AQ_F_0800044_20100423_EI_Fac-EI-Rpt

knLen'tory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 W R RO COPY County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2009
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president, secretary,treasurer, or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g., a Regional Administrator of EPA).
CERTIFICATION STATEMENT*
a=ortant: Legally Responsible fi i l r f
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report,including attached calculations and documentation, is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Signature Bel use blue ink): Date Signed: ` 2% U'C ev
Printed Name: David Peele
Si ature: 4,6 �(�Z�,_
This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: [e-mail]
Ra
�
Information on this Form cannot be held confide A°P 2 3 ?010
DAQ WARO
141,6 �O copy

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr % Difference
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Nitrous Oxide (N20) 10024972 0.047500 0.051000 -6.91)/`0
Methane (CH4) 74-82-8 0.024700 0.036000 -31.4%
Carbon Dioxide (CO2) 124389 8,967.15 9,388.47 -4.5%
CO2 equivalent (sum of individual GHG pollutant emission times their 8,148.83 metric tons
1995 IPCC Global Warming Potential (GWP), converted to metric tons)
Criteria Pollutants Actual Emissions % Difference
(Tons/Year)
Pollutant CAS CY 2009 CY 2008
from ED I from Fees
CO CO 2.37 2.27 4.6%
NOx NOx 11.33 10.56 7.3%
PM(TSP) T'SP 0.920000 0.907000 1.4%
PM10 PM10 0.520000' 0.497000 4.6%
PM2.5 PM2.5 0.230000 0.187000 23.0%
S02 ' S02 16.94 17.85 -5.1%
VOC (�� fit` VOC 309.15 416.18 -25.7%
Hazardous Air Pollutants (HAPs) Actual Emissions `% Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Polycyclic Organic Matter(Specific Compounds from OAQPS for 1.09 1.23 -11.4
Ti9
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000160 0.000300 N/A
5655317PAH)
Naphthalene (Component of 833291POMTV) 91-20-3 1.09 1.23 -10.8%
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.000160 0.000300 N/A
f,r. Tv-1004
06/08/2010 WARO COPY
Page 1 of 4

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Hazardous Air Pollutants (HAPs) Actual Emissions '%o Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Polyeyelie Organic Matter (7 P.41I Compounds for NIF) 0.000160 0.000300 1
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000160 0.000300 N/A
5655317PAH)
Nickel& Compounds, sum total mass includes elemental 2.00 2.07 -3.4%
Nickel Unlisted Compounds (Component of NIC - N1C-other 2.00 2.07 -3.2%
Specify)
Mercury& Compounds-all total mass includes Hg Vapor 0.333970 0.345090 -3.2%
Mercury Unlisted Compounds-Specify Compound HGC-Other 0.333970 0.345090 -3.2%
(Component of HGC)
Manganese & compounds 1.56 1.61 -3.1%
Manganese Unlisted Compounds-Specify MNC-Other 1.56 1.61 -3.2%
Compound(Component of MNC)
Lead& compounds 0.990760 1.02 -2.9%
Lead Unlisted Compounds -Specify Compound NBC-other 0.990760 1.02 -3.2%
(Component of PBC)
Chromium (VI)Non-Specific Compounds, as Chrom(VI) 0.023150 0.023930 -3.3
(Component CRC)
Chromium (VI)Non-Specific Unlisted Compounds - NSCR6-Other 0.023150 0.023930 -3.3%
Specify Compound(Component of NSCR6& CRC)
Chromium-All/Total (includes Chromium(VI) categories, metal 6.48 6.70 -3.3%
and others
Chromium (VI)Non-Specific Unlisted Compounds - NSCR6-other 0.023150 0.023930 -3.3°ro
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds -Specify CRC-other 6.46 6.67 -3.2°/0
Compound(Component of CRC)
Cadmium & compounds (total mass includes elemental metal) 1.22 1.26 -3.2
Cadmium Unlisted Compounds-Specify Compound CDC-Other 1 .22 1.26 -3.2%
(Component of CDC)
06/08/2010 Page 2 of 4

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Hazardous Air Pollutants (HAPs) Actual Emissions `%, Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Beryllium & compounds (Total mass) 0.278300 0.287580 -3.2%
Beryllium Unlisted Compounds-Specify Compound BEC-Other 0.278300 0.287580 -3.2%
(Component of BEC)
Arsenic & Compounds (total mass of elemental AS, arsine and all 0.467550 0.483130 -3.2%
inorganic com ounds
Arsenic Unlisted Compounds -Specify Compound ASC-Other 0.467550 0.483130 --1
(Component of ASQ IJ
Acetaldehyde W9 _ 75-07-0 0.643470 0.204400 214.8'Vo
Acrolein �� 107-02-8 0.077990 0.030240 157.9%
Benzene 71-43-2 0.953290 1.28 -25.4%,
Chloroform 67-66-3 Not 2,453.00 N/A
Reported
Ethyl acetate 141-78-6 11.446.56 7.276.74 57.3`%o
Ethyl benzene 10041-4 0.050210 0.051880 -3.2%
Formaldehyde 50-00-0 27.04 27.28 -0.9%
Hexane isomers, except n-hexane HEXANEISO 503,760.02 621,228.96 -18.9%
Hexane, n- ��'� ,1�gsJ"7r/ 110-54-3 53,480.12 133,597.81 -60.0%
Methanol (methyl alcohol) 67-56-1 44,782.05 64,389.64 -30.5%
Toluene 108-88-3 5.24 5.47 -4.2%
Xylene (mixed isomers) 1330-20-7 0.238980 0.353140 -32.3%
Xylene, o- 95-47-6 0.086050 0.088920 -3.2%
Largest Individual HAP Hexane, n- 53,480.12 lbs
Total HAP Emissions 8,310.93 lbs
06/08/2010 Page 3 of 4

Annual Air Emissions Inventory Summary
2009 Totals Facility ID#:0800044
Recrystallization Sclarsolide Biomass Botanical Plant Other
Pollutant Boller#1 Boiler#2 Boller#3 Gen NI Gen#2 Gen#J Gen#4 Pk-Gen Rotocel Recovery Nutrient EVG WWTP Totals Units
(SFG) (SDE) Extraction Extraction Processes
Extraction
CO 3125.8E 3632.01 2203.11 1.17 1.96 3.01 0.00 17.15 8984.310 Tons/Yr Methane 0.00828 ii.00966o 0.00582 0.00019 0.00031 0.00048 0.00000 0.00553 0.030 Tons(Yr Nitrous Oxide 0.01552 0.01820 0.01165 0.00003 0.00004 0.00007 0.00000 0.00055 0.048 Tons/YrTSP 0.2754085 0.3200013 0.194107 0.008278674 0.013797062 0,02119935 0 0.08893919 Tons/Yr
20 PM-10 0.13770425 0.16000065 0.0970535 0,008278674 0.013797062 0.02119935 0 0.0889397E 0.0.92 Tons/Yr
0.034428063 0.040000163 0.024263375 0.008278674 1 0.013797062 0.02119935 1 0 .0.08693919 1 Sox 5.88820105 8.8180278E 4,1344791 0.007744568 1 0.01290692E 0.01983185 0.22E Tons/Yr
0 0.08133021
NOx 3.304902 3.8400156 2.3292841 0.117770814 0.196274327 0.30157785 18.93E Tons/Yr 0 1.2387800E VOC 0.02754085 0.03200013 0.01E-107 0.009817E-4 0.016022394 11 327 Tons/Yr
0.0248196 0 0.10096164 154.31075 21.78 18.14597 22.2585 78.9635 0 12.87 0.57 309.103 Tons/Yr
CO 0.68852125 0.80000325 0.4852675 0.02537013 0.047281318 0.06496575 0 0.26642655 Tons/Yr
Arsenic .373
A e 0,040956084 0.068273201 0.10490259 0 0.430208766 2 /
0.004940499 0.00823373 0.012651225 0 0.051883065 .373 644 Yr
0.163096914 0 Lbs Lbs(Yr
.18950477 0.114950165 0.
enzene 0.059020042 0.088576278 0.04159713 0.08304E-09 0 0..468 Lbs/Yr
Benzo a ene L 1.67345E-05 2.57126E-05 0953 Lbs/Yr
Be Ium 0.112800458 0.068422718 0.000105449 0.00016 Lbs/Yr
Bulanol 0.278 Lbs/Yr
a m m 0.426883175 0.496002015 0.30088585
0.00 0.000 Lbs/Yr
Calcium hydroxide 1.224 Lbs/Yr
Chloroform 0.00 0.000 LbWr
Chromium 2.252290713 2.818970631 1.587407048
0 0.00 0.000 Lbs/Yr
-Chromium N 01007986847 0.009280038 0.005629103
8.457 Lbs/Yr
Ethanol-100% 0.023 Lbs/Yr
SDA M192.56I
00 Lbs/Yr
1272.2E 2969.08 .372 Lbs/Yr
elate 2043 0 9211 .318 Lbs/Yr
Ethyl benzene 0.01748844 0.020320083 0.012325795
Elh enediamine 50 Lbs/Yr
0 00 LbsNr
ormaldeh a 9.086828049 10.55812289 6.404366353 0.063024744 0.105035694 0.1613886 0 . 41 Lbs/Yr
Hexane Isomers 304331.661712.447 29203.152 156439.58 0 12073.163 9.998 LN•Hexane 4289.83861 32538.493 15313.B48 1243.7736 0 86.13747 ..92 Lbs/Yr
He are IsomersN-He ane 0.00 0 Lbs/Yr
Isobut atxlale 0.00 00 Lbs/Yr
Iso ro acetate 4358 .840 Lbs/Yr
Lead Compounds 0.345810127 0.401569631 0.243584874
-15580 0.D0 -15580.000 Lbs/Yr
an anese 0.54385637E 0.831682586 0.383167218
0.991 Lbs/Yr
Menu 0.118487796 0.13538055 0.082107261
0 1,559 Lbs/Yr
Methanol 0.334 Lbs/Yr
43512.55 131.83 0.00 1137.67 44782.049 Lbs/Yr
Na Nickel
a 0.35640614 0.414113882 0.25719366E 0.004528236 0.007548328 0.017596098 0 0.04756415 1.093 Lbs/Yr
Nkkal 0.698986773 0.812163299 0.492643566 1.093 Lbs/Yr
SUINr Oloxlde
0.00 0.000 Lbs/Yr
o uene 1.708834334 1.965288065 1.204239828 0.015222078 .02530644 0.05593893 0 0.22E-07282 0.00 5.242 Lbs/Yr
X ene 0.015222078 0.025386781 0.03697E-5 0 0.15E65593 0.23E Lbs/Yr
o-X ene 0.299919857 0.348481478 0.211382523
0.860 Lbs/Yr
ii
DAQ WARD

1
Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2009
Total Run Time: 15558.3 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.3
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Fuel Boiler#1 Boiler#2 Boiler#3 [Hours
Boiler
Used
January: 22830.0 35309.4 9098.1 67237.5 638.6 46b.5 348.2 1452.3 0.040 13.448
February: 12333.8 23965.8 25551.0 61850.6 460.0 146.0 567.8 1173.8 0.037 12.370
March: 1796.9 34731.7 15465.4 51994.0 182.2 590.7 474.6 1247.5 0.031 10.399
April: 20120.1 11907.4 0.0 32027.5 562.8 330 5 0.0 893.3 0.019 6.406
May: 19444.4 27437.3 2126.8 49008.5 543.9 508.7 112.7 1165.3 0.029 9.802
June: 50221.2 49325.6 61675.7 161222.5 714.3 6971 696.9 2108.3 0.095 32.245
July: 52860.0 38864.1 66933.0 158657.1 739.3 711.0 743.7 2194.0 0.094 31.731
August: 15189.4 18346.6 13257.0 46793.0 411.6 269.6 294.6 975.8 0.028 9.359
September: 15444.0 18371.5 0.0 33815.5 432.0 307.2 0 0 739.2 0.020 6.763
October: 22322.3 13790.2 0.0 36112.5 624.4 602.6 0.0 1227.0 0.021 7.223
November: 21332.0 25290.0 0.0 46622.0 596.7 604.0 0.0 1200.7 0.028 9.324
December: 21514.4 22661.7 0.0 1 44176.1 601.8 579.3 0.0 1181.1 0.026 8.835
Total: 275408.5 320001.3 194107.0 1 789516.8 6507.E 1 5812.2 1 3238.5 15558.3 0.468 157.903
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-161 143 42.3 6507.6 275408.5
2 H-102 143 55.1 5812 22 320001.3
3 H-103 180 59.9 3238.5 194107.0
Total 46
6 157.315201 15558.3 789516.8
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. Tons/Yr Tons/Yr TonsNr Tons/Yr
TSP 2.00 0.275 0.320 0.194 0.790
PM-10 1.00 0.138 0.160 0.097 0.395
PM-2.5 0.25 0.034 0.040 0.024 0.099
Sox 42.60 5.866 6.816 4.134 16.817
Nox 24.00 3.305 3.840 2.329 9,474
VOC 0.20 0.028 0.032 0.019 0.079
CO 5.00 0.689 0.800 0.485 1.974
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.92E-04 0.163 0.190 0,115 0.468
Benzene 2.14E-04 0.059 0.069 0.042 0.169
Beryllium 3.53E-04 0.097 0.113 0.068 0.278
Cadmium 1.55E-03 0.427 1 0.496 0.301 1.224
Chromium 8.18E-03 2.252 2.617 1.587 6.457 0 , O Z
Chromium VI 2.90E-05 0.008 0.009 0.00E 1 0.023
Ethyl benzene 6.35E-05 0.017 0.020 0,012 1 0.050
Formaldehyde 3.30E-02 9.087 10,558 6.404 26,049
Lead 1.25E-03 0.346 0.402 0 244 0.991
Manganese 1.97E-03 0.544 0.632 0.383 1.559
Mercury 4,23E-04 0,116 0.135 0 082 0.334
Na thalene 1.29E-03 0.356 0.414 0.251 1.022
Nickel 2.54E-03 0,699 0,812 0.493 2.004
G:\Environmental\Air Permit\Air ReportsWnnual Air Emissions Inventory\2009 Report\2009 AAE Calc

