AQ_F_0800044_20110420_EI_Cmb-EI-File

Facility Total CY 2010.Emission Summary Recorded in D Facility ID #: 0800044
Facility Name: Avoca Incorporated L' va CRY Permit#(s): 01819T38
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr % Change
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Nitrous Oxide (N20) 10024972 0.038100 0.047500 -19.8%
Methane (CH4) 74-82-8 0.019800 0.024700 -19.8%
Carbon Dioxide (CO2) 124389 7,200.16 8,967.15 -19.7%
CO2 equivalent (sum of individual GHG pollutant emission times their 6,543.08 metric tons
1995 IPCC Global Warming Potential (GWP), converted to metric tons)
Criteria Pollutants Actual Emissions % Change
(Tons/Year)
Pollutant CAS CY 2010 CY 2009
from ED I from Fees
CO Co 1.90 2.37 -19.8%
NOx Nox 9.07 11.33 -19.9Iyo
PM(TSP) TSP 0.730000 0.920000 -20.7%
PM10 PM10 0.420000 0.520000 -19.2%,
PM2.5 PM2.5 0.180000 0.230000 -21.7%
S02 S02 13.60 16.94 -19.7%,
VOC VoC 231.31 309.15 -2.5.2%
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Polycyclic Organic Matter (Specific Compounds from OAQPSfor 0.876450 1.09 -19.6` ;
T i)
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000130 0.000160 N/A
5655317PAH)
Naphthalene (Component of 833291POMTV) 91-20-3 0.876320 1.09 -19.80%
Polycyclic Organic Matter (7 PAH Compounds for NIF) 0.000130 0.000160 N/A
WaRO Copy
08/01/201 1 Page 1 of 4

Facility Total CY 2010 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Polycyclic Organic Matter (7 PAH Compounds for NIF) 0.000130 0.000160 N/A
Benzo(a)pyrene (Component of 833291POWV& 50-32-8 0.000130 0.000160 N/A
5655317PAH)
Nickel& Compounds, sum total mass includes elemental 1.61 2.00 -19.5
Nickel Unlisted Compounds (Component of NIC- N1C-Other 1.61 2.00 -19.70%
Specify)
Mercury & Compounds -all total mass includes Hg Vapor 0.268160 0.333970 -19.7%
Mercury Unlisted Compounds -Specify Compound HGC-Other 0.268160 0.333970 -19.7%
(Component of HGC)
Manganese & compounds 1.25 1.56 -19.9io
Manganese Unlisted Compounds -Specify MNC-Other 1.25 1.56 -1.9.7%
Compound(Component of MNC)
Lead& compounds 0.795540 0.990760 -19.7%
Lead Unlisted Compounds - Specify Compound PSC-other 0.795540 0.990760 -19.7%,
(Component of PBC)
Chromium (VI)Non-Specific Compounds, as Chrom(VI) 0.018590 0.023150 -19.7%
(Component CRC)
Chromium (VI) Non-Specific Unlisted Compounds - NSCR6-other 0.018590 0.023150 -19.7%)
Specify Compound(Component of NSCR6 & CRC)
Chromium-AIL/Total (includes Chromium (VI) categories, metal 5.20 6.48 -19.8%
and others)
Chromium (VI) Non-Specific Unlisted Compounds - NSCR6-Other 0.018590 0.023150 -19.70%
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds - Specify CRC-Other 5.18 6.46 -19.70%
Compound(Component of CRC)
Cadmium & compounds (total mass includes elemental metal) 0.982620 1.22 -19.5%
Cadmium Unlisted Compounds - Specify Compound CDC-Other 0.982620 1.22 -19.7%)
(Component of CDC)
08/01/2011 Page 2 of 4

Facility Total CY 2010 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Beryllium & compounds (Total mass) 0.223470 0.278300 -19.7%
Beryllium Unlisted Compounds -Specify Compound BEC-other 0.223470 0.278300 -19.7'%)
(Component of BEC)
Arsenic & Compounds (total mass of elemental AS, arsine and all 0.375420 0.467550 -19.7%
inorganic compounds)
Arsenic Unlisted Compounds -Specify Compound ASC-Other 0.375420 0.467550 -19.7%
(Component of ASQ
Acetaldehyde 75-07-0 0.507600 0.643470 -21.1`%o
Acrolein 107-02-8 0.061530 0.077990 -21.1'%
Benzene 71-43-2 0.754390 0.953290 -20.9%,
Chloroform 67-66-3 6,498.00 Not N/A
Reported
Ethyl acetate 141-78-6 13,423.58 11,446.56 17.30/0
Ethyl benzene 100-41-4 0.040310 0.050210 -19.7`%
Formaldehyde 50-00-0 21.70 27.04 -19.8`%►
Hexane isomers, except n-hexane HEXANEISO 317,924.35 503,760.02 -36.9%
Hexane, n- 110-54-3 105,072.54 53,480.12 96.50/0
Methanol (methyl alcohol) 67-56-1 23,366.46 44,782.05 -47.8%
Toluene 108-88-3 4.20 5.24 -19.8%
Xylene (mixed isomers) 1330-20-7 0.188520 0.238980 -21.1%
Xylene, o- 95-47-6 0.069100 0.086050 -19.70/0
Largest Individual HAP Hexane, n- 105,072.54
lbs
Total HAP Emissions 134,976.11
lbs
08/01/201 1 Page 3 of 4

DAQ's Comments Regarding Inventory
facility asked that DAQ adjust methonal number reported too large. done
08/01/2011 Page 4 of 4

• .
Hopkins, Arni
From: Brian Conner[[e-mail]]
Sent: Thursday, July 21, 2011 9:59 AM
To: Hopkins, Arni
Subject: Avoca AERO Questions
Hey Arni,
I had a message from you asking about the 2009 vs. 2010 n-hexane and Methanol emissions in Avoca's AERO report.
In 2009 we ran the rotocel and recovery operations(sage harvest)for 67 days. In 2010 we ran the rotocel and recovery
(sage harvest) for 39 days.The rotocel and recovery process uses hexane solvent that contains less than 1% n-hexane.
Methanol is used in the recovery process. The decrease in methanol during 2010 form 2009 is due to the fewer days of
operation in 2010.
However we show an increase in the n-hexane emissions for 2010 vs. 2009.The increase in n-hexane emissions is due to
the increase in the amount of further processing that occurs with the sage material in the other processes
(SFG/Recrystallization and Sclareolide).The lag in the next steps in the process after the original rotocel and recovery
operations can take several months to occur.Therefore much of the sage that was originally processed in the rotocel
and recovery in 2009 was not further processes until 2010 in SFG and Sclareolide. SFG uses the 90% n-hexane and
Sclareolide uses 32% n-hexane so n-hexane emissions will be higher with these processes than with the rotocel and
recovery. SFG ran for 125 days in 2009 and 308 days in 2010.Sclareolide ran for 107 days in 2009 and 258 days in 2010.
This explains the major increase in n-hexane emissions in 2010 over 2009.
If you have any more questions or need more information on this, please feel free to contact me.
Thanks.
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
1
1

Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2010
These forms must he completed and returned even if the facility did not operate or emissions were zero
The legally defined"Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship; a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION STATEMENT:
r t nt: Legally Resl2on5ible Official.read and sign after all s z mi
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to $25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Signature w use blue ink): Date Signed: otO o20
Printed Name: David Peele
,Signature:
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: david.peele@avocaine,com
Information on this Form cannot be held confidential
1

Annual Air Emissions Inventory Summary _
2010 Totals Facility ID#:0800044
Plant Pollutant Boiler 07 Boiler ir2 Boller N3 Gen Mi Gen N2 Gen p3 Gen p4 Pk-Gen Rotocel Recove Recrystallizetion Sclareoltde Biomass Botanical Other
ry (SFG) (SDE) Extraction Extraction Nutrient EVG WWTP Processes Totals Units
Extraction
CO 2731.21 2383.65 2080.47 0.38 0.63 0.77 0.00 3.06 1 7200.162 1 Tons/Yr
Methane 0,00722 0.00630 0.00550 0.00006 0.00010 0.00012 0600000 0.00049 0.020 TonslYr
NitrousT Oxk1e 0.01444 0.01260 0.01100 0.00001 0.00001 0.00002 0.00000 0.00007 0.020 Tons/Yr
M-1 0,2406349 0.210013 0.1833011 0.008031713 0.013386188 0.01639125 0 0.06490935 0.737 TonslYr
PM-10 MM722
45 0.1050065 0.09165055 0.008031713 0.013386188 0.01839125 0 0.D6490935 0.420 Tons/Yr
PM-2.5 3113 0.026251625 0.022912638 0.008031713 0.013388188 0.01839125 0 0.06490935 OA20 TonslYr
Sox 337 4.4732769 3.9D431343 0.007513538 0.012522563 0.01533375 0 0.06072165 13.599 TonslYr
Nox 88 2.520156 2.1996132 0.114257588 0.190429313 0.23317875 0 0.92338785 9.069 TonsKr
VOC 49 0.0210013 0.01833011 0,00932715 0.01554525 0.019035 0 0+0753786 2.2238 9.1 42..6825 48.41 31.8175 0 1.58229.050 TonsNr
CO 25 0.5250325 0.45825275 0.024613313 0.041022188 0.05023125 0 0.19891575 1.900 Tons/Yr
Acetrolei a0.039744023 -0.066240038 0.08111025 0 0.32119659 0.500 Lbs/Yr
Acrolein0.OD4793119 0.007988531 0.009781875 0 0.038736225 0.061 Lbs/Yr
Arsenic 988 0.124369699 0.1085509110.375 Lbs/Yr
enzene 059 0.045005788 0.039281428 0.048345728 0.060576213 0.09868475 0 0.39071241 0.754 Lbs/Yr
Benzo a rene 9.74189E-O6 1.62362E-05 0.000019681 0 7.87288E-05 00.754 Lbs/Yr
Be Ilium O.OB4823802 0.074029583 0.064613638
Butanol 0.223 LbslYr
Cad.ium 0.372984095 0.32552015 0.284116705
0.DO 0.000 Lbs/Yr
Calcium hydroxide 0.983 Lbs/Yr
Chloroform 0.00 0.000 Lbs/Yr
Chromium 1.967912212 1.717488314 1.499036396
7848 1 0.00 7848.000 LbslYr
Chromium IV 0.006978412 0.006090377 0.005315732
5.184 Lbs/Yr
Ethanol-100% 0,018 Lbs/Yr
206.272 Lbs/Yr
�0 Ethanol Ethyl
a-SDA - 189.30 2312.4 0. 2501.752 Lbs/Yr
Ethyl
acetate 94 0 312. - 13.58 13423,580. 2Lbs/Yr
Eth(benzene 0.015280318 0.013335828 0.01183962 Lbs/Yr
FOnnaElh lenediamineOmO4O
_ F 0 0.000 Lbs/Yr
Hexane Isomers
de 7.939507691 6.929768922 8.047836493 0.06114465 0.10190775 0.124785 0 0.4941486 21.698 Lbs/Yr
Hexane Isomers "183857.4T7 381s.0o75 63515.2 83526.82 0 3205.948 317924.426 Ltu/1'r
N-Hexane
Heane Isomers 71063.4925 33306.768 108.1795 0 1 3.85176 V 105072.524 Lbs/Yr
N-He tans 0.00 - 0.000 Lbs/Vr
Isobut lacetate 0.00 0.000 Lbs/Yr
Iso ro l acetate 0 0.00 0.000 LbslYr
Lead Com unds 0.301972736 0.283545314 0.23002455
0.00 0.000 Lbs/Yr
0
Manganese 0.475013293 0.414565662 0.361836371 0.796 Lbs/Yr
Mercury tha 0.101788583 0.088835499 0.077536365
_ 0 1.251 Lbs/Yr
Methanol -' 0.268 lbs/Yr
18265.96' 7 2 1390.62 3182.12 23368.422 Lbsll'r
Na lhalene 0.311405624 0.271777823 0.237209954 0.004394124 0.00732354 0.0089678 0 0.035511898 - 0.677 LbslYr
Nickel 0.610731376 0.533012994 0.485218192
Sulfur Dioxkle 1.809 Lbs/Yr
Toluene 1.49289892 1.302920652 1 1.137200024 1 0.021193358 1 0.035322263 0.04 225175 0 0.17127693 0.00 0.000 Lbs/Yr
X lane 0.00 4.204 Lbs(Yr
0.014767988 0.024613313 0.03013875 0 0.11934945 0.189 Lbs/Yr
o-X lane 0.028205141 0.022870418 0.01996148
0.089 LDs/Yr

