DEQp00021111

Page 1 of 9
ANNUAL POLLUTANT ANALYSIS MONITORING REQUIREMENT
Report Form A
(Revised June 1990)
I. Facility Information:
NPDES Permit NO: j%I CO0045 3 Discharge ( Pipe) No: eo l year: 1 g -1Z
Facility"Name: B,)Pp_0r- pj4.Y [ala*s: County: :ZL4P5J
7
Person(s) Collecting Samples: WAjeAr,J 'PA f i4gL-
Status of facility wastewater treatment operation on day of sampling:
typical:_ c� Yes No
If no, explain briefly:
Analytical Laboratory: Industrial and Environmental Analysts, Inc.
II. Sampling:
24 hr composite for main sample/grab sample for purgeable fraction
Date Sampled: (composite sample) Corresponding sample taken for toxicity testing:
Sampling begun (date, time): Z-1qh 2 _,) Yes
Sampling finished Adate, time): Zj57b- z No
Date and time sampled (grab sample):
Sample I.D.: 951-022-1 (Pipe 001)
Field Parameters: pH 7.05
Temperature.18.6 Degrees C
Rr %, a 'V' 12
MAR i 8
199'
CENTRAL FIZZ' Copy

Sample ID: 951-022-1 (Pipe 001)
A. Purgeable (Volatile Organic) Fraction, EPA Method 8240 Page 2 of 9
Number of chemicals detected in Fraction 1
Fraction STORET Number.84085
STORET Compound Quantitation Quantitation Concentration GC/MS
Number Limit Target �1 Limit* Detected Confirmation?
Pollutants to be analyzed for: (ug/L) } (ug/L) (ug/L) Yes No
34210 Acrolein 100 <100 x
34215 Acrylonitrile 100 <100 x
34030 Benzene 5 <5 x
32101 Bromodichloromethane 5 <5 x
32104 Bromoform 5 <5 x
34413 Bromomethane 10 <10 X
32102 Carbon tetrachloride 5 <5 x
34301 Chlorobenzene 6 <6 x
34311 Chloroethane 10 <10 x
34576 2-Chloroethyl vinyl ether 10 <10 x
32106 Chloroform 5 <5 x
34418 Chloromethane 10 <10 x
32105 Dibromochloromethane 5 <5 x
34496 1,1-Dichloroethane 5 <5 x
34531 1,2-Dichloroethane 5 <5 x
34501 1,1-Dichloroethylene 5 <5 x
34546 trans--1,2-bichloroethylene 5 <5 x
34541 1,2-Dichloropropane 6 <6 x
34704 cis-1,3-Dichloropropane 5 <5 x
34699 trans-1,3-Dichloropropene 5 <5 x
34371 Ethylbenzene 8 <8 x
34423 Methylene chloride 5 <5 x
34516 1,1,2,2 -Tetrachloroethane 7 <7 x
34475 Tetrachloroethylene 5 <5 x
34010 Toluene 6 <6 x
34506 1,1,1 -Trichloroethane 5 <5 x
34511 1,1,2 -Trichloroethane 5 <5 x
39180 Trichloroethylene 5 <5 x
34488 Trichlorofluoromethane 10 <10 x
39175 Vinyl chloride 10 <10 x
*If different from quantitation limit target
AW 9,
149P
CENTRAL FILE Copy

Probable _stimated Library Match
compound Molecular Concentration Probability
Wei ht u L a
Identification Basis
Retention ' Check all that oppl,o
Time (RT j ; Library Manual
Min i Match Interpretation RT
Scan
Number
Difluorcdimeth I Silone 96 16 91
2.39
X
141
---------------------
Complete only if non—targeted compounds are present:
Retention
Int=�rnol Standard Time
Min
Bromochlorom ethane 8.68
cn O
n
3 m
m -D
— c
o�
ca
CD
Q
o -
m
w
LEC

Sample I.D.: 951-022-1 (Pipe 001)
B. Acid Extractable Fraction, EPA Method 8270` Page 4 of 9
Number of chemicals detected in Fraction 0
Fraction STORET Number 45582
STORET Compound Quantitation Quantitation Concentration GC/MS
Number Limit Target- Limit* Dptected Confirmation?
je
Pollutants to be analyzed for: (ug/L), (ug/L) (ug/L) Yes No
ti
34452
4-Chloro-3-methylphenol
10
<10 X
34586
2 -Chlorophenol
10
<10 X
34601
2,4-Dichlorophenol
10
<10 X
34606
2,4 -Dimethylphenol
10
<10 X
34616
2,4-Dinitrophenol
50
<50 X
34657
2-Methyl-4,6-dinitrophenol
50
<50 X
34591
2-Nitrophenol
10
<10 X
34646
4-Nitrophenol
50
<50 X
39032
Pentachlorophenol
50
<50 X
34694
Phenol
10
<10 X
34621
2,4,6 -Trichlorophenol
10
<10 X
*If different from quantitation limit target
t
BAR 19
J Y�
CENTRAL FILE COPY

