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13
EA
An Aquarion Company
Page I of 9
ANNUAL POLLUTANT ANALYSIS MONITORING REQUIREMENT
Report Form A
(Revised June 1990)
I. Facility Information:
NPDES Permit No: dr- 0002573 Discharge (Pipe) No: Qa f Year: 9,93
Facility Name: i0fap'Ji Class: County:
I
Person (s) Collecting Samples: t& K 1.5 Ot/-r L_ +
Status of facility wastewater treatment operation on day of sampling:
typical: Yes No
If no, explain briefly:
Analytical Laboratory: -Industrial and Environmental Analysts, Inc.
II. sampling:
24 hr composite for main sample/grab sample for purgeable fraction
Date sampled: (composite sample) Corresponding sample taken for toxicity testing:
Sampling begun (date, time): Yes
Sampling finished (date, time): No
Date and time sampled (grab sample):
pH: 7.02
Temperature: 21 Degrees C
W
CU
GJ
Lo
71
W
IEA
An Aquarion Company
,mple ID: 1176-483-1 (Pipe 001)
. Purgeable (Volatile Organic) Fraction, EPA Method 603**/624
umber of chemicals detected in Fraction 0
:action STORET Number 84085
20RET
Compound Quantitation
Quantitation
amber
Limit
Target
Limit*
ollutants to be analyzed for: (ug/L)
(ug/L)
4210
Acrolein**-
100
5
4215
Acrylonitrile**
100
5
4030
Benzene
5
2101
Bromodichloromethane
5
2104
Bromoform
5
4413
Bromomethane
10
2102
Carbon tetrachloride
5
4301
Chlorobenzene
6
:4311.
Chloroethane
10
;4576
2-Chloroethyl vinyl ether
10
12106
Chloroform
5
34418
Chloromethane
10
32105
Dibromochloromethane
5
34496
1,1-Dichloroethane
5
34531
1,2-Dichloroethan.e
5
34501
1,1-Dichloroethylene
5
34546
trans-1,2-Dichloroethylene 5
34541
1,2-Dichloropropane
6
34704:
cis-1,3-Dichloropropane
5
34699'.
trans-1,3-Dichloropropene
5
34371
Ethylbenzene
8
34423
Methylene chloride
5,
34516
1,1,2,2 -Tetrachloroethane
7
34475
Tetrachloroethylene
5
34010
Toluene
6
34506
1,1,1 -Trichloroethane
5
34511=
1,1,2 -Trichloroethane
5
39180
Trichloroethylene
5
34488
Trichlorofluoromethane
10
39175
Vinyl chloride
10
I)v
*if
different from quantitation
limit target
4
Page 2 of 9
Concentration
Detected
(ug/L)
<5
<5
<5
<5
<5
<10
<5
<6
<10
<10
<5
<10
<5
<5
<5
<5
<5
<6
<5
<5
<8
<5
<7
<5
<6
<5
<5
<5 '
<10
<10
GC/MS
Confirmation?
Yes No
• x ,
1EA
An Aquarion Company
Sample I.D.: 1176-483-1 (Pipe 001)-
B. Acid Extractable Fraction, EPA Method 625
Number of chemicals detected in Fraction 10
Fraction STORET Number 45582
STORET
Compound Quantitation Quantitation
Number
Limit
Target Limit*
?ollutants to be analyzed for:
(ug/L) (ug/L)
34452
4-Chloro-3-methylphenol
10
34586
2 -Chlorophenol
10
34601
2,4-Dichlorophenol
10
34606
2,4 -Dimethylphenol
.10
34616
2,4-Dinitrophenol
50
34657
2-Methyl-4,6-dinitrophenol
50
34591
2-Nitrophenol
.10
34646
4-Nitrophenol
50
39032
Pentachlorophenol
50
34694
Phenol
10
34621
2,4,6 -Trichlorophenol
10
*If different from quantitation limit target
r
Page 4 of 9
Concentration GC/MS
Detected Confirmation?
