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HomeMy WebLinkAboutDEQp000209007 ftft NORTH CAROLINA DEPT. OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES ENVIRONMENTAL MANAGEMENT COMMISSION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER ' STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTION I. APPLICATION AND FACILITY DESCRIPTION ' Unless otherwise specified on this form all Mems are to be completed. It an Item Is not applicable Indicate 'NA'. ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET BEFORE FILLING OUT THESE ITEMS. Please Print or Type `�Z�L�► ,���� 1. Legal Name of Applicant 101 E. I. DUPONT DE NEMOURS & CO., INC. tJC V-0� (FAYETTEVILLE WORKS see instructions) o0 2 Mailing Address of Applicant (see Instructions) Number & Street 102a P. 0. DRAWER Z City 102b FAYETTEVILLE ' State 102c NC Zip Code 1024 919102 3, Applicant's Authorized Agent (see Instructions) Name and Title 103a Michael E. Johnson Environmental Coordinator ' Number& Street 103b A 0 l)rawPr 7 ' City 103c Fayetteville State 1034 N( Zip Code 1039 28302 ' Telephone 1031 910 678-1155 Area Number 4. Previous Application code If a previous application for a pennR under the National Pollutant Discharge Elimination System has been made, give the date of application. 104 90 11 28 YR MO DAY ' I certify that I am familiar with the information contained in this application and that to the best of my knowledge and belief such information is true, complete, and accurate. ' Michael E. Mayb`err 102e Plant Manager Printed me of o Signing This 1021 ' Signature o Appl n1-72115-6 orized Agent YR MO DAY Date Application Signed North Carolina General Statue (b)(2) ides that Any person who knowingly makes any false statement representation, or certification in any ' application, record, report, plan, or other document or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowIngly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed $10,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provides a punishment by a fine or not more than $10,000 or imprisonment not more than 5 years, or both, for a similar offense.) 11 u 5. Facility (see instructions) Give the name, ownership, and physical location of the plant or other operating facility where discharge(s) presently occurs) or will occur. Name Ownership (Public, Private or both Public and Private) Check block if a Federal facility and give GSA Inventory Control Number Location: Number & Street City County State 6. Nature of Business State the nature of the business conducted at the plant or operating facility. 7. Facility Intake Water (see instructions) Indicate water intake volume per day by sources. Estimate average volume per day in thousand gallons per day. Municipal or private water system Surface water Groundwater Other" Total Item 7 ° If there is intake water from 'other, specify th@ source. 8. Facility Water Use Estimate average volume per day in thousand gallons per day for the following types of water usage at the facility. (See instructions) Noncontact cooling water Baler feed water Process water (including contact cooling water) Sanitary water Other Total Item 8 ° If there are discharges to 'other', specify If there is 'Sanityrywater use, give the number of people served. rT47NT 105b 105c 1054 105e 105f 105g 105h 106a •.. 107a 107b 107c 107d 107e 107f 108a 106b 108c 1084 108e 106f 108g 108h E. I. DUPONT DE NEMOURS & CO., INC. FAYETTEVILLE WORKS pUB :5PRV [] BPP n FED State Highway 87 South Duart Bladen North Carolina Plastic Sheeting Film, and Resins;__ Industrial Orizanic Chemical Manufacturing AGENCY USE 171 0 thousand gallons per day 15 . 100 thousand gallons per day 6 thousand gallons per day thousand gallons per day 15 , 10 6 thousand gallons per day 13,483 thousand gallons per day 730 thousand gallons per day 837 thousand gallons per day '70 A thousand gallons per day 50 thousand gallons per day 15.106 thousand gallons per day River Water Treatment Backwash & Sediment 738 people served f t 9, All Facility Discharges and other Losses. Number and Discharge (See instructions)Volume Specify the number of discharge points and the volume of water discharged or lost from the facility according b the ' categories below. Estimate average volume per day in thousand gallons per day Number of Discharge Points C I= 11 Total Volume Discharged, Million Gallons Per Day Surface Water 109al �— 1094 Sanitary wastewater transport systen 109b1 1 1091:2 0.006 (inc. in 109a2) Storm water transport system 109cl _2_ 10902 0.052 (inc. in 109a2) Combined sanitary and storm water 109d1 109d2 transport system Surface impoundment with no 10981 10962 effluent Underground percolation 109fl 109f2 Well injection 109g1 109g2 Waste acceptance firm 109h1 109h2 Evaporation 1090 10912 0.293 Consumption 109j 1 109)2 Other 109k1 10912 Facility dischargers and volume 10911 10912 15.168 Total Item 9 'If there are discharges to'other', 109ml specify. Permits, Licenses and Applications 10 List all existing, pending or denied permits, licenses and applications related to discharges from this facility (see Issuing For Type of Permit or DateDate Filed Issued Date Denied Expiration Date Agency Agency Use license ID Number YR/MO/DA YR/MO/DA YR/MO/DA YR/MO/DA 11. Maps and Drawings Attach all required maps and drawings to the back of this application. (see instructions) 12. Additional Information instructions) u n 0 0 I I 0 FOR AUF-N(-;Y Lititz STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTION II. BASIC DISCHARGE DESCRIPTION Complete this section for each discharge indicated in Section which the waste water does not go through a treatment works also discharges to surface waters from this facility. SEPARAI ORIGINATE IN THE SAME FACILITY. All values for an existi discharge, values should reflect best engineering estimates. ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS, BEFORE FILLING OUT THESE ITEMS. 1. Discharge Serial No. and Name a Discharge Serial No. 201a (see instructions) b. Discharge Name 271b Give the name of discharge, if any (see instructions) c. Previous Discharge Serial No 201c If aprevious permit application was made for this dis charge (Item 4, Section 1) provide previous discharge serial number. 