NC0000396_J15050306report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050306
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
Mary Ann Ogle
°' Jb
Report Authorized By: 2015.05.29 11:45:26b � � ate; 5/28/2015
(Signature) -04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 40
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015014320
ASHEVILLE
12 -May -15 11:50 AM
illegible
MW -10
2015014321
ASHEVILLE
12 -May -15 9:50 AM
illegible
AMW-3A
2015014322
ASHEVILLE
12 -May -15 11:30 AM
illegible
AMW-3B
2015014323
ASHEVILLE
12 -May -15 2:45 PM
Equipment Blank
2015014324
ASHEVILLE
12 -May -15 2:45 PM
Filter Blank
5 Total Samples
Page 2 of 40

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 40
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/28/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050306
Site: MW -10
Collection Date: 12 -May -15 11:50 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
05/14/2015 12:28
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/14/2015 14:06
Nitrite + Nitrate (Colorimetric)
0.096
mg-N/L
0.01
INORGANIC IONS BY IC
05/13/2015 11:37
MHALL3
1 EPA 200.7
Chloride
8.9
mg/L
0.1
Sulfate
0.30
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/13/2015 11:37
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHALL3
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
05/13/2015 13:37
MHALL3
Aluminum (AI)
0.040
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.242
mg/L
0.01
Manganese (Mn)
0.365
mg/L
0.005
Strontium (Sr)
0.024
mg/L
0.005
Zinc (Zn)
0.051
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
2.39
mg/L
0.01
Magnesium (Mg)
2.59
mg/L
0.005
Potassium (K)
1.36
mg/L
0.1
Sodium (Na)
4.02
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.121
mg/L
0.005
Barium (Ba)
0.047
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.369
mg/L
0.01
Manganese (Mn)
0.340
mg/L
0.005
Strontium (Sr)
0.024
mg/L
0.005
Zinc (Zn)
0.085
mg/L
0.005
Sample #: 2015014320
Matrix: GW -WW
Page 4 of 40
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/14/2015 14:14
LSTARL1
1 EPA 300.0
05/18/2015 18:27
BGN9034
1 EPA 300.0
05/18/2015 18:27
BGN9034
1 EPA 245.1
05/14/2015 12:28
ACPAYNE
1 EPA 245.1
05/14/2015 14:06
ACPAYNE
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 11:37
MHALL3
1 EPA 200.7
05/13/2015 13:37
MHALL3
1 EPA 200.7
05/13/2015 13:37
MHALL3
1 EPA 200.7
05/13/2015 13:37
MHALL3
1 EPA 200.7
05/13/2015 13:37
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3
1 EPA 200.7
05/15/2015 14:58
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050306
Site: MW -10
Collection Date: 12 -May -15 11:50 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
4.69
Copper (Cu)
1.08
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
3.45
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
4.29
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
3.10
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
44
Total Carbon
05/28/2015 11:01
TOC
0.710
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 5 of 40
ug/L
1
1
Sample #:
2015014320
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 11:01
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
0.2
1
EPA 200.8
05/19/2015 13:03
DJSULL1
ug/L
0.3
1
EPA 200.8
05/19/2015 13:03
DJSULL1
Vendor Method V SHEALY
Vendor Method
V_ELE1
mg/L
25 1 SM2540C
05/14/201514:55 AGIBBS5
mg/L
0.1 1 SM5310C/EPA9060A
05/19/201511:50 GHUTCHI
mg/L
5 1 SM2540D
05/13/201511:10 AGIBBS5

Certificate of Laboratory Analysis Page 6 of 40
This report shall not be reproduced, except in full.
