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HomeMy WebLinkAboutAQ_F_1000067_20080501_CEM_GenCorr WA A ® LT .......... NCDENR North Carolina Department of Environment and Natural Resources Division of Air Quality Michael F. Easley, Governor William G. Ross, Jr., Secretary B, Keith Overcash, P.E., Director May 1,2008 Mr. Lynn Haynes Air Monitoring and Technical Support Branch U.S. Environmental Protection Agency The Atlantic Federal Center, 61 Forsyth Street SW Atlanta, Georgia 30303 SUBJECT: Part 75 EPA Field Audit Summary Report Primary Energy—Southport Facility,Units 1 and 2 Facility I.D. No. 1000067 OBIS 10378 Dear Mr. Haynes: Attached is the Part 75 Level I audit report for Primary Energy's Southport Facility, Units 1 and 2 that I conducted on February 26, 2007. The original RATA audit dates were changed with short notice to accommodate installation of new flow monitors. The audit addressed all aspects of a Level I audit including: Inspections of the CEMS and records review. During the Level I audit, no compliance problems involving any regulatory requirements of Part 75 were observed. The Quality Assurance manual appears complete and fully implemented. The maintenance logs as well as emission data records appear complete. Records from EPA's Monitoring Data Checking software 4.2.57 (MDC 4.2.57)were checked with facility records. The facility information was consistent with the MDC information for missing data, failed calibrations, linearity test reports, CEMs model numbers and serial numbers. These records correctly reflect the daily and quarterly activities on the CEM systems. Additional data and RATA results are attached in Appendix 1. If you have any questions regarding this audit,please call me at(919) 715-0726. Sine ety Richard R. Simpson Environmental Engineer Attachment cc: Mr.Manuel Olivia, EPA Clean Air Market Division Mr. Gregory Wagoner, Primary Energy- Southport Mr. Wayne Cook, WilRO Central Files, Brunswick Co. Mike Aldridge, NCDENR-w/o attachment Dennis Igboko; NCDENR IMPAQ— Documents— 1000067 Technical Services Section 1�7one 7 1641 Mail Service Center,Raleigh,North Carolina 27699-1641 1v orthCdrolina 2728 Capital Blvd.,Raleigh,North Carolina 27604 ;Vahavlly Phone: 919-733-17281 FAX 919-733-1812/Internet: www.ncair.org An Equal Opportunity/Affirmative Action Employer—50%Recycled/10%Post Consumer Paper PART 75 CEMS FIELD AUDIT MANUAL: Appendix A - Example Audit Forms and Guide Sheets Primary Energy Southport Units 1 and 2 North Carolina EPA Region 4 CEMS Inspection Sheet Appendix A CEMS Inspection Sheet 1. Plant and Audit Information Plant Name: Primary Energy-Southport ORIS Code: 10378 City: Southport State: North Carolina Plant Contact: Gregory Wagner Contact Phone Number: 1-910-457-5056 x29 Inspector Name: Richard Simpson Audit Date: February 26,2008 2. Probe and Probe Location Checks What to Check Observations Probe locations in the stack or duct are in the Probe locations are the same as in the monitoring plan. same location as in the monitoring plan? Has the duct or stack location been Stack location is the same and has not changed. modified? (Dimensions) Have the probe or probe components(e.g., Probe and components are the same and has not changed. dilution probe orifice) been changed? New flow monitors were installed on Units I and 2. Page A-2 Part 75 Field Audit Manual-July 16,2003 Appendix A CEMS Inspection Sheet 3. Flow Monitors What to Check I Observations Ask the source to perform a daily Daily interference checks procedure as per QA/QC plan. interference check or review the results of the most recent test. App. B §2.1.2 requires a daily interference check for flow monitors. The interference check procedure and criteria are not defined by rule in Part 75. It should be described in the QA/QC Plan. When were the filters or transducers last Filters and transducers are replaced as needed. replaced? How does this compare to the QA/QC Plan? Ask what the QA/QC procedures are for any All temperature and stack pressure monitors compares with temperature and stack pressure monitors QA/QC plan and procedures. used in conjunction with the flow monitor. Have there been any problems? Compare to the QA/QC plan and maintenance records. Check if there have been any changes to k- High flow with gas RATA was performed with monitors at factors and polynomial coefficients since the high/normal load. No changes on k-factors,temp. may last RATA. Changes to correction factors fluctuate so equation may change. should be recorded in the maintenance log. A three load RATA is required following any change to flow monitor k-factors(§75.20(b)). Also see Table 8 -DAHS. What is the status of the control panel lights, All control panel lights, indicators and alarms were indicators and alarms? Displays will vary by functional and O.K. analyzer, so ask the source what the displays