1.10 10.0 N/A
(Component of SBC) Reportcci
Arsenic& Compounds (total mass of'elemental AS, acshic (Iiul 4.10 3.38 0.01 'l•;"�
all inorganic compounds)
Arsenic Metal, elemental, unreacted(Component of 7440-38-2 Not 3.05 0.01 NiA
ASC) Reported
09/18/2014 Page 1 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2113 CY 2012 Demini- %
from ED from Fees mus Change
Arsenic Unlisted Compounds-Speck Compound ASC-other 4.10 0.334640 0.01 ,125.20/
(Component of ASC)
Beryllium & compounds (Total mass) 0.381720 0.386840 1.o -1.3%
Beryllium Metal(unreacted) (Component of BEC) 7440-41-7 0.381720 Not 1 .0 N/A
Reported
Beryllium Unlisted Compounds-Specify Compound BEC-Other Not 0.386840 1.0 N/A
(Component of BEC) Reported
Cadmium& compounds(total mass includes elemental metal) 0.901720 0.806840 0.1 11.80
Cadmium Metal, elemental, unreacted(Component 7440-43-9 0.901720 Not 0.1 N/A
of CDC) Reported
Cadmium Unlisted Compounds-Speck Compound CDC-other Not 0.806840 0. 1 N/A
(Component of CDC) Reported
Chroniiunr-A11/7otal(includes Chromium (VI) categories, 0.801720 3.16 11.l -74.6%
metal and others)
Chromic acid(VI) (Component of So1CR6& CRC) 7738-94-5 0.801720 0.494020 0.01 62.3%
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-other Not 0.232820 0.01 N/A
Speck Compound(Component of NSCR6& CRC) Reported
Chromium Unlisted Compounds-Specify CRC-other Not 2.44 0.1 N/A
Compound(Component of CRC) Reported
Chromium (VI)Non-Specific Compounds, as Chrom(VI) Not 0.232820 0.01 I N14
(Component CRC) Reported
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-Other Not 0.232820 0.01 N/:\
Specify Compound(Component of NSCR6& CRC) Reported
Chromium (VI)Soluble Chromate Compounds(Component of 0.801720 0.494020 0.01 02.3%
CRC)
Chromic acid(VI) (Component of So1CR6& CRC) 7738-94-5 0.801720 0.494020 (0)I 62.3%
Cobalt & compounds Not td 900000 1.0 N/A
Reported
Cobalt Unlisted Compounds-Speck Compound COC-other Not 0.900000 1.0 N/A
(Component of COC) Reported
Lead& compounds 8.93 7.37 1.0 21.2
09/11/1114 Page 2 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demmi-
from ED from Fees mus Change
Lead Unlisted Compounds-Spec6 Compound PBC-other 9.93 7.37 10.0 21.2%
(Component of PBC)
,
Manganese & compounds 2'9.l 5 222.40 10.o -5•?
Manganese Unlisted Compounds-Specify MNC-other 279.15 222.46 10.0 25.5%1
Compound(Component of MNC)
Mercury& Compounds-all total mass includes Hg Vapor 0.204250 0.270510 0.001 1-24.5%
Mercury Unlisted Compounds-Specify Compound HGC-other Not 0.270510 0.001 N/A
(Component of HGC) Reported
Mercury, vapor (Component of HGC) 7439-97-6 0.204250 Not 0.001 N/A
Reported
Nickel& Compounds,sum total mass includes elemental 5.94 4.82 1.0 23.2%
Nickel metal(Component of NIQ 7440-02-0 0.191720 Not 1.0 N/A
Reported
Nickel Unlisted Compounds(Component of NIC- NIC-Other 5.75 4.82 1.0 19.4%
Specify)
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.453500 0.360390 1.0 25.8%
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.453500 0.360390 1.0 25.8%
5655317PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 17.76 14.20 1.0 25.1%
or TP)
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.453500 0.360390 1.0 25.8%
5655317PAH)
Naphthalene (Component of 833291POMM 91-20-3 17.31 13.84 1.0 25.1%
Acetaldehyde 75-07-0 144.73 115.14 10.0 25.7w/o
Acrolein 107-02-8 696.92 555.01 10.0 25.6%
Benzene 71-43-2 734.64 585.39 1.0 25.5%
Carbon tetrachloride 56-23-5 7.84 6.24 1.0 25.6%
Chlorine 7782-50-5 1 137.60 109.61 100.0 25.5%
Chlorobenzene 108-90-7 5.75 4.58 10.0 25.5%
09/18/2014 Page 3 of 6
i
Facility Total CY 2013 Emission Summary Recorded in 1?D Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demim- %
from ED from Fees mus Change
Chloroform 67-66-3 17,022.88 4,839.89 100.0 251.7%
DEHP(Di(2-ethylhexyl)phthalate) 117-81-7 Not 0.006500 10.0 N/A
Reported
Dinitrophenol, 2,4- 51-28-5 Not 0.025000 0.1 N/A
Reported
Ethyl acetate 141-78-6 9,626.70 14,052.59 10.0 -31.5%
Ethyl benzene 100-41-4 5.76 4.75 100.0 21.2%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.05 4.02 1.0 25.6%
Fluorides(sum of all fluoride compounds as mass of B6984-48-8 16.49 20.68 10.0 -20.2%
ion)
Formaldehyde 50-00-0 788.10 637.20 10.0 23.7%
Hexane isomers,except n-hexane HEXANEISO 1.481,559.4 1,352,727.1 100.0 9.5%
3 7
Hexane,n- 110-54-3 170,088.44 130,578.44 100.0 30.3%
Hydrogen chloride (hydrochloric acid) 7647-01-0 15.68 360.70 100.0 -95.7%
MEK(methyl ethyl ketone, 2-butanone) 78-93-3 Not 0.750000 100.0 N/A
Reported
Methanol (methyl alcohol) 67-56-1 310,854.43 290,491.38 1,000.0 7.0%
Methyl bromide (bromomethane) 74-83-9 2.61 2.08 1.0 25.5%
Methyl chloride(chloromethane) 74-87-3 4.00 3.19 1.0 25.4%
Methyl chloroform 71-55-6 5.40 4.30 100.0 25.6%
Methylene chloride 75-09-2 50.53 40.23 1.0 25.6%
N/A
Perchloroethylene(tetrachloroethylene) 127-18-4 Not 5.27 100.0
Reported
Phenol 108-95-2 8.87 7.08 100.0 25.3%
Phosphorus Metal, Yellow or White 7723-14-0 4.70 1.75 1.0 25.3%
Polycyclic Organic Matter(Inc PAH, dioxins, etc.NCPOM 23.28 17.34 1.0 34.3%
&AP 42 historic)
Propionaldehyde 123-38-6 10.61 9.46 10.0
09/18/2014 Page 4 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
Propylene dichloride(1,2-dichloropropane) 78-87-5 Not 4.58 10.0 N/A
Reported
Selenium Compounds SEC Not 0.412100 10.0 N/A
Reported
Styrene 100-42-5 331.04 263.61 100.0 25.6%
TCE(trichloroethylene) 79-01-6 Not 4.16 1,000.0 N/A
Reported
Toluene 108-88-3 196.13 526.51 100.0 -62.7%
Vinyl chloride 75-01-4 3.14 2.50 0.1 25.6%
Xylene(mixed isomers) 1330-20-7 4.78 3.76 100.0 27.3%
Xylene, o- 95-47-6 0.619050 0.776070 100.0 -20.2%
Largest Individual HAP Methanol (methyl alcohol) 310,854.43
Ibs
Total HAP Emissions 501,471.73
lbs
09/18/2014 Page 5 of 6
DAO's Comments Reeardine Inventory
1. Fuel oil consumption on HI01-103 was 80%of the previous year. Generator fuel usage increased 1,589 gallons. Wood
boiler fuel usage increased in 2013 by 4,436 tpy.
2. The metals categories for combustion established by the June 6,2005 email from Brendan Davey(TPB and PWG
approved)were corrected in ED.
3.NOx emissions from H10I-103 were recalculated to 4.42 tons(EF is 20.0 lb/1000 gals).
4.NOx emissions from generators 101-104 was off an order of magnitude. The emission was corrected to 9.96 ton.
5.Generators 101-04 VOC emissions were corrected to 0.3 ton.
6.I added metal emissions to ED for the fire pup generator. I corrected NOx emission to 0.17 ton for the generator.
7. 1 added metals and corrected S02 and VOC emissions for PK-generator.
8. Metals were added to the wood boiler emissions in ED.
9. I asked Brian Conner to separate the isohexane,n-hexane and methanol emissions into the controlled and fugitive
fractions at Rotocel/Recovery/Concrete,SFG and SDE. They have been reporting a total for each pollutant in each area of
the plant. I have created new OS and emission points in ED for the fugitives.
10.In the inventory forms several pollutants are quantified in the negative. Brian said that a campaign often does not end
with the monks end so at that point in the run the recovered solvent may show more than the used.At the campaigns
end,the actual final numbers will balance out(mass balance approach)as can be seen in the following monks totals.
Therefore,if the annual emissions total is in the negative,emissions are considered zero.
11.Avoca uses 3 varieties of Ethanol depending on the product/process and extraction requirements. I inventory each
variety separately just because it makes it easier to keep up with on my end and to match up with inventories.
a)Botanical emitted 3930.22 lbs.of 100%Ethanol and 4447.78 lbs.of SDA Ethano I for a total of 8378 lbs.of Ethanol emitte
b)Biomass only used one type of ethanol(100%)for krill,emitted 10528.95 lbs.
c)PNE used a total of 1078.72 lbs.of ethanol.
d)The bulk of ethanol does go to Waste Water Treatment.Their bugs thrive on ethanol and Avoca assumes all ethanol is
consumed by the bugs.
12. The following notes concern pollutants that changed+/- 10%from 2012.
a)CO emissions decreased due to new stack test value on the wood boilers.
b)NOx emissions increased due to more wood combustion on the wood boilers.
c)The S02 decrease is due to less firing in H101-103.
d)Metals increases are due to wood fuel increase. The metals categories for fuel combustion were changed this year,so
the totals look different in comparison to 2012. As a result the increases and decreases compared to 2012 appear large.
The increase in emissions for all metals except manganese is less than a pound.
e)Fluoride emissions decreased due to less operation of H101-103.
f)HCI emissions drastically decreased due to the difference between two stack tests(done 2/21/2013 and 12/2013).
g)Process solvent emissions are dependent on client demand. The associated HAPs are chloroform,ethyl acetate,
methanol,isohexane,n-hexane,and toluene.
h)AII combustion HAPs increased due to the increase in wood combustion. I added ethylene dichloride,vinyl chloride,
methyl bromide,methyl chloride,methylene chloride,and phosphorus emissions to the wood combustion emissions using
DAQ spreadsheet. I also added several combustion toxics to the AERO data for the engines(NCDAQ spreadsheets).
13. I added n-hexane and isohexane emissions to the W WTP,which accounts for the differenc e in VOCs between what is
now in ED and what Avoca reported.
09/18/2014 Page 6 of 6
I
Avoca, Inc. 2013 Emissions by Process
Process Chemical/Solvent Total Emissions Controlled Emissions Fugitive Emissions Percentage of Total
(Ibs.) (Ibs.) (Ibs.) Loss=Fugitive
Isohexane 1352806.09 26101.48 1326704.60 98.1
Rotocel/Recovery n-Hexane 2041.36 36.02 2005.35 98.2
Methanol 298278.74 1840.23 296438.51 99.4
Isohexane -28580.30 0.01 -28580.31 100.0
Concrete n-Hexane -24.60 0.00 -24.60 100.0
Methanol 2724.59 64.53 2660.06 97.6
Sclareolide Isohexane 71313.31 5277.18 66036.13 92.6
(S D E) n-H exa n e 46968.59 3455.78 43512.81 92.6
Sclareol Recrystallization Isohexane 12078.54 794.08 11284.46 93.4
(SFG) n-Hexane 120992.31 8269.37 112722.94 93.2
Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.com)
Sent: Monday, September 15, 2014 12:20 PM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Ok with me to add the 91bs.
Also, I will give my best estimate for fugitive vs. controlled emissions for SDE and SFG.
Thanks.
Brian
Sent from my U.S.Collulaa,Smanphone
-------- Original message --------
From: "Huddleston, Betsy"
Date:09/15/2014 12:03 PM (GMT-05:00)
To: Brian Conner
Subject: RE: Emissions Inventory Questions
Brian,
I've included a couple of quick notes below for our conversation later this week...
Betsy Huddleston,Environmental Engineer
Washington Regional Office
NC DENR,Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.ore
Betsy.Huddleston@ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
From: Brian Conner [mailto:Brian.Conner@Avocainc.com]
Sent: Saturday, September 13, 2014 9:41 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Betsy,
Below are the answers to the questions that I could handle through email:
1
1. It was diethylamine.When I copied the spread sheet to make it for diethylamine I overlooked changing it
everywhere.
2. The spreadsheet with the sage trials in the biomass boiler is attached.
3. The old original modeling calcs.showed 0.014%by weight hexane in the waste stream leaving recovery going
to waste treatment. I guess they figured not every bit of hexane was removed from the stream.The amount that
goes through is very tiny. I have just continued to use the 0.014%when doing the annual emissions calculations.
If ok with you, I'll add the 9 lbs of n-hexane emission to AFRO.
4. The spreadsheet that I keep calculates the amounts of fugitive vs. controlled emissions for the rotocel,
recovery, and concrete operations.These calcs.were based on modeling(again several years back). I am not
sure if SDE and SFG have been modeled in this way.We may need to update these(M) If necessary,you can
estimate SDE and SFG fugitive fractions. I will create new operating scenarios under each Group to enter
fugitives.
5. You are correct about the negative totals...often a campaign does not end with the month's end so at that point
in the run the recovered solvent may show more than the used.At the campaign's end,the actual final numbers
will balance out(mass balance approach) as can be seen in the following month's totals.
6. We use 3 varieties of Ethanol at Avoca depending on the product/process and extraction requirements. I
inventory each variety separately just because it makes it easier to keep up with on my end and to match up
with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs. of SDA Ethanol for a total of 8378 lbs. of
Ethanol emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs.of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment. Our bugs thrive on ethanol(in fact that is mostly
what the plant operates with) and we assume all ethanol is consumed by the bugs(happy bugs!).
I hope this helps somewhat until we can talk more next week.
Thanks,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddlestonaa ncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 lbs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenediamine. I don't think these are the same chemical,so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations,at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment(6,553lbs iso and 9.03 lbs n-hexane)?
2
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So,we need
to estimate the respective controlled vs.fugitive fractions at Rotocel/Recovery/Concrete, SDE and SFG.
5. 1 assume where there was a negative total,that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.ore
BetV.Huddleston(@-ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
3
Huddleston, Betsy
From: Huddleston, Betsy
Sent: Monday, September 15, 2014 1:00 PM
To: 'Brian Conner'
Subject: RE: Emissions Inventory Questions
I'll also need the split for Recovery, Rotocel and Concrete. I have previous notes but not sure if I'm spot on.
Betsy Huddleston, Enviromnental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.or¢
Betsy.HLiddleston@ncdenr.gov
ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
From: Brian Conner [mailto:Brian.Conner@Avocainc.com]
Sent: Monday, September 15, 2014 12:20 PM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Ok with me to add the 9 lbs.
Also, I will give my best estimate for fugitive vs. controlled emissions for SDE and SFG.
Thanks.
Brian
Sent from my IJ.S.Cellular*Smartphone
-------- Original message --------
From: "Huddleston, Betsy"
Date:09/15/2014 12:03 PM (GMT-05:00)
To: Brian Conner
Subject: RE: Emissions Inventory Questions
Brian,
I've included a couple of quick notes below for our conversation later this week...
Betsy Huddleston, Environmental Engineer
1
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.or¢
Betsy.Huddlestonaamcdenr. og_v
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
From: Brian Conner fmailto:Brian.Conner@Avocainc.com]
Sent: Saturday, September 13, 2014 9:41 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Betsy,
Below are the answers to the questions that I could handle through email:
1. It was diethylamine.When I copied the spread sheet to make it for diethylamine I overlooked changing it
everywhere.
2. The spreadsheet with the sage trials in the biomass boiler is attached.
3. The old original modeling talcs. showed 0.014%by weight hexane in the waste stream leaving recovery going
to waste treatment. I guess they figured not every bit of hexane was removed from the stream.The amount that
goes through is very tiny. I have just continued to use the 0.014%when doing the annual emissions calculations.
If ok with you, I'll add the 9 lbs of n-hexane emission to AERO.
4. The spreadsheet that I keep calculates the amounts of fugitive vs. controlled emissions for the rotocel,
recovery, and concrete operations.These talcs.were based on modeling(again several years back). I am not
sure if SDE and SFG have been modeled in this way.We may need to update these(???) If necessary,you can
estimate SDE and SFG fugitive fractions. I will create new operating scenarios under each Group to enter
fugitives.
S. You are correct about the negative totals...often a campaign does not end with the month's end so at that point
in the run the recovered solvent may show more than the used.At the campaign's end,the actual final numbers
will balance out(mass balance approach) as can be seen in the following month's totals.
6. We use 3 varieties of Ethanol at Avoca depending on the product/process and extraction requirements. I
inventory each variety separately just because it makes it easier to keep up with on my end and to match up
with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs.of SDA Ethanol for a total of 8378 lbs. of
Ethanol emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs. of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment. Our bugs thrive on ethanol(in fact that is mostly
what the plant operates with)and we assume all ethanol is consumed by the bugs(happy bugs!).
I hope this helps somewhat until we can talk more next week.
Thanks,
2
I
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddlestonCcbncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 Ibs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenediamine. I don't think these are the same chemical, so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations, at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment (6,553lbs iso and 9.03 Ibs n-hexane)?
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So, we need
to estimate the respective controlled vs. fugitive fractions at RotoceI/Re cove ry/Concrete, SDE and SFG.
5. 1 assume where there was a negative total,that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington, NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.orZ
Betsy.Huddleston(a ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
3
Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.com]
Sent: Thursday, September 18, 2014 10:29 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Hey Betsy,
Sorry for the delayed response. It has been a hectic week....
You can just count the negative#s for concrete as "0".
Concrete was ran right behind Sage and the daily inventories actually showed a gain in hexane since the rotocel was not
in use and being drained back to the storage tanks.The end inventory is the actual usage for the entire area and
captures both rotocel/recovery and concrete. I just broke out those days that concrete was operating just for record
keeping purposes.
Thanks,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [ma i Ito:betsy.huddleston(a ncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 Ibs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenedia mine. I don't think these are the same chemical, so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations, at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment (6,553lbs iso and 9.03 Ibs n-hexane)?
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So, we need
to estimate the respective controlled vs. fugitive fractions at Rotocel/Recovery/Concrete, SDE and SFG.
5. 1 assume where there was a negative total, that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
1
1
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncait.org
BetU.Huddleston(a7,ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
1
2013 Avoca, Inc. Biomass Boiler Sage Burning Log
* Annual Hexane VOC limit is 35.4 tons/year. Annual n-Hexane emission limit is 10000 lbs/year.
* This satisfies Permit No. 01819T41 condition 2.1.D.a-d.
Sage to Lbs. Sage to Daily Lbs. Daily Lbs.
Sage Infeed Lbs. Hexane/ Rolling Lbs. of
Dryer/ Dryer/ Hexane % n- n-Hexane Rolling Tons of
Date to Rotocel Lbs.Sage out n-Hexane
Biomass Biomass Emitted Hexane Emitted from VOC Emissions
(Lbs.) Desolvitizer Emissions
Boiler Boiler from Dryer Dryer
1/1/2013 0 0.00 0.000 0.00 0.00
1/2/2013 0 0.00 0.000 0.00 0.00
1/3/2013 0 0.00 0.000 0.00 0.00
1/4/2013 0 0.00 0.000 0.00 0.00
1/5/2013 0 0.00 0.000 0.00 0.00
1/6/2013 0 0.00 0.000 0.00 0.00
1/7/2013 0 0.00 0.000 0.00 0.00
1/8/2013 0 0.00 0.000 0.00 0.00
1/9/2013 0 0.00 0.000 0.00 0.00
1/10/2013 _ 0 0.00 0.000 0.00 0.00
1/11/2013 0 0.00 0.000 0.00 0.00
1/12/2013 0 0.00 0.000 0.00 0.00
1/13/2013 0 0.00 0.000 0.00 0.00
1/14/2013 0 0.00 0.000 0.00 0.00
1/1.5/2013 _ _ 0 0.00 0.000 0.00 0.00
1/16/2013 0 0.00 0.000 0.00 0.00
1/17/2013 0 0.00 0.000 0.00 0.00
1/18/2013 0 0.00 0.000 0.00 0.00
1/19/2013 0 0.00 0.000 0.00 0.00
1/20/2013 0 0.00 0.000 0.00 0.00
1/21/2013 0 0.00 0.000 0.00 0.00
1/22/2013 0 0.00 0.000 0.00 0.00
1/23/2013 0 0.00 0.000 0.00 0.00
1/24/2013 0 0.00 0.000 0.00 0.00
1/25/2013 0 0.00 0.000 0.00 0.00
1/26/2013 0 0.00 0.000 0.00 0.00
1/27/2013 0 0.00 0.000 0.00 0.00
1/28/2013 0 0.00 0.000 0.00 0.00
1/29/2013 0 0.00 0.000 0.00 0.00
1/30/2013 0 0.00 0.000 0.00 0.00
1/31/2013 0 0.00 0.000 0.00 0.00
2/1/2013 0 0.00 0.000 0.00 0.00
2/2/2013 0 0.00 0.000 0.00 0.00
2/3/2013 _ 0 0.00 0.000 0.00 0.00
2/4/2013 -- - 0 - 0.0c) - 0.000 0.00 0.00
2/5/2013 0 0.00 _ 0.000 0.00 0.00
2/6/2013 0 0.00 _ 0.000 0.00 0.00
2/7/2013 _ 0 0.00 0.000 0.00 0.00
2/8/2013 _ _ j _ _ o _ - _ 0.00 0.000 0.00 0.00
2/9/2013 _ 0 0.00 _ 0.000 0.00 0.00
2/10/2013-f _ - 0 j 0.00 0.000 0.00 0.00
- 2/11/2013 0 j C.O 0.000 0.00 _ 0.00
2/12/2013 _ __ 0 _ 0.00 0.000 0.00 0.00
2/13/2013 _ �- 0 0.00 0.000 0.00 0.00
2/14/2013 0 0.00 0.000 0.00 0.00
2/15/2013 0 _ _O.CO 0.000 0.00 0.00
2/16/2013 j 0.00 0.000 0.00 0.00
2!17/2013 _ _ 0 0.00 0.000 0.00 _0.Co -
2/18/2013�-_- o ---Y_� 0.00 _- 0.000 0.00 0.00
2/1-9/2013 _- _ 0 0.00 0.000 0.00 0.00
I 2/20/2013 - - 0 - 0.00 0.000 0.00 O.00
2/21/2013 -j 0 __ j 0.00 -�_ 0.000 0.00 0_00
- 2/22/2013 i o 0.00 0.000 0.00 o.oc
2!23/2053 ------ 0 G.GO_ - -_ -- 0_000-- I- O.Co- --- O.Ocl --�
2/24/2013 -- 0 I - O.Oo 0.000 - 0.00 0.00
2/25/2013 _ 0 0.00 0.000 0.00 0.00
0.000 0.00 0.00
2/27/2013 0 0.01- 0.000 0.00 0.0000
2/28/2013 0 0.00 0.000 0.00 0.00 _
3/1/2013 _ 0 0.00 i _ 0.000 0.00 0.00
3/2/2013 0 0.00 0.000 0.00 0.00
3/3/2013 0 0.00 0.000 0.00 0.0_0
3/4/2013 - I _ 0 _0.00 0.000 0.00 0.00
3/5/2013 - 0 _0.00 0.000 0.00 _0.00 -
1 3/6/2013 0 - _0.00 0-000 0.00 _0_00
3/7/2013 _ 0 0.00 I 0.000 0.00 0.00
3/8/2013 0 0.00 0.000 0.00 0.00
3/9/2013 0 0.00 0.000 0.00 0.00
3/10/2013 0 0.00 0.000 0.00 0.00
3/11/2013 0 0.00 0.000 0.00 0.00
3/12/2013 0 0.00 0.000 0.00 0.00
3/13/2013 0 0.00 0.000 0.00 0.00
3/14/2013 0 0.00 0.000 0.00 0.00
3/15/2013 0 0.00 0,000 0.00 0.00
3/16/2013 0 0.00 0.000 0.00 0.00
3/17/2013 0 0.00 0.000 0.00 0.00
3/18/2013 0 0.00 0.000 0.00 0.00
3/19/2013 0 0.00 0.000 0.00 0.00
3/20/2013 0 0.00 0.000 0.00 0.00
3/21/2013 0 0.00 0.000 0.00 0.00
3/22/2013 0 0.00 0.000 0.00 0.00
3/23/2013 0 0.00 0.000 0.00 0.00
3/24/2013 0 0.00 0.000 0.00 0.00
3/25/2013 0 0.00 0.000 0.00 0.00
3/26/2013 0 0.00 0.000 0.00 0.00
3/27/2013 0 0.00 0.000 0.00 0.00
3/28/2013 0 0.00 0.000 0.00 0.00 _.
3/29/2013 0 0.00 0.000 0.00 0.00
3/30/2013 0 0.00 0.000 0.00 0.00 :
3/31/2013 0 0.00 0.000 0.00 0.00
4/1/2013 0 0.00 0.000 0.00 0.00
4/2/2013 0 0.00 0.000 0.00 0.00
4/3/2013 0 0.00 0.000 0.00 QI,QQ
4/4/2013 0 0.00 0.000 0.00 0.00
4/5/2013 0 0.00 0.000 0.00 0.00
4/6/2013 0 0.00 0.000 0.00 0.00
4/7/2013 0 0.00 0.000 0.00 0.00
4/8/2013 0 0.00 0.000 0.00 0.00
4/9/2013 0 0.00 0.000 0.00 0.00
4/10/2013 0 0.00 0.000 0.00 0.00
4/11/2013 0 0.00 0.000 0.00 0.00
4/12/2013 0 0.00 0.000 0.00 0.00
4/13/2013 0 0.00 0.000 0.00 0.00
4/14/2013 0 0.00 0.000 0.00 0.00
4/15/2013 0 0.00 0.000 0.00 0.00
4/16/2013 0 0.00 0.000 0.00 0.00
4/17/2013 0 0.00 0.000 0.00 0.00
4/18/2013 0 0.00 0.000 1 0.00 0.00
4/19/2013 0 0.00 0.000 0.00 0.00
4/20/2013 0 0.00 0.000 0.00 0.00
4/21/2013 0 0.00 0.000 0.00 0.00
4/22/2013 0 0.00 0.000 0.00 0.00
4/23/2013 0 0.00 0.000 0.00 0.00
4/24/2013 0 0.00 0.000 0.00 0.00
4/25/2013 0 0.00 0.000 0.00 0.00
4/26/2013 0 _ 0.00 0.000 0.00 0.00
4/27/2013 0 0.00 0.000 0.00 0.00
4/28/2013 0 0.00 0.000 0.00 0.00
4/29/2013 0 0.00 0.000 0.00 0.00
4/30/2013 0 0.00 0.000 0.00 0.00
5/l/2013 0 0.00 0.000 0.00 0.00
5/2/2013 0 0.00 0.000 0.00 0.00
5/3/2013 0 0.00 0.000 0.00 0.00
5/4/2013 0 0.00 0.000 0.00 0.00
5/5/2013 0 0.00 0.000 0.00 0.00
5/6/2013 0 0.00 0.000 0.00 0.00
5/7/2013 0 0.00 0.000 0.00 0.00
_5/8/2013 0 0.00 0.000 0.00 0.00
5/9/2013 0 0.00 0.000 0.00 0.00
5/10/2013 0 0.00 0.000 0.00 0.00
5/11/2013 0 0.00 0.000 0.00 0.00
5/12/2013 _ _ 0 0.00 0.000 0.00 _0.00 _
5/13/2013 0 0.00 0.000 0.00 0.00
5/14/2013 _ 0 0.00 0.000 0.00 0.00
5/15/2013 0 0.00 0.000 0.00 0.00
5/16/2013 0 0.00 0.000 0.00 0.00
5/17/2013 0 0.00 0.000 0.00 0.00
5/18/2013 0 0.00 0.000 0.00 0.00
5/19/2013 0 0.00 0.000 0.00 0.00
5/20/2013 0 0.00 0.000 0.00 0.00
5/21/2013 0 0.00 0.000 0.00 0.00
5/22/2013 0 0.00 0.000 0.00 0.00
5/23/2013 0 0.00 0.000 0.00 0.00
5/24/2013 0 0.00 0.000 0.00 0.00
5/25/2013 0 0.00 0.000 0.00 0.00
5/26/2013 0 0.00 0.000 0.00 0.00
5/27/2013 0 0.00 0.000 0.00 0.00
5/28/2013 0 0.00 0.000 0.00 0.00
5/29/2013 0 0.00 0.105 0.000 0.00 0.00
5/30/2013 0 0.00 0.105 0.000 0.00 0.00
5/31/2013 0 0.00 0.112 0.000 0.00 0.00
6/1/2013 0 0.00 0.112 0.000 0.00 0.00
6/2/2013 0 0.00 0.112 0.000 0.00 0.00
6/3/2013 0 0.00 0.112 0.000 0.00 0.00
6/4/2013 0 0.00 0.112 0.000 0.00 0.00
6/5/2013 0 0.00 0.112 0.000 0.00 0.00
6/6/2013 0 0.00 0.112 0.000 0.00 0.00
6/7/2G13 0 0.00 0.118 0.000 0.00 0.00
6/8/2013 0 0.00 0.118 0.000 0.00 0.00
6/9/2013 0 0.00 0.118 0.000 0.00 0.00
6/10/2013 0 0.00 0.118 0.000 0.00 0.00
6/11/2013 0 0.00 0.118 0.000 0.00 0.00
6/12/2013 0 0.00 0.118 0.000 0.00 0.00
6/13/2013 0 0.00 0.118 0.000 0.00 0.00
6/14/2013 0 0.00 0.122 0.000 0.00 0.00
6/15/2013 0 0.00 0.122 0.000 0.00 0.00
6/16/2013 0 0.00 0.122 0.000 0.00 0.00
6/17/2013 0 0.00 0.122 0.000 0.00 0.00
6/18/2013 0 0.00 0.122 0.000 0.00 0.00
6/19/2013 0 0.00 0.122 0.000 0.00 0.00
6/20/2013 0 0.00 0.122 0.000 0.00 Q.00
6/21/2013 0 0.0.0 0.118 0.000 0.00 0.00
6/22/2013 0 0.00 0.118 0.000 0.00 0.00
6/23/2013 0 0.00 0.118 0.000 0.00 0.00
6/24/2013 0 0.00 0.118 0.000 0.00 0.00
6/25/2013 0 0.00 0.118 0,000 0.00 0.00
6/26/2013 0 0.00 0.118 0.000 0.00 0.00
6/27/2013 0 0.00 0.118 0.000 0.00 0.00
6/28/2013 0 0.00 0.114 0.000 0.00 0.00
6/29/2013 0 0.00 0.114 0.000 0.00 0.00
6/30/2013 0 0.00- 0.114 0.000 0.00 0.00
7/1/2013 0 0.00 0.114 0.000 0.00 0.00
7/2/2013 0 0.00 0.114 0.000 0.00 0.00
7/3/2013 0 0.00 0.114 0.000 0.00 0.00
7/4/2013 0 0.00 0.114 0.000 0.00 0.00
7/5/2013 0 0.00 0.114 0.000 0.00 0.00
7/6/2013 0 0.00 0.114 0.000 0.00 0.00
7/7/2013 0 0.00 0.114 0.000 0.00 0.00
7/8/2013 0 0.00 0.114 0.000 0.00 0.00
7/9/2013 0 0.00 0.114 0.000 0.00 0.00
7/10/2013 1 213060 40% 85224 0.001129 96.23 0.114 0.110 0.05 0.11
7/11/2013 216100 50% 108050 0.001129 122.01 0.114 0.139 0.11 0.25
7/12/2013 9100 50% 4550 0.001129 5.14 0.114 0.006 0.11 0.25
7/13/2013 0 0.00 0.114 0.000 0.11 0.2.5
7/14/2013 573500 50% 286750 0.001129 323.80 0.114 0.369 0.27 0.62
7/15/2013 0 0.00 0.114 0.000 0.27 0.62
7/16/2013 0 0.00 0.114 0.000 0.27 O.G2
7/17/2013 0 0.00 0.114 0.000 0.27 0.52
7/18/2013 0 0.00 0.114 0.000 0.27 0.62
7/19/2013 0 0.00 0.111 0.000 0.27 0.62
7/20/2013 0 0.00 0.111 0.000 0.27 0.62
7/21/2013 0 0.00 0.111 0.000 0.27 0.62
7/22/2013 0 0.00 O.ill 0.000 0.27 0.62
7/23/2013 0 0.00 0.111 0.000 0.27 0.62
7/24/2013 0 0.00 0.111 0.000 0.27 0.62
7/25/2013 0 0.00 0.111 0.000 0.27 0.62
7/26/2013 0 0.00 0.108 0.000 0.27 0.62
7/27/2013 0 0.00 0.108 0.000 0.27 0.62
7/28/2013 0 0.00 0.108 0.000 0.27 0.62
7/29/2013 _ 0 _ _ 0.00 0.108 0.000 0.27 0.62
7/30/2013 0 0.00 0.108 0.000 0.27 0.62
7/31/2013 0 0.00 0.108 0.000 0.27 0.62
8/1/2013 0 1 0.00 0.106 1 0.000 0.27 0.62
8/2/2013 _0 0.00 0.106 0.000 0.27 0.62
8/3/2013 0 0.00 0.106 0.000 0.27 0.62
8/4/2013 0 0.00 0.106 0.000 0.27 0.62
8/5/2013 0 0.00_ 0.106 0.000 0.27 0.62
8/6/2013 0 0.00 0.106 0.000 0.27 0.62
8/7/2013 0 0.00 0.106 0.000 0.27 0.62
8/8/2013 0 0.00 0.106 0.000 0.27 0.62
8/9/2013 0 0.00 0.118 0.000 0.27 0.62
8/10/2013 0 0.00 0.118 0.000 0.27 0.62
8/11/2013 0 0.00 0.118 0.000 0.27 0.62
8/12/2013 0 1 0.00 0.118 0.000 0.27 0.62
8/13/2013 556580 30% 166974 0.001422 237.44 0.118 0.280 0.39 0.90
8/14/2013 408960 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/15/2013 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/16/2013 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/17/2013 189420 40% 75768 0.001422 107.74 0.128 0.138 0.45 1.04
8/18/2013 270860 40% 108344 0.001422 154.07 0.128 0.197 0.52 1.24
8/19/2013 598940 40% 239576 0.001422 340.68 0.128 0.436 0.69 1.68
8/20/2013 491100 30% 147330 0.001422 209.50 0.128 0.268 0.80 1.94
8/21/2013 570420 30% 171126 0.001422 243.34 0.128 0.311 0.92 2.25
8/22/2013 0 0.001422 0.00 0.128 0.000 0.92 2.25
8/23/2013 0 0.001422 0.00 0.137 0.000 0.92 2.25
8/24/2013 593294 20% 118658.8 0.001422 168.73 0.137 0.231 1.00 2.49
8/25/2013 425380 20% 85076 0.001422 120.98 0.137 0.166 1.06 2.65
8/26/2013 506120 25% 126530 0.001422 179.93 0.137 0.246 1.15 2.90
8/27/2013 447240 25% 111810 0.001422 158.99 0.137 0.218 1.23 3.12
8/28/2013 0 0.001422 0.00 0.137 0.000 1.23 3.12
8/29/2013 0 0.001422 0.00 0.137 1 0.000 1.23 3.12
8/30/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
8/31/2013 0 0.0014.22 0.00 0.156 0.000 1.23 3.12
9/l/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/2/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/3/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/4/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/5/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/6/2013 417000 15% 62550 0.001422 88.95 0.171 0.152 1.28 3.,27
9/7/2013 412460 35% 144361 0.001422 205.28 0.171 0.351 1.38 3.62
9/8/2013 321340 35% 112469 0.001422 159.93 0.171 0.273 1.46 3.89
9/9/2013 326300 35% 114205 0.001422 162.40 0.171 0.278 1.54 4.17
9/10/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/11/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/12/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/13/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/14/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/15/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/16/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/17/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/18/2013 394900 10% 39490 0.001422 56.15 0.184 0.103 1.57 4.27
9/19/2013 507980 35% 177793 0.001422 252.82 0.184 0.465 1.70 4.74
9/20/2013 458990 35% 160646.5 0.001422 228.44 0.184 0.420 1.81 5.16
9/21/2013 352160 35% 123256 0.001422 175.27 0.184 0.322 1.90 5.48
9/22/2013 444000 35% 155400 0.001422 220.98 0.184 0.407 2.01 5.89
9/23/2013 498920 35% 174622 0.001422 248.31 0.184 0.457 2.13 6.35
9/24/2013 502100 35% 175735 0.001422 249.90 0.184 0.460 2.26 6.80
9/25/2013 240740 35% 84259 0.001422 119.82 0.184 0.220 2.32 7.03
9/26/2013 0 0.00 0.000 2.32 7.03
9/27/2013 0 0.00 0.000 2.32 7.03
9/28/2013 0 0.00 0.000 2.32 7.03
9/29/2013 0 0.00 0.000 2.32 7.03
9/30/2013 0 0.00 0.000 _ 2.32 7.03
10/l/2013 0 0.00 0.000 2.32 7.03
10/2/2013 0 0.00 0.000 2.32 7.03
10/3/2013 0 0.00 0.000 2.32 7.03
10/4/2013 0 0.00 0.000 2.32 7.03
10/5/2013 0 0.00 0.000 2.32 7.03
10/6/2013 0 0.00 0.000 2.32 7.03
10/7/2013 0 0.00 0.000 2.32 7.03
10/8/2013 0 0.00 0.000 2.32 7.03
10/9/2013 0 0.00 0.000 2.32 7.03
10/10/2013 0 0.00 0.000 2.32 7.03
10/11/2013 0 0.00 0.000 2.32 7.03
10/12/2013 0 0.00 0.000 2.32 7.03
10/13/2013 0 0.00 0.000 2.32 7.03
10/14/2013 - I 0 0.00 0.000 2.32 7.03
10/15/2013 0 0.00 0.000 2.32 7.03
10/16/2013 0 0.00 0.000 2.32 7.03
10/17/2013 0 0.00 0.000 2.32 7.03
10/18/2013 0 0.00 0.000 2.32 7.03
10/19/2013 0 0.00 0.000 2.32 7.03
10/20/2013 0 0.00 0.000 2.32 7.03
10/21/2013 0 0.00 0.000 2.32 7.03
10/22/2013 0 0.00 0.000 2.32 7.03
10/23/2013 0 0.00 0.000 2.32 7.03
10/24/2013 0 0.00 0.000 2.32 7.03
10/25/2013 0 0.00 0.000 2.32 7.03
10/26/2013 0 0.00 0.000 2.32 7.03
10/27/2013 0 0.00 0.000 2.32 7.03
10/28/2013 0 0.00 0.000 2.32 7.03
10/29/2013 0 0.00 0.000 2.32 7.03
10/30/2013 0 0.00 0.000 2.32 7.03
Eo'L ZE'z 0000 00 O O £10Z/8/ZT
EO'L ZE'z 000 0 00 0 0 ETOZ/L/zT
EO'L z£ Z 000,0 00,0 0 EToz/9/zT
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Eo'L ZE'Z 000,0 OO O 0 EToz/E/ZT
EO'L H'z 000,0 00,0 0 ETOZ/Z/ZT
Eo L z£,z 0000 00 0 0 EToz/T/zT
EO'L ZE'Z 000'0 OO"O 0 £TOZ/0£/TT
EO'L zE'z 000,0 00*0 0 EToz/6z/T1
Eo'L H'z 000,0 00,0 O EToz/8Z/TT
EO'L U'z 0000 00'o 0 EToz/LZ/TT
EO'L ZE'Z 000,0 00,0 0 ETOZ/9Z/TT
EO'L z£'z 000,0 00,0 O EToz/sZ/TT
£O'L ZE'Z 000,0 00 0 0 EToz/vZ/TT
EO'L ZE'Z 000,0 00,0 0 ETOZ/£z/TT
Eo'L ZE'z 000'0 00,0 0 EToz/zz/TT
EO'L Z£z 000,0 00,0 0 EToz/TZ/TT
ML ZE'Z 000,0 00 0 0 ETOZ/OZ/TT
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EO L ZE'Z 0000 00,0 0 EToz/91/TT
£o'L Z£'Z 000'0 00,0 0 ETOz/sT/TT
£O'L ZE'Z 000,0 00,0 0 EToz/bT/TT
EO'L z£z 000,0 00'0 0 EToz/ET/TT
£0'L ZE Z 000 0 00,0 0 ETOZ/ZT/TT
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EO'L ZE z 000,0 00,0 0 EToz/9/11
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SZO'L 61S'ST ZS'9£97 S780L90'0 E-ESS09EE %S99 ti969760T lejol
6L'0 610'0 SZE6ZT'0 OL'ZT 9L6ET00'0 7ES66'9OZ6 %EE TTT'£77807 GSeaany,
Eo'L H 7 000'0 00'0 0 EToz/TE/zT
Eo'L ZE'Z 000"o 00,0 0 ETWOE/ZT
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EO'L ZE'Z 000'0 00,0 0 EToz/9Z/ZT
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EO'L N7 000,0 00'0 0 _ EToz/Tz/zT
ML ZE"Z 000,0 00"o 0 EToz/oz/zT
EO'L ZE'Z 000'0 00'0 0 ETOZ/6T/ZT
EO'L ZE'Z 000"o 00,0 0 EToz/ST/zT
EO'L ZEz 000,0 00'0 0 EToz/LT/zT
EO'L ZE'Z 000'0 00'0 0 ETOZ/91/ZT
EO'L ZE'Z 000'0 00,0 0 EToz/ST/ZT
E01 ZE'Z 000"0 00'0 0 ETOZ/7T/ZT
ML ZE'Z 000,0 00'0 0 EToz/ET/ZT
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EO'L ZE'Z 000'0 00'0 0 ETOZ/TT/ZT
EO'L ZE'Z 000'0 00'0 0 EToz/01/ZT
EO'L ZE'Z 000-0 00'0 0 EToz/6/zT
Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.coml
Sent: Wednesday, May 07, 2014 9:47 AM
To: Huddleston, Betsy
Subject: RE: Engine El04 stack data
Betsy,
The best data that I can find from the CAT spec sheets is:
Velocity= 2050 cfm
Temp. = 1000 OF
Hope this helps.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [ma i Ito:betsy.huddleston@ncdenr.gov]
Sent: Monday, May 05, 2014 4:25 PM
To: Brian Conner
Subject: Engine E104 stack data
Hi Brian,
Do have any stack data for engine E104? I have added to the group of engines in AERC, but need to add a stack for it
(height, diameter,temp,velocity/acfm).
