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IEA Project �: 951-005
Client Name: E. I. duPont de Neumors, Inc.
Date
Sample # Client ID Parameter Results Analyzed
=====____-- ---------------------------
-----------------------------------------------
1 001 Temperature 26.6 C 02/06/91
1 001 pH } 7.52 02/06/91
Sample ID:
A. Purgeable (Volatile Organic) Fraction, EPA Method 603/8240
Number of chemicals detected in Fraction 1
Fraction STORET Number 84085
STOREY Compound Quantitation
Number Limit Target
11,
Pollutants to be analyzed for: (ug/L)
i
34210 Acrolein 100
34215 Acrylonitrile 100
34030 Benzene 5
32101 Bromodichloromethane 5
32104 Bromoform 5
34413 Bromomethane 10
32102 Carbon tetrachloride 5
34301 Chlorobenzene 6
34311 Chloroethane 10
34576 2-Chloroethyl vinyl ether 10
32106 Chloroform 5
34418 Chloromethane 10
32105 Dibromochloromethane 5
34496 1,1-Dichloroethane 5
34531 112-Dichloroethane 5
34501 l,l-Dichloroethylene 5
34546 trans-112-Dichloroethylene 5
34541 112-Dichloropropane 6
34704 cis-1,3-Dichloropropene 5
34699 trans-1,3-Dichloropropene 5
34371 Ethylbenzene 8
34423 Methylene chloride 5
34516 1111212 -Tetrachloroethane 7
34475 Tetrachloroethylene 5
34010 Toluene 6
34506 1,1,1 -Trichloroethane 5
34511 1,112 -Trichloroethane 5
39180 Trichloroethylene 5
34488 Trichlorofluoromethane 10
39175 Vinyl chloride 10
Quantitation
Limit*
*If different from quantitation limit target
Page 2 of 9
Concentration GC/MS
Detected Confirmation?
0
(ug/L) Yes No
<100
X
<100
X
<5
X
<5
%
<5
X
<10
%
<5
X
«6
X
<10
X
<10
X
<5
X
<10
X
<5
X
<5
X
<5
X
<5
X
<5
X
<6
X
<5
X
<5
X
<8
X
<5
X
<7
X
<5
X
<6
X
<5
X
<5
X
<5
%
<10
X
<10
X
Compound
Probable
Molecular
Wei ht
Estimated
Concentration
u L
Library Match
Probability
�
Retention
Time (RT)
Min
Identification Basis
Check all that a I
Scan
Number
Library
Match
Manual
Infer retation
RT
None detected
Complete only if non—targeted compounds are present:
Internal Standard
Retention
Time
z
N
0
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Sample I.D.: 951-005
B. Acid Extractable Fraction, EPA Method 8270 Page 4 of 9
Number of chemicals detected in Fraction 1
Fraction STORET Number 45582
STOREY Compound Quantitation Quantitation Concentration GC/MS
Number Limit Target Limit* Detected Confirmation?
Pollutants to be analyzed for: (ug/Lj (ug/L) (ug/L) Yes No
i
34452 4-Chloro-3-methylphenol 10 <10 X
34586 2 -Chlorophenol 10 <10 X
34601 2,4-Dichlorophenol 10 <10 X
34606 2,4 -Dimethylphenol 10 <10 X
34616 2,4-Dinitrophenol 50 <50 X
34657 2-Methyl-4,6-dinitrophenol 24 <24 X
34591 2-Nitrophenol 10 <10 X
34646 4-Nitrophenol 50 <50 X
39032 Pentachlorophenol 50 <50 X
.34694 Phenol 10 <10 X
34621 214,6 -Trichlorophenol 10 <10 X
*If different from quantitation limit target
1991
Compound
Probable
Molecular
Weight
Estimated
Concentration
(ug/L
Library Match
Probability
%
Retention
Time (RT)
Min
Identification Basis
Gheck all that appli
Scan
Number
Library
Match
Manual
Inter retation
RT
Unknown
155
24
N/A
12.62
X
949
i
won
Complete only if non—targeted compounds are present:
Internal Standard
Retention
Time
Min
Na htholene — d8
1 1.18
*Not all quantitated results can be accompanied by complete ID. Further
investigation should be discussed with your Client Services Representative.