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4, OS-5, OS-6, OS-10, OS-28, OS-29
OS-13 OS-14 OS-15 OS-16 OS-17 OS-20 OS-21 OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH OS-10:OS-30 INCLUDED WITH OS-28
Year: 2010
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month Bn 9enning Received Mbs ax Used Ending Inventory
January: 6272 4092 57002 1933 8431
February: 8431 46371 1116 7315
March: 7315 40233 1425 5890
April: 5890 4352 56331 1025 9217
May: 9217 50694 1043 8174
June: 8174 44957 1695 6479
July: 6479 4349 59554 1483 9345
August: 9345 51398 1454 7891
September: 7891 4352 67337 1624 10619
October: 10619 58405 1096 9523
November: 9523 52377 2095 7428
December: 7428 4515 65687 1615 10328
Monthly Inventory of HP Hexane-95%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 2743 15087 1156 1587
February: 1587 8729 679 908
March: 908 5949 37714 1253 5604
April: 5604 30822 1013 4591
May: 4591 25251 1213 3378
June: 3378 18579 1046 2332
July: 2332 12826 1728 604
August: 604 6012 36388 1265 5351
September: 5351 29431 1441 3910
October: 3910 21505 1100 2810
November: 2810 15455 900 1910
December: 1910 10505 821 1089
Monthly Inventory of IsoHexane-2.5%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 36006 8458 244552 4382 40082
February: 40082 8162 265342 6238 42006
March: 42006 231033 970.4 41036
April: 41036 225696 41036
May: 41036 225696 41036
June: 41036 25991 368646 18874 48153
July: 48153 9378 316418 15584 41947
August: 41947 230706 41947
September: 41947 230706 258.2 41688
October: 41688 229286 41688
November: 41688 229286 41688
December: 41688 229286 41688

Page 2 of 4
Total Hexane Values
Gallons of LP Hexane Used: 17604.00 Gallons of N-Hexane Used: 18646.25
Gallons of HP Hexane Used: 13615.00 Lbs.of N-Hexane Used: 102554.38
Gallons of IsoHexane Used: 46306.60 Gallons of Hexane Isomers Used: 58879.35
Total Gallons of Hexanes Used: 77525.60 Lbs.of Hexane Isomers Used: 323836.42
Total Lbs.of Hexanes Used: 426390.8
Sclareolide(SDE)Operation:OS-5
Percent N-Hexane in Solvent: 34.4
Gallons of Hexane Used in SDE: 17604.00 , : Lbs.of Fugitive Hexane from SDE: 95407.32
Lbs.of Hexane Used in SIDE: 96822 Lbs.of Fugitive N-Hexane from 32820.12
SDE:
Lbs.of SDE Product: 282936.36 Lbs.of Fugitive Hex Isomers from 62587.20
SDE:
Lb.Hexane per Lb.of SDE
0.005
Product:
Lbs.Hexane in SDE Product: 1414.68
Lbs.N-Hexane in SDE Product: 486.65
Accountable Lbs.of Hexane Lost: 1414.68 Accountable and Fugitive Lbs. 96822.00
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 486.65 Accountable and Fugitive Lbs. 33306.77
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 928.03 Accountable and Fugitive Lbs.Hex 63515.23
Lost: Isomers Emitted:
Lbs.of Hexane Sent as 12480
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 3993.6
Waste:
Lbs.of Hex Isomers in Hazardous 8486.4
Waste:
Sclareol Recrystallization(SFG)Operation:OS-6
Percent N-Hexane in Solvent: 94.9
Gallons of Hexane Used in SFG: 13615.00 l' Lbs.of Fugitive Hexane from SFG: 73224.19
Lbs.of Hexane Used in SFG: 74882.5 Lbs.of Fugitive N-Hexane from 69489.75
SFG:
Lbs.of SFG Product: 331663 .' Lbs.of Fugitive Hex Isomers from 3734.43
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 1658.315
Lbs.N-Hexane in SFG Product: 1573.74
Accountable Lbs.of Hexane Lost: 1658.32 Accountable and Fugitive Lbs. 74882.50
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 1573.74 Accountable and Fugitive Lbs. 71063.49
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 8457 Accountable and Fugitive Lbs.Hex 3819.01
Lost: . Isomers Emitted:
Lbs.of Hexane Sent as
14280
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 13566
Waste:
Lbs.of Hex Isomers in Hazardous 714
Waste:

Page 3 of 4
Rotocel,Concrete,&Recovery Operations:OS-4
Gallons of Hexane Used: 34153.00 Gallons sent to WWT: 771298
Lbs.of Hexane Used: 187841.5 Lbs.Waste Water per Gal.Waste 8,34
Water:
Percentage of N-Hexane in a
0.32 Wt/o of Hexane in Waste Water: 0.014
Solvent:
Lbs.of Hexane Sent as
3393.85 Lbs.Hexane Lost in Waste Water: 900.57
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 10.86 Lbs.N-Hexane Lost in Waste 2.88
Waste: Water:
Lbs.of Hex Isomers in Hazardous 3382.99 Accountable Lbs.of Hexane Lost: 24225.99
Waste:
Lbs.Hex per day exiting Mineral
Oil Scrubber from MO tests: 47.98` Accountable Lbs.of N-Hex Lost: 77.52
Accountable Lbs.of Hex Isomers
Days of MO Unit operation: 45 Lost: 24148.46
Lbs.of Hex exiting MO Unit: 2159.1
Lbs.of N-Hex exiting MO Unit: 6.91
Lbs.of Hex Isomers exiting MO 2152.19 Total Lbs.Hexane Lost as 160221.66
Unit: Fugitive:
Lbs.Sage Processed: 16096060 Total Lbs.N-Hex Lost as Fugitive: 512.71
Lbs.Hexane per Lbs.of Spent Total Lbs.Hex Isomers Lost as
Sage(from Desolvitizer tests): 0.001315 Fugitive: 159708.95
Lbs.Hexane in Spent Sage: 21166.32
Lbs.N-Hexane in Spent Sage: 67.73
Lbs.Hexane per Day from A-1 0.000815
Vent Cond.
Days A-1 Operated: 45 Accountable and Fugitive Lbs. 184447.65
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.037 Accountable and Fugitive Lbs. 590.23
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000117 Accountable and Fugitive Lbs.Hex183857.42
Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons of Hexane Used: 11570.00 Lbs.of Fugitive Hexane from 63635
Bio Extraction:
Lbs.of Hexane Used: 63635 Lbs.of Fugitive N-Hexane from Bio 108.18
Extraction:
Lbs.of Biomass Product: 425488 Lbs.of Fugitive Hex Isomers from 63526.82
Bio Extraction:
%n-Hexane 0.17
i

Page 4 of 4
Botanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.of Fugitive N-Hexane from 0
Bot Extraction:
Lbs.of Botanical Product: Lbs.of Fugitive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction(M-13)Operation:OS-29
Gallons of Hexane Used: 583.60 Lbs.of Fugitive Hexane from 3209.8
PNE:
Lbs.of Hexane Used: 3209.8 Lbs.of Fugitive N-Hexane from 3.85176
PNE:
Lbs.of PNE Product: 373.5 Lbs.of Fugitive Hex Isomers from 05.94824
PNE:
%n-Hexane 0.12
Lbs.of Hexane Sent as 5780
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 6.936
Waste:
Lbs.of Hex Isomers in Hazardous 5773.064
Waste:
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: 106669.04 Total Lbs.n-Hexane Released: 105072.52
Fugitive Lbs.Hex Isomers 292763.36 Total Lbs.Hex Isomers Released: 317924.43
Emitted:
Accountable Lbs.n-Hexane Lost: 2137.91 Total Lbs.N-Hexane Sent Off Site: 4011.40
Accountable Lbs.Hex Isomers 25161.07 Total Lbs.Hex Isomers Sent Off 17642.45
Lost: Site:
Total Lbs.Hexane Sent Off Site: 21653.85
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month n-Hexane
(Gallons) (Gallons) (Lbs.)
January: 50100 5208 28641.9
February: 50229 4254 23394.5
March: 52530 8234 45289.7
April: 1 54844 8337 45852.3
May: 52588 6851 37678.7
June: 56964 5492 30208.7
July: 51896 4613 25370.8
August: 55189 8657 47614.8
September: 56217 8155 44851.3
October: 54021 6759 37174.9
November: 51026 5234 28785.2
December: 53105 5382 29599.5
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
56964 8657 47615

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6&OS-7
Year: 2010
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate(pounds):
Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA Alcohol
Total Beginning Beginning New Month
Month Beginning New Recovered New Used Recovered Recovered in Max Monthly Total Ending Ethyl acetate
Inventory Inventory Inventory Received Used Drums (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
January: 4899 4794 105 542.00 4899 542.0 4357 January: 7.45
February: 4357 4252 105 3272.0 570.00 7629 570.0 7059 February: 36.40
March: 7059 6954 105 628.00 7059 628.0 6431 March: 6.83
April: 6431 6326 105 748.00 ; 6431 748.0 5683 Aril: 0.11
May: 5683 5578 105 3320.0 1 895.00:." 9003 895.0 8108 May: 8.19
June: 8108 8003 105 546,00 8108 546.0 7562 June: 10.67
July: 7562 7457 105 867.00 7562 867.0 6695 July: 12.67
August: 6695 6590 105 953.00 6695 953.0 5742 August: -10.58
September: 5742 5637 105 1368.00 5742 1368.0 4374 September: 17.58
October: 4374 4269 105 3713.00 4374 3713.0 661 October: 25.77
November: 661 556 105 2275.00 661 2275.0 -1614 November: -5.20
December: -1614 -1719 105 <,artc205.00 -1614 1 205.0 -1819 December: 3.69
Lbs.of Ethyl acetate used during the year: 13423.5B /
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 3856.00
Lbs.of Ethyl acetate used in SFG:OS-6 94$4
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):OS-7 -1--f13.58'-
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(Crown Process):
Gallons sent to Hazardous Waste: 426.70
Lbs.Sent to Hazardous Waste: 6200.00
Total Lbs.of Ethyl acetate emitted during year: 13423.58

Annual Air Emissions Inventory
Facility ID#: 900044
Ethanol-SDA6S-7&OS-10
1
OS-18,OS-19,OS-27;OS-32 INCLUDED WITH OS-10
_. . Year: 20t0
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol laallonal:
Monthly Beginnina Inventory Bulk Drums
Total SDA h36.40
Total SDA Bulk SDA in Drums Max SDA on SDA to
SDA SDA SDA in Drums SDA in Drums SDA Ending SDA Used SDA Used SDA VOC
Month Beginning Beginning Beginning SDA Used Hand WWT
Inventory Inventory Inventory Received Transferred Received Used Recovered (Lbs) Inventory (gallons) (Lbs.) (Lbs) (Lbs.)
January: 38786.0 27777.8 11008:3 - 1869.8 676 288460 37592 1194 8202.1 8038.1 164.0
February: 37592.1 25908.0 11684.2 10795.0 6655.2 1480 2299 332419 42551 5836 40093.3 39291.5 801.9March: 42551.1 30047.8 12503.4 2582.0 1488 292326 41457 1095 7519.2 7368.8 150.4A ril: 41456.6 27465.8 13990.9 .17.0 284807 41440 17 116.8 114.5 2.3 Ma 41439.E 27448.8 13990.9 5456.0 1579.0266 322173 45582 1313 9023.1 8842.6 180.5 .
June: 45582.2 31325.8 14256.5 - 1620.0 264 173 313150 43871 1711 11753.2 11518.1 235.1 10.67
July: 43871A 29705.8 14165.7 2031.0 301397 41S40 2031 13953.0 13673.9 279.1 12.67
Au ust: 41840.4 27674.8 14165.7 5336.0 64.0 1760. E 324102 48872 -1896 -11651.5 -11418.5 -233.0 -10.58
September: 48872.4 32946.8 15925.7 :.5427.0 2818.0 :::XaCr 373037 51481 2818 19359.7 18972.5 387.2 17.58
October: 51481.4 35555.8 15925.7 5455.0 3863.0 1932 1664<> 391163 52805 4131 28381.3 27813.7 567.6 25.77
November: 5280542 37147.8 15657.5 5455.0 5891.0 6724-.1` 400248 59093 -833 -5722.7 -5608.3 -114.5 -5.20
December: 59093.2 36711.8 22381.5 591.0 405970 58502 591 4060.2 3979.0 81.2 3.69
Total Gallons of SDA Used: 18207.8
Total Lbs.SDA Used: 125087.6
Gallons sent to Hazardous Waste:
lbs.SDA Ethanol set to Hazardous Waste: 0.00
Total Gallons sent to WWT: 17843.64
Total Lbs.sent to WWT: 122585.83
Total SDA Ethanol VOC's 2501.75
Lbs.Botanical Extraction Ethanol Emitted:OS-10
Lbs.PNE Ethanol Emitted:OS-7 .23
Misc.Lbs.SDA Ethanol Emitted:
Total Lbs.of SDA Ethanol Emitted: 2501.75
J

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 2010
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons)
Beginning Max Ending Gallons to
Month InventoryReceived Lbs Used Recovered Inventorywwr VOC (Lbs.)
January: 4118 27110 4118 0 0
February: 4118 27110 4118 0 0
March: 4118 27110 4118 0 0
April: 4118 27110 167 650 4601 164 22
May: 4601 30288 1400 1142 4343 1372 184
June: 4343 28589 4343 0 0
July: 4343 28589 4343 0 0
August: 4343 28589 4343 0 0
September: 4343 28589 4343 0 0
October: 4343 28589 4343 0 0
November: 4343 28589 4343 0 0
December: 4343 28589 4343 0 0
Total Gallons of Ethanol Used: 1567
Total Lbs. Ethanol Used: 10313.5861
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0 n
Total Gallons sent to WWT: 1535 / `v
Total Lbs. sent to WWT: 10107.31438
Total Lbs. of Ethanol Emitted as VOC: 206
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Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: OS-4, OS-7, OS-9
OS-13 03-14 OS-15, OS-16 OS-17 OS-27 OS-32 INCLUDED WITH OS-4
Year: 2010
Info: Lbs/Gal= 6.60 Specifice Gravity=0.793
Monthly Inventory of Methanol (gallons):
Month Beginning Received Max Used Recovered Ending
Inventory Lbs Inventory
January: 16939 111797 16939
February: 16939 111797 16939
March: 16939 3190.0 132851 20129
April: 20129 5790.0 171065 3990.0 21929
May: 21929 6937.0 190516 4861.0 711.6 24717
June: 24717 6870.0 208472 4935.0 26652
July: 26652 175901 6138.0 20514
August: 20514 1320.0 144102 2670.0 19164
September: 19164 3520.0 149712 935.0 21749
October: 21749 143541 21749
November: 21749 143541 1 640.0 1 T 21109
December: 21109 139317 2300.0 18809
Maximum Gallons On-Hand: 31586.6
Maximum Lbs. On-Hand: 208471.56
Gallons Used per Year: 25757
Lbs. Used per Year: 169998.84
Sclareol Recovery Operation: OS-4
Total Lbs. McOH Used: 73303.26 Avg. % MeoH thru Pods: 85
Avg.% McOH in WW: 10.51 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 1.34 Number of Stream Days 41
Number of Stream Days: 41 Total Gal.Thru Pods: 531360
Total Gal. of WW to WWTP: 1253952 Total Gal. McOH Thru Pods: 451656
Total Lbs. of WW to WWTP: 10457959.68 Total Lbs. McOH Thru Pods: 2980929.60
Total Lbs. of McOH to WWTP: 55037.30 Total Lbs. Fugitive Emissions 18265.96
from Recovery:
Accountable Emissions of Total Accountable and Fugitve
McOH from WWTP during 1530.93 Emissions from Recovery: 19796.89
Recovery:
Avg. Removal Efficiency of
WWTP: 97.90

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 10535 Accountable Emissions of
Gallons of McOH to WWT: 10324.3 Y McOH from WWTP during 1362.81
Total Lbs.of McOH to WWT: 6 40. EVG:
Total Lbs. Fugitive Emissions Total Accountable and Fugitve 2753.43
from EVG: 1390.62 Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 4149.4 Accountable.Emissions of
Gallons of McOH to WWT: 4066.412 McOH from WWTP during 268.38
Total Lbs.of McOH to WWT: 26838.3192 PNE:
Total Accountable and Fugitve 816.10
Total Lbs. Emissions PNE: �547.7208 Emissions from PNE:
Totals for All Methanol Operations
Total Lbs. McOH Thru System: 2980929.60 Lbs.of Emissions from Misc., 547.7208Lab:
Lbs. Fugivtive Emissions from 1390.62
Total Lbs. McOH to WWTP: 150016.00 EVG:
Lbs. Fugivtive Emissions from 18265.96
Removal Efficiency of WWTP: 97.90 Recovery:
Lbs.Accountable Emissions 3162.12-`' Total Lbs. Fugitive Emissions: 20204.30
from WWTP: `
Total Lbs. McOH Treated at 150016.00 Total Lbs. McOH Released: 23366.42
WWTP:
Total Lbs. McOH Recycled On- 2807547.18
Site:

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2010
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13444 8100.0 21544 21544
February: 21544 21544 21544
March: 21544 21544 21544
April: 21544 21544 4717.0 16827
May: 16827 16827 16827
June: 16827 16827 16827
Jul : 16827 16827 16827
August: 16827 16827 1400.0 15427
September: 15427 15427 902.0 14525
October: 14525 14525 14525
November: 14525 14525 280.0 14245
December: 14245 14245 549.0 13696
Lbs. of chloroform used during the year: 7848
Lbs. of chloro. used by Misc., QA, and R&D:
Lbs. of chloro. used by EVG: 7848
Lbs. EVG Produced:
Lbs. of chloroform sent to hazardous waste: 1350
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 6498
H:\Environmental\Air PermitAr Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2010
Info: Lbs/Gal - 7.50 All ethylenediamine is contained and
Shipped off cite ,.,i+k +he —^rh,rf
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Ethylenediamine Used: 0
Total Lbs. Ethylenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethylenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Ethylenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2010
Info: Lbs/Gal = 5.70
Monthly Inventory of Heptane (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 496 2827 496
December: 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in
Solvent: 0.85
Gallons of Heptane Used in 0.00 Lbs. of Fugitive Heptane 0.00
SFG: from SFG:
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane 0.00
SFG: from SFG:
Lbs. of SFG Product: Lbs. of Fugitive Hept. 0.00
Isomers from SFG:
Lb. Heptane per Lb. of SFG 0.005
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG
Product: 0.00
Accountable Lbs. of Hexane 0.00 Accountable and Fugitive 0.00
Lost: Lbs. Heptane Emitted:
Accountable Lbs. of N-Hept. 0.00 Accountable and Fugitive 0.00
Lost: Lbs. N-He t. Emitted:
Accountable Lbs. of Hept. Accountable and Fugitive
Isomers Lost: 0.00 Lbs. Hept. Isomers Emitted: 0.00
Lbs. of Heptane Sent as 6800
Hazardous Waste:

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2010
The Plant Material Grinder(OS-3) is operated in building ID#1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.

Monthly VOC's
YEAR: 2010
Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
BOILERS #2 Fuel Oil 11.783 13.299 9.613 7.637 6.882 18.629 18.857 6.845 8.327 7.170 7.867 9.883 126.790 0.063
GENERATORS #2 Fuel Oil 12.083 4.687 36.664 10.208 11.562 39.060 27.811 55.934 9.166 15.520 13.957 8.124 244.776 0.122
EVG Chloroform 0.00 0.00 0.00 4717.00 0.00 0.00 0.00 1400.00 902.00 0.00 280.00 549.00 7848.00 3.92
Methanol; - 1042.83 697.83 244.37, 16727- 601.13 2753.43 1.38
Ethyl acetate 7.46 36.44 6.83 0.11 8.20 0.37 12.68 -10.59 8.99 25.80 -5.20 3.69 94.79 0.05
from SDA
Ethyl acetate 7.45 1 36.40 16.11 800.00 2000.00 1056.00 3915.96 1.96
Eth lediamine 1 0.00 0.00
Ethanol-100% 0.00 0.00 0.00 21.99 184.28 0.00 0.00 0.00 0.00 0.00 0.00 0.00 206.27 0.10
PNE Ethanol-SDA 164.04 801.87 150.38 2.34 180.46 8.19 279.06 -233.03 197.89 567.63 -114.45 81.20 2085.58 1.04
Hexane 112.20 1420.10 1532.30 0.77
n-Hexane 0.00 0.00 0.13 0.00 0.00 0.00 0.00 0.00 1.70 0.00 0.00 0.00 1.84 0.00
Isohexane 0.00 0.00 112.07 0.00 0.00 0.00 0.00 0.00 1418.40 0.00 0.00 0.00 1530.46 0.77
Isobut I acetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00
Methanol I 1 1 547.70 1 547.70 0.27
Biomass Hexane 24101.00 34309.00 5225.00 1 63635.00' 31.82
Extraction n-Hexane 40.97 58.33 8.88 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 108.18 0.05
Isohexane 24060.03 34250.67 5216.12 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 63526.82 31.76
Ethyl acetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.60 0.00 0.00 0.00 8.60 0.00
Botanical Ethanol-SDA 189.30 189.30 0.09
Extraction Hexane.. 0.00 0.00
n-Hexane 0.00 1 0.00 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00 0.00 0.00 1 0.00 0.00 0.00
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Hexane•e ,. 10380T00 80880.65 184687.65 92.34
Rotocel& n-Hexane 0.00 0.00 0.00 0.00 0.00 332.18 258.82 0.00 0.00 0.00 0.00 0.00 591.00 0.30
Recovery Isohexane 0.00 0.00 0.00 0.00 0.00 103474.82 80621.83 0.00 0.00 0.00 0.00 0.00 184096.65 92.05
'-Methanol 4861.70" 13404.26 18265.96 9.13
Hexane. 10631.50 6138.00 7837.50 5637.50 5736.50 9322.50 8156.50 7997.00 8932.00 6028.00 11522.50 8882.50 96822.00 48.41
Sclareolide n-Hexane 3402.08 1 1964.16 2508.00 1804.00 1835.68 2983.20 2610.08 2559.04 2858.24 1928.96 3687.20 2842.40 30983.04 15.49
Isohexane 7229.42 4173.84 5329.50 1 3833.50 3900.82 6339.30 5546.42 5437.96 6073.76 4099.04 7835.30 6040.10 65838.96 32.92
Eth I acetate 542.00 570.00 628.00 748.00 895.00 546.00 867.00 953.00 568.00 1713.00 1219.00 205.00 ` 9454.00 4.73
Hexane - 6358.00 .3734.50 6891.50 5571.50 6671.50 5753.00 9504.00 6957.50 7925.50 6050.00 4950.00 4515.50 74882.50 37.44
Recrystallization n-Hexane 6040.10 3547.78 6546.93 5292.93 6337.93 5465.35 9028.80 6609.63 7529.23 5747.50 4702.50 4289.73 71138.38 35.57
(SFG) Isohexane 317.90 186.73 344.58 278.58 333.58 287.65 475.20 347.88 396.28 302.50 247.50 225.78 3744.13 1.87
He tane 0.00 0.00
N-He tane 0.00 0.00
WWTP Methanol 785.93 745.01 1530.94 0.77
TOTAL LBS.VOC 41835.31 45644.20 120913.81 17759.10 1 14242.09 125142.38 113895.83 17824.49 21214.25 16407.12 19096.94 14856.03 1 470363.85 235.18
TOTAL TONS VOC 20.92 22.82 1 10.46 8.88 1 7.12 62.57 56.95 8.91 10.61 1 8.20 9.55 7.43 1 235.18 1 0.12