2. Discharge Operating Dates a Discharge Began Date 202a If the discharge described below is in operation, give the date (within best estimate) the discharge began b. Discharge to Begin Date 2025 If the discharge has never occurred but is planned for some future date, give the date the discharge will begin. c. Discharge to End Date if the 202c discharge is scheduled to be discontinued within the next 5 years, give the date (within best estimate) the rischarge will and. 3. Engineering Report Available Check if an engineering report is available to reviewing agency upon request (see instructions) 203 4. Discharge Location Name the political boundaries within which the point of discharge is located: I, Items 9, that Is to surface waters. This includes discharges to municipal sewerage systems in prior to being discharged to surface waters. Discharges to wells must be deacnbed where there are E DESCRIPTIONS OF EACH DISCHARGE ARE REQUIRED EVEN IF SEVERAL DISCHARGES ng discharge should be representattve of "twelve previous months of operation. K this is a proposed kPPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET .001_— Treated Process Wastewater and Process Stormwater 001 71 02 N/A YR MO SYR MO en Use North Carolina toad _ Bladen 2D4e Duar t 204f p5a I �XSTR LKE OCE MTS MCS State County ' (If applicable) City or Town Discharge Point Description (see instructions) Discharge into (check one) Stream (Includes ditches, arroyos, and other watercourse$ Lake Ocean Municipal Sanitary Wastewater Transport System ' Municipal Combined Sanitary and Stone Transport System I, Items 9, that Is to surface waters. This includes discharges to municipal sewerage systems in prior to being discharged to surface waters. Discharges to wells must be deacnbed where there are E DESCRIPTIONS OF EACH DISCHARGE ARE REQUIRED EVEN IF SEVERAL DISCHARGES ng discharge should be representattve of "twelve previous months of operation. K this is a proposed kPPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET .001_— Treated Process Wastewater and Process Stormwater 001 71 02 N/A YR MO SYR MO en Use North Carolina toad _ Bladen 2D4e Duar t 204f p5a I �XSTR LKE OCE MTS MCS 70FI-AGENCY Ut ' Municipal Storm Water Transport System ' Well (injection) Other If 'other' is checked, specify type ' 6. Discharge Point - Lat/Long. Give the precise location of the point of discharge to the nearest second. Latitude ' Longitude 7. Discharge Receiving Water Name Name the waterway at the point of discharge. (see instructions) ' If the discharge is through an outfall that extends beyond the shoreline or is below the mean low water line, complete item 8, 'vac, M-7 Suo For Aae^cv Use 8. Offshore Discharge a. Discharge Distance from Shore ' b. Discharge Depth Below Water 9 Discharge Type and Occurrence a Type of Discharge Check whether the discharge is ' continuous or intermittent (See instructions) b. Discharge Occurrence Days per Week. Enter the average ' number of days per week (during periods of discharge) this discharge occurs. c. Discharge Occurrence- Months ' If this discharge normally oper- ates (either intermittently or continuously) on less than a yea around basis (excluding shut- downs for routine maintenance) check the months during the ye4 when the discharge is operating (see instructions) Complete Items 10 and 11 if *intermittent' is checked in Item 9.a. Otherwise, proceed to Item 12, 10. Intermittent Discharge Quantity State the average volume per dis- charge occurrence in thousands of gallons 11. Intermittent Discharge Duration and Frequency ' a Intermittent Discharge Duration Per Day State the average number of hours per day the discharge is operating b. Intermittent Discharge Frequency State the average number of discharge occurena per day during days when discharging ' 12. Maximum Flow Period Give the time period in which the maximum flow of this discharge occurs 2070 208a DISCHARG& f RIAL NUMBER 208b N/A feet ❑ STS (oon) Continuous ❑ WEL 209b 7_days per week ❑ OTH ❑ JAN ❑ FEB ❑ MAR 205b ❑ APR ❑ MAY ❑ JUN 206a N34 DEG. 50 MIN. 00 SEC 206b K78 DEG. 50 MIN. 00 SEC 207a Unnamed stream to Cape Fear River 211b (discharges as part of outfall 002) 2070 208a N/A feet 208b N/A feet 2096 (oon) Continuous ❑ (int) Intermittent 209b 7_days per week 2090 ❑ JAN ❑ FEB ❑ MAR ❑ APR ❑ MAY ❑ JUN ❑ JUL ❑ AUG ❑ SEP ❑ OCT ❑ NOV ❑ DEC *Continuous discharge 210 N/A thousand gallons per day 211a N/A hours per day 211b N/A discharge occurrences per day 212 From N/A to N/A month month V DISCHARGE SERIAL NUMBER 001 13. Activity Description Give a 213a Manufacturing of Polyvinyl Butysal (PVB) narrauvedescription ofactivity Resin and Sheeting producing this rischarge (see instructions) Manufacturing of Polyvinyl B ityral(PVB) Resin (SIC Code 2821) and sheeting (SIC Code 3081) 14. Activity Causing Discharge For each SIC Code which describes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of ft. Instruction Booklet. For SIC Codes not listed in Table t, use raw material or production units normally used for measuring production (see instructions) a Raw Materials 21 21 b. Products Maximum Unit Shared Discharges 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 DISCHARGE SERIAL NUMBER 001 13. Activity Description Give a 213a Manufacture of Hexaf1uoropropylene narrative description of activity Epoxide (HFPO) from the oxidation producing this discharge (see of hexaf luoropropylene (HFP ) insVuctions) 14. Activity Causing Discharge For each SIC Code which describes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of the Instruction Booklet. For SIC Codes not fisted in Table I, use raw material or production units normally used for measuring production (see instructions) a Raw Materials Maximum Unit Shared Discharges sin CrAp Name Amount/Day (See Table 1) (Serial Number) 21 b. Products maYimiim Unit Shared Discharges DISCHARGE SERIAL NUMBER 001 13. Activity Description Give a 213a Manufacture of verfluoronated intermediates narrative description of activity (SIC Code 2869). yerfluoronated resins (SIC producing this rischarge (see Code 2821). and serf 1 uoronated laminated film instruclions) (GTr Cndp 30RI) 14. Activity Causing Discharge For each SIC Code which describes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of the Instruclion Booklet.. For SIC Codes not listed in Table I, use raw material or production units normally used for measuring production (see instructions) a Raw Materials 2 b. Products Maximum Unit Shared Discharges 1 4par+ J - Tlarv'oplos'( C. [VC G 0 u 15 Waste Abatement a Waste Abatement Practices Describe the waste abatement practices used on this dis- charge with a brief