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HomeMy WebLinkAboutIMP Update Letter - Signed - March 2019 - with Tables� DUKE 4i0S.Wilmington Street. Raleigh, NC 27601 ENERGY® Mailing Address Mail Code NC 15 Raleigh, NC27601 919-546-7863 March 20, 2019 North Carolina Department of Environmental Quality Attn: Mr. Jon Risgaard Chief, Animal Feeding Operations and Groundwater Section 1636 Mail Service Center Raleigh, NC 27699 - 1636 Re: Optimized Interim Monitoring Plans (IMP) for 14 Duke Energy Facilities — Modification Request Annual Reports — Modification Request Dear Mr. Risgaard, On December 21, 2018, Duke Energy (Duke) received the North Carolina Department of Environmental Quality (DEQ) approval via email for the Optimized Interim Monitoring Plans (IMP) for the following 14 facilities: • Allen Steam Station (Allen); • Asheville Steam Electric Plant (Asheville); • Belews Creek Steam Station (Belews Creek); • Buck Combined Cycle Station (Buck); • Cape Fear Steam Electric Plant (Cape Fear); • James E. Rogers Energy Complex (Cliffside); • Dan River Combined Cycle Station (Dan River); • HF Lee Energy Complex (HF Lee); • Marshall Steam Station (Marshall); • Mayo Steam Electric Plant (Mayo); • Riverbend Steam Station (Riverbend); • Roxboro Steam Electric Plant (Roxboro); • L.V. Sutton Energy Complex (Sutton); and • W.H. Weatherspoon Power Plant (Weatherspoon). Duke would like to provide clarification and request respective concurrence on a few items related to the December 21, 2018 approved IMP. Item 1: Duke understands that DEQ expects newly installed monitoring wells to be sampled for the minimum suite of Coal Ash Management Act (CAMA) parameters (as listed in the former Fourth Quarter 2018 IMP), and on a quarterly basis for a minimum of four events. Duke believes this expectation may not have been clearly noted in the proposed and subsequently approved December 2018 Optimized IMP. Duke would like to clarify via this letter that newly installed monitoring wells for investigation of potential primary and secondary source assessments or DEQ required data gaps under the CAMA program will be sampled for the former Fourth Quarter 2018 minimum suite of CAMA parameters, as March 20, 2019 Risgaard Letter well as some voluntary parameters (for geochemical modeling purposes). Such new wells will be sampled on a quarterly basis for at least four events. To address, attached Table 1 lists the parameters to be included for such new wells. The attached Tables 2.1 through 2.14 include modified versions of the IMP Optimization summaries of wells, frequency and constituents for each of the 14 Duke facilities, respectively. Item 2: Specifically, after receiving DEQ's approval of the Optimized IMP for the respective 14 facilities, Duke noticed that four sites (Allen, HF Lee, Riverbend and Weatherspoon) had mistakenly listed Comprehensive Water Level Sweeps for quarterly rather than semi-annually. The attached Tables 2.1, 2.8, 2.11 and 2.14 now list comprehensive water level sweeps on a semi-annual basis, consistent with the other 10 facilities. Another change on Tables 2.1 through 2.14 is previously discontinued parameters, total aluminum and dissolved metals, have been re -added to select sites voluntarily to support geochemical modeling. Specifically, dissolved metals may be analyzed for at select well locations (yet to be determined) at some sites during dewatering of the ash basins to help determine if the dewatering process affects the total to dissolved ratio of some metals. Other voluntary parameters have also been added in support of geochemical modeling, but unlike total aluminum and dissolved metals, they were not specifically listed previously as discontinued parameters. Item 3: Duke would like to take this opportunity to propose a revised CAMA quarterly data submittal schedule to better correspond to our 2019 plans for sampling. The current CAMA quarterly data submittal schedule was approved by DEQ via email on June 6, 2018. A revised schedule has been attached as Table 3. Item 4: Another condition of the June 6, 2018 CAMA quarterly data submittal approval issued by DEQ was for each of Duke's Subject Matter Expert to provide updates to the Division of Water Resources (DWR) Regional Office individually on a monthly basis to discuss work done in the previous month and any upcoming work scheduled or proposed for the following month. Duke requests concurrence to provide monthly updates to DWR Regional Offices by the end of each month, rather than mid -month, as is the current practice for some of the sites. This will also allow for monthly updates to be completed with data submittals. Upon approval of the items discussed above, this information and respective attachments will replace the December 21, 2018 versions of the Optimized IMPS for the 14 sites, and will supersede the June 6, 2018 CAMA quarterly data submittal approval. Item 5: Also within the DEQ letter dated December 21, 2018 is a requirement for annual monitoring reports due by April 30. Duke has been in discussions with DEQ staff over the past few weeks and understands DEQ is open to a modification in schedule. As such, Duke proposes the following schedule for 2019 submittal of 2 March 20, 2019 Risgaard Letter annual reports along with annual effectiveness monitoring reports for three sites that have implemented accelerated remediation: • Annual Monitoring Reports Due April 30, 2019 — Allen, Belews Creek, Cliffside, Marshall, Mayo and Roxboro facilities (no change proposed); • Annual Monitoring Reports Due July 31, 2019 — Asheville, Buck, Cape Fear, Dan River, HF Lee, Riverbend, Sutton and Weatherspoon facilities; 0 Annual Effectiveness Monitoring Report Due May 15, 2019 — Sutton (no change proposed); • Annual Effectiveness Monitoring Reports Due July 31, 2019 — Asheville and Belews Creek. The accelerated remediation system at Asheville went into service in March 2018. The system was shut off as requested by DEQ for pump tests completed at the site. The pump tests were completed from May to July 2018. Once the system was to be re -activated, Duke learned the system was struck by lightning sometime during the period of the pump tests. Multiple parts with long -lead times were ordered and the system finally returned to service in February 2019. As the system has not operated much of 2018, an extension to the effectiveness report will allow additional data to be collected and included. For Belews Creek, an extended timeframe for evaluation of the accelerated remediation system will assist in determining the effects of ash basin decanting/dewatering. Operational lowering of the ash basin is underway. Decanting, followed by dewatering, is anticipated to begin in late March/early April 2019 and expected to continue through September 2020. The fate and transport model predicts that decanting will significantly change groundwater conditions in the area of the remediation system. The model predicts that groundwater levels will decrease and that the flow direction may change, strengthening a groundwater divide along Middleton Loop Road. These changes could significantly affect the performance and utility