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HomeMy WebLinkAboutAQ_F_2100051_20060519_EI_Cmb-EI-File Emissions Inventory Review/Data Traddng Form Facility Name: Facility ID: �h.J f` Permit Writer: Inspector: �z� . �� ��,, Confidential? Initial Review/Data Entry ❑ If confidential information received,it has been properly labeled and stored. Sanitized copies have been received for public use. ❑ Two copies of inventory were received and responsible official signed forms. / Inventory Review/Database Entry Forms appear to be complete Calculations and control efficiencies supporting emissions appear correct 2- Calculations appear to add up ok $ All permitted sources and required significant activities are quantified Kl'All compliance issues resulting from review are being addressed. (i.e.toxics,emission limitations / exceeded,unpermitted sources) N/A +❑ All volatile HAPS/TAPS are included in the VOC total All appropriate ID numbers are entered where they should be(Source,Stack) c All changes made in the'review by AQ staff are in bedrrccda ies of the inventory before sending to C merN3:4 entrap ffice. 1 /� ZC� -/. d p4 71 In ,ov- m o! Ic j �5�51 A�?21MIF .� va Signature: Date Billing Contact & General Data updated in FEES database Date Emissions Data loaded into I-BEAM database S/-,/ OG Remember: Confidential copies must be properly handled! (SAAIR\ ADNIIN\2002 Emission Inventories\WARD inventory review form.doc) WnRO Copy Facility Total CY 2005 Emission Summary Recorded in ED Facility ID#: 2100051 Facility Name: Edenton Dyeing and Finishing LLC Permit#(s): 02621 T15 Criteria Pollutants Actual Emissions % Difference (Tons/Year) Pollutant CAS CY 2005 1 CY 2004 from ED from Fees CO co / 17.35 14.66 18.3% NOx NOx ✓34.14 26.78 27.5% PM(TSP) TSP / 26.25 20.89 25.7% PM10 PM10 ,/18.68 20.63 -9.5% PM2.5 PM2.5 /15.22 7.17 112.3% S02 S02 /171.72 132.98 29.1% VOC (Meeting Federal Definition as voc ✓7.31 5.00 46.2% Photochemically reactive) Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2005 CY 2004 from ED from Fees Polycyclic Organic Matter(Specific Compounds from OAQPS for 1,659.98 1,093.92 51.7% T i9 Biphenyl (Component of, 833291POMTV) 92-52-4 1,050.50 692.60 .51.7% Furans - Dibenzofurans (group total- CAA- 132-64-9 205.00 135.00 51.9% unchlorinated) (Component of 833291POMTIg Naphthalene (Component of 833291POAfM 91-20-3 165.48 108.32 52.8% Quinoline (Component of833291POMTk) 91-22-5 239.00 158.00 51.3% Nickel& Compounds, sum total mass, inc elemental 36.22 23.69 52.9% Nickel Unlisted Compounds (Specify& Component NIC-Other 36.22 23.69 52.9% of 3730241NIQ Jlercu)7 & Compounds - ull total mass, inc Hq Vapor 0.050000 0.030000 66.7% Mercury Unlisted Compounds (Specify& HGC-Other 0.050000 0.030000 66.7% Component of HGC) ,llan,une.sc 'S contpuunds 1.29 0.840000 53.6% 05/19/2006 Page 1 of 5 Facility Total CY 2005 Emission Summary Recorded in ED Facility ID#: 2100051 Facility Name: Edenton Dyeina and Finishing LLC Permit#(s): 02621T15. Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2005 CY 2004 from ED from Fees Manganese & compounds 1.29 0.840000 53.6% Manganese Unlisted Compounds (Specify& MNC-Other 1.29 0.840000 53.6% Component of MNC) Lead and Lead compounds 2.88 2.34 23.1% Lead Unlisted Compounds (Specify and Component PBC-Other 2.88 2.34 23.1% of PBC) Glycol ethers (total all individual glycol ethers-See 3,999.00 723.00 453.1% http://d`aq.state.nc.us/toxics/glycoll) Glycol Ethers, Unlisted(Specify& Component of GLYET-Other 3,999.00 723.00 453.1'%, GI.YFT) (See http-Adaq.state.nc.us/toxics/glycol/) Cyanide compounds (see also hydrogen cyanide) Not 0.000000 N/A Reported Cobalt compounds 2.58 1.69 52.7% Cobalt Unlisted Compound(Specify& Component COC-other 2.58 1.69 52.7% off'00 Chromium (VI) Non-Specific Compounds, as Chrom(U) 0.530000 0.430000 23.3% (Component CRC) Chromium (VI) Non-Specific, Unlisted(Specify& NSCR6-Other 0.530000 0.430000 23.3% Component of NSCR6& CRC) Chromium-AIL/Total(Inc Chromium (VI) categories, metal and 0.530000 0.430000 23.3% Others) Chromium (VI)Non-Specific, Unlisted(Specify& NSCR6-Other 0.530000 0.430000 23.3% Component of NSCR6& CRC) Cadmium & compounds (total mass inc elemental metal) 0.270000 0.230000 17.40,o Cadmium Unlisted Compounds (Specify& CDC-Other 0.270000 0.230000 17.4'1/� Component of CDC) BertIlirun 8, compounds (Total mass) Not 0.000000 N/A Reported Arsenic & Compounds (total mass of elemental AS, arsine and all 2.24 2.24 0.0% inorganic compounds) 05/19/2006 Page 2 of 5 Facility Total CY 2005 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing_LLC Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2005 CY 2004 from ED from Fees Arsenic & Compounds (total mass of elemental AS, arsine and all 2.24 2.24 0.0% inorganic compounds) ,4rsenic Unlisted Compounds (Component ofASC- ASC-Other 2.24 2.24 -0.1% SPecify) Antimony & Compounds (total mass, inc elemental SB) 2.25 1.47 53.1 .4ntimony Unlisted Compounds (Component ofSBC SBC-Other 2.25 1.47 53.1% Acetaldehyde 75-07-0 3.03 2.60 16.5% Acetic acid 