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Toluene 6.20E-03 1 1.709 1.985 1.204 4.898
o-X lene 1.09E-03 1 0.300 0.348 0.211 0.860
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor (Ibs/hr) (Ibs/hr) (lbslhr) (tons/yr) (tons/yr) (tons/yr) (tonslyr)
(Ibs/1000 gal)
COZ 22700.00 960.69 1249.79 1360.58 3125.89 3632.01 2203.11 8961.02
Methane
(CH4) 0.06 0.0025 0.0033 0.0036 0.0083 0.0096 0.0058 0.0237
Nitrous Oxide
(N20) 0.12 0.0051 0.0066 0.0072 0.0165 0.0192 0.0116 0.0474
G:1EnvironmentaMir PermitWr ReportslAnnual Air Emissions Inventory\2009 Report12009 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Year: 2009
Total Run Time: 154.3 Hrs/Yr
Efficiency: 75
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Pk-Gen Total (Lbs.)
January: 22.5 37.5 60.0 288.0 408.0 21.249
February: 30.0 50.0 40.0 120.0 6.250
March: 37.5 62.5 100.0 72.0 272.0 14.166
April: 30.0 50.0 80.0 324.0 484.0 25.207
May: 37.5 62.5 10&0 0.0 200.0 10.416
June: 30.0 50.0 80.0 684.0 844.0 43.956
July: 22.5 37.5 60.0 1908.0 2028.0 105.618
August: 37.5 62.5 100.0 450.0 650.0 33.852
September: 33.8 5&3 90.0 72.0 252.1 13.129
October: 37.5 62.5 100.0 36.0 236.0 12.291
November: 30.0 50.0 80.0 72.0 232.0 12.083
December: 30.0 50.0 80.0 72.0 232.0 12.083
Total: 378.8 631.3 970.0 0.0 3978.0 5958.1 310.3
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm Btu/Hr mm Btu/Yr
1 E 101 587 440 25.3 15.0 378.8 2.12 53.41
2 E102 760 570 25.3 25.0 631.3 3.53 89.01
3 E103 603 452 48.5 20.0 970.0 2.82 136.77
4 E 104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 1 2670 2003 55.3 72.0 3978.0 10.15 560.90
Total 5154 3866 154 152 5958.1 21 840
Criteria Pollutants Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
(Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.008 0.014 0.021 0.000 0.087 0.130
PM-10 0.31 0.008 0.014 0.021 0.000 0.087 0.130
PM-2.5 0.31 0.008 0.014 0.021 0.000 0.087 0.130
Sox 0.29 0.008 0.013 0.020 0.000 0.081 0.122
Nox 4.41 0.118 0.196 0.302 0.000 1.237 1.852
VOC 0.36 0.010 0.016 0.025 0.000 0.101 0.151
CO 0.95 0.025 0.042 0.065 0.000 0.266 0.399
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
irPollutants (Lbjm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.041 0.068 0.105 0.000 0.430 0.644
1 U Acrolein 9.25E-05 0.005 0.008 0.013 0.000 0.052 0.078
Benzene --9-3a -84- 0.050 1 0.083 0.128 0.000 0.523 0.784
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.000
Formaldehyde 1.18E-03 0.063 0.105 0.161 0.000 0.662 0.991
Na thalene 8.48E-05 0.005 0.008 0.012 0.000 0.048 0.071
Toluene 4.09E-04 0.022 0.036 0.056 0.000 0.229 0.344
X lene 2.85E-04 0.015 0.025 0.039 0.000 1 0.160 0.239
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
Lb/mm BTU tons/ r tons/ r tons/ r tons/ r tons/ r
CO2 43.99 1.17 1.96 3.01 0.00 6.14
Methane 0.007 0.000187 0.0003115 0.0004787 0.0000000 0.00098
(CH4)
Nitrous Oxide 0.001 0.000027 0.0000445 0.0000684 0.0000000 0.000140
(N20)
Green House Gas Pulutants for Peak Generator
GHG Pollutant Emisson Factor Ibs/yr tons/yr
(Ibs/hp-hr)
CO2 0.31 34306.38 17.15
Methane
(CH4) 0.0001 11.07 0.0055
Nitrous Oxide 0.00001 1.11 0.000 55
(N20)
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#: 0800044
Fire Pumps
Data used for inventory only!
Year. 2009
Total Run Time: 0.0 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/
Month Fuel Operated hour
Used
January: 30.0 1.5 20.0
February: 40.0 2.0 20.0
March: 80.0 4.0 20.0
April: 40.0 2.0 20.0
May: 50.0 2.5 20.0
June: 40.0 2.0 20.0
July: 30.0 1.5 20.0
August: 40,0 1 2.0 20.0
September: 30.0 1.5 20.0
October: 50.0 2.5 20.0
November: 40.0 2.0 20.0
December: 40.0 2.0 20.0
Total: 510.0 25.5 20.0

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2009
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2009 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2009
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13444 13444 13444
February: 13444 13444 13444
March: 13444 13444 13444
April: 13444 13444 13444
May: 13444 13444 13444
June: 13444 13444 13444
July: 13444 13444 13444
August: 13444 13444 13444
September: 13444 13444 13444
October: 13444 13444 13444
November: 13444 13444 13444
December: 13444 13444 13444
Lbs. of chloroform used during the year: 0
Lbs. of chloro. used by Misc., QA, and R&D:
Lbs. of chloro. used by EVG: 0
Lbs. EVG Produced:
Lbs. of chloroform sent to hazardous waste:
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 0
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6&OS-7
Year: 2009
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate fpoundsl:
Month.Beginning Invent oW 1 Bulk Drums Ethyl acetate Used in SDA Alcohol
a;
Total Beginning Beginning New Recovered Recovered In Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Month Emitted Lbs.Inventory Inventory Inventory (Lbs.)
Janua 12881„, !38§1 9000 663.00 8086.88 1583.12 12881 7166.8 5714 Janua 36.67
Februa : 5714 3218 2496 148.00 _ 4329,38 1938,3.8 5714 2539.0 3175 February: 17.23
March: 3175 3070 105 3175 0.0 3175 March: 29.26
April: 3175 3070 105 67.00 _ 3175 67.0 3108 Aril: 20.15
-May: 3108 3003 105 _ 3108 0.0 3108 May: 48.66
June: 3108 3003 105 3108 0.0 3108 June: 7.52
July: 3108 3003 105 3108 0.0 3108 July: 7.88
August: 3108 3003 105 219.00 3108 219.0 2889 August: 3.63
September: 2889 2784 105 3272.0 338.00 6161 338.0 5823 September: 28.94
October: 5823 5718 105 555.00 _ 5823 555.0 5268 October: 0.30
November: 5268 5163 105 5268 0.0 5268 November: 50.20
December: 5268 5163 105 369.00 _ 5268 369.0 1 4899 December: 0.00
Lbs.of Ethyl acetate used during the year: 11446.32
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 9210.76
Lbs.of Ethyl acetate used In SFG:OS-6 2043.00
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):OS-7 192.56
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(Crown Process):
Total Lbs,of Ethyl acetate emitted during year: 11446.32

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2009
All ethylenediamine is contained and
Info: Lbs/Gal = 7.50 shipped off-site with the product.
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985. 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 2009
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 3630 23896 3630
February: 3630 23896 3630
March: 3630 23896 3630
�
April: 3630 23896
3630
May: 3630 23896 3630
June: 3630 23896 3630
Jul 6 3 30
2389
6
3630
August: 3630 23896 3630
September: 3630 23896 3630
October: 3630 23896 3630
November: 3630 23896 3630
December: 3630 23896 3630
Total Gallons of Ethanol Used: 0
Total Lbs. Ethanol Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. of Ethanol Emitted as VOC: 0

Gallons to VOC (Lbs.)
WWT
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0

Annual Air Emissions Inventory
Facility ID#:0800044
Ethanol-SDA:OS-7&OS-10
.su5- 3 f.•„ „_ ( .,.i,r . 19.OS-27,OS-32 INCLUDED WITH OS-10 a 1.,,� p_ ,.)e ?,K ter+• ,,F':' ;,s I€ ib�' €?bs"'
;` „aX�a ,...,r.�r _ ...«.e.. .n��k•..,c �`,.n�� •,„k, .�.� ,w,..,&ta.. � T2
r
Year. � 2009 .
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol(gallons),
Monthly Beginning Inventory Bulk Drums
Total SDA Bulk SDA in Drums Total SDA SDA to Ethyl SDA Max SDA on Y
SDA SDA SDA in Drums SDA Hand Ending SDA Used SDA Used WWT SDA VOC Acetate
Month Beginning Beginning Beginning SDA Used Recovered Inventory (gallons)Received Transferred Received Recovered
Inventory Inventory Inventory Used (Lbs) ry (9 ) (Lbs.) (Lbs.) (Lbs.) Emitted
-. ,__�_ T __---- ------- - (Lbs.)
Janua 18714 '10976 7738�.. 6041.0 1510.3 4369 170065 18876 5879 40390.4 39582.E 80Z8 36.67
February: 1887E 15507 3369 25910 _7687_ __ 1517 129675 16114 2762 18971.8 18592.4 379.4 17.23
March: 16114 1291E 3198 10983,0 " 8902.0 _ 142 4354 _ 186156 22407 4690 32223.5 31579.0 644.5 1
29.28
April: 22407 14997 7410 5787.0 8875.0 _ _ 525 169 193690 24963 3231 22194.6 21750.7 443.9 20.15
May: 24963 1790s 7054 4903. 7 . _ 324 _ 273 205179 22066 7800 53586.3 52518.5 1071.8 48.68
June: 2206E 15063 7003 5743.0- 1208 0 _ 191045 26603 1206 8285.2 8119.5 165.7 7.52
July: 26603 19600 7003 1609 0 -- _------- ----
_-
155 500 182760 25339W-464O
8680.6 8507.0 173.6I
August: 25339 17991 7348 582.0 _ 174079 ff
3998.3 3918.4 80.0
September: 24757 17409 7348 12090.0 1389.0
_ 6029 253139 -31878,8 -31239.3 -ti37.5 October: 41487 28110 13377 48.0 _ 285018 329.8 323.2 6.8 November: 41439 28082 13377 '. 5394.0 _ 5678.0 4190 _ 1830_ 321743 55282.9 54177.2 1105.7December: 38786 27778 11008 266460 38786 0.0 0.0 0.0
Total Gallons of SDA Used: 30868.8
Total Lbs.SDA Used: 212068.6
Gallons sent to Hazardous Waste:
Lbs.SDA Ethanol sent to Hazardous Waste: 0.00
Total Gallons sent to WWT: 30251.41
Total Lbs.sent to WWT: 207827.22
Total SDA Ethanol VOC's 4241.37
Lbs.Botanical Extraction Ethanol Emitted:OS-10 7272. 99 -'
Lbs.PNE Ethanol Emitted:OS-7 2969.08 -
Misc.Lbs.SDA Ethanol Emitted: _
Total Lbs.of SDA Ethanol Emitted: 4241,37

