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HomeMy WebLinkAboutAQ_F_2100051_20050531_EI_Cmb-EI-File 2004 Emissions InventoIy Review/Data Tracking Form Facility Name: 606PJ7-01/ yE,1y6 � /NiSVING County/Premise Number: Z/,zD5/ Assigned to: _I?f/ Confidential? 111- Initial Review /Data Entry tl ❑ If confidential information received,it has been properly labeled and stored. Sanitized copies have been / received for public use. ❑ Two copies of inventory were received and forms were signed by responsible official. C- Inventory Review/Database Entry Forms appear to be complete Calculations and control efficiencies /`' supporting emissions appear correct Calculations appear to add up ok /All permitted sources and required significant activities are quantified All compliance issues resulting from review are being addressed.(i.e.toxics,emission limitations exceeded,unpermitted sources) All volatile HAPS/TAPS are included in the VOC total /All appropriate ID numbers are entered where they should be(Source,Stack) ❑ All changes made in the review by AQ staff are in both copies of the inventory before sending to -5,W Central Office. _�./}�� /� ��j Comments: A4t," / 17 �'I ! /7'7Cj , Signature: J Date Billing Contact & General Data updated in FEES database fZ31 Date Emissions Data loaded into E"AQ database /a5 Remember: Confidential copies must be properly handled! )NEN\2004 Emission Inventories\WARD inventory review form.doc) Facility Total CY 2004 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing Permit#(s): 02621T15 Criteria Pollutants �/'JVf NT�2Y A PPaO►P Actual Emissions % Difference (Tons/Year) Pollutant `%` CAS CY 2004 CY 2003 from ED from Fees CO CO 14.66 14.54 0.8% NOx NOx 26.78 42.26 -36.6% PM(TSP) TSP 20.89 49.20 -57.5% PM10 PM10 20.63 16.92 21.9% PM2.5 PM2.5 7.17 10.49 -31.6% S02 S02 132.98 173.41 -23.3% VOC (Meeting Federal Definition as voC 5.00 4.03 24.1% photochemically reactive) Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2004 CY 2003 from ED from Fees Polycyclic Organic Matter (Specific Compoundsfrom OAQPSfor 1,093.92 283.52 285.8% TT) Biphenyl (Component of 833291POMTV) 92-52-4 692.60 207.78 233.3% Furans -Dibenzofurans (group total- CAA - 132-64-9 135.00 18.11 645.4% unchlorinated) (Component of 833291POMTV) Naphthalene (Component of 833291POMTV) 91-20-3 108.32 36.63 195.7% Quinoline (Component of 833291POMTV) 91-22-5 158.00 21.00 652.4% Nickel& Compounds, sum total mass, inc elemental 23.69 32.00 -26.0% Nickel Unlisted Compounds (Specify & Component NIC-other 23.69 32.00 -26.0% of 3730241NIC) Mercury & Compounds- all total mass, inc Hg Vapor 0.030000 0.043050 -30.3% Mercury Unlisted Compounds (Specify& Component HGC-Other 0.030000 0.043050 -30.3% of HGC) Manganese & compounds 0.840000 1.14 -26.3% Manganese Unlisted Compounds (Specify & MNC-other 0.840000 1.14 -26.5% Component of MNC) Lead and Lead compounds 2.34 70.38 -96.7% 05/31/2005 Page 1 of 5 Facility Total CY 2004 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing, LLC Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2004 CY 2003 from ED from Fees Lead and Lead compounds 2.34 70.38 -96.7% Lead Unlisted Compounds (Specify and Component PBC-Other 2.34 70.38 -96.7% of PBC) Glycol ethers (total all individual glycol ethers-See 723.00 781.26 -7.5% http://daq.state.nc.us/toxics/glycol Glycol Ethers, Unlisted(Specify& Component of GLYET-Other 723.00 781.26 -7.5% GLYET) (See http://daq.state.nc.us/toxics/glycol/) Cyanide compounds (see also hydrogen cyanide) Not 0.000000 N/A Reported Cobalt compounds 1.69 2.29 -26.2% Cobalt Unlisted Compound(Specify & Component of COC-Other 1.69 2.29 -26.3% COC) Chromium (VI)Non-Specific Compounds, as Chrom(VI) 0.430000 173.24 -99.8% (Component CRC) Chromium (VI) Non-Specific, Unlisted(Sped & NSCR6-Other 0.430000 173.24 -99.8% Component of NSCR6& CRC) Chromium -AII/Total (Inc Chromium (VI) categories, metal and 0.430000 173.24 -99.8% Others) Chromium (VI) Non-Specific, Unlisted(Specify& NSCR6-Other 0.430000 173.24 -99.8% Component of NSCR6& CRC) Cadmium & compounds (total mass inc elemental metal) 0.230000 4.40 -94.8% Cadmium Unlisted Compounds (Specify& CDC-other 0.230000 4.40 -94.8%, Component of CDC) Beryllium & compounds (Total mass) Not 0.000000 N/A Reported Arsenic & Compounds (total mass of elemental AS, arsine and all 2.24 56.03 -96.0% inorganic compounds) Arsenic Unlisted Compounds (Component ofASC- ASC-Other 2.24 56.03 -96.0% Specify) Antimony & Compounds (total mass, inc elemental SB) 1.47 1.98 -25.8% Antimony Unlisted Compounds (Component of SBC- SBC-Other 1.47 1.98 -25.8% Specify) Acetaldehyde 75-07-0 2.60 3.01 -13.7% 05/31/2005 Page 2 of 5 Facility Total CY 2004 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing LLC Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2004 CY 2003 from ED from Fees Acetic acid 64-19-7 229.00 231.23 -1.0% Acetophenone 98-86-2 0.070000 0.079320 -11.7% Acrolein 107-02-8 1.32 1.53 -13.9% Acrylamide 79-06-1 109.00 69.61 56.6% Ammonia(as NH3) 7664-41-7 133.40 66.78 99.8% Benzene 71-43-2 6.00 6.96 -13.7% Benzyl chloride 100-44-7 3.20 3.70 -13.6% Bromine 7726-95-6 Not Not N/A Reported Reported Bromoform 75-25-2 0.180000 0.206230 -12.7% Carbon disulfide 75-15-0 0.590000 0.687440 -14.2% Chloroacetophenone, 2- 532-27-4 0.030000 0.037020 -19.0% Chlorobenzene 108-90-7 0.100000 0.116340 -14.0% Chloroform 67-66-3 0.270000 0.311990 43.5% Cumene 98-82-8 0.020000 0.028030 -28.6% Dimethyl sulfate 77-78-1 0.220000 0.253820 -13.3% Dinitrotoluene, 2,4- 121-14-2 0.001280 0.001480 N/A Dioxane, 1,4- 123-91-1 Not Not N/A Reported Reported Ethyl benzene 100-41-4 0.450000 0.521300 -13.7% Ethyl chloride (chloroethane) 75-00-3 0.190000 0.222100 -14.5% Ethylene dibromide 106-93-4 0.005480 0.006350 -13.7% Ethylene dichloride (1,2-dichloroethane) 107-06-2 0.180000 0.211520 -14.9% Ethylene glycol 107-21-1 1,242.00 577.00 11.5.3% Fluorides (sum of all fluoride compounds) 16984-48-8 10.46 14.21 -26.4% Formaldehyde 50-00-0 450.17 741.46 -39.3% 05/31/2005 Page 3 of 5 Facility Total CY 2004 Emission Summary Recorded in ED Facility ID #: 2100051 Facility Name: Edenton Dyeing and Finishing LLC Permit#(s): 02621T15 Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2004 CY 2003 from ED from Fees Hexane, n- 110-54-3 0.310000 0.354300 -12.5% Hydrogen chloride (hydrochloric acid) 7647-01-0 5,479.00 6,345.60 -13.7% Hydrogen fluoride (hydrofluoric acid as mass of HF- 7664-39-3 685.00 793.20 -13.6% Component of Fluorides) Isophorone 78-59-1 2.65 3.07 -.13.6% Methyl bromide 74-83-9 0.730000 0.846080 -13.7% Methyl chloride 74-87-3 Not Not N/A Reported Reported Methyl ethyl ketone 78-93-3 1.78 2.06 -13.7% Methyl hydrazine 60-34-4 0.780000 0.898960 -13.20/o Methyl methacrylate 80-62-6 0.090000 0.105760 -14.9% Methyl tertiary butyl ether(MTBE) 1634-04-4 0.160000 0.185080 43.6% Methylene chloride 75-09-2 1.32 1.53 -13.9% Phenol 