are and what they mean. Check range settings, and compare to the Range/span settings were compared to MDC data and O.K. monitoring plan. Has the source done the NOx—400 ppm, CO2—20%. annual span/range check required by App.A? E Part 75 Field Audit Manual—July 16, 2003 Page A-3 CEMS Inspection Sheet Appendix A 4. Dilution Air Systems (Including Air Cleaning Subsystem) What to Check Observations Has the dilution probe orifice been changed? The dilution probe orifice is normally changed as needed If the orifice has been changed, ask if there is and according to the QA/QC plan. a procedure for changing the orifice in the QA/QC Plan, what prompts a change,and how the dilution ratio is verified. Is the dilution probe ejector pump vacuum NA. at or below the certification value? How often is it checked? What is the dilution ratio? Check the Dilution ratio is 100:1 and analyzer flow settings correspond dilution air and analyzer flow settings. to the QA/QC plan. How are these set and verified? These should all be described in the QA/QC plan. Are correction factors applied to the dilution Correction factors are not used on this small system ratio for changes in pressure, temperature,or molecular weight? Have these been changed since the last RATA? Changes to correction factors should be recorded in the maintenance log,. QA testing may also be required . (Also see Table 8 -DAHS). Check the inlet and outlet pressures of COZ The inlet pressure is 100 psi and outlet pressure is 70 psi. air cleaner filter. Compare levels to the Levels compare to QA/QC procedure. QA/QC Plan. How often are the air cleaning filters and Heatless filter replaced quarterly as needed. drying agents replaced? Compare to the QA/QC plan. 5. Source Level Extractive Systems What to Check •. Observations'` Check the umbilical lines entering the CEMS Umbilical lines were checked and no moisture was present. shelter for condensation(visible water drops). For a dry system using chillers check the Wet, NA chiller temperature. What is the proper temperature range, and how often is it verified? Compare against the QA/QC Plan. Page A-4 Part 75 Field Audit Manual—July 16,2003 Appendix A CEMS Inspection Sheet 6. Analyzers What to Check Observations Ask the source if there have been any changes since the No major changes have taken place. Analyzer last audit or certification/recertification. Document the serial numbers correspond to MDC data and the serial numbers and compare to those in the monitoring monitoring plan. plan. What is the status of the control panel lights, indicators All control panel lights ,indicators and alarms and alarms? Displays will vary by analyzer,so ask the were functional and O.K. source what the displays are and what they mean. Check range settings, and compare to the monitoring Range/span settings were compared to MDC plan. Has the source done the annual span/range check data and O.K. required by App. A? NOx—400 ppm, CO2—20%, Flow 4020 afpm Compare the sample flow rate, if displayed by a Sample flow rate is displayed and corresponds to rotameter(or a digital reading),to the QA/QC Plan. the QA/QC plan. Unit 1: NOx—0.816 Lpm CO2—0.518 Lpm Unit 2: NOx—0.613 Lpm CO2—0.490 Lpm Have there been any changes to correction factors(NO, No known changes to the correction factors. quenching and moisture monitors)since the last RATA? Changes to correction factors should be recorded in the maintenance log,and the QA/QC Plan should outline the procedures for changing the correction factors(Appendix B, Section 1.1.3). QA testing may also be required(See §75.20(b),and Recertification and Diagnostic Testing Policy). Part 75 Field Audit Manual—July 16,2003 Page A-5 CEMS Inspection Sheet Appendix A 7. Calibration Gases What to Inspect Observations Spot check the cylinder certificates versus the cylinder Cylinder numbers engraved checked with numbers engraved on the cylinder. Table A may be used certificates and everything o.k. to record information for each cylinder. Verify that gases meet calibration gas definition in§ Verified and o.k. 72.2. See Table B. Check the expiration date of gas in cylinders. Use of an All cylinders in use before expiration and o.k. expired cylinder is not in compliance with§ 75.21(c). Check the concentration values for each cylinder. Are Concentration ranges are correct with the span. concentration ranges correct for the span? Linearity test point ranges are shown below: Point 1: 20%-30%of span Point 2: 50%-60%of span Point 3: 80%- 100%of span Check the zero air gas documentation. (Supplier Just zero air is used not zero gas. certification): SOz, NO,and THC s 0.1 ppm CO s 1 ppm,and COZ < 400 ppm [See§ 72.2 and Policy Manual 10.2, 10.3] Record the concentration values to check against the Concentration values checked with DAHS values recorded by the DAHS for calibration error and through daily calibration. linearity