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4, OS-5, OS-6, OS-10, OS-28, OS-29
OS-13.OS-14,OS-15.OS-16,OS-17,OS-20,OS-21,OS-22.OS-23.OS-32 ALL INCLUDED WITH OS-4
OS-18.OS-19 INCLUDED WITH OS-10:OS-30 INCLUDED WITH OS-28
Year: 2009
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 5798 4178 54868 1185 8791
February: 8791 48351 1223 7568
March: 7568 41624 1094 6474
April: 6474 35607 858 5616
May: 5616 30888 5616
June: 5616 30888 5616
July: 5616 30888 5616
August: 5616 30888 5616
September: 5616 4390 55033 561 9445
October: 9445 51948 1606 7839
November: 7839 43115 482 7357
December: 7357 40464 1085 6272
Monthly Inventory of HP Hexane-95%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 3006 16533 722.36 2284
February: 2284 12560 54927 1734
March: 1734 9539 1734
April: 1734 9539 376.36 1358
May: 1358 7469 348.18 11010
June: 1010 5554 1 1010
Jul : 1010 5554 11010
August: 1010 5554 924.91 185
September: 85 5964 33269 670.91 5378
October: 5378 29579 1377,09 4001
November: 4001 22005 1030 2971
December: 2971 16340 228 2743
Monthly Inventory of IsoHexane-2.5%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 34473 7611 231462 3872 38212
February: 38212 210166 4728 33484
March: 33484 184162 33484
April: 33484 184162 33484
May: 33484 14834 265749 6356 41962
June: 41962 33189 413331 1 28248 46903
July: 46903 32751 438097 40978 38676
August: 38676 212718 2485 ' 36191
September: 36191 199051 179 36012
October: 36012 198066 6A 36006
November: 36006 198031 36006
December: 1 36006 198031 36006

Page 2 of 4
Total Hexane Values
Gallons of LP Hexane Used: 8094.00 Gallons of N-Hexane Used: 9191.94
Gallons of HP Hexane Used: 6227.08 Lbs.of N-Hexane Used: 50555.67
Gallons of IsoHexane Used: 86852.40 Gallons of Hexane Isomers Used: 91981.54
Total Gallons of Hexanes Used: 101173.48 Lbs.of Hexane Isomers Used: 505898.47
Total Lbs.of Hexanes Used: 556454.14
Sclareolide(SIDE)Operation:OS-5
Percent N-Hexane in Solvent: 34.4
Gallons of Hexane Used in SDE: 8094.00 ` Lbs.of Fugitive Hexane from SDE: 44021.96
Lbs.of Hexane Used in SDE: 44517 Lbs.of Fugitive N-Hexane from 15143.55
SDE:
Lbs.of Fugitive Hex Isomers from
Lbs.of SDE Product: 99008.58 SDE: 28878.40
Lb.Hexane per Lb.of SDE 0.005
Product:
Lbs.Hexane in SDE Product: 495.04
Lbs.N-Hexane in SDE Product: 170.29
Accountable Lbs.of Hexane Lost: 495.04 Accountable and Fugitive Lbs. 44517.00
Hexane Emitted
Accountable Lbs.of N-Hex Lost: 170.29 Accountable and Fugitive Lbs. 15313.85
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 324.75 Accountable and Fugitive Lbs.Hex 29203.15
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 9180.05
Waste:
Lbs.of N-Hex Sent as Hazadarous 2g37.616
Waste:
Lbs.of Hex Isomers in Hazardous
Waste: 6242.434
Sclareol Recrvstallization(SFG)Operation:OS-6
Percent N-Hexane in Solvent: 95
Gallons of Hexane Used in SFG: 6227.08 Lbs.of Fugitive Hexane from SFG 33802.92
Lbs.of Hexane Used in SFG: 34248.94 Lbs.of Fugitive N-Hexane from 32112.77
SFG:
Lbs.of Fugitive Hex Isomers from
Lbs.of SFG Product: 89204 1690.15
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 446.02
Lbs.N-Hexane in SFG Product: 423.72
Accountable Lbs.of Hexane Lost: 446.02 Accountable and Fugitive Lbs. 34248.94
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 423.72 Accountable and Fugitive Lbs. 32536.49
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 22.30 Accountable and Fugitive Lbs.Hex 1712.45
Lost: Isomers Emitted:

i
Page 3 of 4
Rotocel,Concrete,&Recovery Operations:OS 4
Gallons of Hexane Used: 56113.00 Gallons sent to WWT: 1237489
Lbs.of Hexane Used: 308621.5 Lbs.Waste Water per Gal.Waste 8.34
Water:
Percentage of N-Hexane in
Solvent: 1.39 Wt%of Hexane in Waste Water: 0.014
Lbs,of Hexane Sent as Hazardous
Waste: 6684.8 Lbs.Hexane Lost in Waste Water: 1444.89
Lbs.of N-Hex Sent as Hazadarous 9292 Lbs.N-Hexane Lost in Waste
Waste: . Water: 20.08
Lbs.of Hex Isomers in Hazardous
Waste: 6591.88 Accountable Lbs.of Hexane Lost: 40870.97
Lbs.Hex per day exiting Mineral
Oil Scrubber from MO tests): 47.17 Accountable Lbs.of N-Hex Lost: 568.11
Days of MO Unit operation: 67 Accountable Lbs.of Hex Isomers 40302.86
Lost:
Lbs.of Hex exiting MO Unit: 3160.39
Lbs.of N-Hex exiting MO Unit: 43.93
Lbs.of Hex Isomers exiting MO
Unit: 3116.46 Total Lbs.Hexane Lost as Fugitive: 267750.53
Lbs.Sage Processed: 32642380, Total Lbs.N-Hex Lost as Fugitive: 3721.73
Lbs.Hexane per Lbs.of Spent 0.001111 Total Lbs.Hex Isomers Lost as 264028.80
Sage(from Desolvitizer tests): Fugitive:
Lbs.Hexane in Spent Sage: 36265.68
Lbs.N-Hexane in Spent Sage: 504.09
Lbs.Hexane per Day from A-1
Vent Cond. 0.000815
Days A-1 Operated: 67 Accountable and Fugitive Lbs. 308621.5
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.055 Accountable and Fugitive Lbs. 4289.84 /
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000759 Accountable and Fugitive Lbs.Hex 304331.66
Isomers Emitted:

Page 4 of 4
Biomass Extraction Operation:OS-28
Gallons of Hexane Used: 28714.00' s.of Fugitive exane from
Bio Extraction: 157683.35
Lbs.of Fugitive N-Hexane from Bio
Lbs.of Hexane Used: 157927 Extraction: 1243.77
Lbs.of Biomass Product: 1202435.1_. Lbs.of Fugitive Hex Isomers from 156439.58
Bio Extraction:
%n-Hexane -0.79
Lbs.Hexane as Hazardous Waste 243.65
Lbs.n-Hexane as Hazardous
Waste t::1'92
Bo
tanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.of Fugitive N-Hexane from Bot 0
Extraction:
Lbs.of Botanical Product: Lbs.of Fugitive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction M-13 Operation:OS-29
Gallons of Hexane Used: 2025.40 Lbs.of Fugitive Hexane from 11139.7
PNE:
Lbs.of Fugitive N-Hexane from
Lbs.o, Hexane Used: 11139.7 PNE: 88.00363
Lbs.of PNE Product: 25.872 Lbs.of Fugitive Hex Isomers from 11051.69637
PNE:
%n-Hexane 0.79
i
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: 53999.98 Total Lbs.n-Hexane Released: 53471.96
Fugitive Lbs.Hex Isomers
Emitted: 462088.62 Total Lbs.Hex Isomers Released: 502738.53
Accountable Lbs.n-Hexane Lost: 1162.12 Total Lbs.N-Hexane Sent Off Site: 92.92
Accountable Lbs.Hex Isomers 40649.91 Total Lbs.Hex Isomers Sent Off 6591.88
Lost: Site:
Total Lbs.Hexane Sent Off Site: 6684.80
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 49287 5938 32658.3
February: 42786 4907 26985.8
March: 41692 4556 25060.4
April: 40458 3924 21583.8
EEMay: 48588 3806 20930.3
June: 53529 3929 21609.7
Jul 45302 3723 20478.5
August: 41892 2783 15304.1
September: 50835 9032 49675.0
October: 47846 7209 39652.2
November: 46334 6077 1 33422.1
December: 45021 5513 30321.2
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
53529 9032 49675

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2009
Info: Lbs/Gal = 5.70
Monthly Inventory of Heptane (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 496 2827 496
December: 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in
Solvent: 0.85
Gallons of Heptane Used in 000 Lbs. of Fugitive Heptane
SFG: . from SFG: 0.00
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane
SFG: from SFG: 0.00
Lbs. of Fugitive Hept.
Lbs. of SFG Product: Isomers from SFG: 0.00
Lb. Heptane per Lb. of SFG 0.005
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG
Product: 0.00
Accountable Lbs. of Hexane 000 Accountable and Fugitive
Lost: . Lbs. Heptane Emitted: 0.00
Accountable Lbs. of N-Hept. 000 Accountable and Fugitive
Lost: . Lbs. N-He t. Emitted: 0.00
Accountable Lbs. of Hept. 0 Accountable and Fugitive
Isomers Lost: .00 Lbs. Hept. Isomers Emitted: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2009
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid Obs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 2000'''' 0 1098 902
October: 902 0 902
November: 902 0 169.6 732
December: 732 0 732

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2009
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Month Inventory Received (Lbs) New Used Recovered Recovered Inventory
_ Used
January: 138 2648 20116 416 1377 3747
February: 3747 27055 845 2902
March: 2902 20955 2902
April: 2902 1323 30507 1334 1377 1514
May: 1514 10933 1514
June: 1514 10933 1514
July: 1514 10933 _ 1514
August: 1514 10933 1514
September: 1514 10933 1514
October: 1514 10933 1514
November: 1514 10933 1514
December: 1514 10933 1514
Gallons of IBAC used during the year @ PNE (OS-7): _ 3972
Lbs. Of IBAC used during the year @ PNE (OS-7): _ 28678
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): _ 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste: 24320
Lbs. of IBAC sent to wwt: _
Lbs. of IBAC emitted during year: 4358

Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyi acetate: OS-7, Os-10
Year: 2009
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 1 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste: 15580
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: -15580

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: Os-4, OS-i, OS-9
OS-13, OS-14. OS-15, OS-16, OS-17, OS-27, OS-32 INCLUDED WITH OS-4
Year: 2009
Info: Lbs/Gal = 6.60 Specifice Gravity = 0.793
Monthly Inventory of Methanol (gallons):
Beginning Max Ending
Month InventoryReceived Lbs Used Inventory
January: 14737 97264 998.7 13738
February: 13738 90673 13738
March: 13738 90673 13738
April: 13738 90673 13738
May: 13738 12186.0 171100 25924
June: 25924 5990.0 210634 8225.0 23689
July: 23689 6114.0 196702 12658.0 17145
August: 17145 113159 206.0 16939
September: 16939 111799 16939
October: 16939 1 111799 16939
November: 16939 111799 16939
December: 16939 111799 16939
Maximum Gallons On-Hand: 31914.3
Maximum Lbs. On-Hand: 210634.38
Gallons Used per Year: 22087.7
Lbs. Used per Year: 145778.82
Sclareoi Recovery Operation: OS-4
Total Lbs. McOH Used: 139187.4 Avg. % MeoH thru Pods: 85
Avg. % McOH in WW: 13.2 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 2.8 Number of Stream Days 67
Number of Stream Days: 67 Total Gal. Thru Pods: 868320
Total Gal. of WW to WWTP: 270144 Total Gal. McOH Thru Pods: 738072
Total Lbs. of WW to WWTP: 2253000.96 Total Lbs. McOH Thru Pods: 4871275.20
Total Lbs. of McOH to WWTP: 95674.85 Total Lbs. Fugitive Emissions from Recovery: 43512.55
Accountable Lbs. Emissions of Total Accountable and Fugitve
McOH from WWTP during 1073.08 Emissions from Recovery: 44585.62
et c e — I I,,d
Avg. RemoEalficiency of
WWTP: 98.88
� �9

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 0 Accountable Emissions of
Gallons of McOH to WWT: 0 McOH from WWTP during 0.00
Total Lbs. of McOH to WWT: 0.00 EVG:
Total Lbs. Fugitive Emissions 0.00 Total Accountable and Fugitve 0.00
from EVG: Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 998.7 Accountable Emissions of
Gallons of McOH to WWT: 978.726 McOH from WWTP during 64.60
Total Lbs. of McOH to WWT: 6459.5916 PNE:
Total Accountable and Fugitve 196.42
Total Lbs. Emissions PNE: 131.8284 Emissions from PNE:
Totals for All Methanol Operations
Lbs. of Emissions from Misc., 131.8284
Total Lbs. McOH Thru System: 4871275.20 Lab:
Total Lbs. McOH to WWTP: 102134.45 Lbs. Fugivtive Emissions from 0.00EVG:
Removal Efficiency of WWTP: 98`9
Lbs. Fugivtive Emissions from 43512.55
Recovery:
Lbs.Accountable Emissions 1137,67 Total Lbs. Fugitive Emissions: 43644.37
from WWTP: -----
Total Lbs. McOH Treated at 102134.45 Total Lbs. McOH Released: 44782.05
WWTP:
Total Lbs. McOH Recycled On- 4724358.71
Site:
i
1"p Q
- 'Kla l

SARA 313 R Reporting
Facility ID#: 0800044
Maganese
200
Info: Potassium permanganate contains 33-35% Manganese.
Monthly Inventory of Potassium Permanganate (pounds:
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 16537 16537
June: 16537 16537 16537
Jul : 16537 16537 16537
August: 16537 16537 16537
September: 16537 1 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Oft-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2009
info: Lbs/Gal =
Monthl Invento of Sulfur dioxide (pounds):
Y rY (p )
Month
Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
i December: 0 , 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs. of Sulfur dioxide used by Misc., QA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2009
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month
Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc..-
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2009
The Plant Material Grinder (OS-3) is operated in building ID # 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.