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 2527948-3836
Fax: 252-975-3716
www.ncair.ora
Betsy.HuddIestoii@ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
1
RE: Engine E104 stack data Page 1 of 1
RE: Engine E104 stack data
Brian Conner [Brian.Conner@Avocainc.com]
Sent:Tuesday,May 06,2014 10:09 AM
To: Huddleston,Betsy
Betsy,
This is what I have:
Generator E104 is located directly beside E102.They use the same fuel tank.
The stack height is 11 ft., and it is a horizontal stack.
The diameter is 8 inches.
It is 534 BHP/401 HP.
I am trying to find data on stack temp. and velocity.
I will get that to you as soon as I get it from Gregory Poole.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddleston@ncdenr.gov]
Sent: Monday, May 05, 2014 4:25 PM
To: Brian Conner
Subject: Engine E104 stack data
Hi Brian,
Do have any stack data for engine E104? I have added to the group of engines in AERO, but need to add a stack
for it(height, diameter,temp,velocity/acfm).
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR,Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.org
Betsy.Huddleston@ncdenr.gov
************************************************************************
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
https://mail.nc.gov/owa/?ae=Item&t=IPM.Note&id=RgAAAAAsvlGQkJp3Tq WuCPA29r8... 5/6/2014
M
o�m
Page 1of2 7 l,d ",,)bU 112r1SOOybV1
Diu eM4 90/q k6�CN)
Annual Air Emissions Inventory l Chun ��L,3,//�M �n/isje�
Facility ID#:0800044
Boilers : OS-1 Cm'a5'"°� AF" IS AY��/i-tr
Year: 2013 Unre",hod iro t2v DAQ
Total Run Time: 8882.8 Hrs/Yr /00/7(y
Efficiency: 85 %,
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 17578.3 34313.6 6023.6 57915.5 491.7 1422.4 197.6 2111.7 0.032 11.583
February: 3844.7 16471.5 2594.9 22911.1 188.2 139.3 124.2 451.7 0.013 4.582
March: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.000 0.000
April: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0,000 0,000
May: 0.0 1 14269.3 4697.0 18966.3 0.0 55.8 170.3 226.1 0.011 3,793
June: 3261.6 5.0 254.4 3521.0 119.0 114.8 10.6 244.4 0.002 0.704
July: 3449.9 9363.9 15.2 12829.0 96.5 103.7 10.5 210.7 0.007 2.566
August: 15629.9 37425.2 1975.4 55030.5 437.2 379.6 48.6 865.4 0.031 11.006
September: 24681.8 52129.7 9465.0 86276.5 690.4 0.0 252.4 942.8 0.048 17.255
October: 23055.2 31918.0 241.8 55215.0 644.9 457.1 40.3 1142.3 0.031 11.043
November: 21803.9 25135.6 912.4 47851.9 609.9 505.8 55.3 1171.0 0.027 9.570
December: 25890.2 52719.2 3054.2 81663.6 724.2 582.1 210.4 1516.7 0.046 16.333
Total: 139195.5 273751.0 29233.9 442180.4 4002.0 3760.E 1120.2 8882.8 0.248 88.436
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 34.8 4002.0 139195.5
2 H-102 143 72.8 3760.6 273751.0
a
3 H-103 180 26.1 1120.2 29233.9
Total 466 133.67302 8882.8 442180.4
r�
aS�r
Criteria Pollutants E T
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total C�rf e n SA
Pollutants Lbs./1000 al. Tons/Yr TonsNr TonsNr TonsNr fr 14e,o..6l�
TSP 3.3 2,00 0.7 �, 0,139 0.274 0.029 0.442
PM-10 1.00 0.070 0.137 0.015 0.221
PM-2.5 0,25 0.017 0,034 0.004 0.055 0 hl 4 � )Li s y,y3�r s
Sox 42,60 2.965 5,831 0.623 9.418 S L/$ 9
Nox 24,00 (2o,") 1.670 3.285 0.351 5.306
VOC 0.20 0.014 0.027 0.003 0.044
CO 5.00 0.348 0.684 0.073 1.105
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.078 0.153 0.016 0.248
Benzene 2.75E-03 0.383 0,753 0.080 1.216
Beryllium 4.20E-04 0.058 0.115 0.012 0.186
Cadmium 4.20E-04 0.058 0,115 0.012 0.186
-Ghromm 4.20E-04 0.058 0.115 0.012 0,186 Ch,,omlc aGd 0119
Cl.,un\t ChromwpaVl 0.004 0.008 0.001 0.013
Jua Ethyl benzene 8.17E-04 0.114 0.224 0.024 0.361
Flouride 3.73E-02 5.192 10.211 1.090 16.493
Formaldehyde 4.80E-02 6.681 13.140 1,403 21.225
Lead 1.26E-03 0.175 0.345 0.037 0,557
Manganese 8.40E-04 0.117 0.230 0.025 •0.371
Me rcu 4.20E-04 0.058 0,115 0.012 0.186
Na thalene 3.30E-04 0.046 0.090 0.010 0.146
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Page 2 of 2
Annual Air Emissions Inventor
y
Facility ID#:0800044
Boilers : OS-1
Nickel 4.20E-04 0.058 0.115 0.012 0.186 S��r nl VY✓` 0 9 3
Toluene 7.97E-02 1 11.094 21.818 1 2.330 35.242 1.5
o-X lene 1.40E-03 1 0.195 0.383 1 0.041 0.619 1
nit /
Gt�ID✓Ore err Or'
Green House Gas Pulutants
�tv)
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor (lbs/hr) (Ibslhr) (Ibslhr) (tonslyr) (tonslyr) (tonslyr) (tons/yr)
(lbs/1000 gal)
CO2 22700.00 789.54 1652.44 592.40 1579.87 3107.07 331.80 5018.75 y974.Q �pQ Swt}
Methane 0.06 0.0021 0.0044 0.0016 0.0042 0.0082 0.0009 0.0133 0.2 �SQaO! 1
(CH4)
Nitrous Oxide 0.12 0.0042 0.0087 0.0031 0.0084 0.0164 0.0018 0.0265 Q O Y
(N20)
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Page 1 or 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year.
Total Run Time: 200.1 HrsNr
Efficiency: 0. % /GS /J 1nwWu \
Sulfur Content 0 3 % ( J
Number 2 Fuel: 141000 BtulGal D' t 1U
(q/
Fuel Usage(gallons) VOC /VOX Con t �'^ �,
/�/
Month E101 E102 E103 E104 Total (Lbs.) I e 1'
January: 397.5 662.5 530.0 530.0 2120.0 110.4 G l e oktw
February: 30.0 50.0 40.0 120.0 6.2
March: 30.0 50.0 40.0 40.0 160.0 8.3
April: 30.0 50.0 40.0 40.0 160.0 8.3
May: 33.8 45.0 45.0 45.0 168.8 8.8
June: 37.5 75.0 50.0 50.0 212.5 1 11.1
July: 30.0 50.0 31.0 40.0 161.0 7.9
Au ust: 37.5 62.5 50.0 50.0 200.0 10.4
Se tember: 30.0 50.0 40.0 40.0 160.0 8.3
October: 30.0 50.0 40.0 40.0 160.0 8.3
November: 30.0 50.0 40.0 40.0 160.0 8.3
December. 45.0 75.0 50.0 60.0 230.0 12.0
Total: 761.3 1270.0 1 996.0 1 975.0 4002.3 208.4
Heat Rate
Generator No. ID# I Bho I ho I HrlYr GalsIHr I GalslYr MM BhilHr MM BWNr
1 E101 1 587 1 440 1 50.8 15.0 761.3 2.12 107.34
2 E102 760 570 50.8 25.0 1270.0 3.53 179.07
3 E103 603 452 49.8 20.0 996.0 2.82 140.44
4 E104 1 534 1 401 1 48.8 20.0 975.0 2.82 137.48
Total 2484 1 1863 1 200 80 4002.3 11 564
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4kO.0028
Pollutants (LbIMM BTU) (TonslYr) (TonslYr) (TonslYr) (TonsNr)
TSP 0.100 0.005 0.009 0.007 0.007 PM-10 0.100 0.005 0.009 0.007 0.007PM-2.5 0.100 0.005 0.009 0.007 0.007Sox 0.141 0.008 0.013 0.010 0.010N0x . 0.320 0:017 0.028 0.022 0.0224 A
VOC i 0.360 0.019 0.032 0.025 0.025 0.102 8,(r,3
CO 0.850 0.046 0.076 1 0.060 1 0.058 1 0.240
HazardouslToxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Air Pollutants (LbIMM BTU) (LbaNr) (LbsNr) (LbsNr) (LbslYr) (LbslYr)
Acetaldeh de 2.52E-05 0.002705 0.004513 0.003539 0.003464 0.014
Acrolein 7.88E-06 0.000846 0.001411 0.001107 0.001083 0.004
Arsenic nl 4.00E-06 0.000429 0.000716 0.000562 0.000550 0.002
Benzene 7.76E-04 0.083298 0.138958 0.108978 0.106681 - .438 ^/_✓0�7I1 �G/ 0,001
Benzo a rene 2.57E-07 0.000028 0.000046 0.000036 0.000035 0.000
Beryllium M,AAZ 3.00E-06 0.000322 0.000537 0.000421 0.000412 1'0.002
Cadmium 4J 3.00E-06 0.000322 0.000537 0.000421 0.000412 -0.002 leu d O,OU-5
For raideh de 7.89E-05 0.008469 0.014129 0.011080 0.010847 -10.045 0,00 y
Ne halene 1.30E-04 0.013955 0.023279 0.018257 0.017872 - .0.073 MG^'ls U/r't#�
Toluene 2.81E-04 0.030163 0.050319 0.039463 0.038630 0.159 IhU Q Z
X lene 1.93E-04 0.020717 0.034561 0.027104 0.026533 0.109
�/JI c O,CCJ 2 nlcf'i
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
LbIMM BTU tons r tons r tons r tons tons r
CO, 43.990 2.3610 3.9386 3.0889 3.0238 12.41
Methane 0.009 0.0005 0.0008 0.0006 0.0006 0.00254
(CHd)
Nitrous Oxide 0.001 0.0001 0.0001 0.0001 0.0001 0.000282
(Nz0)
HAEnvironmentalkAir PennBWir ReponsxAnnual Air Emissions Inventory\2013 Report\2013 AAE Calc Page 1
Qa►, A in 2W3
Annual Air Emissions Inventory
Facility ID#:0800044
PK- Generator : OS-12
Year: 2013
Total Run Time: 132.8 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0_3 %
Number 2 Fuel: 141000 Btu/Gal
Emisson tFactor
Hazardous/
Fuel Usage Hours VOC Criteria Factor Pk-Gen -GenMonth Pollutants (Lb/MM (Tons/Yr) Toxic Air s/Yr)(gallons) Operated (Lbs.) BTU PollutantsTSP 0.1 0.0674 Acetaldeh de0340Janua : 2160 30 112.49 PM-10 0.1 0.0674 Acrolein 0106Februa : 0.0 0.0 0.00 PM-2.5 0.1 0.0674 Arsenic 0054
March: 144.0 2.0 7.50 315) Sox 1 0.141 d•2 0.0950 Benzene 7.76E-04 1.0458
April: 756.0 10.5 39.37 Nox 3.2 2.1563 Benzo a rene 2.57E-07 0.0003
May: 162.0 2.3 8.44 a9tb' VOC 0.36 o,ol. 0.2426 Be Ilium 3.00E-06 0.0040
June: 1836.0 25.5 95.62 �' CO 0.85 0.5728 Cadmium 3.00E-06 0.0040
Jul 1080.0 15.0 56.25 Formaldeh de 7.89E-OS 0.1063
August: 1656.0 23.0 86.24 Na thalene 1.30E-04 0.1752
September: 828.0 11.5 43.12 Toluene 2.81E-04 0.3787
October: 180.0 2.5 9.37 X lene 1.93E-04 0.2601
November: 144.0 2.0 7.50
December: 612.0 8.5 31.87 i1,1s j<AP 42 -+ hp f��).'�Q �O 'r PPS �� y�l 56 M15)s
Total: 9558.0 1 132.8 497.8 Heat Rate G vt y (,4y)gwA�l"e V
Generator No. ID# Bhp ho Hr/Yr Gals/Hr GalsNr MM Btu/Hr MM Btu/Yr
Pk-Gen Pk-Gen 2670 1 2003 1 132.8 72.0 1 9558.0 1 10.15 1347.68
Green House Gas Pulutants for Peak Generator cA.um 1( QGI d ljj oO 4
GHG Pollutant Emisson Factor Ibs/yr tons/yr L?QoL Oi O f
(Lb/MM BTU)
44 43.990 59284.36 29.64
Methane 0.009 12.13 0.0061 Oil 7
(CH4)
Nitrous Oxide 0.007 9.43 0.00472 /V(444X
(N20)
Annual Air Emissions Inventory y2
Facility ID#:0800044
Fire Pumps ,�✓o
Data used for inventory only! p
Year: 2013 1 G J ecQ 4kv �J
Total Run Time: 38.5 HrslYr tO(� may)/55/07)5
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC
Month Fuel Operated hour (lbs.)
Used
January: 540.0 27.0 20.0 28.123
February: 40.0 2.0 20.0 2.083
March: 50.0 2.5 20.0 2.604
April: 10.0 0.5 20.0 0.521
May: 0.0 0.0 #DIV/0! 0.000
June: 0.0 0.0 #DIV/0! 0.000
July: 40.0 2.0 20.0 2.083
August: 50.0 2.5 20.0 2.604
September: 30.0 1.5 20.0 1.562
October: 10.0 0.5 20.0 0.521
November: 0.0 0.0 #DIV/0! 0.000
December: 0.0 0.0 #DIV/0! 0.000
Total: 770.0 38.5 20.0 40.1
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 285 214 38.5 20.0 1 770.0 2.82 108.57
Criteria Emisson Factor (Lb/MM FP
Pollutants BTU) (Tons/Yr
TSP 0.31 0.017
PM-10 0.31 '0.017 A"-"L-
PM-2.5 0.31 0.017
Sox 0.152 '0.008
Nox 4.41 0.239 Od
VOC 0.36 'O.020 0.0/
CO 0.95 /0.052 0,04 Green House Gases
GHG Emisson Factor E101
Hazardous/Toxi Emisson Factor (LbIMM FP Pollutant K IMM BTU tons/ r
c Air Pollutants BTU) (Lbs/Yr) COz 73.960 8.853
Acetaldehyde 7.67E-04 -0.083 Methane 0.003 0.000359
Nitrous
Acrolein 9.25E-05 0.010 AQ Oxide 0.0006 0.000072
D (NZO)
Arsenic 4.00E-06 0.0004 1
Benzene 9.33E-04 ' 0.101
Benzo a rene 1.88E-07 0.00002
Beryllium 3.00E-06 0.0003 M�"4-7 Z, 3E'4
Cadmium 3.00E-06 '0.0003
Formaldehyde 1.18E-03 0.128 ( L¢.R.0 qC--
Na thalene 8.48E-05 - 0.009
Toluene 4.09E-04 0.044 C/rromlr au
X lene 2.85E-04 0.031
h/c!� Z. 3E -v
Criteria Pollutants Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler
Pollutants (Lb/MM BTU) (TonsNr) Pollutants (Lb/MM BTU) (LbsNr)
TSP 0.0014 0.122 Acetaldehyde 8.30E-04 144.613
PM-10 0.0014 0.122 Acrolein 4.00E-03 696.928
PM-2.5 0.0014 0.122 Benzene 4.20E-03 731.774
Sox 0.03 2.178 Benzo a rene 2.60E-06 0.453
Nox 0.22 /19.166 Carbon
, 4.50E-05 7.840
tetrachloride
VOC 0.02 1.481r r Chlorine 7.90E-04 137.643 / OrH
CO 0.19 16.726 FUG" ,Awes Chlorobenzene 3.30E-05 ' 5.750 2,°�6'S (�l
p� Chloroform 2.80E-05 4.878
POT Ethyl benzene 3.10E-05 5.401
Green House Gas Pulutants Formaldehyde 4.40E-03 766.621 �/h con CI
Emisson Factor E101 ST✓
GHG Pollutant Lb/MM BTU tons/ r Napthalene 9.70E-05 16.901
CO2 195.000 16987.6 Phenol 5.10E-05 8.886
Methane 0.021 1.8 Propionaldehyde 6.10E-05 10.628
(CH4)
Nitrous Oxide 0.013 1.1 Styrene 1.90E-03 331.041
(N20)
Toluene 9.20E-04 160.293
X lene 2.50E-05 4. 56
/rok,11 broo„de, 4v�,-dm�V641dY' a,4er7/c 3.83 fTW4hyl CAI0TQfor^` S; ya
ISC-5 1b1(rm V14 DAG Spra4S6d &ry/hrm 0,19 PWn 21, 76
z ( 4bS Cpdm/rr» 0. 7I
rr �r td e (� sP Ch,,omr Acid 0,b )
]4 rnr IWV 7E�S 1b/Mrr�V LPG Of 9.34
2-3 F -5 �
9, 70ibs 2- 70. 77
y,o rbs
z,�E -y Ibrrn�r iv,�a s, �5
So,s Ibs
Annual Air Emissions inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2: OS-33
Fuel Source : Wood Chips
Year: 2013
Total Run Time: 8114.0 HrsNr
Wood Chips 994000 BTU/ton
'Emission Factors determined by Emissions test conducted on 1 2/1 912 01 3
Boiler Operation (Hours) Wood Chips Burned(Tons) CO PM HCL Hoc Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Hours Chips
j January: 552.0 552.0 552.0 1169.0 1169.5 2338.5 3591.9 26.1912 1.68372 0.00543 18708
February: 576.0 576.0 576.0 852.0 853.0 1705.0 2618.9 19.096 1.2276 0.00396 13640
March: 744.0 744.0 744.0 694.0 694.0 1388.0 2132.0 15.5456 0.99936 0.00322 11104
April: 720.0 1 720.0 720.0 584.0 585.0 1169.0 1795.6 13.0928 0.84168 0.00271 9352
May: 578.0 480.0 578.0 806.0 631.0 1437.0 2207.2 16.0944 1.03464 0.00333 11496
June: 720.0 720.0 720.0 1352.0 1352.0 2704.0 4153.3 30.2848 1.94688 0.00627 21632
July: 744.0 744.0 744.0 1157.0 1157.0 2314.0 3554.3 25.9168 1.66608 0.00537 18512
August: 744.0 744.0 744.0 1023.0 1023.0 2046.0 3142.7 22.9152 1.47312 0.00475 16368
September: 531.0 720.0 720.0 362.0 490.5 852.5 1309.4 9.548 0.6138 0.00198 6820
October: 744.0 744.0 744.0 1047.5 1047.5 2095.0 3217.9 23.464 1.5084 0.00486 16760
November: 720.0 720.0 720.0 974.0 975.0 1949.0 2993.7 21.8288 1.40328 0.00452 15592
December: 552.0 552.0 552.0 890.0 891.0 1781.0 2735.6 19.9472 1.28232 0.00413 14248
Total: 7925.0 8016.0 8114.0 10910.5 10868.5 21779.0 33452.5 11243.925 i15.681 0.05053 174232.0
Average 660.4 668.0 676.2 909.2 905.7 1814.9 2787.7 20.327 1.307 0.00421 14519.3
121Zv1 3 5seB FI -5 Z1 zl/2013 -cs4 v&&.w
A
j 5/mil �r /L//�C1/�,//�.ficN�IS �ul4v�D . APO`ED
P07
h c/ 9E- S l6/IrmB/i NC/ 0,0026 Ib/nnm
/Ip� 2, 95 X Iv -�1b/�nm P� 2 3/C- -7 IhlMn67�
CoOo i9 lop r"V 3 % Jy Co SSppm EF 3 ✓ ai
CjG��/� a� Ly /S3Z9 c/bCFr /Z.//'-'oilro7sN�r
z592 0 GCyr
Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2013
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 10 0 10
December: 1 0 0 1 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2013 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0 135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000
Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9 [VG
Year: 2013
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max New Used Recovered Recovered Total Used Ending Product
Inventory Used Inventory Lbs.
January: 10800 8100.0 18900 0.0 18900
February: 18900 18900 4050.0 6375.0 6054.0 4371.0 14529 1386
March: 14529 14529 4050.0 5616.0 5328.0 4338.0 10191 1606
April: 10191 10800.0 20991 5100.0 5100.0 15891 1672
May: 15891 15891 795.0 795.0 15096 946
June: 15096 15096 0.0 15096
July: 15096 15096 3959.0 11382.0 14228.5 1112.5 13984 1276
August: 13984 13984 94&0 5246.0 10341.0 -4149.0 18133 1298
September: 18133 18133 0.0 18133 374
October: 18133 8100.0 26233 5250.0 5250.0 20983 1958
November: 20983 1 3 1 1100.0 1100.0 19883 704
December: 19883 19883 0.0 19883
Lbs. of chloroform used during the year: 17918 1791 7
Lbs. of chloro. used by Misc., OA, and R&D:
Lbs. of chloro. used by EVG: 17918
Lbs. EVG Produced: 11220
Lbs. of chloroform sent to hazardous waste: 900
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted during year: OS-9 17018
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Annual Air Emissions Inventory
Facility ID#: 0800044
Dieftlamine : OS-1, / ,'
Year: 2013
b
Used for Nicotine Extraction in Botanical Extraction
Info: Lbs/Gal = 5.90 Process
Monthly Inventory of Diethylamine (gallons):
Month Beginning Received Max Used Used Ending
Inventory Gals. Lbs Gals. Lbs. Inventory
January: 0 0 0 0
February: 0 0 0 0
March: 0 0 0 0
April: 0 0 0 0
May: 0 0 1 0 0
June: 0 0 0 0
July: 0 0 0 0
August: 0 0 0 0
September: 0 0 0 0
October: 0 0 0 1 0
November: 0 1 2830 16698 1 2189 12917 1 641
December: 1 641 1 3781 1 1 0 1 641
Total Gallons of Eth lenediamine Used: 2189
Total Lbs. Ethylenediamine Used: 12917.46
Gallons sent to Hazardous Waste: 0
Lbs. Dieth lamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Ethylenediamine Emitted: OS-10 12917.46
vJc Co�i6 kk A' 0, ys 11�7r_5
Annual Air Emissions Inventory
Facility ID#:08000"
Ethyl acetate : OS-6,OS-7,OS-10, OS-28
Year: 2013
Info: LbslGal= 7.50
Monthly Inventory of Ethyl acetate(Pounds):
Ethyl acetate Used in SDA-35A
Month Bedinning Inventory Bulk Drums Alcohol
Total Beginning Beginning New Recovered Recovered in Max Monthly Total Ending Month Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
Inventory Inventory Inventory
January: 4020 4020 0 1260.00 4020 '1260.0 2780 January: 45.19
February: 2760 2760 0 200.00 2760 - 200.0 2560 February: 108.44
March: 2560 2560 0 366.00 2560 356.0 2204 March: 69.00
ril: 2204 2204 0 1219.00 2204 1219.0 985April: 11.47
May: 985 985 0 3200.0 4185 0.0 4185 May: 173.94
June: 4185 4185 0 4800.0 8985 0.0 8985 June: 161.41
Jul 8985 1 8985 0 1 1 315,00 1 8985 315.0 8670 July: 83.22
Au ust 8670 8670 0 1 1465.00 1 8670 1465.0 N6455
Au ust: 13.82
Se Umber. 7205 7205 0 7205 0.0 September: 40.46
October. 7205 7205 0 3200.0 949.00 10405 949.0 October. 81.38
November. 9456 9456 0 2501.00 9456 .2501.0 November. 0.00
December. 6955 6955 0 500.00 6955 December. 73.37
fpfA! -g�ro5lbs -�
Ethyl acetate Emissions by Source
Ethyl acetate Emitted Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted
from SDA in Botanical
Month Extraction:OE=?6 Biomass Extraction:OS•28 SDA in PNE:OST PNE:O) from SFG rC�-6
(Lbs.) pSyp (Lbs.) (Lbs.) 053� (Lbs.) (Lbs.) 033/
Janua : 45.19 0.00 0.00 1260.00
February: 81.00 0.00 27.45 200.00
March: 54.42 0.00 14.58 356.00
-April: -0.93 0.00 12.41 1219.00
May: 69.15 104.80 0.00
June: 53.10 100.25 0.06
July: 0.00 .84.02 -0.80 315.00
August: 0.00 13.82 0.00 1465.00
September: 0.00 46.86 -6.40
October., 0.00 81.38 0.00 949.00
November. 0.00 0.00 0.00 2501.00
December. 73.37 0.00 0.00 500.00
Avers a 31.27 36.59 3.94 #DIV/0! 89
Total 1 375.29 431 47.29 1 0.00 1 ✓ 6785.00
Z 211.53 + 163.76
(n ct 0 ik1 one
Annual
Air Emissions Inventory
E:{h`(' )J[!TL A - Facility ID#:0800044
Etf of 200 proof) -OS-10 OS-28
Year: 2013
Info: Lbs/Gal= 6.68 %SDA Ethyl acetate = 4.0 4
Monthly Inventory of Ethanol(gallons):
jE
thyl
Beginning Recovered Max Recovered Difference in Recovered Ending Gallons to
Month Inventory New Received Received (Lbs) New Used Sent Off-Site Recovered Used Total Used Inventory WWT V
January: 40707 5495 71435 774402 5495 68349 3086 3086 8581 40707 8409 45.2
February: 40707 5523 85021 864026 5523 75164 9857 9857 15380 40707 15072 81.0
March: 40707 48029 584149 40717 7312 7312 7312 40707 7166 38.5
A ril: 40707 12913 38606 607124 12913 51696 .13090 -13090 -177 40707 -174 -0.9
Ma 40707 31270 33688 895590 15635 55328 -21640 4254 19899 30438 19501 2515.1 104.8
June: 30438 69227 656098 15635 49816 19412 4920 20555 29295 20144 2598.0 108.3
July: 29295 10870 79688 788989 10870 85131 -5444 5084 15954 18767 15635 2016.5 84.0
Au ust: 18767 22856 274005 10158 12698 2624 2624 26842 2572 331.7 13.8
September. 28842 189864 1 8898 8898 19944 8720 1124.7 46.9
October: 19944 6390 173354 6390 1 9062 15452 10882 15143 1953.0 81.4
November. 10882 71633 0 10882 0 0.0 0.0
December. 10882 71633 0 10882 0 0.0 0.0
Total Gallons of Ethanol Used: 114477
Total Lbs.Ethanol Used: 753602.7493
Gallons sent to Hazardous Waste:
Lbs.Ethanol sent to Hazardous Waste: 0
Total Gallons sent to WWT: 112188
Total Lbs.sent to WWT: 738530.6943 1
Total Lbs.of Ethanol Emitted as VOC: 14469 7- 2-3/CnS
Botanical Extraction Operation:OS-30 ` O
Y
Lbs.EtOH Lbs.Ethyl
Month #Da s Lbs.Botanical Gallons EtOH- Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate Product
Operated Product SDA Used Used Recovered WWTP E�OOCC as Emitted as
VOC
January: 31 41755.92 8580.7 56486.75 55357.01 1084.5 45.2 Krill
February: 28 52682.56 15379.7 101244.57 99219.67 1943.9 81.0 Krill
March: 18 33867.00 7312.0 48134.90 47172.20 924.2 38.5 Krill
-April: 21 33123.20 -177.3 -1167.17 -1143.82 -22.4 -0.9 Krill
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0
August: 0.00 0.00 0.0 0.0
September: 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Avera a 25 40357.17 7773.8 17058.25 #DIV/01 16717.09 327.52
Total 98 161428.68 31095.1 204699.04 0.00 200605.06 3930.22 rr163.70
Biomass Extraction Operation:OS-28
Lbs.EtOH Lbs.Ethyl
Month #Days Lbs.Biomass Gallons EtOH- Lbs.EtOH Lbs.EtOH LbS.EtOH to E Acetate Product
Operated Product SDA Used Used Recovered W WTP v�as Emitted as
VOC
January: 0.00 0.00 0.0 0.0
February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
-April: 0.00 0.00 0.0 0.0
Maw 26 52272.00 19899.0 130995.12 128375.21 2515.1 104.8 Krill
June: 30 F438906. 0 20555.0 135313.57 132607.29 2598.0 108.3 Krill
Ju : 31 0 15954.0 105025.18 102924.68 2016.5 84.0 Krill
Au ust: 16 0 2624.0 17273.79 16928.32 331.7 13.8 Krill
Se tember: 30 0 8898.0 58575.53 57404.02 1124.7 46.9 Krill
October: 31 0 15452.0 101720.52 99686.11 1953.0 81.4 Krill
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Avera a 27 0 13897.0 45741.96 #DIV/0! 44827.14 87825 36.59Total 164 .00 83382.0 548903.71 0.00 537925.63 10538.96 439.12
Annual Air Emissions Inventory
Facility IDa:08000"
Ethanol-SDA-35A:OS-7&OS-10
OS-18 OS-19 OS-27 OS412 INCLUDED WITH OS-1_0_
Year. 2013
Into: LbslGal= 6.87 %SOA Ethyl acetate= 4.54
Monthly Inventory of Ethanol Iwllonsl:
MOMhIy Baainninp Inventory Bulk Drums
TpteI SDA
Total SDA Bulk SDA In Drums SDA Max SDA on SDA to Ethyl
Month Beginning Beginning Beginning SDA SDA SDA Drams SOA Ending Soon s) SDA Used SDA VOC
Received Transferred SDA Used Received Recovered In Recovered SDA Disposed Hand Inventory (Wllone) [Lbs.) WWT (Lbs.) Ace Lb.)
tate VOC
Inventory Inventory Inventory Drums Used I�sl (�•) (�')
Janes . 2g72M 11671A 18053.9 2D4207 1 29725 0 0.0 1791M.8
0.0 0.0
Febnte . 29724.5 11671.0 18053.5 4400.0 204207 25325 4400 3022810 577.1 27A
March: 25324.5 7271.0 18053.5 10669.0 10669.0 5780.6 247275 31105 4888 33583.0 8172 30.5
April: 31105.2 7271.0 238342 6289.0 985.0 2670.0 1668.3 256898 35405 1989 13662.5 280.8 12A
Ma. 35405.4 12575.0 22830.4 6490.0 5304.0 5780.E 287822 30871 11095 76161.6 1453.9 69.1
June: 30810.8 13781.0 17049.8 6231.0 9892.5 1170.0 254477 28519 8523 58549.6 1117.8 53.2
Ju . 28519.3 10299.5 18219+8 128A 195928 28647 -128 -880.0 -16.8 -0.3
Aomori: 28647.4 70299.5 18347.9 196808 28647 0 0.0 0.0 00
.6.
September: 28647.4 10299.5 18347.9 6452.0 1028.E 241133 36128 -1027 .7052.4 -751.8 S.4
October: 38125.9 t6751.5 19374.4 248135 w M 0 0.0 0.0 0.0
November. 38725.8 78751.5 19374.E 248185 36128 0 0.0 0.0 0.0
December. U125.9 16751.5 19374.d 17999.0 71782.0 330618 38363 11762 80604.9 8 1542.7 73.4
Total 46130.0 0.0 43812.E 0.0 8450.E 9771.8 0.0 2915743.3 382925.2 41491.8 286047.1 279346.1 6N2.1 258.8
Botanical Extraction Operation:OS-10
8 Da Lbs.Botanical Gallons EtDH- Lbs.EtOH- Lbs'EtOH. Lbs.EtOH- EtOH-SDA Ethyl Acetate
Mont Days
Operated Protluct SDA Used SDA Used SDA SOA to VOC(Lbs.) VOC(Lbs.) Product
covered WWTP
Jana a00 0.00 0.0 0.0
Februa . 0.00 0.00 00 00
March: 11 1918.85 2561.0 17525.37 17174.86 334.6 15.9 Tobacco
nl: 000 0.00 0.0 0.0
Ma : 28 8899.80 11084.6 78151.20 74629.18 1453.9 69.1 Cranbemr
June: 14 4792.55 9683.0 66522.21 8037.90 57314.62 1118.8 53.1 Cranberry
July: o.DO o.00 0.0 0.0 Total SDA Ethanol Data
Au cant: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 51263.1
September. 0.00 0.00 0.0 0.0 Total Lbs.SDA Used: 352177.8
October. 0.00 0.00 0.0 0.0 Total Gallons cant to W WT: 40661.88
November 0.00 0.00 0.0 0.0 Total Lbs.send to W WT: 279345.74
Dttember. 24 4954.80 11762.0 BOt104.94 79188.84 15427 73.E Cranbe Total Lbs.SDA Ethanol Emitted as VDD•s: 3442.11
Avers 19 Si41.00 87702 200&3.64 8037.90 19025.61 870.85 Lbs.Botanical Extraction Ethanol Emined as VOC:OS-10 4447.78
Tote) 75 20564.00 18080.8 241003.72 8037.90 22830857 4147.78 11.53 Lbs.PNE Ethanol Emitted as VOC:OS-7 994.31
PNE Operation:OS-7
8 Da Lbs.PNE Gallon EtOH- lbs.EtOH- Lba.EIGH- PSDAto
H- EtOH-SDA Ethyl Acetate
Month Days SDA o Product
Operated Product SDA Used SDA Used RveVOC(Ibs.) VOCILbs.)0.00 0.0 0.0
Februa 7 1319.50 4400.0 30228.00 4 577.1 27.4 Dews
March: 18 2582.55 8118.0 56770.66 39713.001 308.E 14.6 Dews
NI: 11 3655.0 25109.85 11447.4812 280.8 12A Tobsoco
0.00 0.0 0.0
June: 4 9.5 65.27 12 0.1 Tobacco
Ju . 5 N.80 0.DO 879.71 2 -1&8 -0.8 Tobacco
Au ust: 3 0.00 0.0 0.0 Tobacco
Se mber.. 9 0.007062.74 9 .134.7 SA Tobacco
October. 0.00 000 0.0 0.0
November. 0.00 0.00 0.0 0.0
December. 0.00 000 00 1 0.0
Average 8 1X62 4045.E 8264,18 14773.23 4253.27 82.8E 3
Total 68 3943.85 18182.5 111173.78 59092.93 510J8.21 994.1J 47.29
Annual Air Emissions Inventory
Facility 100:08000"
Ethanol-SDA-3A:OS-7&OS-10
OS II OS19 OS27 OS-32 INCLUDED WITH OS-10
Year. 2013
Irdo: LbslGal 6.87 %SDA Methanol 5
Monthly Inventory of Ethanol(aallonsk
Monthly Beginning Inventory Bulk Drums
Max SDA on Total SOA SDA to EtOHSDA
Total SDA Bulk SDA in Drums SDA SDA SDA in Drums SDA SDA Ending SDA I/aed SDA Used Methanol
Month Beginning Beginning Beginning Received Transferred SDA Used Received Recovered in Recovered SDA Disposed Hand Inventory (genons) (Lbs.) WWT VOC VOC(Lbs,)
Inventory Inventory Inventory Drums Used (�) G I_ (�') (�°')
Janes : 0.0 0.0 0.0 0 0 0 0.0 0.0 Ciao 0.00
Februe Ciao Ciao Ciao 435.5 54.4 29N 381 54 373.7 385.3 7A 0.37
March: 351A 381.1 0.0 2618 381 0 Ciao Ciao Ciao 1.00
26
NI: 381.1 381.1 0.0 2177.8 182.8 17578 2376 183 1255.8 1230.7 23.9 1.28
Ma 2373.9 2375.9 Ciao 1088.8 1994.8 780.0 23802 2250 1215 6345.4 8178.5 158.6 8.35
Juaas: 2248.8 1489.9 TWO532 942 15457 2291 -41 -281.9 -276.3 -5.4 -0.26
00
July: 2291.0 1416.7 874.2 15739 2291 0 Ciao 554 30. 0..5
August 2291A 1418.7 874.2 230.9 15739 2522 -231 -1588.8 -1554.8 -30.1 -1.59
September. 2521.9 1416.7 1105.2 1 117325 2522 0 0.0 0.0 0.0 0.00
October. 2521.9 %16.7 1105.2 633.5 0
17325 3055 -534 -3885.1 -35g1.8 -9 ..00
November. 3055.4 1418.7 1638.7 20991 3055 0 Ciao Ciao 0.00 0,00
December: 3055.4 1416.7 1638.7 20991 3055 0 Ciao Ciao Ciao 0.
TONI 3701.9 0.0 2285.2 0.0 0.0 16M7 Ciao 17D557.4 24179.8 848:b 444L3 {352.5 $4.4 4.4
Botanical Extraction Operation:OS-10
Lbs.EtOH- Lbs.EtDH-
5 Days Los.Botanical Gallons EtOH- Lbs.EtOH- SDA SDA toEtOHSDA Methanol VOC Product
Month
Operated Product SDA Used SDA Used Racove VOC(�) (Lbs.)
Janes 0.00 1 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
ag; DOD 0.00 OAO 0.00
0,00 0.00 1 0.00 0.00
Juror: 0.00 0.00 0.00 O.oD
M y. 0.00 0.00 0.00 0.00 Total SDA Ethanol Data _
Ai must: 0.00 0.00 0.00 0.00 Total Gallons d SDA Used: 1156911.0
0.00 0.00 0.00 0.00 Total Lbs.SDA Used:
Se mbar: 0.00 0.00 0.00 Goo Total Gallons sent W W W r: 833•58
November. 0.00 0.00 0.00 0.00 Total Lbs.wad W WVR: 4332.70
December. Ciao- 0.00 0.00 0.00 Trial Lbs.SDA Ethanol Emitted es VOCS: 54.J9
Avers SDNNI SOIVNI SOIVNI 0.00 A11VI01 0.00 0.00 0.00 Lbs.Botanist Extraction Ethanol Entitled a VOC:OS10 0.00
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 0.00 Lbs.PNE Ethanol Emoted a VOC:OS-7 84.19
PNE Operation:OS-7
-GW
5 Days Lbs.PNE Gallons EtOH- Lbs.EtOH- EIOH- Lbs.ElOtl- EIOHSDA McNaml VOC
Month Operated Product SDA Used SDA Used S A �W VOC(Lbs.) (Lbs.) Product
ract VIA111TIP
January: 0.00 0.00 1 0.0 0-0
Febrw 3 54.4 373.73 366.25 7.1 Nw307
Sveet Potato
March: Ciao
April: 23 7683.80 182.8 1255.84 1230.72 23.9Swat Potato
SvreM Potato,
May: 27 1715.59 1994.8 13701.28 5358.60 8178.78 158.8Carrots
June: 53.2 365.48 647.45 -276.33 -5.4 Canoes
J ; 0,0p 0.00 0.0
Auoust 3 0.00 1588.60 -1554.87 -30.1 Roaem
SsptsnnbM 4 0.00 0.00 0.0 Rosema
October. 5 O.OD 3W5.15 -3591.S4 -69.8Roaema
November. 0,00 0.00 Ciao 0.0
December. 0.00 0.00 0.0 0.0
Avers 11 1699.80 571.3 1427.21 2614.45 395.70 7.03
Total 65 3399.19 2295.2 156g8.32 11257.80 1 4352.70 BC38 44
Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4 OS-5,OS-6,OS-10,OS-28,OS-29
OS-13 OS-14 OS-15 OS-16 OS-20 OS-21 OS-22 OS-23.OS-92 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH 05-10•OS-30 INCLUDED WITH OS-28
Year: 2013
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-</=40%n-Hexane(gallons):
Beginning Max
Month Inventory Received Lbe Used Ending Inventory
January: 7659 4460 W655 1788 10331
Febma : 10331 56821 1881 8450
March: 8450 46475 1937 0513
April: 6513 4599 61116 1609 9503
May: 9503 52267 1390 8113
June: 8113 44622 1419 6694
Jul : 6694 4494 61534 2382 8806
Au ust: 1 8806 1 48433 3308 5500
Se tembar: 5500 4354 54197 2284 7570
October- 1 7570 1 4647 1 67194 1 2208 1 10009
November: 1D009 1 1 55050 2046 7963
December: 7963 3513 83118 2525 8951
Monthly Inventory of HP Hexane-</=95%n-Hexane(oallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 10027 55149 1553 8474
February: 8474 46607 1908 6486
March: 6486 35673 1760 4726
April: 4726 6066 59356 1152 9640
May: 9640 53020 9640
June: 9640 53020 2081 7559
Jul : 7559 41575 1594 5965
Au ust: 1 5965 1 5884 1 65170 2900 8949
Se tember: 8949 49220 2623 6326
October: 6326 34793 1 2991 3335
November: 3335 6428 53683 3629 8132
December- 1 6132 1 33723 1 3080 3052
Monthly Inventory of IsoHexane-</-5 n-Hexane Wallons):
Beginning Max
Month InventoryReceived Lbs Used Ending Inventory
January: 36026 47434 459030 41155 42305
Febma : 42305 6459 268202 -667 49431
March: 49431 271871 49431
April: 49431 271871 49431
May: 49431 141 DO 349421 2294 61237
June: 61237 28824 495336 19631 70430
Jul : 70430 15161 470751 19805 65786
Ati usl: 1 65788 1 33226 544586 32084 68928
Se tember: 66928 19635 478097 34149 52414
October: 52414 1 53418 582078 1 46230 59502
November- 1 59602 1 25450 467788 1 19034 66018
December: 1 66018 1 36857 565813 36245 66630
Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers(Lbs.):
Percent n-Hexane: 0.138
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
Ju : 0.00 0.00
August: I Sae 1 1921.40 2.65 1918.75
September. Sae 1 2168.25 2.99 2165.26
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Avera a #DIVl01 2044.83 0.47 3
Total 0 4089.65 5.64 84.0
Total Hexane Values
Gallons of LP Hexane Used: 24775.00 Gallons of N-Hexane Used: 30918.03
Gallons of HP Hexane Used: 25351.00 Lbs.of N.Hexane Used: 1 170049.19
Gallons of IsoHexane Used: 249960.00 1 Gallons of Hexane Isomers Used:1 263435.47
Total Gallons of Hexanes Used: 300086.00 1 Lbs.of Hexane Isomers Used: 1448895.06
Total Lbs.of Hexanes Used: 1 1650473
Sclareolide(SDE)Operation:OSrb Q S'3 to
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used X n-Hexane Hazardous Emitted Emitted homers
Waste (Lbs.) (Lbs.) Emitted
January: 27 42460.0 1788.0 9834 39.9 9834.00 3923.8 5910.23
February: 22 35527.8 1881.0 10345.5 39.9 832.7 5765.65 2300.5 3465.16
March: 26 44495.0 1937.0 10653.5 39.9 10653.50 4250.7 6402.75
April: 26 34676.4 1609.0 8849.5 39.9 8849.50 3531.0 5318.55
May: 22 1 31372.0 1390.0 7645 1 39.9 7645.00 3050.4 4594.65
June: 18 22710.6 1419.0 7804.5 39.9 771 3564.00 1422.0 2141.96
July: 28 43927.4 2382.0 13101 39.9 13101.00 5227.3 7873.70
August: 30 52140.0 3306.0 18183 39.9 185.5 17162.75 6847.9 10314.81
September: 30 50452.6 2284.0 12562 39.8 709.1 8661.95 3447.5 5214.49
October: 24 38137.0 2208.0 12144 39.7 12144.00 4821.2 7322.83
November: 29 45815.0 2046.0 11253 39.3 11253.00 4422A 6830.57
December: 21 32291.6 2525.0 13887.5 38.6 770.9 9647.55 3724.0 5923.60
Averse 25 39500.5 2064.6 11355.2 39.7 663.840 9856.825 3 49 59
Total 303 474005.4 24775.0 136263 3289.200 118281.900 46968.59T 71313.308
Page 3 of 5 /
Sclareol Recrvstallization(SFG)Operation:OSB p 5 39
Gallons Hexane Monthly Monthly onthly M
N Days Lbs.SFG Gallons Hexane Lbs.Hexane Sentas Hexane n-Hexane Isomer
Hexane
Month Operated Product Used Used X n-Hexane Hazardous Emitted Emitted
Waste (Lbs.) (Lbs.) Emitted
(Lbs.)