of the remediation system. Extending the submittal of the Belews Creek Effectiveness Monitoring report to the end of July 2019 will provide several months of extraction system data collected during ash basin decanting progress and be very valuable in assessing the extraction system's performance in regards to significant changing site conditions. If you have any questions or need any clarification regarding the information provided, feel free to contact me at lohn.toepfer@duke-energy.com or at 919-546-7863 at your convenience. Respectfully submitted, AohnToepfer, PPE Lead Engineer, Duke Energy EHS CCP Waste & Groundwater Programs March 20, 2019 Risgaard Letter cc (via e-mail): Steve Lanter - NCDEQ CRO Eric Smith - NCDEQ CRO Brandy Costner— Mooresville Regional Office Shuying Wang —Winston-Salem Regional Office Ted Campbell —Asheville Regional Office Eric Rice — Raleigh Regional Office Will Hart —Washington Regional Office Geoff Kegley — Wilmington Regional Office Kent White — Fayetteville Regional Office Ed Sullivan - Duke Energy Bryan Moeller— Duke Energy Kathy Webb — SynTerra Corp. Attachments: Table 1— Summary of Analytical Parameters for Newly Installed Wells Table 2.1- Summary of Wells, Frequency, & Parameters —Allen Table 2.2 - Summary of Wells, Frequency, & Parameters —Asheville Table 2.3 - Summary of Wells, Frequency, & Parameters — Belews Creek Table 2.4 - Summary of Wells, Frequency, & Parameters — Buck Table 2.5 - Summary of Wells, Frequency, & Parameters — Cape Fear Table 2.6 - Summary of Wells, Frequency, & Parameters — Cliffside Table 2.7 - Summary of Wells, Frequency, & Parameters — Dan River Table 2.8 - Summary of Wells, Frequency, & Parameters — HF Lee Table 2.9 - Summary of Wells, Frequency, & Parameters — Marshall Table 2.10 - Summary of Wells, Frequency, & Parameters — Mayo Table 2.11 - Summary of Wells, Frequency, & Parameters — Riverbend Table 2.12 - Summary of Wells, Frequency, & Parameters — Roxboro Table 2.13 - Summary of Wells, Frequency, & Parameters — Sutton Table 2.14 - Summary of Wells, Frequency, & Parameters — Weatherspoon Table 3 - Proposed Sampling Schedules & Respective CAMA Data Submittals 4 TABLE 1 IMP Optimization Summary of Analytical Parameters for Newly Installed Wells (to begin Q1 2019) For each of Duke Energy's 14 North Carolina facilities, new wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily. After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. A summary of analytical parameters to include under this criteria is provided below. SUMMARY OF ANALYTICAL PARAMETERS FOR NEWLY INSTALLED WELLS Minimum CAMA Parameters per Q4 2018 IMP (Metals are Totals) Additional Voluntary Parameters [Dissolved (0.45 micron filter)] Aluminum Mercury Molybdenum Aluminum Antimony Mercury Molybdenum Nickel Alkalinity (CO3/HCO3) Antimony Nickel Arsenic Arsenic Potassium Barium Phosphorus Barium Radium (226 + 228) Beryllium Potassium Beryllium Selenium Boron Selenium Boron Sodium Cadmium Silver Cadmium Strontium Calcium Sodium Calcium Sulfate Chromium Strontium Chloride Sulfide Cobalt Thallium Chromium Total Dissolved Solids (TDS) Copper Vanadium Cobalt Thallium Iron Zinc Copper Total Organic Carbon (TOC) Lead Hexavalent Chromium Uranium (233+234+236+238) Lithium Iron Lead Total Suspended Solids (TSS) Magnesium IManganese Vanadium Magnesium Zinc Additional Voluntary Parameters (Totals) Manganese Fluoride Lithium Nitrate + Nitrite Phosphorus Methane* Additional Field Water Quality Parameters A� = A Dissolved Oxygen (DO) Oxidation -Reduction Potential (ORP) Redox Potential (Eh) Turbidity Temperature Specific Conductance pH * W.H. Weatherspoon Power Plant only Table 2.1- Allen Wells for Quarterly Monitoring (33) AB-21SS* AB-25SS* AB-29SS* AB-32D AB-33D AB-33SS* AB-34S AB-35PWS* AB-38SS* AB-10BR*/ BRL* GWA-3BRL* GWA-4BRL* GWA-5BRL* GWA-6BRL* CP-1S*/D* CP-2S*/D* CP-3S*/D* CP-4S*/D* CP-5S*/D* CP-6S*/D*/BR* BG-1BR* CCR-26S* / D* / BR* CCR-16BR* Allen Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually - March 2019 Wells for Semi -Annual Monitoringt (103) -A i AB-04S / D / BR GWA-05S / D / BRA AB-06R GWA-06S / DA / BRA AB-09S / D GWA-07S / D AB-10S / D GWA-08S AB-13S / D GWA-09S / D / BR AB-14D / BR GWA-14S / DA AB-20S / D GWA-15S / D AB-21S / SL / D** / BRL GWA-19S / D** AB-22S / D / BR / BRL GWA-22S / D AB-24S / SL / D** / BR GWA-23S / D** AB-25S / SL / BRU** / BR** GWA-24SA / D / BR AB-26S / D AB-12S / D AB-30S BG-01S / DA AB-32S BG-2S / D / 2BRA2 AB-33S BG-3S / D AB-34D BG-4S / D / BR AB-35S / D** / BR GWA-16S / D AB-36S / D GWA-21S / DA / BR AB-37S / D GWA-26S / D AB-38S / D / BR Comprehensive Water Level Sweeps (includes wells in Semi- Annual, Quarterly, and Discontinued Monitoring Lists) AB-39S / D GWA-01S / D / BR GWA-02S / D GWA-03S / D / BRA GWA-04S / D / BR Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" Additional Water Quality 2018 CSA Update COIs (Total & Dissolved Where Applicable) Parameters (Total & Dissolved Where Applicable) Antimony --------------------------------- Lithium --------------------------------- Aluminum ----------------------------------------- Arsenic --------------------------------- Manganese --------------------------------- Alkalinity (CO3/HCO3) ----------------------------------------- Beryllium Molybdenum Calcium --------------------------------- Boron --------------------------------- Nickel ----------------------------------------- Chloride --------------------------------- Cadmium --------------------------------- --------------------------------- Selenium --------------------------------- ----------------------------------------- Dissolved Oxygen (DO) ----------------------------------------- Chromium (total) Strontium Redox Potential (Eh) --------------------------------- Chromium (hexavalent) --------------------------------- ----- ------------------------------------------------------------ Sulfate ------------- -------------------- --------- Magnesium ----------------------------------------- Cobalt Thallium Nitrate + Nitrite --------------------------------- Iron --------------------------------- Total Dissolved Solids (TDS) ----------------------------------------- Oxidation -Reduction Potential (ORP) Vanadium pH --------------------------------- _________ Potassium Specific Conductance --------------------------------- Sodium Total Organic Carbon (TOC) ------------------------------- Temperature ------------------------------- Turbiditv MP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act CDEQ = North Carolina Department of Envrionmental Quality Discontinue Sampling Wells/Water Level Only (23) A B-01 R AB-02/D AB-05 AB-06A AB-11D AB-23S / BRU** AB-27S /D / BR AB-28S / D AB-29S / SL / D AB-30D AB-31S GWA-08D GWA-17S / D GWA-18S / D To Be Replaced No well replacements planned at this time To be Abandoned GWA-6D i-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for ctive events. New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Zuarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will ie re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for he well in which they replace; however, additional parameters may be included voluntarily. ** Denotes well was previously approved by DEQ to be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Respective well is proposed to remain a boron -and -sulfate -only sample location; however, if the pH improves with redevelopment to fall <_ 8.