Loading...
HomeMy WebLinkAboutAQ_F_0800102_20090629_EI_Fac-EI-Rpt Facility Total CY 2008 Emission Summary Recorded in ED Facility ID #: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit #(s): 08849T03 Green House Gases Pollutants (GHG) Actual Emissions Tons/l'r '%o Difference Pollutant CAS Not Not N/A Reported Reported CO2 equivalent (sum of individual GHG pollutant emission times their No GHGs 1995 IPCC Global Warming Potential (GWP), converted to metric tons) Reported Criteria Pollutants Actual Emissions % Difference (Tons/Yea r) Pollutant CAS CY 2008 CY 2007 from ED from Fees CO Co 63.99 95.04 -32.71% NOx Nox 18.33 61.86 -70.4`%, PM(TSP) TSP 2.87 4.16 -31.0'%, PM10 PMIO 2.87 4.16 -31.0'%, PM2.5 PM2.5 2.87 3.86 -25.7% S02 sot 3.12 6.70 -53.4% VOC VOC 14.86 12.52 18.7% Hazardous Air Pollutants (HAPs) Actual Emissions % Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2008 CY 2007 from ED from Fees Total Reduced Sulfur(TRS) 1,651.11 1,074.75 53.6% Hydrogen sulfide 7783-U6-4 1,502.35 977.92 53.6% Methyl mercaptan 74-93-1 148.76 96.83 53.6% Mercury & Compounds - all total mass includes Hg Vapor 0.050000 0.045070 10.9% Mercury, vapor (Component of HGC) 7439-97-6 0.050000 0.045070 10.9°/o Manganese & compounds 101.00 101.00 0.0% Manganese Unlisted Compounds-Specify MNC-Other 101.00 101.00 0.0% Compound(Component of MNC) 07/23/2009 Pagel of 3 Facility Total CY 2008 Emission Summary Recorded in ED Facility ID M 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T03 Hazardous Air Pollutants (HAPs) Actual Emissions °/, Difference and/or Toxic Air Pollutants (TAPs) (Pounds/Year) Pollutant CAS CY 2008 CY 2007 from ED from Fees Acetaldehyde 75-07-0 2.40 16.00 -85.0% Acrolein 107-02-8 0.300000 1.90 -84.2% Acrylonitrile 107-13-1 0.032000 0.020410 56.8% Benzene 71-43-2 9.09 24.14 -62.3% 13utadiene, 1,3- 106-99-0 0.100000 0.800000 -87.5% Carbon disulfide 75-15-0 0.028000 0.017570 59.4%, Carbon tetrachloride 56-23-5 5.99 3.90 53.4% Carbonyl sulfide 463-58-1 35.65 22.65 57.4%, CFC-12 (Dichlorodifluoromethane) 75-71-8 398.04 259.10 53.6% Chlorobenzene 108-90-7 0.028000 0.018200 53.8% Chloroform 67-66 0.045000 0.028950 .5.5.4% Dichlorobenzene(p), 1,4- 106-46-7 0.053000 0.033930 56.2% Dichlorofluoromethane 75-43-4 334.85 217.96 53.6% Ethyl benzene 100-41-4 0.039000 0.024500 59.2% Ethyl chloride (chloroethane) 75-00-3 0.016000 0.010430 :53.4`%, Ethyl mercaptan 75-08-1 175.91 114.50 53.6`%, Ethylene dichloride (1,2-dichloroethane) 107-06-2 0.037000 0.024000 54.2`%, Ethylidene dichloride (1,1-dichloroethane) 75-34-3 4.15 2.70 53.6`%, Formaldehyde 50-00-0 3.60 24.60 -8-;.4`%, HCFC-22 (Chlorodifluoromethane) 75-45-6 3.20 2.51 27.5`%, Hexane, n- 110-54-3 10.99 6.98 57.4°/, MEK (methyl ethyl ketone, 2-butanone) 78-93-3 225.64 143.36 57.4`%, Methyl chloride (chloromethane) 74-87-3 0.006000 0.004080 N/A Methyl chloroform 71-55-6 0.049000 0.032350 -51.-'%, 07/23/2009 Page 2 of 3 Facility Total CY 2008 Emission Summary Recorded in ED Facility ID #: 0800102 Facility Name: Eastern Carolina Regional Solid Waste Landfill Permit#(s): 08849T03 Ilazardous Air Pollutants (HAPs) Actual Emissions '%, Difference and/or Toxic Air Pollutants (TAPS) (Pounds/Year) Pollutant CAS CY 2008 CY 2007 from ED from Fees Methylene chloride 75-09-2 0.010600 0.006870 54.3% MIBK (methyl isobutyl ketone) 108-10-1 0.024000 0.015410 55.7% Perchloroethylene (tetrachloroethylene) 127-18-4 6.81 4.43 53.6% Polycyclic Organic Matter(Inc PAH, dioxins, etc. POM 74.10 500.90 -85.2'%o NC & AP 42 historic) Propylene dichloride (1,2-dichloropropane) 78-87-5 0.042000 0.027400 53.3'Yo TCE (trichloroethylene) 79-01-6 0.033000 0.021240 55.4% Tetrachloroethane, 1,1,2,2- 79-34-5 0.042000 0.027130 54.80/o Toluene 108-88-3 10.27 14.20 -27.7% Vinyl chloride 75-01-4 30.91 20.12 53.6% Vinylidene chloride 75-35-4 0.024000 0.015670 53.20/o Xylene (mixed isomers) 1330-20-7 4.98 8.49 -41.4% Largest Individual HAP Manganese Unlisted Compounds - 101.001bs Specify Compound (Component of Total HAP Emissions MNQ 300.90 lbs DAQ's Comments RejjardinI4 Inventory 07/23/2009 Page 3 of 3 V,JWN C [� � �r � � � CEC CARLSON ENVIRONMENTAL CONSULT 2 9 2jv O LanAfi//Gas.Air PrrnimnR,and Rrpi4Mry Corny/unm Srrvues �79 WARO �ov TITLE V ANNUAL AIR EMISSIONS INVENTORY JANUARY 1,2008—DECEMBER 31, 2008 REPUBLIC SERVICES: EAST CAROLINA REGIONAL MSW LANDFILL AULANDER,NORTH CAROLINA TITLE V PERMIT NO.08849T03 FACILITY AIRS NO.07/08/00102 Prepared for: NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Washington Regional Office 943 Washington Square Mall Washington,NC 27889 (252) 946-6481 On Behalf of: REPUBLIC SERVICES OF NORTH CAROLINA, LLC 1922 Republican Road Aulander,NC 27805 (800) 862-8396 Prepared by: CARLSON ENVIRONMENTAL CONSULTANTS, PC 400 West Windsor Street Monroe,NC 28112 (704) 506-7312 June 16,2009 Carlson Environmental Consultants, PC 305 South Main Street Monroe,NC 28112 704-283-9765 704-283-9755 fax June 16,2009 Mr.Robert Fisher VIA CERTIFIED US MAIL Regional Supervisor NCDENR—Washington Regional Office 943 Washington Square Mall Washington,NC 27889 Subject: Title V Annual Air Emissions Inventory January 1, 2008 to December 31, 2008 East Carolina Regional MSW Landfill—Aulander,NC Facility ID No. 07/08/00102 Title V Permit No. 08849T03 Dear Mr. Fisher: On behalf of Republic Services of North Carolina,LLC (Republic), Carlson Environmental Consultants,PC (CEC) is submitting two(2) copies of the Title V Annual Air Emissions Inventory for Calendar Year 2008 for the East Carolina Regional MSW Landfill located near Aulander,North Carolina. This report is submitted in accordance with the requirements listed in the facilities Title V Air Operating Permit(No. 08849T03) Condition 3X, which requires this report to be submitted to the NCDENR postmarked no later than June 30, 2009. This submittal includes the AERO forms,Responsible Official Certification, and back-up calculations. Please note that the facility General Manager has changed from Bill Cooksey to Chuck Forth. The Responsible Official remains Drew Isenhour,Area President for Republic Services of North Carolina,LLC. If you have any questions or comments regarding this submittal,please feel free to contact me at (704) 283-9765. incerel L. Carlson,P.E. I t i II U C5� President Carlson Environmental Consultants, PC i Attachments I J U N 2 9 2009 cc: Ray Hoffman, PE, Republic DA0 WARD Chuck Forth, ECRL Jeff McNabb, CEC SACarlson Env\Projects\Republic\East CarohnaWr Emissions\2008 Air emissions\ECRL.coverletter.AERO.2008.doc Gmail - Inventory submission confirmation -- 0800102 Page 1 of 1 G -wf i Kristofer Carlson <carlsonenv@gmail.com> ,:A NiC ih�``l� E.ETr. Inventory submission confirmation -- 0800102 1 message DENR.DAQ.Emission_lnventory_UG@lists.ncmail.net Wed, Jun 17, <DENR.DAQ.Emission_Inventory_UG@lists.ncmail.net> 2009 at 3:04 PM Dear Kristofer Carlson Your submittal of the 2008 emission inventory for Eastern Carolina Regional Solid Waste Landfill, 0800102, has been received by the North Carolina Division of Air Quality (DAQ). Please remember to: - print the Certification Form (see AERO Closeout page), - have the Responsible Official sign it in blue ink, - include copies of spreadsheets or calculations used in creating this inventory, and - mail (postmark) it to NCDAQ, 943 Washington Square Mall, Washington, NC 27889 by the required due date in order for this submittal to be considered complete. If you have any questions, please feel free to contact Mike Smithwick, in the Washington Regional Office, at(252) 946-6481. The Division of Air Quality thanks you for using AERO, the on line emissions inventory program. Sincerely DAQ http://mail.google.com/mail/?ui=2&ik=cO322f9dc3&view=pt&search=inbox&th=121 ef9b... 6/17/2009 Inventory Certification Form(Title V) Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2008 These forms must be completed and returned even if the facility did not operate or emissions were zero The legally defined "Responsible Official" of record for your facility is William Cooksey This person or one that meets the definition below must sign this certification form. The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one of the following: 1. For a corporation: a resident secretary,treasurer, or vice-president of the corporation in charge of a principal rP p �'� p rp g P p business function, or any other person who performs similar policy or decision making functions for the overall operation of one or more manufacturing,production, or operating facilities applying for a or subject to a permit and either i. the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25 million(in second quarter 1980 dollars); or ii. the delegation of authority to such representatives is approved in advance by the permitting authority; 2. For partnership or sole propietorship; a general partner or the proprietor,respectively; 3. for a muncipality, state, federal, or other public agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency(e.g., a Regional Administrator of EPA). CERTIFICATION STATEMENT (important: Legally Reapon5ible Official.read and sign after all submissions are finaU certify that I am the responsible official for this facility, as described above, and hereby certify that the information contained in this air emissions report, including attached calculations and documentation,is true, accurate and complete. (Subject to legal enalities of up to $25,000 per occurrence and possible imprisonment as outlined-in G.S.