108-95-2 0.070000 0.084610 -17.3`% Phosphorus Metal, Yellow or White 7723-14-0 2.65 3.58 -26.0% Polycyclic Organic Matter (Inc PAH, dioxins, etc. POM 0.300000 0.457200 -34.4% NC & AP 42 historic) Propionaldehyde 123-38-6 1.74 2.01 -13.4% Selenium Compounds SEC 0.190000 0.260220 -27.0% Styrene 100-42-5 0.110000 0.132200 -16.80/0 Tetrachloroethane, 1,1,2,2- 79-34-5 Not Not N/A Reported Reported Toluene 108-88-3 2.84 3.63 -21.8% Trichlorobenzene, 1,2,4- 120-82-1 0.000000 706.37 -100.0% Vinyl acetate 108-05-4 0.030000 0.040190 -25.4% Xylene 1330-20-7 94.20 14.51 549.2% 05/31/2005 Page 4 of 5 DAQ's Comments Reliardinj! Inventory 05/31/2005 Page 5 of 5 A Air Emission Inventory Summary 2004 Edenton Dyeing & Finishing LLC CRITERIA POLLUTANT EMISSIONS JPER TON BILLABLE TOTAL POLLUTANT Tons/ r) SOURCE ID#(s r B-1, B-2, B-3, AHS1, CHS1, TF-1, TF-2, PM �31 S�:86 20 TF-3, TF-4, D-1, D-2 PM-10 21.47 B-1, B-2, B-3, AHS1, CHS1, TF-1, TF-2, Z4.b TF-3, TF-4, D-1, D-2 PM-2.5 7.16 B-1, B-2, B-3, AHS1, CHS1, TF-1, TF-2, TF-3, TF-4, D-1, D-2 SOz 132.99 B-1, B-2, B-3, TF-1, TF-2, TF-3, TF-4, D-1, D-2 CO 14.66 B-1, B-2, B-3, TF-1, TF-2, TF-3, TF-4, D-1, D-2 NOx 26.78 B-1, B-2, B-3, TF-1, TF-2, TF-3, TF-4, D-1, D-2 B-1, B-2, B-3, TF-1, TF-2, TF-3, TF-4, D-1, VOC 5.09 D-2, DM1 -25, DC1 - DC3, RW-A, DR-1, MBO-1,WO-1,BR1 - BR4, JSTEAM-1, JEM- 1 Note: VOC Emissions listed above are inclusive of HAPs&TAPs listed below TOXIC POLLUTANT EMISSIONS TOTAL POLLUTANT CAS# SOURCE ID#(s) (Ibs/yr) ACETALDEHYDE 75-07-0 B-2 2.60 ACETIC ACID 64-19-7 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3 231.76 ACETOPHENONE 98-86-2 B-2 0.07 ACROLEIN 107-02-8 B-2 1.32 ACRYLAMIDE 79-06-1 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3 108.76 AMMONIA 7664-41-7 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3, 139.37 DM-1 - DM-25 ANTIMONY ANTIMONYCPDS B-1, B-2, B-3 1.55 ARSENIC ARSENICCPDS B-1, B-2, B-3 2.24 BENZENE 71-43-2 B-1, B-2, B-3 6.00 BENZYL CHLORIDE 100-44-7 B-2 3.20 BERYLLIUM BERYLCPDS B-1, B-2, B-3 0.10 BIPHENYL 92-52-4 B-2, TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, 692.61 DC-3, DM-1 - DM-25 BIS(2-ETHYLHEXYL)PHTHALATE 117-81-7 B-2 0.33 BROMINE 7726-95-6 B-2 506.83 BROMOFORM 75-25-2 B-2 0.18 CADMIUM CADMIUMCPDS B-1, B-2, B-3 0.34 CARBON DISULFIDE 75-15-0 B-2 0.59 2-CHLOROACETOPHENONE 532-27-4 B-2 0.03 CHLOROBENZENE 108-90-7 B-2 0.10 CHLOROFORM 67-66-3 B-2 0.27 CHROMIUM (VI) CHROM6CPDS B-1, B-2, B-3 0.43 COBALT COBALTCPDS B-1, B-2, B-3 2.14 CUMENE 98-82-8 B-2 0.02 CYANIDE CNC B-2 11.42 Page 7 of 29 Air Emission Inventory Summary- 2004 Edenton Dyeing & Finishing LLC TOXIC POLLUTANT EMISSIONS TOTAL POLLUTANT CAS# SOURCE ID#(s) (Ibs/yr) DIBENZOFURANS 132-64-9 B-2, TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, 135.25 DC-3, DM-1 - DM-25 DIMETHYL SULFATE 77-78-1 B-2 0.22 2,4-DINITROTOLUENE 51-28-5 B-2 0.001 1,4,-DIOXANE 123-91-1 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3 0.00 ETHYL BENZENE 100-41-4 B-1, B-2, B-3 0.45 ETHYL CHLORIDE 75-00-3 B-2 0.19 ETHLYENE DICHLORIDE 107-6-2 B-2 0.18 ETHYLENE DIBROMIDE 106-93-4 B-2 0.005 FLUORIDE 16984-48-8 NA NA FORMALDEHYDE 55-00-0 B-1, B-2, B-3, TF-1, TF-2, TF-3, TF-4, DC- 499 1, DC-2, DC-3, DM-1 - DM-25 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3, GLYCOL ETHERS GLYCOLETHER DM-1 -DM-25, RW-A, DR-1, MBO-1,WO- 723 1,BR1 -BR4, JSTEAM-1, JEW HEXANE 110-54-3 B-2 0.31 HYDROGEN CHLORIDE 7647-01-0 B-2 5479.20 HYDROGEN FLUORIDE 7664-39-3 B-2 684.90 ISOPHORONE 78-59-1 B-2 2.65 LEAD LEADCPDS B-1, B-2, B-3 2.34 MANGANESE MANGCPDS B-1, B-2, B-3 3.08 MERCURY MERCCPDS B-1, B-2, B-3 0.41 METHLENE CHLORIDE 75-09-2 B-2 1.32 METHYL BROMIDE 74-83-9 B-2 0.73 METHYL CHLORIDE 74-87-3 B-2 2.42 METHYL ETHYL KETONE 78-93-3 B-2 1.78 METHYL HYDRAZINE 60-34-4 B-2 0.78 METHYL METHACRYLATE 80-62-6 B-2 0.09 METHYL TERT-BUTYL ETHER 1634-04-4 B-2 0.16 MOLYBDENUM 7439-98-7 B-1, B-3 0.22 NAPHTHALENE 91-20-3 B-1, B-3, TF-1, TF-2, TF-3, TF-4, DM-1 - 108.36 DM-25, DC-1, DC-2, DC-3 NICKEL NICKCPDS B-1, B-2, B-3 24.97 PHENOL 108-95-2 B-2 0.07 PHOSPHOROUS 7723-14-0 B1, B-3 2.65 POM POM B-1, B-2, B-3 0.25 PROPIONALDEHYDE 123-38-6 B-2 1.74 SELENIUM SEC B-1, B-3 0.19 STYRENE 100-42-5 B-2 0.11 2,3,7,8-TCDD 1746-01-6 B-2 6.53E-08 TETRACHLOROETHYLENE 127-18-14 B-2 0.20 TOLUENE 108-88-3 B-1, B-2, B-3 2.83 1,2,4-TRICHLOROBENZENE 120-82-1 TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, DC-3, 0.00 DM-1 - DM-25 1,1,1-TRICHLOROETHANE 71-55-6 B-1, B-2, B-3 0.16 B-2, TF-1, TF-2, TF-3, TF-4, DC-1, DC-2, VINYL ACETATE 108-05-4 DC-3 0.03 Page 8 of 29 Air Emission Inventory Summary- 2004 Edenton Dyeing & Finishing LLC XYLENES 1330-20-7 - DM-25, DC-1, DC-2, DC-3 94.83 Page 9 of 29 (� Inventory Certification Form(Title V) l' Facility Name: Edenton Dyeing and Finishing,L APR 2 7 2005 J Facility ID : 2100051 125 Dye Plant Road Permit: 02621 Edenton,NC 27932 County : Chowan VIAP.n DAQ Region :WARO North Carolina Department of Environment and a al Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2004 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is Hugh Tindal This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition. 40 CFR Part 70.2 defines a responsible as meaning one of the following: 1.For a corporation: a president,secretary,treasurer, or vice—president of the corporation in charge of a principal business function,or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production, or operating facilities applying for a or subject to a permit and either i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars); or ii.the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship; a general partner or the proprietor,respectively; 3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA). ERTIFI STATEMENT: (Important: L 1 fficial.read and signi i n m l certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained in this air emissions report,including attached calculations and documentation, is true,accurate and complete. (Subject to legal enalities of up to $10,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: U40 110= M f A JC RO S Signature: This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: M f0 5 e @ 61 y e y `10 J . C.0 M Information on this Form cannot be held confidential 1 Air Emissions Inventory Data Input Sheet Fuel Usage Data for year 2004 Edenton Dyeing & Finishing LLC For each Source, input requested data in cells for amounts consumed (used) in calendar year. Boilers Fuel Oil #6 Hours of Source (ID#) (gallons) Operation % Sulfur Boiler#1 (B1) 168,233 6,672 2.1 0.6 Boiler#3 (B3) 112,156 6,672 2.1 0.4 280,389 Hours of Coal (Ibs) I Operation % Sulfur % Ash Boiler#2 (B2) 9,132,0001 6,672 1.0 5.44 Tenter Frames, Loop Dryer & Belt Dryer Total Propane used, all sources (gallons): 278,056 gallons 4.199 Total Propane used, all sources (Ibs): 1,167,557 Ibs 1167557 % of Total Propane Propane Used Used Propane Hours of Source (ID#) in Source (gallons) Used (Ibs) Operation Tenter Frame 5 (TF5) 53.1 147,699 620,187 6,672 Tenter Frame 4 (TF4) 5.4 15,132 63,541 6,672 Tenter Frame 3 (TF3) 40.3 111,995 470,267 6,672 0.0 1 0 0 0 Belt Dryer (D-2) 1.2 3,230 13,562 6,672 100.0 278,056 1,167,557 Page 1 of 29 Boiler#1 &3 Emissions RCE NO: B-1 &B-3 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC NO 6 FUEL OIL USAGE= 280,389 GAL HEAT VALUE: 147000 BTU/GAL HRS OF OPER. = 6672.00 HRS %SULFUR: 2.1 PERCENT RATED INPUT= 86.9 MM BTU/HR(Total Capacity of B1 &63) CRITERIA POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (Ib/1000 gal no.6 fuel oil) (1000 gal no.6 fuel oil) Ib/ r (lb/day) (lb/hr) (lb/15 min) NY) PM(7.59 x(1.12 x%sulfur+0.37)) 20.7 280.389 5,792.83 20.838 0.8682 0.217 2.90 PM-10(7.17 x(1.12 x%sulfur+0.37)) 19.5 280.389 5,472.28 19.684 0.8202 0.205 2.74 PM 2.5(4.67 x(1.12 x%sulfur+0.37)) 12.7 280.389 3,564.23 12.821 0.534 0.134 1.78 S02(157 x%SULFUR) 329.7 280.389 92,444.25 332.533 13.856 3.464 46.22 S03(2.0 x%SULFUR) 4.2 280.389 1177.63 4.236 0.177 0.044 0.59 CO 5 280.389 1401.95 5.043 0.210 0.053 0.70 NOx 55 280.389 15421.40 55.473 2.311 0.578 7.71 VOC non-methane) 0.28 280.389 78.51 0.282 0.012 0.003 0.04 Notes 1)Lb/yr=usage x emission factor 2)Lb/hr=(lb/yr)/hrs of oper. 3)Criteria pollutant emission factors from AP-42(factors used are for No.6 fuel oil)(09/98).PM emission factors from Table 1.3-5.POM factor from DENR F02000.xls calculations spreadsheet 4)Fuel oil amount is based on actual 2004 gallons 5)Heat content of fuel Oil#6 from Title V Draft Permit. Page 5 of 29 Boiler#1 &3 Emissions SOURCE NO: B-1 &B-3 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC HAZARDOUS/TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal) (1000 gal no.6 fuel oil) (lb/ r) 7 (Ib/da ) (Ib/hr) (lb/15 min) (tpy) ANTIMONY 5.25E-03 280.389 1.47 5.30E-03 2.21 E-04 5.52E-05 7.36E-04 ARSENIC 1.32E-03 280.389 0.37 1.33E-03 5.55E-05 1.39E-05 1.85E-04 BENZENE 2.14E-04 280.389 0.06 2.16E-04 8.99E-06 2.25E-06 3.00E-05 BERYLLIUM 2.78E-05 280.389 0.01 2.80E-05 1.17E-06 2.92E-07 3.90E-06 CADMIUM 3.98E-04 280.389 0.11 4.01E-04 1.67E-05 4.18E-06 5.58E-05 CHROMIUM(VI) 2.48E-04 280.389 0.07 2.50E-04 1.04E-05 2.61E-06 3.48E-05 COBALT 6.02E-03 280.389 1.69 6.07E-03 2.53E-04 6.32E-05 8.44E-04 ETHYLBENZENE 6.36E-05 280.389 0.02 6.41E-05 2.67E-06 6.68E-07 8.92E-06 FLUORIDE 3.73E-02 280.389 10.46 3.76E-02 1.57E-03 3.92E-04 5.23E-03 FORMALDEHYDE 3.30E-02 280.389 <% 9.25 3.33E-02 1.39E-03 3.47E-04 4.63E-03 LEAD 1.51 E-03 280.389 0.42 1.52E-03 6.35E-05 1.59E-05 2.12E-04 MANGANESE 3.00E-03 280.389 0.84 3.03E-03 1.26E-04 3.15E-05 4.21E-04 MERCURY 1.13E-04 280.389 0.03 1.14E-04 4.75E-06 1.19E-06 1.58E-05 NAPHTHALENE 1.13E-03 280.389 0.32 1.14E-03 4.75E-05 1.19E-05 1.58E-04 NICKEL 8.45E-02 280.389 23.69 8.52E-02 3.55E-03 8.88E-04 1.18E-02 PHOSPHOROUS 9.46E-03 280.389 2.65 9.54E-03 3.98E-04 9.94E-05 1.33E-03 POLYCYCLIC ORGANIC MATTER(POM) 4.04E-05 280.389 - 0.01 4.07E-05 1.70E-06 4.24E-07 5.66E-06 SELENIUM 6.83E-04 280.389 0.19 6.89E-04 2.87E-05 7.18E-06 9.58E-05 TOLUENE 6.20E-03 280.389 1.74 6.25E-03 2.61 E-04 6.51 E-05 8.69E-04 1,1,1-TRICHLOROETHANE 2.36E-04 280.389 0.07 2.38E-04 9.92E-06 2.48E-06 3.31E-05 XYLENE(as o-XYLENE) 1.09E-04 280.389 0.03 1.10E-04 4.58E-06 1.15E-06 1.53E-05 Notes: 1)Lb/yr=emission factor x usage 2)Toxic/HAP emission factors from AP-42(09/98) Page 6 of 29 iL r o n'11 Boiler#1 Emissions SOURC �B-1 " Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 NO 6 FUEL OIL USAGE= 168,233 GAL HEAT VALUE: 147000 BTU/GAL HRS OF OPER. = 6672.00 HRS %SULFUR: 2.1 PERCENT RATED INPUT= 33.4 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal no.6 fuel oil) (1000 gal no.6 fuel oil (lb/ r) T (lb/day) (lb/hr) (lb/15 min) (t PM (7.59 x(1.12 x%sulfur+0.37)) 20.7 168.233 3,475.70 12.503 0.5209 0.130 1.74 PM-10(7.17 x(1.12 x%sulfur+0.37)) 19.5 168.233 3,283.37 11.811 0.4921 0.123 1.64 PM 2.5(4.67 x(1.12 x%sulfur+0.37)) 12.7 168.233 2,138.54 7.693 0.321 0.080 1.07 S02(157 x%SULFUR) 329.7 168.233 55,466.55 199.520 8.313 2.078 27.73 S03(2.0 x%SULFUR) 4.2 168.233 706.58 2.542 0.106 0.026 0.35 CO 5 168.233 841.17 3.026 0.126 0.032 0.42 NOx 55 168.233 9252.84 33.284 1.387 0.347 4.63 VOC non-methane 0.28 168.233 47.11 0.169 0.007 0.002 0.02 Notes 1)Lb/yr=usage x emission factor 2)Lb/hr=(lb/yr)/hrs of oper. 3)Criteria pollutant emission factors from AP-42(factors used are for No.6 fuel oil)(09/98).PM emission factors from Table 1.3-5.POM factor from DENR F02000.xls calculations spreadsheet 4)Fuel oil amount is based on actual 2004 gallons with 1998 boiler operation scenario.(40%for Boiler#1) 5)Heat content of fuel Oil#6 from Title V Draft Permit. Page 11 of 29 L Boiler#1 Emissions SOURCE NO: B-1 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 HAZARDOUS/TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal) (1000 gal no.6 fuel oil) (lb/yr) (lb/day) (lb/hr) (lb/15 min (tp ) ANTIMONY 5.25E-03 168.233 0.88 3.18E-03 1.32E-04 3.31 E-05 4.42E-04 ARSENIC 1.32E-03 168.233 0.22 7.99E-04 3.33E-05 8.32E-06 1.11E-04 BENZENE 2.14E-04 168.233 0.04 1.30E-04 5.40E-06 1.35E-06 1.80E-05 BERYLLIUM 2.78E-05 168.233 0.00 1.68E-05 7.01E-07 1.75E-07 2.34E-06 CADMIUM 3.98E-04 168.233 0.07 2.41E-04 1.00E-05 2.51E-06 3.35E-05 CHROMIUM(VI) 2.48E-04 168.233 0.04 1.50E-04 6.25E-06 1.56E-06 2.09E-05 COBALT 6.02E-03 168.233 1.01 3.64E-03 1.52E-04 3.79E-05 5.06E-04 ETHYLBENZENE 6.36E-05 168.233 0.01 3.85E-05 1.60E-06 4.01 E-07 5.35E-06 FLUORIDE 3.73E-02 168.233 6.28 2.26E-02 9.41 E-04 2.35E-04 3.14E-03 FORMALDEHYDE 3.30E-02 168.233 )5.55 2.00E-02 8.32E-04 2.08E-04 2.78E-03 LEAD 1.51E-03 168.233 0.25 9.14E-04 3.81E-05 9.52E-06 1.27E-04 MANGANESE 3.00E-03 168.233 0.50 1.82E-03 7.56E-05 1.89E-05 2.52E-04 MERCURY 1.13E-04 168.233 0.02 6.84E-05 2.85E-06 7.12E-07 9.51 E-06 NAPHTHALENE 1.13E-03 168.233 0.19 6.84E-04 2.85E-05 7.12E-06 9.51 E-05 NICKEL 8.45E-02 168.233 14.22 5.11 E-02 2.13E-03 5.33E-04 7.11 E-03 PHOSPHOROUS 9.46E-03 168.233 1.59 5.72E-03 2.39E-04 5.96E-05 7.96E-04 POLYCYCLIC ORGANIC MATTER(POM) 4.04E-05 168.233 0.01 2.44E-05 1.02E-06 2.55E-07 3.40E-06 SELENIUM 6.83E-04 168.233 0.11 4.13E-04 1.72E-05 4.31E-06 5.75E-05 TOLUENE 6.20E-03 168.233 1.04 3.75E-03 1.56E-04 3.91 E-05 5.22E-04 1,1,1-TRICHLOROETHANE 2.36E-04 168.233 0.04 1.43E-04 5.95E-06 1.49E-06 1.99E-05 XYLENE(as o-XYLENE) 1.09E-04 168.233 0.02 6.60E-05 2.75E-06 6.87E-07 9.17E-06 Notes: 1)Lb/yr=emission factor x usage 2)Toxic/HAP emission factors from AP-42(09/98) Page 12 of 29 Boiler#3 Emissions SOURCE NO: B-3 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 NO 6 FUEL OIL USAGE= 112,156 GAL HEAT VALUE: 147000 BTU/GAL HRS OF OPER. = 6672.00 HRS %SULFUR: 2.1 PERCENT RATED INPUT= 53.5 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal no.6 fuel oil) (1000 gal no.6 fuel oil) (lb/ r) (lb/day) (lb/hr) (lb/15 min) (tp ) PM(7.59 x(1.12 x%sulfur+0.37)) 20.7 112.156 2317.13 8.335 0.347 0.087 1.16 PM-10(7.17 x(1.12 x%sulfur+0.37)) 19.5 112.156 2188.91 7.874 0.328 0.082 1.09 PM 2.5(4.67 x(1.12 x%sulfur+0.37)) 12.7 112.156 1425.69 5.128 0.214 0.053 0.71 S02(157 x%SULFUR) 329.7 112.156 36977.70 133.013 5.542 1.386 18.49 CO 5 112.156 560.78 2.017 0.084 0.021 0.28 NOx 55 112.156 6168.56 22.189 0.925 0.231 3.08 VOC(non-methane) 0.28 112.156 31.40 0.113 0.005 0.001 0.02 Notes: 1)Lb/yr=usage x emission factor 2)Lb/hr=(lb/yr)/hrs of oper. 3)Criteria pollutant emission factors from AP-42(factors used are for No.6 fuel oil)(09/98).PM emission factors from Table 1.3-5.POM factor from DENR F02000.xls calculations spreadsheet 4)Fuel oil amount is based on actual 2004 gallons with 1998 boiler operation scenario.