N
C
'D
u
C. Base/Neutral Fraction, EPA Method 8270 Page 6 of 9
Number of chemicals detected in Fraction 4
Fraction STORET Number 45583
v
STORET Compound Quantitation Quantitation Concentration GC/MS
Number Limit Target Limit* Detected Confirmation?
Pollutants to be analyzed for: (ug /L) (ug/L) (ug/L) Yes No
34205 Acenaphthene 10 <10 X
34200 Acenaphthylene 10 Jf' <10 X
34220 Anthracene 10 <10 X
39120 Benzidine 50 i <50 X
34526 Benzo (a) anthracene 10 <10 X
34247 Benzo (a) pyrene 10 <10 X
34230 Benzo (b) fluorantheno 10 <10 X
34521 Benzo (ghi) perylene 10 <10 X
34242 Benzo (k) fluoranthene 10 <10 X
34278 Bis (2-chloroethoxy)methan 10 <10 X
34273 B19(2-chloroethyl)ether 10' <10 X
34283 Bis(2-chloroisopropyl)ethe 10 <10 X
39100 Bis(2-ethylhexyl)phthalate 10 <10 X
34636 4-Bromophenyl phenyl ether 10 <10 X
34292 Butyl benzyl phthalate 10 <10 X
34581 2-Chloronaphthalene 10 <10 X
34641 4-Chlorophenyl phenyl ethe 10 <10 X
34320 Chrysene 10 <10 X
34556 Dibenzo(a,h) anthracene 10 <10 X
34536 112 -Dichlorobenzene 10 <10 X
34566 1,3 -Dichlorobenzene 10 <10 X
34571 1,4 -Dichlorobenzene 10 <10 X
34631 3,3-Dichlorobenzidine 20 <20 X
34336 Diethyl phthalate 10 <10 X
34341 Dimethyl phthalate 10 <10 X
39110 Di -n -butyl phthalate 10 <10 X
34611 2,4-Dinitrotoluene 10 <10 X
34626 2,6-Dinotrotoluene 10 <10 X
34596 Di-n-octyl phthalate 10 <10 X
34346 1,2-Diphenylhydrazine 10 <10 X
34376 Fluoranthene 10 <10 X
34381 Fluorene 10 <10 'X
39700 Hexachlorobenzene 10 <10 X
34391 Hexachlorobutadiene 10 <10 X
34386 Hexachlorocyclopentadiene 10 <10 X
34396 Hexachloroethane 10 <10 X
34403 Indeno(11213-cd)pyrene 10 <10 X
34408 Isophorone 10 <10 X
34696 Naphthalene 10. <10 X
34447 Nitrobenzene 10 <10 X
34438 N-nitrosodimethylamine 10 <10 X
34428 N-nitroso-di-n-propylamine 10 <10 X,,
34433 N-nitrosodiphenylamine 10 <10.
34461 Phenanthrene 10 <10 X `
34469 Pyrene 10 <14' �., ZX 19�
34551 1,2,4-Trichlorobenzene 10 <16 %3 '' X
*If different from quantitation target kr
2. Other base/neutrals (up to 10 highest peaks)
N
Page 7 of 9
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Page 7 of 9
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951-005-1
D. Organochlorine/Organophosphorus Pesticides and PCB's"
Number of chemicals detected in Fraction 0
Fraction STORET Number 00188 "
Page 8 of 9
STOREY Compound Quantitation Quantitation Concentration Confirmation?