Compound
Probable Estimated
Molecular Concentration
Weight u L
Library Match
Probability
Retention
Time (RT)
Min
Identification Basis
Check all that apply)
Scan
Number
Library
Match
Manual
Interpretation
RT
None Detected
Complete c ily if non—targeted compounds are present:
TM

L
sample I.D.: 951-022-1 (Pipe 001)
C. Base/Neutral Fraction, EPA Method 8270 Page 6 of 9
Number of chemicals detected in Fraction 10
Fraction STORET Number 45583
STORET Commpound
Quantitation
Quantitation Concentration
GC/MS
Number
Limit Target
Limit* Detected
Confirmation?
Pollutants to be analyzed for:
(ug/L)
(ug/L) (ug/L)
Yes No
34205
Acenaphthene
10
<10
`<10
34200
Acenaphthylene
10
34220
Anthracene
10
<10
39120
Benzidine
50 }
<50
34526
Benzo (a) anthracene
10
<10
34247
Benzo (a) pyrene
10
<10
34230
Benzo (b) fluoranthene
10
<10
34521
Benzo (ghi.) perylene
10
<10
34242
Benzo (k) fluoranthene
10
<10
34278
Bis (2-chloroethoxy)methane
10
<10
34273
Bis(2-chloroethyl)ether
10
<10
34283
Bis(2-chloroisopropyl)ether,
10
<10
39100
Bis(2--ethyihexyl)phthalate
10
<10
34636
4-Bromophenyl phenyl ether
10
<10
34292
Butyl benzyl phthalate
10
<10
34581
2-Chloronaphthalene
10
<10
34641
4-Chlor6phenyl phenyl ether
10
<10
34320
Chrysene.
10
<10
34556
Dibenzo(a,h) anthracene
10
<10
34536
1,2 -Dichlorobenzene
10
<10
34566
1,3 -Dichlorobenzene
10
<10
34571
1,4 -Dichlorobenzene
10
<10
34631
3,3-Dichlorobenzidine
20
<20
34336
Diethyl phthalate
10
<10
34341
Dimethyl phthalate
10
<10
39110
Di -n -butyl phthalate
10
<10
34611
2,4-Dinitrotoluene
10
<10
34626
2,6-Dinotrotoluene
10
<10
34596
Di-n-octyl phthalate
10
<10
34346
1,2-Diphenylhydrazine
10
<10
34376
Fluoranthene
10
<10
34381
Fluorene
<10
39700
Hexachlorobenzene
!10
10
<10
34391
Hexachlorobutadiene
10
<10
34386
Hexachlorocyclopentadiene
10
<10
34396
Hexachloroethane
10
<10
34403
Indeno(1,2,3-cd)pyrene
10
<10
34408
Isophorone
10
<10
34696
Naphthalene
10
<10
34447
Nitrobenzene
10
<10
34438
N-nitrosodimethylamine
10
<10
34428
N-nitroso-di-n-propylamine
10
<10
34433
N-nitrosodiphenylamine
10
<10
34461
Phenanthrene
10
<10
34469
Pyrene
10
<10
34551
1,2,4-Trichlorobenzene
10
<10
*If
different from quantitation target
x
c 'A2?V S%
X p(AR X 9 I
x 19y�
CENTRAL FILE copy

s
Probable Estimated
Compound Molecular Concentration
Wei ht (ug/L
V
Library Match Retention
Probability Time (RT)
% Min
Identification Basis
Check all that apply)
Scan
Number
Library Manual
Match Inter retotion
RT
Unknown 5
7.37
Phenonthr ene—d 10
2 0.2 2
480
Sulfonylbis—Methane 640
84.9 8.23
X
558
Unknown 160
8.92
618
Unkncwn 160
9.30
653
Unkncwn 59
13.47
1026
Unkncwn Acetamide 4
15.82
1235
Unknown 6
16.83
1327
Unkncwn 7
18.03
1433
Unkncwn Hydrocarbon 28
19.15
1533
Unkncwn 5
20.30
1636
Complete only if non—torgeted compounds are present:
F—
Internal Standard
Retention
Time
Min
1, 4—Dick orobenzene—d4
8.98
Naphthol ie—d8
12.10
Acena htF:ene—d10
16-.50
Phenonthr ene—d 10
2 0.2 2
C sene--d12
26.88
Per lene—J12
30.22
R
e
N C
I �
0
m
0
Y
0
cn
m
V
O
Me

