DEQp00021135

0
IEA LABORATORY RESULTS
Y
IEA Project #: 951-005
Client Name: E. I. duPont de Neumors, Inc.
Date
Sample # Client ID Parameter Results Analyzed
a.
1 001 Temperature, 26.6 C 02/06/91
1 001 pH t 7.52 02/06/91
30A 7�

Sample ID: 951-005
A. Purgeable (Volatile Organic) Fraction, EPA Method 603/8240 Page 2 of 9
Number of chemicals detected in Fraction 1
Fraction STORET Number 84085
STORET Compound Quantitation Quantitation Concentration GC/MS
Number Limit Target Limit* Detected Confirmation?
Pollutants to be analyzed for: (ug/L)(ug/L) (ug/
L) Yes No
t
34210
Acrolein
100
<100
34215
Acrylonitrile
100
<100
34030
Benzene
5
<5
x
32101
Bromodichloromethane
5
<5
x
32104
Bromoform
5
<5
x
34413
Bromomethane
10
<10
x
32102
Carbon tetrachloride
5
<5
x
34301
Chlorobenzene
6
<<6
X
34311
Chloroethane
10
<10
x
34576
2-Chloroethyl vinyl ether
10
<10
x
32106
Chloroform
5
<5
x
34418
Chloromethane
10
<10
x
32105
Dibromochloromethane
5
<5
x
34496
1,1-Dichloroethane
5
<5
x
34531
1,2-Dichloroethane
5
<5
x
34501
1,1-Dichloroethylene
5
<5
x
34546
trans-1,2-Dichloroethylene
5
<5
x
34541
1,2-Dichloropropane
6
<6
x
34704
cis-1,3-Dichloropropene
5
<5
x
34699
trans-1,3-Dichloropropene
5
<5
x
34371
Ethylbenzene
8
<8
x
34423
Methylene chloride
5
<5
x
34516
1,1,2,2 -Tetrachloroethane
7
<7
x
34475
Tetrachloroethylene
5
<5
x
34010
Toluene
6
<6
x
34506
1,1,1 -Trichloroethane
5
<5
x
34511
1,1,2 -Trichloroethane
5
<5
x
39180
Trichloroethylene
5
<5
x
34488
Trichlorofluoromethane
10
<10
x
39175
Vinyl chloride
10
<10
x
*If different from quantitation limit target
X
x

Compound
Probable
Molecular
Wei ht
Estimated
Concentration
(u )
Library Match
Probability
(7.)
Retention
Time (RT)
(Min)
Identification Basis
(Check all that aoolv)
Scan
Number
Library
Motch
Manual
Interpretation
RT,
None Defected
Complete only if non—targeted compounds are present:
Retention
Internal Standard Time
(Min)
1,
U
M
L4
0
ft

Sample I.D.: 951-005
B. Acid
Extractable Fraction,
EPA Method 8270
Page 4 of 9
Number of chemicals detected in Fraction 1
Fraction
STORET Number 45582
STORET
Compound
Quantitation Quantitation
Concentration
GC/MS
Number
Limit Target Limit*
Detected
Confirmation?
Al
Pollutants to be analyzed for:
(ug/ L)' (ug/L)
(ug/L)
Yes No
4
34452
4-Chloro-3-methylphenol 10
<10
X
34586
2 -Chlorophenol
10
<10
X
34601
2,4-Dichlorophenol .-
10
<10
X
34606
2,4 -Dimethylphenol"
10
<10
X
34616
2,4-Dinitrophenol
50
<50
X
34657
2-Methyl-4,6-dinitrophenol 24
<24
X
34591
2-Nitrophenol
10
<10
X
34646
4-Nitrophenol
50
<50
X
39032
Pentachlorophenol
50
<50
X
34694
Phenol
10
<10
X
34621
2,4,6 -Trichlorophenol
10
<10
X
*If different from quantitation limit target

Compound
Probable
Molecular
Wei ht'
Estimated
Concentration
(un/L
Library Match
Probability
%
Retention
Time (RT)
Min
Identification Basis
Check all.that apply)
Scan
Number
Library
Match
Manual
Interpretation
RT
Unknown
155
24
N/A
12.62
X
949
Complete only if non—targeted compounds are present:
Internal Standard
Retention
Time
Min
Naphthalene — d8
11.18
*Not all quantitated results can be accompanied by complete ID. Further
investigation should be discussed with your Client Services Representative.
I
s
CD
D
n
a
(D
x
D
n
O
(n
(n
C
O
to
3
(D
N
CD
D
'

