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HomeMy WebLinkAboutNC0004961_RBSS CSA Report_Figures_20150818JI I C LVI.H I IVIV IVIHI+ DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA URIC AUGUST 2015 FIGURE 2-1 'F o�y ;. \ - _ EN�RG� Q oos- . S Y Piz ow _ � '� �\\\ / ( '�\\���� Yy�{}r• Wit" � {,'Sj _r!' � i ;. .. . - - ASH BASIN SECONDARY CELL �. \ ` RC,oR14 qR/� l F / \ II IIII \ \ � � = � �� L.l• (fi/.�l I I /. ��, �\\ � �\ \ \ �)>>>I J Z_- \\� hi 11111 ASH BASIN \�\\ \�'>IIIv�/j%��-'f((.,I:�. ' I PRIMARY CELL j\ III IIIlIII II i '/ / /. r I `. /�/%\ � I II I I I I I I III � 1 . � / J I l ii/// �. � 111 II I•�l. / // � _ •,���\�� - -. i \ J /� - II III III �i� j ✓ (-. / .;�'�/r.1 I l \` . \�'`11 r t v /// ( �� �1/,)�4) I , _ \IIII I l ii� _ / /. / . (. , - �� •! � �/ /�Jl� � �// /jl ;l \ \\ � I . � � � I \ ' . ' i � i% ` - •�' ill >1 J - _--___"' ____� _` -�j} /' (IIII' � \\ � �� \\\'��� �\;I��lll(..( l((� /l 11 / -�� \\ l l\ ' / 1 I /(%'�%��/'/ //r���= �� �\�� \\�• / //j/l%/�\�\\1.. I \ � �-_— ,� 1 // � ►� ll� >i�r J. ( 1 I \ \. \ 1 \ � � / r � ' ee �/ /� \� \\ 1I CINDER \ STORAGEI)I IJI IJJ / /J / / l z I� ✓ j// / PI /�r,., :,�----��-_.,-�1�1n �i/��-%�`-_/ �r��• ((( � -, � ti ) .�. ) e � ,,/( ,,/ %�lilt \\\\\ 1 /l ASH )) \ /r. yam�tl//(/�,1 \+'3.\\I 1/ \ STORAGE / / / / \ -\ \ \ 1. \\Illlli j,a\\.o\�I/ HORSESHOE BEACH RD �10, Am VA I 1 IlC _ -J /o V111� 41 �r(��� o ;I. l -.�// /Illpl I \ ;' I v � - �� I l/ / 1 (� \\�\ `��"` � / ( . ��•I 1(� � � � � .�, (_ - \ \ \ _ 1 I /� f � , � / / 1 1 l \ �`� � I \ � =�- �a\III ({ ` . / � l/i��' )������ � .\,t (/ - l /, �� \\�\ \\I\ �, . � �L.•1 1\ ." '�i/(JI )):�I`!/ _--!• '�1, / •� ��\\\�\\\ ,h ��c\\\\\ \\\\ �\ \ ,,�//A//�/ / I \ ll( III 1. / �� 1 \ \\ I } I I � , / -� IIIt.� J/ \\� .\ - ��\\ \\\\ • � \� \\ \ -� � //�f-� ���., � �Y.j �(� ///,� 1 11 IIII/, • '�- /i/� I \\ �//� I(,I<�' �.� �f /\\ \ ti., \\�\\\\\ y\\\\ . � _� /` � _' I / / \I \ \e �/ � \�t \ \ i�� � / /�/ \J � � . �% � ! � \• \R�t III 1r\ I•I1 \ � -`.���'%-----���/ 1 i_ /ii f, �_� .\ I I ,I '. '-owl I I \ / PI i \�\ ✓// �.�� � • \k )) I MOUNTAIN \\ / �e\\\ \�t111\\ ISLAND LAKE Its 1 • 1 � ....i NAb, LL NTION A THE,�,NECK 4} RIVERBEND C t STEAM STATIQX ,juC►statiori r Nm— 'r RRENT WAST.t BOUNDARY (APPROX) it • • J � i,`f • • r D a Power V i llage • i JAI � • •r � • • • • • r i NOTES: I. SOURCE: USGS TOPOGRAPHIC MAP - PAW CREEK, CREATED 1948. SCALE (FEET) 500 0 500 1000 F�2 1948 PAW CREEK TOPO DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN a 11 Ir Ir ------------- r� DATE AUGUST 2015 FIGURE 2-3 GASTON COUNTY, NORTH CAROLINA FN PRIMARY ASH �• .. '- \ POND •� \ � YARD SUMP PUMP LOAD CENTER \ \ 1 // I� .` ;� .: �11� I'I I'IIIII I •: / \ �: I �:. • I I I I I I I I I I I I I I .`.. . YARD DRAINAGE SYSTE • �• - .. •" - "� I � I I III I i 1 ' ��r \ \ \' III IIII I IIII - .` �. ..-_......., .., Q�op •_ ,`. � - -_� - .;III IIII �II� � .. �WG� ,,,l�I III IIIII II d YARD DRAINAGE SYST� M DISCHARGE PIPE h;lil II I! I !I,i ASH BASIN PFtw� VP`�� `' - e J/ I I I I I I PRIMARY CELL LPG P \sv �VO Olt 41, ASH SLUICE PIPING \\\ CINDER �\ DOZER FUELING STATION STORAGE �\ INTAKE CANAL �. -' \\ \ I / / //,� \� TRACTOR SHED I I I / _ J/ / ` `mil -', �,; \� \� �/' LOCOMOTIVE FUELING STATION I .I I r`\ \`-i ✓%� __-�i!! o = _ _ _ _ OLD JUNCTION HOUSE � I I ,- _ i/ ��� / �/ �___—�------------- —�� s. /. SEWAGE TREATMENT SYSTEM OIL STORAGE HOUSEI:' �, ELECTRICAL STORAGE t3 FORMER COAL PILE :1,1\\�/ / /,� _ /, / / /°�// //� /�I / /,� —/ =. •' k- BUILDING e } \ I,, I I I \� J/// o - . I I ' I / � I NEW CRUSHER HIOUSE\���� /��/ _� t \ \� I ASHSTORAGE r _ LOADING DOCK li'li , I —J � \ \ ) \ \ \ COAL TREATM.ENT BUILDING; USED MINERAL OIL TANK LIGHT -OFF FUEL OIL TAW a/,/!��' / J-\ SHIPPING CONTAINER � � � I 1 1\\\\\\L\` COMBUSTION TURBINE -POWER HOUSE CABLE TRAY \, \ . i;- COAL LOWERING WELL GROUNDWATER REMEDIATION SHACK - \ OLD SAMPLE HOUSE 1 I - - JET WAREHOUSE y INSTRUMENT HOUSE J / 10C COMBUSTION TURBINE WAREHOUSE \ i 11C COMBUSTION TURBINE \ \� 1 -., _ - " .•\ is OLD CRUSHER HOUSE 11C HEAT RECOVERY STEAM GENERATOR LOWER WAREHOUSE 9C HEAT RECOVERY STEAM GENER TO, . � -A-- - MAIN FUEL OIL � � / / -/ 8C COMB �I U8 CAR DUMPER BUILDING/// �_. � ' .: i-:.• I I 1 / / _ _, t_ ---..�%" I lI I ��COMBUSTIQN POWER U9 .. ; \ _ \ `\ \ I ► I I I l 1 � -; �I ^ / 1 I I TURBINE HOUSE U10 SULFURIC ACID SYSTEM I 1 LARK MAINTENANCE MAIN GENERATOR _ - II / 1. CENTER URE TEM / / r- fi / STEP-UP AND AUXILIARY / - 11 TRANSFORMERS \ 1100 kV SWITCHYARD 9C COMBUSTION— '�,/ PRECIPITATORS ,`- TURBINE ADMINISTRATIVE BUILDING °j` MAINTENANCE SHOP OUBLE WIDE TRAILER �t<Q' RIVERBEND BREAK ROOM ® WATER TOWER INSTRUMENTAND - \ \` \ \ �� �i -* STEAM STATION - GUARD SHACK CONTROL SHOP 0��. / �ACKFLOW PREVENTER _ `'� / ° ° ° / "L HOUSE MICROWAVE BUILDING �, rUVFL . • 1 \ \ � �,, , .� III � \ . • � 1 .. . - ,,// // \ �\ RELAY HOUSE Vn `DISC o1o\ 230 kV SWITCHYARD / ���•.1/I�li I ,1 1 \ o �`` 1 1-�1 \\ 1 1 / / r / /° v. \\ \�e\� �Q' DISCHARGE CANAL \ �\ lllllllll/ l II II POND �0, COWAN'S FORD WILDLIFE REFUGE (TOWN OF HUNTERSVILLE PARK OR NATURE PRESERVE) COWAN'S FORD WILDLIFE REFUGE (TOWN OF HUNTERSVILLE PARK OR NATURE PRESERVE) G4 00'111� za RESIDENTIAL (ZONING - RURAL (R)) \\v > RURAL HILL NATURE RESERVE (TOWN OF HUNTERSVILLE PARK OR NATURE PRESERVE) MOUNTAIN ISLAND LAKE 4�1 N't - X \4\7)_1 COWAN'S FORD ASH BASIN WILDLIFE REFUGE SECONDARYCELL (TOWN OF HUNTERSVILLE PARK OR NATURE PRESERVE) Al, I \�\\\�� 1 /j/ / ;� ,:, ,•+:� ���, '�\;: \\1\\Ill•I:�)1 �riliil4��'�} ��1tt���:�-�, Z AL u xk, L ASH BASIN 'o Jill PRI MARY CELL V: N 10/0 1 ....... .. .. k/, V Ix 4M lilIII Nil) .7-�XN ASH r�TORAGE N N c7 - 02 J r HORSESHOE BEND BEACH RD J JIM f 1;✓7N 7_ r jj 4j• STONEWATER (ZONING -SINGLE FAMILY RESIDENTfALtR-12)y x\ T _4 A� vlk vflrk 46 #WWI INDUSTRIAL /11 V, (Zo LIGHT INDUSTRIAL (L-1)) q I INV N, 01' V '77 mA_ eW M, 1xv ITM V41 HIII, All v kc 1�� AV w DUKE ENERGY CAROLINAS, LLC L 1� RIVERBEND STEAM STATION ASH BA RIWERBE VI) ST :A M STAI Ill] 4 FLI DW SC HEM NrIC ' Bra iindwat w Rem W Y 14, Oil Water 2014 ie on Water ie �aretor 0.01 MGD 1.D1 Stormwater from MID lioof Drains & 111. P wing DAB Storm ivat er from Co at MID Pile O.00L I U.IDi G.b01 MI■ Geneial 'hint MGD MGD Drinking hater 6ysteni [StyafMt.IIDIII'Saplil Sanitary 0 Sanitary Ilrstem IVest ewat er 0.0 is MID _ D. D21 StDimwaterfromPendAreas& MGD I Upgradientwatershed turbine gloom Sump a 0.I25 3.015 M iD vfGD Bailer Room Suml I4 Y 0.015IVGD 011 End Pit Suml i 0.0 t5 MGD 0.16 CIA WIGD IAGD Catuw)aRiver Intake funnel PlantChiller [Wem FIDws Ire opproximateg averages which hare a high variability ai i a duly basis 1.1 Eva mration 6 M in 1011tratiun Ash Basin Surface Sei!)age hit ermitt ant O.1119 Iv4GD ' 0,1 0 r Ifall 001 MID rrack 1 Sol iper Somp GrDiindweter 0.O6 MGD yard Dralu lump D.131 MID D.1B5 Intermittent MID Dotfall 1 D02 Outfall 002A Mauntaili IslanS lake ' - { ' i . _. r � .ice • 4 r� ♦. y �+'� ./� �' • _ • r i to i , 004 • 20kU X+500 20mm 5153 ASH 02 �.., Figure 5- Known sample of ash for comparison. .i •� s a lam. 20kV X 1, 000 10r,•m 5153 ASH 03 IMJ IAMWA AIM O ,p 80°!°D y 70%, C1 0 60% u 0% 20 106 LI % — Volcanic Ash Shale Fly Ash Bottom Ash 5i RAI Fe Ca ■ ether Major Elements Mirror Elements ■Trsee Elements NOTES: 1. FIGURE WAS OBTAINED FROM THE EPRI COMPARISON OF COAL COMBUSTION PRODUCTS TO OTHER MATERIALS - CHEMICAL CHARACTERISTICS, FIGURE 3-1, PG 3-2, EPRI, FINAL REPORT, SEPTEMBER 2010. F)l ELEMENTAL COMPOSITION FOR BOTTOM ASH, FLY ASH, SHALE, AND VOLCANIC ASH DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 3-2 GASTON COUNTY, NORTH CAROLINA 1000 _ .1 00 J 10 0 1 0.1 a) 0.01 0.001 b-- 0.0001 0.0000,1 As Ba cd cr pb Hg Se Ag OMininwm aximum P�eraemkie Element TICi_P regalattxy Limit 1 W` Rrrtil� NOTES: 1. FIGURE WAS OBTAINED FROM THE EPRI COMPARISON OF COAL COMBUSTION PRODUCTS TO OTHER MATERIALS — CHEMICAL CHARACTERISTICS, FIGURE 9-1, PG 9-1, EPRI, FINAL REPORT, SEPTEMBER 2010. F)l COAL ASH TCLP LEACHATE CONCENTRATION VS REGULATORY LIMITS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 3-3 ASTON COUNTY, NORTH CAROLINA 100000 10000 1000--- E. loo Ic 10 c� 0 1 C � i].1 0 0.01 0.001 NOTES: 1. EPRI 2009B. • } As Ba Cd Cr Pb Fitt Se Ag Sb Be B Co Cu Mn Ni TI 1V Zn ERA Residential Soil Screening Level Element *Concentrations less than Fly Ash Range (101 and 901 percentile) method detection limits. TRACE ELEMENTS IN FLY ASH VS SOIL (EPRI) DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 3-4 ASTON COUNTY, NORTH CAROLINA 100000 10000 - f � � 1000 - E l oo I � I 0 I 'C 'V 0.1 0.01 0.001 As Ba Cd Cr Pb Hg Se Ag5b Be B Cu Mn N1 TI V Zr EPA Residential Soil Screening Level Element `Concentrations less than Bottom Ash Range (10' and 90' percentile) method detection limits. NOTES: 1. EPRI 2009B. TRACE ELEMENTS IN BOTTOM ASH VS SOIL (EPRI) F MI offifth DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE AUGUST 2015 FIGURE 3-5 " BR O O KSHIRE BLVD (SECONDARYCELL) (PRIMARYCELL) ASH BASIN CINDERSTORAGEASHSTORAGE RIVERBENDSTEAM STATION H O R S E S H O E N C 1 6 STEAM PLANT C O P P E R H E R O N C O V E LEE AUBURN MARIN TURNOUT B R A X T O N G A T E LUCIA RIVERBEND B R O O K R I D G E W IL L O W S P R I N G R I V E N D E L L C E D A R T H E L O O P L A U R E L G L E N JOHNSON S U M M E R W I N D R O C K Y B E E C H B L U F F CRICKET HOLLOW COVEPOINTE L A K E H A V E N S T O N E W A T E R B A Y H O R S E S H O E L A K E K E S T R E L OAKFOXRIDGE WOODWARDRIDGE N O R T H C E N T U R I O N N I V E N S C O V E S T O N E W A T E R B A Y WATERFORDVIL L A G E G L E N W O O D W I N D S R I V E R S I D E HOLDS W ORTH HIDDENPINES H O L B E R T E D D I E N I C H O L S NC 16 W I L L O W T R E E NC 16LUMBER HORSESHOE BEND BEACH NECK RD NEC K R D JOHNSON-D A V I S RD BALLYPATLN DRAKE COVE RD J O H N S O N - D A V I S R D D U K E A C C E S S R D N E C K R D A R T H U R A U T E N R D 1 USGS RECEPTOR MAPDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE AU GUST 2015 4-1 P A T H : G :\P R O J E C T S \D U K E _E N E R G Y \A S H _B A S I N _W E L L S _R E C E P T O R S \C L I F F S I D E \M X D \R B S S _F I G _4 _1 _2 0 1 5 0 7 2 3 _M C M .M X D - U S E R : M M U R C H I S - D A T E : 7 /2 3 /2 0 1 5 NOTES:1. ASH BASIN WASTE BOUNDARIES AND ASH STORAGE AREA BOUNDARIES ARE APPROXIMATE.2. PRIVATE WELLS LOCATIONS ARE APPROXIMATE.3. USGS 7.5-MINUTE SERIES TOTOGRAPHIC BASEMAP COPYRIGHT:© 2013 NATIONAL GEOGRAPHIC SOCIETY, I-CUBED4. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a).5. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS LAKE NORMAN SOUTH, NC AND MOUNTAIN ISLAND LAKE, NC-VA.6. DUKE ENERGY PROPERTY BOUNDARY WAS SUPPLIED BY DUKE ENERGY REAL ESTATE.7. INFORMATION PERTAINING TO IDENTIFIED WATER SUPPLY WELLS IS INCLUDED IN TABLE 4-1 Legend DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY 0.5 MILE OFFSET FROM ASH BASINCOMPLIANCE BOUNDARY STREAM "SURFACE WATER INTAKE REPORTED PRIVATE WATER SUPPLY WELL N 500 0 500 1,000SCALE (FEET) Brookshire Blvd (SECONDARYCELL) (PRIMARYCELL) ASH BASIN CINDERSTORAGEASHSTORAGE RIVERBENDSTEAM STATION H O R S E S H O E D RSTEAM PLANT RD C O P P E R C V H E R O N C O V E D R LEE ST AUBURNCV MARIN CT TURNOUTDR B R A X T O N G A T E C T LUCIA RIVERBEND HWY B R O O K R I D G E D R W IL L O W S P R I N G T R L R I V E N D E L L C T C E D A R S T L A U R E L G L E N C T JOHNSONST S U M M E R W I N D L N R O C K Y L N CRICKET HOLLOW COVEPOINTE L A K E H A V E N D R S T O N E W A T E R B A Y L N H O R S E S H O E L A K E R DOAKSTFOXRIDGE L N WOODWARDRIDGE DR S O U T H C E N T U R I O N L N N I V E N S C O V E R D WATERFORD DRVIL L A G E G L E N W A Y W O O D W I N D S D R R I V E R S I D E D R HOLDSWORTH DR HIDDENPINES DR H O L B E R T L N E D D I E N I C H O L S D R W I L L O W T R E E L N N C 16 H W Y L U M B E R L N HORSESHOEBENDBEACH RD 1 NECK RD NEC K R D JOHNSON-D A V I S RD BALLYPATLN DRAKE COVE RD J O H N S O N - D A V I S R D D U K E A C C E S S R D N E C K R D A R T H U R A U T E N R D RECEPTOR MAPDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE AU GUST 2015 4-2 P A T H : G :\P R O J E C T S \D U K E _E N E R G Y \A S H _B A S I N _W E L L S _R E C E P T O R S \R I V E R B E N D \M X D \R B S S _F I G _4 _2 _2 0 1 5 0 7 2 3 _M C M .M X D - U S E R : M M U R C H I S - D A T E : 7 /2 3 /2 0 1 5 NOTES:1. ASH BASIN WASTE BOUNDARIES AND ASH STORAGE AREA BOUNDARIES ARE APPROXIMATE.2. PRIVATE WELLS LOCATIONS ARE APPROXIMATE.3.ORTHOPHOTOGRAPHY IS FROM NC ONEMAP GIS ONLINE SERVICE.4. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a).5. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS LAKE NORMAN SOUTH, NC AND MOUNTAIN ISLAND LAKE, NC-VA.6. DUKE ENERGY PROPERTY BOUNDARY WAS SUPPLIED BY DUKE ENERGY REAL ESTATE.7. PROPERTY BOUNDARIES WERE SUPPLIED BY THE GASTON COUNTY AND MECKLENBURG COUNTY GIS OFFICES.8. INFORMATION PERTAINING TO IDENTIFIED WATER SUPPLY WELLS IS INCLUDED IN TABLE 4-1 Legend DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY 0.5 MILE OFFSET FROM ASH BASINCOMPLIANCE BOUNDARY STREAM PROPERTY LINES REPORTED PRIVATE WATER SUPPLY WELL N 500 0 500 1,000SCALE (FEET) r, 5 NOTES: 1. ASH BASIN, ASH STORAGE AREA, AND CINDER STORAGE AREA WASTE BOUNDARIES ARE APPROXIMATE. 2. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 3. CMP IS ASSUMED TO BE AN ABBREVIATION FOR CORRUGATED METAL PIPE. HDPE IS ASSUMED TO BE AN ABBREVIATION FOR HIGH DENSITY POLYETHYLENE. CPP IS ASSUMED TO BE AN ABBREVIATION FOR CORRUGATED PLASTIC PIPE. RCP IS ASSUMED TO BE AN ABBREVIATION FOR REINFORCED CONCRETE PIPE. 4. UNDERGROUND FEATURES PROVIDED BY STANTEC AND DUKE ENERGY. 5. PIPE LOCATION AND LENGTH SHOWN ARE APPROXIMATE. T �i J � � y , a � 1 s •� A 4�- Ar { i `` .. Y 46 1. k-y; -.'S C �*g1 ., l ;-1 r ♦-+. 1. _ r 1 _ ',� A . �� S' _�'i'i"�f a� s' f a E s 1 _ �,� • ` F �►�tY 5 .r ,•c 1�,Y'.- vit ��+�'MR ii '1`�iI•• �_1 ,�Y: - � <' � �,'.T.,�yt�f' ti '. � i Jtt' .�cf- 5 w �.° ram' a»• '� , ' _ .r M _ ""� ti F t y� .►i ter, '4'M, ' vr%i§ a'� - a •, `' , ,'.• ?� 'd ,� r°r �''�" � .a"•l' t � `�'R_" s, 6;�-�` �'- -�- y� .. �= -Z4 rY�.. .'�.i _ {.,ray • iF:~- r f �. �d ��. x /17, �_ i ik _` 40 r I .,� , J +'` ' • - r I �{ 4^�. , .yi ..yifi .y' r �.; ., ♦ -r `r< !ri i• _ .; l at _ _ � b r , � ��'� � �'r i�+� ..�' ht 'i'! s. �. �l �T'��1 f,�-�,�p�j,��� '� d 5'. �, d f _ � r2�*�t F }-4_- .8 r•��,gtC t« .L Ft _ �s - '�. + . - :' '+la'- .^r-� _ . _ 'ss.. s�`. t•fr'_. :%.•i. M `•_' ':3'. rl'. `--i ; " T:s :"':C'r' ''' 3.rL&t41,' LEGEND: N ASH BASIN WASTE BOUNDARY 1500 FT OFFSET FROM ASH BASIN WASTE BOUNDARY PIPE SEGMENT ASH BASIN UNDERGROUND FEATURES MAP DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTO N COUNTY, NORTH CARO D NA DATE AUGUST 2015 FIGURE 43 NOTES: 1. ASH BASIN, ASH STORAGE AREA, AND CINDER STORAGE AREA WASTE BOUNDARIES ARE APPROXIMATE. 2. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 3. CMP IS ASSUMED TO BE AN ABBREVIATION FOR CORRUGATED METAL PIPE. HDPE IS ASSUMED TO BE AN ABBREVIATION FOR HIGH DENSITY POLYETHYLENE. CPP IS ASSUMED TO BE AN ABBREVIATION FOR CORRUGATED PLASTIC PIPE. RCP IS ASSUMED TO BE AN ABBREVIATION FOR REINFORCED CONCRETE PIPE. 4. UNDERGROUND FEATURES PROVIDED BY STANTEC AND DUKE ENERGY. 5. PIPE LOCATION AND LENGTH SHOWN ARE APPROXIMATE. i '> �rh 111 1r t Fi! ?'y�M*' L i., .�, � �y ° P: �• � *+�\ - !�' �µ � `. � �`�* r r � ���� r � �.� � � �� �.'. � � -• Yam„ 1 � 1. � r''t.. -� - C. r .. , VF 14 s ( ,i. < '�' � i. +may :• �vC 'ri , .•-�,''!� .. ' l t li Y , ^ r, r ) rrr- r�fi kr Jr .4.1fw a" "V '.• r "fit 7 �.. � � �� . :�`` as `w�+! '�,'�, �r�4 I t + j r� � .... Z w.'i. -r 10, 41 4 R J L q 6 a 1 4 , SCALE (FEET) /00' 0 /00' 200' l" = 200' � LEGEND: N ASH BASIN WASTE BOUNDARY 1500 FT OFFSET FROM ASH BASIN WASTE BOUNDARY PIPE SEGMENT ASH STORAGE AND CINDER STORAGE UNDERGROUND FEATURES MAP DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE GASTON COUNTY, NORTH CAROD NA 44 r �k p.. F i= (i h' NOTES: 1. ASH BASIN, ASH STORAGE AREA, AND CINDER STORAGE AREA WASTE BOUNDARIES ARE APPROXIMATE. 2. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 3. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS MOUNTAIN ISLAND LAKE, NC AND ON -SITE OBSERVATIONS. ':�'. y �•. � tea• � fiv 3 ♦ � } SURFACE WATER BODIES DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTO N COUNTY, NORTH CARO D NA LEGEND: ASH BASIN WASTE BOUNDARY 1500 FT OFFSET FROM ASH BASIN WASTE BOUNDARY STREAM DATE AUGUST 2015 FIGURE 45 12 3 4 NC OneMap, NC Center for Geographic Information and Analysis, NC PROPERTIES CONTIGUOUS TOTHE ASH BASIN WASTE BOUNDARYRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE AU GUST 2015 4-6 P A T H : G :\P R O J E C T S \D U K E _E N E R G Y \A S H _B A S I N _W E L L S _R E C E P T O R S \R I V E R B E N D \M X D \R B S S _F I G _4 _6 _2 0 1 5 0 7 2 3 _V 1 0 _2 _M C M 2 .M X D - U S E R : M M U R C H I S - D A T E : 7 /2 3 /2 0 1 5 NOTES:1. ASH BASIN WASTE BOUNDARIES AND ASH STORAGE AREA BOUNDARIES ARE APPROXIMATE.2. PROPERTY BOUNDARIES WERE SUPPLIED BY THE GASTON COUNTY AND MECKLENBURG COUNTY GIS OFFICES.3.ORTHOPHOTOGRAPHY IS FROM NC ONEMAP GIS ONLINE SERVICE.4. INFORMATION PERTAINING TO IDENTIFIED PROPERTIES IS INCLUDED IN TABLE 4-2 Legend ASH BASIN WASTE BOUNDARY PROPERTY BOUNDARY N 500 0 500 1,000SCALE (FEET) Tectonic Map Explanation (NOTE: Subsurface continuation of terranes shown in lighter shade of same color) Triassic -Jurassic basins (patterned subs:nrface; rifting 3f Fangaea) Igneous Rocks _190-179 Ma dikes sjVs. & flaws rRifting of Pangaea) 285-265 Ma granitoidplutons rModern age dates) 325-285 Ma granitoidplutons rModerrn age dates) 350-325 Ma granitoidplutons rModerrf age dates) 380-355 Ma granitoidplutons rModern age dates) O410-80 Malplutons Likely Ordovician plutons (no rile dates) ©Ordoviciar plutons (Modern age dates) Greenstone and arTtp,'ribolite (Ne3prvterozoic to Ordovician) of arc, VORB, and continental affinities. Only Blue Ridge units shown, includes Catoctin Frn. (VA) S. Hillabea Greenstcane (AL -GA). Uiframafic rocks (Neaproterozoic to Ordovician) 700-530 Ma are -related granitoids (Carolina superterrane) -735 Ma rift -related a;kalic pfutons (Faded rifting 3f Rodinia) Laurentian Platform & Rifted Margin Clastic Wedges Allegha.nian (Mississippian -Pe) Acadian and iVeoacadian (Late Den -"rly Mississippiarn) Jermisan Ghent (Al) (Early to Middle Devonian) Talladega belt (AL -GA) O Fossilifereous Erin Slate (early Mississippian) Lay Darts Formation (Middle Ordovician? to Devonian?) Lower Cambrian to Lower Ordovician Laurentian margin clastic and carbonate rocks I� Rifted margin succession equivalents (iVeopro(erozcric- Early Cambrian) Wedowee Group(?) (AL) (Ordovician oryoc,nger) Tcaconian Martinsburg -Tuscarora rCaradoc to Llandoveary) Blo._jntian-Sevier Roakrvart Mineral Bluff (Murphy syncline in Bice Ridge) rL lan virfr L la ndeho) Necproterozoic to Ordovician(?, rocks 3f tue Nurphysyrnchre (includes Nantahala and Brasstown Formations) Platform Rocks Cambrian -Ordovician clastic to carbonate Riftet:d i"vliargin ;cocks Ne;cproterozoic-Earlyl Cambrian clastic & volcanic rocks. Includes Balfimore lerrane. Quartzite of unknown affinity in windows in Cartoogachaye terrane, Tugaloo !errane, and Sawretown Mountains window Pine Mountain Window Rock-- Wetamorphosed Paleazofc ptatform(?) cover - 1.0 -1. t GA basement rocks Basement Rocks (Blue Ridge and wes t?m Piedmont all Condw;anan affinity based on Ph isra'npes) 1.0-1.2 Ga with offer inh, ritance. erharnockile indicated by darker red. 1.8 Ga Wars Hill terrane, Terranes Accreted During Taconian Events (Laurentian affinity. distal, deep -water deposits) Hamburg cornpiex (iHc) Allochthons and u istostrornes of deop-Evator, distal margin clas!ics and carbonafes (Dauphin Formation) thrust into the fooreland over the Myerstown euxinic platform limestooe, and covered by the Martinsburg Formation. Includes greenschist facics eeauivalent clastic Cocalico Fcrrnatiort to the SE. Westminster terrane Q NeoproterotoiclCambrian-Middle Ofdovician deposition & volcanism. Sedimentary component }» volcanic. Dah►omega ,gold beit Neoproterozoic Carobrion-Middle Ordovician clastic deposition R MORa.rarc volcanism, minor 1.15 Ga j?) bascmeot. Sediment ity component »A volcanic_ Contains detrital zircons ofpossibla Gondwanan or Penokean affinity Cowrock terrane NeoproleroroiclCambrialn clastic deposftion, ophlc 10A + vokanism, minor ?.15Gal?) basement. Sedimentary component >3-:1, volcanic. Middle Ordovician ton.ilite pluton. Cartoogechaye terrane iNeoproterozoic/° ambrian(?l clastic deposition, ophiorite (ntafic- ultramafic complexesa, & MORBlarc volcanism. minor 1. IS Ga basement. Sedimentary c3mpum?nt>volcanic. Terranes Accreted Daring Neoacadian to Alleghanian Events idistal, deep -water deposits and arc-to-MORB volcanics) Cat Square terrane MixedLaurentian B ►yva�onian affinity, post-430 Pita deposition, minor,arc-to-14ORB volconics. Tupaio+o (-Milton-Potomac-PhiladelphiaV terrane Dis at Laurentian; NeoproterozoicfCambirlan-Viddte rdavician deposition & volcanism, minor 1.15 Go bas erneni, arc-to-MORS volcanics; m-Wanges, Abundant Ordovician pleltons. Sedimentary component>> volcanic. Smith River allochthon Neoproterozoic metasedimentary and rneta volcanic rocks: Ordovician plutons. May have Laurentian and Peri-G3ndwanar► provenance. OKings Mountain (KM] terrane Mixed Laurentian & Avalonian affinity, Neoproterozoic to Cambrian(?) depositicrr with Laurentian affinity; arc volcanic rocks of peri-Gondwanan affinity. Carolina superterrane (peri-Gondwanar.) Supraffa 5rat rle trpraerustal flow grades corrrponents iVeoproterozoie deposition and arc volcanism to Ordovician (?) deposition_ Charlotte terrane lnfracrustal (high grade) cotnpcnents Neo,proterozotc deposr i3n and are volcanism. Brunswick (Charleston) terrane U Rocks of largely unknown composition and provenance (likely peri-Gondwanan) Wiggfns-Suwannee suture Alleghanian deformation obscured by failed riftin and deposition of Triassic -Jurassic sediments otgthe South Georgia basin, Joins East Coast magnetic anomaly. Suwannee terrane (Gondwanan provenance) (units and configurations after Thomas. 19H) Ordovician -Devonian scdi'menlaryrocks Neoproterozoic Cambrian folsic volcanic rocks Supracrus(at flow grades components Neoproterozoic deposition and volcanism to Ordovician deposition. Middle Proterozoic Rokelides basement and African(?) crust (central Appalachians;. .-. rs:...,_ �� : �~ «- .* 1 �a�-� - a er r� Rj��•01 V. Carte�rsvill u GA � +c. # � YO � r by 11EC - ! -,� � f,� `���:,, �f^��,�� �✓���� ►A TC • re rite Gr. r V loop AePAN, 1k V. 0 -,.1 A - �4 1 � �, �� •C)�. efl- b . •Oi�'� • -'�}�• •�S�' ��,'i � - _ • Nlli�l P 's \yip+ - tb AIL • w"-.4 •'-•'' '"'�``•-.O• a Q•-• .O ►�'•. lay •w.�� 1�� _ - ■ - � o � � ' O_ ,�► o �,a as - - - o �' r ti ®� � - At/ • � O r . w- a. �Y rr r� +Pw s R- • ,. 0- w O.� �V� F - • i .0N ZN x � � r9 `-i. e -r Alabatn a9nell . vi��� gr fro p V .............. FL ViT1 '-' -q'� '� q V1 -e ofi-, -o ar•1• -_., .!►.�i �1Col(>ltnbta 1 I V L F\ D L 1 V L ) Nr— NI arolinr', �--� N. o - ti • e. 'fit 1s • c+�i+ y r7 -.. -. c, 71 Q � � ON I AV -. • ;�� � ��- •�� Abbreviations are S— JILHI I JIHI IVIV!f -"war d Symbols Aa - Alto allochthon (GA) BBw - Brasstown Bald window (GA) / d '�' -• Ci �� «-+ -t+ b •- `rJ •, r Av-Avondalemassit PA l �_ • • - ( ) brow -Dog River-Qao iha window (At -GA) c� �q Crt. tern: - Carloogaehaye terrane (GA-tytC) / 1r b - GBMw -Greif Ba15am Mountains window (MC) 6-k ; � �' Cgh - HonDatomega gold belt (PA) GMw Crandfather Mountain window .VC h'8rr - Hooey 8raoa rrp�and (PA) ( ) `- q + ■ - ry ' * ` - �ry �_ 4- ` -� h'c - Hamburg complex (PA) LCw - Limestone Cove wradow (T!+) i• .-+ - o ,_w _' b-' + � ounta'o",_ KMKin Min belt q , -MCw -Mountain City window ITN( `. �- . . a •- -_ _ MR - Minc Ridge rrassd (PA) o •• •�- . _•Z 2 ' oe0r' • Td - Toxaway Boma (SC -NC) Nw- Newton wirrdow(NC, .0- • SCw-Shhootrn Creekwirrdovs (NC -GA) TFd Tall.rlah Falls dome l'GA) g f 'A) C, • - 6 WC - west Chaster massif (PA) SMw - Sauratown Mountains window (NC) �� , �' • -' -- 4 • - L� ' • _ Wm - Wilmington complex .GE -PA) TC+e - Tuckaleecace Cove, Crades Covc. `se .p Q, ©- "o « Wr- WhiWrereertrant (SC) and Wear Cove windows (THY) / IN, 11 0-o`' .o--'^ •a- NaTE. The Warne fault or f. is not used wish E - Ecfaglte locality s1` .. - O o- frames of faults in hea Valley and Ridge nr Plareau_ ft,i `�.,: •, r ~' rfajo subsuriase boundary -ft. mft 4140 u R Subsurface boundary data �- onacrortagn.Lls f y Dextral strike -slip fauh ,lides�w� C 81S = Chtsap.ake Bay impact structure U ��— (X-VA) / 7i rfrrust fault Inner Piedmont Structure nentti Mormal fault 30 o extent ofsa►n al Salt Flow line (7) derived fnm ............... .... iAr"r<gAy wreed„ aenmagnefs data rraees of anticlinal hirges o - rAhughpmy Pf&®au WV -PA -NY) � IV Ca o 100 I kilometers 100 I miles NOTES: 1. HATCHER, R. D. JR., BREAM, B. R., AND MERSCHAT, A. J., 2007, TECTONIC MAP OF THE SOUTHERN AND CENTRAL APPALACHIANS: A TALE OF THREE OROGENS AND A COMPLETE WILSON CYCLE, IN HATCHER, R. D., JR, CARLSON, M. P., MCBRIDE, J. H., AND MARTINEZ CATALAN, J. R., EDS., 4-D FRAMEWORK OF CONTINENTAL CRUST: GEOLOGICAL SOCIETY OF AMERICA MEMOIR 200, P. 595-632. Flow the darived from ? ` ;speculated thrustfaul. (AL -GA border) mineral Fnea-lon Speculated sibsurface extent cf the Central Pledmort suture her eath Carolina supertarram SE of the Abbeville thrust sheet (SC NC) 77-- ' O 76 33" 75°. 340 Af- AIlatoo ia fault (.-PA) Agr- Augusta fault (GA -SC) Asr Ascauga fault (GA-sC) BAP - Box Ankle fault (GA) BF.`- Bartlerts Fcrryfauh (AL -GA! Bs.- Bogertown shear zone �Nc-SC) CFAf- Craale of Forestry in America fault I'NC) CGMf - Chunky Gal Wountain faun (GA -MC) GY Greenbrier fault (W TN) Ghl-SHr- Gold Hill -Silver WE fau.ts (NC -SC) GRF- Coat.4ocf fault (Ai -GA) GSF- Great Smoky fault 'NC -TN -:;A) Hf- Haye_501ei hutt'locally the lavetuLs surure) (GA -NO HMV - Po►st3n Mountain fault (TN -VA) 1101-iron Mountain fault [TN -VA) KMsz -flings Mountain shear zone (NC -SC) LFf- Linville Fats fault (VC) MU- Miller Cove fact, and equivalents (TiV-GA) MSF- Mill Spring fault (GA -SC --NC) NCF- fYutbish Creel fault (NC -VA) PG-HV- Pleasant G.