January: 31 38435 1553.0 8541.5 91.8 8541.50 7841A 700.40
February: 26 36030 1988.0 10934 91.9 10934.00 10048.3 885.65
March: 31 36425 1760.0 9680 91.9 9680.00 8895.9 784.08
April: 24 26505 1152.0 6336 92.2 6336.00 5841.8 494.21
may: 1 0.0 0 0.00 1 0.0 0.00
June: 28 57494 2081.0 11445.5 92.3 58.2 11125.40 1 10268.7 856.66
July: 30 66620 1594.0 8767 92.3 8767.00 1 8091.9 675.06
August: 29 78577 2900.0 15950 92.0 610.9 12590.05 1 11582.8 1007.20
September: 29 65749 2623.0 14426.5 91.6 232.7 13146.85 12042.3 1104.32
October: 30 74445 2991.0 16450.5 91.6 16450.50 15068.7 1381.84
November: 30 70171 3629.0 19959.5 88.9 19959.50 17744.0 2215.50
December: 27 60971 3080.0 16940 87.3 254.5 15540.25 13566.6 1973.61
Averse 29 55584 2112.6 11619 91.3 289 11089.24 10082.89 1006.55
Total 1 317 1 611422 26361.0 1 139431 1156 133070.85 12 92.31 12078.64
Rotocel&Recovery Operations:O 0535
Gallons Monthly Monthly Monthly
p Days Lbs.Sage Lbs.Sage Gallons Hexane Hexane Hexane n•Hezane Hexane
Monty Isomers
Operated Product Processed Used Lbs.Hexane Used X n-Hexane Sent as
Hazardous Emitted Emitted Emitted
waste (Lbs.) (Lbs.)
January: 31 104951.0 8734280.0 41155 226352.5 0.178 628AO 222896.3 396.8 222499.5
February: 3 10387.0 174440.0 3899 21444.5 0.105 21444.5 22.5 21422.0
March: 0.0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
Maw 3 1222.0 1 1233260.0 2294 12617.0 1 0.107 1 12617.0 13.5 12603.5
Jule: 30 76187.0 18030674.0 19631 107970.5 0.117 36.40 1 107770.3 126.1 107644.2
Jul 31 39950.0 7696128.0 19805 108927.5 0.112 108927.5 122.0 108805.5
Au ust: 30 68620.0 12130410.0 32084 176462.0 0.124 176482.0 218.8 176243.2
Septeimber: 30 69664.0 12999150.0 34149 187819.5 0.178 7.30 187779.4 334.2 187445.1
October. 31 79759.0 12809325.0 46230 254265.0 0.169 254265.0 429.7 253835.3
November: 30 98606.0 10829780.0 19034 104687.0 0.145 104687.0 151.E 104535.2
December: 27 86997.0 10007372.0 28727 157998.5 0.143 157998.5 225.9 157772�111i2A;
6
Averse 25 63633 9464481.9 24701 113212.0 0.138 224.03 112904.0 170.1
Total 246 636333 94644819.0 247008 13686".0 672.10 136047.5 2041.4
Lbs.Hex per day exiting Mineral Accountable Lbs.of Hexane
Oil Scrubber 106.25 Emitted: 140586.29
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 26137.5 Accountable Lbs.of N•Hex Emitted: 193.73
Lbs.of N-Hex exiting MO Unit: 36.02 Accountable Lbs.of Hexane 140392 56
Isomers Lost:
Lbs.of Hex Isomers exiting MO 26101.48 Fugitive Lbs.Hexane Emitted: 1214261.1E
Unit:
Lbs.Hexane per Lbs.of Spent 0.001140 Fugitive Lbs.n-Hexane Emitted: 1673.25
Sae from Desolvitizer tests
Lbs.Hexane in Spent Sage: 107895.09 ug a s. tt a isomers
Emitteded: 1212587.91
Lbs.N•Hezane In Spent Sage: 148.88 Accountable and Fugitive Lbs. 1354847.45
Hexane Emitted:
Lbs.Hexane per Day from A•1 0 000815 Accountable and Fugitive Lbs. 1866.98
Vent Cond. N-Hex
Emitted:
Lbs.Hex Exiting A-1 Vent: 0.200 Accountable and Fugitive Lbs.Hex 1352980.47
Isomers Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000276
Gallons sent to W WT: 5612789
Lbs.Waste Water per Gal.Waste 8.34
Wt%of Hexane in Waste Water:
Lbs.Hexane Lost In Waste Water. 6553.49 In'^
Lbs.N-Hexane Lost in Waste 8.03 -�� OSa �V wr Au(A4(GY1 VY Io,,
Water:
Page 4 of 5
Concrete Overations:f7S-4
Gallons Monthly
Hexane Monthly Monthly Hexane
Month #Days Lbs.Concrete lbs.Concrete Gallons Hexane Lbs Hexane Used %n-Hexane Sant as Emitted Emitted Hexane n-Hexane Isomers
.
Operated Product Processed Used Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0.0 0.0 0.0 0.0
February: 12 27683 43890.0 -4566 -25113 0.098 -25113.0 -24.6 -25088.4
March: 0 634.90 -3492.0 0.0 -3492.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0 0.0 0.0 0.0
Jut 0 0.0 0.0 0.0
Au ust: 0 0.0 0.0 0.0
Se tember: 0 0.0 0.0 0.0
October: 0 0.0 0.0 0.0
November: 0 0.0 0.0 0.0
December: 0 0.0 0.0 0.0
Averse 12 27883 43890.0 -4588 •2092.8 0.098 834.90 -2383.7 •2.1 -2381.7 L
Total 12 27683 43890.0 d688 -25113.0 634.80 -28806.0 -24:8 -28680.3
Lbs.Hexane per Day from A-1 0.000815 Accountable Lbs.of Hexane Lost: 94.62
Vent Cond.
Days A-1 Operated: 12 Accountable Lbs.of N-Hex Lost: -0.35
Lbs.Hex Exiting A-1 Vent: 0.010 Accountable Lbs.of Hexane 94.97
Isomers Lost:
Lbs.N-Hex Exiting A-1 Vent: -0.446555 Fugitive Lbs.Hexane Lost: 47287.33
Gallons sent to WWT: 81026 Fugitive Lbs.n-Hexane Lost: 46.34
Lbs,Waste Water per Gal.Waste 8.34 Fugitvs lbs.Hexane Isomers Lost 47240.99
Water:
Wt%of Hexane In Waste Water: 0.014 Accountable and Fugitive Lbs. 47381.95
Hexane Emitted:
Lbs.Hexane Lost in Waste Water. 94.61 Accountable and Fugitive Lbs. 45.99
N-Hex Emitted:
Lbs.N-Hexane Lost in Waste 0 Accountable and Fugitive Lbs.Hex 47335.98
Water. Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
Month
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane r h n-Hexane Sent as Hexane n-Hexane Hexane Operated Product Used Used Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.)
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 6663.0 0.00 0.0 0
May: 0 1 0.00 1 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 25 175672 7518.0 41349 0.173 41349.00 71.5 41277.486
Average 25 #DIVI01 7518.0 3446.75 0.173 6663.0 3445.76 5.96 3 79
Total 25 0 7518.0 1 41349.00 1 6663.0 41349.00 .53 41277.47
Page 5 of 5
Botanical Extraction Operation:OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Emitted
Waste (Lbs.) (Lbs.)
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
Ma 0 1 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Avers s #DIV/01 #01V/01 0DIV101 0.00 #DfV/01 #DIV10I 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00
Plant Nutrient Extraction(M-13)Operation:OS-29
Gallons Hexane Monthly Monthly Monthly
Hexane
Isomers#Days Lbs.PNE Gallons Hexane Lbs.Hexane Santos Hexane n-Hexane
Month X n-Hexane Isomers
Operated Product Used Used Hazardous Emitted Emitted Emitted
Waste (Lbs.) (Lbs.)
January: 0.0 0 0.00 0.0
February: 0.0 0 0.00 0.0
March: 0.0 0 0.00 0.0
April: 0.0 0 0.00 0.0
May: 0.0 1 0 1 0.00 0.0
June: 0.0 0 0.00 0.0
July: 0.0 0 0.00 0.0
August: 0.0 0 0.00 0.0
September: 0.0 0 0.00 0.0
October: 0.0 0 0.00 0.0
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Averse #DIVI01 #DIVI01 #DIVI01 0.0 #DIV101 #DIVI01 0.000 0.00 0.00
Total 0 0 0 0.0 0.0 0.000 0.00 0.00
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1554250.25 Total Lbs.Hexane Released: 1699020.80
Fugitive Lbs.N-Hexane Emitted: 169752.03 Total Lbs.n-Hexane Released: 169951.04
Fugitive Lbs.Hexane Isomers 1384498 22 Total Lbs.Hex Isomers Released: 1529069.76
Emitted:
Accountable Lbs.Hexane Lost: 144770.55 Total Lbs.Hexane Sent Off She: 68175.25
Accountable Lbs.n-Hexane Lost: 199.01 Total Lbs.N-Hexane Sent Off Site: #DIV/01
Accountable s. ex Somers 144571 54 o s. ex somers en #DNI01
Lost: Site:
Annual Summarw Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 61110 11977 65870.8
February: 64367 9384 51612.5
March: 60670 6942 38180.3
April: 69574 12680 69738.8
May: 789N 3303 18164.4
June: 94683 9730 53516.5
Ju : 80557 9093 50011.3
Au ust: 81377 10511 57808.1
Se tember: 68310 8901 48954.3
October: 72946 7129 39210.4
November: 80113 8676 41715.5
December. 78633 1 8214 34178.8
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
84683 12680 69739
Page 1 of 2
Annual Air Emissions Inventory
Facility IDN:08000 �
Methanol:O - �-8 °5-3 S o S'4
OS-13 OS.14 OS-15 OS-16 OS-17 OS-27 05-321NCLLIDED WITH OS 4
Year: 2013
Info: Lbs/Gal= 6.62 Specifics Gravity-0.793
Monthly Inventory of Methanol laallonsl: Methanol Used Alcoholoh in SDA-3A
al
Month Beginning Raceivetl Max Used Recovered Ending oJanua
Methanol
Inventory (Lbs) Inventory Emitted(Lbs.)
January: 13272 7328.0 138372 11077.0 9523 0.00
Februa : 9523 14703.0 160376 5665.0 18561 0.37
March: 18561 122874 4790.0 13771 0.00
April: 13771 15650.0 194767 6576.0 23845 1.26
Ma 23845 157854 2788.0 21057 8.35
June: 21057 139397 8288.0 12769 -0.28
Jul : 12789 15160.0 184890 8078.0 19853 0.00
19853 7882.0 183811240.0 16495 -1.59
Ss mMr. 16195 7587.0 15S423 9050.0 15032 September: 0.00
October: 1 15032 1 22993.0 1 251728 1 14368.0 1 23657 October: -3.67
November: 1 23667 1 8349.0 1 211880 1 11959.0 1 20047 November. 0.00
December: 20047 7808.0 184400 9523.0 18332 December: 0.00
Maximum Gallons On-liantl: 38025
Maximum Lbs.On-Hand: 251726.5
Gallons Used per Year.. 102400
Lbs.Used per Year: 877888
Sclareol Recovery Ooerationi OS-4
Accountable
N Days Gallons WON Lbs.McOH Avg.GPM Sent Lbs.WON to Avg'% Total Gel. Monthly Avg. Emissions of Total Lbs, Total Lbs
Month Operated Used Used to VANTP WWTP Methanol in Water to Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP (O Emissions
17
January31 11077 73329.74 1.4 26342.3 6.37 124145 98.5 395.1345 40987.44 47382.575
February3 1345 8903.9 1.4 2094.6 5.23 17072 99.1 18.8514 5809.3 6828.1514
March 0 0 0 0
April 0 0 0 0
Me 3 0 1.4 1366.E 5.12 8492 99.1 12.2994 0 0
June 30 8288 54885.5E 1.16 22491.5 6.91 159898 98.9 247,4005 32375.06 32622.467
Jul 31 4668 30888.92 2.27 14D43 2.70 158887 99.3 98.301 16845.92 16944.221
Au oust 30 8150 54019.2 1.02 20240.6 7.16 103337 99 202,406 33778.8 33981.006
September 30 8115 53721.3 1.25 20022.9 5.76 123732 99.2 180.1832 33698.4 33858.583
October 31 9004 59606.48 1.17 19913.4 5.85 109848 99.2 159,3072 39893.08 39852.387
November 30 10639 70430.18 1.4 23571.1 5.89 137323 98.7 306.4243 46859.08 47165.5D4
December 27 9523 63042.26 1A 21810.4 5.84 175279 98.9 239,9144 41231.86 41471.774
Averse 24.60 7868.56 39067.38 1.39 17189.84 5.68 112761.30 88.99 1 29 25008.89
Total 246 70817 468908.54 171896.4 1127613 989.9 1840.2279 278.74 106.67
p5 3S
Concrete Operation:OS-4
Accountable
N Days Gallons WON Lite.WON Avg.GPM Sant lbs.McOH to Avg'% Total Gal. Monthly Avg. Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP Methanol In Waterto Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP Emissions
(OS-171
January 0 0.00 0 0
Febmary 12 1288 8526.58 1.4 588e.5 4.88 479M 98.9 64.63 2660.06 2724.5915
March 0 0.00 0 0
April 0 0.00 0 0
may 0 0.00 0 0
June 0 0.00 0 0
July 0 0.00 0 0
August 0 0.00 0 0
September 0 0.00 0 0
October 0 0.00 0 0
November 0 0.00 0 0
December 0 0.00 0 0
Averacie 12.00 1288.00 710.55 1.40 5866.50 4.80 47996.00 98.90 U= 227.05
Total 12 1288 8525.56 5866.5 47998 98.9 84.531 '2660.08 2724.5915 n
1
tj
rr4 P
30o130 s
Page 2 of 2
oy9)
Accountable
Emissions of Total Lbs.e Days Gallons McOH Lbs.MdOH Gallons one MSOH Lbs.McOH to Total ions
Month Operated Used Use0 to WWTP yyyVTp MaOH from Fugitmission Emissions
WWTP Emissions
(OS-17)
January 0 0 0.00 0.00 0.00 0.00
February 25 3032 20071.84 2971.36 19670.40 393.41 401.44 794.84
March 22 4790 31709.8 4694.2 31075.60 621.51 634.20 1255.71
April 22 5576 36913.12 5464.48 36174.88 723.50 738.26 1481.76
Mav 11 2788 18456.56 2732.24 1808743 361.75 369.13 730.88
June 0 0 0.00 0.00 0.00 0.00
July 17 3410 22674.2 3341.8 22122.72 442.45 451.48 893.94
Au ust 18 3080 20389.6 3018.4 19981.81 399.64 407.79 80743
September 8 935 6189.7 916.3 6085.91 121.32 123.79 245.11
October 25 5354 36609+68 5256.72 34799.49 695.99 710.19 1406.18
November 7 1320 8738.4 1293.6 8563.63 171.27 174.77 346.04
December 0 0 0.00 0.00 0.00 0.00
Average 17.00 3366.11 16712.74 2474.09 16378.49 327M 334.25 661.82
Total 153 30295 200552.9 196541.84 3930. AW1.06 7941.89
PNE Operation:OS-7
Accountable
a Days Gallons McOH Lbs.MeOH Gallons Lbs. to Emissions of Total Lbs. Total Lbs.
Monet Operated Used Used to WVJTP TP WWTpWTp McOHfrom ssion Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.D0 0.00 O.DO 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 0.00
Ju 0 0 0.00 ID
DOO 0.00
Au ust 0 0 0.00 0.00 0.00
Se mbar 0 0 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00
Nowmber 0 0 0,00 0.00 0.00
December 0 0 0.00 0.00 0.D0
Amore 9DrV/01 ODIV/01 0.00 0.00 0.00 0.00 0.00 0.00
Total 0 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol Operations
Total Lbs.MsDH Thru System: 2842128.00 Lbs.Fugivdve Emissions from EVG: 4011.06
Total s.M90H Treatedat 374304 74 Lbs,Fuglvtiw Emissions from Recovery: 298278.74
WWTP:
Calculated emova Efficiency of W WTP: 99.95 Lbs.Fugitive Emissions from Concrete: 215W.08
Lbs.Accountable Emissions 5835.80 Total Lbs.Fugitive Emissions: 308790.09
from WWTP(OS-IT):
Lbs.of Emissions from W WTP 1840.23 Total Lbs.McOH Released: 312625.68
Dunn Recove
Lbs.of Emisa ons m 64.5315 Total Lbs.MaOH Recycled On-Site: 2467823.26
Durin Concrete Recove
Lbs.of Emissions
hom W WTP 3930.84
tat Aeration Chamber OS-17:
Los.INEmiasions rom isc.,
Lab:
Annual Air Emissions Inventory
Facility ID#:08000g4
Heptane : OS-6, OS-7, OS-10
Year: ® 1
Info: Lbs/Gal= 5.70
Mon h1v Inventory of He tape allons :
Beginning Max Recovered Ending
Month InventoryReceived Lbs New Used Used Recovered Inventory
January: 7058 40231 240.0 556.3 7374
February: 7374 1 42034 7374
March: 7374 1 2200 54574 3355.0 6219
April: 6219 35450 2189.3 1592.5 5622
May: 5622 32048 5622
June: 5622 32048 240.0 150.0 5532
July: 5532 31535 150.0 1424.6 6607
August: 6807 5185 68355 2750.0 9242
September: 9242 3300 71490 3017.1 1796.5 11321
October: 11321 64532 11321
November: 11321 9179 116853 7199.0 13301
December: 1 13301 75818 13301
'SFG M-13 O ration:OS 39
Gallons Monthly Monthly
Gallons Gallon Heptane n-
Month #Days Lbs.PNE Heptane Lbs.Heptane %n-Heptans Heptane Heptane Sent Emitted as Heptane
Operated Product Used Used Recovered as Hazardous VOC Emitted
Waste (Lbs.) (Lbs.)
January: 19 26506 240.0 1368.0 556.3 1802.9 0.00
February: 0.0 0.0 0.00
March: 0.0 1 0.0 0.00
April: 1 0.0 1 0.0 0.00
May: 0.0 1 0.0 0.00
June: 0.0 0.0 0.00
July: 0.0 0.0 0.00
August: 0.0 0.0 0.00
September: 0.0 0.0 0.00
October: 0.0 0.0 0.00
November: 0.0 0.0 0.00
December: 0.0 0.0 0.00
Averse 19 26506 1 240.0 114.0 #DIV101 556.3 11 #DN/01 -150.2 0.00
Total 1 19 26606 240.0 1368.0 1 556.3 1 0.0 1 -1802.9 0.00
Botanical Extraction Operation:OSf0 OS VO
Gallons Monthly Monthly
#Days Lbs. Gallons Lbs.Heptane Gallons Heptane Sent Heptane n-
Month Botanical Heptane Used as Hazardous%n-Heptane Heptane Emitted as Heptane Product
Operated product Used Recovered VOC Emitted
Waste
January: 0.0 0 0.00
February: 0.0 0 0.00
March: 11 3355.00 19123.5 1592.5 10046.25 0.00 Tobacco
A rii: 1 21 1 2189.30 12479.0 12479.01 0.00 Krill
may: 0.0 0 0.00
June: 0.0 0 0.00
July: 0.0 0 0.00
Au ust: 5 2750.00 15675.0 178.9 179 13635.54 0.00 Tobacco
Se tember: 9 3017.10 17197.5 1796.5 6957.42 0.00 Tobacco
October: 0.0 0 0.00
November: 11 7199.00 41034.3 41034.3 0.00 Nicotine
December: 0.0 0 0.00
Averse 11 #DIV/0! 3702.08 8792.4 #DIVI01 1189.3 178.9 7012.710 0.00
Total 57 0.00 18610.40 106508.3 3567.9 178.8 84162.520 0.00
SFG Operation:OS-6
Gallons Monthly 1000
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Heptane Sent HeptaneMonth Operated Product Heptane Used %n•Heptane Heptane as Hazardous Emitted as
Used Recovered Waste VOC
January: 0.0 0
February: 0.0 0
March: 0.0 0
April: 0.0 0
May: 0.0 0 0.00
June: 0.0 0 0.00
July: 0.0 0 0.00
August: 0.0 0 0.00
September: 0.0 0 0.00
October: 0.0 0 0.00
November: 0.0 0 0.00
December: 0.0 0 0.00
Avera a #DIV/01 #DIVl01 #DIVIO! 0.0 #DIV/01 DIV/01 #DIV/01 0.000 0.00
Total 0 0 0 0.0 0.0 0.0 0.000 0.00
PNE M-13 O eration:OS-7
Gallons Monthly Monthly
#Days Lbs.PNE Gallons Lbs.Heptane o Gallons Heptane Sent Heptane n-
Month Heptane /o n-Heptane Heptane as Hazardous Emitted as Heptane Product
Operated Product Used Used Recovered waste VOC Emitted
January: 0.0 0.0 0.00
February: 0.0 0.0 0.00
March: 0.0 0.0 0.00
April: 1 0.0 0.0 0.00
Ma : 0.0 0.0 0.00
June: 4 240.0 1368.0 150.0 513.0 0.00 Tobacco
July: 5 150.0 855.0 1424.6 -7265.2 0.00 Tobacco
Au ust: 0.0 0.0 0.00
Se tember: 0.0 178.9 -1019.7 0.00
October: 0.0 0.0 0.00
November: 0.0 0.0 0.00
December: 0.0 178.9 -1019.7 0.00
Avera e 5 #DIV101 195.0 185.3 #DIVIO! 787.3 178.9 -732.6 0.00
Total 9 0 390.0 2223.0 1574.6 357.8 -8791.7 0.00
Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2013
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (lbs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2013
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Month Inventory Received (Lbs) New Used Recovered Recovered Inventory
Used
January: 998 7206 998
Februa 998 7206 998
March: 998 7206 998
April: 998 7206 998
May: 998 7206 998
June: 998 7206 998
July: 998 7206 998
August: 998 7206 998
September: 998 7206 998
October: 998 7206 998
November: 998 7206 998
December: 998 7206 998
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyl acetate: OS-7, OS-10
Year: 2013
Info: Lbs/Gal =
Monthly inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of[PAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0
Annual Air Emissions Inventory
Facility ID#:0800044
n-Butylacetate: OS-10
Year: 2013
Info: Lbs/Gal= 7.35
Monthly Inventory of n-Butyl acetate(nallons):
Month Beginning Received Max Used Recovered Ending
Inventory Lbs New Used Recovered Used Inventory
Janua : 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
Au ust: 1 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 1 0 0 0
Gallons of NBAC used during the year @ PNE(OS-7): 0
Lbs.Of NBAC used during the year @ PNE(OS-7): 0
Gallons of NBAC used during the year OS-10 :
Lbs.Of NBAC used during the year@(OS-10 : 0
Lbs.of NBAC used by Misc.,QA,and R&D:
Lbs.of NBAC sent to hazardous waste: 12580
Lbs.of NBAC sent to wwt:
Lbs.of NBAC emitted during year: -12580
Annual Air Emissions Inventory
Facility ID#:0800044
Pentanone: OS-10
Year: 2013
Info: Lbs/Gal= 6.01
Monthly Inventory of Pentanone(gallons):
Beginning Max Used Ending
Month InventoryReceived Lbs New Used Recovered Used Recovered Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
Au ust: 1 0 1 0 0
September: 1 0 1 0 0
October: 0 0 0
November: 0 0 0
December: 0 1 0 0
Gallons of Pentanone used during the year @ PNE(OS-7): 0
Lbs.Of Pentanone used during the year @ PNE(OS-7): 0
Gallons of Pentanone used during the year OS-10):
Lbs.Of Pentanone used during the year OS-10 : 0
Lbs.of Pentanone used by Misc.,CIA,and R&D:
Lbs.of Pentanone sent to hazardous waste: 1360
Lbs.of Pentanone sent to wwt:
Lbs.of Pentanone emitted during year: -1360
Annual Air Emissions Inventory
Facility ID#: 0800044
Maganese
Year: 2073
Info: Potassium permanganate contains 33-35% Manganese.
Monthiv In entory of Potassium Perman anate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 1 16537 16537
June: 16537 16537 16537
Jul : 16537 16537 1 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November7 1 16537 16537 16537
December: 1 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2013
Info: Lbs/Gal =
Monthly Inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs. of Sulfur dioxide used by Misc., QA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2013
Info: Lbs/Gal = 7.50 All ethylenediamine is contained and
shipped off-site with the product.
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
Jul : 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0
I
Annual Air Emissions Inventory
Facility ID#:0800044
Toluene
Year. 2013
Info: Lbs/Gal= 7.23
Monthly Inventory of Toluene(gallons):
Beginning Max Ending
Month Inventory Received Lbs In Process Recovered In Product Total Used Inventory
January: 1531 11069 0 1531
February: 1531 11069 0 1531
March: 1531 11069 0 1531
April: 1531 11069 0 1531
May: 1531 11069 0 1531
June: 1531 11069 0 1631
July: 1531 11069 0 1531
August, 1531 1 11069 0 1531
September. 1531 11069 0 1531
October: 1531 11069 0 1531
November: 1531 11069 0 1531
December: 1531 11069 0 1531
November: 1531 11069 0 1531
December: 1531 11069 0 1531
Total 0 0 0 0 0 21434
Botanical Extraction Operation:OS-10
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Emitted as Toluene Toluene
Operated Product Toluene Used Used Recovered in Product
VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/01 #DIV/01
February: 0.00 0.00 0.00 #DIV/01 #DIV/01
March: 0.00 0.00 0.00 #DIV/01 #DIV/Of
April: 0.00 0.00 0.00 #DIV/Of #DIV/01
May: 0.00 0.00 0.00 #DIV/01 #DIV/01
June: 0.00 0.00 0.00 #DIV/01 #DIV/01
July: 0.00 0.00 0.00 #DIV/01 #DIV/01
August 0.00 0.00 0.00 #DIV/01 #DIV/01
September. 0.00 0.00 0.00 #DIVI01 #DIV/01
October: 0.00 0.00 0.00 #DIV/01 #DIV/01
November: 0.00 0.00 0.00 #DIV/01 #DIVI01
December: 0.00 0.00 0.00 #DIV/OI #DIV/01
Averse #DIVI01 #DIVI01 #DIVI01 0.00 #DIVIOI 0.00 0.00 #DIVI01 #DIV/01
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 #DIV/01 #DIVI01
PNE Operation:OS-7
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Operated Product Toluene Used Used Recovered in Product Emitted as Toluene Toluene
VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/01 #DIV/01
February: 0.00 0.00 0.00 #DIV/01 #DIV/01
March: 0.00 0.00 0.00 #DIVI01 #DIV/01
April: 0.00 0.00 0.00 #DIVI91 #DIVI01
May: 0.00 0.00 0.00 #DIV/01 #DIV/01
June: 0.00 0.00 0.00 #DIV/01 #DIV/01
July: 0.00 0.00 0.00 1 #DIVI01 #DIV/01
August: 0.00 0.00 0.00 #DIVI01 #DIV/OI
September: 0.00 0.00 0.00 #DIV/01 #DIV/01
October: 0.00 0.00 0.00 #DIV/oI #DIV/01
November. 0.00 0.00 0.00 #DIV/01 #DIVI01
December. 0.00 0.00 0.00 #DIV/Ot #DIV/01
Averse #DIVI01 #DIVI01 #DIVIOI 0.00 #DIV/OI 0.00 0.00 #DIV/01 #DIVI01
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 #DIVI01 #DIVI01
Gallons of Toluene used during the year. 0.00
Lbs.of Toluene used during the year. 0.00
Lbs.Botanical Extraction Toluene Emitted:OS-10 0.00
Lbs.PNE Toluene Emitted:OS-7 0.00
Lbs.of Toluene sent to hazardous waste:
Total Fugitive Lbs.Toluene Emitted: 0.00
Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2013
The Plant Material Grinder(OS-3) is operated in building ID# 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.
7
COPY of RECORD Date Submitted: 4/9/201410:36:48
Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility I : 0800044
841 Avoca Farm Road Permit : 0 Berle
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sin this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
.F.RTIFICATION STATEMENT!
L
the responsible official for this facility,as described above,and hereby certify that the information contained
ns report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Si ature Below use blue ink): Date Signed:
rioted Name: David e e i�'/• _e'���
Si nature:
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official:
david.peele@avocaine.com
Information on this Form cannot be held confidential ij 6 ZQ�
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered In AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
Listing of Emission Sources and Control Devices on Permit. See instructions
DES ID on Air DES Description GCS ID GCS Description CD ID's
Permit
one(1)jet ejector
One distillation column venturi—type wet scrubber
A-2 (6 gallons per minute CS-1 (10 GPM injection rate, CD—M-34
nominal process rate) ID No.M-34) Sclareolide
[MACT FFFF] O s.
one condenser(ID No.
One centrifuge[MACT CS-11 CD-3001)installed on CD—EX-3001
C-3001 FFFF] centrifuge,reactor and
heat exchanger/dryer
C-31203 One centrifuge [MACT
FFFF]
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-1201 One steam—heated dryer CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
[MACT FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
rocess)
one(1)jet ejector
venturi—type wet scrubber
D-1202 One steam—heated dryer CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
Ops.
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-1215 One reactor[MACT CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
process)
D-1218 One reactor[MACT CS-7 One(1)water spray CD—Z-9215,CD—Z-9216
FFFF] fume scrubber used in the
EVG Operation(batch
flavorant process),One
(1)caustic solution fume
scrubber used in the EVG
2
Operation(batch flavorant
process)
one(1)jet ejector
venturi—type wet scrubber
One batch reactor CS-1 (10 GPM injection rate, CD—M-34
D-1231 A [MACT FFFF]
ID No.M-34)Sclareolide
s.
one(1)jet ejector
venturi—type wet scrubber
D-1231B One batch reactor CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-2202 One reactor[MACT CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
process)
one condenser(ID No.
D 3001 One steam—heated dryer CS-11 CD-3001)installed on CD—EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/dryer
One waste solids
separator vessel(1,333
D3121 1 gallon capacity)[MACT
FFFF
One product extract
D31214 reactor MACT FFFF]
One No. 2 fuel oil—fired
emergency generator
6101 (587 horsepower
maximum rated power
output) [MACT ZZZZ]
One No.2 fuel oil—fired
emergency generator
G 102 (760 horsepower
maximum rated power
output)[MACT ZZZZ
One No. 2 fuel oil—fired
emergency generator
E103 (603 horsepower
maximum rated power
ou ut) [MACT ZZZZ]
Chilled Water—Cooled
Process equipment leaks Condenser,Packed Tower
ES-1001-1-1—F [PSD,MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
ES-1001-1-1—P1 JArcon process tank M-1 CS-17 Chilled Water—Cooled CD-31209,CD-1001-2—S-1
[PSD,CAM,MACT Condenser,Packed Tower
3
FFFF] Scrubber(10 gpm mineral
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Stripper T-5 and receiver Condenser,Packed Tower
ES-1001-1-1—P2 M-21 [PSD,CAM, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Seven process tanks of Chilled Water—Cooled
various capacities and Condenser,Packed Tower
ES-1001-1-1-P3 one fixed roof methanol CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
storage tank(7,050 oil scrubbing liquid
gallon capacity) [PSD, injection rate),
MACT FFFF]
Chilled Water—Cooled
Recovery Operations Condenser,Packed Tower
ES-1001-1-1—WW wastewater stream[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed Tower
ES-1001-1-2—F Process equipment leaks CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
[MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Six process tanks of Condenser,Packed Tower
ES-1001-1-2—P various capacities[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Concrete Operations Condenser,Packed Tower
EES-1001-1-2-WW wastewater stream CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
[MACT FFFF] oil scrubbing liquid
injection rate),
one(1)jet ejector
venturi—type wet scrubber
Process equipment leaks CS-1 10 GPM injection rate, CD—M-34
ES-1001-1-3—F [MACT FFFF]
ID No.M-34)Sclareolide
O s.
one(1)jet ejector
Twelve process tanks of venturi—type wet scrubber
ES-1001-1-3—P various capacities CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
Biological conversion one(1)jet ejector
equipment for the venturi—type wet scrubber
ES-1001-1-3—WW purification of sclareolide CS-1 (10 GPM injection rate, CD—M-34
wastewater stream ID No.M-34)Sclareolide
MACT FFFF] O s.
ES-1001-1-4—F Process equipment leaks CS-1 I one(1)jet ejector CD—M-34
[MACT FFFF] venturi—type wet scrubber
(10 GPM injection rate,
4
ID No.M-34)Sclareolide
O s.
one(1)jet ejector
venturi-type wet scrubber
Four process tanks of ES-1001-1-4-P various capacities CS-1 (10 GPM injection rate, CD-M-34
ID No.M-34) Sclareolide
s.
one(1)jet ejector
SDE Operations venturi-type wet scrubber
ES-1001-1-4-WW wastewater stream CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
s.
Chilled Water-Cooled
Process equipment leaks CS-16 Condenser,Liquid CD-100111EX1002,CD-100111EX1003
ES-1001-11-F [PSD,MACT FFFF] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-1001,desolventizer
Z-1002,day tank 90024
(6,000 gallon capacity),
first-stage evaporator Chilled Water-Cooled
ES-1001-11-P EX-1012,second-stage CS-16 Condenser,Liquid CD-1001 1 1EX1002,CD-1001 11 EX 1003
evaporator EX-1013, Nitrogen-Cooled
distillation column Condenser,
EX-90008,and nine
process tanks of various
capacities [PSD,CAM,
MACT FFFF
Botanical extraction Chilled Water-Cooled
ES-1001-11-WW operation wastewater CS-16 Condenser,Liquid CD-1001 1 1EX1002,CD-1001 1 IEX1003
stream[PSD,MACT Nitrogen-Cooled
FFFF] Condenser,
Chilled Water-Cooled
Condenser,Packed Tower
Process equipment leaks ES-1001-2-1-F [PSD,MACT FFFF] CS-17 Scrubber(10 gp m mineral CD-31209,CD-1001-2-5-1
oil scrubbing liquid
injection rate),
Rotocel extractor, Chilled Water-Cooled
desolventizer,and Condenser,Packed Tower
solvent CS-17 Scrubber 10 m mineral CD-31209,CD-1001-2-S-1
ES-1001-2-1-P1 separation/recovery
[PSD,CAM,MACT oil scrubbing liquid
FFFF] injection rate),
Chilled Water-Cooled
Two solvent recycle Condenser,Packed Tower
ES-1001-2-1-P2 process tanks[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
CAM,MACT FFFF] oil scrubbing liquid
injection rate),
ES-1001-2-1-WW Rotocel Operations CS-17 Chilled Water-Cooled CD-31209,CD-1001-2-5-1
wastewater stream[PSD, Condenser,Packed Tower
MACT FFFF] Scrubber(10 gpm mineral
oil scrubbing liquid
5
injection rate),
one condenser(ID No.
rES-1003-10-F Process equipment leaks CS-11 CD-3001)installed on CD-EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/drver
cess tanks of
EJ:;J
capacities
FFFF
Enesat
ser(ID No.
cess wastewater CS-11nalled onCD-EX-3001
[MACT FFFF] ctor andger/dryer
ES-1003-2-1-F Process equipment leaks
CT FFFF]
Seven process tanks of
ES-1003-2-1-P various capacities
MACT FFFF
PNE process wastewater
ES-1003-2-1-WW stream[MACT FFFF]
one(1)jet ejector
venturi-type wet scrubber
ES-1003-2-2-F Process equipment leaks CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34)Sclareolide
O s.
one(1)jet ejector
EVG Operation venturi-type wet scrubber
ES-1003-2-2-WW wastewater stream CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
S.
Chilled Water-Cooled
Biomass extraction :CS-:21 Condenser,Liquid CD-1004-2EX1002,CD-1004-2EX1003
ES- ]004-1 debagging[PSD] Nitrogen-Cooled
Condenser,
Chilled Water-Cooled
Process equipment leaks CS-21 Condenser,Liquid CD-1004-2EX1002,CD-1004-2EX1003
ES-1004-2-F [PSD] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-41001,desolventizer
Z-41002,day tank
490025 (9,953 gallon
capacity),isohexane
storage tank 490024 Chilled Water-Cooled
ES-1004-2-P (13,536 gallon capacity), CS-21 Condenser,Liquid CD-1004-2EX1002, CD-1004-2EX1003
first stage evaporator Nitrogen-Cooled
EX-41012,second stage Condenser,
evaporator EX-41013,
distillation column
EX-490008,and nine
process tanks of various
capacities [PSD,CAM]
6
Chilled Water-Cooled
Biomass extraction Condenser,Liquid
ES-1004-2-WW operation wastewater CS-21 CD-1004-2EX1002,CD-1004-2EX1003
Nitrogen-Cooled
stream[PSD] Condenser,
Bagfilter(254 square CD-1004-2-FF2
ES-1004-2Silo Biomass silo loadout CS-23 feet of filter area),
One biomass/bio-based
solids-fired boiler(24 one simple cyclone(144
million Btu per hour CS-24 inches in diameter),one CD-BB IC,CD-BB 1BH
ES-BB 1 maximum heat input rate) bagfilter(8,900 square
[NSPS-Dc,MACT- feet of filter area),
DDDDD
One biomass/bio-based
solids-fired boiler(24 one simple cyclone(144
million Btu per hour CS-24 inches in diameter),one CD-BB1C,CD-BB1BH
ES-BB2 maximum heat input rate) bagfilter(8,900 square
[NSPS-Dc,MACT- feet of filter area),
DDDDD]
ES-MDSU-1024 molecular sieve
Imaxnnum
o.2 fuel oil-fired Oxidation Catalyst
d use emergency [17,070 acfm(6,854
ES-PkGenitor(2,935 kilowatt CS-22 CD-CatOxl
scfin)inlet air flow rate at
rated power 695 OF-835 OF],
) [MACT ZZZZ]
neNo. 2 fuel one simple cyclone(144
oil/propane-fired rotary inches in diameter),one
ES-RD dryer(30 million Btu per CS-24 CD-BBIC,CD-BB1BH
bagfilter(8,900 square
hour maximum heat input feet of filter area),
rate)
One No. 2 fuel oil-fired
emergency fire water
FP pump(285 horsepower
maximum rated power
ou ut) [MACT ZZZZ]
one(1)jet ejector
venture-type wet scrubber
One centrifuge[MACT CS-1 (10 GPM injection rate, CD-M-34
-1 FFFF]
ID No.M-34) Sclareolide
O S.
One No.2 fuel oil-fired
boiler(20.3 million Btu
H-101 per hour maximum rated
heat input)[2D .1109
case-by-case MACT]
One No. 2 fuel oil-fired
boiler(20.3 million Btu
H-102 per hour maximum rated
heat input) [21) .1109
case-by-case MACT
H-103 One No.2 fuel oil-fired
boiler(25.2 million Btu
per hour maximum rated
7
heat input)[2D.1109
case—by—case MACT]
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
HB-1 box[MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed Tower
HB-2 One steam—heated hot CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
box [MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
HB-3 box [MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
H 13 4 box [MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
ECS process:batch
IECS preparation of
ethylenediamine/copper
sulfate solution
IES—PV propane vaporizer
No. 2 fuel oil storage
ITK102 tank(495 gallon
capacity)
No.2 fuel oil storage
ITK103 tank(495 gallon
ca aci )
No.2 fuel oil storage
ITK9238 tank(50,000 gallon
ca aci )
No. 2 fuel oil storage
ITK9239 tank(50,000 gallon
capacity)
No.2 fuel oil storage
ITKFP tank(270 gallon
capacity)
Wastewater treatment
IW WTP—AT2 plant aeration tank No.2
(63,500 gallon capacity)
Wastewater treatment
IWWTP-AT3 plant aeration tank No. 3
(63,500 gallon capacity)
Wastewater treatment
IWWTP—CLR plant clarifier(1,310
gallon capacity)
8
Wastewater treatment
IWWTP-ET1 plant equalization tank
No. 1 (65,500 gallon
capacity)
Wastewater treatment
IWWTP-ET2 plant equalization tank
No.2(65,500 gallon
capacity)
one(1)jet ejector
venturi-type wet scrubber
M-10 One batch reactor CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
one(1)jet ejector
venturi-type wet scrubber
M-10A One batch reactor CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34)Sclareolide
s.
one(1)jet ejector
One acetic acid storage venturi-type wet scrubber
M-20 tank(10,135 gallon CS-1 (10 GPM injection rate, CD-M-34
capacity)[MACT FFFF] ID No.M-34) Sclareolide
O s.
