HomeMy WebLinkAboutDEQp00021174Facility Name:
NPDES No.:
Type of Waste:
Facility Status:
Permit Status:
Receiving Stream:
Stream Classification:
Subbasin:
County:
Regional Office:
Requestor:
Date of Request:
Topo Quad:
FACT SHEET FOR WASTELOAD ALLOCATION
Wasteload Allocation Summary
(approach taken, correspondence with region, EPA, etc.)
Dilution here is >30:1. Limits for pH, BOD5, and TSS are BPT limits for plastic, nylon, and
tape products (SUBPART 140 CFR 414.41). The OCPSF guidelines were given as defined in 40
CFS 414.91. These limits are based on the highest monthly average OCPSF-contributing flow in
the past 12 months. A new fluoride limit was calculated using 17 MGD flow (cooling water and
process water) and the latest S7Q10 statistic, assuming no background fluoride levels. This
resulted in the new limit given as a concentration not a mass. The toxicity test will remain a
pass/fail chronic analysis using ceriodaphnia but will be given at an IWC of 3.2% because mer;
4P 0iffit. iffl.,4-MaQape Fear Ga /Cu Q/70r1
gl4f 4MC 1014Y .
Special Schedule Requirements and additional comments from Reviewers:
Recommended by: Date:
h3r
Reviewed by
Instream Assessment,
Regional Supervisor:
Permits & Engineerin
RETURN TO TECHNICAL SERVICES BY:
MAK I y
S �
1993
ENV. MANAGEMENT
FAYETTEVILLE REG. OFFICT
Request # 7250,7251,
7252
E.I. DuPont de Nemours & Co.,
Inc./Fayetteville Works
NC0003573
Industrial - 97%/Domestic - 3%
Existing
Renewal
Cape Fear River
r
C
030616
Bladen
Stream Characteristic:
release from,
Fayetteville
US GS #
Jordan Dam
Nizich
Date:
1989
11/23/92
Drainage Area (mi2):
H23SE
Summer 7Q10 (cfs):
791
Winter 7Q10 (cfs):
Average Flow (cfs):
5676
30QIWC)2(%):
3.1
Wasteload Allocation Summary
(approach taken, correspondence with region, EPA, etc.)
Dilution here is >30:1. Limits for pH, BOD5, and TSS are BPT limits for plastic, nylon, and
tape products (SUBPART 140 CFR 414.41). The OCPSF guidelines were given as defined in 40
CFS 414.91. These limits are based on the highest monthly average OCPSF-contributing flow in
the past 12 months. A new fluoride limit was calculated using 17 MGD flow (cooling water and
process water) and the latest S7Q10 statistic, assuming no background fluoride levels. This
resulted in the new limit given as a concentration not a mass. The toxicity test will remain a
pass/fail chronic analysis using ceriodaphnia but will be given at an IWC of 3.2% because mer;
4P 0iffit. iffl.,4-MaQape Fear Ga /Cu Q/70r1
gl4f 4MC 1014Y .
Special Schedule Requirements and additional comments from Reviewers:
Recommended by: Date:
h3r
Reviewed by
Instream Assessment,
Regional Supervisor:
Permits & Engineerin
RETURN TO TECHNICAL SERVICES BY:
MAK I y
S �
1993
ENV. MANAGEMENT
FAYETTEVILLE REG. OFFICT
101
TOXICS/METALS/CONVENTIONAL PARAMETERS
Type of Toxicity Test: Chronic pass/fail test using ceriodaphnia
Existing Limit: 3.3%
Recommended Test/Limit: 3.3%
Monitoring Schedule: Feb, May, Aug, Nov
Existing Limits (00.1_
Monthly Average Daily Max.
FLOW (MGD): 2.0
BODS (lbs/day): 182 570
TSS (lbs/day): 312 556
pH (SU): 6-9
*See attached list for OCPSF Chemical specific limits existing for the 001 outfall.
Existing Limits (0021
Monthly Average Daily Max.
FLOW (MGD): 15.0
BODS (mg/1): monitor
Temperature (°C): monitor*
COD (mg/1): monitor
Fluoride (lbs/day): 7663** 7663
pH (SU): 6-9
*The temperature of the effluent shall be such as not to cause an increase in the temperature of the receiving stream
of more than 2.8°C and in no case cause the ambient water temperature to exceed 3rC.
**The samples for fluoride must be taken downstream of the 001 discharge, unless or until, all neutralized Nafion
Area streams are discharged entirely into the cooling water outfall, 002.
Existing Limits (003)
Monthly Average Daily Max.
FLOW (MGD): monitor
TSS (mg/1): 30 45
Settleable Solids (ml/1): 0.1 0.2
pH (SII): 6-9
*The discharge shall not cause the turbidity of the receiving water to exceed 50 NTU. If the turbiditiy exceeds these
levels due to natural background conditions, the discharge level cannot cause any increase in the turbidity in the
receiving water.
Recommended Limits are listed on the next nage.
TOXICS/METALS/CONVENTIONAL PARAMETERS
Recommended Limits (001)
Monthly Average Daily Max.