tests. Read the cylinder regulator pressure. Cylinder pressure All cylinder regulator pressures are above should not be< 150 psi. 150 psi. Check the regulator outlet pressure. The pressure or Checked and pressure as per QA test and calibration gas flow rate should be set as specified in the QA/QC procedure. QA test procedures in the QA/QC plan. Are stainless steel regulators used for SOZ cylinders? NA Page A-6 Part 75 Field Audit Manual—July 16,2003 Appendix A CEMS Inspection Sheet Table A: Calibration Gas Records Gas Cylinder Certificate Type of Cal Gas Cylinder Expiration Certificate No.: Concentration (e.g.,SRM,IPRM,, .Pressure I Date on File etc., NOx CC109673 230 Daily Calibration 1650 1/15/09 Yes CO2 CC50771 10.81% Daily Calibration 350 3/20/10 Yes Table B: Part 75 Calibration Gases (§ 72.2) Calibration Gas Type Abbr. Description NIST-standard reference material SRM Calibration gas obtained from the National Institute of Standards and Technology(NIST) NIST- standard reference material- PRM Listed in a declaration of equivalence with "EPA equivalent compressed gas primary Traceability Protocol for Assay and Certification of reference material Gaseous Calibration Standards," September 1997, EPA- 600/R-97/121[Traceability Protocol] NIST-traceable reference material NTRM Tested and certified by NIST NIST/EPA-approved certified CRM Approved by EPA and NIST as evidenced by a certificate reference materials or other documentation issued by a certifying standard-setting body Gas manufacturer's intermediate GMIS Assayed and certified by direct comparison to one of the standard other NIST standards listed in this table according to section 2.1.2.1 of the Traceability Protocol EPA protocol gas Protocol Vendor-certified to be within 2.0 percent of the cylinder label concentration [See Traceability Protocol] Zero air material Zero Air Calibration gas certified by gas vendor: SO2,NO,,and Total Hydrocarbons s 0.1 ppm, CO s 1 ppm,or CO2 s 400 ppm. If a mixture, other components certified not to interfere with target compound. Research gas mixture RGM NIST analyzed and certified as "NIST traceable." 8. DAHS Part 75 Field Audit Manual—July 16,2003 Page A-7 CEMS Inspection Sheet Appendix A What'to Check Observations Make sure that the version used is previously DAHS certified per MDC information and certified/recertified by checking against the Monitoring monitoring plan. Plan. Ask to see and check the DAHS verification test for the DAHS verified for missing data procedure for missing data and calculation routines. Verification test Unit 1 on 7/15/07 at 11:00 with substituted data results for the missing data routines and emissions of NOX at 160.4 ppm. calculations are required to be kept on site by§§ 75.20(c)(9)and 75.63(a)(2)(iii). A vendor certification that the software meets Part 75 requirements is sufficient for missing data routines. Ask the source what type of correction factors are Correction factors are applied when needed and applied, and how they are entered into the DAHS as noted in QA/QC procedure. Real time data of (pressure/temperature compensation,flow and moisture boiler variables are attached in Appendix 1. monitoring polynomials,sonic velocity correction factors, NO,;quenching correction factors,dilution ratio settings). Also ask if any changes have been made. Changes to correction factors should be recorded in the maintenance log, and the QA/QC Plan should outline the procedures for changing the correction factors(Appendix B, Section 1.1.3). QA testing may also be required(See§75.20(b), and Recertification and Diagnostic Testing Policy). How are the RATA results recorded? RATA reference RATA results are recorded in the 600 records method data and RATA results can be input by hand. through MDC. The stack testing transfer results Review some recent tests to verify that hard copy and through computer disc or laptop. electronic data match. Check that the dates and time, linearity error,relative accuracy,and bias adjustment factors(BAF)match. (See the RATA review sheet for additional checks.) Is any other data input by hand? If so spot check to see No other known data is input by hand. that the DAHS data agree with hard copy data. The following types of data may be entered manually: -Negative(<0)emission values -Erroneous emission values(if significant must be approved by EPA) -SO2 concentration<2.0 ppm -Reference method back-up data -RATA reference method data and RATA results -Leak checks,7-day calibration error tests,and cycle time tests -Operating data(load and time) -Add-on control equipment operation during missing data periods[See item 8,below] Page A-8 Part 75 Field Audit Manual—July 16,2003 Appendix A CEMS Inspection Sheet 9. Optional Control Equipment Parameter Monitoring (§ 75.34) hat to Check Observation W s Check the QA/QC Plan which will identify add-on SOZ or NA NO,control equipment parameters and acceptable ranges if the source is using add-on control equipment missing data options. Parameters and acceptable ranges are required by App B,§ 1.1.1. Review control equipment parameter monitoring NA records for a number of missing data periods. Compare the parameter data to the acceptable ranges in the QA/QC Plan. Identify any periods when the range is exceeded and how the missing data period was flagged in the DAHS (control operating properly or not operating properly). Ask the source how it enters proper control equipment NA operation for missing data periods into the DAHS. Manual entry of missing data period information is allowed by Part 75. Part 75 Field Audit Manual—July 16,2003 Page A-9 CEMS Inspection Sheet Appendix A 10. Maintenance Log Review What to Check! Observation Do the log entries sufficiently describe the action taken? Log entry sufficiently described the action taken Are the entries understandable? and entry was understandable. Does the log show maintenance checks at the frequency The maintenance log represents the correct identified in the QA/QC Plan? Are all records available 'frequency and were available as per QA/QC (see Table C)? procedure. Identify recurring failures or malfunctions recorded in No recurring failures and malfunctions were the log. recorded outside of quarterly maintenance. A new flow monitor was installed. Are malfunctions resolved as specified in the QA/QC Malfunctions were resolved as per QA/QC plan. Plan? Do events in the maintenance log correspond to reported Maintenance log corresponds to the missing data missing data periods in the quarterly reports? periods. Are there repeated adjustments to the zero or span? No known repeated adjustments to the zero or span. Have system parts or components been replaced? If so has No known major replacements or components. the proper recertification or diagnostic testing been However new flow monitors were installed on performed? Units 1 and 2. Does the log show any pre-RATA adjustments? No known pre-RATA adjustments. Table C: Maintenance Record Requirements (Appendix B § 1.1.3) The following records are required by the QA/QC Plan provisions of Part 75: • date, time, and description of any testing, adjustment, repair, replacement,or preventive maintenance action performed on any monitoring system. • records of any corrective actions associated with a monitor's outage period. • any adjustment that changes a system's ability to record and report emissions data(e.g., changing of flow monitor or moisture monitoring system polynomial coefficients, K factors or mathematical algorithms, changing of temperature and pressure coefficients and dilution ratio settings). • a written explanation of the procedures used to make the adjustment(s)shall be kept. Page A-10 Part 75 Field Audit Manual—July 16,2003 Appendix A CEMS Inspection Sheet 11. QA/QC Plan Review What to Check Observation Is there a written QA/QC Plan (it may be stored QA/QC procedure documents were revised on electronically but should be available),and when was it 9/4/04. However, facility will revise for the new last updated? flow monitors. (Appendix B § 1) Are calibration error test and linearity test procedures Calibration error test and linearity test outlined in the plan? procedures were outlined in the QA/QC (Appendix B, § 1.2.1) procedure. Are calibration and linearity test adjustment Calibration and linearity test adjustment procedures outlined? (Appendix B,§ 1.2.2) procedures were outlined in the QA/QC procedure. Preventive maintenance procedures and recordkeeping Preventive maintenance procedures and record identified? keeping were outlined in the QA/QC procedure. (Appendix B, §§ 1.1.1 and 2) Are RATA test procedures provided? (Appendix B,§ RATA test procedures are provided in the 1.2.3) QA/QC procedure. Are emissions and QA test recordkeeping and reporting Record keeping and reporting procedures were procedures, including missing data procedures, outlined in the QA/QC procedures. addressed? (Appendix B, § 1.1.2) If using add-on control equipment missing data options, NA are control equipment parameters identified?