-ove-Huntrngton Valley shear zone ^-MLi) PMf - Paris Mountain fault (segment of Brindle Creek fault) (SC) Rsa" - Rosemont shear zone (PA) SFr- S.4opc Fork fault (►YC) SW- Six A+fle fault (SC --Ale) SMtf - Sturrpho3se ilountain fault (SC -NC) Spr- Spotsfrvaaia fault (VA) SR'- Soque River fault (GA --NC) SKI - Stone Wail line fault (AL -GA) YB! - Yellow Breeches thrust(PA) 35 TECTONOSTRATIGRAPHIC MAP OF THE SOUTHERN AND CENTRAL APPALACHIANS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 51 GASTO N COUNTY, NORTH CARO U NA Riverbend Steam StationProperty Line Lake Norman Mountain Island Lake C a t a w b a R i v e r REGIONAL GEOLOGIC MAPDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION AUGUST 2015 5-2 G :\P r o j e c t s \D u k e _E n e r g y \A s h _B a s i n _G W _A s s e s s m e n t \G e o l o g i c _S i t e _V i c i n i t y _M a p s \M X D s \F i g _5 _ 2 _R i v e r b e n d _S i t e _V i c i n i t y _G e o l o g y _M a p _ 2 0 1 5 0 7 1 6 .m x d DATE FIGURE 5,000 0 5,000 10,000SCALE (FEET) N GASTON COUNTY, NORTH CAROLINA Notes:Source: Geologic Map of the Charlotte 1° x 2° Quadrangle, North Carolina and South Carolina, 1988, R. Goldsmith, D. J. Milton, and J. W. Horton, Jr., USGS. Metamorphosed quartz diorite and tonalitemqd SOIL Regolith ZONE unsaturated zone _ Water tatYie REGOLITH Regolith RESIDUUM saturated zone TRANSITION ZONE WEATHERED BEDROCK r% f� UNWEATHERED BEDROCK r phi ♦ FRACTURED BEDROCK ♦ SHEET JOINT ol r � r � t� BEDROCK ' STRUCTURE FRACTURE NOTES: 1. HARNED, D.A. AND DANIEL III, C.C. 1992. THE TRANSITION ZONE BETWEEN BEDROCK REGOLITH: CONDUIT FOR CONTAMINATION?, P. 336-348, IN DANIEL, C.C., III, WHITE, R.K., AND STONE, P.A., EDS., GROUNDWATER IN THE PIEDMONT: PROCEEDINGS OF A CONFERENCE ON GROUND WATER IN THE PIEDMONT OF THE EASTERN UNITED STATES, OCTOBER 16-18, 1989, CLEMSON UNIVERSITY, 693P. F)l INTERCONNECTED TWO MEDIUM PIEDMONT GROUNDWATER SYSTEM DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 5-3 GASTON COUNTY, NORTH CAROLINA A LAND SOIL SURFACE 0 SAPROLITE c, a TRANSITION ZONE �%D���O�D�)p� (f t'CJQG :� f BEDROCK CIO 1 a) Foliated/Layered Bedrock LAND SOIL SAPROLITE i i INDISTINCT ' TRANSITION ZONE BEDROCK b) Massive/Plutonic Bedrock NOTES: 1. HARNED, D.A. AND DANIEL III, C.C. 1992. THE TRANSITION ZONE BETWEEN BEDROCK REGOLITH: CONDUIT FOR CONTAMINATION?, P. 336-348, IN DANIEL, C.C., III, WHITE, R.K., AND STONE, P.A., EDS., GROUNDWATER IN THE PIEDMONT: PROCEEDINGS OF A CONFERENCE ON GROUND WATER IN THE PIEDMONT OF THE EASTERN UNITED STATES, OCTOBER 16-18, 1989, CLEMSON UNIVERSITY, 693P. F)l CONCEPTUAL VARIATIONS OF THE TRANSITION ZONE DUE TO ROCK TYPE STRUCTURE DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE 5-4 GASTON COUNTY, NORTH CAROLINA Slope Aquifer Boundary and TopograpEc Divide mmmmmmm Discharge Bomdanj - - - - - - - Compaitment (G) Boundai77 ................. Water Table Fractures Groundwater Flow Direction NOTES: 1. LEGRAND, H.E. 2004. A MASTER CONCEPTUAL MODEL FOR HYDROGEOLOGICAL SITE CHARACTERIZATION IN THE PIEDMONT AND MOUNTAIN REGION OF NORTH CAROLINA, A GUIDANCE MANUAL, NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY, GROUNDWATER SECTION, 50P. F�2 PIEDMONT SLOPE -AQUIFER SYSTEM DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE AUGUST 2015 FIGURE 5-5 ") ") ") ") ") ") ") ")") ")") ")")")") ") ") ") ") ") ") ")") ")") ") ") ") ") ") ") ") ") ") ") ") MOUNTAIN ISL AND LAKE mgb DOgm DOgm DScgb DScgb DScgb mqdmqd mqd mqd mqd mqd mqd mqd mqd mqd mqd Metadiorite Gneiss Metadiorite Metadiorite Metadiabase Metadiorite Metadiorite Metadiabase Metadiorite MetadioriteMetadiorite MetadioriteMetadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite Metadiorite MetadioriteMetadiabase MetadiabaseMetadiorite Metadiorite SITE GEOLOGIC MAPDUKE ENERGY CA ROLINA S, LLCRIVERBEND STEAM STATION ASH BASINGASTON C OUN TY, NORTH CAROLINA DATE FIGURE AUGUST 2015 6-1 NOTES:1. ASH BASIN WASTE BOUNDARIES AND ASH STORAGE AREA BOUNDARIES ARE APPROXIMATE..2. ORTHOPHOTOGRAPHY IS FROM NC ONEMAP GIS ONLINE SERVICE.3. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a).4. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS CHESNEE, NC-SC, AND BOILING SPRINGS SOUTH, NC-SC.5. DUKE ENERGY PROPERTY BOUNDARY WAS SUPPLIED BY DUKE ENERGY REAL ESTATE.6. BASED ON GEOLOGIC MAP OF THE CHARLOTTE 1' x 2' QUADRANGLE, NORTH CAROLINA AND SOUTH CAROLINA (GOLDSMITH, MILTON, AND THORTON, 1988)7. SERVICE LAYER CREDITS: NC ONEMAP, NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS, NC 911 BOARD N Legend GEO LO GY (DS cgb) Gab bro of the Concord Plutonic Suite -Gabbro, norite, gabbronorite, and hornble ndegabbro; major minerals are plagio bclase, bothclinopyroxene and orthopyroxene, andhornblende, olivine or quartz (DO gm) Metagranite an d M etagranodiorite - Verylight gray to p inkish -gray, m ediu m- to co arse-grained, foliated, metamo rphosed biotite granite,biotite granodiorite, and hornblende-biotitegranite at M ountain Island, N .C.; coarse-grainedphase is characterized by euhed ral, zonedplagioclase crystals and mosaics o f highlysutured quartz grains (m gb) Me tagabbro - Dark, coarse-grained;abundant am phibole replaces o livine andpyroxene, although relicts o f these m ineralsoccur; ep idote is com mon , biotite and spinel m aybe present; pla gioclase is less ab undant than themafic minerals; quartz is rare or absent (m qd) Me tam orpho se d Q uartz Diorite andTonalite - G ray, usually m ediu m- to co arse-grained, generally foliated ro ck comp oseddominantly of plagioclase, quartz, biotite,hornblende, and epidote . Bio tite, hornblende, andepidote co mmon ly associated in clots replacingoriginal mafic phenocrysts; clots may be smearedout, thus definin g foliationOUTCROPPINGS Metadiabase Metadiorite TOP-OF-ROCK AT B ORINGS ")Gneiss ")Metadiabase ")Metadiorite Contacts - Solid where approximate; dotted whereconcealed DUKE EN ERG Y PRO PERTY BO UND ARY ASH BAS IN WA STE BOU NDARY ASH BAS IN CO MPL IAN CE BOU NDA RY ASH BAS IN CO MPL IAN CE BOU NDA RYCOINCIDENT WITH DU KE ENE RGYPROPERTY BOU NDA RY 500 0 500 1,000SCALE (FEET) +:- 4r` JWW • - r c?40, �/ t SiL jo . s-r -sue - - _- � � � - •r• ' } `F ; ,t •sue =s/ _ _ ' lool t T fit. c ►�Y ' vw _�Tt t•i_-� a���`%' �i� je - �t3�E'x(�ia',�`� _-ice_"_: f _��_��- - - - - e i { -� � .; f i ! _ _ f- _'! -2;r ;• . - - _ 1. - �r - - t�• !�1 �s 3J°; t -t - t- YT � ice-- 4 -,er —i - - - - k� _1@"� sf� ��i - �^ '. y y' - AKA ;• _4-4 rj� 1p fJ4kv _ >)t. Juk IL L�A vs lip As Y, rt vv JL #'.T mmW ifs;16, i1poo cl IN <i l - .SP S_ f LA PON rA 0� {c NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE. SCALE (FEET) 3. AS -BUILT MONITORING WELL LOCATIONS PROVIDED BY DUKE ENERGY. 4. SHALLOW MONITORING WELLS (S) - WELL SCREEN INSTALLED ACROSS THE SURFICIAL WATER TABLE. 150' 0 /50' 500' 5. SHALLOW LOWER MONITORING WELLS (SL) - BOTTOM OF WELL SCREEN SET AT THE ASH-REGOLITH INTERFACE. l" - 500' 6. INTERMEDIATE MONITORING WELLS (1) - WELL SCREEN INSTALLEDIN REGOLITH BELOW WATER TABLE AND BELOW ASH IN ASH BASIN. 7. DEEP MONITORING WELLS (D) - WELL SCREEN INSTALLED IN THE TRANSITION ZONE BETWEEN COMPETENT BEDROCK AND THE REGOLITH. 8. BEDROCK UPPER MONITORING WELLS (BRU) - WELL SCREEN INSTALLED IN COMPETENT BEDROCK IN THE FIRST 15 FEET WHERE NO TRANSITION ZONE EXISTS. 9. BEDROCK MONITORING WELL (BR) - WELL SCREEN INSTALLED IN ROCK FRACTURE ZONE WITHIN COMPETENT BEDROCK. 10. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NC DOT GEOGRAPHIC INFORMATION SYSTEM (GIS) WEB SITE. 11. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 12. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107 (a). 13. SEEP SAMPLING LOCATIONS WERE OBTAINED BY HDR USING A TRIMBLE HANDHELD GPS UNIT ON APRIL 29,2014. 14. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS MOUNTAIN ISLAND LAKE, NC. * INDICATES SEEP SAMPLING LOCATIONS WERE NOT RECORDED WITH GPS UNIT AND ARE APPROXIMATE. LEGEND: DUKE ENERGY PROPERTY BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH OR CINDER STORAGE AREA BOUNDARY STREAM TOPOGRAPHIC CONTOUR (4 FOOT) EXISTING ASH BASIN VOLUNTARY GROUNDWATER MONITORING WELL EXISTING ASH BASIN COMPLIANCE GROUNDWATER MONITORING WELL GROUNDWATER MONITORING WELL LOCATION OBSERVATION WELL LOCATION SEEP SAMPLE LOCATION SURFACE WATER SAMPLE LOCATION MONITORING WELL AND SAMPLE LOCATIONS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROB NA DATE AUGUST 2015 FIGURE 6-2 NOTES: 1. BASE MAP FROM MOUNTAIN ISLAND LAKE, N.C. AND LAKE NORMAN SOUTH, N.C. USGS 7.5-MINUTE TOPOGRAPHIC QUADRANGLES - 46_� 41-\ Aw Pow $7 ` �, r` + A ,�• �. �'" S� `a,,,�� - ,r .� �4 '+.,� f . i 1 ..a r- • `fi Y I f� `'r 1' � � �` �.� - - '� T, �' �711 . ......... Rozzelie Bridge J's 67 1 0 �Nz)�W� -00 * t 0 1 2 0 1 MILE MN low D 1000 2000 3000 4000 50M 6000 7000 FEET ----------------- ------ Topographic 1 5 0 1 KILOMETER J) .,.d . _\ p I �­j . I 611 lineament 0-02- CONTOUR INTERVAL 10 FEET I I MIL 171' I NATIONAL GEODETIC VERTICAL DATUM OF 1929 U Base map- Mountain Island Lake, N.C. and Lake Norman UTM GRID AND 1996 MAGNE11C NORTH 4711 DECLINATION AT CENTER Or SHEET South, N.C. USGS 7.5-minute topographic quadrangles TOPOGRAPHIC LINEAMENTS AND ROSE DIAGRAM DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN DATE AUGUST 2015 FIGURE GASTON COUNTY, NORTH CAROL NA 6-3 , � '� • + r: a ... a .. ' f� .%.. �.. R f� 1 a . rd el 'mil } `� t . • - t ti ' , � � : , � � • _ fn /7" kf 06 _ r AL p� ., F-"4, \\t r > r : r y h • :..� _ 1 y Jam'; - '. r � _t: . , ��. 1 ... -. .. aj(— � car '..a� - � J i � •,� � i Y ,r , �" - ��.: � � ,�::, � °� .�` s,�•.- r its x "� �� _ � � � . l : .. - Se 1 4f a� Pik �•.'�'� � r `� �v� ''1� h _ r 1 8. ,.a y r r !r , ; i 45 F r - f 3� 0 Y � v V a �" �*�:v' �- ;�..' � � � - ;i- _ . , •,�"• ?'�"j may&, •�. � I} � � get AERIAL PFiOTOGRAP kND ROSE DIAGRAM JUKE ENERGY CARC :ZIVER6END STEAM .5 f LINtA NAS, LL 4TION A -o. !< !< !< !< !<!<!< !<!< !< !< !<!<!< !< !< !< !< !< !< !<!<!< !< !<!< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !<!< !<!< !< !<!< C a t a w b a R i v e r F L O W FLOW F L O W F L O W AB2SAB2SNRNR AB6SAB6S686.73'686.73' AS2SAS2S694.09'694.09'AS3SA AS3SA 710.01'710.01' GWA23SGWA23S705.89'705.89' MW3S MW3S 645.06'645.06' MW6S MW6S 649.73'649.73' MW7S MW7S NRNR MW7SRMW7SR709.04'709.04' MW8I 707.16'MW8I 707.16' MW8S 709.86'MW8S 709.86' AB1S AB1S 685.73'685.73' AB3SAB3S706.26'706.26' AB4SAB4S705.91'705.91' AB5S AB5S 707.5'707.5' AB5SLAB5SL706.87'706.87' AB7IAB7I713.78'713.78'AB7SAB7S714.42'714.42' AB8S 656.55'AB8S 656.55' AS1S AS1S 678.17'678.17' BG1SBG1S670.96'670.96' BG2SBG2S651.82'651.82' BG3SBG3S644.96'644.96' C1SC1S653.31'653.31' C2S C2S 656.39'656.39' GWA10SGWA10S643.79'643.79'GWA1S GWA1S 661.15'661.15' GWA20S GWA20S NRNR GWA22S 712.92'GWA22S 712.92' GWA2SGWA2S645.13'645.13' GWA3S GWA3S 646.21'646.21'GWA3SAGWA3SA645.52'645.52' GWA4S GWA4S 674.17'674.17' GWA5SGWA5S710.41'710.41' GWA6S GWA6S 715.45'715.45' GWA7S GWA7S 670.18'670.18' GWA8S GWA8S 671.26'671.26' GWA9S GWA9S 648.24'648.24' MW10MW10643.74'643.74' MW11SR MW11SR 664.68'664.68' MW12MW12NRNR MW13MW13643.07'643.07' MW14MW14652.62'652.62' MW15MW15643.74'643.74' MW1SMW1S652.58'652.58' MW2S MW2S 687.03'687.03' MW4SMW4S648.16'648.16' MW5SMW5S643.55'643.55' MW9MW9647.74'647.74' OB1 OB1 707.75'707.75'OB2 OB2 675.98'675.98' S R -1 9 1 2 POTENTIOMETRIC SURFACE – SHALLOW WELLS (S)(7/8 - 10, 2015) DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE 6-5 P A T H : S :\P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A N S I B _G W _C O N T O U R _S _W E L L _C O N T O U R S .M X D - U S E R : D S O U C I E - D A T E : 8 /1 7 /2 0 1 5 LEGEND !<ASH BASIN ASSESSMENT GROUNDWATERMONITORING WELL !<ASH BASIN COMPLIANCE GROUNDWATERMONITORING WELL !<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL GROUNDWATER CONTOUR LINE DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENTWITH DUKE ENERGY PROPERTY BOUNDARY STREAM AU GUST 2015 N 500 0 500 1,000 SCALE (FEET) NR - NO READING !< !< !< !< !< !< !< !< !<!< !< !< !< !< !<!<!< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< !< C a t a w b a R i v e r FL O W F L O W F L O W FLOW AB1DAB1D666.2'666.2' AB2DAB2D678.41'678.41' AS1DAS1D675.39'675.39' AB3D 700.2'AB3D 700.2' AB4DAB4D702.91'702.91' AB5DAB5D677.13'677.13' AB7DAB7D713.48'713.48' AB8DAB8D658.58'658.58' AS2D AS2D 695.47'695.47'AS3DAS3D712.53'712.53'BG1D BG1D 674.44'674.44' BG2DBG2D647.96'647.96' BG3DBG3D644.85'644.85' C2DC2D653.38'653.38' GWA20DGWA20DNRNR GWA22DGWA22D709.29'709.29'GWA23DGWA23D704.94'704.94' GWA3DGWA3D645.5'645.5' GWA4DGWA4D673.88'673.88' GWA5DGWA5DNRNR GWA6DGWA6D714.74'714.74' GWA7D GWA7D 670.98'670.98' GWA8D GWA8D 671.08'671.08' GWA9DGWA9D653.78'653.78' MW11DRMW11DR664.59'664.59' MW15DMW15D643.84'643.84' MW1DMW1D649.95'649.95' MW2DMW2D687.39'687.39' MW3DMW3D652.45'652.45' MW4DMW4D647.32'647.32' MW5DMW5D647.66'647.66' MW6DMW6D650.63'650.63' MW7DMW7D714.4'714.4' MW8DMW8D705.55'705.55' MW9DMW9D647.93'647.93' 6 8 5 ' 6 8 5 ' 6 6 5 '6 6 5 '6 4 5 ' 6 4 5 ' 685' 685' 665' 665' 6 8 5 '6 8 5 ' 645' 645' 7 0 5 ' 7 0 5 ' 7 0 5 '7 0 5 ' 705' 705' 7 0 5 '7 0 5 ' 7 1 5 '7 1 5 ' 7 0 5 ' 7 0 5 '6 6 5 ' 6 6 5 '6 4 5 ' 6 4 5 ' S R -1 9 1 2 POTENTIOMETRIC SURFACE – DEEP WELLS (D)(7/8 - 10, 2015) DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE 6-6 P A T H : S :\P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A N S I B _G W _C O N T O U R _D _W E L L _C O N T O U R S .M X D - U S E R : D S O U C I E - D A T E : 8 /1 7 /2 0 1 5 LEGEND !<ASH BASIN ASSESSMENT GROUNDWATERMONITORING WELL !<ASH BASIN COMPLIANCE GROUNDWATERMONITORING WELL !<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL Groundwater Contour Line DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENTWITH DUKE ENERGY PROPERTY BOUNDARY STREAM AU GUST 2015 N 500 0 500 1,000 SCALE (FEET) NR - NO READING !< !< !< !< !< !< !<!<!< !<!< !< !<!< !< !< !< !< C a t a w b a R i v e r F L O W GWA23BRGWA23BR703.38'703.38' GWA7BR**GWA7BR**'' AB3BR AB3BR 583.67'583.67' AB6BRUAB6BRU663.59'663.59'BG2BRBG2BR693.83'693.83'C1BRUC1BRU549.33'549.33' GWA20BR GWA20BR NRNR GWA22BRGWA22BRNRNR GWA2BRGWA2BR645.24'645.24' GWA4BRGWA4BRNRNR GWA7BR 671.01'GWA7BR 671.01' GWA9BRGWA9BR541.34'541.34' MW15BRMW15BR643.95'643.95' MW7BRMW7BR711.76'711.76' MW9BRMW9BR648.72'648.72' GWA2BRUGWA2BRUNANA GWA1BRUGWA1BRU662.07'662.07' GWA10BRUGWA10BRU643.92643.92 7 2 0 '7 2 0 ' 7 0 0 '7 0 0 ' 6 8 0 '6 8 0 ' 6 6 0 '6 6 0 ' S R -1 9 1 2 POTENTIOMETRIC SURFACE – BEDROCK WELLS (BRU AND BR)(7/8 - 10, 2015) DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA DATE FIGURE 6-7 P A T H : S :\P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A N S I B _G W _C O N T O U R _B R _W E L L _ C O N T O U R S .M X D - U S E R : D S O U C I E - D A T E : 8 /1 7 /2 0 1 5 LEGEND !<ASH BASIN ASSESSMENT GROUNDWATERMONITORING WELL GROUNDWATER CONTOUR LINE DUKE ENERGY PROPERTY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENTWITH DUKE ENERGY PROPERTY BOUNDARY STREAM AU GUST 2015 N 500 0 500 1,000 SCALE (FEET) NR - NO READING &< &<&< &<&<&< &<&<&< ## !( !( !( !( !( !( !( !( !( !( !( !( !( !( !( C a t a w b a R i v e r AB3D AB4S AB4D AB5S AB5SLAB5D AB7SAB7DC1S RBSW001RBSW002 S-5 S-4 S-3 S-1 S-6 S-7 S-8S-2 S-9 S-10 S-11 S-12 S-13 SW-1 SW-2 ASH BASINPRIMARYCELL ASH BASINSECONDARYCELL ASHSTORAGEAREA CIN DERSTORAGEAREA SOURCE CHARACTERIZATION SAMPLE LOCATION MAP GASTON COUNTY, NORTH CAROLINA P A T H : \\S A C -S R V 0 1 \G I S \P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A R C H D _S O U R C E C H A R A C T E R I Z A T I O N _S A M P L E L O C A T I O N .M X D - U S E R : S N O R T O N - D A T E : 8 /1 7 /2 0 1 5 LEGEND: !(SEEP AND SEDIM ENT SAMPLE LOCATION !(SUR FACE WATER SAM PLE LOCATION #NCDENR MARC H 20 14 SAMPLE LOCATION &<POREWATER SAM PLE LOCATIONS ASH BASIN C OMPLIANC E BOUN DARY ASH BASIN C OMPLIANC E BOUN DARY C OINC ID ENTWITH DUKE EN ER GY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY DUKE ENERGY PROPERTY BOU NDARY STREAM DATE FIGURE AUGUST 2015 7-1 DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN N 500 0 500 1,000 SCALE (FEET) '. 4 � ": ass - ` �._ .•�: �� _.i _, . ,'. lop r. , s� .- r ��. t • - � `- r` . S � - it =i_ � �,,a . -�: f + - • f 4-4 .4 `'�{It'll •• .. -. J * 1 - -. , + -•_- iF ol C.-Ir = ti - . �yy� try - . ai � •! - • Y \ ' / �_ ', �,.K m4wW i _ _ -. 1 1 '� 1 ! - - • - by - - � r-�_ .+ �. i ,tea ' ;_ ter � •. JAIL■ - �'` T Or ` �: r� -_ t �.t • ail � - ..� �-,�� NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE. 3. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NC DOT GEOGRAPHIC INFORMATION SYSTEM (GIS) WEB SITE. 4. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 5. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L .0107 (a). 6. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS MOUNTAIN ISLAND LAKE, NC. , ` 40 . L �. . s� e SCALE (FEET) 200' 0 200' 400' + ,' e X it 4 3# NrAbc- • - • ` .�,'.t f'� �, t mot. �' lip e v r -t : �' • =* mot' {4 If � _ . � . s.� � ' � i� 1r.1��� •wit-���.#wir.y�� _ : fir: �{� 7•t+�i -JI . 4'�7js t �'�•et �� ' �� i� �� .-- _ Y. `` -, r _ '*���'fj.. giff4 �f`3',1`.4<_::F �'-if z-: �si�:�•_T�'j_�.-♦ .. � _sue .' �' �,•t • � ,1 �� =y;t� � !i i � � •r• � !" f: _ ".., '� -�1. i �" �►. �!-� - f � :l �'- �. •_.l.4 a. `t: DUKE ENERGY PROPERTY BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH OR CINDER STORAGE AREA BOUNDARY STREAM TOPOGRAPHIC CONTOUR (4 FOOT) NCDENR MARCH 2O14 SEEP SAMPLE LOCATIONS NCDENR MARCH 2O14 SAMPLE LOCATIONS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROD NA DATE AUGUST 2015 FIGURE 72 &< &<&< &< &<&< &< &<&<&<&< &< &< &<&< &< &< &< &< &< &<&< &< &< &< &<&<&< &< &< &< &<&< N C-16 Business S R -1 9 0 9 SR-1992 SR-1910 SR-1915 S R -1 9 8 8 SR-1918 SR-1945 SR-1946 SR-1989 SR-1990 S R -1 9 4 4 S R -2 2 5 3 S R - 2 0 7 4 S R -5 5 5 3 SR-1968 S R - 2 2 7 9 S R -5 5 5 1 S R - 5 5 5 2 R M P-4 5 4 4 S R -2 3 2 1 S R -3 3 2 3 SR-1916 S R -1 9 8 5 SR-1911 S R -1 9 6 1 S R -2 1 2 9 S R - 5 5 8 8 N C-16 Business S R -1 9 1 3 S R -1 9 5 7 S R -1 9 1 7 N C -1 6 N C-16 N C - 2 7 3 N C - 2 7 3 S R -5 5 1 0 SR-1912 S R -1 9 1 2 N C -1 6 NC-16 S R - 1 9 6 9 S R - 2 1 6 5 SR-2165 SR-2127 S R - 2 1 2 6 S R -2 1 2 6 SOIL ANALYTICAL RESULTS – PLAN VIEW (PSRG EXCEEDANCES) GASTON COUNTY, NORTH CAROLINA P A T H : \\S A C -S R V 0 1 \G I S \P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A R C H D _C H E M B O X _S O I L S .M X D - U S E R : R O L D E N - D A T E : 8 /1 7 /2 0 1 5 LEGEND &<ASH BASIN ASSESSMENT GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENTWITH DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY DATE FIGURE AUGUST 2015 8-1 DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN N Sample Dept h (ft )58.5-60 68.5-70SoilSoil Cobalt 13.5 17.3Iron18,600 16,000Vanadium33.6 34.9Manganese477575 GWA -5D A naly t e (mg/kg) Sample Dept h (ft )13.5-15 23.5-25SoilSoil Cobal t 34.7 20.1Iron23,200 19,000Vanadium73.8 59.2Manganese813296 GWA -7D A nalyt e (mg/kg) Sample Depth (ft )7-8Soil Cobal t 73.8Iron58,900Vanadium209Manganese1,700 GWA -7S A naly t e (mg/kg) Sample Dept h (ft )8.5-10 18.5-20SoilSoil Cobal t 87 102Nickel*DNE 151Iron54,200 36,400Vanadium80.1 33.5Manganese9591,410 GWA -8D A naly t e (mg/kg) Sample Dept h (ft)1-1 3.5-5SoilSoil Iron *DNE 109,000Arsenic*DNE 3.5 JCobalt38.7 19.8Iron62,500 *DNEVanadium143148Manganese1,560 937 GWA -9D A nalyt e (mg/kg) Sample Dept h (ft )43.5-45 53.5-55SoilSoil Cobalt 7.3 J 14.7Iron12,300 J 21,000Vanadium29.2 58.5Manganese446 J 615 MW-7BR A naly t e (mg/kg) Sample Dept h (ft )3.5-5Soil Cobalt 37.9Iron26,000Vanadium55.4Manganese656 MW-9D A nalyt e (mg/kg) Sample Dept h (ft )33.5-35 43.5-45SoilSoil Cobalt 17.6 15.9Iron27,400 36,700Vanadium91128Manganese9051,270 OB-1 A naly t e (mg/kg) Sample Dept h (ft )38.5-40 48.5-50SoilSoil Cobal t 36.1 16.8Iron41,000 24,900Vanadium13080.2Manganese1,950 938 OB-2 A nalyt e (mg/kg) Sample Dept h (ft )28.5-30 33.5-35SoilSoil Cobal t 34.8 38.9Iron31,700 55,200Vanadium88.2 133Manganese1,090 2,940 GWA -1D A naly t e (mg/kg) Sample Dept h (ft )53.5-55Soil Cobal t 75Iron41,300Vanadium81.6Manganese1,950 A B-4S A naly te (mg/kg) Sample Depth (ft)43.5-45 48.5-50 58.5-61.5AshSoilSoil Arseni c 20.9 *DNE *DNECobalt*DNE 36.1 63.6Nickel*DNE *DNE 167Iron3,390 42,400 19,000Vanadium9.9 58.1 40.4Manganese*DNE 485 3,320 A B-4D A nalyt e (mg/kg) Sample Dept h (ft )3.5-5 28.5-30 48.5-50 58.5-60 63.5-65AshAshAshSoilSoil Arse ni c 14.2 55.4 40 *DNE *DNEArsenic*DNE *DNE *DNE 3.5 J 3.7 JCobalt3.8 J 8.2 J 8.4 16.2 6 JIron6,130 13,500 19,100 36,600 37,100Vanadium15.3 46.4 39 119 141Manganese*DNE *DNE 98.1 135 108 A B-5D A nalyt e (mg/kg)Sample Depth (ft)3.5-5 13.5-15SoilSoil Cobalt 6.6 J 17.4Iron48,800 36,400Vanadium11874.4Manganese335574 MW-15D A naly t e (mg/kg) Sample Depth (ft )38.5-40 43.5-45SoilSoil Cobal t 15 12.6Iron24,100 32,300Vanadium89.4 126Manganese7131,120 GWA -2BRU A naly te (mg/kg) Sample Depth (ft)43.5-45 48.5-50SoilSoil Cobal t 25.4 10.5Iron19,000 18,200Vanadium55.8 55.5Manganese1,270 523 GWA -6D A nalyt e (mg/kg) Sample Depth (ft)8-9 13-14SoilSoil Cobalt 24.4 20.7Iron30,100 25,400Vanadium59.3 69Manganese1,840 893 GWA -10S A naly t e (mg/kg) Sample Dept h (ft)3.5-5 38.5-40 48.5-50 68.5-70SoilAshSoilSoil Arseni c *DNE 35.6 33.8 26.5Cobalt*DNE 4.5 J 4.1 J 4.1 JIron7,620 J 9,710 7,220 17,900Vanadium18.1 39.7 23.9 47.9 A B-3D A nalyt e (mg/kg) Sample Dept h (ft )13-15 20-25SoilSoil Cobal t *DNE 70.1Cobalt48.4 *DNEIron57,500 50,200Boron51.7 50Vanadium140145Manganese1,080 1,660 A B-8S A naly t e (mg/kg) Sample Depth (ft )3-5 18.5-20 23-24 27-28 34-35.5 73-75SoilSoilSoilSoilSoilSoil Cobalt *DNE 14.6 11 12.1 8 *DNEIron34,100 23,800 18,100 23,500 19,400 13,500Vanadium67.5 62.3 45.4 50.6 41.6 30.5Manganese114943626724542805 BG-3D A naly te (mg/kg) Sample Dept h (ft )3.5-5 48-49 53-54 60-62 74-75SoilSoilSoilSoilSoil Arsenic 5.5 J *DNE *DNE *DNE *DNECobalt*DNE 14.6 8.5 13.8 9.2Iron36,500 17,100 16,000 20,600 14,600Vanadium89.2 43.9 40.8 58.8 37.9Manganese*DNE 290 689 1,440 975 BG-2D A nalyt e (mg/kg) Sample Dept h (ft )18.5-19Soil Iron 5,320Vanadium11.5Manganese155 GWA -3D A nalyt e (mg/kg) Sample Depth (ft )38.5-40 48.5-50SoilSoil Cobal t *DNE 3.9 JIron7,160 6,990Vanadium7 J 9.3Manganese77.7 113 GWA -22D A nalyt e (mg/kg) Sample Dept h (ft )3.5-5 8.5-10 13.5-15 23.5-25AshAshSoilSoil Arse ni c 34.9 47.8 *DNE *DNECobalt*DNE *DNE *DNE 6Iron18,100 20,400 6,380 11,500Selenium2.7 J 3 J *DNE *DNEVanadium10.6 13.3 15.2 23.3Manganese*DNE *DNE *DNE 242 C-1BRU A naly t e (mg/kg) Sample Dept h (ft )3.5-5 8.5-10 18.5-20 23.5-25AshAshSoilSoil Arse ni c 27.6 10.3 *DNE *DNECobalt4.2 3.7 3.1 J 14Iron19,600 14,300 39,000 12,800Selenium3.4 *DNE *DNE *DNEVanadium15.9 21.1 38.1 40.1Manganese10379.1 *DNE 237 C-2D A nalyt e (mg/kg) Sample Dept h (ft )3.5-5 33.5-35 73.5-75 83.5-85.5 88.5-90.5AshAshAshSoilSoil Arseni c 69.2 31.9 33 *DNE *DNECobalt11.4 8.4 7.5 5.1 5.2Iron9,290 5,240 9,690 14,400 7,540Selenium2.5 J 2.9 J 2.5 J *DNE *DNEVanadium67.7 44.4 37.9 35.4 17.2Manganese*DNE *DNE 74.2 170 194 A S-1D A naly t e (mg/kg) Sample Depth (ft )33.5-35 38.5-40SoilSoil Cobal t 6.9 18.6Iron5,230 7,710Vanadium9.9 14.2Manganese336210 GWA -23D A naly te (mg/kg) Sample Dept h (ft )3.5-5 33.5-35 43.5-45 53.5-55 58.5-60AshAshAshSoilSoil Arsenic 101 61.2 67.2 8.6 *DNEAntimony2.2 J *DNE *DNE *DNE *DNECobalt13.3 9 9.9 5.2 8.3Iron8,340 6,820 8,360 16,600 11,100Selenium2.9 J 3.2 J 3.1 J *DNE *DNEVanadium95.7 52.1 56.5 46 21Manganese*DNE *DNE *DNE 127 793 A S-3D A nalyt e (mg/kg)Sample Depth (ft )3-4.5 18.5-20 23.5-25 28.5-30 30-31.5AshAshSoilSoilSoil Arse ni c 40.6 62.7 *DNE *DNE 10.9Cobalt9.6 11.2 5.9 6.1 3.7Iron6,010 6,270 J+12,200 12,900 14,300Selenium2.9 J 3 J *DNE *DNE *DNEVanadium54.1 84.2 33.8 37.3 44.4Manganese*DNE *DNE 313 276 85 A S-2D A nalyt e (mg/kg) Sample Dept h (ft )15-19 24-26 32-35 34-36SoilSoilSoilSoil Cobal t 25.5 5.8 J 4.4 J 3.1 JIron38,700 10,200 8,190 4,950Selenium5.6 J *DNE *DNE *DNEVanadium62.9 19.2 17.3 *DNEManganese367269168231 GWA -4S A nalyt e (mg/kg) Sample Dept h (ft )5-6 14-15 24-25 30-31 34-35 44-45SoilSoilSoilSoilSoilSoil Cobal t *DNE 5 J 22.8 12.1 13.9 9.9Iron32,200 26,800 28,200 20,000 19,300 13,500Selenium*DNE *DNE *DNE 4.7 J *DNE *DNEVanadium89.2 70.2 75.8 59.7 53.3 38Manganese*DNE 226 1,140 518 921 817 BG-1D A nalyt e (mg/kg) Sample Dept h (ft )3.5-5 8.5-10 23.5-25 28.5-30AshAshSoilSoil Arse nic 26.7 68.3 *DNE 24.6Antimony*DNE 2 J-*DNE *DNECobalt8.3 11.8 J+*DNE 4.7Iron6,790 8,240 7,830 21,200Vanadium40.9 77.8 58.2 56.3Manganese*DNE 88.5 *DNE 119 A B-7D A naly t e (mg/kg) Sample Depth (ft )18.5-20Soil Arseni c 35.1Cobalt8.3Iron16,400Selenium2.4 JVanadium66.9Manganese158 A B-7S A naly t e (mg/kg) Sample Dept h (ft )40-41.5 45-46.5SoilSoil Cobal t *DNE 5 JIron9,880 16,300Vanadium1931.1Manganese131184 GWA -20D A naly t e (mg/kg) SCALE (FEET) 2,000 0 2,000 4,000 NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW mg/L: MILLIGRAMS PER LITERµg/L: MICROGRAMS PER LITERBOLD: EXCEEDS INDUSTRIAL HEALTH STANDARDUNDERLINED & ITALICS: EXCEEDS PROTECTION OF GROUNDWATERBOLD, UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER A nalyt e CA S No.NC PSRG Ind1 NC PSRG Prot GW1 Aluminum 7429-90-5 100,000 NSAntimony7440-36-0 94 0.9Arsenic7440-38-2 3 5.8Barium7440-39-3 44,000 580Beryllium7440-41-7 460 63Boron7440-42-8 46,000 45Cadmium7440-43-9 200 3Chromium*16065-83-1 100,000 360,000Cobalt7440-48-4 70 0.9Copper7440-50-8 9400 700Cr(VI)18540-29-9 6.3 3.8Iron7439-89-6 100,000 150Lead7439-92-1 800 270Manganese7439-96-5 5,200 65Mercury7439-97-6 8 1Molybdenum7439-98-7 1,200 NSNickel7440-02-0 4,400 130Nitrate14797-55-8 100,000 NSSelenium7782-49-2 1,200 2.1Silver7440-22-4 1,200 3.4Strontium7440-24-6 100,000 NSThallium7440-28-0 2.4 0.28Tin7440-31-5 100,000 10,000Vanadium7440-62-2 1,200 6Zinc7440-66-6 70,000 1,200* Chromium standard shown is f or C hromium III f or comparison.No av ailable standard f or Total C hromium. A ll units shown in mg/kg.1 - North Carolina DENR Inactiv e Hazardous Sites Branch - Preliminary Soil Remediation Goals (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater PSRG shown f or comparison. 1 12 I 3 4 5 I 6 I 7 8 AS -ID AS-2D AS-31D Sample De th ft 3.5-5 33.5-35 73.5-75 83.5-85.5 88.5-90.5 Sample Depth ft 3-4.5 1 18.5-20 23.5-25 28.5-30 30-31.5 Sample Depth ft 3.5-5 33.5-35 43.5-45 1 53.5-55 58.5-60 Ash Ash ,ash Soil Soil Ash Ash Sail Soil Sail Ash Ash Ash Sail Soil Ana' e / k Ana Ilyte / k Ana /k Arsenic 69.2 31.9 33 "DNE *DNE Arsenic 40.6 62.7 'DNE '°DNE 10.9 Arsenic 101 61.2 67.2 866 *DNE Cobalt 11.4 84 7.5 51 5.2 Cobalt 9.6 11.2 5.9 6.1 3.7 Antimony 2.2] *DNE *DNE *DNE *DNE Cobalt 13.3 9 9.9 52 83 Iron 9290 5240 14400 7540 Iron 6010 9270]+ 12200 12900 14300 _9690 Iran 8340 6820 8350 16600 11100 Selenium 2.5] 29] 2.5.1 DNE DNE Selenium 2.91 33 DNE *DNE *DNE Selenium 2.9] 3.2] 3.1 ] DNE DNE Vanadium 67.7 44.4 37.9 35.4 17.2 Vanadium 54.1 84.2 33.8 37.3 44.4 Vanadium 95.7 52.1 56.5 46 21 A manganese "DNE 'DNE Z4.2 170 194 Man aneseI *DNE "DNE 313 276 85 ian anese *DNE I *DNE I *DNE 1 127 1 793 SOUTHWEST NORTHEAST 800 r 800 =i III _. f WTmmill-- ----------------------------- 700 WA_ 4B z 0 a w w G WA-4D Sample a th ft 118-119.5 PWR Anal a I /k mg/ � Iql ran 3,970 Manganese 21Z 500 ' ' 0 GWA-46R Sample Depth (ftj 121.5-122.1 Rock Anal to (mg/ k Iron 1280 200 400 GWA-4S Sample Depth fit 15-19 24-26 32-35 34-36 Soil Soil Soil Soil Ana /k Cobalt 25.5 5.87 4.4 J 3.13 Iron .36700 10200 8190 4950 Selenium 5.61 'DCJE 'DNE 'DNE Vanadlum 62.9 19.2 17.3 *DNE Manganese, 367 269 168 2.31 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION 800 1000 1200 DISTANCE (ft) SECTION A SCALE: HORIZ 1 "=100' FIG 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 1400 1600 NOT FOR CONSTRUCTION m 2000 I141111 N N I 00 Ld ry D 0 L1 Ld Z J 2 U Q 60 --J 500 2200 DUKE ENERGY CAROLINASILIC DUKE ENERGY.. GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA ANALYTE NC PSRG Ind' NC PSRG Prot GW' ALUMINUM 100,00 NS ANTIMONY 94 0.9 ARSENIC 3 5.8 BARIUM 44.000 580 BERYLLIUM 460 63 BORON 46,000 45 CADMIUM 200 3 CHROMIUM* 100 000 360,000 COBALT 70 0.9 I COPPER 9.400 700 Cr(VI) 6.3 3.8 IRON 100,000 ! 