narrative (see instructions) b. Waste Abatement Codes Using the codes listed in Table 11 of the Instruction Booklet, describe the waste abatement processes for this discharge in the order in which they occur if possible. I NARRATIVE: 0 DISCHARGE SERIAL NUMBER 001 215a I Narrative: See Below 215b I (1)ESEPAR (2)'SEGRE '(3)LOCALS (4)0MONIT (5)CNEUTR (6)EMERGE (7)PEQUAL (8)BAERAT (g)CHUTRI (10VAERAT (11) BACTIV (12) PSKTMC (13) PFLOAT 04),STHTCK (15) SPRRSS (16) SOTHER(I) (17)_SOTHER(2) (18) (1 g) (20) (21) (22) (23) (24) (25) SOTHER(1) - SLUDGE DRYING SOTHER (2) - SLUDGE LANDFILLING Wastewater collected from area sumps are sent to a 750,000 gal Equalization Basin (biological activity with aeration). A 175,000 gal Emergency Retention Tank is available for temporary storage of unsuitable wastewaters. Waters enter a 250,000 gal Pre -digester Tank (biological activity with aeration), followed by a 1,700,000 gal Aeration Tank where the main biodegradation occurs.. The treated water then goes to two clarifiers (120,000 and 168,000 gal) in parallel. The clarified treated effluent is discharged through Outfall 001. The wasted sludge is sent to a Dissolved Air Floatation (DAF) unit and then a Rotary Filter for thickening. The thickened sludge is dewatered in a Screw Press, and then dried -in steam heated dryers. The dried sludge is transported off-site to a commercial landfill. DISCHARGE SERIAL NUMBER 001 16. Wastewater Characteristics Check the box beside each constituent which is present in the effluent (discharge water). This determination is to based on actual analysis or best estimate. (see instructions) Parameter Present Parameter Present 216 216 Co+or Uopper 00060 X 01042 Ammonia I run 00610 X 01045 organic rn en 5+c 0 X 01051 Nitrate Magnesium 00620 X 00927 Nitrite Manganese 00615 01055 os rus ercury 00665 X 71900 Sulfate Molybdenum 00945 X builide Nickel 00745 01067 Sullite Selenium 00740 01147 dromi a auver 71870 01077 Chloride otasswm X 00940 X 00937 Cyanide odium X 00720 00929 rwonde Thallium 00951 X 01059 Aluminum Titanium 01105 X 01152 Antimony in 01097 X 01102 rsernc 01002 iinc 01092 X -Tery+um -Aigictoes, 01012 74051 num Chlorinated organic compounds* 01007 74052 Boron esuc+ es 01022 74053 cadmium 00+550 grease X 01027 a+cium Fhenois 00916. 32730 °dlt Surfactants X 01037 38260 Chromium Chloride 01034 500G0 ecai oo+ orm Oactena X ctivl 74055 7oiry be ' Specify substances, compounds andior elements in Item 26. Pesticides (insecticides, fungicides, and rodenticides) must be reported in terms of the acceptable common names specified in Acceptable Common Names and Chemical names for the Mrodent Srafemenf on Pesbdde Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as required by Subsection 162.7(b� of the Regulations for the Enforcement of the Federal Insecticide, Fungicide, and Rodenticide Act IM11111 w DISCHARGE SERIAL NUMBER 001 17. Description of Intake and Discharge For each of the parameters listed below, enter in the appropriate box the value or code letter answer called for (see instructions) In addition, enter the parameter name and code and all required values for any of the following parameters if they ere checked in Item 16: ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and chlorine (residual). Other discharges sharing intake flow (serial numbers) (see instructions) Influent uent Parameter and Code Untreated Intake In -Plant Treated ar y Average minimum Value -Maximum Value Frequency of Analysis Numbero Analyses bample Type Water Intake Observed or Observed or 217 (Daily Water Expected Expected average) (Daily During During average) Discharge Discharge Activity Activity (1 (2) (3 4 (5 6 (7) 8 row MGD 50050 N/A N/A 0.85 10.049 1.79 CONT. 1278 N/A P Units 00400 N/A N/A 6.3 8.3 3/7 546 G emperature (winter) =C N/A N/A 23.7 18 33 3/7 546 G emperature (summer) C. C 74025 N/A N/A 129.4 20 36 3/7 1 546 G bloChemciai uxygen Demand (BOD 5 -Day) mg/I 00310 N/A N/A 5.3 BDL 120 3/7 546 C emicar Oxygen Demand (COD) mg/I 00340 N/A N/A 1 45 45 45 N/A 1 C Total spen (nonfilterable) Solids mg/l 00530 N/A N/A 17.6 BDL 440 3/7 546 C peGx (73nouctance micromhos/cm at 25`C 00095 N/A N/A 4600 4600 N/A I 1 C a e matter (residue) mIA LT LT LT 00545 N/A I N/A 10.1 0.1 0.1 N/A 1 C Other discharges sharing intake flow (serial numbers) (see instructions) DISCHARGE SERIAL NUMBER 001 17 (Conrd) Parameter and Code 217 Innuent trnuent -Untreatedin-Plant Intake Water (Daily average) 11) Treated Intake Water (Daily average) 2) aiy Average g/L (3 minimum Value Observed or Expected During Discharge Activity 4 maximum Value Observed or Expected During Discharge Activity S of Analys+s t6 Number of Analyses 7 e Type 8) See attached 17. 18, Plant Controls Check if the following plant oontrois are available for this discharge 218 Alternate power source for major pumping facility APS Alarm or emergency procedure for power or equipment failure ALM Complete item 19 if discharge is frorr cooling ancVor steam water generation and water treatment additives are used 19. Water Treatment Additives If the discharge is treated with any conditioner, inhibitor, or algicide, answer the following: a Name of Material(s) 219a b, Name and address of 219b manufacturer c, Quantity (pounds added per 219c million gallons of water treated) FOR AGENCY USE DISCHARGE SERIAL NUMBER 001 17 t nnt'Al Eluent Daily Average (all values are mg/L) Mimimum Value Observed During Discharge Activity Maximum Value Observed During Discharge Activity Frequency of Analysis Number of Analyses Sanple Type Organic Nitrogen 00605 20.45 1.7 62.4 1/30 41 C Phosphorus___ 00665 3.02 0.2 8.1 1/30 41 C Oil & Grease 00550 6.89 <1 41 4/YR 18 G Color 00080 25 units 25 units 25 units NA 1 C Ammonia 00610 0.1 0.1 0.1 NA 1 C Nitrate 00620 35 35 35 NA 1 C Nitrite 00615 0.10 0.10 0.10 NA 1 C Sulfate 00945 1500 1500 1500 NA 1 C Chloride 00940 59 59 59 NA 1 C Aluminum 01105 740 740 740 NA 1 C Fecal Coliform Bacteria 74055 2100 col/dl 2100 col/dl 2100 col/dl NA 1 G Surfactants 38260 0.446 0.446 0.446 NA 1 C Total Iron 01045 0.423 0.423 0.423 NA 1 C Fluoride 00951 J 180 1 180 180 J NA 1 C FOR AGENCY USE 17. (Cont'd) DISCHARGE SERIAL NUMBER 001 Effluent Daily Mimimum Maximum Frequency Number of Sanple Average Value Value of Analysis Analyses Type 6 Observed Observed LT 5 LT 5 LT 5 values (all v alu During During Bromoform 32104 LT 5 LT 5 are u Discharge Discharge G Carbon Tetrachloride 32102 LT 5 LT 5 Activiri I Activity 6 G Chlorobenzene 34301 Acrolein 34210 LT 50 LT 50 LT 50 1/YR 5 G Acrylonitrile 34215 LT 50 LT 50 LT 50 1/YR 6 G Benzene 34030 LT 5 LT 5 LT 5 1/YR 6 G Bromoform 32104 LT 5 LT 5 LT 5 1/YR 6 G Carbon Tetrachloride 32102 LT 5 LT 5 LT 5 1/YR 6 G Chlorobenzene 34301 LT 6 LT 6 LT 6 1/YR 5 G Chlorodibromomethane 32105 LT 5 LT 5 LT 5 1/YR 6 G Chloroethane 34311 LT 10 LT 10 LT 10 1/YR 6 G 2-Chloroeth lvin 1 ether 34576 LT 10 LT 10 LT 10 1/YR 5 G Chloroform 32106 LT 5 LT 5 LT 5 1/YR 6 G Dichlorobromomethane 32101 LT 5 LT 5 LT 5 1/YR 5 G 1,1-Dichloroethane 34496 LT 5 LT 5 LT 5 1/YR 6 G 1,2-Dichloroethane 34531 LT 5 LT 5 LT 5 1/YR 6 G 1,1-Dichloroethleve 34501 LT 5 LT 5 LT 5 1/YR 6 G 1,2-Dichloropropane 34541 LT 6 LT 6 LT 6 I/YR 5 G 1,3-Dichloropropyjene 34699 LT 5 LT 5 LT 5 1/YR 6 G Ethlbenzene 34371 LT 8 LT 8 LT 8 1/YR 6 G Methyl Bromide 34413 LT 10 LT 10 LT 10 I/YR 5 G Methyl Chloride 34418 LT 10 LT 10 LT 10 1/YR 6 G Methylene Chloride 34423 LT 5 LT 5 LT 5 l/YR 6 G 1,1,2,2 -Tetrachloroethane 34516 LT 7 LT 7 LT 7 I/YR 5 G Tetrachloroethylene 34475 LT 5 LT 5 LT 5 1/YR 6 G Toluene 34010 LT 6 LT 6 LT 6 1/YR 6 G 1,2-trans-dichloroeth lene 34546 LT 5 LT 5 LT 5 1/YR 5 G 1,1,1 -Trichloroethane 34506 LT 5 LT 5 LT 5 I/YR 6 G 1,1,2 -Trichloroethane 34511 LT 5 LT 5 LT 5 I/YR 6 G Trichloroethylene 39180 LT 10 LT 10 LT 10 1/YR 6 G Vinyl Chloride 39175 LT 10 LT 10 LT 10 1/YR 6 G FOR AGENCY USE 17. (Cont'd) DISCHARGE SERIAL NUMBER 001 Daily Mimimum Maximum Frequency Number of Sanple Average Value Value of Analysis Analyses Type 6 Observed Observed LT 10 LT 10 LT 10 (all values Dur C 4,6-Dinitro-o-cresol 34657 LT 50 LT50 are ug/DuringDuring Discharge Discharge C 2,4-Dinitro henol 34616 LT 50 LT 50 Activity I Activity 6 C 2-Nitrophenol 34591 2 -Chloro hent 34586 LT 10 LT 10 LT 10 1/YR 6 C 2,4-Dichloro heno1 34601 LT 10 LT 10 LT 10 1/YR 6 C 2,4-Dimeth 1 henol 34606 LT 10 LT 10 LT 10 1/YR 6 C 4,6-Dinitro-o-cresol 34657 LT 50 LT50 LT 50 1/YR 6 C 2,4-Dinitro henol 34616 LT 50 LT 50 LT 50 1/YR 6 C 2-Nitrophenol 34591 LT 10 LT 10 LT 10 1/YR 6 C 4-Nitrophenol 34646 LT 50 LT 50 LT 50 1/YR 6 C P -chloro -m -cresol 34452 LT 10 LT 10 LT 10 1/YR 5 C Pentachlorophenol 39032 LT 50 LT 50 LT 50 1/YR 5 C Phenol 34694 LT 10 LT 10 LT 10 1/YR 6 C 2,4,6-Trichlor hent 34621 LT 10 LT 10 LT 10 1/YR 5 C Acenaphthene 34205 LT 10 LT 10 LT 10 1/YR 6 C Acena hth lene 34200 LT 10 LT 10 LT 10 1/YR 6 C Anthracene 34220 LT 10 LT 10 LT 10 1/YR 6 C Benzidine 39120 LT 50 LT 50 LT 50 1/YR 5 C Benzo(a)anthracene 34526 LT 10 LT 10 LT 10 1/YR 6 C Benz a me 34247 LT 10 LT 10 LT 10 1/YR 6 C 3,4-benzofluoranthene 34230 LT 10 LT 10 LT 10 1/YR 6 C Benz lene 34521 LT 10 LT 10 LT 10 YYR 5 C Benz k fluoranthene 34242 LT 10 LT 10 LT 10 1/YR 6 C Bis 2-chloroetho ethane 34278 LT 10 LT 10 LT 10 1/YR 5 C Bi 2-chloroeth 1 ther 34273 LT 10 LT 10 LT 10 1/YR 5 C Bi 2-chloroi 1 er 34283 LT 10 LT 10 LT 10 1/YR 5 C Bis 2-eththe 1 hthalate 39100 16.3 LT 10 81 1/YR 6 C 4-Bromo hen 1 phenyl ether 34636 LT 10 LT 10 LT 10 1/YR 5 C Butvlbenzyl plithalate 34292 LT 10 LT 10 LT 10 1/YR 5 C 2-Chlorona hthalene 34581 LT 10 LT 10 LT 10 1/YR 5 C 4 -Chloro hent phenyl ether 34641 1 LT 10 1 LT 10 LT 10 1/YR 5 C FOR AGENCY USE 1111 HL 17. (Cont'd) DISCHARGE SERIAL NUMBER 001 Daily Mimimum Maximum Frequency Number of Sanple Average Value Value of Analysis Analyses Type 6 Observed Observed LT 10 LT 10 LT 10 (all values During ung 1,3 -dichlorobenzene 34566 LT 10 LT 10 are ug/L) Discharge Discharge C 1,4 -dichlorobenzene 34571 LT 10 LT 10 Activity I Activity 6 C 3,3'-dichlorobenzidine 34631 Cbrysene 34320 LT 10 LT 10 LT 10 1/YR 6 C Dibenz a,h thracene 34556 LT 10 LT 10 LT 10 1/YR 6 C 1,2 -dichlorobenzene 34536 LT 10 LT 10 LT 10 1/YR 6 C 1,3 -dichlorobenzene 34566 LT 10 LT 10 LT 10 1/YR 6 C 1,4 -dichlorobenzene 34571 LT 10 LT 10 LT 10 1/YR 6 C 3,3'-dichlorobenzidine 34631 LT 20 LT 20 LT 20 1/YR 6 C Diethyl phthalate 34336 LT 10 LT 10 LT 10 1/YR 6 C Dimethyl phthalate 34341 LT 10 LT 10 LT 10 I/YR 6 C Di -n -butyl phthalate 39110 LT 10 LT 10 LT 10 I/YR 6 C 2,4-dinitrotoluene 34611 LT 10 LT 10 LT 10 1/YR 6 C 2,6-dinitrotoluene 34626 LT 10 LT 10 LT 10 11YR 6 C Di-n-octyl phthalate 34596 LT 10 LT 10 LT 10 1/YR 5 C 1,2 -di hen Ih drazine 34346 LT 10 LT 10 LT 10 1/YR 6 C Fluroranthene 34376 LT 10 LT 10 LT 10 1/YR 6 C Fluorene 34381 LT 10 LT 10 LT 10 11YR 6 C Hexachlorobenzene 39700 LT 10 LT 10 LT 10 1/YR 6 C Hexachlorobutadiene 34391 LT 10 LT 10 LT 10 1/YR 5 C Hexachlorocyclopentadiene 34386 LT 10 LT 10 LT 10 1/YR 6 C Hexachloroethane 34396 LT 10 LT 10 LT 10 1/YR 6 C Inden 1,2,3 -cd ene 34403 LT 10 LT 10 LT 10 1/YR 6 C Iso horone 34408 LT 10 LT 10 LT 10 1/YR 5 C Na thalene 34696 LT 10 LT 10 LT 10 I/YR 6 C Nitrobenzene 34447 LT 10 LT 10 LT 10 1/YR 6 C N-nitrosodimeth lamine 34438 LT 10 LT 10 LT 10 I/YR 6 C N-nitrosodi-n-propylmine 34428 LT 10 LT 10 LT 10 1/YR 5 C N-nitrosodi hen lamine 34433 LT 10 LT 10 LT 10 1/YR 5 C Phenanthrene 34461 LT 10 LT 10 LT 10 I/YR 6 C Pyrene 34469 LT 10 1 LT 10 1 LT 10 1 1/YR 1 6 C 1,2,4-trichlorobenzene 34551 LT 10 j LT 10 1 LT 10 1 1/YR 1 6 C hTM CY USE ij 17. (Cont'd) DISCHARGE SERIAL NUMBER 001 Daily Mimimum Maximum Frequency Number of Sanple Average Value Value of Analysis Analyses Type 1 Observed Observed LT 0.050 LT 0.050 LT 0.050 (all values During During Gamma -BHC 39340 LT 0.050 LT 0.050 are ug/L) Discharge Discharge C Delta -BHC 34259 LT 0.050 LT 0.050 Activity I Activity 1 C Chlordane 39350 Aldrin 39330 LT 0.050 LT 0.050 LT 0.050 NA 1 C Alpha -BHC 39337 LT 0.050 LT 0.050 LT 0.050 NA 1 C Beta -BHC 39338 LT 0.050 LT 0.050 LT 0.050 NA 1 C Gamma -BHC 39340 LT 0.050 LT 0.050 LT 0.050 NA 1 C Delta -BHC 34259 LT 0.050 LT 0.050 LT 0.050 NA 1 C Chlordane 39350 LT 0.50 LT 0.50 LT 0.50 NA 1 C 4,4' -DDT 39300 LT 0.10 LT 0.10 LT 0.10 NA 1 C 4,4' -DDE 39320 LT 0.10 LT 0.10 LT 0.10 NA 1 C 4,4' -DDD 39310 LT 0.10 LT 0.10 LT 0.10 NA 1 C Dieldrin 39380 LT 0.10 LT 0.10 LT 0.10 NA 1 C Al ha-Endosulfan 34361 LT 0.050 LT 0.050 LT 0.050 NA 1 C Beta-Endosulfan 34356 LT 0.10 LT 0.10 LT 0.10 NA 1 C Endosulfan Sulfate 34351 LT 0.10 LT 0.10 LT 0.10 NA 1 C Endrin 39390 LT 0.10 LT 0.10 LT 0.10 NA 1 C Endrin Aldehyde 34366 LT 0.10 LT 0.10 LT 0.10 NA 1 C Heptachlor 39410 LT 0.050 LT 0.050 LT 0.050 NA 1 C Heptachlor Epoxide 39420 LT 0.050 LT 0.050 LT 0.050 NA 1 C PCB -1242 39496 LT 0.50 LT 0.50 LT 0.50 NA 1 C PCB -1254 39504 LT 1.0 LT 1.0 LT 1.0 NA 1 C PCB -1221 39488 LT 0.50 LT 0.50 LT 0.50 NA 1 C PCB -1232 39492 LT 0.50 LT 0.50 LT 0.50 NA 1 C