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CHEMOURS COMPANY - FAYETTEVILLE WORKS
POLYMER
PROCESSING
AID
PROCESS
06-12-2017
VINYL
ETHERS
PROCESS
OUTFALL
002
r' n
tRIVERDISCHARGE
POINT
Family of fluorocarbon surfactants used to produce
ChemoursTM Teflon® and Kalrex® fluoropolymers,
as well as sales to outside producers of
fluoropolymers.
Newest line of products are called "Generation X"
or "GenX" which replaced APFO.
Initial commercial production was under an USEPA
TSCA Consent Order.
06-12-2017
HFPO
Dimer Acid
F1. i�de
Hydrolysis
Reactor
PPA Process
NH4OH
FRD
903 -
"GenX"
NH3
FRD-901
902
Neutralization
Reactor
905
Neutralization
Reactor
FRD-902
"GenX"
FRD-905
"GenX"
Family of fluorocarbon compounds used to produce
DuPont products such as Nafion® membranes,
Teflon®, Kalrez®, Krytox®, and Viton®, as well
as sales to outside customers.
• Hexafluoropropylene oxide (HFPO)
• Perfluoronated vinyl ethers - PMVE, PEVE,
PPVE, EVE, and P SEPVE
• Precursors - MMF, RSU, and Freon® E-2
-12-201'
FWbromonomers (FPS) / Nafion0 Membrane (IXM)
VE -No
PSEPV
Polymer
06-12-20
er
E-2
Dispersions
Nafion® Membranes
Products
HFP
HFPOHFPO
02
SO3
HFPO PAF/ HFA
TFE
COF2
DMC — MMF 71RSU
-South
VE -No
PSEPV
Polymer
06-12-20
er
E-2
Dispersions
Nafion® Membranes
S M y
• Vinyl Ethers Process generates HFPO Dimer
Acid during the PPVE campaign.
• HFPO Dimer Acid (FRD-902) is the raw
material used to produce the GenX products.
• HFPO Dimer Acid abatement system was
installed/started in November 2013.
• Since that start-up it is estimated the HFPO
Dimer Acid concentration during normal PPVE
operation to be approximately 100 ppt at Lock
& Dam No. 1
6-12-2017
A I . I