150 PLEAD 800 270 I MANGANESE 5,200 65 I MERCURY 8 1 MOLYBDENUM 1,200 NS NICKEL 4,400 130 NITRATE 100,000 NS SELENIUM 1,200 2.1 SILVER 1.200 3.4 STRONTIUM 100.OQ NS THALLIUM 2.4 0.28 TIN 100.000 10.000 VANADIUM _ 1,200 6 ZINC*** 70,000 1,200 *Chromium standard shown is for Chromium III for comparison. No available standard for Total Chromium. All units shown in mg/kg. 1- North Caroilina DENR Inactive Hazardous Sites Branch - Preliminary Soil Remediation Goals (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater PSRG shown for comparison. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION <3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOW PSRG: PRELIMINARY SOIL REMEDIATION GOAL FT: FEET MG/KG: MILLIGRAMS PER LITER juG/L: MICROGRAMS PER LITER BOLD: EXCEEDS INDUSTRIAL HEALTH STANDARD UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION A -A' SOLID MATRIX ANALYTICAL RESULTS D C B IA 0 1" 2" FILENAME FIGURE 8-2.1.DWG SHEET SCALE AS NOTED FIGURE 8-2.1 0 5 1.1 7 .09 ON 700 N 00 LLJ L. z 0 Q LLI > z Ld w J 2 U Q 600 2400 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 2600 2800 ISSUE DATE DESCRIPTION 3000 3200 3400 DISTANCE (ft) 3600 SECTION A SCALE: HORIZ 1 "=100' IFIC 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 3800 NOT FOR CONSTRUCTION 4000 A' NORTHEAST 1 800 GWA-9D sample Depth ft 1-1 50.5-51 _43.5-5 Soil Soil PWR Ana e f k Iron *ONE i *DNE Arsenic ° DNE 3.53 *DNE Cobalt 36.7 19.8 14.5 Iron 62500 *DNE 20700 4200 BE IA-9BR GWA-9S 700 .o J 500 4400 DUKE ENERGY CAROLINAS.LLC /� DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA ANALYTE NC PSRG Ind' NC PSRG Prot GW' ALUMINUM 100,00 NS ANTIMONY 94 0.9 ARSENIC 3 5.8 BARIUM 44.000 580 BERYLLIUM 460 63 BORON 46,000 45 CADMIUM 200 3 CHROMIUM* 100,000 360,000 COBALT 70 0.9 I COPPER 9.400 700 Cr(VI) 6.3 3.8 IRON 100,000 ! 150 PLEAD 800 270 I MANGANESE 5,200 65 I MERCURY 8 1 MOLYBDENUM 1,200 NS NICKEL 4,400 130 NITRATE 100,000 NS SELENIUM 1,200 2.1 SILVER 1,200 3.4 STRONTIUM 100.OQ NS THALLIUM 2.4 0.28 TIN 100.000 10.000 VANADIUM _ 1,200 6 ZINC*** 70,000 1,200 *Chromium standard shown is for Chromium III for comparison. No available standard for Total Chromium. All units shown in mg/kg. 1- North Caroilina DENR Inactive Hazardous Sites Branch - Preliminary Soil Remediation Goals (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater PSRG shown for comparison. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION <3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOW PSRG: PRELIMINARY SOIL REMEDIATION GOAL FT: FEET MG/KG: MILLIGRAMS PER LITER pG/L: MICROGRAMS PER LITER BOLD: EXCEEDS INDUSTRIAL HEALTH STANDARD UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH — ASH F — FILL S — ALLUVIUM M1 — SOIL/SAPROLITE; N < 50 M2 — SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ — PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR — SOUND ROCK;REC >: 85% AND RQD >— 50% CROSS SECTION A -A' SOLID MATRIX ANALYTICAL RESULTS IC Im 0 1" 2" FILENAME FIGURE 8-2.2.DWG SHEET SCALE AS NOTED FIGURE 8-2.2 LV /W 1 2 3 0 5 A 7 91 B WEST 800 N 7001 650 ' .19 5501 500 '- 0 C-1D Sample Depth ft 3.5-5 1 8.5-10 1 13.5-15 1 23.5-25 Ash Ash Soil Soil Ana to _ { k Arsenic 34.9 47..8 *DNE *DNE Cobalt *DNE *DNE *DNE 6 Iron 18100 20400 6380 11500 Selenium 271 33 *DNE *DNE Vanadium 10.6 133 15.2 233 Manganese *DNE *DNE *DNE 242 �\ I C-2D Sample Depth ft 3.5-5 8.5-10 118.5-20 23.5-25 Ash Ash Sail Soil Ana Ilyte / k Arsenic 27.6 10.3 *DNE *DNE Cobalt 4.2 33=7 3.1 J 14 Iron 19600 14300 39000 12800 Selenium 34 *DNE "DNE *DNE Vanadium 15.9 1 21.1 381 40.1 Manganese 103 1 79.1 *DNE 237 We .� 111 IIml AB-8D Sample Depth ft 90-00.5 PWR Ana Ilyte / k Cobalt 3] Iron 5590 Vanadium 11.4 Manganese 130 200 400 600 800 1000 1200 1400 DISTANCE (ft) HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION SECTION B SCALE: HORIZ 1 "=100' IFIG 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 1600 AB -SS �Sam le De th ft 13-15 20-25 Soil Soil Ana to / k Cobalt *DNE 70.4 Cobalt 48.4 '`DNE Iro n 57500 50200 Boron 51.7 50 Vanadium 140 145 Manganesel 10,60 1660 PRIMARY E I m 2000 2200 AB-5D AB-5SL AB-5S 2400 I AB- 5D ISam le lie th ft 3.5-5 1 28.5-30 1 48.5-50 7T 58.5-60 63.5-65 Ash Ash Ash Soil Soil Ana to /k Arsenic 14.2 55.4 40 *DNE "DNE Arsenic *DNE "DNE *DNE 3.51 3.71 Cobalt 3.61 8.2J 8.4 16.2 6J Iron 6130 13500 1.4100 36600 37100 Vanadium 15.3 46.4 39 119 141 Man anew *DNE *DNE I 98,1 1 135 1108 NOT FOR CONSTRUCTION DUKE ENERGY CAROLINAS.LLC /� DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA EAST 1800 1700 1650 C � C IN C4 *Chromium standard shown is for Chromium III for comparison. 00 No available standard for Total Chromium. Lv All units shown in mg/kg. W 1- North Caroilina DENR Inactive Hazardous Sites U Branch - Preliminary Soil Remediation Goals L- (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater 600 PSRG shown for comparison. Z NOTES: J U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT 2Z J = ESTIMATED CONCENTRATION <3.0 = LESS THAN LABORATORY REPORTING LIMIT Q J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOW PSRG: PRELIMINARY SOIL REMEDIATION GOAL 1550 FT: FEET MG/KG: MILLIGRAMS PER LITER pG/L: MICROGRAMS PER LITER BOLD: EXCEEDS INDUSTRIAL HEALTH STANDARD B UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER -J500 2600 ANALYTE NC PSRG Ind' NC PSRG Prot GW' ALUMINUM 100,00 NS ANTIMONY 94 0.9 ARSENIC 3 5.8 BARIUM 44.000 580 BERYLLIUM 460 63 BORON 46,000 45 CADMIUM 200 3 CHROMIUM* 100.000 360,000 COBALT 70 0.9 I COPPER 9.400 700 Cr(VI) 6.3 3.8 IRON 100,000 150 PLEAD 800 270 I MANGANESE 5,200 65 I MERCURY 8 1 MOLYBDENUM 1,200 NS NICKEL 4,400 130 NITRATE 100,000 NS SELENIUM 1,200 2.1 SILVER 1,200 3.4 STRONTIUM 100.OQ NS THALLIUM 2.4 0.28 TIN 100.000 10.000 VANADIUM 1,200 6 ZINC*** 70,000 1,200 LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION B-B' SOLID MATRIX ANALYTICAL RESULTS 0 1" 2" FILENAME FIGURE 8-3.1.DWG SHEET SCALE AS NOTED FIGURE 8-3.1 /0 1 2 3 0 5 7 .09 AB-4D Sample Depth ft 3.5-5 43.5-45 48.5-50 58.5-61.5 Fill Ash Soil Soil Ana a Jk Arsenic *DNE 209 *DNE *DNE Cobalt *DNE *DNE 36.1 63.6 Nickel *DNE *DNE *DNE 167 Iron 17600 3390 42400 19000 Vanadium 36.4 9.9 581 40.4 Man anew *DNE *DNE 485 3.320 700 650 o6 z Lt.l o Of Q � w � J LL- w 1111111Y9I61 W Z J 2 U Q 550 500 2600 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 3000 ISSUE DATE DESCRIPTION 3200 ABAS Sample Depth ft 5 3,.5-55 Soil Ana e (mg/kg) Cobalt 75 Ira n 41300 'vanadium 81.6 Manganese 1950 3400 3600 3800 DISTANCE (ft) SECTION B SCALE: HORIZ 1 "=40' IFIG 11-1 VERT 1"=10' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 4000 NOT FOR CONSTRUCTION 4200 4400 4600 DUKE ENERGY CAROLINAS,LLC /� DUKE AENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA M• 700 650 550 500 ANALYTE NC PSRG Ind' NC PSRG Prot GW' ALUMINUM 100,00 NS ANTIMONY 94 0.9 ARSENIC 3 5.8 BARIUM 44.000 580 BERYLLIUM 460 63 BORON 46,000 45 CADMIUM 200 3 CHROMIUM* 100,000 360,000 COBALT 70 0.9 I COPPER 9.400 700 Cr(VI) 6.3 3.8 IRON 100,000 150 PLEAD 800 270 I MANGANESE 5,200 65 I MERCURY 8 1 MOLYBDENUM 1,200 NS NICKEL 4,400 130 NITRATE 100,000 NS SELENIUM 1,200 2.1 SILVER 1,200 3.4 STRONTIUM 100.OQ NS THALLIUM 2.4 0.28 TIN 100.000 10.000 VANADIUM 1,200 6 ZINC*** 70,000 1,200 *Chromium standard shown is for Chromium III for comparison. No available standard for Total Chromium. All units shown in mg/kg. 1— North Caroilina DENR Inactive Hazardous Sites Branch — Preliminary Soil Remediation Goals (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater PSRG shown for comparison. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION <3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J— = ESTIMATED CONCENTRATION BIASED LOW PSRG: PRELIMINARY SOIL REMEDIATION GOAL FT: FEET MG/KG: MILLIGRAMS PER LITER pG/L: MICROGRAMS PER LITER BOLD: EXCEEDS INDUSTRIAL HEALTH STANDARD UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH — ASH F — FILL S — ALLUVIUM M1 — SOIL/SAPROLITE; N < 50 M2 — SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ — PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR — SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION B-B' SOLID MATRIX ANALYTICAL RESULTS IC IC 0 1" 2" FILENAME FIGURE 8-3.2.DWG SHEET SCALE AS NOTED FIGURE 8-3.2 LV /Fj 1 2 3 0 5 7 z 0 a w J w C NORTHWEST 750 r-- 700 650 •90 550 500 CATAWBA RIB MOUNTAIN ISLAN M 0 200 400 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 AB-4D Sample Depth (ft) 43.5-45 48.5-50 58.5-61.5 Ash Soil Soil Analyte (mg/kg) Arsenic 20.9 *DNE *DNE Cobalt *DNE 36.1 63.6 Nickel *DNE *DNE 167 Iron 3390 42400 19000 Vanadium 9.9 58.1 40.4 Manganese *DNE 485 3320 AB-4S Sample Depth (ft) 53.5-55 Soil Analyte (mg/kg) Cobalt 75 Iron 41300 Vanadium 81.6 Manganese 1950 AB-3D Sample Depth ft 3.5-5 38.5-40 46.5-50 68.5-70 Soil Ash Soil Sail Aria a /k Arsenic "DNE 35.6 33.8 26.5 Cobalt "DNE 4.5J 4.1 J 4.1 J Iron 7620 J 9710 7220 17900 Vanadium 18.1 39.7 23.9 47.9 INTERMEDIATE DAM N I AB-4D AB-4S mom — — — ----------------- MW-1 1 DR MW-1 1 SR 600 800 1000 1200 1400 1600 1800 DISTANCE (ft) ISSUE DATE DESCRIPTION SECTION SCALE: HORIZ 1 "=120' IFIG 11-1 VERT 1 "=30' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 2000 NOT FOR CONSTRUCTION EIRM WI; AB-3D I li II IAB-3S 2200 2400 GWA-7S Sample Depth (ft j 7-8 Soil Analyte (mg/kg) Cobalt 73.8 Iron 58900 Vanadium 209 Manganese 1700 GWA-7D Sample Depth (ft}' 13.5-15 23.5-25 Sail Soil Analyte (mg/kg) �uu 2600 erw DUKE ENERGY CAROLINAS,LLC /� DUKE AENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA Iran Vanadium 3000 ----__ CWA-7D 3200 LEGEND: C' SOUTHEAST -------1 750 GWA-7B GWA-7S 3400 700 650 550 500 WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >- 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION C-C' SOLID MATRIX ANALYTICAL RESULTS 0 ill2" FILENAME FIGURE 8-4.1.DWG SHEET SCALE AS NOTED FIGURE 8-4 C C LV IIIIFj 1 Sample Depth (ft)3.5-5 D Ash WEST Anal e (mg/kg) 00 Arsenic Arsenic Cobalt Iran Vanadium Manganese 14.2 *DNE 3.8 J 6130 15.3 *DNE CAT) MOL IN •! 0 200 2 AB-5D 28.5-30 48.5-50 Ash Ash 55.4 40 *DNE *DNE 8.2 J 8.4 13500 19100 46.4 39 *DNE 98.1 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 MW-1 D Mw-1 S 58.5-60 Soil *DNE 3.5 J I PRIMARY DAM 3 14 Sample Depth (ft} 3.5-5 Ash Analyte (mg/kg) 63.5-65 Arsenic 26.7 Soil Antimony *DNE Cobalt 6.3 *DNE Iron 6790 3.71 Vanadium 40.9 A r Manganese *DNE AB-613RU AB-6S AE3-5D Afi6A�SL AB-5SL z 400 600 800 1000 ISSUE DATE DESCRIPTION 23.5-25 Soil *DNE *DNE *DNE 7830 58.2 *DNE 5 28.5-30 Soil 24.6 *DNE 9 1200 1400 1600 DISTANCE (ft) SECTION D SCALE: HORIZ 1 "=100' FIG 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 NOT FOR CONSTRUCTION Sample Dep Analyte (mg Sal c Van Manc :rr 6 1 7 1 8 2000 2200 DUKE ENERGY CAROLINAS.LLC DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA f 800 D N-7BR VAW-7D 700 600 1 ' 500 2400 2600 2800 LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH — ASH F — FILL S — ALLUVIUM M1 — SOIL/SAPROLITE; N < 50 M2 — SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ — PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR — SOUND ROCK;REC >: 85% AND RQD >— 50% CROSS SECTION D-D' SOLID MATRIX ANALYTICAL RESULTS 0 1" 2" FILENAME FIGURE 8-5.DWG SHEET SCALE AS NOTED FIGURE 8-5 LV /0 1 2 3 0 5 A 7 91 F 800 700 650 4- z 0 w MW—� 500 400 0 200 400 600 800 1000 1200 1400 1600 vv DISTANCE (ft) HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION SECTION E SCALE: HORIZ 1 "=80' IFIG 11-1 VERT 1 "=40' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 NOT FOR CONSTRUCTION DUKE ENERGY CAROLINAS,LLC /� DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA ANALYTE NC PSRG Ind' NC PSRG Prot GW' ALUMINUM 100,00 NS ANTIMONY 94 0.9 I ARSENIC 3 5.8 BARIUM _ 44,000 580 BERYLLIUM 460 63 _ BORON 46,000 45 CADMIUM 200 3 _ CHROMIUM* 100,000 360,000 COBALT 70 0.9 I COPPER 9.400 700 Cr(VI) 6.3 3.8 IRON 100,000 150 PLEAD 800 270 I MANGANESE 5,200 65 I MERCURY 8 1 _ MOLYBDENUM_ 1,200 NS NICKEL 4,400 130 NITRATE 100,000 NS SELENIUM 1,200 2.1 SILVER 1,200 3.4 STRONTIUM--1 00.0Qa NS THALLIUM 2.4 0.28 TIN 100,000 10.000 VANADIUM 1,200 6 ZINC*** 70,000 1,200 C C *Chromium standard shown is for Chromium III for comparison. No available standard for Total Chromium. All units shown in mg/kg. 1 — North Caroilina DENR Inactive Hazardous Sites Branch — Preliminary Soil Remediation Goals (PSRG) Table (March 2015). Industrial Health Based Soil PSRG and Protection of Groundwater PSRG shown for comparison. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION <3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J— = ESTIMATED CONCENTRATION BIASED LOW PSRG: PRELIMINARY SOIL REMEDIATION GOAL FT: FEET MG/KG: MILLIGRAMS PER LITER pG/L: MICROGRAMS PER LITER BOLD: EXCEEDS INDUSTRIAL HEALTH STANDARD UNDERLINED & ITALICS: EXCEEDS BOTH INDUSTRIAL HEALTH STANDARD & PROTECTION OF GROUNDWATER LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH — ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >: 50% CROSS SECTION E-El SOLID MATRIX ANALYTICAL RESULTS 0 1" 2" FILENAME FIGURE 8-6.DWG SHEET SCALE AS NOTED FIGURE 8-6 /W ir iL - - - , �-It pim 0006, • Ir -L _ `e. ' • i __ a _ •�'' — - _ _ . _ ♦ .fir �, - 444 ti Av r _ l Y•E !t. � -i �'Y+_ �.�t a.. Itv' '3 r'�•• - � - - -,•, �f' s�� � 1 le jr 46. -' - - hS• \ f yt .``:'t3Y'.t�.�1 -it: �! 1.- ..'y`,f � :� �' -- � y`. �It�-�� Y � - ` _ `� f �_ � • -.-r tC J ` � '^� 1 ''. {�•1f --may^� I - � -' •t � , � � - - •f _ -I - � F _ �l t _ \ < ' J>_ i•,lT£''._r'��+�?Y�t "-�. _ mot!; a �'., � 3. t -' ' ••re - pat...:• zlet 9. It •21 �- '.�,��! ,�,s Fps �- �+ 4 PIP -- r �•' ,� a s' •'• - ^�: {� +'�rr�.s�•-�{4��_l• '1'/Tfz, --- •,* '> �i tyi. `- rsi � y.'�'�1e t_ s to �f � _S i..", i f ,� j�.1�?� ,.. .41 40 volm meow � � _ _ .I' _s• a s 1 � �� -- - �'. - - - -+= J.-♦ �• - •-a• '�.t - -, t atr``r ++`i ��� r4Z I,��s ; i'> IN ft `� r,� * 1 , � .fie-'. , • v' -i , +�- ` e� '- 4 -. - � � ' - t r ,• _ 1•,� —��1j' �-JS �} � - ,�, _ -- - � �` e -.� it — - ��S- - �,ti ' a �. - r `> 'fit �� ��_ � _ ■p ,,�•, ' • , r •� - +'�R.•f�� .r r • � . - 1� • .ice_ IR _.LC •'! _ie. NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE. 3. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NC DOT GEOGRAPHIC INFORMATION SYSTEM (GIS) WEB SITE. 4. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 5. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L .0107 (a). 6. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS MOUNTAIN ISLAND LAKE, NC. SCALE (FEET) 200' 0 200' 400' DUKE ENERGY PROPERTY BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH OR CINDER STORAGE AREA BOUNDARY STREAM TOPOGRAPHIC CONTOUR (4 FOOT) SEEP AND SEDIMENT SAMPLE LOCATION ® SURFACE WATER SAMPLE LOCATIONS fir NDPES IN -STREAM MONITORING LOCATION SEEP AND SURFACE WATER SAMPLE LOCATIONS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROD NA DATE AUGUST 2015 FIGURE 91 ARSENIC CONCENTRATIONS IN GROUNDWATERDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-1 MEAN CONCENTRATION BY COUNTY OF ARSENIC IN NC PRIVATE WELL WATER IN 2009 (µg/L)ADAPTED FROM SANDERS ET AL. (2011) Approximate location of Riverbend Steam Station Average arsenic concentration (µg/L) STATE AND FEDERAL WATER STANDARDSDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-2 PA T H : C : \ U S E R S \ M M U R C H I S \ D O C U M E N T S \ C S A S E C T I O N 1 0 - 2 \ R I V E R B E N D \ I R O N _ F O R M A T T E D . M X D - U S E R : M M U R C H I S - D A T E : 8 / 1 2 / 2 0 1 5 CONSTITUENTS OF INTEREST NEAR RIVERBEND STEAM STATION WITHTHEIR ASSOCIATED STATE AND FEDERAL DRINKING WATER STANDARDS Approximate location of Riverbend Steam Station MANGANESE AND SOIL REGIONSDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-3 MANGANESE CONCENTRATIONS IN GROUNDWATER AND SOIL REGIONS OF NORTH CAROLINA(GILLESPIE 2013) Approximate location of Riverbend Steam Station $ REGIONAL GROUNDWATER QUALITYDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-4 MANGANESE CONCENTRATIONS IN GROUNDWATER (µg/L) IN A 20-MILE RADIUS SURROUNDING THE SITEUSGS NURE DATABASE Legend $Riverbend Site Manganese (µg/L) 0.00 - 12.50 12.51 - 25.00 25.01 - 50.00 50.01 - 100.00 100.01 - 434.00 N S o u t h C a r o l i n a S o u t h C a r o l i n a N o r t h C a r o l i n a N o r t h C a r o l i n a THALLIUM DISTRIBUTION IN SOILDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-5 THALLIUM CONCENTRATIONS IN C HORIZON OF SUBSTRATEUSGS MINERAL RESOURCES DATABASE $+ $Approximate location of Riverbend Steam Station $ REGIONAL GROUNDWATER QUALITY - VANADIUMDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-6 VANADIUM CONCENTRATIONS IN GROUNDWATER (µg/L) IN A 20-MILE RADIUS SURROUNDING THE SITEUSGS NURE DATABASE Legend $Riverbend Site Vanadium (µg/L) -0.10 - 0.00 0.01 - 0.30 0.31 - 0.60 0.61 - 1.80 1.81 - 14.80 N S o u t h C a r o l i n a S o u t h C a r o l i n a N o r t h C a r o l i n a N o r t h C a r o l i n a $ REGIONAL GROUNDWATER QUALITYDUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASINGASTON COUNTY, NORTH CAROLINA DATE FIGURE AUGUST 2015 10-7 PA T H : C : \ U S E R S \ M M U R C H I S \ D O C U M E N T S \ C S A S E C T I O N 1 0 - 2 \ R I V E R B E N D \ N U R E _ R I V E R B E N D _ P H . M X D - U S E R : M M U R C H I S - D A T E : 8 / 1 2 / 2 0 1 5 GROUNDWATER PH (STANDARD UNITS) IN A 20-MILE RADIUS SURROUNDING THE SITEUSGS NURE DATABASE Legend $Riverbend Site pH 5.40 - 6.00 6.01 - 6.50 6.51 - 7.00 7.01 - 7.50 7.51 - 8.20 N S o u t h C a r o l i n a S o u t h C a r o l i n a N o r t h C a r o l i n a N o r t h C a r o l i n a . . � � I - - - - . � - - --- , I I . ;� - � , i". .;� �l _ . ,�� I -;�. N, �J, �.-4,r �i­ I,_' �� ­1 . - I � ': . � , *1 � , ..�� t , �­ ',� .., - I . , . lk . *� - P, - ..'� I - _ml lt "lo, �� - 1. t " 1. I I., . � � �1�1'1 . 4 k,��, .� 1.�. 11 11 �l I � 1. .. I , . I ,,, � t1l , . , *' I � '.4 "'. 44 V : �::, i " , . 1� _ �_ - .� � �;� , -,,� - - , ,�', I . � . o - . �- - . I 2 " ". �, A_** . ill , ,�, .�, . . . # �' �� �,, , - ­ - I * . -7 r "- " ", , �, , , f. _ . . . "T . -11 � - - , . , -f , - � .'�, � I f I __ �v , _ . 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"� - . i t q � /�' * � , , ,. - I 0, , �l ", � &;r _ .�. . i, , , �. - . . � � 4 .L � _ .. I �, - - *�_l � �� � , � - , .& . I I , . I I . . 0- I '. I r�� - - It NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATEAND ISAPPROXIMATE. 2. ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE. 3. AS -BUILT MONITORING WELL LOCATIONS PROVIDED BY DUKE ENERGY. 4. SHALLOW MONITORING WELLS (S) - WELL SCREEN INSTALLED ACROSS THE SURFICIAL WATER TABLE. 5. SHALLOW LOWER MONITORING WELLS (SQ - BOTTOM OF WELL SCREEN SETATTHEASH-REGOLITH INTERFACE. 6. INTERMEDIATE MONITORING WELLS (1) - WELL SCREEN INSTALLEDIN REGOLITH BELOW WATERTABLEAND BELOWASH INASH BASIN. 7. DEEP MONITORING WELLS (D) - WELL SCREEN INSTALLED IN THE TRANSITION ZONE BETWEEN COMPETENT BEDROCK AND THE REGOLITH. 8. BEDROCK UPPER MONITORING WELLS (BRU) - WELL SCREEN INSTALLED IN COMPETENT BEDROCK IN THE FIRST15 FEETWHERE NOTRANSITION ZONE EXISTS. 9. BEDROCK MONITORING WELL (BR) - WELL SCREEN INSTALLED IN ROCK FRACTURE ZONE WITHIN COMPErENT BEDROCK. 10. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NC DOT GEOGRAPHIC INFORMATION SYSTEM (GIS)WEBSITE. 11. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 12. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCACO2L.0107 (a). 13. SEEP SAMPLING LOCATIONS WERE OBTAINED BY HDR USING A TRIMBLE HANDHELDGPS UNIT ON APRIL 29,2014. 14. HYDROGRAPHY WAS OBTAINED FROM USGS 7.5-MINUTE SERIES TOPOGRAPHIC MAPS MOUNTAIN ISLAND LAKE, NC. * INDICATES SEEP SAMPLING LOCATIONS WERE NOT RECORDED WITH GPS UNIT AND ARE APPROXIMATE. ,,, ­:,� . . . , Y�_�'r;�'. ,�, � . I I . -, 4*40 SCALE (FEET) 150, 0 150, -500, /" = -500' I � ­­ .,,,. "�'. . - � : ::,r _��Fr';f_W,r - - I . "r 11 _.. . - . " , � :1 I � ... . j;, " ", ., ­ �: 't , �; wli�._J . .". �� I . . ­ �171, ,., T I . ' F,>, � v 'k. -V� . 1, . ' .r-: ... , I . "I q -1 �__. _%�.�� " .... I 1. 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I I � I :11 � � :?: � ,� . . �r � 1C � I �' �; , - I I ASH BASIN COMPLIANCE BOUNDARY COINCIDENT �l r WITH DUKE ENERGY PROPERTY BOUNDARY ,_,� � I � . 11 .1 I � �� �: � , � ASH BASIN WASTE BOUNDARY I "J owa"o* I ASH OR CINDER STORAGE AREA BOUNDARY ­J&.,� ,,_r4"�, ,- t- dw.� - i� 7 �, __4. . � ­ __ STREAM " - ` k I ii�l Las TOPOGRAPHIC CONTOUR (4 FOOT) Ilz "Ill 1, -0 EXISTING ASH BASIN VOLUNTARY GROUNDWATER 11 I MONITORINGWELL ­1111111 .f '. '..., , 11 I EXISTING ASH BASIN COMPLIANCE GROUNDWATER � 1� MONITORINGWELL - . ��l GROUNDWATER MONITORING WELL LOCATION - .. I I ........ . � .. � . r I � I , � ".. � - OBSERVATION WELL LOCATION I , -It, , , , , , " - , � **� - �111 , - �' - - - - - - , � . � I -, - , , � , - � - � , � I 771 -, ,_ SEEP SAMPLE LOCATION 4 I - , _ �-ltm .. 11 . 1: " '.,..,,,��, �� . '_ -�,_ � 1, 0 - _� ;e� I , .vll� - . -1-1 - � , ­ _. _, " I'll I . 1. . � r �'*' X'� i�.l _c , - - _ r �r_ _��.�-.',,' ."ki - 70 ,­ ,'�.' _­ - � ''_ � ,�� ., .. 1;'�, r 3 ­ �-.�, .- "".. .4., � _ _ SURFACE WATER SAMPLE LOCATION ,�� , - - - -1 .- � ­ ,l lz_ ,.� V­ ,� f";�;"Qi�z� *,,_ r ,�, :r- . . . 11. ll,�� 0 ­ .m ,., t I I—'. i* I Ir I . �'r 1�.- . - .�,l ­ . ---- :: , 11, �,� , . � J. . . � .1 I I ­1 "Ill r � 1* I , , � . , I 1, _% � , , ,,i4, . .. �� I , I . A.- "I I , ��� , , 1,11 I if,k- - , , — . . . . . ,:::l, I .!,. - ..,. ,� ......... I'll, 11 rrr MJ� � � 1��l ....... s" --- . ". i. I i MONITORING WELL AND SAMPLE LOCATIONS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CARODNA DATE FIGURE 10-8 FLUSH -MOUNT STEEL WELL MANHOLE COVER LOCKABLE WELL PLUG o 2'x2'X4" CONCRETE WELL PAD -EXISTING GROUND ( STEEL MANHOLE SKIRT PORTLAND CEMENT AND BENTONITE MIX GROUT SEAL TO SURFACE WELL CASING (2-INCH DIA. SCH. 40 PVC) B-INCH DIA. BOREHOLE �FERSDEEP AND BEDROCK OUTER CASING (6-INCH DIA. SCH. 40 PVC FOR DEEP AND BEDROCK WELLS) TYPICAL FLUSH —MOUNT WELL COVER SCALE: NTS 4-FT (TYP) WELL PLUG PROTECTIVE WELL VAULT WITH LOCKING COVER (2-FT MIN. HEIGHT) 2'x2'X4" CONCRETE WELL PAD / -EXISTING GROUND GROUT SEAL TO SURFACE WELL CASING (2-INCH DIA. SCH. 40 PVC) �I ----.BENTONITE SEAL N TOP OF SCREEN FILTER SAND I O 2-INCH DIA. SCH. 40 PVC SCREEN (0.010-INCH SLOT) WITH PRE -PACKED FILTER SAND THREADED PVC CAP TYPICAL SHALLOW MONITORING WELL (Single Cased) SCALE: NTS ROTECTIVE WELL VAULT 'ITH LOCKING COVER t-FT MIN. HEIGHT) 2'x2'X4" CONCRETE WELL PAD PROTECTIVE BOLLARD FILLED WITH CONCRETE AND PAINTED YELLOW —0 (TYPICAL) TYPICAL PROTECTIVE BOLLARDS SCALE: NTS PROTECTIV WITH U (2-FT U 5 in WELL PLUG PROTECTIVE WELL VAULT WITH LOCKING COVER ;RETE WELL PAD (2—FT MIN. HEIGHT) 2'x2'X4" CONCRETE WELL PAD 3 GROUND /- -EXISTING GROUND TO SURFACE I I I II I I GROUT SEAL TO SURFACE WELL CASING . SCH. 40 PVC) N w (2—INCH DIA. SCH. 40 PVC) BOREHOLE 8—INCH DIA. BOREHOLE INCH DIA. C) SET C) SETAPPROX. OUTER CASING (6—INCH DIA. PARTIALLY SCH. 40 PVC) SET APPROX. ROCK 1—FOOT INTO COMPETENT BEDROCK (V I EAL BENTONITE SEAL N EEN TOP OF SCREEN FILTER SAND SCH. 40 PVC SCREEN SLOT) WITH PRE -PACKED THREADED PVC CAP TYPICAL DEEP MONITORING WELL (Double Cased) SCALE: NTS NOTES: 1. MONITORING WELLS WILL BE CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 02C .0108 STANDARDS OF CONSTRUCTION: WELLS OTHER THAN WATER SUPPLY. 2. PROTECTIVE COVERS TO BE PAINTED BRIGHT YELLOW WITH WEATHER RESISTANT PAINT. 3. WELL TAG IDS TO BE ATTACHED TO WELL PROTECTIVE COVER WITH MECHANICAL RIVETS OR SET INSIDE FLUSH -MOUNT WELL COVER. 4. PROTECTIVE BOLLARDS (CONE -TAPERED, FILLED WITH CONCRETE, AND PAINTED YELLOW) ARE TO BE INSTALLED AS NECESSARY FOR WELLS LOCATED IN AREAS WITH NEARBY VEHICULAR TRAFFIC. 5. SLOPE 2' X 2' CONCRETE PAD SURFACE UPWARD TO PROTECTIVE COVER TO PREVENT PONDING WATER. 6. WELL ID TO BE ETCHED IN 2' X 2' CONCRETE PAD. 7. ALL CONSTRUCTION MEASUREMENTS ARE APPROXIMATE. F)� in 2-INCH DIA. SCH. 40 PVC SCREEN (0.010-INCH SLOT) WITH PRE -PACKED FILTER SAND z THREADED PVC CAP w PORTLAND CEMENT AND BENTONITE GROUT MIX IF REQUIRED BOTTOM OF BORING TYPICAL BEDROCK MONITORING WELL (Double Cased) SCALE: NTS WELL CONSTRUCTION DETAILS DUKE ENERGY CAROLINAS, LLC ALLEN STEAM STATION ASH BASIN DATE August 2015 FIGURE 10-9 100 10 9 R7 A 8.8 6.25 � 4.39 A 5.65 3.02 4.65 3.19 2,76 2.84 1.8 14 2L Standard: 10 ug/I 1.34 1.28 µg/l. 10 - 1 NTU 0. 81 0.8v 5 5 5 5 5 5 5 5 5 5 s 5 5 5 5 5 1 0 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tChromium ■ Chromium, diss (ug/1)—dr-Turbidity, field (NTU) MW-7SR DATE Chromium and Turbidity DUKE ENERGY CAROLINAS, LLC AUGUST 2015 RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY. NORTH CAROLINA 10000 1000 1710 1420 921 1000 182 634 509 100 310 2L Standard: 3GO µgJL 295 301 252 84.1 291 235 220 147 29.7 µg/L100 NTU vNV 79 21.7 72 \/ 8.19 \10.7 ® 7.73 10 ■ 10 6,92 6.95 _. 5.08 432 4.28 5.51 5.23 3.19 1 1 — Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-1.4 Feb-15 Jun-15 Oct-10 +Iron, total (ug/1) ■ Iron, dins (ug/1) —A—Turbidity, field (NTU) VW-10 DATE Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 10 486 2L Standard: 300 µg/L 138 109 87 63 67 39 62 46 38 ■ 33 30 33 28 20 ■ 14 5.07 5.44 6.13 • 3.44 2.72 / 3.53 2.41 3.34 2.48 2.05 2 2.35 .55 1.37 1 Oct-10 100 10 NTU 1 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 +Iron, total (ug/1) IN Iron, diss (ug/1) —Turbidity, field (NTU) M W-11 SR DATE Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA µg/L 100000 10000 1000 100 10 1 Oct-10 37700 30300 23000 24100 24100 19000 20600 19300 20900 16900 18300 19200 21100 /32500 21000 13500 7690 18.8 9.32 18.3 13.7 2L Standard: 300 µ lL 7.67 7.78 y 6.4 4.67 \ / 3.75' \ .3..'6'. 3.14v 3-15 2.4 2.44 100 10 NTU 1 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tlron, total (ug/I) ■ Iron, diss (ug/I) --*—Turbidity, field.(NTU) M W-13 DATE F)""Z Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 686 935 660 421 1 371 374 369 472 280 206 /,n 175 98 100 25.6 2LStandard:300µ lL 58 Y 14.4 A 12.9 µg/L 8.64 - 10 NTU 8.21 13 6.09 6.52 5.48 10 4.89 5.08 4.31 3.92 3.24 2.04 1.85 1 11 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tlron, total (ug/1) ■ Iron, diss (ug/1) —A—Turbidity, field (NTU) M W-14 DATE Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 465 399 274 4 227 168 230 160 198 2L Standard: 300 paS/L 100 44 1 75 58 74 v v 72 55 40 13.2 45 µg/L 10.8 10.9 10 NTU 7.99 6.02 10 3:83 4.16 3.35 V2.15 2.59 273' 2.48 1:7T 1.5 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-7.5 Jun-15 tlron, total (ug/I) ■ Iron, diss (ug/1) --*—Turbidity, field (NTU) M W-15 Dare Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA me 1000 100 10 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 —III—Iron, total (ug/1) ■ Iron, diss (ug/1) —*-Turbidity, field.