PCB -1248 39500 LT 0.50 LT 0.50 LT 0.50 NA 1 C PCB -1260 39508 LT 1.0 LT 1.0 LT 1.0 NA 1 C PCB -1016 34671 LT 0.50 LT 0.50 LT 0.50 NA 1 C Toxaphene 39400 LT 5.0 LT 5.0 LT 5.0 NA 1 C ' FOR AGENCY USE ' 17 hrnnt'd) P1 DISCHARGE SERIAL NUMBER 001 Eluent Daily Average (all values are ug/L) Mimimum Value Observed luring Discharge Activity Maximum Value Observed During Discharge Activity Frequency of Analysis Number of Analyses Sanple Type Antimony, Total 01097 LT 50 LT 50 LT 50 NA 1 C Arsenic, Total 01002 LT 10 LT 10 LT 10 NA 1 C Beryllium, Total 01012 LT 25 LT 25 LT 25 NA 1 C Cadmium Total 01027 LT 2 LT 2 LT 2 NA 1 C Chromium, Total 01034 LT 5 LT 5 LT 5 NA 1 C Copper, Total 01042 4.03 4.03 4.03 NA 1 C Lead, Total 01051 LT 10 LT 10 LT 10 NA 1 C Mercury, Total 71900 LT 0.200 LT 0.200 LT 0.200 NA 1 C Nickel, To 01067 LT 10 LT 10 LT 10 NA 1 C Selenium, Total 01147 LT 5 LT 5 LT 5 NA 1 C Silver, Total 01077 LT 5 LT 5 LT 5 NA 1 C Thallium, Total 01059 LT 10 LT 10 LT 10 NA 1 C Zinc, Total 01092 64.1 64.1 64.1 NA 1 C Cyanide, Total 00720 LT 0.010 LT 0.010 LT 0.010 NA 1 G Phenols, Total 32730 LT 0.005 LT 0.005 LT 0.005 NA 1 G DISCHARGE SERIAL NUMBER 001 d Chemical composition of theseI 2194 1% additives (see instructions) OF OF Complete Items 20-25 if there is a thermal discharge OF: (e.g., associated with a steam and/or power generation OF plant, steel mill, petroleum refinery, or any other and the total discharge flow is OF: manufacturing process) 10 million gallons per day or more. (see instructions) 20. Thermal Discharge Source_ Check 220 the appropriate item(s) indicating the source of the discharge (see instructions) Boiler Blowdown ❑ BLBD Boiler Chemical Cleaning ❑ BCCL Ash Pond Overflow ❑ APOF Boiler Water Treatment - ❑ EPBD Evaporator Blowdown Oil and Coal Fired Plants -Effluent ❑ OCFP from Air Pollution Control Devices Condense Cooling Water ❑ COND Cooling Tower Blowdown ❑ CTBD Manufacturing Process ❑ MFPR Other ❑ OTHR 21. Dischar je/Receiving Water Temperature Difference Give the maximum temperature difference between the discharge and receiving waters for summer and winter operating conditions (see instructions) °F Summer 221a Winter 221b °F 22. Discharge Temperature , Rate of Change Per Hour 222 °F./hour Give the maximum possible rate of temperature change per hour of discharge under operating conditions (see instructions) 23. Water Temperature, Percentile Repo rt(F requency of Occurrence) In the table below, enter the temperature which is exceeded 10% of the year, 5% of the year, 1% of the year and not at all (maximum yearly temperature). (see instructions) F f requency o occurrence a. Intake Water Temperature 223a (subject to natural changes b. Discharge Water Temperature 223b 100/0 /° 1% Maximum OF OF OF: OF: OF OF OF: OF: 24. Water Intake Velocity 224 feet/sec. (see instructions) 25. Retention Time Give the length of 225 minutes time, in minutes, from start of water temperature rise to discharge of cooling water. (see instructions) 111111111 Z. DISCHARGE SERIAL NUMBER 001 - Additional Intomiation 0 0 0 11 -WOMWEINVA1111 =0 '1011111111 STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTION II. BASIC DISCHARGE DESCRIPTION Complete this section for each discharge Indicated which the waste water does not go through a treatr also discharges to surface waters from this facility. ORIGINATE IN THE SAME FACILITY. All values 1 discharge, values should reflect best engineering ADDITIONAL INSTRUCTIONS FOR SELECTE BEFORE FILLING OUT THESE ITEMS. 1. Discharge Serial No. and Name a Discharge Serial No. (see instructions) b. Discharge Name Give the name of discharge, if any (see instructions) c. Previous Discharge Serial No It a previous permit application was made for this dis- charge (Item 4, Section 11 provide previous discharge serial number. 2 Discharge Operating Dates a Discharge Began Date If the discharge described below is in operation, give the date (within best estimate) the discharge began b. Discharge to Begin Date If the discharge has never occurred but is planned for some future date, give the date the discharge will begin. c. Discharge to End Date If the discharge is scheduled to be discontinued within the next 5 years, give the date (within best estimate) the discharge will end. 3. Engineering Report Available Check if an engineering report is available to reviewing agency upon request (see instructions) 4. Discharge Location Name the political boundaries within which the point of discharge is located: in Section rent works SEPARA7 or an existi estimates. D ITEMS 201a 201b 201c 202a 202b 202c 2x3 204a 204b 2D4c I, Items 9,nnthat Is torged surface waters. This includes discharges to municipal sewerage systems to Drior to beE DESCRIPT ONS OF EACH DISCHARGE RE REto surface waters. QUIRED s to wells EVEN IF SEVERAL DISCHA GrES e rg discharge should be rspreaentative of the twelve previous months of operation. M this is a proposed kPPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET 002 Final Facility EfflUent DjsnhargP__ 002 71 02 N/A YR MO N/A YR MO en Use North Carolina 204d Bladen 204e Duart 204f 205a I ® STR n LKE (] OCE (] MTS (] MCS State County ' (If applicable) City or Town Discharge Point Description (see instructions) Discharge into (check one) Stream (includes ditches, arroyos, and other watercourses Lake Ocean Municipal Sanitary Wastewater Transport System Municipal Combined Sanitary and Storm Transport System in Section rent works SEPARA7 or an existi estimates. D ITEMS 201a 201b 201c 202a 202b 202c 2x3 204a 204b 2D4c I, Items 9,nnthat Is torged surface waters. This includes discharges to municipal sewerage systems to Drior to beE DESCRIPT ONS OF EACH DISCHARGE RE REto surface waters. QUIRED s to wells EVEN IF SEVERAL DISCHA GrES e rg discharge should be rspreaentative of the twelve previous months of operation. M this is a proposed kPPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET 002 Final Facility EfflUent DjsnhargP__ 002 71 02 N/A YR MO N/A YR MO en Use North Carolina 204d Bladen 204e Duart 204f 205a I ® STR n LKE (] OCE (] MTS (] MCS [TI I I Municipal Storrs Water Transport System ' Well (injection) Other If 'other is checked, specify type 6. Discharge Point - Ilgng. Give the gprease location of the point of discharge to the nearest second. Latitude ' 7. Dharge Receiving Water Name Name the waterway at the point of discharge. (see instructions) ' If the discharge is through an ouffall that extends beyond the shoreline or is below the mean low water line, complete item 8, rr-0. 