(60%for Boiler#3) 5)Heat content of fuel Oil#6 from Title V Draft Permit. Page 15 of 29 Boiler#3 Emissions SOURCE NO: B-3 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 HAZARDOUS/TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/1000 gal) (1000 gal no.6 fuel oil) (Ib/ r) (Ib/da (Ib/hr) (Ib/15 min) (tp ) ANTIMONY 5.25E-03 112.156 0.59 2.12E-03 8.83E-05 2.21 E-05 2.94E-04 ARSENIC 1.32E-03 112.156 0.15 5.33E-04 2.22E-05 5.55E-06 7.40E-05 BENZENE 2.14E-04 112.156 0.02 8.63E-05 3.60E-06 8.99E-07 120E-05 BERYLLIUM 2.78E-05 112.156 0.00 1.12E-05 4.67E-07 1.17E-07 1.56E-06 CADMIUM 3.98E-04 112.156 0.04 1.61 E-04 6.69E-06 1.67E-06 2.23E-05 CHROMIUM(VI) 2.48E-04 112.156 0.03 1.00E-04 4.17E-06 1.04E-06 1.39E-05 COBALT 6.02E-03 112.156 0.68 2.43E-03 1.01 E-04 2.53E-05 3.38E-04 ETHYLBENZENE 6.36E-05 112.156 0.01 2.57E-05 1.07E-06 2.67E-07 3.57E-06 FLUORIDE 3.73E-02 112.156 4.18 1.50E-02 6.27E-04 1.57E-04 2.09E-03 FORMALDEHYDE 3.30E-02 112.156 1.33E-02 5.55E-04 1.39E-04 1.85E-03 LEAD 1.51 E-03 112.156 0.17 6.09E-04 2.54E-05 6.35E-06 8.47E-05 MANGANESE 3.00E-03 112.156 0.34 1.21 E-03 5.04E-05 1.26E-05 1.68E-04 MERCURY 1.13E-04 112.156 0.01 4.56E-05 1.90E-06 4.75E-07 6.34E-06 NAPHTHALENE 1.13E-03 112.156 0.13 4.56E-04 1.90E-05 4.75E-06 6.34E-05 NICKEL 8.45E-02 112.156 9.48 3.41E-02 1.42E-03 3.55E-04 4.74E-03 PHOSPHOROUS 9.46E-03 112.156 1.06 3.82E-03 1.59E-04 3.98E-05 5.30E-04 POLYCYCLIC ORGANIC MATTER(POM) 4.04E-05 112.156 U /30-. 0 1.63E-05 6.79E-07 1.70E-07 2.27E-06 SELENIUM 6.83E-04 112.156 0.08 2.76E-04 1.15E-05 2.87E-06 3.83E-05 TOLUENE 6.20E-03 112.156 0.70 2.50E-03 1.04E-04 2.61 E-05 3.48E-04 1,1,1-TRICHLOROETHANE 2.36E-04 112.156 0.03 9.52E-05 3.97E-06 9.92E-07 1.32E-05 XYLENE(as o-XYLENE) 1.09E-04 112.156 0.01 4.40E-05 1.83E-06 4.58E-07 6.11 E-06 Notes: 1)Lb/yr=emission factor x usage 2)Toxic/HAP emission factors from AP-42(09/98) Page 16 of 29 Boiler#2 Emissions SOURCE NO: B-2 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 MUTILCYCLONE CONTROLLED-TRAVELING GRATE BOILER HEAT VALUE: 13964 BTU/LB COAL USAGE= 9,132,000 LBS %SULFUR: 1.0 PERCENT HRS OF OPER.= 6,672 HRS %ASH: 5.44 PERCENT RATED INPUT= 42.3 MM BTU/HR PM CONTROL 78 PERCENT CRITERIA POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/ton coal tons coal Ib/ r Ib/hr t ��p` PM(9+0.04E-6 x heat value x 2000) 10.12 4566 46195 6.924 23.10 �jV1u1' PM-10(5+0.04E-6 x heat value x 2000) 6.12 4566 27931 4.186 13.97 Y0_e PM 2.5(0.06 x%ASH) 0.33 4566 1490.34 0.223 0.75 101 uop SOx (38 x%sulfur) 38 4566 173508 26.005 86.75 5 CO 6 4566 27396 4.106 13.70 NOx 7-5 4566 34245 5.133 17.12 VOC 1 0.06 4566 274 0.041 0.14 0 Note: Ib tJ" 1) PM,PM10,&PM 2.5 emission factors include multicyclone control and both filterable anddcc7yfndensible particulates as listed in AP-42(9/98) 2)Lb/yr=usage x emission factor 3)Lb/hr=(Ib/yr)/hrs of oper. � ;� W 4)Criteria pollutant emission factors from AP-42(9198). TOXIC POLLUTANTS EMISSIONS EMISSION ACTUAL ACTUAL b� FACTOR USAGE EMISSIONS POLLUTANT (lb/ton) tons coal Ib/ r Ib/hr t ACETALDEHYDE 5.70E-04 4566 2.60 3.90E-04 1.30E-03 ACETOPHENONE 1.50E-05 4566 0.07 1.03E-05 3.42E-05 ACROLEIN 2.90E-04 4566 1.32 1.98E-04 6.62E-04 ANTIMONY 1.80E-05 4566 0.08 1.23E-05 4.11E-05 ARSENIC 4.10E-04 4566 1.87 2.81 E-04 9.36E-04 BENZENE 1.30E-03 4566 5.94 8.90E-04 2.97E-03 BENZYL CHLORIDE 7.00E-04 4566 3.20 4.79E-04 1.60E-03 BERYLLIUM 2.10E-05 4566 0.10 1.44E-05 4.79E-05 BIPHENYL 1.70E-06 4566 0.01 1.16E-06 3.88E-06 BIS(2-ETHYLHEXYL)PHTHALATE(DEHP) 7.30E-05 4566 0.33 5.00E-05 1.67E-04 ROMtNE"- -__-- - t.1-tE-01 4566 `506,83 --7-:60E-02--_ 26 01 BROMOFORM 3.90E-05 4566 0.18 2.67E-05 8.90E-05 CADMIUM 5.10E-05 4566 0.23 3.49E-05 1.16E-04 CARBON DISULFIDE 1.30E-04 4566 0.59 8.90E-05 2.97E-04 2-CHLOROACETOPHENONE 7.00E-06 4566 0.03 4.79E-06 1.60E-05 CHLOROBENZENE 2.20E-05 4566 0.10 1.51E-05 5.02E-05 CHLOROFORM 5.90E-05 4566 0.27 4.04E-05 1.35E-04 CHROMIUM(VI) 7.90E-05 4566 0.36 5.41E-05 1.80E-04 COBALT 1.00E-04 4566 0.46 6.84E-05 2.28E-04 CUMENE •5.30E-06 4566 0.02 3.63E-06 1.21E-05 CYANIDE 2.50E-03 4566 11.42 1.71E-03 --6.74€-03 niBENZQFU­RANCS•------_- --- - ----2.UE07 -- -_-4b66 - 9.18E-04_..-1.38E-G7--- -- 5Q&&7 DIMETHYL SULFATE -4.80E-05 4566 0.22 3.28E-05 1.10E-04 2,4-DINITROTOLUENE 2.80E-07 4566 1.28E-03 1.92E-07 6.39E-07 ETHYL BENZENE 9.40E-05 4566 0.43 6.43E-05 2.15E-04 ETHYL CHLORIDE 4.20E-05 4566 0.19 2.87E-05 9.59E-05 ETHLYENE DICHLORIDE 4.00E-05 4566 0.18 2.74E-05 9.13E-05 ETHYLENE DIBROMIDE 1.20E-06 4566 5.48E-03 8.21E-07 2.74E-06 9132 O lb /a be�u a' �8�9 Page 13 of 29 s �' Boiler#2 Emissions SOURCE NO: B-2 Air Emission Inventory-Calendar Year 2004 Edenton Dyeing 8 Finishing LLC 0 EMISSION ACTUAL ACTUAL FACTOR USAGE EMISSIONS POLLUTANT (lb/ton) tons coal Ib/ r Ib/hr t FORMALDEHYDE 2.40E-04 4566 1.10 1.64E-04 5.48E-04 HEXANE 6.70E-05 4566 0.31 4.59E-05 1.53E-04 HYDROGEN CHLORIDE 1.20E+00 4566 5479.20 8.21E-01 2.74E+00 HYDROGEN FLUORIDE 1.50E-01 4566 684.90 1.03E-01 3.42E-01 ISOPHORONE 5.80E-04 4566 2.65 3.97E-04 1.32E-03 LEAD 430E=04 4566 .1.92 2.87E-04 9.59E-04 MA1`1GANESE_-__ 4.90E-04- 4566 2.2 - 3-.35E- 2 -03 MERCURY 8.30E-05 4566 0.38 5.6-8E-0 METHYLENE CHLORIDE 2.90E-04 4566 1.32 1.98E-04 6.62E-04 METHYL BROMIDE 1.60E-04 4566 0.73 1.09E-04 3.65E-04 METHYL CHLORIDE 5.30E-04 4566 2.42 3.63E-04 1.21E-03 METHYL ETHYL KETONE 3.90E-04 4566 1.78 2.67E-04 8.90E-04 METHYL HYDRAZINE 1.70E-04 4566 0.78 1.16E-04 3.88E-04 METHYL METHACRYLATE 2.00E-05 4566 0.09 1.37E-05 4.57E-05 METHYL TERT-BUTYL ETHER 3.50E-05 4566 0.16 2.40E-05 7.99E-05 NICKEL - -- 2.80E-04 4566 4.28 192E--04-- -839E-04 PHENOL 1.60E-05 4566 0.07 1.09E-05 3.65E-05 Flm- - 5.20E-05 - 4566 0.24 -3.56E-05 f-19E 04 PROPIONALDEHYDE 3.80E-04 4566 1.74 2.60E-04 8.68E-04 SELENIUM 1.30E-03 4566 5.94 8.90E-04 2.97E-03 STYRENE 2.50E-05 4566 0.11 1.71E-05 5.71E-05 2-,a 7;8-TCDD 1.43E-11 - 4566 6.53E-08 9-79E-12 - TETRACHLOROETHYLENE - 4.30E-05- - 4566 - - --- -2: TOLUENE 2.40E-04 4566 1.10 1.64E-04 5.48E-04 1,1,1-TRICHLOROETHANE 2.00E-05 4566 0.09 1.37E-05 4.57E-05 VINYL ACETATE 7.60E-06 4566 0.03 5.20E-06 1.74E-05 XYLENES 3.70E-05 4566 0.17 2.53E-05 8.45E-05 Note: 1)Lb/yr=emission factor x coal usage 2)Toxic/HAP emission factors from AP-42(09/98)for Controlled Coal Combustion,Table 1.1-13 and 1.1-18 unless noted. 