Monthly VOC's
YEAR: 2009
Lbs of VOC Emissions
TOTAL
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC (tons)
(Ibs.)
BOILERS #2 Fuel Oil 13.448 12.370 10.399 6.406 9.802 32.245 31.731 9.359 6.763 7.223 9.324 8.835 157.903 0.079
GENERATORS #2 Fuel Oil 21.249 6.250 14.166 25.207 10.416 43.956 105.618 33.852 13.129 12.291 12.083 12.083 310.298 0,155
-VG Chloroform 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Methanol 0.00 0.00
Ethyl acetate 36.71 17.25 29.29 20.17 13.97 7.53 7.89 3.63 -28.98 0.30 27.17 0.00 134.94 0.07
from SDA
Ethyl acetate 6819.80 2391.00 ' 29.26, 20 15 13.91 0,23 9274.35 4.64
Eth lediamine 0.00 0.00
Ethanol-100% 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
PNE Ethanol-SDA 807.81 379A4 644.47 443.89R303 1165.70 173.61 79.97 -637.54 6.60 597.80 0.00 2969.05 1.48
H drochloric Acid 0.00 0.00 0.00 0.000 0.00 0.00 0.00 1098.00 0.00 169.60 0.00 1267. 00 0.63
Hexane_ 8883,60 2220.90 1064,80 12169.30 6.08,n-Hexane 0.00 0.00 0.00 0.000 0.00 0.00 70.18 17.55 8.41 0.00 0.00 96.14 0.05
Isohexane 0.00 0.00 0.00 0.000 0.00 0.00 8813.42 2203.35 1056.39 0.00 0.00 12073.16 6.04
Isobut I acetate 60.07 122.00 0.00 192.630 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00 374.70 0.19
Methanol 131.83 1 1 1 131.83 0.07
Biomass Hexane 21296.00 26004.00 34958.00 36498.00 39171.00 157927.00 78.96
Extraction n-Hexane 168.24 205.43 0.00 0.00 276.17 288.33 309.45 0.00 0.00 0.00 0.00 0.00 1247.62 0.62
Isohexane 21127.76 25798.57 0.00 0.00 34681.83 36209.67 38861.55 0.00 0.00 0.00 0.00 0.00 156679.38 78.34
Ethyl acetate 0.00 0.00 0.00 0.00 34.75 0.00 0.00 0.00 0.00 0.00 23.08 0.00 57.83 0.03
Botanical Ethanol-SDA 764.49 I . 507.80 1272.29 . :. 0.64
Extraction Hexane 0.00 0.00
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0,00 0.00 0.00
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Hexane 1118866.00 186208.00 3547.50 , 308621.50 154.31
Rotocel& n-Hexane 0.00 0.00 0.00 0.00 0.00 1652.24 2588.29 49.31 0.00 0.00 0.00 0.00 4289.84 2.14
Recovery Isohexane 0.00 0.00 0.00 0.00 0.00 117213.76 183619.71 3498.19 0.00 0.00 0.00 0.00 304331.66 152.17
Methanol 8894,69 39098.99 -4481.14 43512.54 21.76
Hexane 6517.50 6726.50 6017.00 4719.00 0.00 0.00 0.00 0.00 3085.50 8833.00 2651.00 5967.50 44517.00 22.26.
Sclareolide n-Hexane 2085.60 2152.48 1925.44 1510.08 0.00 0.00 0.00 0.00 987.36 2826.56 848.32 1909.60 14245.44 7.12
Isohexane 4431.90 4574.02 4091.56 3208.92 0.00 0.00 0.00 0.00 2098.14 6006.44 1802.68 4057.90 30271.56 15.14
Ethyl acetate 347.00 148.00 67.00 219.00 -338.00 555.00 369.00 2043.00 1.02
Hexane 3972.98 3020.99 0.00 2069.98 1914.99 0.00 0.00 5087.01 3690.01 7574.00. 5665.00 1254.00 34248.94 17.12
Recrystallization n-Hexane 3774.33 2869.94 0.00 1966.48 1819.24 0.00 0.00 4832.65 3505.50 7195.30 538135 1191.30 32536.49 16.27
(SFG) Isohexane 198.65 151.05 0.00 103.50 95.75 0.00 0.00 254.35 184.50 378.70 283,25 62.70 1712.45 0.86
He tane 0.00
N-He tane 0.00
VWVTP I Methanol 64.60 603.49 1 410.47 59.15 1137,71 0.57
TOTAL LBS.VOC 40089.00 38827.79 6744.58 7564.44 38027.62 165111.85 265207.31 13441.93 9785.79 1805120 9662.86 7611.42 632297.08 316.15
TOTAL TONS VOC 20.04 19.41 3.37 3.78 19.01 82.56 132.60 6.72 4.89 9.03 4.83 3.81 316.15 1 0.16

knLen'tory Certification Form(Title V)
Facility Name: Avoca Incorporated Facility ID : 0800044
841 Avoca Farm Road Permit: 01819
PO Box 129 W R RO COPY County: Bertie
Merry Hill,NC 27957 DAQ Region : WARO
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Air Pollutant Point Source Emissions Inventory—Calendar Year 2009
These forms must be completed and returned even if the facility did not operate or emissions were zero
The legally defined "Responsible Official" of record for your facility is David Peele
This person or one that meets the definition below must sign this certification form.
The official submitting the information must certify that he/she complies with the requirements as specified in Title 15A
NCAC 2Q.0520(b)which references and follows the federal definition.40 CFR Part 70.2 defines a responsible as meaning one
of the following:
1. For a corporation: a president, secretary,treasurer, or vice—president of the corporation in charge of a principal
business function,or any other person who performs similar policy or decision making functions for the overall
operation of one or more manufacturing,production,or operating facilities applying for a or subject to a permit and
either
i.the facilities employ more than 250 persons or have gross annual sales or expenditures exceeding$25
million(in second quarter 1980 dollars); or
ii. the delegation of authority to such representatives is approved in advance by the permitting authority;
2.For partnership or sole propietorship;a general partner or the proprietor,respectively;
3. for a muncipality, state,federal,or other public agency includes the chief executive officer having responsibility for the
overall operations of a principal geographic unit of the agency(e.g., a Regional Administrator of EPA).
CERTIFICATION STATEMENT*
a=ortant: Legally Responsible fi i l r f
certify that I am the responsible official for this facility,as described above,and hereby certify that the information contained
in this air emissions report,including attached calculations and documentation, is true,accurate and complete. (Subject to legal
enalities of up to$25,000 per occurrence and possible imprisonment as outlined in G.S.§143-215.3(a)(2))
Responsible Official's Signature Bel use blue ink): Date Signed: ` 2% U'C ev
Printed Name: David Peele
Si ature: 4,6 �(�Z�,_
This form applies to Title V facilities.If this facility is not classified as Title V,please telephone your regional office Emission
Inventory contact at once for proper forms.
Email address of Responsible Official: [e-mail]
Ra
�
Information on this Form cannot be held confide A°P 2 3 ?010
DAQ WARO
141,6 �O copy

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Green House Gases Pollutants (GHG) Actual Emissions
Tons/Yr % Difference
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Nitrous Oxide (N20) 10024972 0.047500 0.051000 -6.91)/`0
Methane (CH4) 74-82-8 0.024700 0.036000 -31.4%
Carbon Dioxide (CO2) 124389 8,967.15 9,388.47 -4.5%
CO2 equivalent (sum of individual GHG pollutant emission times their 8,148.83 metric tons
1995 IPCC Global Warming Potential (GWP), converted to metric tons)
Criteria Pollutants Actual Emissions % Difference
(Tons/Year)
Pollutant CAS CY 2009 CY 2008
from ED I from Fees
CO CO 2.37 2.27 4.6%
NOx NOx 11.33 10.56 7.3%
PM(TSP) T'SP 0.920000 0.907000 1.4%
PM10 PM10 0.520000' 0.497000 4.6%
PM2.5 PM2.5 0.230000 0.187000 23.0%
S02 ' S02 16.94 17.85 -5.1%
VOC (�� fit` VOC 309.15 416.18 -25.7%
Hazardous Air Pollutants (HAPs) Actual Emissions `% Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Polycyclic Organic Matter(Specific Compounds from OAQPS for 1.09 1.23 -11.4
Ti9
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000160 0.000300 N/A
5655317PAH)
Naphthalene (Component of 833291POMTV) 91-20-3 1.09 1.23 -10.8%
Polycyclic Organic Matter(7 PAH Compounds for NIF) 0.000160 0.000300 N/A
f,r. Tv-1004
06/08/2010 WARO COPY
Page 1 of 4

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Hazardous Air Pollutants (HAPs) Actual Emissions '%o Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Polyeyelie Organic Matter (7 P.41I Compounds for NIF) 0.000160 0.000300 1
Benzo(a)pyrene (Component of 833291POMTV& 50-32-8 0.000160 0.000300 N/A
5655317PAH)
Nickel& Compounds, sum total mass includes elemental 2.00 2.07 -3.4%
Nickel Unlisted Compounds (Component of NIC - N1C-other 2.00 2.07 -3.2%
Specify)
Mercury& Compounds-all total mass includes Hg Vapor 0.333970 0.345090 -3.2%
Mercury Unlisted Compounds-Specify Compound HGC-Other 0.333970 0.345090 -3.2%
(Component of HGC)
Manganese & compounds 1.56 1.61 -3.1%
Manganese Unlisted Compounds-Specify MNC-Other 1.56 1.61 -3.2%
Compound(Component of MNC)
Lead& compounds 0.990760 1.02 -2.9%
Lead Unlisted Compounds -Specify Compound NBC-other 0.990760 1.02 -3.2%
(Component of PBC)
Chromium (VI)Non-Specific Compounds, as Chrom(VI) 0.023150 0.023930 -3.3
(Component CRC)
Chromium (VI)Non-Specific Unlisted Compounds - NSCR6-Other 0.023150 0.023930 -3.3%
Specify Compound(Component of NSCR6& CRC)
Chromium-All/Total (includes Chromium(VI) categories, metal 6.48 6.70 -3.3%
and others
Chromium (VI)Non-Specific Unlisted Compounds - NSCR6-other 0.023150 0.023930 -3.3°ro
Specify Compound(Component of NSCR6& CRC)
Chromium Unlisted Compounds -Specify CRC-other 6.46 6.67 -3.2°/0
Compound(Component of CRC)
Cadmium & compounds (total mass includes elemental metal) 1.22 1.26 -3.2
Cadmium Unlisted Compounds-Specify Compound CDC-Other 1 .22 1.26 -3.2%
(Component of CDC)
06/08/2010 Page 2 of 4