§143-215.3(a)(2)) Responsible Official's Signature Below use blue ink): Date Signed: Printed Name: -Wiiiiam C-e Di evj 1Se.r\ko V( Si afore: 10 - Z -0 This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission Inventory contact at once for proper forms. Email address of Responsible Official: ( {ri�04l d s�1� . C 0 s pi P Information on this Form cannot be held confidential 1 Facility Name East Carolina Regional MSW Landfill Facility ID 0800102 North Carolina Department of Environment and Natural Resources Division of Air Quality General Information If any information already provided to DAQ has changed or otherwise is incorrect, please provide corrections. You may leave blanks where the information is unchanged. (Except Facility ID and Name). Physical (911) Address of Facility 1922 Republican Road, Aulander, NC 27805 Name of Responsible Official Drew Isenhour Title Area President Telephone# ( 828_) 695-2050 E-Mail Address_Isnehourd@repsrv.com Mailing Address of Responsible Official 1220 Commerce Street SW, Conover,NC 28613 Name of Facility Technical/Permit Mailing Contact Chuck Forth Title Site Mann er Telephone#(252) 348- 3322 E-Mail Address forthc0,rgpsrv.com Mailing Address of Responsible Official 1922 Republican Rd., Aulander,NC 27805 Name of Inspection Contact Chuck Forth Title Site Manager Telephone# (252) 348- 3322 E-Mail Address forthcaLepsrv.com Name of Billing/Invoice Contact Ray Hoffman Title Area Engineer Telephone# (828) 320 - 7802 E-Mail Address HoffmanRJna`epsrv.com Billing/Invoice Company Republic Services of North Carolina Billing/Invoice Address 1220 Commerce Street SW, Conover, NC 28613 Standard Industrial Classification (SIC) Code(s) y5 North American Industry Classification System (NAICS —six digit) Code(s)— If known (see instructions) Report Prepared by Kris Carlson Telephone#(704) 283 - 9765 E-Mail Address CarlsonenvAgMail.com Provide to Appropriate DAQ Regional Office as needed. Information on This Form cannot be held confidential. As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Listing of Emission Sources and Control Devices on Permit. See instructions *ES ID on *ES Description *CS ID *CS Description *CD ID's Air Permit Municipal solid waste landfill One landfill gas—fired candlestick—type M ES-01 unici CS-2 flare(3000 scfm, 90 million Btu per hour CD—Flarel heat input), I—ES-04 diesel engines for miscellaneous landfill support IES05 Welding operations IES06 Diesel storage tank IES07 ILeachate storage tank 1 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Emission Source & Operating Scenario List — See Instructions ES Group ID ES ID OS ID OS Description ES-01 1 Municipal solid waste landfill I—ES-04 4 No.2 fuel oil—diesel engines for miscellaneous landfill support IES05 3 maintenance shop welding rods IES06 6 diesel storage tank IES07 2 temporary storage of collected �leachate 2 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2008 1. Emission Source ID (from permit) or ES-01 Emission Source Group ID 2. Emission Source Description: Municipal solid waste landfill [NSPS] 3. Operating Scenario ED/Description: OS — I/Municipal solid waste landfill 4. SCC Number/Description: 50100402/Landfill Dump 5. Throughput/units in 2008: 483629 TON/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) /o Sulfur %Ash Heat Content Btu/units 7. Capture Efficiency k%of Emissions from this Process Vented to Control / Device or Stack): 4 8. Control Device Information Order CS—ID CD ID Control Device Description as listed inpermit) 1 CS-2 CD—Flarel One landfill gas—fired candlestick—type flare(3000 scfm, 90 million Btu per hour heat input) 9.Emission Release Point RP Information: Sources vented to more than one ERP use additional ntry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter#): (F) (Feet/see) Rate(Acfm) Rectangle(L x W) (in 0.1 feet) Flare VERTICAL STACK 35 1 1500 60 2827.43 Flare 3 Operating Scenario: OS — 1 Emission Source/Group ID: ES-01 ".0. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2008) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% 008 1 008 �008 �008 13. Actual Emissions per Pollutant Listed Attach calculations and documentation of emission factors or other estimation methods used. Emission Emissions— Estimation Control GHG GHG Method Efficient Emission CAS y Ef Control II Pollutants Pollutants Code (Net after Factor (Tons/Year) (See all controls) Instructions 2008 Emission Criteria Emissions— Estimation Control Pollutant Criteria Method Efficiency Emission Po`�QS) Code Pollutants Code (Net after Factor Ef Control Pollutants (Tons/Year) (See all controls) Instructions 2008 CO CO 62.52 08 0 NOx NOx 11.49 08 0 TSP TSP 2.82 08 0 PM10 PM10 2.82 08 0 PM2.5 PM2.5 2.82 08 0 S02 S02 2.67 08 0 VOC VOC 13.8 08 98 Emission CAS Emissions Estimation Control HAP/TAP Emission (see HAP/TAPS Method Efficiency EF Control Pollutants (In Alphabetical Order) Code (Net after all Factor instructions) (Pounds/Year) (See controls) Instructions 2008 Acrylonitrile 107-13-1 0.032 08 98 Benzene 71-43-2 3.29 08 98 CFC-12 ichlorodifluoromethane 75-71-8 398.04 08 98 Carbon disulfide 75-15-0 0.028 08 98 Carbon tetrachloride 56-23-5 5.99 08 98 Carbonyl sulfide 463-58-1 35.65 08 98 Chlorobenzene 108-90-7 0.028 08 98 Chloroform 67-66-3 0.045 08 98 Dichlorobenzene 14— 106-46-7 0.053 08 98 4 Dichlorofluoromethane 75-43-4 334.85 08 98 Ethyl benzene 100-41-4 0.039 08 98 Ethyl chloride chloroethane 75-00-3 0.016 08 98 Ethyl merca tan 75-08-1 175.91 08 98 Ethylene dichloride 1,2—dichloroethane 107-06-2 0.037 08 98 Ethylidene dichloride 75-34-3 4.15 08 98 1,1—dichloroethane HCFC-22 Chlorodifluoromethane 75-45-6 3.2 08 98 Hexane, n— 110-54-3 10.99 08 98 Hydrogen sulfide 7783-06-4 1502.35 08 98 Mercury,vapor (Component of HGC 7439-97-6 0.05 08 98 Methyl chloride 74-87-3 0.006 08 98 Methyl chloroform 71-55-6 0.049 08 98 Methyl ethyl ketone 78-93-3 225.64 08 98 Methyl isobutyl ketone 108-10-1 0.024 08 98 Methyl merca tan 74-93-1 148.76 08 98 Methylene chloride 75-09-2 0.0106 08 98 Perchloroeth lene tetrachloroeth lene 127-18-4 6.81 08 98 Propylene dichloride 78-87-5 0.042 08 98 Tetrachloroethane, 1,1,2,2— 79-34-5 0.042 08 98 Toluene 108-88-3 8.97 08 98 Trichloroeth lene 79-01-6 0.033 08 98 Vinyl chloride 75-01-4 30.91 08 98 Vin lidene chloride 75-35-4 0.024 08 98 X lene 1330-20-7 4.08 08 98 5 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2008 1. Emission Source ID (from permit) or I—ES-04 Emission Source Group ED 2. Emission Source Description: diesel engines for miscellaneous landfill support 3. Operating Scenario ED/Description: OS —4/No. 2 fuel oil—diesel engines for miscellaneous landfill support 4. SCC Number/Description: 20200401/Diesel 5. Throughput/units in 2008: 6000CGAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) /o Sulfur %Ash Heat Content Btu/units 7. Capture Efficiency ,%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ED Control Device Description as listed inpermit) 9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow ERP Description (in feet) Circle(enter ft (F) (Feet/sec) Rate(Acfm) Rectangle(L x W) (in 0.1 feet) RP—DIESEL FUGITIVE(NO 1 72 Area= 1 miscellaneous diesel STACK) engines 6 Operating Scenario: OS—4 Emission Source/Group ID: I—ES-04 '0. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2008) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11. Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% 008 1 008 �008 �008 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2008 Criteria Emissions Emission Control Pollutant Criteria Estimation Efficiency Emission o� Code Pollutants Method Code (Net after Factor Ef Control Pollutants (Tons/Year) (See Instructions) all controls) 2008 CO CO 1.47 08 NOx NOx 6.84 08 TSP TSP 0.05 08 PM10 PM10 0.05 08 PM2.5 PM2.5 0.05 08 S02 S02 0.45 08 VOC VOC 0.55 08 HAP/TAP Emissions Emission Control Pollutants (In CAS HAP/TAPS Estimation Efficiency Emission EF Control Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all Factor See Instructions controls) 2008 Acetaldehyde 75-07-0 2.4 08 Acrolein 107-02-8 0.3 08 Benzene 71-43-2 2.9 08 Butadiene, 1,3— 106-99-0 0.1 08 Formaldehyde 50-00-0 3.6 08 Polycyclic Organic Matter (Inc PAH, dioxins, etc.NC AP 42 POM 74.1 08 historic amorphous lob Toluene 108-88-3 1.3 08 X lene 1330-20-7 0.9 08 7 8 As entered in AERO facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2008 1. Emission Source ID (from permit) or IES05 Emission Source Group ID 2. Emission Source Description: Welding operations 3. Operating Scenario HYDescription: OS —3/maintenance shop welding rods 4. SCC Number/Description: 30900500/Metal Work—Welding 5. Throughput/units in 2008: 5000 LB/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) % Sulfur %Ash Heat Content Btu/units 7. Capture Efficiency %of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acf n) Rectangle(L x W) (in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 9 Operating Scenario: OS —3 Emission Source/Group ID: IES05 ".0. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2008) Hours per Day ( 1 ) Days per Week ( 5 ) Weeks per Year ( 50 ) 11. Typical Start&End Times For Operating Scenario: Start: 900 End: 1000 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec 25% arch—May 25% une—Aug. 25% ept.—Nov. 25% 008 1 008 �008 �008 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor (Tons/Year) See Instructions all controls 2008 Criteria Emissions— Emission Control 1�I�T Pollutant Criteria Estimation Efficiency Emission \"`�`G�/'�)�) Code Pollutants Method Code (Net after Factor Ef Control Pollutants (Tons/Year) (See Instructions) all controls) 2008 CO CO 08 NOx NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 08 HAP/TAP Emissions Emission Control Pollutants (In Alphabetical CAS HAP/TAPS Estimation Efficiency Emission EF Control Order) (Pounds/Year) (see instructions) Method Code (Net after all Factor See Instructions controls) 2008 Manganese Unlisted Compounds (Specify MNC—Other 101 08 Component of MNC 10 As entered in AERO facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2008 1. Emission Source ID (from permit) or IES06 Emission Source Group ID 2. Emission Source Description: Diesel storage tank 3. Operating Scenario ED/Description: OS —6/diesel storage tank 4. SCC Number/Description: 39090004/Fuel Storage—Fixed Roof Tanks 5. Throughput/units in 2008: 60000 GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) /o Sulfur %Ash Heat Content Btu/units 7. Capture Efficiency ,I%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed inpermit) 9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/sec) (Acfm) Rectangle(L x W) (in 0.1 feet) F—I FUGITIVE(NO 1 72 Area= 1 fugitive STACK 11 Operating Scenario: OS —6 Emission Source/Group ID: IES06 '0. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2008) Hours per Day ( 10 ) Days per Week ( 6 ) Weeks per Year ( 52 ) 11. Typical Start&End Times For Operating Scenario: Start: 600 End: 1600 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec arch—Magune—Aug. a t.—Nov.008 25% 008 y 25% 008 25% 008 25% 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2008 Criteria Emissions— Emission Control Pollutant Criteria Estimation EfficiencyEmission (NAAQS) Ef Control Pollutants Code Pollutants Method Code (Net after Factor (Tons/Year) (See Instructions) all controls) 2008 CO CO 08 NOz NOx 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 08 HAP/TAP CAS Emissions Emission Estimation Control Emission Pollutants (In HAP/TAPS Efficiency EF Control Alphabetical Order) (see instructions) (Pounds/Year) Method Code (Net after all controls) Factor See Instructions 2008 Benzene 71-43-2 2.9 08 12 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory—Calendar Year 2008 1. Emission Source ID (from permit) or IES07 Emission Source Group ID 2. Emission Source Description: Leachate storage tank 3. Operating Scenario ID/Description: OS —2/temporary storage of collected leachate 4. SCC Number/Description: 40714698/Fixed Roof Tanks—Miscellaneous 5. Throughput/units in 2008: 4000000 E6GAL/yr (e.g.production or fuel use): 6. Fuel Information (If fuel is used) /o Sulfur %Ash Heat Content Btu/units 7. Capture Efficiency k.%of Emissions from this Process Vented to Control Device or Stack): 8. Control Device Information :None Order CS—ID CD ID Control Device Description as listed in ermit 9.Emission Release Point RP Information: Sources vented to more than one ERP use additional entry lines): ERP ID ERP Type Height Diameter Temperature Velocity Volume Flow Rate ERP Description (in feet) Circle(enter#): (F) (Feet/see) (Acfm) Rectangle(L x W) (in 0.1 feet) F-1 FUGITIVE(NO 1 72 Area= 1 fugitive STACK 13 Operating Scenario: OS —2 Emission Source/Group ID: IES07 10. Operating Schedule: (Source/Operating Scenario that best characterizes Calendar Year 2008) Hours per Day ( 24 ) Days per Week ( 7 ) Weeks per Year ( 52 ) 11.Typical Start&End Times For Operating Scenario: Start: 0 End: 2359 12. Seasonal Periods Percent Annual Throu h ut: an—Feb +Dec 25% 25"�o une—Aug. 25o�a �008 ept.—Nov. 25% 008 �arch—May 08 �008 13. Actual Emissions per Pollutant Listed : Attach calculations and documentation of emission factors or other estimation methods used. Emissions— Emission Control GHG CAS GHG Estimation Efficiency Emission Ef Control Pollutants Pollutants Method Code (Net after Factor Tons/Year See Instructions all controls 2008 Criteria Emissions— Emission Control Pollutant Criteria Estimation Efficiency Emission Po� Code Pollutants Method Code (Net after Factor Ef Control Pollutants (Tons/Year) (See Instructions) all controls) 2008 CO CO 08 NOz NOz 08 TSP TSP 08 PM10 PM10 08 PM2.5 PM2.5 08 S02 S02 08 VOC VOC 0.51 08 HAP/TAP CAS Emissions Emission Estimation Control Emission Pollutants (In (see instructions) HAP/TAPS Efficiency Factor EF Control Alphabetical Order) (Pounds/Year) Method Code (Net after all controls) See Instructions 2008 14 Facility Total CY 2008 Emissions Summary As entered in AFRO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO North Carolina Department of Environment and Natural Resources Division of Air Quality Air Pollutant Point Source Emissions Inventory-Calendar Year 2008 Record Facility-Wide Totals From all Permitted and Non-Permitted Air Pollutant Emission Sources Green House Gases Pollutants(GHG) Actual Emissions Tons/Year Pollutant CAS 1 2008 2007 %Difference Criteria Pollutants Actual Emissions Tons/Year Pollutant CAS 2008 2007 %Difference CO CO 63.99 95.039 -32.669746% NOx NOx 18.33 61.855 -70.36618% PM TSP TSP 2.87 4.158 -30.976435% PM10 PM10 2.87 4.158 -30.976435% PM2.5 PM2.5 2.87 3.8628 -25.701565% S02 S02 3.12 6.696 -53,40502% VOC VOC 14.86 12.522 18.671133% Hazardous Air Pollutants APS and/or Toxic Air Pollutants TAPS Actual Emissions Pounds/Year Pollutant I CAS 2008 2007 % Difference Pollutant Grou :Man anese compounds Group Sum:101 Manganese Unlisted Compounds (Specify MNC-Other 101.0 101 0.0% Component of MNC Pollutant Group:Mercury Compounds- all total mass,inc Hg Vapor Group Sum:.05 Mercury,vapor Com onent of HGC 7439-97-6 1 0.05 .04507 10.938542% Pollutant Grou :Total Reduced Sulfur TRS Group Sum:1651.11 Hydrogen sulfide 7783-06-4 1502.35 977.923 53.626614% Methyl merca tan 74-93-1 148.76 96.8304 53.629433% Acetaldehyde 75-07-0 2.4 16 -85.0% Acrolein 107-02-8 0.3 1.9 -84.21052% Acrylonitrile 107-13-1 0.032 .02041 56.7859% Benzene 71-43-2 9.09 24.14025 -62.345043% Butadiene, 1,3- 106-99-0 0.1 .8 -87.5% CFC-12 Dichlorodifluoromethane 75-71-8 398.04 259.098 53.625275% Carbon disulfide 75-15-0 0.028 1 .01757 59.362556% Carbon tetrachloride 56-23-5 5.99 3.90459 53.40919% 15 Carbonyl sulfide 463-58-1 35.65 22.6473 57.413906% Chlorobenzene 108-90-7 0.028 .0182 53.846153% Chloroform 67-66-3 0.045 .02895 55.44042% Dichlorobenzene 1,4- 106-46-7 0.053 .03393 56.20395% Dichlorofluoromethane 75-43-4 334.85 217.961 53.628403% Ethyl benzene 100-41-4 0.039 .0245 59.18368% Ethyl chloride chloroethane 75-00-3 0.016 .01043 53.403652% Ethyl merca tan 75-08-1 175.91 114.502 53.63051% Ethylene dichloride 1,2-dichloroethane 107-06-2 0.037 .024 54.166668% Ethylidene dichloride 75-34-3 4.15 2.70179 53.601868% 1,1-dichloroethane Formaldehyde 50-00-0 3.6 24.6 -85.36585% HCFC-22 Chlorodifluoromethane 75-45-6 3.2 Not reported N/A Hexane, n- 110-54-3 10.99 6.9836 57.368683% Methyl chloride 74-87-3 0.0060 .00408 47.05883% Methyl chloroform 71-55-6 0.049 .03235 51.46831% Methyl ethyl ketone 78-93-3 225.64 143.356 57.39836% Methyl isobutyl ketone 108-10-1 0.024 .01541 55.74302% Methylene chloride 75-09-2 0.0106 .00687 54.294025% Perchloroeth lene tetrachloroeth lene 127-18-4 6.81 4.4341 53.58246% Polycyclic Organic Matter(Inc PAH, dioxins, etc.NC AT 42 historic amorphous POM 74.1 500.9 -85.20663% lob Propylene dichloride 78-87-5 0.042 .0274 53.284668% Tetrachloroethane, 1 1 2,2- 79-34-5 0.042 .02713 54.81017% Toluene 108-88-3 10.27 14.19644 -27.657915% Trichloroeth lene 79-01-6 0.033 .02124 55.367233% Vinyl chloride 75-01-4 30.91 20.1218 53.614494% Vin lidene chloride 75-35-4 0.024 .01567 53.15891% X lene 1330-20-7 4.98 8.4942 -41.371758% 16 As entered in AERO .Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County : Bertie DAQ Region : WARO Comments From Facility: 17 As entered in AERO Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 1922 Republican Road Permit : 08849 Aulander,NC 27805 County: Bertie DAQ Region : WARO Comments From Facility: 6/17/2009 — General Comments 1. General Comments : Please see attached air emissions inventory calculations for additional information. 