3)'Emission factors from DEHNR Bituminuos Coal Combustion spreadsheet(Version 5-b-Ok by Tony Pendola;06/17/97) 3)Biphenyl emission factor given in AP-42=1.7E-06 lb/ton of coal consumed. 4)Where emission factor ranges were given in AP•42,an average of high and low factors was used for emissions. 6k�s Page 14 of 29 Coal &Ash Handling System Emissions Air Emission Inventory-Calendar Year 2004 Edenton Dyeing &Finishing LLC PARTICULATE MATTER Total Coal Emission Uncontrolled Control Device PM PM-10 PM-2.5 Throughput Factor PM Emissions Efficiency Emissions Emissions Emissions Source ID Source Description (tons/ r) (ton PM/ton coal) (tons/ r) (%) (tons/ r) tons/ r (tons/ r) AHS-1 Ash Handling System 4,566 0.0544 248.39 99.9% 0.25 0.15 0.01 CHS-1 Coal Handling System 4,566 0.0050 22.83 80% 4.57 4.57 4.57 CSILO-1 Coal Storage Silo Not In Operation Since 2002 Notes: 1)Control Device Efficiencies taken from Title V Application. 2)Particulate Emissions factors: Ash Handling System:PM Emissions factor=weight fraction of ash in the coal(0.0544,or 5.44%as listed on 1/12/01 coal analysis)The Ash Handling System consists of fly ash and bottom ash from coal consumed in the boiler. Coal Handling System:PM Emissions factor=estimated fugitive dust generated from coal handling(0.005 or 0.5%as listed in the Title V application) Coal Storage Silo did not operate in 2004. 3)PM Uncontrolled Emissions=coal throughput x emission factor 4)PM emissions=uncontrolled emissions x(1-control efficiency) 5)PM10 emissions from the Ash Handling System =PM emissions x(PM10 emission factor/PM emission factor) (PM 10 emission factor=6.12 lb/ton,PM emission factor=10.12 lb/ton) 6)PM2.5 emissions from the Ash Handling System=PM emissions x(PM2.5 emission factor/PM emission factor) (PM2.5 emisson factor=0.33 lb/ton) 7)All PM emissions from Coal Handling System assumed to be equivalent to PM 10 and PM 2.5 I Page 10 of 29 Tenter Frame#3-5 and Dryer Propanemissions Summary SOURCE ID #: TF-1-4, D-1, D-2 Air Emission Inventory-CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 (BTU/GAL) HOURS OPERATION: 6672 (BTU/GAL) LBS USED = 1,167,557 GALLONS USED: 278056 CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 278,056 111 0.400 0.017 0.004 0.056 PM-10 0.4 278,056 111 0.400 0.017 4.17E-03 0.056 PM-2.5 0.4 278,056 111 0.400 0.017 4.17E-03 0.056 S02 0.1 278,056 28 0.100 0.004 1.04E-03 0.014 CO 1.9 278,056 528 1.900 0.079 0.020 0.264 NOx 14 278,056 3,893 14.003 0.583 0.146 1.946 VOC 0.5 278,056 139 0.500 0.021 0.005 0.070 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Actual Propane from Total Facility 2004 Usage (lb to gal conversion=Gal/4.2 lb/gal) 3)Emission Factors from AP-42(10/96) All PM is assumed to be PM-2.5 and PM-10 4)Emission Factor for S02 is from Title V Permit. Page 17 of 29 Tenter Frame#5 Propane Emissions SOURCE ID#: TF-1 Air Emission Inventory-CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 6672 (BTU/GAL) LBS USED = 620,187 (53.1% OF TOTAL) GALLONS USED: 147699 RATED INPUT = 10.2 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r lb/ r Ib/da Ib/hr Ib/15 min t PM 0.4 147,699 59 0.213 0.009 0.002 0.030 PM-10 0.4 147,699 59 0.213 0.009 2.21 E-03 0.030 PM-2.5 0.4 147,699 59 0.213 0.009 2.21 E-03 0.030 S02 0.1 147,699 15 0.053 0.002 5.53E-04 0.007 CO 1.9 147,699 281 1.009 0.042 0.011 0.140 NOx 14 147,699 2,068 7.438 0.310 0.077 1.034 VOC 0.5 147,699 74 0.266 0.011 0.003 0.037 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation(from 1998 Air Inventory) 3)Actual Propane used scaled from Total Facility 2004 Usage(620,187 Ibs)based on percent production by all sources. (lb to gal conversion=Gal/4.2 lb/gal).Tenter Frame#5 53.1%of Total Propane. Emission Factors from AP-42(10/96) All PM is assumed to be PM-2.5 and PM-10 5)Emission Factor for S02 is from Title V Permit. Page 18 of 29 Tenter Frame #2 Propane Emissions SOURCE ID #: TF-2 Air Emission Inventory - CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 0 (BTU/GAL) LBS USED = 0 GALLONS USED: 0 RATED INPUT = 10.8 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 PM-10 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 PM-2.5 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 S02 0.1 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 CO 1.9 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 NOx 14 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 VOC 0.5 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation 3)Actual Propane used scaled from Total Facility 2002 Usage(620,187 Ibs)based on percent production by all sources. (lb to gal conversion=Gal/4.2 Ib/gal).Tenter Frame#2 0%of Total Propane. 4)Emission Factors from AP-42(10/96) 5)Emission Factor for S02 is from Title V Permit. Page 19 of 29 Tenter Frame#3 Propane Emissions SOURCE ID #: TF-3 Air Emission Inventory - CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 6672 (BTU/GAL) LBS USED = 470,267 (40.3% OF TOTAL) GALLONS USED: 111995 RATED INPUT = 12 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 111,995 45 0.161 0.007 0.002 0.022 PM-10 0.4 111 ,995 45 0.161 0.007 1.68E-03 0.022 PM-2.5 0.4 111 ,995 45 0.161 0.007 1.68E-03 0.022 S02 0.1 111,995 11 0.040 0.002 4.20E-04 0.006 CO 1.9 111,995 213 0.765 0.032 0.008 0.106 NOx 14 111,995 1,568 5.640 0.235 0.059 0.784 VOC 0.5 111 ,995 56 0.201 0.008 0.002 0.028 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation(from 1998 Air Inventory) 3)Actual Propane used scaled from Total Facility 2002 Usage(620,187 Ibs)based on percent production by all sources. (lb to gal conversion=Gal/4.2 lb/gal).Tenter Frame#3 40.3%of Total Propane. 4)Emission Factors from AP-42(10/96) 5)Emission Factor for S02 is from Title V Permit. Page 20 of 29 Tenter Frame#4 Propane Emissions SOURCE ID #: TF-4 Air Emission Inventory - CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 6672 (BTU/GAL) LBS USED = 63,541 (5.4% OF TOTAL) GALLONS USED: 15132 RATED INPUT = 15 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 15,132 6 0.022 0.001 0.000 0.003 PM-10 0.4 15,132 6 0.022 0.001 2.27E-04 0.003 PM-2.5 0.4 15,132 6 0.022 0.001 2.27E-04 0.003 S02 0.1 15,132 2 0.005 0.000 5.67E-05 0.001 CO 1.9 15,132 29 0.103 0.004 0.001 0.014 NOx 14 15,132 212 0.762 0.032 0.008 0.106 VOC 0.5 15,132 8 0.027 0.001 0.000 0.004 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation(from 1998 Air Inventory) 3)Actual Propane used scaled from Total Facility 2002 Usage(620,187 Ibs)based on 1998 percent production by all sources. (lb to gal conversion=Gal/4.2 Ib/gal).Tenter Frame#4 5.4%of Total Propane. 