'J!e ' ^. Maes M^r LSUD FoT Aae�ev Use 8. Offshore Discharge a. Discharge Distance from Shore ' b. Discharge Depth Below Water 9 Discharge Type and Occurrence a Type of Discharge Check whether the discharge is ' continuous or intermittent (See instructions) b. Discharge Occurrence Days per Week. Enter the average ' number of days per week (during periods of discharge) this discharge occurs. c. Discharge Occurrence- Months ' If this discharge normally oper- ates (either intermittently or continuously) on less than a yea around basis (excluding shut- downs for routine maintenance) check the months during the ye4 when the discharge is operating (see instructions) Complete Items 10 and 11 if 'intermittent' is checked in Item 9.a. Otherwise, proceed to Item 12. 10. Intermitter., Discharge Quantity State the average volume per dis- charge occurrence in thousands of gallons it. Intermittent Discharge Duration and Frequency ' a Intermittent Discharge Duration Per Day State the average number of hours per day the discharge is operating b. Intermittent Discharge ' Frequency State the average number of discharge occurrena per day during days when discharging 12. Maximum Flow Period Give the ' time period in which the maximum flow of this discharge occurs 206a M 207a 192 207c DISCHARGE BFIAL NUMBER ® STS WEL OTH N34 DEG. __5D—MIN. _.QQ_SEC W78 DEG. 50 MIN. 00 SEC Un–named stream to Cape Fear River 208a N/A feet 208b N/A feet 209a E�(oon) Continuous (int) Intermittent 20% ___I_days per week 2D9c JAN JR FEB ig MAR JaAPR 3aMAY i@JUN JJJUL AUG JR SEP iaOCT` NOV DEC 210 thousand gallons per day 211a hours per day 211b discharge occurrences per day s 212 From N/A to N/A month month DISCHARGE SERIAL NUMBER 002 13. Activity Description Give a 213a 1— Perfluorinated sheeting process — neutralized narrative description of activity nitric acid producing this discharge (we 2— Boiler blowdown and condensate instructions) 3— Cooling Tower blowdown 4— Sto water 5— Non—contact cooling water (filtered water and raw, river watpr) 14. Activity Causing Discharge For each SIC Code which describes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of the Instruction Booklet.. For SIC Codes not listed in Table I, use raw material or production units normally used for measuring production (see instructions) a Raw Materials Maximum Unit Shard Discharges SIC Code Name AmounVDa See Table I Serial Number 461 3083 Nitric—Arid o-oni #2 4939 Water 0.133 463 4939 Water 0.08 464 N/A Water 2.647 465 2821 286 Water- 3081, 3083 b. Products DISCHARGE SERIAL NUMBER 002 13. Activity Description Give a 213a . 6— Treated wastewater effluent uent narrative description of activity from Fa i i tv' s Wastewater Treatment producing thLs discharge (we Plant (Outfall 001) instructions) 14. Activity Causing Discharge For each SIC Code which descnbes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of the Instruction Booldet.. For SIC Codes not listed in Table I, use raw material or production units normally used for measuring production (see instructions) a Raw Materials Maximum Unit Shared Discharges b. Produces �7.1:r_taai!t•�n�y� 15 Waste Abatement a Waste Abatement Practices Describe the waste abatement practices used on this dis- charge with a brief narrative (see instructions) b. Waste Abatement Codes Using the codes listed in Table II of the Instruction Booklet, describe the waste abatement processes for this discharge in the order in which they occur if possible. DISCHARGE SERIAL NUMBER 002 215a Narrative: Dilute nitric acid is neutralized_ with potassium hydroxide 215b (t) CNEUTR J2) (3)_ (4) (5) (6) (7) (6) (9) (13) (14) (15) (16) (17) (18) (19) (20) (21) (22) (23) (24) (25) DISCHARGE SERIAL NUMBER 002 16. Wastewater Characteristics Check the box beside each constituent which is present in the effluent (discharge water). This determination is to based on actual analysis or best estimate. (see instructions) Parameter Present Parameter eresent 216 216 001800080 0 X 0104220 Ammonia 00610 X ron 01045 X Organic nitrogen 00605 X 01051 I a 00620 X agneswm 7 rt Manganese 0061515 01056 Phosphorus Mercury 00665 ate molybdenum 00945 X 01062 Sulfide ICKe 00745 01067 5ultite Selenium 00740 01147 aroml a silver 71870 01077 Chloride Potassium X 00940 X 0037 an1de b0clum 00720 00-29 rtuon a i na lum 00951 X 01059 Aluminum �tanwm 01105 X 01152 Antimony � In 01097 X 01102 Arsenic 01002 inc 01032 X Beryllium Iglcl s X 01012 74051 num L;hionnated organic compou 01007 74052 Boron esuct es 01022 74053 a mtum100650 and gee X 01027 calcium Phenols 00-016, 32730 u,oDalt SurfactantsX 01037 38260 Chromium Chionde X 01034 50060 Fecal oo I orm bacteria amoacuvtty 7405.5 X 74050 be Specify substances, compounds and/or elements in Item 26. Pesticides (insecticides, fungicides, and nodenticides) must be reported in terms of the acceptable common names specified in Acceptable Common Names and Chemical names for the ftradent Statement on Pesoaoe Labels, 2nd Edition, Environmental Protection Agency, Washington, D.C. 20250, June 1972, as required by Subsection 162.7(8) of the Regulations for the Enforcement of the Federal Insecticide, Fungicide, and Rodenticide Act 1 1 1 1 1 1 1 1 1 1 1 DISCHARGE SERIAL NUMBER 002 17. Description of Intake and Discharge For each of the parameters fisted below, enter in the appropriate box the value or code fetter answer called for (see instructions) In addition, enter the parameter name and code and all required values for any of the following parameters if they ere checked in Item 16: ammonia, cyanide, aluminum, arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, zinc, phenols, oil and grease, and chlorine (residual). ' Other dscharges sharing intake flow (serial numbers) (see instructions) influent uen Parameter and Code Untreate5 Intake In-l"lantDaily Treated Average Minimum Value Maximum Value requenry of Analysis Numbero Analyses Sample Type Water Intake Observed or Observed or 217 (Daily Water Expeclied Expected average) (Daily During During average) Discharge Discharge Activity Activity (1 (2) (3) (4 5 6 (7) (8 low XGD 50050 15.10 3.1015.10L12.96 21.91 CONT 1278 N/A P Units 00400 6.7 N/A 6.0 8.8 3/7 546 G Temperature (winter) �C 74026 10.8 N/A 17.6 8 26 7/7 1278 G emperature (summer) VC 74025 22.9 N/A 126.9 15 36 1 7/7 1278 G Biochemcial Lixygen Demand (BOD 5 -Day) mg/I 00310 LT 2.0 IT 2. C 6.6 