64-19-7 229.00 229.00 0.0% Acetophenone 98-86-2 0.080000 0.070000 14.3% Acrolein 107-02-8 1.54 1.32 1.6.7% Acrvlamide 79-06-1 99.00 109.00 -9.2% Ammonia (as NH3) 7664-41-7 74.22 133.40 -44.4% Benzene 71-43-2 7.00 6.00 16.7% Benzyl chloride 100-44-7 3.72 3.20 16.3% Bromine 7726-95-6 Not Not N/A Reported Reported Bronwform 75-25-2 0.210000 0.180000 16.7% Carbon disulfide 75-15-0 0.690000 0.590000 16.9% Chloroacetophenone, 2- 532-27-4 0.040000 0.030000 33.3% Chlorobenzene 108-90-7 0.120000 0.100000 20.0% Chloroform 67-66-3 0.310000 0.270000 14.8% Cumene 98-82-8 0.030000 0.020000 50.0% Dimethyl sulfate 77-78-1 0.260000 0.220000 18.2% Dinitrotoluene, 2,4- 121-14-2 0.001490 0.001280 N/A Dioxane, 1,4- 123-91-1 Not Not N/A Reported Reported 05,'19/2006 Page 3 of 5 Facility Total CY 2005 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing, LLLLC_ Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2005 TCY 2004 from EDm Fees Ethyl benzene 100-41-4 0.530000 0.450000 17.8% Ethyl chloride (chloroethane) 75-00-3 0.220000 0.190000 15.8% Ethylene dibromide 106-93-4 0.006380 0.005480 16.4% Ethylene dichloride (1,2-dichloroethane) 107-06-2 0.210000 0.180000 16.7%, Ethylene glycol 107-21-1 638.00 1,242.00 -48.6% Fluorides (sum of all fluoride compounds) 16984-48-8 15.99 10.46 52.9% Formaldehyde 50-00-0 496.48 450.17 10.3% Hexane, n- 1 10-54-3 0.360000 0.310000 16.1% Hydrogen chloride (hydrochloric acid) 7647-01-0 6,381.00 5,479.00 16.5% Hydrogen fluoride (hydrofluoric acid as mass of 7664-39-3 797.00 685.00 16.4% HF- Component of Fluorides) Isophorone 78-59-1 3.08 2.65 16.2% Methyl bromide 74-83-9 0.850000 0.730000 16.4% Methyl chloride 74-87-3 Not Not N/A Reported Reported Methyl ethyl ketone 78-93-3 2.07 1.78 .16.3% Methyl hydrazine 60-34-4 0.900000 0.780000 1.5.4% Methyl methacrylate 80-62-6 0.110000 0.090000 22.2% Methyl tertiary butyl ether(MTBE) 1634-044 0.190000 0.160000 1 S.8%. Methylene chloride 75-09-2 1.54 1.32 16.7%, Phenol 108-95-2 0.090000 0.070000 28.6% Phosphorus Metal, Yellow or White 7723-14-0 4.05 2.65 52.8% Polycyclic Organic Matter(Inc PAH, dioxins, etc. POM 0.020000 0.300000 -93.3% NC & AP 42 historic) Propionaldehyde 123-38-6 2.02 1.74 16.1% Selenium Compounds SEC 0.290000 0.190000 52.6% 05/19/2006 Page 4 of 5 Facility Total CY 2005 Emission Summary Recorded in ED Facility ID M 2100051 Facility Name: Edenton Dyeing and Finishing LLC Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2005 CY 2004 from ED from Fees Styrene 100-42-5 0.130000 0.110000 18.2%, Tetrachloroethane, 1,1,2,2- 79-34-5 Not Not N/A Reported Reported Toluene 108-88-3 3.94 2.84 38.7`%, Trichlorobenzene, 1,2,4- 120-82-1 Not Not N/A Reported Reported Vinyl acetate 108-05-4 0.040000 0.030000 33.3% Xylene 1330-20-7 65.25 94.20 -30.7% DAQ's Comments Regarding Inventory 05/19/2006 Page 5 of 5 Re: Inventory review Subject: Re: Inventory review From: Betsy Huddleston<Betsy.Huddleston@ncmail.net> Date: Fri, 19 May 2006 12:49:04 -0400 To: "Harrell, Rick" <Rick.Harrell@perdue.com> CC: Jim Gardner<JGardner@dye4you.com> I 've finished with the inventory review and approved it, so it's archived for download to EPA later this year. There were few changes I made to the data (as follows) : 1. I applied your stack test emission rate to the coal fired boiler and calculated 16.4 tons. This will save some money on your fees. 2. I applied percentage distribution to the PM10 and PM2.5 emissions on the coal boiler. I used the AP-42 table for overfeed boilers (55% for PM10 and 43% for PM2 .5) . This is a little different from the assumptions made for last year's inventory. 3 . I changed the annual throughput in the preparation operating scenario to reflect the total pounds of product used in that area. That number was 68679. I calculated it using the usage rates and percentages allocated to preparation in your spreadsheet. If you disagree wtih what I 've done or notice an error, please call or email me and it can be changed. 1 of 1 5/19/2006 12:49 PM RE: Inventory reviews at Edenton Subject: RE: Inventory reviews at Edenton From: "Harrell, Rick" <Rick.Harrell@perdue.com> Date: Fri, 19 May 2006 08:37:34 -0400 To: "Betsy Huddleston" <Betsy.Huddleston@ncmail.net> CC: "Jim Gardner" <JGardner@dye4you.com> Hi Betsy, Thank you for pointing this out. Adjustments to the boiler following your inspection have resulted in very positive results. The boiler is probably operating better than tested rate for particulate. Please include the test rate particulate numbers for the boiler and let me know if I need to do anything. Thanks, Rick Harrell Corporate Environmental Manager 124 East Granville Street Windsor North Carolina , 27983 -----Original Message----- From: Betsy Huddleston [mailto:Betsy.Huddleston@ncmail.net] Sent: Thursday, May 18, 2006 4:35 PM To: Harrell, Rick Subject: Inventory reviews at Edenton Hi Rick: Have picked up the 2005 inventory and noticed that you used AP-42 factors for particulate on the coal boiler. Do you not want to use the cestea particulate rate (filterable + condensable) instead? It's a difference of over 2d,otons worth of fees. I guess it depends on how steady state the plant feels the tested rate is. Just let me know if they want to apply the test rate instead and I 'll edit the data (I ' ll also let Jim Gardner know what I changed) . I'll likely prorate the PM-10 and PM-2 .5 emissions if we use the test numbers. Betsy Huddleston DAQ Washington Regional Office (252) 946-6481 fax (252) 975-3716 DISCLAIMER: This communication, including attachments, may contain confidential, privileged, copyrighted or other legally protected information. If you are not the intended recipient, you are hereby notified that any use, disclosure, dissemination, distribution, or copying of this communication, or any of its contents, is strictly prohibited. If you have received this communication in error, please immediately re-send this communication to the sender and delete the original message and any copy of it, including all attachments, from your computer system. 1 of 1 5/19/2006 9:29 AM Inventory Certification Form(Title V) Facility Name: Edenton Dyeing and Finishing,LLC Facility ID : 2100051 125 Dye Plant Road FIMIAY 1 0 2006 Permit: 02621 Edenton,NC 27932 'eo my : Chowan --- D Q Region : WARO North Carolina Department of Environment and Natural-Reiources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2005 These forms must be completed and returned even if the facility did not ollerate or emissions were zero The legally defined "Responsible Official" of record for your facility is Mark Rose This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation: a president,secretary,treasurer, or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars); or ii. the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship; a general partner or the proprietor,respectively; 3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). CERTIFICATION STATEMENT: (Important: Legally Respon�ible Official, read and signafter allsubmissions certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in this air emissions report,including attached calculations and documentation, is true,accurate and complete. (Subject to legal enalities of up to$10,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: S — — z 00 Printed Name: J o..M c Si afore: �---- This form appl' Vffe V facilities. IAis facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: /�? �&ME.0 � D/J!G' Gaiu Information on this Form cannot be held confidential 1 Facility Name: Facility ID: North Carolina Department of Environment and Natural Resources Division of Air Quality General Information If any information already provided to DAQ has changed or otherwise is incorrect or,please provide corrections. You may leave blanks where the information is unchanged(except Facility ID and Name). Physical(911)Address of Facility: Name of Responsible Official: J ��?E s �• �/¢�/VrG� Title: 20�26cr•0,'- Telephone#: e-mail Address: ,�}QpnrEet �01�' a Mailing Address of Responsible Official: % 1usn/, f .Pd . �� ei4E•vr0N . ^�� _0_793Zi Facility Technical/Permit Mailing Contact: Title: Telephone#: _( ) - e-mail Address- Mailing Address of Technical/Permit mailing contact: Inspection Contact: Title: Telephone#: - e-mail Address: Billing/Invoice Contact: Title: Telephone#: e-mail Address: Billing/Invoice Company: Billing/Invoice Address: Standard Industrial Classification(SIC)Code(s): North American Industry Classification System(NAICS —six digit)Code(s)—If known: (see instructions) Report Prepared by: Telephone#: E-Mail Address: Provide to Appropriate DAQ Regional Office as needed. Information on This Form cannot be held confidential. Boiler#1 &3 Emissions SOURCE NO: B-1 &B-3 Air Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC NO 6 FUEL OIL USAGE= 428,605 GAL HEAT VALUE: 147000 BTU/GAL RATED INPUT= 86.9 MM BTU/HR(Total Capacity of B1 &133) CRITERIA POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal no.6 fuel oil) (1000 gal no.6 fuel oil) (lb/ r) 7 (lb/day) (lb/hr) (lb/15 min) (tp ) PM(7.59 x(1.12 x%sulfur+0.37)) Y 20.7 428.605 8,854.97 #DIV/0! #DIV/0! #DIV/0! 4.43 PM-10(7.17 x(1.12 x%sulfur+0.37)) 19.5 428.605 8,364.97 #DIV/0! #DIV/0! #DIV/0! /4.18 PM 2.5(4.67 x(1.12 x%sulfur+0.37)) 12.7 428.605 5,448.32 #DIV/0! #DIV/0! #DIV/0! ✓2.72 S02(157 x%SULFUR) 329.7 428.605 141,311.07 #DIV/0! #DIV/0! #DIV/0! ✓70.66 S03(2.0 x%SULFUR) 4.2 428.605 1800.14 #DIV/0! #DIV/0! #DIV/0! 0.90 CO 5 428.605 2143.03 #DIV/0! #DIV/0! #DIV/0! 1.07 NOx 55 428.605 23573.28 #DIV/0! #DIV/0! #DIV/0! 11.79 VOC(non-methane) 0.28 428.605 120.01 #DIV/0! #DIV/0! #DIV/0! ✓ 0.06 Notes 1)Lb/yr=usage x emission factor 2)Lb/hr=(lb/yr)/hrs of oper. 3)Criteria pollutant emission factors from AP-42(factors used are for No.6 fuel oil)(09/98).PM emission factors from Table 1.3-5.POM factor from DENR F02000.xls calculations spreadsheet 4)Fuel oil amount is based on actual 2002 gallons 5)Heat content of fuel Oil#6 from Title V Draft Permit. Page 1 of 4 Boiler#1 &3 Emissions SOURCE NO: B-1 &B-3 Air Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC HAZARDOUS/TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (Ib/1000 gal) (1000 gal no.6 fuel oil) (lb/ r) (lb/day) (lb/hr) (lb/15 min) (t ) ANTIMONY 5.25E-03 428.605 2.25 #DIV/0! #DIV/0! #DIV/0! 1.13E-03 ARSENIC 1.32E-03 428.605 0.57 #DIV/0! #DIV/0! #DIV/0! 2.83E-04 BENZENE 2.14E-04 428.605 0.09 #DIV/0! #DIV/0! #DIV/0! 4.59E-05 BERYLLIUM 2.78E-05 428.605 0.01 #DIV/0! #DIV/0! #DIV/0! 5.96E-06 CADMIUM 3.98E-04 428.605 0.17 #DIV/0! #DIV/0! #DIV/0! 8.53E-05 CHROMIUM(VI) 2.48E-04 428.605 0.11 #DIV/0! #DIV/0! #DIV/0! 5.31E-05 COBALT 6.02E-03 428.605 2.58 #DIV/0! #DIV/0! #DIV/0! 1.29E-03 ETHYLBENZENE 6.36E-05 428.605 0.03 #DIV/0! #DIV/0! #DIV/0! 1.36E-05 FLUORIDE 3.73E-02 428.605 15.99 #DIV/0! #DIV/0! #DIV/0! 7.99E-03 FORMALDEHYDE 3.30E-02 428.605 14.14 #DIV/0! #DIV/0! #DIV/0! 7.07E-03 LEAD 1.51E-03 428.605 0.65 #DIV/0! #DIV/0! #DIV/0! 3.24E-04 MANGANESE 3.00E-03 428.605 1.29 #DIV/0! #DIV/0! #DIV/0! 6.43E-04 MERCURY 1.13E-04 428.605 0.05 #DIV/0! #DIV/0! #DIV/0! 2.42E-05 NAPHTHALENE 1.13E-03 428.605 0.48 #DIV/0! #DIV/0! #DIV/0! 2.42E-04 NICKEL 8.45E-02 428.605 36.22 #DIV/0! #DIV/0! #DIV/0! 1.81E-02 PHOSPHOROUS 9.46E-03 428.605 4.05 #DIV/0! #DIV/0! #DIV/0! 2.03E-03 POLYCYCLIC ORGANIC MATTER(POM) 4.04E-05 428.605 0.02 #DIV/0! #DIV/0! #DIV/0! 8.66E-06 SELENIUM 6.83E-04 428.605 0.29 #DIV/0! #DIV/0! #DIV/0! 1.46E-04 TOLUENE 6.20E-03 428.605 2.66 #DIV/0! #DIV/0! #DIV/0! 1.33E-03 1,1,1-TRICHLOROETHANE 2.36E-04 428.605 0.10 #DIV/0! #DIV/0! #DIV/0! 5.06E-05 XYLENE(as o-XYLENE) 1.09E-04 1 428.605 1 0.051 #DIV/0! I #DIV/0! I #DIV/0! I2.34E-05 Notes: 1)Lb/yr=emission factor x usage 2)Toxic/HAP emission factors from AP-42(09/98) Page 2 of 4 MS s 2020 22 CA� Pr'I°5= �,( o � s�°rus P f s, y �i sin bw-7�on P� �f3 `A)0 y2) PM Z Boiler#2 Emissions SOURCE NO: B-2 Air Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC 0 MUTILCYCLONE CONTROLLED-TRAVELING GRATE BOILER HEAT VALUE: 13964 BTU/LB COAL USAGE= 10,636,000 LBS %SULFUR: 1.0 PERCENT xh HRS OF OPER.= 0 HRS %ASH: 5.44 PERCENT RATED INPUT= 42.3 MM BTU/HR PM CONTROL 78 PERCENT r,�ry� CRITERIA POLLUTANTS EMISSIONS (3� EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/ton coal tons coal Ib/ r Ib/hr t PM(9+0.04E-6 x heat value x 2000) 10.12 5318 53803 #DIV/0! fib .90 PM-10(5+0.04E-6 x heat value x 2000) 6.12 5318 32531 #DIV/0! MY46.27 D PM 2.5(0.06 x%ASH)- y,V.? 0.33 5318 1735.80 #DIV/0! I ! O-07 •� I SOx (38 x%sulfur) �A+1^ d 38 5318 202084 #DIV/0! ✓101.04 CO . 6 5318 31908 #DIV/0! /15.95 NOx 7.5 5318 39885 #DIV/0! 1/19.94r7- VOC 0.06 5318 319 #DIV/0! ✓ 0.16 /�l[J'�► Note: f__)•�1`1p)�'1` 1) PM,PM10,&PM 2.5 emission factors include mullicyclone control and both filterable and condensible particulates as listed in AP-42(9/98) 2)Lb/yr=usage x emission factor 3)Lb/hr=(lb/yr)/hrs of oper. Criteria pollutant emission factors from AP-42(9198). TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/ton) tons coal Ib/ r Ib/hr t ACETALDEHYDE 5.70E-04 5318 3.03 #DIV/0! 1.52E-03 ACETOPHENONE 1.50E-05 5318 0.08 #DIV/0! 3.99E-05 ACROLEIN 2.90E-04 5318 1.54 #DIV/0! 7.71E-04 ANTIMONY 1.80E-05 5318 0.10 #DIV/0! 4.79E-05 ARSENIC 4.10E-04 5318 2.18 #DIV/0! 1.09E-03 BENZENE 1.30E-03 5318 6.91 #DIV/0! 3.46E-03 BENZYL CHLORIDE 7.00E-04 5318 3.72 #DIV/0! 1.86E-03 BERYLLIUM 2.10E-05 5318 0.11 #DIV/0! 5.58E-05 BIPHENYL 1.70E-06 5318 0.01 #DIV/0! 4.52E-06 f S(2-ETHYLHEXYL)PHTHALATE(DEHP) 7.30E-05 5318 0.39 #DIV/0! 1.94E-04 ROMINE' " LCr,6VL1J0%0 1.11E-01 5318 590.30 #DIV/0! 2.95E-01 ORM /M DAO, SPAIA091)(f-1 3.90E-05 5318 0.21 #DIV/0! 1.04E-04 CADMIUM 5.10E-05 5318 0.27 #DIV/0! 1.36E-04 CARBON DISULFIDE 1.30E-04 5318 0.69 #DIV/0! 3.46E-04 2-CHLOROACETOPHENONE 7.00E-06 5318 0.04 #DIV/0! 1.86E-05 CHLOROBENZENE 2.20E-05 5318 0.12 #DIV/0! 5.85E-05 CHLOROFORM 5.90E-05 5318 0.31 #DIV/0! 1.57E-04 CHROMIUM(VI) 7.90E-05 5318 0.42 #DIV/0! 2.10E-04 COBALT 1.00E-04 5318 0.53 #DIV/0! 2.66E-04 CUMENE 5.30E-06 5318 0.03 #DIV/0! 1.41E-05 CYANIDE 2.50E-03 5318 13.30 #DIV/0! 6.65E-03 DIBENZOFURANS` 2.01E-07 5318 1.07E-03 #DIV/0! 5.34E-07 DIMETHYL SULFATE 4.80E-05 5318 0.26 #DIV/0! 1.28E-04 2,4-DINITROTOLUENE 2.80E-07 5318 1.49E-03 #DIV/0! 7.45E-07 ETHYL BENZENE 9.40E-05 5318 0.50 #DIV/0! 2.50E-04 ETHYL CHLORIDE 4.20E-05 5318 0.22 #DIV/0! 1.12E-04 ETHLYENE DICHLORIDE 4.00E-05 5318 0.21 #DIV/0! 1.06E-04 ETHYLENE DIBROMIDE 1.20E-06 5318 6.38E-03 #DIV/0! 3.19E-06 04',t&numkus I» hard wy4,-? c-Af- Lwjl Daa spreads AP-yZ Vs-. 5 Ote 50 halt -AA- 7� � 61� 6 k S,►�Pag�of 2�Is A l Ow t/sy,6� �t cw Boiler#2 Emissions SOURCE NO: B-2 Air Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC 0 EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/ton) tons coal Ib/ r Ib/hr t FORMALDEHYDE 2.40E-04 5318 1.28 #DIV/0! 6.38E-04 HEXANE 6.70E-05 5318 0.36 #DIV/0! 1.78E-04 HYDROGEN CHLORIDE 1.20E+00 5318 6381.60 #DIV/0! 3.19E+00 HYDROGEN FLUORIDE 1.50E-01 5318 797.70 #DIV/0! 3.99E-01 ISOPHORONE 5.80E-04 5318 3.08 #DIV/0! 1.54E-03 LEAD 4.20E-04 5318 2.23 #DIV/0! 1.12E-03 MANGANESE 4.90E-04 5318 2.61 #DIV/0! 1.30E-03 MERCURY 8.30E-05 5318 0.44 #DIV/0! 