4)Emission Factors from AP-42(10/96) 5)Emission Factor for S02 is from Title V Permit. Page 21 of 29 Loop Dryer Propane Emissions SOURCE ID#: D-1 Air Emission Inventory-CY 2004 Edenton Dyeing & Finishing LLC PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 0 (BTU/GAL) LBS USED = 0 GALLONS USED: 0 RATED INPUT = 0 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 PM-10 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 PM-2.5 0.4 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 S02 0.1 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 CO 1.9 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 NOx 14 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 VOC 0.5 0 0 #DIV/0! #DIV/0! #DIV/0! 0.000 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation(from 1998 Air Inventory) 3)Actual Propane used scaled from Total Facility 2002 Usage(620,187 Ibs)based on percent production by all sources. (lb to gal conversion=Gal/4.2 lb/gal). Loop Dryer 0%of Total Propane. 4)Emission Factors from AP-42(10/96) 5)Emission Factor for S02 is from Title V Permit. Page 22 of 29 Belt Dryer Propane Emissions SOURCE ID #: D-2 Air Emission Inventory - CY 2004 Edenton Dyeing & Finishing LLC 0 PROPANE COMBUSTION HEAT VALUE 94,000 HOURS OPERATION: 6672 (BTU/GAL) LBS USED = 13,562 (1 .2% OF TOTAL) GALLONS USED: 3230 RATED INPUT = 6 MM BTU/HR CRITERIA POLLUTANTS EMISSIONS EMISSION ANNUAL FACTOR USAGE EMISSIONS POLLUTANT Ib/1000 al al/ r Ib/ r Ib/da Ib/hr Ib/15 min t PM 0.4 3,230 1 0.005 0.000 0.000 0.001 PM-10 0.4 3,230 1 0.005 0.000 4.84E-05 0.001 PM-2.5 0.4 3,230 1 0.005 0.000 4.84E-05 0.001 S02 0.1 3,230 0 0.001 0.000 1.21 E-05 0.0002 CO 1.9 3,230 6 0.022 0.001 0.000 0.003 NOx 14 3,230 45 0.163 0.007 0.002 0.023 VOC 0.5 3,230 2 0.006 0.000 0.000 0.001 NOTES: 1)Lb/yr=annual usage x emission factor/1000 2)Lb/hr=(lb/yr)/annual hrs of operation(from 1998 Air Inventory) 3)Actual Propane used scaled from Total Facility 2002 Usage(620,187 Ibs)based on percent production by all sources. (Ib to gal conversion=Gal/4.2 lb/gal). Belt Dryer 1.2%of Total Propane. 4)Emission Factors from AP-42(10/96) 5)Emission Factor for S02 is from Title V Permit. Page 23 of 29 Air Emissions Inventory Data Input Sheet Process Chemical Usage & Production Data for year 2004 Edenton Dyeing & Finishing LLC For each listed Product, enter Total Amount Used (Ibs) in cells. For each source listed below, enter Total Production (yds) in cells . VOC, HAP and TAP determination is required for each new Product. Process Chemicals Total Product Product Name Amount Used (Ibs) ACETIC ACID 56% 37,577 ACID RED GN 37 ALBATEX FFC 25 A-LUBE CP CONC. 200% 0 ANTIFREEZE 0 ASCOUR MWN 0 ASTRO BLACK GD 30 ASTRO BLUE 3G CON 0 ASTRO RED LF CONC 75 ASTRO TURQ HL 85 ASTRO YELLOW 2GD 80 ASTRO YELLOW HR 30 BLUE BAR-200% NYL 23 BLUE NAVY RLL 400% INTRAMET 0 BURCO WHITE WGS 108 BURCOFIX UPD 28,759 BURCOSCOUR LFE-810 9,030 FABRISET PCE 0 BURCOWET NFW 150% 5,135 CIBACET BROWN E2R 42 DIRECT BR PINK B 0 DIRECT SCARLET 4SWN 0 DIRECT TURQ GRLL 13 DYCLEAN 290-S 0 PERMAFRESH TGC 38,520 FX 259 0 GLOPAD WHITE CS 1,265 HIPOCHEM CARRIER 10-CD 24,750 HIPOCHEM CARRIER RPS 0 HIPOCHEM CP-OS 41,350 Page 2 of 29 HIPOCHEM SS-550 25,807 HYSTRETCH V-29 0 INMONT BLUE GL3W 01-8404 115 INMONT RED CM3W 01-8003 100 INMONT VIOLET V3W 0 1-8501 60 INT BLUE GFD 150% 343 INT BORDEAUX 3BSK 4,120 ISOPROPYL ALCOHOL 99% 0 LEVAFIX BROWN ERN 49 LEVELRITE AM-N 0 BURCO SOFT STP 46,082 MYKON 39 0 NUPEL CDF 1,150 NUSOFT E 0 NUTRABOND SP BPD 8,953 NUTRASET BH 3,119 NYL RED 213SA 25 NYLANTHRENE ORANGE SLF 36 INT ORANGE 2GR 125 PELATEX 0 TURQ. RP 50% 500 RESPAD YELLOW Y3W 01-8209 140 RUBINE CK-GFL 200% INTRASIL 359 SANDOPAN DTC-100-MM 0 SILTONE BV 0 SOL AQUA FAST RED 2131- 10 SUPERLITEFAST RED 313L 0 SUPERLITEFAST RUBINE WLKS 200 15 UNIDIVINE DIF 0 UVITEX RSB 2,400 YELLOW FLMS-NYL 65 Production Finishing Total Total Hours of Source (ID#) Production Operation (yds) Tenter Frame 3 TF3 5,362,952 2,680 40.3 Tenter Frame 4 TF4 724,629 362 5.4 Tenter Frame 5 TF5 7,072,658 3,088 53.1 13,314,898 Belt Dryer D-2 154,659 257 1.2 Steam Fired Dry (Tall) Can Range (DC-1) 514,085 285 41,486,949 Page 3 of 29 Preparation Total Source (ID#) Production Total Hours of Operation (yds) Mezzera Preparation Range (MBO-1) 1,942,235 647 Desize Preparation Range (DR-1) 6,303,315 1,616 Dyeing Total Source (ID#) Production Total Hours of Operation (yds) Atmospheric Dyeing (DM-1 - DM-25) 1,291,311 2,770 Total Production 2004 15,120,294 yds Page 4 of 29 Process Chemical Emissions Alr Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS DYEING FINISHING PREPARATION T YEAR 2000 Chemical Weight MAX. Total % Dyeing % Finishing %Product Preparation Product Name Usage(Ibs)Year 004(Ibs) Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Product Chemical Product Chemical Used in Chemical DM1- TF-1 Dyeing Number (%) ON SITE Usage(Ibs) Used in Usage Used In(Ibs) finishing Usage(Ibs) Preparation Usage(Ibs) DM25 LEVELRITE AM-N 0(GE)2-butoxyethanol X X X 111-76-2 8.10 41 0 100 0.0 0 0 SANDOPAN DTC-100-MM 0(GE)diethylene glycol monobutylether X X 11234.5 13.00 676 0 25 0.0 75 0.0 0 0 DYCLEAN 290-S 0(GE)Ethylenglycol MonobuNlether X X 111-76-2 96.60 966 0 100 0.0 0 0 BURCOSCOUR LFE-810 9,030 GE Glycol Ether X X NA 8,00 400 722.4 40 289.0 60 433.4 14 192 HIPOCHEM CARRIER RPS 0 1 2 3-trichlorobenzene X 87-61-6 15.55 778 0,00 100 0.0 0 0 HIPOCHEM CARRIER RPS 0 1 2 4-tdchlorobenzene X X 120-82-1 59.00 2950 0.00 100 0.0 0 0 HIPOCHEM CARRIER RPS 0 1 2 4-trimeth(benzene X 95-63-6 0.15 8 0.00 100 0.0 0 0 HIPOCHEM CARRIER RPS 0 1 2-dichlorobenzene X 95-50-1 20.00 1000 0.00 100 0.0 0 0 BURCOSOFT STP 0 1 4-Dioxane X X I X 1 123-91-1 0 101 8 01 100 0.0 1 0 0 ALBATEX FFC 25 2-ethyl hexanol X 104-76-7 20.00 100 5 100 5.0 01 1 MIGRATONE 46.082 Acetic Acid X X 64-19-7 2.00 100 921.64 100 921.6 NUPEL CDF 1.150 Acetic Acid X X 64-19-7 95.00 4750 1092.5 100 1092.5 ACETIC ACID 56% 37,577 acetic acid X X 64-19-7 56.00 29680 21043.12 100 21043.1 NUSOFT E 0 Acetic Acid X X 64-19-7 100.00 5000 0 100 0.0 0 0 NUTRABOND SP BPD 8,953 acrylamide X X 79-06-1 1.00 50 89.53 100 89.5 0 25 NUTRASET BH 3119 acrylamide X X 79-06-1 1.00 50 31A9 100 31.2 0 9 BURCOSCOUR LFE-810 9030 Alcohol X I NA 8.00 400 722.4 40 289.0 1 60 433.4 14 192 INMONT VIOLET V3W 01-8501 60 Amino Methyl Propanol X 124-68-5 1 0.6 100 0.6 0.0 0 INMONT BLUE GL3W 01-8404 115 Aminomethyl propanol X 124-68-5 1 1,15 100 1.2 0A 0 INMONT RED CM3W 01-8003 100 Aminomethyl propanol X 124-68-5 1 1 100 1.0 0.1 0 ASTRO BLACK GD 30 Ammonia X 7664-41-7 1.2 0.36 100 0A 0.02 0 ASTRO BLUE 3G CON 0 Ammonia X 766441-7 1 0 100 0.0 0.00 0 ASTRO RED LF CONC 75 Ammonia X 766441-7 1.2 0.9 100 0.9 0.05 0 ASTRO TURQ HL 85 Ammonia X 7664-41-7 1.2 1.02 100 1.0 0.05 0 ASTRO YELLOW 2GD 80 Ammonia X 7664-41-7 1.2 0.96 100 1.0 0.05 0 ASTRO YELLOW HR 30 Ammonia X 7664-41-7 1.2 0.36 100 0.4 0.02 0 GLOPAD WHITE CS 1,265 Ammonia X 766441-7 0.40 4 5.06 100 5A 0.00 1 HIPOCHEM CP-OS 41,350 Ammonia X 7664-41-7 0.30 4 124.05 50 62.0 50 62.0 3.10 33 INMONT VIOLET V3W 01-8501 60 Ammonia X 7664.41-7 1 0.6 