Order # J15050306
Site: AMW-3A
Collection Date: 12 -May -15 9:50 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/18/2015 18:44
Vendor Parameter
Complete
EPA 300.0
05/18/2015 18:44
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.071
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
1.1
mg/L
1
Sulfate
0.34
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/13/2015 11:48
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/13/2015 11:48
MHALL3
Aluminum (AI)
6.54
mg/L
0.005
Barium (Ba)
0.052
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
1.11
mg/L
0.005
Zinc (Zn)
0.013
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/15/2015 15:01
MHALL3
Calcium (Ca)
188
mg/L
0.1
Magnesium (Mg)
0.007
mg/L
0.005
Potassium (K)
8.77
mg/L
0.1
Sodium (Na)
7.70
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
7.20
mg/L
0.005
Barium (Ba)
0.049
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
1.22
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014321
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/14/2015 14:15
LSTARL1
10
EPA 300.0
05/18/2015 18:44
BGN9034
1
EPA 300.0
05/18/2015 18:44
BGN9034
1
EPA 245.1
05/14/2015 12:53
ACPAYNE
1
EPA 245.1
05/14/2015 14:08
ACPAYNE
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
1
EPA 200.7
05/13/2015 11:48
MHALL3
10
EPA 200.7
05/13/2015 13:41
MHALL3
1
EPA 200.7
05/13/2015 13:41
MHALL3
1
EPA 200.7
05/13/2015 13:41
MHALL3
1
EPA 200.7
05/13/2015 13:41
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3
1
EPA 200.7
05/15/2015 15:01
MHALL3

Certificate of Laboratory Analysis Page 7 of 40
This report shall not be reproduced, except in full.
Order # J15050306
Site: AMW-3A
Sample #: 2015014321
Collection Date: 12 -May -15 9:50 AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Chromium (Cr)
3.39
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Copper (Cu)
1.18
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Molybdenum (Mo)
1.47
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/28/2015 11:19
DJSULL1
Vanadium (V) Low Level
8.78
ug/L
0.3
1
EPA 200.8
05/28/2015 11:19
DJSULL1
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Copper (Cu)
1.17
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/19/2015 13:07
DJSULL1
Vanadium (V) Low Level
8.98
ug/L
0.3
1
EPA 200.8
05/19/2015 13:07
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
500
mg/L
25
1
SM2540C
05/14/201514:55
AGIBBS5
Total Carbon
TOC
0.352
mg/L
0.1
1
SM5310C/EPA9060A
05/19/201511:50
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
05/13/2015 11:10
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050306
Site: AMW-3B
Collection Date: 12 -May -15 11:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/19/2015 08:48
Vendor Parameter
Complete
EPA 300.0
05/19/2015 08:48
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.075
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
< 2.5
mg/L
2.5
Sulfate
3.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/13/2015 11:33
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/13/2015 11:33
MHALL3
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.012
mg/L
0.01
Manganese (Mn)
0.005
mg/L
0.005
Strontium (Sr)
0.059
mg/L
0.005
Zinc (Zn)
0.097
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/15/2015 15:05
MHALL3
Calcium (Ca)
6.14
mg/L
0.01
Magnesium (Mg)
1.86
mg/L
0.005
Potassium (K)
2.06
mg/L
0.1
Sodium (Na)
6.07
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.113
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.047
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.060
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014322
Matrix: GW -WW
Page 8 of 40
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/14/2015 14:16
LSTARL1
25
EPA 300.0
05/19/2015 08:48
BGN9034
1
EPA 300.0
05/19/2015 08:48
BGN9034
1
EPA 245.1
05/14/2015 12:55
ACPAYNE
1
EPA 245.1
05/14/2015 14:11
ACPAYNE
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 11:33
MHALL3
1
EPA 200.7
05/13/2015 13:49
MHALL3
1
EPA 200.7
05/13/2015 13:49
MHALL3
1
EPA 200.7
05/13/2015 13:49
MHALL3
1
EPA 200.7
05/13/2015 13:49
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3
1
EPA 200.7
05/15/2015 15:05
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050306
Site: AMW-3B
Collection Date: 12 -May -15 11:30 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.75
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.77
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.344
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
72
Total Carbon
05/28/2015 11:24
TOC
1.4
TOTAL SUSPENDED SOLIDS
1
TSS
8.0
Page 9 of 40
ug/L
1
1
Sample #:
2015014322
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 11:24
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
0.2
1
EPA 200.8
05/19/2015 13:12
DJSULL1
ug/L
0.3
1
EPA 200.8
05/19/2015 13:12
DJSULL1
Vendor Method V SHEALY
Vendor Method
V_ELE1
mg/L
25 1 SM2540C
05/14/201514:55 AGIBBS5
mg/L
0.1 1 SM5310C/EPA9060A
05/19/201511:50 GHUTCHI
mg/L
5 1 SM2540D
05/13/201511:10 AGIBBS5

Certificate of Laboratory Analysis Page 10 of 40
This report shall not be reproduced, except in full.
Order # J15050306
Site: Equipment Blank
Collection Date: 12 -May -15 2:45 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
05/18/2015 16:49
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/14/2015 12:57
Nitrite + Nitrate (Colorimetric)
0.014
mg-N/L
0.01
INORGANIC IONS BY IC
05/13/2015 13:53
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/15/2015 15:09
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/15/2015 15:09
Calcium (Ca)
0.013
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
05/19/2015 12:40
DJSULL1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015014323
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/14/2015 14:18
LSTARL1
1 EPA 300.0
05/18/2015 16:49
BGN9034
1 EPA 300.0
05/18/2015 16:49
BGN9034
1 EPA 245.1
05/14/2015 12:57
ACPAYNE
1 EPA 200.7
05/13/2015 13:53
MHALL3
1 EPA 200.7
05/13/2015 13:53
MHALL3
1 EPA 200.7
05/13/2015 13:53
MHALL3
1 EPA 200.7
05/13/2015 13:53
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.7
05/15/2015 15:09
MHALL3
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
1 EPA 200.8
05/19/2015 12:40
DJSULL1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis Page 11 of 40
This report shall not be reproduced, except in full.
Order # J15050306
Site: Equipment Blank
Collection Date: 12-Mav-15 2:45 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015014323
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/14/201514:55 AGIBBS5
TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 05/19/2015 11:50 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/13/2015 11:10 AGIBBS5

Certificate of Laboratory Analysis Page 12 of 40
This report shall not be reproduced, except in full.
Order # J15050306
Site: Filter Blank
Collection Date: 12 -May -15 2:45 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
05/14/2015 14:13
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/13/2015 11:52
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
05/28/2015 11:15
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015014324
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
05/14/2015 14:13
ACPAYNE
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.7
05/13/2015 11:52
MHALL3
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1
1
EPA 200.8
05/28/2015 11:15
DJSULL1

MIR
m, 8�� One
REPORT OF ANALYSES
Page 13 of 40
Element One lnc.
6319-D Carolina Beach Rd.
Wilmington, NC 26412
Phone: [phone]
Fax: [phone]
el lab0el lab.corn
Duke Energy
May 20, 2015
Laboratory Services
Client Project Name AB GW
Assessment water Asheville
13339 Hagers Ferry Road Bld. MG03A
Client Project Number J15050306
Huntersville, NC 28078
PO Number
Sample Matrix
Sample Type Grab
Date Received
05/14/2015
Date Analyzed 05/15/2015
Method
SM 4500 Sz- D
Time Received
1635
Delivered by FedEx
Received by
JRC
eOne ID Duke Energy ID
Parameter
Result Unit Dil
DL Date
Time
Sampled
Sampled
24770-1 MW -10
Sulfide
< 0.1 mg/L 1
0.1 05/12115
1150
24770-2 AMW-3A
Sulfide
< 0.1 mg/L 1
0.1 05/12/15
0950
24770-3 AMW-3B
Sulfide
< 0.1 mg/L 1
0.1 05/12/15
1130
24770-4 Equipment Blank
Sulfide
< 0.1 mg/L 1
0.1 05/12115
1445
-A �
Ken Smith, Laboratory Director
24770 Duke Report Packet.doc Compiled byltl�
NC Certifications: DW 37788 and DWQ DENR 604

Page 14 of 40
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elementOne
SAMPLE SUBMISSION FORM
Lab 09"24170
Collection Time Analysis Requested
TAT 7 BD
MW -10
Analysis Due Date
05.15.15
Hold Time Expiration
05.1915 @ 0950
Report Due Date
05.26.15
Client: Duke Energy
AMW-3B
Date Rec:
05.14.15
LIMS No J15050306
Equipment
Time Rec:
1635
Project ID Asheville
Rec By
JRC
H >9 Yes
No Temp!5 6°C Yes
No
Ref. Method:
SM4500 S2 D
If No, Record If No, Record
Sample Identification & Collection Information
Lab ID
I Client ID
Collection Date
Collection Time Analysis Requested
1
MW -10
05/12/15
1150 Sulfide
2
AMW-3A
05/12/15
0950 Sulfide
3
AMW-3B
05/12/15
1130 Sulfide
4
Equipment
Blank 05/12/15
1445 Sulfide
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 of 1 Prep By / Date
SS by Labeled By / Date
5/14/201 7:15:45 PM ID Verification By/[ S - `5 -'

X
Y
ug STD
STD
Page 16 of 40
METHOD:
SM 4500 S2- p
0.000
ELEMENT ONE
0.098
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
0.439
UNITS OF ANSWER
U9/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELjqM
5
Lab ID#
24769/764/768/770/713
Na2S•9H2O Lot #
40721
Page 1 of 4
1.0
MAX ALIQUOT
10.00
Date: 05.15.15
STANDARD conc(ppm)
X
Time Analysis Begun 800
Cal Std Lot: WC2-80-5
10
Time Analysis Ended 1300
QC Std Lot: WC2-80-6
2.6614
Analyst: KLS
STD ABSORPTION
Y
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.098
2.50
0.232
5.00
0.439
7.50
0.64
10.00
0.785
o�
AMC
t$�.,�a
Sloe
0,700
Correlation
0.997397391
00s00
SAMP
ABS
ug PER
ALIQUOT
0.400
PREP
VOL in mL
4�
0.300-------------------------
LESS THAN
% SPK REC
SPIKE
LEVEL
0200
.232
0,00
10
10
0=
0.00
700 •M
am om �nm
x
OO
AMC
t$�.,�a
Sloe
0.079327473
Correlation
0.997397391
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
0.0
0.00
10
10
10
<
0
1.0
0.097
0.7588
10
10
10
<
76%
1.0
2.5
0.24
2.6614
10
10
10
0.266
106%
2.5
5
0.45
5.4554
10
10
10
0.546
109%
5.0
7.5
0.661
8.2627
10
10
10
0.826
110%
7.5
10.00
0.815
10.3116
10
10
10
1.031
103%
10.00
24769-1
0.007
-0.4387
10
10
10
24769-1 dup
0.002
-0.5052
10
10
10
NA
24769-1 spk
0.365
4.3245
10
10
10
0.432
86%
5.0
24769-2
0.008
-0.4254
10
10
10
<
24769-2 spk
0.346
4.0717
10
10
10
0.407
81%
5.0
24769-3
0.006
-0.4520
10
10
10
a� ,
24769-3 spk
0.406
4.8700
10
10
10
0.487
97%
5.0
24769-4
0.002
-0.5052
10
10
24769-4 spk
0.438
5.2957
10
10
10
0.530
106%
5.0
24769-5
0.143
1.3708
10
10
10
Q„13
24769-5 spk
0.542
6.6794
10
10
10
0.668
106%
5.0
24769-6
0.004
-0.4786
10
10
10
24769-6 spk
0.452
5.4820
10
10
10
0.548
110%
5.0
24769-7
0.299
3.4463
10
10
10
0 $45
24769-7 spk
0.719
9.0344
10
10
10
0.903
112%
5.0
24769-8
0.001
-0.5185
10
10
10
24769-8 spk
0.438
5.2957
10
10
10
0.530
106%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.444
5.3755
10
10
10
0.538
108%
5.0
Submiffed for QA/QC-
Date:
5.15.15
By: (Print)
KLS
'gn):

Page 17 of 40
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELu
5
Lab ID#
24769/764/768/770/713
05.15.15
800
1300
KLS
-----------------
°
Na2S•9H2O Lot #
40721
Page 2 of 4
--
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: WC2-80-5
1 QC Std Lot: WC2-80-6
STD ABSORPTION
10.00
X
10
Y
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
ug STD
SOLUTION
STD
ABS
omo
-. _ ---- - - - -- - - - - --
�o�
0.00
1.00
2.50
5.00
7.50
10.00
0.000
°�
�z5o
°�°
o.�
0.098
0.232
0.300
QiW
-- - - -- ----- -- --
73Y
0.439
°+DO
0.64
0.785
°.x.00
7.00
400
6A0
x
am low
+zW
gyp;
Sloe
0.079327473 Correlation
0.897397391
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS LESS THAN
ug/mL % SPK REC
SPIKE
LEVEL
24770-1
OAO
0.0000
10
10
10
24770-1 dup
0.001
-0.5185
10
10
10
<Q;1_
NA
24770-1 s k
0.389
4.6438
10
10
10
0.464
93%
5.0
24770-2
0.004 -
-0.4786
10
10
10
-
24770-2 spk
0.448
5.4288
10
10
10
0.543
109%
5.0
24770-3
0.028
-0.1593 '
10
10
10<'Q,T
., •'
24770-3 spk
0.435
5.2558
10
10
10
0.526
105%
5.0
24770-4
0
0.0000
10
10
10'�`-
24770-4 spk
0.44
5.3223
10
10
10
0.532
106%
5.0
24768-1
0.001
-0.5185
10
10
10
24768-1 s k
0.423
5.0961
10
10
10
0.510
102%
5.0
24768-2
0.001
-0.5185
10
10
10
r
24768-2 spk
0.426
5.1361
10
10
10
0.514
103%
5.0
24768-3
0.001
-0.5185
10
10
10
S 0:'1. `
24768-3 spk
0.399
4.7768
10
10
10
0.478
96%
5.0
24768-4
0.003
-0.4919
10
10
10
24768-4 spk
0.377
4.4841
10
10
10
0.448
90%
5.0
24768-5
0.003
-0.4919
10
10
10"
24768-5 spk
0.443
5.3622
10
10
10
0.536
107%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.442
5.3489
10
10
10
0.535
107%
5.0
Submiffed for QA/QC-
Date:
5.15.15
By: (Print)
KLS i

Page 18 of 40
METHOD:
SM 4500 S2- D
ELEMENT ONE
0.079327473
ELEMENT ASSAY:
Sulfide
Spectrophotometer
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
ALI in mL
TAKEN
Wave Length 664
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
24769/764/768/770/713
10
MAX ALIQUOT
10.00
Date:
05.15.15
Na2S•9H2O Lot #
STANDARD conc(ppm)
_
X
Time Analysis Begun
800
40721
Cal Std Lot: WC2-80-5
10
Time Analysis Ended
1300
24764-1 s k
IQC Std Lot: WC2-80-6
4.9099
Analyst:
KLS
Page 3 of 4
STD ABSORPTION
Y
X
Y
0
0.0000
-
ug STD
STD 0.�
SOLUTION
ABS 010 --- -----
- -- - - -
- -
__ ,oma
0.00
0.000 °`°°
��
106%
5.0
24764-3
1.00
0.098 0400
°.
10
----330
-sem
2.50
13.E -- ----- --
0.232 13.20° 2021000
-
24764-3 s k
-,�
5.00
0.439 0,00
10
10
0.406
7.50
0.64 u.000.m 2130
4130 6.00
e00 moo
1200
10.00
I
0.785
x
<
11 T �,
i
Sloe
0.079327473
Correlation
0.997397391
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
24764-1
0.00
0.0000
10
10
10
24764-1 dup
0.001
-0.5185
10
10
10
< 01;
NA
24764-1 s k
0.409
4.9099
10
10
10
0.491
98%
5.0
24764-2
0
0.0000
10
10
10
24764-2 s k
0.44
5.3223
10
10
10
0.532
106%
5.0
24764-3
0
0.0000
10
10
10
<
24764-3 s k
0.345
4.0584
10
10
10
0.406
81%
5.0
24764-4
0.033
-0.0927
10
10
10
<
24764-4 s k
0.343
4.0318
10
10
10
0.403
81%
5.0
24764-5
0.027
-0.1726
10
10
10
<
24764-5 spk
0.307
3.5528
10
10
10
0.355
71%
5.0
234764-6
0.004
-0.4786
10
10
10
24764-6 s k
0.442
5.3489
10
10
10
0.535
107%
5.0
24764-7
0.062
0.2931
10
10
10
24764-7 s k
0.391
4.6704
10
10
10
0.467
93%
5.0
24764-8
0
0.0000
10
10
10
< 1 fi`
24764-8 s k
0.411
4.9365
10
10
10
0.494
99%
5.0
24764-9
0.001
-0.5185
10
10
10
24764-9 s k
0.37
4.3910
10
10
10
0.439
88%
5.0
24764-10
0.004
-0.4786
10
10
10
24764-10 s k
0.365
4.3245
10
10
10
0.432
86%
5.0
24764-11
0.004
-0.4786
10
10
10�
,s
24764-11 spk
0.368
4.3644
10
10
10
0.436
87%
5.0
24764-12
0.008
-0.4254
10
10
10
<
24764-12 spk
0.319
3.7124
10
10
10
0.371
74%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.442
5.3489
10
10
10
0.535
107% 1
5.0
Subn'llffed for QA/QC-
Date:
5.15.15
By: (Print)
KLS
ign):
__..-
i

Page 19 of 40
METHOD: SM 4500 S2- D ELEMENT ONE
ELEMENT ASSAY: Sulfide Spectrophotometer UNITS OF ANSWER ug/mL
Wave Length 664 DETECTION LIMIT u 1.000
CLIENT: Duke SPK LEVELWW 5
Lab ID# 24769/764/768/770/713 MAX ALIQUOT 10.00
Date: 05.15.15 Na2S•9H2O Lot # STANDARD conc(ppm) X
Time Analysis Begun 800 40721 ICal Std Lot: WC2-80-5 10
Time Analysis Ended 1300 1 QC Std Lot: WC2-80-6
Analyst: KLS Page 4 of 4 STD ABSORPTION Y
X Y
ug STD STD
SOLUTION ABS ° - - - - - - -- - - - -- - -- -- - - o�
0.00 0.000
°.w0
1.00 0.098 ° 100 43s s oo
r_-- ____._..___ -.-___..._--. - _._--_ _.. _.-_-__-.____-__ _._-. �•�so
2.50 0.232 ° zoo .232
5.00 0.439 °
7.50 0.64
°.°° 200 400 6.o0 B.W 10.00 12M
10.00 0.785 x
Sloe
0.079327473
Correlation
0.997397391
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
24769-2
0.00
-0.5052
10
10
5
<
24769-2 spk
0.323
3.7657
10
10
5
0.753
75%
5.0
24764-3
0.005
-0.4653
10
10
5
<
24764-3 s k
0.349
4.1116
10
10
5
0.822
82%
5.0
24764-4
0.017
-0.3056
10
10
5
<
24764-4 s k
0.352
4.1515
10
10
5
0.830
83%
5.0
24764-5
0.005
-0.4653
10
10
5
<
24764-5 s k
0.345
4.0584
10
10
5
0.812
81%
5.0
24764-12
0.032
-0.1060
10
10
5
<
24764-12 s k
0.331
3.8721
10
10
5
0.774
77%
5.0
24769-2
0.00
-0.5052
10
10
2
0:5
24769-2 s k
0.364
4.3112
10
10
2
2.156
86%
5.0
24764-3
0.005
-0.4653
10
10
2
24764-3 s k
0.362
4.2845
10
10
2
2.142
86%
5.0
24764-4
0.005
-0.4653
10
10
2
24764-4 s k
0.364
4.3112
10
10
2
2.156
86%
5.0
24764-5
0.007
-0.4387
10
10
2
24764-5 s k
0.365
4.3245
10
10
2
2.162
86%
5.0
24764-12
0.005
-0.4653
10
10
2
<
24764-12 s k
0.332
3.8854
10
10
2
1.943
78%
5.0
24764-12
0.003
-0.4919
10
10
1
K f0",.
24764-12 s k
0.347
4.0850
10
10
1
4.085
82%
5.0
24713
0.006
-0.4520
10
10
1
<
24713 s k
0.302
3.4863
10
10
1
3.486
70%
5.0
24713
0.004
-0.4786
10
10
0.5
4,
24713 s k
0.344
4.0451
10
10
0.5
8.090
81%
5.0
Blank
0
0.0000
10
10
10
1 <
QC
0.44
5.3223
10
10
10
1 0.532
106%
5.0
Submitted for &A/QC-
Date:
5.15.15
By: (Print)
KLS
sig ):

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050306
Lot Number:QE14048
Date Completed:05/21/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QE14048*
Shealy Environmental Services, Inc. Page: 1 of 12
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE14048
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050306
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE14048
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050306
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015014320
Aqueous
05/12/20151150
05/14/2015
002
2015014321
Aqueous
05/12/2015 0950
05/14/2015
003
2015014322
Aqueous
05/12/20151130
05/14/2015
004
2015014323
Aqueous
05/12/20151445
05/14/2015
(4 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QE14048
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050306
Sample Sample ID Matrix Parameter Method Result Q Units Page
001
2015014320
Aqueous
Methane
RSK - 175
230
ug/L
6
002
2015014321
Aqueous
Alkalinity
SM 2320B-
440
mg/L
7
002
2015014321
Aqueous
Bicarbonate Alkalinity
SM 2320B-
30
mg/L
7
002
2015014321
Aqueous
Carbonate Alkalinity
SM 2320B-
350
mg/L
7
003
2015014322
Aqueous
Alkalinity
SM 2320B-
33
mg/L
9
003
2015014322
Aqueous
Bicarbonate Alkalinity
SM 2320B-
33
mg/L
9
(6 detections)
Shealy Environmental Services, Inc. Page: 4 of 12
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE14048-001
Description: 2015014320 Matrix: Aqueous
Date Sampled:05/12/2015 1150 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/15/2015 1433
HMA 75007
1
(Bicarbonate ) SM 2320B-2011
1 05/15/2015 1433
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/15/2015 1433
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 12
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE14048-001
Description: 2015014320 Matrix: Aqueous
Date Sampled:05/12/2015 1150 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/18/2015 2154 DCS 75271
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 230 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE14048-002
Description: 2015014321 Matrix: Aqueous
Date Sampled:05/12/2015 0950 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/15/2015 1445
HMA 75007
1
(Bicarbonate ) SM 2320B-2011
1 05/15/2015 1445
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/15/2015 1445
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
440
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
30
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
350
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE14048-002
Description: 2015014321 Matrix: Aqueous
Date Sampled:05/12/2015 0950 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/18/2015 2213 DCS 75271
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE14048-003
Description: 2015014322 Matrix: Aqueous
Date Sampled:05/12/2015 1130 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/15/2015 1501
HMA 75007
1
(Bicarbonate ) SM 2320B-2011
1 05/15/2015 1501
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/15/2015 1501
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
33
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
33
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 12
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Methane
Client: Duke Energy Laboratory ID: QE14048-003
Description: 2015014322 Matrix: Aqueous
Date Sampled:05/12/2015 1130 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/18/2015 2225 DCS 75271
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE14048-004
Description: 2015014323 Matrix: Aqueous
Date Sampled:05/12/2015 1445 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/15/2015 1506
HMA 75007
1
(Bicarbonate ) SM 2320B-2011
1 05/15/2015 1506
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/15/2015 1506
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE14048-004
Description: 2015014323 Matrix: Aqueous
Date Sampled:05/12/2015 1445 Project Name: AB GW Assessment Water -
Date Received: 05/14/2015 Project Number: J15050306
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/18/2015 2237 DCS 75271
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ75007-001 Matrix: Aqueous
Batch: 75007
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/15/20151344
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ75007-002 Matrix: Aqueous
Batch: 75007
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 91 1 91 90-110 05/15/20151350
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75271-001 Matrix: Aqueous
Batch: 75271
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/18/20151935
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75271-002 Matrix: Aqueous
Batch: 75271
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 120 1 78 70-130 05/18/20151726
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75271-003 Matrix: Aqueous
Batch: 75271
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 110 1 74 5.6 70-130 30 05/18/20151827
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE14048
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
bio ly Hnvinanmeniul wevic y Ino.
131w m m. t Nnmb!r F -AD -014
11486.66 Nurnher 13
1041
Its;Axrt Daly: I V0714
Etre jV4: Aate! 4 +30VI $
Sample Receipt Checklist (SRC.)
Client. Cooler rn8pected hy:�date-
Meads of rcccitpt:
yesu I Tvn
teSES1 ❑ C-_ ient [I UPS ❑ I;etiRx 0 Airbome Exp 2r Other
1. Wets custody seals pres=t on clic cooler?
Yes Nn r] IIIA Z 12. If ca$tody seals were presellit, were they intact and uabzuken?
Cooler ID/Orig"i l temperature upon rxeiptiDerived (cormctesd) temperature upm receipt:
I A _ 4c 1 I tc,� � °c r �C
Method: ❑ Temperatum Blank 'A ilwr Boltics IR Gun ID: IR Gun Corret-tion Factor_ .Q � �G
McLhod of wolant: �Wct lee ❑ Blue ici} Dry Ice _❑ None
3. If renVtirature of any cooler exceeded 45.4°C, was Proj eel Manager iiintified?
Yo ❑ No L] NA aePM notified by SDRC, phone, note (circle ane), other:
{For coolers received via xm iiemial ouurier, PMs = to be not1 ficd
irnmiediate.l .
Yep ❑ Na ❑
AIA 4. ix the commercial courier's packing s4 attached to this form?
Yes No ❑
rS. Were er cusindy prmeduro,; relin uishcd1xcc6vcd) followod?
Yes No ❑
NA Vof 5a WEtsamples relinqui&hed by client to commercial comicr?
YesNo ❑
6, W= stplc IQs listed cm the (X)C?
Yes Ne ❑
?, Were satin lc IDs Listed on all sample containers?
Yes NQ ❑
Was Cha eetkan date & Lune lisltxl ion the OOC?
Yes YU ❑
9. Was cotection date & time listed o.1i ;711 own le cunlwiiers7
ifcs No ❑
10. Did all coatWnu label information TD, date, time;} agree %ith the Coe?
ycwo No
11 _ Wffm tests to be pedmmed listai on the COC"
Yes No
12. Did all as ni les arrive in the propci ountai iam for each TEA?
Yes N,� ❑
13. Laid all containers arrive ill card gcxtditim unbroken, lids oai„ etc, ?
yes N -o ❑
14. Was adcquate .%anti le vulanw available?
Yrrc Nn ❑
Yes I No
15, Were a 1 sainp1m rert IN ed within'A the holding tune tar 49 hours, whichever
Conies first?
16. Were a iLy coon lcs ocartainas wisAu .
Yes ❑ No
irks ❑ No Ur14TA
17_ Were tl ete arly exem smples not ]riled on COC'
❑ 1S. Were b ibbles prcstmt >t -size" ',G"or #im, m in <limetGr to any VOA vials.?
Yes Q No ❑
-NAa I5 - WQM. all metals O&C MEM;'nutlicat samples. received at. a pH of<2?
Yes ❑ No ❑
NA 2G. W= all cyanide andior sulflrlc sarnplczs rceoivcd at a H -}127
Yes 0 No ❑
NA 21. Were till applicable NHYI'i N/cya iide/phenol (<0 2ra1geL) sanipic;s free of
Pd residual Chlorine?
Yes ❑ No
14A E7 1 22. Wor sx►llQctian tears res dMrlmeaited on the COC for NC samples?
Yes ❑ Na ❑
23. Were r. icnt remark.%'rzque,z.-, (i.e, reclu"ed dilhltions-1+4'&OASD designatiom,
NA Fr etc,..) COrroctly transcribed frr11n the Coe into the oomrlwmt Section iia LrMS?
Yes NoC7
24. Was t - quote number used taken from the couluilmr_label'?
SaMple Preservmtrion 1uxt. be rn luted for any sample(s) iln�conwtly prescrrrsd or with hsadspacc.)
Samplc(s) were reoeived i=vrmutly pro ned and were adjusted
accordingly in ssrn le receiving with :cuCla HNO3 HC.NaOH using SR
sample(s)
wemreceiyed Aith bubbles >6 IItn1indiameter_
8111 l @}
mere retie ved. with TRC 50.2 u)V1- (If 921 is No
SC Drinlang Water Project Saalap e(s) pH verified to be !� 2 by Date.
sample(s) -areve not rtpeived ata p14 of<2 and were adjusted alccordinoy using SR?
'Sample labels applied
b -- Vetificd by- Datc:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY Rr:!CORD AND ANALYSIS REQUEST FORM
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ELEMENTS by lCV (FAMt:
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ELEMENTS by lCV (FAMt:
Al. R8, H. FS, Mn, Br,Zwt
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