2.21E-04 METHYLENE CHLORIDE 2.90E-04 5318 1.54 #DIV/0! 7.71E-04 METHYL BROMIDE 1.60E-04 5318 0.85 #DIV/0! 4.25E-04 METHYL CHLORIDE 5.30E-04 5318 2.82 #DIV/0! 1.41 E-03 METHYL ETHYL KETONE 3.90E-04 5318 2.07 #DIV/0! 1.04E-03 METHYL HYDRAZINE 1.70E-04 5318 0.90 #DIV/0! 4.52E-04 METHYL METHACRYLATE 2.00E-05 5318 0.11 #DIV/0! 5.32E-05 METHYL TERT-BUTYL ETHER 3.50E-05 5318 0.19 #DIV/0! 9.31 E-05 NICKEL 2.80E-04 5318 1.49 #DIV/0! 7.45E-04 PHENOL 1.60E-05 5318 0.09 #DIV/0! 4.25E-05 POM' 5.20E-05 5318 0.28 #DIV/0! 1.38E-04 PROPIONALDEHYDE 3.80E-04 5318 2.02 #DIV/0! 1.01E-03 SELENIUM 1.30E-03 5318 6.91 #DIV/0! 3.46E-03 STYRENE 2.50E-05 5318 0.13 #DIV/0! 6.65E-05 2,3,7,8-TCDD 1.43E-11 5318 7.60E-08 #DIV/0! 3.80E-11 TETRACHLOROETHYLENE 4.30E-05 5318 0.23 #DIV/0! 1.14E-04 TOLUENE 2.40E-04 5318 1.28 #DIV/0! 6.38E-04 1,1,1-TRICHLOROETHANE 2.00E-05 5318 0.11 #DIV/0! 5.32E-05 VINYL ACETATE 7.60E-06 5318 0.04 #DIV/0! 2.02E-05 XYLENES 3.70E-05 5318 0.20 #DIV/0! 9.84E-05 Note: 1)Lb/yr=emission factor x coal usage 2)Toxic/HAP emission factors from AP-42(09/98)for Controlled Coal Combustion,Table 1.1-13 and 1.1-18 unless noted. 3)'Emission factors from DEHNR Bituminuos Coal Combustion spreadsheet(Version 5-b-Ok by Tony Pendola;06/17197) 3)Biphenyl emission factor given in AP-42=1.7E-06 lb/ton of coal consumed. 4)Where emission factor ranges were given in AP-42,an average of high and low factors was used for emissions. Page 2 of 2 Tenter Frame#14 and Dryer Propane Emissions Summary SOURCE ID#: TF-1-4, D-1, D-2 Air Emission Inventory-CY 2005 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 (BTU/GAL) LBS USED = 1,447,416 GALLONS USED: 344631 CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r (lb/day) Ib/hr Ib/15 min t PM 0.4 344,631 138 #DIV/0! #DIV/0! #DIV/0! 0.069 PM-10 0.4 344,631 138 #DIV/0! #DIV/0! #DIV/0! 0.069 PM-2.5 0.4 344,631 138 #DIV/0! #DIV/0! #DIV/0! 0.069 S02 0.1 344,631 34 #DIV/0! #DIV/0! #DIV/0! 0.017 CO 1.9 344,631 655 #DIV/0! #DIV/0! #DIV/0! 0.327 NOx 14 344,631 4,825 #DIV/0! #DIV/0! #DIV/0! 2.412 VOC 0.5 344,631 172n #DIV/0! #DIV/0! #DIV/0! 0.086 NOTES: /, _ A �±pryy*hplQcv�pt'Zp�p y_✓apw,.p y r�2*p lo✓l 1)Lb/yr=annual usage x emission factor/1000 2)Actual Propane from Total Facility 2002 Usage (lb to gal conversion=Gal/4.2 lb/gal) 3)Emission Factors from AP-42(10/96) All PM is assumed to be PM-2.5 and PM-10 Emission Factor for S02 is from Title V Permit. Page 1 of 1 Coal &Ash Handling System Emissions Air Emission Inventory-Calendar Year 2005 Edenton Dyeing& Finishing LLC PARTICULATE MATTER Total Coal Emission Uncontrolled Control Device PM PM-10 PM-2.5 Throughput Factor PM Emissions Efficiency Emissions Emissions Emissions Source ID Source Description (tons/ r) (ton PM/ton coal) (tons/ r) (%) (tons/ r) tons/ r) (tons/ r AHS-1 Ash Handling System 5,318 0.0544 289.30 99.9% 0.29 0.17 0.01 CHS-1 Coal Handling System 5,318 0.0050 26.59 80% 5.32 5.32 5.32 CSILO-1 ICoal Storage Silo I Not In Operation Notes: 1)Control Device Efficiencies taken from Title V Application. 2)Particulate Emissions factors: Ash Handling System:PM Emissions factor=weight fraction of ash in the coal(0.0544,or 5.44%as listed on 1/12/01 coal analysis)The Ash Handling System consists of fly ash and bottom ash from coal consumed in the boiler. Coal Handling System:PM Emissions factor=estimated fugitive dust generated from coal handling(0.005 or 0.5%as listed in the Title V application) Coal Storage Silo did not operate in 2002. 3)PM Uncontrolled Emissions=coal throughput x emission factor 4)PM emissions=uncontrolled emissions x(1 -control efficiency) 5)PM10 emissions from the Ash Handling System =PM emissions x(PM10 emission factor/PM emission factor) (PM10 emission factor=6.12 lb/ton,PM emission factor=10.12 lb/ton) 6)PM2.5 emissions from the Ash Handling System=PM emissions x(PM2.5 emission factor/PM emission factor) (PM2.5 emisson factor=0.33 lb/ton) 7)All PM emissions from Coal Handling System assumed to be equivalent to PM 10 and PM 2.5 Page 1 of 1 A � �cess Chemical Emissions Air Emission Inventory-Calendar Year 2005 Edenton Dyeing 8 Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS DYEING FINISHING PREPARATION 1 YEAR 2000 Chemical Weight MAX. Total % Dyeing % Finishing %Product Preparation Year 2003 Product Chemical Product DM1- Product Name Usage(Ibs) Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Used in Usage Used In Chemical Used in PI DM25 TF-1 Number (%) ON SITE Usage(Ibs) Usage(Ibs) Preparation Usage(Ibs) Dyeing (Ibs) Finishing LEVELRITE AM-N 0(GE)2-butoxyethanol X X X 111-76-2 8.10 41 0 100 0.0 0 0 SANDOPAN DTC-100-MM 28,410(GE)dielhyiene glycol monobutylelher X X 112-34-5 13.00 676 3693.3 25 923.3 75 2770.0 46 983 OYCLEAN 290-S 0(GE)Ethylenglycol Monobutylether X X 111-76-2 96.60 966 0 100 0.0 0 0 BURCOSCOUR LFE-810 3,780 GE Glycol Ether X X NA 8.00 400 302.4 40 121.0 60 181.4 6 80 HIPOCHEM CARRIER RPS 0 1 2 3-tichlorobenzene X 87-61-6 15.55 778 0.00 100 0.0 09,000, HIPOCHEM CARRIER RPS 0 1 2 4-tdchlorobenzene X X 120-82-1 59.00 2950 0.00 100 