100 0.6 .0.03 0 INMONT BLUE GL3W 01-8404 115 Ammonia Hydroxide X 1336-21-6 3 3.45 100 3.5 0.17 1 INMONT RED CM3W 01-8003 100 Ammonia Hydroxide X 1336-21-6 3 3 100 3.0 0.15 1 UNIDIVINE DIF 0 Benzyi benzoate X 1 1 120-51-4 30.001 660 0 100 0.0 0.00 0 HIPOCHEM CARRIER 10-CD 24,750 biphenyl X X 92-52-4 20.00 1000 4950.00 100 4950.0 34.60 164 HIPOCHEM CARRIER RPS 0 biphenyl X X 92-52-4 15.00 750 0 100 0.0 0.00 0 INT BLUE GFD 150% 343 Blended Mineral Oil X NA 0 100 0.0 0 0 INTRASIL BORDEAUX 3 BSK 4,120 Blended Mineral Oil X NA 0 100 0.0 0 0 ORANGE 2 RA INTRA 125 Blended Mineral Oil X NA 0 100 0.0 0 0 BLUE NAVY RLL 400%INTRAMET 0 Blended Mineral Oil X Proprietary 100 0.0 0 0 DIRECT BR PINK B 0 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 NYLANTHRENE ORANGE SLF 9 Blended Mineral Oil X Proprietary 100 0.0 0 0 SOL AQUA FAST RED 2BL 10 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 YELLOW FLMS-NYL 65 Blended Mineral Oil X Proprietary 0 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 24,750 dibenzofuran X X 132-64-9 6.00 300 1485.00 100 135.1 7 36 CIBACET BROWN E2R 42 4iethylene glycol X 11146-6 12 5.04 100 5.0 0 1 GLOPAD WHITE CS 1,265 diethylene glycol X 11146-6 9.00 90 113.85 100 113.9 0 32 PERMAFRESH TGC 38,520 diethylene glycol X 111-46-6 1.50 900 577.8 100 577.8 0 163 REMAZOL TURQ RP 50%LIQ 500 Diethylene glycol X 111-46-6 10 50 100 50.0 3 13 ANTIFREEZE 0 diethylene glycol X 111-76-2 70.00 420 0 Nota rd UVITEX RSB 2,400 diiso ro anolamine X 110-97-4 0.50 5 12 25 3.0 1 75 9.0 1 0 3 UNIDIVINE DIF 0 Dipropylene Glycol X 110-98-2 30.00 660 0 100 0.0 0 0 NUPEL CDF 1,150 Dipropylene GI col-Monometh I Ether X 1 34590-94-8 95.001 4750 1092.5 100 1092.5 0 308 FX 259 0 Ethylene Glycol X X 107-21-1 0.50 5 0 100 0.0 0 0 HIPOCHEM CP-OS 41,350 Ethylene Glycol X X 107-21-1 3,00 41 1240.5 50 6203. 50 620.3 31 330 BURCOFIX UPD 28,759 Formaldehyde X X X 50-00-0 1.00 75 287.59 100 287.6 0 81 FABRISET REACTANT PCE 38.520 Formaldehyde X X X 50-00-0 0.01 0 3.852 100 3.9 0 1 HYSTRETCH V-29 0 Formaldehyde X X X 50-00-0 0.10 1 0 100 0.0 0 0 INMONT BLUE G1-3W 01-8404 115 Formaldehyde X X X 50-00-0 0.5 0.575 100 0.6 0.03 0 INMONT RED CM3W 01-8003 100 Formaldehyde X X X 50-00-0 0.5 0.5 100 0.5 0.03 0 MYKON 39 0 Formaldehyde X X X 50-00-0 0.03 0 0 100 0.0 0 0 PERMAFRESH TGC 38,520 formaldehyde X X X 50-00-0 0.50 300 192.6 100 192.6 0 54 INMONT VIOLET V3W 01-8501 60 Formalde de X X X 50-00-0 0.5 0.3 100 0.3 0.02 0 Page 24 of 29 N J Z J O a U _ O N W=U O N M N_ W f K w a N > LU K N 0)H W}U O O O O O N N O N O O N O m < W K> 0 ~LL❑o Q O ❑ ❑ 3 v o ao IrWm3 m N f o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0........ ...... 0 0 0 0 0 0 0 M N U a' O � N a Z O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O Q N U U It O ❑ O O O N O 0 0 0 0'- O O O N O 0 0 0 0 0 0 0 0 0'O O O O �O O O O O O O O O Q �O O N O O O O N O O O O O O O O W U U 0 NN o 0 o Q o 0 0 0 0 0 0 0 o Q o 0 0 0 0 0 0 0 0 0.0 0 0 o Q o 0 0 0 0 0 0 0 0 0 M o 0 o m o m N o 0 0 0 0 o > ❑ 3 m J O W Z d m m ❑ W q N > 0 0 0 0 0 0 0 0 0 0 y o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0... ... 0...... 0 0 0 N p O 2 f a w O Q In o 0 o a o 0 0 0 0 o g Q o 0 0 0 0 0 0 0 o N N o..0 N w LL N N S � U N 000, Fu LL O WN O o o 0 0 0 0 0 0 0 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O U 0 0 0 0 0 0 0 0 0 0 0 0 0 N w ~ y Process Chemical Emissions Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS DYEING FINISHING PREPARATION T YEAR 2000 Chemical Weight MAX. Total % Dyeing % Finishing %Product Preparation Year 2004 Product Chemical Product DM1- Product Name Usage(Ibs) Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Used in Usage Used in Chemical Used in Chemical DM25 TF-1 Number (%) ON SITE Usage(Ibs) Dyeing (Ibs) Finishing Usage(Ibs) Preparation Usage(Ibs) BURCOSCOUR LFE-810 9,030 Hydrocarbon X NA 8.00 400 722A 40 289.0 60 433.4 14 192 BURCO WHITE WGS 108 lsopropanol X 67-63-0 16.50 144 17.82 60 10.7 40 7.1 1 5 BURCOWETNFW 150% 5,135 lsopropanol X 67-63-0 16.50 284 847.275 100 847.3 42 225 ISOPROPYL ALCOHOL 99% 0 isopropyl alcohol X 67-63-0 100.00 5000 0 100 0.0 0 0 LEVELRITE AM-N 0 isopropyl alcohol X 67-63-0 5.00 25 0 100 0.0 0 0 SANDOPAN DTC-100-MM 0 isopropyl alcohol X 67-63-0 7.00 364 0 25 0.0 75 0.0 0 0 SILTONE BV 0 isopropyi alcohol X 67-63-0 1.00 300 0 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 24,750 methyl benzoate X 93-58-3 6.88 344 1702.80 100 155.0 8 41 HIPOCHEM CARRIER 10-CD 24,750 methyl naphthalenes X NA 32.00 1600 7920.00 100 720.7 1 36 192 HIPOCHEM CARRIER 10-CD 24,750 meth I- toluate X 99-75-2 29.00 1450 7177.50 100 653.2 33 174 LEVAFIX BROWN ERN 49 Mineral Oil X 8042-47-5 3 1.47 100 1.5 0 0 RUBINE CK-GFL 200%INTRASIL 359 Mineral oil blend X Proprietary 1.40 5.026 100 5.0 0 1 ALBATEX FFC 25 monoethanolamine X 141-43-5 0.80 4 0.2 too 0.2 0 0 HIPOCHEM CARRIER RPS 0 naphtha solvent X 64742-94-5 1.90 95 0.00 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 24,750 naphthalene X X 91-20-3 4.22 211 1044.45 100 95.0 5 25 HIPOCHEM CARRIER RPS 0 naphthalene X X 91-20-3 0.40 20 0.00 100 0.0 0 0 HIPOCHEM SS-550 25807 Naphthalene X X 91-20-3 0.05 4 12.9035 100 1 12.9 1 1 1 3 INMONT BLUE GL3W 01-8404 115 n-Butyl Alcohol X 71-36-3 5 5.75 100 5.8 0 2 INMONT VIOLET V3W 01-8501 60 n-Butyl Alcohol X 71-36-3 5 3 100 3.0 0 1 INMONT RED CM3W 01-8003 100 n-But Alcohol X 71-36-3 5 5 100 5.0 0 1 Page 25 of 29 CHEMICAL EMISSIONS BY SOURCE 2004 TOTAL VOC EMISSIONS (ENTER FRAMES DRYERS DRY CAN TOTAL TENTER JSTEAM-1,DR- DYEING FRAMES/ EMISSIONS PREPARATION (LBS)PER TF-2 TF-3 TF-4 LOOP D-1 BELT D-2 DC-1 DC-2 DC-3 1,JEM-1,BR-1, DRYERS/ CHEMICAL MBO.1,RW-1, DRY CANS WO-1 0 215 204 0 4 72 0 01 22 14 1 687 22 723 0 5 5 0 0 1 0 0 0 0 252 239 0 4 85 0 0 0 0 0 0 0 0 0 0 0 0 43 822 0 865 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 46 44 01 1 151 0 0 0 8 147 0 155 0 214 203 0 4 72 0 01 0 36 1 685 0 721 0 194 184 0 3 65 0 0 0 33 621 0 654 0 0 0 0 0 0 0 0 0 032 6.18 0 7 0 1 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.00 0.00 0 0 0 28 27 0 0 10 0 0 0 0 0 0 0 0 0 0 0 0 5 103 0 108 0 4 4 0 0 1 0 0 0 0 2 2 0 0 1 0 0 0 0 1 1 0 0 0 0 0 0 1 13 0 14 01 1 0 0 1 0 0 0 Page 28 of 29 Process Chemical Emissions Air Emission Inventory-Calendar Year 2004 Edenton Dyeing&Finishing LLC 0 TOTAL CHEMICAL USAGE BY PROCESS DYEING I DYEING FINISHING PREPARATION 7 YEAR 2000 Chemical Weight MAX. Total % Dyeing % Finishing %Product Preparation Year 2004 Product Chemical Product DMt- Product Name Usage(Ibs) Chemical Ingredient VOC HAP TAP Abstract Percent CHEMICAL Chemical Used in Usage Used in Chemical Used t Chemical DM25 TF•1 Number (%) ON SITE Usage(Ibs) Dyeing (Ibs( Finishing Usage(Ibs) Preparation Usage(Ibs) it RS.1 INMONT BLUE GL3W 01-8404 115 Petroleum Distillate X 64742-95-6 10 11.5 100 11.5 0.58 3 INMONT VIOLET V3W 01-8501 60 Petroleum Distillate X 64742-95-6 6 3.6 100 3.6 0.18 1 A-LUBE