6/17/2009 —Operating Scenario Comments 1. OSOS4 : 2. SEE ATTACHED CALCULATIONS 6/17/2009—Operating Scenario Comments 1. OS OS3 : 2. SEE ATTACHED CALCULATIONS 6/17/2009—Operating Scenario Comments 1. OS 0S1 : 2.D CALCULATIONS 3. OS OS1 18 Emissions by Operating Scenario for Pollutant 2008 Inventory Facility Name: Eastern Carolina Regional Solid Waste Landfill Facility ID : 0800102 Permit : 08849 Process ID Operating Scenario Emission Rate(Tons/Yr)Emission Source ID CO maintenance shop welding rods IES05 6 diesel storage tank IES06 o. 2 fuel oil—diesel engines for miscellaneous 1.47 —ES-04 landfill support �eniporary storage of collected leachate I NS07 1 Municipal solid waste landfill 162.52 S—01 NOx 3 maintenance shop welding rods IES05 6 diesel storage tank IES06 o.2 fuel oil—diesel engines for miscellaneous 6.84 —ES-04 landfill support ' Municipal solid waste landfill 111.49 S-01 '. emporary storage of collected leachate S07 PM TSP o. 2 fuel oil—diesel engines for miscellaneous 05 —ES-04 landfill support 3 maintenance shop welding rods IES05 1 —Municipal solid waste landfill 2.82 S-01 6 iesel storage tank IES06 12 kemporary storage of collected leachate IES07 PM 10 o. 2 fuel oil—diesel engines for miscellaneous .05 —ES-04 landfill support 1 Municipal solid waste landfill 2.82 S-01 3 maintenance shop welding rods IES05 6 iesel storage tank MS06 em or storage of collected leachate S07 PM2.5 o. 2 fuel oil—diesel engines for miscellaneous 05 —ES-04 landfill support maintenance shop welding rods IES05 Municipal solid waste landfill 2.82 S-01 �__tetnporary iesel stora e tank S06 storage of collected leachate S07 1 S02 Zmaintenance shop welding rods IIES05 Municipal solid waste landfill 2.67 S-01 6 diesel storage tank IES06 temporary storage of collected leachate IES07 Vo.2 fuel oil— diesel engines for miscellaneous 45 —ES-04 a dfill support VOC 3 maintenance shop welding rods EES05 No. 2 fuel oil—diesel engines for miscellaneous 55 —ES-04 landfill support 6 diesel storage tank IES06 1 Municipal solid waste landfill 13.8 S-01 kernporary storage of collected leachate .51 IEES07 Process ID Operating Scenario Emission Rate(Pounds/Yr)Emission Source ID Acetaldeh de Vo.2 fuel oil—diesel engines for miscellaneous 4 —ES-04 a dfill support Acrolein 4 o. 2 fuel oil—diesel engines for miscellaneous 3 —ES-04 andfill support Acrylonitrile 1 Municipal solid waste landfill 1.032 S-01 Benzene 1 Munici al solid waste landfill 3.29 S-01 No. 2 fuel oil—diesel engines for miscellaneous 2.9 —ES-04 landfill support 6 diesel storage tank P.9 XS06 Butadiene 1 3— o. 2 fuel oil— diesel engines for miscellaneous 1 —ES-04 landfill support CFC-12 Dichlorodifluoromethane 1 Municipal solid waste landfill 1398.04 S-01 Carbon disulfide 1 Municipal solid waste landfill 1.028 S-01 Carbon tetrachloride unici al solid waste landfill 15.99 S-01 Carbonyl sulfide 1 Municipal solid waste landfill 135.65 S-01 2 Chlorobenzene Municipal solid waste landfill 028 S—01 Chloroform 1 Municipal solid waste landfill 1.045 S-01 Dichlorobenzene 14— 1 unici al solid waste landfill .053 S—01 Dichlorofluoromethane 1 Municipal solid waste landfill 1334.85 S-01 Eth lbenzene 1 Municipal solid waste landfill 1.039 S-01 Ethyl chloride chloroethane 1 Municipal solid waste landfill 1.016 S-01 Ethyl merca tan 1 Municipal solid waste landfill 1175.91 S-01 Eth lene dichloride 1 2—dichloroethane 1 Municipal solid waste landfill 1.037 S-01 nth lidene dichloride 1 1—dichloroethane Municipal solid waste landfill 15 S-01 Formaldeh de o.2 fuel oil—diesel engines for miscellaneous 3.6 —ES-04 andfill support HCFC-22 Chlorodifluoromethane 1 Municipal solid waste landfill 13.2 S—01 Hexane n- 1 Municipal solid waste landfill 110.99 S—01 Hydrogen sulfide 1 Municipal solid waste landfill 11502.35 S—01 -- Manganese Unlisted Compounds(Specify Component of MNC 3 Imaintenance shop welding rods 1101 ES05 Merc va or(Component of HGC 1 Municipal solid waste landfill OS S-01 Methyl chloride 11 Municipal solid waste landfill 1.006 S—01 Methyl chloroform 1 unici al solid waste landfill 049 S—01 3 Methyl ethyl ketone Municipal solid waste landfill 25.64 S-01 Methyl isobytyl ketone 1 Municipal solid waste landfill 1.024 S-01 Methyl merca tan 1 Municipal solid waste landfill 1148.76 S—01 Methylene chloride 1 Municipal solid waste landfill .0106 S-01 Perchloroeth lene tetrachloroeth lene 1 Municipal solid waste landfill 16.81 S-01 Pol c clic Organic Matter Inc PAH dioxins etc.NC AP 42 historic amorphous r lob o. 2 fuel oil—diesel engines for miscellaneous andfill su ort 174.1 �—ES-04 Pro lene dichloride 1 Municipal solid waste landfill 1.042 S-01 Tetrachloroethane 1 1 2 2- 1 Municipal solid waste landfill 1.042 S-01 Ioluene �ao. 2 fuel oil—diesel engines for miscellaneous 1.3 —ES-04 ndfill support 1 unici al solid waste landfill 18.97 S-01 Trichloroeth lene 1 Municipal solid waste landfill 1.033 S-01 Vinyl chloride 1 Municipal solid waste landfill 130.91 S-01 Vin lidene chloride 1 Municipal solid waste landfill 1.024 S-01 X lene �ao. 2 fuel oil—diesel engines for miscellaneous 9 —ES-04 ndfill support 1 Municipal solid waste landfill 4.08 5-01 4 NC DAQ - EMISSIONS INVENTORY Page 1 of 2 Facility Total CY 2008 Emission Summary Facility Id : 0800102 Green House Gases Pollutants(GHG Actual Emissions onsNear Pollutant CAS 1 2008 1 2007 % Difference Criteria Pollutants Actual Emissions (TonsNear Pollutant CAS 2008 2007 % Difference CO CO 63.99 95.039 -32.669746% NOx NOx 18.33 61.855 -70.36618% PM(TSP) TSP 2.87 4.158 -30.976435% PM10 PM10 2.87 4.158 -30.976435% PM2.5 PM2.5 2.87 3.8628 -25.701565% S02 S02 3.12 6.696 -53.40502% VOC VOC 14.86 12.522 18.671133% Hazardous Air Pollutants HAPS and/or Toxic Air Pollutants TAPs Actual Emissions (PoundsNear) Pollutant CAS 1 2008 1 2007 % Difference Manganese&com ounds101 Manganese Unlisted Compounds (Specify& MNC-Other 101.0 101 0.0% Component of MNC Mercury&Compounds-all total mass, inc Hg Vapor.05 Mercury, vapor(Component of 7439-97-6 0.05 .04507 10.938542% HGC Total Reduced Sulfur RS)1651.11 Hydrogen sulfide 7783-06-4 1502.35 977.923 53.626614% Methyl mercaptan 74-93-1 148.76 96.8304 53.629433% Acetaldehyde 75-07-0 2.4 16 -85.0% Acrolein 107-02-8 0.3 1.9 -84.21052% Acrylonitrile 107-13-1 0.032 .02041 56.7859% Benzene 71-43-2 9.09 24.14025 -62.345043% Butadiene, 1,3- 106-99-0 0.1 .8 -87.5% DichloroCFC-1omethane 75-71-8 398.04 259.098 53.625275% Carbon disulfide 75-15-0 0.028 .01757 59.362556% Carbon tetrachloride 56-23-5 5.99 3.90459 53.40919% Carbonyl sulfide 463-58-1 35.65 22.6473 57.413906% Chlorobenzene 108-90-7 0.028 .0182 53.846153% Chloroform 67-66-3 0.045 .02895 55.44042% Dichlorobenzene( , 1,4- 106-46-7 0.053 .03393 56.20395% Dichlorofluoromethane 75-43-4 334.85 217.961 53.628403% Ethyl benzene 100-41-4 0.039 .0245 59.18368% Ethyl chloride(chloroethane) 75-00-3 0.016 .01043 53.403652% Ethyl merca tan 75-08-1 175.91 114.502 53.63051% Ethylene dichloride(1,2- 107-06-2 0.037 .024 54.166668% dichloroethane Ethylidene dichloride(1,1- 75-34-3 4.15 2.70179 53.601868% dichloroethane Formaldehyde 50-00-0 3.6 24.6 -85.36585% HCFC-22 75-45-6 3.2 Not reported N/A Chlorodifluoromethane Hexane, n- 110-54-3 10.99 6.9836 57.368683% Methyl chloride 74-87-3 0.0060 .00408 47.05883% http://xapps.enr.state.nc.us/aq/aero/EDFacTotals.jsp 6/17/2009 NC DAQ - EMISSIONS INVENTORY Page 2 of 2 Methyl chloroform 71-55-6 0.049 .03235 51.46831% Methyl ethyl ketone 78-93-3 225.64 143.356 57.39836% Methyl isobutyl ketone 108-10-1 0.024 .01541 55.74302% Methylene chloride 75-09-2 0.0106 .00687 54,294025% Perchloroethylene 127-18-4 6.81 4.4341 53.58246% (tetra chloroeth lene) Polycyclic Organic Matter(Inc PAH, dioxins, etc. NC&AP 42 POM 74.1 500.9 -85.20663% historic amorphous lob) Propylene dichloride 78-87-5 0.042 .0274 53.284668% Tetrachloroethane, 1,1,2,2- 79-34-5 0.042 .02713 54.81017% Toluene 108-88-3 10.27 14.19644 -27.657915% Trichloroeth lene 79-01-6 0.033 .02124 55.367233% Vinyl chloride 75-01-4 30.91 20.1218 53.614494% Vin lidene chloride 75-35-4 0.024 .01567 53.15891% X lene 1330-20-7 4.98 8.4942 -41.371758% close http://xapps.enr.state.ne.us/aq/aero/EDFacTotalsjsp 6/17/2009 EAST CAROLINA REGIONAL MSW LANDFILL 2008 ANNUAL AIR POLLUTANT POINT SOURCE ENUSSIONS INVENTORY CALCULATIONS TABLE OF CONTENTS Section Page 1 Introduction.....................................................................................................................A-2 2 Fugitive Landfill Emissions ............................................................................................A-4 3 Open Flare Emissions......................................................................................................A-9 Attachment A Model Output East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-1 SECTION 1 INTRODUCTION The Annual Emissions Inventory Report(Report) presented herein was prepared by Carlson Environmental Consultants, PC (CEC) on behalf of Republic Services of North Carolina, LLC (Republic) for the East Carolina Regional MSW Landfill (Landfill). The Landfill is required by 15A NCAC 2Q.0207 and 2D.0202 and Condition 3X of its Title V Air Operating Permit (No. 08849T03) to quantify its air emissions on a calendar year basis and pay fees to the North Carolina Department of Environment and Natural Resources (NCDENR). The emission sources identified in this Report were based on CEC's knowledge of the site, discussions and correspondence with Republic, Hodges, Harbin,Newberry& Tribble, Inc., and review of existing permits, previous emissions inventories, compliance reports, and other information provided by Republic. Table 1 on the following page is a summary of the emission rates from all applicable air pollutant emission sources at the Landfill during calendar year 2008. East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-2 TABLE 1. 