Facility Total CY 2009 Emission Summary Recorded in ED Facility ID #: 0800044
Facility Name: Avoca Incorporated Permit#(s): 01819T36
Hazardous Air Pollutants (HAPs) Actual Emissions `%, Difference
and/or Toxic Air Pollutants (TAPS) (Pounds/Year)
Pollutant CAS CY 2009 CY 2008
from ED from Fees
Beryllium & compounds (Total mass) 0.278300 0.287580 -3.2%
Beryllium Unlisted Compounds-Specify Compound BEC-Other 0.278300 0.287580 -3.2%
(Component of BEC)
Arsenic & Compounds (total mass of elemental AS, arsine and all 0.467550 0.483130 -3.2%
inorganic com ounds
Arsenic Unlisted Compounds -Specify Compound ASC-Other 0.467550 0.483130 --1
(Component of ASQ IJ
Acetaldehyde W9 _ 75-07-0 0.643470 0.204400 214.8'Vo
Acrolein �� 107-02-8 0.077990 0.030240 157.9%
Benzene 71-43-2 0.953290 1.28 -25.4%,
Chloroform 67-66-3 Not 2,453.00 N/A
Reported
Ethyl acetate 141-78-6 11.446.56 7.276.74 57.3`%o
Ethyl benzene 10041-4 0.050210 0.051880 -3.2%
Formaldehyde 50-00-0 27.04 27.28 -0.9%
Hexane isomers, except n-hexane HEXANEISO 503,760.02 621,228.96 -18.9%
Hexane, n- ��'� ,1�gsJ"7r/ 110-54-3 53,480.12 133,597.81 -60.0%
Methanol (methyl alcohol) 67-56-1 44,782.05 64,389.64 -30.5%
Toluene 108-88-3 5.24 5.47 -4.2%
Xylene (mixed isomers) 1330-20-7 0.238980 0.353140 -32.3%
Xylene, o- 95-47-6 0.086050 0.088920 -3.2%
Largest Individual HAP Hexane, n- 53,480.12 lbs
Total HAP Emissions 8,310.93 lbs
06/08/2010 Page 3 of 4

Annual Air Emissions Inventory Summary
2009 Totals Facility ID#:0800044
Recrystallization Sclarsolide Biomass Botanical Plant Other
Pollutant Boller#1 Boiler#2 Boller#3 Gen NI Gen#2 Gen#J Gen#4 Pk-Gen Rotocel Recovery Nutrient EVG WWTP Totals Units
(SFG) (SDE) Extraction Extraction Processes
Extraction
CO 3125.8E 3632.01 2203.11 1.17 1.96 3.01 0.00 17.15 8984.310 Tons/Yr Methane 0.00828 ii.00966o 0.00582 0.00019 0.00031 0.00048 0.00000 0.00553 0.030 Tons(Yr Nitrous Oxide 0.01552 0.01820 0.01165 0.00003 0.00004 0.00007 0.00000 0.00055 0.048 Tons/YrTSP 0.2754085 0.3200013 0.194107 0.008278674 0.013797062 0,02119935 0 0.08893919 Tons/Yr
20 PM-10 0.13770425 0.16000065 0.0970535 0,008278674 0.013797062 0.02119935 0 0.0889397E 0.0.92 Tons/Yr
0.034428063 0.040000163 0.024263375 0.008278674 1 0.013797062 0.02119935 1 0 .0.08693919 1 Sox 5.88820105 8.8180278E 4,1344791 0.007744568 1 0.01290692E 0.01983185 0.22E Tons/Yr
0 0.08133021
NOx 3.304902 3.8400156 2.3292841 0.117770814 0.196274327 0.30157785 18.93E Tons/Yr 0 1.2387800E VOC 0.02754085 0.03200013 0.01E-107 0.009817E-4 0.016022394 11 327 Tons/Yr
0.0248196 0 0.10096164 154.31075 21.78 18.14597 22.2585 78.9635 0 12.87 0.57 309.103 Tons/Yr
CO 0.68852125 0.80000325 0.4852675 0.02537013 0.047281318 0.06496575 0 0.26642655 Tons/Yr
Arsenic .373
A e 0,040956084 0.068273201 0.10490259 0 0.430208766 2 /
0.004940499 0.00823373 0.012651225 0 0.051883065 .373 644 Yr
0.163096914 0 Lbs Lbs(Yr
.18950477 0.114950165 0.
enzene 0.059020042 0.088576278 0.04159713 0.08304E-09 0 0..468 Lbs/Yr
Benzo a ene L 1.67345E-05 2.57126E-05 0953 Lbs/Yr
Be Ium 0.112800458 0.068422718 0.000105449 0.00016 Lbs/Yr
Bulanol 0.278 Lbs/Yr
a m m 0.426883175 0.496002015 0.30088585
0.00 0.000 Lbs/Yr
Calcium hydroxide 1.224 Lbs/Yr
Chloroform 0.00 0.000 LbWr
Chromium 2.252290713 2.818970631 1.587407048
0 0.00 0.000 Lbs/Yr
-Chromium N 01007986847 0.009280038 0.005629103
8.457 Lbs/Yr
Ethanol-100% 0.023 Lbs/Yr
SDA M192.56I
00 Lbs/Yr
1272.2E 2969.08 .372 Lbs/Yr
elate 2043 0 9211 .318 Lbs/Yr
Ethyl benzene 0.01748844 0.020320083 0.012325795
Elh enediamine 50 Lbs/Yr
0 00 LbsNr
ormaldeh a 9.086828049 10.55812289 6.404366353 0.063024744 0.105035694 0.1613886 0 . 41 Lbs/Yr
Hexane Isomers 304331.661712.447 29203.152 156439.58 0 12073.163 9.998 LN•Hexane 4289.83861 32538.493 15313.B48 1243.7736 0 86.13747 ..92 Lbs/Yr
He are IsomersN-He ane 0.00 0 Lbs/Yr
Isobut atxlale 0.00 00 Lbs/Yr
Iso ro acetate 4358 .840 Lbs/Yr
Lead Compounds 0.345810127 0.401569631 0.243584874
-15580 0.D0 -15580.000 Lbs/Yr
an anese 0.54385637E 0.831682586 0.383167218
0.991 Lbs/Yr
Menu 0.118487796 0.13538055 0.082107261
0 1,559 Lbs/Yr
Methanol 0.334 Lbs/Yr
43512.55 131.83 0.00 1137.67 44782.049 Lbs/Yr
Na Nickel
a 0.35640614 0.414113882 0.25719366E 0.004528236 0.007548328 0.017596098 0 0.04756415 1.093 Lbs/Yr
Nkkal 0.698986773 0.812163299 0.492643566 1.093 Lbs/Yr
SUINr Oloxlde
0.00 0.000 Lbs/Yr
o uene 1.708834334 1.965288065 1.204239828 0.015222078 .02530644 0.05593893 0 0.22E-07282 0.00 5.242 Lbs/Yr
X ene 0.015222078 0.025386781 0.03697E-5 0 0.15E65593 0.23E Lbs/Yr
o-X ene 0.299919857 0.348481478 0.211382523
0.860 Lbs/Yr
ii
DAQ WARD

1
Page 1 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Year: 2009
Total Run Time: 15558.3 Hrs/Yr
Efficiency: 85 %
Sulfur Content: 0.3
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) Boiler Operation(Hours) Arsenic VOC
Emissions Emissions
Total Total (Lbs.) (Lbs)
Month Boiler#1 Boiler#2 Boiler#3 Boiler Fuel Boiler#1 Boiler#2 Boiler#3 [Hours
Boiler
Used
January: 22830.0 35309.4 9098.1 67237.5 638.6 46b.5 348.2 1452.3 0.040 13.448
February: 12333.8 23965.8 25551.0 61850.6 460.0 146.0 567.8 1173.8 0.037 12.370
March: 1796.9 34731.7 15465.4 51994.0 182.2 590.7 474.6 1247.5 0.031 10.399
April: 20120.1 11907.4 0.0 32027.5 562.8 330 5 0.0 893.3 0.019 6.406
May: 19444.4 27437.3 2126.8 49008.5 543.9 508.7 112.7 1165.3 0.029 9.802
June: 50221.2 49325.6 61675.7 161222.5 714.3 6971 696.9 2108.3 0.095 32.245
July: 52860.0 38864.1 66933.0 158657.1 739.3 711.0 743.7 2194.0 0.094 31.731
August: 15189.4 18346.6 13257.0 46793.0 411.6 269.6 294.6 975.8 0.028 9.359
September: 15444.0 18371.5 0.0 33815.5 432.0 307.2 0 0 739.2 0.020 6.763
October: 22322.3 13790.2 0.0 36112.5 624.4 602.6 0.0 1227.0 0.021 7.223
November: 21332.0 25290.0 0.0 46622.0 596.7 604.0 0.0 1200.7 0.028 9.324
December: 21514.4 22661.7 0.0 1 44176.1 601.8 579.3 0.0 1181.1 0.026 8.835
Total: 275408.5 320001.3 194107.0 1 789516.8 6507.E 1 5812.2 1 3238.5 15558.3 0.468 157.903
Boiler# ID# GPH Hi-Fire Gals/Hr Hr/Yr Gals/Yr
1 H-161 143 42.3 6507.6 275408.5
2 H-102 143 55.1 5812 22 320001.3
3 H-103 180 59.9 3238.5 194107.0
Total 46
6 157.315201 15558.3 789516.8
Criteria Pollutants
Criteria Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants Lbs./1000 al. Tons/Yr Tons/Yr TonsNr Tons/Yr
TSP 2.00 0.275 0.320 0.194 0.790
PM-10 1.00 0.138 0.160 0.097 0.395
PM-2.5 0.25 0.034 0.040 0.024 0.099
Sox 42.60 5.866 6.816 4.134 16.817
Nox 24.00 3.305 3.840 2.329 9,474
VOC 0.20 0.028 0.032 0.019 0.079
CO 5.00 0.689 0.800 0.485 1.974
Hazardous Air Pollutants
Hazardous Air Emisson Factor Boiler#1 Boiler#2 Boiler#3 Total
Pollutants (lbs/1000 gal) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Arsenic 5.92E-04 0.163 0.190 0,115 0.468
Benzene 2.14E-04 0.059 0.069 0.042 0.169
Beryllium 3.53E-04 0.097 0.113 0.068 0.278
Cadmium 1.55E-03 0.427 1 0.496 0.301 1.224
Chromium 8.18E-03 2.252 2.617 1.587 6.457 0 , O Z
Chromium VI 2.90E-05 0.008 0.009 0.00E 1 0.023
Ethyl benzene 6.35E-05 0.017 0.020 0,012 1 0.050
Formaldehyde 3.30E-02 9.087 10,558 6.404 26,049
Lead 1.25E-03 0.346 0.402 0 244 0.991
Manganese 1.97E-03 0.544 0.632 0.383 1.559
Mercury 4,23E-04 0,116 0.135 0 082 0.334
Na thalene 1.29E-03 0.356 0.414 0.251 1.022
Nickel 2.54E-03 0,699 0,812 0.493 2.004
G:\Environmental\Air Permit\Air ReportsWnnual Air Emissions Inventory\2009 Report\2009 AAE Calc

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#:0800044
Boilers : OS-1
Toluene 6.20E-03 1 1.709 1.985 1.204 4.898
o-X lene 1.09E-03 1 0.300 0.348 0.211 0.860
Green House Gas Pulutants
Emission Boiler#1 Boiler#2 Boiler#3 Boiler#1 Boiler#2 Boiler#3 Total
GHG Pollutant Factor (Ibs/hr) (Ibs/hr) (lbslhr) (tons/yr) (tons/yr) (tons/yr) (tonslyr)
(Ibs/1000 gal)
COZ 22700.00 960.69 1249.79 1360.58 3125.89 3632.01 2203.11 8961.02
Methane
(CH4) 0.06 0.0025 0.0033 0.0036 0.0083 0.0096 0.0058 0.0237
Nitrous Oxide
(N20) 0.12 0.0051 0.0066 0.0072 0.0165 0.0192 0.0116 0.0474
G:1EnvironmentaMir PermitWr ReportslAnnual Air Emissions Inventory\2009 Report12009 AAE Calc