One plant material one(1)fabric filter(244
grinder(1,011 pounds CS-4 square feet of filter CD-1003-4-1
MHL- 1002 per hour nominal feed surface area,ID No.
rate) CD-1003-4-1)
one condenser(ID No.
R-3001 One reactor[MACT CS-11 CD-3001)installed on CD-EX-3001
FFFF] centrifuge,reactor and
heat exchanger/dryer
one reactor[MACT
R-3002 FFFF]
one condenser(ID No.
One hexane storage tank CD-3001)installed on
T-3001 (6,700 gallon capacity) CS-11 CD-EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/dryer
Four process tanks one condenser(ID No.
T-3002 through CD-3001)installed on CD-EX-3001
T-300 [MACT FFFF] (2,500 CS-11 centrifuge,reactor and
gallons capacity each) heat exchanger/dryer
T-3003 one process tank[MACT
FFFF]
T-3004 one process tank[MACT
FFFF]
T-3005 one process tank[MACT
FFFF]
Wastewater treatment
W WTP-AT I plant aeration tank No. 1
[PSD,MACT FFFF]
9
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
Emission Source & Operating Scenario List - See Instructions
DES Group ID RES ID S!28
ID *OS Description
GRl ES-1004-1,ES-1004-2-F, Extraction of Fermented Biomass
ES-1004-2-P,ES-1004-2-WW
Biomass Boiler Operation with
GR2 ES-BB1,ES-BB2,ES-RD 33 Wood Chips as fuel source
G-76 H-101,H-102,H-103 1 Boilers
G-77 E101,E102,E103 2 Generators
ES-1001-1-2-P,ES-1001-1-2-WW,
ES-1001-2-1-F,ES-1001-2-1-P1,
ES-1001-2-1-P2,ES-1001-2-1-WW, Rotocel, Sage,Recovery,and
G-94 HB-1,HB-2,HB-3,HB-4, 35 Distillation
ES-1001-1-1-F,ES-1001-1-1-P1,
ES-1001-1-1-P2,ES-1001-1-1-P3,
ES-1001-1-1-WW,ES-1001-1-2-F
ES-1001-1-3-F,ES-1001-1-3-P,
ES-1001-1-3-WW,ES-1001-1-4-F,
ES-1001-1-4-P,ES-1001-1-4-WW, 36 Conversions(Sclareolide SDE:
G-95 ES-1003-2-2-F,ES-1003-2-2-WW, Biological and Chemical)
G-17,M-10,M-10A,M-20,A-2,
D-1202,D-1231A,D-1231B
ES-1003-10-F,ES-1003-10-WW,
G-96 R-3001,T-3001,T-3002 through 39 Sclazeol Re-crystallization(SFG)
T-300,C-3001,D-3001
ES-1003-2-1-F,ES-1003-2-1-P, 37 Plant Nutrient Extraction(PNE
G-97 ES-1003-2-1-WW,C-31203,D31211, 38 PNE-Isohexane Extraction
D31214
G-99 D-1201,D-1215,D-1218,D-2202 9 EVG(batch flavorant)
Botanical extraction process
G-150 ES-1001-11-F,ES-1001-11-P, 40 (includes botanical vents,
ES-1001-11-WW condensers,tanks,etc)
ES-1003-10-P.13A NONE NONE
ES-1004-2Silo 30 Silo load out of spent biomass
ES-MDSU-1024 NONE NONE
ES-PkGenl 12 Peak Shaving Generator.
FP NONE NONE
IECS 31 EDA Process
IES-PV NONE INONE
10
ITK102 NONE NONE
ITK103 NONE NONE
ITK9238 NONE NONE
ITK9239 NONE NONE
IMP NONE NONE
IWWTP—AT2 NONE NONE
IWWTP—AT3 NONE NONE
IWWTP—CLR NONE NONE
IWWTP—ETl NONE NONE
IWWTP—ET2 NONE NONE
MHZ-1002 34 Misc: Plant MMIGrinder
R-3002 NONE NONE
T-3003 NONE NONE
T-3004 NONE NONE
T-3005 NONE NONE
Waste Water Treatment 1st
32 Aeration Chamber(Includes
WWTP—AT1 methanol usages from PNE and
EVG)
11
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group GRl consisting of ES—1004-1,ES-1004-2—F,ES-1004-2—P,
Emission Source Group ID ES-1004-2—WW
2. Emission Source Description: Biomass Extraction Operation
3. Operating Scenario ID/Description: OS—28/Extraction of Fermented Biomass
4. SCC Number/Description: 39999994/Miscellaneous Industrial Processes ;Other Not Classified
5. Throughput/units in 2013: 563752 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /a Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(°/n of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-21 CD-1004-2EX1002 One chilled water condenser
2 CS-21 CD-1004-2EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
averse outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ent lines
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-4 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
12
Operating Scenario: OS—28 Emission Source/Group ID: GR1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours Day Days per Week ( 7 ) Weeks per Year ( 52 )
P Y ( 24 )
I I.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
an—Feb +Dec 0"o arch—May 30% une—Aug. 41"Vo Sept.—Nov. 29%
013 013 �013 2013
13. Aetna l Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation in
used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
E
CO 08 0
NOx 08 0
TSP 08 0
PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 26.16 08 98
Emissions Emission Control
HAP/TAP Pollutants (►n CAS HAP/TAPS Estimation Efficiency Emission EF Control
(see instructions) pounds/Year Method Code (Net after all Factor
Alphabetical Order) ( ) See Instructions controls)
2013
Ethyl acetate 141-78-6 439.12 08 98
Hexane (isomers, HEXANEISO 41277.47 08 98
except n—hexane
Hexane n— 110-54-3 71.53 08 98
13
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility H) : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source H)(from permit)or Group GR2 consisting of ES—BB1,ES—BB2,ES—RD
Emission Source Group ID
2. Emission Source Description: Biomass Boilers
3. Operating Scenario ED/Description: OS—33Biomass Boiler Operation with Wood Chips as fuel source
4. SCC Number/Description: 10200904Bark;Bark—fired Boiler(<50,000 Lb Steam)
5. Throughputtunits in 2013: 21779 TON/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) FSulfur 1 0 /o Ash 1 0 Heat Content 8000000 Btu/ton
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-24 CD—BB1C one simple cyclone 144 inches in diameter
2 CS-24 CD—BB 1BH one ba filter(8,900 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines :
ERP ID ERP Type Height Nameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/see) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
Biomass Boilers
EP—BB 1 VERTICAL STACK 60 3 240.8 24 10178.76 Exhaust
14
Operating Scenario: OS— 33 Emission Source/Group ID: GR2
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 250�o arch—May 24"�o une—Aug. 24"�u Sept.—Nov. 27%
013 013 013 2013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants CAS Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Carbon Dioxide CO2 124389 16987.6 08 0
Methane CH4 74-82-8 1.83 08 0
Nitrous Oxide 20 10024972 1.13 08 0
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 16.73 08 99
NOx NOx 19.17 08 99
TSP TSP 0.12 08 99
PM10 PM10 0.12 08 99
PM2.5 PM2.5 0.12 08 99
S02 S02 2.18 08 99
VOC VOC 1.48 08 99
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldeh de 75-07-0 144.6 08 99
Acrolein 107-02-8 696.9 08 99
Benzene 71-43-2 731.8 08 99
Benzo(a)pyrene(Component of 50-32-8 0.453 08 99
POMTV POM7
Carbon tetrachloride 56-23-5 7.84 08 99
Chlorine 7782-50-5 137.6 08 99
Chlorobenzene 108-90-7 5.75 08 99
Chloroform 67-66-3 4.88 08 99
Eth lbenzene 100-41-4 5.4 08 99
Formaldehyde 50-00-0 766.6 08 99
15
Hexane(isomers,except HEXANEISO 4089.7 08 0
n—hexane
Hexane n— 110-54-3 5.64 08 0
Hydrogen chloride 7647-01-0 15.68 08 99
(hydrochloric acid
Mercury Unlisted Compounds HGC—Other 0.051 08 99
(Specify Component of HGC
Naphthalene (Component of 91-20-3 16.9 08 99
POMTV
Phenol 108-95-2 8.87 08 99
Pro ionaldeh de 123-38-6 10.63 08 99
S rene 100-42-5 331.04 08 99
Toluene 108-88-3 160.29 08 99
X lene 1330-20-7 4.36 08 99
16
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-76 consisting of H-101,H-102,H-103
Emission Source Group ID
2. Emission Source Description: Boilers
3. Operating Scenario ID/Description: OS— 1/Boilers
4. SCC Numb er/Description: 2020040 1/Diesel;Diesel
5. Throughputtunits in 2013: 442180.4 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash 0 Heat Content 141000 Btu/gallon
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ent lines
qIDERP Type Height iameter Temperature Velocity Volume Flow EPP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
boiler:vertical with
ICAL STACK 45 2.2 425 34.5 7868.74 min ca
boiler:vertical with
EP—B-3 VERTICAL STACK 45 2.5 500 34.6 10190.54 rain ca
EP—B-2 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler:Horizontal
17
Operating Scenario: OS- 1 Emission Source/Group ID: G-76
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Through ut:
�an-Feb +Dec 18% arch-May 5% une-Aug. 35% OP3-Nov. 42%
013 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions- Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants CAS Pollutants Method Code (Net after Factor
actor
See Instructions all controls
2013
Carbon Dioxide CO2 124389 5018.7476 08 22.7
Methane CH4 74-82-8 0.0133 08 0.00006
Nitrous Oxide 20 10024972 0.0265 08 0.00012
Emissions- Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 1.11 08 0.005
NOx NOx 5.31 08 0.024
TSP TSP 0.73 08 0.0033
PM10 PM10 0.22 08 0.001
PM2.5 PM2.5 0.06 08 0.00025
S02 S02 9.42 08 0.0426
VOC VOC 0.04 08 0.0002
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical HAP/TAPS
(see instructions) Method Code (Net after all Factor
Order) (Pounds/Year) controls)
See Instructions
2013
Arsenic Unlisted
Compounds(Specify ASC-Other 0.26186 08 5.922E-7
Component of ASC
Benzene 71-43-2 1.216 08 0.00000275
Beryllium Compound,
Unlisted (Specify BEC-Other 0.18572 08 4.2E-7
Com onent of BEC
Cadmium Unlisted
Compounds (Specify CDC-Other 0.18572 08 4.2E-7
Component of CDC
Chromium (VI) NSCR6-Other 0.18572 08 4.2E-7
Non-Specific,Unlisted
18
R
at
f CRC—Other 0.01282 08 2.9E-8
Eth 1 benzene 100-41-4 0.36126 08 8.17E-7
Fluorides(sum
of all 16984-48-8 16.49333 08 0.0000373
fluoride compounds)
Formaldehyde 7PBC—Other
0 21.22466 08 0.000048
Lead Unlisted Compounds 0.00000126
(Specify and Component of 0.55715 08
PBC
Manganese Unlisted
Compounds(Specify MNC—Other 0.37143 08 :8.4E-7
Component of MNC
Mercury Unlisted
Compounds(Specify HGC—Other 0.18704 08 4.23E-7
Component of HGC
Naphthalene(Component of 91-20-3 0.14725 08 3.33E-7
POMTV
Nickel Unlisted Compounds NIC—Other 0.18572 08 4.2E-7
(Specify Component of NIC
Toluene 108-88-3 35.24178 08 0.0000797
X lene o— 95-47-6 0.61905 08 0.0000014
19
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or Group G-77 consisting of E101,E102, E103
Emission Source Group ID
2. Emission Source Description: Generators
3. Operating Scenario ID/Description: OS —2/Generators
4. SCC Number/Description: 20100102/Distillate Oil(Diesel) ; Reciprocating
5. Throughputlunits in 2013: 4002.3 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /a Sulfur 0.0014 /o Ash 0 Heat Co77E:00 Btu/gallon(Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emissio:Release Point ERP Information: Sources vented to more than one ERP use additional entr linesERP IDERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP101 VERTICAL STACK 12 0.67 1063 160.9 3403.66 Vertical
EP102 VERTICAL STACK 11 0.67 885 203.4 4302.7 Vertical
EP103 VERTICAL STACK 10 0.67 1063 174.4 3689.24 Vertical
20
Operating Scenario: OS —2 Emission Source/Group ID: G-77
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 60 I arch—May 14% une—Aug. 13% Sept.—Nov. 13%
013 013 013 013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Carbon Dioxide CO2 124389 12.41 09
Methane CH4 74-82-8 0.0025 09
Nitrous Oxide 20 10024972 0.0003 09
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
=PM2.5PM2.05
0.24 09
0.09 09
0.03 09
0.03 09
0.03 09
S02 S02 0.04 09
VOC VOC 0.1 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (in Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldehyde 75-07-0 0.014 09
Acrolein 107-02-8 0.004 09
Arsenic Unlisted Compounds ( ASC—Other 0.002 09
Fecif Com onent of ASCBenzene 71-43-2 0.438 09
o(a)pyrene(Component of 50-32-8 0.0001 09
POMTV POM7llium Compound,Unlisted BEC—Other 0.002 09
(Specify Component of BEC
Cadmium Unlisted Compounds CDC—Other 0.002 09
(Specify Component of CDC
21
Formaldehyde 50-00-0 0.045 09
Naphthalene (Component of 91-20-3 0.073 09
POMTV
Toluene 108-88-3 0.159 09
X lene 1330-20-7 0.109 09
22
COPY of RECORD Date Submitted: 419/201 4 1 0:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-94 consisting of ES-1001-1-2—P,ES-1001-1-2—WW,
Emission Source Group ID ES-1001-2-1—F,ES-1001-2-1—P1,ES-1001-2-1—P2,ES-1001-2-1—WW,
HB-1,HB-2,HB-3,HB-4,ES-1001-1-1—F,ES-1001-1-1—P1,
ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2—F
2. Emission Source Description: Rotocel,Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—35/Rotocel, Sage,Recovery,and Distillation
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 94644819 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-17 CD-31209 One chilled water condenser
2 CS-17 CD-1001-2—S-1 One packed tower scrubber(8 gallons per minute minimum mineral oil
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1001-11-1 VERTICAL STACK 42 0.5 68 127.4 1500.89 Vertical
23
Operating Scenario: OS—35 Emission Source/Group ID: G-94
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
FSeNov. 39/o
an—Feb +Dec 20% 1% �013—Aug 40% 0
013 �arch—May
13
13. Actual Emissions per Pollutant Usted
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants
CAS Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 826.56 03 98
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In HAP/TAPS
(see instructions) pounds/Year) Method Code (Net after all Factor
Alphabetical Order) ( See Instructions controls)
2013
Hexane(isomers, HEXANEISO 1352806.09 03
exce tn—hexane
Hexane n— 110-54-3 2041.36 03
Methanol 67-56-1 300938.8 03
24
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-95 consisting of ES—100 1—1-3—F,ES—1001-1-3—P,
Emission Source Group ID ES-1001-1-3—WW,ES-1001-1-4—F,ES-1001-1-4—P,
ES-1001-1-4—WW,ES-1003-2-2—F,ES-1003-2-2—WW,G-17,M-10,
M-10A,M-20,A-2,D-1202,D-1231A,D-1231B
2. Emission Source Description: Conversions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—36/Conversions(Sclareolide SDE: Biological and Chemical)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 474005.4 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(°/u of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed in ennit
1 CS-1 CD—M-34 One venturi—type wet scrubber(10 gallons per minute minimum liquid
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry fines):
ERP ID ERP Type Height Nameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feetlsec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-1 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
25
Operating Scenario: OS— 36 Emission Source/Group ID: G-95
10.operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 23a/o arch—May 19% 111 Aug. 31o/a 3ept.-1 27'
013 013 �013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 59.14 03 98
Emissions Emission Control
HAP/TAP Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order
(see instructions) (Pounds/Year) Method Code (Net after all Factor
P ) See Instructions) controls)
2013
Hexane (isomers, HEXANEISO 71313.31 03 98
except n—hexane
Hexane n— 110-54-3 46968.59 03 98
26
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-96 consisting of ES-1003-10—F,ES-1003-10—WW,R-3001,
Emission Source Group ID T-3001,T-3002 through T-300,C-3001,D-3001
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—39/Sclareol Re—crystallization(SFG)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013: 611422 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur I Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD II) Control Device Description
as listed inpermit)
1 CS-11 CD—EX-3001 One chilled water condenser
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height iameter Temperature Velocity Volume ERP
(in feet) Circle(enter (F) (Feettsec) Flow Rate Description
): (Acfm)
ectangle(L x
in 0.1 feet)
P-1003-10-1 DOWNWARD—FACING VENT 19 0.17 80 3 4. Horizontal
P-1003-10-3 HORIZONTAL STACK 19 0.17
80J"'p-
0.1 0.1133 Horizontal
1003-10-4 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-5 HORIZONTAL STACK 25 0.17 80 10.2 13.89 Horizontal
P-1003-10-61 HORIZONTAL STACK 30 0.17 100 0.1 0.13 Horizontal
27
P-1003-10-7 VERTICAL STACK 19 0.17 80 53 72.17 Vertical
IEP-1003-10-21 HORIZONTAL STACK 1 18 0.17 80 0.1 0.13 IT Horizontal
28
Operating Scenario: OS— 39 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 220�o 140�o une—Aug. 35"�o Sept.—Nov. 29%
013 �arch—May
13 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 70.92 03 98
Emissions Emission Control
HAP/TAP Pollutants (1❑ CAS HAP/TAPS Estimation Efficiency Emission EF Control
(see instructions) Method Code (Net after all Factor
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 141-78-6 8765 03 0
Hexane(isomers, HEXANEISO 12078.54 03 98
except n—hexane
Hexane n— 110-54-3 120992.31 03 98
29
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit)or Group G-97 consisting of ES-1003-2-1—F,ES-1003-2-1—P,
Emission Source Group ID ES-1003-2-1—WW,C-31203, D31211,D31214
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS —37/Plant Nutrient Extraction(PNE)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in
Comments Field
5. Throughput/units in 2013: 7343.04 LB/yr
(e.g. production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Control Device Description
Order CS—ID CD ID
as listed inpermit)
9. Emission Release PointZnlormatjon: Sources vented to more than one ERP use additional ent lines
ERP ID ERPTmeter Temperature Velocity Volume FlowERP Description
cle(enter#): (F) (Feet/sec) Rate(Acfm)
tangle(L x W)
.1 feet)
P-1003-2-1 VERTICA1 75 53 2497.56 Veritical
30
Operating Scenario: OS —37 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25"vo S 013
ept.—Nov. 25%
013 013 �013
t13. Actual Emissions Aer Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 0.57 03
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In HAP/TAPS
(see instructions) Method Code (Net after all Factor
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 141-78-6 47.29 03
Methanol 67-56-1 4.44 08
31
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-97 consisting of ES-1003-2-1—F,ES-1003-2-1—P,
Emission Source Group ID ES-1003-2-1—WW,C-31203,D31211,D31214
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ED/Description: OS—38/PNE—Isohexane Extraction
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013:
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) Sulfur /o Ash Heat Content
ro
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS-11) CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try tines):
ERP ID ERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Vcritical
32
Operating Scenario: OS — 38 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
�an—Feb +Dec 25a�o arch—May 250�o une—Aug. 25"�u Sept.—Nov. 25%
013 013 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emissions Emission Control
HAP/TAP CAS Estimation Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code Alphabetical Order) (Pounds/Year) Net after all controls)
)
See Instructions
2013
33
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-99 consisting of D-1201,D-1215,D-1218,D-2202
Emission Source Group ID
2. Emission Source Description: EVG(batch flavorant)
3. Operating Scenario ID/Description: OS—9/EVG (batch flavorant)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in
Comments Field
5. Throughputtunits in 2013: 11220 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o$u]fur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-7 CD—Z-9215 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
2 CS-7 CD—Z-9216 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e trV lines):
ERP ID ERP Type Height *a meter
Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#). (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
34
Operating Scenario: OS — 9 Emission Source/Group ID: G-99
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec T7120�oT�orch—May 380�o une—Aug. 230�o Sept.—Nov. 27%
013 3 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 10.51 03 98
HAP/TAP CAS Emissions Emission Estimation Control Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
Chloroform 67-66-3 17018 03 0
Methanol 67-56-1 4011.06 03
35
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-150 consisting of ES—1001-11—F,ES—1001-11—P,
Emission Source Group ID ES-1001-11—WW
2. Emission Source Description: Botanical Extraction Operations
3. Operating Scenario ID/Description: OS—40/Botanical extraction process(includes botanical vents,condensers,
tanks,etc)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 193325 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) Sulfur TOAsh Heat Content/a
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information:
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-16 CD-100111EX1002 One chilled water condenser
2 CS-16 CD-100111EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP i Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-11 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
36
Operating Scenario: OS—40 Emission Source/Group ID: G-150
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu7400%
t:
an—Feb +Dec arch—May une—Aug. 3% Sept.—Nov. 60�u51% 013 013 013
013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission C:er
l
GHG CAS GHG Estimation Efcy Emission Ef Control
Pollutants Pollutants Method Code ( Factor
Tons/Year See Instructions allls
2013
Emissions— Emission Control
Criteria Emission
Pollutant Criteria Estimation Efficiency Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
XPM2.15;
CO 08 0
NOx 08 0
TSP 08 0
PM10 08 0
PM2.5 08 0
S02 S02 08 0
VOC VOC 52.91 03 98
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (in HAP/TAPS Net after all Factor
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 1
141-78-6 375.29 03 0
37
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or ES-1004-2Silo
Emission Source Group ID
2. Emission Source Description: Biomass silo loadout
3. Operating Scenario ED/Description: OS—30/Silo load out of spent biomass
4. SCC Number/Description: 39999994/Miscellaneous Industrial Processes ;Other Not Classified
5. Throughputtunits in 2013:
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur fo Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed in ermit
1 CS-23 CD-1004-2—FF2 One ba tlter 254 square feet of filter area
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional en lines):
ERP ID ERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
ectangle(L x
in 0.1 feet)
Dust Collector on
P-1004-2—FF2 HORIZONTAL STACK 10 8.5 72 0.64 2180 Silo
38
Operating Scenario: OS—30 Emission Source/Group ID:
ES-1004-2Silo
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% �une—Aug. 25% ept.—Nov. 25%
013 013 013 013
13. Actual Emissions ger Pollutant Usted
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
�QS) Code Pollutants Method Code (Net after Factor
Pollutants (TonsNear) (See Instructions) all controls)
2013
CO CO 08
NOa NOs 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP Emissions Emission Control Emission
CAS HAPPPAPS Estimation Efficiency EF Control
Alphabetical Order)Pollutants (see instructions) after all
ctions) Method Code y Factor
der) (Pounds/Year) controls)
See Instructions
2013
39
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bettie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or ES—PkGen1
Emission Source Group ID
2. Emission Source Description: One No. 2 fuel oil—fired limited use emergency generator(2,935 kilowatt
maximum rated power output) [MACT ZZZZ]
3. Operating Scenario ID/Description: OS — 12/Peak Shaving Generator
4. SCC Number/Description: 20300102/Distillate Oil(Diesel) ; Turbine
5. Throughput/units in 2013: 9558 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) %Sulfur 0.0014 /°Ash 0 Heat Content 141000 Btu/gallon
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
S. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-22 CD—CatOxl One catalv tic oxidizer 695 °F minimum inlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional en'
lines
ERP ID ERP Type eight iameter Temperature Velocity Volume Flow ERP
H Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-9 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
40
Operating Scenario:OS— 12 Emission Source/Group ID: ES—PkGenl
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 290�o 110�0 une—Aug. 480�o �013
ept.—Nov. 12'%
013 �arch—May
13 �013
13. Actual Emissions pgr Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2013
Carbon Dioxide CO2 124389 29.64 09 0
Methane CH4 74-82-8 0.006 09 0
Nitrous Oxide 20 10024972 0.005 09 0
Criteria Emissions
Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2013
CO CO 0.57 09 95 AFTER
NOx NOx 2.16 09 98 AFTER
TSP TSP 0.07 09 98 AFTER
PM10 PM10 0.07 09 98 AFTER
PM2.5 PM2.5 0.07 09 0
S02 S02 0.1 09
VOC VOC 0.24 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldehyde 75-07-0 0.03 09
Acrolein 107-02-8 0.01 09
Arsenic Unlisted Compounds( ASC—Other 0.005 09
Specify Component of ASC
Benzene 71-43-2 1.05 09
Benzo(a)pyrene(Component of 50-32-8 0.0004 09
POMTV POM7
Beryllium Compound,Unlisted BEC—Other 0.004 09
(Specify Component of BEC
Cadmium Unlisted Compounds CDC—Other 0.004 09
(Specify Component of CDC
41
1
Formaldehyde 50-00-0 0.106 09
Naphthalene(Component of 91-20-3 0.175 09
POMTV
Toluene 108-88-3 0.379 09
X lene 1330-20-7 0.26 09
42
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or IECS
Emission Source Group ID
2. Emission Source Description: ECS process: batch preparation of ethylenediamine/copper sulfate solution
3. Operating Scenario ID/Description: OS —31/EDA Process
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013:
(e.g. production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
43
Operating Scenario: OS— 31 Emission Source/Group ID: IECS
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o Var
ch—May 25"�u une—Aug. 25"�o Sept.—Nov. 25%
�013 13 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP CAS Emissions Estimation Control Emission
Pollutants On Efficiency Factor EF Control
(see instructions) HAP/TAPS Method Code Ef
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
44
I
COPY of RECORD Date Submitted: 419/201410:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or MHZ-1002
Emission Source Group ID
2. Emission Source Description: Misc: Grinder,air stripper, lime silo, and Aphios
3. Operating Scenario ID/Description: OS —34/Misc: Plant Material Grinder
4. SCC Number/Description: 31299999/Miscellaneous Machinery ; Other Not Classified
5. Throughput/units in 2013:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-4 CD-1003-4-1 One ba filter 244 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than on ry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1003-4-1 HORIZONTAL STACK 20 1.3 75 37.7 3002.4 Horizontal
45
Operating Scenario: OS — 34 Emission Source/Group ID: MHZ-1002
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
013 013 �013 2013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP CAS Emissions Estimation Control Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
46
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or WWTP—AT1
Emission Source Group ID
2. Emission Source Description: Wastewater treatment plant aeration tank No. 1 [PSD,MACT FFFF]
3. Operating Scenario ED/Description: OS—32/Waste Water Treatment 1st Aeration Chamber(Includes methanol
usages from PNE and EVG)
4. SCC Number/Description: 30182006/Wastewater Treatment;Chemical Plant Wastewater System:
Aerated Impoundment
5. Throughput/units in 2013: 9561581 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur Ash FHeat Content
Btu/units
7. Capture Efficiency
(0/9 of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional en lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-14 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
47
1
Operating Scenario: OS— 32 Emission Source/Group ID: WWTP—ATI
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu Orb ut:
�an—Feb +Dec 20% arch—May 1% une—Aug. 40% Sept.—Nov. 39%
013 013 013 013
13. Actual Emission per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
CASGHG Estimation Efficiency Emission Ef Control
:G:HG
nts Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions
Emission Control
Criteria Emission
Pollutant Criteria Estimation Efficiency Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants W
Tons/Year) (See Instructions) all controls)
2013
CO 08
Ox 08
SP 08
M10 08
M2.5 08
02 08
OC 2.92 03
Emission
HAS Emissions Estimation Control EmissionPoHAP/TAPS Efficiency EF Control
nstructions) Method Code Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
P See Instructions
2013
Methanol 67-56-1 5835.6 03
48
Facility Total CY 2013 Emissions Summary
COPY of RECORD Date Submitted: 4/9/201410:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
Record Facility—Wide Totals From all Permitted and Non—Permitted Air Pollutant Emission Sources
Green House Gases Pollutants(GHG)
Actual Emissions Tons/Year
Pollutant CAS 2013 2012 %Change
Carbon Dioxide CO2 124389 22048.398 33942.1755 —35.041294%
Methane CH4 74-82-8 1.8518 9.4356 —80.37433%
Nitrous Oxide 20 10024972 1.1618 1.2643 —8.10725%
Criteria Pollutants
Actual Emissions Tons/Year
Pollutant CAS 2013 2012 % Change
CO CO 18.65 43.64 —57.263977%
NOx NOx 26.73 24.08 11.004982%
PM SP TSP 0.95 1.073 —11.463184%
PM10 PM10 0.44 .443 —0.67719895%
PM2.5 PM2.5 0.28 .233 20.171677%
S02 S02 11.74 13.64 —13.929623%
VOC VOC 1051.55 931.29 12.913279%
Hazardous Air Pollutants S and/or Toxic Air Pollutants APs
Actual Emissions(Pounds/Year)
Pollutant CAS 1 2013 1 2012 % Change
Pollutant Grou :Arsenic Com ounds total mass of elemental AS arsine and all inorganic compounds) Group Sum:.26886
Arsenic Unlisted Compounds( ASC—Other 0.26886 .33464 —19.656939%
Svecify Component of ASC
Pollutant Groupffleryllium compounds(Total mass Group Sum:.19172
Beryllium Compound,Unlisted BEC—Other 0.19172 .38684 —50.439457%
(Specify Component of BEC
Pollutant Grou :Cadmium com ounds total mass inc elemental metal GroupSum:.19172
Cadmium Unlisted Compounds CDC—Other 0.19172 .80684 —76.23817%
(Specify Component of CDC
Pollutant Grou :Chromium on—Specific Com ounds as Chrom Com onent CRC Group Sum:.18572
Chromium(VI)Non—Specific, NSCR6—Other 0.18572 .23282 —20.230225%
Unlisted(Specify Component of
49
NSCR6 CRC
Pollutant Grou :Chromium-A1VTota1 Inc Chromium I categories,metal and Others Group Sum:.19854
Chromium(VI)Non-Specific,
Unlisted(Specify Component of NSCR6-Other 0.18572 .23282 -20.230225%
NSCR6 CRC
Chromium Unlisted Compounds CRC-Other 0.01282 2.43608 -99.47375%
(Specify Component of CRC
Pollutant Grou :Lead and Lead compounds Group Sum:.55715
Lead Unlisted Compounds PBC-Other 0.55715 7.37153 -92.441864%
(Specify and Component of PBC
Pollutant Grou :Man anese com ounds Group Sum:.37143
Manganese Unlisted Compounds MNC-Other 0.37143 222.46468T -
Pollutant99.83304%
(Specify Component of MNC
Group:Mercury Compounds-all total mass in Hiz Vapor Group Sum:.23804
Mercury Unlisted Compounds IHGC-Other 0.23804 .27051 -12.003249%
(Specify Component of HGC
Pollutant Grou :Nickel Com ounds sum total mass inc elemental Group Sum:.18572
Nickel Unlisted Compounds NIC-Other 0.18572 4.81682 -96.14435%
(Specify Component of NIC
Pollutant Grou :Pol c clic Or anic Matter 7 PAH Compounds for NIF Group Sum:.4535
Benzo(a)pyrene(Component of 50-32-8 0.4535 .36039 25.8359%
POMTV POM7
Pollutant Grou :Pol c clic Or anic Matter(Specific Co m ounds from OA PS for Group Sum:17.74875
Benzo(a)pyrene(Component of 50-32-8 0.4535 .36039 25.8359%
POMTV POM7
Naphthalene(Component of 91-20-3 17.29525 13.83879 24.976606%
POMTV
Acetaldehyde 75-07-0 144.644 115.13857 25.626013%
Acrolein 107-02-8 696.914 555.01168 25.567453%
Benzene 71-43-2 734.504 585.38843 25.472933%
Carbon tetrachloride 56-23-5 7.84 6.24 25.641031%
Chlorine 7782-50-5 137.6 109.61 25.535995%
Chlorobenzene 108-90-7 5.75 4.58 25.545855%
Chloroform 67-66-3 17022.88 4839.89 251.72038%
Ethyl acetate 141-78-6 9626.7 14052.59 -31.495188%
Ethyl benzene 100-41-4 5.76126 4.75289 21.21593%
Fluorides(sum of all fluoride 16984-48-8 16.49333 20.67684 -20.23283%
compounds)
Formaldehyde 50-00-0 787.97565 637.19606 23.662985%
Hexane(isomers,except HEXANEISO 1481565.1 1352727.17 9.524316%
n-hexane
Hexane n- 110-54-3 170079.44 130578.44 30.250784%
Hydrogen chloride(hydrochloric 7647-01-0 15.68 360.7 -95.65289%
acid
Methanol 67-56-1 310789.9 290491.38 6.9876537%
Phenol 108-95-2 8.87 7.08 25.282486%
Pro ionaldeh de 123-38-6 10.63 8.46 25.650118%
Styrene 100-42-5 331.04 263.61 25.579466%
Toluene 108-88-3 196.06978 526.5064 -62.76023%
X lene 1330-20-7 4.729 3.7557 25.915276%
50
X lene o— 95-47-6 0.61905 .77607 —20.232708
0/0
51
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Comments From Facility:
52
200 Emissions Inventory Review / Data Tracking Form
Facility Name: Avoca Incorporated Facility ID: 0800044
Facility Assigned to: Data Entry: Bertie County
Classification: Betsy Huddleston eth Confidential Copy Submitted?
Title V ❑ YES
NO
Initial Review/Data Entry
Er Enter date received into ED. Date Received: y/4 j2oi t1
Assigned to appropriate individual. Date Assigned: � IQI`/ Date Due:
E!f Paper copy submitted: One copy received with supporting documentation,certification form signed by responsible official,and
` appears generally complete;?Roo+A
)J Electronic copy submitted: All supporting documentation and certification form (with time/date stamp)signed by responsible
official has been received. , l
Comments: coo tvotPSr ac—
/ Inventory Review
(a All forms and supporting documentation appear to be complete if paper submission(check ED OS data if electronic).
Contact,address,phone number changes entered into I-Beam/Facilities if necessary.
All known operating scenarios,control devices,and emission release points have been entered for each emission source(permitted,
insignificant,and unpermitted)or note that the emission source was not operated or not required to report.
d Evaluate"U"sources for significance and address according to olicy.
® Calculations/forms appear to add up correctly.CO&P c f a as �, 16,,✓7a
db
I f All compliance issues are being addressed(e.g.Toxics limits,above TV thresholds,large emissions increase/decrease,installation
without a permit).
EI' All volatile HAPs/TAPs were included in the VOC total.
[( Calculations and control efficiencies appear correct. Emission factors are the best available and most current factors appropriate for
the reporting facility(e.g.stack testing,AP-42,etc.).
[�( Review facility comments and address any issues.
{� Update ED(Data Entry Main)if additional information is required(corrections due date and date received).
if Check all ED QA/QC reports.
Comparison with previous emission inventory must be made and outliers(> 101/6)must be investigated and explained.
L� Put inventory review comments and summarize any changes in ED-Data Entry Main"DAQ internal comments".
R/ Print and attach the facility total report.
Date Review Complete: 20i If Signature:
Date Submitted to El Coordinator:
Date Approved: s/ZoI y Initials:"r
1. Fuel oil consumption on H101-103 was 80%of the previous year. Generator fuel usage increased 1,589 gallons. Wood
boiler fuel usage increased in 2013 by 4,A36 tpy.
2. The metals categories for combustion established by the June 6, 2005 email from Brendan Davey(TPB and PWG approved)
were corrected in ED.
3. NOx emissions from H101-103 were recalculated to 4.42 tons (EF is 20.0 Ib/1000 gals).
4. NOx emissions from generators 101-104 was off an order of magnitude. The emission was corrected to 9.96 ton.
5. Generators 101-04 VOC emissions were corrected to 0.3 ton.
6. 1 added metal emissions to ED for the fire pup generator. I corrected NOx emission to 0.17 ton for the generator.
7. 1 added metals and corrected SO2 and VOC emissions for PK-generator.
8. Metals were added to the wood boiler emissions in ED.
9. 1 asked Brian Conner to separate the isohexane, n-hexane and methanol emissions into the controlled and fugitive fractions
at Rotocel/Recovery/Concrete, SFG and SDE. They have been reporting a total for each pollutant in each area of the plant. I
have created new OS and emission points in ED for the fugitives.
10. In the inventory forms several pollutants are quantified in the negative. Brian said that a campaign often does not end with
the month's end so at that point in the run the recovered solvent may show more than the used. At the campaign's end, the
actual final numbers will balance out (mass balance approach) as can be seen in the following month's totals. Therefore, if
the annual emissions total is in the negative, emissions are considered zero.
11. Avoca uses 3 varieties of Ethanol depending on the product/process and extraction requirements. I inventory each variety
separately just because it makes it easier to keep up with on my end and to match up with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs. of SDA Ethanol for a total of 8378 lbs. of Ethanol
emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs. of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment.Their bugs thrive on ethanol and Avoca assumes all ethanol is
consumed by the bugs.
12. The following notes concern pollutants that changed +/- 10%from 2012.
a) CO emissions decreased due to new stack test value on the wood boilers.
b) NOx emissions increased due to more wood combustion on the wood boilers.
c) The SO2 decrease is due to less firing in H101-103.
d) Metals increases are due to wood fuel increase. The metals categories for fuel combustion were changed this year, so
the totals look different in comparison to 2012. As a result the increases and decreases compared to 2012 appear large.
The increase in emissions for all metals except manganese is less than a pound.
e) Fluoride emissions decreased due to less operation of H101-103.
f) HCI emissions drastically decreased due to the difference between two stack tests (done 2/21/2013 and 12/2013).
g) Process solvent emissions are dependent on client demand. The associated HAPs are chloroform, ethyl acetate,
methanol, isohexane, n-hexane, and toluene.
h) All combustion HAPs increased due to the increase in wood combustion. I added ethylene dichloride,vinyl chloride,
methyl bromide, methyl chloride, methylene chloride, and phosphorus emissions to the wood combustion emissions
using DAQ spreadsheet. I also added several combustion toxics to the AERO data for the engines(NCDAQ
spreadsheets).
13. 1 added n-hexane and isohexane emissions to the WWTP, which accounts for the difference e in VOCs between what is now
in ED and what Avoca reported.
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Green House Gases Pollutants (GHG) Actual Emissions %Tons/Yr
Pollutant CAS CY 2013 CY 2012 Demini- Change
from ED from Fees mus
Carbon Dioxide (CO2) 124389 22,048.40 33,942.18 5,000.0 -35.0%
Nitrous Oxide(N20) 10024972 1.16 1.26 I .0 -8.1%
Methane (CH4) 74-82-8 1.85 9.44 10.0 -80.4%
CO2 equivalent(sum of individual GHG pollutant emission 20,364.32 metric tons
times their 1995 IPCC Global Warming Potential(GWP),
converted to metric tons)
Criteria Pollutants Actual Emissions
(Tons/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
CO Co 18.70 43.64 0.5 -57.1%
NOx Nox 27.84 24.08 0.5 15.6%
PM(TSP) TSP 0.970000 1.07 0.5 -9.6%
PM10 PM10 0.460000 0.4430010 0.5 3.8%
PM2.5 PM2.5 0.300000 0.233000 0.5 28.8%
S02 S02 11.85 13.64 0.5 -13.1%
VOC VoC 1,055.94 931.29 0.5 13.4%
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
Antimony & Compounds(total mass, inc elemental SB) Not 1.10 10.0 N/A
Reported
Antimony Unlisted Compounds-Speck Compound SBC-other Not 1.10 10.0 N/A
(Component of SBC) Reportcci
Arsenic& Compounds (total mass of'elemental AS, acshic (Iiul 4.10 3.38 0.01 'l•;"�
all inorganic compounds)
Arsenic Metal, elemental, unreacted(Component of 7440-38-2 Not 3.05 0.01 NiA
ASC) Reported
09/18/2014 Page 1 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPs) (Pounds/Year)
Pollutant CAS CY 2113 CY 2012 Demini- %
from ED from Fees mus Change
Arsenic Unlisted Compounds-Speck Compound ASC-other 4.10 0.334640 0.01 ,125.20/
(Component of ASC)
Beryllium & compounds (Total mass) 0.381720 0.386840 1.o -1.3%
Beryllium Metal(unreacted) (Component of BEC) 7440-41-7 0.381720 Not 1 .0 N/A
Reported
Beryllium Unlisted Compounds-Specify Compound BEC-Other Not 0.386840 1.0 N/A
(Component of BEC) Reported
Cadmium& compounds(total mass includes elemental metal) 0.901720 0.806840 0.1 11.80
Cadmium Metal, elemental, unreacted(Component 7440-43-9 0.901720 Not 0.1 N/A
of CDC) Reported
Cadmium Unlisted Compounds-Speck Compound CDC-other Not 0.806840 0. 1 N/A
(Component of CDC) Reported
Chroniiunr-A11/7otal(includes Chromium (VI) categories, 0.801720 3.16 11.l -74.6%
metal and others)
Chromic acid(VI) (Component of So1CR6& CRC) 7738-94-5 0.801720 0.494020 0.01 62.3%
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-other Not 0.232820 0.01 N/A
Speck Compound(Component of NSCR6& CRC) Reported
Chromium Unlisted Compounds-Specify CRC-other Not 2.44 0.1 N/A
Compound(Component of CRC) Reported
Chromium (VI)Non-Specific Compounds, as Chrom(VI) Not 0.232820 0.01 I N14
(Component CRC) Reported
Chromium (VI)Non-Specific Unlisted Compounds- NSCR6-Other Not 0.232820 0.01 N/:\
Specify Compound(Component of NSCR6& CRC) Reported
Chromium (VI)Soluble Chromate Compounds(Component of 0.801720 0.494020 0.01 02.3%
CRC)
Chromic acid(VI) (Component of So1CR6& CRC) 7738-94-5 0.801720 0.494020 (0)I 62.3%
Cobalt & compounds Not td 900000 1.0 N/A
Reported
Cobalt Unlisted Compounds-Speck Compound COC-other Not 0.900000 1.0 N/A
(Component of COC) Reported
Lead& compounds 8.93 7.37 1.0 21.2
09/11/1114 Page 2 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants(TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demmi-
from ED from Fees mus Change
Lead Unlisted Compounds-Spec6 Compound PBC-other 9.93 7.37 10.0 21.2%
(Component of PBC)
,
Manganese & compounds 2'9.l 5 222.40 10.o -5•?