Annual Air Emissions Inventory
Facility ID#: 0800044
Fire Pumps ,
Data used for inventory only!
Year: 2010
Total Run Time: 25.0 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/
Month Fuel Operated hour
Used
January: 40.0 2.0 20.0
February: 30.0 1.5 20.0
March: 50.0 2.5 20.0
April: 40.0 2.0 20.0
May: 50.0 2.5 20.0
June: 40.0 2.0 20.0
July: 40.0 2.0 20.0
August: 50.0 2.5 20.0
September: 40.0 2.0 20.0
October: 50.0 2.5 20.0
November: 40 0 2.0 20.0
December: 30.0 1.5 20.0
Total: 500.0 25.0 20.0

Page 1 of 2
Annual Air Emissions Inventory
V
Facility ID#:0800044
Boilers : OS-1
Year: 2010
Total Run Time: 16346.0 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 24024.0 34891.0 0.0 58915.0 672.0 689.5 0.0 1361.5 0.035 11.783
February: 23387.7 32579.4 10526.9 66494.0 654.2 288.3 385.3 1327.8 1 0.039 13.299
March: 2754.1 16432.9 28876.5 48063.5 203.1 379.3 641.7 1224.1 0.028 9.613
April: 4916.7 15849.3 17419.1 38185.1 242.7 549.7 430.1 1222.5 0.023 7.637
May: 13341.9 5866.1 15201.0 34409.0 373.2 372.6 337.8 1083.6 0.020 6.882
June: 33867.2 17080.3 42195.0 93142.5 568.4 576.0 562.6 1707.0 0.055 18.629
July: 37939.5 25320.6 31022.4 94282.5 671.4 678.3 497.0 1846.7 0.056 18.857
August: 21632.3 12591.2 0.0 34223.5 605.1 594.8 0.0 1199.9 0.020 1 6.845
September: 20406.1 21226.9 0.0 41633.0 570.8 601.1 3.0 1174.9 0.025 8.327
October: 21603.7 12315.2 1933.5 35852.4 604.3 593.7 133.2 1 1331.2 0.021 7.170
November: 15315.3 6348.5 17669.7 39333.5 428.4 454.9 406.2 1289.5 0.023 7.867
December: 21446A 9511.E 18457.0 49415.0 599.9 123.3 454.1 1577.3 0.029 9.883
Total: 240634.9 210013.0 183301.1 633949.0 6193.5 1 6301.5 1 3851.0 16346.0 0.375 126.790
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 38.9 6193.5 240634.9
2 H-102 143 33.3 6301.5 210013.0
3 H-103 180 47.6 3851.0 183301.1
Total 466 119.77859 16346 633949.0
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. TonsNr Tons/Yr) Tons/Yr TonsNr
TSP 2.00 0.241 0.210 0.183 0.634
PM-10 1.00 0.120 0.105 0.092 0.317
PM-2.5 0.25 0.030 0.026 0.023 0.079
Sox 42.60 5.126 4.473 3.904 13.503
Nox 24.00 1 2.888 1 2.520 2.200 7.607
VOC 0.20 1 0.024 1 0.021 0.018 0.063
CO 5.00 1 0.602 1 0.525 0.458 1.585
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.92E-04 0.143 0.124 0.109 0.375
Benzene 2.14E-04 0.052 0.045 0.039 0.136
Beryllium 3.53E-04 0.085 0.074 0.065 0.223
Cadmium 1.55E-03 0.373 0.326 0.284 0.983
Chromium 8.18E-03 1.968 1.717 1.499 5.184
Chromium VI 2.90E-05 0.007 0.006 0.005 0.018
Ethyl benzene 6.35E-05 0.015 0.013 0.012 0.040
Formaideh de 3.30E-02 7.940 6.929 6.048 20.917
Lead 1.25E-03 0.302 0.264 0.230 0.79E
Man anese 1.97E-03 0.475 0.415 0.362 1.251
Mercury 4.23E-04 0.102 0.089 0.078 0.268
Na thalene 1.29E-03 0.311 0.272 0.237 0.820
Nickel 2.54E-03 0.611 0.533 0.465 1.609
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc
1

Page 2 of 2
4
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Toluene 6.20E-03 1 1.493 1.303 1.137 3.933
o-X lene 1.09E-04 1 0.026 0.023 0.020 1 0.069
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)
CO, 22700.00 881.96 756.53 1080.48 2731.21 2383.65 2080.47 7195.32
Methane 0.06 0.0023 0.0020 0.0029 0.0072 0.0063 0.0055 0.0190
(CH4)
Nitrous Oxide 0.12 0.0047 0.0040 0.0057 0.0144 0.0126 0.0110 0.0380
(N20)
G:1EnvironmentaMir PermitWr Reports\Annual Air Emissions Inventory12011 Report\2011 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Year: 2010
Total Run Time: 127.8 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usa a allons VOC
Month E101 E102 E103 104 Pk-Gen Total (Lbs.)
January: 30.0 5&0 80.0 72.0 232.0 12.083
February: 22.5 37.5 30.0 0.0 90.0 4.687
March: 37.5 62.5 100.0 504.0 704.0 36.664
April: 30.0 50.0 80.0 36.0 196.0 10.208
May: 37.5 62.5 50.0 72.0 222.0 11.562
June: 30.0 50.0 40.0 630.0 750.0 39.060
July: 30.0 50.0 40.0 414.0 534.0 27.811
August: 30.0 50.0 1 40.0 954.0 1074.0 55.934
September: 30.0 50.0 60.0 36.0 176.0 9.166
October: 37.5 62.5 90.0 108.0 298.0 15.520
November: 30.0 50.0 80.0 108.0 268.0 13.957
December: 22.5 37.5 60.0 36.0 156.0 8.124
Total: 367.5 612.5 750.0 0-0 2970.0 4700.0 244.8
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm Btu/Hr mm Btu/Yr
1 E101 587 440 24.5 15.0 367.5 2.12 51.82
2 E102 760 570 24.5 25.0 612.5 3.53 86.36
3 E 103 603 452 37.5 20.0 750.0 2.82 105.75
4 E 104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 2670 2003 41.3 72.0 2970.0 10.15 418.77
Total 5154 3866 128 152 4700.0 21 663
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Pollutants (Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.008 0.013 0.016 0.000 0.065 0.103
PM-10 0.31 0.008 0.013 0.016 0.000 0.065 0.103
PM-2.5 0.31 0.008 0.013 0.016 0.000 0.065 0.103
Sox 0.29 0.008 0.013 0.015 0.000 0.061 0.096
Nox 4.41 0.114 0.190 0.233 0.000 0.923 1.461
VOC 0.36 0.009 0.016 0.019 0.000 0.075 0.119
CO 1 0.95 0.025 1 0.041 0.050 0.000 0.199 0.315
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Air Pollutants (Lb/mm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.040 0.066 0.081 0.000 0.321 0.508
Acrolein 9.25E-05 0.005 0.008 0.010 0.000 0.039 0.061
Benzene 9.33E-04 0.048 0.081 0.099 0.000 1 0.391 0.618
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.00012
Formaldehyde 1.18E-03 0.061 0.102 0.125 0.000 0.494 0.782
Na thalene 8.48E-05 0.004 0.007 0.009 0.000 0.036 0.056
Toluene 4.09E-04 0.021 0.035 0.043 0.000 0.171 0.271
X lene 2.85E-04 0.015 1 0.025 1 0.030 0.000 0.119 0.189
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Green House Gas Pulutants
Emisson Factor E101 E102 E103 E104 Total
GHG Pollutant Lb/ al. tans/ r` tons/ r tons/ r tons/ r tons/ r
CO2 2.0600000 0.38 0.63 0.77 0.00 1.78
Methane 0.0003289 0.00 0.00 0.00 0.00 0.00028
(CH4)
Nitrous Oxide 0.0000470 0.00 0.00 0.00 0.00 0.000041
(N20)
Green House Gas Pulutants for Peak Generator
GHG Pollutant Emisson Factor Ibs/yr tons/yr
(Lb/gal.)
CO2 2.0600000 6118.20 3.06
Methane 0.0003289 0.98 0.0005
(CH4)
Nitrous Oxide 0.0000470 0.14 0.00007
(N20)
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2010
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
K\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2010 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 &0
April: 0.0 0.0 0.0
May: &0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
Se tember: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Uperatioii T iiiie (hvilrs):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2010
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (lbs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 732 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2010
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Recovered
Month Received Recovered
Inventory (Lbs) New Used Inventory
Used
January: 1514 10931 1514
February: 1514 10931 1514
March: 1514 10931 1514
April: 1514 10931 1514
May: 1514 10931 1514
June: 1514 10931 1514
July: 1514 10931 1514
August: 1514 10931 1514
September: 1514 10931 1514
October: 1514 10931 ;,;: 1514
November: 1514 10931 1514
December: 1514 10931 1514
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @(OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0300044
Isopropyl acetate: OS-7, OS-10
Year: 2010
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of [PAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Maqanese
Year: 2010
Info: Potassium permanganate contains 33-35% Manganese.
Monthly Inventory of Potassium Permanganate (pounds):
Beginning Max EnIding
Month Received Used
Inventory Lbs nventorV
January:—
anua 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 16537 16537
June: 16537 16537 16537
July: 16537 16537 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Ma_x Lbs. Maaanese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 510
Info: Lbs/Gal =
Monthiy inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs.
_� [�..1[.._ a:_..:.�.. _a L... 11N a.,, !lA -.1 04 r%
Lbs. VI Jullul dioxide Used by IVAlisc.I \.(Y11 allu 1\I.A✓.
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2010
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc.:
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00

Facility Total CY 2010.Emission Summary Recorded in D Facility ID #: 0800044
Facility Name: Avoca Incorporated L' va CRY Permit#(s): 01819T38
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr % Change
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Nitrous Oxide (N20) 10024972 0.038100 0.047500 -19.8%
Methane (CH4) 74-82-8 0.019800 0.024700 -19.8%
Carbon Dioxide (CO2) 124389 7,200.16 8,967.15 -19.7%
CO2 equivalent (sum of individual GHG pollutant emission times their 6,543.08 metric tons
1995 IPCC Global Warming Potential (GWP), converted to metric tons)
Criteria Pollutants Actual Emissions % Change
(Tons/Year)
Pollutant CAS CY 2010 CY 2009
from ED I from Fees
CO Co 1.90 2.37 -19.8%
NOx Nox 9.07 11.33 -19.9Iyo
PM(TSP) TSP 0.730000 0.920000 -20.7%
PM10 PM10 0.420000 0.520000 -19.2%,
PM2.5 PM2.5 0.180000 0.230000 -21.7%
S02 S02 13.60 16.94 -19.7%,
VOC VoC 231.31 309.15 -2.5.2%
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Polycyclic Organic Matter (Specific Compounds from OAQPSfor 0.876450 1.09 -19.6` ;
T i)
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000130 0.000160 N/A
5655317PAH)
Naphthalene (Component of 833291POMTV) 91-20-3 0.876320 1.09 -19.80%
Polycyclic Organic Matter (7 PAH Compounds for NIF) 0.000130 0.000160 N/A
WaRO Copy
08/01/201 1 Page 1 of 4