2008 ANNUAL EMISSION RATE SUMMARY(tons/yr) Emission Sources I.D. Emission NMOC VOCs HAPs NO,, CO NH3 SO,, PM PMio PM2.5 HCl TRS # Source Municipal Solid ES-0I Waste Landfill 34.3 13.4 1.48 -- -- t -- -- -- -- -- 0.90 (Fugitive Surface Emissions ES-02 Roads -- -- -- -- -- -- -- -- - ES-03 Heavy Equipment -- -- -- -- -- -- -- -- -- -- -- -- Internal ES-04 Combustion -- 0.55 0.05 6.87 1.47 -- 0.45 0.05 0.05 0.05 -- -- Engines Welding -- t t -- -- -- -- -- -- -- -- -- Operations ES-06 Diesel Storage t t-- -- -- -- -- -- -- -- - Tank - -- ES-07 Tank ate Storage _ 0.51 0.51 CD-01 Open Flare 0.38 0.40 0.04 11.49 62.52 -- 2.67 2.82 2.82 2.82 0.04 -- Total 34.68 14.86 2.08 18.33 63.99 t 3.12 2.87 2.87 2.87 0.04 0.90 East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No.08849T03 A-3 SECTION 2 FUGITIVE LANDFILL EMISSIONS (ES-01) INTRODUCTION This section addresses the generation and fugitive emissions of landfill gas (LFG), non- methane organic compounds (NMOCs), volatile organic compounds (VOCs), hazardous air pollutants (HAPs), total reduced sulfur (TRS) compounds, and ammonia(NH3). The fugitive emissions are assumed to be those emissions that are uncontrolled by the active LFG collection system. The Landfill has an LFG collection and control system that was estimated to have collected approximately 60 percent of the generated LFG. Therefore, approximately 40 percent of emissions generated by the buried waste of the Landfill are assumed to be uncontrolled, fugitive emissions in 2008. LFG generation from the landfill operation during 2008 was calculated using CEC's version of the U.S. EPA Landfill Gas Emissions Model (LandGEM). A description of the LandGEM parameters is provided below and the Model output is attached. The LandGEM uses a first-order decay equation to predict landfill gas generation based on the amount and age of the waste in place. The formula is presented in 40 CFR Part 60.754(a)(1)(i). The parameters Lo and k used in the LandGEM are the values that are tailored to this site for this emissions inventory based upon the actual amount of LFG collected by the active LFG system. The methane generation potential, L,,, for the MSW landfill cells was set equal to 100 cubic meters (m3) of methane (C144) per megagram (Mg) of waste and the methane generation rate constant, k, was 0.04 yr 1. These values for Lo and k are recommended for municipal solid waste (MSW) landfills that are located in geographical regions that receive average or above average annual precipitation, such as Aulander,North Carolina. The concentration of NMOC in LFG was set to 595 parts per million by volume (ppmv) as hexane. This NMOC value is recommended by AP-42 Section 2.4 for MSW landfills where actual site-specific NMOC sampling has not been performed. The refuse filling history and projections used in the Title V Permit application,previous emission statements, and the actual waste tonnages provided by the Landfill were input to the LandGEM. Note that the models estimate emissions based on the amount of waste in- place at the beginning of each year. The waste in-place (known inert wastes and construction and demolition wastes have been excluded) at the beginning of 2008 has been estimated at 5.657 million Mg, which is about 6,237 million tons. The LandGEM calculates East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-4 that the methane generation rate in 2008 was 16.73 million cubic meters. Assuming that the methane content in the LFG is 50 percent, the volume of LFG generated in 2008 is estimated to be 2,248 cfrn. The model output is included in Attachment A. Non-Methane Organic Compound (NMOC) Emissions NMOC generation from the landfill was calculated using the LandGEM. The model parameters were similar to the values above and the model output is attached. The LandGEM output calculates that the NMOC generation rate for 2008 is 77.7Mg (85.7 tons). Assuming an LFG collection efficiency of 60 percent in 2008, the fugitive NMOC emission rate in 2008 is estimated to be 34.3 tons. Volatile Orizanic Compound (VOC) Emissions Because site-specific data is not available, VOC generation is assumed to be 39 percent of the NMOC generation. This assumption is based on information contained in AP-42 Section 2.4 (revised November 1998) Table 2.4-2. The NMOC generation rates were extracted from the LandGEM output and represent the emissions from the landfill during 2008. The VOC generation rates were calculated by converting the NMOC generation rates (shown in the LandGEM output) from Mg/yr to tons/yr, and then multiplying by 0.39 (i.e., VOC is 39 percent of NMOC). The fugitive VOC emission rates in 2008 is 13.4 tons. TABLE 2. AIR POLLUTANT GENERATION AND EMISSION RATES Fugitive Fugitive Fugitive Fugitive NMOC NMOC Surface NMOC Surface TRS Surface VOC Surface HAP Generation Generation Emissions Emissions Emissions Emissions Year (Mg/yr) (ton/yr) (ton/yr) (ton/yr) (ton/yr) (ton/yr) 2008 77.7 85.7 34.3 0.90 13.4 1.48 Notes: 1.VOC generation is assumed to be 39 percent of NMOC generation. 2.It is assumed that the LFG collection system efficiency is 60 percent in 2008. 3.Model output is located in Attachment A. Hazardous Air Pollutant (HAP) Emissions The estimation of HAP emissions from the landfill is based on equations (3) and (4) in AP- 42 Section 2.4. Those equations are presented below. The first step is to estimate the generation rate of the pollutant in cubic meters per year(m3/yr). Next, the volumetric generation rate estimate is converted to a mass generation rate (tons per year). East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-5 Equation 3: 3 Q in = 2.0 X Q CP P yr Cho lob where: QP = Pollutant generation rate (m3/yr) QCh4 = Methane generation rate (in 3/yr) from the LandGEM Cp = Pollutant concentration in LFG (ppmv) 2.0 = Multiplication factor (assumes LFG is 50 percent methane, 50 percent carbon dioxide, nitrogen, etc.) Equation 4: Mp (tons/yr) = Qp ((MWP(glgmol))(1atm)) ton (8-20 5 x 10-') In3 —atm 10 g g (273+TK) 1907.185 k g gmol—K ( ) kg where: MP = Pollutant mass generation rate MWP = Molecular weight of pollutant(g/gmole) T = Temperature of LFG (°C) (Assume 25 degrees Celsius) Of the over 150 chemical compounds identified as HAPs under Section 112 of the Clean Air Act, 28 of these compounds are listed in AP-42 Table 2.4-1 and 2.4-2. Default concentration values from Section 2.4 of AP-42 were used for compounds in which site- specific data was unavailable. All 37 HAP compounds are listed individually in spreadsheets included in Attachment A. Annual emissions of the remaining HAP compounds (i.e., those not included in the AP-42 tables or added to this list) are assumed to be negligible. The HAP emissions in 2008 were estimated to be 1.48 tons. Total Reduced Sulfur(TRS) Emissions The volumetric generation rate of total reduced sulfur compounds is estimated by the following equation, obtained from AP-42 section 2.4.4 revised November 1998 . Note that i g q ( ) East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-6 the 2008 methane generation rate from the landfill (16.73 million cubic meters) is equal to 1124.1 cfin. Equation 3: 3 3 f 3 TRS m = (2.0)116.73xlO' m o CH4 46.9 =1,569.27 m of S yr yr 106 yr Equation 4: 32 g (1 atm) TRS kg _ 1,569.27 m3 S gmol yr yr 8.205 x 10-5 m3 —atm 10 g (298°K) gmol—°K kg The uncontrolled mass emissions of total reduced sulfur compounds is calculated below: TRS Generation=2,042.57kg/yr=2.25 tons/yr Surface Fugitive TRS = (40%)(2.29 tons/yr) = 0.90 tons/yr Ammonia (NH3) Emissions Although MSW landfills are sources of ammonia(NH3) emissions, according to an Environmental Protection Agency(EPA) funded final report titled Development and Selection of Ammonia Emission Factors',they are "very uncertain and not very important sources" and are "minor and insignificant influences" when compared to other possible sources. Therefore, for purposes of this emissions inventory, emission rates of ammonia will be considered insignificant. 1 R Battye,W.Battye,C.Overcash, and S.Fudge.Development and Selection of Ammonia Emission Factors Final Report. Prepared for U.S.Environmental Protection Agency. August 1994. East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-7 SECTION 3 OPEN FLARE EMISSIONS (CD-01) FLARE EMISSIONS Actual flare emissions have been calculated by assuming the flare operated at an average LFG flow of 1,286 scfm over a maximum operating duration of 24 hours a day for 365 days per year, or 8,760 hours per year. Based on site data,this is slightly higher than the actual flare flow and hours of operation, but has been used to be more conservative with these calculations. TABLE 3. ACTUAL FLARE EMISSIONS (CD-01) 2008 LFG Flare Compound LFG Flare Emission Emissions (CD-01) Factors (tpy) NOx 0.068 lb/MMBtu�1� 11.49 CO 0.37 lb/MMBtu(1) 62.52 PM-10 0.001 lb/hr cfin C114(2) 2.82 PM 0.001 lb/hr cfin CH4(2) 2.82 PM-2.5 0.001 lb/hr cfm C1_14(2) 2.82 NMOC 99.2 % destruction(2) 0.38 VOCs (3) 0.40 S02 (4) 2.67 HAPs 98 % and 99.7 % 0.04 destruction(2) HCl (5) 0.032 ' NOX and CO emission factors were obtained from AP-42 Section 2.4. 2 Emission factor obtained from AP-42, Section 2.4. 3 It is assumed that VOC emissions are 39%of NMOC emissions,per AP42, Section 2.4. 4 SOZ emissions are based on an AP-42 concentration of 46.9 ppmv of TRS in LFG. East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-8 s HCl emissions are based on a site-specific amount of Cl in LFG. Emission Rate Calculations The LFG, for purposes of calculating the products of combustion and the associated emissions, is assumed 50 percent methane, 40 percent carbon dioxide, 9 percent nitrogen, and 1 percent oxygen. Concentrations of other LFG constituents are negligible with regard to the combustion process. The presence of nitrogen and oxygen in LFG is assumed due to the potential infiltration of ambient air into the gas extraction system through the surface of the landfill, with a portion of the oxygen being consumed in the aerobic degradation process. Trace LFG constituents make up less than 1 percent of the total gas volume. The flare operating data and emission calculations are presented in the following information. TABLE 4 UTILITY FLARE CD-01 OPERATING DATA Maximum firing rate of LFG 3,000 scfm"' Maximum hours of operation 8,760 hr/yr Average Btu content of LFG(2) 500 Btu/scf Actual LFG firing rate of LFG 1,286 scfm Actual hours of operation 8,628.1 hours/yr 1 Standard cubic feet per minute (scfin). 2 The Higher Heating Value of LFG based on methane content of 50 percent is approximately 500 British Thermal Units (Btu) per standard cubic foot(scf) of gas. ACTUAL EMISSIONS The flare emissions are calculated below for nitrogen oxides (NOx), carbon monoxide (CO), particulate matter (PM-10), volatile organic compounds (VOC), sulfur oxides (as S02), and hydrochloric acid (HCl) from the flare. PTE Heat Release (NMVIBtu/hr) The maximum heat release of the flare is calculated based on a heating value of approximately 500 Btu/scf. (1,286 scf n) 500 Btu 60 min) 1 MMBtu scf hr J 10' Btu East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-9 = 3 8.5 8 MMBtu/hr Nitrogen Oxides, Carbon Monoxide, and Particulate Emission Rates e calculation of the nitrogen oxide O carbon monoxide CO and articulate The g (NOx), ( ), P emissions (PM-10) are based on the emission factors shown in Table C2-1 and the actual estimated firing rate of the flare, 1,286 scfm of LFG. NOx PTE Emissions- 00.068 lb NOx 1 (38.58 MMBtu 1 8,760 hr 1 ton MMBtu J hr J yr 2000lb = 11.49 tDy NOx CO PTE Emissions- 00.37 lb CO) �38.58 MMBtu) r8,760 hr 1 ton MMBtu hr J yr 20001b 2.52 tnv CO Particulate Matter PTE Emissions 0.001 lb PM—10 (1,286 scfm LFG) 0.5 cfm CH4 8,760 hr 1 ton hr—cfm CH4 1 cfm LFG year 2,000 lb =2.82tpy According to Table 2.4-5 in AP-42 Section 2.4 (revised 11/98), particulate matter emissions from flares are predominately less than 2.5 microns in diameter. Therefore, AP-42 recommends using the same emission factor for both PM, PM10 and PM2.5 emission estimates. It is then assumed that the flare emitted 2.82 tpy of PM and PM2.5 emissions in 2008. East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-10 TABLE 5 NMOC, VOC,AND HAP EMISSIONS Pollutant Emissions (tpy)(1)(2) Compound (3) NMOC Emission 0.38 VOC(1) 0.40 TOTAL HAPs(5) 0.04 ' Values represent emissions,which have been collected,but not combusted in the control device. Assumes all collected LFG from the Landfill(i.e.,60%of generated LFG)is sent to be combusted in the flare. 2 Represents 60 percent collection efficiency by the LFG collection system and 98 percent destruction efficiency by the utility flare(CD-0 1). Calculations shown below. 3 Calculation for fugitive VOC emissions from the flare are shown below. 4 HAPs calculated based on AP-42, Section 2.4 guidance and is presented in Exhibit 3 in Appendix D. NMOC and VOC PTE Flare Fugitive Emissions Calculations Given: 2008 NMOC PTE Generation: 77.7 tpy 60 percent LFG collection efficiency Flare destruction efficiency= 99.2 percent= 0.8 percent emissions Therefore: (NMOC Generation)*(LFG Collection Efficiency)*(Percent Emissions) Flare NMOC Emissions = (77.7 tpy)*(0.60)*(0.008) 2008 VOC PTE Generation: 33.4 tpy 60 percent LFG collection efficiency Flare VOC destruction efficiency= 98 percent=2 percent emissions Therefore: (VOC Generation)*(LFG Collection Efficiency)*(Percent Emissions) Flare VOC Emissions = (33.4tpy)*(0.60)*(0.02) = 40 tnv Sulfur Dioxide PTE The emissions of sulfur oxides,particularly sulfur dioxide (S02), from the flare are dependent on the inlet concentration of sulfur-bearing compounds in the LFG. The calculation of the estimated S02 emissions from the flare is based on the assumption that all East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-11 of the total reduced sulfur (TRS)in the LFG is oxidized to 5O2. Since site specific data for the TRS concentration in the LFG at the Landfill was not readily available, SO2 emissions from the flare were estimated based on the published mean concentration of TRS in LFG samples. AP-42 Section 2.4 (revised November 1998) lists concentrations of various compounds in uncontrolled LFG. This section reports that the mean concentration of TRS in LFG is 46.9 ppmv. Molar Flow Rate of LFG to the Flare At a volumetric flow rate of 1,286 scfm,the molar flow rate of LFG into the flare can be calculated as shown below. For this calculation, natural gas processing standards of 60°F (5200 Rankine (R)) and 1 atmosphere have been used. (1,286 scfm) 60 min 1 atm hr 0.7302 atm ft 3 (520° R) lbmole R = 203.211bmole fuel/hour S02 PTE Emissions- Molecular weight of Sulfur (S) =32.06 lb/lbmole 46.9 lbmole H2S C203.21 lbmole fuel l 32.061b SOZ r2 lb S02 r1 ton 8,760 hours 10' lbmole fuel hr J lbmole H2S Ib S 2,000 lb yr = 2.672.67 tnv SOSO2 HAPs PTE HAPs calculations are shown in Exhibit 3. The flare HAPs attributed to open flare CD-01 are based on the flare operating at 1,286 scfm. The HAP emissions are estimated to be 0.04 tons. Hydrochloric Acid MCI) Emissions Hydrochloric acid (HCl) emissions are formed when chlorinated compounds in LFG are combusted in control equipment. The estimation of HCl emissions from the Landfill are based on Equations (3) and (4) in AP-42 Section 2.4, and is presented below. The first step East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-12 1 is to estimate the total Chloride Cal concentration for the LFG. Site-specific sampling on the LFG was performed on May 4, 2005 and a concentration of 46.91 ppmv was calculated. The second step is using equations 3 and 4. The PTE HCl emissions Calculate the Emission Rate, Qci, using Equation 3. Qcr =2.0*Qcx, * Cc' (3) LOE6 Where: Qci =Emission Rate of Cl, m3/yr QCH4 = Generation Rate of CH4, m3/yr= 16.73E06 CCl = Concentration of Cl in landfill gas, ppmv =46.91 ppmv (default value from AP-42) 2.0 =Multiplication factor, based on 50% Methane content Qcj =2.0 * 16.73E06 * (46.91/1.OE6) = 1,569.61 ppmv Calculate the uncontrolled mass emissions of Cl, UMcI, using Equation 4. * MWc, *latm UMc, = Qci m3 —atm (4) 8.205 x 10-5 *1000 g*(273+T°K) gmol—°K kg Where: UMci =Uncontrolled Mass emissions, kg/yr MWc, =Molecular Weight of Cl, g/gmol = 35.453 g/gmol Qci =NMOC emission rate of Cl, ppmv = 1,569.61ppmv T =Temperature of landfill gas, °C =25 °C UM — 1569.61* 35.453 =2,275.88 kg/yr c` 8.205 x 10-5 *1000*(298) HCl emissions =2,275.88 kg/yr= 2.51 tons/yr Flare emissions = (2.51 tons)(60% collection)(98% destruction) = 0.032 tons/yr East Carolina Regional MSW Landfill Facility ID No 07/08/00102 Title V Permit No. 08849T03 A-13 TABLE 6. CALCULATED LFG GENERATION/EMISSION RATES EAST CAROLINA REGIONAL MSW LANDFILL-AULANDER,NC Waste Waste Methane LFG LFG LFG Disposal Waste Disposal Waste Generation Generation Collection Fugitive Rate In-Place Rate In-Place Rates Rates Rates Rates Year tons/ r tons r (m'/yr) cfm) (cfm) (cfm 1993 39,176 0 35,540 0 0.000E+00 0 01 0 1994 243,409 39,176 220,817 35,540 1.422E+05 19 11 8 1995 338,155 282,585 306,769 256,357 1.020E+06 137 82 55 1996 360,497 620,740 327,037 563,126 2.207E+06 297 178 119 1997 345,587 981,237 313,511 890,163 3.429E+06 461 276 184 1998 404,852 1,326,824 367,276 1,203 674 4.548E+06 611 367 244 1999 1 456,157 1,731,676 413,819 1570950 5.839E+06 785 471 314 2000 472,056 2,187,833 428,242 1,984,769 7.265E+06 9761 586 391 2001 446,029 2,659,889 404,631 2,413,011 8.693E+06 1,1681 701 467 2002 380,470 3,105,918 345,157 2,817,641 9.971E+06 1,340 804 536 2003 494,866 3,486,388 448,935 3,162,798 1.096E+07 1,473 884 589 2004 561,909 3,981,254 509,755 3,611,733 1.233E+07 1,656 994 663 2005 570,848 4,543,163 517,865 4,121,488 1.388E+07 1865 1,119 746 2006 585,119 5,114,011 530,811 4,639,353 1.541E+07 2,071 1,242 828 u2 2 537,571 5,699,130 487,677 5,170,164 1.693E+07 2,275 1,365 91k0 483,629 6,236,702 438,741 