(Appendix B,§ 1.1.1) Part 75 Field Audit Manual-July 16, 2003 Page A-1 I Daily Calibration Error Test Observation Sheet Appendix A Daily Calibration Error Test Observation If offline calibrations are done,was the offline-online test passed? _NA System/Component ID: Parameter Monitored: Span Value,S: CE Results Date/time Calibration Value,R CEM Response,A (ppm,%,SCFH or fpm) (ppm,%,SCFH or fpm) (%of span) R-A (ppm,%,SCFH or fpm) Zero level check ee a ace ai y calibration sheet. Upscale check System/Component ID: Parameter Monitored: Span Value,S: CE Results Date/time Calibration Value.R CEM Response,A (ppm,%,SCFH or fpm) (ppm,%,SCFH or fpm) (%of span) R-A (ppm,%,SCFH or fpm) Tern IPvel rherk I Incrale rherk System/Component ID: Parameter Monitored: Span Value,S: CE Results Date/time Calibration Value,R CEM Response,A (ppm,%,SCFH or fpm) (ppm,%,SCFH or fpm) (%of span) R-A (ppm,%,SCFH or fpm) 7Prn level rherk 1lnsrale.rherk System/Component ID Parameter Monitored: Span Value,S. CE Results Date/time Calibration Value,R CEM Response,A (ppm,%,SCFH or fpm) (ppm,%,SCFH or fpm) (%of span) R-A (ppm,%,SCFH or fpm) Tern Ievel rherk Ilncrale rherk For NOx and SO2: Al CE S=IR x 100 S For CO2 and 02: CE = IR — Al where: CE = Calibration Error(%of span) A = Actual CEMS Response R = Reference Gas Value S = CEMS Span Value Page A-]2 Part 75 Field Audit Manual—July 16,2003 APPENDIX 1 Part 75 CEMS Field Audit Information UNI 1 7 Pollutants . _.__ __ Zero — — _ _ -- Span ------- ---- Value Target Drift (%) Value Target Drift °fo e g CO2 (%) 0.130.00 0.1 10. 0 10.81 -0.21 0.2 0.0m 0.08 NOx (PPM) 231.4� Y20.0 3 0.34 Stack Pressure at Initial Cal: �30-37 r vnuat�� ........__: ... _,.. .v ......._ _...... . ......r -�-- Zero — - -T _. Span x �` t Value Tar et Drift / Value Tame q Drift % Interf. Flow (DP) 0.00o OAoo -0.04 0.699 0.700 -0.04 PASS s, VIIttLQl It,`!. _ _ ._. .W ._ __ N_ .. . .. .. -..: ...._. ._ .....:.� .__.: ., Zero --- Span... - � Value Target Drift %) Value Target' Drift Opacity (%°) 0.5 0.00 0.66 40.06 k 40,10 Copyright(C) 1993-200T VIM Technologies, Inc. _ _. _._------- MODE Mt UNIT1 .� Ce �II�IrfYt � � '� Fffi' �o���sf�oosl�:�0_�3 _,a ,...�... . .,...�.__..__ UINIIL Pollutants _ \ - - — Zero -- - --- — - - Span - � # � Value Target Drift % Value Target Drift \ h CO2 (a/O) 0.09 0.00 0.09 F 1.27 '10.81 0.46 Ox (PPNI) 0.0 0.0 0.00 2'I�'.3 �.. 230.0 .1f 0 0 Stack Pressure at Initial Cal: 29.75 r-uHULCIIIL .: � .. .. _.... Zero Span --- h �t k\ Value Tar et Drift % Value Tar et Drift % Interf. � i Flow (DP) -0.001 0.000 �- --0.95 0.700 0.?00 -0.96 ASS ...4;�;c..a�N✓�;�� c''.'v "'.;nn.,..w,�<��sa.X,Hx,^3�.xS : r IJIIUL4211L* Zero — — — Span Value. .Target Drift. /° Value Target Drift /° p tY ( °) O.iS 0.00 0.55 30.55 3'1.50 -0.95 a- �Y Copyright(C) 1993-2007.VIM Technologies, Inc. MODEM 02/26/2008 11=40.33 9� t� "5 UNIT 2 - Alarm 0� '� � � Cogentrix, SouthPort, NC Unit 1 Status Unit 2 Status Maintenances Normal Process Code Unit 1 8 Process Code Unit 2 8 CO2 Unit 1 NOx Raw Unit 1 CO2 Unit 2 NOx Raw Unit 2 3.04 % _ ��� 2.2 ppm 15 9 �� � 132.3 ppm 0 � NOx Ib/Mbtu Unit 1 _ NOx Ib/hr Unit 1_ NOx lb/Mbtu Unit 2 NOx Ib/hr Unit 2 0.263IbslMbtu 15 214.0Ibslhr 15 0.230Ibs/Mbtu I 172.8Ibslhr NOx 24 Hr Avg NOx 30 Day Avg NOx 24 Hr Avg NOx 30 Day Avg _ 0.368 61 6t6 0.405 I' MBtu 0.293 IbIMBtu 0.373 IbtMBtu Steam Flow 1 A Steam Flow 1 B Steam Flow 1 C Steam Flow 2A Steam Flow 2B Steam Flow 2C [--176.7 klbslhr 177.0 klbslhr 179.7 klbslhr 183.9 klbslhr 177.2 klbslhr 175.6 klbslhr Opacity Process Cody 8 Opacity Process Cade 8 Opacity Opacity.6 min Opacity Opacity 6 min 0.00 °fQ 1 i 12.41 °f8 5.16°fo 5.65 °l0 ..I Stack Flow Unit 1 Delta P' _ _Stack Flow Unit 2 Delta P 198.65 kscfm 0.886 inH24 182.43 kscfm 0.923 inH2O Stk Press Unit 1 Stk Temp U1 Stk Press Unit 2 Stk Temp U2 �--------------�=------�-� 1 inHg �W 301.37 i n H g _ 31.39 inHg 11 301.04 DegF > �,� y _. .�6.73._ Copyright(C) 1993 -2007. VIM Technologies, Inc. MODEM 008 114 i i NOx RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 60 RATA PLANT:Primary Energy-Soutliport DATE: 2/29/08 UNIT NAME: UNIT 1 SAMPLING LOCATION: CS001 MONITOR: NOx MONITOR SERIAL NO.: 42C-71812-369 COMPARISON: lb/inmBlu OPERATING LOAD,klb/lir: 533.0 1=used START START END END LOAD lb/mmStu 0-not used RUN DATE TIME DATE TIME Idb/hr RM CEMS DIFF 1 1 02/29/08 0735 02/29/08 0756 533.0 0.259 0.250 -0,009 1 2 02/29/08 0804 02/29/08 0825 533.0 0.268 0.260 -0.008 1 3 02/29/08 0832 02/29/08 0853 533.0 0.253 0.240 -0.013 1 4 02/29/08 0902 02/29/08 0923 533.0 0.260 0.250 -0,01 0 5 02/29/08 0932 02/29/08 0953 533.0 0,274 0.260 -0,014 1 6 02/29/08 1002 02/29/08 1023 533.0 0.265 0.250 -0.015 1 7 02/29/08 1033 02/29/08 1054 533.0 0,268 0.260 -0.008 1 8 02/29/08 1103 02/29/08 1124 533.0 0.251 0.240 -0.011 1 9 02/29/08 1132 02/29/08 1153 533.0 0,259 0.250 -0.009 1 10 02/29/08 1202 02/29/08 1223 533 0 0.260 0.250 -0,010 9 OF RUNS: 9 MEANS: 533.0 0.260 0.254 -0.010 T-VALUE: 2.306 STANDARD DEVIATION: 0.002 95%CONFIDENCE COEFFICIENT: 0.002 RELATIVE ACCURACY 20%of RM?): 4.7% if DRAFTf r t C i f 1 1'. southport-gas RATA-EDR.xls 1 f 5 NOx RELATIVE ACCURACY CALCULATION SUMMARY i TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy-Soutliport DATE: 2/29/08 UNIT NAME: UNIT I UNIT ID/COMMON STACK ID: CS001 MONITOR: NOx MONITORING SYSTEM ID: M10 COMPARISON: ppm wet TEST NUMBER: 1 OPERATING LEVEL: H AVERAGE GROSS LOAD,.klb/hT: 533.0 1=uscd . START START END END LOAD PRM wet D=not uso� RUN DATE TIME DATE TIME k1b1hr RM CEMS DI.FF 1 1 02/29/08 0735 02/29/08 0756 533.0 138.7 140,5 -1.8 1 2 