Facility Total CY 2010 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPs) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Polycyclic Organic Matter (7 PAH Compounds for NIF) 0.000130 0.000160 N/A
Benzo(a)pyrene (Component of 833291POWV& 50-32-8 0.000130 0.000160 N/A
5655317PAH)
Nickel& Compounds, sum total mass includes elemental 1.61 2.00 -19.5
Nickel Unlisted Compounds (Component of NIC- N1C-Other 1.61 2.00 -19.70%
Specify)
Mercury & Compounds -all total mass includes Hg Vapor 0.268160 0.333970 -19.7%
Mercury Unlisted Compounds -Specify Compound HGC-Other 0.268160 0.333970 -19.7%
(Component of HGC)
Manganese & compounds 1.25 1.56 -19.9io
Manganese Unlisted Compounds -Specify MNC-Other 1.25 1.56 -1.9.7%
Compound(Component of MNC)
Lead& compounds 0.795540 0.990760 -19.7%
Lead Unlisted Compounds - Specify Compound PSC-other 0.795540 0.990760 -19.7%,
(Component of PBC)
Chromium (VI)Non-Specific Compounds, as Chrom(VI) 0.018590 0.023150 -19.7%
(Component CRC)
Chromium (VI) Non-Specific Unlisted Compounds - NSCR6-other 0.018590 0.023150 -19.7%)
Specify Compound(Component of NSCR6 & CRC)
Chromium-AIL/Total (includes Chromium (VI) categories, metal 5.20 6.48 -19.8%
and others)
Chromium (VI) Non-Specific Unlisted Compounds - NSCR6-Other 0.018590 0.023150 -19.70%
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds - Specify CRC-Other 5.18 6.46 -19.70%
Compound(Component of CRC)
Cadmium & compounds (total mass includes elemental metal) 0.982620 1.22 -19.5%
Cadmium Unlisted Compounds - Specify Compound CDC-Other 0.982620 1.22 -19.7%)
(Component of CDC)
08/01/2011 Page 2 of 4

Facility Total CY 2010 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T38
Hazardous Air Pollutants (HAPs) Actual Emissions % Change
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2010 CY 2009
from ED from Fees
Beryllium & compounds (Total mass) 0.223470 0.278300 -19.7%
Beryllium Unlisted Compounds -Specify Compound BEC-other 0.223470 0.278300 -19.7'%)
(Component of BEC)
Arsenic & Compounds (total mass of elemental AS, arsine and all 0.375420 0.467550 -19.7%
inorganic compounds)
Arsenic Unlisted Compounds -Specify Compound ASC-Other 0.375420 0.467550 -19.7%
(Component of ASQ
Acetaldehyde 75-07-0 0.507600 0.643470 -21.1`%o
Acrolein 107-02-8 0.061530 0.077990 -21.1'%
Benzene 71-43-2 0.754390 0.953290 -20.9%,
Chloroform 67-66-3 6,498.00 Not N/A
Reported
Ethyl acetate 141-78-6 13,423.58 11,446.56 17.30/0
Ethyl benzene 100-41-4 0.040310 0.050210 -19.7`%
Formaldehyde 50-00-0 21.70 27.04 -19.8`%►
Hexane isomers, except n-hexane HEXANEISO 317,924.35 503,760.02 -36.9%
Hexane, n- 110-54-3 105,072.54 53,480.12 96.50/0
Methanol (methyl alcohol) 67-56-1 23,366.46 44,782.05 -47.8%
Toluene 108-88-3 4.20 5.24 -19.8%
Xylene (mixed isomers) 1330-20-7 0.188520 0.238980 -21.1%
Xylene, o- 95-47-6 0.069100 0.086050 -19.70/0
Largest Individual HAP Hexane, n- 105,072.54
lbs
Total HAP Emissions 134,976.11
lbs
08/01/201 1 Page 3 of 4

DAQ's Comments Regarding Inventory
facility asked that DAQ adjust methonal number reported too large. done
08/01/2011 Page 4 of 4

• .
Hopkins, Arni
From: Brian Conner[[e-mail]]
Sent: Thursday, July 21, 2011 9:59 AM
To: Hopkins, Arni
Subject: Avoca AERO Questions
Hey Arni,
I had a message from you asking about the 2009 vs. 2010 n-hexane and Methanol emissions in Avoca's AERO report.
In 2009 we ran the rotocel and recovery operations(sage harvest)for 67 days. In 2010 we ran the rotocel and recovery
(sage harvest) for 39 days.The rotocel and recovery process uses hexane solvent that contains less than 1% n-hexane.
Methanol is used in the recovery process. The decrease in methanol during 2010 form 2009 is due to the fewer days of
operation in 2010.
However we show an increase in the n-hexane emissions for 2010 vs. 2009.The increase in n-hexane emissions is due to
the increase in the amount of further processing that occurs with the sage material in the other processes
(SFG/Recrystallization and Sclareolide).The lag in the next steps in the process after the original rotocel and recovery
operations can take several months to occur.Therefore much of the sage that was originally processed in the rotocel
and recovery in 2009 was not further processes until 2010 in SFG and Sclareolide. SFG uses the 90% n-hexane and
Sclareolide uses 32% n-hexane so n-hexane emissions will be higher with these processes than with the rotocel and
recovery. SFG ran for 125 days in 2009 and 308 days in 2010.Sclareolide ran for 107 days in 2009 and 258 days in 2010.
This explains the major increase in n-hexane emissions in 2010 over 2009.
If you have any more questions or need more information on this, please feel free to contact me.
Thanks.
Brian Conner
Environmental, Health, &Safety Manager
Avoca, Incorporated
1
1

Inventory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 County : Bertie
Merry Hill,NC 27957 DAQ Region :WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2010
These forms must he completed and returned even if the facility did not operate or emissions were zero
The legally defined"Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president,secretary,treasurer,or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship; a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g.,a Regional Administrator of EPA).
CERTIFICATION STATEMENT:
r t nt: Legally Resl2on5ible Official.read and sign after all s z mi
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report,including attached calculations and documentation,is true,accurate and complete. (Subject to legal
enalities of up to $25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Signature w use blue ink): Date Signed: otO o20
Printed Name: David Peele
,Signature:
This form applies to Title V facilities. If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: david.peele@avocaine,com
Information on this Form cannot be held confidential
1

Annual Air Emissions Inventory Summary _
2010 Totals Facility ID#:0800044
Plant Pollutant Boiler 07 Boiler ir2 Boller N3 Gen Mi Gen N2 Gen p3 Gen p4 Pk-Gen Rotocel Recove Recrystallizetion Sclareoltde Biomass Botanical Other
ry (SFG) (SDE) Extraction Extraction Nutrient EVG WWTP Processes Totals Units
Extraction
CO 2731.21 2383.65 2080.47 0.38 0.63 0.77 0.00 3.06 1 7200.162 1 Tons/Yr
Methane 0,00722 0.00630 0.00550 0.00006 0.00010 0.00012 0600000 0.00049 0.020 TonslYr
NitrousT Oxk1e 0.01444 0.01260 0.01100 0.00001 0.00001 0.00002 0.00000 0.00007 0.020 Tons/Yr
M-1 0,2406349 0.210013 0.1833011 0.008031713 0.013386188 0.01639125 0 0.06490935 0.737 TonslYr
PM-10 MM722
45 0.1050065 0.09165055 0.008031713 0.013386188 0.01839125 0 0.D6490935 0.420 Tons/Yr
PM-2.5 3113 0.026251625 0.022912638 0.008031713 0.013388188 0.01839125 0 0.06490935 OA20 TonslYr
Sox 337 4.4732769 3.9D431343 0.007513538 0.012522563 0.01533375 0 0.06072165 13.599 TonslYr
Nox 88 2.520156 2.1996132 0.114257588 0.190429313 0.23317875 0 0.92338785 9.069 TonsKr
VOC 49 0.0210013 0.01833011 0,00932715 0.01554525 0.019035 0 0+0753786 2.2238 9.1 42..6825 48.41 31.8175 0 1.58229.050 TonsNr
CO 25 0.5250325 0.45825275 0.024613313 0.041022188 0.05023125 0 0.19891575 1.900 Tons/Yr
Acetrolei a0.039744023 -0.066240038 0.08111025 0 0.32119659 0.500 Lbs/Yr
Acrolein0.OD4793119 0.007988531 0.009781875 0 0.038736225 0.061 Lbs/Yr
Arsenic 988 0.124369699 0.1085509110.375 Lbs/Yr
enzene 059 0.045005788 0.039281428 0.048345728 0.060576213 0.09868475 0 0.39071241 0.754 Lbs/Yr
Benzo a rene 9.74189E-O6 1.62362E-05 0.000019681 0 7.87288E-05 00.754 Lbs/Yr
Be Ilium O.OB4823802 0.074029583 0.064613638
Butanol 0.223 LbslYr
Cad.ium 0.372984095 0.32552015 0.284116705
0.DO 0.000 Lbs/Yr
Calcium hydroxide 0.983 Lbs/Yr
Chloroform 0.00 0.000 Lbs/Yr
Chromium 1.967912212 1.717488314 1.499036396
7848 1 0.00 7848.000 LbslYr
Chromium IV 0.006978412 0.006090377 0.005315732
5.184 Lbs/Yr
Ethanol-100% 0,018 Lbs/Yr
206.272 Lbs/Yr
�0 Ethanol Ethyl
a-SDA - 189.30 2312.4 0. 2501.752 Lbs/Yr
Ethyl
acetate 94 0 312. - 13.58 13423,580. 2Lbs/Yr
Eth(benzene 0.015280318 0.013335828 0.01183962 Lbs/Yr
FOnnaElh lenediamineOmO4O
_ F 0 0.000 Lbs/Yr
Hexane Isomers
de 7.939507691 6.929768922 8.047836493 0.06114465 0.10190775 0.124785 0 0.4941486 21.698 Lbs/Yr
Hexane Isomers "183857.4T7 381s.0o75 63515.2 83526.82 0 3205.948 317924.426 Ltu/1'r
N-Hexane
Heane Isomers 71063.4925 33306.768 108.1795 0 1 3.85176 V 105072.524 Lbs/Yr
N-He tans 0.00 - 0.000 Lbs/Vr
Isobut lacetate 0.00 0.000 Lbs/Yr
Iso ro l acetate 0 0.00 0.000 LbslYr
Lead Com unds 0.301972736 0.283545314 0.23002455
0.00 0.000 Lbs/Yr
0
Manganese 0.475013293 0.414565662 0.361836371 0.796 Lbs/Yr
Mercury tha 0.101788583 0.088835499 0.077536365
_ 0 1.251 Lbs/Yr
Methanol -' 0.268 lbs/Yr
18265.96' 7 2 1390.62 3182.12 23368.422 Lbsll'r
Na lhalene 0.311405624 0.271777823 0.237209954 0.004394124 0.00732354 0.0089678 0 0.035511898 - 0.677 LbslYr
Nickel 0.610731376 0.533012994 0.485218192
Sulfur Dioxkle 1.809 Lbs/Yr
Toluene 1.49289892 1.302920652 1 1.137200024 1 0.021193358 1 0.035322263 0.04 225175 0 0.17127693 0.00 0.000 Lbs/Yr
X lane 0.00 4.204 Lbs(Yr
0.014767988 0.024613313 0.03013875 0 0.11934945 0.189 Lbs/Yr
o-X lane 0.028205141 0.022870418 0.01996148
0.089 LDs/Yr