Manganese Unlisted Compounds-Specify MNC-other 279.15 222.46 10.0 25.5%1
Compound(Component of MNC)
Mercury& Compounds-all total mass includes Hg Vapor 0.204250 0.270510 0.001 1-24.5%
Mercury Unlisted Compounds-Specify Compound HGC-other Not 0.270510 0.001 N/A
(Component of HGC) Reported
Mercury, vapor (Component of HGC) 7439-97-6 0.204250 Not 0.001 N/A
Reported
Nickel& Compounds,sum total mass includes elemental 5.94 4.82 1.0 23.2%
Nickel metal(Component of NIQ 7440-02-0 0.191720 Not 1.0 N/A
Reported
Nickel Unlisted Compounds(Component of NIC- NIC-Other 5.75 4.82 1.0 19.4%
Specify)
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.453500 0.360390 1.0 25.8%
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.453500 0.360390 1.0 25.8%
5655317PAH)
Polycyclic Organic Matter(Specific Compounds from OAQPS 17.76 14.20 1.0 25.1%
or TP)
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.453500 0.360390 1.0 25.8%
5655317PAH)
Naphthalene (Component of 833291POMM 91-20-3 17.31 13.84 1.0 25.1%
Acetaldehyde 75-07-0 144.73 115.14 10.0 25.7w/o
Acrolein 107-02-8 696.92 555.01 10.0 25.6%
Benzene 71-43-2 734.64 585.39 1.0 25.5%
Carbon tetrachloride 56-23-5 7.84 6.24 1.0 25.6%
Chlorine 7782-50-5 1 137.60 109.61 100.0 25.5%
Chlorobenzene 108-90-7 5.75 4.58 10.0 25.5%
09/18/2014 Page 3 of 6
i
Facility Total CY 2013 Emission Summary Recorded in 1?D Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demim- %
from ED from Fees mus Change
Chloroform 67-66-3 17,022.88 4,839.89 100.0 251.7%
DEHP(Di(2-ethylhexyl)phthalate) 117-81-7 Not 0.006500 10.0 N/A
Reported
Dinitrophenol, 2,4- 51-28-5 Not 0.025000 0.1 N/A
Reported
Ethyl acetate 141-78-6 9,626.70 14,052.59 10.0 -31.5%
Ethyl benzene 100-41-4 5.76 4.75 100.0 21.2%
Ethylene dichloride (1,2-dichloroethane) 107-06-2 5.05 4.02 1.0 25.6%
Fluorides(sum of all fluoride compounds as mass of B6984-48-8 16.49 20.68 10.0 -20.2%
ion)
Formaldehyde 50-00-0 788.10 637.20 10.0 23.7%
Hexane isomers,except n-hexane HEXANEISO 1.481,559.4 1,352,727.1 100.0 9.5%
3 7
Hexane,n- 110-54-3 170,088.44 130,578.44 100.0 30.3%
Hydrogen chloride (hydrochloric acid) 7647-01-0 15.68 360.70 100.0 -95.7%
MEK(methyl ethyl ketone, 2-butanone) 78-93-3 Not 0.750000 100.0 N/A
Reported
Methanol (methyl alcohol) 67-56-1 310,854.43 290,491.38 1,000.0 7.0%
Methyl bromide (bromomethane) 74-83-9 2.61 2.08 1.0 25.5%
Methyl chloride(chloromethane) 74-87-3 4.00 3.19 1.0 25.4%
Methyl chloroform 71-55-6 5.40 4.30 100.0 25.6%
Methylene chloride 75-09-2 50.53 40.23 1.0 25.6%
N/A
Perchloroethylene(tetrachloroethylene) 127-18-4 Not 5.27 100.0
Reported
Phenol 108-95-2 8.87 7.08 100.0 25.3%
Phosphorus Metal, Yellow or White 7723-14-0 4.70 1.75 1.0 25.3%
Polycyclic Organic Matter(Inc PAH, dioxins, etc.NCPOM 23.28 17.34 1.0 34.3%
&AP 42 historic)
Propionaldehyde 123-38-6 10.61 9.46 10.0
09/18/2014 Page 4 of 6
Facility Total CY 2013 Emission Summary Recorded in ED Facility ID#: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T42
Hazardous Air Pollutants (HAPs) Actual Emissions
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2013 CY 2012 Demini- %
from ED from Fees mus Change
Propylene dichloride(1,2-dichloropropane) 78-87-5 Not 4.58 10.0 N/A
Reported
Selenium Compounds SEC Not 0.412100 10.0 N/A
Reported
Styrene 100-42-5 331.04 263.61 100.0 25.6%
TCE(trichloroethylene) 79-01-6 Not 4.16 1,000.0 N/A
Reported
Toluene 108-88-3 196.13 526.51 100.0 -62.7%
Vinyl chloride 75-01-4 3.14 2.50 0.1 25.6%
Xylene(mixed isomers) 1330-20-7 4.78 3.76 100.0 27.3%
Xylene, o- 95-47-6 0.619050 0.776070 100.0 -20.2%
Largest Individual HAP Methanol (methyl alcohol) 310,854.43
Ibs
Total HAP Emissions 501,471.73
lbs
09/18/2014 Page 5 of 6
DAO's Comments Reeardine Inventory
1. Fuel oil consumption on HI01-103 was 80%of the previous year. Generator fuel usage increased 1,589 gallons. Wood
boiler fuel usage increased in 2013 by 4,436 tpy.
2. The metals categories for combustion established by the June 6,2005 email from Brendan Davey(TPB and PWG
approved)were corrected in ED.
3.NOx emissions from H10I-103 were recalculated to 4.42 tons(EF is 20.0 lb/1000 gals).
4.NOx emissions from generators 101-104 was off an order of magnitude. The emission was corrected to 9.96 ton.
5.Generators 101-04 VOC emissions were corrected to 0.3 ton.
6.I added metal emissions to ED for the fire pup generator. I corrected NOx emission to 0.17 ton for the generator.
7. 1 added metals and corrected S02 and VOC emissions for PK-generator.
8. Metals were added to the wood boiler emissions in ED.
9. I asked Brian Conner to separate the isohexane,n-hexane and methanol emissions into the controlled and fugitive
fractions at Rotocel/Recovery/Concrete,SFG and SDE. They have been reporting a total for each pollutant in each area of
the plant. I have created new OS and emission points in ED for the fugitives.
10.In the inventory forms several pollutants are quantified in the negative. Brian said that a campaign often does not end
with the monks end so at that point in the run the recovered solvent may show more than the used.At the campaigns
end,the actual final numbers will balance out(mass balance approach)as can be seen in the following monks totals.
Therefore,if the annual emissions total is in the negative,emissions are considered zero.
11.Avoca uses 3 varieties of Ethanol depending on the product/process and extraction requirements. I inventory each
variety separately just because it makes it easier to keep up with on my end and to match up with inventories.
a)Botanical emitted 3930.22 lbs.of 100%Ethanol and 4447.78 lbs.of SDA Ethano I for a total of 8378 lbs.of Ethanol emitte
b)Biomass only used one type of ethanol(100%)for krill,emitted 10528.95 lbs.
c)PNE used a total of 1078.72 lbs.of ethanol.
d)The bulk of ethanol does go to Waste Water Treatment.Their bugs thrive on ethanol and Avoca assumes all ethanol is
consumed by the bugs.
12. The following notes concern pollutants that changed+/- 10%from 2012.
a)CO emissions decreased due to new stack test value on the wood boilers.
b)NOx emissions increased due to more wood combustion on the wood boilers.
c)The S02 decrease is due to less firing in H101-103.
d)Metals increases are due to wood fuel increase. The metals categories for fuel combustion were changed this year,so
the totals look different in comparison to 2012. As a result the increases and decreases compared to 2012 appear large.
The increase in emissions for all metals except manganese is less than a pound.
e)Fluoride emissions decreased due to less operation of H101-103.
f)HCI emissions drastically decreased due to the difference between two stack tests(done 2/21/2013 and 12/2013).
g)Process solvent emissions are dependent on client demand. The associated HAPs are chloroform,ethyl acetate,
methanol,isohexane,n-hexane,and toluene.
h)AII combustion HAPs increased due to the increase in wood combustion. I added ethylene dichloride,vinyl chloride,
methyl bromide,methyl chloride,methylene chloride,and phosphorus emissions to the wood combustion emissions using
DAQ spreadsheet. I also added several combustion toxics to the AERO data for the engines(NCDAQ spreadsheets).
13. I added n-hexane and isohexane emissions to the W WTP,which accounts for the differenc e in VOCs between what is
now in ED and what Avoca reported.
09/18/2014 Page 6 of 6
I
Avoca, Inc. 2013 Emissions by Process
Process Chemical/Solvent Total Emissions Controlled Emissions Fugitive Emissions Percentage of Total
(Ibs.) (Ibs.) (Ibs.) Loss=Fugitive
Isohexane 1352806.09 26101.48 1326704.60 98.1
Rotocel/Recovery n-Hexane 2041.36 36.02 2005.35 98.2
Methanol 298278.74 1840.23 296438.51 99.4
Isohexane -28580.30 0.01 -28580.31 100.0
Concrete n-Hexane -24.60 0.00 -24.60 100.0
Methanol 2724.59 64.53 2660.06 97.6
Sclareolide Isohexane 71313.31 5277.18 66036.13 92.6
(S D E) n-H exa n e 46968.59 3455.78 43512.81 92.6
Sclareol Recrystallization Isohexane 12078.54 794.08 11284.46 93.4
(SFG) n-Hexane 120992.31 8269.37 112722.94 93.2
Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.com)
Sent: Monday, September 15, 2014 12:20 PM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Ok with me to add the 91bs.
Also, I will give my best estimate for fugitive vs. controlled emissions for SDE and SFG.
Thanks.
Brian
Sent from my U.S.Collulaa,Smanphone
-------- Original message --------
From: "Huddleston, Betsy"
Date:09/15/2014 12:03 PM (GMT-05:00)
To: Brian Conner
Subject: RE: Emissions Inventory Questions
Brian,
I've included a couple of quick notes below for our conversation later this week...
Betsy Huddleston,Environmental Engineer
Washington Regional Office
NC DENR,Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.ore
Betsy.Huddleston@ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
From: Brian Conner [mailto:Brian.Conner@Avocainc.com]
Sent: Saturday, September 13, 2014 9:41 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Betsy,
Below are the answers to the questions that I could handle through email:
1
1. It was diethylamine.When I copied the spread sheet to make it for diethylamine I overlooked changing it
everywhere.
2. The spreadsheet with the sage trials in the biomass boiler is attached.
3. The old original modeling calcs.showed 0.014%by weight hexane in the waste stream leaving recovery going
to waste treatment. I guess they figured not every bit of hexane was removed from the stream.The amount that
goes through is very tiny. I have just continued to use the 0.014%when doing the annual emissions calculations.
If ok with you, I'll add the 9 lbs of n-hexane emission to AFRO.
4. The spreadsheet that I keep calculates the amounts of fugitive vs. controlled emissions for the rotocel,
recovery, and concrete operations.These calcs.were based on modeling(again several years back). I am not
sure if SDE and SFG have been modeled in this way.We may need to update these(M) If necessary,you can
estimate SDE and SFG fugitive fractions. I will create new operating scenarios under each Group to enter
fugitives.
5. You are correct about the negative totals...often a campaign does not end with the month's end so at that point
in the run the recovered solvent may show more than the used.At the campaign's end,the actual final numbers
will balance out(mass balance approach) as can be seen in the following month's totals.
6. We use 3 varieties of Ethanol at Avoca depending on the product/process and extraction requirements. I
inventory each variety separately just because it makes it easier to keep up with on my end and to match up
with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs. of SDA Ethanol for a total of 8378 lbs. of
Ethanol emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs.of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment. Our bugs thrive on ethanol(in fact that is mostly
what the plant operates with) and we assume all ethanol is consumed by the bugs(happy bugs!).
I hope this helps somewhat until we can talk more next week.
Thanks,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddlestonaa ncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 lbs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenediamine. I don't think these are the same chemical,so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations,at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment(6,553lbs iso and 9.03 lbs n-hexane)?
2
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So,we need
to estimate the respective controlled vs.fugitive fractions at Rotocel/Recovery/Concrete, SDE and SFG.
5. 1 assume where there was a negative total,that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.ore
BetV.Huddleston(@-ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
3
Huddleston, Betsy
From: Huddleston, Betsy
Sent: Monday, September 15, 2014 1:00 PM
To: 'Brian Conner'
Subject: RE: Emissions Inventory Questions
I'll also need the split for Recovery, Rotocel and Concrete. I have previous notes but not sure if I'm spot on.
Betsy Huddleston, Enviromnental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.or¢
Betsy.HLiddleston@ncdenr.gov
ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
From: Brian Conner [mailto:Brian.Conner@Avocainc.com]
Sent: Monday, September 15, 2014 12:20 PM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Ok with me to add the 9 lbs.
Also, I will give my best estimate for fugitive vs. controlled emissions for SDE and SFG.
Thanks.
Brian
Sent from my IJ.S.Cellular*Smartphone
-------- Original message --------
From: "Huddleston, Betsy"
Date:09/15/2014 12:03 PM (GMT-05:00)
To: Brian Conner
Subject: RE: Emissions Inventory Questions
Brian,
I've included a couple of quick notes below for our conversation later this week...
Betsy Huddleston, Environmental Engineer
1
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.or¢
Betsy.Huddlestonaamcdenr. og_v
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
From: Brian Conner fmailto:Brian.Conner@Avocainc.com]
Sent: Saturday, September 13, 2014 9:41 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Betsy,
Below are the answers to the questions that I could handle through email:
1. It was diethylamine.When I copied the spread sheet to make it for diethylamine I overlooked changing it
everywhere.
2. The spreadsheet with the sage trials in the biomass boiler is attached.
3. The old original modeling talcs. showed 0.014%by weight hexane in the waste stream leaving recovery going
to waste treatment. I guess they figured not every bit of hexane was removed from the stream.The amount that
goes through is very tiny. I have just continued to use the 0.014%when doing the annual emissions calculations.
If ok with you, I'll add the 9 lbs of n-hexane emission to AERO.
4. The spreadsheet that I keep calculates the amounts of fugitive vs. controlled emissions for the rotocel,
recovery, and concrete operations.These talcs.were based on modeling(again several years back). I am not
sure if SDE and SFG have been modeled in this way.We may need to update these(???) If necessary,you can
estimate SDE and SFG fugitive fractions. I will create new operating scenarios under each Group to enter
fugitives.
S. You are correct about the negative totals...often a campaign does not end with the month's end so at that point
in the run the recovered solvent may show more than the used.At the campaign's end,the actual final numbers
will balance out(mass balance approach) as can be seen in the following month's totals.
6. We use 3 varieties of Ethanol at Avoca depending on the product/process and extraction requirements. I
inventory each variety separately just because it makes it easier to keep up with on my end and to match up
with inventories.
a) Botanical emitted 3930.22 lbs. of 100% Ethanol and 4447.78 lbs.of SDA Ethanol for a total of 8378 lbs. of
Ethanol emitted.
b) Biomass only used one type of ethanol (100%)for krill and emitted 10528.95 lbs.
c) PNE used a total of 1078.72 lbs. of ethanol.
d) The bulk of ethanol does go to Waste Water Treatment. Our bugs thrive on ethanol(in fact that is mostly
what the plant operates with)and we assume all ethanol is consumed by the bugs(happy bugs!).
I hope this helps somewhat until we can talk more next week.
Thanks,
2
I
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddlestonCcbncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 Ibs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenediamine. I don't think these are the same chemical, so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations, at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment (6,553lbs iso and 9.03 Ibs n-hexane)?
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So, we need
to estimate the respective controlled vs. fugitive fractions at RotoceI/Re cove ry/Concrete, SDE and SFG.
5. 1 assume where there was a negative total,that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington, NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.orZ
Betsy.Huddleston(a ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
3
Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.com]
Sent: Thursday, September 18, 2014 10:29 AM
To: Huddleston, Betsy
Subject: RE: Emissions Inventory Questions
Hey Betsy,
Sorry for the delayed response. It has been a hectic week....
You can just count the negative#s for concrete as "0".
Concrete was ran right behind Sage and the daily inventories actually showed a gain in hexane since the rotocel was not
in use and being drained back to the storage tanks.The end inventory is the actual usage for the entire area and
captures both rotocel/recovery and concrete. I just broke out those days that concrete was operating just for record
keeping purposes.
Thanks,
Brian Conner
Environmental, Health, & Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [ma i Ito:betsy.huddleston(a ncdenr.gov]
Sent: Thursday, September 11, 2014 12:41 PM
To: Brian Conner
Subject: Emissions Inventory Questions
Hi Brian,
I had an easier time working through the annual inventory this year! However, I still ran across a few things for which I
need clarification. Those questions are below. do you have some time tomorrow or next week to talk about them?
1. 12,917.46 Ibs of diethylamine was reported. The top of the page cites diethylamine, but the bottom totals on
the same page cite ethylenedia mine. I don't think these are the same chemical, so we need to clarify just which
one was actually emitted.
2. May I have the spreadsheet that calculated the emissions of hexane from the boilers?
3. On page 3 of hexane calculations, at the bottom it indicates that some hexane was lost to atmosphere at
wastewater treatment (6,553lbs iso and 9.03 Ibs n-hexane)?
4. For both hexane and methanol emissions it's understood that most are fugitive emissions. I got a request from
our toxics staff in Raleigh a few weeks ago to separate the fugitive from the controlled emissions. So, we need
to estimate the respective controlled vs. fugitive fractions at Rotocel/Recovery/Concrete, SDE and SFG.
5. 1 assume where there was a negative total, that meant you recovered more somewhere than was consumed?
6. 1 got confused on the Ethanol/ethyl acetate inventory pages. Did botanical emit 3930.22 Ibs or 4447.78 Ibs of
ethanol, or the sum of those values? I see that Biomass mitted 10,528.95 Ibs ethanol. Did PNE emitted 994.33
Ibs of ethanol or 84.39 Ibs ethanol or the sum of these values? Was any ethanol lost at WWTP?
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
1
1
943 Washington Square Mall,Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncait.org
BetU.Huddleston(a7,ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
1
2013 Avoca, Inc. Biomass Boiler Sage Burning Log
* Annual Hexane VOC limit is 35.4 tons/year. Annual n-Hexane emission limit is 10000 lbs/year.
* This satisfies Permit No. 01819T41 condition 2.1.D.a-d.
Sage to Lbs. Sage to Daily Lbs. Daily Lbs.
Sage Infeed Lbs. Hexane/ Rolling Lbs. of
Dryer/ Dryer/ Hexane % n- n-Hexane Rolling Tons of
Date to Rotocel Lbs.Sage out n-Hexane
Biomass Biomass Emitted Hexane Emitted from VOC Emissions
(Lbs.) Desolvitizer Emissions
Boiler Boiler from Dryer Dryer
1/1/2013 0 0.00 0.000 0.00 0.00
1/2/2013 0 0.00 0.000 0.00 0.00
1/3/2013 0 0.00 0.000 0.00 0.00
1/4/2013 0 0.00 0.000 0.00 0.00
1/5/2013 0 0.00 0.000 0.00 0.00
1/6/2013 0 0.00 0.000 0.00 0.00
1/7/2013 0 0.00 0.000 0.00 0.00
1/8/2013 0 0.00 0.000 0.00 0.00
1/9/2013 0 0.00 0.000 0.00 0.00
1/10/2013 _ 0 0.00 0.000 0.00 0.00
1/11/2013 0 0.00 0.000 0.00 0.00
1/12/2013 0 0.00 0.000 0.00 0.00
1/13/2013 0 0.00 0.000 0.00 0.00
1/14/2013 0 0.00 0.000 0.00 0.00
1/1.5/2013 _ _ 0 0.00 0.000 0.00 0.00
1/16/2013 0 0.00 0.000 0.00 0.00
1/17/2013 0 0.00 0.000 0.00 0.00
1/18/2013 0 0.00 0.000 0.00 0.00
1/19/2013 0 0.00 0.000 0.00 0.00
1/20/2013 0 0.00 0.000 0.00 0.00
1/21/2013 0 0.00 0.000 0.00 0.00
1/22/2013 0 0.00 0.000 0.00 0.00
1/23/2013 0 0.00 0.000 0.00 0.00
1/24/2013 0 0.00 0.000 0.00 0.00
1/25/2013 0 0.00 0.000 0.00 0.00
1/26/2013 0 0.00 0.000 0.00 0.00
1/27/2013 0 0.00 0.000 0.00 0.00
1/28/2013 0 0.00 0.000 0.00 0.00
1/29/2013 0 0.00 0.000 0.00 0.00
1/30/2013 0 0.00 0.000 0.00 0.00
1/31/2013 0 0.00 0.000 0.00 0.00
2/1/2013 0 0.00 0.000 0.00 0.00
2/2/2013 0 0.00 0.000 0.00 0.00
2/3/2013 _ 0 0.00 0.000 0.00 0.00
2/4/2013 -- - 0 - 0.0c) - 0.000 0.00 0.00
2/5/2013 0 0.00 _ 0.000 0.00 0.00
2/6/2013 0 0.00 _ 0.000 0.00 0.00
2/7/2013 _ 0 0.00 0.000 0.00 0.00
2/8/2013 _ _ j _ _ o _ - _ 0.00 0.000 0.00 0.00
2/9/2013 _ 0 0.00 _ 0.000 0.00 0.00
2/10/2013-f _ - 0 j 0.00 0.000 0.00 0.00
- 2/11/2013 0 j C.O 0.000 0.00 _ 0.00
2/12/2013 _ __ 0 _ 0.00 0.000 0.00 0.00
2/13/2013 _ �- 0 0.00 0.000 0.00 0.00
2/14/2013 0 0.00 0.000 0.00 0.00
2/15/2013 0 _ _O.CO 0.000 0.00 0.00
2/16/2013 j 0.00 0.000 0.00 0.00
2!17/2013 _ _ 0 0.00 0.000 0.00 _0.Co -
2/18/2013�-_- o ---Y_� 0.00 _- 0.000 0.00 0.00
2/1-9/2013 _- _ 0 0.00 0.000 0.00 0.00
I 2/20/2013 - - 0 - 0.00 0.000 0.00 O.00
2/21/2013 -j 0 __ j 0.00 -�_ 0.000 0.00 0_00
- 2/22/2013 i o 0.00 0.000 0.00 o.oc
2!23/2053 ------ 0 G.GO_ - -_ -- 0_000-- I- O.Co- --- O.Ocl --�
2/24/2013 -- 0 I - O.Oo 0.000 - 0.00 0.00
2/25/2013 _ 0 0.00 0.000 0.00 0.00
0.000 0.00 0.00
2/27/2013 0 0.01- 0.000 0.00 0.0000
2/28/2013 0 0.00 0.000 0.00 0.00 _
3/1/2013 _ 0 0.00 i _ 0.000 0.00 0.00
3/2/2013 0 0.00 0.000 0.00 0.00
3/3/2013 0 0.00 0.000 0.00 0.0_0
3/4/2013 - I _ 0 _0.00 0.000 0.00 0.00
3/5/2013 - 0 _0.00 0.000 0.00 _0.00 -
1 3/6/2013 0 - _0.00 0-000 0.00 _0_00
3/7/2013 _ 0 0.00 I 0.000 0.00 0.00
3/8/2013 0 0.00 0.000 0.00 0.00
3/9/2013 0 0.00 0.000 0.00 0.00
3/10/2013 0 0.00 0.000 0.00 0.00
3/11/2013 0 0.00 0.000 0.00 0.00
3/12/2013 0 0.00 0.000 0.00 0.00
3/13/2013 0 0.00 0.000 0.00 0.00
3/14/2013 0 0.00 0.000 0.00 0.00
3/15/2013 0 0.00 0,000 0.00 0.00
3/16/2013 0 0.00 0.000 0.00 0.00
3/17/2013 0 0.00 0.000 0.00 0.00
3/18/2013 0 0.00 0.000 0.00 0.00
3/19/2013 0 0.00 0.000 0.00 0.00
3/20/2013 0 0.00 0.000 0.00 0.00
3/21/2013 0 0.00 0.000 0.00 0.00
3/22/2013 0 0.00 0.000 0.00 0.00
3/23/2013 0 0.00 0.000 0.00 0.00
3/24/2013 0 0.00 0.000 0.00 0.00
3/25/2013 0 0.00 0.000 0.00 0.00
3/26/2013 0 0.00 0.000 0.00 0.00
3/27/2013 0 0.00 0.000 0.00 0.00
3/28/2013 0 0.00 0.000 0.00 0.00 _.
3/29/2013 0 0.00 0.000 0.00 0.00
3/30/2013 0 0.00 0.000 0.00 0.00 :
3/31/2013 0 0.00 0.000 0.00 0.00
4/1/2013 0 0.00 0.000 0.00 0.00
4/2/2013 0 0.00 0.000 0.00 0.00
4/3/2013 0 0.00 0.000 0.00 QI,QQ
4/4/2013 0 0.00 0.000 0.00 0.00
4/5/2013 0 0.00 0.000 0.00 0.00
4/6/2013 0 0.00 0.000 0.00 0.00
4/7/2013 0 0.00 0.000 0.00 0.00
4/8/2013 0 0.00 0.000 0.00 0.00
4/9/2013 0 0.00 0.000 0.00 0.00
4/10/2013 0 0.00 0.000 0.00 0.00
4/11/2013 0 0.00 0.000 0.00 0.00
4/12/2013 0 0.00 0.000 0.00 0.00
4/13/2013 0 0.00 0.000 0.00 0.00
4/14/2013 0 0.00 0.000 0.00 0.00
4/15/2013 0 0.00 0.000 0.00 0.00
4/16/2013 0 0.00 0.000 0.00 0.00
4/17/2013 0 0.00 0.000 0.00 0.00
4/18/2013 0 0.00 0.000 1 0.00 0.00
4/19/2013 0 0.00 0.000 0.00 0.00
4/20/2013 0 0.00 0.000 0.00 0.00
4/21/2013 0 0.00 0.000 0.00 0.00
4/22/2013 0 0.00 0.000 0.00 0.00
4/23/2013 0 0.00 0.000 0.00 0.00
4/24/2013 0 0.00 0.000 0.00 0.00
4/25/2013 0 0.00 0.000 0.00 0.00
4/26/2013 0 _ 0.00 0.000 0.00 0.00
4/27/2013 0 0.00 0.000 0.00 0.00
4/28/2013 0 0.00 0.000 0.00 0.00
4/29/2013 0 0.00 0.000 0.00 0.00
4/30/2013 0 0.00 0.000 0.00 0.00
5/l/2013 0 0.00 0.000 0.00 0.00
5/2/2013 0 0.00 0.000 0.00 0.00
5/3/2013 0 0.00 0.000 0.00 0.00
5/4/2013 0 0.00 0.000 0.00 0.00
5/5/2013 0 0.00 0.000 0.00 0.00
5/6/2013 0 0.00 0.000 0.00 0.00
5/7/2013 0 0.00 0.000 0.00 0.00
_5/8/2013 0 0.00 0.000 0.00 0.00
5/9/2013 0 0.00 0.000 0.00 0.00
5/10/2013 0 0.00 0.000 0.00 0.00
5/11/2013 0 0.00 0.000 0.00 0.00
5/12/2013 _ _ 0 0.00 0.000 0.00 _0.00 _
5/13/2013 0 0.00 0.000 0.00 0.00
5/14/2013 _ 0 0.00 0.000 0.00 0.00
5/15/2013 0 0.00 0.000 0.00 0.00
5/16/2013 0 0.00 0.000 0.00 0.00
5/17/2013 0 0.00 0.000 0.00 0.00
5/18/2013 0 0.00 0.000 0.00 0.00
5/19/2013 0 0.00 0.000 0.00 0.00
5/20/2013 0 0.00 0.000 0.00 0.00
5/21/2013 0 0.00 0.000 0.00 0.00
5/22/2013 0 0.00 0.000 0.00 0.00
5/23/2013 0 0.00 0.000 0.00 0.00
5/24/2013 0 0.00 0.000 0.00 0.00
5/25/2013 0 0.00 0.000 0.00 0.00
5/26/2013 0 0.00 0.000 0.00 0.00
5/27/2013 0 0.00 0.000 0.00 0.00
5/28/2013 0 0.00 0.000 0.00 0.00
5/29/2013 0 0.00 0.105 0.000 0.00 0.00
5/30/2013 0 0.00 0.105 0.000 0.00 0.00
5/31/2013 0 0.00 0.112 0.000 0.00 0.00
6/1/2013 0 0.00 0.112 0.000 0.00 0.00
6/2/2013 0 0.00 0.112 0.000 0.00 0.00
6/3/2013 0 0.00 0.112 0.000 0.00 0.00
6/4/2013 0 0.00 0.112 0.000 0.00 0.00
6/5/2013 0 0.00 0.112 0.000 0.00 0.00
6/6/2013 0 0.00 0.112 0.000 0.00 0.00
6/7/2G13 0 0.00 0.118 0.000 0.00 0.00
6/8/2013 0 0.00 0.118 0.000 0.00 0.00
6/9/2013 0 0.00 0.118 0.000 0.00 0.00
6/10/2013 0 0.00 0.118 0.000 0.00 0.00
6/11/2013 0 0.00 0.118 0.000 0.00 0.00
6/12/2013 0 0.00 0.118 0.000 0.00 0.00
6/13/2013 0 0.00 0.118 0.000 0.00 0.00
6/14/2013 0 0.00 0.122 0.000 0.00 0.00
6/15/2013 0 0.00 0.122 0.000 0.00 0.00
6/16/2013 0 0.00 0.122 0.000 0.00 0.00
6/17/2013 0 0.00 0.122 0.000 0.00 0.00
6/18/2013 0 0.00 0.122 0.000 0.00 0.00
6/19/2013 0 0.00 0.122 0.000 0.00 0.00
6/20/2013 0 0.00 0.122 0.000 0.00 Q.00
6/21/2013 0 0.0.0 0.118 0.000 0.00 0.00
6/22/2013 0 0.00 0.118 0.000 0.00 0.00
6/23/2013 0 0.00 0.118 0.000 0.00 0.00
6/24/2013 0 0.00 0.118 0.000 0.00 0.00
6/25/2013 0 0.00 0.118 0,000 0.00 0.00
6/26/2013 0 0.00 0.118 0.000 0.00 0.00
6/27/2013 0 0.00 0.118 0.000 0.00 0.00
6/28/2013 0 0.00 0.114 0.000 0.00 0.00
6/29/2013 0 0.00 0.114 0.000 0.00 0.00
6/30/2013 0 0.00- 0.114 0.000 0.00 0.00
7/1/2013 0 0.00 0.114 0.000 0.00 0.00
7/2/2013 0 0.00 0.114 0.000 0.00 0.00
7/3/2013 0 0.00 0.114 0.000 0.00 0.00
7/4/2013 0 0.00 0.114 0.000 0.00 0.00
7/5/2013 0 0.00 0.114 0.000 0.00 0.00
7/6/2013 0 0.00 0.114 0.000 0.00 0.00
7/7/2013 0 0.00 0.114 0.000 0.00 0.00
7/8/2013 0 0.00 0.114 0.000 0.00 0.00
7/9/2013 0 0.00 0.114 0.000 0.00 0.00
7/10/2013 1 213060 40% 85224 0.001129 96.23 0.114 0.110 0.05 0.11
7/11/2013 216100 50% 108050 0.001129 122.01 0.114 0.139 0.11 0.25
7/12/2013 9100 50% 4550 0.001129 5.14 0.114 0.006 0.11 0.25
7/13/2013 0 0.00 0.114 0.000 0.11 0.2.5
7/14/2013 573500 50% 286750 0.001129 323.80 0.114 0.369 0.27 0.62
7/15/2013 0 0.00 0.114 0.000 0.27 0.62
7/16/2013 0 0.00 0.114 0.000 0.27 O.G2
7/17/2013 0 0.00 0.114 0.000 0.27 0.52
7/18/2013 0 0.00 0.114 0.000 0.27 0.62
7/19/2013 0 0.00 0.111 0.000 0.27 0.62
7/20/2013 0 0.00 0.111 0.000 0.27 0.62
7/21/2013 0 0.00 0.111 0.000 0.27 0.62
7/22/2013 0 0.00 O.ill 0.000 0.27 0.62
7/23/2013 0 0.00 0.111 0.000 0.27 0.62
7/24/2013 0 0.00 0.111 0.000 0.27 0.62
7/25/2013 0 0.00 0.111 0.000 0.27 0.62
7/26/2013 0 0.00 0.108 0.000 0.27 0.62
7/27/2013 0 0.00 0.108 0.000 0.27 0.62
7/28/2013 0 0.00 0.108 0.000 0.27 0.62
7/29/2013 _ 0 _ _ 0.00 0.108 0.000 0.27 0.62
7/30/2013 0 0.00 0.108 0.000 0.27 0.62
7/31/2013 0 0.00 0.108 0.000 0.27 0.62
8/1/2013 0 1 0.00 0.106 1 0.000 0.27 0.62
8/2/2013 _0 0.00 0.106 0.000 0.27 0.62
8/3/2013 0 0.00 0.106 0.000 0.27 0.62
8/4/2013 0 0.00 0.106 0.000 0.27 0.62
8/5/2013 0 0.00_ 0.106 0.000 0.27 0.62
8/6/2013 0 0.00 0.106 0.000 0.27 0.62
8/7/2013 0 0.00 0.106 0.000 0.27 0.62
8/8/2013 0 0.00 0.106 0.000 0.27 0.62
8/9/2013 0 0.00 0.118 0.000 0.27 0.62
8/10/2013 0 0.00 0.118 0.000 0.27 0.62
8/11/2013 0 0.00 0.118 0.000 0.27 0.62
8/12/2013 0 1 0.00 0.118 0.000 0.27 0.62
8/13/2013 556580 30% 166974 0.001422 237.44 0.118 0.280 0.39 0.90
8/14/2013 408960 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/15/2013 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/16/2013 0 0.001422 0.00 0.118 0.000 0.39 0.90
8/17/2013 189420 40% 75768 0.001422 107.74 0.128 0.138 0.45 1.04
8/18/2013 270860 40% 108344 0.001422 154.07 0.128 0.197 0.52 1.24
8/19/2013 598940 40% 239576 0.001422 340.68 0.128 0.436 0.69 1.68
8/20/2013 491100 30% 147330 0.001422 209.50 0.128 0.268 0.80 1.94
8/21/2013 570420 30% 171126 0.001422 243.34 0.128 0.311 0.92 2.25
8/22/2013 0 0.001422 0.00 0.128 0.000 0.92 2.25
8/23/2013 0 0.001422 0.00 0.137 0.000 0.92 2.25
8/24/2013 593294 20% 118658.8 0.001422 168.73 0.137 0.231 1.00 2.49
8/25/2013 425380 20% 85076 0.001422 120.98 0.137 0.166 1.06 2.65
8/26/2013 506120 25% 126530 0.001422 179.93 0.137 0.246 1.15 2.90
8/27/2013 447240 25% 111810 0.001422 158.99 0.137 0.218 1.23 3.12
8/28/2013 0 0.001422 0.00 0.137 0.000 1.23 3.12
8/29/2013 0 0.001422 0.00 0.137 1 0.000 1.23 3.12
8/30/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
8/31/2013 0 0.0014.22 0.00 0.156 0.000 1.23 3.12
9/l/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/2/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/3/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/4/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/5/2013 0 0.001422 0.00 0.156 0.000 1.23 3.12
9/6/2013 417000 15% 62550 0.001422 88.95 0.171 0.152 1.28 3.,27
9/7/2013 412460 35% 144361 0.001422 205.28 0.171 0.351 1.38 3.62
9/8/2013 321340 35% 112469 0.001422 159.93 0.171 0.273 1.46 3.89
9/9/2013 326300 35% 114205 0.001422 162.40 0.171 0.278 1.54 4.17
9/10/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/11/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/12/2013 0 0.001422 0.00 0.171 0.000 1.54 4.17
9/13/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/14/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/15/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/16/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/17/2013 0 0.001422 0.00 0.184 0.000 1.54 4.17
9/18/2013 394900 10% 39490 0.001422 56.15 0.184 0.103 1.57 4.27
9/19/2013 507980 35% 177793 0.001422 252.82 0.184 0.465 1.70 4.74
9/20/2013 458990 35% 160646.5 0.001422 228.44 0.184 0.420 1.81 5.16
9/21/2013 352160 35% 123256 0.001422 175.27 0.184 0.322 1.90 5.48
9/22/2013 444000 35% 155400 0.001422 220.98 0.184 0.407 2.01 5.89
9/23/2013 498920 35% 174622 0.001422 248.31 0.184 0.457 2.13 6.35
9/24/2013 502100 35% 175735 0.001422 249.90 0.184 0.460 2.26 6.80
9/25/2013 240740 35% 84259 0.001422 119.82 0.184 0.220 2.32 7.03
9/26/2013 0 0.00 0.000 2.32 7.03
9/27/2013 0 0.00 0.000 2.32 7.03
9/28/2013 0 0.00 0.000 2.32 7.03
9/29/2013 0 0.00 0.000 2.32 7.03
9/30/2013 0 0.00 0.000 _ 2.32 7.03
10/l/2013 0 0.00 0.000 2.32 7.03
10/2/2013 0 0.00 0.000 2.32 7.03
10/3/2013 0 0.00 0.000 2.32 7.03
10/4/2013 0 0.00 0.000 2.32 7.03
10/5/2013 0 0.00 0.000 2.32 7.03
10/6/2013 0 0.00 0.000 2.32 7.03
10/7/2013 0 0.00 0.000 2.32 7.03
10/8/2013 0 0.00 0.000 2.32 7.03
10/9/2013 0 0.00 0.000 2.32 7.03
10/10/2013 0 0.00 0.000 2.32 7.03
10/11/2013 0 0.00 0.000 2.32 7.03
10/12/2013 0 0.00 0.000 2.32 7.03
10/13/2013 0 0.00 0.000 2.32 7.03
10/14/2013 - I 0 0.00 0.000 2.32 7.03
10/15/2013 0 0.00 0.000 2.32 7.03
10/16/2013 0 0.00 0.000 2.32 7.03
10/17/2013 0 0.00 0.000 2.32 7.03
10/18/2013 0 0.00 0.000 2.32 7.03
10/19/2013 0 0.00 0.000 2.32 7.03
10/20/2013 0 0.00 0.000 2.32 7.03
10/21/2013 0 0.00 0.000 2.32 7.03
10/22/2013 0 0.00 0.000 2.32 7.03
10/23/2013 0 0.00 0.000 2.32 7.03
10/24/2013 0 0.00 0.000 2.32 7.03
10/25/2013 0 0.00 0.000 2.32 7.03
10/26/2013 0 0.00 0.000 2.32 7.03
10/27/2013 0 0.00 0.000 2.32 7.03
10/28/2013 0 0.00 0.000 2.32 7.03
10/29/2013 0 0.00 0.000 2.32 7.03
10/30/2013 0 0.00 0.000 2.32 7.03
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EO'L ZE'Z 000,0 00'0 0 ETOZ/9/ZT
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ML ZE'Z 000,0 00 0 0 ETOZ/OZ/TT
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SZO'L 61S'ST ZS'9£97 S780L90'0 E-ESS09EE %S99 ti969760T lejol
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EO'L ZE'Z 000'0 00'0 0 ETOZ/91/ZT
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ML ZE'Z 000,0 00'0 0 EToz/ET/ZT
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EO'L ZE'Z 000'0 00'0 0 EToz/01/ZT
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Huddleston, Betsy
From: Brian Conner[Brian.Conner@Avocainc.coml
Sent: Wednesday, May 07, 2014 9:47 AM
To: Huddleston, Betsy
Subject: RE: Engine El04 stack data
Betsy,
The best data that I can find from the CAT spec sheets is:
Velocity= 2050 cfm
Temp. = 1000 OF
Hope this helps.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [ma i Ito:betsy.huddleston@ncdenr.gov]
Sent: Monday, May 05, 2014 4:25 PM
To: Brian Conner
Subject: Engine E104 stack data
Hi Brian,
Do have any stack data for engine E104? I have added to the group of engines in AERC, but need to add a stack for it
(height, diameter,temp,velocity/acfm).
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR, Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 2527948-3836
Fax: 252-975-3716
www.ncair.ora
Betsy.HuddIestoii@ncdenr.gov
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
1
RE: Engine E104 stack data Page 1 of 1
RE: Engine E104 stack data
Brian Conner [Brian.Conner@Avocainc.com]
Sent:Tuesday,May 06,2014 10:09 AM
To: Huddleston,Betsy
Betsy,
This is what I have:
Generator E104 is located directly beside E102.They use the same fuel tank.
The stack height is 11 ft., and it is a horizontal stack.
The diameter is 8 inches.
It is 534 BHP/401 HP.
I am trying to find data on stack temp. and velocity.
I will get that to you as soon as I get it from Gregory Poole.
Thanks,
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
From: Huddleston, Betsy [mailto:betsy.huddleston@ncdenr.gov]
Sent: Monday, May 05, 2014 4:25 PM
To: Brian Conner
Subject: Engine E104 stack data
Hi Brian,
Do have any stack data for engine E104? I have added to the group of engines in AERO, but need to add a stack
for it(height, diameter,temp,velocity/acfm).