(NTU) 10 1 NTU 0 M W-7SR DATE F)""Z Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10000 1000 4160 2050 1680 1330 1480 1320 2410 954 1720 1000 217 1120 1 _ 949 110 777 93.7 & 100 100 76 44 2L Stand�r41: 3 µg/L 72.4 6€ \32.6 µg/L 100 71 36 NTU ■ 25 27.4 24.7 ■ 16 30 10 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 00-14 Feb-15 Jun-15 tlron, total (ug/1) ■ Iron, diss (ug/1) —Turbidity, field (NTU) M W-8D DATE Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10000 100 2460 2510 2100 38.7 37.2 51.6 32.2 32.2 43.2 1000 812 1410 643::2 618 629 593 618 942 976 497 787 853 2LStandard:300µWL 23 20.8 "n) 436 19.8 17.7 18.2 14.1 10.8 100 10 µg/L NTU 9.87 44 ■ ■ 10 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tlron, total (ug/1) ■ Iron, diss (ug/1) —*—Turbidity, field.(NTU) M W-81 UATE F)""Z Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10000 1000 2440 1870 1950 1620 1110 1130 A A 1000 10fi0 569 139 100 464 2L Standard: 300 µg/L 263 381 209 49.7 341 272 37 220 A µg/L 100 A 140 NTU 21.2 29.5 18.6 14.3 14.4 19 12.6 ■ 10 13 10.3 ■ 10 4.79 4.28 5.82 5.07 3.56 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tlron, total (ug/1) ■ Iron, diss (ug/1) —Turbidity, field (NTU) M W-9 UATE F)""Z Iron and Turbidity AUGUST2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 1000 I 355 242 198 A 232 133 182 124 100 132 100 67 68 84.1 z Z Zac 72 dard: 50 µg/LNTU 37 48 29.7 36 µg/L 33 21.7 19 ■ 15 10 10 10.7 8.19 --- �7.�73 6.95 5.08 4.32 4.28 5.81 16 5.23 3.19 1 — 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feh-15 Jun-15 +Manganese, tot (ug/1) ■ Manganese, diss (ug/1) —Turbidity, field (NTU) MW-10 DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 384 100 59 2L Standard: 50 µg/L NTU µg/L 10 4 11 2 30 17 14 12 5.44 16 1 13 12 10 10 12 8 $, 5.07 9 7 3.44 2.72 / 3,53 3.34 \ 2.41 2.48 —� T 2.05 2.35 2.55 1.37 3 1 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 Oct-10 +Manganese, tot (ug/1) ■ Manganese, diss (ug/1) (Turbidity, field (NTU) MW-11 SR DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 100000 100 11200 10300 10000 10100 10500 10000 9330 10000 10500 1111 R070 g.. 8760 10400 10300 10300 10300 10100 1000 18'8 18.3 13.7 NTU µg/L 10 7.67 7.78 `A 9.32 100 6.4 4.67 5.26 2L Standard: 50 µg/L /75 3.26 3.14 3.15 2.4 2.44 10 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tManganese, tot (ug/I) ■ Manganese, diss (ug/I) —,Turbidity, field (NTU) M W-13 Dare Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 353 270 193 185 205 1 126 32 100 4 25.6 81 63 90 55 12.9 56 14.4 NTU 43 NP./L 2L Standard: 50 4/1-4/1-10 \, I64� 8.21 8.fi52 20 4A9 &08 6.09 10 5.48 3.92 4.31 3.24 5 5 2.04 :LON 1 1 — Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-:14 Feb-15 Jun-15 Oct-10 tManganese, tot (ug/1) ■ Manganese, diss (ug/1) —Turbidity, field (NTU) M W-14 Dare Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 100 100 86 58 52 53 21. Standard: 50 µg/L 50 45 .46 49 47 45 37 - 41 13.2 NTU 10 10 µg/L 10.8 10.9 7.99 6.02 4.16 3,35 V..3 2.48 2.59 2.73 1.77 2.15 1.5 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tManganese, tot (ug/1) ■ Manganese, diss (ug/1) —Turbidity, field (NTU) MW-15 DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 8.8 10 9.17 6.25 413 5.66 4.39 4.65 256 304 I\V\ 3.19 167 113 2.84 3.02 2.76 122 100 67 68 1.34 1 8 54 43 38 40 \V/31 33 NTU 1.28 49 ` 41 1 2L Standard: 50 µg/L 0.8 0.81 10 1 0 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tManganese, tot (ug/1) ■ Manganese, diss (ug/1) —Turbidity, field (NTU) MW-7SR DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 1000 743 671 535 452 622 174 143 217 82 110 118 86 933 100 100 72.4 100 76 44 74 60 2L standard: 50 Ng/L 34 31 i R/L 41.4 NTU 36 35 274 32.6 25 ■ 24.7 16 12 Is 10 10 ■ 5 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14' Feb-15 Jun-15 tManganese, tot (ug/I) ■ Manganese, dins (ug/1) —Turbidity, field (NTU) M W-8D DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 100 1000 51.6 290 43.2 168 38.7 37.2 32.2 32.2 93 20.8 100 17.7 18.2 23 20.4 52 19.8 2L Standard: 50 µg/L 39 10.8 38 --7 32 14.1 9.97 43 23 47 30 NTU µg/L 10 24 15 10 5 5 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 --#—Manganese, tot (ug/1) ■ Manganese, diss (ug/I) —*—Turbidity, field (NTU) MW-81 DATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 1000 282' 347 4 139 100 87 100 68 62 49 2L Standard: 50 µg/L 49.7 A µg/L 25 25 37 - NTU 29.5 20 19 21.2 A 18.6 14.3 14.4 10 10 12.6 10 10.3 7 7 5 ■ 5.82 5 5.07 5 4.79 4.21 3.56 1 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 —*—Manganese, tot (ug/I) ■ Manganese, diss (ug/I) —*--Turbidity, field (NTU) M W-9 UATE Manganese and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10 SU Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-1-5 May-15 pH (field) —i—Turbidity, field M W-10 Dare pH and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 1000 100 NTU 10 1 10 10 3.4 2L Standard: 6.5 - 8.5SU 2.6 2.24 2.24 1.94 1.77 1.66 1.55 5.83 5 87 5.63 5.67 5.66 5.75 5.67 5.64 5.76 5.65 5.55 5.71 5.73 5.68 0.94 1.24 0.94 1 NTU SU y 0.68 x 0.64 0.18 x 0 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 +pH (field) —Turbidity, field M W-11 DR DATE pH and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10 8 6 4 2 0 Sep-10 r _ate jS;l;I 5.72 5.78 5.72 5.67 5.77 5.68 5.73 5.68 5.62 21-Standard: 6.5 - 8.55U 1,13 3.44 3.53 Y 5 5.07 .44 3.34 2.72 2.35 2.41 2.15 2.48 2.05 1.37 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 +pH (field) —Turbidity, field MW-11SR pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 100 10 NTU 1 10 8 6 SU 4 2 6.27 6.35 18.8 18.3 6.22 6.29 6.18 6.28 6.13 5.99 5.97 5.8 5.86 6.17 6.13 5.97 13.7 2L Standard: 6.5 - 8.5SU 9.32 7 67 7.78 6.4 At 5.26 4.67 .75 3.26 3.14 i3aSe 2.44 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 +pH (field) —Turbidity, field MW-13 pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 100 10 NTU 1 10 8 6 SU 4 2 13.2 5.21 2L Standard: 6.5 - §. 5.16 5.19 5.07 5.2 5.1 5.19 5.11 5.06 5.05 5.07 5.1 5.29 10.8 10.9 7.99 6.02 3.83 4.16 3.35 2.73 2.48 2.59 2.15 1.77 1.5 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 tpH (field) —*--Turbidity, field MW-15 pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 100 10 NTU 1 10 8 6 SU 4 2 8.82 A 6.5 s� 4.73 3.25 3.04 3 2.05 2LStandard &5-8.55U 5.79 5.8 5.68 5.68 5.61 5.56 1.48 5.51 5.5 5.69 5.62 5.48 5.61 5.56 5,79 1.2 0.79 A 0.89 0.59 0.42 0.44 0.29 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 +pH (field) —*—Turbidity, field M W-7D pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 10 1 NTU 0 10 8 6 5U 4 2 9.17 8.8 5.66 z z 4.65 4.39 2.76 3.02 A,--/ Y 3.19 2.84 1.8 2L Standard: 6.5-8.5SU 1.281.34 5.48 5.33 5.34 5.37 5 29 5.13 5.19 4.96 5.06 5.05 5.1 5,05 5.24 5.12 0.8 0.81 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 tpH (field) —*—Turbidity, field MW-7SR pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST 2015 FIGURE Figure 10- 10 1 NTU 0 Su 10 8 6 4 2 217 7 6.84 6.81 110 6.8 6.77 100 93.7 7.08 6.27 6.31 6.34 6.34 6.34 76 6.49 6.41 6.38 6.34 72.4 60 44 41.4 36 32.6 27.4 25 24.7 16 2L Standard: 6.5 - 8.5SU 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 --*--pH (field) —*--Turbidity, field M W-8D pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 1000 100 NTU 10 1 10 8 6 Su 4 2 51,.6 43.2 37.2 38.7 ,1 32.2 23 20.4 19.8 20.8 6.82 17.7 18.2 6.4 6.33 6.4. 6.4 6.38 14.1 �6��O9�,&,0 6 6.03 5.98 6.02 6.01 5.97 5.65 9 87 10.8 21-Standard: 6.5 - 8.5SU 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 --*--pH (field) (Turbidity, field M W-81 pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figue 10- 100 10 NTU 1 10 SU 8 6 4 2 18 16 13.2 10.7 9.98 iLst d:6.5-assu 4.8 478 4.82 5.33 5.22 5.22 T 4.94 7 89 5.08 5.07 4.92 4.83 4.75 4.71 9.46 4.34 7.65 7.07 7.42 6.76 6.12 4.18 2.77 2.72 Y y 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 --*--pH (field) (Turbidity, field M W-8S pH and Turbidity DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN GASTON COUNTY, NORTH CAROLINA Sep-14 Jan-15 May-15 DATE AUGUST2015 FIGURE Figure 10- 100 10 NTU 1 10 1000 8 2L Standard: 6.5 - 8.5SU 100 6.1 5.95 6 6..4 6.4 5.99 6.29 6. 6.23 6.03 6.01 5.97 6.05 37 5.82 Su A NTU 18.6` 4 12.6 14.3 14.4 10 10.3 2 5.82 - "=�— 3.56 -f-----w-' 4.795.07 4.28 0 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 tpH(field) —*--Turbidity, field M W-9 UATE pH and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10 µg/L 1 0 8.82 6.5 4.73 3 3.04 3.25 1.48 2.05 1.2 1 1 1 1 1 1.04 1 2LStandard: lµg/L 1 1 1 � 1 1 1 1 1 1 0v .89 0.74 0.59 0.44 0.42 0.29 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-1.5 Jun-15 tAntimony, tot (ug/1) ■ Antimony, dins (ug/1)—d—Turbidity, field (NTU) MW-7D DATE Antimony and Turbidity AUGUST 2015 DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION ASH BASIN FIGURE Figure 10- GASTON COUNTY, NORTH CAROLINA 10 1 NTU 1 0 1 100 2L Standard: 10 ug/I 10 pg/L 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —h—MW-7D(BG) tMW-8D --*- MW-81 --IFMW-11DR MW-7D vs Deep Wells DATE ChroER Duke Cum inns AUGUST2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 100 14 10 µg/L 2L Standard10 ug/I 1 Sep-10 .Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —BMW-7SR(BG) tMW-10 tMW-11SR CIE—MW-13 MW-14 MW-15 BMW-8S MW-9 MW-7SR vs Shallow Wells DATE Chromium (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE to - Gaston County, NORTH CAROLINA 10000 1000 - 2L Standard: 300 pWL 100 µg/L ■ ■ 20 ■ ■ 10 ® ® ® ® ® ■ ® i 10. ® 1 ■ 1 Sep-30 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —BMW-7D (BG) tMW-8D BMW-81 --IFMW-11DR MW-7D vs Deep Wells DATE Iron (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 100000 10000 1000 A Standard: 300 µg/L 100 10 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 ->jr-MW-7SR(BG) BMW -SS tMW-9—*—MW-10 BMW-115R MW-13 BMW-14 —MW-15 MW-7SR vs Shallow Wells DATE KR Iron (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 1000 . 100 ■ 2L Standard: 50 µg/L ■ µg/L ■ ■ 10 ® ® ® ® 5 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 tMW-7D(BG) tMW-8D BMW-81 --M-MW-11DR MW-71D vs Deep Wells DATE EReli(tot, AUGUST2015 DukeCaro Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 100000 - 10000 - 0 EA00 1000 µ6/L - 7 I 353 9 . . . . ■ . 185 . . 132 100 or 6 00,■ 2L Standard: 50 µg/L 43 8.4 ® 32 ■ ® 18 4 10 ■ . . 4 1 , Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 t MW-11SR fMW-7SR(BG) —0I t MW-9 --IFMW-10 MW-13 MW-14 MW-15 MW-7SSR vs Deep Wells DATE ERManganese (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 9 9 21-Standard: 6.5 - 8.5 SU 8 8 7 7 SU 6 6 5 5 4 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —vk—MW-7D(BG) tMW-8D tMW-81 --)rMW-11DR MW-7D vs Deep Wells DATE pH, field AUGUST2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 9 � - 8 2L Standard: 6.5 - 8.5 SU 7 6.95 6.86 6.79 6.8 6.81 6.71 6.73 6.79 6.85 5.74 6.73 6.76 6.63 6.64 6.64 6 5 SU 4 3 - 2 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —rir--MW-75R(BG) +MW-8S tMW-9 --)IFMW-10 BMW-11SR +MW-13 BMW-14 —MW-15 MW-7SR vs Shallow Wells DATE F)""Z pH, field Duke Carolinas, LLC AUGUST 2015 Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 10 i 1 pg/L 0 • ! ■ i i ■ ■ f ■ i ■ ! ■ � 2L Standard: 1 ug/I Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —BMW-7D (BG) +MW-8D +MW-81 --I—MW-11DR MW-7D vs DeepWells DATE KP Antimony (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 10 M/L 2L Standard: 1 ug/I 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 --A—MW-7SR(BG) BMW-10 tMW-11SR-If—MW-13 —MW-14 MW-15 BMW-8S —MW-9 MW-7SR vs Shallow Wells DATE ERAntimony (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 10 2L Standard: lug/I ug/I 1 IN M 0 M IN 0 0 01 0 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 MW-10 tMW-11DR —BMW-115R —04—MW-13 MW-14 MW-15 MW-8D MW-81 MW-8S tMW-9 Stacked Time Series Plots - Compliance Wells DATE Antimony AUGUST 2015 Duke Energy Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE Figure 10- Gaston County, NORTH CAROLINA 100,000 10,000 1,000 ug/1 300 2L Standard: 100 ON IL 10 1 Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tMW-10 t—MW-11DR MW-11SR —0—MW-13—0—MW-14 MW-15 MW-80 MW-8I MW-8S tMW-9 Stacked Time Series Plots - Compliance Wells DATE Iron AUGUST 2015 Duke Energy Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE Figure 10- Gaston County, NORTH CAROLINA 100,000 10,000 1,000 ug/I 1-7 100 2L Standard: g/I 10 eor Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tMW-10—FMW-I1DR fMW-11SR --(—MW-13—w—MW-14 BMW-15 +MW-8D —MW-81 —MW-85 tMW-9 Stacked Time Series Plots - Compliance Wells DATE Manganese AUGUST 2015 Duke Energy Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE Figure10- Gaston County, NORTH CAROLINA ug/1 10 1 Oct-10 2L Standard: 10 ug/1 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tMW-10 tMW-11DR—1rMW-11SR-I—MW-13 —OK—MW-14 — MW-15 MW-8D —MW-81 —MW-SS +MW-9 Stacked Time Series Plots - Compliance Wells DATE Chromium AUGUST 2015 Duke Energy Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE Figure 10- Gaston County, NORTH CAROLINA 9 8 7 2L Standard: 6.5 - 8.5 SU 6 5 SUI 4 3 2 1 0 -, Oct-10 Feb-11 Jun-11 Oct-11 Feb-12 Jun-12 Oct-12 Feb-13 Jun-13 Oct-13 Feb-14 Jun-14 Oct-14 Feb-15 Jun-15 tMW-10 -41-MW-11DR fMW-11SR -0-BMW-13 --IFMW-14 tMW-15 +MW-8D —MW-81 —MW-85 tMW-9 —Seriesl—Series2 Stacked Time Series Plots - Compliance Wells DATE PH AUGUST 2015 Duke Energy Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE Figure10- Gaston County, NORTH CAROLINA 1000 Ratios > 1 signify concentration greater than concentration in background well. 44 100 072 109.032 ® ® 97;. -- 7.719 70.5 ® ® 43.190 8.722 36.923 ® 43;6 4.051 19.520 17.281 2.343 10 21LStandard: 300 Ng/L O ';� 6.561 7.290 0 4. 32 .976 221 3. 1 /2.575 2.3941.96 2.903 342.141 005 1.4 ■■ ■ ■ .584 c a 1 .872 :gap 76BB 0.90 0.733 .658 0.661 v S 542 0 - .424 .443 452 .354 0.3 67 0.317 0.287 .249 0.258 .204 197 0.147 3 - 0.127 0,109 0 7.046 0.076 0.052 - 0 0.030 0 Sep-30 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 -BMW-81/MW-7D +MW-11DR/MW-7D +MW-10/MW-7SR-IFMW-11SR/MW-7SR tMW-13/MW-7SR --MW-14/MW-7SR -MW-15/MW-7SR-MW-8S/MW-7SR tMW-9/MW-7SR Correlation Plot - Compliance Wells vs. Background DATE FY� Iron (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 1000 Ratios > 1 signify concentration greater than concentration in background well. 5.8065 265.78195 000 3.2500 153.7313 162.2222 118.6765 100 All 91.1504 84.4262 9.8802 42 34.2105 33. c 10 8.6 u o ® 78 5.6061 7.6 6 `m A,6.3.4 ® 581 3.1239 6 32 - 00 3.10 c ® 2.4444 u 2.1257 1. 59 _ 1.18 T1251 1.15 1842 12 .250 .7 it 1.2593 1 0.9298 852 .7734 0.7611 0.686 0.6852 0. 60 0.5526 .48 0.4750 _ 0.4186 2985 .31 0.3226 JWM 7 8.�368 .2124 . 8 6 .1332 0.1414 0.1393 0.1481 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 .Jan-14 May-14 Sep-14 Jan-15 May-15 -9jr-MW-81/MW-7D BMW-11DR/MW-7D tMW-8S/MW-7SR --)I(-MW-9/MW-7SR tMW-10/MW-7SR MW-11SR/MW-7SR BMW-13/MW-7SR -MW-14/MW-7SR -4-MW-15/MW-7SR Correlation Plot - Compliance Well vs. Background DATE Manganese (tot) AUGUST 2015 Duke Carolinas,, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 10 Ratios > 1 signify concentration greater than concentration in background well. 0 c 0 a c m c 1 v c m c 0 V 0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —rhr-MW-81/MW-7D tMW-11DR/MW-7D tMW-10/MW-7SR—W—MW-11SR/MW-7SR tMW-13/MW-7SR +MW-14/MW-7SR—MW-15/MW_7SR—MW-8S/MW-7SR—*—MW-9/MW-7SR Correlation Plot - Compliance Well vs. Background DATE Ch Duke Cum inns AUGUST2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 1.6 Ratios > 1 signify concentration greater than concentration in background well. 2L Standard: 6.5 - 8.5 SU 1.4 1.2 _ 1.0 0 z c 0 0.8 m 0 0 c 0.6 m c 0 u 0.4 0.2 0.0 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 —dr-MW-81/MW-7D tMW-11DR/MW-7D tMW-10/MW-7SR—W—MW-11SR/MW-7SR tMW-14/MW-7SR—0—MW-15/MW-7SR BMW-8S/MW-7SR—MW-9/MW7SR Correlation Plot - Compliance Well vs. Background DATE ER(fipH eld) Dukear AUGUST2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA 0 10 Ratios > 1 signify concentration greater than concentration in background well. 0 1 1 Sep-10 Jan-11 May-11 Sep-11 Jan-12 May-12 Sep-12 Jan-13 May-13 —91r-MW-81/MW-7D tMW-11DR/MW-7D +MW-10/MW-7SR —I--MW-11SR/MW-7SR tMW-13/MW-7SR Sep-13 Jan-14 May-14 Sep-14 Jan-15 May-15 MW-14/MW-7SR MW-15/MW-7SR—MW-8S/MW-7SR tMW-9/MW-7SR Correlation Plot - Compliance Well vs. Background DATE KR Antimony (tot) AUGUST 2015 Duke Carolinas, LLC Riverbend Steam Station Ash Basin FIGURE 10- Gaston County, NORTH CAROLINA Figure 10-61 through 10-117 Unused &<&< &<&< &<&<&< &<&< &<&<&<&<&< &<&<&< &<&< &<&< &<&< &< &<&< &<&<&< &<&< &< &<&< &<&< &<&<&< &<&<&< &<&<&< &<&< &<&< &<&<&<&< &<&< &<&< &<&< &<&<&<&<&<&< &< &<&< &<&< &< &<&< &< &< &< &<&<&< &< &<&< &< &<&< &< &< &<&< SR-20 7 4 SR-1912 GROUNDWAT ER ANALYT ICAL RESULT S – PLAN VIEW (2L EXCEEDANCES) GASTON COUNTY, NORTH CAROLINA PAT H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ G W . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND ST EAM ST AT ION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL &<ASH BASIN COMPLIANCEGROUNDWATER MONITORING WELL &<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER Antimony 6.3Chromium 49.2Cobalt 2.9Iron 370Vanadium 20 AB-1DAnalyte (µg/L)Antimony 3.2Cobalt 15.9Iron 510Manganese 250Vanadium 1.8 AB-1SAnalyte (µg/L) Chromium 13Vanadium 32.4 AB-2DAnalyte (µg/L)Antimony 3.1Cobalt 17.1Iron 1,700Manganese 330Vanadium 3.8 AB-2SAnalyte (µg/L) Chromium 51Total Dissolved Solids 946,000Vanadium 11.5 AB-3DAnalyte (µg/L) Antimony 1.2Vanadium 24 AB-4DAnalyte (µg/L) Antimony 1.2Vanadium 12.5 AB-5DAnalyte (µg/L) Analyte (µg/L) Sample 1 Sample 2Antimony *DNE 2.5Cobalt *DNE 1.8Iron *DNE 970Vanadium 11.9 18.6 AB-6BRU Antimony 1.8Iron 730Vanadium 25.2 AB-6SAnalyte (µg/L) Antimony 7.5Chromium 24.7Vanadium 40.5 AB-7DAnalyte (µg/L)Cobalt 1.6Iron 380Manganese 85 AB-7IAnalyte (µg/L) Manganese 140Vanadium 2.7 AB-8DAnalyte (µg/L)Manganese 150Vanadium 0.79 J AB-8SAnalyte (µg/L) Antimony 3Chromium 903Vanadium 14.4 AS-1DAnalyte (µg/L)Boron 2,200Cobalt 5.4Iron 660Manganese 1,900Total Dissolved Solids 750,000 J-Vanadium 1.6 J+ AS-1SAnalyte (µg/L) Chromium 22.5Vanadium 34.6 AS-2DAnalyte (µg/L)Chromium 44.8Cobalt 12.4Iron 2,090Manganese 640Vanadium 3.9 AS-2SAnalyte (µg/L) Antimony 1.6Chromium 23.5Vanadium 18.2 AS-3DAnalyte (µg/L) Cobalt 3Iron 2,200Manganese 300Vanadium 5.9 BG-1SAnalyte (µg/L) Iron 930Manganese 63Vanadium 3.7 BG-3DAnalyte (µg/L)Antimony 1.3 J+Manganese 240Vanadium 0.75 J+ BG-3SAnalyte (µg/L) Arsenic 25.8Cobalt 102Iron 175,000Manganese 3,200Sulfate 559,000Total Dissolved Solids 1,110,000Vanadium 4 C-1SAnalyte (µg/L) Vanadium 10.9 C-2DAnalyte (µg/L)Cobalt 39.7Manganese 600Vanadium 0.52 J C-2SAnalyte (µg/L) Antimony 3.2Iron 720Vanadium 21 GWA-1DAnalyte (µg/L)Chromium 11.6Cobalt 2.1Iron 1,800Manganese 110Vanadium 7.9 GWA-1SAnalyte (µg/L) Vanadium 11.8 GWA-2BRAnalyte (µg/L)Iron 590 Manganese 95 87.2 Vanadium 2.3 GWA-2SAnalyte (µg/L) Cobalt 1.1Manganese 9,200Sulfate 1,310,000Total Dissolved Solids 2,390,000Vanadium 4.6 GWA-3DAnalyte (µg/L) Cobalt 4.5Manganese 190 GWA-5SAnalyte (µg/L) Chromium 24.8Vanadium 28 GWA-6DAnalyte (µg/L)Cobalt 27.6Iron 1,100Manganese 1,300Vanadium 4.8 GWA-6SAnalyte (µg/L) Vanadium 10.9 GWA-7BRAnalyte (µg/L)Iron 440Vanadium 12.1 GWA-7DAnalyte (µg/L)Iron 790Vanadium 3.5 J+ GWA-7SAnalyte (µg/L) Iron 1,300Manganese 96 GWA-8DAnalyte (µg/L)Manganese 720 GWA-8SAnalyte (µg/L) Manganese 90Vanadium 2.8 GWA-9DAnalyte (µg/L)Cobalt 50.1Manganese 2,900Vanadium 0.52 J+ GWA-9SAnalyte (µg/L) Antimony 1.1Vanadium 6.8 GWA-10DAnalyte (µg/L)Cobalt 10Manganese 250Vanadium 0.62 J GWA-10SAnalyte (µg/L) Vanadium 22.4 MW-15DAnalyte (µg/L)Vanadium 2.2 MW-15BRAnalyte (µg/L) Antimony 2.3Vanadium 7.8 MW-9BRAnalyte (µg/L)Analyte (µg/L) Sample 1 Sample 2Antimony 5.4 2.7Chromium 20.6 27Vanadium 12.5 12.8 MW-9D Cobalt 1.3Vanadium 2.7 MW-15Analyte (µg/L) Vanadium 6.2 MW-3DAnalyte (µg/L) Vanadium 1.1 MW-4DAnalyte (µg/L) Manganese 68Vanadium 0.6 J+ MW-3SAnalyte (µg/L) Vanadium 2.1 MW-11DRAnalyte (µg/L)Vanadium 1.4 MW-11SRAnalyte (µg/L) Vanadium 4.7 MW-2DAnalyte (µg/L) Manganese 530Vanadium 2.1 J+ MW-1DAnalyte (µg/L)Cobalt 61Iron 30,800Manganese 2,600 MW-1SAnalyte (µg/L) Vanadium 1.2 MW-10Analyte (µg/L) Vanadium 2.7 MW-9Analyte (µg/L) Cobalt 1.1Iron 2,700Vanadium 4.1 MW-8DAnalyte (µg/L)Iron 2,100Vanadium 2.8 MW-8IAnalyte (µg/L)Manganese 57Vanadium 0.32 J+ MW-8SAnalyte (µg/L) Vanadium 2.6 J+ MW-14Analyte (µg/L) Cobalt 23.7Iron 15,700Manganese 8,300 MW-13Analyte (µg/L) Vanadium 8.6 MW-5DAnalyte (µg/L) Vanadium 0.35 J MW-6SAnalyte (µg/L)Vanadium 3.8 MW-6DAnalyte (µg/L) Cobalt 18.4Iron 420Manganese 12,700Sulfate 1,420,000Total Dissolved Solids 23,000,000Vanadium 1.3 GWA-3SAAnalyte (µg/L) 500 0 500 1,000 SCALE (FEET) Cobalt 1.64Iron 4,440Manganese 87Vanadium 32.1 AB-3BRAnalyte (µg/L)Analyte (µg/L) Sample 1 Sample 2Antimony *DNE 1.7Arsenic 283 *DNECobalt 1.9 *DNEIron 6,500 990Manganese 910 730Total Dissolved Solids *DNE 519,000Vanadium 11.3 4.9 AB-3S Manganese 1,200 AB-4SAnalyte (µg/L) Antimony 21.6Arsenic 651Boron 1,400Iron 660Thallium 0.48Vanadium 231 AB-5SAnalyte (µg/L)Antimony 3.2Arsenic 75.1Boron 2,400Vanadium 151 AB-5SLAnalyte (µg/L) Arsenic 24.3Cobalt 13.4Iron 11,200 Manganese 1,300 1,340 Vanadium 1.1 AB-7SAnalyte (µg/L) Antimony 3.3Chromium 32.3Cobalt 1.3Iron 1,500Total Dissolved Solids 555,000Vanadium 22 BG-1DAnalyte (µg/L) Iron 760 JVanadium 4.6 BG-2BRAnalyte (µg/L)Chromium 57.5Vanadium 29.9 BG-2DAnalyte (µg/L)Manganese 370Vanadium 0.35 J BG-2SAnalyte (µg/L) Chromium 186Cobalt 1.9Iron 660Sulfate 376,000 J+Thallium 3.2Total Dissolved Solids 2,900,000Vanadium 2.1 GWA-20DAnalyte (µg/L)Chromium 133Cobalt 12.7Iron 9,500Manganese 320Vanadium 23 GWA-20SAnalyte (µg/L)Chromium 108Vanadium 4.33 GWA-22BRAnalyte (µg/L)Antimony 1.4Chromium 174Cobalt 3.4Iron 2,600Manganese 120Vanadium 18.5 GWA-22DAnalyte (µg/L)Antimony 2.2Cobalt 1.3 GWA-22SAnalyte (µg/L)Chromium 15.6Total Dissolved Solids 790,000Vanadium 5.3 GWA-23BRAnalyte (µg/L)Cobalt 3.3Iron 530Manganese 82 GWA-23SAnalyte (µg/L) Antimony 18.2Chromium 46Iron 1,500Manganese 61Total Dissolved Solids 18,100,000Vanadium 4 GWA-2BRUAnalyte (µg/L) Vanadium 2.4 GWA-4DAnalyte (µg/L)Cobalt 1.7Manganese 120Vanadium 0.84 J GWA-4SAnalyte (µg/L) Chromium 24.5Vanadium 13.9 GWA-5DAnalyte (µg/L) Antimony 4.5Arsenic 10.7Chromium 40.6Iron 450Vanadium 67.5 GWA-9BRAnalyte (µg/L) Chromium 24.7Total Dissolved Solids 1,180,000Vanadium 2.1 MW-7BRAnalyte (µg/L) Analyte CAS No.NC 2L GroundwaterIMAC1 Antimony 7440-36-0 1*Arsenic 7440-38-2 10Barium7440-39-3 700Beryllium7440-41-7 4*Boron 7440-42-8 700Cadmium7440-43-9 2Chloride**16887-00-6 250,000Chromium7440-47-3 10Cobalt7440-48-4 1*Copper**7440-50-8 1,000Iron7439-89-6 300Lead7439-92-1 15Manganese7439-96-5 50Mercury7439-97-6 1Nickel7440-02-0 100Nitrate**14797-55-8 10,000Nitrite as N**14797-65-0 1,000Selenium7782-49-2 20Sulfate**14808-79-8 250,000Thallium7440-28-0 0.2Total Dissolved Solids** TDS 500,000Vanadium7440-62-2 0.3*Zinc**7440-66-6 1000* Interim Maximum Allowable Concentration (IMAC) All units shown in µg/L. ** Unit reported in mg/L in standard, converted here to µg/L to match units displayed on figure. 1 - North Carolina 15A NCAC 02L.0202 Groundwater Standards (As of 4/2013). Interim Maximum Allowable Concentration shown where no standard is available for comparison. &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1 1 1 1 11 11 11 0 .5 0 .5 00..55 00 ..55 0 .50 .5 0 . 5 0 . 5 00 ..55 S R -2 0 7 4 S R -1 9 1 2 AABB--11SS33..22 ((22..88 )) AABB--22SS33..11 ((33..44 )) AB-6SAB-6S1.8 1.8 (1.7 )(1.7 ) AB-7IAB-7I1J+ 1J+ (3.6 )(3.6 ) AB-8SAB-8S˂0.5U (˂0.5U)˂0.5U (˂0.5U) AS-1SAS-1S0.26J (0.23J)0.26J (0.23J) AS-2SAS-2S0.21J (0.18J)0.21J (0.18J)BG-1SBG-1S0.43J (0.23J)0.43J (0.23J) BG-2SBG-2S0.33J (0.25J)0.33J (0.25J) BG-3SBG-3S1.3J+1.3J+ (1.4J+)(1.4J+) C-2SC-2S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-10SGWA-10S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-1SGWA-1S0.28J (0.22J)0.28J (0.22J) GWA-20SGWA-20S0.22J (˂0.5U)0.22J (˂0.5U)GWA-22SGWA-22S2.2 2.2 (3.5 )(3.5 ) GWA-23SGWA-23S0.24J (˂0.5U)0.24J (˂0.5U) GWA-2SGWA-2S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-3SAGWA-3SA0.77J+ (0.6J+)0.77J+ (0.6J+) GWA-4SGWA-4S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-5SGWA-5S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-6SGWA-6S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-7SGWA-7S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-8SGWA-8S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-9SGWA-9S0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-10MW-10˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-11SRMW-11SR0.87 (0.72 )0.87 (0.72 ) MW-13MW-130.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-14MW-140.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-15MW-15˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-1SMW-1S0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-3SMW-3S0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-5SMW-5S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-6SMW-6S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-8IMW-8I0.5UJ (0.5UJ)0.5UJ (0.5UJ)MW-8SMW-8S0.83J+ (0.4J+)0.83J+ (0.4J+) MW-9MW-9˂0.5U (˂0.5U)˂0.5U (˂0.5U) ANTIMONY ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-119 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR ANTIMONY IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 55 55 1 1 1 1 1 1 11 1 1 1 1 1 1 11 11 11 1 1 11 11 11 0 0 ..5 5 0 .50 .5 0 .5 0 .5 00..55 00 .. 55 0 0 ..5 5 0 .50.5 S R -2 0 7 4 S R -1 9 1 2 AABB--11DD66..33 ((11..55 )) AB-2DAB-2D1 (0.85 )1 (0.85 ) AB-3DAB-3D0.22J (˂0.5U)0.22J (˂0.5U) AABB--44DD11..22 ((11..44 )) AB-5DAB-5D1.2 1.2 (0.58 ) (0.58 ) AB-7DAB-7D7.5 7.5 (7.2J+)(7.2J+) AB-8DAB-8D˂0.5U (˂0.5U)˂0.5U (˂0.5U) AS-1DAS-1D3 3 (2.7 )(2.7 ) AS-2DAS-2D1J+ 1J+ (1.3J+)(1.3J+) AS-3DAS-3D1.6 1.6 (1.2 )(1.2 )BBGG--11DD33..33 ((33..99 )) BG-2DBG-2D0.72 (0.63 )0.72 (0.63 ) BG-3DBG-3D0.16J (˂0.5U)0.16J (˂0.5U) C-2DC-2D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-10DGWA-10D1.1 1.1 (˂0.5U) (˂0.5U) GWA-1DGWA-1D3.2 3.2 (2.6 )(2.6 ) GWA-20DGWA-20D˂0.5U (˂0.5U)˂0.5U (˂0.5U)GWA-22DGWA-22D1.4 1.4 (˂0.5U) (˂0.5U) GWA-23DGWA-23D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-3DGWA-3D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-4DGWA-4D˂0.5U (0.17J)˂0.5U (0.17J) GWA-5DGWA-5D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-6DGWA-6D0.25J (0.25J)0.25J (0.25J) GWA-7DGWA-7D0.17J (˂0.5U)0.17J (˂0.5U) GWA-8DGWA-8D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-9DGWA-9D0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-11DRMW-11DR0.590.59 MW-15DMW-15D0.74 (0.74 )0.74 (0.74 ) MW-1DMW-1D0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-2DMW-2D0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-3DMW-3D0.5UJ (0.5UJ)0.5UJ (0.5UJ) MW-4DMW-4D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-5DMW-5D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-6DMW-6D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-8DMW-8D0.21J+ (0.5UJ)0.21J+ (0.5UJ) MW-9DMW-9D5.4 5.4 (16.8 )(16.8 ) ANTIMONY ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-120 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR ANTIMONY IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &<1 1 1 1 1 1 11 11 0 0 ..5 5 0 .5 0 .5 0 0 ..5 5 0.50.5 00..55 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR˂1U (˂1U)˂1U (˂1U) AB-6BRUAB-6BRU2.5 2.5 (0.29J) (0.29J) BG-2BRBG-2BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-20BRGWA-20BR˂1U (˂1U)˂1U (˂1U) GWA-22BRGWA-22BR˂1U (˂1U)˂1U (˂1U) GWA-23BRGWA-23BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-2BRGWA-2BR0.24J (0.25J)0.24J (0.25J) GWA-2BRUGWA-2BRU18.2 18.2 (22.4 )(22.4 ) GWA-4BRGWA-4BR˂1U ˂1U (1.41 )(1.41 ) GWA-7BRGWA-7BR0.96 (0.25J)0.96 (0.25J) GWA-9BRGWA-9BR4.54.5 MW-15BRMW-15BR0.25J (0.21J)0.25J (0.21J) MW-7BRMW-7BR0.86 (0.22J)0.86 (0.22J) MW-9BRMW-9BR2.3 2.3 (1.3 )(1.3 ) ANTIMONY ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL IMAC CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-121 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR ANTIMONY IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1 1 0 0 ..5 5 0 0 . . 