(ug/L) Yes No
<10 X
<10 X
<10 X
<10 X
<50 X
<50 X
<10 X
<50 X
<50 X
<10 X
<10 X
m
n
v
CIO
r
rn
Compound
rrooaoie
Molecular
Wei ht
tsnmaieo
Concentration
u L
unrur y Muicn
Probability
%
Rclty oii
Time (RT)
Min
U;, ,,,U,
Aceno hthene—d10
Scan
Number
Library
Match
Manual
Interpretation
IRT
Unknown
Per lene—d 12
67
13.72
1066
Unknown
4
14.44
1 140
Unknown
7
17.36
1436
4—(2, 2, 4—trimethyl—
ent I)phenol
10
18.47
1549
Unknown
4
20.84
1790
Unknown
15
22.15
1923
Hexodeconoic acid
9
22.31
1940
Unknown
5
23.65
2075
Substituted Hexodece—
noic acid
6
25.56
2269
Unknown
5
29.62
2681
z
Complete only if non—targeted compounds ,are present:
Internal Standard
Retention
Time
Min
1, 4—Dichlorobenzene—d4
9.39
No htholene—d8
12.49
Aceno hthene—d10
17.00
Phenanthrene—d 10
20.75
Chr sene—d 12
2 7.6 0
Per lene—d 12
31.38
CO-
CD
x
V n
c p
I �
�M
CO N
W
-r
CD o
C) ::I-_
o�
CD
to
.D
CD
❑
X-
-0
c❑
CD
CP
0
1EA
An Aquarion Company
Sample I.D.: 1176-483-1 (Pipe 001)
C. Base/Neutral Fraction, EPA Method 625 Page 6 of 9
Number of chemicals detected in Fraction 10
Fraction STORET Number 45583
STORET
Commpound Quantitation
Quantitation
Concentration
GC/MS
Number
Limit
Target
Limit*
Detected
Confirmation?
Pollutants to be analyzed for:
(ug/L)
(ug/L)
(ug/L)
Yes
No
34205
Acenaphthene
10
<10
X
34200
Acenaphthylene
10
<10
X
34220
Anthracene
10
<10
X
39120
Benzidine
50
<50
X
34526
Benzo (a) anthracene
10
<10
X
34247
Benzo (a) pyrene
10
<10
X
34230
Benzo (b) fluoranthene
10
<10
X
34521
Benzo (ghi) perylene
10
<10
X
34242
Benzo (k) fluoranthene
10
<10
X
34278
Bis (2-chloroethoxy)methane
10 _
<10
X
34273
Bis(2-chloroethyl)ether
10
<10
X
34283
Bis(2-chloroisopropyl)ether
10
<10
X
39100
Bis(2-ethylhexyl)phthalate
10
<10
X
34636
4-Bromophenyl phenyl ether
10
<10
X
34292
Butyl.benzyl phthalate
10
<10
X
34581
2-Chloronaphthalene
10
<10
X
34641
4-Chlorophenyl phenyl ether
10
<10
X
34320
Chrysene
10
<10
X
34556
Dibenzo(a,h) anthracene
10
<10
X
34536
1,2 -Dichlorobenzene
10
<10
X
34566
1,3 -Dichlorobenzene
10
<10
X
34571
1,4 -Dichlorobenzene
10
<10
X
34631
3,3-Dichlorobenzidine
20
<20
X
34336
Diethyl phthalate
10
<10
X
34341
Dimethyl phthalate
10
<10
X
39110
Di -n -butyl phthalate
10
<10
X
34611
2,4-Dinitrotoluene
10
<10
X
34626
2,6-Dinotrotoluene
10
<10
X
�7
34596
Di-n-octyl phthalate
10
<10
X
CO
34346
1,2-Diphenylhydrazine
10
<10
X
34376
Fluoranthene
10
_.