0.0 0 HIPOCHEM CARRIER RPS 0 1 2 4-trimeth benzene X 95-63-6 0.15 8 0.00 100 0.0 0HIPOCHEM CARRIER RPS 0 1 2-dichlorobenzene X 95-50-1 20.00 1000 0.00 100 0.0 0BURCOSOFTSTP 014-Dioxane X X X 123-91-1 0.10 8 0 100 0.0 0ALBATEX FFC 0 2-elh I hexanol X 104.76-7 20.00 100 0 100 0.0 0 MIGRATONE 55.513 Acetic Acid X X 64-19.7 2.00 100 1110.26 100 1110.3 NUPEL CDF 0 Acetic Acid X X 64-19-7 95.00 4750 0 100 0.0 ACETIC ACID 56% 76.834 acetic acid X X 64-19-7 56.00 29M 43027.04 100 43027.0 NUSOFT E 0 Acetic Acid X X 64-19-7 100.00 5000 0 100 0.0 0 0 NUTRABOND SP BPD 2,928acrylamide X X 79-06A 1.00 50 29.28 100 29.3 0 8 NUTRASETBH 8070 acrvlamide X X 79.06-1 1.00 50 80.7 100 80.7 0 23 BURCOSCOUR LFE-810 3,780 Alcohol X NA 8.00 400 302.4 40 121.0 60 181.4 6 80 INMONT VIOLET V3W 01-8501 85 Amino Methyl Propanol X 124-68-5 1 0.85 100 0.9 0.0 0 INMONT BLUE GL3W 01-8404 65 Aminomethyl propanol X 124-68.5 1 0.65 100 0.7 0.0 0 INMONT RED CM3W 01-8003 80 Aminometh I propanol X 124-68.5 11 0.8 100 0.8 1 0.0 0 ASTRO BLACK GD 10 Ammonia X 7664-41-7 1.2 0.12 100 0.1 0.01 0 ASTRO BLUE 3G CON 60 Ammonia X 7664-41-7 1 0.6 100 0.6 0.03 0 ASTRO RED LF CONC 85 Ammonia X 7664-41-7 1.2 1.02 100 1.0 0.06 0 ASTRO TURO HL 80 Ammonia X 7664-41-7 1.2 0.96 100 1.0 0.05 0 ASTRO YELLOW 2GD 40 Ammonia X 7664-41-7 1.2 0.48 100 0.5 0.02 0 ASTRO YELLOW HR 10 Ammonia X 7664-41-7 1.2 0.12 100 0.1 0.01 0 LOPAD WHITE CS 2,450 Ammonia X 7664-41-7 0.40 4 9.8 100 9.8 0.00 3 HIPOCHEM CP-OS 20,250 Ammonia X 7664-41-7 0.30 4 60.75 50 30.4 50 30.4 1.52 16 INMONT VIOLET V3W 01-8501 85 Ammonia X 766441-7 1 0.85 100 0.9 0.04 0 INMONT BLUE GL3W 01-8404 65 Ammonia Hydroxide X 1336-21-6 3 1.95 100 2.0 0.10 1 INMONT RED CM3W 01-8003 80 Ammonia Hydroxide X 1336-21-8 3 2.4 100 2.4 0.12 1 UNIDIVINE DIF 0 Benz(benzoate X 120-51-4 30.00 660 0 100 0.0 0.00 0 HIPOCHEM CARRIER 10-CD 37.525 biphenyl X X 92-52-4 20.00 1000 7505.00 100 7505.0 I52.46 279 HIPOCHEM CARRIER RPS 0 biphenyl X X 92-52-4 15.00 750 0 100 0.0 0.00 0 INT BLUE GFD 150% 0 Blended Mineral Oil X NA 0 100 0.0 0 0 INTRASIL BORDEAUX 3 BSK 0 Blended Mineral Oil X NA 0 100 0.0 0 0 ORANGE 2 RA INTRA 370 Blended Mineral Oil X NA 0 100 0.0 0 0 BLUE NAVY RLL 400%INTRAMET 2.474 Blended Mineral Oil X Proprietary 100 0.0 0 0 DIRECT BR PINK B 278 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 NYLANTHRENE ORANGE SLF 9 Blended Mineral Oil X Proprietary 100 0.0 0 0 SOL AQUA FAST RED 28L 181 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 YELLOW FLMS-NYL 0 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 37,525 dibenzofuran X X 132-64-9 6.00 300 2251.50 100 204.9 10 55 CIBACET BROWN E2R 228 Diethylene glycol X 111-46-6 12 27.36 100 27.4 1 7 GLOPAD WHITE CS 2.450 dethylene glycol X 111-46-6 9.00 90 220.5 100 220.5 0 62 PERMAFRESH TGC 84,526 dethylene glycol X 111-46-6 1.50 900 1267.89 100 1267.9 0 357 REMAZOL TURQ RP 50%LIQ 2.108 Diethylene glycol X 111.46-6 10 210.8 100 210.8 11 56 ANTIFREEZE 0 diethyiene alvcol X 111-76.2 70.00 420 01 Note pro UVITEX RSB 3725 diiso ro nolamine X 110-974 0.50 5 18.625 25 4.7 7 14.0 0 5 UNIDIVINE DIF 0 Dipropylene Glycol X 110-98-2 30.00 660 0 100 0.0 0 0 NUPEL CDF 0 Dipropylene GI col-Monometh I Ether X I 1 34590.94-8 95.001 4750 0 1 100 0.0 1 0 0 FX 259 0 Ethylene Glycol X X 107-21-1 0.50 5 0 100 0.0 0 0 HIPOCHEM CP-OS 20,250 Ethylene Glycol X X 107-21-1 3.00 41 607.5 50 303.8 50 3038 15 162 BURCOFIXUPD 10,119 Formaldehyde X X X 50-00-0 1.00 75 101.19 100 101.2 0 29 FABRISET REACTANT PCE 114,526 Formaldehyde X X X 50-00-0 0,01 0 8,4526 1 W 8.5 0 2 HYSTRETCH V-29 0 Formaldehyde X X X 50-00-0 0.10 1 0 100 0.0 0 0 INMONT BLUE GL3W 01-a404 65 Formaldehyde X X X 50.00-0 0.5 0.325 100 0.3 0.02 0 INMONT RED CM3W 01-8003 80 Formaldehyde X X X 50-00-0 0.5 0.4 100 0.4 0.02 0 MYKON 39 0 Formaldehyde X X X 50-00-0 0.03 0 0 100 0.0 0 0 PERMAFRESHTGC 84,526 formaldehyde X X X 50-00-0 0.50 300 422.63 100 422.6 0 119 INMONT VIOLET V3W 01-8501 85 Fornalde de X X X 50-00-0 0.5 0.425 100 1 0.4 1 1 1 0.02 0 Page 1 of 6 CHEMICAL EMISSIONS BY SOURCE 2005 TOTAL V C EMISSIONS (ENTER FRAMES DRYERS DRY CANS TOTAL TENTER EMISSIONS JSTEAM-1,DR DYEING FRAMES 1 PREPARATION (LBS)PER TF-2 TF-3 TF-4 LOOP D-1 BELT D-2 DC-1 DC-2 DC-3 1,JEM-1,BRA, DRYERS/ CHEMICAL MBO.1,RW-1, DRY CANS WO-'1 0 0 0 0 0 0 0 0 0 0 1099 1042 0 19 369 0 0 138 52 3799 148 3999 0 0 0 0 0 0 0 0 0 0 90 85 0 2 30 0 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 See Note 9 Below 229 229 0 0 0 0 0 0 0 0 0 0 9 9 0 0 0 0 0 0 0 99 0 99 0 25 24 0 0 0 0 0 0 0 90 85 0 2 30 0 0 9 6 288 9 303 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.12 2.19 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 78 0 3 3 0 0 0 0 0 0 0 18 17 0 0 6 0 0 1.52 0 0 0 0 0 0 0 0 0 1.7 71 1.52 0 1 1 0 0 0 0 0 0 01 1 1 01 0 0 01 0 0 0 01 0 0 0 0 0 0 0.00 0.00 0 0 0 0 312 296 0 5 105 0 0 0 52.46 998 0 1050 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01 611 58 0 1 20 0 0 0 10 195 0 205 0 8 8 0 0 3 0 0 0 0 69 66 0 1 0 0 0 0 12 1567 0 1579 0 399 379 0 7 0 0 0 0 0 63 59 0 1 21 0 0 0 