5 5 00 ..55 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S0.17J (0.14J)0.17J (0.14J) AB-2SAB-2S0.2J (˂0.5U)0.2J (˂0.5U) AB-6SAB-6S0.82 (0.88 )0.82 (0.88 ) AB-7IAB-7I˂0.5U (0.12J)˂0.5U (0.12J) AB-8SAB-8S˂0.5U (˂0.5U)˂0.5U (˂0.5U) AS-1SAS-1S1.4 (0.95 )1.4 (0.95 ) AS-2SAS-2S0.42J (˂0.5U)0.42J (˂0.5U)BG-1SBG-1S0.21J (˂0.5U)0.21J (˂0.5U) BG-2SBG-2S0.12J (0.14J)0.12J (0.14J) BG-3SBG-3S˂0.5U (˂0.5U)˂0.5U (˂0.5U) C-2SC-2S0.95J+ (0.86 )0.95J+ (0.86 ) GWA-10SGWA-10S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-1SGWA-1S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-20SGWA-20S3.3 (˂0.5U)3.3 (˂0.5U)GWA-22SGWA-22S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-23SGWA-23S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-2SGWA-2S0.28J (0.14J)0.28J (0.14J) GWA-3SAGWA-3SA0.23J (0.21J)0.23J (0.21J) GWA-4SGWA-4S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-5SGWA-5S˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-6SGWA-6S0.24J+ (0.17J)0.24J+ (0.17J) GWA-7SGWA-7S0.2J+ (˂0.5U)0.2J+ (˂0.5U) GWA-8SGWA-8S˂0.5U (0.18J)˂0.5U (0.18J) GWA-9SGWA-9S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-10MW-100.16J (˂0.5U)0.16J (˂0.5U) MW-11SRMW-11SR˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-13MW-130.39J (0.36J)0.39J (0.36J) MW-14MW-14˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-15MW-150.25J (˂0.5U)0.25J (˂0.5U) MW-1SMW-1S˂0.5U (0.49J)˂0.5U (0.49J) MW-3SMW-3S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-5SMW-5S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-6SMW-6S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-8IMW-8I0.12J (˂0.5U)0.12J (˂0.5U) MW-8SMW-8S˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-9MW-90.18J (0.12J)0.18J (0.12J) ARSENIC ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-122 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR ARSENIC IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 1 1 11 11 0 .50.5 0 .50 .5 0.50.5 0 .50.5 0.5 0.5 0.50.5 0.50.5 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D0.84 (0.51 )0.84 (0.51 ) AB-2DAB-2D0.72 (0.67 )0.72 (0.67 ) AB-3DAB-3D0.49J (˂0.5U)0.49J (˂0.5U) AB-4DAB-4D0.65 (0.6 )0.65 (0.6 ) AB-5DAB-5D0.25J (0.45J)0.25J (0.45J) AB-7DAB-7D2.2 (1.9 )2.2 (1.9 ) AB-8DAB-8D0.17J (0.31J)0.17J (0.31J) AS-1DAS-1D0.68 (0.32J)0.68 (0.32J) AS-2DAS-2D0.66 (0.43J)0.66 (0.43J) AS-3DAS-3D0.97 (0.87 )0.97 (0.87 )BG-1DBG-1D2 (2.1 )2 (2.1 ) BG-2DBG-2D0.66 (0.6 )0.66 (0.6 ) BG-3DBG-3D0.81 (0.38J)0.81 (0.38J) C-2DC-2D1.3J+ (1.3 )1.3J+ (1.3 ) GWA-10DGWA-10D0.29J (0.36J)0.29J (0.36J) GWA-1DGWA-1D0.93 (0.82 )0.93 (0.82 ) GWA-20DGWA-20D0.64 (0.27J+)0.64 (0.27J+)GWA-22DGWA-22D0.91 (0.78 )0.91 (0.78 ) GWA-23DGWA-23D0.9 (0.82J+)0.9 (0.82J+) GWA-3DGWA-3D0.65 (0.72 )0.65 (0.72 ) GWA-4DGWA-4D0.22J (0.28J)0.22J (0.28J) GWA-5DGWA-5D0.96 (1.1 )0.96 (1.1 ) GWA-6DGWA-6D1J+ (1 )1J+ (1 ) GWA-7DGWA-7D0.48J (0.46J)0.48J (0.46J) GWA-8DGWA-8D˂0.5U (0.12J)˂0.5U (0.12J) GWA-9DGWA-9D0.13J (˂0.5U)0.13J (˂0.5U) MW-11DRMW-11DR˂0.5U˂0.5U MW-15DMW-15D1 (1.2 )1 (1.2 ) MW-1DMW-1D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-2DMW-2D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-3DMW-3D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-4DMW-4D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-5DMW-5D˂0.5U (0.12J)˂0.5U (0.12J) MW-6DMW-6D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-8DMW-8D0.32J (0.12J)0.32J (0.12J) MW-9DMW-9D0.38J (0.28J)0.38J (0.28J) ARSENIC ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-123 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR ARSENIC IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 11 11 1 1 11 00 0.50.5 0 .5 0 .5 0 .5 0 .5 0 .50 .5 0.5 0.5 0.50.5 0.5 0.5 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR1.23 (˂1U)1.23 (˂1U) AB-6BRUAB-6BRU0.75 (0.21J)0.75 (0.21J) BG-2BRBG-2BR0.28J (0.12J)0.28J (0.12J) GWA-20BRGWA-20BR˂1U (˂1U)˂1U (˂1U)GWA-22BRGWA-22BR˂1U (˂1U)˂1U (˂1U)GWA-23BRGWA-23BR0.28J (˂0.5U)0.28J (˂0.5U) GWA-2BRGWA-2BR1.3 (1.4 )1.3 (1.4 ) GWA-2BRUGWA-2BRU0.36J (0.18 )0.36J (0.18 ) GWA-4BRGWA-4BR˂1U (˂1U)˂1U (˂1U) GWA-7BRGWA-7BR0.29J (0.23J)0.29J (0.23J) GWA-9BRGWA-9BR10.710.7 MW-15BRMW-15BR0.78 (0.68 )0.78 (0.68 ) MW-7BRMW-7BR0.23J (0.24J)0.23J (0.24J) MW-9BRMW-9BR0.69 (0.52 )0.69 (0.52 ) ARSENIC ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-124 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR ARSENIC IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 4 0 0 4 0 0 1 0 01 0 0 1 0 0100 1 1 0 0 0 0 1 1 0 0 0 0 1 0 0 1 0 0 1 0 0 1 0 0 100100 100 100 4 0 040 0 770000 5 05 0 5 050 5 0 5 0 5 5 0 0 5050 5050 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S˂50U (˂50U)˂50U (˂50U) AB-2SAB-2S˂50U (˂50U)˂50U (˂50U) AB-6SAB-6S45J (41J)45J (41J) AB-7IAB-7I˂50U (˂50U)˂50U (˂50U) AB-8SAB-8S220 (240J+)220 (240J+) AS-1SAS-1S2,200 2,200 (1,900 )(1,900 ) AS-2SAS-2S˂50U (˂50U)˂50U (˂50U)BG-1SBG-1S˂50U (˂50U)˂50U (˂50U) BG-2SBG-2S˂50U (˂50U)˂50U (˂50U) BG-3SBG-3S˂50U (˂50U)˂50U (˂50U) C-2SC-2S170 (170J+)170 (170J+) GWA-10SGWA-10S170 (170 )170 (170 ) GWA-1SGWA-1S50UJ (˂50U)50UJ (˂50U) GWA-20SGWA-20S˂50U (30J+)˂50U (30J+)GWA-22SGWA-22S˂50U (˂50U)˂50U (˂50U) GWA-23SGWA-23S˂50U (˂50U)˂50U (˂50U) GWA-2SGWA-2S460 (440 )460 (440 ) GWA-3SAGWA-3SA50UJ (˂50U)50UJ (˂50U) GWA-4SGWA-4S50UJ (˂50U)50UJ (˂50U) GWA-5SGWA-5S˂50U (˂50U)˂50U (˂50U) GWA-6SGWA-6S˂50U (34J+)˂50U (34J+) GWA-7SGWA-7S˂50U (˂50U)˂50U (˂50U) GWA-8SGWA-8S240 (240 )240 (240 ) GWA-9SGWA-9S200 (210 )200 (210 ) MW-10MW-10180 (170 )180 (170 ) MW-11SRMW-11SR360 (340 )360 (340 ) MW-13MW-1360 (66 )60 (66 ) MW-14MW-14130 (110 )130 (110 ) MW-15MW-15280 (260 )280 (260 ) MW-1SMW-1S300 (310 )300 (310 ) MW-3SMW-3S260 (260 )260 (260 ) MW-5SMW-5S330 (320 )330 (320 ) MW-6SMW-6S230 (240 )230 (240 ) MW-8IMW-8I˂50U (˂50U)˂50U (˂50U)MW-8SMW-8S˂50U (˂50U)˂50U (˂50U) MW-9MW-936J (37J)36J (37J) BORON ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-125 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR BORON IS 700 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 100100 5050 1 0 0 1 0 0 100 100 11 00 0 0 5 0 5 0 5050 5050 5 0 5 0 44 00 00 44 00 00 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D65 (67 )65 (67 ) AB-2DAB-2D160 (200 )160 (200 ) AB-3DAB-3D˂50U (˂50U)˂50U (˂50U) AB-4DAB-4D˂50U (26J)˂50U (26J) AB-5DAB-5D150 (170J+)150 (170J+) AB-7DAB-7D50UJ (36J)50UJ (36J) AB-8DAB-8D440 (470 )440 (470 ) AS-1DAS-1D˂50U (˂50U)˂50U (˂50U) AS-2DAS-2D28J (˂50U)28J (˂50U) AS-3DAS-3D27J (˂50U)27J (˂50U)BG-1DBG-1D27J (49J)27J (49J) BG-2DBG-2D50UJ (˂50U)50UJ (˂50U) BG-3DBG-3D˂50U (˂50U)˂50U (˂50U) C-2DC-2D˂50U (˂50U)˂50U (˂50U) GWA-10DGWA-10D140 (110 )140 (110 )GWA-1DGWA-1D33J (31J)33J (31J) GWA-20DGWA-20D˂50U (˂50U)˂50U (˂50U)GWA-22DGWA-22D˂50U (˂50U)˂50U (˂50U) GWA-23DGWA-23D˂50U (37J)˂50U (37J) GWA-3DGWA-3D34J (34J)34J (34J) GWA-4DGWA-4D50UJ (˂50U)50UJ (˂50U) GWA-5DGWA-5D˂50U (31J+)˂50U (31J+) GWA-6DGWA-6D˂50U (˂50U)˂50U (˂50U) GWA-7DGWA-7D˂50U (˂50U)˂50U (˂50U) GWA-8DGWA-8D110 (120 )110 (120 ) GWA-9DGWA-9D260J+ (260 )260J+ (260 ) MW-11DRMW-11DR320 (320 )320 (320 ) MW-15DMW-15D170 (190 )170 (190 ) MW-1DMW-1D650 (650 )650 (650 ) MW-2DMW-2D˂50U (˂50U)˂50U (˂50U) MW-3DMW-3D260 (270 )260 (270 ) MW-4DMW-4D270 (290 )270 (290 ) MW-5DMW-5D380 (400 )380 (400 ) MW-6DMW-6D320 (340 )320 (340 ) MW-8DMW-8D50UJ (˂50U)50UJ (˂50U) MW-9DMW-9D50UJ (˂50U)50UJ (˂50U) BORON ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL ISOCONCENTRATION CONTOUR DATE FIGURE AUGUST 2015 10-126 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR BORON IS 700 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 4 0 0 4 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 110000 5 5 0 0 5 5 0 0 5500 5 0 5 0 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR˂50U (˂50U)˂50U (˂50U) AB-6BRUAB-6BRU480 (460 )480 (460 ) BG-2BRBG-2BR˂50U (˂50U)˂50U (˂50U) GWA-20BRGWA-20BR˂50U (˂50U)˂50U (˂50U)GWA-22BRGWA-22BR˂50U (˂50U)˂50U (˂50U) GWA-23BRGWA-23BR˂50U (˂50U)˂50U (˂50U) GWA-2BRGWA-2BR˂50U (˂50U)˂50U (˂50U) GWA-2BRUGWA-2BRU˂50U (50 )˂50U (50 ) GWA-4BRGWA-4BR˂50U (˂50U)˂50U (˂50U) GWA-7BRGWA-7BR˂50U (˂50U)˂50U (˂50U) GWA-9BRGWA-9BR210210 MW-15BRMW-15BR260 (240 )260 (240 ) MW-7BRMW-7BR˂50U (˂50U)˂50U (˂50U) MW-9BRMW-9BR˂50U (˂50U)˂50U (˂50U) BORON ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-127 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR BORON IS 700 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1 1 1 1 11 1 1 1 1 11 11 11 11 1 1 11 1 1 1 0 1 0 1 0 1 0 0 .50 .5 0 0 ..5 5 0 .50.5 0.50.5 0 . 5 0 . 5 0.50.5 0 . 5 0 . 5 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S1.8J+ (0.48J)1.8J+ (0.48J) AB-2SAB-2S2.5J+ (0.3J+)2.5J+ (0.3J+) AB-6SAB-6S1.2J+ (0.78J+)1.2J+ (0.78J+) AB-7IAB-7I0.9J+ (1.1J+)0.9J+ (1.1J+) AB-8SAB-8S3.8 (3.1 )3.8 (3.1 ) AS-1SAS-1S6.1 (0.66J+)6.1 (0.66J+) AS-2SAS-2S44.8 44.8 (10.2 )(10.2 ) BG-1SBG-1S5.2 (0.43J+)5.2 (0.43J+) BG-2SBG-2S0.83 (0.41J)0.83 (0.41J) BG-3SBG-3S0.25J+ (0.33J+)0.25J+ (0.33J+) C-2SC-2S0.64J+ (0.51J+)0.64J+ (0.51J+) GWA-10SGWA-10S3.5J (1J)3.5J (1J) GWA-1SGWA-1S11.6 11.6 (1.1J) (1.1J) GWA-20SGWA-20S133 133 (0.38J+) (0.38J+)GWA-22SGWA-22S1.9J+ (0.77J+)1.9J+ (0.77J+) GWA-23SGWA-23S3.2J+ (0.54J+)3.2J+ (0.54J+) GWA-2SGWA-2S2.8J+ (1J+)2.8J+ (1J+) GWA-3SAGWA-3SA0.53J+ (0.55J+)0.53J+ (0.55J+) GWA-4SGWA-4S2.1 (2.2 )2.1 (2.2 ) GWA-5SGWA-5S0.57J+ (0.32J+)0.57J+ (0.32J+) GWA-6SGWA-6S1.7J+ (0.52J+)1.7J+ (0.52J+) GWA-7SGWA-7S3.8 (2.3J+)3.8 (2.3J+) GWA-8SGWA-8S6.4J+ (1.5J+)6.4J+ (1.5J+) GWA-9SGWA-9S0.32J+ (0.36J+)0.32J+ (0.36J+) MW-10MW-102.7 (2.1J+)2.7 (2.1J+) MW-11SRMW-11SR1.8J (1.9J)1.8J (1.9J) MW-13MW-130.38J+ (0.4J+)0.38J+ (0.4J+) MW-14MW-141.7J+ (1.3J+)1.7J+ (1.3J+) MW-15MW-156.8 (4.9 )6.8 (4.9 ) MW-1SMW-1S0.57J+ (0.5UJ)0.57J+ (0.5UJ) MW-3SMW-3S0.44J+ (0.41J+)0.44J+ (0.41J+) MW-5SMW-5S1.7 (1.6 )1.7 (1.6 ) MW-6SMW-6S0.5UJ (0.36J+)0.5UJ (0.36J+) MW-8IMW-8I1.3J+ (0.71J+)1.3J+ (0.71J+)MW-8SMW-8S0.71J+ (0.42J+)0.71J+ (0.42J+) MW-9MW-91.2 (1J+)1.2 (1J+) CHROMIUM ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-128 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR CHROMIUM IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 1 0 0 1 0 0 1 0 1 0 1 010 1 01 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1010 1010 1010 0 .50 .5 0 0 ..5 5 0 .5 0 .5 00..55 0 . 5 0 . 5 0.50.5 0 0 . . 5 5 S R -2 0 7 4 S R -1 9 1 2 AABB--11DD4499..22 ((2211..22 )) AABB--22DD1133((1122..11 )) AABB--33DD5511((4455..33 )) AB-4DAB-4D7.4 (6.4 )7.4 (6.4 ) AB-5DAB-5D5.3 (3.9 )5.3 (3.9 ) AABB--77DD2244..77 ((2266..44 )) AB-8DAB-8D1.4 (0.43J)1.4 (0.43J) AS-1DAS-1D903 903 (830 )(830 ) AS-2DAS-2D22.5 22.5 (20.7 )(20.7 ) AS-3DAS-3D23.5 23.5 (20.9 )(20.9 )BBGG--11DD3322..33 ((2288..77 )) BBGG--22DD5577..55 ((5555..99 )) BG-3DBG-3D0.97J+ (0.86J+)0.97J+ (0.86J+) C-2DC-2D2.5J+ (2.7J+)2.5J+ (2.7J+) GWA-10DGWA-10D6.1 (7.9 )6.1 (7.9 ) GWA-1DGWA-1D6.1 (2.9J)6.1 (2.9J) GWA-20DGWA-20D186 186 (144 )(144 ) GWA-22DGWA-22D174 174 (171 )(171 ) GWA-23DGWA-23D55 55 (53.6 )(53.6 ) GWA-3DGWA-3D1.1 (0.86 )1.1 (0.86 ) GWA-4DGWA-4D2.1 (0.6 )2.1 (0.6 ) GGWWAA--55DD2244..55 ((1111..99 )) GGWWAA--66DD2244..88 ((2211 )) GWA-7DGWA-7D3.3 (2.1 )3.3 (2.1 ) GWA-8DGWA-8D4.2J+ (2.5J+)4.2J+ (2.5J+) GWA-9DGWA-9D0.39J+ (0.4J+)0.39J+ (0.4J+) MW-11DRMW-11DR2.5J2.5J MW-15DMW-15D3.5 (3.5 )3.5 (3.5 ) MW-1DMW-1D0.8J+ (0.66J+)0.8J+ (0.66J+) MW-2DMW-2D3.6J+ (2.3J+)3.6J+ (2.3J+) MW-3DMW-3D1.7J+ (1.8J+)1.7J+ (1.8J+) MW-4DMW-4D1.4J+ (1.3J+)1.4J+ (1.3J+) MW-5DMW-5D2.7J+ (2.4J+)2.7J+ (2.4J+) MW-6DMW-6D1.9J+ (1.1J+)1.9J+ (1.1J+) MW-8DMW-8D4.1 (0.77J+)4.1 (0.77J+) MW-9DMW-9D27 27 (26.3 )(26.3 ) CHROMIUM ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-129 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR CHROMIUM IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 1 1 1 1 1 1 1 1 1 1 11 11 1 1 11 1 1 1 010 1 1 0 0 1 0 1 0 1 010 1 1 0 0 1 01 0 1010 1 0 1 0 1010 1100 11 00 0 .50 .5 0 .50 .5 0 .5 0 .5 0 .50.5 0.50.5 00..55 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR8.27 (1.99 )8.27 (1.99 ) AB-6BRUAB-6BRU8.1 (3.1J)8.1 (3.1J) BG-2BRBG-2BR2.3 (0.52J+)2.3 (0.52J+) GWA-20BRGWA-20BR16.7 16.7 (3.85 ) (3.85 )GWA-22BRGWA-22BR108 108 (49.5 )(49.5 ) GWA-23BRGWA-23BR15.6 15.6 (13.4 )(13.4 ) GWA-2BRGWA-2BR7.4 (3.4 )7.4 (3.4 ) GWA-2BRUGWA-2BRU46 46 (22.9 )(22.9 ) GWA-4BRGWA-4BR38.1 38.1 (29.4 )(29.4 ) GWA-7BRGWA-7BR5.8 (7.8 )5.8 (7.8 ) GWA-9BRGWA-9BR40.640.6 MW-15BRMW-15BR4.9 (4.2 )4.9 (4.2 ) MMWW--77BBRR2244..77 ((2233..33 )) MW-9BRMW-9BR4J (5 )4J (5 ) CHROMIUM ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-130 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR CHROMIUM IS 10 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1010 1010 1010 1 0 1 0 1 0 1 0 1 0 1 0 11 11 1 1 1 1 1 1 11 11 11 1 1 11 11 11 0 .50.5 0 .5 0 .5 0 .5 0 .5 0.50.5 0 . 5 0 . 5 0.50.5 0 0 . . 5 5 S R -2 0 7 4 S R -1 9 1 2 AABB--11SS1155..99 ((1166..22 )) AABB--22SS1177..11 ((1155..99 )) AB-6SAB-6S0.31J (˂0.5U)0.31J (˂0.5U) AABB--77II11..66 ((11..55 )) AB-8SAB-8S0.55 (0.56 )0.55 (0.56 ) AS-1SAS-1S5.4 5.4 (5.3 )(5.3 ) AS-2SAS-2S12.4 12.4 (10.1 )(10.1 )BBGG--11SS33((11..99 )) BG-2SBG-2S0.69 (0.69 )0.69 (0.69 ) BG-3SBG-3S0.54 (0.54 )0.54 (0.54 ) C-2SC-2S39.7 39.7 (42.5 )(42.5 ) GWA-10SGWA-10S10 10 (10.3 )(10.3 ) GWA-1SGWA-1S2.1 2.1 (0.23J) (0.23J) GWA-20SGWA-20S12.7 12.7 (3 )(3 )GWA-22SGWA-22S1.3 1.3 (1.2 )(1.2 ) GWA-23SGWA-23S3.3 3.3 (3.1 )(3.1 ) GWA-2SGWA-2S0.34J (˂0.5U)0.34J (˂0.5U) GWA-3SAGWA-3SA18.4 18.4 (19.8 )(19.8 ) GWA-4SGWA-4S1.7 1.7 (1.4 )(1.4 ) GGWWAA--55SS44..55 ((44..66 )) GGWWAA--66SS2277..66 ((2255..33 )) GWA-7SGWA-7S1J+ (0.31J+)1J+ (0.31J+) GGWWAA--88SS6666..88 ((22 )) GGWWAA--99SS5500..11 ((5511 )) MW-10MW-100.9 (0.72 )0.9 (0.72 ) MW-11SRMW-11SR˂0.5U (˂0.5U)˂0.5U (˂0.5U) MMWW--11332233..77 ((2244..33 )) MW-14MW-14˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-15MW-151.3 1.3 (0.58 ) (0.58 ) MMWW--11SS6611((6600..77 )) MW-3SMW-3S0.14J (˂0.5U)0.14J (˂0.5U) MMWW--55SS11..99 ((22..22 )) MW-6SMW-6S0.2J (0.21J)0.2J (0.21J) MW-8IMW-8I0.76 (0.5UJ)0.76 (0.5UJ)MW-8SMW-8S0.23J (0.2J)0.23J (0.2J) MW-9MW-90.87 (0.67 )0.87 (0.67 ) COBALT ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-131 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR COBALT IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 11 1 1 1 1 11 0 .5 0 .5 0 . 5 0 . 5 0.50.5 0 . 5 0 . 5 0 . 5 0 . 5 0 .5 0 .5 0 .50.5 S R -2 0 7 4 S R -1 9 1 2 AABB--11DD22..99 ((˂˂00..55UU)) AB-2DAB-2D0.15J (˂0.5U)0.15J (˂0.5U) AB-3DAB-3D0.18J (˂0.5U)0.18J (˂0.5U) AB-4DAB-4D0.18J (˂0.5U)0.18J (˂0.5U) AB-5DAB-5D˂0.5U (˂0.5U)˂0.5U (˂0.5U) AB-7DAB-7D˂0.5U (0.5UJ)˂0.5U (0.5UJ) AB-8DAB-8D0.73 (0.61 )0.73 (0.61 ) AS-1DAS-1D0.18J (˂0.5U)0.18J (˂0.5U) AS-2DAS-2D0.2J (˂0.5U)0.2J (˂0.5U) AS-3DAS-3D0.16J (˂0.5U)0.16J (˂0.5U)BBGG--11DD11..33 ((11..33 )) BG-2DBG-2D˂0.5U (˂0.5U)˂0.5U (˂0.5U) BG-3DBG-3D0.84 (0.14J)0.84 (0.14J) C-2DC-2D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-10DGWA-10D0.19J (˂0.5U)0.19J (˂0.5U) GWA-1DGWA-1D0.55 (˂0.5U)0.55 (˂0.5U) GGWWAA--2200DD11..99 ((˂˂00..55UU))GWA-22DGWA-22D3.4 3.4 (˂0.5U) (˂0.5U) GWA-23DGWA-23D˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-3DGWA-3D1.1 1.1 (1.2 )(1.2 ) GWA-4DGWA-4D0.52 (0.52 )0.52 (0.52 ) GWA-5DGWA-5D0.21J (˂0.5U)0.21J (˂0.5U) GWA-6DGWA-6D0.3J+ (˂0.5U)0.3J+ (˂0.5U) GWA-7DGWA-7D0.63 (˂0.5U)0.63 (˂0.5U) GWA-8DGWA-8D0.7 (0.16J)0.7 (0.16J) GWA-9DGWA-9D0.58 (0.47J+)0.58 (0.47J+) MW-11DRMW-11DR0.5UJ0.5UJ MW-15DMW-15D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-1DMW-1D0.51 (0.25J)0.51 (0.25J) MW-2DMW-2D0.14J (˂0.5U)0.14J (˂0.5U) MW-3DMW-3D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-4DMW-4D0.67 (0.57 )0.67 (0.57 ) MW-5DMW-5D0.24J (˂0.5U)0.24J (˂0.5U) MW-6DMW-6D˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-8DMW-8D1.1 1.1 (0.5UJ) (0.5UJ) MW-9DMW-9D˂0.5U (0.5UJ)˂0.5U (0.5UJ) COBALT ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-132 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR COBALT IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 11 11 0 .50.5 0 .50.5 S R -2 0 7 4 S R -1 9 1 2 AABB--33BBRR11..6644 ((˂˂11UU)) AB-6BRUAB-6BRU1.8 1.8 (˂0.5U) (˂0.5U) BG-2BRBG-2BR0.82 (0.17J)0.82 (0.17J) GWA-20BRGWA-20BR˂1U (˂1U)˂1U (˂1U) GWA-22BRGWA-22BR˂1U (˂1U)˂1U (˂1U) GWA-23BRGWA-23BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-2BRGWA-2BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-2BRUGWA-2BRU0.81 (0.5 )0.81 (0.5 ) GWA-4BRGWA-4BR˂1U (˂1U)˂1U (˂1U) GWA-7BRGWA-7BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) GWA-9BRGWA-9BR0.750.75 MW-15BRMW-15BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-7BRMW-7BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) MW-9BRMW-9BR˂0.5U (˂0.5U)˂0.5U (˂0.5U) COBALT ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL IMAC CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-133 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR COBALT IS 1 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1,000 1,000 1 0 ,0 0 010,0 0 0 1 ,0 0 0 1 ,0 0 0 1 ,0 0 0 1 ,0 0 0 1 ,0 0 01,0 0 0 1 , 0 0 0 1 , 0 0 0 1 , 0 0 0 1 , 0 0 0 1 ,0 0 0 1 ,0 0 0 1 1 0 0 ,,0 0 0 0 0 0 300 300 3 0 0300 3 3 0 0 0 0 3 0 0 3 0 0 300 300 3 0 0 3 0 0 33 00 00 3 3 0 0 00 300300 3 0 0300 3 0 030 0 300300 3 0 0 3 0 0 3 0 0 3 0 0 5050 5050 5 0 5 0 5 050 5050 5 050 5 0 5 0 5 0 5 0 S R -2 0 7 4 S R -1 9 1 2 AABB--11SS551100((˂˂5500UU)) AABB--22SS11,,770000 ((˂˂5500UU)) AB-6SAB-6S730 730 (˂50U) (˂50U) AABB--77II338800((˂˂5500UU)) AB-8SAB-8S160 (˂50U)160 (˂50U) AS-1SAS-1S660 660 (˂50U) (˂50U) AS-2SAS-2S2,090 2,090 (314 )(314 )BBGG--11SS22,,220000 ((˂˂5500UU)) BG-2SBG-2S28J (˂50U)28J (˂50U) BG-3SBG-3S50UJ (˂50U)50UJ (˂50U) C-2SC-2S140J+ (˂50U)140J+ (˂50U) GWA-10SGWA-10S87 (32J)87 (32J) GWA-1SGWA-1S1,800 1,800 (˂50U) (˂50U) GWA-20SGWA-20S9,500 9,500 (34J) (34J)GWA-22SGWA-22S94 (˂50U)94 (˂50U) GWA-23SGWA-23S530 530 (˂50U) (˂50U) GWA-2SGWA-2S590 590 (˂50U) (˂50U) GWA-3SAGWA-3SA420 420 (190 ) (190 ) GWA-4SGWA-4S220 (˂50U)220 (˂50U) GWA-5SGWA-5S44J+ (˂50U)44J+ (˂50U) GGWWAA--66SS11,,110000 ((˂˂5500UU)) GGWWAA--77SS779900((˂˂5500UU)) GWA-8SGWA-8S58 (˂50U)58 (˂50U) GWA-9SGWA-9S170J+ (26J)170J+ (26J) MW-10MW-10220 (˂50U)220 (˂50U) MW-11SRMW-11SR46J (33J)46J (33J) MMWW--11331155,,770000 ((1155,,000000 )) MW-14MW-1428J+ (˂50U)28J+ (˂50U) MW-15MW-15160 (˂50U)160 (˂50U) MMWW--11SS3300,,880000 ((3300,,660000 )) MW-3SMW-3S140J+ (˂50U)140J+ (˂50U) MW-5SMW-5S˂50U (˂50U)˂50U (˂50U) MW-6SMW-6S250J+ (71J+)250J+ (71J+) MMWW--88II22,,110000 ((˂˂5500UU))MW-8SMW-8S85J+ (˂50U)85J+ (˂50U) MW-9MW-9220 (˂50U)220 (˂50U) IRON ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-134 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR IRON IS 300 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 11,,0000 00 11 00 00 110000 110000 1 1 0 0 0 0 1 0 010 0 1 0 010 0 1 0 010 0110000 1 0 0 1 0 0 1 1 0 0 0 0 1 0 0 1 0 0 1 1 , ,000000 3 3 0 0 0 0 300300 300 300 3 3 0 0 0 0 3 0 030 0 3300 0 0 3300 0 0 3 3 00 00 5050 5050 5500 5050 5 050 5 05 0 5 050 5 0 5 0 5 05 0 S R -2 0 7 4 S R -1 9 1 2 AABB--11DD337700((˂˂5500UU)) AB-2DAB-2D130 (˂50U)130 (˂50U) AB-3DAB-3D270 (˂50U)270 (˂50U) AB-4DAB-4D130 (˂50U)130 (˂50U) AB-5DAB-5D56 (˂50U)56 (˂50U) AB-7DAB-7D94J+ (˂50U)94J+ (˂50U) AB-8DAB-8D300 (60 )300 (60 ) AS-1DAS-1D107 (100 )107 (100 ) AS-2DAS-2D221 (˂50U)221 (˂50U) AS-3DAS-3D279 (˂50U)279 (˂50U)BBGG--11DD11,,550000 ((˂˂5500UU)) BG-2DBG-2D˂50U (˂50U)˂50U (˂50U) BBGG--33DD993300((˂˂5500UU)) C-2DC-2D56J+ (˂50U)56J+ (˂50U) GWA-10DGWA-10D170 (˂50U)170 (˂50U)GWA-1DGWA-1D720 720 (˂50U) (˂50U) GWA-20DGWA-20D660 660 (˂50U) (˂50U)GWA-22DGWA-22D2,600 2,600 (˂50U) (˂50U) GWA-23DGWA-23D33J (˂50U)33J (˂50U) GWA-3DGWA-3D˂50U (˂50U)˂50U (˂50U) GWA-4DGWA-4D62 (˂50U)62 (˂50U) GWA-5DGWA-5D86 (˂50U)86 (˂50U) GWA-6DGWA-6D290J+ (˂50U)290J+ (˂50U) GGWWAA--77DD444400((˂˂5500UU)) GGWWAA--88DD11,,330000 ((˂˂5500UU)) GWA-9DGWA-9D270 (80 )270 (80 ) MW-11DRMW-11DR62 (˂50U)62 (˂50U) MW-15DMW-15D75J+ (˂50U)75J+ (˂50U) MW-1DMW-1D74J+ (˂50U)74J+ (˂50U) MW-2DMW-2D72J+ (˂50U)72J+ (˂50U) MW-3DMW-3D44J+ (˂50U)44J+ (˂50U) MW-4DMW-4D230J+ (˂50U)230J+ (˂50U) MW-5DMW-5D200J+ (˂50U)200J+ (˂50U) MW-6DMW-6D93J+ (˂50U)93J+ (˂50U) MW-8DMW-8D2,700 2,700 (˂50U) (˂50U) MW-9DMW-9D180 (88 )180 (88 ) IRON ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-135 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR IRON IS 300 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 1 0 0 1 0 0 1 ,0 0 01,0 0 0 1 0 0 1 0 0 1 0 0100 1 0 010 0 11 00 00 1 0 01 0 0 1 1 0 0 0 0 1 0 01 0 0 1 0 0 1 0 0 1 0 0 1 0 0 3 0 0 3 0 0 3 0 0300 3 0 0300 3 3 0 0 0 0 3 3 00 00 300300 55 00 5 050 5 0 5 0 5050 5 0 5 0 5 0 5 0 5 0 5 0 S R -2 0 7 4 S R -1 9 1 2 AABB--33BBRR44,,444400 ((3333 )) AB-6BRUAB-6BRU970 970 (52 ) (52 ) BG-2BRBG-2BR760J760J (˂50U) (˂50U) GWA-20BRGWA-20BR143 (˂10U)143 (˂10U) GWA-22BRGWA-22BR61 (˂10U)61 (˂10U) GWA-23BRGWA-23BR140 (˂50U)140 (˂50U) GWA-2BRGWA-2BR64 (˂50U)64 (˂50U) GWA-2BRUGWA-2BRU1,500 1,500 (50 ) (50 ) GWA-4BRGWA-4BR87 (˂10U)87 (˂10U) GWA-7BRGWA-7BR77 (˂50U)77 (˂50U) GWA-9BRGWA-9BR450450 MW-15BRMW-15BR54 (˂50U)54 (˂50U) MW-7BRMW-7BR˂50U (˂50U)˂50U (˂50U) MW-9BRMW-9BR180 (˂50U)180 (˂50U) IRON ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-136 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR IRON IS 300 µg/LNON DETECT CONTOUR CONCENTRATION IS 50 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 100100 1 0 0 1 0 0 1,000 1,000 1 ,0 0 01,0 0 0 100100 1 0 0100 1 0 0 1 0 0 100100 11 00 00 1 0 0 1 0 0 1 0 0100 1 1 0 0 0 0 11,,00 00 0 0 55 00 00 1 1 ,,00 0000 1 1 ,,000000 1 1 0 0 0 0 1 , 0 0 0 1 , 0 0 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 5050 5 050 5 050 5 0 5 0 5 05 0 5 05 0 55 00 5 0 5 0 5 5 0 0 5500 5 0 5 0 5050 55 5 5 5 5 55 55 55 S R -2 0 7 4 S R -1 9 1 2 AABB--11SS225500((226600 )) AABB--22SS333300((331100 )) AB-6SAB-6S12 (˂5U)12 (˂5U) AABB--77II8855((7777 )) AB-8SAB-8S150 150 (140 )(140 ) AS-1SAS-1S1,900 1,900 (1,700 )(1,700 ) AS-2SAS-2S640 640 (580 )(580 )BBGG--11SS330000((224400 )) BG-2SBG-2S370 370 (360 )(360 ) BBGG--33SS224400((224400 )) C-2SC-2S600 600 (580 )(580 ) GWA-10SGWA-10S250 250 (240 )(240 ) GWA-1SGWA-1S110 110 (30 ) (30 ) GGWWAA--2200SS332200((115500 ))GWA-22SGWA-22S48 (44 )48 (44 ) GGWWAA--2233SS8822((8811 )) GWA-2SGWA-2S95 95 (56 )(56 ) GWA-3SAGWA-3SA12,700 12,700 (13,600 )(13,600 ) GWA-4SGWA-4S120 120 (92 )(92 ) GGWWAA--55SS119900((220000 )) GWA-6SGWA-6S1,300 1,300 (1,100 )(1,100 ) GWA-7SGWA-7S30 (16 )30 (16 ) GGWWAA--88SS772200((776600 )) GWA-9SGWA-9S2,900 2,900 (3,000 )(3,000 ) MW-10MW-1036 (30 )36 (30 ) MW-11SRMW-11SR32 (29 )32 (29 ) MW-13MW-138,300 8,300 (8,700 )(8,700 ) MW-14MW-144J (3.1J)4J (3.1J) MW-15MW-1533 (26 )33 (26 ) MMWW--11SS22,,660000 ((22,,660000 )) MMWW--33SS6688((5533 )) MW-5SMW-5S39 (49 )39 (49 ) MW-6SMW-6S44 (43 )44 (43 ) MW-8IMW-8I39 (2.8J)39 (2.8J)MW-8SMW-8S57 57 (54 )(54 ) MW-9MW-97 (4.6J)7 (4.6J) MANGANESE ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-137 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR MANGANESE IS 50 µg/LNON DETECT CONTOUR CONCENTRATION IS 5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1100 1 010 1010 1010 1 0 1 0 1 01 0 5 0 5 0 5 0 5 0 5 0 5 0 5 5 0 0 5 050 5050 5050 5 5 5 5 55 55 55 55 5 5 55 5 5 5 5 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D10 (˂5U)10 (˂5U) AB-2DAB-2D5.6 (˂5U)5.6 (˂5U) AB-3DAB-3D6.7 (˂5U)6.7 (˂5U) AB-4DAB-4D4.1J (˂5U)4.1J (˂5U) AB-5DAB-5D˂5U (˂5U)˂5U (˂5U) AB-7DAB-7D4.6J (˂5U)4.6J (˂5U) AB-8DAB-8D140 140 (130 )(130 ) AS-1DAS-1D3.7J (˂5U)3.7J (˂5U) AS-2DAS-2D8.2 (˂5U)8.2 (˂5U) AS-3DAS-3D12 (˂5U)12 (˂5U) BG-1DBG-1D27 (˂5U)27 (˂5U) BG-2DBG-2D˂5U (˂5U)˂5U (˂5U) BBGG--33DD6633((1144 )) C-2DC-2D9.1 (7 )9.1 (7 ) GWA-10DGWA-10D10 (˂5U)10 (˂5U) GWA-1DGWA-1D28 (˂5U)28 (˂5U) GWA-20DGWA-20D15 (˂5U)15 (˂5U)GWA-22DGWA-22D120 120 (˂5U) (˂5U) GWA-23DGWA-23D˂5U (˂5U)˂5U (˂5U) GWA-3DGWA-3D9,200 9,200 (11,600 )(11,600 ) GWA-4DGWA-4D28 (27 )28 (27 ) GWA-5DGWA-5D˂5U (˂5U)˂5U (˂5U) GWA-6DGWA-6D6.8 (˂5U)6.8 (˂5U) GWA-7DGWA-7D28 (˂5U)28 (˂5U) GGWWAA--88DD9966((6699 )) GGWWAA--99DD9900((8833 )) MW-11DRMW-11DR9.1 (6.3 )9.1 (6.3 ) MW-15DMW-15D3.3J+ (˂5U)3.3J+ (˂5U) MW-1DMW-1D530 530 (430 )(430 ) MW-2DMW-2D8.3 (7.7 )8.3 (7.7 ) MW-3DMW-3D˂5U (˂5U)˂5U (˂5U) MW-4DMW-4D24J+ (22J+)24J+ (22J+) MW-5DMW-5D8.1J+ (3J+)8.1J+ (3J+) MW-6DMW-6D8.4J+ (7.2J+)8.4J+ (7.2J+) MW-8DMW-8D40 (3.5J)40 (3.5J) MW-9DMW-9D8.1 (4.6J)8.1 (4.6J) MANGANESE ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-138 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR MANGANESE IS 50 µg/LNON DETECT CONTOUR CONCENTRATION IS 5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 1 0 1 0 1 010 11 0 0 1 01 0 1100 5 05 0 5 0 5 0 5 5 5 5 55 55 55 S R -2 0 7 4 S R -1 9 1 2 AABB--33BBRR8877((˂˂55UU)) AB-6BRUAB-6BRU25 (2.8J)25 (2.8J) BG-2BRBG-2BR28J (˂5U)28J (˂5U) GWA-20BRGWA-20BR˂5U (˂5U)˂5U (˂5U)GWA-22BRGWA-22BR˂5U (˂5U)˂5U (˂5U) GWA-23BRGWA-23BR4.4J (˂5U)4.4J (˂5U) GWA-2BRGWA-2BR5UJ (3.5J)5UJ (3.5J) GWA-2BRUGWA-2BRU61 61 (5 ) (5 ) GWA-4BRGWA-4BR˂5U (˂5U)˂5U (˂5U) GWA-7BRGWA-7BR4.2J (˂5U)4.2J (˂5U) GWA-9BRGWA-9BR1313 MW-15BRMW-15BR4.4J (˂5U)4.4J (˂5U) MW-7BRMW-7BR˂5U (˂5U)˂5U (˂5U) MW-9BRMW-9BR7.5 (˂5U)7.5 (˂5U) MANGANESE ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-139 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR MANGANESE IS 50 µg/LNON DETECT CONTOUR CONCENTRATION IS 5 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 1 1 0 0 0 0 ,,0 0 0 0 0 0 1100,,000000 11 00 ,,00 00 00 1 1 0 0 ,,0 0 0 0 0 0 1 1 0 0 ,,0 0 0 0 0 0 1100,,000000 1100,,000000 1 1 0 0 , , 0 0 0 0 0 0 1 1 00 00 ,,000000 2 2 5 5 00 ,, 00 00 00 11 00 00 00 1 1 0 0 0 0 0 0 1 1 0 0 0 0 0 0 1 1 0 0 0 0 0 0 11000000 11 00 00 00 110000 0 0 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S690J690J AB-2SAB-2S1,000UJ1,000UJ AB-6SAB-6S15,70015,700 AB-7IAB-7I6,3006,300 AB-8SAB-8S132,000132,000 AS-1SAS-1S231,000231,000 AS-2SAS-2S5,2005,200 BG-1SBG-1S580J580J BG-2SBG-2S2,9002,900 BG-3SBG-3S2,4002,400 C-2SC-2S60,40060,400 GWA-10SGWA-10S31,00031,000 GWA-1SGWA-1S˂1,000U˂1,000U GWA-20SGWA-20S980J980J GWA-22SGWA-22S˂1,000U˂1,000U GWA-23SGWA-23S˂1,000U˂1,000U GWA-2SGWA-2S36,10036,100 GWA-3SAGWA-3SA1,420,0001,420,000 GWA-4SGWA-4S84,70084,700 GWA-5SGWA-5S˂1,000U˂1,000U GWA-6SGWA-6S1,2001,200 GWA-7SGWA-7S530J530J GWA-8SGWA-8S36,000J+36,000J+ GWA-9SGWA-9S26,50026,500 MW-10MW-1019,50019,500 