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4, OS-5, OS-6, OS-10, OS-28, OS-29
OS-13 OS-14 OS-15 OS-16 OS-17 OS-20 OS-21 OS-22 OS-23 OS-32 ALL INCLUDED WITH OS-4
OS-18 OS-19 INCLUDED WITH OS-10:OS-30 INCLUDED WITH OS-28
Year: 2010
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month Bn 9enning Received Mbs ax Used Ending Inventory
January: 6272 4092 57002 1933 8431
February: 8431 46371 1116 7315
March: 7315 40233 1425 5890
April: 5890 4352 56331 1025 9217
May: 9217 50694 1043 8174
June: 8174 44957 1695 6479
July: 6479 4349 59554 1483 9345
August: 9345 51398 1454 7891
September: 7891 4352 67337 1624 10619
October: 10619 58405 1096 9523
November: 9523 52377 2095 7428
December: 7428 4515 65687 1615 10328
Monthly Inventory of HP Hexane-95%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 2743 15087 1156 1587
February: 1587 8729 679 908
March: 908 5949 37714 1253 5604
April: 5604 30822 1013 4591
May: 4591 25251 1213 3378
June: 3378 18579 1046 2332
July: 2332 12826 1728 604
August: 604 6012 36388 1265 5351
September: 5351 29431 1441 3910
October: 3910 21505 1100 2810
November: 2810 15455 900 1910
December: 1910 10505 821 1089
Monthly Inventory of IsoHexane-2.5%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 36006 8458 244552 4382 40082
February: 40082 8162 265342 6238 42006
March: 42006 231033 970.4 41036
April: 41036 225696 41036
May: 41036 225696 41036
June: 41036 25991 368646 18874 48153
July: 48153 9378 316418 15584 41947
August: 41947 230706 41947
September: 41947 230706 258.2 41688
October: 41688 229286 41688
November: 41688 229286 41688
December: 41688 229286 41688

Page 2 of 4
Total Hexane Values
Gallons of LP Hexane Used: 17604.00 Gallons of N-Hexane Used: 18646.25
Gallons of HP Hexane Used: 13615.00 Lbs.of N-Hexane Used: 102554.38
Gallons of IsoHexane Used: 46306.60 Gallons of Hexane Isomers Used: 58879.35
Total Gallons of Hexanes Used: 77525.60 Lbs.of Hexane Isomers Used: 323836.42
Total Lbs.of Hexanes Used: 426390.8
Sclareolide(SDE)Operation:OS-5
Percent N-Hexane in Solvent: 34.4
Gallons of Hexane Used in SDE: 17604.00 , : Lbs.of Fugitive Hexane from SDE: 95407.32
Lbs.of Hexane Used in SIDE: 96822 Lbs.of Fugitive N-Hexane from 32820.12
SDE:
Lbs.of SDE Product: 282936.36 Lbs.of Fugitive Hex Isomers from 62587.20
SDE:
Lb.Hexane per Lb.of SDE
0.005
Product:
Lbs.Hexane in SDE Product: 1414.68
Lbs.N-Hexane in SDE Product: 486.65
Accountable Lbs.of Hexane Lost: 1414.68 Accountable and Fugitive Lbs. 96822.00
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 486.65 Accountable and Fugitive Lbs. 33306.77
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 928.03 Accountable and Fugitive Lbs.Hex 63515.23
Lost: Isomers Emitted:
Lbs.of Hexane Sent as 12480
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 3993.6
Waste:
Lbs.of Hex Isomers in Hazardous 8486.4
Waste:
Sclareol Recrystallization(SFG)Operation:OS-6
Percent N-Hexane in Solvent: 94.9
Gallons of Hexane Used in SFG: 13615.00 l' Lbs.of Fugitive Hexane from SFG: 73224.19
Lbs.of Hexane Used in SFG: 74882.5 Lbs.of Fugitive N-Hexane from 69489.75
SFG:
Lbs.of SFG Product: 331663 .' Lbs.of Fugitive Hex Isomers from 3734.43
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 1658.315
Lbs.N-Hexane in SFG Product: 1573.74
Accountable Lbs.of Hexane Lost: 1658.32 Accountable and Fugitive Lbs. 74882.50
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 1573.74 Accountable and Fugitive Lbs. 71063.49
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 8457 Accountable and Fugitive Lbs.Hex 3819.01
Lost: . Isomers Emitted:
Lbs.of Hexane Sent as
14280
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 13566
Waste:
Lbs.of Hex Isomers in Hazardous 714
Waste:

Page 3 of 4
Rotocel,Concrete,&Recovery Operations:OS-4
Gallons of Hexane Used: 34153.00 Gallons sent to WWT: 771298
Lbs.of Hexane Used: 187841.5 Lbs.Waste Water per Gal.Waste 8,34
Water:
Percentage of N-Hexane in a
0.32 Wt/o of Hexane in Waste Water: 0.014
Solvent:
Lbs.of Hexane Sent as
3393.85 Lbs.Hexane Lost in Waste Water: 900.57
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 10.86 Lbs.N-Hexane Lost in Waste 2.88
Waste: Water:
Lbs.of Hex Isomers in Hazardous 3382.99 Accountable Lbs.of Hexane Lost: 24225.99
Waste:
Lbs.Hex per day exiting Mineral
Oil Scrubber from MO tests: 47.98` Accountable Lbs.of N-Hex Lost: 77.52
Accountable Lbs.of Hex Isomers
Days of MO Unit operation: 45 Lost: 24148.46
Lbs.of Hex exiting MO Unit: 2159.1
Lbs.of N-Hex exiting MO Unit: 6.91
Lbs.of Hex Isomers exiting MO 2152.19 Total Lbs.Hexane Lost as 160221.66
Unit: Fugitive:
Lbs.Sage Processed: 16096060 Total Lbs.N-Hex Lost as Fugitive: 512.71
Lbs.Hexane per Lbs.of Spent Total Lbs.Hex Isomers Lost as
Sage(from Desolvitizer tests): 0.001315 Fugitive: 159708.95
Lbs.Hexane in Spent Sage: 21166.32
Lbs.N-Hexane in Spent Sage: 67.73
Lbs.Hexane per Day from A-1 0.000815
Vent Cond.
Days A-1 Operated: 45 Accountable and Fugitive Lbs. 184447.65
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.037 Accountable and Fugitive Lbs. 590.23
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000117 Accountable and Fugitive Lbs.Hex183857.42
Isomers Emitted:
Biomass Extraction Operation:OS-28
Gallons of Hexane Used: 11570.00 Lbs.of Fugitive Hexane from 63635
Bio Extraction:
Lbs.of Hexane Used: 63635 Lbs.of Fugitive N-Hexane from Bio 108.18
Extraction:
Lbs.of Biomass Product: 425488 Lbs.of Fugitive Hex Isomers from 63526.82
Bio Extraction:
%n-Hexane 0.17
i

Page 4 of 4
Botanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.of Fugitive N-Hexane from 0
Bot Extraction:
Lbs.of Botanical Product: Lbs.of Fugitive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction(M-13)Operation:OS-29
Gallons of Hexane Used: 583.60 Lbs.of Fugitive Hexane from 3209.8
PNE:
Lbs.of Hexane Used: 3209.8 Lbs.of Fugitive N-Hexane from 3.85176
PNE:
Lbs.of PNE Product: 373.5 Lbs.of Fugitive Hex Isomers from 05.94824
PNE:
%n-Hexane 0.12
Lbs.of Hexane Sent as 5780
Hazardous Waste:
Lbs.of N-Hex Sent as Hazadarous 6.936
Waste:
Lbs.of Hex Isomers in Hazardous 5773.064
Waste:
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: 106669.04 Total Lbs.n-Hexane Released: 105072.52
Fugitive Lbs.Hex Isomers 292763.36 Total Lbs.Hex Isomers Released: 317924.43
Emitted:
Accountable Lbs.n-Hexane Lost: 2137.91 Total Lbs.N-Hexane Sent Off Site: 4011.40
Accountable Lbs.Hex Isomers 25161.07 Total Lbs.Hex Isomers Sent Off 17642.45
Lost: Site:
Total Lbs.Hexane Sent Off Site: 21653.85
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month n-Hexane
(Gallons) (Gallons) (Lbs.)
January: 50100 5208 28641.9
February: 50229 4254 23394.5
March: 52530 8234 45289.7
April: 1 54844 8337 45852.3
May: 52588 6851 37678.7
June: 56964 5492 30208.7
July: 51896 4613 25370.8
August: 55189 8657 47614.8
September: 56217 8155 44851.3
October: 54021 6759 37174.9
November: 51026 5234 28785.2
December: 53105 5382 29599.5
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
56964 8657 47615

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6&OS-7
Year: 2010
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate(pounds):
Month Beginning Inventory Bulk Drums Ethyl acetate Used in SDA Alcohol
Total Beginning Beginning New Month
Month Beginning New Recovered New Used Recovered Recovered in Max Monthly Total Ending Ethyl acetate
Inventory Inventory Inventory Received Used Drums (Lbs) Used(Lbs.) Inventory Emitted(Lbs.)
January: 4899 4794 105 542.00 4899 542.0 4357 January: 7.45
February: 4357 4252 105 3272.0 570.00 7629 570.0 7059 February: 36.40
March: 7059 6954 105 628.00 7059 628.0 6431 March: 6.83
April: 6431 6326 105 748.00 ; 6431 748.0 5683 Aril: 0.11
May: 5683 5578 105 3320.0 1 895.00:." 9003 895.0 8108 May: 8.19
June: 8108 8003 105 546,00 8108 546.0 7562 June: 10.67
July: 7562 7457 105 867.00 7562 867.0 6695 July: 12.67
August: 6695 6590 105 953.00 6695 953.0 5742 August: -10.58
September: 5742 5637 105 1368.00 5742 1368.0 4374 September: 17.58
October: 4374 4269 105 3713.00 4374 3713.0 661 October: 25.77
November: 661 556 105 2275.00 661 2275.0 -1614 November: -5.20
December: -1614 -1719 105 <,artc205.00 -1614 1 205.0 -1819 December: 3.69
Lbs.of Ethyl acetate used during the year: 13423.5B /
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 3856.00
Lbs.of Ethyl acetate used in SFG:OS-6 94$4
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):OS-7 -1--f13.58'-
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(Crown Process):
Gallons sent to Hazardous Waste: 426.70
Lbs.Sent to Hazardous Waste: 6200.00
Total Lbs.of Ethyl acetate emitted during year: 13423.58