34381
Fluorene
10
<10
X
39700
Hexachlorobenzene
10
<10
X
W P-
34391
34391
Hexachlorobutadiene
10
<10
X
34386
Hexachlorocyclopentadiene
10
"
<10
X
clan
34396
Hexachloroethane
10
<10
X
34403
Indeno(1,2,3-cd)pyrene
10
<10
X
34408
Isophorone
10
<10
X
34696
Naphthalene
10
<10
X
34447
Nitrobenzene
10
<10
X
34438
N-nitrosodimethylamine
10
<10
X
14428
N-nitroso-di-n-propylamine
10
<10
X
14433
N-nitrosodiphenylamine
10
<10
X
14461
Phenanthrene
10
<10
X
14469
Pyrene
10
<10
X
14551
1,2,4-Trichlorobenzene
10
<10
X
*If different from quantitation target
Compound
1, 1'—oxy1bis[2—methoxy—],
ethane
Unknown
Unknown
Unknown
1, 2—Benzisoxazole
Unknown
Unknown . lkone
Unknown
Unknown
rr uuuuie
Molecular
Weight
134
C,IIrrIUIeU
Concentration
u L
10
60
6
6
5
5
4
4
9
uDr Ur y nnUlL;n
Probability
56
rcerenrrUrr
Time (RT)
(Min)
8,20
9.78
11.52
16.31
16.78
17.52
20.62
21.92
23.81
12.49
necK all inar a I
17.00
20.75
Scan
Number
Library
Match
Manual
Interpretation
RT
505
666
843
V 0
m
1330
oo
1377
oo C
CA
1453
0 0
1767
1899
Unknown Alkane
oCD
8
24.15
CD
❑
v
2091
2126
y
Complete only if non—targeted compounds are present:
Internal Standard
Retention
Time
Min
1, 4—dichlorobenzene—d4
9,39
ala htholene—d8
12.49
Ac na hthene—d 10
Phenanthrene—d 10
17.00
20.75
Chr Bene—d 12
2 7.6 0
Per lene—d12
31.38
531t'd `tV�r.LP433 A8 002u
N
cn 0
❑
y
CD
—❑
� N
n
CD
V 0
m
oo
oo C
CA
�o
0 0
CD
c❑'
C)
oCD
CD
❑
v
Q
CD
.r
0
r
IEA
An Aquarion Company
Sample ID: 1176-483-1 (Pipe 001)
Page 8
of 9L'..
D. Organochlorine/Organophosphorus Pesticides and PCB's
jr)
Number of chemicals detected in Fraction -0
Fraction STORET Number 00188
STORET Compound Quantitation- Quantitation
Concentration Confirmation?
Number Limit Target Limit*
Detected
Dual Column GC/MS
I.Pollutants to be analyzed for:
(ug/L) (ug/L)
(ug/L)
Yes
No Yes No
Organochlorine Pesticides/PCB's:
EPA Method 8080
39330 Aldrin
0.05
<0.05
x
x
39337 alpha -BHC
0.05
<0.05
x
x
39338 Beta -BHC
0.05
<0.05
x
x
34259 Delta -BHC
0.1
<0.1
x
x
39340 Gamma -BHC (Lindane)
0.05
<0.05
x
x
39350 Chlordane
0.2
<0.2
x
x
39310 4,41 -DDD
0.1
<0.1
x
x
'39320 4,41 -DDE
0.1
<0.1
x
x
39300 4,41 -DDT
0.1
<0.1
x
x
39380 Dieldrin
0.02
<0.02
x
x
34361 Endosulfan I (alpha)
0.1
<0.1
x
x
34356 Endosulfan II (beta)
0.1
<0.1
x
x
34351 Endosulfan sulfate
0.7
<0.7
x
x
39390 Endrin
0.06
<0.06
x
x
34366 Endrin aldehyde
0.2
<0.2
x
x
39410 Heptachlor-
0.05
<0.05
x
x
39420 Heptachlor epoxide
0.8
<0.8
x
x
39480 Methoxychlor
0.5
<0.5
x
x
39755 Mirex -
0.2
<0.2
x
x
39400 Toxaphene
2.4
<2.4
x
x
34671 PCB 1016
0.5
<0.5
x
x
39488 PCB 1221
0.5
<0.5
x
x
39492 PCB 1232
0.5
<0.5
X
x
39496 PCB 1242
0.5
<0.5
x
39500 PCB 1248
0.5
1.0
<0.5
<1A,
x
x
Ox
0
x
39504 PCB 1254
39508 PCB 1260
1.0
<1.0
x
--r w
X
Organophosphorus Pesticides EPA
Method 8140
39560 Demeton
2.5
<2.5
x x
39540 Parathion (ethyl)
0.6
<0.6
x x
E. Herbicides, EPA Method 8150
Number of chemicals detected in Fraction 0
Fraction STORET Number 00148
STORET Compound Quantitation Quantitation
Concentration
Confirmation?