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Year: 2009
Total Run Time: 154.3 Hrs/Yr
Efficiency: 75
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Fuel Usage(gallons) VOC
Month E101 E102 E103 E104 Pk-Gen Total (Lbs.)
January: 22.5 37.5 60.0 288.0 408.0 21.249
February: 30.0 50.0 40.0 120.0 6.250
March: 37.5 62.5 100.0 72.0 272.0 14.166
April: 30.0 50.0 80.0 324.0 484.0 25.207
May: 37.5 62.5 10&0 0.0 200.0 10.416
June: 30.0 50.0 80.0 684.0 844.0 43.956
July: 22.5 37.5 60.0 1908.0 2028.0 105.618
August: 37.5 62.5 100.0 450.0 650.0 33.852
September: 33.8 5&3 90.0 72.0 252.1 13.129
October: 37.5 62.5 100.0 36.0 236.0 12.291
November: 30.0 50.0 80.0 72.0 232.0 12.083
December: 30.0 50.0 80.0 72.0 232.0 12.083
Total: 378.8 631.3 970.0 0.0 3978.0 5958.1 310.3
Heat Rate
Generator No. ID# Bhp hp Hr/Yr Gals/Hr Gals/Yr mm Btu/Hr mm Btu/Yr
1 E 101 587 440 25.3 15.0 378.8 2.12 53.41
2 E102 760 570 25.3 25.0 631.3 3.53 89.01
3 E103 603 452 48.5 20.0 970.0 2.82 136.77
4 E 104 534 401 0.0 20.0 0.0 2.82 0.00
Pk-Gen Pk-Gen 1 2670 2003 55.3 72.0 3978.0 10.15 560.90
Total 5154 3866 154 152 5958.1 21 840
Criteria Pollutants Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
(Lb/mm BTU) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr) (Tons/Yr)
TSP 0.31 0.008 0.014 0.021 0.000 0.087 0.130
PM-10 0.31 0.008 0.014 0.021 0.000 0.087 0.130
PM-2.5 0.31 0.008 0.014 0.021 0.000 0.087 0.130
Sox 0.29 0.008 0.013 0.020 0.000 0.081 0.122
Nox 4.41 0.118 0.196 0.302 0.000 1.237 1.852
VOC 0.36 0.010 0.016 0.025 0.000 0.101 0.151
CO 0.95 0.025 0.042 0.065 0.000 0.266 0.399
Hazardous/Toxic Emisson Factor Gen.#1 Gen.#2 Gen.#3 Gen.#4 Pk-Gen Total
irPollutants (Lbjm BTU) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr) (Lbs/Yr)
Acetaldehyde 7.67E-04 0.041 0.068 0.105 0.000 0.430 0.644
1 U Acrolein 9.25E-05 0.005 0.008 0.013 0.000 0.052 0.078
Benzene --9-3a -84- 0.050 1 0.083 0.128 0.000 0.523 0.784
Benzo a rene 1.88E-07 0.000 0.000 0.000 0.000 0.000 0.000
Formaldehyde 1.18E-03 0.063 0.105 0.161 0.000 0.662 0.991
Na thalene 8.48E-05 0.005 0.008 0.012 0.000 0.048 0.071
Toluene 4.09E-04 0.022 0.036 0.056 0.000 0.229 0.344
X lene 2.85E-04 0.015 0.025 0.039 0.000 1 0.160 0.239
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc Page 1

Page 2 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Generators : OS-2
Green House Gas Pulutants
GHG Pollutant Emisson Factor E101 E102 E103 E104 Total
Lb/mm BTU tons/ r tons/ r tons/ r tons/ r tons/ r
CO2 43.99 1.17 1.96 3.01 0.00 6.14
Methane 0.007 0.000187 0.0003115 0.0004787 0.0000000 0.00098
(CH4)
Nitrous Oxide 0.001 0.000027 0.0000445 0.0000684 0.0000000 0.000140
(N20)
Green House Gas Pulutants for Peak Generator
GHG Pollutant Emisson Factor Ibs/yr tons/yr
(Ibs/hp-hr)
CO2 0.31 34306.38 17.15
Methane
(CH4) 0.0001 11.07 0.0055
Nitrous Oxide 0.00001 1.11 0.000 55
(N20)
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc Page 2

Annual Air Emissions Inventory
Facility ID#: 0800044
Fire Pumps
Data used for inventory only!
Year. 2009
Total Run Time: 0.0 Hrs/Yr
Efficiency: 75 %
Sulfur Content: 0.3 %
Number 2 Fuel: 141000 Btu/Gal
Gallons Hours Gallons/
Month Fuel Operated hour
Used
January: 30.0 1.5 20.0
February: 40.0 2.0 20.0
March: 80.0 4.0 20.0
April: 40.0 2.0 20.0
May: 50.0 2.5 20.0
June: 40.0 2.0 20.0
July: 30.0 1.5 20.0
August: 40,0 1 2.0 20.0
September: 30.0 1.5 20.0
October: 50.0 2.5 20.0
November: 40.0 2.0 20.0
December: 40.0 2.0 20.0
Total: 510.0 25.5 20.0

Annual Air Emissions Inventory
Facility ID#: 0800044
Butanol: OS-7, OS-10
Year: 2009
Info: Lbs/Gal = 6.76
Monthly Inventory of Butanol (gallons):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Gallons of Butanol used during the year: 0
Lbs. Of Butanol used during the year:
Lbs. of Butanol used by Misc., QA, and R&D:
Lbs. of Butanol sent to hazardous waste:
Lbs. of Butanol sent to wwt:
Lbs. of Butanol emitted during year: 0
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc

Annual Air Emissions Inventory
Facility ID#: 0800044
Calcium hydroxide
Year: 2009 Common Name : Lime
Monthly Inventory of Calcium hydroxide (pounds):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0.0 0.0 0.0
February: 0.0 0.0 0.0
March: 0.0 0.0 0.0
April: 0.0 0.0 0.0
May: 0.0 0.0 0.0
June: 0.0 0.0 0.0
July: 0.0 0.0 0.0
August: 0.0 0.0 0.0
September: 0.0 0.0 0.0
October: 0.0 0.0 0.0
November: 0.0 0.0 0.0
December: 0.0 0.0 0.0
Lbs. Of Lime used during the year: 0.00
Lbs./Hr. of Lime Uploaded (design): 33000
Operation Time (hours):
Lbs/Hr of Lime Emitted (design): 0.135
Lbs/Year of Lime Emitted: 0.000
Tons/Year of Lime Emitted: 0.000

Annual Air Emissions Inventory
Facility ID#: 0800044
Chloroform : OS-9
Year: 2009
Info: Lbs/Gal = 12.35
Monthly Inventory of Chloroform (pounds):
Month Beginning Received Max Used Ending
Inventory Inventory
January: 13444 13444 13444
February: 13444 13444 13444
March: 13444 13444 13444
April: 13444 13444 13444
May: 13444 13444 13444
June: 13444 13444 13444
July: 13444 13444 13444
August: 13444 13444 13444
September: 13444 13444 13444
October: 13444 13444 13444
November: 13444 13444 13444
December: 13444 13444 13444
Lbs. of chloroform used during the year: 0
Lbs. of chloro. used by Misc., QA, and R&D:
Lbs. of chloro. used by EVG: 0
Lbs. EVG Produced:
Lbs. of chloroform sent to hazardous waste:
Pounds of chloroform sent to WWT:
Pounds of chloroform emitted during year: OS-9 0
C:\Environmental\Air Permit\Air Reports\Annual Air Emissions Inventory\2009 Report\2009 AAE Calc

Annual Air Emissions Inventory
Facility ID#:0800044
Ethyl acetate : OS-6&OS-7
Year: 2009
Info: Lbs/Gal= 7.50
Monthly Inventory of Ethyl acetate fpoundsl:
Month.Beginning Invent oW 1 Bulk Drums Ethyl acetate Used in SDA Alcohol
a;
Total Beginning Beginning New Recovered Recovered In Max Monthly Total Ending Ethyl acetate
Month Beginning New Recovered Received New Used Used Drums (Lbs) Used(Lbs.) Inventory Month Emitted Lbs.Inventory Inventory Inventory (Lbs.)
Janua 12881„, !38§1 9000 663.00 8086.88 1583.12 12881 7166.8 5714 Janua 36.67
Februa : 5714 3218 2496 148.00 _ 4329,38 1938,3.8 5714 2539.0 3175 February: 17.23
March: 3175 3070 105 3175 0.0 3175 March: 29.26
April: 3175 3070 105 67.00 _ 3175 67.0 3108 Aril: 20.15
-May: 3108 3003 105 _ 3108 0.0 3108 May: 48.66
June: 3108 3003 105 3108 0.0 3108 June: 7.52
July: 3108 3003 105 3108 0.0 3108 July: 7.88
August: 3108 3003 105 219.00 3108 219.0 2889 August: 3.63
September: 2889 2784 105 3272.0 338.00 6161 338.0 5823 September: 28.94
October: 5823 5718 105 555.00 _ 5823 555.0 5268 October: 0.30
November: 5268 5163 105 5268 0.0 5268 November: 50.20
December: 5268 5163 105 369.00 _ 5268 369.0 1 4899 December: 0.00
Lbs.of Ethyl acetate used during the year: 11446.32
Misc.Lbs.of Ethyl acetate used(PNE):OS-7 9210.76
Lbs.of Ethyl acetate used In SFG:OS-6 2043.00
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(PNE):OS-7 192.56
Lbs.of Ethyl acetate VOC from SDA Ethanol Loss(Crown Process):
Total Lbs,of Ethyl acetate emitted during year: 11446.32

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethylenediamine : OS-31
Year: 2009
All ethylenediamine is contained and
Info: Lbs/Gal = 7.50 shipped off-site with the product.
Monthly Inventory of Ethylenediamine (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 1985. 14888 1985
February: 1985 14888 1985
March: 1985 14888 1985
April: 1985 14888 1985
May: 1985 14888 1985
June: 1985 14888 1985
July: 1985 14888 1985
August: 1985 14888 1985
September: 1985 14888 1985
October: 1985 14888 1985
November: 1985 14888 1985
December: 1985 14888 1985
Total Gallons of Eth lenediamine Used: 0
Total Lbs. Eth lenediamine Used: 0
Gallons sent to Hazardous Waste:
Lbs. Eth lenediamine set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. Eth lenediamine Emitted: OS-31 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Ethanol (100%) - OS-7
Year: 2009
Info: Lbs/Gal = 6.58
Monthly Inventory of Ethanol (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 3630 23896 3630
February: 3630 23896 3630
March: 3630 23896 3630
�
April: 3630 23896
3630
May: 3630 23896 3630
June: 3630 23896 3630
Jul 6 3 30
2389
6
3630
August: 3630 23896 3630
September: 3630 23896 3630
October: 3630 23896 3630
November: 3630 23896 3630
December: 3630 23896 3630
Total Gallons of Ethanol Used: 0
Total Lbs. Ethanol Used: 0
Gallons sent to Hazardous Waste:
Lbs. Ethanol set to Hazardous Waste: 0
Total Gallons sent to WWT: 0
Total Lbs. sent to WWT: 0
Total Lbs. of Ethanol Emitted as VOC: 0

Gallons to VOC (Lbs.)
WWT
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0

Annual Air Emissions Inventory
Facility ID#:0800044
Ethanol-SDA:OS-7&OS-10
.su5- 3 f.•„ „_ ( .,.i,r . 19.OS-27,OS-32 INCLUDED WITH OS-10 a 1.,,� p_ ,.)e ?,K ter+• ,,F':' ;,s I€ ib�' €?bs"'
;` „aX�a ,...,r.�r _ ...«.e.. .n��k•..,c �`,.n�� •,„k, .�.� ,w,..,&ta.. � T2
r
Year. � 2009 .
Info: Lbs/Gal= 6.87 %SDA Ethyl acetate= 4.54
Monthly Inventory of Ethanol(gallons),
Monthly Beginning Inventory Bulk Drums
Total SDA Bulk SDA in Drums Total SDA SDA to Ethyl SDA Max SDA on Y
SDA SDA SDA in Drums SDA Hand Ending SDA Used SDA Used WWT SDA VOC Acetate
Month Beginning Beginning Beginning SDA Used Recovered Inventory (gallons)Received Transferred Received Recovered
Inventory Inventory Inventory Used (Lbs) ry (9 ) (Lbs.) (Lbs.) (Lbs.) Emitted
-. ,__�_ T __---- ------- - (Lbs.)
Janua 18714 '10976 7738�.. 6041.0 1510.3 4369 170065 18876 5879 40390.4 39582.E 80Z8 36.67
February: 1887E 15507 3369 25910 _7687_ __ 1517 129675 16114 2762 18971.8 18592.4 379.4 17.23
March: 16114 1291E 3198 10983,0 " 8902.0 _ 142 4354 _ 186156 22407 4690 32223.5 31579.0 644.5 1
29.28
April: 22407 14997 7410 5787.0 8875.0 _ _ 525 169 193690 24963 3231 22194.6 21750.7 443.9 20.15
May: 24963 1790s 7054 4903. 7 . _ 324 _ 273 205179 22066 7800 53586.3 52518.5 1071.8 48.68
June: 2206E 15063 7003 5743.0- 1208 0 _ 191045 26603 1206 8285.2 8119.5 165.7 7.52
July: 26603 19600 7003 1609 0 -- _------- ----
_-
155 500 182760 25339W-464O
8680.6 8507.0 173.6I
August: 25339 17991 7348 582.0 _ 174079 ff
3998.3 3918.4 80.0
September: 24757 17409 7348 12090.0 1389.0
_ 6029 253139 -31878,8 -31239.3 -ti37.5 October: 41487 28110 13377 48.0 _ 285018 329.8 323.2 6.8 November: 41439 28082 13377 '. 5394.0 _ 5678.0 4190 _ 1830_ 321743 55282.9 54177.2 1105.7December: 38786 27778 11008 266460 38786 0.0 0.0 0.0
Total Gallons of SDA Used: 30868.8
Total Lbs.SDA Used: 212068.6
Gallons sent to Hazardous Waste:
Lbs.SDA Ethanol sent to Hazardous Waste: 0.00
Total Gallons sent to WWT: 30251.41
Total Lbs.sent to WWT: 207827.22
Total SDA Ethanol VOC's 4241.37
Lbs.Botanical Extraction Ethanol Emitted:OS-10 7272. 99 -'
Lbs.PNE Ethanol Emitted:OS-7 2969.08 -
Misc.Lbs.SDA Ethanol Emitted: _
Total Lbs.of SDA Ethanol Emitted: 4241,37