cess chemical 0 6 5 0 0 0 0 0 0 0 17 0 17 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01 0 01 0 01 0 01 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 15 578 15 608 0 181 171 0 3 61 0 0 15 0 32 30 0 1 0 0 0 0 0 3 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 006 481 0 481 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 133 126 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 Page 4 of 6 Process Chemical Emissions Air Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS DYEING FINISHING PREPARATION 1 YEAR 2000 Chemical Weight MAX. Total % Dyeing % Finishing %Product Preparation Year 2003 Product Chemical Product DM1 Product Name Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Chemical Used In Chemical TF•1 Usage(Ibs) Number N ON SITE Usage(Ibs Used Dyeing g Usage Used In(Ibs) Finishing Usage(Ibs) Preparation Usage(Ibs) DM25 j BURCOSCOUR LFE-810 3.780 Hydrocarbon X NA 8.00 400 302.4 40 121.0 60 181.4 6 80 BURCO WHITE WGS 90 Isopropanol X 67-63-0 16.50 144 14.85 60 8.9 40 5.9 0 4 BURCOWET NFW 150% 655 Isopropanol X 67-63-0 16.50 284 108.075 100 108.1 5 29 ISOPROPYL ALCOHOL 99% 0 Isopropyl alcohol X 67-63-0 100.00 5000 0 100 0.0 0 0 LEVELRITE AM-N 0 isopropyl alcohol X 67-63-0 5,00 25 0 100 0.0 0 0 SANDOPAN OTC-100-MM 28.410 Isopropyl alcohol X 67-63-0 7.00 364 1988.7 25 497.2 75 1491.5 25 529 SILTONE BV 0 isopropyl alcohol X 67-63-0 1.00 300 0 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 37,525 methyl benzoate X I 93-58-3 6881 3441 2581,72 100 234.9 1 1 12 63 HIPOCHEM CARRIER 10-CD 37,526,methyl naphthalenes X NA 32.00 1600 12008.00 100 1092.7 55 291 HIPOCHEM CARRIER 10-CD 37.525 meth I- •toluale X 99-75-2 29.00 1450 10882,25 100 990.3 50 263 LEVAFIX BROWN ERN 177 Mineral Oil X 8042-47-5 3 5.31 100 5.3 0 1 RUBINE CK-GFL 200%INTRASIL 319 Mineral oil blend X Proprietary 1.40 4.466 100 4.5 0 1 ALBATEX FFC 0 monoethanolamine X 141-43-5 0,80 4 0 100 0.0 0 0 HIPOCHEM CARRIER RPS 0 naphtha solvent X 64742-94-5 1.90 95 0,00 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 37,525 naphthalene X X 91-20-3 4.22 211 1563.56 100 144.1 7 38 HIPOCHEM CARRIER RPS 0 naphthalene X X 91-20-3 0,40 20 0.00 100 0.0 0 0 HIPOCHEM SS-550 42,177 Naphthalene X X 91-20-3 1 0.051 4 21.0885 100 21.1 1 6 INMONT BLUE GL3W 01-8404 65 n-Butyl Alcohol X 71-36-3 5 3,25 1() 3.3 0 1 INMONT VIOLET V3W 01-8501 85 n-Butyl Alcohol X 71-36-3 5 4.25 100 4.3 0 1 INMONT RED CM3W 01-8003 80 n-But I Alcohol X 71-36-3 5 4 100 4.0 0 1 Page 2 of 6 CHEMICAL EMISSIONS BY SOURCE 2005 TOTAL VOC EMISSIONS (ENTER FRAMES DRYERS DRY CANS TENTER TOTAL JSTEAM-1,DR FRAMES I EMISSIONS 1,JEM-1,BR-1, DYEING DRYERS/ PREPARATION (LBS)PER TF-2 TF-3 TF4 LOOP D•1 BELT D-2 DC-1 DC-2 DC-3 MBO.1,RW1, DRY CANS CHEMICAL WO-11 0 001 85 0 2 30 0 0 9 6 288 9 303 0 5 4 0 0 1 0 0 0 0 32 30 0 1 11 0 0 0 0 0 0 0 0 0 0 0 0 31 2008 75 2113 0 0 0 0 0 0 0 0 0 0 592 561 0 10 199 0 0 75 0 0 0 0 0 0 0 0 0 0 70 66 01 1 23 01 01 0 12 223 0 235 Oil 325 308 0 6 109 0 0 0 55 1039 0 1094 0 295 279 0 5 99 00 0 50 942 0 991 0 2 1 0 0 1 0 0 0 0.49 9.30 0 10 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 43 41 0 1 14 0 0 0 0 0 0 0 0 0 0 0 0 8 157 0 165 0 6 6 01 0 21 0 01 0 0 1 1 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 1 11 0 12 0 1 1 0 0 0 0 0 0 Page 5 of 6 Process Chemical Emissions Alr Emission Inventory-Calendar Year 2005 Edenton Dyeing&Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS UYLINU DYEING FINISHING PREPARATION 1 YEAR 2000 Year 2003 Chem cal Product Chemica Product al Weight MAX. Total % Dyeing % Finishing %Product Preparation M l Product Name Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Chemical Used It Chemical D 11- TF-1 Usage(Ibs) Number (%) ON SITE Usage(Ibs Used In Usage Used In Usage(Ibs) Preparation Usage(Ibs) DM25 Dyeing (Ibs) Finishing INMONT BLUE GL3W 01-8404 65 Petroleum Distillate X 64742-95-6 10 6.5 100 6.5 0.33 2 INMONT VIOLET V3W 01-8501 85 Petroleum Distillate X 64742-95-6 6 5.1 100 5.1 0.26 1 A-LUBE CP CONC.200% 0 petroleum distillates X 64741.88-4 100.00 500 0 100 0.0 0.00 0 RESPAD YELLOW Y3W 01-8209 100 Petroleum distillates X 64742-94-5 6 6 100 6.0 0.30 2 HIPOCHEM CARRIER RPS 0 petroleum distillates X 64742-95-6 3.00 150 0.00 100 0.0 0.00 0 ASCOUR MWN 7,650 petroleum distillates X 8032-32-4 80.00 4000 6120 60 113.8 40 75.9 5.69 50 HIPOCHEM CARRIER 10-CD 37,525 quinollne X X 91-22-5 7.00 350 2626.75 100 239.0 12 64 MYKON 39 0 Vinyl Acetate X X 108-05-4 0.13 2 0 100 0.0 0 0 ACID RED GN 841 White mineral oil X 8042-47-5 1 5 8.41 100 8.4 0 2 BLUE BAR-200%NYL 56 White mineral oil X 8042-47-5 1 5 0,56 100 0.6 0 0 DIRECT SCARLET 4SWN 57 White mineral oil X 8042-47-5 1 10 0.57 100 0.6 0 0 DIRECT TURQ GRLL 231 While mineral oil X 8042-47-5 1 5 2.31 100 2.3 0 1 NYL RED 213SA 55 White mineral oil X 8042-47-5 1.20 0.66 100 0.7 0 0 SUPERLITEFAST RED 3BL 663 While mineral oil X 8042-47-5 1 6.63 100 6.6 0 2 SUPERLITEFAST RUBINE WLKS 200 1 White mineral oil X 8042-47-5 1 0.01 100 0.0 0 0 YELLOW FLMS-NYL 0 While mineral oil X I I I 8042-47-5 