Number Limit Target Lifhit*
Detected
Dual Column
Pollutants to be analyzed for:
(ug/L) (ug/L)
(ug/L)
Yes No
39730 2,4-D
12
<12
x
39045 Silvex
2
<2
x
39740 2,4,5-T
2
<2
x
*If different from quantitation
limit target
1�]E
An Aquarion Company
ID: 1176-483-1 (Pipe 001)
_c Analytical Information:
_c Fraction Method
able
able
3xtractable
GC Operating Conditions
Extraction Column Description
Batch Continuous Length X ID, Film Thickness,
Column Type, Carrier Gas & Flow
Rate, Temperature Program
Page 9 of 9
Surrogates (Spikes)
Compound Recovery
603 30mx0.53mm,1.0um df
Stabilwax,He 40mis/mn. 45 deg.0 N/A
(2 min), 100 deg.0 @ 7 deg/min
(.1 min) 180 deg.0 @ 20 deg/min.
624 DB -624, 75mx0.53 IDx3u 1,2 -DCH -d4
He - 10ml/min, 35 deg.0-5 min to Tol-d8
155 deg.0-0 min at 6 deg.0/min BFB
625
Le:Acid Extractable 625
X 30mx0.32mm, 0.5um, DB -5, 625, Phenol -d5
He, 30 cm/sec, 40•deg.0 (4 min)- 2-Fluorophenol
300 deg.C, 10 deg/min. 2,4,6-Tribromo-
phenol
X 30x x 0.25mm,0.25um,DB-5 d5 -phenol'
He,30cm/sec, 40C (4min)-
270C, 10/min
Library size (number of reference spectra): 55,000+
etals and other Chemicals
r of Metals and other Chemicals(as listed above) detected in Sample: 6
ion STORET Number 78240
T Compound Quantitation Quantitation Concentration
r Limit Target Limit* Detected
tants to be analyzed for (ug/L) (ug/L) (ug/L)
Aluminum 50
Antimony 50
Arsenic 10
Beryllium 25
Cadmium 2
Chromium 5
Copper 2
Lead 10
Mercury 0.2
Nickel 10
Selenium 5
Silver 5
Zinc 10
Inorganics:
Barium 500
Chloride 1000
Cyanide 20
Fluoride 100
ifferent from quantitation limit target
930 '
<50
<10
Pj
<25
0
C1
<2
O
5
5
r7
<10
--
<0.2
A
<10
w
f--
<5
r
'k <5
u3
100 ---
<500
66,000
10 <10
14,000
tical Laboratory Representative:
is��f i� CG- �9EYi Date:
ity Operator in Responsible Charge (OCR):
tify that this r ort J s accurate and complete to the best of my knowledge.
3: �a /moi x,,, , Date: 5 —,?,5— 92_.
N/A
106
106
104
78
60
70
50
IEA
An Aquarion Company
ID: 1176-483-1 (Pipe 001)
.c Analytical Information: Page 9a of 9
c Fraction
Method
GC Operating Conditions
Surrogates (Spikes)
Extraction
Column Description
Compound
Recovery
Batch Continuous
Length X ID, Film Thickness,
%
Column Type, Carrier Gas & Flow
Rate, Temperature Program
eutral
625 X
30mxO.32mm, 0.5um, DB -5, 625,
Nitrobenzene -d5
97
table
He, 30 cm/sec, 40 deg.0 (4 min)-
2-Fluorobiphenyl
80
300 deg.C, 10 deg/min.
Terphenyl-dl4
25
chlorine
8080 X
30m x 0.53mm, 1.0um, DB -1701
TCX
80
ides
30m x 0.53mm, 1.0um, RTX -35
DCB
460
He,4ul/mn,150degC(3min.)-220degC
4deg/mn, 270degC(18min),6deg/min.
phosphorus
8140 X
30m x 0.53mm, 1.0um, DB -1701
N/A
N/A
Wes
He, 50ml/min, 180degC(10 min)-
220degC(5 min), 10/min
Wes
8150 %
30m x 0.53mm, 1.0um, RTX -35
2,4 -DB
90
30m x 0.53mm, 1.0um, DB -1701
He, 5.0ml/min, 180degC(10 min)-
220degC(5 min), 10/min
a:Acid Extractable
625 X
30x 0.25mm,0.25um,DB-5
d5 -phenol
50
He,30cm/sec, 40C (4min)-
270C, 10/min
Library size (number
of reference spectia): 55,000+
a