C: Base/Neutral Fraction, EPA Method 8270
Page 6 of
9
Number
of chemicals detected in Fraction 4
Fraction STORET Number 45583
STORET
Compound Quantitation
Quantitation
Concentration
GC/MS
Number
Limit Target
Limit*
Detected
Confirmation?
Pollutants to be analyzed for:
(ug/L)
(ug/L)
(ug/L)
Yes No
34205
Acenaphthene
10
<10
X
34200
Acenaphthylene
10 ,A,
y,<10
X
34220
Anthracene
10 '4
<10
X
39120
Benzidine
50
<50
X
34526
Benzo (a) anthracene
10
<10
X
34247
Benzo (a) pyrene
10
<10
X
34230
Benzo (b) fluoranthene
10
<10
X
34521
Benzo (ghi) perylene
10
<10
X
34242
Benzo (k) fluoranthene
10
<10
X
34278
Bis (2-chloroethoxy)methan
10
<10
X
34273
Bis(2-chloroethyl)ether
10'
<10
X
34283
Bis(2-chloroisopropyl)ethe
10
<10
X
39100
Bis(2-ethylhexyl)phthalate
10
<10
X
34636
4-Bromophenyl phenyl ether
10
<10
X
34292
Butyl benzyl phthalate
10
<10
X
34581
2-Chloronaphthalene
10
<10
X
34641
4-Chlorophenyl phenyl ethe
10
<10
X
34320
Chrysene
10
<10
X
34556
Dibenzo(a,h) anthracene
10
<10
X
34536
1,2 -Dichlorobenzene
10
<10
X
34566
1,3 -Dichlorobenzene
10
<10
X
34571
1,4 -Dichlorobenzene
10
<10
x
34631
3,3-Dichlorobenzidine
20
<20
X
34336
Diethyl phthalate
10
<10
X
34341
Dimethyl phthalate
10
<10
X
39110
Di -n -butyl phthalate
10
<10
X
34611
2,4-Dinitrotoluens
10
<10
X
`34626
2,6-Dinotrotoluene
10
<10
X
34596
Di-n-octyl phthalate
10
<10
X
34346
1,2-Diphenylhydrazine
10
<10
X
34376
Fluoranthene
10
<10
X
34381
Fluorene
10
<10
'X
39700
Hexachlorobenzene
10
<10
X
34391
Hexachlorobutadiene
10
<10
X
34386
Hexachlorocyclopentadiene
10
<10
X
34396
Hexachloroethane
10
<10
X
34403
Indeno(1,2,3-cd)pyrene
10
<10
X
34408
Isophorone
10
<10
X
34696
Naphthalene
10_
<10
X
34447
Nitrobenzene
10
<10
X
34438
N-nitrosodimethylamine
10
<10
X
34428
N-nitroso-di-n-propylamine
10
<10
X
34433
N-nitrosodiphenylamine
10
<IQ
X`_ .--
34461
Phenanthrene
10
<10`
X
34469
Pyrene
10
<lp
tX
34551
1, 2, 4-Trichlorobenzene
10
<10`
*If different from quantitation target

Compound
Probable
Molecular
Wei ht
Estimated.
Concentration
(ug/L
Library Match
Probability
Retention
Time (RT)
MinMatch
Identification Basis
Check all. that appl,
Scan
Number.
Library
Manual.
Inter retation
RT
1, 1—diethox —butane
146
8
54
5.77
X
X
337
2, 2'—ozobis(2—methyl
ro onenitrile
164
270
74
8.48
X
X
RT
580
Pent aoxa entadecone
222
27
89
15.88
X
X
1242
Unknown
135
10
N/A
16.15
X
1265
t
Complete only if non—targeted compounds are present:
Internal Standard
Retention
Time
Min
1, 4—Dichlorobenzene — d4
8.02
Naphthalene — d8
11.18
Acenaphthene — d10
15.55
*Not all quantitated results can be accompanied by complete ID. Further
investigation should be discussed with your Client Services Representative.
N
N