Sample ID: 951-022-1 (Pipe 001) Page 8 of 9
D. organochlorine/Organophosphorus Pesticides and PCB's
Number of chemicals detected in Fraction 0
Fraction STORET Number 00188
STORET
Compound
Quantitation Quantitation Concentration Confirmation?
Number
Limit Target Limit*
Detected
Dual
Column GC/MS
1.Pollutants to be analyzed for: (ug/L) (ug/L)
(ug/L)
Yes
No Yes No
Organochlorine Pesticides/PCB's: EPA Metho4 8080
39330
Aldrin
0.05
<0.05
x
x
39337
alpha -BHC
0.05 `
<0.05
x
x
39338
Beta -BHC
0.05
<0.05
x
x
34259
Delta -BHC
0.1
<0.1
x
x
39340
Gamma -BHC (Lindane)
0.05
<0.05
x
x
39350
Chlordane
0.2
<0.2
x
x
39310
4,4' -DDD
0.1
<0.1
x
x
39320
4,4' -DDE
0.1
<0.1
x
x
39300
4,4' -DDT
0.1
<0.1
x
x
39380
Dieldrin
0.02
<0.02
x
x
34361
Endosulfan I (alpha.)
0.1
<0.1
x
x
34356
Endosulfan II (beta)
0.1
<0.1
x
x
34351
Endosulfan-sulfate
0.7
<0.7
x
x
39390
Endrin
0.06
<0.06
x
x
34366
Endrin aldehyde
0.2
<0.2
x
x
39410
Heptachlor
0.05
<0.05
x
x
39420
Heptachlor epoxide
0.8
<0.8
x
x
39480
Methoxychlor
0.5
<0.5
x
x
39755
Mirex
0.2
<0.2
x
x
39400
Toxaphene
2.4
<2.4
x
x
34671
PCB 1016
0.5
<0.5
x
x
39488
PCB 1221
0.5
<0.5
x
x
39492
PCB 1232
0.5
<0.5
X
X
39496
PCB 1242
0.5
<0.5
x
x
39500
PCB 1248
0.5
<0.5
x
x
39504
PCB 1254
1.0
<1.0
x
x
39508
PCB 1260
1.0
<1.0
x
x
Organophosphorus Pesticides
EPA Method 8080
39560
Demeton
2.5
<2.5
x
x
39540
Parathion (ethyl)
0.6
<0.6
x
x
E. Herbicides, EPA Method 8150
Number of chemicals detected in Fraction 0
Fraction STORET Number 00148
STORET Compound Quantitation Quantitation Concentration Confirmation?
Number Limit Target Limit* Detected Dual Column
Pollutants to be analyzed for: (ug/L) (ug/L) (ug/L) Ynn
39730 2,4-D 12 <12 X
39045 Silvex 2 <2 X �AR j 9 199
39740 2,4,5-T 2
*If different from quantitation limit target C&NT
R,qL FILE COPT

M,4,(, 1

rganic Analytical Information:
rganic Fraction Method
urgeables 8240
951-022-1 (Pipe 001)
GC operating Conditions
Extraction Column Description
Batch Continuous Length X ID, Film Thickness,
Column Type, Carrier Gas & Flow
Rate, Temperature Program
cid Extractable 8270 X
ise Neutral Extractable 8270
X
Page 9 of 9
Surrogates (Spikes)
Compound Recovery
DB624, 75m x .53 ID x 3um He 10ml 1,2-Dichloroethane-d
(min) 35deg C (5min) to 155 Toluene -d8
Deg C 0 (min)at 6Deg C (min) p-Bromofluorobenzene
si
30m x 0.32mm, 0.5um, DB -5, 625 Phenol -d5
v He 30cm/sec, 40Deg C (4 min) 2-Fluorophenol
:/MS Library size (number of reference spectra): 55,000
300 Deg C, 10 Degree C /min 2,4,6-Tribromophenol
30m x 0.32mm, 0.5um, DB -5, 625 Nitrobenzene -d5
He 30cm/sec, 40Deg C (4 min) 2-Fluorobiphenyl
300 Deg C, 10 (min) Terpenyl-d14
Metals and Other Chemicals
tuber of Metals and Other Chemicals(as listed above) detected in Sample 7
action STORET Number 78240
ORET Compound Quantitation Quantitation Concentration
mber Limit Target Limit* Detected
llutants to be analyzed for (ug/L) (ug/L) (ug/L)
104 Aluminum
50
750
D97 Antimony
50
<50
D02 Arsenic
10
<10
)12 Beryllium
25
<25
D27 Cadmium
2
<2.0
334 Chromium
5
5.6
)42 Copper
2
4.0
)51 Lead
10
<10
)00 Mercury
0.2
<0.2
)67 Nickel
10
10.,
.47 Selenium
5
<5.0
)77 Silver
5
<5.0
192 Zinc
10
58,
8•ier
ierInorganics:
107 Barium
500
<500
40 Chloride
1000
46,000
20 Cyanide
20
<10
51 Fluoride
100
160;000 -
different from
quantitation limit target
lyticall LaaboratoRepresentative:
ned:
Date:
ility Operator in Responsible Charge (OCR):
ertify that this report is accurate and complete to the best of my knowledge.
ned: Date:
J
194?
(-`'vTRIC FILE Copy
102
100
101
45
44
70
55
51
33