51657,841 1.822E+07 2,448J 1,469 979 AP-42 DEFAULT NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% AP-42 COLLECTION EFFICIENCY OF LFG SYSTEM: 60% AP-42 DECAY RATE CONSTANT: 0.04 AP-42 ULTIMATE METHANE RECOVERY RATE: 3,203.7 ft3/ton METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35.314667 cu ft per cu m 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg Notes: 1.Waste disposal for years 1993-2007 provided by Republic. TABLE 7. CALCULATED NMOC and VOC GENERATION/EMISSION RATES EAST CAROLINA REGIONAL MSW LANDFILL-AULANDER,NC NMOC NMOC NMOC VOC VOC VOC Generation Generation Surface Fugitive Generation Generation Surface Fugitive Rates Rates Rates Rates Rates Rates Year tons/ r r tons/ r tons/ r tons/ r 1993 0.0 0.0 0.0 0.0 0.0 0.0 1994 0.7 0.6 0.3 0.3 0.2 0.1 1995 4.8 4.4 1.9 1.9 1.7 0.7 1996 10.4 9.4 4.2 4.0 3.7 1.6 1997 16.1 14.6 6.4 6.3 5.7 2.5 1998 21.4 19.4 8.6 8.3 7.6 3.3 1999 27.5 24.9 11.0 10.7 9.7 4.3 2000 34.2 31.0 13.7 13.3 12.1 5.3 2001 40.9 37.1 16.4 15.9 14.5 6.4 2002 46.9 42.5 18.8 18.3 16.6 7.3 2003 51.5 46.8 20.6 20.1 18.2 8.0 2004 58.0 52.6 23.2 22.6 20.5 9.0 2005 65.3 59.2 26.1 25.5 23.1 1 10.2 2006 1 72.5 65.7 29.0 28.3 25.6 11.3 2007 79.6 72.2 31.8 31.0 28.2 12.4 2008 85.7 77.7 34.3 33.4 30.3 13.4 AP 42 DEFAULT NMOC CONCENTRATION IN LFG: 595 ppmv ASSUMED METHANE CONTENT OF LFG: 50% AP 42 DEFAULT VOC CONTENT OF NMOC: 39% AP-42 COLLECTION EFFICIENCY OF LFG SYSTEM: 60% AP-42 DECAY RATE CONSTANT: 0.04 AP42 ULTIMATE METHANE RECOVERY RATE: 3,203.7 ft3/ton METRIC EQUIVALENT: 100 cu m/Mg Conversions: 35.314667 cu ft per cu m 1.1023113 ton per Mg 32.037 cu ft/ton per cu m/Mg TABLE 8.CALCULATED HAPITAP GENERATION/EMI ATES EAST CAROLINA REGIONAL MSW LANDFILL-AULANDER,NC 20D8 Total Methane Generation(m3/yr)= 16,728,870 LFG Collection Efficiency(%)= 60.0% Landfill Gas Temperature eQ'= 25.0 Halogenated Destruction Eff.(%)7= 98.D% Non-Halogmated Destruction Eff.(%)°= 99.7 HAP/TAP EMISSIONS Year LFG(din) Generated Surface Emissions Flare Total Emissions 2008 2,248 3.69 1.49 0.04 1.51 Collected HAP. Pollutant Mol.Wt. Cono.s Q(p)I M )� FM(p)s M(p)-FM(p)4 Flare Total HAPs Total FiAPs Total Haps CAS No. ol) my m^3/r ( ( Ib/ ) Ib/da IbPor 1,1,1-tricidoroethaneT"P'Iw 71-556 133.42 0.0003 0.010 0.055 0-000 0.000 0.000 0.000 0.048 0.000 0.000 I,1,2,2-tetrachloroethane T"P,tw 79-34-5 167.85 0.0002 0.007 0.046 0.000 0.000 0.000 0.000 0.040 0.000 0,000 I'l-ichloroethanelw 75-34-3 99.95 0.03378 1.130 4.574 0.005 0.002 0.003 0.000 4.030 0.011 0.000 1,1-0ichlome0xne1w 75-35-4 %.94 0.0002 0.007 0.027 0.000 0.000 0.000 0.000 0.023 0.000 0.000 1,24ehlorodhane TAP'Iw 107-06-2 98.% 0.0003 0.010 0.041 0.000 0.000 0.000 0.0D0 0.036 0.000 0.000 1,2-0ichlo ro anc" 78-87-5 112.99 0.0003 0.010 0.046 0.000 0.000 0.D00 0.000 0.041 0.000 0.000 ac Ionitrilc T"P.I 107-13-1 53.06 0.0005 0.017 0.036 0.0001 0.000 0.000 0.000 0.032 0.000 0.000 beracne T"P.Iw 71-43-2 79.11 0.03478 1.164 3.717 0.0041 0,002 0.002 0.000 3.275 0.009 0.000 carbon disulfide TIw 7545-0 76.13 0.0003 0.010 0.031 0.000 0.000 0.000 0.000 0.028 0.000 0.000 carbon[e[nrchlorideT"P'Iw 56-23-5 153.94 0.0314 1.051 6.610 0.007 0.003 0.004 0.000 5.824 0.016 0.001 carbonyl sulfide"' 463-58-1 60.07 0.49 16.394 40.277 0.044 0.019 0.027 0,000 35.486 0.097 0-0D4 chlombcnTcnc TAP,nw 109-90-7 112.56 0.0002 0.007 0.031 0.000 0.000 0.000 0.000 0.027 0.000 0.000 chlaroe(hanelw 75.00-3 64.52 0.0002 0.007 0.018 0.000 0.0001 0.000 0.000 0.016 0.000 0.000 chlomfb-T"".1 67-W3 119.39 0.00031 0.010 0.049 0.000 0.000 0.000 0.000 0.043 0.0D0 0.000 chloronndhaoe:Iw 74-87-3 50.49 0.00011 0.003 0.007 0.000 0.000 0.000 0.000 O.D06 0.000 0.000 dichlombeozene""p'" 95-50-1 147.00 0.0003 0.010 0.0601 0.000 0.000 0.000 0.000 0.053 0.000 0.000 diddorodifluoromethme TAP 75-71-8 120.91 2.65109 88.699 438.620 0.483 0.193 0.290 0.006 396.449 1.059 0.044 didilorofluomncibiane TAP 7543-4 102.92 2.62 97.659 368.990 0.406 0.163 0.244 0.005 325.093 0.891 0.037 dichloromcthane T"P.Iw 754)9-2 94.94 0.0001 0.003 0.012 0.000 0.000 0.000 0.000 0.010 0.000 0.000 ethyl mercaptan 1"p 75-08-1 62.13 2.28 76.284 193.838 0.213 0.085 0.128 0.003 170.782 0.468 0.019 eth Ibeomn 10D-41-4 106.16 0.0003 0.010 0.044 0,000 0.000 0.000 0.000 0.038 0.000 0.000 ethylene dibronnide TM,11 106-93-4 197.88 0.0002 0.007 0.051 0.000 0.000 0.000 0.000 0.045 0.000 0.000 hexane TAP'Iw 110-54-3 96.18 0.10332 3.524 12A20 0.014 0.005 0.008 0.000 10.943 0.030 0.001 hydrogen sulfide TM 77834)6-04 34.08 35.5 1187.750 1655.502 1.823 0.729 1.094 0.022 1459.592 1 3.996 0.167 rnerwry and can undr lw 743-99-76 200.61 2.92E-04 0.010 0.090 0.000 0.000 0.000 0.000 0.071 0.000 0.000 methyl ethyl ketone TAP'Iw 7843-3 72.11 2.38379 86.448 254.950 0.281 0.112 0.168 0.001 224.625 0.615 0.026 methyl isobutyl ketone TAP'1w 108-10-1 100.16 0.0002 0.007 0.027 0.000 0.000 0.000 0.000 0.024 0.000 0.000 methyl rnerca tan TM 74-93-1 48.11 2.49 83.310 163.922 0.181 0.072 0,108 0.002 144.424 0.396 0.016 mhlometh Icne T"P.Iw 127-186 165.93 0.03308 1.107 7.506 0.008 0.003 0.005 0.000 6.614 0.018 0.001 toluene TAP,Iw 108-88-3 92.13 0.08036 2.699 10.131 0.011 0.004 0.007 0.000 8.926 0.024 0.001 ;k or:lenne TA u" 79-016 131.39 0.0002 0.007 0.036 0.000 0.000 0.000 0.000 0.032 0.000 0.000 vin(chloride TAP'- 75-01-4 62.50 0.3983 13.326 34.064 0.039 0.015 0.023 0.000 30.012 0.082 0.003 lanes T"P.Iw 1330-20-7 106.16 0.03176 1.063 4.614 0.005 0.002 0.003 0.000 4.065 0.011 0.000 tricldommaafluoronlethane 7569.4 137.37 0.05382 1.901 10.117 0.0111 0.004 0.007 0.000 8.913 0.024 0.001 Ethyl Acetate 141-786 88.11 1.14%4 39.459 138.578 0.153 0.061 0.092 0.000 122.095 0.335 0.014 Styrene 10042-5 1 104.15 0.00406 0.136 0.579 0.001 0.1100 0.000 0.000 0.510 0.001 0.000 I4-0)chlomb=-e 10646-7 147.1q 00003 0.010 t.060 0.000 0.000 0.000 0.000 0.053 0.000 0.000 Total HAPsfrAPs 3349.753 3.689 1.4761 2.213 0.039 Nola: I.(Xp)-Volumebic misnon nle of the poll,l L AP-42 Swum 2.4 equation(3). 2.M(p)-Mau gmmtion of pollu t If m mllmtion odala,this is Jan egad b the meta emiuion nb of the pollunnt.AP42 cyuatim(4). 3.FM(p)-Fugitive minion rang fmm the lvd011 surf 4.M(p)-FM(p)-Quantilyof)W'adeh-e dW(heeanlmldevm S.Pallet WI conemtntims u.d to compuk the aU.Jed emiuioru am f J..pmif,.camping end the LPAb AP42 S«lion 2.4 Tabk 2.4-1 and Tabk 2A-2. 6.The Imdfill get kmpcnlurt wet.1,W d fmm AP42 Smtion 2.4. 7.The AP42 Sedmi 2A&&O for Ilan I eta t m Eff,6m y wet w .d. T"r dmde mnpmnda gut am clsui..d u W i..4 pollulmu per APA2 and CAA Smaon It 2. iw cl o mmpaunda d t am clauifid u haurdms air poliulan"per AP42 and CAA Section 112. -The mmpo.da find above vmo mmpiW f AP42(.,id Nov.1999)and CAA Smtim 112. East Carolina Regional Solid Waste Landfill 2008 Emission Inventory Documentation Internal Combustion Engines Parameter I Value I Units jBasis Engine rating 147 hp Rating of combined engines Hours of operation 3000 hours Combined hours for all engines Annual diesel fuel consumption --8,MD gallons Combined consumption for all engines Compound _ .,.Fuel Use. Emission Factor Dest Eft Emission Rate Basis/Reference Value Units Value I Units % Ibsthr tpy or Ibs/yr I'I Nitrogen Oxides NOx 147 h hr/hr 0.031 Ibs/h hr N/A 4.557 6.836 AP42 Fifth Edition,Table 3.3-1 Carbon Monoxide CO 147 h hr/hr 0.00668 Ibs/h hr N/A 0.982 1.473 AP42 Fifth Edition,Table 3.3-1 Part.Matter<10 microns PM10 147 h hr/hr 0.00022%/h hr N/A 0.032 0.049 AP-42 Fifth Edition,Table 3.3-1 Non-Methane O anic Carbon NMOC - �. aa; ,. . «.., Volatile Organic Carbon(VOC) 147 h hdhr 0.00251 Ibs/h hr �N/A 0.369 0.553� AP42 Fifth Edition Table 3.3-1 Sulfur Dioxide(S02) 147 hp-hrmv 0.00205 Ibs1hp-hr N/A 0.301 0.452 AP-42 Fish Edition,Table 3.3-1 Total HAPs N/A 0.031 93.5 Sum of Hazardous Air Pollutants below Acetaldehyde 147 h hr1hr 5.37E-06 Ibsrn hr N/A 0.001 2.4 AP-42 Fifth Edition,Table 3.3-2;convert to Ibsen hr using 7,000 Btum hr Acroiein 147 h hr/hr 6.48E-07 Ibs/h hr N/A 0.000 0.3 APJ2 Fifth Edition Table 3.3}2;convert to Ibwb hr using 7,000 BNm hr Benzene 147 h hr/hr 6.53E-06 Ibs/h hr N/A 0.001 2.9 AP-42 Fifth Edition Table 3.3-2;convert to Ibsen hr using 7,000 Btum hr 1 3-Butadiene 147 h hr/hr 2.74E-07 Ibs/h hr N/A 0.000 0.1 AP-42 Fifth Edition,Table 3.3-2;convert to Item hr using 7,000 Btu/h r Formaldehyde 147 h hr/hr 826E-06 Ibs/h hr N/A 0.001 3.6 AP42 Fifth Edition Table 3.3-2;convert to Ibsen r using 7,000 Btu/h hr Propylene 147 h hr/hr 1.81E-05 Ibs/h hr N/A 0.003 8.0 AP42 Fifth Edition,Table 3.3-2;convert to Ibsen r using 7,000 Bhrm hr Toluene 147 h hr/hr 2.86E-I Ibs/h hr N/A 0.000 1.3 AP42 Fifth Edition Table 3.3-2;convert to Ibsen r using7,000 Blum hr Total PAHs 147 h hr/hr 1.68E-04 Ibs/h hr N/A 0.025 74.1 AP�2 FiM Edition Table 3.3-2;convert to Ibsen hr u 7,000 Blum hr Xylenes 147 hp-hr/hr 2.00E-06 IbsRl�hr N/A 0.000 0.9 AP42 Fifth Edition,Table 3.3-2;convert to Ibsmphr using 7,000 Bh�hµhr (1) tons per year for criteria pollutants and pounds per year for HAPs Diesel Storage Tank The tank VOC emissions were calculated using the TANKS 4.0 software program. TANKS 4.0 Inputs (Distillate fuel oil no.2 selected) Tank Dimensions(Horizontal Tank) Shell Length(ft): 17 feet Diameter(ft) 