FLOW (MGD): 2.0
BOD5 (lbs/day): 4&2� 175- .wo- %• EL
r , TSS (lbs/day): 31-2-2-97,.3 -56-95D- EL
�✓ (SU): 6-9
�o5t/.4(e attached list for OCPSF Chemical specific limits recommended for the 001 outfall.
Recommended Limits (002)
Monthly Average Daily Max.
FLOW (MGD): 15.0
BODS (mg/1): monitor
Temperature (°C): monitor*
COD (mg/1): monitor
Fluoride (mg/1): 63** WQ
pH (St): 6-9
*The temperature of the effluent shall be such as not to cause an increase in the temperature of the receiving stream
of more than 2.8°C and in no case cause the ambient water temperature to exceed 32°C.
**The samples for fluoride must be taken downstream of the 001 discharge, unless or until, all neutralized Nafion
Area streams are discharged entirely into the cooling water outfall, 002.
Recommended Limits (003)
Monthly Average Daily Max.
FLOW (MGD): monitor
TSS (mg/1): 30 45
Settleable Solids (ml/1): 0.1 0.2
pH (St): 6-9
*The discharge shall not cause the turbidity of the receiving water to exceed 50 NTU. If the turbiditiy exceeds these
levels as a result of natural background conditions, the discharge level cannot cause any increase in the turbidity in
the receiving water.
Limits Changes Due To: Parameter s Affec
Change in 7Q10 data x tox. test, fluoride
Change in stream classification
Data from Priority Pollutant Analysis
Change in discharge rates x OCPSF parameters
New pretreatment information
Other (onsite toxicity study, interaction, etc.)
X Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate
receiving water will be consumed. This may affect future water quality based effluent limitations for additional
dischargers within this portion of the watershed.
L
No parameters are water quality limited, but this discharge may affect future allocations.
4
INSTREAM MONITORING REQUIREMENTS
Upstream Location: Cape Fear River approximately 50' upstream of outfall
Downstream Location: Cape Fear River at nearest accessible downstream site
Parameters: Turbidity
Special instream monitoring locations or monitoring frequencies:
MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS
Adequacy of Existing Treatment
Has the facility de nstrated the ability to meet the proposed new limits with existing treatment
facilities? Yes No
If no, which parameters cannot be met?
Would a "phasing in" of the new limits be appropriate? Yes No
If yes, please provide a schedule (and basis for that schedule) with the regional
office recommendations:
If no, why not?
Special Instru tions or Conditions
Wasteload sent to EPA? (Major) (Y or N)
(If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old
assumptions that were made, and description of how it fits into basinwide plan)
Additional Information attached? (Y or N) If yes, explain with attachments.
6X TV5'rRQM,W L4 X0 5 ;)CF-5F1/�or2�Sr9 �r LAa rr M1�W�
L.ocgA--norf MAP, CLp 0c5r- LIM175 .
W4
Facility Name _ 56(l�-02AII---f,4Yt-1-77-VIU-,e-Permit # Pipe #
CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY)
The effluent discharge shall at no time exhibit chronic toxicity using test procedures utlinMi
1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Chronic Bioassay
Procedure - Revised *September 1989) or subsequent versions.
The effluent concentration at which there may be no observable inhibition of rep rodu ti cant mortality
is .3- L% (defined as treatment two in the North Carolina procedure ument). Th dol er shall perform
monitoring using this procedure to establish compliance a permit 'tioq. a first test will be
pe rfo ter t1grtydays from the effective date of this
Efflu camp '
permitted final effluent discharge below all nt prQc
't ' g mont of
fo this tin shall be rfortrned I t the NPDES
ses.
All toxicity testing results required as part o. i
Monitoring Form (MR -1) for the month in hi
Additionally, DEM Form to (original) ' to
mut co did n entered on
it was o us' g the parameter
sent to th folio ng address:
the Effluent Disc arge
code TGP
Test data shall be complete andtas
rate a
association with a toxicity tewell
sample must be asured anded if
Should any sing e q arterly mng in
been immediat ly til such tiat arev&rt to quarter in montcifid
any test
NOTE: FaflSjre to'3WAlmonitoring
hieve testa
survival and a ate envnronr.
retesting(withinys of initial
noncompliance i
7Q10 c
Permitted Flo O GD
IWC 3 P� D �Y
Basin &Sub -basin
Receiving Strq4mm (,^lPa 2
County P4,t j5Aj
QCL PIF Version 9191
Carolina
Creek Ro
1 27607
lude allpgAng chemi hysical measurements performed in
dose/response data. T residual chlorine of the effluent toxicity
ne is employed for ' infection of the waste stream.
failure to me specified limits, then monthly monitoring will
st is pass Upon passing, this monthly test requirement will
or tests performed by the North Carolina Division of
to the receiving stream, this permit may be re -opened and
or limits.
specified in the cited document, such as minimum control organism
)ls, shall constitute an invalid test and will require immediate
event). Failure to submit suitable test results will constitute
Recommended by:
Date 9
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FAYETTEVILLE WORKS
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PAGE 2 OF 2
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EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL NC0003573
During the period beginning on the effective date of the permit and lasting until expiration, the
Permittee is authorized to discharge from outfall serial number 001 (Continued). Such discharges
shall be limited and monitored by the permittee as specified below:
Effluent Characteristics
Mon. Avg.
Daily Max.
Measurement Sample
*Sample
lbs/day
lbs/day
Frequency
Type
Location
Acenaphthene
0.17
0.58
Quarterly
Grab
E
Acrylonitrile
0.76
2.37
Quarterly
Grab
E
Benzene
0.29
1.33
Quarterly
Grab
E
Carbon Tetrachloride
0.14
0.37
Quarterly
Grab
E
Chlorobenzene
0.12
0.27
Quarterly
Grab
E
1,2,4-Trichlorobenzene
0.54
1.37
Quarterly
Grab
E
Hexachlorobenzene
0.12
0.27
Quarterly
Grab
E
1,2-Dichloroethane
0.54
2.07
Quarterly
Grab
E
1,1,1 -Trichloroethane
0.17
0.53
Quarterly
Grab
E
Hexachloroethane
0.17
0.53
Quarterly
Grab
E
1,1-Dichloroethane
0.17
0.58
Quarterly
Grab
E
1,1,2 -Trichloroethane
0.17
0.53
Quarterly
Grab
E
Chloroethane
0.82
2.63
Quarterly
Grab
E
Chloroform
0.17
0.45
Quarterly
Grab
E
2 -Chlorophenol
0.24
0.96
Quarterly
Grab
E
1,2 -Dichlorobenzene
0.61
1.60
Quarterly
Grab
E
1,3 -Dichlorobenzene
0.24
0.43
Quarterly
Grab
E
1,4 -Dichlorobenzene
0.12
0.27
Quarterly
Grab
E
1,1-Dichloroethylene
0.13
0.25
Quarterly
Grab
E
1,2-trans-Dichloroethylene
0.17
0.53
Quarterly
Grab
E
2,4-Dichlorophenol
0.31
1.10
Quarterly
Grab
E
1,2-Dichloropropane
1.21
2.25
Quarterly
Grab
E
1,3-Dichloropropylene
0.23
0.43
Quarterly
Grab
E
2,4 -Dimethylphenol
0.14
0.35
Quarterly
Grab
E
2,4-Dinitrotoluene
0.89
2.79
Quarterly
Grab
E
2,6-Dinitrotoluene
2.01
6.28
Quarterly
Grab
E
Ethylbenzene
0.25
1.06
Quarterly
Grab
E
Fluoranthene
0.20
0.67
Quarterly
Grab
E
Methylene Chloride
0.32
0.87
Quarterly
Grab
E
Methyl Chloride
0.68
1.86
Quarterly
Grab
E
Hexachlorobutadiene
0.16
0.48
Quarterly
Grab
E
Naphthalene
0.17
0.58
Quarterly
Grab
E
Nitrobenzene
0.21
0.67
Quarterly
Grab
E
2-Nitrophenol
0.32
0.68
Quarterly
Grab
E
4-Nitrophenol
0.57
1.22
Quarterly
Grab
E
2,4-Dinitrophenol
0.56
1.21
Quarterly
Grab
E
4,6-Dinitro-o-cresol
0.62
2.71
Quarterly
Grab
E
Phenol
0.12
0.25
Quarterly
Grab
E
Bis(2-ethylhexyl)phthalate
0.81
2.73
Quarterly
Grab
E
Di -n -butyl phthalate
0.21
0.56
Quarterly
Grab
E
Diethyl phthalate
0.64
2.00
Quarterly
Grab
E
Dimethyl phthalate
Benzo(a)anthracene
0.15
0.17
0.46
0.58
Quarterly
Quarterly
Grab _
Grab-,
F1�,
Benzo(a)pyrene
0.18
0.60
Quarterly
Grab
IFL t (Continued)
Effluent Characteristics Mon. Avg. Daily Max. Measurement Sample
*Sample Location: E -Effluent
',�
*Sample
Location
E
E
E
E
E
E
E
E
E
E
E
E
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APP 4
lbs/day
lbs/day
Frequency
Type
3,4-Benzofluoranthene
0.18
0.60
Quarterly
Grab
Benzo(k)fluoranthene
0.17
0.58
Quarterly
Grab
Chrysene
0.17
0.58
Quarterly
Grab
Acenaphthylene
0.17
0.58
Quarterly
Grab
Anthracene
0.17
0.58
Quarterly
Grab
Fluorene
0.17
0.58
Quarterly
Grab
Phenanthrene
0.17
0.58
Quarterly
Grab
Pyrene
0.20
0.67
Quarterly
Grab
Tetrachloroethylene
0.17
0.55
Quarterly
Grab
Toluene
0.21
0.78
Quarterly
Grab
Trichloroethylene
0.17
0.53
Quarterly
Grab
Vinyl Chloride
0.82
2.63
Quarterly
Grab
*Sample Location: E -Effluent
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*Sample
Location
E
E
E
E
E
E
E
E
E
E
E
E
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APP 4