Annual Air Emissions Inventory
Facility ID#: 900044
Ethanol-SDA6S-7&OS-10
1
OS-18,OS-19,OS-27;OS-32 INCLUDED WITH OS-10
_. . Year: 20t0
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol laallonal:
Monthly Beginnina Inventory Bulk Drums
Total SDA h36.40
Total SDA Bulk SDA in Drums Max SDA on SDA to
SDA SDA SDA in Drums SDA in Drums SDA Ending SDA Used SDA Used SDA VOC
Month Beginning Beginning Beginning SDA Used Hand WWT
Inventory Inventory Inventory Received Transferred Received Used Recovered (Lbs) Inventory (gallons) (Lbs.) (Lbs) (Lbs.)
January: 38786.0 27777.8 11008:3 - 1869.8 676 288460 37592 1194 8202.1 8038.1 164.0
February: 37592.1 25908.0 11684.2 10795.0 6655.2 1480 2299 332419 42551 5836 40093.3 39291.5 801.9March: 42551.1 30047.8 12503.4 2582.0 1488 292326 41457 1095 7519.2 7368.8 150.4A ril: 41456.6 27465.8 13990.9 .17.0 284807 41440 17 116.8 114.5 2.3 Ma 41439.E 27448.8 13990.9 5456.0 1579.0266 322173 45582 1313 9023.1 8842.6 180.5 .
June: 45582.2 31325.8 14256.5 - 1620.0 264 173 313150 43871 1711 11753.2 11518.1 235.1 10.67
July: 43871A 29705.8 14165.7 2031.0 301397 41S40 2031 13953.0 13673.9 279.1 12.67
Au ust: 41840.4 27674.8 14165.7 5336.0 64.0 1760. E 324102 48872 -1896 -11651.5 -11418.5 -233.0 -10.58
September: 48872.4 32946.8 15925.7 :.5427.0 2818.0 :::XaCr 373037 51481 2818 19359.7 18972.5 387.2 17.58
October: 51481.4 35555.8 15925.7 5455.0 3863.0 1932 1664<> 391163 52805 4131 28381.3 27813.7 567.6 25.77
November: 5280542 37147.8 15657.5 5455.0 5891.0 6724-.1` 400248 59093 -833 -5722.7 -5608.3 -114.5 -5.20
December: 59093.2 36711.8 22381.5 591.0 405970 58502 591 4060.2 3979.0 81.2 3.69
Total Gallons of SDA Used: 18207.8
Total Lbs.SDA Used: 125087.6
Gallons sent to Hazardous Waste:
lbs.SDA Ethanol set to Hazardous Waste: 0.00
Total Gallons sent to WWT: 17843.64
Total Lbs.sent to WWT: 122585.83
Total SDA Ethanol VOC's 2501.75
Lbs.Botanical Extraction Ethanol Emitted:OS-10
Lbs.PNE Ethanol Emitted:OS-7 .23
Misc.Lbs.SDA Ethanol Emitted:
Total Lbs.of SDA Ethanol Emitted: 2501.75
J

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 2010
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons)
Beginning Max Ending Gallons to
Month InventoryReceived Lbs Used Recovered Inventorywwr VOC (Lbs.)
January: 4118 27110 4118 0 0
February: 4118 27110 4118 0 0
March: 4118 27110 4118 0 0
April: 4118 27110 167 650 4601 164 22
May: 4601 30288 1400 1142 4343 1372 184
June: 4343 28589 4343 0 0
July: 4343 28589 4343 0 0
August: 4343 28589 4343 0 0
September: 4343 28589 4343 0 0
October: 4343 28589 4343 0 0
November: 4343 28589 4343 0 0
December: 4343 28589 4343 0 0
Total Gallons of Ethanol Used: 1567
Total Lbs. Ethanol Used: 10313.5861
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0 n
Total Gallons sent to WWT: 1535 / `v
Total Lbs. sent to WWT: 10107.31438
Total Lbs. of Ethanol Emitted as VOC: 206
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Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: OS-4, OS-7, OS-9
OS-13 03-14 OS-15, OS-16 OS-17 OS-27 OS-32 INCLUDED WITH OS-4
Year: 2010
Info: Lbs/Gal= 6.60 Specifice Gravity=0.793
Monthly Inventory of Methanol (gallons):
Month Beginning Received Max Used Recovered Ending
Inventory Lbs Inventory
January: 16939 111797 16939
February: 16939 111797 16939
March: 16939 3190.0 132851 20129
April: 20129 5790.0 171065 3990.0 21929
May: 21929 6937.0 190516 4861.0 711.6 24717
June: 24717 6870.0 208472 4935.0 26652
July: 26652 175901 6138.0 20514
August: 20514 1320.0 144102 2670.0 19164
September: 19164 3520.0 149712 935.0 21749
October: 21749 143541 21749
November: 21749 143541 1 640.0 1 T 21109
December: 21109 139317 2300.0 18809
Maximum Gallons On-Hand: 31586.6
Maximum Lbs. On-Hand: 208471.56
Gallons Used per Year: 25757
Lbs. Used per Year: 169998.84
Sclareol Recovery Operation: OS-4
Total Lbs. McOH Used: 73303.26 Avg. % MeoH thru Pods: 85
Avg.% McOH in WW: 10.51 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 1.34 Number of Stream Days 41
Number of Stream Days: 41 Total Gal.Thru Pods: 531360
Total Gal. of WW to WWTP: 1253952 Total Gal. McOH Thru Pods: 451656
Total Lbs. of WW to WWTP: 10457959.68 Total Lbs. McOH Thru Pods: 2980929.60
Total Lbs. of McOH to WWTP: 55037.30 Total Lbs. Fugitive Emissions 18265.96
from Recovery:
Accountable Emissions of Total Accountable and Fugitve
McOH from WWTP during 1530.93 Emissions from Recovery: 19796.89
Recovery:
Avg. Removal Efficiency of
WWTP: 97.90

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 10535 Accountable Emissions of
Gallons of McOH to WWT: 10324.3 Y McOH from WWTP during 1362.81
Total Lbs.of McOH to WWT: 6 40. EVG:
Total Lbs. Fugitive Emissions Total Accountable and Fugitve 2753.43
from EVG: 1390.62 Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 4149.4 Accountable.Emissions of
Gallons of McOH to WWT: 4066.412 McOH from WWTP during 268.38
Total Lbs.of McOH to WWT: 26838.3192 PNE:
Total Accountable and Fugitve 816.10
Total Lbs. Emissions PNE: �547.7208 Emissions from PNE:
Totals for All Methanol Operations
Total Lbs. McOH Thru System: 2980929.60 Lbs.of Emissions from Misc., 547.7208Lab:
Lbs. Fugivtive Emissions from 1390.62
Total Lbs. McOH to WWTP: 150016.00 EVG:
Lbs. Fugivtive Emissions from 18265.96
Removal Efficiency of WWTP: 97.90 Recovery:
Lbs.Accountable Emissions 3162.12-`' Total Lbs. Fugitive Emissions: 20204.30
from WWTP: `
Total Lbs. McOH Treated at 150016.00 Total Lbs. McOH Released: 23366.42
WWTP:
Total Lbs. McOH Recycled On- 2807547.18
Site:

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2010
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13444 8100.0 21544 21544
February: 21544 21544 21544
March: 21544 21544 21544
April: 21544 21544 4717.0 16827
May: 16827 16827 16827
June: 16827 16827 16827
Jul : 16827 16827 16827
August: 16827 16827 1400.0 15427
September: 15427 15427 902.0 14525
October: 14525 14525 14525
November: 14525 14525 280.0 14245
December: 14245 14245 549.0 13696
Lbs. of chloroform used during the year: 7848
Lbs. of chloro. used by Misc., QA, and R&D:
Lbs. of chloro. used by EVG: 7848
Lbs. EVG Produced:
Lbs. of chloroform sent to hazardous waste: 1350
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 6498
H:\Environmental\Air PermitAr Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2010
Info: Lbs/Gal - 7.50 All ethylenediamine is contained and
Shipped off cite ,.,i+k +he —^rh,rf
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Ethylenediamine Used: 0
Total Lbs. Ethylenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethylenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Ethylenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2010
Info: Lbs/Gal = 5.70
Monthly Inventory of Heptane (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 496 2827 496
December: 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in
Solvent: 0.85
Gallons of Heptane Used in 0.00 Lbs. of Fugitive Heptane 0.00
SFG: from SFG:
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane 0.00
SFG: from SFG:
Lbs. of SFG Product: Lbs. of Fugitive Hept. 0.00
Isomers from SFG:
Lb. Heptane per Lb. of SFG 0.005
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG
Product: 0.00
Accountable Lbs. of Hexane 0.00 Accountable and Fugitive 0.00
Lost: Lbs. Heptane Emitted:
Accountable Lbs. of N-Hept. 0.00 Accountable and Fugitive 0.00
Lost: Lbs. N-He t. Emitted:
Accountable Lbs. of Hept. Accountable and Fugitive
Isomers Lost: 0.00 Lbs. Hept. Isomers Emitted: 0.00
Lbs. of Heptane Sent as 6800
Hazardous Waste:

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2010
The Plant Material Grinder(OS-3) is operated in building ID#1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.

Monthly VOC's
YEAR: 2010
Lbs of VOC Emissions
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC TOTAL (tons)
(lbs.)
BOILERS #2 Fuel Oil 11.783 13.299 9.613 7.637 6.882 18.629 18.857 6.845 8.327 7.170 7.867 9.883 126.790 0.063
GENERATORS #2 Fuel Oil 12.083 4.687 36.664 10.208 11.562 39.060 27.811 55.934 9.166 15.520 13.957 8.124 244.776 0.122
EVG Chloroform 0.00 0.00 0.00 4717.00 0.00 0.00 0.00 1400.00 902.00 0.00 280.00 549.00 7848.00 3.92
Methanol; - 1042.83 697.83 244.37, 16727- 601.13 2753.43 1.38
Ethyl acetate 7.46 36.44 6.83 0.11 8.20 0.37 12.68 -10.59 8.99 25.80 -5.20 3.69 94.79 0.05
from SDA
Ethyl acetate 7.45 1 36.40 16.11 800.00 2000.00 1056.00 3915.96 1.96
Eth lediamine 1 0.00 0.00
Ethanol-100% 0.00 0.00 0.00 21.99 184.28 0.00 0.00 0.00 0.00 0.00 0.00 0.00 206.27 0.10
PNE Ethanol-SDA 164.04 801.87 150.38 2.34 180.46 8.19 279.06 -233.03 197.89 567.63 -114.45 81.20 2085.58 1.04
Hexane 112.20 1420.10 1532.30 0.77
n-Hexane 0.00 0.00 0.13 0.00 0.00 0.00 0.00 0.00 1.70 0.00 0.00 0.00 1.84 0.00
Isohexane 0.00 0.00 112.07 0.00 0.00 0.00 0.00 0.00 1418.40 0.00 0.00 0.00 1530.46 0.77
Isobut I acetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00
Methanol I 1 1 547.70 1 547.70 0.27
Biomass Hexane 24101.00 34309.00 5225.00 1 63635.00' 31.82
Extraction n-Hexane 40.97 58.33 8.88 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 108.18 0.05
Isohexane 24060.03 34250.67 5216.12 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 63526.82 31.76
Ethyl acetate 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.60 0.00 0.00 0.00 8.60 0.00
Botanical Ethanol-SDA 189.30 189.30 0.09
Extraction Hexane.. 0.00 0.00
n-Hexane 0.00 1 0.00 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00 0.00 0.00 1 0.00 0.00 0.00
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Hexane•e ,. 10380T00 80880.65 184687.65 92.34
Rotocel& n-Hexane 0.00 0.00 0.00 0.00 0.00 332.18 258.82 0.00 0.00 0.00 0.00 0.00 591.00 0.30
Recovery Isohexane 0.00 0.00 0.00 0.00 0.00 103474.82 80621.83 0.00 0.00 0.00 0.00 0.00 184096.65 92.05
'-Methanol 4861.70" 13404.26 18265.96 9.13
Hexane. 10631.50 6138.00 7837.50 5637.50 5736.50 9322.50 8156.50 7997.00 8932.00 6028.00 11522.50 8882.50 96822.00 48.41
Sclareolide n-Hexane 3402.08 1 1964.16 2508.00 1804.00 1835.68 2983.20 2610.08 2559.04 2858.24 1928.96 3687.20 2842.40 30983.04 15.49
Isohexane 7229.42 4173.84 5329.50 1 3833.50 3900.82 6339.30 5546.42 5437.96 6073.76 4099.04 7835.30 6040.10 65838.96 32.92
Eth I acetate 542.00 570.00 628.00 748.00 895.00 546.00 867.00 953.00 568.00 1713.00 1219.00 205.00 ` 9454.00 4.73
Hexane - 6358.00 .3734.50 6891.50 5571.50 6671.50 5753.00 9504.00 6957.50 7925.50 6050.00 4950.00 4515.50 74882.50 37.44
Recrystallization n-Hexane 6040.10 3547.78 6546.93 5292.93 6337.93 5465.35 9028.80 6609.63 7529.23 5747.50 4702.50 4289.73 71138.38 35.57
(SFG) Isohexane 317.90 186.73 344.58 278.58 333.58 287.65 475.20 347.88 396.28 302.50 247.50 225.78 3744.13 1.87
He tane 0.00 0.00
N-He tane 0.00 0.00
WWTP Methanol 785.93 745.01 1530.94 0.77
TOTAL LBS.VOC 41835.31 45644.20 120913.81 17759.10 1 14242.09 125142.38 113895.83 17824.49 21214.25 16407.12 19096.94 14856.03 1 470363.85 235.18
TOTAL TONS VOC 20.92 22.82 1 10.46 8.88 1 7.12 62.57 56.95 8.91 10.61 1 8.20 9.55 7.43 1 235.18 1 0.12