5 feet Volume(gallons) 2500 gallons Turnovers 24 Net Throughput(gal/yr): 60000 gallons/year Is tank heated(y/n): N Is tank underground(y/n): N Paint Characteristics Shell Color/shade: White/white Shell Condition: Good Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig): 0.03 Meteorological Data used in Emissions Calculations: Raleigh,North Carolina(Avg Atmospheric Pressure=14.53 psia) Results Losses(Ibs) Workin Breath in Total Distillate fuel oil no.2 1.26 0.48 1.74 NOTE: All VOC emissions are assumed to be HAPs(assigned as benzene) TANKS 4.0 Report Page 1 of 5 TANKS 4.0.9d Emissions Report - Detail Format Tank Indentification and Physical Characteristics Identification User Identification: diesel storage tank_ECRL City: Aulander State: North Carolina Company: Republic Type of Tank: Horizontal Tank Description: Tank Dimensions Shell Length (ft): 17.00 Diameter(ft): 5.00 Volume(gallons): 2,500.00 Turnovers: 24.00 Net Throughput(gal/yr): 60,000.00 Is Tank Heated (y/n): N Is Tank Underground(y/n): N Paint Characteristics Shell Color/Shade: White/White Shell Condition Good Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig) 0.03 Meterological Data used in Emissions Calculations:Raleigh,North Carolina(Avg Atmospheric Pressure=14.53 psia) file://C:\Program Files\Tanks409d\summarydisplay.htm 6/17/2009 TANKS 4.0 Report Page 2 of 5 TANKS 4.0.9d Emissions Report - Detail Format Liquid Contents of Storage Tank diesel storage tank_ECRL - Horizontal Tank Aulander, North Carolina Liquid Daily Liquid Surf. Bulk Vapor Liquid Vapor Temperature(deg F) Temp Vapor Pressure(psia) Mol. Mass Mass Mol. Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. Fract Weight Distillate fuel oil no.2 All 61.17 55.60 66.73 59.30 0.0068 0.0056 0.0082 130.0000 188.00 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/17/2009 TANKS 4.0 Report Page 3 of 5 TANKS 4.0.9d Emissions Report - Detail Format Detail Calculations (AP-42) diesel storage tank_ECRL - Horizontal Tank Aulander, North Carolina Annual Emission Calcaulations Standing Losses(lb): 0.4752 Vapor Space Volume(cu ft): 212.6078 Vapor Density(lb/cu ft): 0.0002 Vapor Space Expansion Factor. 0.0388 Vented Vapor Saturation Factor. 0.9991 Tank Vapor Space Volume: Vapor Space Volume(cu ft): 212.6078 Tank Diameter(ft): 5.0000 Effective Diameter(ft): 10.4058 Vapor Space Outage(ft): 2.5000 Tank Shell Length(ft): 17.0000 Vapor Density Vapor Density(lb/cu ft): 0.0002 Vapor Molecular Weight(IbAb-mole): 130.0000 Vapor Pressure at Daily Average Liquid Surface Temperature(psis): 0.0068 Daily Avg.Liquid Surface Temp.(deg.R): 520.8354 Daily Average Ambient Temp.(deg.F): 59.2833 Ideal Gas Constant R (psia cuft/(lb-mol-deg R)): 10.731 Liquid Bulk Temperature(deg.R): 518.9733 Tank Paint Solar Absorptance(Shell): 0.1700 Daily Total Solar Insulation Factor(Btu/sqft day): 1,393.0797 Vapor Space Expansion Factor Vapor Space Expansion Factor. 0.0388 Daily Vapor Temperature Range(deg.R): 22.2671 Daily Vapor Pressure Range(psia): 0.0026 Breather Vent Press.Setting Range(psia): 0.0600 Vapor Pressure at Daily Average Liquid Surface Temperature(psla): 0.0068 Vapor Pressure at Daily Minimum Liquid Surface Temperature(psia): 0.0056 Vapor Pressure at Daily Maximum Liquid Surface Temperature(psia): 0.0082 Daily Avg.Liquid Surface Temp.(deg R): 520.8354 Daily Min.Liquid Surface Temp.(deg R): 515.2687 Daily Max.Liquid Surface Temp.(deg R): 526.4022 Daily Ambient Temp.Range(deg.R): 21.7167 Vented Vapor Saturation Factor Vented Vapor Saturation Factor. 0.9991 Vapor Pressure at Daily Average Liquid: Surface Temperature(psia): 0.0068 Vapor Space Outage(ft): 2.5000 Working Losses(lb): 1.2613 Vapor Molecular Weight(lb/lb-mole): 130.0000 Vapor Pressure at Dally Average Liquid Surface Temperature(psia): 0.0068 Annual Net Throughput(gal/yr.): 60,000.0000 Annual Turnovers: 24.0000 Turnover Factor: 1.0000 Tank Diameter(ft): 5.0000 Working Loss Product Factor: 1.0000 Total Losses(lb): 1.7364 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/17/2009 TANKS 4.0 Report Page 4 of 5 TANKS 4.0.9d Emissions Report - Detail Format Individual Tank Emission Totals Emissions Report for: Annual diesel storage tank_ECRL - Horizontal Tank Aulander, North Carolina Losses(lbs) Components Working Loss Breathing LossI Total Emissions Distillate fuel oil no.2 1.26 0.48 1.74 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/17/2009 TAN t.0 Report Pag )f 6 TANKS 4.0.9d Emissions Report- Detail Format Tank Indentification and Physical Characteristics Identification User Identification: ECL250,000GAL_2009 City: NORTH_ CAROLINA State: AULANDER Company: REPUBLIC Type of Tank: Vertical Fixed Roof Tank Description: Tank Dimensions Shell Height(ft): 30.00 Diameter(ft): 40.00 Liquid Height(ft): 29.00 Avg.Liquid Height(ft): 29.00 Volume(gallons): 250,000.00 Turnovers: 16.00 Net Throughput(galtyr): 4,000,000.00 Is Tank Heated(y/n): N Paint Characteristics Shell Color/Shade: White/White Shell Condition Good Roof Color/Shade: White/White Roof Condition: Good Roof Characteristics Type: Dome Height(ft) 0.00 Radius(ft)(Dome Roof) 0.00 Breather Vent Settings Vacuum Settings(psig): -0.03 Pressure Settings(psig) 0.03 Meterological Data used in Emissions Calculations:Raleigh,North Carolina(Avg Atmospheric Pressure=14.53 psia) file://C-.Wrogram Files\Tanks409d\summarydisplay.htm 6/15/2009 TAN W Report Pag( )f 6 TANKS 4.0.9d Emissions Report- Detail Format Liquid Contents of Storage Tank ECL_250,000GAL_2009 -Vertical Fixed Roof Tank NORTH CAROLINA,AULANDER Liquid Daily Liquid Surf. Bulk Vapor Liquid Vapor Temperature(deg F) Temp Vapor Pressure(psia) Mal. Mass Mass Mal. Basis for Vapor Pressure Mixture/Component Month Avg. Min. Max. (deg F) Avg. Min. Max. Weight. Fract. FracL Weight Calculations LANDFILL LECHATE All 61.17 55.60 66.73 59.30 0.3679 0.2635 0.5112 25.0200 34.40 r I file://C:\Program Files\Tanks409d\summarydisplay.htm 6/15/2009 TAN 1.0 Report Pagl )f 6 TANKS 4.0.9d Emissions Report - Detail Format Detail Calculations (AP-42) ECL_250,000GAL_2009 -Vertical Fixed Roof Tank NORTH CAROLINA,AULANDER Annual Emission Calcaulations Standing Losses(lb): 147.6103 Vapor Space Volume(cu ft): 4,704.3694 Vapor Density(lb/cu ft): 0.0016 Vapor Space Expansion Factor. 0.0560 Vented Vapor Saturation Factor: 0.9320 Tank Vapor Space Volume: Vapor Space Volume(cu ft): 4,704.3694 Tank Diameter(ft): 40.0000 Vapor Space Outage(ft): 3.7436 Tank Shell Height(ft): 30.0000 Average Liquid Height(ft): 29.0000 Roof Outage(ft): 2.7436 Roof Outage(Dome Roof) Roof Outage(ft): 2.7436 Dome Radius(ft): 40.0000 Shell Radius(ft): 20.0000 Vapor Density Vapor Density(lb/cu ft): 0.0016 Vapor Molecular Weight(lb/lb-mole): 25.0200 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.3679 Daily Avg.Liquid Surface Temp.(deg.R): 520.8354 Daily Average Ambient Temp.(deg.F): 59.2833 Ideal Gas Constant R (psia cuft/(lb-mol-deg R)): 10.731 Liquid Bulk Temperature(deg.R): 518,9733 Tank Paint Solar Absorptance(Shell): 0.1700 Tank Paint SolarAbsorplance(Roof): 0.1700 Daily Total Solar Insulation Factor(Btu/sgft day): 1,393.0797 Vapor Space Expansion Factor Vapor Space Expansion Factor: 0.0560 Daily Vapor Temperature Range(deg.R): 22.2671 Daily Vapor Pressure Range(psia): 0.2477 Breather Vent Press.Setting Range(psia): 0.0600 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.3679 Vapor Pressure at Daily Minimum Liquid Surface Temperature(psia): 0.2635 Vapor Pressure at Daily Maximum Liquid Surface Temperature(psia): 0.5112 Daily Avg.Liquid Surface Temp.(deg R): 520.8354 Daily Min.Liquid Surface Temp.(deg R): 515.2687 Daily Max.Liquid Surface Temp.(deg R): 526.4022 Daily Ambient Temp.Range(deg.R): 21.7167 Vented Vapor Saturation Factor Vented Vapor Saturation Factor: 0.9320 Vapor Pressure at Daily Average Liquid: Surface Temperature(psis); 0.3679 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/15/2009 TAN 4.0 Report Pagi )f 6 Vapor Space Outage(ft): 3.7436 Working Losses(lb): 876.6531 Vapor Molecular Weight(IbAb-mole): 25.0200 Vapor Pressure at Daily Average Liquid Surface Temperature(psia): 0.3679 Annual Net Throughput(gal/yr.): 4,000,000.0000 Annual Turnovers: 16.0000 Turnover Factor: 1.0000 Maximum Liquid Volume(gal): 250,000.0000 Maximum Liquid Height(ft): 29.0000 Tank Diameter(ft): 40.0000 Working Loss Product Factor. 1.0000 Total Losses(lb): 1,024.2634 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/15/2009 TAN 1.0 Report Paq( )f 6 TANKS 4.0.9d Emissions Report - Detail Format Individual Tank Emission Totals Emissions Report for: Annual ECL_250,000GAL_2009 -Vertical Fixed Roof Tank NORTH CAROLINA, AULANDER Losses(Ibs) Components =1Working Loss Breathing Loss Total Emissions LANDFILL LECHATE =1 876.65 1 147.61 1,024.26 file://C:\Program Files\Tanks409d\summarydisplay.htm 6/15/2009 i East Carolina Regional Solid Waste Landfill 2008 Emission Inventory Documentation Welding Assume worst case conditions as listed in Title V Permit Application (same approach as last year) 5000 Ibs welding rods used in 2003 0.0202 Ibs fumes/Ibs welding rods (from Title V application) 101 Ibs total fumes (assume to be all HAPs, manganese)