Number Limit Target Limit* Detected Dual Column GC/MS
1.Pollutants to be analyzed for: (ug/L) (ug/L) (ug/L) Yes No Yes No
Organochlorine Pesticides/PCB's: EPA Method 8080 ,
39330 Aldrin 0.05 <0.05 % X
39337 alpha -BHC 0.05 <0.05 X X
39338 Beta -BHC 0.05 <0.05 x x
34259 Delta -BHC 0.1 <001 X X
39340 Gamma -BHC (Lindane) 0*05 <0.05 X x
39350 Chlordane 0.2 <0.2 X x
39310 4,4' -DDD 0.1 <001 X x
39320 4,4' -DDE 0.1 <061 X x
39300 4,4' -DDT - 0.1 <0.1 X x
3.9380 Dieldrin 0.02 <0902 x x
34361 Endosulfan I (alpha) 0.1 <0.1 x x
34356 Endosulfan II (beta) 0.1 <001 x x
34351 Endosulfan sulfate 0.7 <0.7 x x
39390 Endrin 0.06 <0.06 x x
34366 Endrin aldehyde 0.2 <0.2 x x
39410 Heptachlor 0.05 <0005 X x
39420 Heptachlor epoxide 0.8 <0.8 x x
39480 Methoxychlor 0.5 <0.5 x x
39755 Mirex 0.2 <0.2 x x
39400 Toxaphene 2.4 <2.4 x x
34671 PCB 1016 0.5 <0.5 x x
39488 PCB 1221 0.5 <095 x x
39492 PCB 1232 0.5 <0.5 x x
39496 PCB 1242 0.5 <0.5 x x
39500 PCB 1248 0.5 <0.5 x x
39504 PCB 1254 1.0 <100 x x
39508 PCB 1260 1.0 <1.0 x x
Organophosphorus Pesticides EPA Meth8080
39560 Demeton 2.5 <2.5 x
39540 Parathion (ethyl) 0.6 <0.6 x
E. Herbicides, EPA Method 8150
Number of chemicals detected in Fraction 0
Fraction STORET Number 00148
STORET Compound Quantitation Quantitation Concentration Confirmation?
Number Limit Target Limit* Detected Dual Column
Pollutants to be analyzed for: (ug/L) (ug/L) (ug/L) Yes No
39730 214-D 12 <12 X-
39045 Silvex 2 <2 x
39740 21415-T 2 <2 x
*If different from quantitation limit target
Wo
Organic Analytical Information:
Organic Fraction Method
Page 9 of 9
GC Operating Conditions Surrogates(Spikes)
Extraction Column Description Compound Recovery
Batch Continuous Length x ID, Film Thickness, g
6olumn Type, Carrier Gas & Flow
Rate, Temperature Program
Purgeable 8240 75m x 0.53mm, 3.Oum,dB-624 1,2-Dichloro 100
15ml/min. He, 20(5min.) ethane -d4
6C/min. 150 (2 min.) Toluene 97
BFB 97
9c id Extractables 8270 % 30m x 0.32mm, 0.25um, dB -5 2 -Fluoro- 48
He 30 cm/sec, 40(4 min), phenol -d5
1OC/min.,300 (5 min.) Phenol -d5 33
214,6-Tribromo- 93
phenol
3ase/Neutral 8270 % 30m x 0.32mm, 0.25um, dB -5 Nitrobenzene -d5 75
:xtractable He 30 cm/sec, 40(4 min), 2-Fluorobiphenyl 66
1OC/min.,300 (5 min.) Terphenyl-d14 70
?urgeable 603 % 30m x 0.53mm, 1.0 um
Stabilwax He 10 ml/min, 40 C (2.9 min.)
20 C/min, 150 C (4 min)
IC/MS Library size (number of reference spectra)s Volatiles 42,000+1 Semivolatiles 49,000+
Metals and Other Chemicals
'umber of chemicals detected in Fraction
'raction STORET Number 78240
TORET Compound quantitation
umber Limit Target
ollutants to be analyzed for: (ug/L)
1104 Aluminum 50
1097 Antimony 50
1002 Arsenic 10
1012 Beryllium 25
1027 Cadmium 2
L034 Chromium 5
L042 Copper 2
L051 Lead 10
L900 Mercury 0,2
L067 Nickel 10
L147 Selenium 5
L077 Silver 5
L092 Zinc 10
.her Inorganics:
007 Barium 500
1940 Chloride 1000
1720 Cyanide 20
X951 Fluoride 100
:f different from quantitation limit target
alytical Laboratory Representative:
Quantitation
Limit*
(ug/L)
Concentration
Detected
(ug/L)
260
<50
<10
<25
<2
<5
<2
<10
<0.2
<10
<5
<5
80
<500
110,000
<20
76,000
gned
Date: �3I Z2 9 �
cility er or in Responsible Charge (OCR) s p li'1, � ,� t,�/ /, �.
certify at this report i# accurate and complete to the best of my knowledge.
gned: 1 , �ti rF.I�C� .< Dates