1 11 01 100 0.0 0 0 NUPEL CDF 0 Xylene X I X X 1 1330-20-7 5.00 250 0 100 0.0 0 0 PELATEX 0 xylene X X X 1330-20-7 5.00 250 0 too 0.0 0 0 HIPOCHEM CARRIER 10-CD 37.525 X lene o-x lene X X X 95-47-6 1.90 95 712.98 100r,4j, 3 17 TOTAL VOC'S BY SOURCE 333 3758 Page 3 of 6 CHEMICAL EMISSIONS BY SOURCE 2005 TOTAL VOC EMISSIONS (ENTER FRAMES DRYERS DRY CANS TOTAL TENTER EMISSIONS JSTEM-1 DYEING FRAMES/ PREPARATION (LBS)PER TF-2 TF-3 TF-0 LOOP D-1 BELT D-2 DC-1 DCEIC-31,JEM-1, , DRYERS/ CHEMICAL MBO.1,RW-1,-1 DRY CANS WO-1 0 2 2 0 0 1 0 0 0 0 2 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 6.57 197 4 207 0 2 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 56 54 0 1 19 0 0 4 0 71 67 0 1 24 0 0 0 12 227 0 239 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0.96 18.21 0 19 0 0 0 0 0 0 0 0 0 0 2 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 62 0 65 0 19 18 0 0 6 0 0 0 01 42021 39861 01 721 11851 01 01 259 333 13433 259 114103 • Page 6 of 6 .1 i, � .... .... ........u... .of�.ur.. �-rr�.ur..r�x. VatlU Irr Usage(Ibe) Number (X) ON SITE Usage Dyeing Usage I (Ibe) (Ibe) F ,INMONT BLUE GL3W 01-8404 60 Pet(oletml Disblate X 64742-95-6 10 6 100 6.0 IIN6IONT VIOLET V3W 01-8501 184 Petrdetxn Distillate X 64742-95-6 6 11.04 1D0 11.0 IA-LURE CP CONC.200% 0 pelrolam dstilates X 64741-88-4 100.00 500 0 100 0.0 RESPAD YELLOW Y3W 01-8209 90 PetroWm clsdlates X 64742-94-5 6 SA 100 5.4 HIPOCHEM CARRIER RPS 5.500 petrolew dstllates X 64742-95-6 3.00 150 165.00 100 26.9 ASCOUR MWN 0 troleun dstilates X 8032-324 80.00 4000 0 60 0.0 HIPOCHEM CARRIER 10-CD 3,300 qxnoirie X X 91-22-5 7.00 350 231.00 100 21.0 MYKON 39 01 V� Acetate X X 1 108-054 0.13 2 0 ACID RFD GN 23 Mile mirwKni all X 8042-47-6 1 5 0,23 100 0.2 i111-OF BAR-200%1JYL 27 Mile Mtmt it)all X 8042-47.5 1 5 027 100 0.3 jDIRECT SCARLET 4SWN 0 White mirleral all X 8042-47-5 1 10 0 100 0.0 DIRECT TURQ GRILL 34 White mineral all X 804247-5 1 5 0,34 100 0.3 NYL RED 213SA 0 WNte mineral oil X 8042-47-5 1.20 0 100 0.0 SUPERLITEFAST RED 38L 0 WNte mineral oll X &M2-47-5 1 0 1D0 0.0 SUPERLITEFAST RUBINE WLKS 200 51 White Mrleral all X 8042-47-5 1 0.51 100 0.5 YELLOW FLMS-NYL 39I White mineral oil X I 1 1 W4247-5 1 11 1 0.39 I inn I0.4 14UPEL CDF 184 Xylene X X X 1330 20 7 5.00 250 9.2 PEIATEY. 0 xyiene X X X 1330-20-7 5.00 250 0 fIIPOCHEM CARRIER 10-CD 3300X o- X X X 95-47-6 1.90 95 62.70 1D0 5.7 7T61 AL VOC'S BY SOURCE I---- - -- trout. �1)P,,d,,cl Usage was p,&Aded by Place Dye �)Tme,Ch*Mkel Usage By PW*tf If the%each product It used In Dyov.FHsltlrq,onaw Ptepwatim as pNen by Piece Dye. 1)161t V ey •odds limits that for VOCA WITAP w/pinding at Dyeing,%5 Is emitted d the process.66%h wilted at tie Thar Frame with Do Oder 10%wrMled d the Sloan Cara W s tdal d 1 DO%emlttod, 1 Ts1e V appacdim side lha1 far VOCMM(TAP drl"I q al tta Todai Fromelt,90%It wined a o nihod d tha Fromet.The dhee 10%Is assunod ihmDugh protest Imewtodge to be olnllod to tie W WTP. 5;Tlhe V appscaum Odes Cat for VOCMAP/TAP o i*ms kq In 0a Preparation Process.5%Is emitted at the prKlmses,95%Is emitted at the Thaw FrMnot and 10%Is writhed d the Stec Cara. 6)FamM for colculsiv i;CMmkal Emisslom W,the 0,t Ptoctts:Dyeft Chorticd Eldadom a Dyotq Chanicd utsge(Es)x 0.05(See Notes 1 L 3) 7)Flnhhtq Proctas CMmicsl Frsstlom CokuAdlor": a)Toiler Frwnee 6 Dryon:CdcuAdbm for so&Tortor Frame mid Dryw Is batetl an the total yew 2002 production for all Thaw Fromet old Dryom.A pwcsrepo of production it cdttided fer each hems: (op-%Ptodrellon TF-1 a Actual v~ion for Tortes Froma 1 dFAdod by the Sum of Production M al 4 Toiler Fr es a Dryers)TF-1 a 31.3%.TF•2 t 0%.TF.1 a 36.0%.TF-4 a 351%,61•0%.D-2•0.6% •To txade wry umomkds added at Dyeing w dA.Pmpwdbn(Soo Notes 1,J l 5),smsticm wo coicu med by T trier Fr-cciryor Erdssiora a Toiler Fromo(w Dryer)Prod ctim%s I(Dyenp Chw rkw Ueegs x 0.09)4(Preparation Chemksi Usags x 0.e5)+(FWS"Chornlcd Use"x 0.9)) b)Dry Cons DG2 and D43 nd opwded In 2002.rM to Include rry om)ttlom Rom cMmiraes oddoci d DyOV or Preprdbn,emitsiora we cdcu4lod by Dry(Steam)can Emssim(DC-1)•lmri q CMmical us►"x 0.1)a(Preparation Chonkof Utogs x 0.1)) (Soo Notes 1,5 L 5) 9)FormWe for caiculatxq Chomkal Emist)om Io,the Pnpw tin Procost:Pr♦prdbn Chm icd Emissions a Props tim ch icd Usage(bt)x ODS(see Note 6) 9)Aretic Aced sir omltslon tlklllMllwa:Acetic Acid Is used In the rk*hk g Process.99-%Is dsctargod IhV11ph the WWTP.Air wnetalOm rs based on the Total Yards Produced that we attached,and the "'pit d fend,.par yonl.Dots Rom the 1995 At h+wtery Ode that 30%or production it BNac-h d.and"each yard Bieaelad-Ighs 0.6 bit mind has 6.61E-05 bs d Aedk Acid that it washed to the 1a. Acotk AIM Air Emssion Ms)a Produdtn(MI yard+)x 30%eltached x 0.6bslyrd x 6.S1E-M bs Arotk Acid por pond of hb c. TM Tore)Arctic Acid omistbm we divided between oach Tarts,Frame bred m tie%pn chutlbn or each(s"Note To above). 10)All-ii Preparom source omission we dNWod equasy Snag a6 equ0n,"t operotWV daeq yew 20012 In INS Sours(DR-1,BR-1,6 AB01). Page 3 of 6