Betsy Huddleston, Environmental Engineer
Washington Regional Office
NC DENR,Division of Air Quality
943 Washington Square Mall, Washington,NC 27889
Phone: 252-948-3836
Fax: 252-975-3716
www.ncair.org
Betsy.Huddleston@ncdenr.gov
************************************************************************
Email correspondence to and from this address is subject to the North Carolina
Public Records Law and may be disclosed to third parties unless the content is exempt by
statute or other regulation.
************************************************************************
https://mail.nc.gov/owa/?ae=Item&t=IPM.Note&id=RgAAAAAsvlGQkJp3Tq WuCPA29r8... 5/6/2014
M
o�m
Page 1of2 7 l,d ",,)bU 112r1SOOybV1
Diu eM4 90/q k6�CN)
Annual Air Emissions Inventory l Chun ��L,3,//�M �n/isje�
Facility ID#:0800044
Boilers : OS-1 Cm'a5'"°� AF" IS AY��/i-tr
Year: 2013 Unre",hod iro t2v DAQ
Total Run Time: 8882.8 Hrs/Yr /00/7(y
Efficiency: 85 %,
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 17578.3 34313.6 6023.6 57915.5 491.7 1422.4 197.6 2111.7 0.032 11.583
February: 3844.7 16471.5 2594.9 22911.1 188.2 139.3 124.2 451.7 0.013 4.582
March: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.000 0.000
April: 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0,000 0,000
May: 0.0 1 14269.3 4697.0 18966.3 0.0 55.8 170.3 226.1 0.011 3,793
June: 3261.6 5.0 254.4 3521.0 119.0 114.8 10.6 244.4 0.002 0.704
July: 3449.9 9363.9 15.2 12829.0 96.5 103.7 10.5 210.7 0.007 2.566
August: 15629.9 37425.2 1975.4 55030.5 437.2 379.6 48.6 865.4 0.031 11.006
September: 24681.8 52129.7 9465.0 86276.5 690.4 0.0 252.4 942.8 0.048 17.255
October: 23055.2 31918.0 241.8 55215.0 644.9 457.1 40.3 1142.3 0.031 11.043
November: 21803.9 25135.6 912.4 47851.9 609.9 505.8 55.3 1171.0 0.027 9.570
December: 25890.2 52719.2 3054.2 81663.6 724.2 582.1 210.4 1516.7 0.046 16.333
Total: 139195.5 273751.0 29233.9 442180.4 4002.0 3760.E 1120.2 8882.8 0.248 88.436
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 34.8 4002.0 139195.5
2 H-102 143 72.8 3760.6 273751.0
a
3 H-103 180 26.1 1120.2 29233.9
Total 466 133.67302 8882.8 442180.4
r�
aS�r
Criteria Pollutants E T
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total C�rf e n SA
Pollutants Lbs./1000 al. Tons/Yr TonsNr TonsNr TonsNr fr 14e,o..6l�
TSP 3.3 2,00 0.7 �, 0,139 0.274 0.029 0.442
PM-10 1.00 0.070 0.137 0.015 0.221
PM-2.5 0,25 0.017 0,034 0.004 0.055 0 hl 4 � )Li s y,y3�r s
Sox 42,60 2.965 5,831 0.623 9.418 S L/$ 9
Nox 24,00 (2o,") 1.670 3.285 0.351 5.306
VOC 0.20 0.014 0.027 0.003 0.044
CO 5.00 0.348 0.684 0.073 1.105
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.60E-04 0.078 0.153 0.016 0.248
Benzene 2.75E-03 0.383 0,753 0.080 1.216
Beryllium 4.20E-04 0.058 0.115 0.012 0.186
Cadmium 4.20E-04 0.058 0,115 0.012 0.186
-Ghromm 4.20E-04 0.058 0.115 0.012 0,186 Ch,,omlc aGd 0119
Cl.,un\t ChromwpaVl 0.004 0.008 0.001 0.013
Jua Ethyl benzene 8.17E-04 0.114 0.224 0.024 0.361
Flouride 3.73E-02 5.192 10.211 1.090 16.493
Formaldehyde 4.80E-02 6.681 13.140 1,403 21.225
Lead 1.26E-03 0.175 0.345 0.037 0,557
Manganese 8.40E-04 0.117 0.230 0.025 •0.371
Me rcu 4.20E-04 0.058 0,115 0.012 0.186
Na thalene 3.30E-04 0.046 0.090 0.010 0.146
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Page 2 of 2
Annual Air Emissions Inventor
y
Facility ID#:0800044
Boilers : OS-1
Nickel 4.20E-04 0.058 0.115 0.012 0.186 S��r nl VY✓` 0 9 3
Toluene 7.97E-02 1 11.094 21.818 1 2.330 35.242 1.5
o-X lene 1.40E-03 1 0.195 0.383 1 0.041 0.619 1
nit /
Gt�ID✓Ore err Or'
Green House Gas Pulutants
�tv)
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor (lbs/hr) (Ibslhr) (Ibslhr) (tonslyr) (tonslyr) (tonslyr) (tons/yr)
(lbs/1000 gal)
CO2 22700.00 789.54 1652.44 592.40 1579.87 3107.07 331.80 5018.75 y974.Q �pQ Swt}
Methane 0.06 0.0021 0.0044 0.0016 0.0042 0.0082 0.0009 0.0133 0.2 �SQaO! 1
(CH4)
Nitrous Oxide 0.12 0.0042 0.0087 0.0031 0.0084 0.0164 0.0018 0.0265 Q O Y
(N20)
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Page 1 or 1
Annual Air Emissions Inventory
Facility ID#:0800044
Generators : OS-2
Year.
Total Run Time: 200.1 HrsNr
Efficiency: 0. % /GS /J 1nwWu \
Sulfur Content 0 3 % ( J
Number 2 Fuel: 141000 BtulGal D' t 1U
(q/
Fuel Usage(gallons) VOC /VOX Con t �'^ �,
/�/
Month E101 E102 E103 E104 Total (Lbs.) I e 1'
January: 397.5 662.5 530.0 530.0 2120.0 110.4 G l e oktw
February: 30.0 50.0 40.0 120.0 6.2
March: 30.0 50.0 40.0 40.0 160.0 8.3
April: 30.0 50.0 40.0 40.0 160.0 8.3
May: 33.8 45.0 45.0 45.0 168.8 8.8
June: 37.5 75.0 50.0 50.0 212.5 1 11.1
July: 30.0 50.0 31.0 40.0 161.0 7.9
Au ust: 37.5 62.5 50.0 50.0 200.0 10.4
Se tember: 30.0 50.0 40.0 40.0 160.0 8.3
October: 30.0 50.0 40.0 40.0 160.0 8.3
November: 30.0 50.0 40.0 40.0 160.0 8.3
December. 45.0 75.0 50.0 60.0 230.0 12.0
Total: 761.3 1270.0 1 996.0 1 975.0 4002.3 208.4
Heat Rate
Generator No. ID# I Bho I ho I HrlYr GalsIHr I GalslYr MM BhilHr MM BWNr
1 E101 1 587 1 440 1 50.8 15.0 761.3 2.12 107.34
2 E102 760 570 50.8 25.0 1270.0 3.53 179.07
3 E103 603 452 49.8 20.0 996.0 2.82 140.44
4 E104 1 534 1 401 1 48.8 20.0 975.0 2.82 137.48
Total 2484 1 1863 1 200 80 4002.3 11 564
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4kO.0028
Pollutants (LbIMM BTU) (TonslYr) (TonslYr) (TonslYr) (TonsNr)
TSP 0.100 0.005 0.009 0.007 0.007 PM-10 0.100 0.005 0.009 0.007 0.007PM-2.5 0.100 0.005 0.009 0.007 0.007Sox 0.141 0.008 0.013 0.010 0.010N0x . 0.320 0:017 0.028 0.022 0.0224 A
VOC i 0.360 0.019 0.032 0.025 0.025 0.102 8,(r,3
CO 0.850 0.046 0.076 1 0.060 1 0.058 1 0.240
HazardouslToxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Total
Air Pollutants (LbIMM BTU) (LbaNr) (LbsNr) (LbsNr) (LbslYr) (LbslYr)
Acetaldeh de 2.52E-05 0.002705 0.004513 0.003539 0.003464 0.014
Acrolein 7.88E-06 0.000846 0.001411 0.001107 0.001083 0.004
Arsenic nl 4.00E-06 0.000429 0.000716 0.000562 0.000550 0.002
Benzene 7.76E-04 0.083298 0.138958 0.108978 0.106681 - .438 ^/_✓0�7I1 �G/ 0,001
Benzo a rene 2.57E-07 0.000028 0.000046 0.000036 0.000035 0.000
Beryllium M,AAZ 3.00E-06 0.000322 0.000537 0.000421 0.000412 1'0.002
Cadmium 4J 3.00E-06 0.000322 0.000537 0.000421 0.000412 -0.002 leu d O,OU-5
For raideh de 7.89E-05 0.008469 0.014129 0.011080 0.010847 -10.045 0,00 y
Ne halene 1.30E-04 0.013955 0.023279 0.018257 0.017872 - .0.073 MG^'ls U/r't#�
Toluene 2.81E-04 0.030163 0.050319 0.039463 0.038630 0.159 IhU Q Z
X lene 1.93E-04 0.020717 0.034561 0.027104 0.026533 0.109
�/JI c O,CCJ 2 nlcf'i
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
LbIMM BTU tons r tons r tons r tons tons r
CO, 43.990 2.3610 3.9386 3.0889 3.0238 12.41
Methane 0.009 0.0005 0.0008 0.0006 0.0006 0.00254
(CHd)
Nitrous Oxide 0.001 0.0001 0.0001 0.0001 0.0001 0.000282
(Nz0)
HAEnvironmentalkAir PennBWir ReponsxAnnual Air Emissions Inventory\2013 Report\2013 AAE Calc Page 1
Qa►, A in 2W3
Annual Air Emissions Inventory
Facility ID#:0800044
PK- Generator : OS-12
Year: 2013
Total Run Time: 132.8 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0_3 %
Number 2 Fuel: 141000 Btu/Gal
Emisson tFactor
Hazardous/
Fuel Usage Hours VOC Criteria Factor Pk-Gen -GenMonth Pollutants (Lb/MM (Tons/Yr) Toxic Air s/Yr)(gallons) Operated (Lbs.) BTU PollutantsTSP 0.1 0.0674 Acetaldeh de0340Janua : 2160 30 112.49 PM-10 0.1 0.0674 Acrolein 0106Februa : 0.0 0.0 0.00 PM-2.5 0.1 0.0674 Arsenic 0054
March: 144.0 2.0 7.50 315) Sox 1 0.141 d•2 0.0950 Benzene 7.76E-04 1.0458
April: 756.0 10.5 39.37 Nox 3.2 2.1563 Benzo a rene 2.57E-07 0.0003
May: 162.0 2.3 8.44 a9tb' VOC 0.36 o,ol. 0.2426 Be Ilium 3.00E-06 0.0040
June: 1836.0 25.5 95.62 �' CO 0.85 0.5728 Cadmium 3.00E-06 0.0040
Jul 1080.0 15.0 56.25 Formaldeh de 7.89E-OS 0.1063
August: 1656.0 23.0 86.24 Na thalene 1.30E-04 0.1752
September: 828.0 11.5 43.12 Toluene 2.81E-04 0.3787
October: 180.0 2.5 9.37 X lene 1.93E-04 0.2601
November: 144.0 2.0 7.50
December: 612.0 8.5 31.87 i1,1s j<AP 42 -+ hp f��).'�Q �O 'r PPS �� y�l 56 M15)s
Total: 9558.0 1 132.8 497.8 Heat Rate G vt y (,4y)gwA�l"e V
Generator No. ID# Bhp ho Hr/Yr Gals/Hr GalsNr MM Btu/Hr MM Btu/Yr
Pk-Gen Pk-Gen 2670 1 2003 1 132.8 72.0 1 9558.0 1 10.15 1347.68
Green House Gas Pulutants for Peak Generator cA.um 1( QGI d ljj oO 4
GHG Pollutant Emisson Factor Ibs/yr tons/yr L?QoL Oi O f
(Lb/MM BTU)
44 43.990 59284.36 29.64
Methane 0.009 12.13 0.0061 Oil 7
(CH4)
Nitrous Oxide 0.007 9.43 0.00472 /V(444X
(N20)
Annual Air Emissions Inventory y2
Facility ID#:0800044
Fire Pumps ,�✓o
Data used for inventory only! p
Year: 2013 1 G J ecQ 4kv �J
Total Run Time: 38.5 HrslYr tO(� may)/55/07)5
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/ VOC
Month Fuel Operated hour (lbs.)
Used
January: 540.0 27.0 20.0 28.123
February: 40.0 2.0 20.0 2.083
March: 50.0 2.5 20.0 2.604
April: 10.0 0.5 20.0 0.521
May: 0.0 0.0 #DIV/0! 0.000
June: 0.0 0.0 #DIV/0! 0.000
July: 40.0 2.0 20.0 2.083
August: 50.0 2.5 20.0 2.604
September: 30.0 1.5 20.0 1.562
October: 10.0 0.5 20.0 0.521
November: 0.0 0.0 #DIV/0! 0.000
December: 0.0 0.0 #DIV/0! 0.000
Total: 770.0 38.5 20.0 40.1
Heat Rate
FP ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm mm
Btu/Hr Btu/Yr
FP FP 285 214 38.5 20.0 1 770.0 2.82 108.57
Criteria Emisson Factor (Lb/MM FP
Pollutants BTU) (Tons/Yr
TSP 0.31 0.017
PM-10 0.31 '0.017 A"-"L-
PM-2.5 0.31 0.017
Sox 0.152 '0.008
Nox 4.41 0.239 Od
VOC 0.36 'O.020 0.0/
CO 0.95 /0.052 0,04 Green House Gases
GHG Emisson Factor E101
Hazardous/Toxi Emisson Factor (LbIMM FP Pollutant K IMM BTU tons/ r
c Air Pollutants BTU) (Lbs/Yr) COz 73.960 8.853
Acetaldehyde 7.67E-04 -0.083 Methane 0.003 0.000359
Nitrous
Acrolein 9.25E-05 0.010 AQ Oxide 0.0006 0.000072
D (NZO)
Arsenic 4.00E-06 0.0004 1
Benzene 9.33E-04 ' 0.101
Benzo a rene 1.88E-07 0.00002
Beryllium 3.00E-06 0.0003 M�"4-7 Z, 3E'4
Cadmium 3.00E-06 '0.0003
Formaldehyde 1.18E-03 0.128 ( L¢.R.0 qC--
Na thalene 8.48E-05 - 0.009
Toluene 4.09E-04 0.044 C/rromlr au
X lene 2.85E-04 0.031
h/c!� Z. 3E -v
Criteria Pollutants Hazardous Air Pollutants
Criteria Emisson Factor Boiler Hazardous Air Emisson Factor Boiler
Pollutants (Lb/MM BTU) (TonsNr) Pollutants (Lb/MM BTU) (LbsNr)
TSP 0.0014 0.122 Acetaldehyde 8.30E-04 144.613
PM-10 0.0014 0.122 Acrolein 4.00E-03 696.928
PM-2.5 0.0014 0.122 Benzene 4.20E-03 731.774
Sox 0.03 2.178 Benzo a rene 2.60E-06 0.453
Nox 0.22 /19.166 Carbon
, 4.50E-05 7.840
tetrachloride
VOC 0.02 1.481r r Chlorine 7.90E-04 137.643 / OrH
CO 0.19 16.726 FUG" ,Awes Chlorobenzene 3.30E-05 ' 5.750 2,°�6'S (�l
p� Chloroform 2.80E-05 4.878
POT Ethyl benzene 3.10E-05 5.401
Green House Gas Pulutants Formaldehyde 4.40E-03 766.621 �/h con CI
Emisson Factor E101 ST✓
GHG Pollutant Lb/MM BTU tons/ r Napthalene 9.70E-05 16.901
CO2 195.000 16987.6 Phenol 5.10E-05 8.886
Methane 0.021 1.8 Propionaldehyde 6.10E-05 10.628
(CH4)
Nitrous Oxide 0.013 1.1 Styrene 1.90E-03 331.041
(N20)
Toluene 9.20E-04 160.293
X lene 2.50E-05 4. 56
/rok,11 broo„de, 4v�,-dm�V641dY' a,4er7/c 3.83 fTW4hyl CAI0TQfor^` S; ya
ISC-5 1b1(rm V14 DAG Spra4S6d &ry/hrm 0,19 PWn 21, 76
z ( 4bS Cpdm/rr» 0. 7I
rr �r td e (� sP Ch,,omr Acid 0,b )
]4 rnr IWV 7E�S 1b/Mrr�V LPG Of 9.34
2-3 F -5 �
9, 70ibs 2- 70. 77
y,o rbs
z,�E -y Ibrrn�r iv,�a s, �5
So,s Ibs
Annual Air Emissions inventory
Facility ID#: 0800044
Biomass Boilers : ES-BB1 & ES-BB2: OS-33
Fuel Source : Wood Chips
Year: 2013
Total Run Time: 8114.0 HrsNr
Wood Chips 994000 BTU/ton
'Emission Factors determined by Emissions test conducted on 1 2/1 912 01 3
Boiler Operation (Hours) Wood Chips Burned(Tons) CO PM HCL Hoc Heat Rate
Month ES-BB1 ES-BB2 Max Boiler ES-BB1 ES-BB2 Total Wood Lbs. Lbs. Lbs. Lbs. MM Btu/Month
Hours Chips
j January: 552.0 552.0 552.0 1169.0 1169.5 2338.5 3591.9 26.1912 1.68372 0.00543 18708
February: 576.0 576.0 576.0 852.0 853.0 1705.0 2618.9 19.096 1.2276 0.00396 13640
March: 744.0 744.0 744.0 694.0 694.0 1388.0 2132.0 15.5456 0.99936 0.00322 11104
April: 720.0 1 720.0 720.0 584.0 585.0 1169.0 1795.6 13.0928 0.84168 0.00271 9352
May: 578.0 480.0 578.0 806.0 631.0 1437.0 2207.2 16.0944 1.03464 0.00333 11496
June: 720.0 720.0 720.0 1352.0 1352.0 2704.0 4153.3 30.2848 1.94688 0.00627 21632
July: 744.0 744.0 744.0 1157.0 1157.0 2314.0 3554.3 25.9168 1.66608 0.00537 18512
August: 744.0 744.0 744.0 1023.0 1023.0 2046.0 3142.7 22.9152 1.47312 0.00475 16368
September: 531.0 720.0 720.0 362.0 490.5 852.5 1309.4 9.548 0.6138 0.00198 6820
October: 744.0 744.0 744.0 1047.5 1047.5 2095.0 3217.9 23.464 1.5084 0.00486 16760
November: 720.0 720.0 720.0 974.0 975.0 1949.0 2993.7 21.8288 1.40328 0.00452 15592
December: 552.0 552.0 552.0 890.0 891.0 1781.0 2735.6 19.9472 1.28232 0.00413 14248
Total: 7925.0 8016.0 8114.0 10910.5 10868.5 21779.0 33452.5 11243.925 i15.681 0.05053 174232.0
Average 660.4 668.0 676.2 909.2 905.7 1814.9 2787.7 20.327 1.307 0.00421 14519.3
121Zv1 3 5seB FI -5 Z1 zl/2013 -cs4 v&&.w
A
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CjG��/� a� Ly /S3Z9 c/bCFr /Z.//'-'oilro7sN�r
z592 0 GCyr
Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2013
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 10 0 10
December: 1 0 0 1 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
H:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2013 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0 135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000
Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9 [VG
Year: 2013
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max New Used Recovered Recovered Total Used Ending Product
Inventory Used Inventory Lbs.
January: 10800 8100.0 18900 0.0 18900
February: 18900 18900 4050.0 6375.0 6054.0 4371.0 14529 1386
March: 14529 14529 4050.0 5616.0 5328.0 4338.0 10191 1606
April: 10191 10800.0 20991 5100.0 5100.0 15891 1672
May: 15891 15891 795.0 795.0 15096 946
June: 15096 15096 0.0 15096
July: 15096 15096 3959.0 11382.0 14228.5 1112.5 13984 1276
August: 13984 13984 94&0 5246.0 10341.0 -4149.0 18133 1298
September: 18133 18133 0.0 18133 374
October: 18133 8100.0 26233 5250.0 5250.0 20983 1958
November: 20983 1 3 1 1100.0 1100.0 19883 704
December: 19883 19883 0.0 19883
Lbs. of chloroform used during the year: 17918 1791 7
Lbs. of chloro. used by Misc., OA, and R&D:
Lbs. of chloro. used by EVG: 17918
Lbs. EVG Produced: 11220
Lbs. of chloroform sent to hazardous waste: 900
Pounds of chloroform sent to WWT: 0
Pounds of chloroform emitted during year: OS-9 17018
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2013 Report\2013 AAE Calc
Annual Air Emissions Inventory
Facility ID#: 0800044
Dieftlamine : OS-1, / ,'
Year: 2013
b
Used for Nicotine Extraction in Botanical Extraction
Info: Lbs/Gal = 5.90 Process
Monthly Inventory of Diethylamine (gallons):
Month Beginning Received Max Used Used Ending
Inventory Gals. Lbs Gals. Lbs. Inventory
January: 0 0 0 0
February: 0 0 0 0
March: 0 0 0 0
April: 0 0 0 0
May: 0 0 1 0 0
June: 0 0 0 0
July: 0 0 0 0
August: 0 0 0 0
September: 0 0 0 0
October: 0 0 0 1 0
November: 0 1 2830 16698 1 2189 12917 1 641
December: 1 641 1 3781 1 1 0 1 641
Total Gallons of Eth lenediamine Used: 2189
Total Lbs. Ethylenediamine Used: 12917.46
Gallons sent to Hazardous Waste: 0
Lbs. Dieth lamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Ethylenediamine Emitted: OS-10 12917.46
vJc Co�i6 kk A' 0, ys 11�7r_5
Annual Air Emissions Inventory
Facility ID#:08000"
Ethyl acetate : OS-6,OS-7,OS-10, OS-28
Year: 2013
Info: LbslGal= 7.50
Monthly Inventory of Ethyl acetate(Pounds):
Ethyl acetate Used in SDA-35A
Month Bedinning Inventory Bulk Drums Alcohol
Total Beginning Beginning New Recovered Recovered in Max Monthly Total Ending Month Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
Inventory Inventory Inventory
January: 4020 4020 0 1260.00 4020 '1260.0 2780 January: 45.19
February: 2760 2760 0 200.00 2760 - 200.0 2560 February: 108.44
March: 2560 2560 0 366.00 2560 356.0 2204 March: 69.00
ril: 2204 2204 0 1219.00 2204 1219.0 985April: 11.47
May: 985 985 0 3200.0 4185 0.0 4185 May: 173.94
June: 4185 4185 0 4800.0 8985 0.0 8985 June: 161.41
Jul 8985 1 8985 0 1 1 315,00 1 8985 315.0 8670 July: 83.22
Au ust 8670 8670 0 1 1465.00 1 8670 1465.0 N6455
Au ust: 13.82
Se Umber. 7205 7205 0 7205 0.0 September: 40.46
October. 7205 7205 0 3200.0 949.00 10405 949.0 October. 81.38
November. 9456 9456 0 2501.00 9456 .2501.0 November. 0.00
December. 6955 6955 0 500.00 6955 December. 73.37
fpfA! -g�ro5lbs -�
Ethyl acetate Emissions by Source
Ethyl acetate Emitted Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted from Ethyl acetate Emitted
from SDA in Botanical
Month Extraction:OE=?6 Biomass Extraction:OS•28 SDA in PNE:OST PNE:O) from SFG rC�-6
(Lbs.) pSyp (Lbs.) (Lbs.) 053� (Lbs.) (Lbs.) 033/
Janua : 45.19 0.00 0.00 1260.00
February: 81.00 0.00 27.45 200.00
March: 54.42 0.00 14.58 356.00
-April: -0.93 0.00 12.41 1219.00
May: 69.15 104.80 0.00
June: 53.10 100.25 0.06
July: 0.00 .84.02 -0.80 315.00
August: 0.00 13.82 0.00 1465.00
September: 0.00 46.86 -6.40
October., 0.00 81.38 0.00 949.00
November. 0.00 0.00 0.00 2501.00
December. 73.37 0.00 0.00 500.00
Avers a 31.27 36.59 3.94 #DIV/0! 89
Total 1 375.29 431 47.29 1 0.00 1 ✓ 6785.00
Z 211.53 + 163.76
(n ct 0 ik1 one
Annual
Air Emissions Inventory
E:{h`(' )J[!TL A - Facility ID#:0800044
Etf of 200 proof) -OS-10 OS-28
Year: 2013
Info: Lbs/Gal= 6.68 %SDA Ethyl acetate = 4.0 4
Monthly Inventory of Ethanol(gallons):
jE
thyl
Beginning Recovered Max Recovered Difference in Recovered Ending Gallons to
Month Inventory New Received Received (Lbs) New Used Sent Off-Site Recovered Used Total Used Inventory WWT V
January: 40707 5495 71435 774402 5495 68349 3086 3086 8581 40707 8409 45.2
February: 40707 5523 85021 864026 5523 75164 9857 9857 15380 40707 15072 81.0
March: 40707 48029 584149 40717 7312 7312 7312 40707 7166 38.5
A ril: 40707 12913 38606 607124 12913 51696 .13090 -13090 -177 40707 -174 -0.9
Ma 40707 31270 33688 895590 15635 55328 -21640 4254 19899 30438 19501 2515.1 104.8
June: 30438 69227 656098 15635 49816 19412 4920 20555 29295 20144 2598.0 108.3
July: 29295 10870 79688 788989 10870 85131 -5444 5084 15954 18767 15635 2016.5 84.0
Au ust: 18767 22856 274005 10158 12698 2624 2624 26842 2572 331.7 13.8
September. 28842 189864 1 8898 8898 19944 8720 1124.7 46.9
October: 19944 6390 173354 6390 1 9062 15452 10882 15143 1953.0 81.4
November. 10882 71633 0 10882 0 0.0 0.0
December. 10882 71633 0 10882 0 0.0 0.0
Total Gallons of Ethanol Used: 114477
Total Lbs.Ethanol Used: 753602.7493
Gallons sent to Hazardous Waste:
Lbs.Ethanol sent to Hazardous Waste: 0
Total Gallons sent to WWT: 112188
Total Lbs.sent to WWT: 738530.6943 1
Total Lbs.of Ethanol Emitted as VOC: 14469 7- 2-3/CnS
Botanical Extraction Operation:OS-30 ` O
Y
Lbs.EtOH Lbs.Ethyl
Month #Da s Lbs.Botanical Gallons EtOH- Lbs.EtOH Lbs.EtOH Lbs.EtOH to Acetate Product
Operated Product SDA Used Used Recovered WWTP E�OOCC as Emitted as
VOC
January: 31 41755.92 8580.7 56486.75 55357.01 1084.5 45.2 Krill
February: 28 52682.56 15379.7 101244.57 99219.67 1943.9 81.0 Krill
March: 18 33867.00 7312.0 48134.90 47172.20 924.2 38.5 Krill
-April: 21 33123.20 -177.3 -1167.17 -1143.82 -22.4 -0.9 Krill
May: 0.00 0.00 0.0 0.0
June: 0.00 0.00 0.0 0.0
July: 0.00 0.00 0.0 0.0
August: 0.00 0.00 0.0 0.0
September: 0.00 0.00 0.0 0.0
October: 0.00 0.00 0.0 0.0
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Avera a 25 40357.17 7773.8 17058.25 #DIV/01 16717.09 327.52
Total 98 161428.68 31095.1 204699.04 0.00 200605.06 3930.22 rr163.70
Biomass Extraction Operation:OS-28
Lbs.EtOH Lbs.Ethyl
Month #Days Lbs.Biomass Gallons EtOH- Lbs.EtOH Lbs.EtOH LbS.EtOH to E Acetate Product
Operated Product SDA Used Used Recovered W WTP v�as Emitted as
VOC
January: 0.00 0.00 0.0 0.0
February: 0.00 0.00 0.0 0.0
March: 0.00 0.00 0.0 0.0
-April: 0.00 0.00 0.0 0.0
Maw 26 52272.00 19899.0 130995.12 128375.21 2515.1 104.8 Krill
June: 30 F438906. 0 20555.0 135313.57 132607.29 2598.0 108.3 Krill
Ju : 31 0 15954.0 105025.18 102924.68 2016.5 84.0 Krill
Au ust: 16 0 2624.0 17273.79 16928.32 331.7 13.8 Krill
Se tember: 30 0 8898.0 58575.53 57404.02 1124.7 46.9 Krill
October: 31 0 15452.0 101720.52 99686.11 1953.0 81.4 Krill
November: 0.00 0.00 0.0 0.0
December: 0.00 0.00 0.0 0.0
Avera a 27 0 13897.0 45741.96 #DIV/0! 44827.14 87825 36.59Total 164 .00 83382.0 548903.71 0.00 537925.63 10538.96 439.12
Annual Air Emissions Inventory
Facility IDa:08000"
Ethanol-SDA-35A:OS-7&OS-10
OS-18 OS-19 OS-27 OS412 INCLUDED WITH OS-1_0_
Year. 2013
Into: LbslGal= 6.87 %SOA Ethyl acetate= 4.54
Monthly Inventory of Ethanol Iwllonsl:
MOMhIy Baainninp Inventory Bulk Drums
TpteI SDA
Total SDA Bulk SDA In Drums SDA Max SDA on SDA to Ethyl
Month Beginning Beginning Beginning SDA SDA SDA Drams SOA Ending Soon s) SDA Used SDA VOC
Received Transferred SDA Used Received Recovered In Recovered SDA Disposed Hand Inventory (Wllone) [Lbs.) WWT (Lbs.) Ace Lb.)
tate VOC
Inventory Inventory Inventory Drums Used I�sl (�•) (�')
Janes . 2g72M 11671A 18053.9 2D4207 1 29725 0 0.0 1791M.8
0.0 0.0
Febnte . 29724.5 11671.0 18053.5 4400.0 204207 25325 4400 3022810 577.1 27A
March: 25324.5 7271.0 18053.5 10669.0 10669.0 5780.6 247275 31105 4888 33583.0 8172 30.5
April: 31105.2 7271.0 238342 6289.0 985.0 2670.0 1668.3 256898 35405 1989 13662.5 280.8 12A
Ma. 35405.4 12575.0 22830.4 6490.0 5304.0 5780.E 287822 30871 11095 76161.6 1453.9 69.1
June: 30810.8 13781.0 17049.8 6231.0 9892.5 1170.0 254477 28519 8523 58549.6 1117.8 53.2
Ju . 28519.3 10299.5 18219+8 128A 195928 28647 -128 -880.0 -16.8 -0.3
Aomori: 28647.4 70299.5 18347.9 196808 28647 0 0.0 0.0 00
.6.
September: 28647.4 10299.5 18347.9 6452.0 1028.E 241133 36128 -1027 .7052.4 -751.8 S.4
October: 38125.9 t6751.5 19374.4 248135 w M 0 0.0 0.0 0.0
November. 38725.8 78751.5 19374.E 248185 36128 0 0.0 0.0 0.0
December. U125.9 16751.5 19374.d 17999.0 71782.0 330618 38363 11762 80604.9 8 1542.7 73.4
Total 46130.0 0.0 43812.E 0.0 8450.E 9771.8 0.0 2915743.3 382925.2 41491.8 286047.1 279346.1 6N2.1 258.8
Botanical Extraction Operation:OS-10
8 Da Lbs.Botanical Gallons EtDH- Lbs.EtOH- Lbs'EtOH. Lbs.EtOH- EtOH-SDA Ethyl Acetate
Mont Days
Operated Protluct SDA Used SDA Used SDA SOA to VOC(Lbs.) VOC(Lbs.) Product
covered WWTP
Jana a00 0.00 0.0 0.0
Februa . 0.00 0.00 00 00
March: 11 1918.85 2561.0 17525.37 17174.86 334.6 15.9 Tobacco
nl: 000 0.00 0.0 0.0
Ma : 28 8899.80 11084.6 78151.20 74629.18 1453.9 69.1 Cranbemr
June: 14 4792.55 9683.0 66522.21 8037.90 57314.62 1118.8 53.1 Cranberry
July: o.DO o.00 0.0 0.0 Total SDA Ethanol Data
Au cant: 0.00 0.00 0.0 0.0 Total Gallons of SDA Used: 51263.1
September. 0.00 0.00 0.0 0.0 Total Lbs.SDA Used: 352177.8
October. 0.00 0.00 0.0 0.0 Total Gallons cant to W WT: 40661.88
November 0.00 0.00 0.0 0.0 Total Lbs.send to W WT: 279345.74
Dttember. 24 4954.80 11762.0 BOt104.94 79188.84 15427 73.E Cranbe Total Lbs.SDA Ethanol Emitted as VDD•s: 3442.11
Avers 19 Si41.00 87702 200&3.64 8037.90 19025.61 870.85 Lbs.Botanical Extraction Ethanol Emined as VOC:OS-10 4447.78
Tote) 75 20564.00 18080.8 241003.72 8037.90 22830857 4147.78 11.53 Lbs.PNE Ethanol Emitted as VOC:OS-7 994.31
PNE Operation:OS-7
8 Da Lbs.PNE Gallon EtOH- lbs.EtOH- Lba.EIGH- PSDAto
H- EtOH-SDA Ethyl Acetate
Month Days SDA o Product
Operated Product SDA Used SDA Used RveVOC(Ibs.) VOCILbs.)0.00 0.0 0.0
Februa 7 1319.50 4400.0 30228.00 4 577.1 27.4 Dews
March: 18 2582.55 8118.0 56770.66 39713.001 308.E 14.6 Dews
NI: 11 3655.0 25109.85 11447.4812 280.8 12A Tobsoco
0.00 0.0 0.0
June: 4 9.5 65.27 12 0.1 Tobacco
Ju . 5 N.80 0.DO 879.71 2 -1&8 -0.8 Tobacco
Au ust: 3 0.00 0.0 0.0 Tobacco
Se mber.. 9 0.007062.74 9 .134.7 SA Tobacco
October. 0.00 000 0.0 0.0
November. 0.00 0.00 0.0 0.0
December. 0.00 000 00 1 0.0
Average 8 1X62 4045.E 8264,18 14773.23 4253.27 82.8E 3
Total 68 3943.85 18182.5 111173.78 59092.93 510J8.21 994.1J 47.29
Annual Air Emissions Inventory
Facility 100:08000"
Ethanol-SDA-3A:OS-7&OS-10
OS II OS19 OS27 OS-32 INCLUDED WITH OS-10
Year. 2013
Irdo: LbslGal 6.87 %SDA Methanol 5
Monthly Inventory of Ethanol(aallonsk
Monthly Beginning Inventory Bulk Drums
Max SDA on Total SOA SDA to EtOHSDA
Total SDA Bulk SDA in Drums SDA SDA SDA in Drums SDA SDA Ending SDA I/aed SDA Used Methanol
Month Beginning Beginning Beginning Received Transferred SDA Used Received Recovered in Recovered SDA Disposed Hand Inventory (genons) (Lbs.) WWT VOC VOC(Lbs,)
Inventory Inventory Inventory Drums Used (�) G I_ (�') (�°')
Janes : 0.0 0.0 0.0 0 0 0 0.0 0.0 Ciao 0.00
Februe Ciao Ciao Ciao 435.5 54.4 29N 381 54 373.7 385.3 7A 0.37
March: 351A 381.1 0.0 2618 381 0 Ciao Ciao Ciao 1.00
26
NI: 381.1 381.1 0.0 2177.8 182.8 17578 2376 183 1255.8 1230.7 23.9 1.28
Ma 2373.9 2375.9 Ciao 1088.8 1994.8 780.0 23802 2250 1215 6345.4 8178.5 158.6 8.35
Juaas: 2248.8 1489.9 TWO532 942 15457 2291 -41 -281.9 -276.3 -5.4 -0.26
00
July: 2291.0 1416.7 874.2 15739 2291 0 Ciao 554 30. 0..5
August 2291A 1418.7 874.2 230.9 15739 2522 -231 -1588.8 -1554.8 -30.1 -1.59
September. 2521.9 1416.7 1105.2 1 117325 2522 0 0.0 0.0 0.0 0.00
October. 2521.9 %16.7 1105.2 633.5 0
17325 3055 -534 -3885.1 -35g1.8 -9 ..00
November. 3055.4 1418.7 1638.7 20991 3055 0 Ciao Ciao 0.00 0,00
December: 3055.4 1416.7 1638.7 20991 3055 0 Ciao Ciao Ciao 0.
TONI 3701.9 0.0 2285.2 0.0 0.0 16M7 Ciao 17D557.4 24179.8 848:b 444L3 {352.5 $4.4 4.4
Botanical Extraction Operation:OS-10
Lbs.EtOH- Lbs.EtDH-
5 Days Los.Botanical Gallons EtOH- Lbs.EtOH- SDA SDA toEtOHSDA Methanol VOC Product
Month
Operated Product SDA Used SDA Used Racove VOC(�) (Lbs.)
Janes 0.00 1 0.00 0.00 0.00
February: 0.00 0.00 0.00 0.00
March: 0.00 0.00 0.00 0.00
ag; DOD 0.00 OAO 0.00
0,00 0.00 1 0.00 0.00
Juror: 0.00 0.00 0.00 O.oD
M y. 0.00 0.00 0.00 0.00 Total SDA Ethanol Data _
Ai must: 0.00 0.00 0.00 0.00 Total Gallons d SDA Used: 1156911.0
0.00 0.00 0.00 0.00 Total Lbs.SDA Used:
Se mbar: 0.00 0.00 0.00 Goo Total Gallons sent W W W r: 833•58
November. 0.00 0.00 0.00 0.00 Total Lbs.wad W WVR: 4332.70
December. Ciao- 0.00 0.00 0.00 Trial Lbs.SDA Ethanol Emitted es VOCS: 54.J9
Avers SDNNI SOIVNI SOIVNI 0.00 A11VI01 0.00 0.00 0.00 Lbs.Botanist Extraction Ethanol Entitled a VOC:OS10 0.00
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 0.00 Lbs.PNE Ethanol Emoted a VOC:OS-7 84.19
PNE Operation:OS-7
-GW
5 Days Lbs.PNE Gallons EtOH- Lbs.EtOH- EIOH- Lbs.ElOtl- EIOHSDA McNaml VOC
Month Operated Product SDA Used SDA Used S A �W VOC(Lbs.) (Lbs.) Product
ract VIA111TIP
January: 0.00 0.00 1 0.0 0-0
Febrw 3 54.4 373.73 366.25 7.1 Nw307
Sveet Potato
March: Ciao
April: 23 7683.80 182.8 1255.84 1230.72 23.9Swat Potato
SvreM Potato,
May: 27 1715.59 1994.8 13701.28 5358.60 8178.78 158.8Carrots
June: 53.2 365.48 647.45 -276.33 -5.4 Canoes
J ; 0,0p 0.00 0.0
Auoust 3 0.00 1588.60 -1554.87 -30.1 Roaem
SsptsnnbM 4 0.00 0.00 0.0 Rosema
October. 5 O.OD 3W5.15 -3591.S4 -69.8Roaema
November. 0,00 0.00 Ciao 0.0
December. 0.00 0.00 0.0 0.0
Avers 11 1699.80 571.3 1427.21 2614.45 395.70 7.03
Total 65 3399.19 2295.2 156g8.32 11257.80 1 4352.70 BC38 44
Page 1 of 5
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4 OS-5,OS-6,OS-10,OS-28,OS-29
OS-13 OS-14 OS-15 OS-16 OS-20 OS-21 OS-22 OS-23.OS-92 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH 05-10•OS-30 INCLUDED WITH OS-28
Year: 2013
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-</=40%n-Hexane(gallons):
Beginning Max
Month Inventory Received Lbe Used Ending Inventory
January: 7659 4460 W655 1788 10331
Febma : 10331 56821 1881 8450
March: 8450 46475 1937 0513
April: 6513 4599 61116 1609 9503
May: 9503 52267 1390 8113
June: 8113 44622 1419 6694
Jul : 6694 4494 61534 2382 8806
Au ust: 1 8806 1 48433 3308 5500
Se tembar: 5500 4354 54197 2284 7570
October- 1 7570 1 4647 1 67194 1 2208 1 10009
November: 1D009 1 1 55050 2046 7963
December: 7963 3513 83118 2525 8951
Monthly Inventory of HP Hexane-</=95%n-Hexane(oallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 10027 55149 1553 8474
February: 8474 46607 1908 6486
March: 6486 35673 1760 4726
April: 4726 6066 59356 1152 9640
May: 9640 53020 9640
June: 9640 53020 2081 7559
Jul : 7559 41575 1594 5965
Au ust: 1 5965 1 5884 1 65170 2900 8949
Se tember: 8949 49220 2623 6326
October: 6326 34793 1 2991 3335
November: 3335 6428 53683 3629 8132
December- 1 6132 1 33723 1 3080 3052
Monthly Inventory of IsoHexane-</-5 n-Hexane Wallons):
Beginning Max
Month InventoryReceived Lbs Used Ending Inventory
January: 36026 47434 459030 41155 42305
Febma : 42305 6459 268202 -667 49431
March: 49431 271871 49431
April: 49431 271871 49431
May: 49431 141 DO 349421 2294 61237
June: 61237 28824 495336 19631 70430
Jul : 70430 15161 470751 19805 65786
Ati usl: 1 65788 1 33226 544586 32084 68928
Se tember: 66928 19635 478097 34149 52414
October: 52414 1 53418 582078 1 46230 59502
November- 1 59602 1 25450 467788 1 19034 66018
December: 1 66018 1 36857 565813 36245 66630
Page 2 of 5
Monthly Emissions of IsoHexane from Biomass Boilers(Lbs.):
Percent n-Hexane: 0.138
Month Material Emissions Hexane Emitted n-Hexane Hexane Isomers
Burned Factor Lbs. Emitted Lbs. Emitted Lbs.