CP CONC.200% 0 petroleum distillates X 64741-88-4 100.00 500 0 100 0.0 0.00 0 RESPAD YELLOW Y3W 01-8209 140 Petroleum distillates X 64742-94-5 6 8.4 too 8.4 0.42 2 HIPOCHEM CARRIER RPS 0 petroleum distillates X 64742-95-6 3.00 150 0.00 100 0.0 0.00 0 ASCOUR MWN 0 petroleum distillates X 8032-32-4 80.00 4000 0 60 0.0 40 0.0 0.00 0 HIPOCHEM CARRIER 10-CD 24,750 quinoline X X 91-22-5 7.00 350 1732.50 100 157.7 8 42 MYKON 39 0 Vinyl Acetate X X 108.054 0.13 2 0 100 0.0 0 0 ACID RED GN 37 White mineral oil X 0042-47-5 1 5 0.37 100 0.4 0 0 BLUE BAR-200%NYL 23 White mineral oil X 804247-5 1 5 0.23 100 0.2 0 0 DIRECT SCARLET 4SW N 0 White mineral oil X 804247-5 1 10 0 100 0.0 0 0 DIRECT TURQ GRILL 13 While mineral oil X 804247-5 1 5 0.13 100 0.1 0 0 NYL RED 2BSA 25 White mineral oil X 804247-5 1.20 0.3 100 0.3 0 0 SUPERLITEFAST RED 3BL 0 White mineral oil X 804247-5 1 0 100 0.0 0 0 SUPERLITEFAST RUBINE WLKS 200 15 White mineral oil X 804247-5 1 0.15 100 0.2 0 0 YELLOW FLMS-NYL 65 White mineral oil X I I 1 804247-5 1 1 1 0.65 100 1 0.7 0 0 NUPEL CDF 1,150 Xylene X X X 1330-20.7 5.00 250 57.5 100 57.5 0 16 PELATEX 0 xylene X X X 1330-20-7 5.00 250 0 100 0.0 0 0 HIPOCHEM CARRIER 10-CD 24.750 X ene o-x lene X X X 95-47-6 1.90 95 470.25 100 42.8 2 11 TOTAL VOC'S BY SOURCE 0.0 900425.8 920613.8 256 2567 Notes 1)Product Usage was provided by Piece Dye 11)Since max wt.%data was used from MSDS for each chain 2)Told Chemical Usage By Process is be%each product is used in Dyeing,Finishing,and/or Preparation as given by Piece Dye. Adjustments were made in the following products to ensw 3)Title V application slates that for VOC/HAP7TAP originating at Dyeing,%5 is emitted at the process.85%is emitted al the Tenter Frame with the other 10%emitted at the Steam Cans for a lotal of 100%emitted. -HIPOCHEM Carrier I0-CD-methyl benzoate adjusted fi Title V application star that for VOC/HAPlTAP originating at the Tenter Frames,90%is emitted is emitted at the Frames.The other 10%is assumed through process knowledge to be emitted to the W W TP. -HIPOCHEM Carder RPS-1,2,3,Uchbrobenzene adjus 5)Title V application states that for VOC/HAP/TAP originating in the Preparation Process,5%is emitted at the processes.85%Is emitted at the Tenter Frames and 10%is emitted at the Steam Cans. -Permafresh Toe-diethylene glycol adjusted from 9%w 6)Formula for calculating Chemical Emissions for the Dyeing Process:Dyeing Chemical Emissions=Dyeing Chemical Usage(lbs)x 0.05(See Notes 1&3) 12)Process air emissions of 1,2,44bichbroben-and biphei 7)Finishing Process Chemical Emissions Calculations remain on the cloth and are emitted at the tenter frames.T a)Tenter Frames&Dryers'.Calculations for each Tenter Frame and Dryer isbased an the total year 2002 production for all Tenter Frames and Dryers.A percentage of production ism calculated for each frae: and 0,037%of biphenyl is emitted to air(per SIMMS mx (eg:%Production TF-1=Actual production for Tenter Frame 1 divided by the Sum of Production for ail Tenter Frames+Dryers)TF-1=31.3%,TF-2=0%,TF-3=35o%,TF4=33.2%,D-1 is 0%,D-2=0.6% 13)Assume 3.1%of VOC's from Ascour MW N Is emitted at dy -To Include my chemicals added at Dyeing and/or Preparation(Sea Notes 1,3&5),emissions are calculated by (Mfg stales that 1%remains on cloth and s subsequently Tenter Frame/Dryer Emissions=Tenter Frame for Dryer)Production%x I(Dyeing Chemical Usage x 0,85)+(Preparation Chemical Usage x 0.85)+Finishing Chemical Usage x 0.9)) tabulates%emitted at W W TP to be 2.0%.Total Air En b)Dry Cars DC-2 and DC-3 not operated in 2002,and to include eery emissions from chemicals added at Dyeing or Preparation,emissions are calculated by 14)Process air emissions for all components of Hipochem RP: Dry(Stearn)Can Emission(DC-1)_[(Dyeing Chemical Usage x 0.1)+(Preparation Chemical Usage x 0.1)I (Sea Notes 1,3&5) amounts discharged WW W TP and amounts emitted from 8)Formula for calculating Chamkd Emissions for the Preparation Process:Preparation Chemical Emissions=Preparation Chemical Usage(Ibs)x 0,05(See Note 5) -Total Dye Chemical Usage(Hipochem RPS Components 9)Acetic Acid air emission calculations:Acetic Acid is used In the Finishing Process.as+%is discharged through the W W TP.Air emissions are based on the Told Yards Produced that are Bleached,and the (Total Arc Emissions for Hp-h-RPS for 1,2,4-TCB/T weight of fabric per yard.Data from the 1998 Air Inventory slate that 30%of production is Bleached,and that each yard Bleached weighs 0.5 lbs and has 5.51 E-05 lbs of Acetic Acid that is emitted to the dr. -Total Dye Chemical Usage(Hipochem 10-CD Componen Acetic Acid Air Emission(bs)=Production(in yards)x 30%Bleached x 0.5111astyad x 5.51 E-05 Ibs Acetic Acid per pound of fabric. (Total Air Emissions for Biphenyl for Hipochem 10-CD/T The Told Acetic Acid emissions are divided between each Tenter Frame based on the%production of each(See Note 7a aboye). -AN air emissions used for calculations were taken from Ye 10)Assume Preparation source emissions are divided equally among all equipment operating during yea 2004 in this Source(OR-1,BR-1,&MB0.1). 15)Told 2002-at.acid emissions adjusted for amount disc( Page 26 of 29 CHEMICAL EMISSIONS BY SOURCE 2004 TOTAL VOC EMISSIONS (ENTER FRAMES DRYERS DRY CANS TOTAL TENTER EMISSIONS JSTEAM-1,DR- DYEING FRAMES/ PREPARATION (LBS)PER TF-2 TF-3 TF-4 LOOP D-1 BELT D-2 DC-1 DC-2 DC-3 1,JEM-1,BR-1, DRYERS/ CHEMICAL III RW-1, DRY CANS WO-1 0 3 3 0 0 1 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 118 22 0 24 0 2 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 47 44 0 1 16 0 0 0 8 150 0 158 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.09 1.74 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O 0 0 0 0 0 0 18 17 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 92 0 95 0 13 12 0 0 4 0 0 O 01 28711 27231 01 491 7041 01 0 96 256 9144 96 9636 oncal,therelme the mid chemical M,%in some cases exceeds 100%. ure VOCs were not over repsted: firm 20%wt to 8.88 wt.% fisted from 20%wt to 15.55 wt% M to 1.5%wl. aryl were adjusted per mfg informal Hipochem stales only 20%of 1.2.4-TCB and 17.5%of biphenyl The rernei 1,2,4-tab and bphenyl go to waste treatrnent when,4.757%of 1,2.4-Icb is invited to nodeln7) tying.finishing,pmparabon,and W W TP.The remanng mount is treated at the W W TR y emitted.TANKS 4.0 indicates that 0.00233%will be emitted in Dyeing.SIMS Model for Title V lions=%hom Dyeing+%hom WWiP+%from Cloth subsequently emif al=3.1% xS and Hpochem 10-CD(except BphenN and 1,2,4-TCB-Sea Note 13)were adjusted to account for n what remains on the cloth. 's)=Year 2002 Maid-x Weight%x Percent Used in Dyeing x Total 1,2,4-TCB Usage)=18.3% cis)=Yes 2000 Mawnum x Weight%x Percent Used in Dyeing x Told Biphenyl Usage tar Hiopchem 10-CD)=9.1% es 2002 Form R data Xaaged through W W TR As Emissions(b/ys)=Total Emissions x 90%(emted to s) Page 29 of 29