Page 1 of 4
Annual Air Emissions Inventory
Facility ID#:0800044
Hexane
OS-4, OS-5, OS-6, OS-10, OS-28, OS-29
OS-13.OS-14,OS-15.OS-16,OS-17,OS-20,OS-21,OS-22.OS-23.OS-32 ALL INCLUDED WITH OS-4
OS-18.OS-19 INCLUDED WITH OS-10:OS-30 INCLUDED WITH OS-28
Year: 2009
Info: Lbs/Gal= 5.50
Monthly Inventory of LP Hexane-34.4%(gallons):
Month Beginning Received Max Used Ending Inventory
Invento Lbs
January: 5798 4178 54868 1185 8791
February: 8791 48351 1223 7568
March: 7568 41624 1094 6474
April: 6474 35607 858 5616
May: 5616 30888 5616
June: 5616 30888 5616
July: 5616 30888 5616
August: 5616 30888 5616
September: 5616 4390 55033 561 9445
October: 9445 51948 1606 7839
November: 7839 43115 482 7357
December: 7357 40464 1085 6272
Monthly Inventory of HP Hexane-95%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 3006 16533 722.36 2284
February: 2284 12560 54927 1734
March: 1734 9539 1734
April: 1734 9539 376.36 1358
May: 1358 7469 348.18 11010
June: 1010 5554 1 1010
Jul : 1010 5554 11010
August: 1010 5554 924.91 185
September: 85 5964 33269 670.91 5378
October: 5378 29579 1377,09 4001
November: 4001 22005 1030 2971
December: 2971 16340 228 2743
Monthly Inventory of IsoHexane-2.5%(gallons):
Month Beginning Received Max Used Ending Inventory
Inventory Lbs
January: 34473 7611 231462 3872 38212
February: 38212 210166 4728 33484
March: 33484 184162 33484
April: 33484 184162 33484
May: 33484 14834 265749 6356 41962
June: 41962 33189 413331 1 28248 46903
July: 46903 32751 438097 40978 38676
August: 38676 212718 2485 ' 36191
September: 36191 199051 179 36012
October: 36012 198066 6A 36006
November: 36006 198031 36006
December: 1 36006 198031 36006

Page 2 of 4
Total Hexane Values
Gallons of LP Hexane Used: 8094.00 Gallons of N-Hexane Used: 9191.94
Gallons of HP Hexane Used: 6227.08 Lbs.of N-Hexane Used: 50555.67
Gallons of IsoHexane Used: 86852.40 Gallons of Hexane Isomers Used: 91981.54
Total Gallons of Hexanes Used: 101173.48 Lbs.of Hexane Isomers Used: 505898.47
Total Lbs.of Hexanes Used: 556454.14
Sclareolide(SIDE)Operation:OS-5
Percent N-Hexane in Solvent: 34.4
Gallons of Hexane Used in SDE: 8094.00 ` Lbs.of Fugitive Hexane from SDE: 44021.96
Lbs.of Hexane Used in SDE: 44517 Lbs.of Fugitive N-Hexane from 15143.55
SDE:
Lbs.of Fugitive Hex Isomers from
Lbs.of SDE Product: 99008.58 SDE: 28878.40
Lb.Hexane per Lb.of SDE 0.005
Product:
Lbs.Hexane in SDE Product: 495.04
Lbs.N-Hexane in SDE Product: 170.29
Accountable Lbs.of Hexane Lost: 495.04 Accountable and Fugitive Lbs. 44517.00
Hexane Emitted
Accountable Lbs.of N-Hex Lost: 170.29 Accountable and Fugitive Lbs. 15313.85
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 324.75 Accountable and Fugitive Lbs.Hex 29203.15
Lost: Isomers Emitted:
Lbs.of Hexane Sent as Hazardous 9180.05
Waste:
Lbs.of N-Hex Sent as Hazadarous 2g37.616
Waste:
Lbs.of Hex Isomers in Hazardous
Waste: 6242.434
Sclareol Recrvstallization(SFG)Operation:OS-6
Percent N-Hexane in Solvent: 95
Gallons of Hexane Used in SFG: 6227.08 Lbs.of Fugitive Hexane from SFG 33802.92
Lbs.of Hexane Used in SFG: 34248.94 Lbs.of Fugitive N-Hexane from 32112.77
SFG:
Lbs.of Fugitive Hex Isomers from
Lbs.of SFG Product: 89204 1690.15
SFG:
Lb.Hexane per Lb.of SFG 0.005
Product:
Lbs.Hexane in SFG Product: 446.02
Lbs.N-Hexane in SFG Product: 423.72
Accountable Lbs.of Hexane Lost: 446.02 Accountable and Fugitive Lbs. 34248.94
Hexane Emitted:
Accountable Lbs.of N-Hex Lost: 423.72 Accountable and Fugitive Lbs. 32536.49
N-Hex Emitted:
Accountable Lbs.of Hex Isomers 22.30 Accountable and Fugitive Lbs.Hex 1712.45
Lost: Isomers Emitted:

i
Page 3 of 4
Rotocel,Concrete,&Recovery Operations:OS 4
Gallons of Hexane Used: 56113.00 Gallons sent to WWT: 1237489
Lbs.of Hexane Used: 308621.5 Lbs.Waste Water per Gal.Waste 8.34
Water:
Percentage of N-Hexane in
Solvent: 1.39 Wt%of Hexane in Waste Water: 0.014
Lbs,of Hexane Sent as Hazardous
Waste: 6684.8 Lbs.Hexane Lost in Waste Water: 1444.89
Lbs.of N-Hex Sent as Hazadarous 9292 Lbs.N-Hexane Lost in Waste
Waste: . Water: 20.08
Lbs.of Hex Isomers in Hazardous
Waste: 6591.88 Accountable Lbs.of Hexane Lost: 40870.97
Lbs.Hex per day exiting Mineral
Oil Scrubber from MO tests): 47.17 Accountable Lbs.of N-Hex Lost: 568.11
Days of MO Unit operation: 67 Accountable Lbs.of Hex Isomers 40302.86
Lost:
Lbs.of Hex exiting MO Unit: 3160.39
Lbs.of N-Hex exiting MO Unit: 43.93
Lbs.of Hex Isomers exiting MO
Unit: 3116.46 Total Lbs.Hexane Lost as Fugitive: 267750.53
Lbs.Sage Processed: 32642380, Total Lbs.N-Hex Lost as Fugitive: 3721.73
Lbs.Hexane per Lbs.of Spent 0.001111 Total Lbs.Hex Isomers Lost as 264028.80
Sage(from Desolvitizer tests): Fugitive:
Lbs.Hexane in Spent Sage: 36265.68
Lbs.N-Hexane in Spent Sage: 504.09
Lbs.Hexane per Day from A-1
Vent Cond. 0.000815
Days A-1 Operated: 67 Accountable and Fugitive Lbs. 308621.5
Hexane Emitted:
Lbs.Hex Exiting A-1 Vent: 0.055 Accountable and Fugitive Lbs. 4289.84 /
N-Hex Emitted:
Lbs.N-Hex Exiting A-1 Vent: 0.000759 Accountable and Fugitive Lbs.Hex 304331.66
Isomers Emitted:

Page 4 of 4
Biomass Extraction Operation:OS-28
Gallons of Hexane Used: 28714.00' s.of Fugitive exane from
Bio Extraction: 157683.35
Lbs.of Fugitive N-Hexane from Bio
Lbs.of Hexane Used: 157927 Extraction: 1243.77
Lbs.of Biomass Product: 1202435.1_. Lbs.of Fugitive Hex Isomers from 156439.58
Bio Extraction:
%n-Hexane -0.79
Lbs.Hexane as Hazardous Waste 243.65
Lbs.n-Hexane as Hazardous
Waste t::1'92
Bo
tanical Extraction Operation:OS-10
Gallons of Hexane Used: Lbs.of Fugitive Hexane from 0
Bot Extraction:
Lbs.of Hexane Used: 0 Lbs.of Fugitive N-Hexane from Bot 0
Extraction:
Lbs.of Botanical Product: Lbs.of Fugitive Hex Isomers from 0
Bot Extraction:
%n-Hexane
Plant Nutrient Extraction M-13 Operation:OS-29
Gallons of Hexane Used: 2025.40 Lbs.of Fugitive Hexane from 11139.7
PNE:
Lbs.of Fugitive N-Hexane from
Lbs.o, Hexane Used: 11139.7 PNE: 88.00363
Lbs.of PNE Product: 25.872 Lbs.of Fugitive Hex Isomers from 11051.69637
PNE:
%n-Hexane 0.79
i
Totals for All Operations
Fugitive Lbs.N-Hex.Emitted: 53999.98 Total Lbs.n-Hexane Released: 53471.96
Fugitive Lbs.Hex Isomers
Emitted: 462088.62 Total Lbs.Hex Isomers Released: 502738.53
Accountable Lbs.n-Hexane Lost: 1162.12 Total Lbs.N-Hexane Sent Off Site: 92.92
Accountable Lbs.Hex Isomers 40649.91 Total Lbs.Hex Isomers Sent Off 6591.88
Lost: Site:
Total Lbs.Hexane Sent Off Site: 6684.80
Annual Summary:Maximum n-Hexane On-Hand
Total Hexane Total Total N-Hexane
Month (Gallons) n-Hexane (Lbs.)
Gallons
January: 49287 5938 32658.3
February: 42786 4907 26985.8
March: 41692 4556 25060.4
April: 40458 3924 21583.8
EEMay: 48588 3806 20930.3
June: 53529 3929 21609.7
Jul 45302 3723 20478.5
August: 41892 2783 15304.1
September: 50835 9032 49675.0
October: 47846 7209 39652.2
November: 46334 6077 1 33422.1
December: 45021 5513 30321.2
Max Hexane Max N-Hexane Max N-Hexane
Maximum Hexane On-Hand Gal. Gal. Lbs.
53529 9032 49675

Annual Air Emissions Inventory
Facility ID#: 0800044
Heptane : OS-6
Year: 2009
Info: Lbs/Gal = 5.70
Monthly Inventory of Heptane (gallons):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 496 2827 496
February: 496 2827 496
March: 496 2827 496
April: 496 2827 496
May: 496 2827 496
June: 496 2827 496
July: 496 2827 496
August: 496 2827 496
September: 496 2827 496
October: 496 2827 496
November: 496 2827 496
December: 496 2827 496
Sclareol Recrystallization (SFG) Operation
Percent N-Heptane in
Solvent: 0.85
Gallons of Heptane Used in 000 Lbs. of Fugitive Heptane
SFG: . from SFG: 0.00
Lbs. of Heptane Used in 0 Lbs. of Fugitive N-Heptane
SFG: from SFG: 0.00
Lbs. of Fugitive Hept.
Lbs. of SFG Product: Isomers from SFG: 0.00
Lb. Heptane per Lb. of SFG 0.005
Product:
Lbs. Hexane in SFG Product: 0
Lbs. N-Heptane in SFG
Product: 0.00
Accountable Lbs. of Hexane 000 Accountable and Fugitive
Lost: . Lbs. Heptane Emitted: 0.00
Accountable Lbs. of N-Hept. 000 Accountable and Fugitive
Lost: . Lbs. N-He t. Emitted: 0.00
Accountable Lbs. of Hept. 0 Accountable and Fugitive
Isomers Lost: .00 Lbs. Hept. Isomers Emitted: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Hydrochloric Acid : OS-7
Year: 2009
Info: Lbs/Gal =
Monthly Inventory of Hydrochloric Acid Obs):
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 2000'''' 0 1098 902
October: 902 0 902
November: 902 0 169.6 732
December: 732 0 732

Annual Air Emissions Inventory
Facility ID#: 0800044
Isobutyl acetate: OS-7, OS-10
Year: 2009
Info: Lbs/Gal = 7.22
Monthly Inventory of Isobutyl acetate (gallons):
Beginning Max Used Ending
Month Inventory Received (Lbs) New Used Recovered Recovered Inventory
_ Used
January: 138 2648 20116 416 1377 3747
February: 3747 27055 845 2902
March: 2902 20955 2902
April: 2902 1323 30507 1334 1377 1514
May: 1514 10933 1514
June: 1514 10933 1514
July: 1514 10933 _ 1514
August: 1514 10933 1514
September: 1514 10933 1514
October: 1514 10933 1514
November: 1514 10933 1514
December: 1514 10933 1514
Gallons of IBAC used during the year @ PNE (OS-7): _ 3972
Lbs. Of IBAC used during the year @ PNE (OS-7): _ 28678
Gallons of IBAC used during the year @ (OS-10):
Lbs. Of IBAC used during the year @ (OS-10): _ 0
Lbs. of IBAC used by Misc., QA, and R&D:
Lbs. of IBAC sent to hazardous waste: 24320
Lbs. of IBAC sent to wwt: _
Lbs. of IBAC emitted during year: 4358