ILT 1 70 4/YR 14 1 C Chemical Uxygen Demand (COD) mgA 00340 109 LT 25 55.4 LT 5 1 392 4/YR 14 C o spen (nonfilterable) Solids mg/l 0053 27 LT 6 LT 6 LT 6 LT 6 N/A 1 C Speafic Conductance micromhos/cm at 25'C 00093 109 140 540 540 N/A 1 C Settleable a r (residue) MIA 00545 LT 0.1 ILT 04T 0.1 LT 0.1 LT 0.1 N/A t1 C ' Other dscharges sharing intake flow (serial numbers) (see instructions) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 DISCHARGE SERIAL NUMBER 002 17. (Conrd) Parameter and Code 217 n uen F-muent n Intake Water (Daily average) (1) n an Treated Intake Water (Daily average) 2) a� y Average (3) inimum Value Observed or Expected During Discharge Activity 1 (4 aximum Value Observed or Expected During Discharge Activity 5 requenry of Analysis (6 um er of Analyses 7 e Type 8) See attached pumping facility Q APS Alarm or emergency procedure for page for Item power or equipment failure ® ALM Complete Item 19 if discharge is frorr cooling and/or steam water generation and water treatment additives are used 19. Water Treatment Additives If the discharge is treated with any conditioner, inhibitor, or algicide, answer the following: a Name ofMaterial(s) 219a *Note: Outfall 002 discharge is not treated with any chemicals However. the BCH Energy Proiect's Boiler and Cooling Tower waters contain b. Name and address of 219b treatment additives which 18. Plant Controls Check if the following plant controls are available for this discharge 218 Alternate power source for major pumping facility Q APS Alarm or emergency procedure for power or equipment failure ® ALM Complete Item 19 if discharge is frorr cooling and/or steam water generation and water treatment additives are used 19. Water Treatment Additives If the discharge is treated with any conditioner, inhibitor, or algicide, answer the following: a Name ofMaterial(s) 219a *Note: Outfall 002 discharge is not treated with any chemicals However. the BCH Energy Proiect's Boiler and Cooling Tower waters contain b. Name and address of 219b treatment additives which are discharged through manufacturer Outfall 002. See attached page for Item 19. c, Quantity (pounds added per 219c million gallons of water treated) FOR AGENCY USE 1 11 /rnnt'rll 11 F, n r r DISCHARGE SERIAL NUMBER 002 Effluent Daily Average (all values are mg/L) Mimimum Value Observed During Discharge Activity Maximum Value Observed luring Discharge Activity Frequency of Analysis Number of Analyses Sanple Type Fluoride 00951 6.85 0.02 86 1/7 178 C Color 00080 100 units 100 units 100 units NA 1 C Ammonia 00610 0.1 0.1 0.1 NA 1 C Nitrate 00620 2.3 2.3 2.3 NA 1 C Nitrite 00615 0.04 0.04 0.04 NA 1 C Sulfate 00945 130 130 130 NA 1 C Chloride 00940 14 14 14 NA 1 C Aluminum 01105 1950 1950 1950 NA 1 C Fecal Coliform Bacteria 74055 690 col/dl 690 col/dl 690 col/dl NA 1 C Surfactants 38260 0.252 0.252 0.252 NA 1 C Organic Nitrogen 00605 0.8 0.8 0.8 NA 1 C Total Phosphorus 00665 0.17 0.17 0.17 NA 1 C Total Iron 01045 1.44 1.44 1.44 NA 1 C Total Sodium 00929 44.8 44.8 44.8 NA 1 C Total Potassium 00937 82.5 82.5 82.5 NA 1 C Oil & Grease 00550 LT 5 LT 5 LT 5 NA 1 C ' FOR AGENCY USE I17 trnnt,tll 1 DISCHARGE SERIAL NUMBER 002 Effluent Daily Average values (all v are u alu Mimimum Value Observed During Discharge Activity Maximum Value Observed During Discharge Activity Frequency of Analysis Number of Analyses Sanple Type Acrolein 34210 LT 5 LT 5 LT 5 NA 1 G Acrylonitrile 34215 LT 5 LT 5 LT 5 NA 1 G Benzene 34030 IT 5 LT 5 LT 5 NA 1 G Bromoform 32104 LT 5 LT 5 LT 5 NA 1 G Carbon Tetrachloride 32102 LT 5 LT 5 LT 5 NA 1 G Chlorobenzene 34301 LT 5 LT 5 LT 5 NA 1 G Chlorodibromomethane 32105 LT 5 LT 5 LT 5 NA 1 G Chloroethane 34311 LT 10 LT 10 LT 10 NA 1 G 2-Chloroeth lvin 1 ether 34576 LT 10 LT 10 LT 10 NA 1 G Chloroform 32106 LT 5 LT 5 LT 5 NA 1 G Dichlorobromomedme 32101 LT 5 LT 5 LT 5 NA 1 G 1,1-Dichloroethane 34496 LT 5 LT 5 LT 5 NA 1 G 1,2-Dichloroedme 34531 LT 5 LT 5 LT 5 NA 1 G 1,1-Dichloroethleve 34501 LT 5 LT 5 LT 5 NA 1 G 1,2-Dichloro o ane 34541 LT 5 LT 5 LT 5 NA 1 G 1,3-Dichloropropylene 34699 LT 5 LT 5 LT 5 NA 1 G Ethlbenzene 34371 LT 5 LT 5 LT 5 NA 1 G Methyl Bromide 34413 LT 10 LT 10 LT 10 NA 1 G Methyl Chloride 34418 LT 10 LT 10 LT 10 NA 1 G Methylene Chloride 34423 LT 5 LT 5 LT 5 NA 1 G 1,1,2,2 -Tetrachloroethane 34516 LT 5 LT 5 LT 5 NA 1 G Tetrachloroethylene 34475 IT 5 LT 5 LT 5 NA 1 G Toluene 34010 LT 5 LT 5 LT 5 NA 1 G 1,2-trans-dichloroeth leve 34546 LT 5 LT 5 LT 5 NA 1 G 1,1,1 -Trichloroethane 34506 LT 5 LT 5 LT 5 NA 1 G 1,1,2 -Trichloroethane 34511 LT 5 LT 5 ELT LT 5 NA 1 G Trichloroethylene 39180 LT 5 5 LT 5 NA 1 G Vinyl Chloride 39175 LT 10 LT 10 LT 10 NA 1 G ' FOR AGENCY USE FFI_1I I I I id ' 17 irnnt,d) G D D DISCHARGE SERIAL NUMBER 002 Effluent Daily Average values (all v are ual Mimimum Value Observed During Discharge ActivityActivity Maximum Value Observed During Discharge Frequency of Analysis Number of Analyses Sanple Type 2-Chlorophenol 34586 LT 10 LT 10 LT 10 NA 1 C 2,4-Dichloro henol 34601 LT 10 LT 10 LT 10 NA 1 C 2,4 -Dimethylphenol 34606 LT 10 LT 10 LT 10 NA 1 C 4,6-Dinitro-o-cresol 34657 LT 50 LT50 LT 50 NA I C 2,4-Dinitro henol 34616 LT 50 LT 50 LT 50 NA 1 C 2-Nitrophenol 34591 LT 10 LT 10 LT 10 NA 1 C 4-Nitrophenol 34646 LT 50 LT 50 LT 50 NA 1 C p -chloro -m -cresol 34452 LT 10 LT 10 LT 10 NA 1 C Pentachlorophenol 39032 LT 50 LT 50 LT 50 NA 1 C Phenol 34694 LT 10 LT 10 LT 10 NA I C 2,4,6 -Trichlorophenol 34621 LT 10 LT 10 LT 10 NA 1 C Acenaphthene 34205 IT 10 LT 10 LT 10 NA 1 C Acenaphthylene 34200 LT 10 LT 10 LT 10 NA 1 C Anthracene 34220 LT 10 LT 10 LT 10 NA 1 C Benzidine 39120 LT 50 LT 50 LT 50 NA 1 C Benzo(a)anthracene 34526 LT 10 LT 10 LT 10 NA 1 C Benzo(a)pyrene 34247 LT 10 LT 10 LT 10 NA 1 C 3,4-benzofluoranthene 34230 LT 10 LT 10 LT 10 NA 1 C Benz leve 34521 LT 10 LT 10 LT 10 NA 1 C Benz fluoranthene 34242 LT 10 LT 10 LT 10 NA 1 C Bis 2-chloroetho ethane 34278 LT 10 LT 10 LT 10 NA 1 C Bi 2-chloroeth 1 ther 34273 LT 10 LT 10 LT 10 NA 1 C Bi 2-chloroiso ro 1 ther 34283 LT 10 LT 10 LT 10 NA 1 C Bis 2-ethvlhe I hthalate 39100 LT 10 LT 10 LT 81 NA 1 C 4-Bromo hen 1 phenyl ether 34636 LT 10 LT 10 LT 10 NA 1 C Butylbenzyl phthalate 34292_ LT 10 LT 10 LT 10 NA 1 C 2 -Chloro na hthalene 34581 1 LT 10 LT 10 LT 10 NA 1 C 4 -Chloro hen 1 phenyl ether 34641 1 LT 10 LT 10 J LT 10 NA 1 C 11 r 11 n L r D FOR AGENCY USE DISCHARGE SERIAL NUMBER 002 17 Wnnt'ch Effluent Daily Average (all values are ug/L) Mimilnum Value Observed During Discharge Activity Maximum Value Observed Dunng Discharge Activity Frequency of Analysis Number of Analyses Sanple Type Chrysene 34320 LT 10 LT 10 LT 10 NA 1 C Dibenz a,h anthracene 34556 LT 10 LT 10 LT 10 NA 1 C 1,2 -dichlorobenzene 34536 LT 5 LT 5 LT 5 NA 1 C 1,3 -dichlorobenzene 34566 LT 5 LT 5 LT 5 NA 1 C 1,4 -dichlorobenzene 34571 LT 5 LT 5 LT 5 NA 1 C 3,3'-dichlorobenzidine 34631 LT 10 LT 10 LT 10 NA 1 C Diethyl phthalate 34336 LT 10 LT 10 LT 10 NA 1 C Dimethyl phthalate 34341 LT 10 LT 10 LT 10 NA 1 C Di -n -butyl phthalate 39110 LT 10 LT 10 LT 10 NA 1 C 2,4-dinitrotoluene 34611 LT 10 LT 10 LT 10 NA 1 C 2,6-dinitrotoluene 34626 LT 10 LT 10 LT 10 NA 1 C Di-n-octyl phthalate 34596 23 23 23 NA 1 C 1,2 -di hen lh drazine 34346 LT 10 LT 10 LT 10 NA 1 C Fluroranthene 34376 LT 10 LT 10 LT 10 NA 1 C Fluorene 34381 LT 10 LT 10 LT 10 NA 1 C Hexachlorobenzene 39700 LT 10 LT 10 LT 10 NA 1 C Hexachlorobutadiene 34391 LT 10 LT 10 LT 10 NA 1 C Hexachlorocyclopentadiene 34386 LT 10 LT 10 LT 10 NA 1 C Hexachloroethane 34396 LT 10 LT 10 LT 10 NA 1 C Indeno 1,2,3 -cd ene 34403 LT 10 LT 10 LT 10 NA 1 C Iso horone 34408 LT 10 LT 10 LT 10 NA 1 C Na thalene 34696 LT 10 LT 10 LT 10 NA 1 C Nitrobenzene 34447 LT 10 LT 10 LT 10 NA 1 C N-nitrosodimeth lamine 34438 LT 10 LT 10 LT 10 NA 1 C N-nitrosodi-n-propylamine 34428 LT 10 LT 10 LT 10 NA 1 C N-nitrosodi hen lamine 34433 LT 10 LT 10 LT 10 NA 1 C Phenanthrene 34461 LT 10 LT 10 LT i0 NA 1 C Pyrene 34469 LT 10 LT 10 LT 10 NA 1 C 1,2,4-trichlorobenzene 34551 LT 10 LT 10 LT 10 NA 1 C FOR AGENCY USE 17. (Cont'd) DISCHARGE SERIAL NUMBER 002 Daily Mimimum Maximum Frequency Number of Sample Average Value Value of Analysis Analyses Type 1 Observed Observed LT 25 LT 25 LT 25 (all values ung During Cadmium Total 01027 LT 2 LT 2 are ug/L) Discharge Discharge C Chromium, Total 01034 LT 5 LT 5 Activity I Antivity 1 C Copper, Total 01042 Antimony, Total 01097 LT 50 LT 50 LT 50 NA 1 C Arsenic, Total 01002 LT 10 LT 10 LT 10 NA 1 C Beryllium, Total 01012 LT 25 LT 25 LT 25 NA 1 C Cadmium Total 01027 LT 2 LT 2 LT 2 NA 1 C Chromium, Total 01034 LT 5 LT 5 LT 5 NA 1 C Copper, Total 01042 6.83 6.83 6.83 NA 1 C Lead, Total 01051 LT 10 LT 10 LT 10 NA 1 C Mercury, Total 71900 LT 0.200 LT 0.200 LT 0.200 NA 1 C Nickel, Total 01067 LT 10 LT 10 LT 10 NA 1 C Selenium, Total 01147 LT 5 LT 5 LT 5 NA 1 C Silver, Total 01077 LT 5 LT 5 LT 5 NA 1 C Thallium, Total 01059 LT 10 LT 10 LT 10 NA 1 C Zinc, Total 01092 18.8 18.8 18.8 NA 1 C Cyanide, Total 00720 LT 0.010 LT 0.010 LT 0.010 NA 1 C Phenols, Total 32730 LT 0.005 LT 0.005 LT 0.005 NA 1 C 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 FOR AGENCY USE DISCHARGE SERIAL NUMBER 002 19. Water Treatment Additives. If the discharge is treated with any conditioner, inhibitor, or algicide, answer the following: Note: The above additives are used solely in the BCH Energy Project Facility located at the Dupont Fayetteville Works and which ultimately discharges through the DuPont Outfall 002. 219b Name and address 291c Quantity (pounds added per 291d Chemical 219a Name of Material of manufacturer million gallon of water treated) composition Betz Industrial Corp Bio-Trol 88P Landmark Plaza 5 lb/day at the BCH Facility See attached 4303-8 Oleander Dr. (0.33 lb/million gal at Outfall 002) DEM Form 101 Wilmington, NC 28403 Betz Industrial Corp Cor-Trol 778P Landmark Plaza 0.069 lb/day at the BCH Facility See attached 4303-8 Oleander Dr. (0.0046 lb/million gal at Outfall 002) DEM Form 101 Wilmington, NC 28403 Betz Industrial Corp Balanced Polymer 54400 Landmark Plaza 0.1541b/day at the BCH Facility See attached 4303-8 Oleander Dr. (0.010 lb/million gal at Outfall 002) DEM Form 101 Wilmington, NC 28403 Betz Industrial Corp Opti -Meeh Landmark Plaza 0.038 lb/day at the BCH Facility See attached 4303-8 Oleander Dr. (0.00251b/million gal at Outfall 002) DEM Form 101 Wilmington, NC 28403 Betz Industrial Corp Continuum 29000 Landmark Plaza 3.60 lb/day at the BCH Facility See attached 4303-8 Oleander Dr. (0.238 lb/million gal at Outfall 002) DEM Form 101 Wilmington, NC 28403 Note: The above additives are used solely in the BCH Energy Project Facility located at the Dupont Fayetteville Works and which ultimately discharges through the DuPont Outfall 002. 11 r 0 G d Chemical composition of theseI 219d additives (see instructions) Complete Items 20-25 if there is a thermal discharge (e.g., associated with a steam and/or power generation plant, steel mill, petroleum refinery, or any other manufacturing process) and the total discharge flow is 10 million gallons per day or more. (see instructions) 20. Thermal Discharge Source- Check 220 the appropriate item(s) indicating the source of the discharge (see instructions) Boiler Blowdown Boiler Chemical Cleaning Ash Pond Overflow Boiler Water Treatment - Evaporator Blowdown Oil and Coal Fired Plants -Effluent from Air Pollution Control Devices Condense Cooling Water Cooling Tower Blowdown Manufacturing Process Other 21. Discharge,Receiving Water Temperature Difference Give the maximum temperature difference between the discharge and receiving waters for summer and winter operating conditions (see instructions) Summer 221a Winter 221b 22. Discharge Temperature, Rate of Change Per Hour 222 Give the maximum possible rate of temperature change perhourof discharge under operating conditions (see instructions) 23. Water Temperature, Percentile Report(Frequency of Occurrence) In the table below, enter the temperature which is exceeded 10% of the year, 5% of the year, 1% of the year and not at all (maximum yearty temperature). (see instructions) Frequency of occurrence a. Intake Water Temperature 223a (subject to natural changes b. Discharge Water Temperature 223b 24. Water Intake Velocity (see instructions) 25. Retention Time Give the length of time. in minutes, from start of water temperature rise to discharge of cooling water. (see instructions) DISCHARGE SERIAL NUMBER 002 See attached D.E.M. Form 101 for compositions. © BLBD 0 BCCL APOF [] EPBD OCFP R9 COND ® CTBD ® MFPR OTHR 10.8 °F 23.4 °F 0.5 °FJhour I 100/0 /0 1% maximum 84.6 OF 85.5°F 87.2 OF 88.8°F 87.8 OF I 91.4°F 1 95 OF I 96.8°F 224 1.6 feet/sec. 225 35 minutes 111111111 26. DISCHARGE SERIAL NUMBER 002 Additional 1 ntomiabo n em inrormauon _ 16 Biocide used in the BCH Energy Project's Coolin Tower is BETZ Bio-Trol 88P. For all the treatment chemicals used in the facility, a D.E.M. Form 101 is attache