January: 0.00 0.00
February: 0.00 0.00
March: 0.00 0.00
April: 0.00 0.00
May: 0.00 0.00
June: 0.00 0.00
Ju : 0.00 0.00
August: I Sae 1 1921.40 2.65 1918.75
September. Sae 1 2168.25 2.99 2165.26
October: 0.00 0.00
November: 0.00 0.00
December: 0.00 0.00
Avera a #DIVl01 2044.83 0.47 3
Total 0 4089.65 5.64 84.0
Total Hexane Values
Gallons of LP Hexane Used: 24775.00 Gallons of N-Hexane Used: 30918.03
Gallons of HP Hexane Used: 25351.00 Lbs.of N.Hexane Used: 1 170049.19
Gallons of IsoHexane Used: 249960.00 1 Gallons of Hexane Isomers Used:1 263435.47
Total Gallons of Hexanes Used: 300086.00 1 Lbs.of Hexane Isomers Used: 1448895.06
Total Lbs.of Hexanes Used: 1 1650473
Sclareolide(SDE)Operation:OSrb Q S'3 to
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.SDE Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used X n-Hexane Hazardous Emitted Emitted homers
Waste (Lbs.) (Lbs.) Emitted
January: 27 42460.0 1788.0 9834 39.9 9834.00 3923.8 5910.23
February: 22 35527.8 1881.0 10345.5 39.9 832.7 5765.65 2300.5 3465.16
March: 26 44495.0 1937.0 10653.5 39.9 10653.50 4250.7 6402.75
April: 26 34676.4 1609.0 8849.5 39.9 8849.50 3531.0 5318.55
May: 22 1 31372.0 1390.0 7645 1 39.9 7645.00 3050.4 4594.65
June: 18 22710.6 1419.0 7804.5 39.9 771 3564.00 1422.0 2141.96
July: 28 43927.4 2382.0 13101 39.9 13101.00 5227.3 7873.70
August: 30 52140.0 3306.0 18183 39.9 185.5 17162.75 6847.9 10314.81
September: 30 50452.6 2284.0 12562 39.8 709.1 8661.95 3447.5 5214.49
October: 24 38137.0 2208.0 12144 39.7 12144.00 4821.2 7322.83
November: 29 45815.0 2046.0 11253 39.3 11253.00 4422A 6830.57
December: 21 32291.6 2525.0 13887.5 38.6 770.9 9647.55 3724.0 5923.60
Averse 25 39500.5 2064.6 11355.2 39.7 663.840 9856.825 3 49 59
Total 303 474005.4 24775.0 136263 3289.200 118281.900 46968.59T 71313.308
Page 3 of 5 /
Sclareol Recrvstallization(SFG)Operation:OSB p 5 39
Gallons Hexane Monthly Monthly onthly M
N Days Lbs.SFG Gallons Hexane Lbs.Hexane Sentas Hexane n-Hexane Isomer
Hexane
Month Operated Product Used Used X n-Hexane Hazardous Emitted Emitted
Waste (Lbs.) (Lbs.) Emitted
(Lbs.)
January: 31 38435 1553.0 8541.5 91.8 8541.50 7841A 700.40
February: 26 36030 1988.0 10934 91.9 10934.00 10048.3 885.65
March: 31 36425 1760.0 9680 91.9 9680.00 8895.9 784.08
April: 24 26505 1152.0 6336 92.2 6336.00 5841.8 494.21
may: 1 0.0 0 0.00 1 0.0 0.00
June: 28 57494 2081.0 11445.5 92.3 58.2 11125.40 1 10268.7 856.66
July: 30 66620 1594.0 8767 92.3 8767.00 1 8091.9 675.06
August: 29 78577 2900.0 15950 92.0 610.9 12590.05 1 11582.8 1007.20
September: 29 65749 2623.0 14426.5 91.6 232.7 13146.85 12042.3 1104.32
October: 30 74445 2991.0 16450.5 91.6 16450.50 15068.7 1381.84
November: 30 70171 3629.0 19959.5 88.9 19959.50 17744.0 2215.50
December: 27 60971 3080.0 16940 87.3 254.5 15540.25 13566.6 1973.61
Averse 29 55584 2112.6 11619 91.3 289 11089.24 10082.89 1006.55
Total 1 317 1 611422 26361.0 1 139431 1156 133070.85 12 92.31 12078.64
Rotocel&Recovery Operations:O 0535
Gallons Monthly Monthly Monthly
p Days Lbs.Sage Lbs.Sage Gallons Hexane Hexane Hexane n•Hezane Hexane
Monty Isomers
Operated Product Processed Used Lbs.Hexane Used X n-Hexane Sent as
Hazardous Emitted Emitted Emitted
waste (Lbs.) (Lbs.)
January: 31 104951.0 8734280.0 41155 226352.5 0.178 628AO 222896.3 396.8 222499.5
February: 3 10387.0 174440.0 3899 21444.5 0.105 21444.5 22.5 21422.0
March: 0.0 0.0 0.0 0.0
April: 0.0 0.0 0.0 0.0
Maw 3 1222.0 1 1233260.0 2294 12617.0 1 0.107 1 12617.0 13.5 12603.5
Jule: 30 76187.0 18030674.0 19631 107970.5 0.117 36.40 1 107770.3 126.1 107644.2
Jul 31 39950.0 7696128.0 19805 108927.5 0.112 108927.5 122.0 108805.5
Au ust: 30 68620.0 12130410.0 32084 176462.0 0.124 176482.0 218.8 176243.2
Septeimber: 30 69664.0 12999150.0 34149 187819.5 0.178 7.30 187779.4 334.2 187445.1
October. 31 79759.0 12809325.0 46230 254265.0 0.169 254265.0 429.7 253835.3
November: 30 98606.0 10829780.0 19034 104687.0 0.145 104687.0 151.E 104535.2
December: 27 86997.0 10007372.0 28727 157998.5 0.143 157998.5 225.9 157772�111i2A;
6
Averse 25 63633 9464481.9 24701 113212.0 0.138 224.03 112904.0 170.1
Total 246 636333 94644819.0 247008 13686".0 672.10 136047.5 2041.4
Lbs.Hex per day exiting Mineral Accountable Lbs.of Hexane
Oil Scrubber 106.25 Emitted: 140586.29
(Average from MO Tests):
Lbs.of Hex exiting MO Unit: 26137.5 Accountable Lbs.of N•Hex Emitted: 193.73
Lbs.of N-Hex exiting MO Unit: 36.02 Accountable Lbs.of Hexane 140392 56
Isomers Lost:
Lbs.of Hex Isomers exiting MO 26101.48 Fugitive Lbs.Hexane Emitted: 1214261.1E
Unit:
Lbs.Hexane per Lbs.of Spent 0.001140 Fugitive Lbs.n-Hexane Emitted: 1673.25
Sae from Desolvitizer tests
Lbs.Hexane in Spent Sage: 107895.09 ug a s. tt a isomers
Emitteded: 1212587.91
Lbs.N•Hezane In Spent Sage: 148.88 Accountable and Fugitive Lbs. 1354847.45
Hexane Emitted:
Lbs.Hexane per Day from A•1 0 000815 Accountable and Fugitive Lbs. 1866.98
Vent Cond. N-Hex
Emitted:
Lbs.Hex Exiting A-1 Vent: 0.200 Accountable and Fugitive Lbs.Hex 1352980.47
Isomers Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000276
Gallons sent to W WT: 5612789
Lbs.Waste Water per Gal.Waste 8.34
Wt%of Hexane in Waste Water:
Lbs.Hexane Lost In Waste Water. 6553.49 In'^
Lbs.N-Hexane Lost in Waste 8.03 -�� OSa �V wr Au(A4(GY1 VY Io,,
Water:
Page 4 of 5
Concrete Overations:f7S-4
Gallons Monthly
Hexane Monthly Monthly Hexane
Month #Days Lbs.Concrete lbs.Concrete Gallons Hexane Lbs Hexane Used %n-Hexane Sant as Emitted Emitted Hexane n-Hexane Isomers
.
Operated Product Processed Used Hazardous Emitted
Waste (Lbs.) (Lbs.) Lbs.
January: 0.0 0.0 0.0 0.0
February: 12 27683 43890.0 -4566 -25113 0.098 -25113.0 -24.6 -25088.4
March: 0 634.90 -3492.0 0.0 -3492.0
April: 0.0 0.0 0.0 0.0
May: 0.0 0.0 0.0 0.0
June: 0 0.0 0.0 0.0
Jut 0 0.0 0.0 0.0
Au ust: 0 0.0 0.0 0.0
Se tember: 0 0.0 0.0 0.0
October: 0 0.0 0.0 0.0
November: 0 0.0 0.0 0.0
December: 0 0.0 0.0 0.0
Averse 12 27883 43890.0 -4588 •2092.8 0.098 834.90 -2383.7 •2.1 -2381.7 L
Total 12 27683 43890.0 d688 -25113.0 634.80 -28806.0 -24:8 -28680.3
Lbs.Hexane per Day from A-1 0.000815 Accountable Lbs.of Hexane Lost: 94.62
Vent Cond.
Days A-1 Operated: 12 Accountable Lbs.of N-Hex Lost: -0.35
Lbs.Hex Exiting A-1 Vent: 0.010 Accountable Lbs.of Hexane 94.97
Isomers Lost:
Lbs.N-Hex Exiting A-1 Vent: -0.446555 Fugitive Lbs.Hexane Lost: 47287.33
Gallons sent to WWT: 81026 Fugitive Lbs.n-Hexane Lost: 46.34
Lbs,Waste Water per Gal.Waste 8.34 Fugitvs lbs.Hexane Isomers Lost 47240.99
Water:
Wt%of Hexane In Waste Water: 0.014 Accountable and Fugitive Lbs. 47381.95
Hexane Emitted:
Lbs.Hexane Lost in Waste Water. 94.61 Accountable and Fugitive Lbs. 45.99
N-Hex Emitted:
Lbs.N-Hexane Lost in Waste 0 Accountable and Fugitive Lbs.Hex 47335.98
Water. Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons Hexane Monthly Monthly Monthly
Month
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane r h n-Hexane Sent as Hexane n-Hexane Hexane Operated Product Used Used Hazardous Emitted Emitted Isomers
Waste (Lbs.) (Lbs.)
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 6663.0 0.00 0.0 0
May: 0 1 0.00 1 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 25 175672 7518.0 41349 0.173 41349.00 71.5 41277.486
Average 25 #DIVI01 7518.0 3446.75 0.173 6663.0 3445.76 5.96 3 79
Total 25 0 7518.0 1 41349.00 1 6663.0 41349.00 .53 41277.47
Page 5 of 5
Botanical Extraction Operation:OS-10
Gallons Hexane Monthly Monthly Monthly
#Days Lbs.Biomass Gallons Hexane Lbs.Hexane Sent as Hexane n-Hexane Hexane
Month Operated Product Used Used %n-Hexane Hazardous Emitted Emitted Isomers
Emitted
Waste (Lbs.) (Lbs.)
January: 0 0.00 0.0 0
February: 0 0.00 0.0 0
March: 0 0.00 0.0 0
April: 0 0.00 0.0 0
Ma 0 1 0.00 0.0 0
June: 0 0.00 0.0 0
July: 0 0.00 0.0 0
August: 0 0.00 0.0 0
September: 0 0.00 0.0 0
October: 0 0.00 0.0 0
November: 0 0.00 0.0 0
December: 0 0.00 0.0 0
Avers s #DIV/01 #01V/01 0DIV101 0.00 #DfV/01 #DIV10I 0.00 0.00 0.00
Total 0 0 0.0 0.00 0.0 0.00 0.00 0.00
Plant Nutrient Extraction(M-13)Operation:OS-29
Gallons Hexane Monthly Monthly Monthly
Hexane
Isomers#Days Lbs.PNE Gallons Hexane Lbs.Hexane Santos Hexane n-Hexane
Month X n-Hexane Isomers
Operated Product Used Used Hazardous Emitted Emitted Emitted
Waste (Lbs.) (Lbs.)
January: 0.0 0 0.00 0.0
February: 0.0 0 0.00 0.0
March: 0.0 0 0.00 0.0
April: 0.0 0 0.00 0.0
May: 0.0 1 0 1 0.00 0.0
June: 0.0 0 0.00 0.0
July: 0.0 0 0.00 0.0
August: 0.0 0 0.00 0.0
September: 0.0 0 0.00 0.0
October: 0.0 0 0.00 0.0
November: 0.0 0 0.00 0.0
December: 0.0 0 0.00 0.0
Averse #DIVI01 #DIVI01 #DIVI01 0.0 #DIV101 #DIVI01 0.000 0.00 0.00
Total 0 0 0 0.0 0.0 0.000 0.00 0.00
Totals for All Operations
Fugitive Lbs.Hexane Emitted: 1554250.25 Total Lbs.Hexane Released: 1699020.80
Fugitive Lbs.N-Hexane Emitted: 169752.03 Total Lbs.n-Hexane Released: 169951.04
Fugitive Lbs.Hexane Isomers 1384498 22 Total Lbs.Hex Isomers Released: 1529069.76
Emitted:
Accountable Lbs.Hexane Lost: 144770.55 Total Lbs.Hexane Sent Off She: 68175.25
Accountable Lbs.n-Hexane Lost: 199.01 Total Lbs.N-Hexane Sent Off Site: #DIV/01
Accountable s. ex Somers 144571 54 o s. ex somers en #DNI01
Lost: Site:
Annual Summarw Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 61110 11977 65870.8
February: 64367 9384 51612.5
March: 60670 6942 38180.3
April: 69574 12680 69738.8
May: 789N 3303 18164.4
June: 94683 9730 53516.5
Ju : 80557 9093 50011.3
Au ust: 81377 10511 57808.1
Se tember: 68310 8901 48954.3
October: 72946 7129 39210.4
November: 80113 8676 41715.5
December. 78633 1 8214 34178.8
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
84683 12680 69739
Page 1 of 2
Annual Air Emissions Inventory
Facility IDN:08000 �
Methanol:O - �-8 °5-3 S o S'4
OS-13 OS.14 OS-15 OS-16 OS-17 OS-27 05-321NCLLIDED WITH OS 4
Year: 2013
Info: Lbs/Gal= 6.62 Specifics Gravity-0.793
Monthly Inventory of Methanol laallonsl: Methanol Used Alcoholoh in SDA-3A
al
Month Beginning Raceivetl Max Used Recovered Ending oJanua
Methanol
Inventory (Lbs) Inventory Emitted(Lbs.)
January: 13272 7328.0 138372 11077.0 9523 0.00
Februa : 9523 14703.0 160376 5665.0 18561 0.37
March: 18561 122874 4790.0 13771 0.00
April: 13771 15650.0 194767 6576.0 23845 1.26
Ma 23845 157854 2788.0 21057 8.35
June: 21057 139397 8288.0 12769 -0.28
Jul : 12789 15160.0 184890 8078.0 19853 0.00
19853 7882.0 183811240.0 16495 -1.59
Ss mMr. 16195 7587.0 15S423 9050.0 15032 September: 0.00
October: 1 15032 1 22993.0 1 251728 1 14368.0 1 23657 October: -3.67
November: 1 23667 1 8349.0 1 211880 1 11959.0 1 20047 November. 0.00
December: 20047 7808.0 184400 9523.0 18332 December: 0.00
Maximum Gallons On-liantl: 38025
Maximum Lbs.On-Hand: 251726.5
Gallons Used per Year.. 102400
Lbs.Used per Year: 877888
Sclareol Recovery Ooerationi OS-4
Accountable
N Days Gallons WON Lbs.McOH Avg.GPM Sent Lbs.WON to Avg'% Total Gel. Monthly Avg. Emissions of Total Lbs, Total Lbs
Month Operated Used Used to VANTP WWTP Methanol in Water to Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP (O Emissions
17
January31 11077 73329.74 1.4 26342.3 6.37 124145 98.5 395.1345 40987.44 47382.575
February3 1345 8903.9 1.4 2094.6 5.23 17072 99.1 18.8514 5809.3 6828.1514
March 0 0 0 0
April 0 0 0 0
Me 3 0 1.4 1366.E 5.12 8492 99.1 12.2994 0 0
June 30 8288 54885.5E 1.16 22491.5 6.91 159898 98.9 247,4005 32375.06 32622.467
Jul 31 4668 30888.92 2.27 14D43 2.70 158887 99.3 98.301 16845.92 16944.221
Au oust 30 8150 54019.2 1.02 20240.6 7.16 103337 99 202,406 33778.8 33981.006
September 30 8115 53721.3 1.25 20022.9 5.76 123732 99.2 180.1832 33698.4 33858.583
October 31 9004 59606.48 1.17 19913.4 5.85 109848 99.2 159,3072 39893.08 39852.387
November 30 10639 70430.18 1.4 23571.1 5.89 137323 98.7 306.4243 46859.08 47165.5D4
December 27 9523 63042.26 1A 21810.4 5.84 175279 98.9 239,9144 41231.86 41471.774
Averse 24.60 7868.56 39067.38 1.39 17189.84 5.68 112761.30 88.99 1 29 25008.89
Total 246 70817 468908.54 171896.4 1127613 989.9 1840.2279 278.74 106.67
p5 3S
Concrete Operation:OS-4
Accountable
N Days Gallons WON Lite.WON Avg.GPM Sant lbs.McOH to Avg'% Total Gal. Monthly Avg. Emissions of Total Lbs. Total Lbs.
Month Operated Used Used to WWTP WWTP Methanol In Waterto Removal McOH from Fugitive Emissions
WW WWTP Efficiency WWTP Emissions
(OS-171
January 0 0.00 0 0
Febmary 12 1288 8526.58 1.4 588e.5 4.88 479M 98.9 64.63 2660.06 2724.5915
March 0 0.00 0 0
April 0 0.00 0 0
may 0 0.00 0 0
June 0 0.00 0 0
July 0 0.00 0 0
August 0 0.00 0 0
September 0 0.00 0 0
October 0 0.00 0 0
November 0 0.00 0 0
December 0 0.00 0 0
Averacie 12.00 1288.00 710.55 1.40 5866.50 4.80 47996.00 98.90 U= 227.05
Total 12 1288 8525.56 5866.5 47998 98.9 84.531 '2660.08 2724.5915 n
1
tj
rr4 P
30o130 s
Page 2 of 2
oy9)
Accountable
Emissions of Total Lbs.e Days Gallons McOH Lbs.MdOH Gallons one MSOH Lbs.McOH to Total ions
Month Operated Used Use0 to WWTP yyyVTp MaOH from Fugitmission Emissions
WWTP Emissions
(OS-17)
January 0 0 0.00 0.00 0.00 0.00
February 25 3032 20071.84 2971.36 19670.40 393.41 401.44 794.84
March 22 4790 31709.8 4694.2 31075.60 621.51 634.20 1255.71
April 22 5576 36913.12 5464.48 36174.88 723.50 738.26 1481.76
Mav 11 2788 18456.56 2732.24 1808743 361.75 369.13 730.88
June 0 0 0.00 0.00 0.00 0.00
July 17 3410 22674.2 3341.8 22122.72 442.45 451.48 893.94
Au ust 18 3080 20389.6 3018.4 19981.81 399.64 407.79 80743
September 8 935 6189.7 916.3 6085.91 121.32 123.79 245.11
October 25 5354 36609+68 5256.72 34799.49 695.99 710.19 1406.18
November 7 1320 8738.4 1293.6 8563.63 171.27 174.77 346.04
December 0 0 0.00 0.00 0.00 0.00
Average 17.00 3366.11 16712.74 2474.09 16378.49 327M 334.25 661.82
Total 153 30295 200552.9 196541.84 3930. AW1.06 7941.89
PNE Operation:OS-7
Accountable
a Days Gallons McOH Lbs.MeOH Gallons Lbs. to Emissions of Total Lbs. Total Lbs.
Monet Operated Used Used to WVJTP TP WWTpWTp McOHfrom ssion Emissions
WWTP Emissions
OS-17
January 0 0 0.00 0.00 0.00 0.00
February 0 0 0.D0 0.00 O.DO 0.00
March 0 0 0.00 0.00 0.00 0.00
April 0 0 0.00 0.00 0.00 0.00
May 0 0 0.00 0.00 0.00 0.00
June 0 0 0.00 0.00 0.00 0.00
Ju 0 0 0.00 ID
DOO 0.00
Au ust 0 0 0.00 0.00 0.00
Se mbar 0 0 0.00 0.00 0.00
October 0 0 0.00 0.00 0.00
Nowmber 0 0 0,00 0.00 0.00
December 0 0 0.00 0.00 0.D0
Amore 9DrV/01 ODIV/01 0.00 0.00 0.00 0.00 0.00 0.00
Total 0 0 0 0.00 0.00 0.00 0.00
Totals for All Methanol Operations
Total Lbs.MsDH Thru System: 2842128.00 Lbs.Fugivdve Emissions from EVG: 4011.06
Total s.M90H Treatedat 374304 74 Lbs,Fuglvtiw Emissions from Recovery: 298278.74
WWTP:
Calculated emova Efficiency of W WTP: 99.95 Lbs.Fugitive Emissions from Concrete: 215W.08
Lbs.Accountable Emissions 5835.80 Total Lbs.Fugitive Emissions: 308790.09
from WWTP(OS-IT):
Lbs.of Emissions from W WTP 1840.23 Total Lbs.McOH Released: 312625.68
Dunn Recove
Lbs.of Emisa ons m 64.5315 Total Lbs.MaOH Recycled On-Site: 2467823.26
Durin Concrete Recove
Lbs.of Emissions
hom W WTP 3930.84
tat Aeration Chamber OS-17:
Los.INEmiasions rom isc.,
Lab:
Annual Air Emissions Inventory
Facility ID#:08000g4
Heptane : OS-6, OS-7, OS-10
Year: ® 1
Info: Lbs/Gal= 5.70
Mon h1v Inventory of He tape allons :
Beginning Max Recovered Ending
Month InventoryReceived Lbs New Used Used Recovered Inventory
January: 7058 40231 240.0 556.3 7374
February: 7374 1 42034 7374
March: 7374 1 2200 54574 3355.0 6219
April: 6219 35450 2189.3 1592.5 5622
May: 5622 32048 5622
June: 5622 32048 240.0 150.0 5532
July: 5532 31535 150.0 1424.6 6607
August: 6807 5185 68355 2750.0 9242
September: 9242 3300 71490 3017.1 1796.5 11321
October: 11321 64532 11321
November: 11321 9179 116853 7199.0 13301
December: 1 13301 75818 13301
'SFG M-13 O ration:OS 39
Gallons Monthly Monthly
Gallons Gallon Heptane n-
Month #Days Lbs.PNE Heptane Lbs.Heptane %n-Heptans Heptane Heptane Sent Emitted as Heptane
Operated Product Used Used Recovered as Hazardous VOC Emitted
Waste (Lbs.) (Lbs.)
January: 19 26506 240.0 1368.0 556.3 1802.9 0.00
February: 0.0 0.0 0.00
March: 0.0 1 0.0 0.00
April: 1 0.0 1 0.0 0.00
May: 0.0 1 0.0 0.00
June: 0.0 0.0 0.00
July: 0.0 0.0 0.00
August: 0.0 0.0 0.00
September: 0.0 0.0 0.00
October: 0.0 0.0 0.00
November: 0.0 0.0 0.00
December: 0.0 0.0 0.00
Averse 19 26506 1 240.0 114.0 #DIV101 556.3 11 #DN/01 -150.2 0.00
Total 1 19 26606 240.0 1368.0 1 556.3 1 0.0 1 -1802.9 0.00
Botanical Extraction Operation:OSf0 OS VO
Gallons Monthly Monthly
#Days Lbs. Gallons Lbs.Heptane Gallons Heptane Sent Heptane n-
Month Botanical Heptane Used as Hazardous%n-Heptane Heptane Emitted as Heptane Product
Operated product Used Recovered VOC Emitted
Waste
January: 0.0 0 0.00
February: 0.0 0 0.00
March: 11 3355.00 19123.5 1592.5 10046.25 0.00 Tobacco
A rii: 1 21 1 2189.30 12479.0 12479.01 0.00 Krill
may: 0.0 0 0.00
June: 0.0 0 0.00
July: 0.0 0 0.00
Au ust: 5 2750.00 15675.0 178.9 179 13635.54 0.00 Tobacco
Se tember: 9 3017.10 17197.5 1796.5 6957.42 0.00 Tobacco
October: 0.0 0 0.00
November: 11 7199.00 41034.3 41034.3 0.00 Nicotine
December: 0.0 0 0.00
Averse 11 #DIV/0! 3702.08 8792.4 #DIVI01 1189.3 178.9 7012.710 0.00
Total 57 0.00 18610.40 106508.3 3567.9 178.8 84162.520 0.00
SFG Operation:OS-6
Gallons Monthly 1000
#Days Lbs.PNE Gallons Lbs.Heptane Gallons Heptane Sent HeptaneMonth Operated Product Heptane Used %n•Heptane Heptane as Hazardous Emitted as
Used Recovered Waste VOC
January: 0.0 0
February: 0.0 0
March: 0.0 0
April: 0.0 0
May: 0.0 0 0.00
June: 0.0 0 0.00
July: 0.0 0 0.00
August: 0.0 0 0.00
September: 0.0 0 0.00
October: 0.0 0 0.00
November: 0.0 0 0.00
December: 0.0 0 0.00
Avera a #DIV/01 #DIVl01 #DIVIO! 0.0 #DIV/01 DIV/01 #DIV/01 0.000 0.00
Total 0 0 0 0.0 0.0 0.0 0.000 0.00
PNE M-13 O eration:OS-7
Gallons Monthly Monthly
#Days Lbs.PNE Gallons Lbs.Heptane o Gallons Heptane Sent Heptane n-
Month Heptane /o n-Heptane Heptane as Hazardous Emitted as Heptane Product
Operated Product Used Used Recovered waste VOC Emitted
January: 0.0 0.0 0.00
February: 0.0 0.0 0.00
March: 0.0 0.0 0.00
April: 1 0.0 0.0 0.00
Ma : 0.0 0.0 0.00
June: 4 240.0 1368.0 150.0 513.0 0.00 Tobacco
July: 5 150.0 855.0 1424.6 -7265.2 0.00 Tobacco
Au ust: 0.0 0.0 0.00
Se tember: 0.0 178.9 -1019.7 0.00
October: 0.0 0.0 0.00
November: 0.0 0.0 0.00
December: 0.0 178.9 -1019.7 0.00
Avera e 5 #DIV101 195.0 185.3 #DIVIO! 787.3 178.9 -732.6 0.00
Total 9 0 390.0 2223.0 1574.6 357.8 -8791.7 0.00
Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2013
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (lbs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2013
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Month Inventory Received (Lbs) New Used Recovered Recovered Inventory
Used
January: 998 7206 998
Februa 998 7206 998
March: 998 7206 998
April: 998 7206 998
May: 998 7206 998
June: 998 7206 998
July: 998 7206 998
August: 998 7206 998
September: 998 7206 998
October: 998 7206 998
November: 998 7206 998
December: 998 7206 998
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyl acetate: OS-7, OS-10
Year: 2013
Info: Lbs/Gal =
Monthly inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of[PAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0
Annual Air Emissions Inventory
Facility ID#:0800044
n-Butylacetate: OS-10
Year: 2013
Info: Lbs/Gal= 7.35
Monthly Inventory of n-Butyl acetate(nallons):
Month Beginning Received Max Used Recovered Ending
Inventory Lbs New Used Recovered Used Inventory
Janua : 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
Au ust: 1 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 1 0 0 0
Gallons of NBAC used during the year @ PNE(OS-7): 0
Lbs.Of NBAC used during the year @ PNE(OS-7): 0
Gallons of NBAC used during the year OS-10 :
Lbs.Of NBAC used during the year@(OS-10 : 0
Lbs.of NBAC used by Misc.,QA,and R&D:
Lbs.of NBAC sent to hazardous waste: 12580
Lbs.of NBAC sent to wwt:
Lbs.of NBAC emitted during year: -12580
Annual Air Emissions Inventory
Facility ID#:0800044
Pentanone: OS-10
Year: 2013
Info: Lbs/Gal= 6.01
Monthly Inventory of Pentanone(gallons):
Beginning Max Used Ending
Month InventoryReceived Lbs New Used Recovered Used Recovered Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
Au ust: 1 0 1 0 0
September: 1 0 1 0 0
October: 0 0 0
November: 0 0 0
December: 0 1 0 0
Gallons of Pentanone used during the year @ PNE(OS-7): 0
Lbs.Of Pentanone used during the year @ PNE(OS-7): 0
Gallons of Pentanone used during the year OS-10):
Lbs.Of Pentanone used during the year OS-10 : 0
Lbs.of Pentanone used by Misc.,CIA,and R&D:
Lbs.of Pentanone sent to hazardous waste: 1360
Lbs.of Pentanone sent to wwt:
Lbs.of Pentanone emitted during year: -1360
Annual Air Emissions Inventory
Facility ID#: 0800044
Maganese
Year: 2073
Info: Potassium permanganate contains 33-35% Manganese.
Monthiv In entory of Potassium Perman anate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 1 16537 16537
June: 16537 16537 16537
Jul : 16537 16537 1 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November7 1 16537 16537 16537
December: 1 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2013
Info: Lbs/Gal =
Monthly Inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs. of Sulfur dioxide used by Misc., QA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0
Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2013
Info: Lbs/Gal = 7.50 All ethylenediamine is contained and
shipped off-site with the product.
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
Jul : 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0
I
Annual Air Emissions Inventory
Facility ID#:0800044
Toluene
Year. 2013
Info: Lbs/Gal= 7.23
Monthly Inventory of Toluene(gallons):
Beginning Max Ending
Month Inventory Received Lbs In Process Recovered In Product Total Used Inventory
January: 1531 11069 0 1531
February: 1531 11069 0 1531
March: 1531 11069 0 1531
April: 1531 11069 0 1531
May: 1531 11069 0 1531
June: 1531 11069 0 1631
July: 1531 11069 0 1531
August, 1531 1 11069 0 1531
September. 1531 11069 0 1531
October: 1531 11069 0 1531
November: 1531 11069 0 1531
December: 1531 11069 0 1531
November: 1531 11069 0 1531
December: 1531 11069 0 1531
Total 0 0 0 0 0 21434
Botanical Extraction Operation:OS-10
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Emitted as Toluene Toluene
Operated Product Toluene Used Used Recovered in Product
VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/01 #DIV/01
February: 0.00 0.00 0.00 #DIV/01 #DIV/01
March: 0.00 0.00 0.00 #DIV/01 #DIV/Of
April: 0.00 0.00 0.00 #DIV/Of #DIV/01
May: 0.00 0.00 0.00 #DIV/01 #DIV/01
June: 0.00 0.00 0.00 #DIV/01 #DIV/01
July: 0.00 0.00 0.00 #DIV/01 #DIV/01
August 0.00 0.00 0.00 #DIV/01 #DIV/01
September. 0.00 0.00 0.00 #DIVI01 #DIV/01
October: 0.00 0.00 0.00 #DIV/01 #DIV/01
November: 0.00 0.00 0.00 #DIV/01 #DIVI01
December: 0.00 0.00 0.00 #DIV/OI #DIV/01
Averse #DIVI01 #DIVI01 #DIVI01 0.00 #DIVIOI 0.00 0.00 #DIVI01 #DIV/01
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 #DIV/01 #DIVI01
PNE Operation:OS-7
#Days Lbs.Botanical Gallons Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.Toluene Lbs.per Day Lbs.per Hour
Month Operated Product Toluene Used Used Recovered in Product Emitted as Toluene Toluene
VOC Emitted Emitted
January: 0.00 0.00 0.00 #DIV/01 #DIV/01
February: 0.00 0.00 0.00 #DIV/01 #DIV/01
March: 0.00 0.00 0.00 #DIVI01 #DIV/01
April: 0.00 0.00 0.00 #DIVI91 #DIVI01
May: 0.00 0.00 0.00 #DIV/01 #DIV/01
June: 0.00 0.00 0.00 #DIV/01 #DIV/01
July: 0.00 0.00 0.00 1 #DIVI01 #DIV/01
August: 0.00 0.00 0.00 #DIVI01 #DIV/OI
September: 0.00 0.00 0.00 #DIV/01 #DIV/01
October: 0.00 0.00 0.00 #DIV/oI #DIV/01
November. 0.00 0.00 0.00 #DIV/01 #DIVI01
December. 0.00 0.00 0.00 #DIV/Ot #DIV/01
Averse #DIVI01 #DIVI01 #DIVIOI 0.00 #DIV/OI 0.00 0.00 #DIV/01 #DIVI01
Total 0 0.00 0.0 0.00 0.00 0.00 0.00 #DIVI01 #DIVI01
Gallons of Toluene used during the year. 0.00
Lbs.of Toluene used during the year. 0.00
Lbs.Botanical Extraction Toluene Emitted:OS-10 0.00
Lbs.PNE Toluene Emitted:OS-7 0.00
Lbs.of Toluene sent to hazardous waste:
Total Fugitive Lbs.Toluene Emitted: 0.00
Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2013
The Plant Material Grinder(OS-3) is operated in building ID# 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.
7
COPY of RECORD Date Submitted: 4/9/201410:36:48
Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility I : 0800044
841 Avoca Farm Road Permit : 0 Berle
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sin this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1.For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars);or
ii.the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
.F.RTIFICATION STATEMENT!
L
the responsible official for this facility,as described above,and hereby certify that the information contained
ns report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Si ature Below use blue ink): Date Signed:
rioted Name: David e e i�'/• _e'���
Si nature:
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official:
david.peele@avocaine.com
Information on this Form cannot be held confidential ij 6 ZQ�
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered In AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
Listing of Emission Sources and Control Devices on Permit. See instructions
DES ID on Air DES Description GCS ID GCS Description CD ID's
Permit
one(1)jet ejector
One distillation column venturi—type wet scrubber
A-2 (6 gallons per minute CS-1 (10 GPM injection rate, CD—M-34
nominal process rate) ID No.M-34) Sclareolide
[MACT FFFF] O s.
one condenser(ID No.
One centrifuge[MACT CS-11 CD-3001)installed on CD—EX-3001
C-3001 FFFF] centrifuge,reactor and
heat exchanger/dryer
C-31203 One centrifuge [MACT
FFFF]
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-1201 One steam—heated dryer CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
[MACT FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
rocess)
one(1)jet ejector
venturi—type wet scrubber
D-1202 One steam—heated dryer CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
Ops.
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-1215 One reactor[MACT CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
process)
D-1218 One reactor[MACT CS-7 One(1)water spray CD—Z-9215,CD—Z-9216
FFFF] fume scrubber used in the
EVG Operation(batch
flavorant process),One
(1)caustic solution fume
scrubber used in the EVG
2
Operation(batch flavorant
process)
one(1)jet ejector
venturi—type wet scrubber
One batch reactor CS-1 (10 GPM injection rate, CD—M-34
D-1231 A [MACT FFFF]
ID No.M-34)Sclareolide
s.
one(1)jet ejector
venturi—type wet scrubber
D-1231B One batch reactor CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
One(1)water spray
fume scrubber used in the
EVG Operation(batch
D-2202 One reactor[MACT CS-7 flavorant process),One CD—Z-9215,CD—Z-9216
FFFF] (1)caustic solution fume
scrubber used in the EVG
Operation(batch flavorant
process)
one condenser(ID No.
D 3001 One steam—heated dryer CS-11 CD-3001)installed on CD—EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/dryer
One waste solids
separator vessel(1,333
D3121 1 gallon capacity)[MACT
FFFF
One product extract
D31214 reactor MACT FFFF]
One No. 2 fuel oil—fired
emergency generator
6101 (587 horsepower
maximum rated power
output) [MACT ZZZZ]
One No.2 fuel oil—fired
emergency generator
G 102 (760 horsepower
maximum rated power
output)[MACT ZZZZ
One No. 2 fuel oil—fired
emergency generator
E103 (603 horsepower
maximum rated power
ou ut) [MACT ZZZZ]
Chilled Water—Cooled
Process equipment leaks Condenser,Packed Tower
ES-1001-1-1—F [PSD,MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
ES-1001-1-1—P1 JArcon process tank M-1 CS-17 Chilled Water—Cooled CD-31209,CD-1001-2—S-1
[PSD,CAM,MACT Condenser,Packed Tower
3
FFFF] Scrubber(10 gpm mineral
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Stripper T-5 and receiver Condenser,Packed Tower
ES-1001-1-1—P2 M-21 [PSD,CAM, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Seven process tanks of Chilled Water—Cooled
various capacities and Condenser,Packed Tower
ES-1001-1-1-P3 one fixed roof methanol CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
storage tank(7,050 oil scrubbing liquid
gallon capacity) [PSD, injection rate),
MACT FFFF]
Chilled Water—Cooled
Recovery Operations Condenser,Packed Tower
ES-1001-1-1—WW wastewater stream[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed Tower
ES-1001-1-2—F Process equipment leaks CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
[MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Six process tanks of Condenser,Packed Tower
ES-1001-1-2—P various capacities[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Concrete Operations Condenser,Packed Tower
EES-1001-1-2-WW wastewater stream CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
[MACT FFFF] oil scrubbing liquid
injection rate),
one(1)jet ejector
venturi—type wet scrubber
Process equipment leaks CS-1 10 GPM injection rate, CD—M-34
ES-1001-1-3—F [MACT FFFF]
ID No.M-34)Sclareolide
O s.
one(1)jet ejector
Twelve process tanks of venturi—type wet scrubber
ES-1001-1-3—P various capacities CS-1 (10 GPM injection rate, CD—M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
Biological conversion one(1)jet ejector
equipment for the venturi—type wet scrubber
ES-1001-1-3—WW purification of sclareolide CS-1 (10 GPM injection rate, CD—M-34
wastewater stream ID No.M-34)Sclareolide
MACT FFFF] O s.
ES-1001-1-4—F Process equipment leaks CS-1 I one(1)jet ejector CD—M-34
[MACT FFFF] venturi—type wet scrubber
(10 GPM injection rate,
4
ID No.M-34)Sclareolide
O s.
one(1)jet ejector
venturi-type wet scrubber
Four process tanks of ES-1001-1-4-P various capacities CS-1 (10 GPM injection rate, CD-M-34
ID No.M-34) Sclareolide
s.
one(1)jet ejector
SDE Operations venturi-type wet scrubber
ES-1001-1-4-WW wastewater stream CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
s.
Chilled Water-Cooled
Process equipment leaks CS-16 Condenser,Liquid CD-100111EX1002,CD-100111EX1003
ES-1001-11-F [PSD,MACT FFFF] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-1001,desolventizer
Z-1002,day tank 90024
(6,000 gallon capacity),
first-stage evaporator Chilled Water-Cooled
ES-1001-11-P EX-1012,second-stage CS-16 Condenser,Liquid CD-1001 1 1EX1002,CD-1001 11 EX 1003
evaporator EX-1013, Nitrogen-Cooled
distillation column Condenser,
EX-90008,and nine
process tanks of various
capacities [PSD,CAM,
MACT FFFF
Botanical extraction Chilled Water-Cooled
ES-1001-11-WW operation wastewater CS-16 Condenser,Liquid CD-1001 1 1EX1002,CD-1001 1 IEX1003
stream[PSD,MACT Nitrogen-Cooled
FFFF] Condenser,
Chilled Water-Cooled
Condenser,Packed Tower
Process equipment leaks ES-1001-2-1-F [PSD,MACT FFFF] CS-17 Scrubber(10 gp m mineral CD-31209,CD-1001-2-5-1
oil scrubbing liquid
injection rate),
Rotocel extractor, Chilled Water-Cooled
desolventizer,and Condenser,Packed Tower
solvent CS-17 Scrubber 10 m mineral CD-31209,CD-1001-2-S-1
ES-1001-2-1-P1 separation/recovery
[PSD,CAM,MACT oil scrubbing liquid
FFFF] injection rate),
Chilled Water-Cooled
Two solvent recycle Condenser,Packed Tower
ES-1001-2-1-P2 process tanks[PSD, CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-S-1
CAM,MACT FFFF] oil scrubbing liquid
injection rate),
ES-1001-2-1-WW Rotocel Operations CS-17 Chilled Water-Cooled CD-31209,CD-1001-2-5-1
wastewater stream[PSD, Condenser,Packed Tower
MACT FFFF] Scrubber(10 gpm mineral
oil scrubbing liquid
5
injection rate),
one condenser(ID No.
rES-1003-10-F Process equipment leaks CS-11 CD-3001)installed on CD-EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/drver
cess tanks of
EJ:;J
capacities
FFFF
Enesat
ser(ID No.
cess wastewater CS-11nalled onCD-EX-3001
[MACT FFFF] ctor andger/dryer
ES-1003-2-1-F Process equipment leaks
CT FFFF]
Seven process tanks of
ES-1003-2-1-P various capacities
MACT FFFF
PNE process wastewater
ES-1003-2-1-WW stream[MACT FFFF]
one(1)jet ejector
venturi-type wet scrubber
ES-1003-2-2-F Process equipment leaks CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34)Sclareolide
O s.
one(1)jet ejector
EVG Operation venturi-type wet scrubber
ES-1003-2-2-WW wastewater stream CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
S.
Chilled Water-Cooled
Biomass extraction :CS-:21 Condenser,Liquid CD-1004-2EX1002,CD-1004-2EX1003
ES- ]004-1 debagging[PSD] Nitrogen-Cooled
Condenser,
Chilled Water-Cooled
Process equipment leaks CS-21 Condenser,Liquid CD-1004-2EX1002,CD-1004-2EX1003
ES-1004-2-F [PSD] Nitrogen-Cooled
Condenser,
Immersion extractor
Z-41001,desolventizer
Z-41002,day tank
490025 (9,953 gallon
capacity),isohexane
storage tank 490024 Chilled Water-Cooled
ES-1004-2-P (13,536 gallon capacity), CS-21 Condenser,Liquid CD-1004-2EX1002, CD-1004-2EX1003
first stage evaporator Nitrogen-Cooled
EX-41012,second stage Condenser,
evaporator EX-41013,
distillation column
EX-490008,and nine
process tanks of various
capacities [PSD,CAM]
6
Chilled Water-Cooled
Biomass extraction Condenser,Liquid
ES-1004-2-WW operation wastewater CS-21 CD-1004-2EX1002,CD-1004-2EX1003
Nitrogen-Cooled
stream[PSD] Condenser,
Bagfilter(254 square CD-1004-2-FF2
ES-1004-2Silo Biomass silo loadout CS-23 feet of filter area),
One biomass/bio-based
solids-fired boiler(24 one simple cyclone(144
million Btu per hour CS-24 inches in diameter),one CD-BB IC,CD-BB 1BH
ES-BB 1 maximum heat input rate) bagfilter(8,900 square
[NSPS-Dc,MACT- feet of filter area),
DDDDD
One biomass/bio-based
solids-fired boiler(24 one simple cyclone(144
million Btu per hour CS-24 inches in diameter),one CD-BB1C,CD-BB1BH
ES-BB2 maximum heat input rate) bagfilter(8,900 square
[NSPS-Dc,MACT- feet of filter area),
DDDDD]
ES-MDSU-1024 molecular sieve
Imaxnnum
o.2 fuel oil-fired Oxidation Catalyst
d use emergency [17,070 acfm(6,854
ES-PkGenitor(2,935 kilowatt CS-22 CD-CatOxl
scfin)inlet air flow rate at
rated power 695 OF-835 OF],
) [MACT ZZZZ]
neNo. 2 fuel one simple cyclone(144
oil/propane-fired rotary inches in diameter),one
ES-RD dryer(30 million Btu per CS-24 CD-BBIC,CD-BB1BH
bagfilter(8,900 square
hour maximum heat input feet of filter area),
rate)
One No. 2 fuel oil-fired
emergency fire water
FP pump(285 horsepower
maximum rated power
ou ut) [MACT ZZZZ]
one(1)jet ejector
venture-type wet scrubber
One centrifuge[MACT CS-1 (10 GPM injection rate, CD-M-34
-1 FFFF]
ID No.M-34) Sclareolide
O S.