Annual Air Emissions Inventory
Facility ID#: 0800044
Isopropyi acetate: OS-7, Os-10
Year: 2009
Info: Lbs/Gal =
Monthly Inventory of Isopropyl acetate (pounds):
Month Beginning Received Max Used Ending
Invento Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 1 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
December: 0 0 0
Lbs. of IPAC used during the year @ PNE (OS-7): 0
Lbs. of IPAC used during the year @ (OS-10):
Lbs. of IPAC used by Misc., QA, and R&D:
Lbs. of IPAC sent to hazardous waste: 15580
Lbs. of IPAC sent to wwt:
Lbs. of IPAC emitted during year: -15580

Page 1 of 2
Annual Air Emissions Inventory
Facility ID#: 0800044
Methanol: Os-4, OS-i, OS-9
OS-13, OS-14. OS-15, OS-16, OS-17, OS-27, OS-32 INCLUDED WITH OS-4
Year: 2009
Info: Lbs/Gal = 6.60 Specifice Gravity = 0.793
Monthly Inventory of Methanol (gallons):
Beginning Max Ending
Month InventoryReceived Lbs Used Inventory
January: 14737 97264 998.7 13738
February: 13738 90673 13738
March: 13738 90673 13738
April: 13738 90673 13738
May: 13738 12186.0 171100 25924
June: 25924 5990.0 210634 8225.0 23689
July: 23689 6114.0 196702 12658.0 17145
August: 17145 113159 206.0 16939
September: 16939 111799 16939
October: 16939 1 111799 16939
November: 16939 111799 16939
December: 16939 111799 16939
Maximum Gallons On-Hand: 31914.3
Maximum Lbs. On-Hand: 210634.38
Gallons Used per Year: 22087.7
Lbs. Used per Year: 145778.82
Sclareoi Recovery Operation: OS-4
Total Lbs. McOH Used: 139187.4 Avg. % MeoH thru Pods: 85
Avg. % McOH in WW: 13.2 Avg. Gal/Min Thru Pods: 9
Avg. Gals/Min Sent to WWTP: 2.8 Number of Stream Days 67
Number of Stream Days: 67 Total Gal. Thru Pods: 868320
Total Gal. of WW to WWTP: 270144 Total Gal. McOH Thru Pods: 738072
Total Lbs. of WW to WWTP: 2253000.96 Total Lbs. McOH Thru Pods: 4871275.20
Total Lbs. of McOH to WWTP: 95674.85 Total Lbs. Fugitive Emissions from Recovery: 43512.55
Accountable Lbs. Emissions of Total Accountable and Fugitve
McOH from WWTP during 1073.08 Emissions from Recovery: 44585.62
et c e — I I,,d
Avg. RemoEalficiency of
WWTP: 98.88
� �9

Page 2 of 2
EVG Operation: OS-9
Gallons of McOH Used: 0 Accountable Emissions of
Gallons of McOH to WWT: 0 McOH from WWTP during 0.00
Total Lbs. of McOH to WWT: 0.00 EVG:
Total Lbs. Fugitive Emissions 0.00 Total Accountable and Fugitve 0.00
from EVG: Emissions from EVG:
PNE Operation: OS-7
Gallons of McOH Used: 998.7 Accountable Emissions of
Gallons of McOH to WWT: 978.726 McOH from WWTP during 64.60
Total Lbs. of McOH to WWT: 6459.5916 PNE:
Total Accountable and Fugitve 196.42
Total Lbs. Emissions PNE: 131.8284 Emissions from PNE:
Totals for All Methanol Operations
Lbs. of Emissions from Misc., 131.8284
Total Lbs. McOH Thru System: 4871275.20 Lab:
Total Lbs. McOH to WWTP: 102134.45 Lbs. Fugivtive Emissions from 0.00EVG:
Removal Efficiency of WWTP: 98`9
Lbs. Fugivtive Emissions from 43512.55
Recovery:
Lbs.Accountable Emissions 1137,67 Total Lbs. Fugitive Emissions: 43644.37
from WWTP: -----
Total Lbs. McOH Treated at 102134.45 Total Lbs. McOH Released: 44782.05
WWTP:
Total Lbs. McOH Recycled On- 4724358.71
Site:
i
1"p Q
- 'Kla l

SARA 313 R Reporting
Facility ID#: 0800044
Maganese
200
Info: Potassium permanganate contains 33-35% Manganese.
Monthly Inventory of Potassium Permanganate (pounds:
Month Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 16537 16537 16537
February: 16537 16537 16537
March: 16537 16537 16537
April: 16537 16537 16537
May: 16537 16537 16537
June: 16537 16537 16537
Jul : 16537 16537 16537
August: 16537 16537 16537
September: 16537 1 16537 16537
October: 16537 16537 16537
November: 16537 16537 16537
December: 16537 16537 16537
Max Lbs. Potassium Permanganate on Hand: 16537
Lbs. of Potassium Permanganate used during the year: 0
Max Lbs. Maganese on Hand: 5623
Lbs. of Maganese used: 0
Percentage Maganese sent On-Site: 100
Percentage Maganese sent Off-Site: 0
Lbs. Maganese Shipped On-Site: 0
Lbs. Maganese Shipped Oft-Site: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Sulfur dioxide
Year: 2009
info: Lbs/Gal =
Monthl Invento of Sulfur dioxide (pounds):
Y rY (p )
Month
Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 0 0 0
February: 0 0 0
March: 0 0 0
April: 0 0 0
May: 0 0 0
June: 0 0 0
July: 0 0 0
August: 0 0 0
September: 0 0 0
October: 0 0 0
November: 0 0 0
i December: 0 , 0 0
Lbs. of Sulfur dioxide used during the year: 0
Lbs. of Sulfur dioxide used by Misc., QA, and R&D:
Lbs. of Sulfur dioxide sent to hazardous waste:
Lbs. of Sulfur dioxide sent to wwt:
Lbs. of Sulfur dioxide emitted during year: 0

Annual Air Emissions Inventory
Facility ID#: 0800044
Toluene
Year: 2009
Info: Lbs/Gal = 7.23
Monthly Inventory of Toluene (gallons):
Month
Beginning Received Max Used Ending
Inventory Lbs Inventory
January: 920 6652 920
February: 920 6652 920
March: 920 6652 920
April: 920 6652 920
May: 920 6652 920
June: 920 6652 920
July: 920 6652 920
August: 920 6652 920
September: 920 6652 920
October: 920 6652 920
November: 920 6652 920
December: 920 6652 920
November: 920 6652 920
December: 920 6652 920
Gallons of Toluene used during the year: 0.00
Lbs. of Toluene used during the year: 0.00
Lbs. of Toluene sent to hazardous waste:
Total Gal. of Toluene sent to WWTP:
Specific Gravity of WW: 8.60
Avg. ppm Toluene in WW: 800.00
Lbs. of Toluene sent to WWTP: 0.00
Lbs. of Toluene used by Misc, Labs, etc..-
Fugitive Toluene Loss in Process:
Lbs. of Toluene emitted during year: 0.00

Annual Air Emissions Inventory
Facility ID#: 0800044
Plant Material Grinder : OS-3
Year: 2009
The Plant Material Grinder (OS-3) is operated in building ID # 1003-4. The grinder has a filter
which captures 99 + % of all particulates. There are no solvents, HAP/TAPS, or VOC associated
with the grinder's operation. Essentially there are no emissions associated with the plant
material grinder.

Monthly VOC's
YEAR: 2009
Lbs of VOC Emissions
TOTAL
SOURCE CHEMICAL TOTAL
JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC (tons)
(Ibs.)
BOILERS #2 Fuel Oil 13.448 12.370 10.399 6.406 9.802 32.245 31.731 9.359 6.763 7.223 9.324 8.835 157.903 0.079
GENERATORS #2 Fuel Oil 21.249 6.250 14.166 25.207 10.416 43.956 105.618 33.852 13.129 12.291 12.083 12.083 310.298 0,155
-VG Chloroform 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Methanol 0.00 0.00
Ethyl acetate 36.71 17.25 29.29 20.17 13.97 7.53 7.89 3.63 -28.98 0.30 27.17 0.00 134.94 0.07
from SDA
Ethyl acetate 6819.80 2391.00 ' 29.26, 20 15 13.91 0,23 9274.35 4.64
Eth lediamine 0.00 0.00
Ethanol-100% 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
PNE Ethanol-SDA 807.81 379A4 644.47 443.89R303 1165.70 173.61 79.97 -637.54 6.60 597.80 0.00 2969.05 1.48
H drochloric Acid 0.00 0.00 0.00 0.000 0.00 0.00 0.00 1098.00 0.00 169.60 0.00 1267. 00 0.63
Hexane_ 8883,60 2220.90 1064,80 12169.30 6.08,n-Hexane 0.00 0.00 0.00 0.000 0.00 0.00 70.18 17.55 8.41 0.00 0.00 96.14 0.05
Isohexane 0.00 0.00 0.00 0.000 0.00 0.00 8813.42 2203.35 1056.39 0.00 0.00 12073.16 6.04
Isobut I acetate 60.07 122.00 0.00 192.630 0.00 0.00 0.00 0.00 0.00 1 0.00 0.00 374.70 0.19
Methanol 131.83 1 1 1 131.83 0.07
Biomass Hexane 21296.00 26004.00 34958.00 36498.00 39171.00 157927.00 78.96
Extraction n-Hexane 168.24 205.43 0.00 0.00 276.17 288.33 309.45 0.00 0.00 0.00 0.00 0.00 1247.62 0.62
Isohexane 21127.76 25798.57 0.00 0.00 34681.83 36209.67 38861.55 0.00 0.00 0.00 0.00 0.00 156679.38 78.34
Ethyl acetate 0.00 0.00 0.00 0.00 34.75 0.00 0.00 0.00 0.00 0.00 23.08 0.00 57.83 0.03
Botanical Ethanol-SDA 764.49 I . 507.80 1272.29 . :. 0.64
Extraction Hexane 0.00 0.00
n-Hexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0,00 0.00 0.00
Isohexane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Hexane 1118866.00 186208.00 3547.50 , 308621.50 154.31
Rotocel& n-Hexane 0.00 0.00 0.00 0.00 0.00 1652.24 2588.29 49.31 0.00 0.00 0.00 0.00 4289.84 2.14
Recovery Isohexane 0.00 0.00 0.00 0.00 0.00 117213.76 183619.71 3498.19 0.00 0.00 0.00 0.00 304331.66 152.17
Methanol 8894,69 39098.99 -4481.14 43512.54 21.76
Hexane 6517.50 6726.50 6017.00 4719.00 0.00 0.00 0.00 0.00 3085.50 8833.00 2651.00 5967.50 44517.00 22.26.
Sclareolide n-Hexane 2085.60 2152.48 1925.44 1510.08 0.00 0.00 0.00 0.00 987.36 2826.56 848.32 1909.60 14245.44 7.12
Isohexane 4431.90 4574.02 4091.56 3208.92 0.00 0.00 0.00 0.00 2098.14 6006.44 1802.68 4057.90 30271.56 15.14
Ethyl acetate 347.00 148.00 67.00 219.00 -338.00 555.00 369.00 2043.00 1.02
Hexane 3972.98 3020.99 0.00 2069.98 1914.99 0.00 0.00 5087.01 3690.01 7574.00. 5665.00 1254.00 34248.94 17.12
Recrystallization n-Hexane 3774.33 2869.94 0.00 1966.48 1819.24 0.00 0.00 4832.65 3505.50 7195.30 538135 1191.30 32536.49 16.27
(SFG) Isohexane 198.65 151.05 0.00 103.50 95.75 0.00 0.00 254.35 184.50 378.70 283,25 62.70 1712.45 0.86
He tane 0.00
N-He tane 0.00
VWVTP I Methanol 64.60 603.49 1 410.47 59.15 1137,71 0.57
TOTAL LBS.VOC 40089.00 38827.79 6744.58 7564.44 38027.62 165111.85 265207.31 13441.93 9785.79 1805120 9662.86 7611.42 632297.08 316.15
TOTAL TONS VOC 20.04 19.41 3.37 3.78 19.01 82.56 132.60 6.72 4.89 9.03 4.83 3.81 316.15 1 0.16