MW-11SRMW-11SR37,60037,600 MW-13MW-1315,70015,700 MW-14MW-1430,10030,100 MW-15MW-1529,00029,000 MW-1SMW-1S1,200J-1,200J- MW-3SMW-3S29,90029,900 MW-5SMW-5S10,20010,200 MW-6SMW-6S36,70036,700 MW-8IMW-8I˂1,000U˂1,000U MW-8SMW-8S580J580J MW-9MW-924,60024,600 SULFATE ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-140 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR SULFATE IS 250000 µg/LNON DETECT CONTOUR CONCENTRATION IS 1000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 1 1 0 0 0 0 ,,0 0 0 0 0 0 1 0 ,0 0 010,0 0 0 1 0 ,0 0 010,0 0 0 11 00 ,,00 00 00 1 0 ,0 0 010,0 0 0 1 0 ,0 0 010,0 0 0 1 0 ,0 0 0 1 0 ,0 0 0 10,000 10,000 11 00 ,, 00 00 00 10,000 10,000 10,000 10,000 1 0 , 0 0 0 1 0 , 0 0 0 1 1 0 0 ,,0 0 0 0 0 0 110000 ,,00 00 0 0 1 1 0 0 0 0 ,,0 0 0 0 0 0 2 2 5 5 0 0 ,,000000 225500 ,,00 0 0 0 0 1 1 00 00 00 1 0 0 0100 0 1 0 0 01000 10001000 1 0 0 0 1 0 0 0 10001000 1 0 0 0 1 0 0 0 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D22,80022,800 AB-2DAB-2D22,70022,700 AB-3DAB-3D144,000144,000 AB-4DAB-4D13,10013,100 AB-5DAB-5D56,30056,300 AB-7DAB-7D46,50046,500 AB-8DAB-8D136,000136,000 AS-1DAS-1D21,30021,300 AS-2DAS-2D26,00026,000 AS-3DAS-3D18,00018,000 BG-1DBG-1D48,400J+48,400J+ BG-2DBG-2D31,10031,100 BG-3DBG-3D1,1001,100 C-2DC-2D1,9001,900 GWA-10DGWA-10D25,90025,900 GWA-1DGWA-1D8,7008,700 GWA-20DGWA-20D376,000J+376,000J+ GWA-22DGWA-22D23,50023,500 GWA-23DGWA-23D10,60010,600 GWA-3DGWA-3D1,310,0001,310,000 GWA-4DGWA-4D4,4004,400 GWA-5DGWA-5D5,0005,000 GWA-6DGWA-6D15,50015,500 GWA-7DGWA-7D32,30032,300 GWA-8DGWA-8D23,800J+23,800J+ GWA-9DGWA-9D33,20033,200 MW-11DRMW-11DR36,00036,000 MW-15DMW-15D40,10040,100 MW-1DMW-1D86,10086,100 MW-2DMW-2D720J720J MW-3DMW-3D26,70026,700 MW-4DMW-4D30,90030,900 MW-5DMW-5D44,60044,600 MW-6DMW-6D34,60034,600 MW-8DMW-8D˂1,000U˂1,000U MW-9DMW-9D27,60027,600 SULFATE ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-141 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR SULFATE IS 250000 µg/LNON DETECT CONTOUR CONCENTRATION IS 1000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< 5 5 0 0 ,,0 0 0 0 0 0 2 0 ,0 0 0 2 0 ,0 0 0 2 0 ,0 0 0 2 0 ,0 0 0 2 0 ,0 0 0 2 0 ,0 0 0 22 00,,000000 22 00,,00 00 00 1 1 0 0 ,,0 0 0 0 0 0 1 0 ,0 0 0 1 0 ,0 0 0 1 0 ,0 0 0 1 0 ,0 0 0 10,000 10,000 10,000 10,000 11 00 ,,00 00 00 1100,,000000 1 0 0 0 1 0 0 0 1 0 0 01 0 0 0 1 0 0 0 1 0 0 0 10001000 1 0 0 0 1 0 0 0 1000 1000 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR17,00017,000 AB-6BRUAB-6BRU87,00087,000 BG-2BRBG-2BR8,2008,200 GWA-20BRGWA-20BR5,8005,800 GWA-22BRGWA-22BR21,00021,000GWA-23BRGWA-23BR18,00018,000 GWA-2BRGWA-2BR39,50039,500 GWA-2BRUGWA-2BRU3,0003,000 GWA-4BRGWA-4BR6,9006,900 GWA-7BRGWA-7BR21,50021,500 MW-15BRMW-15BR39,50039,500 MW-7BRMW-7BR7,2007,200 MW-9BRMW-9BR18,00018,000 SULFATE ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-142 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR SULFATE IS 250000 µg/LNON DETECT CONTOUR CONCENTRATION IS 1000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 2 2 0 0 0 0 ,,0 0 0 0 0 0220000,,000000 2 2 0 0 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,000000 50,000 50,000 5500,,000000 5500,,000000 5 5 0 0 ,, 0 0 0 0 0 0 550000,,000000 55 0 0 0 0 ,, 0 0 0 0 0 0 25000 25000 22 55000000 22 55 00 00 00 2 5 0 0 025000 2 5 0 0 025000 22 55 00 00 0 0 2 2 5 5 0 0 0 0 0 0 2 2 5 5 0 0 0 0 0 0 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S40,00040,000 AB-2SAB-2S30,00030,000 AB-6SAB-6S296,000296,000 AB-7IAB-7I41,00041,000 AB-8SAB-8S274,000274,000 AS-1SAS-1S750,000J-750,000J- AS-2SAS-2S62,000J-62,000J-BG-1SBG-1S˂25,000U˂25,000U BG-2SBG-2S87,00087,000 BG-3SBG-3S57,00057,000 C-2SC-2S160,000J+160,000J+ GWA-10SGWA-10S109,000109,000 GWA-1SGWA-1S78,00078,000 GWA-20SGWA-20S31,00031,000 GWA-22SGWA-22S˂25,000U˂25,000U GWA-23SGWA-23S27,00027,000 GWA-2SGWA-2S132,000132,000 GWA-3SAGWA-3SA23,000,00023,000,000 GWA-4SGWA-4S187,000187,000 GWA-5SGWA-5S˂25,000U˂25,000U GWA-6SGWA-6S31,000J+31,000J+ GWA-7SGWA-7S65,000J+65,000J+ GWA-8SGWA-8S85,00085,000 GWA-9SGWA-9S60,00060,000 MW-10MW-1069,000J (25,000 )69,000J (25,000 ) MW-11SRMW-11SR˂25,000U˂25,000U MW-13MW-1387,00087,000 MW-14MW-14138,000138,000 MW-15MW-15227,000227,000 MW-1SMW-1S60,00060,000 MW-3SMW-3S118,000118,000 MW-5SMW-5S58,00058,000 MW-6SMW-6S121,000121,000 MW-8IMW-8I77,00077,000 MW-8SMW-8S˂25,000U˂25,000U MW-9MW-9114,000114,000 TOTAL DISSOLVED SOLIDS ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-143 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR TOTAL DISSOLVED SOLIDS IS 500000 µg/LNON DETECT CONTOUR CONCENTRATION IS 25000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 2 2 0 0 0 0 ,,0 0 0 0 0 0 2 2 0 0 00 ,, 00 0000 2 2 0 0 0 0 ,,0 0 0 0 0 0 5 5 0 0 , , 0 0 0 0 0 0 5500,,000000 5 5 0 0 ,,0 0 0 0 0 0 22 00 00 ,,00 00 00 22 00 00 ,,0 0 0 0 0 0 2 2 0 0 0 0 ,,0 0 0 0 0 0 220000,,000000 2 2 0 0 0 0 ,,0 0 0 0 0 0 2 2 0 0 0 0 ,,0 0 0 0 0 0 55 00,, 00 00 00 50,000 50,000 5500,,000000 5 5 0 0 ,,0 0 0 0 0 0 5 0 ,0 0 050,0 0 0 55 00 ,,00 00 00 5 5 0 0 ,,0 0 0 0 0 0 5 5 00 ,,00 00 00 55 00 ,,00 00 00 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 55 00 00 ,,0 0 0 0 0 0 5 5 0 0 0 0 ,,0 0 0 0 00 5 5 0 0 0 0 ,,0 0 0 0 0 0 5 5 0 0 0 0 ,,0 0 0 0 0 0 550000,,000000 2 5 0 0 0 2 5 0 0 0 2 2 5 5 0 0 0 0 0 0 2 2 5 5 0 0 0 0 0 0 2500025000 22 55 00 00 00 22 5 5 0 0 0 0 0 0 22 55 0 0 0 0 0 0 2 5 0 0 025000 2500025000 2 2 5 5 0 0 0 0 0 0 22 55 00 00 00 2 5 0 0 0 2 5 0 0 0 2 2 5 5 0 0 0 0 0 0 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D351,000351,000 AB-2DAB-2D241,000241,000 AB-3DAB-3D946,000946,000 AB-4DAB-4D159,000159,000 AB-5DAB-5D214,000214,000 AB-7DAB-7D326,000326,000 AB-8DAB-8D361,000361,000 AS-1DAS-1D390,000J-390,000J- AS-2DAS-2D280,000J-280,000J- AS-3DAS-3D110,000J-110,000J-BG-1DBG-1D555,000555,000 BG-2DBG-2D261,000261,000 BG-3DBG-3D231,000231,000 C-2DC-2D152,000J+152,000J+ GWA-10DGWA-10D185,000185,000 GWA-1DGWA-1D232,000232,000 GWA-20DGWA-20D2,900,0002,900,000 GWA-22DGWA-22D214,000214,000 GWA-23DGWA-23D196,000196,000 GWA-3DGWA-3D2,390,0002,390,000 GWA-4DGWA-4D101,000101,000 GWA-5DGWA-5D137,000137,000 GWA-6DGWA-6D184,000J+184,000J+ GWA-7DGWA-7D176,000176,000 GWA-8DGWA-8D128,000128,000 GWA-9DGWA-9D26,00026,000 MW-11DRMW-11DR140,000140,000 MW-15DMW-15D241,000241,000 MW-1DMW-1D197,000197,000 MW-2DMW-2D92,00092,000 MW-3DMW-3D141,000141,000 MW-4DMW-4D113,000113,000 MW-5DMW-5D186,000186,000 MW-6DMW-6D129,000129,000 MW-8DMW-8D111,000111,000 MW-9DMW-9D243,000243,000 TOTAL DISSOLVED SOLIDS ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-144 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR TOTAL DISSOLVED SOLIDS IS 500000 µg/LNON DETECT CONTOUR CONCENTRATION IS 25000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< 2 0 0 ,0 0 0200,0 0 0 220000,,000000 2 2 0 0 00 ,,00 0000 220000,,00 00 00 200,000200,000 55 00 ,,00 00 00 5 0 ,0 0 050,0 0 0 55 00 ,,00 00 00 5 5 0 0 ,,0 0 0 0 0 0 55 00,,000000 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 5 0 0 ,,0 0 0 0 0 0 5 0 ,0 0 0 5 0 ,0 0 0 22 0000,,00 00 00 22 00 00 ,,0 0 0 0 0 0 550000,,000000 5 5 0 0 00 ,,000000 5 0 0 ,0 0 0 5 0 0 ,0 0 0 2255 00 00 00 22 55 00 00 00 2 5 0 0 025000 2 2 5 5 0 0 0 0 0 0 2 5 0 0 0 2 5 0 0 0 2 5 0 0 0 2 5 0 0 0 2 5 0 0 0 2 5 0 0 0 S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR160,000160,000 AB-6BRUAB-6BRU247,000247,000 BG-2BRBG-2BR118,000118,000 GWA-20BRGWA-20BR380,000380,000 GWA-22BRGWA-22BR360,000360,000 GWA-23BRGWA-23BR790,000790,000 GWA-2BRGWA-2BR164,000164,000 GWA-2BRUGWA-2BRU18,100,00018,100,000 GWA-4BRGWA-4BR1,500,0001,500,000 GWA-7BRGWA-7BR141,000141,000 MW-15BRMW-15BR232,000232,000 MW-7BRMW-7BR1,180,0001,180,000 MW-9BRMW-9BR107,000107,000 TOTAL DISSOLVED SOLIDS ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL NORTH CAROLINA 2L CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-145 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER NC 2L STANDARD FOR TOTAL DISSOLVED SOLIDS IS 500000 µg/LNON DETECT CONTOUR CONCENTRATION IS 25000 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 0 .10.1 S R -2 0 7 4 S R -1 9 1 2 AB-1SAB-1S˂0.1U (0.018J)˂0.1U (0.018J) AB-2SAB-2S0.072J (0.052J)0.072J (0.052J) AB-6SAB-6S(˂0.1U)(˂0.1U) AB-7IAB-7I0.048J+ (0.042J+)0.048J+ (0.042J+) AB-8SAB-8S0.02J (˂0.1U)0.02J (˂0.1U) AS-1SAS-1S0.076J (0.065J)0.076J (0.065J) AS-2SAS-2S0.11 (0.085J)0.11 (0.085J)BG-1SBG-1S0.032J (0.016J)0.032J (0.016J) BG-2SBG-2S0.033J+ (0.031J)0.033J+ (0.031J) BG-3SBG-3S˂0.1U (˂0.1U)˂0.1U (˂0.1U) C-2SC-2S0.09J (0.095J)0.09J (0.095J) GWA-10SGWA-10S˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-1SGWA-1S˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-20SGWA-20S0.087J (0.04J)0.087J (0.04J)GWA-22SGWA-22S0.02J (0.02J)0.02J (0.02J) GWA-23SGWA-23S˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-2SGWA-2S(˂0.1U)(˂0.1U) GWA-3SAGWA-3SA˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-4SGWA-4S0.1UJ (˂0.1U)0.1UJ (˂0.1U) GWA-5SGWA-5S˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-6SGWA-6S0.054J (0.041J)0.054J (0.041J) GWA-7SGWA-7S˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-8SGWA-8S0.031J (˂0.1U)0.031J (˂0.1U) GWA-9SGWA-9S0.04J (0.041J)0.04J (0.041J) MW-10MW-10(˂0.1U)(˂0.1U) MW-11SRMW-11SR˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-13MW-130.072J (0.076J)0.072J (0.076J) MW-14MW-14˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-15MW-15(˂0.1U)(˂0.1U) MW-1SMW-1S˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-3SMW-3S˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-5SMW-5S˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-6SMW-6S˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-8IMW-8I0.02J (˂0.1U)0.02J (˂0.1U)MW-8SMW-8S0.033J (˂0.1U)0.033J (˂0.1U) MW-9MW-9˂0.1U (˂0.1U)˂0.1U (˂0.1U) THALLIUM ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-146 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR THALLIUM IS 0.2 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 110.20.2 0 0 ..1 1 S R -2 0 7 4 S R -1 9 1 2 AB-1DAB-1D0.064J (0.097J)0.064J (0.097J) AB-2DAB-2D0.06J (0.055J)0.06J (0.055J) AB-3DAB-3D0.025J (0.018J)0.025J (0.018J) AB-4DAB-4D˂0.1U (0.027J)˂0.1U (0.027J) AB-5DAB-5D˂0.1U (˂0.1U)˂0.1U (˂0.1U) AB-7DAB-7D˂0.1U (˂0.1U)˂0.1U (˂0.1U) AB-8DAB-8D˂0.1U (˂0.1U)˂0.1U (˂0.1U) AS-1DAS-1D˂0.1U (˂0.1U)˂0.1U (˂0.1U) AS-2DAS-2D˂0.1U (˂0.1U)˂0.1U (˂0.1U) AS-3DAS-3D˂0.1U (˂0.1U)˂0.1U (˂0.1U)BG-1DBG-1D˂0.1U (˂0.1U)˂0.1U (˂0.1U) BG-2DBG-2D0.1UJ (˂0.1U)0.1UJ (˂0.1U) BG-3DBG-3D˂0.1U (˂0.1U)˂0.1U (˂0.1U) C-2DC-2D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-10DGWA-10D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-1DGWA-1D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-20DGWA-20D3.2 3.2 (3.1 )(3.1 )GWA-22DGWA-22D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-23DGWA-23D˂0.1U (0.1UJ)˂0.1U (0.1UJ) GWA-3DGWA-3D˂0.1U (0.016J)˂0.1U (0.016J) GWA-4DGWA-4D0.1UJ (0.094J)0.1UJ (0.094J) GWA-5DGWA-5D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-6DGWA-6D˂0.1U (˂0.1U)˂0.1U (˂0.1U) GWA-7DGWA-7D0.018J (0.032J)0.018J (0.032J) GWA-8DGWA-8D˂0.1U (0.027J)˂0.1U (0.027J) GWA-9DGWA-9D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-11DRMW-11DR˂0.1U˂0.1U MW-15DMW-15D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-1DMW-1D0.034J (0.061J)0.034J (0.061J) MW-2DMW-2D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-3DMW-3D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-4DMW-4D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-5DMW-5D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-6DMW-6D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-8DMW-8D˂0.1U (˂0.1U)˂0.1U (˂0.1U) MW-9DMW-9D˂0.1U (˂0.1U)˂0.1U (˂0.1U) THALLIUM ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR NON DETECT CONTOUR DATE FIGURE AUGUST 2015 10-147 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR THALLIUM IS 0.2 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< S R -2 0 7 4 S R -1 9 1 2 AB-3BRAB-3BR˂0.2U (˂0.2U)˂0.2U (˂0.2U) AB-6BRUAB-6BRU˂0.1U (˂0.1U)˂0.1U (˂0.1U) BG-2BRBG-2BR˂0.1U (0.016J)˂0.1U (0.016J) GWA-20BRGWA-20BR˂0.2U (˂0.2U)˂0.2U (˂0.2U) GWA-22BRGWA-22BR˂0.2U (˂0.2U)˂0.2U (˂0.2U) GWA-23BRGWA-23BR0.077J (0.077J)0.077J (0.077J) GWA-2BRGWA-2BR˂0.1U (˂0.1U)˂0.1U (˂0.1U)GWA-2BRUGWA-2BRU0.03J (0.025 )0.03J (0.025 ) GWA-4BRGWA-4BR˂0.2U (˂0.2U)˂0.2U (˂0.2U) GWA-7BRGWA-7BR˂0.1U (0.017J)˂0.1U (0.017J) GWA-9BRGWA-9BR˂0.1U˂0.1U MW-15BRMW-15BR(˂0.1U)(˂0.1U) MW-7BRMW-7BR0.064J+ (0.071J)0.064J+ (0.071J) MW-9BRMW-9BR0.017J (˂0.1U)0.017J (˂0.1U) THALLIUM ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL DATE FIGURE AUGUST 2015 10-148 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR THALLIUM IS 0.2 µg/LNON DETECT CONTOUR CONCENTRATION IS 0.1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< 3 3 33 33 33 33 0 0 .. 3 3 0.30.3 0 . 3 0 . 3 0.30.3 0 0 ..3 3 0 .3 0 .3 0 .3 0 .3 0 .3 0 .3 0.30.3 00..33 0.30.3 0 0 ..3 3 0 .30.3 0 .30 .3 0 .3 0 .3 0 0 ..3 3 0.30.3 0.30.3 S R -2 0 7 4 S R -1 9 1 2 AABB--11SS11..88 ((˂˂11UU)) AABB--22SS33..88 ((˂˂11UU)) AB-6SAB-6S25.2 25.2 (24.3 )(24.3 ) AB-7IAB-7I˂1U (˂1U)˂1U (˂1U) AB-8SAB-8S0.79J0.79J (0.37J)(0.37J) AS-1SAS-1S1.6J+1.6J+ (0.48J+)(0.48J+) AS-2SAS-2S3.9 3.9 (˂1U) (˂1U)BBGG--11SS55..99 ((˂˂11UU)) BG-2SBG-2S0.35J0.35J (˂1U) (˂1U) BG-3SBG-3S0.75J+0.75J+ (0.7J+)(0.7J+) C-2SC-2S0.52J0.52J (˂1U) (˂1U) GWA-10SGWA-10S0.62J0.62J (0.39J)(0.39J) GWA-1SGWA-1S7.9 7.9 (0.86J)(0.86J) GWA-20SGWA-20S23 23 (˂1U) (˂1U)GWA-22SGWA-22S˂1U (˂1U)˂1U (˂1U) GWA-23SGWA-23S˂1U (˂1U)˂1U (˂1U) GWA-2SGWA-2S2.3 2.3 (1.1 )(1.1 ) GWA-3SAGWA-3SA1.3 1.3 (0.66J)(0.66J) GWA-4SGWA-4S0.84J0.84J (0.37J)(0.37J) GWA-5SGWA-5S˂1U (˂1U)˂1U (˂1U) GGWWAA--66SS44..88 ((˂˂11UU)) GWA-7SGWA-7S3.5J+3.5J+ (1UJ)(1UJ) GWA-8SGWA-8S˂1U (˂1U)˂1U (˂1U) GWA-9SGWA-9S0.52J+0.52J+ (0.42J+)(0.42J+) MW-10MW-101.2 1.2 (0.46J)(0.46J) MW-11SRMW-11SR1.4 1.4 (1.3 )(1.3 ) MW-13MW-131UJ1UJ (1UJ)(1UJ) MW-14MW-142.6J+2.6J+ (2.6J+)(2.6J+) MW-15MW-152.7 2.7 (˂1U) (˂1U) MW-1SMW-1S1UJ1UJ (1UJ)(1UJ) MW-3SMW-3S0.6J+0.6J+ (0.54J+)(0.54J+) MW-5SMW-5S˂1U ˂1U (0.53J)(0.53J) MW-6SMW-6S0.35J0.35J (0.3J) (0.3J) MMWW--88II22..88 ((00..9944JJ))MW-8SMW-8S0.32J+0.32J+ (0.45J+)(0.45J+) MW-9MW-92.7 2.7 (2.1J+)(2.1J+) VANADIUM ISOCONCENTRATION CONTOUR MAP - SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR DATE FIGURE AUGUST 2015 10-149 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR VANADIUM IS 0.3 µg/LNON DETECT CONTOUR CONCENTRATION IS 1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< 11 00 1 01 0 1 01 0 1 0 1 0 1 01 0 1010 1100 1 0 1 0 33 33 33 3 3 33 33 33 33 3 3 33 33 3 3 3 3 33 1 0 1 0 0.30.3 0 . 3 0 . 3 0.30.3 0.30.3 0 . 3 0 . 3 0.3 0.3 0 .30.3 0.30.3 0 .30.3 0 .30.3 0.30.3 0 .3 0 .3 0 .30.3 0 .30.3 0 0 ..3 3 0 .3 0 .3 S R -2 0 7 4 S R -1 9 1 2 AABB--11DD2200((1111..55 )) AABB--22DD3322..44 ((3311..11 )) AABB--33DD1111..55 ((77..44 )) AABB--44DD2244((2244..11 )) AB-5DAB-5D12.5 12.5 (12.7 )(12.7 ) AABB--77DD4400..55 ((4411..11 )) AB-8DAB-8D2.7 2.7 (2.3 )(2.3 ) AS-1DAS-1D14.4 14.4 (13.4 )(13.4 ) AS-2DAS-2D34.6 34.6 (31.8 )(31.8 ) AS-3DAS-3D18.2 18.2 (17.2 )(17.2 )BBGG--11DD2222((2200 )) BBGG--22DD2299..99 ((2299..22 )) BG-3DBG-3D3.7 3.7 (3.1 )(3.1 ) C-2DC-2D10.9 10.9 (9.5 )(9.5 ) GWA-10DGWA-10D6.8 6.8 (7.7 )(7.7 ) GWA-1DGWA-1D21 21 (16.9 )(16.9 ) GWA-20DGWA-20D2.1 2.1 (0.66J)(0.66J)GWA-22DGWA-22D18.5 18.5 (16.1 )(16.1 ) GWA-23DGWA-23D34.1 34.1 (31.9 )(31.9 ) GWA-3DGWA-3D4.6 4.6 (4.3 )(4.3 ) GWA-4DGWA-4D2.4 2.4 (2.4 )(2.4 ) GGWWAA--55DD1133..99 ((1133..99 )) GGWWAA--66DD2288((2266..99 )) GGWWAA--77DD1122..11 ((1111..66 )) GGWWAA--88DD55..55 ((55..55 )) GGWWAA--99DD22..88 ((22..33 )) MW-11DRMW-11DR2.12.1 MW-15DMW-15D22.4 22.4 (23.6 )(23.6 ) MW-1DMW-1D2.1J+2.1J+ (1.9J+)(1.9J+) MW-2DMW-2D4.7 4.7 (4.5 )(4.5 ) MMWW--33DD66..22 ((55..88 )) MMWW--44DD11..11 ((˂˂11UU)) MMWW--55DD88..66 ((88..55 )) MMWW--66DD33..88 ((33..77 )) MW-8DMW-8D4.1 4.1 (1.2 )(1.2 ) MW-9DMW-9D12.8 12.8 (12.5 )(12.5 ) VANADIUM ISOCONCENTRATION CONTOUR MAP - DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL &<COMPLIANCE GROUNDWATER MONITORING WELL &<VOLUNTARY GROUNDWATER MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR DATE FIGURE AUGUST 2015 10-150 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR VANADIUM IS 0.3 µg/LNON DETECT CONTOUR CONCENTRATION IS 1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) &< &< &< &< &<&< &<&< &< &< &< &< &< &< 1 1 0 0 1 01 0 1010 11 0 0 1 0 1 0 3 3 3 3 3 3 3 3 33 33 33 33 33 00..33 0 . 3 0 . 3 0.30.3 00 .. 33 0 .3 0 .3 0.30.3 S R -2 0 7 4 S R -1 9 1 2 AABB--33BBRR3322..11 ((1199 )) AB-6BRUAB-6BRU18.6 18.6 (11.4 )(11.4 ) BBGG--22BBRR44..66 ((22..77 )) GWA-20BRGWA-20BR3.43 3.43 (3.1 )(3.1 )GWA-22BRGWA-22BR4.33 4.33 (9.95 )(9.95 ) GWA-23BRGWA-23BR5.3 5.3 (3.9 )(3.9 ) GWA-2BRGWA-2BR11.8 11.8 (12.3 )(12.3 ) GWA-2BRUGWA-2BRU4 4 (1 )(1 ) GWA-4BRGWA-4BR0.9 0.9 (0.753 )(0.753 ) GGWWAA--77BBRR1100..99 ((1100..99 )) GWA-9BRGWA-9BR67.567.5 MW-15BRMW-15BR2.2 2.2 (2.1 )(2.1 ) MMWW--77BBRR22..11 ((22..11 )) MW-9BRMW-9BR7.8 7.8 (7.8 )(7.8 ) VANADIUM ISOCONCENTRATION CONTOUR MAP - BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA LEGEND: &<GROUNDWATER ASSESSMENT MONITORING WELL IMAC CONTOUR ISOCONCENTRATION CONTOUR DATE FIGURE AUGUST 2015 10-151 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN 300 0 300 600 SCALE (FEET) NOTES: GROUNDWATER IMAC FOR VANADIUM IS 0.3 µg/LNON DETECT CONTOUR CONCENTRATION IS 1 µg/L • PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE• ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE• ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014)• THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107(a)• ALL CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (µg/L) 2.5 TOTAL CONCENTRATION(2.1) DISSOLVED CONCENTRATIONU LESS THAN LABORATORY REPORTING LIMITJ ESTIMATED CONCENTRATIONJ+ ESTIMATED CONCENTRATION (BIASED HIGH) 1 12 I 3 14 I 5 16 17 18 A SOUTHWEST 800 F----. 70, GWE z 0 a w w G WA-4BR Jig/L) hromium 38.1 ed Solids 1,500,000 anadium 0.9 50W 0 200 400 600 800 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION AS-2D 1000 1200 DISTANCE (ft) SECTION A SCALE: HORIZ 1 "=100' IFIC 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 1400 AS-3D 1600 NOT FOR CONSTRUCTION AS-3D Ana to (jig/ L Anti mon ' 1.6 Chromium 23.5 %vanadium 18.2 1800 2000 NORTHEAST 1 800 700 LLJ C' L_ 600 LLJ Z J 2 U Q --J 500 2200 DUKE ENERGY CAROLINASILIC /� DUKE ENERGY.: GASTON COUNTY' RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) ANALYTE NC 2L GROUNDWATER IMAC ANTIMONY 1** ARSENIC 10 BARIUM 700 BERYLLIUM 4** � CADMIUM UM 200 CHLORIDE*** 250,000 CHROMIUM 10 COBALT 1** COPPER*** 1,000 IRON 300 I LEAD 15 (MANGANESE 50 MERCURY 1 NICKEL 100 NITRATE*** 10,000 NITRATE AS N*** 1.000 pH (field) 6.5 - 8.5 SELENIUM 20 SULFATE*** 250,000 THALLIUM 0.2 TOTAL DISSOLVED SOLIDS 500,000 VANADIUM 0.3** ZINC*** 1000 ** Interim Maximum Allowable Concentration (IMAC) *** Unit reported in mg/L in standard, converted here to lug/L to match units displayed on figure. All units shown in pug/L except pH which is standard units. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION 3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOW *DNE = DOES NOT EXCEED LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION A -A' GROUNDWATER ANALYTICAL RESULTS 0 1" Z, FILENAME SCALE AS NOTED D C B IA SHEET FIGURE 10- .1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 SOUTHWEST 800 700 I O LL.I z 0 j W w z J W J _ U Q 600 AB- 7S Ana lyte 1 L Arsenic Cobalt Iron Manganese, Vanadiurn AB- 7I Ana lyte (p / L Cobalt 1 Iron A Man anese L 500 1- 2200 AB- I U Ana lyte J L Antimony 7.5 Chromium 24.7 Vanadiuml 40.5 'N%% N"*� AB-3BR I AB-3D Fff 1K1TC0AAC-n1ATC nA\A --—————————————— — — — --- WATER IN BASIN AB-21a Ana a /L Chromium 13 Vanadium 32.4 AB-2D AB-2S II SECONDARY DAM AB-2S Anal a /L Antimony Cobalt Iron Manganese Vanadium Vanadium 2.8 GWA-9BR Arsenic Chromium Iran Vanadium 2400 2600 2800 3000 3200 3400 3600 3800 4000 4200 DISTANCE (ft) HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION SECTION A SCALE: HORIZ 1 "=100' IFIC 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 NOT FOR CONSTRUCTION 10.7 40.6 450 67.5 A' NORTHEAST 1 800 700 GWA-9BR GWA-9S ]P GWA-9S Arm lyte / L Cobalt 50.1 Manganese 2900 Vanadium 0.52 3+ Iwo] J 500 4400 DUKE ENERGY CAROLINAS.LLC /� DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) ■C ANALYTE NC 2L GROUNDWATER IMAC ANTIMONY 1** ARSENIC 10 BARIUM 700 BERYLLIUM 4** BORON 700 CADMIUM 2 CHLORIDE*** 250,000 CHROMIUM 10 COBALT 1** COPPER*** 1,000 IRON 300 I LEAD 15 (MANGANESE 50 MERCURY 1 NICKEL 100 NITRATE*** 10,000 NITRATE AS N*** 1.000 pH (field) 6.5 - 8.5 SELENIUM 20 SULFATE*** 250,000 THALLIUM 0.2 TOTAL DISSOLVED SOLIDS 500,000 VANADIUM 0.3** ZINC*** 1000 I C ** Interim Maximum Allowable Concentration (IMAC) *** Unit reported in mg/L in standard, converted here to pug/L to match units displayed on figure. All units shown in pug/L except pH which is standard units. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION 3.0 = LESS THAN LABORATORY REPORTING LIMIT I— J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOW *DNE = DOES NOT EXCEED LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION A -A' GROUNDWATER ANALYTICAL RESULTS 0 1" 2° FILENAME SCALE AS NOTED /W SHEET FIGURE 10- .2 1 2 1 3 5 n. 7 : w r r B WEST 800 700 — a� Cf)� M I I 3i0 CD r,-- GWA-3S 650 .•• 550 500 1- 0 GWA-3D knalyte (Ng/L) Cobalt 1.1 Manganese 9200 Sulfate 1310000 Total Dissolved Solids 2390000 Vanadium 4.6 GWA- 3SA Ana lyte / L Coba1t 18.4 Iro n 420 Manganese 12700 Sulfate 1420000 Total Dissolved Solids 23000000 Vanadium 1.3 200 400 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 C-1BRU C-1S i C-2D C-is Analyte WglL) Arsenic Cobalt Iron 25.8 102 175000 Manganese 3200 Sulfate 559000 Total Dissolved Solids 1110000 F, Vanadium 4 C-2D Analyte (Ng/L) Vanadiuml 10.9 ISSUE DATE DESCRIPTION C-2S C-2S Analyte [pg/I Cobalt Manganese Vanadium 39.7 600 0.523 AB-8D Ana to / L flan anew 140 Vanadium2.7 1200 1400 DISTANCE (ft) SECTION B SCALE: HORIZ 1 "=100' IFIG 11-1 VERT 1 "=25' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 1600 NOT FOR CONSTRUCTION PRIMARY DAM AB-8S Analyte (Ng/L) Manganese Vanadium 15Q 0.793 AB-5SL Analyte / L Antiniony ti.2 Arsenic 5.1 Boron 2400 Vanadium 151 AB -SD Ana lyte / L Antimony 1.2 Vanadium 12.5 2000 2200 .. , Milo o 10, iI DUKE ENERGY CAROLINAS,LLC /� DUKE AENERGY.. GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA EAST 800 700 AB -SS Analyte / L Antimony 21.6 f Arsenio 651 Boron 1400 iron 660 Thallium 0.48 Vanadium 2-31 �E 1 50 NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) ANALYTE NC 2L GROUNDWATER IMAC ANTIMONY 1** ARSENIC 10 BARIUM 700 BERYLLIUM 4** BORON 700 CADMIUM 2 CHLORIDE*** 250,000 1 CHROMIUM 10 COBALT 1** COPPER*** 1,000 IRON 300 I LEAD 15 (MANGANESE 50 MERCURY 1 NICKEL 100 NITRATE*** 10,000 1 NITRATE AS N*** 1.000 pH (field) 6.5 - 8.5 SELENIUM 20 SULFATE*** 250,000 THALLIUM 0.2 TOTAL DISSOLVED SOLIDS 500,000 VANADIUM 0.3** ZINC*** 1000 6 ** Interim Maximum Allowable Concentration (IMAC) *** Unit reported in mg/L in standard, converted here to pug/L to match units displayed on figure. All units shown in pug/L except pH which is standard units. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION No 3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH O J- = ESTIMATED CONCENTRATION BIASED LOW W *DNE = DOES NOT EXCEED U LLL 550 Z J U Q 500 2400 2600 LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH - ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION B-B' GROUNDWATER ANALYTICAL RESULTS 0 1" 2° FILENAME SCALE AS NOTED C C SHEET FIGURE 10- .1 1 2 3 5 A 7 : WEST 800 700 6 O z •- 0 Q Lv J W LLL 600 LL.I Z J U �Q 550 500 B' EAST AB -IS Ana to f L INTERMEDIATE DAM Antimony 3.2 Cobalt 15.9 AB-4D WATER SECONDARY DAM AB-1 D Iron 510 - AB-4S IN BASIN AB-1S Manganese 250 Vanadium 1.8 i MW-13 R- - _ _ CATAWBA RIVER Arsenic MOUNTAIN ISLAND LAKE AB-1 [ Ana e f L Antimony 6.3 Chromium 49.2 Cobalt 2.9 ==J Mom iron 370 Vanadium 20 AB-4D Ana to j L Antimony1.2 Vanadium 24 Antimony 2.2 42$ Cobalt 5.7 Manganese 1,240 Vanadium 166 AB-45 Analyte CN91�] h7W-13 Ana e L) 2600 2800 3000 3200 3400 3600 3800 4000 4200 4400 4600 4800 DISTANCE (ft) HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION SECTION rB SCALE: HORIZ 1 "=40' FIG 11-1 VERT 1"=10' PROJECT MANAGER DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 NOT FOR CONSTRUCTION DUKE ENERGY CAROLINASILIC /� DUKE ENERGY.: GASTON COUNTY RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA 700 650 550 500 NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) C ANALYTE NOT FOR CONSTRUCTION DUKE ENERGY CAROLINASILIC /� DUKE ENERGY.: GASTON COUNTY RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA 700 650 550 500 NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) C ANALYTE NC 2L GROUNDWATER IMAC ANTIMONY 1** � ARSENIC 10 � � BARIUM 700 � BERYLLIUM 4** � BORON 700 � � CADMIUM 2 � � CHLORIDE*** 250,000 � CHOBOMIUM 10 ** � COPPER*** 1,000 � � IRON 300 � I LEAD 15 � (MANGANESE 50 � I MERCURY 1 � � NICKEL 100 � � NITRATE*** 10,000 � � NITRATE AS N*** 1.000 � pH (field) 6.5 - 8.5 � SELENIUM 20 � � SULFATE*** 250,000 � � THALLIUM 0.2 � � TOTAL DISSOLVED SOLIDS 500,000 � VANADIUM 0.3** ZINC*** 1000 I C ** Interim Maximum Allowable Concentration (IMAC) *** Unit reported in mg/L in standard, converted here to pug/L to match units displayed on figure. All units shown in pug/L except pH which is standard units. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION 3.0 = LESS THAN LABORATORY REPORTING LIMIT l--- J+ = ESTIMATED CONCENTRATION BIASED HIGH J- = ESTIMATED CONCENTRATION BIASED LOWLV *DNE = DOES NOT EXCEED LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH -ASH F - FILL S - ALLUVIUM M1 - SOIL/SAPROLITE; N < 50 M2 - SAPROLITE/WEATHERED ROCK; N >- 50% OR REC S 50% TZ - PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR - SOUND ROCK;REC >- 85% AND RQD >- 50% CROSS SECTION B-B' GROUNDWATER ANALYTICAL RESULTS 0 1" 2- FILENAME SCALE AS NOTED SHEET FIGURE 10- .2 HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 1 000000000246403 NOT FOR CONSTRUCTION DUKE ENERGY CAROLINAS,LLC DUKE ENERGY.: GASTON COUNTY RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA CROSS SECTION C-Cl GROUNDWATER ANALYTICAL RESULTS 0 1" 2° FILENAME SCALE I AS NOTED SHEET FIGURE 10- HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECTNUMBER 000000000246403 DUKE ENERGY CAROLINAS,LLC RIVERBEND STEAM STATION NOT FDUKE OR �� COMPREHENSIVE SITE ENERGY, CONSTRUCTION ASSESSMENT NORTH CAROLINA C c 0 0 CROSS SECTION D-D' GROUNDWATER ANALYTICAL RESULTS V. 2-- FILENAME SHEET SCALE AS NOTED FIGURE 10- 1 2 3 5 1.1 7 : E NORTH 800 70 650 I, a w J LIJ MW-9D M 500 400 MW-9D Ana lyte / L Say rn pie 1 Sample 2 Antimony 5.4 2.7 Chromium 20.6 27 Vanadium 12.5 12.8 MW-9BR Ana a /L Antimonyl 2.3 Vanadium 7.8 AS- 2D Ana lyte / L Chromium 22.5 Vanadium 34.6 AS-2S Anallyte (N9/L) Chromium 44.8 Cobalt 12.4 Iran 2090 Manganese 640 Vanadium 3.9 GWA-23D Ana to 1 L Chromium 55 Vanadium 34.1 E' SOUTH 800 GWA--23BR I 1 q I GWA-23S 1' ' ' 400 0 200 400 600 800 1000 1200 1400 1600 DISTANCE (ft) HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 704.338.6700 ISSUE DATE DESCRIPTION SECTION E SCALE: HORIZ 1 "=80' IFIG 11-1 VERT 1 "=40' PROJECT MANAGER S. SPINNER, P.G. DRAWN BY: - DESIGNED BY: - CHECKED BY: - APPROVED BY: - PROJECT NUMBER 000000000246403 NOT FOR CONSTRUCTION DUKE ENERGY CAROLINASILIC /� DUKE ENERGY.: GASTON COUNTN RIVERBEND STEAM STATION COMPREHENSIVE SITE ASSESSMENT NORTH CAROLINA NOTE: 1. CONCENTRATIONS OF CONSTITUENTS OF INTEREST IN GROUNDWATER REPORTED IN UNITS OF MICROGRAMS PER LITER (ug/L) ANALYTE NC 2L GROUNDWATER IMAC ANTIMONY 1** ARSENIC 10 BARIUM 700 BERYLLIUM 4** BORON 700 CADMIUM 2 CHLORIDE*** 250,000 CHROMIUM 10 COBALT 1** COPPER*** 1,000 IRON 300 I LEAD 15 (MANGANESE 50 MERCURY 1 NICKEL 100 NITRATE*** 10,000 NITRATE AS N*** 1.000 pH (field) 6.5 — 8.5 SELENIUM 20 SULFATE*** 250,000 THALLIUM 0.2 TOTAL DISSOLVED SOLIDS 500,000 VANADIUM 0.3** ZINC*** 1000 ** Interim Maximum Allowable Concentration (IMAC) *** Unit reported in mg/L in standard, converted here to lug/L to match units displayed on figure. All units shown in pug/L except pH which is standard units. NOTES: U = NOT DETECTED ABOVE LABORATORY REPORTING LIMIT J = ESTIMATED CONCENTRATION 3.0 = LESS THAN LABORATORY REPORTING LIMIT J+ = ESTIMATED CONCENTRATION BIASED HIGH J— = ESTIMATED CONCENTRATION BIASED LOW *DNE = DOES NOT EXCEED LEGEND: WATER TABLE SURFACE (SUMMER 2015) ASH — ASH F — FILL S — ALLUVIUM M1 — SOIL/SAPROLITE; N < 50 M2 — SAPROLITE/WEATHERED ROCK; N >! 50% OR REC < 50% TZ — PARTIALLY WEATHERED ROCK; REC>50% AND RQD <50% BR — SOUND ROCK;REC >: 85% AND RQD >- 50% CROSS SECTION E-El GROUNDWATER ANALYTICAL RESULTS 0 1" 2° FILENAME SCALE AS NOTED SHEET FIGURE 10- C C LV /0 NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- MW - 5 S ( W G ) M W - 6 S ( W G ) M W - 8 D ( W G ) M W - 8 I ( W G ) M W - 8 S ( W G ) M W - 9 ( W G ) Al k a l i n i t y , C O 3 Al k a l i n i t y , H C O 3 60 0 0 2 1 3 0 0 3 2 8 0 0 2 1 8 0 0 1 1 0 0 4 2 4 0 0 Ca l c i u m 88 9 1 1 1 0 0 5 7 6 0 2 9 6 0 3 4 5 1 2 4 0 0 Ch l o r i d e 70 0 0 6 6 0 0 1 2 0 0 7000 2 2 0 0 Ma g n e s i u m 84 5 6 7 4 0 1 3 2 0 9 2 0 2 4 6 3 6 5 0 Ni t r o g e n , N O 2 p l u s N O 3 54 41 2 4 35 Po t a s s i u m So d i u m 10 7 0 0 7 3 1 0 1 0 0 0 0 7 5 8 0 10900 Su l f a t e 10 2 0 0 3 6 7 0 0 580 2 4 6 0 0 0 50 0 0 10 0 0 0 15 0 0 0 20 0 0 0 25 0 0 0 30 0 0 0 35 0 0 0 40 0 0 0 45 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N A S H B A S I N P O R E W A T E R S A M P L E S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 3 S ( P W ) A B - 4 S ( P W ) A B - 5 S ( P W ) A B - 5 S L ( P W ) A B - 7 S ( P W ) C - 1 S ( P W ) Al k a l i n i t y , C O 3 18 0 0 0 Al k a l i n i t y , H C O 3 25 4 0 0 0 6 9 6 0 0 2 0 1 0 0 0 4 0 0 0 0 2 4 1 0 0 1 1 0 0 0 Ca l c i u m 42 2 0 0 3 5 3 0 0 7 9 7 0 0 8 9 9 0 0 1 3 3 0 0 5 4 6 0 0 Ch l o r i d e 12 9 0 0 6 0 0 0 1 1 5 0 0 7 9 0 0 2 1 0 0 9 4 0 0 Ma g n e s i u m 63 8 0 6 2 3 0 1 6 9 0 0 6 7 7 4 2 5 0 2 3 5 0 0 Ni t r o g e n , N O 2 p l u s N O 3 60 19 Po t a s s i u m 51 4 0 2 0 5 0 0 1 4 1 0 0 2 0 8 0 0 4 5 4 0 2 3 6 0 0 So d i u m 14 4 0 0 0 1 9 5 0 0 1 1 4 0 0 9 5 6 0 9 0 4 0 2 1 9 0 0 Su l f a t e 99 3 0 0 8 8 9 0 0 9 9 6 0 0 2 0 8 0 0 0 6 4 8 0 0 5 5 9 0 0 0 0 10 0 0 0 0 20 0 0 0 0 30 0 0 0 0 40 0 0 0 0 50 0 0 0 0 60 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S U R F A C E W A T E R A N D A S H B A S I N W A T E R DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 D (W G ) AB - 1 S ( W G ) AB - 2 D (W G ) AB - 2 S ( W G ) AB - 3 B R (W G ) AB - 3 D (W G ) AB - 4 D (W G ) AB - 5 D (W G ) AB - 6 B R U (W G ) AB - 6 S ( W G ) AB - 7 D (W G ) AB - 7 I ( W G ) AB-8D (WG)AB-8S (WG) S - 1 3 ( W S ) S W - 1 (WS) S W - 2 ( W S ) S W - 3 ( W S ) Al k a l i n i t y , C O 3 21 1 0 0 0 3 6 4 0 0 8 6 1 0 0 3 0 9 0 0 0 2 7 2 0 0 5 7 8 0 0 2 7 0 0 0 2 4 5 0 0 0 1 1 0 0 0 0 Al k a l i n i t y , H C O 3 72 0 0 0 1 9 0 0 1 0 7 0 0 0 1 6 0 0 1 9 9 0 0 5 3 9 0 0 9 2 4 0 0 6 9 8 0 0 9 8 0 0 7 7 3 0 0 2 8 5 0 0 3 9 6 0 0 1 2 0 0 0 1 2 0 0 0 1 0 6 0 0 0 Ca l c i u m 12 3 0 0 0 1 1 7 0 6 4 0 0 0 1 1 3 0 3 1 3 0 0 2 8 3 0 0 0 3 2 9 0 0 4 2 6 0 0 9 2 8 0 0 9 4 4 0 0 7 0 1 0 0 2 0 3 0 6 1 3 0 0 3 7 7 0 0 8 5 4 0 1 8 9 0 0 1 6 3 0 0 5 7 0 0 0 Ch l o r i d e 49 0 0 5 3 0 0 6 4 0 0 3 3 0 0 2 2 0 0 6 4 0 0 2 5 0 0 4 7 0 0 5 4 0 0 8 8 0 0 7 2 0 0 1 8 0 0 5 8 0 0 5 3 0 0 1 2 0 0 5 4 0 0 5 4 0 0 5 5 0 0 Ma g n e s i u m 52 4 9 7 4 2 7 0 6 1 0 1 9 3 0 1 4 1 5 7 1 1 9 5 0 9 3 7 0 5 7 . 9 7 2 6 1 2 7 0 0 1 1 7 0 0 2 5 8 0 3 7 2 0 3 3 5 0 1 4 4 0 0 Ni t r o g e n , N O 2 p l u s N O 3 23 0 7 2 0 8 3 9 4 0 4 8 7 3 5 3 0 2 0 0 1 2 0 1 6 1 3 0 5 1 2 0 0 7 9 2 9 0 Po t a s s i u m 69 2 0 4 0 4 0 1 8 8 0 0 8 0 2 0 0 8 4 2 0 1 7 0 0 0 4 3 4 0 0 1 0 2 0 0 8 1 5 0 3 7 1 0 5 4 4 0 4 9 4 0 9 3 1 0 So d i u m 78 3 0 2 9 6 0 1 1 8 0 0 1 9 8 0 0 5 0 3 0 0 9 9 5 0 1 8 2 0 0 1 8 3 0 0 8 8 2 0 2 9 5 0 0 5 0 5 0 1 4 0 0 0 1 4 8 0 0 6 9 6 0 4 5 9 0 4 7 8 0 1 0 8 0 0 Su l f a t e 22 8 0 0 6 9 0 2 2 7 0 0 1 7 0 0 0 1 4 4 0 0 0 1 3 1 0 0 5 6 3 0 0 8 7 0 0 0 1 5 7 0 0 4 6 5 0 0 6 3 0 0 1 3 6 0 0 0 1 3 2 0 0 0 5 4 1 0 0 5 5 2 0 0 1 1 9 0 0 0 0 50 0 0 0 10 0 0 0 0 15 0 0 0 0 20 0 0 0 0 25 0 0 0 0 30 0 0 0 0 35 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N B A C K G R O U N D W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- BG - 1 D ( W G ) B G - 1 S ( W G ) B G - 2 B R ( W G ) B G - 2 D ( W G ) B G - 2 S ( W G ) B G - 3 D ( W G ) B G - 3 S ( W G ) Al k a l i n i t y , C O 3 40 1 0 0 0 91 3 0 0 Al k a l i n i t y , H C O 3 10 2 0 0 7 5 4 0 0 5 9 0 0 0 2 2 1 0 0 4 3 2 0 0 2 8 9 0 0 Ca l c i u m 83 3 0 0 1 4 6 0 2 4 2 0 0 5 7 6 0 0 1 1 0 0 0 9 4 3 0 6 1 4 0 Ch l o r i d e 61 0 0 1 9 0 0 2 2 0 0 1 0 0 0 0 8 9 0 0 2 8 0 0 4 6 0 0 Ma g n e s i u m 11 2 1 3 3 0 3 1 0 0 8 4 . 4 2 2 1 0 2 2 7 0 7 7 5 Ni t r o g e n , N O 2 p l u s N O 3 30 4 0 5 0 0 1 0 0 0 3 9 0 0 1 6 0 0 Po t a s s i u m 13 0 0 0 0 48 8 0 So d i u m 75 6 0 0 7 6 7 0 2 9 2 0 0 7 1 8 0 1 6 4 0 0 7 2 6 0 Su l f a t e 48 4 0 0 5 8 0 8 2 0 0 3 1 1 0 0 2 9 0 0 1 1 0 0 2 4 0 0 0 50 0 0 0 10 0 0 0 0 15 0 0 0 0 20 0 0 0 0 25 0 0 0 0 30 0 0 0 0 35 0 0 0 0 40 0 0 0 0 45 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S E E P S A M P L E S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- RB S W 0 0 1 ( S e e p ) R B S W 0 0 2 ( S e e p ) S - 1 1 ( S e e p ) S - 2 ( S e e p ) S - 4 ( S e e p ) S - 5 ( S e e p ) S - 6 ( S e e p ) S - 7 ( S e e p ) S - 8 ( S e e p ) S - 9 ( S e e p ) Al k a l i n i t y , C O 3 Al k a l i n i t y , H C O 3 25 0 0 2 4 6 0 0 1 3 4 0 0 5 9 2 0 0 2 5 5 0 0 1 0 7 0 0 3 0 2 0 0 2 2 4 0 0 4 3 1 0 0 2 3 2 0 0 Ca l c i u m 35 3 0 1 2 7 0 0 4 0 5 0 4 3 0 0 0 7 9 9 0 6 1 4 0 4 7 3 0 3 4 2 0 8 5 2 0 7 4 1 0 Ch l o r i d e 41 0 0 6 8 0 0 6 8 0 0 6 5 0 0 7 3 0 0 6 6 0 0 6 1 0 0 1 3 0 0 6 5 0 0 Ma g n e s i u m 32 4 2 7 2 0 2 7 1 0 7 9 3 0 6 8 0 0 7 4 0 0 7 5 9 0 5 9 8 0 2 7 3 0 6 4 6 0 Ni t r o g e n , N O 2 p l u s N O 3 12 0 0 9 9 0 4 5 3 1 0 9 6 2 9 4 5 1 2 1 5 0 0 1 1 0 Po t a s s i u m 28 1 0 5 1 8 0 So d i u m 54 8 0 7 7 8 0 5 8 5 0 6 8 4 0 7 4 4 0 7 1 6 0 6 8 3 0 7 1 4 0 Su l f a t e 47 0 0 1 8 4 0 0 1 6 5 0 0 8 9 3 0 0 2 5 4 0 0 3 5 1 0 0 2 4 5 0 0 1 4 0 0 2 5 6 0 0 0 10 0 0 0 20 0 0 0 30 0 0 0 40 0 0 0 50 0 0 0 60 0 0 0 70 0 0 0 80 0 0 0 90 0 0 0 10 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N B E D R O C K W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 3 B R ( W G ) A B - 6 B R U ( W G ) B G - 2 B R ( W G ) GW A - 2 0 B R (W G ) GW A - 2 2 B R (W G ) GW A - 2 3 B R (W G ) GW A - 2 B R (W G ) GW A - 2 B R U (W G ) GW A - 4 B R (W G ) GW A - 7 B R (W G ) GWA-9BR (WG)MW-15BR (WG)MW-7BR (WG) M W - 9 B R ( W G ) Al k a l i n i t y , C O 3 86 1 0 0 2 7 0 0 0 6 0 2 0 0 0 1 4 2 0 0 0 2 1 7 0 0 0 1 1 5 0 0 0 0 5 6 0 0 0 0 1 4 9 0 0 1 0 5 0 0 0 6 5 7 0 0 0 5 5 2 0 0 Al k a l i n i t y , H C O 3 19 9 0 0 9 2 4 0 0 7 5 4 0 0 6 4 1 0 0 4 5 4 0 0 6 5 2 0 0 Ca l c i u m 31 3 0 0 9 2 8 0 0 2 4 2 0 0 9 7 6 0 0 3 0 3 0 0 0 3 0 7 0 0 0 2 7 4 0 0 3 4 3 0 0 0 5 4 5 0 0 0 3 3 6 0 0 1 7 5 0 0 8 1 6 0 5 3 7 0 0 0 5 6 2 0 0 Ch l o r i d e 22 0 0 5 4 0 0 2 2 0 0 1 9 0 0 7 4 0 0 2 0 0 0 5 2 0 0 1 3 1 0 0 4 8 0 0 3 0 0 0 7 5 0 0 4 9 0 0 6 3 0 0 Ma g n e s i u m 19 3 0 9 3 7 0 3 1 0 0 9 0 4 5 3 2 5 7 4 3 5 0 1 9 6 1 7 6 2 4 0 1 2 7 1 0 8 0 3 2 3 0 Ni t r o g e n , N O 2 p l u s N O 3 48 1 2 0 5 0 0 1 2 8 7 7 5 1 6 0 9 1 7 7 1 9 2 5 0 Po t a s s i u m 18 8 0 0 4 3 4 0 0 5 2 4 0 0 9 3 6 0 2 7 7 0 0 8 9 3 0 2 5 3 0 0 0 1 0 6 0 0 0 4 8 4 0 1 6 2 0 0 0 5 1 3 0 0 1 7 8 0 0 3 9 1 0 So d i u m 19 8 0 0 1 8 3 0 0 7 6 7 0 3 1 4 0 0 2 7 4 0 0 2 3 3 0 0 9 3 6 0 1 6 2 0 0 0 5 2 5 0 0 6 9 4 0 1 3 3 0 0 0 5 0 1 0 0 2 5 3 0 0 1 1 6 0 0 Su l f a t e 17 0 0 0 8 7 0 0 0 8 2 0 0 5 8 0 0 2 1 0 0 0 1 8 0 0 0 3 9 5 0 0 3 0 0 0 6 9 0 0 2 1 5 0 0 3 9 5 0 0 7 2 0 0 1 8 0 0 0 0 20 0 0 0 0 40 0 0 0 0 60 0 0 0 0 80 0 0 0 0 10 0 0 0 0 0 12 0 0 0 0 0 14 0 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 D ( W G ) A B - 2 D ( W G ) A B - 3 D ( W G ) A B - 4 D ( W G ) A B - 5 D ( W G ) A B - 7 D ( W G ) A B - 8 D ( W G ) A S - 1 D ( W G ) A S - 2 D ( W G ) A S - 3 D ( W G ) Al k a l i n i t y , C O 3 21 1 0 0 0 3 6 4 0 0 3 0 9 0 0 0 2 7 2 0 0 5 7 8 0 0 1 1 0 0 0 0 8 7 0 0 0 3 7 0 0 0 Al k a l i n i t y , H C O 3 72 0 0 0 1 0 7 0 0 0 5 3 9 0 0 6 9 8 0 0 7 7 3 0 0 1 8 0 0 0 Ca l c i u m 12 3 0 0 0 6 4 0 0 0 2 8 3 0 0 0 3 2 9 0 0 4 2 6 0 0 7 0 1 0 0 6 1 3 0 0 1 1 1 0 0 0 6 9 9 0 0 2 0 4 0 0 Ch l o r i d e 49 0 0 6 4 0 0 6 4 0 0 2 5 0 0 4 7 0 0 7 2 0 0 5 8 0 0 5 7 0 0 4 1 0 0 3 1 0 0 Ma g n e s i u m 52 4 2 7 0 1 4 1 5 7 1 1 9 5 0 1 2 7 0 0 2 5 8 7 4 0 Ni t r o g e n , N O 2 p l u s N O 3 23 0 8 3 7 3 5 3 0 2 0 0 1 3 0 9 4 Po t a s s i u m 69 2 0 4 0 4 0 8 0 2 0 0 8 4 2 0 1 7 0 0 0 8 1 5 0 3 7 1 0 1 4 2 0 0 6 6 9 0 3 7 6 0 So d i u m 78 3 0 1 1 8 0 0 5 0 3 0 0 9 9 5 0 1 8 2 0 0 2 9 5 0 0 1 4 0 0 0 3 0 5 0 0 2 5 0 0 0 1 2 4 0 0 Su l f a t e 22 8 0 0 2 2 7 0 0 1 4 4 0 0 0 1 3 1 0 0 5 6 3 0 0 4 6 5 0 0 1 3 6 0 0 0 2 1 3 0 0 2 6 0 0 0 1 8 0 0 0 0 50 0 0 0 10 0 0 0 0 15 0 0 0 0 20 0 0 0 0 25 0 0 0 0 30 0 0 0 0 35 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- BG - 1 D ( W G ) B G - 2 D ( W G ) B G - 3 D ( W G ) C - 2 D ( W G ) G W A - 1 0 D ( W G ) G W A - 1 D ( W G ) G W A - 2 0 D ( W G ) G W A - 2 2 D ( W G ) G W A - 2 3 D ( W G ) G W A - 3 D ( W G ) Al k a l i n i t y , C O 3 40 1 0 0 0 9 1 3 0 0 3 6 0 0 3 6 6 0 0 3 5 0 0 0 1 3 7 0 0 0 0 9 2 5 0 0 9 8 2 0 0 Al k a l i n i t y , H C O 3 59 0 0 0 4 3 2 0 0 9 8 7 0 0 9 6 1 0 0 1 4 8 0 0 0 4 8 2 0 0 4 4 4 0 0 7 2 9 0 0 Ca l c i u m 83 3 0 0 5 7 6 0 0 9 4 3 0 2 3 8 0 0 2 5 6 0 0 4 7 4 0 0 7 5 8 0 0 0 4 4 4 0 0 4 6 4 0 0 4 3 7 0 0 0 Ch l o r i d e 61 0 0 1 0 0 0 0 2 8 0 0 2 2 0 0 6 4 0 0 3 2 0 0 9 8 0 0 5 7 0 0 2 6 0 0 6 5 0 0 Ma g n e s i u m 11 2 8 4 . 4 2 2 7 0 3 1 5 0 5 8 1 0 6 0 6 1 2 4 0 5 0 . 3 1 1 3 0 0 0 Ni t r o g e n , N O 2 p l u s N O 3 30 1 0 0 0 1 6 0 0 2 5 1 8 1 9 0 5 9 5 5 4 6 Po t a s s i u m 13 0 0 0 0 4 8 8 0 6 4 4 0 0 1 6 6 0 0 1 8 8 0 0 0 3 4 6 0 0 1 1 4 0 0 So d i u m 75 6 0 0 2 9 2 0 0 1 6 4 0 0 1 1 9 0 0 2 8 3 0 0 1 5 3 0 0 7 3 9 0 0 2 9 4 0 0 1 3 8 0 0 4 8 0 0 0 Su l f a t e 48 4 0 0 3 1 1 0 0 1 1 0 0 1 9 0 0 2 5 9 0 0 8 7 0 0 3 7 6 0 0 0 2 3 5 0 0 1 0 6 0 0 1 3 1 0 0 0 0 0 20 0 0 0 0 40 0 0 0 0 60 0 0 0 0 80 0 0 0 0 10 0 0 0 0 0 12 0 0 0 0 0 14 0 0 0 0 0 16 0 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 4 D ( W G ) G W A - 5 D ( W G ) G W A - 6 D ( W G ) G W A - 7 D ( W G ) G W A - 8 D ( W G ) G W A - 9 D ( W G ) M W - 1 1 D R ( W G ) M W - 1 5 D ( W G ) M W - 1 D ( W G ) M W - 2 D ( W G ) Al k a l i n i t y , C O 3 59 6 0 0 4 7 9 0 0 113000 Al k a l i n i t y , H C O 3 50 7 0 0 1 6 9 0 0 8 1 0 0 0 4 5 4 0 0 3 0 6 0 0 1 6 1 0 0 1 8 9 0 0 4 0 7 0 0 Ca l c i u m 12 3 0 0 2 8 0 0 0 4 7 8 0 0 2 4 5 0 0 1 4 6 0 0 1 4 1 0 0 9 1 5 0 5 2 7 0 0 2 5 3 0 0 6 9 5 0 Ch l o r i d e 32 0 0 2 1 0 0 2 4 0 0 4 4 0 0 6 3 0 0 6 7 0 0 5 9 0 0 6 2 0 0 7 9 0 0 4 6 0 0 Ma g n e s i u m 29 5 0 4 5 3 1 8 5 5 4 8 0 9 7 2 0 6 3 9 0 6 3 5 0 8 9 9 8 2 5 0 4 1 2 0 Ni t r o g e n , N O 2 p l u s N O 3 11 0 2 1 8 4 1 2 1 3 3 2 0 8 2 Po t a s s i u m 32 0 0 8700 So d i u m 98 0 0 9 3 6 0 9 8 7 0 2 0 2 0 0 4 8 0 0 8 2 5 0 6 7 7 0 1 8 3 0 0 9 7 3 0 5 9 3 0 Su l f a t e 44 0 0 5 0 0 0 1 5 5 0 0 3 2 3 0 0 2 3 8 0 0 3 3 2 0 0 3 6 0 0 0 4 0 1 0 0 8 6 1 0 0 7 2 0 0 20 0 0 0 40 0 0 0 60 0 0 0 80 0 0 0 10 0 0 0 0 12 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- MW - 3 D ( W G ) M W - 4 D ( W G ) M W - 5 D ( W G ) M W - 6 D ( W G ) M W - 8 D ( W G ) M W - 9 D ( W G ) Al k a l i n i t y , C O 3 75600 Al k a l i n i t y , H C O 3 53 2 0 0 1 7 0 0 0 7 3 8 0 0 3 1 0 0 0 3 2 8 0 0 2 4 0 0 0 0 Ca l c i u m 17 1 0 0 1 0 9 0 0 2 4 3 0 0 1 4 0 0 0 5 7 6 0 7 2 6 0 0 Ch l o r i d e 66 0 0 5 4 0 0 6 5 0 0 6 6 0 0 1 2 0 0 2 7 0 0 Ma g n e s i u m 87 5 0 3 8 5 0 1 2 9 0 0 6 9 5 0 1 3 2 0 9 5 5 Ni t r o g e n , N O 2 p l u s N O 3 32 1 8 1 4 0 41 4 6 0 Po t a s s i u m 4350 So d i u m 40 4 0 7 7 5 0 8 1 7 0 6 6 7 0 1 0 0 0 0 1 6 8 0 0 Su l f a t e 26 7 0 0 3 0 9 0 0 4 4 6 0 0 3 4 6 0 0 27600 0 50 0 0 0 10 0 0 0 0 15 0 0 0 0 20 0 0 0 0 25 0 0 0 0 30 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 S ( W G ) A B - 2 S ( W G ) A B - 6 S ( W G ) A B - 8 S ( W G ) A S - 1 S ( W G ) A S - 2 S ( W G ) B G - 1 S ( W G ) B G - 2 S ( W G ) B G - 3 S ( W G ) C - 2 S ( W G ) Al k a l i n i t y , C O 3 24 5 0 0 0 Al k a l i n i t y , H C O 3 19 0 0 1 6 0 0 2 8 5 0 0 3 5 0 0 0 0 4 2 0 0 0 1 0 2 0 0 2 2 1 0 0 2 8 9 0 0 Ca l c i u m 11 7 0 1 1 3 0 9 4 4 0 0 3 7 7 0 0 1 6 7 0 0 0 4 8 7 0 1 4 6 0 1 1 0 0 0 6 1 4 0 1 1 8 0 0 Ch l o r i d e 53 0 0 3 3 0 0 8 8 0 0 5 3 0 0 1 8 3 0 0 2 6 0 0 1 9 0 0 8 9 0 0 4 6 0 0 3 2 0 0 Ma g n e s i u m 97 4 6 1 0 5 7 . 9 1 1 7 0 0 3 4 0 0 0 1 3 1 0 1 3 3 0 2 2 1 0 7 7 5 4 6 4 0 Ni t r o g e n , N O 2 p l u s N O 3 72 0 9 4 0 1 6 2 0 0 3 2 0 4 0 3 9 0 0 3 6 0 0 Po t a s s i u m 10 2 0 0 9 5 5 0 4 7 0 0 8380 So d i u m 29 6 0 8 8 2 0 1 4 8 0 0 1 2 9 0 0 8 2 8 0 7 1 8 0 7 2 6 0 4 0 4 0 Su l f a t e 69 0 1 5 7 0 0 1 3 2 0 0 0 2 3 1 0 0 0 5 2 0 0 5 8 0 2 9 0 0 2 4 0 0 6 0 4 0 0 0 50 0 0 0 10 0 0 0 0 15 0 0 0 0 20 0 0 0 0 25 0 0 0 0 30 0 0 0 0 35 0 0 0 0 40 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 1 0 S ( W G ) G W A - 1 S ( W G ) G W A - 2 0 S ( W G ) G W A - 2 2 S ( W G ) G W A - 2 3 S ( W G ) G W A - 2 S ( W G ) G W A - 3 S A ( W G ) G W A - 4 S ( W G ) G W A - 5 S ( W G ) G W A - 6 S ( W G ) Al k a l i n i t y , C O 3 Al k a l i n i t y , H C O 3 43 0 0 2 5 0 0 0 7 8 0 0 2 9 0 0 8 4 0 0 3 2 0 0 0 3 6 3 0 0 1 7 6 0 0 2 7 0 0 9 8 0 0 Ca l c i u m 50 4 0 4 1 6 0 2 7 8 0 6 9 6 8 5 8 1 3 2 0 0 3 6 7 0 0 0 2 5 2 0 0 9 1 5 1 3 9 0 Ch l o r i d e 57 0 0 5 2 0 0 8 1 0 0 2 8 0 0 2 3 0 0 5 8 0 0 6 1 0 0 2 9 0 0 9 8 0 2 9 0 0 Ma g n e s i u m 58 4 0 3 3 9 0 1 1 6 0 4 3 1 4 3 5 7 3 6 0 1 3 4 0 0 0 8 0 4 0 2 7 8 7 9 5 Ni t r o g e n , N O 2 p l u s N O 3 12 0 1 4 4 8 0 3 2 0 2 6 2 3 Po t a s s i u m 10 6 0 0 So d i u m 46 2 0 6 7 4 0 4 4 3 0 2 5 1 0 6 4 9 0 4 4 0 0 0 6 6 6 0 2 9 6 0 Su l f a t e 31 0 0 0 9 8 0 3 6 1 0 0 1 4 2 0 0 0 0 8 4 7 0 0 1 2 0 0 0 20 0 0 0 0 40 0 0 0 0 60 0 0 0 0 80 0 0 0 0 10 0 0 0 0 0 12 0 0 0 0 0 14 0 0 0 0 0 16 0 0 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 7 S ( W G ) G W A - 8 S ( W G ) G W A - 9 S ( W G ) M W - 1 0 ( W G ) M W - 1 1 S R ( W G ) M W - 1 3 ( W G ) M W - 1 4 ( W G ) M W - 1 5 ( W G ) M W - 1 S ( W G ) M W - 3 S ( W G ) Al k a l i n i t y , C O 3 Al k a l i n i t y , H C O 3 32 7 0 0 1 2 0 0 5 9 0 0 1 4 6 0 0 5 7 9 0 0 4 5 8 0 0 3 1 0 0 2 8 2 0 0 4 3 4 0 0 Ca l c i u m 65 4 0 2 0 7 0 2 1 7 0 4 2 9 0 9 2 9 0 9 3 4 0 6 7 9 0 3 9 3 0 2 0 1 0 1 3 8 0 0 Ch l o r i d e 26 0 0 6 2 0 0 6 8 0 0 6 4 0 0 6 0 0 0 4 2 0 0 1 3 5 0 0 6 0 0 0 1 0 7 0 0 7 1 0 0 Ma g n e s i u m 43 6 0 6 3 9 0 2 7 6 0 2 9 4 0 5 9 9 0 4 6 7 0 1 6 5 0 0 3 1 1 0 9 8 6 8 8 5 0 Ni t r o g e n , N O 2 p l u s N O 3 60 0 1 4 0 4 7 2 5 0 7 1 4 9 1 2 Po t a s s i u m 40 8 0 So d i u m 65 1 0 5 9 7 0 6 2 2 0 7 5 0 0 3 1 2 0 2 5 5 0 9 2 4 0 6 0 9 0 4 1 6 0 Su l f a t e 53 0 3 6 0 0 0 2 6 5 0 0 1 9 5 0 0 3 7 6 0 0 1 5 7 0 0 3 0 1 0 0 2 9 0 0 0 1 2 0 0 2 9 9 0 0 0 10 0 0 0 20 0 0 0 30 0 0 0 40 0 0 0 50 0 0 0 60 0 0 0 70 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE CA T I O N / A N I O N C O N C E N T R A T I O N S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- MW - 5 S ( W G ) M W - 6 S ( W G ) M W - 8 D ( W G ) M W - 8 I ( W G ) M W - 8 S ( W G ) M W - 9 ( W G ) Al k a l i n i t y , C O 3 Al k a l i n i t y , H C O 3 60 0 0 2 1 3 0 0 3 2 8 0 0 2 1 8 0 0 1 1 0 0 4 2 4 0 0 Ca l c i u m 88 9 1 1 1 0 0 5 7 6 0 2 9 6 0 3 4 5 1 2 4 0 0 Ch l o r i d e 70 0 0 6 6 0 0 1 2 0 0 7000 2 2 0 0 Ma g n e s i u m 84 5 6 7 4 0 1 3 2 0 9 2 0 2 4 6 3 6 5 0 Ni t r o g e n , N O 2 p l u s N O 3 54 41 2 4 35 Po t a s s i u m So d i u m 10 7 0 0 7 3 1 0 1 0 0 0 0 7 5 8 0 10900 Su l f a t e 10 2 0 0 3 6 7 0 0 580 2 4 6 0 0 0 50 0 0 10 0 0 0 15 0 0 0 20 0 0 0 25 0 0 0 30 0 0 0 35 0 0 0 40 0 0 0 45 0 0 0 C o n c e n t r a t i o n ( µ g / L ) NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 S ( W G ) A B - 2 S ( W G ) A B - 6 S ( W G ) A B - 8 S ( W G ) A S - 1 S ( W G ) A S - 2 S ( W G ) B G - 1 S ( W G ) B G - 2 S ( W G ) B G - 3 S ( W G ) C - 2 S ( W G ) G W A - 1 0 S ( W G ) Su l f a t e : C h l o r i d e 0. 1 3 0 0 . 0 0 0 1 . 7 8 4 2 4 . 9 0 6 1 2 . 6 2 3 2 . 0 0 0 0 . 3 0 5 0 . 3 2 6 0 . 5 2 2 1 8 . 8 7 5 5 . 4 3 9 0. 0 0 0 5. 0 0 0 10 . 0 0 0 15 . 0 0 0 20 . 0 0 0 25 . 0 0 0 30 . 0 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 1 S ( W G ) G W A - 2 0 S ( W G ) G W A - 2 2 S ( W G ) G W A - 2 3 S ( W G ) G W A - 2 S ( W G ) G W A - 3 S A ( W G ) G W A - 4 S ( W G ) G W A - 5 S ( W G ) G W A - 6 S ( W G ) G W A - 7 S ( W G ) G W A - 8 S ( W G ) Su l f a t e : C h l o r i d e 0. 0 0 0 0 . 1 2 1 0 . 0 0 0 0 . 0 0 0 6 . 2 2 4 2 3 2 . 7 8 7 2 9 . 2 0 7 0 . 0 0 0 0 . 4 1 4 0 . 2 0 4 5 . 8 0 6 0. 0 0 0 50 . 0 0 0 10 0 . 0 0 0 15 0 . 0 0 0 20 0 . 0 0 0 25 0 . 0 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 9 S ( W G ) M W - 1 0 ( W G ) M W - 1 1 S R ( W G ) M W - 1 3 ( W G ) M W - 1 4 ( W G ) M W - 1 5 ( W G ) M W - 1 S ( W G ) M W - 3 S ( W G ) M W - 5 S ( W G ) M W - 6 S ( W G ) Su l f a t e : C h l o r i d e 3. 8 9 7 3 . 0 4 7 6 . 2 6 7 3 . 7 3 8 2 . 2 3 0 4 . 8 3 3 0 . 1 1 2 4 . 2 1 1 1 . 4 5 7 5 . 5 6 1 0. 0 0 0 1. 0 0 0 2. 0 0 0 3. 0 0 0 4. 0 0 0 5. 0 0 0 6. 0 0 0 7. 0 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S H A L L O W W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- MW - 8 D ( W G ) M W - 8 I ( W G ) M W - 8 S ( W G ) M W - 9 ( W G ) Su l f a t e : C h l o r i d e 0. 0 0 0 0 . 0 0 0 0 . 0 8 3 1 1 . 1 8 2 0. 0 0 0 2. 0 0 0 4. 0 0 0 6. 0 0 0 8. 0 0 0 10 . 0 0 0 12 . 0 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N B A C K G R O U N D W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- BG - 1 D ( W G ) B G - 1 S ( W G ) B G - 2 B R ( W G ) B G - 2 D ( W G ) B G - 2 S ( W G ) B G - 3 D ( W G ) B G - 3 S ( W G ) Su l f a t e : C h l o r i d e 7. 9 3 0 . 3 1 3 . 7 3 3 . 1 1 0 . 3 3 0 . 3 9 0 . 5 2 0. 0 0 1. 0 0 2. 0 0 3. 0 0 4. 0 0 5. 0 0 6. 0 0 7. 0 0 8. 0 0 9. 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N P O R E W A T E R DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 3 S ( P W ) A B - 3 S L ( P W ) A B - 4 S ( P W ) A B - 4 S L ( P W ) A B - 5 S ( P W ) A B - 6 S ( P W ) A S - 7 S ( P W ) I B - 1 S ( P W ) Su l f a t e : C h l o r i d e 24 . 9 2 . 6 2 . 1 1 6 . 8 2 . 0 6 . 5 7 . 8 1 7 . 5 0. 0 5. 0 10 . 0 15 . 0 20 . 0 25 . 0 30 . 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S E E P S A M P L E S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- RB S W 0 0 1 ( S e e p ) R B S W 0 0 2 ( S e e p ) S - 1 1 ( S e e p ) S - 2 ( S e e p ) S - 4 ( S e e p ) S - 5 ( S e e p ) S - 6 ( S e e p ) S - 7 ( S e e p ) S - 8 ( S e e p ) S - 9 ( S e e p ) Su l f a t e : C h l o r i d e 0 4 . 4 9 2 . 4 3 1 3 . 1 3 3 . 9 1 4 . 8 1 3 . 7 1 0 . 2 3 0 . 0 0 3 . 9 4 02468101214 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N B E D R O C K W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 3 B R ( W G ) A B - 6 B R U ( W G ) B G - 2 B R ( W G ) GW A - 2 0 B R (W G ) GW A - 2 2 B R (W G ) GW A - 2 3 B R (W G ) GW A - 2 B R ( W G ) GW A - 2 B R U (W G ) GW A - 4 B R ( W G ) G W A - 7 B R ( W G ) G W A - 9 B R ( W G ) M W - 1 5 B R ( W G ) M W - 7 B R ( W G ) M W - 9 B R ( W G ) Su l f a t e : C h l o r i d e 7. 7 3 1 6 . 1 1 3 . 7 3 3 . 0 5 2 . 8 4 9 . 0 0 7 . 6 0 0 . 2 3 1 . 4 4 7 . 1 7 0 . 0 0 5 . 2 7 1 . 4 7 2 . 8 6 0. 0 0 2. 0 0 4. 0 0 6. 0 0 8. 0 0 10 . 0 0 12 . 0 0 14 . 0 0 16 . 0 0 18 . 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 D ( W G ) A B - 2 D ( W G ) A B - 3 D ( W G ) A B - 4 D ( W G ) A B - 5 D ( W G ) A B - 7 D ( W G ) A B - 8 D ( W G ) A S - 1 D ( W G ) A S - 2 D ( W G ) A S - 3 D ( W G ) Su l f a t e : C h l o r i d e 4. 6 5 3 . 5 5 2 2 . 5 0 5 . 2 4 1 1 . 9 8 6 . 4 6 2 3 . 4 5 3 . 7 4 6 . 3 4 5 . 8 1 0. 0 0 5. 0 0 10 . 0 0 15 . 0 0 20 . 0 0 25 . 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- BG - 1 D ( W G ) B G - 2 D ( W G ) B G - 3 D ( W G ) C - 2 D ( W G ) G W A - 1 0 D ( W G ) G W A - 1 D ( W G ) G W A - 2 0 D ( W G ) G W A - 2 2 D ( W G ) G W A - 2 3 D ( W G ) G W A - 3 D ( W G ) Su l f a t e : C h l o r i d e 7. 9 3 3 . 1 1 0 . 3 9 0 . 8 6 4 . 0 5 2 . 7 2 3 8 . 3 7 4 . 1 2 4 . 0 8 2 0 1 . 5 4 0. 0 0 50 . 0 0 10 0 . 0 0 15 0 . 0 0 20 0 . 0 0 25 0 . 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- GW A - 4 D ( W G ) G W A - 5 D ( W G ) G W A - 6 D ( W G ) G W A - 7 D ( W G ) G W A - 8 D ( W G ) G W A - 9 D ( W G ) M W - 1 1 D R ( W G ) M W - 1 5 D ( W G ) M W - 1 D ( W G ) M W - 2 D ( W G ) Su l f a t e : C h l o r i d e 1. 3 8 2 . 3 8 6 . 4 6 7 . 3 4 3 . 7 8 4 . 9 6 6 . 1 0 6 . 4 7 1 0 . 9 0 0 . 1 6 0. 0 0 2. 0 0 4. 0 0 6. 0 0 8. 0 0 10 . 0 0 12 . 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N D E E P W E L L S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- MW - 3 D ( W G ) M W - 4 D ( W G ) M W - 5 D ( W G ) M W - 6 D ( W G ) M W - 8 D ( W G ) M W - 9 D ( W G ) Su l f a t e : C h l o r i d e 4. 0 5 5 . 7 2 6 . 8 6 5 . 2 4 0 . 0 0 1 0 . 2 2 0. 0 0 2. 0 0 4. 0 0 6. 0 0 8. 0 0 10 . 0 0 12 . 0 0 R a t i o NO T E : C e l l v a l u e o f 0 i n d i c a t e s a n a l y t e r e s u l t i s n o n - d e t e c t o r n o t r e p o r t a b l e . DATE SU L F A T E : C H L O R I D E R A T I O S I N S U R F A C E W A T E R A N D A S H B A S I N W A T E R S A M P L E S DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N A S H B A S I N FIGURE GA S T O N C O U N T Y , N O R T H C A R O L I N A AUGUST 2015 10- AB - 1 D ( W G ) A B - 1 S ( W G ) A B - 2 D ( W G ) A B - 2 S ( W G ) AB - 3 B R (W G ) AB - 3 D ( W G ) A B - 4 D ( W G ) A B - 5 D ( W G ) AB - 6 B R U (W G ) AB - 6 S ( W G ) A B - 7 D ( W G ) A B - 7 I ( W G ) A B - 8 D ( W G ) A B - 8 S (WG) S - 1 3 ( W S ) S W - 1 ( W S) S W - 2 ( W S ) S W - 3 ( W S ) Su l f a t e : C h l o r i d e 4. 6 5 0 . 1 3 3 . 5 5 0 . 0 0 7 . 7 3 2 2 . 5 0 5 . 2 4 1 1 . 9 8 1 6 . 1 1 1 . 7 8 6 . 4 6 3 . 5 0 2 3 . 4 5 2 4 . 9 1 0 . 0 0 1 0 . 0 2 1 0 . 2 2 2 1 . 6 4 0. 0 0 5. 0 0 10 . 0 0 15 . 0 0 20 . 0 0 25 . 0 0 30 . 0 0 R a t i o �m \m to ^ice �o Ory� AB 0o mc' 'moo oam Gr TO 0 Calcium CATIONS '00 Ash Basin Porewater Ash Basin Water �o Background Monitoring Wells Co 4 3k 0o d �4 ,B-7S-21 3 / p0 ryo F. o ryo �o 00 n 0 00 0 Chloride+Nitrogen, NO2 plus NO3 ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite) DATE PIPER DIAGRAM -ASH BASIN POREWATER, WATER, AND AUGUST 2015 F)l BACKGROUND MONITORING WELLS DUKE ENERGY CAROLINAS, LLC FIGURE RIVERBEND STEAM STATION ASH BASIN 10- GASTON COUNTY. NORTH CAROLINA '00 Ash Basin Porewater Ash Basin Water ^ice �o 10w� c-is Seeps y 4 Q SW-1 �OrV 60 AB-5SL SW S-2 `O `Q p S-5 ems. SW-3 S 9 AB-7S Oaf �0 b0 Gr � 0 /�\7 A / Q) �O `o' SO "o a0 0 O Calcium CATIONS n O �O b0 00 00 00 n Chloride+Nitrogen, NO2 plus NO3 ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite) DATE PIPER DIAGRAM -ASH BASIN POREWATER, WATER, AND AUGUST 2015 F)l SEEPS DUKE ENERGY CAROLINAS, LLC FIGURE RIVERBEND STEAM STATION ASH BASIN 10- GASTON COUNTY, NORTH CAROLINA '00 ® Ash Basin Porewater GWA-3SA \; GWA-3D Downgradient'IS" Wells `Po ro� 0 Downgradient "D" Wells �O C-15 dam. q GWA-1OS ® Downgradient "BR" Wells Q MW-1D 43 0� AMS k Z -0 AB-5SL 00 N " AB-8D 0GWA-8S �N�. 'moo MW-11DR MW-11SR % / W-15 aZ � GWA-2S� i O O b '4 AB-7S Ur GWA-SD AB-1S AB -SS AB-SBRU / c0 AB-4S ry0 GWA-7BR AMID ABA AB-2D O AB-3D O GWA-7D 0 Calcium CATIONS Chloride+Nitrogen, NO2 plus NO3 ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite). DATE PIPER DIAGRAM -ASH BASIN POREWATER, WATER, AND AUGUST 2015 F)l DOWNGRADIENT "S", "D", AND "BR" MONITORING WELLS DUKE ENERGY CAROLINAS, LLC FIGURE RIVERBEND STEAM STATION ASH BASIN 10- GASTON COUNTY. NORTH CAROLINA '00 Ash Basin Porewater \m � Ash Basin Water cv0 �o Upgradient "S" Wells � GWA-4S c-1s d 0 Upgradient "D" Wells k Upgradient "BR" Wells Ory 00 SW-1 00 N moo. SW-2 o�m per' AB-5SL 4 SW-3 3 0 Oda VO ABJS PO Gr � AB-5S AB-4S / �'o ryo GWA-20S GWA-22BR ;' ..' WA-5D / \ / \ 0 / O 0 �o `PO oo "o 'Po 0 0 Calcium CATIONS Chloride+Nitrogen, NO2 plus NO3 ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite) DATE PIPER DIAGRAM -ASH BASIN POREWATER, WATER, AND AUGUST 2015 F)l UPGRADIENT "S", "D", AND "BR" MONITORING WELLS DUKE ENERGY CAROLINAS, LLC FIGURE RIVERBEND STEAM STATION ASH BASIN 10- GASTON COUNTY, NORTH CAROLINA '00 Ash Basin Porewater �m \m � Ash Basin "S" Wells Co �0 0 Ash Basin "D" Wells �O n m ® Ash Basin "BR" Wells y Q AB-8S C-1 s c 3k ory °o 0o d mo. AB-3D �c O, AB-5SL ems. c3 �° a� V AS-1S �L O o AB-7S P Gr AB -IS �0 A13-5S AB-4S ry0 AB-1D A -2D AB-5D \\ O O AS-2D B-3 AB-4D C-2D \ 100 AS-313 100 AB-3BR C-1 S AS-2S O AB-3S AB-8S 80 p0� a 80 � N° .... AB-5SL a c3k C \� n6 7s m p 60 m° 0 ° yP. F Q ABA-8D G� x \ 60 N c3 �' AS-1 S / o 40 40 AMIDAB 85� C-1S \ AB-1S A -SS \ AB-5S ', AB-5D AS-1S.-7S AB-3D AB-3S 00 O 20 C-2D AMID AB-3D AS-2S AS-3D20 AB-36R AS-2D / `,,.,. AB-4S AB-1S PDD AB-5SL AS Q AS-3D / C AS-2S AB-2D AB-1D \ / AB-3S �O AB4DD \ �• \\ AB-3BR :� 00 0 "O COO O 00 p0 ap O O ry0 �O 00 00 00 n Calcium Chloride+Nitrogen, NO2 plus NO3 CATIONS ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite). PIPER DIAGRAM -ASH BASIN POREWATER, "S", "D", AND "BR" MONITORING WELLS DATE DUKE ENERGY CAROLINAS, LLC AUGUST 2015 F)l RIVERBEND STEAM STATION ASH BASIN FIGURE 10- GASTON COUNTY, NORTH CAROLINA '00 \m Co roo ® Ash Basin "S" Wells �O n Seeps OryQ AB-8S 00 00 N mac, S-2 07 A ems. S-5 am vo ao r AB-1 s G AS is s_y / �0 S-11 ry0 O / \ / \ / \ / \ / \ O �O 00 (110 10 �01 O O �O b0 00 00 O Calcium Chloride+Nitrogen, NO2 plus NO3 CATIONS ANIONS NOTE: Nitrate plus Nitrite was reported by the laboratory and is used here. Equivalent weight of 54 used (average of nitrate and nitrite). DATE PIPER DIAGRAM - ASH BASIN "S" WELLS AND SEEPS DUKE ENERGY CAROLINAS, LLC AUGUST 2015 F)l RIVERBEND STEAM STATION ASH BASIN FIGURE 10- GASTON COUNTY, NORTH CAROLINA &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &<&< &< &< &< &< &< C a t a w b a R i v e r SR-207 4 SR-1912 AB1S AB2S AB6S AB7I AB8S AS1S AS2S BG1S BG2S BG3S C2S GWA1S GWA2S GWA3SA GWA4S GWA5S GWA6S GWA7S GWA8S GWA9S GWA10S GWA20S GWA22SGWA23S MW10 MW11SR MW13 MW14 MW15 MW8SMW8I MW9 MW1S MW3S MW5S MW6S DETECTION MONITORING CONSTITUENTS DETECTED IN SHALLOW WELLS GASTON COUNTY, NORTH CAROLINA PA T H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ D C _ S . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL &<ASH BASIN COMPLIANCEGROUNDWATER MONITORING WELL &<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) Analyte AbbreviationBoronBCalciumCaChlorideCl-pH (field)pHSulfateSO4Total Dissolved Solids TDS Sample MW-15Sample Date 6/23/2015Constituent (µg/L)B 280 Ca 3,930 Cl-6,000 SO4 29,000 TDS 227,000 Sample GWA-10SSample Date 7/2/2015Constituent (µg/L)B 170 Ca 5,040 Cl-5,700 SO4 31,000 TDS 109,000 Sample MW-13Sample Date 6/30/2015Constituent (µg/L)B 60 Ca 9,340 Cl-4,200 SO4 15,700 TDS 87,000 Sample AB-1SSample Date 7/9/2015Constituent (µg/L)Ca 1,170 Cl-5,300 SO4 690 JTDS 40,000 Sample MW-5SSample Date 6/25/2015Constituent (µg/L)B 330 Ca 889 Cl-7,000 SO4 10,200 TDS 58,000 Sample MW-6SSample Date 6/18/2015Constituent (µg/L)B 230 Ca 11,100 Cl-6,600 SO4 36,700 TDS 121,000 Sample MW-3SSample Date 6/30/2015Constituent (µg/L)B 260 Ca 13,800 Cl-7,100 SO4 29,900 TDS 118,000 Sample GWA-1SSample Date 7/2/2015Constituent (µg/L)Ca 4,160 Cl-5,200 TDS 78,000 Sample MW-11SR Sample Date 7/2/2015Constituent (µg/L)B 360 Ca 9,290 Cl-6,000 SO4 37,600 Sample GWA-9SSample Date 6/30/2015Constituent (µg/L)B 200 Ca 2,170 Cl-6,800 SO4 26,500 TDS 60,000 Sample GWA-2S Sample Date 6/22/2015Constituent (µg/L)B 460 Ca 13,200 Cl-5,800 SO4 36,100 TDS 132,000 Sample MW-10Sample Date 6/23/2015Constituent (µg/L)B 180 Ca 4,290 Cl-6,400 SO4 19,500 TDS 69,000 J Sample AB-6SSample Date 6/22/2015Constituent (µg/L)B 45 JCa94,400 Cl-8,800 SO4 15,700 TDS 296,000 Sample MW-1SSample Date 6/29/2015Constituent (µg/L)B 300 Ca 2,010 Cl-10,700 SO4 1,200 J-TDS 60,000 Sample MW-9Sample Date 7/6/2015Constituent (µg/L)B 36 JCa12,400 Cl-2,200 SO4 24,600 TDS 114,000 Sample AB-8SSample Date 6/20/2015Constituent (µg/L)B 220 Ca 37,700 Cl-5,300 SO4 132,000 TDS 274,000 Sample C-2SSample Date 6/19/2015Constituent (µg/L)B 170 Ca 11,800 Cl-3,200 SO4 60,400 TDS 160,000 J+ Sample GWA-3SASample Date 7/1/2015Constituent (µg/L)Ca 367,000 Cl-6,100 SO4 1,420,000 TDS 23,000,000 Sample AS-1SSample Date 6/5/2015Constituent (µg/L)B 2,200 Ca 167,000 M6Cl-18,300 SO4 231,000 TDS 750,000 J- Sample GWA-4SSample Date 7/10/2015Constituent (µg/L)Ca 25,200 Cl-2,900 SO4 84,700 TDS 187,000 Sample GWA-20SSample Date 7/11/2015Constituent (µg/L)Ca 2,780 Cl-8,100 SO4 980 JTDS31,000 Sample AS-2SSample Date 6/5/2015Constituent (µg/L)Ca 4,870 Cl-2,600 SO4 5,200 TDS 62,000 J- Sample MW-8ISample Date 7/1/2015Constituent (µg/L)Ca 2,960 J+TDS 77,000 Sample MW-8SSample Date 6/30/2015Constituent (µg/L)Ca 345 Cl-7,000 SO4 580 J Sample GWA-23SSample Date 7/10/2015Constituent (µg/L)Ca 858 Cl-2,300 TDS 27,000 Sample GWA-22SSample Date 7/10/2015Constituent (µg/L)Ca 696 Cl-2,800 Sample GWA-5SSample Date 6/18/2015Constituent (µg/L)Ca 915 Cl-980 J Sample AB-7ISample Date 7/7/2015Constituent (µg/L)Ca 2,030 Cl-1,800 SO4 6,300 TDS 41,000 Sample GWA-6SSample Date 6/19/2015Constituent (µg/L)Ca 1,390 Cl-2,900 SO4 1,200 TDS 31,000 J+ Sample BG-1SSample Date 7/6/2015Constituent (µg/L)Ca 1,460 Cl-1,900 SO4 580 J Sample BG-2SSample Date 7/10/2015Constituent (µg/L)Ca 11,000 Cl-8,900 SO4 2,900 TDS 87,000 Sample BG-3SSample Date 6/30/2015Constituent (µg/L)Ca 6,140 Cl-4,600 SO4 2,400 TDS 57,000 Sample GWA-7SSample Date 6/19/2015Constituent (µg/L)Ca 6,540 Cl-2,600 SO4 530 JTDS65,000 J+Sample GWA-8SSample Date 6/28/2015Constituent (µg/L)B 240 Ca 2,070 Cl-6,200 SO4 36,000 J+TDS 85,000 Sample MW-14Sample Date 6/30/2015Constituent (µg/L)B 130 Ca 6,790 Cl-13,500 SO4 30,100 TDS 138,000 &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< &<C a t a w b a R i v e r SR-207 4 SR-1912 AB1D AB2D AB3D AB4D AB5D AB7D AB8D AS1D AS2D AS3D BG1D BG2D BG3D C2D GWA1D GWA3D GWA4D GWA5D GWA6D GWA7D GWA8D GWA9D GWA10D GWA20D GWA22DGWA23D MW9D MW15D MW11DR MW8D MW1D MW2D MW3D MW4D MW5D MW6D DETECTION MONITORING CONSTITUENTS DETECTED IN DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA PA T H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ D C _ D . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL &<ASH BASIN COMPLIANCEGROUNDWATER MONITORING WELL &<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) Analyte AbbreviationBoronBCalciumCaChlorideCl-pH (field)pHSulfateSO4Total Dissolved Solids TDS Sample GWA-3DSample Date 6/17/2015Constituent (µg/L)B 34 JCa437,000 Cl-6,500 SO4 1,310,000 TDS 2,390,000 Sample GWA-4DSample Date 7/10/2015Constituent (µg/L)Ca 12,300 Cl-3,200 SO4 4,400 TDS 101,000 Sample AS-1DSample Date 6/5/2015Constituent (µg/L)Ca 111,000 Cl-5,700 SO4 21,300 TDS 390,000 J- Sample C-2DSample Date 6/19/2015Constituent (µg/L)Ca 23,800 Cl-2,200 SO4 1,900 TDS 152,000 J+ Sample MW-9DSample Date 7/1/2015Constituent (µg/L)Ca 72,600 J-Cl-2,700 SO4 27,000 TDS 223,000 Sample AB-8DSample Date 6/17/2015Constituent (µg/L)B 440 Ca 61,300 Cl-5,800 SO4 136,000 TDS 361,000 Sample MW-1DSample Date 6/29/2015Constituent (µg/L)B 650 Ca 25,300 Cl-7,900 SO4 86,100 TDS 197,000 Sample AB-5DSample Date 6/20/2015Constituent (µg/L)B 150 Ca 42,600 Cl-4,700 SO4 56,300 TDS 214,000 Sample GWA-20DSample Date 7/16/2015Constituent (µg/L)Ca 758,000 J-Cl-9,800 SO4 376,000 J+TDS 2,900,000 Sample AS-2DSample Date 6/8/2015Constituent (µg/L)B 28 JCa69,900 M1Cl-4,100 SO4 26,000 TDS 280,000 J- Sample MW-8D Sample Date 7/1/2015Constituent (µg/L)Ca 5,760 Cl-1,200 TDS 111,000 Sample GWA-23DSample Date 7/16/2015Constituent (µg/L)Ca 46,400 Cl-2,600 SO4 10,600 TDS 196,000 Sample GWA-22DSample Date 7/10/2015Constituent (µg/L)Ca 44,400 Cl-5,700 SO4 23,500 TDS 214,000 Sample AS-3DSample Date 6/5/2015Constituent (µg/L)B 27 JCa20,400 Cl-3,100 SO4 18,000 TDS 110,000 J- Sample GWA-5DSample Date 7/11/2015Constituent (µg/L)Ca 28,000 Cl-2,100 SO4 5,000 TDS 137,000 Sample AB-7DSample Date 7/1/2015Constituent (µg/L)Ca 70,100 Cl-7,200 SO4 46,500 TDS 326,000 Sample GWA-6DSample Date 6/19/2015Constituent (µg/L)Ca 47,800 Cl-2,400 SO4 15,500 TDS 184,000 J+ Sample AB-3DSample Date 7/7/2015Constituent (µg/L)Ca 283,000 Cl-6,400 SO4 144,000 TDS 946,000 Sample BG-1DSample Date 7/11/2015Constituent (µg/L)B 27 JCa83,300 Cl-6,100 J-SO4 48,400 J+TDS 555,000 Sample BG-2DSample Date 7/11/2015Constituent (µg/L)Ca 57,600 Cl-10,000 SO4 31,100 TDS 261,000 Sample BG-3DSample Date 7/6/2015Constituent (µg/L)Ca 9,430 Cl-2,800 SO4 1,100 TDS 231,000 Sample GWA-8DSample Date 6/28/2015Constituent (µg/L)B 110 Ca 14,600 Cl-6,300 SO4 23,800 J+TDS 128,000 Sample GWA-7DSample Date 6/17/2015Constituent (µg/L)Ca 24,500 Cl-4,400 SO4 32,300 TDS 176,000 Sample GWA-9DSample Date 7/1/2015Constituent (µg/L)B 260 J+Ca 14,100 Cl-6,700 SO4 33,200 TDS 26,000 Sample MW-5DSample Date 6/18/2015Constituent (µg/L)B 380 Ca 24,300 Cl-6,500 SO4 44,600 TDS 186,000 Sample AB-2DSample Date 7/8/2015Constituent (µg/L)B 160 Ca 64,000 Cl-6,400 SO4 22,700 TDS 241,000 Sample MW-5DSample Date 6/18/2015Constituent (µg/L)B 380 Ca 24,300 Cl-6,500 SO4 44,600 TDS 186,000 Sample AB-1DSample Date 7/9/2015Constituent (µg/L)B 65 Ca 123,000 Cl-4,900 SO4 22,800 TDS 351,000 Sample MW-4DSample Date 6/18/2015Constituent (µg/L)B 270 Ca 10,900 Cl-5,400 SO4 30,900 TDS 113,000 Sample GWA-10DSample Date 7/3/2015Constituent (µg/L)B 140 Ca 25,600 Cl-6,400 SO4 25,900 TDS 185,000 Sample MW-15DSample Date 6/18/2015Constituent (µg/L)B 170 Ca 52,700 Cl-6,200 SO4 40,100 TDS 241,000 Sample MW-3DSample Date 6/30/2015Constituent (µg/L)B 260 Ca 17,100 Cl-6,600 SO4 26,700 TDS 141,000 Sample GWA-1DSample Date 7/2/2015Constituent (µg/L)B 33 JCa47,400 Cl-3,200 SO4 8,700 TDS 232,000 Sample MW-11DRSample Date 7/2/2015Constituent (µg/L)B 320 Ca 9,150 Cl-5,900 SO4 36,000 TDS 140,000 Sample MW-2DSample Date 6/30/2015Constituent (µg/L)Ca 6,950 Cl-4,600 SO4 720 JTDS92,000 Sample AB-4DSample Date 7/8/2015Constituent (µg/L)Ca 32,900 Cl-2,500 SO4 13,100 TDS 159,000 &< &< &< &< &< &<&< &< &< &<&< &< &< &< C a t a w b a R i v e r SR-207 4 SR-1912 DETECTION MONITORING CONSTITUENTS DETECTED IN BEDROCK WELLS (BR AND BRU) GASTON COUNTY, NORTH CAROLINA PA T H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ D C _ B R . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) Sample GWA-4BRSample Date 7/27/2015Constituent (µg/L)Ca 545,000 Cl-4,800 SO4 6,900 TDS 1,500,000 Sample GWA-20BRSample Date 7/27/2015Constituent (µg/L)Ca 97,600 Cl-1,900 SO4 5,800 TDS 380,000 Sample GWA-23BRSample Date 7/17/2015Constituent (µg/L)Ca 307,000 Cl-2,000 SO4 18,000 TDS 790,000 Sample GWA-22BRSample Date 7/21/2015Constituent (µg/L)Ca 303,000 Cl-7,400 SO4 21,000 TDS 360,000 Sample MW-9BRSample Date 7/2/2015Constituent (µg/L)Ca 56,200 Cl-6,300 SO4 18,000 TDS 107,000 Sample MW-15BRSample Date 6/23/2015Constituent (µg/L)B 260 Ca 8,160 Cl-7,500 SO4 39,500 TDS 232,000 Sample MW-7BRSample Date 7/10/2015Constituent (µg/L)Ca 537,000 Cl-4,900 SO4 7,200 TDS 1,180,000 Sample AB-6BRU AB-6BRUSample Date 6/22/2015 7/2/2015Constituent (µg/L)B 480 430 Ca 41,600 92,800 Cl-5,300 5,400 SO4 83,500 87,000 TDS 247,000 212,000 Sample GWA-7BRSample Date 7/7/2015Constituent (µg/L)Ca 33,600 Cl-3,000 SO4 21,500 TDS 141,000 Sample GWA-2BRSample Date 6/17/2015Constituent (µg/L)Ca 27,400 Cl-5,200 SO4 39,500 TDS 164,000 Sample GWA-9BRSample Date 7/10/2015Constituent (µg/L)B 210 Ca 17,500 Sample BG-2BRSample Date 7/17/2015Constituent (µg/L)Ca 24,200 Cl-2,200 SO4 8,200 TDS 118,000 Sample AB-3BRSample Date 7/23/2015Constituent (µg/L)Ca 31,300 Cl-2,200 SO4 17,000 TDS 160,000 Analyte AbbreviationBoronBCalciumCaChlorideCl-pH (field)pHSulfateSO4Total Dissolved Solids TDS &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &<&< &< &< &< &< &< C a t a w b a R i v e r SR-207 4 SR-1912 ASSESSMENT MONITORING CONSTITUENTS DETECTED IN SHALLOW WELLS (S) GASTON COUNTY, NORTH CAROLINA PA T H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ A C _ S . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-104 N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL &<ASH BASIN COMPLIANCEGROUNDWATER MONITORING WELL &<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) Analyte AbbreviationAntimonySbArsenicAsBariumBaBerylliumBeCadmiumCdChromiumCrCobaltCoLeadPbMercuryHgMolybdenum MoSeleniumSeThalliumTlRadium-226 Ra-226Radium-228 Ra-228 Sample GWA-3SASample Date 7/1/2015Constituent (µg/L)As 0.23 JBa100 Cd 0.19 Co 18.4 Cr 0.53 J+Mo 0.56 J+Pb 0.14 J+Sb 0.77 J+Se 5.7 Sample MW-9Sample Date 7/6/2015Constituent (µg/L)As 0.18 JBa58 Co 0.87 Cr 1.2 Mo 0.14 JPb0.21 Sample AB-8SSample Date 6/20/2015Constituent (µg/L)Ba 130 Be 0.18 JCd0.16 Co 0.55 Cr 3.8 Hg 0.11 J+Se 1.2 Tl 0.02 J Sample MW-1SSample Date 6/29/2015Constituent (µg/L)Ba 22 Co 61 Cr 0.57 J+Mo 0.12 JPb0.064 J Sample AB-6SSample Date 6/22/2015Constituent (µg/L)As 0.82 Ba 9 Co 0.31 JCr1.2 J+Mo 7.6 Pb 0.19 Sb 1.8 Se 2.6 Sample MW-10Sample Date 6/23/2015Constituent (µg/L)As 0.16 JBa56 Be 0.15 JCd0.082 Co 0.9 Cr 2.7 Hg 0.081 J+Pb 0.15 Se 0.53 Sample GWA-2SSample Date 6/22/2015Constituent (µg/L)As 0.28 JBa52 Co 0.34 JCr2.8 J+Hg 0.088 J+Mo 0.1 JPb0.076 J Sample GWA-1SSample Date 7/2/2015Constituent (µg/L)Ba 60 Co 2.1 Cr 11.6 Mo 0.43 JPb0.21 J+Sb 0.28 J Sample MW-3SSample Date 6/30/2015Constituent (µg/L)Ba 17 Co 0.14 JCr0.44 J+Pb 0.24 Sample MW-15Sample Date 6/23/2015Constituent (µg/L)As 0.25 JBa86 Be 0.22 Co 1.3 Cr 6.8 Hg 0.078 J+Pb 0.6 Se 2 Sample GWA-10SSample Date 7/2/2015Constituent (µg/L)Ba 29 Be 0.11 JCd0.032 JCo10 Cr 3.5 J Sample MW-13Sample Date 6/30/2015Constituent (µg/L)As 0.39 JBa300 Co 23.7 Cr 0.38 J+Hg 0.072 JTl0.072 J Sample AB-1SSample Date 7/9/2015Constituent (µg/L)As 0.17 JBa21 Be 0.12 JCo15.9 Cr 1.8 J+Hg 0.11 J+Mo 0.17 JPb0.18 Sb 3.2 Sample MW-5SSample Date 6/25/2015Constituent (µg/L)Ba 22 Be 0.072 JCo1.9 Cr 1.7 Hg 0.26 Pb 0.062 JSe0.29 J Sample MW-6SSample Date 6/18/2015Constituent (µg/L)Ba 8.4 Co 0.2 JPb0.051 J Sample GWA-9SSample Date 6/30/2015Constituent (µg/L)Ba 30 Be 0.078 JCo50.1 Cr 0.32 J+Hg 0.11 JPb0.14 Tl 0.04 J Sample MW-14Sample Date 6/30/2015Constituent (µg/L)Ba 7.8 Cr 1.7 J+Mo 0.37 J Sample GWA-8SSample Date 6/28/2015Constituent (µg/L)Ba 130 Cd 0.054 JCo66.8 Cr 6.4 J+Tl 0.031 J Sample GWA-7S Sample Date 6/19/2015Constituent (µg/L)As 0.2 J+Ba 39 Co 1 J+Cr 3.8 Hg 0.075 J+Pb 0.26 Sample BG-3SSample Date 6/30/2015Constituent (µg/L)Ba 33 Cd 0.031 JCo0.54 Cr 0.25 J+Hg 0.073 JMo0.14 JSb1.3 J+ Sample BG-2SSample Date 7/10/2015Constituent (µg/L)As 0.12 JBa71 Co 0.69 Cr 0.83 Mo 0.19 JSb0.33 JTl0.033 J+ Sample BG-1SSample Date 7/6/2015Constituent (µg/L)As 0.21 JBa42 Be 0.076 JCd0.034 JCo3 Cr 5.2 Mo 0.2 JPb0.61 Ra-226 1.01 J+Sb 0.43 JTl0.032 J Sample GWA-6SSample Date 6/19/2015Constituent (µg/L)As 0.24 J+Ba 45 Be 0.079 JCd0.2 Co 27.6 Cr 1.7 J+Hg 0.073 J+Pb 0.59 Tl 0.054 J Sample AB-7ISample Date 7/7/2015Constituent (µg/L)Ba 35 Cd 0.036 J+Co 1.6 Cr 0.9 J+Pb 0.11 J+Sb 1 J+Tl 0.048 J+ Sample GWA-5SSample Date 6/18/2015Constituent (µg/L)Ba 17 Co 4.5 Cr 0.57 J+Hg 0.11 J+Mo 0.19 J Sample GWA-22SSample Date 7/10/2015Constituent (µg/L)Ba 34 Cd 0.075 JCo1.3 Cr 1.9 J+Mo 0.1 JPb0.071 JSb2.2 Tl 0.02 J Sample GWA-23SSample Date 7/10/2015Constituent (µg/L)Ba 37 Cd 0.04 JCo3.3 Cr 3.2 J+Mo 0.13 JPb0.18 Sb 0.24 J Sample MW-8ISample Date 7/1/2015Constituent (µg/L)As 0.12 JBa42 Be 0.24 J+Co 0.76 Cr 1.3 J+Mo 3.2 J+Pb 0.28 J+Tl 0.02 J Sample AS-2SSample Date 6/5/2015Constituent (µg/L)As 0.42 JBa170 Be 0.21 Cd 0.13 Co 12.4 Cr 44.8 Mo 1.5 Pb 1.4 Sb 0.21 JTl0.11 Sample GWA-20SSample Date 7/11/2015Constituent (µg/L)As 3.3 Ba 67 Be 0.65 Cd 0.13 Co 12.7 Cr 133 Mo 14.3 Pb 7.5 Sb 0.22 JSe0.31 JTl0.087 J Sample GWA-4SSample Date 7/10/2015Constituent (µg/L)Ba 26 Be 0.26 Cd 0.12 Co 1.7 Cr 2.1 Pb 0.083 JSe0.4 J Sample AS-1SSample Date 6/5/2015Constituent (µg/L)As 1.4 Ba 100 Cd 0.054 JCo5.4 Cr 6.1 Mo 136 Pb 0.14 Sb 0.26 JSe0.49 JTl0.076 J Sample C-2SSample Date 6/19/2015Constituent (µg/L)As 0.95 J+Ba 36 Be 1.9 Cd 0.21 Co 39.7 Cr 0.64 J+Hg 0.27 J+Pb 0.2 Se 1.5 Tl 0.09 J SampleMW-9D (POSSIBLY NOT MW-9D-(CJM-8/1/15))Sample Date 7/2/2015Constituent (µg/L)As 0.28 JBa23 Cr 27 Mo 7 Pb 0.091 J+Sb 2.7 Se 0.38 J Sample MW-8SSample Date 6/30/2015Constituent (µg/L)Ba 57 Be 0.089 JCd0.036 JCo0.23 JCr0.71 J+Pb 0.076 JSb0.83 J+Tl 0.033 J Sample AB-2SSample Date 7/8/2015Constituent (µg/L)As 0.2 JBa28 Be 0.15 JCd0.065 JCo17.1 Cr 2.5 J+Mo 0.24 JPb0.29 Sb 3.1 Tl 0.072 J Sample MW-11SRSample Date 7/2/2015Constituent (µg/L)Ba 25 Cd 0.026 JCr1.8 JMo0.16 JSb0.87 Se 0.71 &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &< &<&< &< &< &< &< &< &< &< &< &< &< C a t a w b a R i v e r SR-207 4 SR-1912 ASSESSMENT MONITORING CONSTITUENTS DETECTED IN DEEP WELLS (D) GASTON COUNTY, NORTH CAROLINA PA T H : G : \ P R O J E C T S \ D U K E E N E R G Y \ A S H B A S I N \ M A P _ D O C S \ R I V E R B E N D \ R E P O R T _ R I V E R B E N D _ A R C H E _ C H E M B O X _ A C _ D . M X D - U S E R : K K E I G H T L - D A T E : 8 / 1 7 / 2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL &<ASH BASIN COMPLIANCEGROUNDWATER MONITORING WELL &<ASH BASIN VOLUNTARY GROUNDWATERMONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) Analyte AbbreviationAntimonySbArsenicAsBariumBaBerylliumBeCadmiumCdChromiumCrCobaltCoLeadPbMercuryHgMolybdenum MoSeleniumSeThalliumTlRadium-226 Ra-226Radium-228 Ra-228 Sample GWA-4D Sample Date 7/10/2015Constituent (µg/L)As 0.22 JBa26 Co 0.52 Cr 2.1 Mo 1 Sample AS-1D Sample Date 6/5/2015Constituent (µg/L)As 0.68 Ba 51 Co 0.18 JCr903 Mo 57.4 Pb 0.11 Sb 3 Se 1.1 Sample C-2DSample Date 6/19/2015Constituent (µg/L)As 1.3 J+Ba 19 Cr 2.5 J+Hg 0.085 J+Mo 1.1 J+ Sample GWA-3DSample Date 6/17/2015Constituent (µg/L)As 0.65 Ba 49 Cd 0.11 Co 1.1 Cr 1.1 Hg 0.13 J+Mo 6.8 Se 5.2 Sample MW-9D Sample Date 7/1/2015Constituent (µg/L)As 0.38 JBa21 Cr 20.6 Mo 6 J+Sb 5.4 Se 0.38 J Sample AB-8DSample Date 6/17/2015Constituent (µg/L)As 0.17 JBa45 Co 0.73 Cr 1.4 Hg 0.11 J+Mo 1.3 Se 0.34 J Sample MW-1D Sample Date 6/29/2015Constituent (µg/L)Ba 31 Cd 0.12 Co 0.51 Cr 0.8 J+Hg 0.11 JPb0.064 JSe0.28 JTl0.034 J Sample AB-5D Sample Date 6/20/2015Constituent (µg/L)As 0.25 JBa27 Cr 5.3 Mo 5.4 Sb 1.2 Se 0.31 J Sample AB-4D Sample Date 7/8/2015Constituent (µg/L)As 0.65 Ba 18 Co 0.18 JCr7.4 Mo 3.3 Pb 0.055 JSb1.2 Se 0.47 J Sample MW-2DSample Date 6/30/2015Constituent (µg/L)Ba 23 Co 0.14 JCr3.6 J+Mo 0.12 J Sample GWA-1DSample Date 7/2/2015Constituent (µg/L)As 0.93 Ba 18 Co 0.55 Cr 6.1 Mo 10.5 Pb 0.13 J+Sb 3.2 Sample MW-3DSample Date 6/30/2015Constituent (µg/L)Ba 7.7 Cr 1.7 J+Hg 0.088 JPb0.09 J Sample MW-15D Sample Date 6/18/2015Constituent (µg/L)As 1 Ba 9.1 Cr 3.5 Hg 0.073 JMo10.7 Pb 0.059 JSb0.74 Se 1.1 Sample GWA-10D Sample Date 7/3/2015Constituent (µg/L)As 0.29 JBa58 Co 0.19 JCr6.1 Mo 4.1 Pb 0.42 Sb 1.1 Se 0.41 J Sample MW-4DSample Date 6/18/2015Constituent (µg/L)Ba 65 Co 0.67 Cr 1.4 J+Hg 0.15 JPb0.058 J Sample AB-1D Sample Date 7/9/2015Constituent (µg/L)As 0.84 Ba 30 Be 0.068 JCd0.031 JCo2.9 Cr 49.2 Hg 0.09 JMo4.6 Pb 0.85 Sb 6.3 Se 0.46 JTl0.064 J Sample MW-5D Sample Date 6/18/2015Constituent (µg/L)Ba 32 Co 0.24 JCr2.7 J+Hg 0.095 J+Mo 0.24 JPb0.082 J Sample AB-2DSample Date 7/8/2015Constituent (µg/L)As 0.72 Ba 13 Cd 0.045 JCo0.15 JCr13 Mo 8.9 Pb 0.13 Sb 1 Se 0.57 Tl 0.06 J Sample MW-6DSample Date 6/18/2015Constituent (µg/L)Ba 7.4 Cr 1.9 J+Mo 0.18 JPb0.051 J Sample GWA-9DSample Date 7/1/2015Constituent (µg/L)As 0.13 JBa9.4 Co 0.58 Cr 0.39 J+Mo 0.47 J+Pb 0.074 J+ Sample GWA-8DSample Date 6/28/2015Constituent (µg/L)Ba 5.3 Co 0.7 Cr 4.2 J+Mo 0.68 J+Pb 0.072 J+ Sample GWA-7D Sample Date 6/17/2015Constituent (µg/L)As 0.48 JBa13 Co 0.63 Cr 3.3 Hg 0.13 J+Mo 2.5 Pb 0.35 Sb 0.17 JSe0.24 JTl0.018 J Sample BG-3D Sample Date 7/6/2015Constituent (µg/L)As 0.81 Ba 50 Be 0.53 Co 0.84 Cr 0.97 J+Mo 2.8 Pb 5.1 Sb 0.16 JSe0.23 J Sample BG-2DSample Date 7/11/2015Constituent (µg/L)As 0.66 Ba 42 Cd 0.05 JCr57.5 Mo 5.2 Pb 0.093 JSb0.72 Se 2.9 Sample BG-1DSample Date 7/11/2015Constituent (µg/L)As 2 Ba 370 Co 1.3 Cr 32.3 Hg 0.12 J+Mo 9.4 Pb 0.24 Ra-226 0.652 J+Ra-228 3.18 J+Sb 3.3 Se 2.1 Sample AB-3D Sample Date 7/7/2015Constituent (µg/L)As 0.49 JBa190 Co 0.18 JCr51 Mo 34.5 Pb 0.44 J+Sb 0.22 JSe3.1 Tl 0.025 J Sample GWA-6DSample Date 6/19/2015Constituent (µg/L)As 1 J+Ba 27 Co 0.3 J+Cr 24.8 Hg 0.071 J+Mo 7.6 Sb 0.25 JSe0.56 Sample AB-7D Sample Date 7/1/2015Constituent (µg/L)As 2.2 Ba 41 Cr 24.7 Mo 8.5 J+Sb 7.5 Se 0.77 Sample GWA-5D Sample Date 7/11/2015Constituent (µg/L)As 0.96 Ba 9.6 Co 0.21 JCr24.5 Mo 3 Pb 1.3 Sample AS-3D Sample Date 6/5/2015Constituent (µg/L)As 0.97 Ba 21 Co 0.16 JCr23.5 Mo 22.1 Pb 0.094 JSb1.6 Se 0.66 Sample GWA-22DSample Date 7/10/2015Constituent (µg/L)As 0.91 Ba 61 Be 0.28 Co 3.4 Cr 174 Mo 7.1 Pb 1.2 Sb 1.4 Se 1.1 Sample GWA-23DSample Date 7/16/2015Constituent (µg/L)As 0.9 Ba 15 Cr 55 Mo 4.9 Se 0.4 J Sample MW-8DSample Date 7/1/2015Constituent (µg/L)As 0.32 JBa43 Be 0.12 J+Co 1.1 Cr 4.1 Mo 2.3 J+Pb 0.73 J+Sb 0.21 J+ Sample AS-2D Sample Date 6/8/2015Constituent (µg/L)As 0.66 Ba 50 Co 0.2 JCr22.5 Mo 10.5 Sb 1 J+Se 1.2 Sample GWA-20DSample Date 7/16/2015Constituent (µg/L)As 0.64 Ba 360 Cd 0.027 JCo1.9 Cr 186 Mo 71.8 Pb 1.1 Se 6.7 Tl 3.2 Sample MW-11DRSample Date 7/2/2015Constituent (µg/L)Ba 54 Be 0.071 JCr2.5 JMo0.14 JPb0.081 J+Sb 0.59 Se 0.72 &< &< &< &<&< &< &< &< &< &<&< &< &< &< C a t a w b a R i v e r S R -2 0 7 4 S R -1 9 1 2 ASSESSMENT MONITORING CONSTITUENTS DETECTED IN BEDROCK WELLS (BRU AND BR) GASTON COUNTY, NORTH CAROLINA P A T H : G :\P R O J E C T S \D U K E E N E R G Y \A S H B A S I N \M A P _D O C S \R I V E R B E N D \R E P O R T _R I V E R B E N D _A R C H E _C H E M B O X _A C _B R .M X D - U S E R : K K E I G H T L - D A T E : 8 /1 7 /2 0 1 5 DATE FIGURE AUGUST 2015 10-TBD N DUKE ENERGY CAROLINAS, LLCRIVERBEND STEAM STATION ASH BASIN LEGEND &<ASH BASIN ASSESSMENTGROUNDWATER MONITORING WELL ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARYCOINCIDENT WITH DUKE ENERGYPROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH STORAGE DUKE ENERGY PROPERTY BOUNDARY NOTES:U = NOT DETECTED ABOVE THE LABORATORY REPORTING LIMITJ = ESTIMATED CONCENTRATION<3.0 = LESS THAN THE LABORATORY REPORTING LIMITJ+ = ESTIMATED CONCENTRATION BIASED HIGHJ- = ESTIMATED CONCENTRATION BIASED LOW µG/L: MICROGRAMS PER LITER 500 0 500 1,000 SCALE (FEET) An alyte Abbreviat io nAntimonySbArsenicAsBariumBaBerylliumBeCadmiumCdChromiumCrCobaltCoLeadPbMercuryHgMolybdenumMoSeleniumSeThalliumTlRadium-226 Ra-226Radium-228 Ra-228 Sample GWA-2BRSample Date 6/17/2015Constituent (µg/L)As 1.3 Ba 7.7 Cr 7.4 Hg 0.15 J+Mo 5.9 Pb 0.048 JSb0.24 JSe1.2 Sample MW-15BRSample Date 6/23/2015Constituent (µg/L)As 0.78 Ba 23 Cr 4.9 Hg 0.088 J+Mo 8.2 Pb 0.066 JSb0.25 JSe0.57 Sample GWA-9BRSample Date 7/10/2015Constituent (µg/L)As 10.7 Ba 3.7 JCo0.75 Cr 40.6 Mo 47.3 Pb 0.84 Sb 4.5 Se 1.6 Sample GWA-7BRSample Date 7/7/2015Constituent (µg/L)As 0.29 JBa18 Cr 5.8 Mo 2.2 Pb 0.14 Sb 0.96 Se 0.3 J Sample BG-2BRSample Date 7/17/2015Constituent (µg/L)As 0.28 JBa13 Co 0.82 Cr 2.3 Hg 0.79 J-Mo 12.8 Pb 0.35 Se 0.6 Sample AB-3BRSample Date 7/23/2015Constituent (µg/L)As 1.23 Ba 18 Co 1.64 Cr 8.27 Mo 5.66 Se 15.4 Sample MW-7BRSample Date 7/10/2015Constituent (µg/L)As 0.23 JBa340 Cr 24.7 Mo 13.3 Pb 0.21 Sb 0.86 Se 0.51 Tl 0.064 J+ Sample GWA-22BRSample Date 7/21/2015Constituent (µg/L)Ba 185 Cr 108 Mo 946 Se 4.39 Sample GWA-23BRSample Date 7/17/2015Constituent (µg/L)As 0.28 JBa130 Cr 15.6 Mo 5.2 Pb 0.31 Se 0.3 JTl0.077 J Sample GWA-20BRSample Date 7/27/2015Constituent (µg/L)Ba 553 Cr 16.7 Mo 6.06 Sample GWA-4BRSample Date 7/27/2015Constituent (µg/L)Ba 383 Cr 38.1 Mo 18.2 Sample MW-9BRSample Date 7/2/2015Constituent (µg/L)As 0.69 Ba 21 Cr 4 JMo3.4 Pb 0.33 J+Sb 2.3 Se 0.22 JTl0.017 J Sample AB-6BRU AB-6BRUSample Date 6/22/2015 7/2/2015Constituent (µg/L)As 0.24 J 0.75 Ba 5.6 38 Cd --0.026 JCo--1.8 Cr 2.4 J+8.1 Hg 0.085 J+--Mo 1.2 2.8 Pb --0.73 J+Sb 0.32 J 2.5 Se --0.27 J Sample GWA-2BRUSample Date 7/10/2015Constituent (µg/L)As 0.36 JBa280 Co 0.81 Cr 46 Mo 60.1 Pb 0.81 Sb 18.2 Se 2.3 Tl 0.03 J Av'� f'. Ad 14 y. r w 4` r • a .; k''Vop Al . oil aV �� Ma oil I NOTES: 1. ASH STORAGE BOUNDARY AND CINDER STORAGE BOUNDARY ARE APPROXIMATE. 2. AS -BUILT MONITORING WELL LOCATIONS PROVIDED BY DUKE ENERGY. 3. SHALLOW MONITORING WELLS (S) - WELL SCREEN INSTALLED ACROSS THE SURFICIAL WATER TABLE. 4. DEEP MONITORING WELLS (D) - WELL SCREEN INSTALLED IN THE TRANSITION ZONE BETWEEN COMPETENT BEDROCK AND THE REGOLITH. 5. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NCDOT GEOGRAPHIC INFORMATION SYSTEM (GIS) WEB SITE. 6. ORTHOPHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 7. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L .0107 (a). 8. PROPOSED WELL LOCATIONS ARE APPROXIMATE AND MAY BE ADJUSTED DUE TO FIELD CONDITIONS. 9. SEEP SAMPLING LOCATIONS WERE OBTAINED BY HDR USING A TRIMBLE HANDHELD GPS UNIT ON APRIL 29, 2014. * INDICATES SEEP SAMPLING LOCATIONS WERE NOT RECORDED WITH GPS UNIT AND ARE APPROXIMATE. n { f r { .. i a. • a i 4 ox • �� !' tt�' fiJ ' ?r4 ro I i' L►fi�.r..�t- JriL a..r,�s _w•_. r � .._"+�.a,` •aYYa.. .... _ ,. �«., '� .tar . , SCALE (FEET) 150, 0 /50, 300, l" - 300, r 'yr J t +r P . ,rr u..x...,� 4 •� �.x��' k W' A.� �.¢B ''f �.®& �,. {y. f�u�.�s' n F r a r t `4 F .A` y "t 4. 4 f a � tiWfl r i 44 r, a Tn fi"yGGG� 4• '�v Syy LEGEND: ® DUKE ENERGY PROPERTY BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH OR CINDER STORAGE AREA BOUNDARY STREAM TOPOGRAPHIC CONTOUR (4 FOOT) A��v.� 'te, `_ y Y wy � � � . TRANSECT LINE EXISTING ASH BASIN VOLUNTARY GROUNDWATER MONITORING WELL r +r 9 f' K k ;. . 4*� Y i '� kK � `>y '`' .4 �#. EXISTING ASH BASIN COMPLIANCE GROUNDWATER � 1i4+ 9 MONITORING WELL GWAP GROUNDWATER MONITORING WELL LOCATION OBSERVATION WELL LOCATION PROPOSED ADDITIONAL GROUNDWATER MONITORING WELL LOCATION SEEP SAMPLE LOCATION SURFACE WATER SAMPLE LOCATION MAJOR FLOW TRANSECTS DUKE ENERGY CAROLINAS, LLC RIVERBEND STEAM STATION GASTON COUNTY, NORTH CAROB NA DATE FIGURE HU M A N H E A L T H CO N C E P T U A L S I T E M O D E L DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N GA S T O N C O U N T Y , N O R T H C A R O L I N A $8*867, 2015 12-1DATEFIGURE SO U R C E PR I M A R Y RE L E A S E ME C H A N I S M PR I M A R Y AF F E C T E D ME D I A EX P O S U R E RO U T E PRIMARY RECEPTOR Co a l A s h Ba s i n In f i l t r a t i o n Sp r i n g s / S e e p s Pr e c i p i t a t i o n & D i s s o l u t i o n Su b s u r f a c e S o i l Gr o u n d w a t e r Construction Worker Outdoor Worker Off-site Resident Trespasser Su r f a c e S o i l In c i d e n t a l I n g e s t i o n De r m a l Pa r t i c u l a t e I n h a l a t i o n In c i d e n t a l / P o t a b l e I n g e s t i o n De r m a l In h a l a t i o n In c i d e n t a l I n g e s t i o n De r m a l In c i d e n t a l I n g e s t i o n De r m a l In h a l a t i o n Se d i m e n t Su r f a c e W a t e r NP D E S Di s c h a r g e In c i d e n t a l I n g e s t i o n De r m a l No t e : Ex p o s u r e p a t h w a y s a r e b a s e d o n t h e c u r r e n t u n d e r s t a n d i n g o f t h e S i t e a n d a r e s u b j e c t t o c h a n g e . Po t e n t i a l l y C o m p l e t e E x p o s u r e P a t h w a y In c o m p l e t e o r I n s i g n i f i c a n t P a t h w a y Le g e n d : EC O L O G I C A L AUGUST 3, 2015 12-2DATEFIGURE CO N C E P T U A L S I T E M O D E L DU K E E N E R G Y C A R O L I N A S , L L C RI V E R B E N D S T E A M S T A T I O N GA S T O N C O U N T Y , N O R T H C A R O L I N A SO U R C E EX P O S U R E ME D I A PR I M A R Y RE L E A S E ME C H A N I S M PR I M A R Y AF F E C T E D ME D I A EX P O S U R E RO U T E PRIMARY RECEPTOR Aquatic/Riparian T e r r e s t r i a l Co a l A s h Ba s i n In f i l t r a t i o n Sp r i n g s / S e e p s Pr e c i p i t a t i o n & D i s s o l u t i o n So i l (U p l a n d a n d R i p a r i a n ) Gr o u n d w a t e r Po t e n t i a l l y C o m p l e t e E x p o s u r e P a t h w a y In c o m p l e t e o r I n s i g n i f i c a n t P a t h w a y A q u a t i c B i o t a Sediment Infauna Aquatic/Riparian Plants Piscivorous Wildlife Herbivorous Wildlife Omnivorous Wildlife Terrestrial Plants Terrestrial Invertebrates Herbivorous Wildlife Omnivorous Wildlife Carnivorous Wildlife Ex p o s u r e p a t h w a y s a r e b a s e d o n t h e c u r r e n t u n d e r s t a n d i n g o f t h e S i t e a n d a r e s u b j e c t t o c h a n g e . So i l In c i d e n t a l I n g e s t i o n De r m a l o r R o o t A b s o r p t i o n Te r r e s t r i a l In v e r t e b r a t e s In g e s t i o n Sm a l l M a m m a l s an d B i r d s In g e s t i o n Be n t h i c a n d Aq u a t i c I n v e r t e b r a t e s In g e s t i o n Se d i m e n t In c i d e n t a l I n g e s t i o n De r m a l o r R o o t A b s o r p t i o n Fi s h In g e s t i o n Su r f a c e W a t e r Se d i m e n t Su r f a c e W a t e r In g e s t i o n o r G i l l U p t a k e De r m a l o r R o o t A b s o r p t i o n Aq u a t i c / R i p a r i a n Pl a n t s In g e s t i o n Ve g e t a t i o n In g e s t i o n Le g e n d : No t e : NP D E S Di s c h a r g e