One No.2 fuel oil-fired
boiler(20.3 million Btu
H-101 per hour maximum rated
heat input)[2D .1109
case-by-case MACT]
One No. 2 fuel oil-fired
boiler(20.3 million Btu
H-102 per hour maximum rated
heat input) [21) .1109
case-by-case MACT
H-103 One No.2 fuel oil-fired
boiler(25.2 million Btu
per hour maximum rated
7
heat input)[2D.1109
case—by—case MACT]
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
HB-1 box[MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
Condenser,Packed Tower
HB-2 One steam—heated hot CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2-5-1
box [MACT FFFF] oil scrubbing liquid
injection rate),
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
HB-3 box [MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
Chilled Water—Cooled
One steam—heated hot Condenser,Packed Tower
H 13 4 box [MACT FFFF] CS-17 Scrubber(10 gpm mineral CD-31209,CD-1001-2—S-1
oil scrubbing liquid
injection rate),
ECS process:batch
IECS preparation of
ethylenediamine/copper
sulfate solution
IES—PV propane vaporizer
No. 2 fuel oil storage
ITK102 tank(495 gallon
capacity)
No.2 fuel oil storage
ITK103 tank(495 gallon
ca aci )
No.2 fuel oil storage
ITK9238 tank(50,000 gallon
ca aci )
No. 2 fuel oil storage
ITK9239 tank(50,000 gallon
capacity)
No.2 fuel oil storage
ITKFP tank(270 gallon
capacity)
Wastewater treatment
IW WTP—AT2 plant aeration tank No.2
(63,500 gallon capacity)
Wastewater treatment
IWWTP-AT3 plant aeration tank No. 3
(63,500 gallon capacity)
Wastewater treatment
IWWTP—CLR plant clarifier(1,310
gallon capacity)
8
Wastewater treatment
IWWTP-ET1 plant equalization tank
No. 1 (65,500 gallon
capacity)
Wastewater treatment
IWWTP-ET2 plant equalization tank
No.2(65,500 gallon
capacity)
one(1)jet ejector
venturi-type wet scrubber
M-10 One batch reactor CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34) Sclareolide
O s.
one(1)jet ejector
venturi-type wet scrubber
M-10A One batch reactor CS-1 (10 GPM injection rate, CD-M-34
[MACT FFFF] ID No.M-34)Sclareolide
s.
one(1)jet ejector
One acetic acid storage venturi-type wet scrubber
M-20 tank(10,135 gallon CS-1 (10 GPM injection rate, CD-M-34
capacity)[MACT FFFF] ID No.M-34) Sclareolide
O s.
One plant material one(1)fabric filter(244
grinder(1,011 pounds CS-4 square feet of filter CD-1003-4-1
MHL- 1002 per hour nominal feed surface area,ID No.
rate) CD-1003-4-1)
one condenser(ID No.
R-3001 One reactor[MACT CS-11 CD-3001)installed on CD-EX-3001
FFFF] centrifuge,reactor and
heat exchanger/dryer
one reactor[MACT
R-3002 FFFF]
one condenser(ID No.
One hexane storage tank CD-3001)installed on
T-3001 (6,700 gallon capacity) CS-11 CD-EX-3001
[MACT FFFF] centrifuge,reactor and
heat exchanger/dryer
Four process tanks one condenser(ID No.
T-3002 through CD-3001)installed on CD-EX-3001
T-300 [MACT FFFF] (2,500 CS-11 centrifuge,reactor and
gallons capacity each) heat exchanger/dryer
T-3003 one process tank[MACT
FFFF]
T-3004 one process tank[MACT
FFFF]
T-3005 one process tank[MACT
FFFF]
Wastewater treatment
W WTP-AT I plant aeration tank No. 1
[PSD,MACT FFFF]
9
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
Emission Source & Operating Scenario List - See Instructions
DES Group ID RES ID S!28
ID *OS Description
GRl ES-1004-1,ES-1004-2-F, Extraction of Fermented Biomass
ES-1004-2-P,ES-1004-2-WW
Biomass Boiler Operation with
GR2 ES-BB1,ES-BB2,ES-RD 33 Wood Chips as fuel source
G-76 H-101,H-102,H-103 1 Boilers
G-77 E101,E102,E103 2 Generators
ES-1001-1-2-P,ES-1001-1-2-WW,
ES-1001-2-1-F,ES-1001-2-1-P1,
ES-1001-2-1-P2,ES-1001-2-1-WW, Rotocel, Sage,Recovery,and
G-94 HB-1,HB-2,HB-3,HB-4, 35 Distillation
ES-1001-1-1-F,ES-1001-1-1-P1,
ES-1001-1-1-P2,ES-1001-1-1-P3,
ES-1001-1-1-WW,ES-1001-1-2-F
ES-1001-1-3-F,ES-1001-1-3-P,
ES-1001-1-3-WW,ES-1001-1-4-F,
ES-1001-1-4-P,ES-1001-1-4-WW, 36 Conversions(Sclareolide SDE:
G-95 ES-1003-2-2-F,ES-1003-2-2-WW, Biological and Chemical)
G-17,M-10,M-10A,M-20,A-2,
D-1202,D-1231A,D-1231B
ES-1003-10-F,ES-1003-10-WW,
G-96 R-3001,T-3001,T-3002 through 39 Sclazeol Re-crystallization(SFG)
T-300,C-3001,D-3001
ES-1003-2-1-F,ES-1003-2-1-P, 37 Plant Nutrient Extraction(PNE
G-97 ES-1003-2-1-WW,C-31203,D31211, 38 PNE-Isohexane Extraction
D31214
G-99 D-1201,D-1215,D-1218,D-2202 9 EVG(batch flavorant)
Botanical extraction process
G-150 ES-1001-11-F,ES-1001-11-P, 40 (includes botanical vents,
ES-1001-11-WW condensers,tanks,etc)
ES-1003-10-P.13A NONE NONE
ES-1004-2Silo 30 Silo load out of spent biomass
ES-MDSU-1024 NONE NONE
ES-PkGenl 12 Peak Shaving Generator.
FP NONE NONE
IECS 31 EDA Process
IES-PV NONE INONE
10
ITK102 NONE NONE
ITK103 NONE NONE
ITK9238 NONE NONE
ITK9239 NONE NONE
IMP NONE NONE
IWWTP—AT2 NONE NONE
IWWTP—AT3 NONE NONE
IWWTP—CLR NONE NONE
IWWTP—ETl NONE NONE
IWWTP—ET2 NONE NONE
MHZ-1002 34 Misc: Plant MMIGrinder
R-3002 NONE NONE
T-3003 NONE NONE
T-3004 NONE NONE
T-3005 NONE NONE
Waste Water Treatment 1st
32 Aeration Chamber(Includes
WWTP—AT1 methanol usages from PNE and
EVG)
11
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group GRl consisting of ES—1004-1,ES-1004-2—F,ES-1004-2—P,
Emission Source Group ID ES-1004-2—WW
2. Emission Source Description: Biomass Extraction Operation
3. Operating Scenario ID/Description: OS—28/Extraction of Fermented Biomass
4. SCC Number/Description: 39999994/Miscellaneous Industrial Processes ;Other Not Classified
5. Throughput/units in 2013: 563752 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /a Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(°/n of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-21 CD-1004-2EX1002 One chilled water condenser
2 CS-21 CD-1004-2EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
averse outlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ent lines
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-4 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
12
Operating Scenario: OS—28 Emission Source/Group ID: GR1
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours Day Days per Week ( 7 ) Weeks per Year ( 52 )
P Y ( 24 )
I I.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
an—Feb +Dec 0"o arch—May 30% une—Aug. 41"Vo Sept.—Nov. 29%
013 013 �013 2013
13. Aetna l Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation in
used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
E
CO 08 0
NOx 08 0
TSP 08 0
PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 26.16 08 98
Emissions Emission Control
HAP/TAP Pollutants (►n CAS HAP/TAPS Estimation Efficiency Emission EF Control
(see instructions) pounds/Year Method Code (Net after all Factor
Alphabetical Order) ( ) See Instructions controls)
2013
Ethyl acetate 141-78-6 439.12 08 98
Hexane (isomers, HEXANEISO 41277.47 08 98
except n—hexane
Hexane n— 110-54-3 71.53 08 98
13
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility H) : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source H)(from permit)or Group GR2 consisting of ES—BB1,ES—BB2,ES—RD
Emission Source Group ID
2. Emission Source Description: Biomass Boilers
3. Operating Scenario ED/Description: OS—33Biomass Boiler Operation with Wood Chips as fuel source
4. SCC Number/Description: 10200904Bark;Bark—fired Boiler(<50,000 Lb Steam)
5. Throughputtunits in 2013: 21779 TON/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) FSulfur 1 0 /o Ash 1 0 Heat Content 8000000 Btu/ton
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-24 CD—BB1C one simple cyclone 144 inches in diameter
2 CS-24 CD—BB 1BH one ba filter(8,900 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines :
ERP ID ERP Type Height Nameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/see) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
Biomass Boilers
EP—BB 1 VERTICAL STACK 60 3 240.8 24 10178.76 Exhaust
14
Operating Scenario: OS— 33 Emission Source/Group ID: GR2
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 250�o arch—May 24"�o une—Aug. 24"�u Sept.—Nov. 27%
013 013 013 2013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants CAS Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Carbon Dioxide CO2 124389 16987.6 08 0
Methane CH4 74-82-8 1.83 08 0
Nitrous Oxide 20 10024972 1.13 08 0
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 16.73 08 99
NOx NOx 19.17 08 99
TSP TSP 0.12 08 99
PM10 PM10 0.12 08 99
PM2.5 PM2.5 0.12 08 99
S02 S02 2.18 08 99
VOC VOC 1.48 08 99
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldeh de 75-07-0 144.6 08 99
Acrolein 107-02-8 696.9 08 99
Benzene 71-43-2 731.8 08 99
Benzo(a)pyrene(Component of 50-32-8 0.453 08 99
POMTV POM7
Carbon tetrachloride 56-23-5 7.84 08 99
Chlorine 7782-50-5 137.6 08 99
Chlorobenzene 108-90-7 5.75 08 99
Chloroform 67-66-3 4.88 08 99
Eth lbenzene 100-41-4 5.4 08 99
Formaldehyde 50-00-0 766.6 08 99
15
Hexane(isomers,except HEXANEISO 4089.7 08 0
n—hexane
Hexane n— 110-54-3 5.64 08 0
Hydrogen chloride 7647-01-0 15.68 08 99
(hydrochloric acid
Mercury Unlisted Compounds HGC—Other 0.051 08 99
(Specify Component of HGC
Naphthalene (Component of 91-20-3 16.9 08 99
POMTV
Phenol 108-95-2 8.87 08 99
Pro ionaldeh de 123-38-6 10.63 08 99
S rene 100-42-5 331.04 08 99
Toluene 108-88-3 160.29 08 99
X lene 1330-20-7 4.36 08 99
16
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-76 consisting of H-101,H-102,H-103
Emission Source Group ID
2. Emission Source Description: Boilers
3. Operating Scenario ID/Description: OS— 1/Boilers
4. SCC Numb er/Description: 2020040 1/Diesel;Diesel
5. Throughputtunits in 2013: 442180.4 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur 0.0014 /o Ash 0 Heat Content 141000 Btu/gallon
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ent lines
qIDERP Type Height iameter Temperature Velocity Volume Flow EPP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
boiler:vertical with
ICAL STACK 45 2.2 425 34.5 7868.74 min ca
boiler:vertical with
EP—B-3 VERTICAL STACK 45 2.5 500 34.6 10190.54 rain ca
EP—B-2 VERTICAL STACK 45 2.2 425 34.5 7868.74 boiler:Horizontal
17
Operating Scenario: OS- 1 Emission Source/Group ID: G-76
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Through ut:
�an-Feb +Dec 18% arch-May 5% une-Aug. 35% OP3-Nov. 42%
013 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions- Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants CAS Pollutants Method Code (Net after Factor
actor
See Instructions all controls
2013
Carbon Dioxide CO2 124389 5018.7476 08 22.7
Methane CH4 74-82-8 0.0133 08 0.00006
Nitrous Oxide 20 10024972 0.0265 08 0.00012
Emissions- Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 1.11 08 0.005
NOx NOx 5.31 08 0.024
TSP TSP 0.73 08 0.0033
PM10 PM10 0.22 08 0.001
PM2.5 PM2.5 0.06 08 0.00025
S02 S02 9.42 08 0.0426
VOC VOC 0.04 08 0.0002
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical HAP/TAPS
(see instructions) Method Code (Net after all Factor
Order) (Pounds/Year) controls)
See Instructions
2013
Arsenic Unlisted
Compounds(Specify ASC-Other 0.26186 08 5.922E-7
Component of ASC
Benzene 71-43-2 1.216 08 0.00000275
Beryllium Compound,
Unlisted (Specify BEC-Other 0.18572 08 4.2E-7
Com onent of BEC
Cadmium Unlisted
Compounds (Specify CDC-Other 0.18572 08 4.2E-7
Component of CDC
Chromium (VI) NSCR6-Other 0.18572 08 4.2E-7
Non-Specific,Unlisted
18
R
at
f CRC—Other 0.01282 08 2.9E-8
Eth 1 benzene 100-41-4 0.36126 08 8.17E-7
Fluorides(sum
of all 16984-48-8 16.49333 08 0.0000373
fluoride compounds)
Formaldehyde 7PBC—Other
0 21.22466 08 0.000048
Lead Unlisted Compounds 0.00000126
(Specify and Component of 0.55715 08
PBC
Manganese Unlisted
Compounds(Specify MNC—Other 0.37143 08 :8.4E-7
Component of MNC
Mercury Unlisted
Compounds(Specify HGC—Other 0.18704 08 4.23E-7
Component of HGC
Naphthalene(Component of 91-20-3 0.14725 08 3.33E-7
POMTV
Nickel Unlisted Compounds NIC—Other 0.18572 08 4.2E-7
(Specify Component of NIC
Toluene 108-88-3 35.24178 08 0.0000797
X lene o— 95-47-6 0.61905 08 0.0000014
19
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or Group G-77 consisting of E101,E102, E103
Emission Source Group ID
2. Emission Source Description: Generators
3. Operating Scenario ID/Description: OS —2/Generators
4. SCC Number/Description: 20100102/Distillate Oil(Diesel) ; Reciprocating
5. Throughputlunits in 2013: 4002.3 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /a Sulfur 0.0014 /o Ash 0 Heat Co77E:00 Btu/gallon(Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9.Emissio:Release Point ERP Information: Sources vented to more than one ERP use additional entr linesERP IDERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP101 VERTICAL STACK 12 0.67 1063 160.9 3403.66 Vertical
EP102 VERTICAL STACK 11 0.67 885 203.4 4302.7 Vertical
EP103 VERTICAL STACK 10 0.67 1063 174.4 3689.24 Vertical
20
Operating Scenario: OS —2 Emission Source/Group ID: G-77
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 60 I arch—May 14% une—Aug. 13% Sept.—Nov. 13%
013 013 013 013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Carbon Dioxide CO2 124389 12.41 09
Methane CH4 74-82-8 0.0025 09
Nitrous Oxide 20 10024972 0.0003 09
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
=PM2.5PM2.05
0.24 09
0.09 09
0.03 09
0.03 09
0.03 09
S02 S02 0.04 09
VOC VOC 0.1 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (in Alphabetical Order) (see instructions) (pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldehyde 75-07-0 0.014 09
Acrolein 107-02-8 0.004 09
Arsenic Unlisted Compounds ( ASC—Other 0.002 09
Fecif Com onent of ASCBenzene 71-43-2 0.438 09
o(a)pyrene(Component of 50-32-8 0.0001 09
POMTV POM7llium Compound,Unlisted BEC—Other 0.002 09
(Specify Component of BEC
Cadmium Unlisted Compounds CDC—Other 0.002 09
(Specify Component of CDC
21
Formaldehyde 50-00-0 0.045 09
Naphthalene (Component of 91-20-3 0.073 09
POMTV
Toluene 108-88-3 0.159 09
X lene 1330-20-7 0.109 09
22
COPY of RECORD Date Submitted: 419/201 4 1 0:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-94 consisting of ES-1001-1-2—P,ES-1001-1-2—WW,
Emission Source Group ID ES-1001-2-1—F,ES-1001-2-1—P1,ES-1001-2-1—P2,ES-1001-2-1—WW,
HB-1,HB-2,HB-3,HB-4,ES-1001-1-1—F,ES-1001-1-1—P1,
ES-1001-1-1—P2,ES-1001-1-1—P3,ES-1001-1-1—WW,ES-1001-1-2—F
2. Emission Source Description: Rotocel,Sage,Recovery,and Distillation/Concrete Operations
3. Operating Scenario ID/Description: OS—35/Rotocel, Sage,Recovery,and Distillation
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 94644819 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-17 CD-31209 One chilled water condenser
2 CS-17 CD-1001-2—S-1 One packed tower scrubber(8 gallons per minute minimum mineral oil
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1001-11-1 VERTICAL STACK 42 0.5 68 127.4 1500.89 Vertical
23
Operating Scenario: OS—35 Emission Source/Group ID: G-94
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
FSeNov. 39/o
an—Feb +Dec 20% 1% �013—Aug 40% 0
013 �arch—May
13
13. Actual Emissions per Pollutant Usted
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG GHG Estimation Efficiency Emission Ef Control
Pollutants
CAS Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 826.56 03 98
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In HAP/TAPS
(see instructions) pounds/Year) Method Code (Net after all Factor
Alphabetical Order) ( See Instructions controls)
2013
Hexane(isomers, HEXANEISO 1352806.09 03
exce tn—hexane
Hexane n— 110-54-3 2041.36 03
Methanol 67-56-1 300938.8 03
24
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-95 consisting of ES—100 1—1-3—F,ES—1001-1-3—P,
Emission Source Group ID ES-1001-1-3—WW,ES-1001-1-4—F,ES-1001-1-4—P,
ES-1001-1-4—WW,ES-1003-2-2—F,ES-1003-2-2—WW,G-17,M-10,
M-10A,M-20,A-2,D-1202,D-1231A,D-1231B
2. Emission Source Description: Conversions(Sclareolide: Biological and Chemical)
3. Operating Scenario ID/Description: OS—36/Conversions(Sclareolide SDE: Biological and Chemical)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 474005.4 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(°/u of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed in ennit
1 CS-1 CD—M-34 One venturi—type wet scrubber(10 gallons per minute minimum liquid
injection rate
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional ntry fines):
ERP ID ERP Type Height Nameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feetlsec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-1 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
25
Operating Scenario: OS— 36 Emission Source/Group ID: G-95
10.operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 23a/o arch—May 19% 111 Aug. 31o/a 3ept.-1 27'
013 013 �013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 59.14 03 98
Emissions Emission Control
HAP/TAP Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control
Alphabetical Order
(see instructions) (Pounds/Year) Method Code (Net after all Factor
P ) See Instructions) controls)
2013
Hexane (isomers, HEXANEISO 71313.31 03 98
except n—hexane
Hexane n— 110-54-3 46968.59 03 98
26
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County :Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-96 consisting of ES-1003-10—F,ES-1003-10—WW,R-3001,
Emission Source Group ID T-3001,T-3002 through T-300,C-3001,D-3001
2. Emission Source Description: Re—crystallization of Sclareol(SFG)
3. Operating Scenario ID/Description: OS—39/Sclareol Re—crystallization(SFG)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013: 611422 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur I Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD II) Control Device Description
as listed inpermit)
1 CS-11 CD—EX-3001 One chilled water condenser
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines):
ERP ID ERP Type Height iameter Temperature Velocity Volume ERP
(in feet) Circle(enter (F) (Feettsec) Flow Rate Description
): (Acfm)
ectangle(L x
in 0.1 feet)
P-1003-10-1 DOWNWARD—FACING VENT 19 0.17 80 3 4. Horizontal
P-1003-10-3 HORIZONTAL STACK 19 0.17
80J"'p-
0.1 0.1133 Horizontal
1003-10-4 HORIZONTAL STACK 19 0.17 80 0.1 0.13 Horizontal
P-1003-10-5 HORIZONTAL STACK 25 0.17 80 10.2 13.89 Horizontal
P-1003-10-61 HORIZONTAL STACK 30 0.17 100 0.1 0.13 Horizontal
27
P-1003-10-7 VERTICAL STACK 19 0.17 80 53 72.17 Vertical
IEP-1003-10-21 HORIZONTAL STACK 1 18 0.17 80 0.1 0.13 IT Horizontal
28
Operating Scenario: OS— 39 Emission Source/Group ID: G-96
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 220�o 140�o une—Aug. 35"�o Sept.—Nov. 29%
013 �arch—May
13 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
Ef Control
(NAAQS)
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 70.92 03 98
Emissions Emission Control
HAP/TAP Pollutants (1❑ CAS HAP/TAPS Estimation Efficiency Emission EF Control
(see instructions) Method Code (Net after all Factor
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 141-78-6 8765 03 0
Hexane(isomers, HEXANEISO 12078.54 03 98
except n—hexane
Hexane n— 110-54-3 120992.31 03 98
29
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit)or Group G-97 consisting of ES-1003-2-1—F,ES-1003-2-1—P,
Emission Source Group ID ES-1003-2-1—WW,C-31203, D31211,D31214
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ID/Description: OS —37/Plant Nutrient Extraction(PNE)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in
Comments Field
5. Throughput/units in 2013: 7343.04 LB/yr
(e.g. production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Control Device Description
Order CS—ID CD ID
as listed inpermit)
9. Emission Release PointZnlormatjon: Sources vented to more than one ERP use additional ent lines
ERP ID ERPTmeter Temperature Velocity Volume FlowERP Description
cle(enter#): (F) (Feet/sec) Rate(Acfm)
tangle(L x W)
.1 feet)
P-1003-2-1 VERTICA1 75 53 2497.56 Veritical
30
Operating Scenario: OS —37 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu hut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25"vo S 013
ept.—Nov. 25%
013 013 �013
t13. Actual Emissions Aer Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 0.57 03
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (In HAP/TAPS
(see instructions) Method Code (Net after all Factor
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 141-78-6 47.29 03
Methanol 67-56-1 4.44 08
31
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-97 consisting of ES-1003-2-1—F,ES-1003-2-1—P,
Emission Source Group ID ES-1003-2-1—WW,C-31203,D31211,D31214
2. Emission Source Description: Plant Nutrient Extraction(PNE)
3. Operating Scenario ED/Description: OS—38/PNE—Isohexane Extraction
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013:
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) Sulfur /o Ash Heat Content
ro
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS-11) CD ID Control Device Description
as listed inpermit)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try tines):
ERP ID ERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) hate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Vcritical
32
Operating Scenario: OS — 38 Emission Source/Group ID: G-97
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
�an—Feb +Dec 25a�o arch—May 250�o une—Aug. 25"�u Sept.—Nov. 25%
013 013 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emissions Emission Control
HAP/TAP CAS Estimation Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code Alphabetical Order) (Pounds/Year) Net after all controls)
)
See Instructions
2013
33
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region: WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-99 consisting of D-1201,D-1215,D-1218,D-2202
Emission Source Group ID
2. Emission Source Description: EVG(batch flavorant)
3. Operating Scenario ID/Description: OS—9/EVG (batch flavorant)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed ; Specify in
Comments Field
5. Throughputtunits in 2013: 11220 LB/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o$u]fur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-7 CD—Z-9215 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
2 CS-7 CD—Z-9216 One water spray fume scrubber(0.5 gallons per minute minimum water
injection rate
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e trV lines):
ERP ID ERP Type Height *a meter
Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#). (F) (Feet/sec) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
34
Operating Scenario: OS — 9 Emission Source/Group ID: G-99
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec T7120�oT�orch—May 380�o une—Aug. 230�o Sept.—Nov. 27%
013 3 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08 0
NOx NOx 08 0
TSP TSP 08 0
PM10 PM10 08 0
PM2.5 PM2.5 08 0
S02 S02 08 0
VOC VOC 10.51 03 98
HAP/TAP CAS Emissions Emission Estimation Control Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
Chloroform 67-66-3 17018 03 0
Methanol 67-56-1 4011.06 03
35
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or Group G-150 consisting of ES—1001-11—F,ES—1001-11—P,
Emission Source Group ID ES-1001-11—WW
2. Emission Source Description: Botanical Extraction Operations
3. Operating Scenario ID/Description: OS—40/Botanical extraction process(includes botanical vents,condensers,
tanks,etc)
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughputtunits in 2013: 193325 LB/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) Sulfur TOAsh Heat Content/a
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information:
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-16 CD-100111EX1002 One chilled water condenser
2 CS-16 CD-100111EX1003 One cryogenic(nitrogen)condenser system(-40°F maximum 24—hour
average outlet temperature)
9.Emission Release Point ERP i Information: Sources vented to more than one ERP use additional ntry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-11 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
36
Operating Scenario: OS—40 Emission Source/Group ID: G-150
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu7400%
t:
an—Feb +Dec arch—May une—Aug. 3% Sept.—Nov. 60�u51% 013 013 013
013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission C:er
l
GHG CAS GHG Estimation Efcy Emission Ef Control
Pollutants Pollutants Method Code ( Factor
Tons/Year See Instructions allls
2013
Emissions— Emission Control
Criteria Emission
Pollutant Criteria Estimation Efficiency Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
XPM2.15;
CO 08 0
NOx 08 0
TSP 08 0
PM10 08 0
PM2.5 08 0
S02 S02 08 0
VOC VOC 52.91 03 98
Emissions Emission Control
HAP/TAP CAS Estimation Efficiency Emission EF Control
Pollutants (in HAP/TAPS Net after all Factor
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions controls)
2013
Ethyl acetate 1
141-78-6 375.29 03 0
37
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Berrie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or ES-1004-2Silo
Emission Source Group ID
2. Emission Source Description: Biomass silo loadout
3. Operating Scenario ED/Description: OS—30/Silo load out of spent biomass
4. SCC Number/Description: 39999994/Miscellaneous Industrial Processes ;Other Not Classified
5. Throughputtunits in 2013:
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur fo Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information
Order CS—ID CD ID Control Device Description
as listed in ermit
1 CS-23 CD-1004-2—FF2 One ba tlter 254 square feet of filter area
9.Emission Release Point RP Information: Sources vented to more than one ERP use additional en lines):
ERP ID ERP Type Height iameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/sec) Rate(Acfm)
ectangle(L x
in 0.1 feet)
Dust Collector on
P-1004-2—FF2 HORIZONTAL STACK 10 8.5 72 0.64 2180 Silo
38
Operating Scenario: OS—30 Emission Source/Group ID:
ES-1004-2Silo
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 25% arch—May 25% �une—Aug. 25% ept.—Nov. 25%
013 013 013 013
13. Actual Emissions ger Pollutant Usted
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission Ef Control
�QS) Code Pollutants Method Code (Net after Factor
Pollutants (TonsNear) (See Instructions) all controls)
2013
CO CO 08
NOa NOs 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
HAP/TAP Emissions Emission Control Emission
CAS HAPPPAPS Estimation Efficiency EF Control
Alphabetical Order)Pollutants (see instructions) after all
ctions) Method Code y Factor
der) (Pounds/Year) controls)
See Instructions
2013
39
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bettie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or ES—PkGen1
Emission Source Group ID
2. Emission Source Description: One No. 2 fuel oil—fired limited use emergency generator(2,935 kilowatt
maximum rated power output) [MACT ZZZZ]
3. Operating Scenario ID/Description: OS — 12/Peak Shaving Generator
4. SCC Number/Description: 20300102/Distillate Oil(Diesel) ; Turbine
5. Throughput/units in 2013: 9558 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (if fuel is used) %Sulfur 0.0014 /°Ash 0 Heat Content 141000 Btu/gallon
(Btu/units)
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
S. Control Device Information
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-22 CD—CatOxl One catalv tic oxidizer 695 °F minimum inlet temperature)
9.Emission Release Point ERP Information: Sources vented to more than one ERP use additional en'
lines
ERP ID ERP Type eight iameter Temperature Velocity Volume Flow ERP
H Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
ectangle(L x W)
in 0.1 feet)
EP-1-9 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
40
Operating Scenario:OS— 12 Emission Source/Group ID: ES—PkGenl
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 290�o 110�0 une—Aug. 480�o �013
ept.—Nov. 12'%
013 �arch—May
13 �013
13. Actual Emissions pgr Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
(Tons/Year) See Instructions all controls
2013
Carbon Dioxide CO2 124389 29.64 09 0
Methane CH4 74-82-8 0.006 09 0
Nitrous Oxide 20 10024972 0.005 09 0
Criteria Emissions
Emission Control
(NAAQS) Pollutant Criteria Estimation Efficiency Emission Ef Control
Pollutants Code Pollutants Method Code (Net after Factor
(Tons/Year) (See Instructions) all controls)
2013
CO CO 0.57 09 95 AFTER
NOx NOx 2.16 09 98 AFTER
TSP TSP 0.07 09 98 AFTER
PM10 PM10 0.07 09 98 AFTER
PM2.5 PM2.5 0.07 09 0
S02 S02 0.1 09
VOC VOC 0.24 09
Emissions Emission Control
HAP/TAP CAS HAP/TAPS Estimation Efficiency Emission EF Control
Pollutants (In Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor
See Instructions controls)
2013
Acetaldehyde 75-07-0 0.03 09
Acrolein 107-02-8 0.01 09
Arsenic Unlisted Compounds( ASC—Other 0.005 09
Specify Component of ASC
Benzene 71-43-2 1.05 09
Benzo(a)pyrene(Component of 50-32-8 0.0004 09
POMTV POM7
Beryllium Compound,Unlisted BEC—Other 0.004 09
(Specify Component of BEC
Cadmium Unlisted Compounds CDC—Other 0.004 09
(Specify Component of CDC
41
1
Formaldehyde 50-00-0 0.106 09
Naphthalene(Component of 91-20-3 0.175 09
POMTV
Toluene 108-88-3 0.379 09
X lene 1330-20-7 0.26 09
42
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or IECS
Emission Source Group ID
2. Emission Source Description: ECS process: batch preparation of ethylenediamine/copper sulfate solution
3. Operating Scenario ID/Description: OS —31/EDA Process
4. SCC Number/Description: 30199998/*Other Organic Chemica Manufacture Not Listed; Specify in
Comments Field
5. Throughput/units in 2013:
(e.g. production or fuel use):
6. Fuel Information (if fuel is used) ro
Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional e try lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
P-1003-2-1 VERTICAL STACK 20 1 75 53 2497.56 Veritical
43
Operating Scenario: OS— 31 Emission Source/Group ID: IECS
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throughput:
an—Feb +Dec 250�o Var
ch—May 25"�u une—Aug. 25"�o Sept.—Nov. 25%
�013 13 013 013
13. Actual Emissions per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Criteria Emissions— Emission Control
Pollutant Criteria Estimation Efficiency Emission Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP CAS Emissions Estimation Control Emission
Pollutants On Efficiency Factor EF Control
(see instructions) HAP/TAPS Method Code Ef
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
44
I
COPY of RECORD Date Submitted: 419/201410:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID (from permit) or MHZ-1002
Emission Source Group ID
2. Emission Source Description: Misc: Grinder,air stripper, lime silo, and Aphios
3. Operating Scenario ID/Description: OS —34/Misc: Plant Material Grinder
4. SCC Number/Description: 31299999/Miscellaneous Machinery ; Other Not Classified
5. Throughput/units in 2013:
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) /o Sulfur /o Ash Heat Content
Btu/units
7. Capture Efficiency
(%of Emissions from this Process Vented to Control 100
Device or Stack):
8. Control Device Information :
Order CS—ID CD ID Control Device Description
as listed inpermit)
1 CS-4 CD-1003-4-1 One ba filter 244 square feet of filter area
9.Emission Release Point ERP Information: Sources vented to more than on ry lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm)
Rectangle(L x
in 0.1 feet)
P-1003-4-1 HORIZONTAL STACK 20 1.3 75 37.7 3002.4 Horizontal
45
Operating Scenario: OS — 34 Emission Source/Group ID: MHZ-1002
10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu h ut:
an—Feb +Dec 25% arch—May 25% une—Aug. 25% Sept.—Nov. 25%
013 013 �013 2013
13. Actual Emissions per Pollutant Listed :
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
GHG CAS GHG Estimation Efficiency Emission Ef Control
Pollutants Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions— Emission Control
Criteria Pollutant Criteria Estimation Efficiency Emission
(NAAQS) Ef Control
Code Pollutants Method Code (Net after Factor
Pollutants (Tons/Year) (See Instructions) all controls)
2013
CO CO 08
NOx NOx 08
TSP TSP 08
PM10 PM10 08
PM2.5 PM2.5 08
S02 S02 08
VOC VOC 08
Emission
HAP/TAP CAS Emissions Estimation Control Emission
Pollutants (in HAP/TAPS Efficiency Factor EF Control
(see instructions) Method Code
Alphabetical Order) (Pounds/Year) See Instructions (Net after all controls)
2013
46
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
1. Emission Source ID(from permit)or WWTP—AT1
Emission Source Group ID
2. Emission Source Description: Wastewater treatment plant aeration tank No. 1 [PSD,MACT FFFF]
3. Operating Scenario ED/Description: OS—32/Waste Water Treatment 1st Aeration Chamber(Includes methanol
usages from PNE and EVG)
4. SCC Number/Description: 30182006/Wastewater Treatment;Chemical Plant Wastewater System:
Aerated Impoundment
5. Throughput/units in 2013: 9561581 GAL/yr
(e.g.production or fuel use):
6. Fuel Information (If fuel is used) ro
Sulfur Ash FHeat Content
Btu/units
7. Capture Efficiency
(0/9 of Emissions from this Process Vented to Control
Device or Stack):
8. Control Device Information :None
Order CS—ID CD ID Control Device Description
as listed inpermit)
9. Emission Release Point ERP Information: Sources vented to more than one ERP use additional en lines):
ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description
(in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm)
Rectangle(L x W)
in 0.1 feet)
EP-1-14 VERTICAL STACK 20 0.17 80 0.1 0.13 Horizontal
47
1
Operating Scenario: OS— 32 Emission Source/Group ID: WWTP—ATI
10.Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2013)
Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 )
11.Typical Start& End Times For Operating Scenario: Start: 0 End: 2359
12. Seasonal Periods Percent Annual Throu Orb ut:
�an—Feb +Dec 20% arch—May 1% une—Aug. 40% Sept.—Nov. 39%
013 013 013 013
13. Actual Emission per Pollutant Listed
Attach calculations and documentation of emission factors or other estimation methods used.
Emissions— Emission Control
CASGHG Estimation Efficiency Emission Ef Control
:G:HG
nts Pollutants Method Code (Net after Factor
Tons/Year See Instructions all controls
2013
Emissions
Emission Control
Criteria Emission
Pollutant Criteria Estimation Efficiency Ef Control
(NAAQS) Code Pollutants Method Code (Net after Factor
Pollutants W
Tons/Year) (See Instructions) all controls)
2013
CO 08
Ox 08
SP 08
M10 08
M2.5 08
02 08
OC 2.92 03
Emission
HAS Emissions Estimation Control EmissionPoHAP/TAPS Efficiency EF Control
nstructions) Method Code Factor
Alphabetical Order) (Pounds/Year) (Net after all controls)
P See Instructions
2013
Methanol 67-56-1 5835.6 03
48
Facility Total CY 2013 Emissions Summary
COPY of RECORD Date Submitted: 4/9/201410:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County: Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2013
Record Facility—Wide Totals From all Permitted and Non—Permitted Air Pollutant Emission Sources
Green House Gases Pollutants(GHG)
Actual Emissions Tons/Year
Pollutant CAS 2013 2012 %Change
Carbon Dioxide CO2 124389 22048.398 33942.1755 —35.041294%
Methane CH4 74-82-8 1.8518 9.4356 —80.37433%
Nitrous Oxide 20 10024972 1.1618 1.2643 —8.10725%
Criteria Pollutants
Actual Emissions Tons/Year
Pollutant CAS 2013 2012 % Change
CO CO 18.65 43.64 —57.263977%
NOx NOx 26.73 24.08 11.004982%
PM SP TSP 0.95 1.073 —11.463184%
PM10 PM10 0.44 .443 —0.67719895%
PM2.5 PM2.5 0.28 .233 20.171677%
S02 S02 11.74 13.64 —13.929623%
VOC VOC 1051.55 931.29 12.913279%
Hazardous Air Pollutants S and/or Toxic Air Pollutants APs
Actual Emissions(Pounds/Year)
Pollutant CAS 1 2013 1 2012 % Change
Pollutant Grou :Arsenic Com ounds total mass of elemental AS arsine and all inorganic compounds) Group Sum:.26886
Arsenic Unlisted Compounds( ASC—Other 0.26886 .33464 —19.656939%
Svecify Component of ASC
Pollutant Groupffleryllium compounds(Total mass Group Sum:.19172
Beryllium Compound,Unlisted BEC—Other 0.19172 .38684 —50.439457%
(Specify Component of BEC
Pollutant Grou :Cadmium com ounds total mass inc elemental metal GroupSum:.19172
Cadmium Unlisted Compounds CDC—Other 0.19172 .80684 —76.23817%
(Specify Component of CDC
Pollutant Grou :Chromium on—Specific Com ounds as Chrom Com onent CRC Group Sum:.18572
Chromium(VI)Non—Specific, NSCR6—Other 0.18572 .23282 —20.230225%
Unlisted(Specify Component of
49
NSCR6 CRC
Pollutant Grou :Chromium-A1VTota1 Inc Chromium I categories,metal and Others Group Sum:.19854
Chromium(VI)Non-Specific,
Unlisted(Specify Component of NSCR6-Other 0.18572 .23282 -20.230225%
NSCR6 CRC
Chromium Unlisted Compounds CRC-Other 0.01282 2.43608 -99.47375%
(Specify Component of CRC
Pollutant Grou :Lead and Lead compounds Group Sum:.55715
Lead Unlisted Compounds PBC-Other 0.55715 7.37153 -92.441864%
(Specify and Component of PBC
Pollutant Grou :Man anese com ounds Group Sum:.37143
Manganese Unlisted Compounds MNC-Other 0.37143 222.46468T -
Pollutant99.83304%
(Specify Component of MNC
Group:Mercury Compounds-all total mass in Hiz Vapor Group Sum:.23804
Mercury Unlisted Compounds IHGC-Other 0.23804 .27051 -12.003249%
(Specify Component of HGC
Pollutant Grou :Nickel Com ounds sum total mass inc elemental Group Sum:.18572
Nickel Unlisted Compounds NIC-Other 0.18572 4.81682 -96.14435%
(Specify Component of NIC
Pollutant Grou :Pol c clic Or anic Matter 7 PAH Compounds for NIF Group Sum:.4535
Benzo(a)pyrene(Component of 50-32-8 0.4535 .36039 25.8359%
POMTV POM7
Pollutant Grou :Pol c clic Or anic Matter(Specific Co m ounds from OA PS for Group Sum:17.74875
Benzo(a)pyrene(Component of 50-32-8 0.4535 .36039 25.8359%
POMTV POM7
Naphthalene(Component of 91-20-3 17.29525 13.83879 24.976606%
POMTV
Acetaldehyde 75-07-0 144.644 115.13857 25.626013%
Acrolein 107-02-8 696.914 555.01168 25.567453%
Benzene 71-43-2 734.504 585.38843 25.472933%
Carbon tetrachloride 56-23-5 7.84 6.24 25.641031%
Chlorine 7782-50-5 137.6 109.61 25.535995%
Chlorobenzene 108-90-7 5.75 4.58 25.545855%
Chloroform 67-66-3 17022.88 4839.89 251.72038%
Ethyl acetate 141-78-6 9626.7 14052.59 -31.495188%
Ethyl benzene 100-41-4 5.76126 4.75289 21.21593%
Fluorides(sum of all fluoride 16984-48-8 16.49333 20.67684 -20.23283%
compounds)
Formaldehyde 50-00-0 787.97565 637.19606 23.662985%
Hexane(isomers,except HEXANEISO 1481565.1 1352727.17 9.524316%
n-hexane
Hexane n- 110-54-3 170079.44 130578.44 30.250784%
Hydrogen chloride(hydrochloric 7647-01-0 15.68 360.7 -95.65289%
acid
Methanol 67-56-1 310789.9 290491.38 6.9876537%
Phenol 108-95-2 8.87 7.08 25.282486%
Pro ionaldeh de 123-38-6 10.63 8.46 25.650118%
Styrene 100-42-5 331.04 263.61 25.579466%
Toluene 108-88-3 196.06978 526.5064 -62.76023%
X lene 1330-20-7 4.729 3.7557 25.915276%
50
X lene o— 95-47-6 0.61905 .77607 —20.232708
0/0
51
COPY of RECORD Date Submitted: 4/9/2014 10:36:48
As entered in AERO
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit : 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region : WARO
Comments From Facility:
52