Annual Air Emissions Inventory
Facility ID#: 0800044
Fire Pumps ,
Data used for inventory only!
Year: 2010
Total Run Time: 25.0 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 15 ppm
Cetane# 40
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/
Month Fuel Operated hour
Used
January: 40.0 2.0 20.0
February: 30.0 1.5 20.0
March: 50.0 2.5 20.0
April: 40.0 2.0 20.0
May: 50.0 2.5 20.0
June: 40.0 2.0 20.0
July: 40.0 2.0 20.0
August: 50.0 2.5 20.0
September: 40.0 2.0 20.0
October: 50.0 2.5 20.0
November: 40 0 2.0 20.0
December: 30.0 1.5 20.0
Total: 500.0 25.0 20.0

Page 1 of 2
Annual Air Emissions Inventory
V
Facility ID#:0800044
Boilers : OS-1
Year: 2010
Total Run Time: 16346.0 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.0014 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Boiler#1 Boiler#2 Boiler#3 Boiler
Fuel Used Hours
January: 24024.0 34891.0 0.0 58915.0 672.0 689.5 0.0 1361.5 0.035 11.783
February: 23387.7 32579.4 10526.9 66494.0 654.2 288.3 385.3 1327.8 1 0.039 13.299
March: 2754.1 16432.9 28876.5 48063.5 203.1 379.3 641.7 1224.1 0.028 9.613
April: 4916.7 15849.3 17419.1 38185.1 242.7 549.7 430.1 1222.5 0.023 7.637
May: 13341.9 5866.1 15201.0 34409.0 373.2 372.6 337.8 1083.6 0.020 6.882
June: 33867.2 17080.3 42195.0 93142.5 568.4 576.0 562.6 1707.0 0.055 18.629
July: 37939.5 25320.6 31022.4 94282.5 671.4 678.3 497.0 1846.7 0.056 18.857
August: 21632.3 12591.2 0.0 34223.5 605.1 594.8 0.0 1199.9 0.020 1 6.845
September: 20406.1 21226.9 0.0 41633.0 570.8 601.1 3.0 1174.9 0.025 8.327
October: 21603.7 12315.2 1933.5 35852.4 604.3 593.7 133.2 1 1331.2 0.021 7.170
November: 15315.3 6348.5 17669.7 39333.5 428.4 454.9 406.2 1289.5 0.023 7.867
December: 21446A 9511.E 18457.0 49415.0 599.9 123.3 454.1 1577.3 0.029 9.883
Total: 240634.9 210013.0 183301.1 633949.0 6193.5 1 6301.5 1 3851.0 16346.0 0.375 126.790
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-101 143 38.9 6193.5 240634.9
2 H-102 143 33.3 6301.5 210013.0
3 H-103 180 47.6 3851.0 183301.1
Total 466 119.77859 16346 633949.0
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. TonsNr Tons/Yr) Tons/Yr TonsNr
TSP 2.00 0.241 0.210 0.183 0.634
PM-10 1.00 0.120 0.105 0.092 0.317
PM-2.5 0.25 0.030 0.026 0.023 0.079
Sox 42.60 5.126 4.473 3.904 13.503
Nox 24.00 1 2.888 1 2.520 2.200 7.607
VOC 0.20 1 0.024 1 0.021 0.018 0.063
CO 5.00 1 0.602 1 0.525 0.458 1.585
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.92E-04 0.143 0.124 0.109 0.375
Benzene 2.14E-04 0.052 0.045 0.039 0.136
Beryllium 3.53E-04 0.085 0.074 0.065 0.223
Cadmium 1.55E-03 0.373 0.326 0.284 0.983
Chromium 8.18E-03 1.968 1.717 1.499 5.184
Chromium VI 2.90E-05 0.007 0.006 0.005 0.018
Ethyl benzene 6.35E-05 0.015 0.013 0.012 0.040
Formaideh de 3.30E-02 7.940 6.929 6.048 20.917
Lead 1.25E-03 0.302 0.264 0.230 0.79E
Man anese 1.97E-03 0.475 0.415 0.362 1.251
Mercury 4.23E-04 0.102 0.089 0.078 0.268
Na thalene 1.29E-03 0.311 0.272 0.237 0.820
Nickel 2.54E-03 0.611 0.533 0.465 1.609
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2011 Report\2011 AAE Calc
1

Page 2 of 2
4
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Toluene 6.20E-03 1 1.493 1.303 1.137 3.933
o-X lene 1.09E-04 1 0.026 0.023 0.020 1 0.069
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor
(Ibs/1000 gal) (Ibs/hr) (Ibs/hr) (Ibs/hr) (tons/yr) (tons/yr) (tons/yr) (tons/yr)
CO, 22700.00 881.96 756.53 1080.48 2731.21 2383.65 2080.47 7195.32
Methane 0.06 0.0023 0.0020 0.0029 0.0072 0.0063 0.0055 0.0190
(CH4)
Nitrous Oxide 0.12 0.0047 0.0040 0.0057 0.0144 0.0126 0.0110 0.0380
(N20)
G:1EnvironmentaMir PermitWr Reports\Annual Air Emissions Inventory12011 Report\2011 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Year: 2010
Total Run Time: 127.8 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usa a allons VOC
Month E101 E102 E103 104 Pk-Gen Total (Lbs.)
January: 30.0 5&0 80.0 72.0 232.0 12.083
February: 22.5 37.5 30.0 0.0 90.0 4.687
March: 37.5 62.5 100.0 504.0 704.0 36.664
April: 30.0 50.0 80.0 36.0 196.0 10.208
May: 37.5 62.5 50.0 72.0 222.0 11.562
June: 30.0 50.0 40.0 630.0 750.0 39.060
July: 30.0 50.0 40.0 414.0 534.0 27.811
August: 30.0 50.0 1 40.0 954.0 1074.0 55.934
September: 30.0 50.0 60.0 36.0 176.0 9.166
October: 37.5 62.5 90.0 108.0 298.0 15.520
November: 30.0 50.0 80.0 108.0 268.0 13.957
December: 22.5 37.5 60.0 36.0 156.0 8.124
Total: 367.5 612.5 750.0 0-0 2970.0 4700.0 244.8
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm Btu/Hr mm Btu/Yr
1 E101 587 440 24.5 15.0 367.5 2.12 51.82
2 E102 760 570 24.5 25.0 612.5 3.53 86.36
3 E 103 603 452 37.5 20.0 750.0 2.82 105.75
4 E 104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 2670 2003 41.3 72.0 2970.0 10.15 418.77
Total 5154 3866 128 152 4700.0 21 663
Criteria Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Pollutants (Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.008 0.013 0.016 0.000 0.065 0.103
PM-10 0.31 0.008 0.013 0.016 0.000 0.065 0.103
PM-2.5 0.31 0.008 0.013 0.016 0.000 0.065 0.103
Sox 0.29 0.008 0.013 0.015 0.000 0.061 0.096
Nox 4.41 0.114 0.190 0.233 0.000 0.923 1.461
VOC 0.36 0.009 0.016 0.019 0.000 0.075 0.119
CO 1 0.95 0.025 1 0.041 0.050 0.000 0.199 0.315
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
Air Pollutants (Lb/mm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.040 0.066 0.081 0.000 0.321 0.508
Acrolein 9.25E-05 0.005 0.008 0.010 0.000 0.039 0.061
Benzene 9.33E-04 0.048 0.081 0.099 0.000 1 0.391 0.618
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.00012
Formaldehyde 1.18E-03 0.061 0.102 0.125 0.000 0.494 0.782
Na thalene 8.48E-05 0.004 0.007 0.009 0.000 0.036 0.056
Toluene 4.09E-04 0.021 0.035 0.043 0.000 0.171 0.271
X lene 2.85E-04 0.015 1 0.025 1 0.030 0.000 0.119 0.189
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Green House Gas Pulutants
Emisson Factor E101 E102 E103 E104 Total
GHG Pollutant Lb/ al. tans/ r` tons/ r tons/ r tons/ r tons/ r
CO2 2.0600000 0.38 0.63 0.77 0.00 1.78
Methane 0.0003289 0.00 0.00 0.00 0.00 0.00028
(CH4)
Nitrous Oxide 0.0000470 0.00 0.00 0.00 0.00 0.000041
(N20)
Green House Gas Pulutants for Peak Generator
GHG Pollutant Emisson Factor Ibs/yr tons/yr
(Lb/gal.)
CO2 2.0600000 6118.20 3.06
Methane 0.0003289 0.98 0.0005
(CH4)
Nitrous Oxide 0.0000470 0.14 0.00007
(N20)
G:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2010
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
K\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2010 Report\2010 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2010 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 &0
April: 0.0 0.0 0.0
May: &0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
Se tember: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Uperatioii T iiiie (hvilrs):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2010
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid (lbs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 732 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2010
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Recovered
Month Received Recovered
Inventory (Lbs) New Used Inventory
Used
January: 1514 10931 1514
February: 1514 10931 1514
March: 1514 10931 1514
April: 1514 10931 1514
May: 1514 10931 1514
June: 1514 10931 1514
July: 1514 10931 1514
August: 1514 10931 1514
September: 1514 10931 1514
October: 1514 10931 ;,;: 1514
November: 1514 10931 1514
December: 1514 10931 1514
Gallons of IBAC used during the year @ PNE (OS-7): 0
Lbs. Of IBAC used during the year @ PNE (OS-7): 0
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @(OS-10): 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste:
Lbs. of IBAC sent to wwt:
Lbs. of IBAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0300044
Isopropyl acetate: OS-7, OS-10
Year: 2010
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of [PAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste:
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Maqanese
Year: 2010
Info: Potassium permanganate contains 33-35% Manganese.
Monthly Inventory of Potassium Permanganate (pounds):
Beginning Max EnIding
Month Received Used
Inventory Lbs nventorV
January:—
anua 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 16537 16537
June: 16537 16537 16537
July: 16537 16537 16537
August: 16537 16537 16537
September: 16537 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Ma_x Lbs. Maaanese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Off-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 510
Info: Lbs/Gal =
Monthiy inventory of Sulfur dioxide (pounds):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs.
_� [�..1[.._ a:_..:.�.. _a L... 11N a.,, !lA -.1 04 r%
Lbs. VI Jullul dioxide Used by IVAlisc.I \.(Y11 allu 1\I.A✓.
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2010
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc.:
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00