02/29/08 0804 02/29/08 0825 533,0 146.8 148.0 -1.2 t) 3 02/29/08 0832 02/29/08 0853 533.0 136.4 138.7 -2.3 1 4 02/29/08 0902 02/29/08 0923 533.0 140.2 142.4 -2.2 1 5 02/29/08 0932 02/29/08 0953 533.0 148.4 150.3 -1.9 1 6 02/29/08 1002 02/29/08 1023 533.0 142.9 143.3 -0.4 1 7 02/29/08 1033 02/29/08 1054 533.0 144.4 145.2 -0.8 1 8 02/29/08 1103 02/29/08 1124 533.0 136.1 136.7 -0.6 1 9 02/29/08 1132 02/29/08 1153 533.0 140.2 141.1 -0.9 1 10 02/29/08 1202 02/29/08 1223 533.0 140.2 142.1 -1.9 #OF RUNS: 9 MEANS: 533.0 142.0 143.3 -1.300 T-VALUE: 2.306 STANDARD DE IATION: 0.661 BIAS TEST: PASSED 95%CONFIDENCE ICIENT: 0.508 f1 BIAS FACTOR: 1.000 RELATIVE A ({10%of RM7): 1.3% : r r- l t F c:. L f r southport-gas RATA-EDR.xls r 1 CO2 RELATIVE ACCURACY CALCULATION SUMMARY i TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy-Southport DATE: 2/29/08 UNIT NAME: UNIT 1 UNIT ID/COMMON STACK ID: CSOOI MONITOR: CO2 MONITORING SYSTEM ID: CIO COMPARISON: %wet TEST NUMBER: I OPERATING LEVEL: H AVERAGE GROSS LOAD,klblhr: 533.0 1=used START START END END LOAD %wet 0-not used RUN DATE TIME DATE TIME klh/hr RM CEMS DIFF 0 1 02/29/08 0735 02/29/08 0756 533.0 11,51 12.30 -0.8 1 2 02/29/08 0804 02/29/08 0825 533.0 11.77 12.30 -0.5 1 3 02/29/08 0832 02/29/08 0853 533.0 11.60 12.30 -0.7 1 4 02/29/08 0902 02/29/08 0923 533.0 11.60 12.30 -0.7 1 5 02/29/08 0932 02/29/08 0953 53 3.0 11.64 12.30 -0.7 1 6 02/29/08 1002 02/29/08 1023 533.0 11.61 12.10 -0.5 1 7 02/29/08 1033 02/29/08 1054 533.0 11,60 12.30 -0.7 i 8 02/29/08 1103 02/29/08 1124 533.0 11,67 12.30 -0.6 l 9 02/29/08 1132 02/29/08 1153 533.0 11.65 12.30 -0.7 t 10 02/29/08 1202 02/29/08 1223 533.0 11.59 12.1.0 -0.5 #OF RUNS: 9 MEANS: 533.0 11.64 12.26 -0,619 T-VALUE: 2.306 STAND DEVIATION: 0.086 BIAS TEST: NA 95%CONFIDE oEFFICIENT: 0.066 BIAS FACTOR: LOOO RELAT v%L CY(<10%of RM?), 5.9% i r F- r i:. j. E_ southport-gas RATA-EDR.xls i 3 i FLOW RATE RELATIVE ACCURACY CALCULATION SUMMARY i TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy-Southport DATE: 2/14/06 UNIT NAME: UNIT 1 UNIT ID/COMMON STACK ID: CS001 MONITOR: FLOW MONITORING SYSTEM ID: F10 COMPARISON-. SCFH,wet TEST NUMBER: 1 OPERATING LEVEL: H AVERAGE GROSS LOAD,klb/hr: 533.8 1-USED 0--NOT START START END END WAD SCFH,wet USED RUT DATE TIME DATE TIME klk4ir RAI CEMS DIFF 1 1 02/08/0 0732 02/08/07 0753 533.0 10,483,535 10,439,714 43,821 1 2 , ( /08/ 0838 02/08/07 0859 533.0 10,438,533 10,381,263 :i7,270 U 3 0 !0 07 0832 02l08/07 0853 533.0 10,577,047 10,300,857 276,190 1 4 0 0 /07 0902 02/08/07 0923 533.0 10,374,493 10,318,421 56,072 1 5 02 8/07 0932 02/08/07 0953 533.0 10,447,174 10,352,000 95,674 1 6 02 /07 1002 02/08/07 1023 533.0 10,427,354 10,340,526 86,828 1 7 0 /0 07 1033 02/08/07 1055 533.0 10,449,691 10,363,714 85,977 1 8 /08 7 1103 02/08/07 1124 533.0 10,461,813 10,296,632 165,181 1 9 2/08/ 7 1132 02/08/07 1153 537.0 105451,931 10,355,143 96,788 1 10 02/08/ 1202 02/08/07 1223 536.0 10,435,960 10,382,842 53,118 I #OF RUNS: 9 MEANS: 533.8 10,441,221 10,358,917 82,303 T-VALUE: 2.306 STANDARD—DEVIATION: 36,978 BIAS TEST: NOT PASSED 95%CONFID FFICIENT: 28,423 BIAS FACTOR: 1.008 RELATIV CY(<7.5%of RM?): 1.1% r. i t- 1_ F 4- I' k> I' k_ Ul-Ilow-lulll.xls FLOW RATE RELATIVE ACCURACY CALCULATION S-UMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy,Southport DATE: 12/0/07 UNIT NAME: Unit 1 UNIT ID/COMMON STACK ID: CS001 MONITOR: Flow MONITORING SYSTEM ID: FIO COMPARISON: SCFH Wet TEST NUNMER: I OPERATING LEVEL: M AVERAGE GROSS LOAD,klb/hr: 386.6 1=USED I><NOT START START END END LOAD SCFH Wet USED RUN DATE TIME DATE TIME k1b/hr RNI CENIS DIFF 0 1 2/28/08 1441 02/28/08 1451 386.0 8,081,629 8,446,200 -364,571 1 2 02/29/08 1451 02/28/08 150I 385.0 8,285,912 8,466,000 -180,088 0 3 02/28/08 2025 02/28/08 2035 390.0 8,087,729 8,386,800 -299,071 1 4 02/28/08 1524 02/28/08 1534 392.0 8,368,468 8,492,400 -123,932 1 5 02/28/08 1534 02/28/08 1544 389.0 8,267,809 8,387,400 -119.591 I 6 02/28/08 1544 02/28/08 1554 398.0 8,304,759 8,421,000 -116,241 1 7 02/28/08 1606 02/28/08 1616 395.0 8,420,421 8,630,000 -209,579 0 8 02/28/08 1616 02/28/08 1626 398.0 8,346,038 8,602,667 -256,629 1 9 02/28/08 1626 02/28/08 1636 380.0 8,338,901 8,434,200 -95,299 1 10 02/28/08 1653 02/28/08 1703 380.0 8,343,272 8,284,200 59,072 1 11 02/28/08 1703 02/28/08 1713 381 8,398,641 8,353,200 45,441 1 12 02/28/08 1713 02/28/08 1723 379 8,481,878 8,368,500 113,378 4 OF RUNS: 9 MEANS: 386.6 8,356,673 8,426,322 -69,649 T-VALUE: 2.306 STANDARD DEVIATION: 113,666 BIAS TEST: PASSED 95% CONFIDENCE COEFFICIENT: 87,372 BIAS FACTOR: 1.000 RELA Y(<7.5%,@f'RM?): 1.88% I t r r F E. t kF f. Ul flow-mid.xls FLOW RATE RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy, Southport DATE: 12/6/07 UNIT NAME: Unit 1 UNIT ID/COMMON STACK ID: CS001 MONITOR: Flow MONITORING SYSTEM ID: F10 COMPARISON: SCFH Wet TEST NUMBER: I OPERATING LEVEL: L AVERAGE GROSS LOAD,klb/hr: 99A 1=USED 0=NOT START START END END LOAD SCFH Wet USED RIJN DATE TIME DATE TIME Idb/lor RM CEMB DIFF 0 1 2/29/08 1328 02/29/08 1338 103.0 3,592,165 3,916,200 -324,035 0 2 02/29/08 1338 02/29/08 1348 106,0 3,322,432 3,818,400 -495,968 1 3 02/29/08 1348 02/29/08 1358 104.0 3,527,222 3,703,200 -175,978 1 4 02/29/08 1406 02/29/08 1416 102.0 3,408,807 3,611,333 -202,526 1 5 02/29/08 1416 02/29/08 1426 97.0 3,243,456 3,448,667 -205,211 0 6 02/29/08 1426 02/29/08 1436 96.0 3,083,485 3,358,200 -274,715 1 7 02/29/08 1450 02/29/08 1500 96.0 3,097,015 3,363,600 -266,585 1 8 02/29/08 1500 02/29/08 1510 100.0 3,238,547 3,343,200 -104,653 1 9 02/29/08 1510 02/29/08 1520 99,0 3,245,552 3,358,500 -112,948 1 10 02/29/08 1.532 02/29/08 1542 98.0 3,170,127 3,345,000 -174,873 1 11 02/29/08 1542 02/29/08 1552 99 3,198,145 3,304,200 -106,055 1 12 02/29/08 1552 02/29/08 1602 100 3,195,930 3,335,400 -139,470 #OF RUNS: 9 NEANS: 99A 3,258,311 3,423,678 -165,366 T-VALUE: 2,306 ,ST DEVIATION: 54,816 BIAS TEST: PASSED 95%CONF E OEFFICIENT: 42,136 BIAS FACTOR: 1.000 I2ELAT Tcy (<7.5%of RNL?): 6.37% t t V f. EEFFF 4: U1 flow-low.xls s NOx RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 60 RATA PLAIN: Primary Energy-Southport DATE: 2/28/08 UNIT NAME: UNIT 2 SAMPLING LOCATION: CS002 MONITOR: NOx MONITOR SERIAL NO.: 42C-71812-369 COMPARISON: lb/mmBtu OPERATING LOAD,klb/br: 530,8 i=used START START END END LOAD Ib/mointu _ D=not used RUN DATE TIME DATE TIME ld"r RM CEMS RIFF 1 1 02/28/08 0802 02/28/08 0823 531.0 0.281 0,260 -0.021 1 2 02/28/08 0832 02/28/08 0853 531.0 0.291 0.270 -0.021 1 3 02/28/08 0948 02/28/08 1009 531.0 0.291 0.270 -4.021 1 4 02/28/08 1028 02/28/08 1049 531.0 0.285 0.270 -0.015 1 5 02/28/08 1100 02/28/08 1121 531.0 0.275 0,260 -0,015 0 6 02/28/08 1130 02/28/08 1151 530.0 0.285 0.260 -0.025 t 7 02/28/08 1200 02/28/08 1221 530.0 0.269 0.250 -0.019 1 8 02/28/08 1229 •2/28/08 1250 530.0 0.262 0.240 -0.022 1 9 02/28/08 1308 02/29/08 1329 531.0 0.272 0.250 -0.022 1 10 02/28/08 1340 02/28/08 1401 531.0 0.273 0.250 -0,023 #OF RUNS: 9 MEANS: 530.8 0.278 0.258 -0,020 T-VALUE: 2.306 STANDARD DE ON: 0.003 95%CONFIDENCE O T: 0.002 RELATIVE ACCUR a 20%ofRM7): 8.0% F t f 4- E. f: j. soutliport-gas RATA-EDR.xls i NOx RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy-Southport DATE: 2/28/08 UNIT NAME: UNIT 2 UNIT ID/COMMON STACK ID: CS102 MONITOR: NOx MONITORING SYSTEM ID: M10 COMPARISON: ppm wet TEST NUMBER: I OPERATING LEVEL: H AVERAGE GROSS LOAD,klb/lir: 530.7 Ssused START START END END LOAD ppm wet 0-not used RUN DATE TIME DATE TIME ldb/hr RM CEMS D1FF 1 1 02/28/08 0802 02/28/08 0823 531.0 147.2 147.1 0.1 1 2 02/28/08 0832 02/28/08 0853 531.0 152.2 151.8 0.4 0 3 02/28/08 0948 02/28/08 1009 531.0 149.0 152.2 -3.2 1 4 02/28/08 1028 02/28/08 1049 531.0 146.0 149.0 -3 1 5 02/28/08 1100 02/28/08 1121 531.0 143.0 144.9 -1.9 1 6 02/28/08 1130 02/28/08 1151 530.0 1479 I46.0 1.9 1 7 02/28/08 1200 02/28/08 1221 530.0 138.7 140.6 -1.9 1 8 02/28/08 1229 02/28/08 1250 530,0 134.8 136.4 -1.6 1 9 02/28/08 1308 02/28/08 1329 531.0 142.5 142.5 0 1 10 02/28/08 1340 02/28/08 1401 531.0 142.1 142.7 -0.6 #OF RUNS: 9 MEANS: 530.7 143.8 144.6 -0.733 T-VALUE: 2.306 STAND TION: 1.503 BIAS TEST: PASSED 95%m CONFIDE C FFICIENT: 1.156 I BIAS FACTOR: 1,000 RELATIVE AC Y(<10%of Rhl?): 1.3% t k t k c kkt r. southport-gas RATA-EDR.xIs CO2 RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Enerp-Southport DATE: 2/28/08 UNIT NAINIE: UNIT 2 UNIT ID/COMMON STACK ID: CS002 MONITOR: CO2 MONITORING SYSTEM ID: C10 COMPARISON: %wet TEST NUMBER: 1 OPERATING LEVEL: H AVERAGE GROSS LOAD,klb/hr: 530.7 t=used START START END END LOAD %wet 0=not used RUN DATE TIME DATE TIME Idb/hr RM CEMS DIFF 1 1 02/28/08 0802 02/28/08 0823 531.0 11.26 12.10 -0.840 1 2 02/28/08 0832 02/28/08 0853 531.0 11.25 12.10 -0.850 1 3 02/28/08 0948 02/28/08 1009 531.0 11.02 12.10 -1.080 I 4 02/28/08 1028 02/28/08 1049 531.0 11,01 12.10 -1.090 1 5 02/28/08 1100 02/28/08 1121 531.0 11.19 12.20 -1.010 1 6 02/28/08 1130 02/28/08 1.1.51 530.0 11.16 12.10 -0.940 1 7 02/28/08 1200 02/28/08 1221 530.0 11.08 12.20 -1.120 0 8 02/28/08 1229 02/28/08 1250 530.0 11.07 12.20 -1.130 1 9 02/28/08 1308 02/28/08 1329 531.0 11.26 12.20 -0.940 1 10 02/28/08 1340 02/28/08 1401 531.0 1.1.21 12.20 -0.990 �#OF RUNS. 9 MEANS: 510,8 11.16 12.14 -0,984 T-VALUE: 2.306 STAND IATION: 0.101 BIAS TEST: NA 95%CONnf CENT: 0.078 ICBIAS FACTOR: 1.000 RELATIVE A EY(<ltl°lo of I2M?); 9.5% I i i t: 1: k:. southport-gas RATA-EDR.xls l I CO2 RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy-Southport DATE: 2/29/08 UNIT NAME: UNIT 2 UNIT ID/COMMON STACK ID: CS002 MONITOR: CO2 MONITORING SYSTEM ID: C20 COMPARISON: %wet TEST NUMBER: I OPERATING LEVEL: H AVERAGE GROSS LOAD,k1b/hr: 536.2 1=used START START END - END LOAD %wet 9=not used RUN DATE TIME DATE TIME k1b/iir RM CEMS RIFF 1 1 02/29/08 0735 02/29/08 0756 537.0 .11.26 11.90 -0,640 1 2 02/29/08 0804 02/29/08 0825 537.0 11.25 11.90 -0.650 1 3 02/29/08 0932 02/29/08 0853 538.0 11.08 11,80 -0.720 0 4 02/29/08 0902 02/29/08 0923 537.0 11.13 11.90 -0.770 1 5 02/29/08 0932 02/29/08 0953 536.0 11.1E 1I90 -1,720 1 6 02/29/08 1002 02/29/08 1023 536.0 11.31 12.00 -0.690 1. 7 02/29/08 1033 02/29/08 1054 535.0 1 IA 1 12.10 -0.690 1 8 02/29/08 1103 02/29/08 .1124 534.0 11.36 12.00 -0.640 9 02/29/08 1132 02/29/08 1153 536.0 11.33 11.90 -0.570 10 02/29/08 1202 02/29/08 1223 536.0 1.1.31 12.00 4690 #Or RUNS: 9 MEANS: 536.1 11.28 11.94 -0.668 T-VALUE: 2.306 STANDARD DEVIATION: 0.048 BIAS TEST: 'NA 95%CONFIDENCE COEFFICIENT: 0.037 BIAS FACTOR: 1.000 RELATIVE ACCURACY(<1.00 of RM?): 6.2% I i 1 I F 1, E: 6 h is k= E southport-gas RATA-EDR.xls Er FLOW RATE RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Prii]]aly Energy-Southport DATE: 2/28/08 UNIT NAME: UNIT 2 UNIT ID/COMMON STACK ID: CS002 MONITOR: FLOW MONITORING SYSTEM ID: F20 COMPARISON: SCFH,wet TEST NUMBER: 1 OPERATING LEVEL: H AVERAGE GROSS LOAD,k1b/hr: 530,7 ]—USED O=NOT START START END END LOAD SCFH,wet USED RUN DATE TIME DATE TIME klh/hr RM CEMS DIFF 1 1X27,7 0802 02/08/07 0823 531.0 11,334,923 10,998,857 336,066 1 2 0832 02/08/07 0853 531.0 11,671,351 11,141,714 529.637 1 3 7 0948 02/08/07 1009 531.0 11,605,734 11,042,571 563,163 1 4 7 1028 02/08/07 1049 531.0 11,368,540 11,150,211 218,329 1 5 7 1100 02/08/07 1121 531.0 11,362,723 11,043,429 319,294 1 6 7 1130 02/08/07 1151 530.0 11,303,649 11,033,400 270,249 1 7 7 1200 02/08/07 1221 530.0 11,268,083 11,015,429 252,654 1 87 1229 02/08/07 1250 530.0 11,405,902 11,019,158 386,744 0 9 1308 02/08/07 1329 531.0 11,591,314 11,004,571 586,743 1 10 1340 02/08/07 1401 531.0 11,521,883 11,012,857 509,026 #OFRL'NS: 9 MIEANS: 530.7 11,426,976 11,050,847 376,129 T-VALUE: 2.306 STANDAItDDEV2ATIiN: I28,702 BIAS TEST: NOT PASSED 95%CONFIDENCE CQJWFICIENT: 98,929 .00 BIAS FACTOR 1.034 RELATIVE ACC 5%of RM?): 4.2% { rE 6 F i f: E t E' U2-flow-high.xls r.: F: 0 i I 1 FLOW RATE RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy,Southport DATE: 12/6/07 UNIT NAME-. unit 2 UNIT ID/COMMON STACK ID: CS002 MONITOR: Flow MONITORING SYSTEM ID: F20 COMPARISON: SCFH Wet TEST NUMBER: 1 OPERATING LEVEL: M AVERAGE GROSS LOAD,klb/hr: 390.6 1—USED 0=NOT START START END END LOAD SCI+H Wet USED RUN DATE TIAIE DATE TIME k1h/hr RM GEMS DIFF 1 1 2/28/08 1441 02/28/08 1451 395.0 9,588,429 9,179,400 409,029 1 2 02/28/08 1451 02/28/08 1501 398.0 9,668,492 8,967,600 700,892 1 3 02/28/08 1501 02/28/08 1511 396.0 9,564,394 9,399,600 164,794 0 4 02/28/08 1524 02/28108 1534 385.0 8,633,550 9,782,250 -1,148,700 0 5 02/28/08 1534 02/28/08 1544 391.0 8,665,954 9,921,600 -1,255,646 0 6 02/28/08 1544 02/28/08 1554 391.0 8,198,593 10,219,800 -2,021,207 1 7 02/28/08 1606 02/28/08 1616 381.0 9,379,501 10,038,000 -658,499 I 8 02/28/08 1616 02/28/08 1626 382.0 9,322,299 9,762,000 -439,701 1 9 02/28/08 1626 02/28/08 1636 389.0 9,271,592 9,391,500 -119,908 1 10 02/28/08 1.653 02/28/08 1703 392.0 9,729,196 9,328,200 400,996 1 11 02/28/08 1703 02/28/08 1713 389 9,719,951 9,412,800 307,151 1 12 02/28/08 1713 02/28/08 1723 393 9,740,513 9,500,400 240,113 #OF RUNS: 9 MEANS: 390.6 9,553,819 9,442,167 111,652 T-VALUE: 2.306 STANDARD DEVIATION: 436,985 j BIAS TEST: PASSED 95%CONFIDENCE COEFFICIENT: 335,896 BIAS FACTOR: 1.000 RELATIVE A'*j4Fr 7 %of RM?): 4.68% f i, G r. U2 flaw-mid.xls `I i FLOW RATE RELATIVE ACCURACY CALCULATION SUMMARY TYPE OF TEST: 40 CFR 75 RATA PLANT: Primary Energy, Southport DATE: 12/6/07 UNIT NAME: Unit 2 UNIT ID/COMMON STACK ID: CS002 MONITOR: Flow MONITORING SYSTEM ID: F20 COMPARISON: SCFH Wet TEST NUMBER: 1 OPERATING LEVEL; L AVERAGE GROSS LOAD,k1b/hr: 111.6 1—USED O—NOT START START END END LOAD SC1F H Wet USED RUN DATE TIME DATE TIME klb/hr RM CEMS DIFF 1 1 2/29/08 1328 02/29/08 1338 108 3,087,722 3,352,500 -2647778 I 2 02/29/08 1338 02/29/08 1348 109 3,178,228 3,315,600 -137,372 1 3 02/29/08 1348 02/29/08 1358 111 3,247,383 3,348,600 -101,217 1 4 02/29/08 1406 02/29/08 1416 110 3,166,257 3,314,400 -148,143 1 5 02/29/08 1416 02/29/08 1426 108 3,205,003 3,325,200 -120,197 1 6 02/29l08 1426 02/29/08 1436 112 3,210,138 3,284,250 -74,112 1 7 02/29/08 1450 02/29/08 1500 115 3,161,037 3,334,200 -173,163 I 8 02/29/08 1500 02/29/08 1510 116 3,144,359 3,308,400 -164,041 0 9 02/29/08 1510 02/29/08 1520 116 3,086,389 3,448,200 -361,811 1 10 02/29/08 1532 02/29/08 1542 115 3,138,967 3,446,400 -307,433 0 11 02/29/08 1542 02/29/08 1552 116 3,104,622 3,440,400 -335,778 0 12 02/29/08 1552 02/29/08 1602 109 3,094,100 3,504,000 -409,900 #OF RUNS: 9 MEANS. 111.6 3,171,010 3,336,617 -165,606 T-VALUE: 2.306 STANDARD DEVIATION: 75.574 BIAS TEST: PASSED 95%C ENCE COEFFICIENT: 58,091 BIAS FACTOR: 1.000 RELATIVE ACC {7.5%ofRM?): 7.05% i i f 4 it F t F k E U2 flow-iow.xis t: