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HomeMy WebLinkAboutNC0000396_J15060543 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15060543 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4640 09: 8:3 61) Report Authorized By: -� 2015.07.0 42 09:58:37 (Signature) RGY> _04'00' Date: Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/2/2015 1 of 86 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 86 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015019563 ASHEVILLE 11 -Jun -15 9:00 AM illegible MW -19(2-3) 2015019564 ASHEVILLE 11 -Jun -15 10:45 AM illegible MW -19(5-6) 2015019565 ASHEVILLE 12 -Jun -15 10:20 AM illegible MW -20S(2-3) 2015019566 ASHEVILLE 12 -Jun -15 10:25 AM illegible MW -20S(5-6) 2015019567 ASHEVILLE 14 -Jun -15 2:30 PM illegible MW-23BR(2-3) 2015019568 ASHEVILLE 14 -Jun -15 4:40 PM illegible MW-23BR(6-7) 2015019574 ASHEVILLE 11 -Jun -15 8:50 AM illegible Equipment Blank 2015019576 ASHEVILLE 12 -Jun -15 10:15 AM illegible Equipment Blank 2015019577 ASHEVILLE 14 -Jun -15 2:25 PM illegible Equipment Blank 9 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 3 of 86 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/2/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW -19(2-3) Collection Date: 11 -Jun -15 9:00 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 86 Sample #: 2015019563 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW -19(5-6) Collection Date: 11 -Jun -15 10:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 86 Sample #: 2015019564 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW -20S(2-3) Collection Date: 12 -Jun -15 10:20 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 86 Sample #: 2015019565 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW -20S(5-6) Collection Date: 12 -Jun -15 10:25 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 86 Sample #: 2015019566 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW-23BR(2-3) Collection Date: 14 -Jun -15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 86 Sample #: 2015019567 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: MW-23BR(6-7) Collection Date: 14 -Jun -15 4:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 9 of 86 Sample #: 2015019568 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis 10 of 86 This report shall not be reproduced, except in full. Order # J15060543 Site: Equipment Blank Collection Date: 11 -Jun -15 8:50 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015019574 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060543 Site: Equipment Blank Collection Date: 12 -Jun -15 10:15 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015019576 Matrix: SOIL 11 of 86 Method Analysis Date/Time Analyst Vendor Method V_PACE Site: Equipment Blank Collection Date: 14 -Jun -15 2:25 PM Certificate of Laboratory Analysis 12 of 86 This report shall not be reproduced, except in full. Order # J15060543 Sample #: 2015019577 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE -- Additional Information -- -PLP sulfate blank is 2.4 mg/L. Final report RL for the samples at or above this number. Data is acceptable. MG -K 7/2/2015 aceAnaiXical www.pacelabs.com July 01, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 )ig,8y fte. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 73 lacmnalyfica( www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Drinking Water Certification #: 37712 Florida/NELAP Certification #: E87648 North Carolina Wastewater Certification #: 40 Massachusetts Certification #: M-NC030 South Carolina Certification #: 99030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 73 aceAnaiXical www.pacelabs.com CERTIFICATIONS Project: J15060543 Pace Project No.: 92254832 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 73 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15060543 Pace Project No.: 92254832 Lab ID Sample ID Matrix Date Collected Date Received 92254832001 2015019563 Solid 06/11/15 09:00 06/17/15 14:35 92254832002 2015019565 Solid 06/12/1510:20 06/17/1514:35 92254832003 2015019567 Solid 06/14/1514:30 06/17/1514:35 92254832004 2015019564 Solid 06/11/1510:45 06/17/1514:35 92254832005 2015019566 Solid 06/12/1510:25 06/17/1514:35 92254832006 2015019568 Solid 06/14/1516:40 06/17/1514:35 92254832007 2015019574 Water 06/11/15 08:50 06/17/15 14:35 92254832008 2015019576 Water 06/12/1510:15 06/17/1514:35 92254832009 2015019577 Water 06/14/1514:25 06/17/1514:35 92254832010 2015019563 SPLP Water 06/11/15 09:00 06/17/15 14:35 92254832011 2015019565 SPLP Water 06/12/15 10:20 06/17/15 14:35 92254832012 2015019567 SPLP Water 06/14/15 14:30 06/17/15 14:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 73 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92254832001 2015019563 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832002 2015019565 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832003 2015019567 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832004 2015019564 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 73 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832005 2015019566 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832006 2015019568 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92254832007 2015019574 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92254832008 2015019576 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92254832009 2015019577 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92254832010 2015019563 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M 92254832011 2015019565 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M 92254832012 2015019567 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli %yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92254832001 2015019563 EPA 6010 Aluminum 12600 mg/kg 34.7 06/24/15 09:32 M1 EPA 6010 Barium 44.0 mg/kg 3.5 06/24/15 09:32 M1 EPA 6010 Beryllium 0.75 mg/kg 0.35 06/24/15 09:32 EPA 6010 Calcium 328 mg/kg 173 06/24/15 09:32 EPA 6010 Chromium 10.1 mg/kg 1.7 06/24/15 09:32 EPA 6010 Copper 4.6 mg/kg 1.7 06/24/15 09:32 EPA 6010 Iron 11700 mg/kg 13.9 06/24/15 09:32 M1 EPA 6010 Magnesium 2460 mg/kg 173 06/24/15 09:32 EPA 6010 Manganese 114 mg/kg 1.7 06/24/15 09:32 M1 EPA 6010 Nickel 6.5 mg/kg 1.7 06/24/15 09:32 EPA 6010 Potassium 1060 mg/kg 347 06/24/15 09:32 EPA 6010 Strontium 5.7 mg/kg 3.5 06/24/15 09:32 EPA 6010 Zinc 36.5 mg/kg 6.9 06/24/15 09:32 EPA 6020 Cobalt 4AJ mg/kg 6.9 06/24/15 13:56 M6 EPA 6020 Lead 4.7J mg/kg 6.9 06/24/15 13:56 M6 EPA 6020 Vanadium 17.9 mg/kg 6.9 06/24/15 13:56 M6 ASTM D2974-87 Percent Moisture 28.2 % 0.10 06/24/15 18:45 EPA 9045 pH at 25 Degrees C 4.8 Std. Units 0.10 06/23/15 15:55 EPA 300.0 Sulfate 22.3 mg/L 2.8 06/25/15 11:53 B EPA 9056 Sulfate 262J mg/kg 348 06/25/15 06:38 D3 EPA 9060 Modified RPD% 1.6 % 0.10 06/27/15 11:41 EPA 9060 Modified Total Organic Carbon 2560 mg/kg 839 06/27/15 11:41 EPA 9060 Modified Total Organic Carbon 2520 mg/kg 840 06/27/15 11:48 EPA 9060 Modified Mean Total Organic Carbon 2540 mg/kg 840 06/27/15 11:41 92254832002 2015019565 EPA 6010 Aluminum 6020 mg/kg 37.7 06/24/15 09:57 EPA 6010 Barium 35.5 mg/kg 3.8 06/24/15 09:57 EPA 6010 Beryllium 0.41 mg/kg 0.38 06/24/15 09:57 EPA 6010 Calcium 178J mg/kg 189 06/24/15 09:57 EPA 6010 Chromium 5.8 mg/kg 1.9 06/24/15 09:57 EPA 6010 Copper 3.0 mg/kg 1.9 06/24/15 09:57 EPA 6010 Iron 5910 mg/kg 15.1 06/24/15 09:57 EPA 6010 Magnesium 1530 mg/kg 189 06/24/15 09:57 EPA 6010 Manganese 70.7 mg/kg 1.9 06/24/15 09:57 EPA 6010 Nickel 3.9 mg/kg 1.9 06/24/15 09:57 EPA 6010 Potassium 795 mg/kg 377 06/24/15 09:57 EPA 6010 Strontium 3.1 J mg/kg 3.8 06/24/15 09:57 EPA 6010 Zinc 24.0 mg/kg 7.5 06/24/15 09:57 EPA 6020 Cobalt 7.3J mg/kg 7.5 06/24/15 14:44 EPA 6020 Vanadium 11.5 mg/kg 7.5 06/24/15 14:44 EPA 7471 Mercury 0.0065J mg/kg 0.012 06/24/15 17:38 ASTM D2974-87 Percent Moisture 34.2 % 0.10 06/24/15 18:45 EPA 9045 pH at 25 Degrees C 4.1 Std. Units 0.10 06/23/15 15:55 EPA 300.0 Sulfate 17.8 mg/L 3.0 06/25/15 12:07 B EPA 9056 Sulfate 366J mg/kg 379 06/25/15 07:44 D3 EPA 9060 Modified RPD% 20.4 % 0.10 06/27/15 12:28 EPA 9060 Modified Total Organic Carbon 4250 mg/kg 907 06/27/15 12:28 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 7 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 KPi %Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92254832002 2015019565 EPA 9060 Modified Total Organic Carbon 3470 mg/kg 912 06/27/15 12:34 EPA 9060 Modified Mean Total Organic Carbon 3860 mg/kg 909 06/27/15 12:28 92254832003 2015019567 EPA 6010 Aluminum 13900 mg/kg 31.3 06/24/15 10:13 EPA 6010 Barium 60.5 mg/kg 3.1 06/24/15 10:13 EPA 6010 Beryllium 0.62 mg/kg 0.31 06/24/15 10:13 EPA 6010 Calcium 218 mg/kg 157 06/24/15 10:13 EPA 6010 Chromium 17.8 mg/kg 1.6 06/24/15 10:13 EPA 6010 Copper 8.3 mg/kg 1.6 06/24/15 10:13 EPA 6010 Iron 20800 mg/kg 12.5 06/24/15 10:13 EPA 6010 Magnesium 1720 mg/kg 157 06/24/15 10:13 EPA 6010 Manganese 70.4 mg/kg 1.6 06/24/15 10:13 EPA 6010 Nickel 4.9 mg/kg 1.6 06/24/15 10:13 EPA 6010 Potassium 1070 mg/kg 313 06/24/15 10:13 EPA 6010 Strontium 3.5 mg/kg 3.1 06/24/15 10:13 EPA 6010 Zinc 31.0 mg/kg 6.3 06/24/15 10:13 EPA 6020 Cobalt 4.1 J mg/kg 6.3 06/24/15 14:50 EPA 6020 Lead 10 mg/kg 6.3 06/24/15 14:50 EPA 6020 Vanadium 26.9 mg/kg 6.3 06/24/15 14:50 EPA 7471 Mercury 0.039 mg/kg 0.0098 06/24/15 17:42 ASTM D2974-87 Percent Moisture 18.0 % 0.10 06/24/15 18:45 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 06/23/15 15:55 EPA 300.0 Sulfate 5.5 mg/L 2.4 06/25/15 12:48 B EPA 9060 Modified RPD% 5.7 % 0.10 06/27/15 12:40 EPA 9060 Modified Total Organic Carbon 3600 mg/kg 725 06/27/15 12:40 EPA 9060 Modified Total Organic Carbon 3400 mg/kg 731 06/27/15 12:47 EPA 9060 Modified Mean Total Organic Carbon 3500 mg/kg 728 06/27/15 12:40 92254832004 2015019564 EPA 6010 Aluminum 11000 mg/kg 33.2 06/24/15 10:17 EPA 6010 Barium 72.9 mg/kg 3.3 06/24/15 10:17 EPA 6010 Beryllium 0.74 mg/kg 0.33 06/24/15 10:17 EPA 6010 Calcium 705 mg/kg 166 06/24/15 10:17 EPA 6010 Chromium 11.6 mg/kg 1.7 06/24/15 10:17 EPA 6010 Copper 8.1 mg/kg 1.7 06/24/15 10:17 EPA 6010 Iron 16100 mg/kg 13.3 06/24/15 10:17 EPA 6010 Magnesium 3040 mg/kg 166 06/24/15 10:17 EPA 6010 Manganese 159 mg/kg 1.7 06/24/15 10:17 EPA 6010 Nickel 6.3 mg/kg 1.7 06/24/15 10:17 EPA 6010 Potassium 3430 mg/kg 332 06/24/15 10:17 EPA 6010 Strontium 4.8 mg/kg 3.3 06/24/15 10:17 EPA 6010 Zinc 34.6 mg/kg 6.6 06/24/15 10:17 EPA 6020 Cobalt 11.6 mg/kg 6.6 06/24/15 15:28 EPA 6020 Lead 4AJ mg/kg 6.6 06/24/15 15:28 EPA 6020 Vanadium 17.6 mg/kg 6.6 06/24/15 15:28 EPA 7471 Mercury 0.0057J mg/kg 0.010 06/24/15 17:44 ASTM D2974-87 Percent Moisture 23.6 % 0.10 06/24/15 18:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 �n%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92254832004 2015019564 EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 06/22/15 15:35 EPA 9056 Sulfate 184J mg/kg 322 06/25/15 08:29 EPA 9060 Modified RPD% 6.5 % 0.10 06/27/15 13:29 EPA 9060 Modified Total Organic Carbon 2420 mg/kg 784 06/27/15 13:29 EPA 9060 Modified Total Organic Carbon 2270 mg/kg 778 06/27/15 13:34 EPA 9060 Modified Mean Total Organic Carbon 2350 mg/kg 781 06/27/15 13:29 92254832005 2015019566 EPA 6010 Aluminum 57900 mg/kg 382 06/24/15 10:21 EPA 6010 Barium 179 mg/kg 38.2 06/24/15 10:21 EPA 6010 Beryllium 6.1 mg/kg 3.8 06/24/15 10:21 EPA 6010 Calcium 8530 mg/kg 1910 06/24/15 10:21 EPA 6010 Chromium 93.5 mg/kg 19.1 06/24/15 10:21 EPA 6010 Copper 35.5 mg/kg 19.1 06/24/15 10:21 EPA 6010 Iron 24400 mg/kg 153 06/24/15 10:21 EPA 6010 Magnesium 8290 mg/kg 1910 06/24/15 10:21 EPA 6010 Manganese 1530 mg/kg 19.1 06/24/15 10:21 EPA 6010 Nickel 32.7 mg/kg 19.1 06/24/15 10:21 EPA 6010 Potassium 3790J mg/kg 3820 06/24/15 10:21 EPA 6010 Strontium 62.7 mg/kg 38.2 06/24/15 10:21 EPA 6010 Zinc 87.1 mg/kg 76.3 06/24/15 10:21 EPA 6020 Vanadium 9.2 mg/kg 7.6 06/24/15 15:31 EPA 7471 Mercury 0.0067J mg/kg 0.012 06/24/15 17:46 ASTM D2974-87 Percent Moisture 33.8 % 0.10 06/24/15 18:45 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 06/22/15 15:35 EPA 9056 Sulfate 203J mg/kg 371 06/25/15 08:51 EPA 9060 Modified RPD% 27.8 % 0.10 06/27/15 13:39 EPA 9060 Modified Total Organic Carbon 40000 mg/kg 6370 06/27/15 13:39 EPA 9060 Modified Total Organic Carbon 30200 mg/kg 6230 06/27/15 13:45 EPA 9060 Modified Mean Total Organic Carbon 35100 mg/kg 6300 06/27/15 13:39 92254832006 2015019568 EPA 6010 Aluminum 11000 mg/kg 28.2 06/24/15 10:25 EPA 6010 Barium 51.5 mg/kg 2.8 06/24/15 10:25 EPA 6010 Beryllium 0.95 mg/kg 0.28 06/24/15 10:25 EPA 6010 Calcium 89AJ mg/kg 141 06/24/15 10:25 EPA 6010 Chromium 11.3 mg/kg 1.4 06/24/15 10:25 EPA 6010 Copper 9.2 mg/kg 1.4 06/24/15 10:25 EPA 6010 Iron 18300 mg/kg 11.3 06/24/15 10:25 EPA 6010 Magnesium 1480 mg/kg 141 06/24/15 10:25 EPA 6010 Manganese 67.8 mg/kg 1.4 06/24/15 10:25 EPA 6010 Nickel 4.8 mg/kg 1.4 06/24/15 10:25 EPA 6010 Potassium 1320 mg/kg 282 06/24/15 10:25 EPA 6010 Strontium 1.91 mg/kg 2.8 06/24/15 10:25 EPA 6010 Zinc 19.6 mg/kg 5.6 06/24/15 10:25 EPA 6020 Lead 5.2J mg/kg 5.6 06/24/15 15:35 EPA 6020 Vanadium 12.9 mg/kg 5.6 06/24/15 15:35 EPA 7471 Mercury 0.015 mg/kg 0.0094 06/24/15 17:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 Page 9 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 K2'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92254832006 2015019568 ASTM D2974-87 Percent Moisture 13.7 % 0.10 06/24/15 18:45 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 06/22/15 15:35 EPA 9060 Modified RPD% 16.5 % 0.10 06/27/15 13:51 EPA 9060 Modified Total Organic Carbon 541J mg/kg 691 06/27/15 13:51 EPA 9060 Modified Total Organic Carbon 458J mg/kg 698 06/27/15 13:57 EPA 9060 Modified Mean Total Organic Carbon 5001 mg/kg 694 06/27/15 13:51 92254832007 2015019574 EPA 6020A Aluminum 132 ug/L 10.0 06/26/1511:50 M1 EPA 6020A Barium 0.60 ug/L 0.30 06/26/15 11:50 EPA 6020A Calcium 34.3J ug/L 40.0 06/26/15 11:50 EPA 6020A Chromium 0.31J ug/L 0.50 06/26/1511:50 EPA 6020A Copper 0.26J ug/L 1.0 06/26/15 11:50 EPA 6020A Iron 296 ug/L 50.0 06/26/15 11:50 EPA 6020A Lead 0.42 ug/L 0.10 06/26/15 11:50 EPA 6020A Magnesium 13.5 ug/L 10.0 06/26/15 11:50 EPA 6020A Manganese 3.3 ug/L 0.50 06/26/15 11:50 EPA 6020A Nickel 0.46J ug/L 0.50 06/26/15 11:50 EPA 6020A Potassium 24.7J ug/L 50.0 06/26/15 11:50 EPA 6020A Vanadium 0.36J ug/L 1.0 06/27/15 09:13 EPA 6020A Zinc 16.9 ug/L 5.0 06/26/15 11:50 92254832008 2015019576 EPA 6020A Aluminum 2380 ug/L 10.0 06/26/15 12:13 EPA 6020A Antimony 0.50 ug/L 0.50 06/26/15 12:13 EPA 6020A Arsenic 6.4 ug/L 0.50 06/26/15 12:13 EPA 6020A Barium 91.9 ug/L 0.30 06/26/15 12:13 EPA 6020A Beryllium 0.90 ug/L 0.20 06/26/15 12:13 EPA 6020A Boron 2.6J ug/L 5.0 06/26/15 12:13 EPA 6020A Cadmium 0.026J ug/L 0.080 06/26/15 12:13 EPA 6020A Calcium 1170 ug/L 40.0 06/26/15 12:13 EPA 6020A Chromium 2.3 ug/L 0.50 06/26/15 12:13 EPA 6020A Cobalt 1.6 ug/L 0.50 06/26/15 12:13 EPA 6020A Copper 6.2 ug/L 1.0 06/26/15 12:13 EPA 6020A Iron 1710 ug/L 50.0 06/26/15 12:13 EPA 6020A Lead 3.2 ug/L 0.10 06/26/15 12:13 EPA 6020A Magnesium 250 ug/L 10.0 06/26/15 12:13 EPA 6020A Manganese 30.4 ug/L 0.50 06/26/15 12:13 EPA 6020A Molybdenum 0.21J ug/L 0.50 06/26/1512:13 EPA 6020A Nickel 3.3 ug/L 0.50 06/26/15 12:13 EPA 6020A Potassium 365 ug/L 50.0 06/26/15 12:13 EPA 6020A Selenium 0.73 ug/L 0.50 06/26/15 12:13 EPA 6020A Sodium 500 ug/L 50.0 06/26/15 12:13 EPA 6020A Strontium 47.1 ug/L 0.50 06/26/15 12:13 EPA 6020A Thallium 0.14 ug/L 0.10 06/26/15 12:13 EPA 6020A Vanadium 9.5 ug/L 1.0 06/27/15 09:38 EPA 6020A Zinc 4AJ ug/L 5.0 06/26/15 12:13 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 10 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 KPiS%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92254832009 2015019577 EPA 6020A Aluminum 15900 ug/L 10.0 06/26/15 12:32 EPA 6020A Antimony 0.22J ug/L 0.50 06/26/15 12:32 EPA 6020A Arsenic 3.2 ug/L 0.50 06/26/15 12:32 EPA 6020A Barium 152 ug/L 0.30 06/26/15 12:32 EPA 6020A Beryllium 0.70 ug/L 0.20 06/26/15 12:32 EPA 6020A Boron 5.4 ug/L 5.0 06/26/15 12:32 EPA 6020A Cadmium 0.46 ug/L 0.080 06/26/15 12:32 EPA 6020A Calcium 1860 ug/L 40.0 06/26/15 12:32 EPA 6020A Chromium 30.8 ug/L 0.50 06/26/15 12:32 EPA 6020A Cobalt 41.1 ug/L 0.50 06/26/15 12:32 EPA 6020A Copper 18.3 ug/L 1.0 06/26/15 12:32 EPA 6020A Iron 19900 ug/L 50.0 06/26/15 12:32 EPA 6020A Lead 11.5 ug/L 0.10 06/26/15 12:32 EPA 6020A Magnesium 3320 ug/L 10.0 06/26/15 12:32 EPA 6020A Manganese 436 ug/L 0.50 06/26/15 12:32 EPA 6020A Molybdenum 3.0 ug/L 0.50 06/26/15 12:32 EPA 6020A Nickel 14.1 ug/L 0.50 06/26/15 12:32 EPA 6020A Potassium 3970 ug/L 50.0 06/26/15 12:32 EPA 6020A Selenium 3.3 ug/L 0.50 06/26/15 12:32 EPA 6020A Sodium 2580 ug/L 50.0 06/26/15 12:32 EPA 6020A Strontium 11.6 ug/L 0.50 06/26/15 12:32 EPA 6020A Thallium 0.30 ug/L 0.10 06/26/15 12:32 EPA 6020A Vanadium 24.7 ug/L 1.0 06/27/15 09:42 EPA 6020A Zinc 202 ug/L 5.0 06/26/15 12:32 EPA 7470A Mercury 0.040J ug/L 0.20 06/21/15 21:13 92254832010 2015019563 SPLP EPA 6020A Aluminum 662 ug/L 10.0 06/28/15 12:18 EPA 6020A Antimony 0.18J ug/L 0.50 06/28/15 12:18 EPA 6020A Arsenic 0.38J ug/L 0.50 06/28/15 12:18 EPA 6020A Barium 254 ug/L 0.30 06/28/15 12:18 EPA 6020A Beryllium 1.4 ug/L 0.20 06/28/15 12:18 EPA 6020A Boron 103 ug/L 5.0 06/28/15 12:18 EPA 6020A Cadmium 0.38 ug/L 0.080 06/28/15 12:18 EPA 6020A Calcium 2590 ug/L 40.0 06/28/15 12:18 EPA 6020A Chromium 4.0 ug/L 0.50 06/28/15 12:18 EPA 6020A Cobalt 2.6 ug/L 0.50 06/28/15 12:18 EPA 6020A Copper 2.0 ug/L 1.0 06/28/15 12:18 EPA 6020A Iron 51.5 ug/L 50.0 06/28/15 12:18 EPA 6020A Lead 0.76 ug/L 0.10 06/28/15 12:18 EPA 6020A Magnesium 210 ug/L 10.0 06/28/15 12:18 EPA 6020A Manganese 389 ug/L 0.50 06/28/15 12:18 EPA 6020A Molybdenum 0.56 ug/L 0.50 06/28/15 12:18 EPA 6020A Nickel 5.5 ug/L 0.50 06/28/15 12:18 EPA 6020A Potassium 1490 ug/L 50.0 06/28/15 12:18 EPA 6020A Selenium 0.54 ug/L 0.50 06/28/15 12:18 EPA 6020A Sodium 1880 ug/L 50.0 06/28/15 12:18 EPA 6020A Strontium 54.7 ug/L 0.50 06/28/15 12:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 11 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 K4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92254832010 2015019563 SPLP EPA 6020A Thallium 0.23 ug/L 0.10 06/28/15 12:18 EPA 6020A Vanadium 0.47J ug/L 1.0 06/28/15 12:18 EPA 6020A Zinc 190 ug/L 5.0 06/28/15 12:18 92254832011 2015019565 SPLP EPA 6020A Aluminum 313 ug/L 10.0 06/28/15 12:21 EPA 6020A Arsenic 0.24J ug/L 0.50 06/28/15 12:21 EPA 6020A Barium 342 ug/L 0.30 06/28/15 12:21 EPA 6020A Beryllium 0.91 ug/L 0.20 06/28/15 12:21 EPA 6020A Boron 98.5 ug/L 5.0 06/28/15 12:21 EPA 6020A Cadmium 0.53 ug/L 0.080 06/28/15 12:21 EPA 6020A Calcium 2400 ug/L 40.0 06/28/15 12:21 EPA 6020A Chromium 1.4 ug/L 0.50 06/28/15 12:21 EPA 6020A Cobalt 11.9 ug/L 0.50 06/28/15 12:21 EPA 6020A Copper 3.3 ug/L 1.0 06/28/15 12:21 EPA 6020A Iron 15.3J ug/L 50.0 06/28/15 12:21 EPA 6020A Lead 0.39 ug/L 0.10 06/28/15 12:21 EPA 6020A Magnesium 301 ug/L 10.0 06/28/15 12:21 EPA 6020A Manganese 206 ug/L 0.50 06/28/15 12:21 EPA 6020A Molybdenum 0.31J ug/L 0.50 06/28/1512:21 EPA 6020A Nickel 4.1 ug/L 0.50 06/28/15 12:21 EPA 6020A Potassium 543 ug/L 50.0 06/28/15 12:21 EPA 6020A Selenium 1.4 ug/L 0.50 06/28/15 12:21 EPA 6020A Sodium 1950 ug/L 50.0 06/28/15 12:21 EPA 6020A Strontium 68.9 ug/L 0.50 06/28/15 12:21 EPA 6020A Thallium 0.11 ug/L 0.10 06/28/15 12:21 EPA 6020A Vanadium 0.39J ug/L 1.0 06/28/15 12:21 EPA 6020A Zinc 147 ug/L 5.0 06/28/15 12:21 92254832012 2015019567 SPLP EPA 6020A Aluminum 44.4 ug/L 10.0 06/28/15 12:42 EPA 6020A Arsenic 0.14J ug/L 0.50 06/28/15 12:42 EPA 6020A Barium 139 ug/L 0.30 06/28/15 12:42 EPA 6020A Beryllium 0.11J ug/L 0.20 06/28/1512:42 EPA 6020A Boron 88.4 ug/L 5.0 06/28/15 12:42 EPA 6020A Cadmium 0.10 ug/L 0.080 06/28/15 12:42 EPA 6020A Calcium 442 ug/L 40.0 06/28/15 12:42 EPA 6020A Chromium 1.7 ug/L 0.50 06/28/15 12:42 EPA 6020A Cobalt 0.89 ug/L 0.50 06/28/15 12:42 EPA 6020A Copper 0.86J ug/L 1.0 06/28/15 12:42 EPA 6020A Iron 17.3J ug/L 50.0 06/28/15 12:42 EPA 6020A Lead 0.12 ug/L 0.10 06/28/15 12:42 EPA 6020A Magnesium 228 ug/L 10.0 06/28/15 12:42 EPA 6020A Manganese 24.0 ug/L 0.50 06/28/15 12:42 EPA 6020A Molybdenum 0.27J ug/L 0.50 06/28/15 12:42 EPA 6020A Nickel 1.1 ug/L 0.50 06/28/15 12:42 B EPA 6020A Potassium 316 ug/L 50.0 06/28/15 12:42 EPA 6020A Sodium 2280 ug/L 50.0 06/28/15 12:42 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 Lab Sample ID Client Sample ID Method Parameters 92254832012 2015019567 SPLP EPA 6020A Strontium EPA 6020A Thallium EPA 6020A Zinc SUMMARY OF DETECTION Result UnitE 6.2 ug/L 0.0951 ug/L 88.8 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 KPi %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Report Limit Analyzed Qualifiers 0.50 06/28/1512:42 0.10 06/28/1512:42 5.0 06/28/1512:42 Page 13 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 Kai %fft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24868 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254832001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1250113) • Aluminum • Iron • MSD (Lab ID: 1250114) • Aluminum • Barium • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15162 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24869 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254832001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1250117) • Vanadium • MSD (Lab ID: 1250118) • Antimony • Arsenic • Cobalt • Lead • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 01, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10077 Analyte Comments: QC Batch: MPRP/24869 N2: The lab does not hold TNI accreditation for this parameter. •2015019563 (Lab ID:92254832001) • Antimony •2015019564 (Lab ID:92254832004) • Antimony •2015019565 (Lab ID:92254832002) • Antimony •2015019566 (Lab ID:92254832005) • Antimony •2015019567 (Lab ID:92254832003) • Antimony •2015019568 (Lab ID:92254832006) • Antimony • BLANK (Lab ID: 1250115) • Antimony • LCS (Lab ID: 1250116) • Antimony • MS (Lab ID: 1250117) • Antimony • MSD (Lab ID: 1250118) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 Kai %Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: MPRP/55611 B: Analyte was detected in the associated method blank. • BLANK for HBN 363185 [MPRP/556 (Lab ID: 2008101) • Nickel Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55423 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254832007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 2002625) • Aluminum • MSD (Lab ID: 2002626) • Aluminum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 01, 2015 QC Batch: MPRP/55611 Pace Analytical Services, Inc. 9800 Kai %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254516016,92254629019 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 2008488) • Aluminum • MS (Lab ID: 2008490) • Aluminum • Calcium • Strontium • MSD (Lab ID: 2008489) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 �n%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 t Q'igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/38288 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1490817) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 �4c8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23465 B: Analyte was detected in the associated method blank. • BLANK for HBN 269766 [WETA/234 (Lab ID: 1494036) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 Kai %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 Kai %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47613 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015019563 (Lab ID:92254832001) • Chloride • Sulfate •2015019564 (Lab ID:92254832004) • Chloride • Sulfate •2015019565 (Lab ID:92254832002) • Chloride • Sulfate •2015019566 (Lab ID:92254832005) • Chloride • Sulfate •2015019567 (Lab ID:92254832003) • Chloride • Sulfate •2015019568 (Lab ID:92254832006) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kai %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 01, 2015 Analyte Comments: QC Batch: WETA/47613 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015019568 (Lab ID: 92254832006) • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 Kai %Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015019563 (Lab ID:92254832001) •2015019564 (Lab ID:92254832004) •2015019565 (Lab ID:92254832002) •2015019566 (Lab ID:92254832005) •2015019567 (Lab ID:92254832003) •2015019568 (Lab ID:92254832006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060543 Pace Project No.: 92254832 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: July 01, 2015 Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 6 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 1inic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019563 Lab ID: 92254832001 Collected: 06/11/15 09:00 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/01/2015 04:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12600 mg/kg 34.7 17.3 5 06/23/15 17:15 06/24/15 09:32 7429-90-5 M1 44.0 mg/kg 3.5 1.7 5 06/23/15 17:15 06/24/15 09:32 7440-39-3 M1 0.75 mg/kg 0.35 0.17 5 06/23/15 17:15 06/24/15 09:32 7440-41-7 ND mg/kg 17.3 8.7 5 06/23/15 17:15 06/24/15 09:32 7440-42-8 328 mg/kg 173 86.6 5 06/23/15 17:15 06/24/15 09:32 7440-70-2 10.1 mg/kg 1.7 0.87 5 06/23/15 17:15 06/24/15 09:32 7440-47-3 4.6 mg/kg 1.7 0.87 5 06/23/15 17:15 06/24/15 09:32 7440-50-8 11700 mg/kg 13.9 6.9 5 06/23/15 17:15 06/24/15 09:32 7439-89-6 M1 2460 mg/kg 173 86.6 5 06/23/15 17:15 06/24/15 09:32 7439-95-4 114 mg/kg 1.7 0.87 5 06/23/15 17:15 06/24/15 09:32 7439-96-5 M1 ND mg/kg 3.5 1.7 5 06/23/15 17:15 06/24/15 09:32 7439-98-7 6.5 mg/kg 1.7 0.87 5 06/23/15 17:15 06/24/15 09:32 7440-02-0 1060 mg/kg 347 173 5 06/23/15 17:15 06/24/15 09:32 7440-09-7 ND mg/kg 347 173 5 06/23/15 17:15 06/24/15 09:32 7440-23-5 5.7 mg/kg 3.5 1.7 5 06/23/15 17:15 06/24/15 09:32 7440-24-6 36.5 mg/kg 6.9 3.5 5 06/23/15 17:15 06/24/15 09:32 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7440-36-0 M6, N2 ND mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7440-38-2 M6 ND mg/kg 0.83 0.42 100 06/23/1517:15 06/24/1513:56 7440-43-9 4AJ mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7440-48-4 M6 4.7J mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7439-92-1 M6 ND mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7782-49-2 ND mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7440-28-0 17.9 mg/kg 6.9 3.5 100 06/23/1517:15 06/24/1513:56 7440-62-2 M6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.011 0.0056 1 06/23/1517:30 06/24/1517:31 7439-97-6 Analytical Method: ASTM D2974-87 28.2 % 0.10 0.10 1 06/24/1518:45 Analytical Method: EPA 9045 4.8 Std. Units 0.10 0.10 1 06/23/15 15:55 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/24/15 02:45 22.3 mg/L 2.8 1.4 1 06/25/1511:53 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 0.28 0.28 1 06/25/15 22:19 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 7.0 3.5 1 06/25/15 02:24 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019563 Lab ID: 92254832001 Collected: 06/11/15 09:00 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 348 174 5 06/25/15 06:38 16887-00-6 D3,M1 Sulfate 262J mg/kg 348 174 5 06/25/15 06:38 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 34.8 17.4 5 06/25/15 06:38 14797-55-8 H3 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 1.6 % 0.10 0.10 1 06/27/1511:41 Total Organic Carbon 2560 mg/kg 839 419 1 06/27/15 11:41 7440-44-0 Total Organic Carbon 2520 mg/kg 840 420 1 06/27/15 11:48 7440-44-0 Mean Total Organic Carbon 2540 mg/kg 840 420 1 06/27/15 11:41 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019565 Lab ID: 92254832002 Collected: 06/12/15 10:20 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/01/2015 04:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6020 mg/kg 37.7 18.9 5 06/23/15 17:15 06/24/15 09:57 7429-90-5 35.5 mg/kg 3.8 1.9 5 06/23/15 17:15 06/24/15 09:57 7440-39-3 0.41 mg/kg 0.38 0.19 5 06/23/15 17:15 06/24/15 09:57 7440-41-7 ND mg/kg 18.9 9.4 5 06/23/15 17:15 06/24/15 09:57 7440-42-8 178J mg/kg 189 94.3 5 06/23/15 17:15 06/24/15 09:57 7440-70-2 5.8 mg/kg 1.9 0.94 5 06/23/15 17:15 06/24/15 09:57 7440-47-3 3.0 mg/kg 1.9 0.94 5 06/23/15 17:15 06/24/15 09:57 7440-50-8 5910 mg/kg 15.1 7.5 5 06/23/15 17:15 06/24/15 09:57 7439-89-6 1530 mg/kg 189 94.3 5 06/23/15 17:15 06/24/15 09:57 7439-95-4 70.7 mg/kg 1.9 0.94 5 06/23/15 17:15 06/24/15 09:57 7439-96-5 ND mg/kg 3.8 1.9 5 06/23/15 17:15 06/24/15 09:57 7439-98-7 3.9 mg/kg 1.9 0.94 5 06/23/15 17:15 06/24/15 09:57 7440-02-0 795 mg/kg 377 189 5 06/23/15 17:15 06/24/15 09:57 7440-09-7 ND mg/kg 377 189 5 06/23/15 17:15 06/24/15 09:57 7440-23-5 3.1J mg/kg 3.8 1.9 5 06/23/15 17:15 06/24/15 09:57 7440-24-6 24.0 mg/kg 7.5 3.8 5 06/23/15 17:15 06/24/15 09:57 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7440-36-0 ND mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7440-38-2 ND mg/kg 0.91 0.45 100 06/23/1517:15 06/24/1514:44 7440-43-9 7.3J mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7440-48-4 ND mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7439-92-1 ND mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7782-49-2 ND mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7440-28-0 11.5 mg/kg 7.5 3.8 100 06/23/1517:15 06/24/1514:44 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0065J mg/kg 0.012 0.0059 1 06/23/1517:30 06/24/1517:38 7439-97-6 Analytical Method: ASTM D2974-87 34.2 % 0.10 0.10 1 06/24/1518:45 Analytical Method: EPA 9045 4.1 Std. Units 0.10 0.10 1 06/23/15 15:55 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/24/15 02:45 17.8 mg/L 3.0 1.5 1 06/25/1512:07 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 0.30 0.30 1 06/25/15 22:20 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 7.6 3.8 1 06/25/15 02:25 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019565 Lab ID: 92254832002 Collected: 06/12/15 10:20 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 379 189 5 06/25/15 07:44 16887-00-6 D3 Sulfate 366J mg/kg 379 189 5 06/25/15 07:44 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 37.9 18.9 5 06/25/15 07:44 14797-55-8 H3 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 20.4 % 0.10 0.10 1 06/27/1512:28 Total Organic Carbon 4250 mg/kg 907 453 1 06/27/15 12:28 7440-44-0 Total Organic Carbon 3470 mg/kg 912 456 1 06/27/15 12:34 7440-44-0 Mean Total Organic Carbon 3860 mg/kg 909 455 1 06/27/15 12:28 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019567 Lab ID: 92254832003 Collected: 06/14/15 14:30 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/01/2015 04:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 13900 mg/kg 31.3 15.7 5 06/23/1517:15 06/24/1510:13 7429-90-5 60.5 mg/kg 3.1 1.6 5 06/23/1517:15 06/24/1510:13 7440-39-3 0.62 mg/kg 0.31 0.16 5 06/23/1517:15 06/24/1510:13 7440-41-7 ND mg/kg 15.7 7.8 5 06/23/1517:15 06/24/1510:13 7440-42-8 218 mg/kg 157 78.3 5 06/23/1517:15 06/24/1510:13 7440-70-2 17.8 mg/kg 1.6 0.78 5 06/23/1517:15 06/24/1510:13 7440-47-3 8.3 mg/kg 1.6 0.78 5 06/23/1517:15 06/24/1510:13 7440-50-8 20800 mg/kg 12.5 6.3 5 06/23/1517:15 06/24/1510:13 7439-89-6 1720 mg/kg 157 78.3 5 06/23/1517:15 06/24/1510:13 7439-95-4 70.4 mg/kg 1.6 0.78 5 06/23/1517:15 06/24/1510:13 7439-96-5 ND mg/kg 3.1 1.6 5 06/23/1517:15 06/24/1510:13 7439-98-7 4.9 mg/kg 1.6 0.78 5 06/23/1517:15 06/24/1510:13 7440-02-0 1070 mg/kg 313 157 5 06/23/1517:15 06/24/1510:13 7440-09-7 ND mg/kg 313 157 5 06/23/1517:15 06/24/1510:13 7440-23-5 3.5 mg/kg 3.1 1.6 5 06/23/1517:15 06/24/1510:13 7440-24-6 31.0 mg/kg 6.3 3.1 5 06/23/1517:15 06/24/1510:13 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7440-36-0 ND mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7440-38-2 ND mg/kg 0.75 0.38 100 06/23/1517:15 06/24/1514:50 7440-43-9 4.1J mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7440-48-4 10 mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7439-92-1 ND mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7782-49-2 ND mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7440-28-0 26.9 mg/kg 6.3 3.1 100 06/23/1517:15 06/24/1514:50 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.039 mg/kg 0.0098 0.0049 1 06/23/1517:30 06/24/1517:42 7439-97-6 Analytical Method: ASTM D2974-87 18.0 % 0.10 0.10 1 06/24/1518:45 Analytical Method: EPA 9045 4.7 Std. Units 0.10 0.10 1 06/23/15 15:55 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/24/15 02:45 5.5 mg/L 2.4 1.2 1 06/25/1512:48 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 0.24 0.24 1 06/25/15 22:21 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 06/24/15 02:45 ND mg/L 6.1 3.0 1 06/25/15 02:29 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019567 Lab ID: 92254832003 Collected: 06/14/15 14:30 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 300 150 5 06/25/15 08:07 16887-00-6 D3 Sulfate ND mg/kg 300 150 5 06/25/15 08:07 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.0 15.0 5 06/25/15 08:07 14797-55-8 H3 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 5.7 % 0.10 0.10 1 06/27/1512:40 Total Organic Carbon 3600 mg/kg 725 362 1 06/27/15 12:40 7440-44-0 Total Organic Carbon 3400 mg/kg 731 366 1 06/27/15 12:47 7440-44-0 Mean Total Organic Carbon 3500 mg/kg 728 364 1 06/27/15 12:40 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019564 Lab ID: 92254832004 Collected: 06/11/15 10:45 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11000 mg/kg 33.2 16.6 5 06/23/1517:15 06/24/1510:17 7429-90-5 Barium 72.9 mg/kg 3.3 1.7 5 06/23/1517:15 06/24/1510:17 7440-39-3 Beryllium 0.74 mg/kg 0.33 0.17 5 06/23/1517:15 06/24/1510:17 7440-41-7 Boron ND mg/kg 16.6 8.3 5 06/23/1517:15 06/24/1510:17 7440-42-8 Calcium 705 mg/kg 166 83.0 5 06/23/1517:15 06/24/1510:17 7440-70-2 Chromium 11.6 mg/kg 1.7 0.83 5 06/23/1517:15 06/24/1510:17 7440-47-3 Copper 8.1 mg/kg 1.7 0.83 5 06/23/1517:15 06/24/1510:17 7440-50-8 Iron 16100 mg/kg 13.3 6.6 5 06/23/1517:15 06/24/1510:17 7439-89-6 Magnesium 3040 mg/kg 166 83.0 5 06/23/1517:15 06/24/1510:17 7439-95-4 Manganese 159 mg/kg 1.7 0.83 5 06/23/1517:15 06/24/1510:17 7439-96-5 Molybdenum ND mg/kg 3.3 1.7 5 06/23/1517:15 06/24/1510:17 7439-98-7 Nickel 6.3 mg/kg 1.7 0.83 5 06/23/1517:15 06/24/1510:17 7440-02-0 Potassium 3430 mg/kg 332 166 5 06/23/1517:15 06/24/1510:17 7440-09-7 Sodium ND mg/kg 332 166 5 06/23/1517:15 06/24/1510:17 7440-23-5 Strontium 4.8 mg/kg 3.3 1.7 5 06/23/1517:15 06/24/1510:17 7440-24-6 Zinc 34.6 mg/kg 6.6 3.3 5 06/23/1517:15 06/24/1510:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7440-36-0 N2 Arsenic ND mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7440-38-2 Cadmium ND mg/kg 0.80 0.40 100 06/23/1517:15 06/24/1515:28 7440-43-9 Cobalt 11.6 mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7440-48-4 Lead 4AJ mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7439-92-1 Selenium ND mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7782-49-2 Thallium ND mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7440-28-0 Vanadium 17.6 mg/kg 6.6 3.3 100 06/23/1517:15 06/24/1515:28 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0057J mg/kg 0.010 0.0051 1 06/23/1517:30 06/24/1517:44 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.6 % 0.10 0.10 1 06/24/15 18:45 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 0.10 1 06/22/15 15:35 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 322 161 5 06/25/15 08:29 16887-00-6 D3 Sulfate 184J mg/kg 322 161 5 06/25/15 08:29 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.2 16.1 5 06/25/15 08:29 14797-55-8 H3 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019564 Lab ID: 92254832004 Collected: 06/11/15 10:45 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 6.5 % 0.10 0.10 1 06/27/1513:29 Total Organic Carbon 2420 mg/kg 784 392 1 06/27/15 13:29 7440-44-0 Total Organic Carbon 2270 mg/kg 778 389 1 06/27/15 13:34 7440-44-0 Mean Total Organic Carbon 2350 mg/kg 781 390 1 06/27/15 13:29 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019566 Lab ID: 92254832005 Collected: 06/12/15 10:25 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 57900 mg/kg 382 191 5 06/23/1517:15 06/24/1510:21 7429-90-5 Barium 179 mg/kg 38.2 19.1 5 06/23/1517:15 06/24/1510:21 7440-39-3 Beryllium 6.1 mg/kg 3.8 1.9 5 06/23/1517:15 06/24/1510:21 7440-41-7 Boron ND mg/kg 191 95.4 5 06/23/1517:15 06/24/1510:21 7440-42-8 Calcium 8530 mg/kg 1910 954 5 06/23/1517:15 06/24/1510:21 7440-70-2 Chromium 93.5 mg/kg 19.1 9.5 5 06/23/1517:15 06/24/1510:21 7440-47-3 Copper 35.5 mg/kg 19.1 9.5 5 06/23/1517:15 06/24/1510:21 7440-50-8 Iron 24400 mg/kg 153 76.3 5 06/23/1517:15 06/24/1510:21 7439-89-6 Magnesium 8290 mg/kg 1910 954 5 06/23/1517:15 06/24/1510:21 7439-95-4 Manganese 1530 mg/kg 19.1 9.5 5 06/23/1517:15 06/24/1510:21 7439-96-5 Molybdenum ND mg/kg 38.2 19.1 5 06/23/1517:15 06/24/1510:21 7439-98-7 Nickel 32.7 mg/kg 19.1 9.5 5 06/23/1517:15 06/24/1510:21 7440-02-0 Potassium 3790J mg/kg 3820 1910 5 06/23/1517:15 06/24/1510:21 7440-09-7 Sodium ND mg/kg 3820 1910 5 06/23/1517:15 06/24/1510:21 7440-23-5 Strontium 62.7 mg/kg 38.2 19.1 5 06/23/1517:15 06/24/1510:21 7440-24-6 Zinc 87.1 mg/kg 76.3 38.2 5 06/23/1517:15 06/24/1510:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7440-36-0 N2 Arsenic ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7440-38-2 Cadmium ND mg/kg 0.92 0.46 100 06/23/1517:15 06/24/1515:31 7440-43-9 Cobalt ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7440-48-4 Lead ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7439-92-1 Selenium ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7782-49-2 Thallium ND mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7440-28-0 Vanadium 9.2 mg/kg 7.6 3.8 100 06/23/1517:15 06/24/1515:31 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0067J mg/kg 0.012 0.0061 1 06/23/1517:30 06/24/1517:46 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 33.8 % 0.10 0.10 1 06/24/15 18:45 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 06/22/15 15:35 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 371 185 5 06/25/15 08:51 16887-00-6 D3 Sulfate 203J mg/kg 371 185 5 06/25/15 08:51 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 37.1 18.5 5 06/25/15 08:51 14797-55-8 H3 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 Iji %Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019566 Lab ID: 92254832005 Collected: 06/12/15 10:25 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 27.8 % 0.10 0.10 1 06/27/1513:39 Total Organic Carbon 40000 mg/kg 6370 3180 1 06/27/15 13:39 7440-44-0 Total Organic Carbon 30200 mg/kg 6230 3120 1 06/27/15 13:45 7440-44-0 Mean Total Organic Carbon 35100 mg/kg 6300 3150 1 06/27/15 13:39 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 1jin%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 Sample: 2015019568 Lab ID: 92254832006 Collected: 06/14/15 16:40 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11000 mg/kg 28.2 14.1 5 06/23/1517:15 06/24/1510:25 7429-90-5 Barium 51.5 mg/kg 2.8 1.4 5 06/23/1517:15 06/24/1510:25 7440-39-3 Beryllium 0.95 mg/kg 0.28 0.14 5 06/23/1517:15 06/24/1510:25 7440-41-7 Boron ND mg/kg 14.1 7.1 5 06/23/1517:15 06/24/1510:25 7440-42-8 Calcium 89AJ mg/kg 141 70.6 5 06/23/1517:15 06/24/1510:25 7440-70-2 Chromium 11.3 mg/kg 1.4 0.71 5 06/23/1517:15 06/24/1510:25 7440-47-3 Copper 9.2 mg/kg 1.4 0.71 5 06/23/1517:15 06/24/1510:25 7440-50-8 Iron 18300 mg/kg 11.3 5.6 5 06/23/1517:15 06/24/1510:25 7439-89-6 Magnesium 1480 mg/kg 141 70.6 5 06/23/1517:15 06/24/1510:25 7439-95-4 Manganese 67.8 mg/kg 1.4 0.71 5 06/23/1517:15 06/24/1510:25 7439-96-5 Molybdenum ND mg/kg 2.8 1.4 5 06/23/1517:15 06/24/1510:25 7439-98-7 Nickel 4.8 mg/kg 1.4 0.71 5 06/23/1517:15 06/24/1510:25 7440-02-0 Potassium 1320 mg/kg 282 141 5 06/23/1517:15 06/24/1510:25 7440-09-7 Sodium ND mg/kg 282 141 5 06/23/1517:15 06/24/1510:25 7440-23-5 Strontium 1.91 mg/kg 2.8 1.4 5 06/23/1517:15 06/24/1510:25 7440-24-6 Zinc 19.6 mg/kg 5.6 2.8 5 06/23/1517:15 06/24/1510:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7440-36-0 N2 Arsenic ND mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7440-38-2 Cadmium ND mg/kg 0.68 0.34 100 06/23/1517:15 06/24/1515:35 7440-43-9 Cobalt ND mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7440-48-4 Lead 5.2J mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7439-92-1 Selenium ND mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7782-49-2 Thallium ND mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7440-28-0 Vanadium 12.9 mg/kg 5.6 2.8 100 06/23/1517:15 06/24/1515:35 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.015 mg/kg 0.0094 0.0047 1 06/23/1517:30 06/24/1517:49 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.7 % 0.10 0.10 1 06/24/15 18:45 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 06/22/15 15:35 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 289 145 5 06/25/15 09:13 16887-00-6 D3 Sulfate ND mg/kg 289 145 5 06/25/15 09:13 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.9 14.5 5 06/25/15 09:13 14797-55-8 H3 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 IjiQ%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019568 Lab ID: 92254832006 Collected: 06/14/15 16:40 Received: 06/17/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 16.5 % 0.10 0.10 1 06/27/1513:51 Total Organic Carbon 541J mg/kg 691 346 1 06/27/15 13:51 7440-44-0 Total Organic Carbon 458J mg/kg 698 349 1 06/27/15 13:57 7440-44-0 Mean Total Organic Carbon 500J mg/kg 694 347 1 06/27/15 13:51 7440-44-0 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 IjiS%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019574 Lab ID: 92254832007 Collected: 06/11/15 08:50 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 132 ug/L 10.0 3.0 1 06/23/15 06:46 06/26/15 11:50 7429-90-5 M1 ND ug/L 0.50 0.15 1 06/23/15 06:46 06/26/15 11:50 7440-36-0 ND ug/L 0.50 0.11 1 06/23/15 06:46 06/26/15 11:50 7440-38-2 0.60 ug/L 0.30 0.081 1 06/23/15 06:46 06/26/15 11:50 7440-39-3 ND ug/L 0.20 0.067 1 06/23/15 06:46 06/26/15 11:50 7440-41-7 ND ug/L 5.0 1.1 1 06/23/15 06:46 06/26/15 11:50 7440-42-8 ND ug/L 0.080 0.024 1 06/23/15 06:46 06/26/15 11:50 7440-43-9 34.3J ug/L 40.0 16.0 1 06/23/15 06:46 06/26/15 11:50 7440-70-2 0.31J ug/L 0.50 0.17 1 06/23/15 06:46 06/26/15 11:50 7440-47-3 ND ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 11:50 7440-48-4 0.26J ug/L 1.0 0.21 1 06/23/15 06:46 06/26/15 11:50 7440-50-8 296 ug/L 50.0 13.7 1 06/23/15 06:46 06/26/15 11:50 7439-89-6 0.42 ug/L 0.10 0.046 1 06/23/15 06:46 06/26/15 11:50 7439-92-1 13.5 ug/L 10.0 3.2 1 06/23/15 06:46 06/26/15 11:50 7439-95-4 3.3 ug/L 0.50 0.24 1 06/23/15 06:46 06/26/15 11:50 7439-96-5 ND ug/L 0.50 0.094 1 06/23/15 06:46 06/26/15 11:50 7439-98-7 0.46J ug/L 0.50 0.16 1 06/23/15 06:46 06/26/15 11:50 7440-02-0 24.7J ug/L 50.0 11.7 1 06/23/15 06:46 06/26/15 11:50 7440-09-7 ND ug/L 0.50 0.20 1 06/23/15 06:46 06/26/15 11:50 7782-49-2 ND ug/L 50.0 16.3 1 06/23/15 06:46 06/26/15 11:50 7440-23-5 ND ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 11:50 7440-24-6 ND ug/L 0.10 0.015 1 06/23/15 06:46 06/26/15 11:50 7440-28-0 0.36J ug/L 1.0 0.28 1 06/23/15 06:46 06/27/15 09:13 7440-62-2 16.9 ug/L 5.0 2.4 1 06/23/15 06:46 06/26/15 11:50 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/21/15 15:05 06/21/15 21:09 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 14'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019576 Lab ID: 92254832008 Collected: 06/12/15 10:15 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 2380 ug/L 10.0 3.0 1 06/23/15 06:46 06/26/15 12:13 7429-90-5 0.50 ug/L 0.50 0.15 1 06/23/15 06:46 06/26/15 12:13 7440-36-0 6.4 ug/L 0.50 0.11 1 06/23/15 06:46 06/26/15 12:13 7440-38-2 91.9 ug/L 0.30 0.081 1 06/23/15 06:46 06/26/15 12:13 7440-39-3 0.90 ug/L 0.20 0.067 1 06/23/15 06:46 06/26/15 12:13 7440-41-7 2.6J ug/L 5.0 1.1 1 06/23/15 06:46 06/26/15 12:13 7440-42-8 0.026J ug/L 0.080 0.024 1 06/23/15 06:46 06/26/15 12:13 7440-43-9 1170 ug/L 40.0 16.0 1 06/23/15 06:46 06/26/15 12:13 7440-70-2 2.3 ug/L 0.50 0.17 1 06/23/15 06:46 06/26/15 12:13 7440-47-3 1.6 ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 12:13 7440-48-4 6.2 ug/L 1.0 0.21 1 06/23/15 06:46 06/26/15 12:13 7440-50-8 1710 ug/L 50.0 13.7 1 06/23/15 06:46 06/26/15 12:13 7439-89-6 3.2 ug/L 0.10 0.046 1 06/23/15 06:46 06/26/15 12:13 7439-92-1 250 ug/L 10.0 3.2 1 06/23/15 06:46 06/26/15 12:13 7439-95-4 30.4 ug/L 0.50 0.24 1 06/23/15 06:46 06/26/15 12:13 7439-96-5 0.21J ug/L 0.50 0.094 1 06/23/15 06:46 06/26/15 12:13 7439-98-7 3.3 ug/L 0.50 0.16 1 06/23/15 06:46 06/26/15 12:13 7440-02-0 365 ug/L 50.0 11.7 1 06/23/15 06:46 06/26/15 12:13 7440-09-7 0.73 ug/L 0.50 0.20 1 06/23/15 06:46 06/26/15 12:13 7782-49-2 500 ug/L 50.0 16.3 1 06/23/15 06:46 06/26/15 12:13 7440-23-5 47.1 ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 12:13 7440-24-6 0.14 ug/L 0.10 0.015 1 06/23/15 06:46 06/26/15 12:13 7440-28-0 9.5 ug/L 1.0 0.28 1 06/23/15 06:46 06/27/15 09:38 7440-62-2 4AJ ug/L 5.0 2.4 1 06/23/15 06:46 06/26/15 12:13 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/21/15 15:05 06/21/15 21:11 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 Ijig%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019577 Lab ID: 92254832009 Collected: 06/14/15 14:25 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 15900 ug/L 10.0 3.0 1 06/23/15 06:46 06/26/15 12:32 7429-90-5 0.22J ug/L 0.50 0.15 1 06/23/15 06:46 06/26/15 12:32 7440-36-0 3.2 ug/L 0.50 0.11 1 06/23/15 06:46 06/26/15 12:32 7440-38-2 152 ug/L 0.30 0.081 1 06/23/15 06:46 06/26/15 12:32 7440-39-3 0.70 ug/L 0.20 0.067 1 06/23/15 06:46 06/26/15 12:32 7440-41-7 5.4 ug/L 5.0 1.1 1 06/23/15 06:46 06/26/15 12:32 7440-42-8 0.46 ug/L 0.080 0.024 1 06/23/15 06:46 06/26/15 12:32 7440-43-9 1860 ug/L 40.0 16.0 1 06/23/15 06:46 06/26/15 12:32 7440-70-2 30.8 ug/L 0.50 0.17 1 06/23/15 06:46 06/26/15 12:32 7440-47-3 41.1 ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 12:32 7440-48-4 18.3 ug/L 1.0 0.21 1 06/23/15 06:46 06/26/15 12:32 7440-50-8 19900 ug/L 50.0 13.7 1 06/23/15 06:46 06/26/15 12:32 7439-89-6 11.5 ug/L 0.10 0.046 1 06/23/15 06:46 06/26/15 12:32 7439-92-1 3320 ug/L 10.0 3.2 1 06/23/15 06:46 06/26/15 12:32 7439-95-4 436 ug/L 0.50 0.24 1 06/23/15 06:46 06/26/15 12:32 7439-96-5 3.0 ug/L 0.50 0.094 1 06/23/15 06:46 06/26/15 12:32 7439-98-7 14.1 ug/L 0.50 0.16 1 06/23/15 06:46 06/26/15 12:32 7440-02-0 3970 ug/L 50.0 11.7 1 06/23/15 06:46 06/26/15 12:32 7440-09-7 3.3 ug/L 0.50 0.20 1 06/23/15 06:46 06/26/15 12:32 7782-49-2 2580 ug/L 50.0 16.3 1 06/23/15 06:46 06/26/15 12:32 7440-23-5 11.6 ug/L 0.50 0.13 1 06/23/15 06:46 06/26/15 12:32 7440-24-6 0.30 ug/L 0.10 0.015 1 06/23/15 06:46 06/26/15 12:32 7440-28-0 24.7 ug/L 1.0 0.28 1 06/23/15 06:46 06/27/15 09:42 7440-62-2 202 ug/L 5.0 2.4 1 06/23/15 06:46 06/26/15 12:32 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.040J ug/L 0.20 0.022 1 06/21/15 15:05 06/21/15 21:13 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 16'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019563 SPLP Lab ID: 92254832010 Collected: 06/11/15 09:00 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 662 ug/L 10.0 3.0 1 06/27/1513:23 06/28/1512:18 7429-90-5 0.18J ug/L 0.50 0.15 1 06/27/1513:23 06/28/1512:18 7440-36-0 0.38J ug/L 0.50 0.11 1 06/27/1513:23 06/28/1512:18 7440-38-2 254 ug/L 0.30 0.081 1 06/27/1513:23 06/28/1512:18 7440-39-3 1.4 ug/L 0.20 0.067 1 06/27/1513:23 06/28/1512:18 7440-41-7 103 ug/L 5.0 1.1 1 06/27/1513:23 06/28/1512:18 7440-42-8 0.38 ug/L 0.080 0.024 1 06/27/1513:23 06/28/1512:18 7440-43-9 2590 ug/L 40.0 16.0 1 06/27/1513:23 06/28/1512:18 7440-70-2 4.0 ug/L 0.50 0.17 1 06/27/1513:23 06/28/1512:18 7440-47-3 2.6 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:18 7440-48-4 2.0 ug/L 1.0 0.21 1 06/27/1513:23 06/28/1512:18 7440-50-8 51.5 ug/L 50.0 13.7 1 06/27/1513:23 06/28/1512:18 7439-89-6 0.76 ug/L 0.10 0.046 1 06/27/1513:23 06/28/1512:18 7439-92-1 210 ug/L 10.0 3.2 1 06/27/1513:23 06/28/1512:18 7439-95-4 389 ug/L 0.50 0.24 1 06/27/1513:23 06/28/1512:18 7439-96-5 0.56 ug/L 0.50 0.094 1 06/27/1513:23 06/28/1512:18 7439-98-7 5.5 ug/L 0.50 0.16 1 06/27/1513:23 06/28/1512:18 7440-02-0 1490 ug/L 50.0 11.7 1 06/27/1513:23 06/28/1512:18 7440-09-7 0.54 ug/L 0.50 0.20 1 06/27/1513:23 06/28/1512:18 7782-49-2 1880 ug/L 50.0 16.3 1 06/27/1513:23 06/28/1512:18 7440-23-5 54.7 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:18 7440-24-6 0.23 ug/L 0.10 0.015 1 06/27/1513:23 06/28/1512:18 7440-28-0 0.47J ug/L 1.0 0.28 1 06/27/1513:23 06/28/1512:18 7440-62-2 190 ug/L 5.0 2.4 1 06/27/1513:23 06/28/1512:18 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/27/1512:17 06/27/1514:39 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 Iji '8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019565 SPLP Lab ID: 92254832011 Collected: 06/12/15 10:20 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 313 ug/L 10.0 3.0 1 06/27/1513:23 06/28/1512:21 7429-90-5 ND ug/L 0.50 0.15 1 06/27/1513:23 06/28/1512:21 7440-36-0 0.24J ug/L 0.50 0.11 1 06/27/1513:23 06/28/1512:21 7440-38-2 342 ug/L 0.30 0.081 1 06/27/1513:23 06/28/1512:21 7440-39-3 0.91 ug/L 0.20 0.067 1 06/27/1513:23 06/28/1512:21 7440-41-7 98.5 ug/L 5.0 1.1 1 06/27/1513:23 06/28/1512:21 7440-42-8 0.53 ug/L 0.080 0.024 1 06/27/1513:23 06/28/1512:21 7440-43-9 2400 ug/L 40.0 16.0 1 06/27/1513:23 06/28/1512:21 7440-70-2 1.4 ug/L 0.50 0.17 1 06/27/1513:23 06/28/1512:21 7440-47-3 11.9 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:21 7440-48-4 3.3 ug/L 1.0 0.21 1 06/27/1513:23 06/28/1512:21 7440-50-8 15.3J ug/L 50.0 13.7 1 06/27/1513:23 06/28/1512:21 7439-89-6 0.39 ug/L 0.10 0.046 1 06/27/1513:23 06/28/1512:21 7439-92-1 301 ug/L 10.0 3.2 1 06/27/1513:23 06/28/1512:21 7439-95-4 206 ug/L 0.50 0.24 1 06/27/1513:23 06/28/1512:21 7439-96-5 0.31J ug/L 0.50 0.094 1 06/27/1513:23 06/28/1512:21 7439-98-7 4.1 ug/L 0.50 0.16 1 06/27/1513:23 06/28/1512:21 7440-02-0 543 ug/L 50.0 11.7 1 06/27/1513:23 06/28/1512:21 7440-09-7 1.4 ug/L 0.50 0.20 1 06/27/1513:23 06/28/1512:21 7782-49-2 1950 ug/L 50.0 16.3 1 06/27/1513:23 06/28/1512:21 7440-23-5 68.9 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:21 7440-24-6 0.11 ug/L 0.10 0.015 1 06/27/1513:23 06/28/1512:21 7440-28-0 0.39J ug/L 1.0 0.28 1 06/27/1513:23 06/28/1512:21 7440-62-2 147 ug/L 5.0 2.4 1 06/27/1513:23 06/28/1512:21 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/27/1512:17 06/27/1514:42 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060543 Pace Project No.: 92254832 Pace Analytical Services, Inc. 9800 Iji %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015019567 SPLP Lab ID: 92254832012 Collected: 06/14/15 14:30 Received: 06/17/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/01/2015 04:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 44.4 ug/L 10.0 3.0 1 06/27/1513:23 06/28/1512:42 7429-90-5 ND ug/L 0.50 0.15 1 06/27/1513:23 06/28/1512:42 7440-36-0 0.14J ug/L 0.50 0.11 1 06/27/1513:23 06/28/1512:42 7440-38-2 139 ug/L 0.30 0.081 1 06/27/1513:23 06/28/1512:42 7440-39-3 0.11J ug/L 0.20 0.067 1 06/27/1513:23 06/28/1512:42 7440-41-7 88.4 ug/L 5.0 1.1 1 06/27/1513:23 06/28/1512:42 7440-42-8 0.10 ug/L 0.080 0.024 1 06/27/1513:23 06/28/1512:42 7440-43-9 442 ug/L 40.0 16.0 1 06/27/1513:23 06/28/1512:42 7440-70-2 1.7 ug/L 0.50 0.17 1 06/27/1513:23 06/28/1512:42 7440-47-3 0.89 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:42 7440-48-4 0.86J ug/L 1.0 0.21 1 06/27/1513:23 06/28/1512:42 7440-50-8 17.3J ug/L 50.0 13.7 1 06/27/1513:23 06/28/1512:42 7439-89-6 0.12 ug/L 0.10 0.046 1 06/27/1513:23 06/28/1512:42 7439-92-1 228 ug/L 10.0 3.2 1 06/27/1513:23 06/28/1512:42 7439-95-4 24.0 ug/L 0.50 0.24 1 06/27/1513:23 06/28/1512:42 7439-96-5 0.27J ug/L 0.50 0.094 1 06/27/1513:23 06/28/1512:42 7439-98-7 1.1 ug/L 0.50 0.16 1 06/27/1513:23 06/28/1512:42 7440-02-0 316 ug/L 50.0 11.7 1 06/27/1513:23 06/28/1512:42 7440-09-7 ND ug/L 0.50 0.20 1 06/27/1513:23 06/28/1512:42 7782-49-2 2280 ug/L 50.0 16.3 1 06/27/1513:23 06/28/1512:42 7440-23-5 6.2 ug/L 0.50 0.13 1 06/27/1513:23 06/28/1512:42 7440-24-6 0.095J ug/L 0.10 0.015 1 06/27/1513:23 06/28/1512:42 7440-28-0 ND ug/L 1.0 0.28 1 06/27/1513:23 06/28/1512:42 7440-62-2 88.8 ug/L 5.0 2.4 1 06/27/1513:23 06/28/1512:42 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/27/1512:17 06/27/1514:44 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. B Page 46 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iji %Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: MERP/13956 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92254832007, 92254832008, 92254832009 METHOD BLANK: 2001526 Matrix: Water Associated Lab Samples: 92254832007, 92254832008, 92254832009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/21/15 20:42 LABORATORY CONTROL SAMPLE: 2001527 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2001528 2001529 MS MSD 92254629012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 5.0 98 100 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: MERP/14038 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92254832010, 92254832011, 92254832012 METHOD BLANK: 2008125 Matrix: Water Associated Lab Samples: 92254832010, 92254832011, 92254832012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/27/1514:15 LABORATORY CONTROL SAMPLE: 2008126 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.6 113 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2008127 2008128 MS MSD 92255416009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 15 15 17.5 17.9 117 119 80-120 2 20 MATRIX SPIKE SAMPLE: 2008129 92254516016 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Mercury ug/L ND 15 17.6 118 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �n%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: MERP/5891 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1250120 Matrix: Solid Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 06/24/1517:23 LABORATORY CONTROL SAMPLE: 1250121 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.087 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1250122 1250123 MS MSD 92254832001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .111 .11 0.12 0.12 107 111 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: MPRP/24868 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1250111 Matrix: Solid Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.0 06/24/15 09:24 Barium mg/kg ND 0.50 06/24/15 09:24 Beryllium mg/kg ND 0.050 06/24/15 09:24 Boron mg/kg ND 2.5 06/24/15 09:24 Calcium mg/kg ND 25.2 06/24/15 09:24 Chromium mg/kg ND 0.25 06/24/15 09:24 Copper mg/kg ND 0.25 06/24/15 09:24 Iron mg/kg ND 2.0 06/24/15 09:24 Magnesium mg/kg ND 25.2 06/24/15 09:24 Manganese mg/kg ND 0.25 06/24/15 09:24 Molybdenum mg/kg ND 0.50 06/24/15 09:24 Nickel mg/kg ND 0.25 06/24/15 09:24 Potassium mg/kg ND 50.4 06/24/15 09:24 Sodium mg/kg ND 50.4 06/24/15 09:24 Strontium mg/kg ND 0.50 06/24/15 09:24 Zinc mg/kg ND 1.0 06/24/15 09:24 Pace Analytical Services, Inc. 9800 �Q%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1250112 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 128 127 99 80-120 Barium mg/kg 12.8 12.7 99 80-120 Beryllium mg/kg 1.3 1.3 99 80-120 Boron mg/kg 128 128 100 80-120 Calcium mg/kg 641 638 100 80-120 Chromium mg/kg 12.8 12.7 99 80-120 Copper mg/kg 12.8 12.4 96 80-120 Iron mg/kg 128 127 99 80-120 Magnesium mg/kg 641 656 102 80-120 Manganese mg/kg 12.8 12.6 99 80-120 Molybdenum mg/kg 12.8 12.3 96 80-120 Nickel mg/kg 12.8 12.8 100 80-120 Potassium mg/kg 641 633 99 80-120 Sodium mg/kg 641 645 101 80-120 Strontium mg/kg 12.8 12.7 99 80-120 Zinc mg/kg 64.1 63.3 99 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1250113 1250114 MS MSD 92254832001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 12600 174 178 15000 13400 1370 451 75-125 11 20 M1 Barium mg/kg 44.0 17.4 17.8 62.7 57.2 107 74 75-125 9 20 M1 Beryllium mg/kg 0.75 1.67 1.81 2.4 2.4 94 91 75-125 0 20 Boron mg/kg ND 174 178 157 166 88 91 75-125 5 20 Calcium mg/kg 328 871 892 1170 1170 96 95 75-125 1 20 Chromium mg/kg 10.1 17.4 17.8 26.3 26.3 93 91 75-125 0 20 Copper mg/kg 4.6 17.4 17.8 20.6 21.1 92 93 75-125 2 20 Iron mg/kg 11700 174 178 12000 10500 174 -644 75-125 13 20 M1 Magnesium mg/kg 2460 871 892 3370 3130 104 75 75-125 7 20 Manganese mg/kg 114 17.4 17.8 132 121 106 39 75-125 9 20 M1 Molybdenum mg/kg ND 17.4 17.8 14.4 15.3 82 85 75-125 6 20 Nickel mg/kg 6.5 17.4 17.8 23.4 23.5 97 95 75-125 1 20 Potassium mg/kg 1060 871 892 1900 1820 97 86 75-125 4 20 Sodium mg/kg ND 871 892 825 925 93 102 75-125 11 20 Strontium mg/kg 5.7 17.4 17.8 22.8 23.0 98 97 75-125 1 20 Zinc mg/kg 36.5 87.1 89.2 122 119 99 92 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: MPRP/24869 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1250115 Matrix: Solid Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 06/24/1513:49 N2 Arsenic mg/kg ND 0.052 06/24/1513:49 Cadmium mg/kg ND 0.0062 06/24/1513:49 Cobalt mg/kg ND 0.052 06/24/1513:49 Lead mg/kg ND 0.052 06/24/1513:49 Selenium mg/kg ND 0.052 06/24/1513:49 Thallium mg/kg ND 0.052 06/24/1513:49 Vanadium mg/kg ND 0.052 06/24/1513:49 Pace Analytical Services, Inc. 9800 t 4,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1250116 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.5 97 80-120 N2 Arsenic mg/kg 2.6 2.4 95 80-120 Cadmium mg/kg .26 0.24 95 80-120 Cobalt mg/kg 2.6 2.6 103 80-120 Lead mg/kg 2.6 2.6 103 80-120 Selenium mg/kg 2.6 2.4 95 80-120 Thallium mg/kg 2.6 2.6 101 80-120 Vanadium mg/kg 2.6 2.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1250117 1250118 MS MSD 92254832001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.62 3.48 ND ND 75 54 75-125 20 M6, N2 Arsenic mg/kg ND 3.62 3.48 ND ND 80 67 75-125 20 M6 Cadmium mg/kg ND .362 .348 ND ND 75 76 75-125 20 Cobalt mg/kg 4AJ 3.62 3.48 8.1 6.8J 106 72 75-125 20 M6 Lead mg/kg 4.7J 3.62 3.48 7.9 7.1 91 70 75-125 11 20 M6 Selenium mg/kg ND 3.62 3.48 4.3J 4AJ 82 89 75-125 20 Thallium mg/kg ND 3.62 3.48 3.9J ND 102 86 75-125 20 Vanadium mg/kg 17.9 3.62 3.48 19.0 17.8 32 -2 75-125 6 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: MPRP/55423 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92254832007, 92254832008, 92254832009 METHOD BLANK: 2002623 Matrix: Associated Lab Samples: 92254832007, 92254832008, 92254832009 Blank Parameter Units Result Water Reporting Limit Analyzed Aluminum ug/L ND 10.0 06/26/1511:41 Antimony ug/L ND 0.50 06/26/1511:41 Arsenic ug/L ND 0.50 06/26/1511:41 Barium ug/L ND 0.30 06/26/1511:41 Beryllium ug/L ND 0.20 06/26/1511:41 Boron ug/L ND 5.0 06/26/1511:41 Cadmium ug/L ND 0.080 06/26/1511:41 Calcium ug/L ND 40.0 06/26/1511:41 Chromium ug/L ND 0.50 06/26/1511:41 Cobalt ug/L ND 0.50 06/26/1511:41 Copper ug/L ND 1.0 06/26/1511:41 Iron ug/L ND 50.0 06/26/1511:41 Lead ug/L ND 0.10 06/26/1511:41 Magnesium ug/L ND 10.0 06/26/1511:41 Manganese ug/L ND 0.50 06/26/1511:41 Molybdenum ug/L ND 0.50 06/26/1511:41 Nickel ug/L ND 0.50 06/26/1511:41 Potassium ug/L ND 50.0 06/26/1511:41 Selenium ug/L ND 0.50 06/26/1511:41 Sodium ug/L ND 50.0 06/26/1511:41 Strontium ug/L ND 0.50 06/26/1511:41 Thallium ug/L ND 0.10 06/26/1511:41 Vanadium ug/L ND 1.0 06/27/15 09:08 Zinc ug/L ND 5.0 06/26/1511:41 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2002624 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 80.2 100 80-120 Antimony ug/L 80 78.1 98 80-120 Arsenic ug/L 80 79.6 100 80-120 Barium ug/L 80 78.6 98 80-120 Beryllium ug/L 80 80.7 101 80-120 Boron ug/L 80 79.2 99 80-120 Cadmium ug/L 80 79.4 99 80-120 Calcium ug/L 1000 983 98 80-120 Chromium ug/L 80 79.5 99 80-120 Cobalt ug/L 80 79.8 100 80-120 Copper ug/L 80 78.1 98 80-120 Iron ug/L 1000 1000 100 80-120 Pace Analytical Services, Inc. 9800 �g%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 LABORATORY CONTROL SAMPLE: 2002624 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.8 100 80-120 Magnesium ug/L 1000 978 98 80-120 Manganese ug/L 80 79.7 100 80-120 Molybdenum ug/L 80 78.8 99 80-120 Nickel ug/L 80 80.9 101 80-120 Potassium ug/L 1000 963 96 80-120 Selenium ug/L 80 80.5 101 80-120 Sodium ug/L 1000 975 97 80-120 Strontium ug/L 80 78.8 99 80-120 Thallium ug/L 80 79.5 99 80-120 Vanadium ug/L 80 80.2 100 80-120 Zinc ug/L 80 80.2 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2002625 2002626 MS MSD 92254832007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 132 80 80 578 479 558 434 75-125 19 20 M1 Antimony ug/L ND 80 80 77.6 79.5 97 99 75-125 2 20 Arsenic ug/L ND 80 80 79.8 80.2 100 100 75-125 1 20 Barium ug/L 0.60 80 80 78.7 79.9 98 99 75-125 1 20 Beryllium ug/L ND 80 80 82.8 83.2 103 104 75-125 1 20 Boron ug/L ND 80 80 84.1 84.3 104 105 75-125 0 20 Cadmium ug/L ND 80 80 79.4 79.8 99 100 75-125 1 20 Calcium ug/L 34.3J 1000 1000 1020 1080 99 104 75-125 5 20 Chromium ug/L 0.31J 80 80 79.4 81.1 99 101 75-125 2 20 Cobalt ug/L ND 80 80 80.0 80.6 100 101 75-125 1 20 Copper ug/L 0.26J 80 80 78.6 79.3 98 99 75-125 1 20 Iron ug/L 296 1000 1000 1380 1350 108 105 75-125 2 20 Lead ug/L 0.42 80 80 81.4 81.7 101 102 75-125 0 20 Magnesium ug/L 13.5 1000 1000 986 1030 97 101 75-125 4 20 Manganese ug/L 3.3 80 80 83.6 83.7 100 101 75-125 0 20 Molybdenum ug/L ND 80 80 78.1 79.4 98 99 75-125 2 20 Nickel ug/L 0.46J 80 80 81.0 82.6 101 103 75-125 2 20 Potassium ug/L 24.7J 1000 1000 990 1010 97 99 75-125 2 20 Selenium ug/L ND 80 80 80.7 79.2 101 99 75-125 2 20 Sodium ug/L ND 1000 1000 1000 1010 99 100 75-125 1 20 Strontium ug/L ND 80 80 79.1 80.2 99 100 75-125 1 20 Thallium ug/L ND 80 80 81.6 81.9 102 102 75-125 0 20 Vanadium ug/L 0.36J 80 80 81.8 80.6 102 100 75-125 1 20 Zinc ug/L 16.9 80 80 97.5 98.3 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: MPRP/55611 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92254832010, 92254832011, 92254832012 METHOD BLANK: 2008101 Matrix: Associated Lab Samples: 92254832010, 92254832011, 92254832012 Blank Parameter Units Result Water Reporting Limit Analyzed Aluminum ug/L ND 10.0 06/28/1512:07 Antimony ug/L ND 0.50 06/28/1512:07 Arsenic ug/L ND 0.50 06/28/1512:07 Barium ug/L ND 0.30 06/28/1512:07 Beryllium ug/L ND 0.20 06/28/1512:07 Boron ug/L ND 5.0 06/28/1512:07 Cadmium ug/L ND 0.080 06/28/1512:07 Calcium ug/L ND 40.0 06/28/1512:07 Chromium ug/L ND 0.50 06/28/1512:07 Cobalt ug/L ND 0.50 06/28/1512:07 Copper ug/L ND 1.0 06/28/1512:07 Iron ug/L ND 50.0 06/28/1512:07 Lead ug/L ND 0.10 06/28/1512:07 Magnesium ug/L 3.7J 10.0 06/28/1512:07 Manganese ug/L ND 0.50 06/28/1512:07 Molybdenum ug/L ND 0.50 06/28/1512:07 Nickel ug/L 0.17J 0.50 06/28/1512:07 Potassium ug/L ND 50.0 06/28/1512:07 Selenium ug/L ND 0.50 06/28/1512:07 Sodium ug/L ND 50.0 06/28/1512:07 Strontium ug/L ND 0.50 06/28/1512:07 Thallium ug/L ND 0.10 06/28/1512:07 Vanadium ug/L ND 1.0 06/28/1512:07 Zinc ug/L ND 5.0 06/28/1512:07 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2008102 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 81.6 102 80-120 Antimony ug/L 80 75.2 94 80-120 Arsenic ug/L 80 75.2 94 80-120 Barium ug/L 80 77.1 96 80-120 Beryllium ug/L 80 75.7 95 80-120 Boron ug/L 80 73.9 92 80-120 Cadmium ug/L 80 78.0 98 80-120 Calcium ug/L 1000 944 94 80-120 Chromium ug/L 80 80.9 101 80-120 Cobalt ug/L 80 80.5 101 80-120 Copper ug/L 80 80.0 100 80-120 Iron ug/L 1000 996 100 80-120 Pace Analytical Services, Inc. 9800 "%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 LABORATORY CONTROL SAMPLE: 2008102 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.8 98 80-120 Magnesium ug/L 1000 992 99 80-120 Manganese ug/L 80 79.7 100 80-120 Molybdenum ug/L 80 78.4 98 80-120 Nickel ug/L 80 81.7 102 80-120 Potassium ug/L 1000 991 99 80-120 Selenium ug/L 80 75.6 95 80-120 Sodium ug/L 1000 996 100 80-120 Strontium ug/L 80 78.9 99 80-120 Thallium ug/L 80 81.8 102 80-120 Vanadium ug/L 80 79.6 100 80-120 Zinc ug/L 80 78.7 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2008488 2008489 MS MSD 92254629019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 4910 80 80 4740 5120 -216 264 75-125 8 20 M1 Antimony ug/L 0.24J 80 80 83.8 83.9 104 105 75-125 0 20 Arsenic ug/L 0.36J 80 80 86.6 86.5 108 108 75-125 0 20 Barium ug/L 143 80 80 228 238 106 118 75-125 4 20 Beryllium ug/L 0.39 80 80 88.5 86.4 110 107 75-125 2 20 Boron ug/L 54.9 80 80 148 145 116 113 75-125 2 20 Cadmium ug/L 0.27 80 80 87.6 89.3 109 111 75-125 2 20 Calcium ug/L 432 1000 1000 1560 1560 113 113 75-125 0 20 Chromium ug/L 4.6 80 80 93.9 95.1 112 113 75-125 1 20 Cobalt ug/L 0.72 80 80 90.6 92.2 112 114 75-125 2 20 Copper ug/L 3.5 80 80 95.8 97.3 115 117 75-125 2 20 Iron ug/L 796 1000 1000 1880 1960 108 116 75-125 4 20 Lead ug/L 0.84 80 80 89.9 91.7 111 114 75-125 2 20 Magnesium ug/L 176 1000 1000 1310 1340 113 117 75-125 2 20 Manganese ug/L 46.3 80 80 136 140 112 117 75-125 3 20 Molybdenum ug/L 0.78 80 80 88.0 87.8 109 109 75-125 0 20 Nickel ug/L 2.7 80 80 95.0 95.9 115 116 75-125 1 20 Potassium ug/L 378 1000 1000 1500 1530 112 115 75-125 2 20 Selenium ug/L 0.33J 80 80 88.0 85.9 110 107 75-125 2 20 Sodium ug/L 2030 1000 1000 3180 3250 115 122 75-125 2 20 Strontium ug/L 10.1 80 80 97.6 100 109 113 75-125 3 20 Thallium ug/L 0.28 80 80 90.6 92.5 113 115 75-125 2 20 Vanadium ug/L 3.6 80 80 93.0 94.5 112 114 75-125 2 20 Zinc ug/L 78.1 80 80 150 158 90 100 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 MATRIX SPIKE SAMPLE: 2008490 92254516016 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2350 80 2460 132 75-125 M1 Antimony ug/L 5.5 80 85.8 100 75-125 Arsenic ug/L 82.4 80 173 113 75-125 Barium ug/L 148 80 233 106 75-125 Beryllium ug/L 0.31 80 84.5 105 75-125 Boron ug/L 394 80 485 114 75-125 Cadmium ug/L 0.15 80 84.1 105 75-125 Calcium ug/L 11400 1000 12700 128 75-125 M1 Chromium ug/L 12.2 80 99.4 109 75-125 Cobalt ug/L 0.52 80 83.0 103 75-125 Copper ug/L 11.1 80 95.9 106 75-125 Iron ug/L 236 1000 1290 105 75-125 Lead ug/L 1.5 80 86.9 107 75-125 Magnesium ug/L 156 1000 1240 109 75-125 Manganese ug/L 3.4 80 86.6 104 75-125 Molybdenum ug/L 5.0 80 86.9 102 75-125 Nickel ug/L 1.8 80 86.2 105 75-125 Potassium ug/L 294 1000 1380 108 75-125 Selenium ug/L 55.5 80 144 111 75-125 Sodium ug/L 1440 1000 2520 108 75-125 Strontium ug/L 202 80 306 131 75-125 M1 Thallium ug/L 0.30 80 86.7 108 75-125 Vanadium ug/L 156 80 244 111 75-125 Zinc ug/L 40.4 80 128 110 75-125 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: PMST/3676 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 SAMPLE DUPLICATE: 1251820 92254318002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.3 16.3 0 10 SAMPLE DUPLICATE: 1251821 35193503010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.2 23.7 2 10 SAMPLE DUPLICATE: 1251822 35193503019 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.9 18.0 26 10 D6 SAMPLE DUPLICATE: 1251823 35193596002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 22.7 24.5 8 10 SAMPLE DUPLICATE: 1251824 35193596011 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.0 8.2 10 10 SAMPLE DUPLICATE: 1251825 35193596020 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 3.9 3.4 14 10 D6 SAMPLE DUPLICATE: 1251826 92254832001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.2 28.5 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 73 aceAnaiXical www.pacelabs.com Project: J15060543 Pace Project No.: 92254832 SAMPLE DUPLICATE: 1251827 Parameter Percent Moisture SAMPLE DUPLICATE: 1251828 Parameter Percent Moisture Pace Analytical Services, Inc. 9800 �n%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA 92255108004 Dup Max Units Result Result RPD RPD Qualifiers 44.4 44.9 1 10 92255108013 Dup Max Units Result Result RPD RPD Qualifiers % 21.0 18.0 15 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: WET/38245 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92254832001, 92254832002, 92254832003 Pace Analytical Services, Inc. 9800 �Q%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1489510 92254321003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.5 1 10 SAMPLE DUPLICATE: 1489511 92254629004 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.8 4.8 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: WET/38288 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92254832004, 92254832005, 92254832006 Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1490817 92255286001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.1 7.1 1 10 D6 SAMPLE DUPLICATE: 1490818 92254629009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.4 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/23465 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92254832001, 92254832002, 92254832003 METHOD BLANK: 1494036 Matrix: Water Associated Lab Samples: 92254832001, 92254832002, 92254832003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.4 2.0 06/25/1510:05 LABORATORY CONTROL SAMPLE: 1494037 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.1 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1494038 1494039 MS MSD 92254516008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 4.5 20 20 22.5 22.7 90 91 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1494040 1494041 MS MSD 92255416011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.3 25 25 26.6 26.4 93 92 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Edge yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/23480 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92254832001, 92254832002, 92254832003 METHOD BLANK: 1495301 Matrix: Water Associated Lab Samples: 92254832001, 92254832002, 92254832003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.10 0.020 06/25/15 21:59 Z2 LABORATORY CONTROL SAMPLE: 1495302 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1495303 1495304 MS MSD 92254516008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 97 97 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1495305 1495306 MS MSD 92254516009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 97 97 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/23463 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92254832001, 92254832002, 92254832003 METHOD BLANK: 1493965 Matrix: Water Associated Lab Samples: 92254832001, 92254832002, 92254832003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/25/15 02:18 LABORATORY CONTROL SAMPLE: 1493966 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1493967 1493968 MS MSD 92254516008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 8.2 20 20 29.6 29.6 107 107 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1493969 1493970 MS MSD 92255416011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 25 25 26.7 26.2 103 101 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/47613 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1251848 1251849 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1251851 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 06/25/15 05:54 Sulfate mg/kg ND 49.9 06/25/15 05:54 LABORATORY CONTROL SAMPLE: 1251849 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1251851 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1251850 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 497 503 101 80-120 497 511 103 80-120 92254832001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 698 619 73 80-120 M1 262J 698 856 85 80-120 92254832001 Dup Units Result Result mg/kg ND ND mg/kg 262J 235J Max RPD RPD Qualifiers 20 D3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Edge Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/47614 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1251859 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/25/15 05:54 LABORATORY CONTROL SAMPLE: 1251860 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.7 53.6 108 80-120 MATRIX SPIKE SAMPLE: 1251862 92254832001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 69.8 66.6 96 80-120 H3 SAMPLE DUPLICATE: 1251861 92254832001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060543 Pace Project No.: 92254832 QC Batch: WETA/29215 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92254832001, 92254832002, 92254832003, 92254832004, 92254832005, 92254832006 METHOD BLANK: 1182722 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/27/15 10:10 LABORATORY CONTROL SAMPLE: 1182723 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 131000 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182724 1182725 MS MSD 92253899016 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 3290 6250 6290 10400 9820 114 104 50-150 6 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182726 1182727 MS MSD 92254832001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2540 8370 8370 10900 11100 100 102 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 67 of 73 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15060543 Pace Project No.: 92254832 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 %%Yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15162 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/10077 [1j Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 68 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tginlc8y ft.. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060543 Pace Project No.: 92254832 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 69 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Ig2,8 rfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060543 92254832 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92254832001 2015019563 EPA 3050 MPRP/24868 EPA 6010 ICP/15162 92254832002 2015019565 EPA 3050 MPRP/24868 EPA 6010 ICP/15162 92254832003 2015019567 EPA 3050 MPRP/24868 EPA 6010 ICP/15162 92254832004 2015019564 EPA 3050 MPRP/24868 EPA 6010 ICP/15162 92254832005 2015019566 EPA 3050 MPRP/24868 EPA 6010 ICP/15162 92254832006 2015019568 EPA 3050 MPRP/24868 EPA6010 ICP/15162 92254832001 2015019563 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832002 2015019565 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832003 2015019567 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832004 2015019564 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832005 2015019566 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832006 2015019568 EPA 3050 MPRP/24869 EPA 6020 ICPM/10077 92254832007 2015019574 EPA 3020 MPRP/55423 EPA 6020A ICPM/24991 92254832008 2015019576 EPA 3020 MPRP/55423 EPA 6020A ICPM/24991 92254832009 2015019577 EPA 3020 MPRP/55423 EPA 6020A ICPM/24991 92254832010 2015019563 SPLP EPA 3020 MPRP/55611 EPA 6020A ICPM/25041 92254832011 2015019565 SPLP EPA 3020 MPRP/55611 EPA 6020A ICPM/25041 92254832012 2015019567 SPLP EPA 3020 MPRP/55611 EPA 6020A ICPM/25041 92254832007 2015019574 EPA 7470A MERP/13956 EPA 7470A MERC/16232 92254832008 2015019576 EPA 7470A MERP/13956 EPA 7470A MERC/16232 92254832009 2015019577 EPA 7470A MERP/13956 EPA 7470A MERC/16232 92254832010 2015019563 SPLP EPA 7470A MERP/14038 EPA 7470A MERC/16326 92254832011 2015019565 SPLP EPA 7470A MERP/14038 EPA 7470A MERC/16326 92254832012 2015019567 SPLP EPA 7470A MERP/14038 EPA 7470A MERC/16326 92254832001 2015019563 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832002 2015019565 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832003 2015019567 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832004 2015019564 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832005 2015019566 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832006 2015019568 EPA 7471 MERP/5891 EPA 7471 MERC/5877 92254832001 2015019563 ASTM D2974-87 PMST/3676 92254832002 2015019565 ASTM D2974-87 PMST/3676 92254832003 2015019567 ASTM D2974-87 PMST/3676 92254832004 2015019564 ASTM D2974-87 PMST/3676 92254832005 2015019566 ASTM D2974-87 PMST/3676 92254832006 2015019568 ASTM D2974-87 PMST/3676 92254832001 2015019563 EPA 9045 WET/38245 92254832002 2015019565 EPA 9045 WET/38245 92254832003 2015019567 EPA 9045 WET/38245 92254832004 2015019564 EPA 9045 WET/38288 92254832005 2015019566 EPA 9045 WET/38288 92254832006 2015019568 EPA 9045 WET/38288 92254832001 2015019563 EPA 300.0 WETA/23465 92254832002 2015019565 EPA 300.0 WETA/23465 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01/2015 04:15 PM without the written consent of Pace Analytical Services, Inc.. Page 70 of 73 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060543 Pace Project No.: 92254832 Lab ID Sample ID QC Batch Method QC Batch 92254832003 2015019567 EPA 300.0 WETA/23465 92254832001 2015019563 EPA 353.2 WETA/23480 92254832002 2015019565 EPA 353.2 WETA/23480 92254832003 2015019567 EPA 353.2 WETA/23480 92254832001 2015019563 SM 4500 -CI -E WETA/23463 92254832002 2015019565 SM 4500 -CI -E WETA/23463 92254832003 2015019567 SM 4500 -CI -E WETA/23463 92254832001 2015019563 EPA 9056 WETA/47613 92254832002 2015019565 EPA 9056 WETA/47613 92254832003 2015019567 EPA 9056 WETA/47613 92254832004 2015019564 EPA 9056 WETA/47613 92254832005 2015019566 EPA 9056 WETA/47613 92254832006 2015019568 EPA 9056 WETA/47613 92254832001 2015019563 EPA 9056 WETA/47614 92254832002 2015019565 EPA 9056 WETA/47614 92254832003 2015019567 EPA 9056 WETA/47614 92254832004 2015019564 EPA 9056 WETA/47614 92254832005 2015019566 EPA 9056 WETA/47614 92254832006 2015019568 EPA 9056 WETA/47614 92254832001 2015019563 EPA 9060 Modified WETA/29215 92254832001 2015019563 EPA 9060 Modified WETA/29223 92254832002 2015019565 EPA 9060 Modified WETA/29215 92254832002 2015019565 EPA 9060 Modified WETA/29223 92254832003 2015019567 EPA 9060 Modified WETA/29215 92254832003 2015019567 EPA 9060 Modified WETA/29223 92254832004 2015019564 EPA 9060 Modified WETA/29215 92254832004 2015019564 EPA 9060 Modified WETA/29223 92254832005 2015019566 EPA 9060 Modified WETA/29215 92254832005 2015019566 EPA 9060 Modified WETA/29223 92254832006 2015019568 EPA 9060 Modified WETA/29215 92254832006 2015019568 EPA 9060 Modified WETA/29223 Date: 07/01/2015 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 71 of 73 s ?ceAtialylk,X i Document Name: Sample Condition Upon Recei) Document Number: F-CHR-CS-003-rev.16 Client Name: DU k.,,— C:�- ja i rc, , J— Courier: ❑ Fed Ex ❑ UPSD USPS❑ Client❑ Commercial❑ et Othey r Custody Seal on Cooler/Box Present: yos ❑ no Seals intact: yes ❑ no J�3p1� if+ Wil{. .- Packing Material: ❑ Bubble 1❑p ❑ Bubble Bags ❑ No _ Other Thermometer Used: IR Gun T1401 Type of Ice: Blue Blue None ❑ Samples on ice, cooling process has begun Document Revised: May 18, 2UIo Pae 1 of 2* Issuing Authority: 84 of 86 Pace Huntersville Quality Office * Page 2 of 2 is for Internal Use Only Temn Correction Factor T1401 No Correction Corrected Cooler Tem r °C Temp.: Client Biological Tissue is Frozen: Yes Nofl/A ©ate and Initial of 1 er on a ar ming contents: , Temp should be above freezing to 6*C Comments: Chain of Custody Present: ACl1es ©No ❑NIA 1. Chain of Custody Filled Out:es ❑Ne ❑NIA 2. Chain of Custody Relinquished:Yes ❑No L1 NIA 3. Sampler Name & Signature on COC: EfY,, Cl No ED] NIA 4. Samples Arrived within Hold Time: ,nYes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): A , Yes No El NIA 6. Rush Turn Around Time Requested: Dyes o ❑NIA 7. Sufficient Volume: es El No El NIA 8. Correct Containers Used:. y e,es El No 1:1 NIA 9• -Pace Containers Used: es ❑No DNIA Containers Intact: es L1 No ❑NIA 10. Filtered volume received for Dissolved tests PYes ❑No EINIA 11. Sample Labels match COC: es ❑No ❑NIA 12. -Includes date/timellD/Analysis Matrix: Ali containers needing preservation have been checked. Yes D No ❑NIA 13. All containers needing preservation are found to be in IQYes ❑No CINIA compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G,1Nl-DRQ (water) El Yes No Samples checked for dechlorination: ❑Yes ❑NoNIA 14. Headspace in VOA Vials( >6mm): Dyes -D No 061A 15. Trip Blank Present: ❑Yes ❑No NIA 16. Trip Blank Custody Seals Present ❑Yes ❑No 1A urchase : face Trip Blank Lot # (if purchased):- Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Comments/ Resolution: SCURF Review: Date: I (a! IT Datefrime: SRF Review:1 Y"M Ioate:CPI UKLt _--I Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers) WOR:92254832 1111111111111111111111 92254832 Page 72 of 73 S.111 I. p X01 aD s ° N!rtca IL lj�r;I e� A. _ z° `t c; ' J M C7 C:�,lurncr 1u C01q;l•:Io-sunur:'• to right f I I I i I y g� �. 0 rn ICC O n ? I OL a ' 0 c Iv CD ! ! pni I I I i I I j I I 7 7 c Ial b`j N! i 7! R. W 1 �iCna� 3 IT ;wto r�JININLg oo � o,!oWQ�o Qi 1— �� y Y ♦ N I V N 0- VWWW ; i I j N - v. F Or,vi6anmr7 pj % �/� I� i I I I 1 IN ' 1 .rt C. I a 2 ° ¢..— j i IlIU^ I I- N i +- I n $ Z i`D o a j I ! E-u'W C U �--' - GLAI i r I I I I I I j I - •� IE ' ° 9 I I I ! � � I j I I IEI! I i ` I I j CJ c, 1 rz I I 1�1. - m mow . V Q rp ,fir lop; i i I G fi c ro j� i m Zo i j GIW N CI 2, jro ✓i'Ci�l O N �(5 �3� `" I r k I I M O� PI I I I 13 w 2L ' ° ! I i - I i I ___w N iu 1 _ °rEn a I ! I I r 17 W Z I u I Comp. 'eArjalY5 s o_ FL X "Grab iReq ire 'm x a Cu i n U` CO 1 !! E Total Metals, Anions, ; O �. LfH 71 ;, 7- 8 oz jar (PACE) 5 I 0 i , r o ! I vro I I l i i j l l TOC 1-4ozjar {PACE) a I m O j� SPLP-Total Metals $ ry 6 j I I I i j� and Anions i I f j i 2- 8 oz jars (PACE) 5 3 Sediment specific a i I I I I tests 2- 8 oz jar I I (ACCESS ANALYTICAL) J 5 h I o� �In + V1 rF t9 a1 X-�f`3 I -CI =°TolaI # of Conlainers M 0 0 Page 73 of 73 &gtffra EDD AB GrokinilwiAef Asse3srnertl - Sall alpfp„${ Asheville 91f_ I" +91rse No,. GW Buelnaee11m: M 7VMll Codi: IOperal4ng UIM1: — NAfftfMN ID .._. = i ilIVOD w 1p — Whonsplrclolk wwwW"a 60tooln un1ehiftimY 41W 4 00 ind uirkad Ebm*.-. N neon It* 14AJw lnlg, t l fpWaawant decounifnir ler All 1F w2 -un awrng tiwlcls +rhPul, Of Frovi" co n -M 40MIT11111IM11 Par oporilrom 11,11111 and Rruco" 1G. i LAB USS urw.x i CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM -DUKE F ■T/ L ✓ 1 l! - -Analytical Laharateryr Sordid _._j I G4rlY MOOM2 dBrAllr�ng FAiO�I { ± 13339 wagere Far>'k 1 a Nwrtcrsv0* N. C. M74 1 IND) 1754345 _7=111.-i1l87kmp—'—_—_---__..,.,, ' ._._._,_._,_._._._._._._,_._,_. .-Arte _. I Laborin Use On Paye i of i rtavlh: SOIL BC oiS-IMBUTIQM �e a,�oruuwe From ura— - � dCOP to Ica LACI. '�{i ill7 i CCPV to CLIENT _SAMPLE P OOPAIM 9Grr .w-Xile, h- d 2,j im" order 1 _u 7i j d � � � - oma ILTM 1 1 L. __ ! ,I � AB GrokinilwiAef Asse3srnertl - Sall alpfp„${ Asheville 91f_ I" +91rse No,. GW Buelnaee11m: M 7VMll Codi: IOperal4ng UIM1: — NAfftfMN ID .._. = i ilIVOD w 1p — Whonsplrclolk wwwW"a 60tooln un1ehiftimY 41W 4 00 ind uirkad Ebm*.-. N neon It* 14AJw lnlg, t l fpWaawant decounifnir ler All 1F w2 -un awrng tiwlcls +rhPul, Of Frovi" co n -M 40MIT11111IM11 Par oporilrom 11,11111 and Rruco" 1G. i LAB USS urw.x i WIN& L - 1`Lee ID j, 13611, 0*dl,�ftt. Aohl ' PO 1142081 1r =0fetr L J v in u} i d i t.urlunWdJ j:++I Z7 .. t I _ M WAM 121JR01i„1uiShaA Pteaorvatlive% when used must hie � "Samalo Description or 10 L =r - p WJ Z3 49 IL EQUIPMENT BLANK 11 PER RAYj 1411fqqlAN" Fly C.=w0W--- ly + j RFV fILIF ?JIMU3175 Pace ' PO 1142081 1r =0fetr LO v in u} t.urlunWdJ j:++I Z7 .. _ v 0—_Ily Pteaorvatlive% when used must hie � ,� y �_ 'q � � � � z odded within 16 minutes of sample � � - :� M P r � < Ys Y Colleciiun lrlf6 mation a q 4 4 E �, w 0 -r +4 F C 9 0 In Date Time Si - -r7eie 11'tir• fA od u +ad /OZ — Mu -4MA' Metall: Al. Sh, As, 9a, Be, 13, Cd, Ca, Crr CG, Cu, Fe, Pla. My, Mrt, WRQ, f NI, I{;,e, Me, Sr, TI, V. Arflans: C1. Nitrate -N. 804 Sediment Soeclik Paramews: %Solids. CIC, Panicle Slee Do Redux Putentlal lequested,,ITurnaround 'ijEj(I *7 amy.