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. "optimized non -new well" or "new well" lists as proposed herein. Table 2.2 - ASHEVILLE Asheville Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive water sweep to occur semi-annually. Modification - March 2019 Wells for Quarterly Monitoring (51) AS-513R (pH) MW-15BRL+ C13-6 MW-16A+ C13-7 M W-16D+ CB-8+ MW-16BR+ CB-8BR+ MW-16BRL+ CCR-100SL+ MW-16BRLL+ CCR-100BR+ MW-17A+ CCR-100BRL+ MW-17BRL+ CCR-101BR+ MW-18D CCR-102S+ MW-18BR+ CCR-102D+ MW-18BRL+ CCR-103D MW-20A CCR-103BR MW-20BR+ EXT-01+ MW-20BRL+ EXT-02 MW-26S EXT-A M W-26BR+ GW-2+ PZ-17BRL+ MW-5D CPA-1D* MW-51311 CPA-1BR* MW-8S+ CPA-2D* MW-9S+ CPA-2BR* M W-9 D+ CPA-4D* MW-9BR+ CPA-4BR* MW-15A+ CPA-3D* MW-15D+ CPA-3BR* Wells for Semi -Annual Monitoringt (35) AMW-03B+ MW-13D C13-1+ MW-13BR CB-1D+ M W-24S+ CB-3 R+ M W-25S C13-4+ MW-25BR C13-413+ MW-25BRL CB-5 P-103 CB-9 PZ-17S+ CB-9SL PZ-17D+ CB-91311 PZ-19 CCR-104D+ CCR-105BR CCR-105D+ GW-1+ GW-1D GW-1BR GW-3+ G W-4+ MW-3D+ MW-6S+ MW-6D+ Comprehensive Water Level Sweeps (includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) MW-6BR+ MW-10+ MW-11 MW-11D Optimized Quarterly & Semi -Annual Parameters for "Non -New" Wells (Total & Dissolved Where Applicable) Antimony -------------------------------------- Manganese -------------------------------------------- Alkalinity (CO3/HCO3) ----------------------------------------- Arsenic Selenium Calcium Beryllium -------------------------------------- Strontium --------------------------------------------•----------------------------------------- Dissolved Oxygen (DO) Boron Sulfate Redox Potential (Eh) Cadmium Total Radium (226 + 228)+ Magnesium Chloride Total Dissolved Solids (TDS) Potassium Chromium (total) Total Uranium (233+234+236+238)+ Sodium Chromium (hexavalent) Vanadium Nitrate + Nitrite Cobalt Lithium Iron Molybdenum Nickel ----------------------------------------- Oxidation-Reduction Potential (ORP) •----------------------------------------- pH •----------------------------------------- Specific Conductance •----------------------------------------- Thallium •----------------------------------------- Total Organic Carbon (TOC) •----------------------------------------- Temperature •------------------------------------- Turbidity-- Discontinue Sampling Wells/Water Level Only (21) MW-14BR MW-23DU MW-23DL MW-23BR AMW-1B ABMW-11BR AMW-2A AMW-2B APZ-30 B-1 B-1-A B-2 CB-1BR CB-I-BRL CB-2 CB-8D GW-5 MW-7BR MW-15BR MW-19BR P-102 EXT-D MW-8BR MW-26BRL+ AS-5BRL To Be Replaced No well replacements planned at this time Abandoned(3) MW-21D MW-22D MW-22BR Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Envrionmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. + Indicates the well to be sampled and analyzed for total radium (226 +228) and total uranium (233+234+236+238). *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. Wells for Quarterly Monitoring (31) AB-04 Lower Ash/SAP CCR-2S/D CCR-13S*/D*/BR* EXO B-01 EXOB-02 GWA-01S GWA-10S(+) GWA-11S/D GWA-18SA GWA-19SA/D GWA-20SA/D(+) GWA-21S/D GWA-27S/D(+) LRB-01S/D/BR LRB-02S/D/BR MW-104BRA(+) MW-200BR M W-04 Table 2.3 - Belews Creek Belews Creek Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive water level sweep to occur semi-annually tion - March 2019 Wells for Semi -Annual Monitoringt (56) AB-1BR GWA-26S/D/BR AB-2S/D GWA-27BR AB-31) GWA-30S/D AB-4S/D/BR/BRD** GWA-31S/D AB-6SL GWA-32S/D AB-7S GWA-3S (att) BG-01S(att)/D GWA-6S BG-02S/D/BRA GWA-7SA BG-03S/D GWA-8S/D GWA-10DA GWA-9BR GWA-16S/DA/BR* * M W-03 GWA-17S MW-20OS/D GWA-18D MW-202S(+)/D(+)/BR(+) GWA-19BR MW-204D GWA-01D/BR** Comprehensive Water Level Sweeps (includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) GWA-20BR GWA-22S/D GWA-24S/D/BR (att) GWA-25BR Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" 2017 CSA Update COls Additional Water Quality Parameters (Total & Dissolved Where Total & Dissolved Where Applicable) Applicable) Antimony --------------------------------- Iron ----------------------------------------- Aluminum ---------------------------------------------------------------------------------- Arsenic Manganese Alkalinity (CO3/HCO3) --------------------------------- ------------Barium------------ ----------------------------------------- - -----------Molybdenum------------ ---------------------------------------------------------------------------------- ------------------------------------Calcium------------------------------------ Beryllium Selenium Dissolved Oxygen (DO) Boron Strontium Lithium --------------------------------- Cadmium ----------------------------------------- Sulfate ---------------------------------------------------------------------------------- Redox Potential (Eh) --------------------------------- ----------------------------------------- Total Dissolved Solids (TDS) ----------------------------- ----------------------- Magnesium ------------ Chromium (total) Thallium Nitrate + Nitrite Chromium (hexavalent) Vanadium Oxidation -Reduction Potential (ORP) Cobalt - pH ---------------------------------------------------------------------------------- Potassium ---------------------------------------------------------------------------------- Radium (total) (+) ---------------------------------------------------------------------------------- Specific Conductance ---------------------------------------------------------------------------------- Sodium ---------------------------------------------------------------------------------- Total Organic Carbon (TOC) ---------------------------------------------------------------------------------- Temperature ---------------------------------------------------------------------------------- Turbidity ------------------------------ ----------------------------- Uranium (total) (+) Discontinue Sampling Wells/Water Level Only (39) AB-1S/D AB-3S AB-4SL (pH) AB-5S/SL/D AB-6S/D AB-7D AB-8S/SL/D AB-9S/D/BR/BRD** GWA-12S/D/BR (SF) GWA-17D GWA-23S/D (SF) GWA-2S/D GWA-3D GWA-6D GWA-7D GWA-9S/D MW-104S/D/BR** MW-201D/BR M W-203S/D/BR M W-204S To Be Replaced No well replacements planned at this time To be Abandoned No wells are scheduled to be abandoned at this time. Notes: owilill IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Envrionmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two of the Quarterly monitoring events and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. ** Denotes well was previously approved by DEQ to be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Respective well is proposed to remain a boron -and - sulfate -only sample location; however, if the pH improves with redevelopment to fall 158.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. `optimized non -new well' or "new well' lists as proposed herein. (+) -Select wells to be sampled for total radium (226 and 228) and total uranium (233, 234, 236, and 238). Wells GWA-10S, GWA-20D, GWA-27D and MW-104BR had at least one or more concentration(s) of total radium (only) reported greater than the Federal MCL, including the latest sample event. MW-104BR was replaced with monitoring well MW-104BRA, due to high pH. Wells GWA-10S, GWA-20D, GWA-27D and MW-104BRA are to be monitored for total radium and total uranium; if results are less than the Federal MCL, revaluation may indicate of historical exceedances are anomalous and a revision to the routine monitoring plan will be considered. Background well cluster MW-202S/D/BR will also be included in semiannual sampling of total radium and total uranium for ongoing comparative purposes. (SF) - GWA-12S/D/BR and GWA-23S/D will be included as part of the Structural Fill assessment monitoring (att) - well is typically dry but will not be replaced; attempt to sample (BG-1S, GWA-3S, GWA-24S) Table 2.4 - Buck LWellsor Quarterly itoring (32) AB-01Dx AB-02Sx / SLx / Dx / BR AB-3Sx / Dx AB-04S / BRL AB-05S AB-09BRA AB-10Sx / Dx / BRx / BRLx AS-01Sx / Dx AS-02Dx AS-03Sx / Dx BG-01 DA GWA-015 GWA-09S / D / BRA GWA-10S / D GWA-14D GWA-15BR MW-01D M W-08B RA MW-11BRL Buck Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually tion - March 2019 Wells for Semi -Annual Monitoringt (74) AB-04S L M W-06 B R AB-05SL MW-07S / D AB-06BRU MW-08S / D AB-07S / BRU MW-09S / D AB-8S / BRU MW-11S / D / BR AB-09S / BRUA MW-12S / D BG-01S / BRA MW-13D BG-02S / D GWA-14S / D BG-03S / BRU GWA-15S / D GWA-01D GWA-16S / D / BR GWA-02S / BRA / BRU MW-08S / D GWA-11S / D GWA-7S / D GWA-12S / BRU GWA-8D GWA-13SR / D GWA-9S / D GWA-14S GWA-18S GWA-15S / D GWA-20S GWA-16S / D/ BR Comprehensive Water Level Sweeps (includes wells in Semi - Annual, Quarterly, and Discontinued Monitoring Lists) GWA-17S GWA-18S / DA GWA-19S / D GWA-20S / D GWD MW-03S 3S / D M W-04S / D MW-5S / D Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total & Dissolved Where Applicable) Antimony Iron Aluminum Arsenic Manganese Alkalinity (CO3/HCO3) Calcium Barium Nickle Boron Selenium Chloride Chromium (total) Sulfate Dissolved Oxygen (DO) Chromium (hexavalent) Thallium Lithium Cobalt Total Dissolved Solids (TDS) Magnesium Vanadium Nitrate + Nitrite Oxidation -Reduction Potential (ORP) pH Phosphorus Potassium Redox Potential (Eh) Sodium Specific Conductance Strontium Temperature Turbidity IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Envrionmental Quality Discontinue Sampling Wells/Water Level Only (7) AB-04BRU AB-05BRU GWA-06S GWA-14BR MW-01S MW-06D M W-06S To Be Replaced AB-04BRL, BG-01DA, GWA- 09BRA,GWA-09D, GWA-09S, GWA-14D To be Abandoned None planned at this time, except for wells to be replaced mi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective nts. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. Well located in basin; will be sampled quarterly until closed for excavation. Wells for Quarterly Monitoring (3) M W-25BR* MW-25BRL* MW-25BRLL* Table 2.5 - Cape Fear Cape Fear Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Semi -Annual Monitoringt (61) ABMW-01 / S / BR MW-17SU / SL / BR ABMW-02SU / SL MW-21SU / SL / BR ABMW-03 / SR / BR MW-22S / BR ABMW-04 / S MW-23S / D / BR ABMW-05S / BR MW-24S / BR BG M W-04 PZ-01 BGTM W-04 PZ-02 CMW-01 PZ-03S / D CMW-02 PZ-04 CMW-03 PZ-05 CMW-05R PZ-06 CMW-06 PZ-08 CMW-07 Comprehensive Water Level Sweeps (includes wells in Semi - Annual, Quarterly, and Discontinued Monitoring Lists) CMW-08 CTM W-01 CTM W-02 CTMW-07 CTMW-08 MW-06BR MW-09 / BR MW-10 / D / BR / BRL MW-11 MW-12 / BR MW-15SU / SL / BR MW-16S / BR Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total and Dissolved as Applicable) Aluminum Manganese Alkalinity (CO3/HCO3) ----------------------------------------- Calcium ----------------------------------------- Antimony ----------- ---------------------- --------------------------------- Molybdenum --------------------------------- Arsenic Nickel Chloride --------------------------------- Barium --------------------------------- --------------------------------- Selenium --------------------------------- ----------------------------------------- Dissolved Oxygen (DO) ----------------------------------------- Beryllium --------------------------------- Strontium --------------------------------- Redox Potential (Eh) ----------------------------------------- Boron --------------------------------- Sulfate --------------------------------- Magnesium ----------------------------------------- Chromium(total) Thallium Nitrate + Nitrite --------------------------------- Chromium (hexavalent) --------------------------------- --------------------------------- Total Dissolved Solids (TDS) --------------------------------- ----------------------------------------- Oxidation -Reduction Potential (ORP) ----------------------------------------- Cobalt --------------------------------- Vanadium --------------------------------- pH ----------------------------------------- Iron --------------------------------- Zinc --------------------------------- Potassium ----------------------------------------- Lithium Specific Conductance ----------------------------------------- Sodium ----------------------------------------- Total Organic Carbon (TOC) ----------------------------------------- Temperature ----------------- ----------------------- Turbidity Discontinue Sampling Wells/Water Level Only (9) ABMW-5 MW-13 MW-18S MW-19S MW-20S / BR MW-5BRR PZ-07 PZ-09 PZ-10 To Be Replaced No well replacements planned at this time To be Abandoned No well replacements planned at this time Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment Cols = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Envrionmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. Table 2.6 - Cliffside Cliffside Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Quarterly Monitoring (106) AB -IS / D / BROR AB-2S/ D / BRO GWA-64BRL* GWA-65BR* / BRL* AB-3S1 / SL1 / MA15* / I / BRUA / BR / BRA GWA-66BRL* AB-4S1 / SL1 / UA15* / LA15* / D / BR GWA-67BR* / BRL* AS-4S AS-7S1 / 1* / BRL AS-8S / D GWA-68BRL* IB-6S* / D* IB-7S* / D* BG-1BRA MW-11S1 / DA / BRO / BRL* CCR-8BR* MW-20D / DR CCR-12BR* MW-30DA1 CCR-17BR* U5-1S CCR-IB-3BR* U5-2S-SLA1 CCR-U5-4BR* U5-6S CLMW-2 AB-7S2 / D2 / BR CLMW-3S1 / D1 AB-8S2 / D2 / BR GWA-11BR* / BRL* AB-9S2 / D2 / BR GWA-20S1 / D1 / BR AS-8BR2 GWA-21S1 / BRU1 / BR' / BRL* AS-9S2 / D2 GWA-22S1 / BRU GWA-57S2 / D2 / BR GWA-34BR* GWA-58S2 / D2 / BR GWA-38S GWA-59S2 / D2 / BR GWA-39S* GWA-60S2/ D2 / BR GWA-40S* GWA-61S2 / D2 / BR GWA-47D GWA-62S2 / D2 / BR GWA-54S / D / BRO GWA-63S2 / D2 Wells for Semi -Annual Monitoringt (147) AB-5S1/ BRU / BR GWA-31D / BRA AB-6S1 / D / BR GWA-33S / D / BR AS-1SB / D GWA-34S AS-2S1 / D1 / BR GWA-35S / D AS-3BRU AS-41D AS-5S / BRU / BR GWA-36S1 / D1 GWA-37S / D GWA-38D AS-6S / D / BRA GWA-42S* AS-713 / BRA GWA-43S / D BG-1S1 / D1 GWA-44S / D / BR CCPMW-IS' / D1 GWA-45D CCR-7S / D GWA-46D CCR-81) GWA-48BR CCR-12S / D GWA-51D CCR-13D GWA-56S / D CCR-15D MW-213A CCR-IB-1S / D MW-8S1 / D CCR-IB-3S / D MW-10S / D CCR-U5-3S / D M W-21D / BR CCR-U5-4S / D MW-22BR / DR CLMW-11 MW-23S / D / DR CLMW-5S MW-24D1 / DR1 CLMW-6 MW-25DR CLP-1*** MW-30S1 / D1 CLP-2*** MW-32S1 / D1 / BR GWA-1BRU MW-34S / BRU GWA-2S1 / BRU'/ BR1 MW-36S / BRU GWA-31)1 MW-38S1 / D1 / BR1 GWA-4S1 / D1 MW-40S / BRU GWA-5S / BRU MW-42S / DA GWA-10S / D U5-113 GWA-11S1 / BRU1 U5-21)1 / BR GWA-12S / BRU GWA-13BR U5-4S / D / BRA U5-5D1 / BR GWA-14S / D / BR U5-61) GWA-23D U5-8S / D / BR GWA-24S / D / BR Comprehensive Water Level Sweeps (includes wells in Semi - Annual, Quarterly, and Discontinued Monitoring Lists) GWA-25S GWA-26S GWA-27DA1 / BR1 GWA-28S /BRU / BR GWA-29D1 / BRA GWA-30S / BR Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" 2018 CSA Update COls Additional Water Quality Parameters (Total & Dissolved Where Applicable) (Total & Dissolved Where Applicable) Arsenic Aluminum --------------------------------------------------------------------------------------------------------- Boron ------------------------------------------------------------------------------------- Alkalinity--------(CO3/HCO3) ------------------------------------------------- -------------------------------------------------------- Chromium (total) ----------------------------------------------------------------------------- Barium --------------------------------------------------------------------------------------------------------- Hexavalent----------------Chromium--------- ------------------------------------------------------------------------------------- Beryllium -------------------------------------------------------------------------------- Cobalt ------------------------------------------------------------------------------------ - Calcium --------------------------------------------------------------------------------------------------------- Iron ------------------------------------------------------------------------------------- Chloride --------------------------------------------------------------------------------------------------------- Manganese ------------------------------------------------------------------------------------- Oxygen (DO) --------------------------------------------------------------------------------------------------------- Radium (226+228)1 -------------------------------Dissolved ------------------------------------------------------ Fluoride --------------------------------------------------------------------------------------------------------- Strontium ------------------------------------------------------------------------------------- Lithium --------------------------------- --------------------------------------------------------------------------------------------------------------- Sulfate --------------------------------------------------------------------------------------------------------- ----------------------------------------------- Magnesium ------------------------------------------------------------------------------------- Thallium Nitrate + Nitrite --------------------------------------------------------------------------------------------------------- Total Dissolved Solids (TDS) --------------------------------------------------------------------------------------------------------- ------------------------------------------------------------------------------------- Oxidation -Reduction Potential (ORP) ------------------------------------------------------------------------------------- Uranium (233+234+236+238) --------------------------------------------------------------------------------------------------------- pH ------------------------------------------------------------------------------------- Vanadium Potassium ------------------------------------------------------------------------------------- Redox Potential (Eh) ------------------------------------------------------------------------------------- Selenium ------------------------------------------------------------------------------------ Specific Conductance ------------------------------------------------------------------------------------ Sodium ------------------------------------------------------------------------------------ Phosphorus ------------------------------------------------------------------------------------ Total Organic Carbon (TOC) ---------------------------------Temperature --------------------------------- -------------------------------------Tu rbid ity------------------------------------ Discontinue Sampling Wells/Water Level Only (22) BG-2D CCPMW-2S / D CCPMW-3S / D CCPMW-4 CCPMW-5 CCPMW-6S / D CCPTW-IS / D CCPTW-2 CCR-6S / D GWA-6S / D GWA-25D GWA-26D GWA-30BRU GWA-32D / BR GWA-45S To Be Replaced AS-7BRA GWA-2BR U5-2S-SLA rNotes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Envrionmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. **Wells were previously approved by DEQ to be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Wells that exhibit elevated pH are proposed to remain a boron -and -sulfate - only sample location; however, if the pH improves with redevelopment to fall <_8.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. "optimized non -new well" or "new well" lists as proposed herein. No wells are currently flagged with this note but maybe in the future. ***Wells were previously approved by DEQ to be sampled for boron only in historic versions of the IMP due to these locations being installed as piezometers intended for water level only. 1Select wells to be sampled for Radium (226+228) 2Quarterly sampling includes additional assessment monitoring wells scheduled to be installed in 2019. The proposed monitoring well locations are based on additional data needs and as requested by NCDEQ. Actual well installation locations will be determined based on field conditions. Table 2.7 - Dan River Wells for Quarterly Monitoring (7) BG-1DA GWA-4S/D GWA-5BR/BRD GWA-6BR GWA-9BR Dan River Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q12019) Comprehensive water level sweep to occur semi-annually - March 2019 Wells for Semi -Annual Monitoringt (44) BG-5S/D MW-22S/D/BR ----------------------------------------- --------------------------- BG-10S/D/BR -----------------------------------------T--------------------------- MW-23D/BR MW_317BR/BRL---- --------------GWA-6S/D --- ----------------- GWA-7S/D MW-20S/D -----------------------------------------�--------------------------- GWA-8S/D/BR CCR-03S/D --------------------------,--------------------------- GWA9S/D LF-CCR04S/D -------------- --------------1- ---- _------ GWA-10D LF-CCR-05S/D ------------------------------t--------------------------- GWA12S/ �-------------4 -------------- -------------GWA_14S/D-------------- Comprehensive Water ---------------GWA_ 15 D--------------4 Level Sweeps GWA-16S/D I ------------------------------------------ (includes wells in Semi- GWA-17D ------------------------------------------0 Annual, Quarterly, and GWA-20S/D Discontinued Monitoring --------------- ---------- MW-12/D Lists ------------------------------------------ MW-21S/D Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total) Antimony Manganese Aluminum •--------------------------------- Arsenic •--------------------------------- --------------------------------- Molybdenum --------------------------------- ----------------------------------------- Alkalinity (CO3/HCO3) ----------------------------------------- Beryllium •--------------------------------- Nickel --------------------------------- Calcium ----------------------------------------- Boron Selenium Chloride •-------------------------------- Beryllium --------------------------------- Strontium ----------------------------------------- Dissolved Oxygen (DO) •--------------------------------- Chromium (total) --------------------------------- Sulfate ----------------------------------------- Redox Potential (Eh) •--------------------------------- Chromium (hexavalent) --------------------------------- Total Dissolved Solids (TDS) ----------------------------------------- Lithium Cobalt Vanadium ]--Oxidation-Reduction Magnesium Iron Potential (ORP) -------------------------------------- pH --------------------------- Phosphorus Potassium Specific Conductance ------------------------------- Sodium ------------------------------- Radium (226+228) ------------------------------- Total Organic Carbon (TOC) ------------------------------- Temperature ------------------------------- Turbiditv IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Envrionmental Quality Discontinue Sampling Wells/Water Level Only (1) GWA-10S To Be Replaced (1) BG-1D (replaced) None Semi -Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for (respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. Table 2.8 - H.F. Lee Wells for Quarterly Monitoring (12) Active Basin ABMW-1S AMW-15S BGMW-9 CMW-5 DMW-2 MW-1 MW-3 Inactive Basins IABMW-3S IMW-4S IMW-6S* IMW-7S* DMW-3 H.F. Lee Energy Complex - IMP Optimization Summary of Wells, Sampling Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Semi -Annual Monitoringt (50) Active Basin Inactive Basins ABMW-1 AMW-6RBC IABMW-1/S IABMW-2S AMW-11S/BC IABMW-3 AMW-12S/BC IMW-1S/BC AMW-13S/BC IMW-2BC AMW-14S/BC IMW-3S/BC AMW-15BC IMW-4BC AMW-16BC IMW-5S/BC AMW-17S/BC SMW-3 AMW-18S SMW-4 AMW-19S/BC BW-1 AMW-20S/BC CW-1 AMW-22S/BC CW-3 AMW-23S/BC CW-4 CCR-100S SMW-5 CMW-6R CTMW-1 MW-2 Comprehensive Water Level Sweeps (includes wells in Semi- Annual, Quarterly, and Discontinued Monitoring Lists) LOLA LLMW-1/S LLM W-2/S Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total) Antimony ------------------------------- Selenium ---------------------------------- Alkalinity (CO3/HCO3) Arsenic Strontium Aluminum ------------------------------- Barium ---------------------------------- Sulfate Calcium ------------------------------- Boron ---------------------------------- Thallium Dissolved Oxygen (DO) ------------------------------- Chloride ---------------------------------- Total Dissolved Solids (TDS) Hexavalent Chromium ------------------------------- Chromium (total) ------------------------------- ---------------------------------- Vanadium Redox Potential (Eh) Cobalt ------------------------------- Magnesium Iron Nitrate + Nitrite ------------------------------- Lithium ------------------------------- Oxidation -Reduction Potential (ORP) Manganese pH Phosphorus Potassium Specific Conductance Sodium Temperature Turbiditv otes IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COIs = Constituents of Interest CAMA = Coal Ash Management Act Discontinue Sampling Wells/Water Level Only (9) Active Basin AMW-9BC AMW-21S/BC BGMW-10 CMW-7 CMW-8 CMW-10 DMW-1 Inactive Basins CW-2 To Be Replaced No well replacements planned at this time To be Abandoned (2) Wells within the footprint of the Active Basin are slated for abandonment in 2019. ABMW-11S CDEQ = North Carolina Department of Envrionmental Quality iemi-Annual monitoring events are scheduled to be performed concurrently with two quarterly monitoring events per year and will include the wells listed under "Wells for Quarterly lonitoring" for respective events. New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re- valuated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in thich they replace; however, additional parameters may be included voluntarily. Wells for Quarterly Monitoring (62) AB-10SL/D/BR/BRL3* AB-12S3/D3/BR3 AB-14D/DU AB-15SL AB-16DU AB-1S3/D3/BR3/BRL3/BRLL3/BRLLL3* AB-20S AB-21S AB-2BR3* AB-3S AB-5S3/D3/DU3/BR3 AB-6S/D/BRA/BRL AB-7DU AB-8DU AL-1S3/D3/BR3/BRL3* AL-2S/D/BR/BRL/BRLL/BRLLL3* AL-3D/BR AL-4D/BR/BRL CCR-9SVDA1 GWA-2 DA GWA-10S GWA-15S3/D3 MW-14BR3/BRL*3 MW-6S3/D3 MW-7S3/D3 MW-8S3/D3 MW-9S3/D3 Table 2.9 - Marshall Marshall Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Semi -Annual Monitoringt (59) AB-12SL3 GWA-6S3/D3 AB-14S GWA-7S/D AB-15D/BR GWA-8S/D AB-20D GWA-9BR AB-21D GWA-10D AB-2S3/D3 GWA-11S3/D3/BR3 AB-3 D GWA-12S3/D* */BR3 AB-9S/D/BR GWA-13S/DA** AL-3S GWA-14S/D BG-1S3/D3/BRA3 MW-1 BG-2S3/BR3 M W-43/D3 BG-3S3/D3/BR3 MW-7 GWA-IS3/D3/BR3 MW-12S/D GWA-3S/D MW-13S/D GWA-4S/D MW-14S3/D3 GWA-5S/D OB-1 (Dry Ash Landfill) Comprehensive Water Level Sweeps (includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) Optimized Quarterly & Semi -Annual Parameters for "Non -New" Wells 2018 CSA Update COls (Total & Dissolved if Applicable) Additional Water Quality Parameters (Total & Dissolved if Applicable) Antimony Manganese Aluminum Arsenic Molybdenum Alkalinity (CO3/HCO3) Barium Nickel Calcium Beryllium Radium (226+228) 3 Dissolved Oxygen (DO) Boron Selenium Fluoride Cadmium Strontium Lithium Chloride Sulfate Magnesium Chromium (total) Total Dissolved Solids (TDS) Nitrate + Nitrite Chromium (hexavalent) Thallium Oxidation -Reduction Potential (ORP) Cobalt Vanadium pH Iron Potassium Specific Conductance Sodium Temperature Total Organic Carbon (TOC) Turbidity Notes: IMP = - Interim - Monitoring- - Plan - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - CSA = Comprehensive Site Assessment ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- COIs = Constituents of Interest ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- CAMA = Coal Ash Management Act ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- NCDEQ = North Carolina Department of Envrionmental Quality ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re- evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. ** Denotes well was previously approved by DEQ to be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Respective well is proposed to remain a boron -and -sulfate -only sample location; however, if the pH improves with redevelopment to fall <_8.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. "optimized non -new well" or "new well" lists as proposed herein. 1 Indicates CCR network well added to IMP per Brandy Costner request (conference call 9/5/18) 2 Well currently included on IMP list that is proposed to be removed from IMP (CAMA) sampling; will continue to be sampled under applicable landfill permit requirements. 3Total radium to be analyzed at select locations in accordance with Q4 2018 IMP Discontinue Sampling Wells/Water Level Only (27) AB-10S AB-11S/D AB-13S/D AB-16S/D AB-4S/SL/D AB-7S/D AB-8S/D GWA-2S MS-82 MS-102 MS-112 MS-132 MW-10S/D MW-11S/D M W-22 M W-32 M W-52 OB-1 (Ash Basin) Recently Abandoned (5) AB-17S/D AB-18S/D/DU To Be Replaced (2) AB-17S/D Wells for Quarterly Monitoring (5) ABMW-4X1 CW-21 MW-16S / D1 / BR' Table 2.10 - Mayo Mayo Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Modification - March 2019 Wells for Semi -Annual Monitoringt (29) ABMW-11 MW-3BR ABMW-2 / BR / BRL MW-SBR ABMW-3 / S MW-9BRL ABMW-4D / BR MW-12S1 / D1 BG-11 MW-13BR BG-21 MW-18D / BR CW-1 / D MW-19D / BR CW-2D1 CW-3 Comprehensive Water Level Sweeps CW-4 CW-5 (includes wells in Semi - Annual, Quarterly, and CW-61 Discontinued Monitoring Lists) M W-2 M W-31 Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" Additional Water Quality 2017 CSA Update COls (Total & Dissolved Where Applicable) Parameters (Total & Dissolved Where Applicable) Arsenic ----------------------------------- Manganese ---------------------------------- Alkalinity (CO3/HCO3) --------------------------------------- Bariu Molybdenum Calcium ----------------------m ------------- Boron ---------------------------------- Radium (226+228) --------------------------------------- Chloride ----------------------------------- Chromium (total) ----------------------------------- ---------------------------------- Strontium ---------------------------------- --------------------------------------- Magnesium --------------------------------------- Chromium(hexavalent) Sulfate Nitrate + Nitrite ------------------------------- ------------------ Cobalt ----------------------------------- --------------------- Total Dissolved Solids (TDS) ---------------------------------- --------------------------------------- pH --------------------------------------- Iron ----------------------------------- Uranium (233+234+236+238) ---------------------------------- Potassium --------------------------------------- Vanadium ____ _ Sodium ____ Total Organic Carbon (TOC) otes MP = Interim Monitoring Plan k = Comprehensive Site Assessment Is = Constituents of Interest 11CAMA = Coal Ash Management Act CDEQ = North Carolina Department of Envrionmental Quality Discontinue Sampling Wells/Water Level Only (4) M W -4 MW-8BR MW-10BR MW-14BR To Be Replaced No well replacements planned at this time To be Abandoned (1) ABMW-4 nual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly r respective events. New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th .uarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells ,ill be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring rotocol for the well in which they replace; however, additional parameters may be included voluntarily. Select wells to be sampled for radium 226 and 228. These select wells are to be monitored for total radium. If concentrations are greater than the Federal MCL, sample uarterly. If concentrations are less than the Federal MCL, reduce total radium sampling to semi-annually and reevaluate historical exceedances as possibly anomalous. If etermined to be anomalous, discontinue sampling for total radium. Background wells BG-1 and BG-2 will also be included in semiannual sampling of total radium for ongoing arative pu Table 2.11 - Riverbend Wells for Quarterly Monitoring (23) CPA-1S*/D* CPA-2S*/D* CPA-3S*/D* CPA-4S* CPA-5S*/D* CPA-6S* CPA-7S*/D* GWA-11S/D GWA-12S/D GWA-20S GWA-2BRU GWA-3SA/D/BR GWA-9D MW-6D Riverbend Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water level Sweep to Occur Semi -Annually Modification - February 2019 Wells for Semi -Annual Monitoringt (68) A13-8S/D MW-1S/D BG-1S/DA MW-2SA/D BG-4S/D MW-3S/D BG-5D/BR MW-4S/D GWA-1S/BRU MW-5S/D GWA-2S/BR MW-6S GWA-4S/D/BR MW-7SR/D/BRA GWA-5S/D MW-8S/I/D GWA-6S/D M W-9/9DA/9BRA GWA-7S/D/BR MW-10 GWA-8S/D MW-11SR/DR GWA-9S/BR MW-13 GWA-10S/BRU MW-14 GWA-13S1 MW-15/15DA/15BR GWA-14S/D OB-1(water level only) GWA-15S/D OB-2 (water level only) GWA-20DA/BR Comprehensive Water Level Sweeps (includes wells in Semi - Annual, Quarterly, and Discontinued Monitoring Lists) GWA-22S/D/BRA Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total) Antimony Iron Aluminum Arsenic Manganese Alkalinity (CO3/HCO3) Beryllium Strontium Calcium Boron Sulfate Dissolved Oxygen (DO) Chromium (total) Total Dissolved Solids (TDS) Redox Potential (Eh) Chromium (hexavalent) Vanadium Lithium Cobalt Magnesium Molybdenum Nickel Nitrate + Nitrite Oxidation -Reduction Potential (ORP) pH Phosphorus Potassium Sodium Specific Conductance Temperature Thallium Turbidity Not IIMP = Interim Monitoring Plan , = Comprehensive Site Assessment s = Constituents of Interest CIA = Coal Ash Management Act INCDEQ = North Carolina Department of Environmental Quality Discontinue Sampling Wells/Water Level Only (10) BG-2S/D/BR BG-3S/D BG-4BR GWA-13D GWA-21S/D/BR To Be Replaced (4) GWA-9BRA GWA-20BRA GWA-22SA MW-4SA 7 7GWA-23ST/DA/7 B ItSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re- evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. 1 GWA-13S will be temporarily sampled until replacement well GWA-22SA is installed. After GWA-22SA is installed: 1. Sampling of GWA-13S will be discontinued 2. Semi-annual water level measurements of GWA-13S will continue 3. Semi-annual sampling and water level measurements of GWA-22SA will begin Table 2.12 - Roxboro Wells for Quarterly Monitoring* (5) CCR-113BR CCR-113D HWMW-1BR GMW-08R MW-21BRLR Roxboro Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Modification - March 2019 Wells for Semi -Annual Monitoringt (73) ABMW-01 (+) GPMW-1BR MW-17BR(+) ABMW-01BR (+) GPMW-ID MW-18BR (+) ABMW-02 (+) GPMW-1S MW-18D (+) ABMW-02BR (+) GPMW-2BR MW-19BRL (+) ABMW-03 GPMW-2D MW-20BRL ABMW-03BR GPMW-3BR MW-22BR ABMW-03BRL GPMW-3D MW-22D ABMW-05D (+) MW-01BR MW-23BRR ABMW-06 MW-02 (+) MW-24BR ABMW-06BR MW-02BR MW-26BR ABMW-07BR MW-03BR (+) MW-27BR ABMW-07BRL MW-04BR MW-28BR BG-01 (+) MW-05BR (+) MW-29BR BG-01BR (+) MW-05D (+) MW-30BR BG-01BRLR (+) MW-06BR (+) MW-31BR BG-2BR (+) MW-06D (+) MW-32BR CW-01 CW-02 (+) MW-07BR MW-08BR MW-33BR** Comprehensive Water Level Sweeps (includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) CW-02D (+) MW-09BR (+) CW-03 MW-10BR (+) CW-03D MW-11BR (+) CW-04 MW-11D (+) CW-05 (+) MW-12BR GMW-06 MW-13BR (+) GMW-07 MW-14BR (+) GMW-09 MW-15BR (+) GMW-10 MW-15D (+) GMW-11 MW-16BR (+) Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" 2017 CSA Update COls Additional Water Quality Parameters (Total & Dissolved (Total & Dissolved Where Applicable) Where Applicable) Antimony Sulfate Aluminum Boron Total Dissolved Solids (TDS) Alkalinity (CO3/HCO3) Chromium (hexavalent) Uranium (233+234+236+238) Arsenic Chromium (total) Vanadium Calcium Cobalt Chloride ------------- -------------------- Iron ----------------------------------------- •-------------------------------------------------------------------------------- Dissolved Oxygen (DO) Manganese Redox Potential (Eh) Molybdenum Lithium Selenium --------------------------------- ----------------------------------------- Magnesium •-------------------------------------------------------------------------------- Strontium Nitrate + Nitrite ----------------------- ---------------------------------------------------------- Oxidation-Reduction Potential (ORP) ----------- ------ pH ------------------------------------------- 7------------------------------------- Potassium •-------------------------------------------------------------------------------- Radium (226+228) (+) ---------------------------- ---------------------- Specific Conductance •-------------------------------------------------------------------------------- Sodium - - - - - - - - - - - - - - - - - - - - - - - - - - Total Organic Carbon (TOC) Temperature Turbidity Discontinue Sampling Wells/Water Level Only (2) ABMW-05 MW-25BR To Be Replaced No well replacements planned at this time To be No wells are schedu7tobeabandoned at thi Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. ** Denotes well was previously approved by DEQ to be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Respective well is proposed to remain a boron -and -sulfate -only sample location; however, if the pH improves with redevelopment to fall <_8.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. "optimized non -new well" or "new well" lists as proposed herein. (+) -Select wells to be sampled for total radium (226 + 228). Table 2.13 - Sutton L.V. Sutton Energy Complex - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Quarterly Monitoring (38) Wells for Semi -Annual Monitoringt (48) MW-12R MW-45B* AW-03C MW-40C M W-33C M W-45C* AW-04C SMW-04C SMW-01C MW-46B* AW-05C SMW-05C SMW-02C MW-46C* AW-08C SMW-06C SMW-03C MW-47B* AW-09C MW-05C MW-08B MW-47C* MW-07C MW-05CD MW-08D MW-41B MW-41C MW-48B* MW-48C* MW-49B* MW-16D MW-05D MW-05R-E MW-08 MW-20 MW-20D MW-41D MW-49C* MW-21C MW-08E FPA-1B* MW-50B* MW-22C MW-37B FPA-1C* MW-50C* MW-23B MW-37C FPA-2B* MW-23C MW-37CD MW-23D MW-37D MW-23E MW-37E MW-24RB MW-41E MW-24RC ABMW-02D MW-27B ABMW-02S MW-27C MW-16 MW-28C MW-36B MW-31R-C SMW-01B MW-36C SMW-05B MW-38C SMW-06B MW-39C MW-05B Comprehensive Site Semiannual water level sweep (includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) FPA-2C* FPA-3B* FPA-3C* FPA-4B* FPA-4C* MW-13R* MW-13R-D* MW-15R* MW-15R-D* MW-43B* MW-43C* MW-44B* M W-44C* Optimized Quarterly & Semi -Annual Parameters for "Non -New" Wells (Total) Arsenic Strontium Alkalinity (CO3/HCO3) Boron Sulfate Aluminum Chloride TDS (Total Dissolved Solids) Barium Chromium (hexavalent) Vanadium Calcium Cobalt Dissolved Oxygen (DO) Iron ---------------------------------------- ------------------------------------------- Lithium -------------------------------------------------------- Manganese Magnesium Molybdenum Nitrate + Nitrite pH Oxidation -Reduction Potential (ORP) Selenium Potassium Redox Potential (Eh) •-------------------------------------------------------- Sodium •-------------------------------------------------------- Specific Conductance -------------------------------------------------------- Temperature •-------------------------------------------------------- Total Organic Carbon (TOC) •-----------------------Fluoride ---------------------- ------------------------ ------------------------------- Turbidity Discontinue Sampling Wells/Water Level Only (20) AW-01C AW-02C AW-02 D AW-05 D AW-06R-D AW-06R-E AW-07R-D AW-09 D MW-11 MW-19 MW-22B MW-28B MW-32C MW-38B MW-38D MW-39B MW-39D M W-40 B MW-40D SMW-06D To Be Replaced No well replacements planned at this time Abandoned/To be Abandoned No wells are scheduled to be abandoned at this time. IMP = Interim Monitoring Plan -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- CSA = Comprehensive Site Assessment -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- COIs = Constituents of Interest -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- CAMA = Coal Ash Management Act -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- NCDEQ = North Carolina Department of Envrionmental Quality -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. Twi-w ---wells------installed----------as---part------of----the-------CAMA------------program wi-----ll--be----monitored----------------------quarterly.-------Samples----------from---these----------lls---will-----be------------analyzed---for---------parameters------------formerly-------- in----cluded-----as---part------of----the---4th-----Quarter-----------2018------IMP-------and ---------- *Newe additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. Wells for Quarterly Monitoring (20) BW-4DA* CPA-1S*/I* CPA-21 * CPA-3S*/I * CPA-4S*/I* CPA-5S*/I * CPA-6S*/I* CPA-7S*/I* CPA-8S*/I* MW-2 (fuel oil well)* MW-4 (fuel oil well)* M W-5511 PW-1 (DEP #2) Table 2.14 - Weatherspoon Weatherspoon Power Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2019) Comprehensive Water Level Sweep to occur Semi -Annually Modification - March 2019 Wells for Semi -Annual Monitoringt (26) AW-02S MW-33S/I/D AW-03S/l MW-411 BW-2S1 MW-521 BW-3S1/11 AW-04S BW-4S1/11 AW-05S CCR-101-BG1 AW-06S CW-2 BW-5S CW-31 CCR-1071 MW-11 MW-41 MW-21 MW-51 M W-31 Comprehensive Water Level Sweeps(includes wells in Semi -Annual, Quarterly, and Discontinued Monitoring Lists) Optimized Quarterly & Semi -Annual Parameters for "Non -New Wells" (Total) Aluminum Manganese Alkalinity (CO3/HCO3) Arsenic Molybdenum Calcium Barium Nickel Dissolved Oxygen (DO) Beryllium Radium (226 + 228) Fluoride Boron Selenium Lithium Chloride Strontium Magnesium Chromium (total) Sulfate Nitrate + Nitrite Chromium (hexavalent) Thallium Oxidation -Reduction Potential (ORP) Cobalt Total Dissolved Solids (TDS) pH Copper Vanadium Potassium Iron Uranium (233+234+236+238) Specific Conductance Lead Zinc Sodium Temperature Turbidity Redox Potential (Eh) Discontinue Sampling Wells/Water Level Only (14) AW-01S/I/D AW-02D AW-03D BW-01 BW-3D BW-4D CW-1 MW-41D MW-531/D M W-54D MW-55D To Be Replaced (2) MW-6 (replaced by CCR-107) MW-7 (replaced by CCR-107) To Be Abandoned (2) M W-6 M W-7 Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment CCIs = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Envrionmental Quality 1 - Wells to be sampled for radionuclides (also bolded text) tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace; however, additional parameters may be included voluntarily. TABLE 3 Proposed Sampling Schedules & Respective CAMA Data Submittals Duke Energy - 14 North Carolina Facilities (to begin Q1 2019) Facility Name a L s N L L L £_ L to Q, ate+ > V of O Z C Allen C Q SA D Q D SA Asheville SA Q SA D Q D Belews Creek SA Q SA D Q D Buck D Q SA D Q D SA Cape Fear* D* SA/ Q D SA D Q Cliffside SA Q D SA D Q D Dan River SA D Q D SA D Q H.F. Lee** SA Q D SA Q Marshall SA Q D SA D Q Mayo Q SA Q D SA D Riverbend* SA Q SA Q Roxboro** Q SA Q D SA D Sutton Q D SA D Q D SA Weatherspoon Q D SA D Q D SA D * There will be (1) Q1 Data Submittal per site per year; however, for Cape Fear and Riverbend, the Data Submittal months for Q1 2019 are not the same as what is planned for 2020 and beyond. This effect is due to the timing of the previous Q4 2018 sampling event. For Cape Fear, the Q1 Data Submittal will be a February submittal in 2019 only and will shift to a January submittal in 2020. For Riverbend, the Q1 Data Submittal will be a March submittal in 2019 only and will shift to a January submittal beginning in 2020. **NPDES Ash Basin Sampling could cease upon receipt of NPDES Permit Modification D = Data Submittal (End of Month) Q = Quarterly CAMA event SA = Semi annual CAMA event Non-CAMA Compliance Categories NPDES Ash Basin and Landfill Sampling NPDES Ash Basin Sampling Landfill Sampling