Sample ID:
951-005-1
D. Organochlorine/Organophosphorus Pesticides and PCB's
Number of chemicals detected in Fraction 0
F
Fraction STORET Number 00188
Page 8 of 9
STORET
Compound
Quantitation Quantitation
Concentration Confirmation?
Number
Confirmation?
Limit Target Limit*
Detected
Dual
Column GC/MS
l.Pollutants to be analyzed for:
(ug/L) (ug/L)
(ug/L)
Yes
No Yes No
Organochlorine Pesticides/PCB's: EPA Methgd 8080
,
39730
2,4-D
39330
Aldrin
0.05
<0.05
x
x
39337
alpha -BHC
0.05 f
<0.05
x
x
39338
Beta -BHC
0.05
<0.05
x
x
34259
Delta -BHC
0.1
<0.1
x
x
39340
Gamma -BHC (Lindane)
0.05
<0.05
x
x
39350
Chlordane
0.2
<0.2
x
x
39310
4,4' -DDD
0.1
<0.1
x
x
39320
4,4' -DDE
0.1
<0.1
x
x
39300
4,4' -DDT
- 0.1
<0.1
x
x
39380
Dieldrin
0.02
<0.02
x
x
34361
Endosulfan I (alpha)
0.1
<0.1
x
x
34356
Endosulfan II (beta)
0.1
<0.1
x
x
34351
Endosulfan sulfate
0.7
<0.7
x
x
39390
Endrin
0.06
<0.06
x
x
34366
Endrin aldehyde
0.2
<0.2
X
x
39410
Heptachlor
0.05
<0.05
X
x
39420
Heptachlor epoxide
0.8
<0.8
x
x
39480
Methoxychlor
0.5
<0.5
x
x
39755
Mirex
0.2
<0.2
x
x
39400
Toxaphene
2.4
<2.4
x
x
34671
PCB 1016
0.5
<0.5
x
x
39488
PCB 1221
0.5
<0.5
x
x
39492
PCB 1232
0.5
<0.5
x
x
39496
PCB 1242
0.5
<0.5
x
x
39500
PCB 1248
0.5
<0.5
x
x
39504
PCB 1254
1.0
<1.0
x
x
39508
PCB 1260
1.0
<1.0
x
x
Organophosphorus Pesticides
EPA Meth8080
39560
Demeton
2.5
<2.5
x
39540
Parathion (ethyl)
0.6
<0.6
x
E. Herbicides, EPA Method 8150
Number of chemicals detected in Fraction 0
Fraction STORET Number 00148
STORET
Compound
Quantitation
Quantitation
Concentration
Confirmation?
Number
Limit Target
Limit*
Detected
Dual Column,
Pollutants to be analyzed
for: (ug/L)
(ug/L)
(ug/t)
Yes No
39730
2,4-D
12
<12
x"
39045
Silvex
2
<2
- x
39740
2,4,5-T
2
<2
x
*If different from quantitation limit target

�C
�-

Pip
- •
O,rganic Analytical Information: Page 9 of 9
Organic Fraction Method GC Operating Conditions Surrogates(Spikes)
Extraction Column Description Compound Recovery
Batch Continuous Length X ID, Film Thickness, $
Column Type, Carrier Gas & Flow
Rate, Temperature Program
Purgeable 8240
75m x 0.53mm,
3.Oum,dB-624
1,2-Dichloro
100
15m1/min. He,
20(5min.)
ethane -d4
6C/min. 150
(2 min.)
Toluene
97
BFB
97
kcid Extractables 8270
X i 30m x 0.32mm,
0.25um, dB -5
2 -Fluoro-
48
He 30 cm/sec,
40(4 min),
phenol -d5
Y IOC/min.,300
(5 min.)
Phenol -d5
33
2,4,6-Tribromo-
93
phenol
3ase/Neutral 8270
K 30m x 0.32mm,
0.25um, dB -5
Nitrobenzene -d5
75
:xtractable
He 30 cm/sec,
40(4 min),
2-Fluorobiphenyl
66
1OC/min.,300
(5 min.)
Terphenyl-d14
70
�urgeable 603 X 30m x 0.53mm, 1.0 um
Stabilwax He 10 ml/min, 40 C (2.9 min.)
20 C/min, 150 C (4 min)
IC/MS Library size (number of reference spectra): Volatiles 42,000+, Semivolatiles 49,000+
1. Metals and Other Chemicals
'umber of chemicals detected in Fraction
Taction STORET Number 78240
TORET Compound Quantitation Quantitation Concentration
umber Limit Target Limit* Detected
ollutants to be analyzed for: (ug/L) (ug/L) (ug/L)
1104 Aluminum 50 260
1097 Antimony 50 <50
1002 Arsenic 10 <10
1012 Beryllium 25 <25
1027 Cadmium 2 <2
1034 Chromium 5 <5
L042 Copper 2 <2
L051 Lead 10 <10
L900 Mercury 0.2 <0.2
L067 Nickel 10 <10
L147 Selenium 5 <5
1077 Silver 5 <5
.092 Zinc 10 80
;her Inorganics:
.007 Barium 500 <500
1940 Chloride 1000 110,000
1720 Cyanide 20 <20
1951 Fluoride 100 76,000
f different from quantitation limit target
alytical Laboratory Representative:
gnedt_ - - L t.u,a X--) - lJ r, Date: 3( Z2.
cilityer �or in Responsible Charge (OCR): �'o k-/,
certify at this/rreport i accurate and complete to the best of my knowledge.
gned: / �L� t_t Date: