The URL can be used to link to this page

Home My WebLink AboutNC0000396_J15050094 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15050094 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101 161) 3106 30 13 06. : : Report Authorized By: 2015.Date; (Signature) -04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/30/2015 1 of 65 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2 of 65 2015013411 ASHEVILLE 04 -May -15 2:00 PM Russo Well Equipment Blank 2015013412 ASHEVILLE 04 -May -15 2:30 PM Russo Well MW -24 SB 1-2 2015013413 ASHEVILLE 05 -May -15 9:45 AM Russo Well MW -24 SB 15-16 2015013414 ASHEVILLE 05 -May -15 10:00 AM Russo Well MW -24 SB 30-32 4 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 3of65 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 6/30/2015 Certificate of Laboratory Analysis 4 of 65 This report shall not be reproduced, except in full. Order # J15050094 Site: Well Equipment Blank Collection Date: 04 -May -15 2:00 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015013411 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050094 Site: Well MW -24 SB 1-2 Collection Date: 04-Mav-15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 65 Sample #: 2015013412 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050094 Site: Well MW -24 SB 15-16 Collection Date: 05-Mav-15 9:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 65 Sample #: 2015013413 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050094 Site: Well MW -24 SB 30-32 Collection Date: 05-Mav-15 10:00 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 65 Sample #: 2015013414 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE -- Additional Information -- Sample 2015013414 is missing total metals results. The vendor is unable to locate additional sample to complete this test. SPLP Sulfate blank is 3.1 mg/L. Sample results are less than 10 times that contained in the blank and should be considered suspect. MG -K 6/30/2015 aceAnaiXical www.pacelabs.com June 23, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 Kigc&y.O�e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 06, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 57 lacmnalyfica( www.pacelabs.com Project: J15050094 Pace Project No.: 92248772 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Pace Analytical Services, Inc. 9800 Kinf6e. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 57 aceAnaiXical www.pacelabs.com Project: J15050094 Pace Project No.: 92248772 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 )i6c8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 57 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15050094 Pace Project No.: 92248772 Lab ID Sample ID Matrix Date Collected Date Received 92248772001 2015013411 Water 05/04/1514:00 05/06/1517:10 92248772002 2015013412 Solid 05/04/1514:30 05/06/1517:10 92248772003 2015013413 Solid 05/05/15 09:45 05/06/15 17:10 92248772004 2015013414 Solid 05/05/1510:00 05/06/1517:10 92248772005 2015013413 SPLP Water 05/05/15 09:45 05/06/15 17:10 92248772006 2015013414 SPLP Water 05/05/15 10:00 05/06/15 17:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 )iyc8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 57 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15050094 92248772 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92248772001 2015013411 EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92248772002 2015013412 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248772003 2015013413 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248772004 2015013414 ASTM D2974-87 KTS 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9060 TJJ 6 PASI-G 92248772005 2015013413 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A DM 1 PASI-M 92248772006 2015013414 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 57 aceAnaiXical www.pacelabs.com Project: J15050094 Pace Project No.: 92248772 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 Kligc8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92248772001 2015013411 EPA 6020A Aluminum 619 ug/L 10.0 05/14/15 15:01 EPA 6020A Antimony 0.17J ug/L 0.50 05/14/15 15:01 EPA 6020A Barium 9.0 ug/L 0.30 05/14/15 15:01 EPA 6020A Calcium 522 ug/L 40.0 05/14/15 15:01 EPA 6020A Chromium 2.7 ug/L 0.50 05/14/15 15:01 EPA 6020A Cobalt 12.0 ug/L 0.50 05/14/15 15:01 EPA 6020A Copper 2.0 ug/L 1.0 05/14/15 15:01 EPA 6020A Iron 1730 ug/L 50.0 05/14/15 15:01 EPA 6020A Lead 0.40 ug/L 0.10 05/15/15 09:02 EPA 6020A Magnesium 343 ug/L 10.0 05/14/15 15:01 EPA 6020A Manganese 23.5 ug/L 0.50 05/14/15 15:01 EPA 6020A Molybdenum 0.77 ug/L 0.50 05/14/15 15:01 EPA 6020A Nickel 1.4 ug/L 0.50 05/14/15 15:01 EPA 6020A Potassium 433 ug/L 50.0 05/14/15 15:01 EPA 6020A Sodium 112 ug/L 50.0 05/14/15 15:01 EPA 6020A Strontium 1.4 ug/L 0.50 05/14/15 15:01 EPA 6020A Thallium 0.025J ug/L 0.10 05/14/15 15:01 EPA 6020A Vanadium 1.3 ug/L 1.0 05/14/15 15:01 EPA 6020A Zinc 7.0 ug/L 5.0 05/14/15 15:01 92248772002 2015013412 EPA 6010 Aluminum 21500 mg/kg 34.9 05/17/15 05:53 EPA 6010 Barium 125 mg/kg 3.5 05/17/15 05:53 EPA 6010 Beryllium 1.9 mg/kg 0.70 05/17/15 19:00 EPA 6010 Boron 36.6 mg/kg 34.9 05/17/15 19:00 EPA 6010 Calcium 1020 mg/kg 174 05/17/15 05:53 EPA 6010 Chromium 48.6 mg/kg 3.5 05/17/15 19:00 EPA 6010 Copper 33.8 mg/kg 3.5 05/17/15 19:00 EPA 6010 Iron 35100 mg/kg 14.0 05/17/15 05:53 EPA 6010 Magnesium 5430 mg/kg 174 05/17/15 05:53 EPA 6010 Manganese 728 mg/kg 3.5 05/17/15 19:00 EPA 6010 Nickel 21.9 mg/kg 3.5 05/17/15 19:00 EPA 6010 Potassium 3900 mg/kg 349 05/17/15 05:53 EPA 6010 Strontium 6.8 mg/kg 3.5 05/17/15 05:53 EPA 6010 Zinc 101 mg/kg 14.0 05/17/15 19:00 EPA 6020 Arsenic 4.6J mg/kg 7.0 05/16/15 16:48 EPA 6020 Cobalt 40.2 mg/kg 7.0 05/16/15 16:48 EPA 6020 Lead 37.5 mg/kg 7.0 05/16/15 16:48 EPA 6020 Selenium 7.0 mg/kg 7.0 05/16/15 16:48 EPA 6020 Vanadium 66.4 mg/kg 7.0 05/16/15 16:48 EPA 7471 Mercury 0.030 mg/kg 0.011 05/15/15 17:08 ASTM D2974-87 Percent Moisture 26.3 % 0.10 05/29/15 10:07 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 05/12/15 10:30 EPA 9060 Total Organic Carbon 6390 mg/kg 811 06/22/15 11:58 EPA 9060 Total Organic Carbon 7400 mg/kg 815 06/22/15 12:04 EPA 9060 Total Organic Carbon 8070 mg/kg 813 06/22/15 12:10 EPA 9060 Total Organic Carbon 5920 mg/kg 820 06/22/15 12:16 EPA 9060 Mean Total Organic Carbon 6940 mg/kg 815 06/22/15 11:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. H1 H3 Qualifiers Page 6 of 57 aceAnaiXical www.pacelabs.com Project: J15050094 Pace Project No.: 92248772 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli ,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92248772002 2015013412 EPA 9060 RSD% 14.0 % 06/22/15 11:58 92248772003 2015013413 EPA 6010 Aluminum 45500 mg/kg 62.9 05/17/15 19:04 EPA 6010 Barium 347 mg/kg 6.3 05/17/15 19:04 EPA 6010 Beryllium 4.4 mg/kg 0.63 05/17/15 19:04 EPA 6010 Boron 54.9 mg/kg 31.4 05/17/15 19:04 EPA 6010 Calcium 231J mg/kg 314 05/17/1519:04 EPA 6010 Chromium 71.7 mg/kg 3.1 05/17/15 19:04 EPA 6010 Copper 52.6 mg/kg 3.1 05/17/15 19:04 EPA 6010 Iron 60000 mg/kg 25.1 05/17/15 19:04 EPA 6010 Magnesium 15400 mg/kg 314 05/17/15 19:04 EPA 6010 Manganese 725 mg/kg 3.1 05/17/15 19:04 EPA 6010 Nickel 27.7 mg/kg 3.1 05/17/15 19:04 EPA 6010 Potassium 13600 mg/kg 629 05/17/15 19:04 EPA 6010 Strontium 5.9J mg/kg 6.3 05/17/15 19:04 EPA 6010 Zinc 199 mg/kg 12.6 05/17/15 19:04 EPA 6020 Cobalt 83.4 mg/kg 6.3 05/16/15 16:51 EPA 6020 Lead 9.8 mg/kg 6.3 05/16/15 16:51 EPA 6020 Selenium 4.6J mg/kg 6.3 05/16/15 16:51 EPA 6020 Vanadium 77.4 mg/kg 6.3 05/16/15 16:51 ASTM D2974-87 Percent Moisture 18.6 % 0.10 05/29/15 10:08 EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 05/14/15 12:30 EPA 300.0 Sulfate 3.9 mg/L 2.5 05/22/15 17:00 B EPA 353.2 Nitrogen, Nitrate 0.30 mg/L 0.25 05/28/15 20:25 H1 EPA 9060 Total Organic Carbon 693J mg/kg 744 05/29/15 18:25 EPA 9060 Total Organic Carbon 793 mg/kg 730 05/29/15 18:31 EPA 9060 Total Organic Carbon 829 mg/kg 743 05/29/15 18:38 EPA 9060 Total Organic Carbon 671J mg/kg 734 05/29/15 18:45 EPA 9060 Mean Total Organic Carbon 747 mg/kg 738 05/29/15 18:25 EPA 9060 RSD% 10.3 % 05/29/15 18:25 92248772004 2015013414 ASTM D2974-87 Percent Moisture 36.2 % 0.10 06/03/15 15:03 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 05/14/15 12:30 EPA 300.0 Sulfate 4.8 mg/L 3.1 05/22/15 17:13 B EPA 353.2 Nitrogen, Nitrate 0.39 mg/L 0.31 05/28/15 20:29 H1 EPA 9060 Total Organic Carbon 520J mg/kg 940 05/29/15 18:57 EPA 9060 Total Organic Carbon 867J mg/kg 935 05/29/15 19:03 EPA 9060 Total Organic Carbon 951 mg/kg 933 05/29/15 19:10 EPA 9060 Mean Total Organic Carbon 695J mg/kg 936 05/29/15 18:51 EPA 9060 RSD% 36.2 % 05/29/15 18:51 92248772005 2015013413 SPLP EPA 6020A Aluminum 92.3 ug/L 10.0 05/29/15 17:01 EPA 6020A Barium 122 ug/L 0.30 05/29/15 17:01 EPA 6020A Boron 74.7 ug/L 5.0 05/29/15 17:01 EPA 6020A Calcium 301 ug/L 40.0 05/29/15 17:01 EPA 6020A Chromium 0.52 ug/L 0.50 05/29/15 17:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 7 of 57 aceAnaiXical www.pacelabs.com Project: J15050094 Pace Project No.: 92248772 Lab Sample ID Method Client Sample ID Parameters 92248772005 2015013413 SPLP EPA 6020A Cobalt EPA 6020A Copper EPA 6020A Iron EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Nickel EPA 6020A Potassium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Zinc 92248772006 2015013414 SPLP EPA 6020A Aluminum EPA 6020A Barium EPA 6020A Boron EPA 6020A Calcium EPA 6020A Chromium EPA 6020A Cobalt EPA 6020A Copper EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Nickel EPA 6020A Potassium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Zinc Pace Analytical Services, Inc. 9800 f igc8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 1.3 ug/L 0.50 05/29/1517:01 0.65J ug/L 1.0 05/29/1517:01 133 ug/L 50.0 05/29/1517:01 0.080J ug/L 0.10 05/29/1517:01 191 ug/L 10.0 05/29/1517:01 31.7 ug/L 0.50 05/29/1517:01 0.35J ug/L 0.50 05/29/1517:01 144 ug/L 50.0 05/29/1517:01 2190 ug/L 50.0 05/29/1517:01 4.7 ug/L 0.50 05/29/1517:01 31.1 ug/L 5.0 05/29/1517:01 4AJ ug/L 10.0 05/29/1517:06 93.5 ug/L 0.30 05/29/1517:06 36.1 ug/L 5.0 05/29/1517:06 291 ug/L 40.0 05/29/1517:06 0.48J ug/L 0.50 05/29/1517:06 1.4 ug/L 0.50 05/29/1517:06 3.1 ug/L 1.0 05/29/1517:06 0.16 ug/L 0.10 05/29/1517:06 248 ug/L 10.0 05/29/1517:06 85.8 ug/L 0.50 05/29/1517:06 0.56 ug/L 0.50 05/29/1517:06 414 ug/L 50.0 05/29/1517:06 1400 ug/L 50.0 05/29/1517:06 4.3 ug/L 0.50 05/29/1517:06 19.0 ug/L 5.0 05/29/1517:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 )igc&y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24119 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92248729001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1212835) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium • Potassium • MSD (Lab ID: 1212836) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 23, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14775 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 Kligc&y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24120 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92248729001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1212839) • Cobalt • Selenium • Vanadium • MSD (Lab ID: 1212840) • Antimony • Cobalt • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffii�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 23, 2015 Analyte Comments: QC Batch: MPRP/24120 N2: The lab does not hold TNI accreditation for this parameter. •2015013412 (Lab ID: 92248772002) • Antimony •2015013413 (Lab ID: 92248772003) • Antimony • BLANK (Lab ID: 1212837) • Antimony • LCS (Lab ID: 1212838) • Antimony • MS (Lab ID: 1212839) • Antimony • MSD (Lab ID: 1212840) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KPi ,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251147009 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1977700) • Boron • MSD (Lab ID: 1977701) • Boron Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 �nic8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KQc&y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KS,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015013412 (Lab ID: 92248772002) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37394 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1456144) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23020 B: Analyte was detected in the associated method blank. • BLANK for HBN 264920 [WETA/230 (Lab ID: 1465540) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KPi ,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015013413 (Lab ID: 92248772003) •2015013414 (Lab ID: 92248772004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 tf� ,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46256 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015013412 (Lab ID: 92248772002) • Chloride • Sulfate •2015013413 (Lab ID: 92248772003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 KPi ,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015013412 (Lab ID: 92248772002) •2015013413 (Lab ID: 92248772003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 57 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15050094 Pace Project No.: 92248772 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 23, 2015 Pace Analytical Services, Inc. 9800 %,8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015013412 (Lab ID: 92248772002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 tri '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013411 Lab ID: 92248772001 Collected: 05/04/15 14:00 Received: 05/06/15 17:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/23/2015 10:45 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 619 ug/L 10.0 3.0 1 05/14/1510:57 05/14/1515:01 7429-90-5 0.17J ug/L 0.50 0.15 1 05/14/1510:57 05/14/1515:01 7440-36-0 ND ug/L 0.50 0.11 1 05/14/1510:57 05/14/1515:01 7440-38-2 9.0 ug/L 0.30 0.081 1 05/14/1510:57 05/14/1515:01 7440-39-3 ND ug/L 0.20 0.067 1 05/14/1510:57 05/14/1515:01 7440-41-7 ND ug/L 5.0 1.1 1 05/14/1510:57 05/14/1515:01 7440-42-8 ND ug/L 0.080 0.024 1 05/14/1510:57 05/14/1515:01 7440-43-9 522 ug/L 40.0 16.0 1 05/14/1510:57 05/14/1515:01 7440-70-2 2.7 ug/L 0.50 0.17 1 05/14/1510:57 05/14/1515:01 7440-47-3 12.0 ug/L 0.50 0.13 1 05/14/1510:57 05/14/1515:01 7440-48-4 2.0 ug/L 1.0 0.21 1 05/14/1510:57 05/14/1515:01 7440-50-8 1730 ug/L 50.0 13.7 1 05/14/1510:57 05/14/1515:01 7439-89-6 0.40 ug/L 0.10 0.046 1 05/14/15 10:57 05/15/15 09:02 7439-92-1 343 ug/L 10.0 3.2 1 05/14/1510:57 05/14/1515:01 7439-95-4 23.5 ug/L 0.50 0.24 1 05/14/1510:57 05/14/1515:01 7439-96-5 0.77 ug/L 0.50 0.094 1 05/14/1510:57 05/14/1515:01 7439-98-7 1.4 ug/L 0.50 0.16 1 05/14/1510:57 05/14/1515:01 7440-02-0 433 ug/L 50.0 11.7 1 05/14/1510:57 05/14/1515:01 7440-09-7 ND ug/L 0.50 0.20 1 05/14/1510:57 05/14/1515:01 7782-49-2 112 ug/L 50.0 16.3 1 05/14/1510:57 05/14/1515:01 7440-23-5 1.4 ug/L 0.50 0.13 1 05/14/1510:57 05/14/1515:01 7440-24-6 0.025J ug/L 0.10 0.015 1 05/14/1510:57 05/14/1515:01 7440-28-0 1.3 ug/L 1.0 0.28 1 05/14/1510:57 05/14/1515:01 7440-62-2 7.0 ug/L 5.0 2.4 1 05/14/1510:57 05/14/1515:01 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/11/15 12:15 05/12/15 20:14 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 K3inic8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013412 Lab ID: 92248772002 Collected: 05/04/15 14:30 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/23/2015 10:45 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 21500 mg/kg 34.9 17.4 5 05/15/15 10:58 05/17/15 05:53 7429-90-5 125 mg/kg 3.5 1.7 5 05/15/15 10:58 05/17/15 05:53 7440-39-3 1.9 mg/kg 0.70 0.35 10 05/15/1510:58 05/17/1519:00 7440-41-7 36.6 mg/kg 34.9 17.4 10 05/15/1510:58 05/17/1519:00 7440-42-8 1020 mg/kg 174 87.2 5 05/15/15 10:58 05/17/15 05:53 7440-70-2 48.6 mg/kg 3.5 1.7 10 05/15/1510:58 05/17/1519:00 7440-47-3 33.8 mg/kg 3.5 1.7 10 05/15/1510:58 05/17/1519:00 7440-50-8 35100 mg/kg 14.0 7.0 5 05/15/15 10:58 05/17/15 05:53 7439-89-6 5430 mg/kg 174 87.2 5 05/15/15 10:58 05/17/15 05:53 7439-95-4 728 mg/kg 3.5 1.7 10 05/15/1510:58 05/17/1519:00 7439-96-5 ND mg/kg 7.0 3.5 10 05/15/1510:58 05/17/1519:00 7439-98-7 21.9 mg/kg 3.5 1.7 10 05/15/1510:58 05/17/1519:00 7440-02-0 3900 mg/kg 349 174 5 05/15/15 10:58 05/17/15 05:53 7440-09-7 ND mg/kg 349 174 5 05/15/15 10:58 05/17/15 05:53 7440-23-5 6.8 mg/kg 3.5 1.7 5 05/15/15 10:58 05/17/15 05:53 7440-24-6 101 mg/kg 14.0 7.0 10 05/15/1510:58 05/17/1519:00 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7440-36-0 4.6J mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7440-38-2 ND mg/kg 0.84 0.42 100 05/15/1510:58 05/16/1516:48 7440-43-9 40.2 mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7440-48-4 37.5 mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7439-92-1 7.0 mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7782-49-2 ND mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7440-28-0 66.4 mg/kg 7.0 3.5 100 05/15/1510:58 05/16/1516:48 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.030 mg/kg 0.011 0.0055 1 05/15/1511:16 05/15/1517:08 7439-97-6 Analytical Method: ASTM D2974-87 26.3 % 0.10 0.10 1 05/29/1510:07 Analytical Method: EPA 9045 6.4 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 333 167 5 ND mg/kg 333 167 5 Analytical Method: EPA 9056 ND mg/kg 33.3 16.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [t'1.' 11 f oaf 6' i D191f, N2 I:fl 05/11/15 02:34 16887-00-6 D3 05/11/15 02:34 14808-79-8 D3 05/11/15 02:34 14797-55-8 H3 Page 24 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 �Q%Y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 Sample: 2015013412 Lab ID: 92248772002 Collected: 05/04/15 14:30 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 6390 mg/kg 811 405 1 06/22/15 11:58 7440-44-0 Total Organic Carbon 7400 mg/kg 815 407 1 06/22/15 12:04 7440-44-0 Total Organic Carbon 8070 mg/kg 813 407 1 06/22/15 12:10 7440-44-0 Total Organic Carbon 5920 mg/kg 820 410 1 06/22/15 12:16 7440-44-0 Mean Total Organic Carbon 6940 mg/kg 815 407 1 06/22/15 11:58 7440-44-0 H3 Surrogates RSD% 14.0 % 1 06/22/1511:58 Date: 06/23/2015 10:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 KS'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013413 Lab ID: 92248772003 Collected: 05/05/15 09:45 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/23/2015 10:45 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 45500 mg/kg 62.9 31.4 10 05/15/1510:58 05/17/1519:04 7429-90-5 347 mg/kg 6.3 3.1 10 05/15/1510:58 05/17/1519:04 7440-39-3 4.4 mg/kg 0.63 0.31 10 05/15/1510:58 05/17/1519:04 7440-41-7 54.9 mg/kg 31.4 15.7 10 05/15/1510:58 05/17/1519:04 7440-42-8 231J mg/kg 314 157 10 05/15/1510:58 05/17/1519:04 7440-70-2 71.7 mg/kg 3.1 1.6 10 05/15/1510:58 05/17/1519:04 7440-47-3 52.6 mg/kg 3.1 1.6 10 05/15/1510:58 05/17/1519:04 7440-50-8 60000 mg/kg 25.1 12.6 10 05/15/1510:58 05/17/1519:04 7439-89-6 15400 mg/kg 314 157 10 05/15/1510:58 05/17/1519:04 7439-95-4 725 mg/kg 3.1 1.6 10 05/15/1510:58 05/17/1519:04 7439-96-5 ND mg/kg 6.3 3.1 10 05/15/1510:58 05/17/1519:04 7439-98-7 27.7 mg/kg 3.1 1.6 10 05/15/1510:58 05/17/1519:04 7440-02-0 13600 mg/kg 629 314 10 05/15/1510:58 05/17/1519:04 7440-09-7 ND mg/kg 629 314 10 05/15/1510:58 05/17/1519:04 7440-23-5 5.91 mg/kg 6.3 3.1 10 05/15/1510:58 05/17/1519:04 7440-24-6 199 mg/kg 12.6 6.3 10 05/15/1510:58 05/17/1519:04 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7440-36-0 ND mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7440-38-2 ND mg/kg 0.75 0.38 100 05/15/1510:58 05/16/1516:51 7440-43-9 83.4 mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7440-48-4 9.8 mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7439-92-1 4.6J mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7782-49-2 ND mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7440-28-0 77.4 mg/kg 6.3 3.1 100 05/15/1510:58 05/16/1516:51 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.010 0.0051 1 05/15/1511:16 05/15/1517:15 7439-97-6 Analytical Method: ASTM D2974-87 18.6 % 0.10 0.10 1 05/29/1510:08 Analytical Method: EPA 9045 5.3 Std. Units 0.10 0.10 1 05/14/15 12:30 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45 3.9 mg/L 2.5 1.2 1 05/22/1517:00 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45 0.30 mg/L 0.25 0.25 1 05/28/15 20:25 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 05/14/15 03:45 ND mg/L 6.1 3.1 1 05/21/15 05:21 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 t 4'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 Sample: 2015013413 Lab ID: 92248772003 Collected: 05/05/15 09:45 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 61.5 30.8 1 05/11/15 02:56 16887-00-6 D3 Sulfate ND mg/kg 61.5 30.8 1 05/11/15 02:56 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 6.1 3.1 1 05/11/15 02:56 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 693J mg/kg 744 372 1 05/29/15 18:25 7440-44-0 Total Organic Carbon 793 mg/kg 730 365 1 05/29/15 18:31 7440-44-0 Total Organic Carbon 829 mg/kg 743 371 1 05/29/15 18:38 7440-44-0 Total Organic Carbon 671J mg/kg 734 367 1 05/29/15 18:45 7440-44-0 Mean Total Organic Carbon 747 mg/kg 738 369 1 05/29/15 18:25 7440-44-0 Surrogates RSD% 10.3 % 1 05/29/1518:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 Kai '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013414 Lab ID: 92248772004 Collected: 05/05/15 10:00 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Surrogates RSD% Date: 06/23/2015 10:45 AM Analytical Method: ASTM D2974-87 36.2 % 0.10 0.10 1 06/03/1515:03 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 05/14/15 12:30 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45 4.8 mg/L 3.1 1.6 1 05/22/1517:13 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45 0.39 mg/L 0.31 0.31 1 05/28/15 20:29 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 05/14/15 03:45 ND mg/L 7.8 3.9 1 05/21/15 05:22 16887-00-6 Analytical Method: EPA 9060 ND mg/kg 934 467 1 05/29/1518:51 7440-44-0 520J mg/kg 940 470 1 05/29/1518:57 7440-44-0 867J mg/kg 935 467 1 05/29/1519:03 7440-44-0 951 mg/kg 933 467 1 05/29/1519:10 7440-44-0 695J mg/kg 936 468 1 05/29/1518:51 7440-44-0 36.2 % 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 Kai '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013413 SPLP Lab ID: 92248772005 Collected: 05/05/15 09:45 Received: 05/06/15 17:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/23/2015 10:45 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 92.3 ug/L 10.0 3.0 1 05/28/15 21:12 05/29/15 17:01 7429-90-5 ND ug/L 0.50 0.15 1 05/28/15 21:12 05/29/15 17:01 7440-36-0 ND ug/L 0.50 0.11 1 05/28/15 21:12 05/29/15 17:01 7440-38-2 122 ug/L 0.30 0.081 1 05/28/15 21:12 05/29/15 17:01 7440-39-3 ND ug/L 0.20 0.067 1 05/28/15 21:12 05/29/15 17:01 7440-41-7 74.7 ug/L 5.0 1.1 1 05/28/15 21:12 05/29/15 17:01 7440-42-8 ND ug/L 0.080 0.024 1 05/28/15 21:12 05/29/15 17:01 7440-43-9 301 ug/L 40.0 16.0 1 05/28/15 21:12 05/29/15 17:01 7440-70-2 0.52 ug/L 0.50 0.17 1 05/28/15 21:12 05/29/15 17:01 7440-47-3 1.3 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 17:01 7440-48-4 0.65J ug/L 1.0 0.21 1 05/28/15 21:12 05/29/15 17:01 7440-50-8 133 ug/L 50.0 13.7 1 05/28/15 21:12 05/29/15 17:01 7439-89-6 0.0801 ug/L 0.10 0.046 1 05/28/15 21:12 05/29/15 17:01 7439-92-1 191 ug/L 10.0 3.2 1 05/28/15 21:12 05/29/15 17:01 7439-95-4 31.7 ug/L 0.50 0.24 1 05/28/15 21:12 05/29/15 17:01 7439-96-5 ND ug/L 0.50 0.094 1 05/28/15 21:12 05/29/15 17:01 7439-98-7 0.35J ug/L 0.50 0.16 1 05/28/15 21:12 05/29/15 17:01 7440-02-0 144 ug/L 50.0 11.7 1 05/28/15 21:12 05/29/15 17:01 7440-09-7 ND ug/L 0.50 0.20 1 05/28/15 21:12 05/29/15 17:01 7782-49-2 2190 ug/L 50.0 16.3 1 05/28/15 21:12 05/29/15 17:01 7440-23-5 4.7 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 17:01 7440-24-6 ND ug/L 0.10 0.015 1 05/28/15 21:12 05/29/15 17:01 7440-28-0 ND ug/L 1.0 0.28 1 05/28/15 21:12 05/29/15 17:01 7440-62-2 31.1 ug/L 5.0 2.4 1 05/28/15 21:12 05/29/15 17:01 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:43 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 57 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015013414 SPLP Lab ID: 92248772006 Collected: 05/05/15 10:00 Received: 05/06/15 17:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/23/2015 10:45 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 4AJ ug/L 10.0 3.0 1 05/28/15 21:12 05/29/15 17:06 7429-90-5 ND ug/L 0.50 0.15 1 05/28/15 21:12 05/29/15 17:06 7440-36-0 ND ug/L 0.50 0.11 1 05/28/15 21:12 05/29/15 17:06 7440-38-2 93.5 ug/L 0.30 0.081 1 05/28/15 21:12 05/29/15 17:06 7440-39-3 ND ug/L 0.20 0.067 1 05/28/15 21:12 05/29/15 17:06 7440-41-7 36.1 ug/L 5.0 1.1 1 05/28/15 21:12 05/29/15 17:06 7440-42-8 ND ug/L 0.080 0.024 1 05/28/15 21:12 05/29/15 17:06 7440-43-9 291 ug/L 40.0 16.0 1 05/28/15 21:12 05/29/15 17:06 7440-70-2 0.48J ug/L 0.50 0.17 1 05/28/15 21:12 05/29/15 17:06 7440-47-3 1.4 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 17:06 7440-48-4 3.1 ug/L 1.0 0.21 1 05/28/15 21:12 05/29/15 17:06 7440-50-8 ND ug/L 50.0 13.7 1 05/28/15 21:12 05/29/15 17:06 7439-89-6 0.16 ug/L 0.10 0.046 1 05/28/15 21:12 05/29/15 17:06 7439-92-1 248 ug/L 10.0 3.2 1 05/28/15 21:12 05/29/15 17:06 7439-95-4 85.8 ug/L 0.50 0.24 1 05/28/15 21:12 05/29/15 17:06 7439-96-5 ND ug/L 0.50 0.094 1 05/28/15 21:12 05/29/15 17:06 7439-98-7 0.56 ug/L 0.50 0.16 1 05/28/15 21:12 05/29/15 17:06 7440-02-0 414 ug/L 50.0 11.7 1 05/28/15 21:12 05/29/15 17:06 7440-09-7 ND ug/L 0.50 0.20 1 05/28/15 21:12 05/29/15 17:06 7782-49-2 1400 ug/L 50.0 16.3 1 05/28/15 21:12 05/29/15 17:06 7440-23-5 4.3 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 17:06 7440-24-6 ND ug/L 0.10 0.015 1 05/28/15 21:12 05/29/15 17:06 7440-28-0 ND ug/L 1.0 0.28 1 05/28/15 21:12 05/29/15 17:06 7440-62-2 19.0 ug/L 5.0 2.4 1 05/28/15 21:12 05/29/15 17:06 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:46 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: MERP/13477 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92248772001 METHOD BLANK: 1960289 Matrix: Water Associated Lab Samples: 92248772001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/12/1519:55 LABORATORY CONTROL SAMPLE: 1960290 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.5 110 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1961286 1961287 MS MSD 92248767008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.037J 5 5 5.6 5.3 112 106 80-120 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: MERP/13677 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92248772005, 92248772006 METHOD BLANK: 1977489 Matrix: Water Associated Lab Samples: 92248772005, 92248772006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/01/1513:04 LABORATORY CONTROL SAMPLE: 1977490 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1980282 1980283 MS MSD 92251147009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.1 103 102 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: MERP/5713 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92248772002, 92248772003 METHOD BLANK: 1212857 Matrix: Solid Associated Lab Samples: 92248772002, 92248772003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 05/15/1516:49 LABORATORY CONTROL SAMPLE: 1212858 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.077 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212859 1212860 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .116 .121 0.11 0.12 95 96 80-120 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: MPRP/24119 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92248772002, 92248772003 METHOD BLANK: 1212833 Associated Lab Samples: 92248772002, 92248772003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.1 05/17/15 04:53 ND 0.51 05/17/15 04:53 ND 0.051 05/17/15 04:53 ND 2.6 05/17/15 04:53 ND 25.6 05/17/15 04:53 ND 0.26 05/17/15 04:53 ND 0.26 05/17/15 04:53 ND 2.0 05/17/15 04:53 ND 25.6 05/17/15 04:53 ND 0.26 05/17/15 04:53 ND 0.51 05/17/15 04:53 ND 0.26 05/17/15 04:53 ND 51.2 05/17/15 04:53 ND 51.2 05/17/15 04:53 ND 0.51 05/17/15 04:53 ND 1.0 05/17/15 04:53 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1212834 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 126 98 80-120 Barium mg/kg 12.8 13.3 104 80-120 Beryllium mg/kg 1.3 1.3 100 80-120 Boron mg/kg 128 125 98 80-120 Calcium mg/kg 638 632 99 80-120 Chromium mg/kg 12.8 13.0 102 80-120 Copper mg/kg 12.8 12.3 96 80-120 Iron mg/kg 128 118 92 80-120 Magnesium mg/kg 638 626 98 80-120 Manganese mg/kg 12.8 12.5 98 80-120 Molybdenum mg/kg 12.8 13.0 102 80-120 Nickel mg/kg 12.8 13.2 104 80-120 Potassium mg/kg 638 607 95 80-120 Sodium mg/kg 638 639 100 80-120 Strontium mg/kg 12.8 12.6 99 80-120 Zinc mg/kg 63.8 64.9 102 80-120 Pace Analytical Services, Inc. 9800 t�inlc&y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212835 1212836 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 8440 186 185 7760 8580 -368 72 75-125 10 20 M1 Barium mg/kg 123 18.6 18.5 109 117 -78 -33 75-125 7 20 M1 Beryllium mg/kg ND 1.79 1.79 2.1 2.0 110 102 75-125 7 20 Boron mg/kg 14.5J 186 185 211 196 106 98 75-125 7 20 Calcium mg/kg 5840 930 924 7540 8320 182 269 75-125 10 20 M1 Chromium mg/kg ND 18.6 18.5 20.0 18.6 106 99 75-125 7 20 Copper mg/kg 48.6 18.6 18.5 52.4 54.1 20 30 75-125 3 20 M1 Iron mg/kg 15800 186 185 14900 16500 -487 401 75-125 10 20 M1 Magnesium mg/kg 6050 930 924 6150 6680 10 69 75-125 8 20 M1 Manganese mg/kg 101 18.6 18.5 123 116 115 76 75-125 6 20 Molybdenum mg/kg ND 18.6 18.5 18.8 17.8 101 96 75-125 6 20 Nickel mg/kg 3.1 18.6 18.5 22.2 21.1 103 98 75-125 5 20 Potassium mg/kg 3110 930 924 3620 3980 55 94 75-125 9 20 M1 Sodium mg/kg ND 930 924 1100 1040 106 100 75-125 6 20 Strontium mg/kg 18.8 18.6 18.5 36.9 37.1 98 99 75-125 0 20 Zinc mg/kg 31.3 93 92.4 125 121 101 97 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: MPRP/24120 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92248772002, 92248772003 METHOD BLANK: 1212837 Matrix: Solid Associated Lab Samples: 92248772002, 92248772003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 05/16/1516:16 N2 Arsenic mg/kg ND 0.051 05/16/1516:16 Cadmium mg/kg ND 0.0061 05/16/1516:16 Cobalt mg/kg ND 0.051 05/16/1516:16 Lead mg/kg ND 0.051 05/16/1516:16 Selenium mg/kg ND 0.051 05/16/1516:16 Thallium mg/kg ND 0.051 05/16/1516:16 Vanadium mg/kg ND 0.051 05/16/1516:16 Pace Analytical Services, Inc. 9800 %gigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1212838 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.7 103 80-120 N2 Arsenic mg/kg 2.6 2.7 102 80-120 Cadmium mg/kg .26 0.25 95 80-120 Cobalt mg/kg 2.6 2.7 103 80-120 Lead mg/kg 2.6 2.6 100 80-120 Selenium mg/kg 2.6 2.6 98 80-120 Thallium mg/kg 2.6 2.6 101 80-120 Vanadium mg/kg 2.6 2.6 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212839 1212840 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.58 3.87 ND ND 80 66 75-125 20 M6, N2 Arsenic mg/kg ND 3.58 3.87 5.2J 5AJ 87 85 75-125 20 Cadmium mg/kg ND .358 .387 0.47J ND 105 87 75-125 20 Cobalt mg/kg 10.3 3.58 3.87 18.6 15.9 230 144 75-125 15 20 M6 Lead mg/kg ND 3.58 3.87 4.5J 4.9J 88 93 75-125 20 Selenium mg/kg ND 3.58 3.87 4.OJ 4.8J 63 78 75-125 20 M6 Thallium mg/kg ND 3.58 3.87 4.OJ 4.1J 92 88 75-125 20 Vanadium mg/kg 46.6 3.58 3.87 56.3 52.2 269 144 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: MPRP/54390 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92248772001 METHOD BLANK: 1965247 Associated Lab Samples: 92248772001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.30 05/14/1514:25 ND 0.20 05/14/1514:25 ND 5.0 05/14/1514:25 ND 0.080 05/14/1514:25 ND 40.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 1.0 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.10 05/14/1514:25 ND 10.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.10 05/14/1514:25 ND 1.0 05/14/1514:25 ND 5.0 05/14/1514:25 Qualifiers Pace Analytical Services, Inc. 9800 %gigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1965248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.3 102 80-120 Antimony ug/L 80 76.5 96 80-120 Arsenic ug/L 80 81.4 102 80-120 Barium ug/L 80 87.9 110 80-120 Beryllium ug/L 80 80.9 101 80-120 Boron ug/L 80 83.6 105 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 83.1 104 80-120 Cobalt ug/L 80 87.0 109 80-120 Copper ug/L 80 85.1 106 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 LABORATORY CONTROL SAMPLE: 1965248 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 89.3 112 80-120 Magnesium ug/L 1000 986 99 80-120 Manganese ug/L 80 81.3 102 80-120 Molybdenum ug/L 80 82.6 103 80-120 Nickel ug/L 80 82.1 103 80-120 Potassium ug/L 1000 974 97 80-120 Selenium ug/L 80 85.6 107 80-120 Sodium ug/L 1000 1060 106 80-120 Strontium ug/L 80 79.7 100 80-120 Thallium ug/L 80 89.2 112 80-120 Vanadium ug/L 80 80.3 100 80-120 Zinc ug/L 80 85.3 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1965451 1965452 MS MSD 92248767008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 7.3J 80 80 91.5 85.4 105 98 75-125 7 20 Antimony ug/L ND 80 80 77.2 77.8 96 97 75-125 1 20 Arsenic ug/L ND 80 80 83.0 83.5 104 104 75-125 1 20 Barium ug/L 0.111 80 80 81.0 81.7 101 102 75-125 1 20 Beryllium ug/L ND 80 80 82.2 82.2 103 103 75-125 0 20 Boron ug/L ND 80 80 85.2 85.1 106 106 75-125 0 20 Cadmium ug/L ND 80 80 87.2 86.7 109 108 75-125 1 20 Calcium ug/L 43.4 1000 1000 1030 1020 99 98 75-125 1 20 Chromium ug/L ND 80 80 82.0 80.1 102 100 75-125 2 20 Cobalt ug/L ND 80 80 80.5 79.7 101 100 75-125 1 20 Copper ug/L ND 80 80 85.2 85.0 106 106 75-125 0 20 Iron ug/L ND 1000 1000 1110 1070 110 106 75-125 4 20 Lead ug/L ND 80 80 87.3 86.2 109 108 75-125 1 20 Magnesium ug/L 12.2 1000 1000 994 978 98 97 75-125 2 20 Manganese ug/L 0.42J 80 80 79.4 77.4 99 96 75-125 2 20 Molybdenum ug/L ND 80 80 84.5 85.8 106 107 75-125 2 20 Nickel ug/L ND 80 80 82.7 81.6 103 102 75-125 1 20 Potassium ug/L 12.9J 1000 1000 944 922 93 91 75-125 2 20 Selenium ug/L ND 80 80 85.7 83.9 107 105 75-125 2 20 Sodium ug/L 51.5 1000 1000 1030 1000 97 95 75-125 2 20 Strontium ug/L 0.21J 80 80 82.3 84.0 103 105 75-125 2 20 Thallium ug/L ND 80 80 89.9 89.6 112 112 75-125 0 20 Vanadium ug/L ND 80 80 79.4 78.8 99 98 75-125 1 20 Zinc ug/L ND 80 80 85.2 85.4 105 105 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: MPRP/54700 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92248772005, 92248772006 METHOD BLANK: 1977698 Associated Lab Samples: 92248772005, 92248772006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.30 05/29/1516:47 ND 0.20 05/29/1516:47 ND 5.0 05/29/1516:47 ND 0.080 05/29/1516:47 ND 40.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 1.0 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.10 05/29/1516:47 ND 10.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.10 05/29/1516:47 ND 1.0 05/29/1516:47 ND 5.0 05/29/1516:47 Qualifiers Pace Analytical Services, Inc. 9800 %gigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1977699 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 85.4 107 80-120 Antimony ug/L 80 78.9 99 80-120 Arsenic ug/L 80 79.8 100 80-120 Barium ug/L 80 79.2 99 80-120 Beryllium ug/L 80 77.9 97 80-120 Boron ug/L 80 81.4 102 80-120 Cadmium ug/L 80 81.2 102 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 81.9 102 80-120 Cobalt ug/L 80 79.1 99 80-120 Copper ug/L 80 82.4 103 80-120 Iron ug/L 1000 1020 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 LABORATORY CONTROL SAMPLE: 1977699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.4 97 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 83.1 104 80-120 Molybdenum ug/L 80 79.8 100 80-120 Nickel ug/L 80 81.4 102 80-120 Potassium ug/L 1000 1010 101 80-120 Selenium ug/L 80 80.3 100 80-120 Sodium ug/L 1000 975 97 80-120 Strontium ug/L 80 79.5 99 80-120 Thallium ug/L 80 79.0 99 80-120 Vanadium ug/L 80 81.7 102 80-120 Zinc ug/L 80 83.0 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1977700 1977701 MS MSD 92251147009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 230 80 80 317 320 109 112 75-125 1 20 Antimony ug/L ND 80 80 80.4 80.8 100 101 75-125 0 20 Arsenic ug/L ND 80 80 81.4 81.4 102 102 75-125 0 20 Barium ug/L 3.5 80 80 83.5 83.9 100 101 75-125 0 20 Beryllium ug/L ND 80 80 80.8 79.0 101 99 75-125 2 20 Boron ug/L 39.5 80 80 84.1 84.4 56 56 75-125 0 20 M1 Cadmium ug/L ND 80 80 83.0 82.3 104 103 75-125 1 20 Calcium ug/L 229 1000 1000 1270 1250 104 102 75-125 2 20 Chromium ug/L ND 80 80 82.0 83.4 102 104 75-125 2 20 Cobalt ug/L ND 80 80 80.4 80.6 100 101 75-125 0 20 Copper ug/L 2.1 80 80 85.6 85.8 104 105 75-125 0 20 Iron ug/L 138 1000 1000 1160 1170 102 104 75-125 1 20 Lead ug/L 0.37 80 80 80.3 80.0 100 99 75-125 0 20 Magnesium ug/L 20.5 1000 1000 1070 1070 105 105 75-125 0 20 Manganese ug/L 15.1 80 80 98.9 99.4 105 105 75-125 0 20 Molybdenum ug/L ND 80 80 80.9 81.7 101 102 75-125 1 20 Nickel ug/L ND 80 80 81.5 82.9 101 103 75-125 2 20 Potassium ug/L 51.5 1000 1000 1070 1070 101 102 75-125 1 20 Selenium ug/L ND 80 80 82.2 78.4 103 98 75-125 5 20 Sodium ug/L ND 1000 1000 1020 1000 98 96 75-125 1 20 Strontium ug/L 2.2 80 80 82.7 82.9 101 101 75-125 0 20 Thallium ug/L ND 80 80 83.8 83.8 105 105 75-125 0 20 Vanadium ug/L ND 80 80 82.6 83.3 103 104 75-125 1 20 Zinc ug/L ND 80 80 84.0 88.6 100 106 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: PMST/3601 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92248772002, 92248772003 SAMPLE DUPLICATE: 1226807 92248729001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.9 31.7 4 10 SAMPLE DUPLICATE: 1226808 92249101012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 17.5 18.8 8 10 SAMPLE DUPLICATE: 1226809 92250205002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.8 24.1 61 10 D6 SAMPLE DUPLICATE: 1226810 92250058004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 56.5 47.1 18 10 D6 SAMPLE DUPLICATE: 1226811 92250183009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 17.9 20.2 12 10 D6 SAMPLE DUPLICATE: 1226812 92250202004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.4 19.8 2 10 SAMPLE DUPLICATE: 1226813 35189696001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 17.9 18.1 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 SAMPLE DUPLICATE: 1226814 35190238001 Dup Max Parameter Units Result Result RPD RPD Percent Moisture % 48.3 49.4 2 10 Pace Analytical Services, Inc. 9800 %gigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: PMST/11267 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92248772004 Pace Analytical Services, Inc. 9800 %gigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1169344 40115130025 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 21.4 20.4 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: WET/37381 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92248772002 SAMPLE DUPLICATE: 1455884 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1455885 Parameter pH at 25 Degrees C Pace Analytical Services, Inc. 9800 1jiT igy6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 92248424014 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.7 6.7 0 10 H3 92248767006 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 3.8 3.8 0 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: WET/37394 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92248772003, 92248772004 Pace Analytical Services, Inc. 9800 I Qgigy60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1456143 92248850001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.0 7.0 0 10 SAMPLE DUPLICATE: 1456144 92248731008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.6 2 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 I S igy6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/23020 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92248772003, 92248772004 METHOD BLANK: 1465540 Matrix: Water Associated Lab Samples: 92248772003, 92248772004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.1 2.0 05/22/1512:56 LABORATORY CONTROL SAMPLE: 1465541 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.7 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1465542 1465543 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 12.6 31.9 31.9 45.6 45.8 104 104 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1465544 1465545 MS MSD 92248773012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 5.4 25.3 25.3 30.6 30.7 99 100 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 14,8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/23082 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92248772003, 92248772004 METHOD BLANK: 1470182 Matrix: Water Associated Lab Samples: 92248772003, 92248772004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.14 0.020 05/28/15 20:01 Z2 LABORATORY CONTROL SAMPLE: 1470183 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470184 1470185 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.39 4 4 4.2 4.2 97 95 90-110 1 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470186 1470187 MS MSD 92248135012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.31 3.1 3.1 3.3 3.3 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijigc&y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/23009 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92248772003, 92248772004 METHOD BLANK: 1464494 Matrix: Water Associated Lab Samples: 92248772003, 92248772004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/21/15 05:11 LABORATORY CONTROL SAMPLE: 1464495 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1464496 1464497 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 31.9 31.9 33.1 32.7 101 100 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1464498 1464499 MS MSD 92248773012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 25.3 25.3 24.9 25.0 97 97 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/46256 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92248772002, 92248772003 METHOD BLANK: 1209286 1209287 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1209289 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.1 05/10/15 23:43 Sulfate mg/kg ND 49.1 05/10/15 23:43 LABORATORY CONTROL SAMPLE: 1209287 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1209289 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1209288 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 Ijigc&y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 501 493 98 80-120 501 489 98 80-120 92248770006 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 612 578 76 80-120 M1 274J 612 837 92 80-120 92248770006 Dup Units Result Result mg/kg ND ND mg/kg 274J 264J Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/46255 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92248772002, 92248772003 METHOD BLANK: 1209282 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 05/10/15 23:43 LABORATORY CONTROL SAMPLE: 1209283 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.1 49.3 98 80-120 MATRIX SPIKE SAMPLE: 1209285 92248770006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 61.2 57.5 94 80-120 H3 SAMPLE DUPLICATE: 1209284 92248770006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/28618 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92248772003, 92248772004 METHOD BLANK: 1161557 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/29/15 07:56 LABORATORY CONTROL SAMPLE: 1161558 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 112000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161559 1161560 MS MSD 92248735001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 710J 7440 7430 7310 7350 89 89 50-150 0 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161561 1161562 MS MSD 92248767006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 737 7210 7220 7870 7480 99 93 50-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050094 Pace Project No.: 92248772 QC Batch: WETA/29106 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92248772002 METHOD BLANK: 1178536 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/19/15 06:50 LABORATORY CONTROL SAMPLE: 1178537 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1178538 1178539 MS MSD 40115817001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1530 6010 6040 7380 7180 97 94 50-150 3 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1178540 1178541 MS MSD 40115817002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 16000 27600 27800 50500 46000 125 108 50-150 9 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 57 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15050094 Pace Project No.: 92248772 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 ftc8y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14775 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nic8y60�e. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15050094 Pace Project No.: 92248772 ANALYTE QUALIFIERS Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 57 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050094 Pace Project No.: 92248772 Pace Analytical Services, Inc. 9800 �Q%y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92248772002 2015013412 EPA 3050 MPRP/24119 EPA 6010 92248772003 2015013413 EPA 3050 MPRP/24119 EPA 6010 92248772002 2015013412 EPA 3050 MPRP/24120 EPA 6020 92248772003 2015013413 EPA 3050 MPRP/24120 EPA 6020 92248772001 2015013411 EPA 3020 MPRP/54390 EPA 6020A 92248772005 2015013413 SPLP EPA 3020 MPRP/54700 EPA 6020A 92248772006 2015013414 SPLP EPA 3020 MPRP/54700 EPA 6020A 92248772001 2015013411 EPA 7470A MERP/13477 EPA 7470A 92248772005 2015013413 SPLP EPA 7470A MERP/13677 EPA 7470A 92248772006 2015013414 SPLP EPA 7470A MERP/13677 EPA 7470A 92248772002 2015013412 EPA 7471 MERP/5713 EPA 7471 92248772003 2015013413 EPA 7471 MERP/5713 EPA 7471 92248772002 2015013412 ASTM D2974-87 PMST/3601 92248772003 2015013413 ASTM D2974-87 PMST/3601 92248772004 2015013414 ASTM D2974-87 PMST/11267 92248772002 2015013412 EPA 9045 WET/37381 92248772003 2015013413 EPA 9045 WET/37394 92248772004 2015013414 EPA 9045 WET/37394 92248772003 2015013413 EPA 300.0 WETA/23020 92248772004 2015013414 EPA 300.0 WETA/23020 92248772003 2015013413 EPA 353.2 WETA/23082 92248772004 2015013414 EPA 353.2 WETA/23082 92248772003 2015013413 SM 4500 -CI -E WETA/23009 92248772004 2015013414 SM 4500 -CI -E WETA/23009 92248772002 2015013412 EPA 9056 WETA/46256 92248772003 2015013413 EPA 9056 WETA/46256 92248772002 2015013412 EPA 9056 WETA/46255 92248772003 2015013413 EPA 9056 WETA/46255 92248772002 2015013412 EPA 9060 WETA/29106 92248772002 2015013412 EPA 9060 WETA/29107 92248772003 2015013413 EPA 9060 WETA/28618 92248772003 2015013413 EPA 9060 WETA/28721 92248772004 2015013414 EPA 9060 WETA/28618 92248772004 2015013414 EPA 9060 WETA/28721 Date: 06/23/2015 10:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14775 ICP/14775 ICPM/9797 ICPM/9797 ICPM/24266 ICPM/24507 ICPM/24507 MERC/15658 MERC/15927 MERC/15927 MERC/5707 MERC/5707 Page 55 of 57 (�CoAnalj*81' Client Name: uocument: Name: uocument Kevisea: oep[ernuai «..cu 1, le Condition Upon Receipt (SCUEPae 1 of 2 Document Number: Issuing Authority: 63 of 65 F-CHR-CS-003-rev.15 Pace Huntersville Qualit Office Courier: [] Fed Ex ❑ UPS❑ USPSC] Client[] Commere aln" Pace Other Custody Seal on Cooler/Box Present: ❑ yes 'Ey no Seats intact: ❑ yes ❑ no Packing Material: © Bubble VDp [�bble Bags ❑ None ❑ Other Thermometer Used: IR Gun T4401 Type of IceUW% Blue None 4_e'amples on ice, cooling process has began Temn Correction Factor T1401 No Correction Corrected Cooler Temp.: A� 'C Biological Tissue is Frozen: Yes No NIA g Dafe and Initl i o p is a at ining contents Temp should be above freezing to 6°C Comments: Chain of Custody Present: JQYes 0No ❑N/A 1. Chain of Custody Filled Out, 1211ses 0No 11 N/A 2. Chain of Custody Relinquished: ❑ e ©No ❑NIA 3. Sampler Name & Signature on COC: es ❑No ❑NIA 4. Samples Arrived within Hold Time: es ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes 91- o ❑NIA 6. Rush Turn Around Time Requested: Dyes " No ❑NIA 7. Sufficient Volume: PYes ❑No ❑NIA 8. Correct Containers Used: XfYes []No 13 NIA 9. -Pace Containers Used: ©Yes Quo ❑NIA Containers Intact: ❑ :est❑No ❑NI/A 10. Filtered volume received for Dissolved tests ❑Yes ONO 11 d1 11. Sample Labels match COC: ❑ es ❑No ❑NIA 12. -Includes date/timellDlAnalysis Matrix: Ail containers needing preservation have been checked, FYes ❑No ❑N1A 13. All containers needing preservation are found to be in iYes ❑No El NIA compliance with EPA recommendation. exceptions: VOA, coliform, TOC, 0&G, WI -DRO (water) ❑Yes 0No Samples checked for dechlorination: ❑Yes ❑No EJ NIA 14. Headspace in VOA Vials ( >6mm): ❑Yes ❑No _01\11A 15. Trip Blank Present: ❑Yes ❑No Trip Blank Custody Seals Present ❑Yes ❑No ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y ! N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: I Kt& Date: Slick W©# . 92248772 SRF Review: Date: 5 I AIs' Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR 92246772 Certification Office ( i.e out of hold, Incorrect preservative, out of temp, Incorrect containers) Page 56 of 57 t En s x w N m a 4?! "Comp. Z7 O � N N ��Iy�,- , a � I ai oNo CO �a � i x g C k1' ;� o I JTJ Ii m I} ,"Grab Req ire m n n c n �I O - W d R ✓f V% i70 n• n n n n D n a y Z N R' Cu 5 n ` OI 'A -lu pH n y =•' I � k to I • v a N r. M m C n C 1- 8 oz jar (PACE) 5 I 0 X ro ! 0 a' ' j I lik 016 solids :CI) ;Llv "miC1i ; I I i , ! I H ' m J L s v d a ro 0 T 7 5__ ml ! I k I I ;� O 2; of •• ! _i._.l...i.._i._.:_..L..J. J.-.L.1..i._._ .L.1.._,._.;'_C'..._..`..' Q Customer to comprete approprlate colunuta to right � N C M ar.l 12 A M k i i II I I • to a SE M ' I I I I-pi�j 3 p Dt I ' ( M ,5T Z rn c f I I t I ! k 0 0 a il n ni O I 4 m a 4?! "Comp. Z7 O -0 ��Iy�,- , j n 78A�agyS 5° i x g C k1' ;� o I JTJ I} ,"Grab Req ire m a k; O - W 0 3 7r:J i70 � F; Total Metals , Anions, i 00 y c 3 6ca 'v pH n I K_ 0 0 C 9�; I • v a 1- 8 oz jar (PACE) 5 0 X i I "Comp. I j 78A�agyS 5° i x g C k1' >i> ,"Grab Req ire m a k; O - W Total Metals , Anions, pH n I r -i W 1- 8 oz jar (PACE) 5 0 X i I j I lik 016 solids "miC1i o i� !..� TOC 1- 4 oz jara 3 3 C i m (PACE) v 3 0 ' r 0 l (A I 0 ©I..i SPLP - Total Metals i it I i j i Imo: and Anions i I ! 2 - 8 oz jars (PACE) i Sediment specific 1 I!! tests 2- 8 oz jar f (ACCESS q ANALYTICAL) 5 I i i ! z O A z t if - 0 0 rr ED g I Z �d Q 1W Page 5�7 of 57 ' ! '.-K , _ 2 Tolai # of Containers CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST POM SYNTERRA EDI) ------------- ------------------------ Analytical Laboratory Servicos ry so Only I i Work Owder I DUKE mall 'co" M60vu Lgluidding J4060 i mwic SOIL D1S'(RISUT*f4 �, 13339 Hagam Ffflry Rd 3�S�04 - I _ ORIGINAL W LAB, 40� ENERGY. M unlotlsvoft. N. C. AIVIN ;L.W*'Jew n�R I Ti� COPY 10 CL1r:NT 875-6245 , , lb 1 i ma 5�.� � SAMPLAE PORMWO Cjow% Vintu U� 2— PACE Coolar Tam n 4CI PO 1142081 RFV C]ATP TIDUM5 LU 0 CD L PFE&i3FVaHV08 whopo LL64Y1 IMASt be 490 qz' -g < rr added withir, 15 ek1jrUbtAS at sample % Nt a w 4n 7.9 4-k C4 V3 C N Uj !7 LAB USE C'.. to Ua"Collectif)n Intarmation CL M < lrom I 0 _j U7 F I "k ab ID Ahh�t_ got) a- e w z 9 "Sample Description or ID Uwe* T]rTm signatwo It lW43D ti WATER EQUIPMENT BLANK (I PFR t)AYL_ ?1w*jftqqiiMi3;�DoWl Wno ,icepud HV: WWTkma RI'MMMI&M-d Bry_ r"WT-0"d Alaw) ts '�.A O"n" By 5 MWTI "Frwft Moms; AI -Ab, A-8, On, Be-, B, CO3 CRI, Cr. C.% Cu. Fo. Pb. MO, Mnr. Mo. Hl, K, Be. Na. Sr. TI, V, Zn, Mercury, PH Anions- t7f. Nitratu-N. 304 % nairykent Sner If6c Paramews: %Solldit. CBC. PaMicle Size Distributim, Redox PotifflVal 27kvquevt*d Turnaround ,A DWi '7 Deys -46 W